HAZOP WORKSHEETeia.onep.go.th/images/monitor/1535867288.pdf1. PSV-5802801/5802802. 2....

170
HAZOP WORKSHEET Review Date: 2013-05-22 P/E/A/C Unit: Ethylene Recovery Unit (58) Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58- 024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0) Node: 58-07 Ref. No. Deviation Causes Possible Consequences Existing Safeguards S Remark Action Status L R Action No. Action Required / Recommendations Action By Action Taken 1 No/Less Flow 1.5. Flow control loop failure (FV-5802301) malfunctions closed or mismanaged closed. 1. Increased level in 58D102 leading to potential carryover of liquid C2 to 58E105 and all the way to the compressor/expander (58K101). Potential compressor/expander damage. 1. 58D102 demister. 2. 58D103 with demister. 3. 58D104 with demister. 4. LAH-5802301. A 4 1 2 1.6. Flow control loop failure (FV-5802401) malfunctions closed or mismanaged closed. 1. Increased level in 58D103 leading to potential carryover of liquid C2 to 58D104 and all the way to the compressor/expander (58K101). Potential compressor/expander damage. 1. 58D103 demister. 2. 58D104 with demister. A 4 1 2 58-07.02 Consider providing level alarm high on LT-5802401. EPC 1.7. Strainer (STR-5815) plugging. 1. Less feed to demethanizer leading to less production of C2. Loss of profit. 1. Strainer (STR- 5810/5811) are provided upstream. 2. Strainer (STR-5815) is designed for 400% opening area. A 3 1 2 1.8. Strainer (STR-5816) plugging. 1. Less residue flowrate downstream leading to increased temperature of feed. Less profit due to less C2 production. 1. Strainer (STR-5816) is designed for 400% opening area. 2. PAH-5802802. A 2 1 1 58-07.03 Consider providing pressure low alarm on PI-5802401. EPC 1.9. Strainer (STR-5817) plugging. 1. Less residue flowrate downstream leading to increased temperature of feed. Less profit due to less C2 production. 1. Strainer (STR-5817) is designed for 400% opening area. A 2 1 1 58-07.04 Consider providing pressure low alarm on PI-5802404. EPC 1.10. XV-5800601 malfunctions closed or mismanaged closed. 1. Potential overpressurization of upstream piping and equipment leading to potential rupture and release of C2/C3. Potential fire and explosion leading to potential operator injury. 1. PIC-5800601 opening 2. PV-5800601 to flare. 3. PSV- 5800601/5800602. P 4 1 2 Sheet: 53 of 196

Transcript of HAZOP WORKSHEETeia.onep.go.th/images/monitor/1535867288.pdf1. PSV-5802801/5802802. 2....

Page 1: HAZOP WORKSHEETeia.onep.go.th/images/monitor/1535867288.pdf1. PSV-5802801/5802802. 2. PSV-5802001/5802002. A 4 1 2 58-07.05 Consider providing high pressure alarm on PI-5802806. EPC

HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.5. Flow control loopfailure (FV-5802301)malfunctions closed ormismanaged closed.

1. Increased level in58D102 leading to potentialcarryover of liquid C2 to58E105 and all the way tothe compressor/expander(58K101).Potentialcompressor/expanderdamage.

1. 58D102 demister.2. 58D103 withdemister.3. 58D104 withdemister.4. LAH-5802301. A 4 1 2

1.6. Flow control loopfailure (FV-5802401)malfunctions closed ormismanaged closed.

1. Increased level in58D103 leading to potentialcarryover of liquid C2 to58D104 and all the way tothe compressor/expander(58K101).Potentialcompressor/expanderdamage.

1. 58D103 demister.2. 58D104 withdemister.

A 4 1 2

58-07.02 Consider providing level alarmhigh on LT-5802401.

EPC

1.7. Strainer (STR-5815)plugging.

1. Less feed todemethanizer leading toless production of C2.Loss of profit.

1. Strainer (STR-5810/5811) areprovided upstream.2. Strainer (STR-5815)is designed for 400%opening area.

A 3 1 2

1.8. Strainer (STR-5816)plugging.

1. Less residue flowratedownstream leading toincreased temperature offeed.Less profit due to less C2production.

1. Strainer (STR-5816)is designed for 400%opening area.2. PAH-5802802. A 2 1 1

58-07.03 Consider providing pressurelow alarm on PI-5802401.

EPC

1.9. Strainer (STR-5817)plugging.

1. Less residue flowratedownstream leading toincreased temperature offeed.Less profit due to less C2production.

1. Strainer (STR-5817)is designed for 400%opening area.

A 2 1 1

58-07.04 Consider providing pressurelow alarm on PI-5802404.

EPC

1.10. XV-5800601malfunctions closed ormismanaged closed.

1. Potentialoverpressurization ofupstream piping andequipment leading topotential rupture andrelease of C2/C3.Potential fire and explosionleading to potentialoperator injury.

1. PIC-5800601opening 2. PV-5800601to flare.3. PSV-5800601/5800602.

P 4 1 2

Sheet: 53 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.10. XV-5800601malfunctions closed ormismanaged closed.

2. Potential increased levelin 58D105. No significantconsequence.

1. Increased level in58D105 leading to potentialoverfilling of the drum.Potential carryover ofresidue liquid to residuegas line to cold box.No significantconsequence.

2. Loss of expander liquidflow to the cold box heatexchangers leading tohigher temperature oftreated offgas.Less profit due to less C2recovery.

1. None.

A 2 1 1

Refer to action 58-07.04.

2 More Flow 2.1. Flow control loopfailure (FV-5802101)malfunctions open ormismanaged open.

1. Decreased level in58D101 leading to potentialtreated offgas blowby todemethanizer (58C101).Potential loss of C2 to thedemethanizer overheadstream leading to less C2recovery.Loss of profit.

1. Demethanizer OVHDcondenser (58E106).

A 2 1 1

2.2. Flow control loopfailure (FV-5802301)malfunctions open ormismanaged open.

1. Decreased level in58D102 leading to potentialtreated offgas blowby todemethanizer (58C101).Potential loss of C2 to thedemethanizer overheadstream leading to less C2recovery.Loss of profit.

1. Demethanizer OVHDcondenser (58E106).

A 2 1 1

1.11. Manual valveupstream of strainer(STR-5817)inadvertently closed.

Sheet: 54 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

2 More Flow 2.3. Flow control loopfailure (FV-5802401)malfunctions open ormismanaged open.

1. Decreased level in58D103 leading to potentialtreated offgas blowby todemethanizer (58C101).Potential loss of C2 to thedemethanizer overheadstream leading to less C2recovery.Loss of profit.

1. Demethanizer OVHDcondenser (58E106).

A 2 1 1

2.4. More methanolinjection at 58E101A/B.

1. Potential methanolcontamination leading topotential ethylene productoffspec.

1. Operator training andprocedures.2. Periodic sampling(SC-5821).

A 2 1 1

3 Reverse Flow No cause identified.

4 Misdirected Flow 4.1. Manual valve onethylene vent line to58E004 mismanagedopen.

1. Reduced pressure in58D404 leading to potentialoperational upset.

1. Upstream PIC-5804702.

A 2 1 1

5 Higher Pressure 5.1. PIC-5802002malfunctions closing PV-5802002 when needed.

1. Potential highercompressor/expander(58K101) suction pressure.Potential compressordischarge piping damage.

1. PSV-5802801/5802802.2. PSV-5802001/5802002. A 4 1 2

58-07.05 Consider providing highpressure alarm on PI-5802806.

EPC

1. Increased pressureupstream leading topotential overpressurizationand damage of upstreampiping and equipment.Potential release of HCs toATM leading to potentialfire.Potential operator injury.

1. PIC-5801501 withalarm high.

P 4 1 2

2. Less feed to theexpander (58K101) leadingto loss of fuel gas.Main furnaces in HYVAHL,TGTU, HMU, and Prime Gshutdown.

1. Backup fuel gas fromDCC Unit 53.2. Backup natural gasfrom existing plant. A 4 1 2

5.2. 58D101 demisterplugging.

Sheet: 55 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

5 Higher Pressure 1. Increased pressureupstream leading topotential overpressurizationand damage of upstreampiping and equipment.Potential release of HCs toATM leading to potentialfire.Potential operator injury.

1. PIC-5801501 withalarm high.

P 4 1 2

2. Less feed to theexpander (58K101) leadingto loss of fuel gas.Main furnaces in HYVAHL,TGTU, HMU, and Prime Gshutdown.

1. Backup fuel gas fromDCC Unit 53.2. Backup natural gasfrom existing plant.

A 4 1 2

1. Increased pressureupstream leading topotential overpressurizationand damage of upstreampiping and equipment.Potential release of HCs toATM leading to potentialfire.Potential operator injury.

1. PIC-5801501 withalarm high.

P 4 1 2

2. Less feed to theexpander (58K101) leadingto loss of fuel gas.Main furnaces in HYVAHL,TGTU, HMU, and Prime Gshutdown.

1. Backup fuel gas fromDCC Unit 53.2. Backup natural gasfrom existing plant. A 4 1 2

5.5. PIC-5802403malfunctions closing PV-5802402.

1. High back pressure toexpander discharge leadingto potentialoverpressurization andrupture of upstream pipingand equipment.Potential release of HCs toATM leading to potentialfire.Potential operator injury.

1. PSV-5802702/5802703.2. PAH-5802802.

P 4 1 2

5.3. 58D102 demisterplugging.

5.4. 58D103 demisterplugging.

Sheet: 56 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

5 Higher Pressure 5.5. PIC-5802403malfunctions closing PV-5802402.

2. Loss of cooling media fordownstream heatexchangers potentiallyleading to increasedtemperature of treatedoffgas feed todemethanizer (58C101).Potential reduced efficiencyof the demethanizerleading to less C2recovery.Loss of profit.

1. Demethanizer OVHDcondenser (58E106).

A 2 1 1

3. Due to blocked outlet ofthe expander, there is nodriving force for theexpander whichconsequently stops thecompressor (via commonshaft). No significantconsequence on thecompressor.

5.6. PIC-5800601malfunctions closing PV-5800601 when needed.

1. Potentialoverpressurization ofupstream piping andequipment leading topotential rupture andrelease of C2/C3.Potential fire and explosionleading to potentialoperator injury.

1. PSV-5800601/5800602.

P 4 1 2

58-07.06 Consider high pressure alarmon PI-5802102.

EPC

6 Lower Pressure 1. Loss of residue gas toflare leading to loss of fuelgas.Main furnaces in HYVAHL,TGTU, HMU, and Prime Gshutdown.

1. FAL-5802802.2. Backup fuel gas fromDCC Unit 53.3. Backup natural gasfrom existing plant.

A 4 1 2

Refer to action 58-07.01.

2. Less regeneration gasleading to potentialincomplete regeneration of58R001A/B and58R004A/B and PRUdryers.

1. FAL-5802802.

A 4 1 2

Refer to action 58-07.01.

6.2. PIC-5800601malfunctions openingPV-5800601 when notneeded.

1. Loss of HCs to flareleading to less flow ofinternal recycles 58C002.No significantconsequence.

6.1. PIC-5802002malfunctions openingPV-5802002 when notneeded.

Sheet: 57 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

6 Lower Pressure 1. More flow of residue gasto 58E105 leading toexcessive cooling oftreated offgas.Potential blue ice (NOx)formation in 58D102leading to potential lineplugging or lineembrittlement.Potential explosion.Potential operator injury.

1. TIC-5802403.

P 3 1 2

58-07.07 Consider low temperaturealarm on TI-5802403.

EPC

2. Less pressure inupstream. No significantconsequence.

7 Higher Temperature 1. Higher temperature ofinternal recycle to 58C002potentially leading toincreased temperature oftreated offgas to dryer(58R001A/B).No significantconsequence.

2. More flow back to58D503.No significantconsequence.

1. Higher temperature oftreated offgas tocompressor (58K101)suction leading to highercompressor dischargetemperature.No significantconsequence.

2. Lower temperature ofdry treated offgas from58E101A/B (shell side) toexpander (58K101).Potential blue ice (NOx)formation in the expanderdischarge potentiallyleading to potentialexplosion.Potential operator injury.

1. TIC-5802403.

P 3 1 2

Refer to action 58-07.07.

6.3. PIC-5802403malfunctions fullyopening PV-5802402.

7.1. TIC-5800601malfunctions openingTV-5800601.

7.2. TIC-5802807 fullyclosing TV-5802807B.

Sheet: 58 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

7 Higher Temperature 1. Higher temperature (-80C) of treated offgas toexpander (58K101).No significantconsequence.

2. Lower residue gastemperature to 58E104 andto downstream equipmentup to compressor (58K101)inlet.No significantconsequence.

8 Lower Temperature No additional causeidentified (refer toconsequence in highertemperature).

9 Higher Level 9.1. LIC-5802001D49malfunctionsopening LV-5802001.

1. Potential 2-phase flow inC3R vapor line (6% liquid)leading to potential higherthan normal vibration in theline.No significantconsequence.

9.2. LIC-5802101malfunctions closing FV-5802101 .

1. Increased level in58D101 leading to potentialcarryover of liquid C2 to58E104 and all the way tothe compressor/expander(58K101).Potentialcompressor/expanderdamage.

1. 58D101 demister.2. 58D102 withdemister.3. 58D103 withdemister.4. 58D104 withdemister.5. FAL-5802101.

A 4 1 2

9.3. LIC-5802301malfunctions closing FV-5802301 .

1. Increased level in58D102 leading to potentialcarryover of liquid C2 to58E105 and all the way tothe compressor/expander(58K101).Potentialcompressor/expanderdamage.

1. 58D102 demister.2. 58D103 withdemister.3. 58D104 withdemister.4. FAL-5802301. A 4 1 2

7.3. TIC-5802403 fullyopening TV-5802403.

Sheet: 59 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

9 Higher Level 9.4. LIC-5802401malfunctions closing FV-5802401 .

1. Increased level in58D103 leading to potentialcarryover of liquid C2 to58D104 and all the way tothe compressor/expander(58K101).Potentialcompressor/expanderdamage.

1. 58D103 demister.2. 58D104 withdemister.3. FAL-5802401.

A 4 1 2

10.1. LIC-5802001malfunctions closing LV-5802001.

1. Reduced level in 58E102leading to loss of heatexchange.Higher temperature of drytreated offgas to expander.No significantconsequence.

10.2. LIC-5802101malfunctions openingFV-5802101 .

1. Decreased level in58D101 leading to potentialtreated offgas blowby todemethanizer (58C101).Potential loss of C2 to thedemethanizer overheadstream leading to less C2recovery.Loss of profit.

1. Demethanizer OVHDcondenser (58E106).2. FAH-5802101.

A 2 1 1

10.3. LIC-5802301malfunctions openingFV-5802301 .

1. Decreased level in58D102 leading to potentialtreated offgas blowby todemethanizer (58C101).Potential loss of C2 to thedemethanizer overheadstream leading to less C2recovery.Loss of profit.

1. Demethanizer OVHDcondenser (58E106).2. FAH-5802301.

A 2 1 1

10.4. LIC-5802401malfunctions openingFV-5802401 .

1. Decreased level in58D103 leading to potentialtreated offgas blowby todemethanizer (58C101).Potential loss of C2 to thedemethanizer overheadstream leading to less C2recovery.Loss of profit.

1. Demethanizer OVHDcondenser (58E106).2. FAH-5802401.

A 2 1 1

Lower Level10

Sheet: 60 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

11 Composition changed No cause identified.

12 More Contamination 12.1. Trace amounts ofNOx in the treatedoffgas.

1. Potential blue iceformation at the cold boxexchanger (at temperatureof approximately -125C at36barg).Potential line plugging.Potential explosion leadingto operator injury.

1. TIC-5802403.

P 4 1 2

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A

19 Steam Failure N/A

20 Cooling Water Failure N/A

21 Nitrogen Failure 21.1. Loss of N2 supplyto the cold box.

1. Loss of purging leadingto potential ingress of airinside the cold boxexchanger leading topotential icing inside thecold box.

58-07.08 Discuss with cold box vendorthe consequence of losing N2blanket.

EPC/Vendor

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture 25.1. Tube pinhole leakin 58E101A/B.

1. Dry treated offgas leaksto residue gas stream andto the fuel gas system.Less C2 recovery leadingto less profit.

1. None.

A 1 1 1

Sheet: 61 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer Feed Pretreatment System 58-006-1 (Rev. 0), 58-015-1 (Rev. 0), 58-020-1 (Rev. 0), 58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-049-1 (Rev. 0)Node: 58-07

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

25 Leakage/Rupture 25.2. Tube pinhole leakin 58E102.

1. Dry treated offgas leaksinto C3R stream leading topotential overpressurizationof the refrigerant system.Potential piping andequipment damage leadingto release of C3R andleaked treated offgas toATM.Potential fire.Potential operator injury.

1. PIC-5805801 withalarm high.

P 4 1 2

25.3. Tube pinhole leakin 58E004.

1. C3R leaks into theexpander recycle stream to58C002.No significantconsequence.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 62 of 196

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Node Title: Reviewed Date: 23-May-13

Node Number: 58-08 Node Color Time: 9:00 - 18:00

58-024-1 (Rev. 0) 58-025-1 (Rev. 0) 58-027-1 (Rev. 0) 58-028-1 (Rev. 0) 58-032-1 (Rev. 0) 58-059-1 (Rev. 0)

58-060-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Demethanizer System

ORANGE

Number of Recommended Actions in this node: 9

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To remove methane and H2, and recover C2+ through the demethanizer (58C101).

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Notes:

Operation andDesignConditions:

Demethanizer Reflux Drum (58D106):Operating(P/T): 28.2barg/-98.5CDesign(P/T): -0.5barg@-115&11barg/-165&65CDemethanizer (58C101):Operating(P/T): 28.3barg/-94C (Top);28.8barg/-9C (Bottom)Design(P/T): 42barg(Top),42.5barg(Bottom)/-165&65C

Demethanizer OVHD Condenser (58E106):Operating(P/T): 28.3barg/-94.2CDesign(P/T): 42barg/-165&65C(1st pass); -0.5barg@-155&11barg/-165&65C(2nd pass)

Demethanizer Reboiler (58E107):Operating(P/T): 28.9barg/-8.7C (Shell)Design(P/T): 43barg/-105&65C (Shell);33.1barg/-46&90C (Tube)

Expander Suction Drum (58D104):Operating(P/T): 28.1barg/-108CDesign(P/T): 42barg/-165&65CExpander Discharge Drum (58D105):Operating(P/T): 13.7barg/-126CDesign(P/T): 17.1barg/-165&65C

Residue Gas Expander/Comp (58K101):Operating(P/T): 28.0/-108.3C (EXP);6.3barg/18C (COMP)Design Capacity@SuctionCondition(Nm3/hr): 16734 (EXP) / 18308(COMP)

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HAZOP WORKSHEET

Review Date: 2013-05-23

1 No/Less Flow 1. Increased level in thedemethanizer (58C101)bottoms leading topotential tray flooding.Potential tray damage.

1. LAH-5802501.2. PDAH-5802509.3. TIC-5802509 withalarm high.

A 4 1 2

2. Reduced level in thedeethanizer (58C201).No C2 recovery.Loss of profit.

1. LIC-5803201 willcontrol FV-5803201 toregulate level in thedeethanizer.

A 3 1 2

1.2. N2 line manualvalve inadvertentlyclosed.

1. Potential air ingress intothe demethanizer (58C101)leading to potential iceformation.Potential corrosion (longterm).

1. Operator training andprocedures.

A 2 1 1

1. Less flow to 58E106 andhigher pressure at 58C101.Potential loss of C2+ to thefuel gas system.Loss of profit.

1. Daily monitoring (AI-5802501).2. Periodic sampling(SC-5810/5811). A 2 1 1

2. Potentialoverpressurization of58C101 due to loss ofreflux or loss of condenser.Potential piping and columndamage leading to releaseof HCs to ATM.Potential fire.Potential operator injury.

1. PT-5802501 (2oo3)will trigger I-5808 to tripdemethanizer reboiler(58E107).2. PSV-5802501/5802502. P 4 1 2

58-08.01 Consider low flow alarm on FI-5802501.

EPC

1.4. XV-5802601 (tubeside of the reboiler)malfunctions closed ormismanaged closed.

1. Loss of C3R flow to the58E107 leading to loss ofreboiler duty.Reduced temperature inthe demethanizer(58C101).Reduced demethanizerefficiency leading to moremethane to the C2+stream.Potential offspec C2product.Loss of profit.

1. TAL-5802510.2. AAH-5802502B.3. Periodic sampling(SC-5812).

A 3 1 2

1.1. Flow control loopfailure (FV-5802502)malfunctions closed ormismanaged closed.

1.3. Strainer (STR-5843)plugging.

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 65 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.4. XV-5802601 (tubeside of the reboiler)malfunctions closed ormismanaged closed.

2. Potentialoverpressurization of58C201 due to moremethane content in theC2+ feed.Potential equipmentdamage leading to releaseof HCs to ATM.Potential fire.Potential operator injury.

1. PIC-5803205 withhigh alarm, opening PV-5803205.2. PT-5803204 (2oo3)will trigger I-5831 willtrip deethanizer reboiler(58E202).3. PSV-5803201/5803202.

P 4 1 2

1. Loss of process sidereboiler recirculation.Reduced temperature inthe demethanizer(58C101).Reduced demethanizerefficiency leading to moremethane to the C2+stream.Potential offspec C2product.Loss of profit.

1. TAL-5802510.2. AAH-5802502B.3. Periodic sampling(SC-5812).

A 3 1 2

2. Potentialoverpressurization of58C201 due to moremethane content in theC2+ feed.Potential equipmentdamage leading to releaseof HCs to ATM.Potential fire.Potential operator injury.

1. PIC-5803205 withhigh alarm, opening PV-5803205.2. PT-5803204 (2oo3)will trigger I-5831 willtrip deethanizer reboiler(58E202).3. PSV-5803201/5803202.

P 4 1 2

1.6. Compressor inletstrainer (STR-5819)plugging.

1. Less flow to compressor(58K101) suction leadingheat buildup and highvibration.Potential compressordamage.

1. PDAH-5802805.2. FAL-5802802.

A 4 1 2

Refer to action 58-07.01.

1.7. Compressor(58K101) suctionmanual valveinadvertently closed.

1. Less flow to compressor(58K101) suction leadingheat buildup and highvibration.Potential compressordamage.

1. FAL-5802802.

A 4 1 2

Refer to action 58-07.01.

1.5. 58E107 inletmanual valve (shell side)inadvertently closed.

Sheet: 66 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1. Blocked compressor(58K101) discharge leadingto surge and highdischarge temperature.Potential compressordamage potentially leadingto release of light end gasto ATM.Potential fire and explosion.Potential operator injury.

1. Operator training andprocedures.2. PSV-5802801/5802802.3. SAH-5802801.

P 4 1 2

Refer to action 58-07.05.

2. Loss of residue gassupply to fuel gas systempotentially leading to lossof fuel gas supply to users.

1. Operator training andprocedures.2. Backup fuel gas fromnatural gas header.

A 4 1 2

1.9. Compressor anti-surge valve (UV-5802801) malfunctionsclosed or mismanagedclosed when needed.

1. Compressor (58K101)high vibration and damage.

1. PSV-5802801/5802802.

A 4 1 2

58-08.02 Confirm this scenario withcompressor vendor.Refer to action 58-07.05.

