Hazard Identification and Risk Assessment - Blacktown City · PDF fileEnviropacific Services...
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Hazard Identification and Risk Assessment
Prepared for
John and Anna Arcidiacono
BP Huntingwood
6 Honeman Close, Huntingwood, NSW
Date: 13/07/2017
Project No: 11034 Revision: A
Cadway Project No 10909
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
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Prepared by:
Authored by Approved by Approval Date
C. Karageorgos C. Rogers 14/07/17
History:
Rev Nature of Change/Issue Author Date
A Issued for DA C. Karageorgos 14/07/17
Disclaimer
This report is based on information provided by the Client in terms of the types of dangerous goods and the
quantities to be stored and handled on site. A facility management plan shall include the quantities of
dangerous goods stored and any relevant information contained in this report so that users are aware of these
requirements. This report assesses only the situations indicated and does not address all possible scenarios or
catastrophic events which may be possible but have a very low likelihood of occurring. Assumptions have
been made, as indicated and these need to be considered in management practices. The report outcomes
do not totally eliminate the risks, but rather present a risk management approach intended to mitigate risks to
as low as practicable to achieve compliance with the appropriate standards for the facility. If the activities or
dangerous goods or quantities change then this assessment shall be updated to ensure compliance is
maintained and safety is properly considered.
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Contents
1. Scope of this Report ....................................................................................................................................... 3
2. Description of Site ........................................................................................................................................... 4
3. Description of the Proposed Fuel Facilities ................................................................................................ 5
4. Findings and Recommendations ................................................................................................................ 7
5. Methodology ................................................................................................................................................. 11
6. Site Manifest .................................................................................................................................................. 12
7. Hazard Identification and Risk Assessment ............................................................................................. 14
8. SEPP 33 Preliminary screening .................................................................................................................... 31
9. Appendix A - Legislation ............................................................................................................................. 32
10. Appendix B - Proposed Site Plan ............................................................................................................... 33
11. Appendix C - Safety Data Sheets ............................................................................................................. 34
12. Appendix D - Enviropacific Services Fuel Experience ........................................................................... 35
13. Appendix E - Enviropacific Services Fuel Industry Clients ..................................................................... 36
14. Appendix G - Enviropacific Services Fuel Industry Projects .................................................................. 37
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1. Scope of this Report
A Hazard Identification and Risk Assessment of the proposed BP Huntingwood Service station 6
Honeman Close, Huntingwood, NSW, 2148 was carried out by Enviropacific Services Pty Ltd on the
13/07/17 on behalf of John and Anna Arcidiacono. The purpose of this Hazard Identification and
Risk Assessment is to report on the compliance of the Hazardous Chemical storage, and the fuel
dispensing system at this facility as required by current National and relevant State Acts,
Regulations, Codes, and Australian Standards and Local Authority Approvals (refer to Appendix A).
The observations and comments in this Hazard Identifications and Risk Assessment Report are based
on information supplied to Enviropacific Services by the client and the proposed works to be
undertaken on site. This report has reviewed the proposed service station and does not assess the
hazards and risks outside of the service station boundary in relation to the adjoining development.
Enviropacific’s duty is to ensure that all information contained in this Hazard Identification and Risk
Assessment Report is accurate and current. Enviropacific Services recommendations are
applicable only to matters relevant to the National and State Acts, Regulations, Codes, Australian
Standards (refer to Appendix A), and Local Authority Approvals made available by the Client.
While this report identifies intentional criminal activities such as vandalism and theft, deliberate acts
of sabotage or terrorism are outside the scope of this document and should be addressed by a
specialist consultant if required. Work Health and Safety risk assessments should be carried out in
addition to this Hazard Identification and Risk Assessment Report.
Items not specifically mentioned in this Hazard Identification and Risk Assessment Report should not
be regarded as having been inspected by Enviropacific Services. Recommendations are not
exhaustive, and when applicable, all recommended works are subject to approval and full
compliance by the National and State Authorities.
Enviropacific Services Pty Ltd is a registered Building Design Company which has worked for and
within the Retail Petroleum Industry for more than 20 years (refer to Appendix D for Enviropacific
Services company profile). The recommendations contained within this document are based on
Enviropacific Services industry experience and on sound professional practice. Opinions and
advice given by Enviropacific Services in the following report represents Enviropacific Services best
judgement, but (to the permitted extent by law) Enviropacific Services accepts no liability for
claims or damages caused by its negligence (or that of its employees or agents) or otherwise. As
such, the reader is invited to obtain any supporting information he or she feels is necessary before
making any decisions.
