HIGH PERFORMANCE COATINGS

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www.chinacoat.net www.chinacoatcongress.net / 高性能塗料 HIGH PERFORMANCE COATINGS - 定義新一代塗料解決方案 Defining Next Generation of Coating Solutions 水性塗料技術 Waterborne Coating Technologies 多功能材料 和塗料 Multi-functional Materials & Coatings 新型、智能和 高效塗料應用 Novel, Smart & Efficient Coating Applications / VOC 自交聯技術 Zero/Low VOC & Self-Crosslinking Technologies 納米複合 材料應用 Nanocomposites for Coatings 基材與塗層 之間附Adhesion Between Substrate & Coating Prof. Jamil Baghdachi 教授 Dir., BSc, MSc, PhD, PE, Fellows: ACS, MRS 美國東密歇根大學聚合物與涂料科技專業在職教授 上海工程技術大學聚合物與涂料科技客座教授 Professor at Eastern Michigan University, USA Professor of Polymers and Coatings and Guest Professor at the Shanghai University of Engineering Science 會議主席 Conference Chairman 用於輕質和 多基材表面的涂料 Coatings for Lightweighting & Multi-Substrate Surfaces 高性能有機和 金屬涂料 High Performance Organic & Metallic Coatings 新的水和溶劑型 系統添加劑 New Additives for Water & Solvent Based Systems 納米結構涂料 Nanostructured Coatings Shanghai New International Expo Centre A CONFERENCE 中國國際涂料展指定學術會議 18–19.11.2019 上海新國際博覽中心

Transcript of HIGH PERFORMANCE COATINGS

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學術會議資料 ABOUT CONFERENCE

報名 / 查詢 REGISTRATION/ENQUIRIES

www.chinacoat.net www.chinacoatcongress.net/

高性能塗料

HIGH PERFORMANCE COATINGS-定義新一代塗料解決方案

— Defining Next Generation of Coating Solutions

水性塗 料技術 Waterborne Coating

Technologies多功能材料 和塗料

Multi-functional Materials & Coatings

新型、智能和 高效塗料應用 Novel, Smart &

Efficient Coating Applications

零 /低 VOC 和 自交聯技術

Zero/Low VOC & Self-Crosslinking

Technologies納米複合 材料應用

Nanocomposites for Coatings

基材與塗層 之間附着力

Adhesion Between Substrate &

Coating

Prof. Jamil Baghdachi 教授Dir., BSc, MSc, PhD, PE, Fellows: ACS, MRS美國東密歇根大學聚合物與涂料科技專業在職教授

上海工程技術大學聚合物與涂料科技客座教授

Professor at Eastern Michigan University, USAProfessor of Polymers and Coatings and Guest Professor at the Shanghai University of Engineering Science

會議主席 Conference Chairman

用於輕質和 多基材表面的涂料

Coatings for Lightweighting & Multi-Substrate

Surfaces

高性能有機和 金屬涂料

High Performance Organic & Metallic

Coatings新的水和溶劑型 系統添加劑

New Additives for Water & Solvent Based Systems

納米結構涂料 Nanostructured

Coatings

Shanghai New International Expo Centre

A CONFERENCE中國國際涂料展指定學術會議18–19.11.2019 上海新國際博覽中心

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會議日程 CONFERENCE PROGRAMME

18.11.2019 ( 星期一 Monday)

08:30 - 09:15 與會者登記 Registration

第 一 節 SESSION I

09:15 - 10:15 主席致辭 CHAIRMAN ADDRESS

塗料與油漆技術全球趨勢Global Trends in Coatings and Paint Technologies

10:15 - 11:00 論文 PAPER 1

實現更好水性塗料潤濕的不同方法Different Approaches to Achieve a Better Wetting of Waterborne Coatings