EPC

1. Loss of motive force tooperate the expanderleading tocompressor/expander stop.PV-5802801 will eventuallyopen to continue operationfor the process side.However, demethanizer willoperate at lower efficiencyleading to less recovery ofC2.Loss of profit.Loss of residue gas to fuelgas system.

1. Common fault alarm.2. Backup fuel gas fromnatural gas header.

A 4 1 2

2. Potential 58C101upstreamoverpressurization leadingto potential equipmentdamage.Potential release of lightend gas to ATM.Potential fire and explosionleading to operator injury.

1. PIC-5802801 willopen PV-5802801.2. PSV-5802501/5802502.

P 4 1 2

58-08.03 Consider high pressure alarmon PT-5802801.

EPC

1.8. Compressor(58K101) dischargemanual valveinadvertently closed.

1.10. Expander inletvalve (XV-5802801) orsuction manual valvemalfunctions closed ormismanaged closed.

Sheet: 67 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1. Increased pressure atthe expander (58K101)discharge and suctionpotentially leading topotential expanderdamage.Potential release of lightend gas to ATM.Potential fire and explosion.Potential operator injury.

1. PAH-5802802.2. PIC-5802801 willopen PV-5802801.

P 4 1 2

Refer to action 58-08.03.

2. Loss of cooling mediumfor the cold box leading tohigher temperature oftreated offgas.Reduced fractionationefficiency at the cold boxleading to loss of product.Loss of profit.

1. PIC-5802801 willopen PV-5802801.

A 3 1 2

3. Higher pressure at thecompressor suction leadingto potentialoverpressurization ofupstream piping andequipment.Potential release of lightend gas to ATM.Potential fire and explosion.Potential operator injury.

1. Bypass line (8"-CG-58028011-H126) fromsuction to discharge ofcompressor is provided.

P 4 1 2

1.12. Residue gas to57K001A/B manualvalve inadvertentlyclosed.

1. Loss of residue gas (forregeneration) to PRUdryers leading toincomplete regeneration.Potential PRU productoffspec.Loss of profit.

1. Operator training andprocedures.2. N2 gas is providedfor backup regenerationgas.

A 3 1 2

2 More Flow 2.1. Flow control loopfailure (FV-5802502)malfunctions open ormismanaged open.

1. Reduced level in thedemethanizer (58C101)bottom leading to potentialgas blowby to deethanizer(58C201).Increased pressure in thecolumn to operationalupset leading to offspecproduct.Loss of profit.

1. LAL-5802501.2. LALL-5802501 (alarmonly).3. LIC-5803201 to openFV-5803201.

A 3 1 2

1.11. Expander(58K101) dischargemanual valveinadvertently closed.

Sheet: 68 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

3 Reverse Flow 3.1. Check valve (SSV-5805) on bypass line(8"-CG-58028011-H126)leaking.

1. Potential reverse flow ofcompressor discharge tosuction through the leakingcheck valve leading to highsuction pressure.Potential compressoroperation upset.

1. FAL-5802802.

A 3 1 2

58-08.04 Consider providing an isolationblock valve downstream ofcheck valve (SSV-5805) withCSO device. Alternatively,consider providing an additionalcheck valve (different type toprevent common cause failure)in series.

EPC

4 Misdirected Flow 4.1. XV-5802501malfunctions open ormismanaged open.

1. Loss of methane to flare.Potential big flaring leadingto community complain.Loss of profit.

1. LAL-5802501.2. LALL-5802501 (alarmonly).3. CCTV (flare stackmonitoring).4. CSR program.

C 2 1 1

5 Higher Pressure 1. Increased flow andpressure to 58D104leading to potentialethylene loss to fuel gassystem.Loss of profit.

1. Daily monitoring (AI-5802701).2. Periodic sampling(SC-5813). A 2 1 1

2. Potential increasedsuction pressure of theexpander (58K101) leadingto higher discharge flowand pressure.Potentialoverpressurization of thecold box exchangersleading to potentialequipment damage.Potential release of residuegas to ATM.Potential fire and explosion.Potential operator injury.

1. PIC-5802801 willopen PV-5802801.

P 4 1 2

Refer to action 58-08.03.

5.1. PDV-5802701malfunctions open ormismanaged open.

Sheet: 69 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

5 Higher Pressure 1. Pressure buildup at theexpander suction leading topotential overpressurizationof upstream piping andequipment.Potential expander andupstream piping/equipmentdamage.Potential release of residuegas to ATM.Potential fire and explosion.Potential operator injury.

1. SAH-5802801.2. Upstream piping andequipment are designedbased on expanderdesign pressure.3. PSV-5800801/5800802.

P 4 1 2

2. Potential increasedpressure downstream ofthe expander leading tooverpressurization ofupstream piping andequipment.Potential expander anddownstreampiping/equipment damage.Potential release of residuegas to ATM.Potential fire and explosion.Potential operator injury.

1. PSV-5802702/5802703.

P 4 1 2

5.2. Demethanizer(58C101) reflux manualvalve inadvertentlyclosed.

1. Potentialoverpressurization of58C101 due to loss ofreflux or loss of condenser.Potential piping and columndamage leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PT-5802501 (2oo3)will trigger I-5808 to tripdemethanizer reboiler(58E107).2. PSV-5802501/5802502.

P 4 1 2

6 Lower Pressure 6.1. PDV-5802701malfunctions closed ormismanaged closed

1. Less flow and pressureto expander suction leadingto less motive force to runthe expander.Potential reduction ofcompressor speed.Operational upset leadingto potential big flaring.Potential communitycomplain.

1. PIC-5802801 willopen PV-5802801.2. Bypass line (8"-CG-58028011-H126) fromsuction to discharge ofcompressor. C 3 1 2

5.2. PV-5802801 or XV-5802802 malfunctionsclosed or mismanagedclosed when needed.

Sheet: 70 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

6 Lower Pressure 6.2. PV-5802801malfunctions open ormismanaged open whennot needed.

1. Lower suction pressureleading to lower expanderspeed.Potential reduction ofcompressor speed.Potential less recovery ofC2 leading to less profit.

1. Bypass line (8"-CG-58028011-H126) fromsuction to discharge ofcompressor.2. PDIC-5802701.

A 3 1 2

7.1. TIC-5802509malfunctions openingTV-5802509.

1. Increased temperatureand pressure in thedemethanizer (58C101)leading to potential lessrecovery of C2.Loss of profit.

1. PT-5802501 (2oo3)will trigger I-5808 to tripdemethanizer reboiler(58E107).2. Daily monitoring (AI-5802501).3. Periodic sampling(SC-5812).

A 3 1 2

58-08.05 Consider high pressure alarmon PI-5802502.

EPC

7.2. TIC-5802807malfunctions closing TV-5802807B or opening ofTV-5802807A.

1. Higher temperature ofresidue gas to compressor(58K101) suction leading tohigher compressordischarge temperature.No significantconsequence.

8.1. TIC-5802509malfunctions closing TV-5802509.

1. Reduced temperature inthe demethanizer(58C101).Reduced demethanizerefficiency leading to moremethane to the C2+stream.Potential offspec C2product.Loss of profit.

1. TAL-5802510.2. AAH-5802502B.3. Periodic sampling(SC-5812).

A 3 1 2

58-08.06 Provide the low-lowtemperature set point for TT-5802002 (2oo3) (LL) which willtrigger I-5807 to close XV-5802001 and trip thecompressor.

Licensor

58-08.07 Consider providing mechanicalstopper for TV-5802807A toprevent it from fully closing.

EPC

4 1 2

8

Higher Temperature7

Lower Temperature

8.2. TIC-5802807malfunctions closing TV-5802807A or opening ofTV-5802807B.

1. Lower residue gastemperature to 58E101 andto downstream equipmentup to compressor (58K101)inlet.Potential damage todownstream piping (withH126 line spec) andcompressor.

1. TT-5802002 (2oo3)(LL) will trigger I-5807to close XV-5802001and trip thecompressor.

A

Sheet: 71 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

9.1. LIC-5802503malfunctions fullyopening LV-5802503.

1. Increased level in thedemethanizer OVDHcondenser leading topotential carryover of liquidC2R to C2R vapor line (2-phase flow).No significantconsequence.

1. Increased level in thedemethanizer (58C101)bottoms leading topotential tray flooding.Potential tray damage.

1. FAL-5802502.2. PDAH-5802509.3. TIC-5802509 withalarm high.

A 4 1 2

2. Reduced level in thedeethanizer (58C201).No C2 recovery.Loss of profit.

1. LIC-5803201 willcontrol FV-5803201 toregulate level in thedeethanizer.

A 3 1 2

1. Increased level in58D104 leading to potentialliquid carryover toexpander (58K101).Potential damage to theexpander.

1. LT-5802702 (2oo3)(HH) will trigger I-5809to trip the expander.

A 4 1 2

2. Less expander liquidflow to cold box heatexchangers leading highertemperature of dry treatedoffgas.Less recovery of C2leading to less profit.

1. Daily monitoring (AI-5802501).2. Periodic sampling(SC-5810).

A 3 1 2

1. Increased level in58D105 leading to potentialliquid carryover to cold boxexchangers.No significantconsequence.

2. Less expander liquidflow to cold box heatexchangers leading highertemperature of dry treatedoffgas.Less recovery of C2leading to less profit.

1. Daily monitoring (AI-5802501).2. Periodic sampling(SC-5810).

A 3 1 2

9

9.2. LIC-5802501malfunctions closing FV-5802501.

9.3. LIC-5802701malfunctions closing LV-5802701.

9.4. LIC-5802703malfunctions closing LV-5802703.

Higher Level

Sheet: 72 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

10 Lower Level 1. Decreased level in thedemethanizer OVDHcondenser (58E106)leading to loss ofcondensation leading toloss of C2.Potential product offspec.Less profit.

1. Daily monitoring (AI-5802501).2. Periodic sampling(SC-5810).

A 3 1 2

2. Loss of reflux to 58C101leading to potentialincreased temperature andpressure in the column.Potentialoverpressurization leadingto equipment damage.Potential release of HCs toATM leading to potentialfire and explosion.Potential operator injury.

1. PT-5802501 (2oo3)will trigger I-5808 to tripdemethanizer reboiler(58E107).2. PSV-5802501/5802502.

P 4 1 2

Refer to action 58-08.05.

10.2. LIC-5802501malfunctions openingFV-5802501.

1. Reduced level in thedemethanizer (58C101)bottom leading to potentialgas blowby to deethanizer(58C201).Increased pressure in thecolumn to operationalupset leading to offspecproduct.Loss of profit.

1. FAH-5802502.

A 3 1 2

10.3. LIC-5802701malfunctions openingLV-5802701.

1. Loss of level in 58D104leading to gas blowby to58D105.Potentialoverpressurization anddamage of 58D105.Potential release of HCs toATM.Potential fire and explosionleading to operator injury.

1. PSV-5802702/5802703.

P 4 1 2

58-08.08 Confirm if PSV-5802702/5802703 can handlegas blowby case from 58D104.

EPC

10.1. LIC-5802503malfunctions closing LV-5802503.

Sheet: 73 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

10 Lower Level 10.4. LIC-5802703malfunctions openingLV-5802703.

1. Loss of level in 58D105leading to gas blowby toexpander liquid line to coldbox exchangers.Potential operational upsetin the cold box heatexchangers.Potential less C2 recovery.Loss of profit.

1. Daily monitoring (AI-5802501).2. Periodic sampling(SC-5810).

A 3 1 2

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13.1. External fire. 1. Potentialoverpressurization anddamage of 58D104.Release of HCs to ATMleading to potential fireescalation.Potential operator injury.

1. PSV-5802701.

P 4 1 2

13.2. External fire. 1. Potentialoverpressurization anddamage of 58E107.Release of HCs to ATMleading to potential vaporcloud explosion and fireescalation.Potential operator injury.

1. PSV-5802601.

P 4 1 2

58-08.09 Check and review if thelocation of PSV-5802601 is onthe top point of 58E107.

EPC

13.3. External fire. 1. Potentialoverpressurization ofexpander (58K101)discharge leading toexpander and downstreampiping/equipment damage.Release of HCs to ATMleading to potential fireescalation.Potential operator injury.

1. PSV-5802803.

P 4 1 2

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A

Relief13

Sheet: 74 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Demethanizer System 58-024-1 (Rev. 0), 58-025-1 (Rev. 0), 58-027-1 (Rev. 0), 58-028-1 (Rev. 0), 58-032-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-08

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

19 Steam Failure N/A

20 Cooling Water Failure N/A

21 Nitrogen Failure No additional causeidentified.

22 IA/PA Failure 22.1. No supply to XV-5802802.

1. Potential loss of residuegas to cold box leading toincreased treated offgastemperature.Loss of profit due to lessC2 recovery.

1. Daily monitoring (AI-5802501).2. Periodic sampling(SC-5810). A 3 1 2

Refer to Action No.58-08.05.

23 Maintenance No additional causeidentified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture 25.1. Tube pinhole leakat 58E107.

1. Dry demethanizer(58C101) bottoms leaksinto C3R stream leading topotential overpressurizationof the refrigerant system.Potential piping andequipment damage leadingto release of C3R andleaked treated offgas toATM.Potential fire and explosion.Potential operator injury.

1. PIC-5805801 withalarm high.

P 4 1 2

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 75 of 196

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Node Title: Reviewed Date: 23-May-13

Node Number: 58-09 Node Color Time: 9:00 - 18:00

58-006-1 (Rev. 0) 58-032-1 (Rev. 0) 58-034-1 (Rev. 0) 58-035-1 (Rev. 0) 58-050-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Deethanizer System

LIGHT BLUE

Number of Recommended Actions in this node: 2

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To remove C3+ and send to DCC unit 53 and in the process recovering C2 as product.

Notes:

Operation andDesignConditions:

Deeethanizer Reboiler Condensate Pot(58D202):Operating(P/T): 4.5barg/156CDesign(P/T): FV@185&23C/11&185CDesuperheater for 58E202 (58Z001):Operating(P/T):Design(P/T): 85barg/11&150C

Deeethanizer (58C201):Operating(P/T): 24.7barg/-14C (Top);24.9barg/68C (Bottom)Design(P/T): 29barg(Top), 29.3(Bottom)/-105&180CDeeethanizer Reboiler (58E202):Operating(P/T): 25.0barg/59.7C (Shell)Design(P/T): 29.8barg/-105&180C (Shell);FV@100&23C/11&185C (Tube)

Deeethanizer Condenser (58E201):Operating(P/T): 25.0barg/-13.6C (Tube)Design(P/T): 22.4barg/-46&65C (Shell);29barg/-105&65C (Tube)Deeethanizer Reflux Drum (58D201):Operating(P/T): 24.5barg/-16.1CDesign(P/T): 29barg/-105&65C

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HAZOP WORKSHEET

Review Date: 2013-05-23

1 No/Less Flow 1. Increased level in thedeethanizer (58C201)bottoms leading topotential tray flooding.Potential tray damage.

1. PDAH-5803209.2. TAL-5803204.3. Daily monitoring (AI-5803201).

A 4 1 2

58-09.01 Consider high level alarm onLT-5803201.

EPC

2. Loss of deethanizerbottoms flow to unit 53.No significantconsequence.

1.2. XV-5803201malfunctions closed ormismanaged closed.

1. Loss of SL flow toreboiler (58E202) leadingto low temperature in thedeethanizer (58C202).Loss of C2 to deethanizerbottoms leading to less C2recovery.Loss of profit.

1. Daily monitoring (AI-5803201).2. Periodic sampling(DC5815).3. TAL-5803204. A 2 1 1

1.3. BFW strainer (STR-5841) plugging.

1. Less BFW flow leadingto higher temperature of SLto reboiler (58E202).No significantconsequence.

Desuperheatersystem for thereboiler will beremoved in thefuture.

1.4. Manual valve (shellside) on reboiler(58E202) inlet lineinadvertently closed.

1. Loss of reboiler(58E202) recirculationleading to low temperaturein the deethanizer(58C202).Loss of C2 to deethanizerbottoms leading to less C2recovery.Loss of profit.

1. Operator training andprocedures.2. Daily monitoring (AI-5803201).3. Periodic sampling(DC5815).4. TAL-5803204.

A 2 1 1

1.5. Flow control loopfailure (FV-5803401)malfunctions closed ormismanaged closed.

1. Potential pump(58P291A/B) running belowminimum flow requirementleading to pump damage.

1. Pump fault alarm.2. Pump is seallesstype.3. FAL-5803402.

A 4 1 2

Refer to action 58-G3.

1.1. Flow control loopfailure (FV-5803201)malfunctions closed ormismanaged closed.

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 77 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.6. Flow control loopfailure (FV-5803402)malfunctions closed ormismanaged closed.

1. Loss of reflux to 58C201leading to highertemperature and pressurein the column.Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosionleading to operator injury.

1. PIC-5803205 withalarm high.2. PT-5803204 (2oo3)(HH) will trigger I-5831to trip reboiler(58E202).3. Daily monitoring (AI-5803401C).4. PSV-5803201/5803202.

P 4 1 2

1. Loss of C2 flow to C2splitter (58C301) leading toloss of C2 recovery.Loss of profit.

1. LAL-5803501.

A 3 1 2

2. Increased level indeethanizer reflux drum(58D201) leading topotential overfilling andcarryover (2-phase flow) ofliquid C2 to 58E004.Potential high vibration inthe line and potential pipedamage.Release of HCs to ATM.Potential fire and explosionleading to operator injury.

1. PIC-5803404 willopen PV-5803404 andliquid C2 will be flashedto vapor phase.2. LAH-5803402.

P 4 1 2

1. Increased level indeethanizer reflux drum(58D201) leading topotential overfilling andcarryover (2-phase flow) ofliquid C2 to 58E004.Potential high vibration inthe line and potential pipedamage.Release of HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PIC-5803404 willopen PV-5803404 andliquid C2 will be flashedto vapor phase.

P 4 1 2

2. Loss of pump suctionleading to pump(58P201A/B) cavitation anddamage.

1. Pump fault alarm.2. Pump is seallesstype.3. FAL-5803402.

A 4 1 2

Refer to action 58-G4.

1.7. Flow control loopfailure (FV-5803403)malfunctions closed ormismanaged closed.

1.8. Pump (58P201A/B)inlet block valve (XV-5803401) malfunctionsclosed or mismanagedclosed.

Sheet: 78 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.9. Pump (58P201A/B)suction strainer (STR-5821/5822) plugging.

1. Less flow to pumpsuction leading to pump(58P201A/B) cavitation anddamage.

1. Pump fault alarm.2. Pump is seallesstype.3. FAL-5803402.4. Standby pump.

A 4 1 2

1.10. Deethanizer refluxpump (58P201A/B) trips.

1. Loss of reflux to 58C201leading to highertemperature and pressurein the column.Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PIC-5803205 withalarm high.2. PT-5803204 (2oo3)(HH) will trigger I-5831to trip reboiler(58E202).3. Daily monitoring (AI-5803401C).4. PSV-5803201/5803202.5. Pump fault alarm.6. Standby pump.

P 4 1 2

1. Loss of C2 flow to C2splitter (58C301) leading toloss of C2 recovery.Loss of profit.

1. LAL-5803501.

A 3 1 2

2. Increased level indeethanizer reflux drum(58D201) leading topotential overfilling andcarryover (2-phase flow) ofliquid C2 to 58E004.Potential high vibration inthe line and potential pipedamage.Release of HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PIC-5803404 willopen PV-5803404 andliquid C2 will be flashedto vapor phase.2. LAH-5803402.

P 4 1 2

2 More Flow 2.1. Flow control loopfailure (FV-5803201)malfunctions open ormismanaged open.

1. Reduced level indeethanizer (58C201)leading to potential gasblowby to DCC unit 53.No significantconsequence.

1.11. XV-5803501malfunctions closed ormismanaged closed.

Sheet: 79 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

2 More Flow 2.2. Flow control loopfailure (FV-5803401)malfunctions fully openor mismanaged fullyopen.

1. Less reflux flow to58C201 leading to highertemperature and pressurein the column.Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

1. FAL-5803402.2. PIC-5803205 withalarm high.3. PT-5803204 (2oo3)(HH) will trigger I-5831to trip reboiler(58E202).4. Daily monitoring (AI-5803401C).5. PSV-5803201/5803202.

P 4 1 2

2.3. Flow control loopfailure (FV-5803402)malfunctions open ormismanaged open.

1. More reflux leading topotential decreasedtemperature in thedeethanizer (58C202).Potential loss of C2 todeethanizer bottomsleading to reduced C2recovery.Loss of profit.

1. TIC-5803204 willcontrol reboiler duty tomaintain temperature.

A 3 1 2

1. More flow of C2 to C2splitter (58C301) leading tohigher level in the C2splitter.Potential flooding leading totray damage.

1. LIC-5803501 withalarm high will controlFV-5803503.2. PDAH-5803507. A 3 1 2

2. Reduced level indeethanizer reflux drum(58D201) leading topotential pump(58P201A/B) damage dueto cavitation.

1. LAL-5803402.2. Pump fault alarm.3. FAL-5803402.4. Sealless pump. A 4 1 2

3. Potential gas blowby toC2 splitter (58C301).Potentialoverpressurization in C2splitter (58C301) leading toequipment damage.Release of HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PT-5803503 (2oo3)(HH) will trigger I-5843to XV-5803501.2. PSV-5803501/5803503.

P 4 1 2

2.5. Both deethanizerreflux pump(58P201A/B) runningsimultaneously.

1. Potential pump(58P201A/B) running belowminimum flow requirementleading to pump damage.

1. Operator training andprocedures.2. Pump minimum flowline (via FV-5803401).

A 4 1 2

2.4. Flow control loopfailure (FV-5803403)malfunctions open ormismanaged open.

Sheet: 80 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

3 Reverse Flow No cause identified.

4 Misdirected Flow XV-5803202malfunctions open ormismanaged open.

Loss of C2 to flare.Loss of profit.Potential big flaring leadingto community complain.Reduced pressure indeethanizer (58C201).

PAL-5803205.CCTV (flare stackmonitoring).CSR program. C 3 1 2

5 Higher Pressure 5.1. PV-5803205Bmalfunctions closed ormismanaged closed.

No significantconsequence.

5.2. PV-5803205Amalfunctions closed ormismanaged closed.

1. Loss of C3R flow todeethanizer condenser(58E201) leading to loss ofcondensation.Potential loss of refluxleading to increasedtemperature and pressurein 58C201.Potentialoverpressurization indeethanizer (58C201)leading to equipmentdamage.Release of HCs to ATM.Potential fire and explosion.Potential operator injury.

1 .FAL-5803402.2. PT-5803204 (2oo3)(HH) will trigger I-5831to trip reboiler(58E202).3. PSV-5803201/5803202.

P 4 1 2

5.3. PV-5803404malfunctions closed ormismanaged closed.

1. Increased pressure in58D201 leading to potentialoverpressurization anddamage.Potentialoverpressurization indeethanizer (58C201)leading to equipmentdamage.Release of HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PT-5803204 (2oo3)(HH) will trigger I-5831to trip reboiler(58E202).2. PSV-5803201/5803202.

