Hetrerogenous reaction
76
Chapter 9 Heterogeneous Reactions
description
Detailed description of heterogenous reaction for observed and true reaction rates
Transcript of Hetrerogenous reaction
Cha
pter
9
Het
erog
eneo
us R
eact
ions
9.1
Het
erog
eneo
us R
eact
ion
in B
iopr
oces
ses
9.2
Con
cent
ratio
n G
radi
ents
and
Rea
ctio
n R
ates
in
Solid
Cat
alys
ts
9.2.
1 Tr
ue a
nd O
bser
ved
Rea
ctio
n R
ates
9.2.
2 In
tera
ctio
n be
twee
n M
ass
Tran
sfer
and
Rea
ctio
n
9.3
Inte
rnal
Mas
s Tr
ansf
er a
nd R
eact
ion
9.3.
1 St
eady
-sta
te S
hell
Mas
s B
alan
ce
9.3.
2 C
once
ntra
tion
Prof
ile: F
irst-o
rder
Kin
etic
s an
d Sp
heric
al G
eom
etry
9.3.
3 C
once
ntra
tion
Prof
ile: Z
ero-
orde
r K
inet
ics
and
Sphe
rical
Geo
met
ry
0
A0
A
0
9.3.
4 C
once
ntra
tion
Prof
ile:
9.3.
5 C
once
ntra
tion
Prof
iles
in O
ther
Sha
pes
9.3.
6 Pr
edic
tion
of O
bser
ved
Rea
ctio
n R
ate
9.4
The
Thie
le M
odul
us a
nd E
ffect
iven
ess
Fact
or
9.4.
1 Fi
rst-o
rder
Kin
etic
s
9.4.
2 Ze
ro-o
rder
Kin
etic
s
9.4.
3 M
icha
elis
-Men
ten
Kin
etic
s
9.4.
4 Th
e O
bser
ved
Thie
le M
odul
us
9.4.
5 W
eisz
’sC
riter
ia
9.4.
6 M
inim
um In
trac
atal
ystS
ubst
rate
Con
cent
ratio
n
9.5
Exte
rnal
Mas
s Tr
ansf
er
9.6
Liqu
id-S
olid
Mas
s-Tr
ansf
er C
orre
latio
ns
9.7
Expe
rimen
tal M
easu
rem
ents
9.7.
1 O
bser
ved
Rea
ctio
n ra
te
9.8
Min
imiz
ing
Mas
s-Tr
ansf
er E
ffect
s
9.8.
1 In
tern
al M
ass
tran
sfer
9.8.
2 Ex
tern
al M
ass
Tran
sfer
9.9
Eval
uatin
g Tr
ue K
inet
ic P
aram
eter
s
1/, (mol min1 per mg enzyme)
1
9.10
Gen
eral
Com
mon
s on
Het
erog
eneo
us R
eact
ion
in B
iopr
oces
sing
Sum
mar
y