11:00 - 11:45 論文 PAPER 2

基於納米二氧化硅防汙表面塗料Silica Nanoparticle-Based Antifouling Surface Coatings

11:45 - 13:00 午餐 LUNCH

第 二 節 SESSION II

13:00 - 13:45 論文 PAPER 3

高性能塗料用創新濕氣固化型乙烯基烷氧基硅烷 聚合物Innovative Moisture Curing Vinyl Alkoxysilane Polymer for High-Performance Coatings

13:45 - 14:30 論文 PAPER 4

如何做到的——水性雙組份聚氨酯塗料理論與實踐How It Works: Waterborne 2K PU Coatings Theory & Practice

14:30 - 15:15 論文 PAPER 5

氟化聚合物(聚偏二氟乙烯)水性塗料Fluoropolymer (PVDF)-Based Waterborne Coatings

15:15 - 15:30 茶歇 COFFEE BREAK

15:30 - 16:15 論文 PAPER 6

獨特的無鈷催化劑 —— 用於改善氧化固化體系 干燥時間及其它附加效益Unique Cobalt-Free Catalyst for Improved Dry Times and Other Added Benefits in Oxidative Cured Systems

16:15 - 17:00 論文 PAPER 7

具有高抗菌功效的含銅玻璃陶瓷Copper-Containing Glass Ceramic with High Antimicrobial Efficacy

17:00 - 17:15 討論環節 Discussion Session

17:15 第一天完 End of Day 1

A CONFERENCE中國國際涂料展指定學術會議

* 論文演講和討論將以英語和普通話進行。All presentation of papers & discussion will be conducted in both English & Chinese (Putonghua).** 主辦單位保留更改主講題目及講者的權利,毋須預先通知。The Organiser reserves the rights to change the programme, paper(s) and / or speakers at any time without prior notice.

19.11.2019 ( 星期二 Tuesday)

12:30 - 13:00 與會者登記 Registration

第 三 節 SESSION III

13:00 - 13:45 論文 PAPER 8

歐盟汽車修補漆面漆 420g/L VOC 標準分析Analysis of EU's 420 g/L VOC Limit for Car Refinish Topcoats

13:45 - 14:30 論文 PAPER 9

蓖麻油基塗料用樹脂的製備和性能研究Synthesis & Properties of Castor Oil-Based Resin for Coatings

14:30 - 15:15 論文 PAPER 10

鈦白粉顏料對塗料光澤保持的多重效應Multiple Effects of TiO2 Pigment on Paint Gloss Retention

15:15 - 15:30 茶歇 COFFEE BREAK

第 四 節 SESSION IV

15:30 - 16:15 論文 PAPER 11

納米透明功能塗料的發展Development of Nanometer Transparent Functional Coatings

16:15 - 17:00 論文 PAPER 12

用於高性能聚氨酯塗料的新型異氰酸酯New Isocyanate for High-Performance Polyurethane Coatings

17:00 - 17:15 討論環節 Discussion Session

17:15 會議結束 End of Conference

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主席致辭 CHAIRMAN ADDRESS塗料與油漆技術全球趨勢Global Trends in Coatings and Paint Technologies近年,塗料、油漆和相關材料的全球趨勢主要集中在兩大領域:高性能多功能塗料及環保材料與工藝。推動這些技術的動力來自它們的經濟價值、技術效益及全球走向生產更安全產品和更環境友好等大勢潮流,同時亦助力開發高性能和高價值塗料材料。這些塗料不僅能作為保護和裝飾性材料,而且遠遠超越傳統塗料定義。這種新開發類別包括高性能和多功能塗料,低 / 零 VOC 超高固體和即備塗料、低能量固化塗料 / 自分層 / 超疏水 / 腐蝕傳感塗料等。本論文將討論高性能和高價值塗料的技術、性能和應用及未來趨勢。

In recent years global trends in coatings, paints and related materials have been in two main areas of high-per formance mult i functional coatings and environmentally friendly materials and processes. Driving forces for these technolog ies have been the recognit ion of the i r economic values, technical benefits and global desire to produce safer products and healthier environment. The result of such movements has been the development of h igh per formance and high-valued coating materials. These coatings not only function as protective and decorative materials, they also push the high performance envelop well beyond traditional definition of coatings. Included in this class of new developments are high performance and multi -functional coatings, low/zero VOC super high sol ids and instant set coatings, low energy cured coatings, self-stratifying, superhydrophobic, and corrosion sensing coatings, etc. This presentation will discuss the technologies, properties, appl icat ions of h igh per formance and h igh va lued coat ings and future trends.