P 4 1 2

Sheet: 81 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

5 Higher Pressure 5.4. PV-5803501malfunctions closed ormismanaged closedwhen needed (not openon demand)

1. Pressure buildup at C2splitter (58C301) leading topotential overpressurizationin C2 splitter (58C301)leading to equipmentdamage.Potential fire and explosion.Potential operator injury.

1. PT-5803503 (2oo3)(HH) will trigger I-5843to XV-5803501.2. PSV-5803501/5803503.

P 4 1 2

6.1. PV-5803205Bmalfunctions open ormismanaged open.

1. Loss of deethanizerOVHD to flare.Potential big flaring leadingto potential communitycomplain.Reduced C2 recovery.Loss of profit.

1. CCTV (flare stackmonitoring).2. CSR program.3. LAL-5803402.4. FAL-5803402.

C 3 1 2

6.2. PV-5803205Amalfunctions open ormismanaged open.

1. More flow of C3R tocondenser (58E201)leading to more C2 in thedeethanizer bottom.Reduced C2 recovery.Loss of profit.

1 .Daily monitoring (AI-5803201).2. Periodic sampling(SC-5815).3. TIC-5803204.

A 3 1 2

6.3. PV-5803404malfunctions open ormismanaged open.

1. Reduced pressure in58D201 and consequentlylower pressure in 58C201.Potential vaporization of C3to deethanizer OVHDleading to potential C2product offspec.Loss of profit.

1. Daily monitoring (AI-5803401C).2. Periodic sampling(SC-5816).3. PAL-5803205. A 3 1 2

6.4. PV-5803501malfunctions open ormismanaged open.

1. Reduced pressure in58C301.Loss of C2 to CBD.Less C2 recovery.Loss of profit.

1. PAL-5803504A.

A 3 1 2

7 Higher Temperature 7.1. TIC-5803205malfunctions closing TV-5803205.

1. Less BFW flow leadingto higher temperature of SLto reboiler (58E202).No significantconsequence.

A 3 1 2

Desuperheatersystem for thereboiler will beremoved in thefuture.

Lower Pressure6

Sheet: 82 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

7 Higher Temperature 7.2. TIC-5803204malfunctions openingLV-5803202.

1. Decreased level in58D202 leading to hightemperature todeethanizer.More C3 to overheadsection.Potential offspec of C2.Loss of profit.

1. Daily monitoring (AI-5803401C).2. Periodic sampling(SC-5816).3. PAH-5803205. A 3 1 2

58-09.02 Consider high alarm on TI-5803202.

EPC

1. Low temperature in thedeethanizer (58C202).Loss of C2 to deethanizerbottoms leading to less C2recovery.Loss of profit.

1. Daily monitoring (AI-5803201).2. Periodic sampling(SC-5815).3. TAL-5803204.

A 3 1 2

2. Potentialoverpressurization in58E202 and 58D202leading to damageequipment.Potential personnel injury.

1. PSV-5803203/5803204.

P 4 1 2

8.2. TIC-5803204malfunctions closing LV-5803202.

1. Increased level in58D202 leading to lowtemperature.Loss of C2 to deethanizerbottoms leading to less C2recovery.Loss of profit.

1. Daily monitoring (AI-5803201).2. Periodic sampling(SC-5815).

A 3 1 2

9 Higher Level 9.1. LIC-5803202malfunctions closing LV-5803202.

1. Increased level in58D202 leading to lowtemperature.Loss of C2 to deethanizerbottoms leading to less C2recovery.Loss of profit.

1. Daily monitoring (AI-5803201).2. Periodic sampling(SC-5815).3. TAL-5803204.

A 3 1 2

9.2. LIC-5803402malfunctions closing FV-5803403.

1. Loss of C2 flow to C2splitter (58C301) leading toloss of C2 recovery.Loss of profit.

1. LAL-5803501.

A 3 1 2

Lower Temperature8 8.1. TIC-5803205malfunctions openingTV-5803205.

Sheet: 83 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

9 Higher Level 9.2. LIC-5803402malfunctions closing FV-5803403.

2. Increased level indeethanizer reflux drum(58D201) leading topotential overfilling andcarryover (2-phase flow) ofliquid C2 to 58E004.Potential high vibration inthe line and potential pipedamage.Release of HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PIC-5803404 willopen PV-5803404 andliquid C2 will be flashedto vapor phase.

P 4 1 2

1. Increased level in thedeethanizer (58C201)bottoms leading topotential tray flooding.Potential tray damage.

1. PDAH-5803209.2. TAL-5803204.3. Daily monitoring (AI-5803201).

A 4 1 2

2. Loss of deethanizerbottoms flow to unit 53.No significantconsequence.

9.4. LIC-5803401malfunctions openingPV-5803205A.

1. Increase level in E201.More flow of C3R tocondenser (58E201)leading to more C2 in thedeethanizer bottom.Reduced C2 recovery.Loss of profit.

1. Daily monitoring (AI-5803201).2. Periodic sampling(SC-5815).3. TIC-5803204.

A 3 1 2

10 Lower Level 10.1. LIC-5803202malfunctions openingLV-5803202.

1. Decreased level in58D202 leading to steamentering condensate pipe.Potential damage to pipe.Potential pipe rupture.Release of hot water toATM.Potential personnel injury.

1. Condensate line(150#) is designedsame as steam designpressure.

A 3 1 2

10.2. LIC-5803402malfunctions openingFV-5803403.

1. More flow of C2 to C2splitter (58C301) leading tohigher level in the C2splitter.Potential flooding leading totray damage.

1. LIC-5803501 withalarm high will controlFV-5803503.2. PDAH-5803507. A 3 1 2

9.3. LIC-5803201malfunctions closing FV-5803201.

Sheet: 84 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

10 Lower Level 10.2. LIC-5803402malfunctions openingFV-5803403.

2. Reduced level indeethanizer reflux drum(58D201) leading topotential pump(58P201A/B) damage dueto cavitation.

1. Pump fault alarm.2. FAL-5803402.3. Sealless pump.

A 4 1 2

10.3. LIC-5803201malfunctions openingFV-5803201.

1. Reduced level indeethanizer (58C201)leading to potential gasblowby to DCC unit 53.No significantconsequence.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure 18.1. Deethanizer Refluxpump (58P201A/B)power supply failure.

1. Loss of reflux to 58C201leading to highertemperature and pressurein the column.Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PIC-5803205 withalarm high.2. PT-5803204 (2oo3)(HH) will trigger I-5831to trip reboiler(58E202).3. Daily monitoring (AI-5803401C).4. PSV-5803201/5803202.5. Pump fault alarm.6. Standby pump withdifferent power feederline.

P 4 1 2

19 Steam Failure No cause identified.

20 Cooling Water Failure No cause identified.

21 Nitrogen Failure No cause identified.

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

Sheet: 85 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-23

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Deethanizer System 58-006-1 (Rev. 0), 58-032-1 (Rev. 0), 58-034-1 (Rev. 0), 58-035-1 (Rev. 0), 58-060-1 (Rev. 0)

Node: 58-09

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

24 Start-up/Shutdown No cause identified.

25.1. Tube pinhole leakat 58E202.

1. C2+ is leaked to thecondensate system.Potential light HCcontamination ofcondensate system andpotential release to ATM atdeaerator.

1. TOC analyzer at thecondensate system.Condensate treatingpackage (74X001).

A 2 1 1

25.2. Tube pinhole leakat 58E201.

1. C2 is leaked to the C3Rsystem.potential increasedpressure and potentialreduced efficiency of C2recovery in the ERUrefrigeration system.

1. PIC-5805801 withhigh alarm.

A 3 1 2

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Leakage/Rupture25

Sheet: 86 of 196

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Node Title: Reviewed Date: 24-May-13

Node Number: 58-10 Node Color Time: 9:00 - 18:00

58-035-1 (Rev. 0) 58-036-1 (Rev. 0) 58-045-1 (Rev. 0) 58-046-1 (Rev. 0) 58-047-1 (Rev. 0) 58-060-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

C2 Splitter System

LIGHT RED

Number of Recommended Actions in this node: 2

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To fractionate ethane and ethylene.

Notes:

Operation andDesignConditions:

C2 Splitter (58C301):Operating(P/T): 6.6barg/-60C (Top);7.3barg/-38C (Bottom)Design(P/T): 10.5barg(Top), 11.2(Bottom)/-110&65C

C2 Splitter Bottoms Reboiler (58E301):Operating(P/T): 18.2barg/-16.2CDesign(P/T): 11.7barg/-110&65C (1st pass);22.5barg/-110&65C (2nd pass)

C2 Splitter Bottoms Reboiler EthyleneLiquid Pot (58D301):Operating(P/T): 18.1barg/-31.8CDesign(P/T): 22.5barg/-110&65C

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HAZOP WORKSHEET

Review Date: 2013-05-24

1 No/Less Flow 1. Increased level in C2splitter (58C301) bottomsleading to potential trayflooding.Potential tray damage.

1. LAH-5803501.2. PDAH-5803507.

A 3 1 2

2. (short term - reboiler stillworking) Loss of C2 flow to58E301 leading toincreased temperature in58C301.Potential more ethanecontamination in ethylene.Potential ethylene offspec.Loss of profit.

1. AAH-5803501D.2. TAH-5803501.

A 3 1 2

3. (long term - reboiler notworking) Decreasedtemperature in C2 splitter.Potential more ethylene inethane.Loss of profit.

1. Daily monitoring (AI-5803502A).2. Periodic sampling(SC-5817).3. TAL-5803505.

A 3 1 2

4. Higher temperature andpressure C2R to C2Rsurge drum (58D404).Potential pressure buildupin 58D404.No significantconsequence.

1. Increased level in C2splitter (58C301) bottomsleading to potential trayflooding.Potential tray damage.

1. Operator training andprocedures.2. LAH-5803501.3. PDAH-5803507.4. PDAH-5803601.5. Standby train.

A 3 1 2

2. (long term - reboiler notworking) Decreasedtemperature in C2 splitter.Potential more ethylene inethane.Loss of profit.

1. Daily monitoring (AI-5803502A).2. Periodic sampling(SC-5817).3. TAL-5803505.

A 3 1 2

1.3. Flow control failure(FV-5803601)malfunctions closed ormismanaged closed.

1. Decreased temperaturein C2 splitter (58C301)leading to more ethylene inethane.Loss of profit.

1. Daily monitoring (AI-5803502A).2. Periodic sampling(SC-5817).3. TAL-5803505.

A 3 1 2

1.1. Flow control failure(FV-5803503)malfunctions closed ormismanaged closed.

1.2. Strainer (STR-5823/5824) plugging.

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: C2 Splitter System 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-045-1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-10

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 88 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: C2 Splitter System 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-045-1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-10

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.4. Manual valve on58E404 shell sidemismanaged closed.

1. Potential pressurebuildup and higher level inC2 splitter (58C301)bottoms leading topotential tray flooding.Potential tray damage.

1. Operator training andprocedures.2. LAH-5803501.3. PDAH-5803507. A 3 1 2

58-10.01 Consider low flow alarm onFIC-5803503.

EPC

2.1. Flow control failure(FV-5803503)malfunctions fully openor mismanaged fullyopen.

1. Decreased level in C2splitter (58C301).Loss of 58E301 return.Loss of profit due toethylene.

1. LAL-5803501.2. PAL-5803504A.3. TAL-5803505.

A 3 1 2

2.2. Flow control failure(FV-5803601)malfunctions open ormismanaged open.

1. More circulation to thereboiler leading toincreased temperature in58C301.More ethane to ethylene.Loss of profit.

1. PIC-5803504 withhigh alarm.2. TAH-5803501.3. AAH-5803501D. A 3 1 2

3 Reverse Flow No cause identified.

4 Misdirected Flow 4.1. 4" manual valvefrom 58E404 to OSBLleft open accidentally.

1. Low temperature ofethane (-36 C)to fuel gassystem leading to potentialdamage to equipment59D001 and piping (H126).Potential release of HC toATM.Potential fire.Potential personnel injury.

1. TT-5806006 (2oo3)(LL) will trigger I-5856to close XV-5806001.

P 4 1 2

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature 7.1. TIC-5803505malfunctions openingFV-5803601.

1. More circulation to thereboiler leading toincreased temperature in58C301.More ethane to ethylene.Loss of profit.

1. PIC-5803504 withhigh alarm.2. TAH-5803501.3. AAH-5803501D. A 3 1 2

8 Lower Temperature 8.1. TIC-5803505malfunctions closing FV-5803601.

1. Decreased temperaturein C2 splitter (58C301)leading to more ethylene inethane.Loss of profit.

1. Daily monitoring (AI-5803502A).2. Periodic sampling(SC-5817).

A 3 1 2

More Flow2

Sheet: 89 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: C2 Splitter System 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-045-1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-10

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

9.1. LIC-5803501malfunctions closing FV-5803503.

1. Increased level in C2splitter (58C301) bottomsleading to potential trayflooding.Potential tray damage.

1. PDAH-5803507.

A 3 1 2

9.2. LIC-5803601malfunctions closing FV-5803601.

1. Decreased temperaturein C2 splitter (58C301)leading to more ethylene inethane.Loss of profit.

1. Daily monitoring (AI-5803502A).2. Periodic sampling(SC-5817).3. TAL-5803505.

A 3 1 2

1. Increased level in58E404 leading to reducedethane vapor to fuel gassystem.Potential 2-phase from58E404 carryover to58K101.Potential damage to58K401.

1. None.

A 3 1 2

58-10.02 Consider high alarm on LIC-5804602.

EPC

2. Potential lowtemperature ethane (-36C)to 58K101 leading topotential damage 58K101and suction line (H126).

1. TT-5802002 (2oo3)(LL) will trigger I-5807to close XV-5802001.

A 3 1 2

10.1. LIC-58036011malfunctions openingFV-5803601.

1. More circulation to thereboiler leading toincreased temperature in58C301.More ethane to ethylene.Loss of profit.

1. PIC-5803504 withhigh alarm.2. TAH-5803501.3. AAH-5803501D. A 3 1 2

10.2. LIC-5803501malfunctions openingFV-5803503.

1. Decreased level in C2splitter (58C301).Loss of 58E301 return.Loss of profit due toethylene.

1. PAL-5803504A.2. TAL-5803505.

A 3 1 2

10.3. LIC-5804603malfunctions openingLV-5804603.

1. Decreased level in58E404 leading to loss ofefficiency.Potential pressure buildupC2R surge drum (58D404).

1. LIC-58034602.2. PIC-5804702.

A 3 1 2

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

Lower Level

Higher Level9

9.3. LIC-5804603malfunctions closing LV-5804603.

10

Sheet: 90 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: C2 Splitter System 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-045-1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-10

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 91 of 196

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Node Title: Reviewed Date: 24-May-13

Node Number: 58-11 Node Color Time: 9:00 - 18:00

58-021-1 (Rev. 0) 58-023-1 (Rev. 0) 58-024-1 (Rev. 0) 58-035-1 (Rev. 0) 58-036-1 (Rev. 0) 58-037-1 (Rev. 0)

58-038-1 (Rev. 0) 58-039-1 (Rev. 0) 58-040-1 (Rev. 0) 58-041-1 (Rev. 0) 58-045-1 (Rev. 0) 58-046-1 (Rev. 0)

58-047-1 (Rev. 0) 58-050-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

C2R Compressor System

YELLOW

Number of Recommended Actions in this node: 7

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To compress ethylene. Ethylene sending to C2 refrigeration system.

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Notes:

Operation andDesignConditions:

Demethanizer Core HX No. 2 (58E104):Operating(P/T): 31.3barg/-57.1CDesign(P/T): 42barg/-155&65C(1st pass);17.1barg/-155&65C(2nd pass);42barg/-155&65C(3rd pass); 11barg/-155&65C(4thpass)Demethanizer Core HX No. 3 (58E105):Operating(P/T): 31.1barg/-80CDesign(P/T): 42barg/-165&65C(1st pass);17.1barg/-165&65C(2nd pass);42barg/-165&65C(3rd pass); 0.5barg@-155&11C/-155&65C(4th pass)

C2R Compressor 1st Stage Suction Drum(58D401):Operating(P/T): 0.2barg/-101CDesign(P/T): 10.5barg/-115&65CC2R Compressor 2nd Stage Suction Drum(58D402):Operating(P/T): 6.6barg/-60CDesign(P/T): 10.5barg/-110&65C

C2R Compressor 3rd Stage Suction Drum(58D403):Operating(P/T): 17.7barg/-31.9CDesign(P/T): 10.5barg/-110&65CC2 Heat Pump/Refrig Compressor 1st and2nd Stage (58K401):Operating(P/T): 8.3barg/-52.1CDesign Capacity@SuctionCondition(Nm3/hr): 2307(1st); 6825(2nd);45625(3rd)

C2 Heat Pump/Refrig Compressor 3rdStage (58K401):Operating(P/T): 8.3barg/-52.1CDesign Capacity@SuctionCondition(Nm3/hr): 2307(1st); 6825(2nd);45625(3rd)C2R Desuperheater No. 1 (58E401):Operating(P/T): 18.6barg/17.7CDesign(P/T): 22.5barg/-46&65C(1st pass);17barg/-46&65C(2nd pass)

C2R Desuperheater No. 2 (58E402):Operating(P/T): 18.4barg/13CDesign(P/T): 22.5barg/-46&65C(1st pass);17barg/-46&65C(2nd pass)C2R Condenser (58E403):Operating(P/T): 18.2barg/-16.2CDesign(P/T): 22.5barg/-110&65C(1st pass); -0.5barg@-46&17C/-110&65C(2nd pass)

Ethane Vaporizer (58E404):Operating(P/T): 7.2barg/-36.5C (Shell);18.2barg/16.2C (Tube)Design(P/T): 17.4barg/-90&65C (Shell);22.5barg/-110&75C (Tube)C2R Condenser Ethylene Liquid Pot(58D405):Operating(P/T): 18.1barg/-31.9CDesign(P/T): 22.5barg/-110&65CEthane Vaporizer Ethylene Liquid Pot(58D406):Operating(P/T): 18.1barg/-31.9CDesign(P/T): 22.5barg/-110&65C

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HAZOP WORKSHEET

Review Date: 2013-05-24

1 No/Less Flow 1.1. Flow control loopfailure (FV-5803502)malfunctions closed ormismanaged closed.

1. Less reflux flow to58C301 leading to highertemperature and pressurein the column.Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PAH-5803504.2. TAH-5803501.3. PT-5803503A/B/C(2oo3) (HH) will triggerI-5843 to close XV-5803501.4. PSV-5803501/5803503.

P 4 1 2

1. Less flow of C2 to58K401 3rd stage suctionleading to potentialdamage to compressor.Potential HCs release toATM.Potential fire and explosion.Potential operator injury.

1. FAL-5804103.2. Anti surge valve (UV-5803901).3. PAL-5804103.

P 4 1 2

2. Higher pressure in theC2 splitter (58C301).Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PAH-5803504.2. PT-5803503A/B/C(2oo3) (HH) will triggerI-5843 to close XV-5803501.3. PSV-5803501/5803503.

P 4 1 2

1.3. MOV-5804001malfunctions closed ormismanaged closed.

1. Loss of flow tocompressor (58K401) 1stsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. Interlock (I-5841) toprevent MOV-5804001to be closed whencompressor is running(refer to note 7 onP&ID# 58-040).2. PAL-5804001.

A 4 1 2

58-11.01 Consider low alarm on FI-5804001.

EPC

1.4. MOV-5804002malfunctions closed ormismanaged closed.

1. Loss of flow tocompressor (58K401) 2ndsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. Interlock (I-5841) toprevent MOV-5804001to be closed whencompressor is running(refer to note 7 onP&ID# 58-040).2. PAL-5804002.

A 4 1 2

58-11.02 Consider low alarm on FI-5804002.

EPC

Action By

1.2. XV-5804101malfunctions closed ormismanaged closed.

P/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

Sheet: 94 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

Action ByP/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

1 No/Less Flow 1.5. MOV-5804101malfunctions closed ormismanaged closed.

1. Loss of flow tocompressor (58K401) 3rdsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. Interlock (I-5841) toprevent MOV-5804001to be closed whencompressor is running(refer to note 6 onP&ID# 58-041).2. FAL-5804103.3. PAL-5804103.

A 4 1 2

1.6. MOV-5804102malfunctions closed ormismanaged closed.

1. Blocked compressor(58K401) discharge leadingto surge and highdischarge pressure andtemperature.Potential compressordamage potentially leadingto release of light end gasto ATM.Potential fire and explosion.Potential operator injury.

1. PAH-5804104.2. PSV-5804101/5804102.3. PT-5804105 (2oo3)(HH) will trigger I-5841to trip compressor(58K401).4. TAH-5804104.

P 4 1 2

1.7. Strainer (STR-5825)plugging.

1. Loss of flow tocompressor (58K401) 1stsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. PAL-5804001.2. PDAH-5804003.

A 4 1 2

1.8. Strainer (STR-5826)plugging.

1. Loss of flow tocompressor (58K401) 2ndsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. PAL-5804002.2. PDAH-5804004.

A 4 1 2

1.9. Strainer (STR-5827)partially plugging.

1. Loss of flow tocompressor (58K401) 3rdsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. PAL-5804103.2. PDAH-5804105.

A 4 1 2

1.10. XV-5804501malfunctions closed ormismanaged closed.

1. Loss of C2R to58E404/58E403/58E301/58D404 leading to ethyleneunit shutdown.

1. Operator training andprocedures.2. LIC-5804701 controlFV-5804702.3. FAL-5804801.

A 3 1 2

Sheet: 95 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

Action ByP/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

1 No/Less Flow 1.11. Strainer (STR-5814) partially plugging.

1. Less flow of C2R to58E104 pass #4 leading toless vapor to compressor2nd stage.Potential surge 58K401and potential prematurefailure to 58K401.

1. Anti surge linecontrol (UV-5803801).2. Strainer is designedfor 400 % opening area.

A 3 1 2

1.12. Strainer (STR-5814) inlet or outletmanual valvemismanaged closed.

1. No flow of C2R to58E104 pass #4 leading toless vapor to compressor2nd stage.Potential surge 58K401and potential damage to58K401.

1. Anti surge linecontrol (UV-5803801).2. Operator training andprocedures.3. PAL-5804002.

A 4 1 2

Refer to Action No. 58-N11.02

1.13. Strainer (STR-5818) partially plugging.

1. Less flow of C2R to58E105 pass #4 leading toless vapor to compressor1st stage.Potential surge 58K401and potential prematurefailure to 58K401.

1. Anti surge linecontrol (UV-5803701).2. Strainer is designedfor 400 % opening area.

A 3 1 2

1.14. Strainer (STR-5818) inlet or outletmanual valvemismanaged closed.

1. No flow of C2R to58E105 pass #4 leading toless vapor to compressor1st stage.Potential surge 58K401and potential damage to58K401.

1. Anti surge linecontrol (UV-5803701).2. Operator training andprocedures.3, PAL-5804001.

A 4 1 2

Refer to Action No. 58-N11.01

1.15. Strainer (STR-5812) partially plugging.

1. Less flow of C2R to58E103 pass #4 leading toless vapor to compressor3rd stage.Potential surge 58K401and potential prematurefailure to 58K401.