The following report is confidential and not to be made available to other parties unless under the
consent of the Client.
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2. Description of Site
Address: BP Huntingwood Service station
6 Honeman Close,
Huntingwood
NSW, 2148
Site Area of proposed works: 15032 m2
Real Property Description: Lot 2 on DP229466
Local Authority: Blacktown Council
Owner: John and Anna Arcidiacono
Operator: John and Anna Arcidiacono
Figure 1 Aerial Photo of Site Locality
PROPOSED SITE
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3. Description of the Proposed Fuel Facilities
The following is a description of the facilities based on the findings and recommendation contained
within this report which when implemented mitigate the identified risks to an acceptable level.
This is a new service station development consisting of a shop building, car canopy and
truck canopy.
The sales building has an area of 475m2.
The car canopy covers has an area 420m2.
The truck canopy covers has an area 380m2.
The car canopy will have 6 x 8 hose fuel dispensers.
The truck canopy will have 5 x 6 hose fuel dispensers.
The Underground Petroleum Storage System (UPSS) consists of 5 x 110kL double contained
skin fibreglass tanks complying with AS 1692-2006 and AS 1940-2004.
A gravity flow, containment and treatment device shall be installed to collect any potential
contamination or spills to prevent hydrocarbons from entering the council stormwater
system. This system shall have a minimum spill capacity of 9,500 litres in the event of a fuel
tanker compartment rupture as required by AS 1940-2004.
The UPSS remote fill points are contained within a spill safe fill box and located within the spill
containment area.
A stainless steel DEF remote fill point is contained within a spill safe fill box and located within
the spill containment area.
Filling of the underground fuel tanks will be conducted by a tanker that will enter in a
forward direction onto the hardstand area. The tanker discharge area will contain an
emergency stop, automatic tank gauging panel, fire hydrant with foam making facilities,
fire extinguishers, and associated compliant signage.
Vents for the UPSS and treatment system shall be located in a landscaping island and
protected by bollards or equivalent.
Vapour Recovery Stage 1 shall be installed on site.
Pipe work shall be installed on site to allow for the installation of Vapour Recovery Stage 2.
Sufficient bollards shall be installed to provide adequate vehicle impact protection to
vulnerable equipment.
Impervious concrete pavements will be installed on site.
1 x emergency stops shall be located under the truck canopy. 1 x emergency stop shall be
located at the shopfront directly accessible from the car canopy. 1 x emergency stop shall
be located on the console.
3 x 9kg ABE fire extinguishers in break glass cabinet shall be located on columns under the
car canopy. 5 x 9kg ABE fire extinguishers in break glass cabinet shall be located on
columns under the truck canopy.
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A fire hose reel will be provided at the forecourt and readily accessible.
A spill kit shall be located in the forecourt.
An air/water point will be located adjacent the car parking bay.
There will be landscaping around the street frontages of the site.
There will be 2 x LPG exchange gas bottle cage located at the front of the shop.
An ice freezer will be located on the plinth at the front of the shop.
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4. Findings and Recommendations
This report is to be referenced in its entirety by the project design team. Excerpts shaded in yellow
however are items to be specifically considered & included as part of the project scope for the
entire multi-disciplinary design team. The relevant disciplines to consider these shaded items
include: civil, electrical, structural & architectural.
The proposed facility can be classified as a Manifest Quantity Workplace as defined in the New
South Wales Work Health and Safety Regulations 2011.
The risk to persons, property, and the environment posed by this proposed service station are
mitigated to an acceptable level of risk provided the following recommendations are
implemented.
A spill containment holding tank of 9,500 litre capacity shall be provided to mitigate the risk
of a fuel tanker compartment sized major spill event from migrating off site and
contaminating the environment or causing damage to persons and/or property.
Instructional signage and training in the use of the facilities shall be provided and
maintained.
Hazchem signage and placarding to be installed in accordance with the New South Wales
Work Health and Safety Regulations 2011.