會議日程 CONFERENCE PROGRAMME

Prof. Jamil Baghdachi 教授東密西根大學,美國 上海工程技術大學,中國

Eastern Michigan University, USA Shanghai University of Engineering Science, China

第 一 節 SESSION I 18.11.2019 (星期一 Monday) • 09:15 – 11:45

論文 PAPER 1實現更好水性塗料潤濕的不同方法Different Approaches to Achieve a Better Wetting of Waterborne Coatings 塗料是多組分體系,因此表面 / 介面對其品質有很大影響。表面缺陷經常在塗層施工期間和之後發生,降低塗層光學性和保護基材能力;最常見的缺陷是基材潤濕性差、在非最佳流動下形成桔皮和凹坑現象;影響這些缺陷的一個非常重要參數,就是所涉及材料的表面張力。

潤濕現象是關鍵點之一,特別是在水性塗料中,因為它們的表面張力較高,所以使用適當的潤濕劑變得至關重要。向塗層 / 空氣或塗層 / 基材介面遷移並調整表面或介面張力的添加劑可改善潤濕性。本論文中,我們將討論降低塗層表面張力的常規方法,及通過親水性添加劑增加下層塗層表面能量的第二種方法,這對後續塗層的潤濕具正面影響。

Coatings are multi -component systems and surfaces/interfaces have strong influence on their quality. Surface defects often occur during and after coating application, and degrade both optical properties of the coating and its abil ity to protect the substrate. Most common defects are poor substrate wetting, non-optimal flow (orange peel) and crater formation. One very significant parameter affecting all these defects is the surface tension of the involved materials.

The wett ing phenomenon i s one of the crucial points, especial ly in waterborne coatings, as their surface tension is higher. Consequently, us ing appropr iate wet t ing agent becomes of upmost impor tance. Addit ives that migrate toward the coating/ai r or coat ing/substrate interface and tailor surface or interface tension can improve wetting. In this presentation, we will the discuss both conventional route to decrease surface tension of coating to be applied, and a second route to increase surface energy of an underlying coating by hydrophilic additives, which positively affects wetting of subsequent coating layer.

Dr. Guillaume Jaunky 博士 畢克化學,德國

BYK-Chemie GmbH, Germany

論文 PAPER 2基於納米二氧化硅防汙表面塗料Silica Nanoparticle-Based Antifouling Surface Coatings傳統抗菌策略重點是通過從表面塗料中釋放有毒殺菌劑,針對性殺死污垢物種。目前,業界正在開發更環保防汙塗料,為表面提供更全面污垢保護,而不依靠毒性機制。

採用超親水材料製備的塗料,由於在塗層介面處產生緊密結合的水層而顯出其更有效的防汙性能,該水層能築起一道物理和能量屏障,防止微生物相互作用和附着。這項目使用納米二氧化硅(SiNP)為低成本平臺材料,以用來製備親水性防汙塗料。

採用較大顆粒製備的塗料,呈現增加的納米級粗糙度並顯示增強抗生物污垢性。使用親水性兩性離子化學物質配對表面形狀效應,可產生出色的抗污染性。這項目展示 SiNP 塗層材料的多功能性和可加工性,並突出開發功能化 SiNP 薄膜的潛力,可作廣泛防汙塗層應用。

Where traditional antimicrobial strategies have focused on targeted killing of fouling species through release of toxic biocides from surface coatings, more environmentally friendly antifouling coatings are being developed to provide surfaces with broad-spectrum fouling protection without relying on toxic mechanisms.