1. Anti surge linecontrol (UV-5803901).2. Strainer is designedfor 400 % opening area.

A 3 1 2

1.16. Strainer (STR-5812) inlet or outletmanual valvemismanaged closed.

1. No flow of C2R to58E103 pass #4 leading toless vapor to compressor3rd stage.Potential surge 58K401and potential damage to58K401.

1. Anti surge linecontrol (UV-5803901).2. Operator training andprocedures.3. PAL-5804103.4. FAL-5804103.

A 4 1 2

Sheet: 96 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

Action ByP/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

1 No/Less Flow 1. Increased pressure andtemperature in 58K401discharge leading loss ofC2 recovery efficiency.Less profit.

1. PAH-5804104.2. TAH-5804104.3. PDAH-5804501.4. Standby strainer.5. Strainer is designedfor 400 % opening area.

A 3 1 2

2. No significantconsequence in C3Rsystem due to level control(LIC-5805101) in 58D503.

1.18. Strainer (STR-5828) inlet or outletmanual valvemismanaged closed.

1. Overpressurization indischarge 58K401 leadingto potential damage to58K401.Potential release of HC toATM.Potential personnel injury.

1. Operator training andprocedures.2. PAH-5804104.3. TAH-5804104.4. PT-5804105A/B/C(2oo3) (HH) will triggerI-5841 to trip 58K401.5. PSV-5804101/5804102.

P 4 1 2

1.19. UV-5803701/5803801/5803901 not open whenrequired.

1. Potential damage to58K401.Potential release of HC toATM.Potential personnel injury.Potential unit shutdown.

1. None.

P 4 1 2

58-11.03 To be confirmed cause,consequence and safeguard forthis scenario with vendorduring compressor packageHAZOP.

EPC/Vendor

1.20. Compressor(58K401) trip.

1. Potential hightemperature andoverpressure in ERU.Potential release HC toATM leading to potentialfire and explosion.Potential personnel injury.

1. Depressurizationsystem (manual).

P 4 1 2

58-11.04 Consider providing one push-button in the control room forERU shutdown.

EPC

2 More Flow 2.1. Flow control loopfailure (FV-5803502)malfunctions open ormismanaged open.

1. More reflux leading topotential decreasedtemperature in the 58C301.Potential loss of C2 to C2splitter bottoms leading toreduced C2 recovery.Loss of profit.

1. TIC-5803505 withlow alarm.2. PDAH-5803505.3. PDAH-5803507.

A 3 1 2

3 Reverse Flow No cause identified.4 Misdirected Flow 4.1. XV-5804102

malfunctions open ormismanaged open whennot needed.

1. Loss of ethylene productto flare.Loss of profit and highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 2 1 1

1.17. Strainer (STR-5828) partially plugging.

Sheet: 97 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

Action ByP/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

4 Misdirected Flow 4.2. 2" manual valvefrom 58E404 to coldflare mismanaged open.

1. Loss of C2R vapor tocold flare.Loss of profit.

1. Operator training andprocedures.

A 3 1 2

58-11.05 To develop operatingprocedure using of 2" manualvalve when heat exchangeefficiency is not good due tonon condensable vapor in C2Rsystem.

EPC

5.1. PIC-5803504malfunctions not openPV-5803504 whenrequired.

1. Increased pressure in58C301.Potentialoverpressurization of thecolumn leading to potentialdamage to piping andequipment.Potential release of HCs toATM.Potential fire and explosion.Potential operator injury.

1. PT-5803403A/B/C(2oo3) (HH) will triggerI-5843 to close XV-5803501.2. PSV-5803501/5803503.

P 4 1 2

5.2. PIC-5804106malfunctions closing PV-5804106.

1. Increased pressure in58K401 discharge leadingto potential damage to58K401.Potential release of HCs toATM.Potential fire and explosion.Potential operator injury.

1. PT-5804105A/B/C(2oo3) (HH) will triggerI-5841 to trip 58K401.2. PSV-5804101/5804102.3. PAH-5804104.

P 4 1 2

5.3. PIC-5804003malfunctions decreasedspeed (SC-5804003).

1. Increased pressure of1st and 2nd suction.No significantconsequence.

6 Lower Pressure 1. Loss of C2 splitterOVHD to flare.Potential big flaring leadingto potential communitycomplain.Reduced C2 recovery.Loss of profit.

1. CCTV (flare stackmonitoring).2. CSR program.

C 3 1 2

2. Potential 58K401 lowsuction leading to potentialdamage to 58K401.

1. PAL-5804103.2. UV-5803901.3. FAL-5804103.

A 4 1 2

6.2. PIC-5804106malfunctions openingPV-5804106.

1. More flow of C2R to58D404 leading tounbalance of C2R to58E301/ 58E403/ 58E404.No significantconsequence.

Higher Pressure5

6.1. PIC-5803504malfunctions openingPV-5803504.

Sheet: 98 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

Action ByP/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

6 Lower Pressure 6.3. PIC-5804003malfunctions increasedspeed (SC-5804003).

1. Potential surge and highvibration leading topremature failure.

1. Anti surge valve (UV-5803701/3801/3901).2. SAH-5804003.

A 4 1 2

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9.1. LIC-5803701malfunctions openingLV-5803701.

1. Increased level in58D401 leading to potentialC2R liquid carryover to58K401.Potential 58K401 damage.

1. LT-5803702 (2oo3)(HH) will trigger I-5841to trip 58K401.

A 4 1 2

9.2. LIC-5803801malfunctions openingLV-5803801.

1. Increased level in58D402 leading to potentialC2R liquid carryover to58K401.Potential 58K401 damage.

1. LT-5803802 (2oo3)(HH) will trigger I-5841to trip 58K401.

A 4 1 2

9.3. LIC-5803901malfunctions openingLV-5803901.

1. Increased level in58D403 leading to potentialC2R liquid carryover to58K401.Potential 58K401 damage.

1. LT-5803902 (2oo3)(HH) will trigger I-5841to trip 58K401.

A 4 1 2

1. Increased level in58E404 leading to reducedethane vapor to fuel gassystem.Potential 2-phase from58E404 carryover to58K101.Potential damage to58K401.

1. None.

A 3 1 2

58-11.06. Consider high level alarm onLIC-5804603.

EPC

2. Potential lowtemperature ethane (-36C)to 58K101 leading topotential damage 58K101and suction line (H126).

1. TT-5802002 (2oo3)(LL) will trigger I-5807to close XV-5802001.

A 3 1 2

9.5. LIC-5804601malfunctions closing PV-5804106.

1. Increased pressure in58K401 discharge leadingto potential damage to58K401.Potential release of HCs toATM.Potential fire and explosion.Potential operator injury.

1. PT-5804105A/B/C(2oo3) (HH) will triggerI-5841 to trip 58K401.2. PSV-5804101/5804102.3. PAH-5804104.

P 4 1 2

Higher Level9

9.4. LIC-5804602malfunctions closing LV-5804603.

Sheet: 99 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

Action ByP/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

1. Decreased level in58D401 leading to less flowto 58K401.Potential damage to58K401.

1. Anti surge valve (UV-5803701).

A 4 1 2

2. Increased temperatureof treated off gas leading toloss of C2 to fuel gas.Loss of profit.

1. TAH-5802509.

A 2 1 1

1. Decreased level in58D402 leading to less flowto 58K401.Potential damage to58K401.

1. Anti surge valve (UV-5803801).

A 4 1 2

2. Increased temperatureof treated off gas leading toloss of C2 to fuel gas.Loss of profit.

1. TAH-5802509.

A 2 1 1

1. Decreased level in58D403 leading to less flowto 58K401.Potential damage to58K401.

1. Anti surge valve (UV-5803901).

A 4 1 2

2. Increased temperatureof treated off gas leading toloss of C2 to fuel gas.Loss of profit.

1. TAH-5802509.

A 2 1 1

10.4. LIC-5804602malfunctions openingLV-5804603.

1. Decreased level in58E404 leading to loss ofefficiency.Potential pressure buildupC2R surge drum (58D404).

1. LIC-5804603.2. PIC-5804702.

A 3 1 2

10.5. LIC-5804601malfunctions openingPV-5804106.

1. More flow of C2R to58D404 leading tounbalance of C2R to58E301/ 58E403/ 58E404.No significantconsequence.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

10.1. LIC-5803701malfunctions closing LV-5803701.

Lower Level10

10.2. LIC-5803801malfunctions closing LV-5803701.

10.3. LIC-5803801malfunctions closing LV-5803701.

Sheet: 100 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-24

Action ByP/E/A/CCauses

Unit: Ethylene Recovery Unit (58)

Node Title: C2R Compressor SystemNode: 58-11

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

58-021-1 (Rev. 0), 58-023-1 (Rev. 0), 58-024-1 (Rev. 0), 58-035-1 (Rev. 0), 58-036-1 (Rev. 0), 58-037-1 (Rev. 0), 58-038-1 (Rev. 0), 58-039-1 (Rev. 0), 58-040-1 (Rev. 0), 58-041-1 (Rev. 0), 58-045-

1 (Rev. 0), 58-046-1 (Rev. 0), 58-047-1 (Rev. 0), 58-050-1 (Rev. 0)

RemarkActionStatus

L RAction

No.Action Required /

Recommendations

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

1. No ethylene todownstream process andusers leading to potentialunit 58 (ERU) shutdown.Potential loss of productleading to loss of profit.

1. Compressor faultalarm.2. Emergency shutdownprocedure. A 4 1 2

2. Potentialoverpressurization ofupstream unit leading toequipment damage andrelease of HC to ATM.Potential fire and explosion.Potential operator injury.

1. PIC-5803504 withalarm high.2. PT-5803503A/B/C(2oo3) (HH) will triggerI-5843 to close XV-5803501.3. PSV-5803501/5803503.

P 4 1 2

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure No cause identified.

23 Maintenance 23.1. No isolation C3Rto coil.

1. Deviation of isolationphilosophy.

1. None.

A 2 2 2

58-11.06 Consider provide additionalisolation valve on upstreamglove valve (C3R vapor from58K501 line).

EPC

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Power Failure 18.1. Compressor(58K401) power supplyfailure.

18

Sheet: 101 of 196

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Node Title: Reviewed Date: 27-May-13

Node Number: 58-12 Node Color Time: 9:00 - 18:00

58-006-1 (Rev. 0) 58-035-1 (Rev. 0) 58-045-1 (Rev. 0) 58-047-1 (Rev. 0) 58-048-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Ethylene Product Stream to Exsting Header

PATTERNED BROWN

Number of Recommended Actions in this node: 5

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To Send Ethylene Product to Exsting Header as Vapor and C2R System

Notes:

Operation andDesignConditions:

C2R Surge Drum (58D404):Operating(P/T): 17.6barg/-31.9CDesign(P/T): 22.5barg/-110&75CEthylene Product Pumps (58P401A/B):Operating(P/T): 17.6barg/-31.9CDesign: 21.64m3/hr

Ethylene Product Vaporizer (58E502):Operating(P/T): 6.0barg/29.4C (Tube)Design(P/T): 47barg/-110&65C (Shell);36.5barg/-46&65C (Tube)

Ethylene Product Heater (58E503):Operating(P/T): 17barg/19.9C (Shell)Design(P/T): 36.5barg/-46&90C (Shell);47barg/-110&65C (Tube)

Ethylene Product Vaporizer Liquid Pot(58D505):Operating(P/T): 5.9barg/5.3CDesign(P/T): 16.5barg/-46&65C

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HAZOP WORKSHEET

Review Date: 2013-05-27

1 No/Less Flow 1. No flow to pump leadingto loss pump suctionpressure.Potential damage to pump.Potential release ofethylene to ATM leading topotential fire and explosion.Potential personnel injury.

1. Pump fault alarm.2. Gas detector.

P 4 1 2

Refer to Action No. 58-G4 and58-G5

2. Increased level in58D404 leading to potentialcarryover to vapor line.Increased pressure in58D404.Operational upset in58D404.

1. LAH-5804702.2. PIC-5804702.3. Alternative outletlines to 58D403/58C301. A 2 1 1

1.2. XV-5804703malfunctions closed ormismanaged closed.

1. Less reflux flow to58C301 leading to highertemperature and pressurein the column.Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

1. PAH-5803504.2. TAH-5803501.3. PT-5803503A/B/C(2oo3) (HH) will triggerI-5843 to close XV-5803501.4. PSV-5803501/5803503.

P 4 1 2

1.3. Ethylene productpumps suction strainer(STR-5836/5837)plugging.

1. Less flow to pumpleading to loss pumpsuction pressure.Potential damage to pump.Potential release ofethylene to ATM leading topotential fire and explosion.Potential personnel injury.

1. Pump fault alarm.2. Standby pump.

P 3 1 2

58-12.01 Consider low flow alarm onFIC-5804702.

EPC

1.4. Ethylene productpumps (58P401A/B)trips.

1. Increased level in58D404 leading to potentialcarryover to vapor line.Increased pressure in58D404.Operational upset in58D404.

1. LAH-5804702.2. PIC-5804702.3. Alternative outletlines to 58D403/58C301.4. Pump fault alarm.5. Standby pump.

A 2 1 1

1.1. XV-5804701malfunctions closed ormismanaged closed.

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Ethylene Product Stream to Storage 58-006-1 (Rev. 0), 58-035-1 (Rev. 0), 58-045-1 (Rev. 0), 58-047-1 (Rev. 0), 58-048-1 (Rev. 0)Node: 58-12

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 103 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Ethylene Product Stream to Storage 58-006-1 (Rev. 0), 58-035-1 (Rev. 0), 58-045-1 (Rev. 0), 58-047-1 (Rev. 0), 58-048-1 (Rev. 0)Node: 58-12

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.4. Ethylene productpumps (58P401A/B)trips.

2. Potential reverse flow ofethylene from existingheader to 58D404.Increased level in 58D404leading to operationalupset in 58D404.

1. PAL-5804801A.2. Check valve oncommon discharge lineof 58P401A/B. A 2 1 1

1.5. Flow control loopfailure (FV-5804702)malfunctions closed ormismanaged closed.

1. No flow to existingheader.Loss of profit.

1. Minimum flow line.2. FAL-5804801.

A 3 1 2

58-12.02 Consider low flow alarm onFIC-5804701.

EPC

1.6. Flow control loopfailure (FV-5804701)malfunctions closed ormismanaged closedwhen required.

1. Potential damage topump.Potential release ofethylene to ATM leading topotential fire and explosion.Potential personnel injury.

1. Gas detector.

P 4 1 2

Refer to Action No. 58-G3

1. No flow to existingheader.Loss of profit.

1. FAL-5804801.

A 2 1 1

2. Potential overpressure of58E502 and pipingupstream.Potential release ofethylene to ATM leading topotential fire and explosion.Potential personnel injury.

1. PIC-5804801B withhigh alarm.2. 58E502 and piping israted to 600#, same as58P401 shutoffpressure.

P 3 1 2

2 More Flow 1. More flow of ethylene toexisting header leading todecreased level in 58D404.Potential less reflux to58C301.Potential offspec ofethylene.Loss of profit.

1. LIC-5804701 tocontrol FV-5804702.

A 4 1 2

2. Potential low NPSHa andcavitation leading topotential damage to pump.

1. Operator training andprocedures.2. NPSHa is calculatedbased on bottom of58D404.

A 4 1 2

1.7. Battery limit manualvalve mismanagedclosed.

2.1. Both Ethyleneproduct pumps(58P401A/B) runningsimultaneously.

Sheet: 104 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Ethylene Product Stream to Storage 58-006-1 (Rev. 0), 58-035-1 (Rev. 0), 58-045-1 (Rev. 0), 58-047-1 (Rev. 0), 58-048-1 (Rev. 0)Node: 58-12

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

2 More Flow 1. More flow of ethylene toexisting header leading todecreased level in 58D404.Potential less reflux to58C301.Potential offspec ofethylene.Loss of profit.

1. LAL-5804701.

A 4 1 2

2. Potential level buildup in58E502 leading to liquidcarryover to downstreamequipment and existingheader.Potential damage toexisting piping (carbonsteel).

1. LIC-5804801.58E503 is designed forpump maximumcapacity.

A 4 1 2

1. Less flow of ethylene toexisting header leading toloss of profit.

1. FAL-5804801.

A 3 1 2

2. Potential pump overloadleading to premature failureof pump.

1. Overload trip isprovided.2. Standby pump.

A 3 1 2

Refer to Action No. 58-G3

3 Reverse Flow No additional causeidentified.

4.1. 2" manual valvefrom 58E502 to coldflare mismanaged open.

1. Loss of C2R vapor tocold flare.Loss of profit.

1. Operator training andprocedures.

A 3 1 2

58-12.03 To develop operatingprocedure using of 2" manualvalve when heat exchangeefficiency is not good due tonon condensable vapor in C2Rsystem.

EPC

4.2. XV-5804702malfunctions open ormismanaged open whennot required.

1. Loss of ethylene productto flare.Loss of profit and highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 2 1 1

Refer to Action No. 58-G5

5 Higher Pressure 5.1. PIC-5804702malfunctions closing PV-5804702 when required.

1. Increased pressure in58D404.No significantconsequence.

Misdirected Flow4

2.2. Flow control loopfailure (FV-5804702)malfunctions open ormismanaged open.

2.3. Flow control loopfailure (FV-5804701)malfunctions open ormismanaged open whennot required.

Sheet: 105 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Ethylene Product Stream to Storage 58-006-1 (Rev. 0), 58-035-1 (Rev. 0), 58-045-1 (Rev. 0), 58-047-1 (Rev. 0), 58-048-1 (Rev. 0)Node: 58-12

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

5 Higher Pressure 5.2. PIC-5804801Amalfunctions closing PV-5804801A.

1. Potential overpressure of58E502 and pipingupstream.Potential release ofethylene to ATM leading topotential fire and explosion.Potential personnel injury.

1. PIC-5804801B withhigh alarm.2. 58E502 and piping israted to 600#, same as58P401 shutoffpressure.

P 3 1 2

5.3. PIC-5804801Bmalfunctions closing PV-5804801B whenrequired.

1. Increased pressure in58E503.No significantconsequence.

6.1. PIC-5804702malfunctions openingPV-5804702 when notrequired.

1. Loss of ethylene productto flare.Loss of profit and highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 2 1 1

6.2. PIC-5804801Amalfunctions openingPV-5804801A.

1. More flow of ethylene toexisting header leading todecreased level in 58D404.Potential less reflux to58C301.Potential offspec ofethylene.Loss of profit.

1. LAL-5804701.2. FIC-5804702 tocontrol FV-5804702.

A 4 1 2

6.3. PIC-5804801Bmalfunctions openingPV-5804801B when notrequired.

1. Loss of ethylene productto flare.Loss of profit and highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 2 1 1

7 Higher Temperature 7.1. TIC-5804801malfunctions openingTV-5804801.

1. Increased temperatureof ethylene.No significantconsequence.

8 Lower Temperature 8.1. TIC-5804801malfunctions closing TV-5804801.

1. Decreased temperatureof ethylene (approximately-13 C) leading to potentialdamage to existing headerpiping (carbon steel).

None.

A 3 1 2

58-12.04 To confirm MDMT of existingcarbon steel header.

IRPC

9 Higher Level 9.1. LIC-5804701malfunctions closing FV-5804702.

1. No flow to existingheader.Loss of profit.

1. Minimum flow line.2. FAL-5804801.

A 3 1 2

Lower Pressure6

Sheet: 106 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Ethylene Product Stream to Storage 58-006-1 (Rev. 0), 58-035-1 (Rev. 0), 58-045-1 (Rev. 0), 58-047-1 (Rev. 0), 58-048-1 (Rev. 0)Node: 58-12

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

9 Higher Level 9.2. LIC-5804801malfunctions closing LV-5804801.

1. Increased shell sidelevel leading to potentialcarryover to 58E503.potential temperature lowerthan MDMT of existingheader (carbon steel).Potential damage to piping.

1. TIC-5804801 withlow alarm.

A 3 1 2

9.3. LIC-5804802malfunctions closing LV-5804802.

1. Increased shell sidelevel leading to potentialcarryover to 58E503.potential temperature lowerthan MDMT of existingheader (carbon steel).Potential damage to piping.

1. TIC-5804801 withlow alarm.

A 3 1 2

1. More flow of ethylene toexisting header leading todecreased level in 58D404.Potential less reflux to58C301.Potential offspec ofethylene.Loss of profit.

1. PIC-5804801A.

A 4 1 2

2. Potential level buildup in58E502 leading to liquidcarryover to downstreamequipment and existingheader.Potential damage toexisting piping (carbonsteel).

1. LIC-5804801.2. 58E503 is designedfor pump maximumcapacity.

A 4 1 2

10.2. LIC-5804801malfunctions openingLV-5804801.

1. Decreased level in58E502.Increased temperature ofethylene.No significantconsequence.

10.3. LIC-5804802malfunctions openingLV-5804802.

1. Decreased level in58E502.Increased temperature ofethylene.No significantconsequence.

11 Composition changed No cause identified.

10.1. LIC-5804701malfunctions openingFV-5804702.

10.1. Lower Level10

Sheet: 107 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Ethylene Product Stream to Storage 58-006-1 (Rev. 0), 58-035-1 (Rev. 0), 58-045-1 (Rev. 0), 58-047-1 (Rev. 0), 58-048-1 (Rev. 0)Node: 58-12

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

12 More Contamination No cause identified.

13 Relief 13.1. External fire. 1. Potentialoverpressurization of58E502 discharge leadingto downstreampiping/equipment damage.Release of HCs to ATMleading to potential fireescalation.Potential operator injury.

1. PSV-5804801 fortube side.

P 4 1 2

58-12.05 Consider providing relief valveat 58E502 shell side in case ofexternal fire.

EPC

14 Sampling No cause identified.15 Abnormal Operation No cause identified.16 Corrosion/Erosion No cause identified.17 Human Errors No cause identified.18 Power Failure Ethylene Product pump

(58P401A/B) powersupply failure.

No flow of ethylene leadingto higher level andpressure in the 58D404.Potentialoverpressurization of thecolumn leading to releaseof HCs to ATM.Potential fire and explosion.Potential operator injury.

PIC-5804702 to controlPV-5804702.Pump fault alarm.Standby pump withdifferent power feederline. P 4 1 2

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture 25.1. Tube pinhole leakat 58E503.

1. Ethylene is leaked to theC3R system.Potential increasedpressure and potentialreduced efficiency of C2recovery in the ERUrefrigeration system.

1. PIC-5805801 withhigh alarm.

A 3 1 2

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 108 of 196

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Node Title: Reviewed Date: 27-May-13

Node Number: 58-13 Node Color Time: 9:00 - 18:00

58-006-1 (Rev. 0) 58-012-1 (Rev. 0) 58-026-1 (Rev. 0) 58-034-1 (Rev. 0) 58-045-1 (Rev. 0) 58-048-1 (Rev. 0)

58-050-1 (Rev. 0) 58-051-1 (Rev. 0) 58-058-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

C3R Compressor Suction Drum System

PATTERNED LIGHT BLUE

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To provide C3R to compressor (58K501)

Notes:PSV-5804503/5804504 set pressure is 17.0 barg, piping design pressure is 16.9 barg.

