heterocycle compounds Copper-mediated thiolation of ...S1 / S27 Supporting information...
Transcript of heterocycle compounds Copper-mediated thiolation of ...S1 / S27 Supporting information...
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Supporting information
Copper-mediated thiolation of carbazole derivatives and related N-heterocycle compounds
Longzhi Zhu,a Xin Cao,a Renhua Qiu,a,b*Takanori Iwasaki,b Vutukuri Prakash Reddy,b Xinhua Xu,a
Shuang-Feng Yina* and Nobuaki Kambea,b*
aCollege of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, P.R. China;
bDepartment of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan ;
[email protected]; [email protected]; [email protected]
Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2015
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1. Data of 1H NMR and 13C NMR of Compounds of 3a-3l, 5a-5e, 7a-7g, 9 and 1b.
1-(Phenylthio)-9-(pyrimidin-2-yl)-9H-carbazole (3a)
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1-((4-Methylphenyl)thio)-9-(pyrimidin-2-yl)-9H-carbazole(3b)
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1-(4-Chlorophenyl)thio)-9-(pyrimidin-2-yl)-9H-carbazole (3c)
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1-((4-Bromophenyl)thio)-9-(pyrimidin-2-yl)-9H-carbazole (3d)
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1-((4-Methoxyphenyl)thio)-9-(pyrimidin-2-yl)-9H-carbazole (3e)
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1-((2-Nitrophenyl)thio)-9-(pyrimidin-2-yl)-9H-carbazole (3f)
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1-((3-Nitrophenyl)thio)-9-(pyrimidin-2-yl)-9H-carbazole (3g)
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1-((4-Nitrophenyl)thio)-9-(pyrimidin-2-yl)-9H-carbazole (3h)
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1-(Cyclohexylthio)-9-(pyrimidin-2-yl)-9H-carbazole (3i)
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1-(Propylthio)-9-(pyrimidin-2-yl)-9H-carbazole (3j)
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1-(Benzylthio)-9-(pyrimidin-2-yl)-9H-carbazole (3k)
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Methyl 3-((9-(pyrimidin-2-yl)-9H-carbazol-1-yl)thio)propano-ate(3l)
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10-(Phenylthio)benzo[h]quinoline (5a)
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10-((4-Methylphenyl)thio)benzo[h]quinoline (5b)
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10-((4-chlorophenyl)thio)benzo[h]quinoline (5c)
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10-((4-methoxyphenyl)thio)benzo[h]quinoline (5d)
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10-(Propylthio)benzo[h]quinoline (5e)
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2-((Phenylthio)thio)-1-(pyrimidin-2-yl)-1H-indole (7a)
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2-((4-methlphenyl)thio)-1-(pyrimidin-2-yl)-1H-indole (7b)
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2-((4-Methoxyphenyl)thio)-1-(pyrimidin-2-yl)-1H-indole (7c)
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2-((4-Chlorophenyl)thio)-1-(pyrimidin-2-yl)-1H-indole (7d)
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2-((4-Nitroxyphenyl)thio)-1-(pyrimidin-2-yl)-1H-indole (7e)
2-((Benzyl)thio)-1-(pyrimidin-2-yl)-1H-indole (7f)
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2-( Cyclohexylthio)-1-(pyrimidin-2-yl)-1H-indole (7g)
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2-(2-(phenylthio)phenyl)quinolone(9)
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N-Phenyl carbazole (1b)