Coatings prepared f rom superhydrophi l ic mater ia l s show promis ing antifouling behavior due to a tightly as bound water layer generated at the coating interface. This hydration layer acts a physical and energetic barr ier, preventing microbial interaction and at tachment. Th i s work describes the use of si l ica nanoparticles (SiNP) as a low-cost, platform material for preparation of hydrophilic antifouling coatings.

Coatings prepared from larger particles presented increased nano-scale roughness and showed improved resistance to biological fouling. Pairing sur face topographic ef fects with hydrophi l ic zwit terionic chemistr ies resu l ted in except iona l fou l ing res i s tance. Th i s work demonst rates versati l ity and processabil ity of S iNP coating materials and highlights potent ia l fo r fu r ther deve lopment of funct iona l i sed S iNP f i lms fo r widespread antifouling coating applications.

楊丹博士 Dr. Dan Yang博士后研究員,澳大利亞臥龍崗大學,澳大利亞

Post-doctoral Fellow, University of Wollongong, Australia

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會議日程 CONFERENCE PROGRAMME

論文 PAPER 4如何做到的 — 水性雙組份聚氨酯塗料理論與實踐How It Works: Waterborne 2K PU Coatings Theory & Practice水性雙組份聚氨酯塗料是基於羥基功能化高分子分散體與水可分散多異氰酸酯組成的反應型雙組份塗料。儘管近 20 年來水性雙組份塗料在實踐中已取得巨大成功,但其理論研究一直落後與實踐。一個對水極為敏感的交聯固化體系為何能在水體系中實現?本論文將總結相關學術研究,從理論深層對水性雙組份聚氨酯塗料得以實現做系統總結。

Wate rborne t wo - com pone nt po lyu retha ne coat i ng ( WB -2KPU R) i s a thermoset t ing react ive system compri sed of water-d i spers ib le polyisocyanates crosslinkers and mixed with hydroxy-functional polymers in a water disperse medium that crosslink upon application to a substrate. Despite the fact that practical knowledge regarding formulation and application of WB 2K-PURs has been recognized for the last two decades, minimal scientific information exists that pertain to its fundamental processes. How does a water-sensitive cross-linking reaction work in a water system? This presentation will summarize relevant academic researches and theories of waterborne two-component polyurethane coatings.

王武生教授 Prof. Wang Wusheng安徽大學化學化工學院,中國

Anhui University, China

論文 PAPER 5氟化聚合物 (聚偏二氟乙烯)水性塗料Fluoropolymer (PVDF)-Based Waterborne Coatings白色冷屋頂塗料可反射太陽能,從而可減少使用建築物內的空調,由此可降低發電用的化石燃料和碳排放。PVDF 樹脂基料塗層具有優異的耐候性、耐沾汙性和耐化學性,特別適合白色冷屋頂塗料的應用。本論文將介紹水性 PVDF 乳液在白色冷屋頂塗料領域的應用,該水性乳液既可單獨使用,亦可與水性丙烯酸樹脂混合使用。PVDF 水性乳液製備的塗料可滿足當前 VOC 排放相關環保法規,並同時具有長期耐候性和耐沾汙性能,讓建築外層歷久常新,保持白色冷屋頂熱反射功效,特別適合中國市場應用。

White cool roof coatings can help reduce the use of air conditioning in a building, in turn decreasing carbon footprints. Polyvinylidene fluoride (PVDF)-based coatings are especially suited for cool white roof applications due to their excellent weatherability, dirt pickup resistance and chemical resistance. This presentation wil l introduce cool white roof options for waterborne PVDF emulsion, either alone or blend with waterborne acrylic resins. PVDF-based coatings are especially suited for China market, as they can readily meet current VOC environmental regulations, and also feature long-term weathering and anti-dirt pick performance, which can keep buildings look new and white, therefore keep them cool.