Operation andDesignConditions:

C2R Desuperheater No. 1 (58E401):Operating(P/T): 18.6barg/17.7CDesign(P/T): 22.5barg/-46&65C(1st pass);17barg/-46&65C(2nd pass)

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HAZOP WORKSHEET

Review Date: 2013-05-27

1 No/Less Flow 1.1. Strainer (STR-5830/5831) plugging.

1. Less flow of C3R to58D503 leading toincreased temperature ofdischarge of compressor.Higher pressure at58D404.Loss of ethylene to flare.Loss of profit.

1. PDAH-5804502.2. Standby strainer.3. Strainer is designedfor 400 % opening area.

A 3 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

1. Loss of propylene tocool down compressor58K401 discharge.Loss of ethylene to flare.Loss of profit and highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 3 1 2

1. Loss of C3R to flare.Loss of profit.

1. None.C 3 1 2

Refer to Action No. 58-G5

5.1. PIC-5805101malfunctions openingPV-5805101A.

1. Potentialoverpressurization in58D503 leading to potentialdamage to 58D503.Potential release of HC toATM leading to fire andexplosion.Potential personnel injury.

1. PSV-5805101/5805102.

P 4 1 2

5.2. PIC-5805101malfunctions closing PV-5805101B whenrequired.

1. Potentialoverpressurization in58D503 leading to potentialdamage to 58D503.Potential release of HC toATM leading to fire andexplosion.Potential personnel injury.

1. PSV-5805101/5805102.

P 4 1 2

6 Lower Pressure 6.1. PIC-5805101malfunctions closing PV-5805101A.

1. Potential increasedpressure of compressor(58K501) discharge leadingto potential operationalupset.

1. PIC-5805801B.

A 2 1 1

4.1. XV-5805101malfunctions open ormismanaged open whennot required.

Higher Pressure5

Causes RemarkAction ByP/E/A/C

Misdirected Flow4

ActionStatus

L RAction

No.Action Required /

Recommendations

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor Suction Drum System 58-006-1 (Rev. 0), 58-012-1 (Rev. 0), 58-026-1 (Rev. 0), 58-034-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-058-1 (Rev. 0)Node: 58-13

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

Sheet: 110 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

Causes RemarkAction ByP/E/A/CActionStatus

L RAction

No.Action Required /

Recommendations

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor Suction Drum System 58-006-1 (Rev. 0), 58-012-1 (Rev. 0), 58-026-1 (Rev. 0), 58-034-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-058-1 (Rev. 0)Node: 58-13

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

6 Lower Pressure 6.1. PIC-5805101malfunctions closing PV-5805101A.

2. Decreased pressure in58D503 leading to potentiallower temperature in58E401.No significantconsequence.

1. Potential increasedpressure of compressor(58K501) discharge leadingto potential operationalupset.

1. PIC-5805801B.

A 2 1 1

2. Decreased pressure in58D503 leading to potentiallower temperature in58E401.No significantconsequence.

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level 9.1. LIC-5805101malfunctions openingLV-5805101.

1. Increased level in58D503.No significantconsequence.

1. Decreased level in58D503 leading to loss ofsuction of 58K501.Potential damage tocompressor.

1. FAL-5805301.2. PAL-5805201.3. PAL-5805301.

A 4 1 2

2. No heat exchangeleading to decreasedethylene producttemperature.Potential damage toexisting header (carbonsteel).

1. TIC-5804801 withlow alarm.

A 3 1 2

3. Higher temperature andpressure in discharge ofcompressor (58K401) andhigher pressure in 58D404.Potential big flaring leadingto community complain.Loss of profit.

1. PIC-5804106 tocontrol PV-5804106.2. CCTV (flare stackmonitoring).3. CSR program.

C 2 1 1

11 Composition changed No cause identified.

6.2. PIC-5805101malfunctions openingPV-5805101B when notrequired.

10.1. LIC-5805101malfunctions closing LV-5805101.

Lower Level10

Sheet: 111 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

Causes RemarkAction ByP/E/A/CActionStatus

L RAction

No.Action Required /

Recommendations

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor Suction Drum System 58-006-1 (Rev. 0), 58-012-1 (Rev. 0), 58-026-1 (Rev. 0), 58-034-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-058-1 (Rev. 0)Node: 58-13

Ref.No.

Deviation Action TakenPossible

ConsequencesExisting Safeguards S

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 112 of 196

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Node Title: Reviewed Date: 28-May-13

Node Number: 58-14 Node Color Time: 9:00 - 18:00

58-020-1 (Rev. 0) 58-026-1 (Rev. 0) 58-037-1 (Rev. 0) 58-045-1 (Rev. 0) 58-048-1 (Rev. 0) 58-049-1 (Rev. 0)

58-050-1 (Rev. 0) 58-051-1 (Rev. 0) 58-053-1 (Rev. 0) 58-057-1 (Rev. 0) 58-058-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

C3R Compressor 2nd Stage System (including final discharge downstreamsystems)

PATTERNED PINK

Number of Recommended Actions in this node: 1

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent:To compress C3R by 58K501 and send it to condense ethylene refrigerator system and cooldown treated offgasfrom 58K001

Notes:

Operation andDesignConditions:

C2R Desuperheater No. 2 (58E402):Operating(P/T): 18.4barg/13CDesign(P/T): 22.5barg/-46&65C(1st pass);17barg/-46&65C(2nd pass)

C3R Compressor 2nd Stage Suction Drum(58D502):Operating(P/T): 2barg/-20CDesign(P/T): 16.5barg/-46&65C

C3 Refrigeration Compressor (58D501):Operating(P/T): 0.23barg/-41.9CDesign Capacity@SuctionCondition(Nm3/hr): 13612(1st); 27910(2nd)

C3R Condenser (58E501):Operating(P/T): 17.7barg/86C (Shell)Design(P/T): 21barg/-46&140C(Shell);16.2barg/11&100C(Tube)

C3R Surge Drum (58D504):Operating(P/T): 17barg/42CDesign(P/T): 21barg/-46&140C

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HAZOP WORKSHEET

Review Date: 2013-05-28

1 No/Less Flow 1.1. Strainer (STR-5832/5833) plugging.

1. Less flow of C3R to58E502 leading toincreased temperature ofdischarge of compressor.Higher pressure at58D404.Loss of ethylene to flare.Loss of profit.

1. PDAH-5804503.2. Standby strainer.3. Strainer is designedfor 400 % opening area.

A 3 1 2

1.2. Strainer (STR-5832/5833) Inlet/ outletmanual valvemismanaged closed.

1. No flow of C3R to58E502 leading toincreased temperature ofdischarge of compressor.Higher pressure at58D404.Loss of ethylene to flare.Loss of profit.

1. Operator training andprocedures.2. PDAH-5804503.3. Standby strainer.4. Strainer is designedfor 400 % opening area.

A 4 1 2

1.3. UV-5804901/5805001 notopen when required.

1. Potential damage to58K501.Potential release of HC toATM.Potential personnel injury.Potential unit shutdown.

1. None.

P 4 1 2

58-14.01 To be confirmed cause,consequence and safeguard forthis scenario with vendorduring compressor packageHAZOP.

EPC

1.4. MOV-5805301malfunctions closed ormismanaged closed.

1. Loss of flow tocompressor (58K501) 2ndsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. Interlock (I-5851) toprevent MOV-5805301to be closed whencompressor is running(refer to note 6 onP&ID# 58-053).2. PAL-5805301.3. FAL-5805301.

A 4 1 2

1.5. Strainer (STR-5839)plugging.

1. Less of flow tocompressor (58K501) 2ndsuction leading to heatbuildup and high vibration.Potential compressordamage.

1. PDAH-5805304.2. PAL-5805301.3. FAL-5805301.

A 3 1 2

1.6. Compressor(58K501) trip.

1. Potential hightemperature andoverpressure in ERU.Potential release HC toATM leading to potentialfire and explosion.Potential personnel injury.

1. Depressurizationsystem (manual).

P 4 1 2

Refer to Action No.58-11.04(Consider providing one push-button in the control room forERU shutdown)

58-020-1 (Rev. 0), 58-026-1 (Rev. 0), 58-037-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-049-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-053-1 (Rev. 0), 58-057-1 (Rev. 0), 58-058-

1 (Rev. 0)

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 2nd Stage System (including final discharge downstream systems)Node: 58-14

Ref.No.

Deviation Causes RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

PossibleConsequences

Existing Safeguards P/E/A/C Action Taken

Sheet: 114 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-2858-020-1 (Rev. 0), 58-026-1 (Rev. 0), 58-037-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-

049-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-053-1 (Rev. 0), 58-057-1 (Rev. 0), 58-058-1 (Rev. 0)

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 2nd Stage System (including final discharge downstream systems)Node: 58-14

Ref.No.

Deviation Causes RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

PossibleConsequences

Existing Safeguards P/E/A/C Action Taken

1 No/Less Flow 1. Blocked compressor(58K501) discharge leadingto surge and highdischarge pressure andtemperature.Potential compressordamage potentially leadingto release of light end gasto ATM.Potential fire and explosion.Potential personnel injury.

1. PAH-5805302.2. PSV-5805201/5805302.3. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).4. TAH-5805302.

P 4 1 2

2. Big flaring leading topotential communitycomplain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 3 1 2

1. Blocked compressor(58K501) discharge leadingto surge and highdischarge pressure andtemperature.Potential compressordamage potentially leadingto release of light end gasto ATM.Potential fire and explosion.Potential personnel injury.

1. PAH-5805302.2. PSV-5805201/5805302.3. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).4. TAH-5805302.

P 4 1 2

2. Big flaring leading topotential communitycomplain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 3 1 2

1. Blocked compressor(58K501) discharge leadingto surge and highdischarge pressure andtemperature.Potential compressordamage potentially leadingto release of light end gasto ATM.Potential fire and explosion.Potential personnel injury.

1. Operator training andprocedures.2. PAH-5805302.3. PSV-5805201/5805302.4. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).5. TAH-5805302.

P 4 1 2

2. Big flaring leading topotential communitycomplain.

1. CCTV (flare stackmonitoring).2. CSR program.

C 3 1 2

1.7. MOV-5805302malfunctions closed ormismanaged closed.

1.8. XV-5805701malfunctions closed ormismanaged closed.

1.9. Inlet/ outlet manualvalve on 58E501mismanaged closed.

Sheet: 115 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-2858-020-1 (Rev. 0), 58-026-1 (Rev. 0), 58-037-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-

049-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-053-1 (Rev. 0), 58-057-1 (Rev. 0), 58-058-1 (Rev. 0)

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 2nd Stage System (including final discharge downstream systems)Node: 58-14

Ref.No.

Deviation Causes RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

PossibleConsequences

Existing Safeguards P/E/A/C Action Taken

1 No/Less Flow 1. No flow of C3R to58E503/58E004/58E017leading to increasedtemperature of discharge ofcompressor (58K501).Higher pressure at58D404.Loss of C2/ C3 to flare.Loss of profit.

1. TAH-5805302.2. PAH-5805302.3. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).

A 4 1 2

2. Potential overfill of58D504 leading tooverpressurization ondischarge compressor(58K501).Potential release of C3Rleading to fire andexplosion.Potential personnel injury.

1. PAH-5805302.2. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).3. PSV-5805301/5805302.4. PIC-5805801 withhigh alarm.5. LAH-5805801.

P 4 1 2

3. Increased level in58D504 leading to potentialC3R liquid carryover toCFA.Big flaring leading topotential communitycomplain.

1. LAH-5805801.2. CCTV (flare stackmonitoring).3. CSR program.

C 3 1 2

2 More Flow 2.1. UV-5804901/5805001 openwhen not required.

1. Less flow of C3R tousers leading to less ofheat exchanger efficiency.Less profit.

1. TIC-5804801 withlow alarm.2. TAL-5802510.3. TIC-5800601 withlow alarm.

A 3 1 2

3 Reverse Flow No cause identified.

4.1. XV-5805801malfunctions open ormismanaged open whennot needed.

1. Loss of C3R to flare.Loss of profit and highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program. C 2 1 1

4.2. Inert gas manualvalve mismanaged openinadvertently.

1. Loss of C3R vapor to58D504 leading to higherpressure in 58D504.Potential loss of C3R toflare.Loss of profit.

1. Operator training andprocedures.2. PAH-5805801.3. RO-5805701. A 3 1 2

Misdirected Flow4

1.10. XV-5805802malfunctions closed ormismanaged closed.

Sheet: 116 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-2858-020-1 (Rev. 0), 58-026-1 (Rev. 0), 58-037-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-

049-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-053-1 (Rev. 0), 58-057-1 (Rev. 0), 58-058-1 (Rev. 0)

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 2nd Stage System (including final discharge downstream systems)Node: 58-14

Ref.No.

Deviation Causes RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

PossibleConsequences

Existing Safeguards P/E/A/C Action Taken

5.1. PIC-5805801Amalfunctions openingPV-5805801A.

1. Increased pressure andtemperature in 58D504leading to potentialoverpressurization in58D504.Potential release of C3R toATM leading to fire andexplosion.Potential personnel injury.

1. PAH-5805302.2. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).3. PSV-5805301/5805302.

P 4 1 2

5.2. PIC-5805801Bmalfunctions closing PV-5805801B.

1. Increased pressure andtemperature in 58D504leading to potentialoverpressurization in58D504.Potential release of C3R toATM leading to fire andexplosion.Potential personnel injury.

1. PAH-5805302.2. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).3. PSV-5805301/5805302.

P 4 1 2

5.3. PDIC-5805802malfunctions closingPDV-5805802.

1. Increased level in58D504 leading to reducedlevel in 58D503.Potential loss of heatexchange efficiency at58E003.Less profit.

1. LAH-5805801.2. TAH-5801202.

A 3 1 2

6.1. PIC-5805801Amalfunctions closing PV-5805801A.

1. Low temperature andpressure in 58D504.No significantconsequence.

1. Loss of C3R to flare.Loss of profit and highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program. C 3 1 2

2. Decreased level in58D504 leading to less flowof C3R to 58D503.Potential loss of heatexchange efficiency at58E003.Less profit.

1. TAH-5801202.2. PDIC-5805802.

A 3 1 2

6.3. PDIC-5805802malfunctions openingPDV-5805802.

1. Decreased level in58D504 leading toincreased level in 58D503.No significantconsequence.

6.2. PIC-5805801Bmalfunctions openingPV-5805801B.

Higher Pressure5

Lower Pressure6

Sheet: 117 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-2858-020-1 (Rev. 0), 58-026-1 (Rev. 0), 58-037-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-

049-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-053-1 (Rev. 0), 58-057-1 (Rev. 0), 58-058-1 (Rev. 0)

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 2nd Stage System (including final discharge downstream systems)Node: 58-14

Ref.No.

Deviation Causes RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

PossibleConsequences

Existing Safeguards P/E/A/C Action Taken

1. Increased temperatureof C3R leading tooverpressurization in58D504 and pipingdownstream.Potential release of C3R toATM leading to fire andexplosion.Potential personnel injury.

1. Operator training andprocedures.2. TAH-5805703.3. PIC-5805801B withhigh alarm.4. PSV-5805301/5805302.

P 4 1 2

2. Potential hot C3R vaporto 58D503 leading tohigher temperature andpressure in 58D503 andloss of C3R liquid torefrigerant system leadingto overpressure incompressor (58K501)downstream section.Potential release of C3R toATM leading to fire andexplosion.Potential personnel injury.

1. TAH-5801202.2. PDIC-5805802.3. XV-5805801.

P 4 1 2

Refer to Action No.58-11.04(Consider providing one push-button in the control room forERU shutdown)

3. Potential to thermalexpansion 58E501 tubeside leading to potentialtube rupture.

1. PSV-5805703.

A 3 1 2

8 Lower Temperature No cause identified.

9 Higher Level 9.1. LIC-5805001malfunctions openingLV-5805001.

1. Increased level in58D502 leading to potentialC3R liquid carryover to58K501.Potential 58K501 damage.

1. LT-5805002A/B/C(2oo3) (HH) will triggerI-5851 to trip 58K501.

A 4 1 2

10 Lower Level 10.1. LIC-5805001malfunctions closing LV-5805001.

1. Decreased level in58D502 leading to lessC3R liquid to users andless C3R vapor flow to58K501 2nd stage.Potential damage to58K501.Loss of profit due to lessheat exchange efficiency.

1. Anti surge valve (UV-5805001).2. TIC-5804801 withlow alarm.3. LAH-5805101.

A 4 1 2

11 Composition changed No cause identified.

12 More Contamination No cause identified.

Higher Temperature7 7.1. Cooling waterinlet/outlet manual valveat 58E501 mismanagedclosed.

Sheet: 118 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-2858-020-1 (Rev. 0), 58-026-1 (Rev. 0), 58-037-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-

049-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-053-1 (Rev. 0), 58-057-1 (Rev. 0), 58-058-1 (Rev. 0)

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 2nd Stage System (including final discharge downstream systems)Node: 58-14

Ref.No.

Deviation Causes RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

PossibleConsequences

Existing Safeguards P/E/A/C Action Taken

13.1. External fire. 1. Potentialoverpressurization of58D504 discharge leadingto downstreampiping/equipment damage.Release of steam to ATM.Potential operator injury.

1. PSV-5805801.

P 4 1 2

13.2. External fire. 1. Potentialoverpressurization of58E501 discharge leadingto downstreampiping/equipment damage.Release of steam to ATM.Potential operator injury.

1. PSV-5805701.

P 4 1 2

13.3. External fire. 1. Potentialoverpressurization of58D502 discharge leadingto downstreampiping/equipment damage.Release of steam to ATM.Potential operator injury.

1. PSV-5805001/5805002.

P 4 1 2

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

1. No propylene todownstream process andusers leading to potentialunit 58 (ERU) shutdown.Potential loss of productleading to loss of profit.

1. Compressor faultalarm.2. Emergency shutdownprocedure. A 4 1 2

2. Potentialoverpressurization ofupstream unit leading toequipment damage andrelease of C3R to ATM.Potential fire and explosion.Potential personnel injury.

1. PAH-5805302.2. PT-5805303A/B/C(2oo3) (HH) will triggerI-5851 to tripcompressor (58K501).3. PSV-5805301/5805302.

P 4 1 2

19 Steam Failure N/A

20 Cooling Water Failure N/A

21 Nitrogen Failure N/A

18.1. Compressor(58K501) power supplyfailure.

Power Failure18

Relief13

Sheet: 119 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-2858-020-1 (Rev. 0), 58-026-1 (Rev. 0), 58-037-1 (Rev. 0), 58-045-1 (Rev. 0), 58-048-1 (Rev. 0), 58-

049-1 (Rev. 0), 58-050-1 (Rev. 0), 58-051-1 (Rev. 0), 58-053-1 (Rev. 0), 58-057-1 (Rev. 0), 58-058-1 (Rev. 0)

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 2nd Stage System (including final discharge downstream systems)Node: 58-14

Ref.No.

Deviation Causes RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

PossibleConsequences

Existing Safeguards P/E/A/C Action Taken

22 IA/PA Failure No cause identified.

23 Maintenance 23.1. One manholeprovided for 58D504.

1. Confined space.Not adequate ventilation.Potential personnel injury.

1. Confined spacepermit to work system.2. Vessel is designedas per UHV Projectspecification.

P 4 1 2

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture 25.1. Tube pinhole leakat 58E501.

1. C3R leaks into coolingwater system leading torelease of VOCs in thecooling water basin.Potential environmentalimpacts.

1. 'AAH-7500102 (HC).

E 2 1 1

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 120 of 196

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Node Title: Reviewed Date: 22-May-13

Node Number: 58-15 Node Color Time: 9:00 - 18:00

58-046-1 (Rev. 0) 58-049-1 (Rev. 0) 58-052-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

C3R Compressor 1st Stage System

PATTERNED PURPLE

Number of Recommended Actions in this node: 4

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To compress C3R vapour in the 1st stage C3R refrigerant compressor (58K501) and send it to users.

Notes:

Operation andDesignConditions:

C2R Condenser (58E403):Operating(P/T): 18.2barg/-16.2CDesign(P/T): 22.5barg/-110&65C(1st pass); -0.5barg@-46C&17barg/-110&65C(2nd pass)

C3R Compressor 1st Stage Suction Drum(58D501):Operating(P/T): 0.23barg/-41.9CDesign(P/T): -0.5barg@-46C&16.5barg/-46&65C

C3 Refrigeration Compressor (58K501):Operating(P/T): 4barg/-10.4CDesign Capacity@SuctionCondition(Nm3/hr): 13612(1st); 27910(2nd)

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HAZOP WORKSHEET

Review Date: 2013-05-22

1 No/Less Flow 1.1. Strainer (STR-5834/5835) plugging.

1. Less flow back to58D501.Less flow to compressor(58K501) suction leading toheat buildup and highvibration.Potential compressordamage.

1. PDAH-5804602.2. PAL-5805201.3. Spare strainer.

A 4 1 2

1.2. MOV-5805201malfunctions closed ormismanaged closed.

1. Loss of flow to thecompressor (58K501)suction leading to heatbuildup and high vibration.Potential compressor (1ststage) damage.

1. PAL-5805201.I-5851 (permissive toclose MOV-5805201only after compressorshutdown).

A 4 1 2

1. Less flow to thecompressor (58K501)suction leading to heatbuildup and high vibration.Potential compressordamage.

1. PDAH-5805204.2. PAL-5805201.3. PIC-5805203 toreduce compressor(58K501) speed.

A 4 1 2

58-N15.01

Consider providing low flowalarm on FI-5805201.

EPC

2. Less compressor(58K501) discharge flowand pressure leading toless cooling efficiency atthe users.Potential operational upsetin the cold box exchangers.Potential offspec ethyleneproduct.Potential loss of C2 to thefuel gas system leading toless profit.

1. PDAH-5805204.2. PAL-5805301.

A 3 1 2

1. Potential unit shutdown. 1. Compressor faultalarm2. FAL-5805301.

A 3 1 2

Refer to 58-N15.01.

2. Potential upstreamoverpressure leading to bigflaring.Potential communitycomplaint.

1. CCTV (flare stackmonitoring).2. CSR program.

C 2 1 1

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

1.3. Compressor(58K501) 1st stagesuction strainer (STR-5838) plugging.

1.4. 1st stage C3refrigeration compressor(58K501) trips.

Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 1st Stage System 58-046-1 (Rev. 0), 58-049-1 (Rev. 0), 58-052-1 (Rev. 0)

Node: 58-15

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/E/A/C Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 122 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 1st Stage System 58-046-1 (Rev. 0), 58-049-1 (Rev. 0), 58-052-1 (Rev. 0)

Node: 58-15

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/E/A/C Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1. Less flow to thecompressor (58K501)suction leading to heatbuildup and high vibration.Potential compressor (1ststage) damage.

1. PAL-5805201.

A 4 1 2

2. Potentialoverpressurization of58D501 and upstreampiping.Potential piping andequipment damage leadingto release of C3R to ATM.Potential fire and explosion.Potential personnel injury.

1. Upstream piping andequipment are designedwith the same or higherconditions with 58D501.

P 4 1 2

5.2. PIC-5805203malfunctions(underspeeding)

1. High suction pressure.No significantconsequence.

6 Lower Pressure 6.1. PIC-5805203malfunctions(overspeeding)

1. Potential vacuumconditions at thecompressor (58K501)suction leading to potentialcompressor and pipingdamage.

1. PAL-5805201.2. SAH-5805203.3. Compressor faultalarm. A 4 1 2

58-N15.02

Confirm with vendor whetherPT-5805203 can cover thevacuum condition andoverpressurization condition.