張明先生 Mr. Scott Zhang市業務拓展負責人 阿科瑪中國投資有限公司,中國

Head of Business Development Arkema China Investment Co., Ltd., China

論文 PAPER 6獨特的無鈷催化劑 — 用於改善氧化固化體系干燥時間及其它附加效益Unique Cobalt-Free Catalyst for Improved Dry Times and Other Added Benefits in Oxidative Cured Systems幾十年來,傳統氧化固化體係依賴常規干燥劑,例如鈷和錳。儘管這些表面干燥劑具有效用,但卻存在許多缺點。這些系統可能會遇到泛黃、變色、邊緣干燥時間長,高膜厚度下的皺摺,及諸如未能符合無APEO 和區域法規等要求的問題。本論文將討論一種新型干燥技術,該技術不僅可改善干燥時間、變黃和變色,而且還可只用一個干燥劑就能達到表面干燥及全干燥的效果。

Traditional oxidative cured systems have relied on conventional driers such as Cobalt and Manganese for decades. Although these surface driers are efficient, there are many drawbacks that arise. These systems may encounter yellowing, discoloration, marginal dry time improvement, wrinkling at high film thicknesses, and issues with regulatory demands such as APEO-free and regional compliance. This presentation will discuss a novel drier technology that not only improves dry time, yellowing, and discoloration but may also yield surface-dry and through-dry in one drier.

Ms. Kellie Salerno 女士技術服務專員 博謝思,美國

Technical Service Specialist Borchers Americas, Inc., USA

論文 PAPER 3高性能塗料用創新濕氣固化型乙烯基烷氧基硅烷聚合物Innovative Moisture Curing Vinyl Alkoxysilane Polymer for High-Performance Coatings在海洋和防護塗料應用中,濕氣固化的烷氧基硅氧烷樹脂被越來越多用作不含異氰酸酯的替代品。與雙組分聚氨酯類似,這些體系根據其不同結構和組成能提供適用于廣泛應用的性能特征;然而,由於不利的性價比,商業化的丙烯酸 - 硅氧烷和環氧 - 硅氧烷的市場佔有率有限。本論文將介紹一種結合叔碳酸乙烯酯和乙烯基烷氧基硅烷單體的新聚合物系列,通過優化工藝參數,單體組成和烷氧基硅烷水平,獲得了固體含量在 70%至 100%之間的一系列聚合物,展現出廣泛優異性能及環保安全使用特性。本體系成本合理並且是高度多樣化濕氣固化技術。通過對配置塗料性能評估表明,除了不含異氰酸酯外,它還具有高固含量,快速硬度發展和非常長的保質期。這使這些乙烯基硅烷共聚物在一些面漆應用中成為雙組分聚氨酯和丙烯酸 - 烷氧基硅氧烷的極具吸引力替代品,尤其是在防護塗料中。

Moisture-curing alkoxysiloxane resins have been increasingly used as isocyanate-free alternatives in marine and protective coatings applications. Similar to 2K polyurethanes, these systems display a broad range of performance characteristics, depending on their structure and composition. However, the commercially available alternatives, acrylic- and epoxy-alkoxysiloxane, have seen limited market penetration, due to an unfavourable cost/performance ratio. This paper presents a new family of polymers, which combine vinyl (neo)ester and vinyl alkoxysilane monomers. Variation of process parameters, monomer composition and alkoxysilane levels yielded a series of polymers with solid content between 70 and 100%, and exhibiting a wide scale of attractive properties and improved environmental profile. Performance evaluation of moisture cure coatings based on this cost-efficient and highly versatile technology demonstrates that it brings high solid content, fast hardness development and very long shelf life, in addition to being isocyanate-free. It makes these vinyl silane copolymers an attractive alternative to 2K polyurethanes and acrylic-alkoxysiloxanes for several topcoat applications, especially protective coatings.

Mr. Denis Heymans 先生高級技術主管,瀚森,比利時

Senior Technology Leader, Hexion Research, Belgium

第 二 節 SESSION II 18.11.2019 (星期一 Monday) • 13:00 – 17:15

論文 PAPER 7具有高抗菌功效的含銅玻璃陶瓷Copper-Containing Glass Ceramic with High Antimicrobial Efficacy醫院獲得性感染(HAIs)和產生抗生素耐藥菌株是對人類健康的主要威脅。銅因其高抗菌效力而聞名,包括殺死超級細菌和臭名昭著的ESKAPE 組病原體的能力。我們尋求一種材料能夠保持銅的抗菌功效同時最大限度地減少含銅物質應用時的缺點—成本,外觀和金屬屬性。在這裡,我們描述了銅 – 玻璃陶瓷粉末作為抗菌表面的添加劑 ; 它的機制是基於控制從雙相玻璃陶瓷的水不穩定相中原位形成的赤銅礦納米晶體中釋放銅(I)離子(Cu1+)。依據美國 EPA 測試銅合金表面消毒劑功效的方法進行評估,含有銅 – 玻璃陶瓷粉末的膠乳塗料使金黃色葡萄球菌,銅綠假單胞菌,產氣假單胞菌和大腸桿菌菌落計數減少≥99.9%,接近基準金屬銅。

Hospital acquired infections (HAIs) and the emergence of antibiotic resistant strains are major threats to human health. Copper is well known for its high antimicrobial efficacy, including the ability to kill superbugs and the notorious ESKAPE group of pathogens. We sought a material that maintains the antimicrobial efficacy of copper while minimizing the downsides – cost, appearance and metallic properties – that limit application. Here we describe a copper-glass ceramic powder as an additive for antimicrobial surfaces; its mechanism is based on the controlled release of copper (I) ions (Cu1+) from cuprite nanocrystals that form in situ in the water labile phase of the biphasic glass ceramic. Latex paints containing copper-glass ceramic powder exhibit ≥99.9% reduction in S. aureus, P. aeruginosa, K. aerogenes and E. Coli colony counts when evaluated by the US EPA test method for efficacy of copper-alloy surfaces as sanitizer, approaching that of benchmark metallic copper.

Dr. Joydeep Lahiri 博士部門副總裁兼項目總監 康寧,美國

Division Vice President and Program Director Corning Incorporated, USA

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論文 PAPER 12

論文 PAPER 8

論文 PAPER 11

論文 PAPER 10

論文 PAPER 9

會議日程 CONFERENCE PROGRAMME

用於高性能聚氨酯塗料的新型異氰酸酯New Isocyanate for High-Performance Polyurethane Coatings今天,塗料、粘合劑和材料行業正面臨環境變化的挑戰。塗料是特別需要高性能的一個領域,因為塗層的功能在美學之外主要是為了保護其所施工的基材。聚氨酯塗料,特別是雙組分體系,因其出色的性能,尤其是耐久性和戶外耐候性而受到青睞;聚異氰酸酯作為聚氨酯和聚脲技術的基礎材料,顯然在這趨勢中發揮着重要作用。本論文將介紹兩個研究專案:一是水基系統,另一是溶劑型低 VOC 系統的解決方案,尤指聚脲素產品。

Today's challenges for coatings, adhesives and materials industries are clearly environment oriented. Coatings particularly is one field in which high performance is required since the function of a coating, outside of its aesthetics, is mainly to protect the substrate it is applied on. Polyurethane coatings, especial ly two components systems, are very appreciated for their outstanding performances, especially durabil ity and outdoor weatherability. Polyisocyanates as building blocks for polyurethane and polyurea technology have clearly their role to play in this trend. Two routes will be exposed in this presentation: One dealing with water based system, the other proposing original solutions for solventborne low VOC system, more specifically for polyurea products.