EPC

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified. 3. Increased level in58D504 leading to potentialC3R liquid carryover toCFA.Big flaring leading topotential communitycomplain.

9 Higher Level 9.1. LIC-5804901malfunctions openingLV-5804901.

1. Increased level in58D501 leading to potentialcarryover of liquid C3R tocompressor suction.Potential compressordamage.

1. LT-5804902 (2oo3)will trigger I-5851 to tripthe compressor(58K501).

A 4 1 2

5.1. 53D501 demisterplugging.

5 Higher Pressure

Sheet: 123 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 1st Stage System 58-046-1 (Rev. 0), 58-049-1 (Rev. 0), 58-052-1 (Rev. 0)

Node: 58-15

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/E/A/C Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

10 Lower Level 10.1. LIC-5804901malfunctions closing LV-5804901.

1. Reduced level in58D501 leading to potentialloss of condensation in the58E403.Potential highertemperature of ethyleneliquid leading to less C2recovery.Loss of profit.

1. LAL-5804701.2. PAL-5805201.

A 3 1 2

58-N15.03

Consider low level alarm on LT-5804601.

EPC

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling 14.1. No sampling pointfor C3R liquidcirculation.

1. Not possible to detectany light HC leak into therefrigeration loop leading topotential increasedpressure and potentialreduced efficiency of C2recovery in the ERUrefrigeration system.

1. PIC-5805801 withalarm high.

A 3 1 2

58-N15.04

Consider relocating samplingpoint (SC-5820) to inlet of theC3R surge drum (58D504).

EPC

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

1. Compressor trips.Potential unit shutdown.

1. Compressor faultalarm2. FAL-5805301.

A 3 1 2

2. Potential upstreamoverpressure leading to bigflaring.Potential communitycomplaint.

1. CCTV (flare stackmonitoring).2. CSR program.3. PSVs provided forpower failure scenario.

C 2 1 1

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

18 Power Failure 18.1. Compressor(58K501) power supplyfailure.

Sheet: 124 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-22Unit: Ethylene Recovery Unit (58)

Node Title: C3R Compressor 1st Stage System 58-046-1 (Rev. 0), 58-049-1 (Rev. 0), 58-052-1 (Rev. 0)

Node: 58-15

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/E/A/C Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

24 Start-up/Shutdown 24.1. HV-5804901malfunctions closed ormismanaged closed.

1. Delayed startup.Loss of profit.

1. Operator training andprocedures.

A 2 1 1

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 125 of 196

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Node Title: Reviewed Date:

Node Number: 58-16 Node Color Time: 9:00 - 18:00

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Number of Recommended Actions in this node:

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent:

Notes:

Operation andDesignConditions:

C2R Condenser (58E403):Operating(P/T):Design(P/T): 22.5barg/-110&65C(1st pass); -0.5barg@-46&17C/-110&65C(2nd pass)

C3R Compressor 1st Stage Suction Drum(58D501):Operating(P/T):Design(P/T): -0.5barg@-46&16.5C/-46&65C

C3 Refrigeration Compressor (58D501):Operating(P/T):Design Capacity@SuctionCondition(Nm3/hr): 13612(1st); 27910(2nd)

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HAZOP WORKSHEET

Review Date:

No/Less Flow

More Flow

Reverse Flow

Misdirected Flow

Higher Pressure

Lower Pressure

Higher Temperature

Lower Temperature

Higher Level

Lower Level

Composition changed

More Contamination

Relief

Sampling

Abnormal Operation

Corrosion/Erosion

Human Errors

Power Failure

Steam Failure

Cooling Water Failure

Nitrogen Failure

IA/PA Failure

Maintenance

Start-up/Shutdown

Leakage/Rupture

Static Electricity

Spare Equipment

Others

Cat.

Unit: Ethylene Recovery Unit (58)

Node Title:

Node: 58-16

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 127 of 196

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Node Title: Reviewed Date: 27-May-13

Node Number: 58-17 Node Color Time: 9:00 - 18:00

58-013-1 (Rev. 0) 58-059-1 (Rev. 0) 58-060-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Regeneration Mode of Treated Offgas Dryers

PATTERNED LIGHT PURPLE

Number of Recommended Actions in this node: 2

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To regenerate treated offgas dryer (58R001A/B) using residue gas from demethanizer section

Notes:

Operation andDesignConditions:

Treated Offgas Dryers (58R001B):Operating(P/T): 35barg/15CDesign(P/T): 42barg/-10&70C

Regen Gas Feed Heater (58E013):Operating(P/T): 7.4barg/32.7C (Tube)Design(P/T): FV@100&50C/11&423C(Shell); 38.5barg/11&290C (Tube)

Regen Gas Feed Heater Condensate Pot(58D004):Operating(P/T): 44.9barg/259CDesign(P/T): FV@423&50C/11&423C

Regen Gas Cooler (58E014):Operating(P/T): 6.3barg/227C (Shell)Design(P/T): FV@100&10.2C/11&290C(Shell); 10barg/11&100C (Tube)

Regen Gas KO Drum (58D002):Operating(P/T): 6.1barg/40CDesign(P/T): FV@100&10.2C/11&80C

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HAZOP WORKSHEET

Review Date: 2013-05-27

1 1.1. XV-5801306Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R001B).

1. Operator training andprocedures.

A 2 2 2

1.2. XV-5801308Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R001B).

1. Operator training andprocedures.

A 2 2 2

1.3. XV-5801303Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R001B).

1. Operator training andprocedures.

A 2 2 2

No/Less Flow(Heating)

1.4. Flow control loopfailure (FV-5805904)malfunctions closed ormismanaged closed.

1. No flow of regen gas todryer (58R001B) forheating.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R001B).

1. TAL-5805902.

A 2 2 2

No/Less Flow(Cooling)

1.5. Flow control loopfailure (FV-5805903)malfunctions closed ormismanaged closed.

1. No flow of regen gas todryer (58R001B) forcooling.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R001B).

1. TAH-5805902.2. TAH-5801301B.

A 2 2 2

No/Less Flow(Depressurization)

1.6. XV-5801307Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R001B).

1. Operator training andprocedures.

A 2 2 2

No/Less Flow 1.7. Manual valve at thedryer vent linemismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R001B).

1. Operator training andprocedures.

A 2 2 2

No/Less Flow

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-013-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-17

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 129 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-013-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-17

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.8. Manual valve inletof 58E013 mismanagedclosed.

1. No flow of regen gas.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R001B).

1. Operator training andprocedures.2. FAL-5805904.3. FAL-5805902. A 2 2 2

1. More flow of regen gasto dryer (58R001A/B).Potential bed lift leading toloss of adsorbent.

1. TAH-5806001.2. RO-5806001.

A 3 1 2

2. Higher temperatureleading to short life time ofdesiccant.

1. TAH-5805902.

A 3 1 2

More Flow(Cooling)

2.2. Flow control loopfailure (FV-5805903)malfunctions fully openor mismanaged fullyopen.

1. More flow of regen gasto dryer (58R001A/B).Potential bed lift leading toloss of adsorbent.

1. RO-5806001.

A 3 1 2

3 Reverse Flow No cause identified.

4.1. XV-5801302Bmalfunction open ormismanaged open when58R001A in operation.

1. Treated offgas is sent to58E014 and 58D002leading to potentialoverpressurization andequipment damage.

1. RO-5806001.2. PSV-5806004/5806005/5806006.

A 3 1 2

4.2. XV-5801304Bmalfunction open ormismanaged open when58R001A in operation.

1. Potential treat offgasback to 58R001B leadingto failure of regeneration.potential overpressurizationand equipment (58E014/58D002) damage.

1. RO-5806001.2. PSV-5806004/5806005/5806006.

A 3 1 2

4.3. XV-5801305Bmalfunction open ormismanaged open when58R001A in operation.

1. Potential treat offgasback to 58R001B leadingto failure of regeneration.potential overpressurizationand equipment (58E014/58D002) damage.

1. RO-5806001.2. PSV-5806004/5806005/5806006.

A 3 1 2

5 Higher Pressure 5.1. PIC-5806006Amalfunctions closing PV-5806006A.

1. Potential pressurebuildup in 58D002 leadingto loss of fuel gas.

1. PSV-5806004/5806005/5806006.2. Back up natural gas.

A 3 1 2

Misdirected Flow4

2 More Flow(Heating)

2.1. Flow control loopfailure (FV-5805904)malfunctions fully openor fully mismanagedopen.

Sheet: 130 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-013-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-17

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

5 Higher Pressure 5.2. PIC-5806006Bmalfunctions closing PV-5806006B whenrequired.

1. Potential pressurebuildup in 58D002 leadingto loss of fuel gas.

1. PSV-5806004/5806005/5806006. A 3 1 2

1. Less regeneration gas todryer (58R001B).Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R001B).

1. FAL-5805904.

A 2 2 2

2. Loss of fuel gas to flaresystem leading to highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program. C 3 1 2

6.1. PIC-5806006Bmalfunctions openingPV-5806006B.

1. Loss of fuel gas to flaresystem leading to highflaring leading to potentialcommunity complain.

1. CCTV (flare stackmonitoring).2. CSR program. C 3 1 2

6.2. PDIC-5806004malfunctions closingPDV-5806004.

1. Lower pressure to fuelgas.Instability of fuel gasheader.No significantconsequence.

7.1. TIC-5805902malfunctions openingFV-5805904.

1. Higher temperature andmore flow of regen gas todryer (58R001A/B).Potential bed lift leading toloss of adsorbent.

1. TAH-5801301B.2. RO-5806001.

A 3 1 2

1. Increased temperatureof fuel gas leading to overdesign temperature of58D002 and pipingdownstream.Potential release of HC toATM leading to fire andexplosion.Potential personnel injury.

1. Operator training andprocedures.2. TAH-5806001.

A 3 1 2

58-17.01 To confirm Regen Gas KODrum (58D002) and pipingdownstream can handle at 240C.

EPC

2. Potential too moreexpansion 58E014 tubeside leading to potentialtube rupture.

1. PSV-5806003.

A 3 1 2

Higher Temperature7

7.2. Manual valve oncooling water inlet/outlet line from 58E014mismanaged closed.

5.3. PDIC-5806004malfunctions openingPDV-5806004.

6 Lower Pressure

Sheet: 131 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-013-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-17

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

8.1. TIC-5805902malfunctions openingFV-5805903.

1. Lower temperatureleading to not successregeneration (cooling step).Regeneration sequencestop.Delayed regeneration ofdryer (58R001B).

1. FAL-5805904.

A 3 1 2

8.2. Manual valve onsteam supply line to58E013 mismanagedclosed.

1. No supply of steam to58E013 leading to noheating of regen gas.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R001B).

1. Operator training andprocedures.2. TAL-5805902.

A 3 1 2

9.1. LIC-5805901malfunctions closing LV-5805901.

1. Decreased temperatureof regen gas.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R001B).

1. TAL-5805902.

A 3 1 2

9.2. LIC-5806001malfunctions closing LV-5806001.

1. Increased level in58D002 leading to potentialwater carryover to fuel gassystem.Potential damage toburner.

1. Demister.2. Fuel gas KO drum(59D001).

A 3 1 2

10.1. LIC-5805901malfunctions openingLV-5805901.

1. Loss of water level in58D004 leading to lowtemperature of regen gas.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R001B).

1. TAL-5805902.

A 3 1 2

10.2. LIC-5806001malfunctions openingLV-5806001.

1. Decreased level in58D002 leading to gasblowby to 53D103.Potential rupture 53D103leading to release offlammable and H2S gas.Potential personnel injury.

1. PSV-5305201/5305202.

P 4 1 2

58-17.02 To confirm PSV-5305201/5305202 is adequatefor gas blowby from Regen GasKO Drum (58D002).

EPC

11 Composition changed No cause identified.

12 More Contamination No cause identified.

Lower Level10

Lower Temperature8

Higher Level9

Sheet: 132 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

P/E/A/C

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-013-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-17

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

13 Relief 13.1. External fire. 1. Potentialoverpressurization of58E013 discharge leadingto downstreampiping/equipment damage.Release of steam to ATMleading to operator injury.

1. PSV-5805901.

P 4 1 2

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion 16.1. Corrosion underinsulation.

1. Potential pipeline leak.Release of HC to ATMleading to fire andexplosion.Potential personnel injury.

1. Material selection issuitable for not to makea corrosion.

P 4 1 2

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture 25.1. Tube pinhole leakat 58E013.

1. SSH steam leak intoregen gas.Failure of regeneration.

1. TAH-5805902.2. Secondary dryer(58R004A/B).

A 3 1 2

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 133 of 196

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Node Title: Reviewed Date: 27-May-13

Node Number: 58-18 Node Color Time: 9:00 - 18:00

58-017-1 (Rev. 0) 58-059-1 (Rev. 0) 58-060-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Regeneration Mode of Secondary Dryers

PATTERNED ORANGE

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To regenerate secondary dryer (58R004A/B) using residue gas from demethanizer section

Notes:

Operation andDesignConditions:

Secondary Dryer (58R004B):Operating(P/T): 32.6barg/40CDesign(P/T): 42barg/11&180C

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HAZOP WORKSHEET

Review Date: 2013-05-27

1.1. XV-5801706Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R004B).

1. Operator training andprocedures.

A 2 2 2

1.2. XV-5801708Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R004B).

1. Operator training andprocedures.

A 2 2 2

1.3. XV-5801703Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R004B).

1. Operator training andprocedures.

A 2 2 2

No/Less Flow(Heating)

1.4. Flow control loopfailure (FV-5805902)malfunctions closed ormismanaged closed.

1. No flow of regen gas todryer (58R004B) forheating.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R004B).

1. TAL-5805901.

A 2 2 2

No/Less Flow(Cooling)

1.5. Flow control loopfailure (FV-5805901)malfunctions closed ormismanaged closed.

1. No flow of regen gas todryer (58R004B) forcooling.Not success regenerationleading regenerationsequence stop.Delayed regeneration ofdryer (58R004B).

1. TAH-5805901.2. TAH-5801701B.

A 2 2 2

No/Less Flow(Depressurization)

1.6. XV-5801707Bmalfunctions closed ormismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R004B).

1. Operator training andprocedures.

A 2 2 2

No/Less Flow 1.7. Manual valve at thedryer vent linemismanaged closed.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R004B).

1. Operator training andprocedures.

A 2 2 2

1 No/Less Flow

Action Taken RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-017-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-18

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/E/A/C

Sheet: 135 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

Action Taken RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-017-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-18

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/E/A/C

1. More flow of regen gasto dryer (58R004A/B).Potential bed lift leading toloss of adsorbent.

1. TAH-5806001.2. RO-5806002.

A 3 1 2

2. Higher temperatureleading to short life time ofdesiccant.

1. TAH-5805901.

A 3 1 2

More Flow(Cooling)

2.2. Flow control loopfailure (FV-5805901)malfunctions fully openor mismanaged fullyopen.

1. More flow of regen gasto dryer (58R004A/B).Potential bed lift leading toloss of adsorbent.

2. RO-5806002.

A 3 1 2

3 Reverse Flow No cause identified.

4.1. XV-5801702Bmalfunction open ormismanaged open when58R004A in operation.

1. Treated offgas is sent to58E014 and 58D002leading to potentialoverpressurization andequipment damage.

1. RO-5806002.2. PSV-5806004/5806005/5806006.

A 3 1 2

4.2. XV-5801704Bmalfunction open ormismanaged open when58R004A in operation.

1. Potential treat offgasback to 58R004B leadingto failure of regeneration.potential overpressurizationand equipment (58E014/58D002) damage.

1. RO-5806002.2. PSV-5806004/5806005/5806006.

A 3 1 2

4.3. XV-5801705Bmalfunction open ormismanaged open when58R004A in operation.

1. Potential treat offgasback to 58R004B leadingto failure of regeneration.potential overpressurizationand equipment (58E014/58D002) damage.

1. RO-5806002.2. PSV-5806004/5806005/5806006.

A 3 1 2

4.4. XV-5801709Bmalfunction open ormismanaged open when58R004A in operation.

1. Not successregeneration leadingregeneration sequencestop.Delayed regeneration ofdryer (58R004B).

1. Operator training andprocedures.

A 2 2 2

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

2 More Flow(Heating)

2.1. Flow control loopfailure (FV-5805902)malfunctions fully openor fully mismanagedopen.

4 Misdirected Flow

Sheet: 136 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

Action Taken RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-017-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-18

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/E/A/C

7 Higher Temperature 7.1. TIC-5805901malfunctions openingFV-5805902.

1. Higher temperature andmore flow of regen gas todryer (58R004A/B).Potential bed lift leading toloss of adsorbent.

1. TAH-5801701B.2. RO-5806002.

A 3 1 2

8 Lower Temperature 8.1. TIC-5805901malfunctions openingFV-5805901.

1. Lower temperatureleading to not successregeneration (cooling step).Regeneration sequencestop.Delayed regeneration ofdryer (58R004B).

1. FAL-5805902.

A 3 1 2

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion 16.1. Corrosion underinsulation.

1. Potential pipeline leak.Release of HC to ATMleading to fire andexplosion.Potential personnel injury.

1. Material selection issuitable for not to makea corrosion.

P 4 1 2

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

Sheet: 137 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-27

Action Taken RemarkActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Unit: Ethylene Recovery Unit (58)

Node Title: Regeneration Mode of Treated Offgas Dryers 58-017-1 (Rev. 0), 58-059-1 (Rev. 0), 58-060-1 (Rev. 0)Node: 58-18

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/E/A/C

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 138 of 196

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Node Title: Reviewed Date:

Node Number: 58-19 Node Color Time: 9:00 - 18:00

58-061-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Methanol Injection System

PATTERNED YELLOW-GREEN

Number of Recommended Actions in this node:

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent:

Notes:This node is excluded from HAZOP due to inadequate vendor information provided.

Operation andDesignConditions:

Methanol Injection Unit (58X001):Operating(P/T): 31barg/23CDesign: 232kg/hr

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Node Title: Reviewed Date:

Node Number: 58-20 Node Color Time: 9:00 - 18:00

58-526-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Anti-Fouling Injection System

PATTERNED GREEN-ORANGE

Number of Recommended Actions in this node:

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent:

Notes:This node is excluded from HAZOP due to inadequate vendor information provided.

Operation andDesignConditions:

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Node Title: Reviewed Date:

Node Number: 58-21 Node Color Time: 9:00 - 18:00

58-527-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Anti-Foam Injection System

PATTERNED ORANGE-PINK

Number of Recommended Actions in this node:

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent:

Notes:This node is excluded from HAZOP due to inadequate vendor information provided.

Operation andDesignConditions:

Anti-Foam Injection Unit (58X003):Operating(P/T): 19.2barg/42CDesign: 0.43kg/hr

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Node Title: Reviewed Date: 28-May-13

Node Number: 58-22 Node Color Time: 9:00 - 18:00

78-003-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

ERU Oily Water Sump System

PATTERNED BROWN

Number of Recommended Actions in this node: 3

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To receive oily water from ERU unit, PRU unit and Prime G+ Unit and pump out to WWT system

Notes:To develop interlock numbering and specify in the drawing as per specification

Operation andDesignConditions:

ERU Oily Water Sump (78T011):Operating(P/T): 0.03barg/42CDesign(P/T): ATM/70C

ERU Oily Water Pumps (78P009A/B):Operating(P/T): 0.03barg/42CDesign: 26.4m3/hr

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HAZOP WORKSHEET

Review Date: 2013-05-28

1.1. MOV-7800301malfunctions closed ormismanaged closed.

1. Oily water divert to78T002/API separatorleading to overload APIseparator capacity leadingto potential release of highoil in storm water to publicreservoir.

1. None.

E 3 1 2

58-22.01 Review and check with SKE&C on the impact of sendingHC to API separator (78T002)to assess further safeguardsneeded.

EPC

1.2. ERU Oily WaterPump (78P009A) trips.

1. Overfilling in sump(78T011).2. Unable to drain oilywater from process.Potential oil spill to ATM.Environmental impact.

1. Spare pump(78P009B).2. LAH-7800301 willclose MOV-7800301.API separator.

E 3 1 2

1.3. Pump dischargeblock valve mismanagedclosed.

1. Potential pump(78P009A) and pipingdamage due to deadhead.

1. Operator training andprocedures.2. Piping is rated to150# higher than pumpshutoff pressure.

A 3 1 2

1.4. Inlet/ outlet manualvalves at Canister(78F011A) mismanagedclosed.

1. Potential VOCaccumulate in 78T011leading to potential VOCleaks into ATM leading toenvironmental impact.

1. Operator training andprocedures.2. Gas detector.

E 3 1 2

1.5 ERU Oily WaterPump (78P009A)suction screen plugging.

1.Potential loss of suctionleading to damage to78P009AB.

1. Pump fault alarm.2. Standby pump isprovided. A 3 1 2

2.1. Both pumps(78P009A/B) running.

1. Increased level incommon oily water basin(78T001).No significant consequence(78T001 capacity is1500m3).

1. Decreased level in sump(78T011) leading topotential pump(78P009A/B) loss suctionand damage.

LAL-7800301.LALL-7800301 will trip78P009A/B.

A 2 1 1

2.2. MOV-7800301malfunctions openlonger than 15minsduring raining.

1. Potential overfilling insump (78T011).Potential release of oilywater.Environmental impact.

1. LAH-7800201.2. LAH-7800701 willstop the pumps(78P008A/B).3. Overflow line connectto API separator.

E 2 1 1

P/C/E/ACauses

No/Less Flow

Action Required /Recommendations

Action ByR

1

2 More Flow

S LConsequences Existing Safeguards

Unit: Ethylene Recovery Unit (58)

Node Title: ERU Oily Water Sump System 78-003-1 (Rev. 0)

Node: 58-22

Ref.No.

Deviation Action Taken RemarkActionStatus

ActionNo.

Sheet: 143 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-28

P/C/E/ACausesAction Required /

RecommendationsAction ByRS LConsequences Existing Safeguards

Unit: Ethylene Recovery Unit (58)

Node Title: ERU Oily Water Sump System 78-003-1 (Rev. 0)

Node: 58-22

Ref.No.

Deviation Action Taken RemarkActionStatus

ActionNo.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5.1. External fire. 1. Potential damage tosump (78T011).

1. Fire fighting system.A 4 1 2

5.2. Ignition source fromhot work activity.

1. Potential internal fireleading to damage to sump(78T011).

1. Hot work permit.2. Snuffing steam.

A 4 1 2

6 Lower Pressure No cause identified.

1. Higher temperatureinside 78T011 leading toHC vaporization andrelease of VOC to ATM.Environmental impact.

1. Operator training andprocedures.2. Canister is provided.

E 3 1 2

2. Higher temperature ofHC and steam leading todamage to polymer seal for78T011 cover plate.

None.

A 2 1 1

58-22.02 Review with SK E&C on theseal material for 78T011 coverplate shall be withstand fortemperature of 100C.

EPC

8 Lower Temperature No cause identified.

9 Higher Level No cause identified.

10 Lower Level No cause identified.

11 Composition changed 11.1. Misoperation ondraining HC to OWSinstead of HBD.

1. HC contamination toOWS header and sump.2. Potential environmentalimpact.

1. Oil skimming nozzleand pump.2. 24" MH to monitordepth of oilcompartment orconnect vacuum truck.3. 10" sample hatch forvisual inspection ofsump level and HC.

E 3 1 2

58-22.03 Consider provided spectacleblind at OWS connection.

EPC

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

5 Higher Pressure

7 Higher Temperature 7.1. SL line block valvemismanaged open.

Sheet: 144 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-28

P/C/E/ACausesAction Required /

RecommendationsAction ByRS LConsequences Existing Safeguards

Unit: Ethylene Recovery Unit (58)

Node Title: ERU Oily Water Sump System 78-003-1 (Rev. 0)

Node: 58-22

Ref.No.

Deviation Action Taken RemarkActionStatus

ActionNo.

18 Power Failure N/A

19 Steam Failure N/A

20 Cooling Water Failure N/A

21 Nitrogen Failure N/A

22 IA/PA Failure N/A

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 145 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-23 Node Color Time: 9:00 - 18:00

58-301-1 (Rev. 0) 58-311-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Steam Condensate System (SSH/CPS)

PATTERNED PINK

Number of Recommended Actions in this node: 2

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply super high pressure steam to 58E013 and return to condensate heater

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1.1. Manual valve onsuper high pressuresteam supply linemismanaged closed.

1. No supply of steam to58E013 leading to noheating of regen gas.Potential regenerationdryer failure.Potential product offspec.

1. Operator training andprocedures.2. Operating cycle ofone vessel for58R001A/B is 48 hr.3. Operating cycle ofone vessel for58R004A/B is 7 days.4. Sequence controlalarm.

A 2 1 1

1. No condensate out from58E013 leading to delayheating step of dryer.No heating of regen gas.Potential regenerationdryer failure.Potential product offspec.

1. Operator training andprocedures.2. Operating cycle ofone vessel for58R001A/B is 48 hr.3. Operating cycle ofone vessel for58R004A/B is 7 days.4. Sequence controlalarm.

A 2 1 1

2. Potential pressurebuildup in condensate pipeleading to potentialdamage to pipe.Potential release ofcondensate to ATM.Potential personnel injury.

1. Condensate pipe israted to H43 pipe specsame as steam pipeline.

P 3 1 2

3 More Flow No cause identified.

4 Reverse Flow No cause identified.

5 Misdirected Flow No cause identified.

6 Higher Pressure No cause identified.

7 Lower Pressure 7.1. Lower pressurefrom main header,

1. Longer heating step fordryer.No significantconsequence.

8 Higher Temperature No cause identified.

9 Lower Temperature 9.1. Lower temperaturefrom main header.

1. Longer heating step fordryer.No significantconsequence.

10 Higher Level N/A.

1

1.2. Manual valve onsuper high pressurecondensate return linemismanaged closed.

No/Less Flow

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SSH/CPS)

L

Node: 58-23

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S R

ActionNo.

Action Required /Recommendations

Action By Action Taken

58-301-1 (Rev. 0), 58-311-1 (Rev. 0)

RemarkActionStatus

Sheet: 147 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SSH/CPS)

L

Node: 58-23

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S R

ActionNo.

Action Required /Recommendations

Action By Action Taken

58-301-1 (Rev. 0), 58-311-1 (Rev. 0)

RemarkActionStatus

11 Lower Level N/A.

12 Composition changed No cause identified.

13 More Contamination No cause identified.

14 Relief No cause identified.

15 Sampling No cause identified.

16 Abnormal Operation No cause identified.

17 Corrosion/Erosion 17.1. Stagnant area atend of header piping.

1. Potential corrosion inpiping.Potential damage to piping.

None.

A 2 1 1

58-23.01 To minimize the pipe line fromequipment to protect pipingcorrosion.

EPC

18 Human Errors No cause identified.

19 Power Failure N/A.

20 Steam Failure No cause identified.

21 Cooling Water Failure N/A.

22 Nitrogen Failure N/A.

23 IA/PA Failure N/A.

24 Maintenance 24.1. No bleed valvebetween manual valves.

1. Not possible to swingspectacle blind with safe.Potential personnel injury.

None.

P 3 1 2

58-23.02 Provide bleed valve forbetween double block valves atthe steam condensate batterylimit.

EPC

25 Start-up/Shutdown No cause identified.

26 Leakage/Rupture No cause identified.

27 Static Electricity No cause identified.

28 Spare Equipment No cause identified.

29 Others No cause identified.

Sheet: 148 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-23 Node Color Time: 9:00 - 18:00

58-311-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Steam Condensate System (SM/CPM)

PATTERNED PINK

Number of Recommended Actions in this node: 2

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply medium pressure steam to 58E011 and return to condensate heater

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1.1. Manual valve onmedium pressure steamsupply line mismanagedclosed.

1. No supply of steam to58E011 leading todecreased temperature ofacetylene polisher(58R003).Potential ethylene productoffspec.

1. Operator training andprocedures.2. Daily monitoring (AI-5801501A).3. TAL-5801501.

A 2 1 1

1. No condensate out from58E011 leading todecreased temperature ofacetylene polisher(58R003).Potential ethylene productoffspec.

1. Operator training andprocedures.2. Daily monitoring (AI-5801501A).3. TAL-5801501.

A 2 1 1

2. Potential pressurebuildup in condensate pipeleading to potentialdamage to pipe.Potential release ofcondensate to ATM.Potential personnel injury.

1. Condensate pipe israted to H210 pipe specsame as steam pipeline.

P 3 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure 6.1. Lower pressurefrom main header.

1. Decreased temperatureof acetylene polisher(58R003).Potential ethylene productoffspec.

1. Daily monitoring (AI-5801501A).2. TAL-5801501.

A 2 1 1

7 Higher Temperature No cause identified.

8 Lower Temperature 8.1. Lower temperaturefrom main header.

1. Decreased temperatureof acetylene polisher(58R003).Potential ethylene productoffspec.

1. Daily monitoring (AI-5801501A).2. TIC-5801501 withlow alarm.

A 2 1 1

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

No/Less Flow1

1.2. Manual valve onmedium pressurecondensate return linemismanaged closed.

PossibleConsequences

Existing Safeguards P/C/E/A Action Taken RemarkDeviation CausesAction Required /

RecommendationsAction By

ActionStatus

S L RAction

No.

Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SM/CPM) 58-311-1 (Rev. 0)

Node: 58-23A

Ref.No.

Sheet: 150 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

PossibleConsequences

Existing Safeguards P/C/E/A Action Taken RemarkDeviation CausesAction Required /

RecommendationsAction By

ActionStatus

S L RAction

No.

Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SM/CPM) 58-311-1 (Rev. 0)

Node: 58-23A

Ref.No.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion 16.1. Stagnant area atend of header piping.

1. Potential corrosion inpiping.Potential damage to piping.

None.

A 2 1 1

58-23A.01

To minimize the pipe line fromequipment to protect pipingcorrosion.

EPC

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure No cause identified.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance 23.1. No bleed valvebetween isolationmanual valves.

1. Not possible to swingspectacle blind with safe.Potential personnel injury.

None.

P 3 1 2

58-23A.02

Consider providing bleed valvefor between double blockvalves at the steam batterylimit.

EPC

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 151 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-24 Node Color Time: 9:00 - 18:00

58-311-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Steam Condensate System (SL/CPL)

PATTERNED BLUE

Number of Recommended Actions in this node: 3

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply low pressure steam to 58E202/58E001/78T011 and utility station and return to condensate heater

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow 1. No supply of steam to58E202 leading todecreased temperature ofdeethanizer (58C201).Loss of profit.

1. Operator training andprocedures.2. TAL-5803204.

A 2 1 1

2. No supply of steam to59E001 (during natural gasbackup mode) leading todecreased temperature offuel gas to furnace.Potential condensation andcorrosionPotential lower temperaturein pipe leading to pipingrupture.Potential release of HC toATM leading to potentialfire and explosion.Potential personnel injury.

1. Operator training andprocedures.

P 4 1 2

58-24.01. Consider managing batterylimit valves to CSO.

EPC

3.No supply of steam to78T011.No significantconsequence.

1.2. Manual valve on lowpressure condensatereturn line mismanagedclosed.

1. No condensate out from58E202 leading todecreased temperature ofdeethanizer (58C201).Loss of profit.

1. Operator training andprocedures.2. TAL-5803204.

A 2 1 1

2. Potential pressurebuildup in condensate pipeleading to potentialdamage to pipe.Potential release ofcondensate to ATM.Potential personnel injury.

1. Condensate pipe israted to H110 pipe specsame as steam pipeline.

P 3 1 2

1.1. Manual valve on lowpressure steam supplyline mismanaged closed.

Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SL/CPL) 58-311-1 (Rev. 0)

Node: 58-24

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Sheet: 153 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SL/CPL) 58-311-1 (Rev. 0)

Node: 58-24

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

1 No/Less Flow 1.2. Manual valve on lowpressure condensatereturn line mismanagedclosed.

3. No condensate out from59E001 (during natural gasbackup mode) leading todecreased temperature offuel gas to furnace.Potential condensation andcorrosionPotential lower temperaturein pipe leading to pipingrupture.Potential release of HC toATM leading to potentialfire and explosion.Potential personnel injury.

1. Operator training andprocedures.

A 2 1 1

Refer to Action No. 58-24.01.

4. Potential pressurebuildup in condensate pipeleading to potentialdamage to pipe.Potential release ofcondensate to ATM.Potential personnel injury.

1. Condensate pipe israted to H110 pipe specsame as steam pipeline.

P 3 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

1. Decreased temperatureof deethanizer (58C201).Loss of profit.

1. Operator training andprocedures.2. TAL-5803204. A 2 1 1

2. (during natural gasbackup mode) Decreasedtemperature of fuel gasfrom 59E001 to furnace.Potential loss of heatefficiency.

1. Operator training andprocedures.2. TIC-5900105.

A 2 1 1

7 Higher Temperature No cause identified.

8 Lower Temperature 8.1. Lower temperaturefrom main header.

1. Decreased temperatureof deethanizer (58C201).Loss of profit.

1. Operator training andprocedures.2. TAL-5803204. A 2 1 1

6 Lower Pressure 6.1. Lower pressurefrom main header.

Sheet: 154 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SL/CPL) 58-311-1 (Rev. 0)

Node: 58-24

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

8 Lower Temperature 8.1. Lower temperaturefrom main header.

2. (during natural gasbackup mode) Decreasedtemperature of fuel gasfrom 59E001 to furnace.Potential loss of heatefficiency.

1. Operator training andprocedures.2. TIC-5900105.

A 2 1 1

3. Potential steamcondensation in pipingleading to potentialhammering.Potential damage to piping.

1. Steam trap providedalong steam header.

A 2 1 1

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion 16.1. Stagnant area atend of header piping.

1. Potential corrosion inpiping.Potential damage to piping.

None.

A 2 1 1

58-24.02 To minimize the pipe line fromequipment to protect pipingcorrosion.

EPC

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure No cause identified.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance 23.1. No bleed valvebetween isolationmanual valves.

1. Not possible to swingspectacle blind with safe.Potential personnel injury.

None.

P 3 1 2

58-24.03 Consider providing bleed valvefor between double blockvalves at the steam batterylimit.

EPC

24 Start-up/Shutdown No cause identified.

Sheet: 155 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25Unit: Ethylene Recovery Unit (58)

Node Title: Steam Condensate System (SL/CPL) 58-311-1 (Rev. 0)

Node: 58-24

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 156 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-25 Node Color Time: 9:00 - 18:00

58-321-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Water Distribution System

PATTERNED BLUE

Number of Recommended Actions in this node: 3

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent:To supply BFW to 58E001/58E202/59E001.To supply portable water to utilities.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1.1. Manual valve onBFW supply linemismanaged closed.

1. Loss of BFW watermake-up leading topotential increased causticconcentration in the washwater circulation.Reduced wash water towerefficiency leading tocarryover of causticdownstream.Potential condensation ofcaustic with C3 leading topotential corrosion ofequipment and pipingdownstream.

1. Operator training andprocedures.2. Daily monitoring (AI-5800401A/B).3. AAH-5801712A(CO2).

A 2 1 1

1.2. Manual valve onpotable water supplyline mismanaged closed.

1. No supply of potablewater to eye washer.Potential personnel injury.

1. Operator training andprocedures.

P 4 1 2

58-25.01. Provide battery limit valves toCSO.

EPC

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure 6.1. Lower pressurefrom main header.

1. Less supply of potablewater to eye washer.Potential personnel injury.

None.

P 4 1 2

58-25.02 To check low pressure alarmprovided on potable water mainheader in UHV and out ofheader.

EPCIRPC

7 Higher Temperature 7.1. Solar radiation. 1. Potential increasedtemperature of potablewater.Potential personnel injury.

None.

P 3 1 2

58-25.03 To provide insulation aboveground piping to ensurepotable water for eye washerand safety shower is lukewarm.

EPC

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination 12.1. Biological growthin pipe line.

1. Potential contaminationof potable water.Potential personnel injury.

1. Operator training andprocedures.

P 3 1 2

13 Relief No cause identified.

Action ByActionStatus

L Action TakenDeviationPossible

ConsequencesS

Unit: Ethylene Recovery Unit (58)

Node Title: Water Distribution System 58-321-1 (Rev. 0)

Node: 58-25

Ref.No.

Remark

No/Less Flow1

P/C/E/A RAction

No.Action Required /

RecommendationsExisting SafeguardsCauses

Sheet: 158 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

Action ByActionStatus

L Action TakenDeviationPossible

ConsequencesS

Unit: Ethylene Recovery Unit (58)

Node Title: Water Distribution System 58-321-1 (Rev. 0)

Node: 58-25

Ref.No.

Remark P/C/E/A RAction

No.Action Required /

RecommendationsExisting SafeguardsCauses

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 159 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-26 Node Color Time: 9:00 - 18:00

58-331-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Cooling Water Distribution System

PATTERNED LIGHT BLUE

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply cooling water to users and return to cooling water tower.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1. No cooling water supplyto ERU leading to potentialoverpressurization in ERU.Potential ERU shutdown.

1. Operator training andprocedures.2. PSVs on eachequipment.

A 4 1 2

2. Potential communitycomplain due to big flaring.

1. CCTV.2. CSR program. C 3 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow 4.1. 8" bypass valveopen in advertently.

1. Less cooling watersupply to users leading toless efficiency.Potential product offspec.Less profit.

1. Operator training andprocedures.

A 3 1 2

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature 7.1. High temperature ofcooling water supplyduring summer season.

1. Less efficiency.Potential product offspec.Less profit.

1. Cooling water toweris designed for ambienttemperature (42 C).

A 3 1 2

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

No/Less Flow1 1.1. Manual valve oncooling water supply/return line mismanagedclosed.

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Cooling Water Distribution System

L

Node: 58-26

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S R

ActionNo.

Action Required /Recommendations

Action By Action Taken

58-331-1 (Rev. 0)

RemarkActionStatus

Sheet: 161 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Cooling Water Distribution System

L

Node: 58-26

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S R

ActionNo.

Action Required /Recommendations

Action By Action Taken

58-331-1 (Rev. 0)

RemarkActionStatus

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 162 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-27 Node Color Time: 9:00 - 18:00

58-341-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Fuel Gas Distribution System

PATTERNED LIGHT RED

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply fuel gas for purging CFA and HFA headers.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date:

1 No/Less Flow 1.1. Manual valve onfuel gas supply linemismanaged closed.

1. No supply of purge gasleading to air ingress.Potential fire and explosion.Potential personnel injury.

1. Operator training andprocedures.2. N2 back up system.3. Other units purgesystem.4. Operatorsurveillance.

P 4 1 2

2 More Flow No cause indentified.

3 Reverse Flow No cause indentified.

4 Misdirected Flow No cause indentified.

5 Higher Pressure No cause indentified.

6 Lower Pressure No cause indentified.

7 Higher Temperature No cause indentified.

8 Lower Temperature No cause indentified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause indentified.

12 More Contamination No cause indentified.

13 Relief No cause indentified.

14 Sampling No cause indentified.

15 Abnormal Operation No cause indentified.

16 Corrosion/Erosion No cause indentified.

17 Human Errors No cause indentified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause indentified.

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Fuel Gas Distribution System 58-341-1 (Rev. 0)

Node: 58-27

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 164 of 196

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HAZOP WORKSHEET

Review Date:

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Fuel Gas Distribution System 58-341-1 (Rev. 0)

Node: 58-27

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

24 Start-up/Shutdown No cause indentified.

25 Leakage/Rupture No cause indentified.

26 Static Electricity No cause indentified.

27 Spare Equipment No cause indentified.

28 Others No cause indentified.

Sheet: 165 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-27A Node Color Time: 9:00 - 18:00

58-341-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Natural Gas Distribution System

PATTERNED LIGHT RED

Number of Recommended Actions in this node: 1

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply natural gas to 58K401 and 58K501.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow 1.1. Manual valve onnatural gas supply linemismanaged closed.

1. No supply of natural gasleading to potential delaystartup of 58K401/58K501.

1. Operator training andprocedures.

A 3 1 2

58-27A.01

To confirm additionalsafeguards for this scenarioduring vendor packageHAZOP.

EPC

2 More Flow No cause indentified.

3 Reverse Flow No cause indentified.

4 Misdirected Flow No cause indentified.

5 Higher Pressure No cause indentified.

6 Lower Pressure No cause indentified.

7 Higher Temperature No cause indentified.

8 Lower Temperature No cause indentified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause indentified.

12 More Contamination No cause indentified.

13 Relief No cause indentified.

14 Sampling No cause indentified.

15 Abnormal Operation No cause indentified.

16 Corrosion/Erosion No cause indentified.

17 Human Errors No cause indentified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause indentified.

24 Start-up/Shutdown No cause indentified.

25 Leakage/Rupture No cause indentified.

Unit: Ethylene Recovery Unit (58)

Node Title: Natural Gas Distribution System 58-341-1 (Rev. 0)

Node: 58-27A

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Sheet: 167 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25Unit: Ethylene Recovery Unit (58)

Node Title: Natural Gas Distribution System 58-341-1 (Rev. 0)

Node: 58-27A

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

26 Static Electricity No cause indentified.

27 Spare Equipment No cause indentified.

28 Others No cause indentified.

Sheet: 168 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-28 Node Color Time: 9:00 - 18:00

58-351-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Instrument Air (AII) Distribution System

PATTERNED ORANGE

Number of Recommended Actions in this node: 1

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply IA to 58K401 and 58K501.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow 1.1. Manual valve on AIIsupply line mismanagedclosed.

1. No supply of AII todepressurization valveleading to potential highflaring.Community complain.Unit shutdown.

1. Operator training andprocedures.2. Air reservoir fordepressurization valve.3. CCTV.4. CSR Program.

C 3 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure 6.1. Upstream userconsume higher AII.

1. Potential low pressureleading to potential unitshutdown.Loss of profit.

1. AII header is sized tocover maximumconsumption atminimum AII supplypressure.

A 3 1 2

58-28.01 To check low pressure alarmprovided on AII main header inUHV and out of unit.

EPCIRPC

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Instrument Air Distribution System 58-351-1 (Rev. 0)

Node: 58-28

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 170 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Instrument Air Distribution System 58-351-1 (Rev. 0)

Node: 58-28

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others N/A.

Sheet: 171 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-28A Node Color Time: 9:00 - 18:00

58-361-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Plant Air (AIP) Distribution System

PATTERNED ORANGE

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply PA to utility station.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow 1.1. Manual valve onAIP supply linemismanaged closed.

1. No supply of AIP toutility station.No significantconsequence.

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

Unit: Ethylene Recovery Unit (58)

Node Title: Plant Air Distribution System 58-361-1 (Rev. 0)

Node: 58-28A

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Sheet: 173 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25Unit: Ethylene Recovery Unit (58)

Node Title: Plant Air Distribution System 58-361-1 (Rev. 0)

Node: 58-28A

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 174 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-29 Node Color Time: 9:00 - 18:00

58-371-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Nitrogen Distribution System

PATTERNED PURPLE

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To supply of nitrogen to users.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1. Potential air ingress intothe demethanizer (58C101)leading to potential iceformation.Potential corrosion (longterm).

1. Operator training andprocedures.

A 2 1 1

2. Loss of N2 blanketingleading to potential causticday tank (58T001)collapse.Potential release of freshcaustic (7%) tosurroundings.Potential operator exposureleading to operator injury.

1. Dike.2. PVSV-5800301.3. PPE.

P 4 1 2

Refer to Action No.58-02.02

3. No secondary seal gasof 58K401/58K501.

None. Refer to Action No.58-27A.01

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

No/Less Flow1 1.1. Manual valve onnitrogen supply linemismanaged closed.

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Nitrogen Distribution System

L

Node: 58-29

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S R

ActionNo.

Action Required /Recommendations

Action By Action Taken

58-371-1 (Rev. 0)

RemarkActionStatus

Sheet: 176 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Nitrogen Distribution System

L

Node: 58-29

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S R

ActionNo.

Action Required /Recommendations

Action By Action Taken

58-371-1 (Rev. 0)

RemarkActionStatus

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 177 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-30 Node Color Time: 9:00 - 18:00

58-701-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Flare Distribution System (HFA)

PATTERNED LIGHT PURPLE

Number of Recommended Actions in this node: 1

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To collect and send HFA gas to flare stack.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow 1.1. Manual valve onpurge gas linemismanaged closed.

1. No supply of purge gasleading to air ingress.Potential fire and explosion.Potential personnel injury.

1. Operator training andprocedures.2. N2 back up system.3. Other units purgesystem.4. Operatorsurveillance.

P 4 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief N/A.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Flare Distribution System (HFA) 58-701-1 (Rev. 0)

Node: 58-30

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 179 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Flare Distribution System (HFA) 58-701-1 (Rev. 0)

Node: 58-30

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

23 Maintenance 23.1. No spareconnection for future tie-in.

1. Difficulty for isolationand modification work.Not possible to tie-in duringunit operation.

None.

A 3 1 2

58-30.01 Consider providing block valveand blind flange for spareconnection.

EPC

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 180 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-31 Node Color Time: 9:00 - 18:00

58-711-1 (Rev. 0) 58-712-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Flare Distribution System (CFA/CBD)

PATTERNED YELLOW

Number of Recommended Actions in this node: 2

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To collect cold vent vapor and cold blow down drain to cold flare stack.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow 1.1. Manual valve onpurge gas linemismanaged closed.

1. No supply of purge gasleading to air ingress.Potential fire and explosion.Potential personnel injury.

1. Operator training andprocedures.2. N2 back up system.3. Other units purgesystem.4. Operatorsurveillance.

P 4 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief N/A.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Flare Distribution System (CFA/CBD) 58-711-1 (Rev. 0), 58-712-1 (Rev. 0)

Node: 58-31

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 182 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Flare Distribution System (CFA/CBD) 58-711-1 (Rev. 0), 58-712-1 (Rev. 0)

Node: 58-31

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

23 Maintenance No spare connection forfuture tie-in.

Difficulty for isolation andmodification work.Not possible to tie-in duringunit operation.