余美娟女士 Ms. Maggie Yu實驗室經理 康睿 ( 上海 ) 貿易有限公司,中國

Lab Manager Vencorex (Shanghai) Trading Company, China

納米透明功能塗料的發展Development of Nanometer Transparent Functional Coatings利用納米粉體和納米技術可製備納米功能塗料,其中最有應用價值的是納米透明功能塗料及相關產品,包括:納米透明隔熱塗料、透明隔熱貼膜、塗膜隔熱玻璃、透明隔熱塑膠板。本論文將講述這些產品所採用的納米粉體原料、製造方法及工藝,各產品達到的性能指標及應用範圍。這些產品雖已有十餘年發展歷史,但近年在中國迅速發展。這些納米透明節能材料在中國有 1000 億人民幣以上的市場需求,值得我們認真 研究、開發與應用。

Nano-functional coatings can be prepared by using nano-powder and nanotechnology. Their most valuable applications are nano-transparent functional coatings and related products, such as nano-transparent thermal insulation coatings, transparent thermal insulation coatings, coated thermal insulation glass, transparent thermal insulation plastic plate. This presentation will talk about nano-powder materials, manufacturing methods and processes used in these products, as well as performance indicators and application ranges achieved by each product. Though these products have seen over 10 years of development, they have been developing rapidly in recent years. The market of nano-transparent energy-saving materials values over RMB¥100 billion in China, therefore worth of delving further research, development and application.

趙石林教授 Prof. Zhao Shilin南京工業大學,中國

Nanjing Tech University, China

www.chinacoat.net www.chinacoatcongress.net/

第 三 節 SESSION III 19.11.2019 (星期二 Tuesday) • 13:00 – 15:15

第 四 節 SESSION IV 19.11.2019 (星期二 Tuesday) • 15:30 – 17:15

鈦白粉顏料對塗料光澤保持的多重效應Multiple Effects of TiO2 Pigment on Paint Gloss Retention大多數塗料中有機基材料會隨着時間推移而分解 — 尤其是暴露在室外的,這種分解導致塗料外觀發生許多變化,尤其是光澤。光澤度下降是一種複雜現象,光澤保持率受許多因素決定,包括許多鈦白粉的顏料特性,其中一些是眾所周知的,而其它則鮮為人知或被誤解。這些經常相互矛盾的效應可使用曝光漆膜發生中的物理和化學變化的綜合模型來解釋。本論文中,我們詳述以上所述的綜合模型並討論相關實驗室數據。

It is well known that the organic binder in most paints will decompose over time — particularly when exposed outdoors. This decomposition causes a change in many impor tant paint appearance at tr ibutes, especia l ly g los s . Glos s los s i s a complex phenomenon, and g los s retention is determined by many factors. These include a number of TiO2 pigment properties, some of which are well recognized, others of which are poorly known or misunderstood. These often conflicting effects can be explained using a comprehensive model of physical and chemical changes that occur in a paint fi lm on exposure. This presentation wil l describe this model and discuss supporting lab data.

Dr. Michael P. Diebold博士科學院士,科慕,美國 Technical Fellow Technology, Chemours Company, USA

歐盟汽車修補漆面漆 420g/L VOC 標準分析Analysis of EU's 420 g/L VOC Limit for Car Refinish Topcoats在制定汽車漆,尤其是汽車修補漆的 VOC 排放標準過程中,歐盟關於汽車修補漆的 VOC 排放標準(Directive 2004/42/CE)得到很高的關注、參考和引用。然而,在市場上和汽車漆行業內部,對這個標準卻缺乏正確理解。本論文將分析和討論 2004/42/CE 中的關於汽車修補漆面漆 420g/L VOC 限值的含義和要點,包括:水性漆 VOC 計算、市場上所謂符合歐盟標準的水性汽車修補漆、用油性高固低粘技術可做出420g/L 的實色面漆和清漆、制定低 VOC 排放標準的要點等。

While producing VOC limits for automotive paint, especially automotive refinish, the EU’s VOC limits for car refinish coatings (Directive 2004/42/CE) is highly recommended and also used as a reference. However, there is lack of understanding about this Directive. This presentation will analyze and discuss key points of 420 g/L VOC limit for car refinish topcoats under the Directive 2004/42/CE, as well as cover the following - calculation of VOC in waterborne paint, the so-called Directive 2004/42/CE compliant refinish found in the market, production of 2K topcoat and 2K clearcoat with VOC < 420g/L and keys to establish a low VOC emission standard.