None.

A 3 1 2

58-31.01 Consider relocating 6" blockvalve and blind flange fromCBD header to CFA for spareconnection.

EPC

Maintenance Lower temperaturecontact.

Potential personnel injury. None.

P 3 2 2

58-31.02 To provide personnel protectionat accessible cold blowdownsystem.

EPC

25 Start-up/Shutdown No cause identified.

26 Leakage/Rupture No cause identified.

27 Static Electricity No cause identified.

28 Spare Equipment No cause identified.

29 Others No cause identified.

Sheet: 183 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-32 Node Color Time: 9:00 - 18:00

58-831-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Closed Drain Distribution System (SHBD)

PATTERNED ORANGE

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To collect SHBD and send to caustic blowdown.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow No cause identified.

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Closed Drain Distribution System (SHBD) 58-831-1 (Rev. 0)

Node: 58-32

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 185 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25

P/C/E/A

Unit: Ethylene Recovery Unit (58)

Node Title: Closed Drain Distribution System (SHBD) 58-831-1 (Rev. 0)

Node: 58-32

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards S Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 186 of 196

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Node Title: Reviewed Date: 25-May-13

Node Number: 58-32 Node Color Time: 9:00 - 18:00

58-841-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Closed Drain Distribution System (HBD)

PATTERNED ORANGE

Number of Recommended Actions in this node: 0

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent: To collect HBD and send to hot blowdown.

Notes:1) No equipment in this node.

Operation andDesignConditions:

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HAZOP WORKSHEET

Review Date: 2013-05-25

1 No/Less Flow Manual valve on batterylimit mismanagedclosed.

1.1. Not possible to drainfrom equipment.Not possible to emptyequipment andmaintenance.Potential startup/shutdowndelay.

1. Operator training andprocedures.

A 3 1 2

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

5 Higher Pressure No cause identified.

6 Lower Pressure No cause identified.

7 Higher Temperature No cause identified.

8 Lower Temperature No cause identified.

9 Higher Level N/A.

10 Lower Level N/A.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure N/A.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

22 IA/PA Failure N/A.

23 Maintenance No cause identified.

Unit: Ethylene Recovery Unit (58)

Node Title: Closed Drain Distribution System (HBD) 58-841-1 (Rev. 0)

Node: 58-32A

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

Sheet: 188 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-25Unit: Ethylene Recovery Unit (58)

Node Title: Closed Drain Distribution System (HBD) 58-841-1 (Rev. 0)

Node: 58-32A

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards P/C/E/A Action Taken Remark

ActionStatus

S L RAction

No.Action Required /

RecommendationsAction By

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture No cause identified.

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 189 of 196

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Node Title: Reviewed Date: 29-May-13

Node Number: 59-01 Node Color Time: 9:00 - 18:00

59-001-1 (Rev. 0)

HAZOP STUDY WORKSHEET

Project Title: UHV Project

Fuel Gas Mixing System

YELLOW

Number of Recommended Actions in this node: 8

Number of Recommended Actions completed in this node:

Drawing No.

Design Intent:To mix fuel gas from header and send it userTo import natural gas as back-up for UHV project

Notes:

Operation andDesignConditions:

Fuel Gas Mixing Drum (58D001):Operating(P/T): 5.5barg/42CDesign(P/T): FV@100&8C/11&80C

Desuperheater for 59E001 (58Z001):Operating(P/T):Design(P/T): 85barg/11&150C

Natural Gas Heater (58E001):Operating(P/T): 50barg/40&60.2C (Shell);4.5barg/155.6C (Tube)Design(P/T): FV@100&69.3C/11&185C(Shell); 90barg/11&76C (Tube)

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HAZOP WORKSHEET

Review Date: 2013-05-29

1 No/Less Flow 1. No flow of fuel gas fromheader to 59D001 leadingto loss fuel gas flow tousers.Potential unit shutdown.Loss of profit.

1. Operator training andprocedures.2. Backup natural gas.3. PIC-5900101A. A 4 1 2

2. Potentialoverpressurization in fuelgas header from unit 52/53.

1. Overpressureprotection on fuel gasheader. P 4 1 2

59-01.01 To confirm overpressureprotection at unit 52/53 isprovided.

EPC

1. No flow of fuel gas fromheader to 59D001 leadingto loss fuel gas flow tousers.Potential unit shutdown.Loss of profit.

1. Operator training andprocedures.2. Backup natural gasand treated offgas fromunit 53.3. PIC-5900101A.

A 4 1 2

2. Potentialoverpressurization in ERU.Potential release of fuelgas to ATM leading to fireand explosion.Potential personnel injury.

1. PIC-5806006B withhigh alarm.2. PSV-5806007/5806008. P 4 1 2

1.3. XV-5900101 orbattery limit valvemalfunctions closed ormismanaged closedwhen required.

1. No backup of naturalgas leading to less flow offuel gas to uses leading toreduced productioncapacity of UHV project.Loss of profit.

1. PAL-5900101A.

A 4 1 2

59-01.02 Consider adding componentpoint alarm for XV-5900101 toindicate abnormal position ofthe valve.

EPC

P 4 1 259-01.03 Consider low temperature

alarm on TIC-5900105.EPC

A 4 1 2

59-01.04 To confirm the minimumtemperature of natural gas afterpressure letdown.

EPC

1.5. Manual valve onfuel gas supply line touser mismanagedclosed.

1. No flow of fuel gas tousers leading to potentialunit shutdown.Loss of profit.

1. Operator training andprocedures.2. PIC-5900101B withhigh alarm.

A 4 1 2

None.

1.1. Manual valve onfuel gas headermismanaged closedwhen ERU shutdown.

1.2. Manual valve fromERU mismanagedclosed.

1.4. Manual valve onsteam line mismanagedclosed when natural gasbackup mode.

1. No flow of steam to59E001 leading to noheating of natural gas.Lower temperature ofnatural gas than MDMT of59E001 and piping.Potential damage to piping.

Unit: Fuel Gas Supply Unit (59)

Node Title: Fuel Gas Mixing System 59-001-1 (Rev. 0)

Node: 59-1

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/C/E/A Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

Sheet: 191 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-29Unit: Fuel Gas Supply Unit (59)

Node Title: Fuel Gas Mixing System 59-001-1 (Rev. 0)

Node: 59-1

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/C/E/A Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

1 No/Less Flow 1.5. Manual valve onfuel gas supply line touser mismanagedclosed.

2. Potentialoverpressurization in Unit59.Potential release of fuelgas to ATM leading to fireand explosion.Potential personnel injury.

1. PIC-5900101B withhigh alarm.2. PSV-5900101/5900102.

P 4 1 2

1.6. Manual valve onnatural gas supply lineto HMU and SRUmismanaged closedwhen required.

1. No supply of natural gasto HMU and SRU leadingto potential delayedstartup.

1. Operator training andprocedures.

A 3 1 2

59-01.05 To confirm existing safeguardin HMU and SRU.

EPC

1.7. Strainer (STR-5902)plugging.

1. Less flow of BFW to59E001 leading highertemperature of natural gas.No significantconsequence.

1.8. Steam trap valvemismanaged closed.

1. Potential wateraccumulation in 59E001over times.Less heat exchangeleading to lowertemperature of natural gas.

1. Operator training andprocedures.

A 3 1 2

Refer to Action No. 59-01.03.

1.9. Steam trap stuckclosed.

1. Potential wateraccumulation in 59E001over times.Less heat exchangeleading to lowertemperature of natural gas.

1. Operator training andprocedures.

A 3 1 2

59-01.07 To ensure proper type of steamtrap downstream of 59E001.

EPC

1.10. Manual valveinlet/outlet 59D001mismanaged closed.

1. No flow of fuel gas fromheader to 59D001 leadingto loss fuel gas flow tousers.Potential unit shutdown.Loss of profit.

1. Operator training andprocedures.

A 4 1 2

59-01.08 Consider providing CSO formanual valves inlet/outlet59D001.

EPC

2 More Flow No cause identified.

3 Reverse Flow No cause identified.

4 Misdirected Flow No cause identified.

Sheet: 192 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-29Unit: Fuel Gas Supply Unit (59)

Node Title: Fuel Gas Mixing System 59-001-1 (Rev. 0)

Node: 59-1

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/C/E/A Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

5.1. PIC-5900105malfunctions openingPV-5900105.

1. Potentialoverpressurization in pipingdownstream and damage.potential release of naturalgas to ATM leading to fireand explosionPotential personnel injury.

1. PSV-5900103/5900104.

P 4 1 2

5.2. PIC-5900101Amalfunctions openingPV-5900101A.

1. More flow of natural gasto 59D001 leading tooverpressurization in59D001 and pipingdownstream and damage.Potential release of fuelgas to ATM leading to fireand explosionPotential personnel injury.

1. PSV-5900101/5900102.

P 4 1 2

5.3. PIC-5900101Bmalfunctions closing PV-5900101B.

1. Overpressurization in59D001 and damage.Potential release of fuelgas to ATM leading to fireand explosionPotential personnel injury.

1. PSV-5900101/5900102.

P 4 1 2

5.4. PIC-5900104Amalfunctions notopening PV-5900104A.

1. No export of fuel gasleading tooverpressurization in59D001 and damage.Potential release of fuelgas to ATM leading to fireand explosionPotential personnel injury.

1. PIC-5900101B withhigh alarm.2. PSV-5900101/5900102.

P 4 1 2

5.5. PIC-5900104Bmalfunctions notopening PV-5900104B.

1. No export of fuel gasleading tooverpressurization in59D001 and damage.Potential release of fuelgas to ATM leading to fireand explosionPotential personnel injury.

1. PIC-5900101B withhigh alarm.2. PSV-5900101/5900102.

P 4 1 2

5 Higher Pressure

Sheet: 193 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-29Unit: Fuel Gas Supply Unit (59)

Node Title: Fuel Gas Mixing System 59-001-1 (Rev. 0)

Node: 59-1

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/C/E/A Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

6.1. PIC-5900105malfunctions closing PV-5900105.

1. No natural gas backupleading to loss of DCCcompressor seal gas.Potential damage tocompressor leading torelease HCs to ATM.Potential fire and explosionleading to personnel injury.

1. Compressorsafeguard system toavoid damage.

P 4 1 2

6.2. PIC-5900101Amalfunctions notopening PV-5900101Awhen required.

1. No backup of naturalgas leading to less flow offuel gas to uses leading toreduced productioncapacity of UHV project.Loss of profit.

None.

A 4 1 2

59-01.06 Consider low pressure alarmon PIC-5900104.

EPC

6.3. PIC-5900101Bmalfunctions openingPV-5900101B.

1. Less pressure in59D001 leading to loss offuel gas to flare.Big flaring leading tocommunity complain.

1. CCTV.2. CSR Program.

C 3 1 2

6.4. PIC-5900104Amalfunctions fullyopening PV-5900104A.

1. Less pressure in59D001 leading to less flowof fuel gas to uses leadingto reduced productioncapacity of UHV project.Loss of profit.

1. PIC-5900101A withlow alarm.

A 4 1 2

6.5. PIC-5900104Bmalfunctions fullyopening PV-5900104B.

1. Less pressure in59D001 leading to less flowof fuel gas to uses leadingto reduced productioncapacity of UHV project.Loss of profit.

1. PIC-5900101A withlow alarm.

A 4 1 2

7.1. TIC-5900105malfunctions openingTV-5900105.

1. More flow of steam to59E001 leading to highertemperature (max. up to 70C).No significantconsequence.

7.2. TIC-5900104malfunctions closing TV-5900104.

1. No flow of BFW to59E001 leading highertemperature of natural gas.No significantconsequence.

7 Higher Temperature

Lower Pressure6

Sheet: 194 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-29Unit: Fuel Gas Supply Unit (59)

Node Title: Fuel Gas Mixing System 59-001-1 (Rev. 0)

Node: 59-1

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/C/E/A Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

8.1. TIC-5900105malfunctions closing TV-5900105.

1. No flow of steam to59E001 leading to noheating of natural gas.Lower temperature ofnatural gas than MDMT of59E001 and piping.Potential damage to piping,

None.

P 4 1 2

Refer to Action No. 59-01.04

8.2. TIC-5900104malfunctions openingTV-5900104.

1. More flow of BFW to59E001 leading to lowersteam temperature.Possible free waterentering to 59E001.Less heat exchangeleading to potentialhammering in steam lineand damage to tube of59E001.

1. Steam trap isprovided.

A 3 1 2

Refer to Action No. 59-01.03

9 Higher Level 9.1. Liquid carryover. 1. Potential liquid carryoverto burner and damage.Potential fire outside thefurnace leading topersonnel injury.

1. LAH-5900101.2. Operator training andprocedures.

P 4 1 2

10 Lower Level No cause identified.

11 Composition changed No cause identified.

12 More Contamination No cause identified.

13 Relief No cause identified.

14 Sampling No cause identified.

15 Abnormal Operation No cause identified.

16 Corrosion/Erosion No cause identified.

17 Human Errors No cause identified.

18 Power Failure N/A.

19 Steam Failure No additional causeidentified.

20 Cooling Water Failure N/A.

21 Nitrogen Failure N/A.

Lower Temperature8

Sheet: 195 of 196

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HAZOP WORKSHEET

Review Date: 2013-05-29Unit: Fuel Gas Supply Unit (59)

Node Title: Fuel Gas Mixing System 59-001-1 (Rev. 0)

Node: 59-1

Ref.No.

Deviation CausesPossible

ConsequencesExisting Safeguards SP/C/E/A Remark

ActionStatus

L RAction

No.Action Required /

RecommendationsAction By Action Taken

22 IA/PA Failure No cause identified.

23 Maintenance No cause identified.

24 Start-up/Shutdown No cause identified.

25 Leakage/Rupture 25.1. Pinhole leak at59E001.

1. Natural gas leaks intocondensate system.Potential release of HCs toATM leading to VOC.Environmental impact.

1. PPE.

E 2 1 1

26 Static Electricity No cause identified.

27 Spare Equipment No cause identified.

28 Others No cause identified.

Sheet: 196 of 196

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Appendix 3 : Scaned Attendance List

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J

E & C

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NODE 04
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NODE 02
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NODE 01
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J

E & C

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NODE 03
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NODE 01
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J

E & C

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NODE 02
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NODE 02
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J

E & C

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NODE 03
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NODE 03
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NODE 01
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J

E & C

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เอกสารแนบที่ 1 �䍟十E�� 3

ฐานข�อม8ลส9ขภาพิจารณของพิจารณน กงาน

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เอกสารแนบที่ 1 �䍟十E�� 4

การที่ 1 �䍟十Eบที่ 1 �䍟十Eวิเคราะห์ผลกระทบสิ่นเห์ผลกระทบสิ่งแวดล้อมหนังสตัวอย่างกรณีที่เกิดผลกระทบสูงสุดพร้อม9การณ�อ9บ ตัวอย่างกรณีที่เกิดผลกระทบสูงสุดพร้อม�ภ ย/อ9บ ตัวอย่างกรณีที่เกิดผลกระทบสูงสุดพร้อม�เห์ผลกระทบสิ่งแวดล้อมหนังสตัวอย่างกรณีที่เกิดผลกระทบสูงสุดพร้อม9ที่ 1 �䍟十E��เก�ดจากการประกอบก�จการอ9ตัวอย่างกรณีที่เกิดผลกระทบสูงสุดพร้อมสาห์ผลกระทบสิ่งแวดล้อมหนังสกรรมที่ 1 �䍟十E��ม�การผล�ตัวอย่างกรณีที่เกิดผลกระทบสูงสุดพร้อมล กษณะเด�ยวิเคราะห์ผลกระทบสิ่ก นที่ 1 �䍟十E Aงในประเที่ 1 �䍟十Eศึกษา และ

ตัวอย่างกรณีที่เกิดผลกระทบสูงสุดพร้อม7างประเที่ 1 �䍟十Eศึกษา

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เหตกุารณ์ : รถกระเช้าชนพนักงาน Flag man ได้รบับาดเจบ็ สรปุรายละเอียดของเหตุการณ์ : พนกังานผูร้บัเหมา เขา้ประกอบตดิตัง้ท่อ WF และตดิตัง้หวั Sprinkler ในอาคารคลงัเกบ็สนิคา้ หลงัจากงานแลว้เสรจ็ จะน ารถกระเชา้ออกไปนอกโรงงานเพื่อขึน้รถเทรลเลอรส์่งคนื โดยม ีFlag man ป ัน่จกัรยานน าหน้า เมือ่มาถงึบรเิวณทีเ่กดิเหตุ มรีถกระบะของผูร้บัเหมาอกีบรษิทั ถอยออกมากะทนัหนั Flag man จงึให้สญัญาณรถกระเชา้เพื่อหยดุ จากนัน้ Flag man จงึขยบัรถออกทางซา้ย(หลบรถกระบะทีก่ าลงัถอย) จงึท าให้คนขบัรถกระเชา้ มองไมเ่หน็ Flag man เมือ่รถกระบะขบัเดนิหน้าออก พนกังานขบัรถกระเชา้คดิว่า Flag man ป ัน่รถจกัรยานไปแลว้ (มองไมเ่หน็) จงึเลื่อนรถกระเชา้ออกไปเพื่อเดนิทางต่อ ท าใหช้นรถ Flag man ลม้ลงและไดร้บับาดเจบ็เลก็น้อยบรเิวณขอ้เทา้ซา้ยจากนัน้ เจา้หน้าที ่รปภ. ทีพ่บเหน็เหตุการณ์ ไดป้ระสานงานเรยีกรถพยาบาลน าส่งโรงพยาบาลระยอง ซึง่โรงพยาบาลฯ ไดต้รวจอาการและใหก้ลบับา้นได ้ซึง่วนัถดัมาไดก้ลบัเขา้ท างานตามปกติ

การวิเคราะหส์าเหต ุ: • สาเหตขุณะนัน้ : - พนักงานขบัรถกระเช้ามองไม่เหน็ Flag man - ขาดการส่ือสารและการให้สญัญาณ ระหว่าง Flag man กบั พนักงานขบัรถกระเช้าในขณะท่ีรถก าลงัเคลื่อนท่ีออก • สาเหตพืุ้นฐาน : - Human error การละเมิดกฏด้านความปลอดภยั การส่ือสารและการให้สญัญาณ

01/2018

ภาพจ าลองลกัษณะรถกระเช้า และการควบคมุรถขณะเกิดเหต ุ

Lay out พื้นท่ีเกิดเหต ุ

หมายเหต:ุ รถกระเช้าในภาพใช้จ าลองอบุติัเหตเุท่านัน้ ไม่เก่ียวข้องกบัอบุติัเหตท่ีุเกิดขึน้และมีขนาดเลก็ แต่รถท่ีเกิดเหตจุะใหญ่และมีความสงูมากกว่า

ข้อเสนอแนะ : 1. ช้ีแจงกฎระเบียบซ า้(Retrain) ก าชบัข้อปฏิบติั ดงัน้ี 1.1วิธีการให้สญัญาณระหว่าง Flag man กบั พนักงานขบัรถและผูเ้ก่ียวข้องอย่างถกูต้องและให้ปฏิบติัอยา่งเครง่ครดั 1.2 เน้นเรือ่งระยะห่างในการน ารถของ Flag man กบั รถกระเช้า ให้ชดัเจน คือ 10 – 15 เมตร ตามกฎระเบียบของทาง IRPC 2.ก าหนดให้รถเทเลอรเ์ข้ามา รบั – ส่ง รถกระเช้าท่ีหน้างานเท่านัน้ 3. Safety จดัท าส่ือ ประชาสมัพนัธ ์ Lesson Learned เพื่อการป้องกนั มิให้เกิดอบุติัเหตซุ า้

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เหตกุารณ์ : พนักงานถกูเคร่ืองจกัรบาดเฉือนน้ิวมือได้รบับาดเจบ็ สรปุรายละเอียดของเหตุการณ์ : ขณะพนกังานควบคุมการผลติ ก าลงัปฏบิตังิานบรเิวณ Roller of Palletizer machine ไดย้นิเสยีงดงัผดิปกตขิองเครือ่งจกัร จงึเขา้ไปสงัเกตดโูดยไมไ่ดปิ้ดสวติชเ์ครือ่งจกัร ขณะนัง่ฟงัเสยีงและสงัเกตดทูี่เครือ่งจกัร ปลายนิ้วชีม้อืขวาไดย้ืน่ชดิเขา้ในร ูFrame ของเครือ่ง ซึง่จดุดงักล่าวมกีารเคลื่อนทีข่ ึน้-ลง ของชุดเรยีง Product จงึเฉีอนทบับรเิวณปลายน้ิวมอืขวาไดร้บับาดเจบ็ จากนัน้ เพื่อนรว่มงานไดน้ าผูบ้าดเจบ็ส่งหอ้งพยาบาลและส่งรกัษาต่อโรงพยาบาลกรงุเทพ-ระยอง ซึง่ผลการ X-Ray พบว่ากระดกูปลายนิ้วชีม้อืขวาแตกเลก็น้อย

การวิเคราะหส์าเหต ุ: • สาเหตขุณะนัน้ : - พนักงานเข้าไปอยู่ในจดุท่ีเครือ่งจกัรก าลงัท างาน • สาเหตพืุ้นฐาน : - Human error ของพนักงาน ท่ีไม่ปฏิบติัตามขัน้ตอนการท างาน เรง่รีบท่ีจะแก้ปัญหาจนลืมถึงอนัตรายท่ีจะเกิดขึน้

02/2018

ข้อเสนอแนะ : 1.อบรมขัน้ตอนการท างานและจิตส านึกในเรือ่งความปลอดภยัให้กบัพนักงานอีกครัง้ พรอ้มทัง้ให้พนักงานท่ีเกิดอบุติัเหตแุชรป์ระสบการณ์ให้กบัพนักงานทุกกะ 2.จดัท าป้าย Safety sign ระวงัเครือ่งจกัรหนีบติดไว ้ท่ีเครือ่ง Palletizer ทุก Line 3.ผูจ้ดัการแผนกและหวัหน้ากะทุกกะ ไป Coaching ในเรือ่งความปลอดภยัให้กบัพนักงานท่ีหน้างานทกุกะ 4.จดัท า Lesson learned 5. จดัท าพืน้ขาว-แดง บริเวณประตทูางเข้าใกล้เครือ่งจกัร เพื่อให้ผูเ้ข้าปฏิบติังานเกิดความตระหนักถึงอนัตรายท่ีอาจเกิดขึน้

ชุด slide

การขึน้-ลง ของชุดเรยีงProduct

ลกัษณะหน้าสมัผสัชดุ Slide เมื่อน้ิวยื่นเขา้ในชอ่ง จงึท าใหเ้กดิการบาดเจบ็

การแก้ปัญหาทนัทีท่ีเกิดเหต ุ1. หวัหน้ากะจดัท า Safety talk, Tool box เน้นเรือ่ง สาเหตุและผลของอบุติัเหตใุห้พนักงานในหน่วยงานทราบโดยด่วน เพื่อให้เกิดความตระหนักถึงความปลอดภยัในการท างาน 2.ท าป้ายห้าม Bypass Safe guard ติดท่ีหน้าเครือ่ง Palletizer ทุก Line

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