劉彤舟博士 Dr. TZ Liu總經理 施美克化工有限公司,中國

General Manager Semeka Chemical Co., Ltd., China

蓖麻油基塗料用樹脂的製備和性能研究Synthesis & Properties of Castor Oil-Based Resin for Coatings 蓖麻油及其脂肪酸因同時具有羥基和碳碳雙鍵兩種反應性官能團,常被用作製備聚合物如蓖麻油基聚氨酯、蓖麻油基丙烯酸及環氧樹脂等起始原料。本論文內容主要為新型改性蓖麻油基單體或預聚物的製備,及其在水性聚氨酯分散體和 Michael 加成固化塗料用樹脂中的應用研究。

Because castor oi l (or its fatty acids) carries two reactive functional groups of hydroxyl and carbon-carbon double bonds, it is often used as a starting material for preparing polymers such as polyurethanes, alkylated res ins, epoxy res ins, etc. This presentation wi l l focus on preparation of novel modif ied castor oi l base monomers or prepolymers, as well as application of waterborne polyurethane dispersants and Michael addition reaction curing coatings.申亮教授 Prof. Shen Liang

江西科技師範大學化學化工學院,中國 Jiangxi Science & Technology Normal University, China

Mr. Jerome Douce研發總監 Vencorex, 法國

R&D Director Vencorex, France

Page 6: HIGH PERFORMANCE COATINGS

學術會議資料 ABOUT CONFERENCE

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大學 / 科研機構 University / R&D

其它 Others

地點

上海新國際博覽中心 • E2-M17 二樓夾層會議室

中國上海浦東新區龍陽路 2345 號,郵編:201204

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Venue2/F., Meeting Room E2-M17, Shanghai New International Expo Centre 2345 Longyang Road, Pudong New Area Shanghai, 201204, P.R. China

Registration DiscountEarly Bird Discount: Register and pay before Sep. 20, 2019: 10% off Register and pay before Oct. 18, 2019: 5% off

Group Discount: Register 3 or more delegates from same company/organization: 10% off

Registration ProceduresPlease e-mail / fax completed Registration Form to the Organiser or register online at www.chinacoat.net/regconf

Cancellations50% of Conference fee will be refunded if the acknowledgement of cancellation is received by no later than October 4, 2019. In all cases, the date of postmark, fax or email send record shall apply. Entire Conference fee will be forfeited if delegates cancel their participation after October 4, 2019 or fail to attend without notifying the Organiser. Substitution of delegates is acceptable. All cancellations and/or changes must be notified in writing and will be confirmed by the Organiser. Refunds will be made 14 days after the end of Conference deducting any necessary administration costs.

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標準費用 Standard Fee*

人民幣 RMB¥2,300 (另加6%增值稅 Plus 6% VAT) 美元 US$340

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* 費用包括 Fees Include: 會議論文集及光碟、與會代表名單、出席証書、「第二十四屆中國國際塗料展」入場證及 會刊、午餐及茶點。

Conference Proceedings (Hard Copy and CD), Conference Delegates List, Certificate of Attendance, CHINACOAT2019 Visitor Pass and Show Directory, Lunch and Coffee Breaks.

所有會議資料將於 2019 年 11 月 18 日在現場登記處派發。

All Conference Materials will be distributed on November 18, 2019 at onsite Reception Counter.

A CONFERENCE 中國國際涂料展指定學術會議

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I 海外、香港及台灣地區 OVERSEAS I 中貿推廣-艾特怡國際有限公司 Sinostar-ITE Int'l Ltd. 梁芷晴 小姐 Ms. Rita Leung (852) 2865 0062 [email protected]

I 國內 CHINA I 新展星展覽 ( 深圳 ) 有限公司上海分公司 New Expostar (SZ) Co., Ltd. Shanghai Branch 丁達奇 先生 Mr. Manu Ding (86 21) 5877 7680 x 110 [email protected]

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A CONFERENCE中國國際涂料展指定學術會議18–19.11.2019 上海新國際博覽中心

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