CCTV with remote monitoring; back-to-base alarm systems and emergency stop button
activation; remote automatic tank gauging for net stock management; active leak
monitoring on the product delivery systems, all with 24 hour reporting and response
capabilities, mitigate the risks present in a service station facility such as this.
A site manifest shall be provided to reflect the on-site refuelling facilities.
An Emergency Plan shall be provided to ensure procedures are in place if an incident was
to occur. Staff training in the implementation of this emergency procedure shall be carried
out and recorded. This Emergency Plan shall be reviewed on a regular basis, when changes
occur on site, or after an incident has occurred.
General:
Provide line marking and directional signage on the forecourt.
Forecourt hardstand surfaces to be designed to be as slip resistant as possible.
Clearly identify entry to shop with pedestrian line marking.
Minimise use of kerbs in areas commonly used by pedestrians. Kerbs in paths of travel shall
be painted in high visibility colour (yellow). Install tactile indicators to Australian Standards.
Spill Containment:
Install an under canopy catchment area that drains to a stormwater treatment system
where the spillage is contained and dealt with in line with specifically formulated
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Emergency Plan. Impervious concrete pavements will be installed on the tanker hardstand
and fuel compound areas.
Fill points are to be installed within a spill safe fill box draining back into the fuel system. This
spill safe fill box is to be located within the under canopy catchment area.
Provide an emergency spill kit on site that is directly accessible from the dispensers. Provide
training on its use to site staff and tanker drivers.
Console operator to monitor forecourt and immediately clean up any minor spill using
existing on site spill kit.
If a major spill occurs, operator to shut down site and follow emergency procedures.
Check tank excavation observation wells and ground water monitoring wells regularly for
contamination.
Provide product reconciliation procedures (auto tank gauging, manual dip) and ensure
product reconciliation is performed daily.
Provide accurately calibrated tank dips or auto tank gauging.
Provide overfill protection within the tanks.
Fuel System
Install sufficient bollards around dispensers and vents to provide mechanical protection.
Shear valves and flame arrestors are to be provided at the dispenser bases.
Provide dispenser nozzles with safety cut out attitude valve.
Remove latching mechanism from dispenser nozzles.
The fuel tanks are made from non-corrosive materials.
Fuel supply pressure pipework shall be:
I. Double contained underground, non-corrodible pipes
Pressure line leak detection shall be installed to all fuel supply pressure pipework.
Auto tank gauging and line leak detection is to be provided to tanks and pipework.
Vents shall be installed to Australian Standards in a well-ventilated location, away from
potential ignition sources and in a protected area away from vehicles in a landscaping
area of the site.
Statutory Signage
Provide statutory signage at dispensers forbidding smoking on site, use of mobile phones or
other electronic device at dispensers, and the filling of non-compliant containers.
Provide signage on dispensers stating that the latch is not to be locked open and left
unattended.
Provide signage near the vents forbidding smoking on site.
Fill points are to be clearly marked to Australian Standards.
Placarding shall be provided.
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Emergency contact details shall be provided.
Tanker unloading:
Implement strict tanker unloading operation controls.
Provide suitable driver training as to traffic awareness and unloading procedures.
Ensure tanker drivers are trained in site-specific conditions.
Place signage at crossovers warning entering traffic of the presence of the tanker.
Fuel tanker driver to place traffic cones 4m from fuel fill point area and tanker. Close off any
refuelling positions within 4m of the tanker unloading position.
Tanker driver to stand by to monitor fuel transfer operation.
Provide tanker drivers with high visibility clothing.
Operation:
Console operator to shut down dispenser if someone is smoking at dispenser.
Console operator to shut down dispenser if someone is using a mobile phone or other
electronic device at dispenser.
Console operator to shut down dispenser if someone is attempting to fill non-compliant
containers.
Console operator to shut down dispenser if the dispenser is not used appropriately.
Console operator to shut down site and proceed with emergency plan, evacuate if
necessary.
Ensure all staff are trained in spill response.
Maintenance:
Ensure maintenance personnel use traffic cones and signage to barricade off dispenser.
Ensure maintenance personnel use high visibility clothing while on site.
Ensure any electrical work done on dispensers is performed by maintenance personnel with
suitable qualifications and training.
Ensure appropriate work permits are obtained.
Ensure area around the dispensers is adequately ventilated and there is no vehicle parked
close by during maintenance.
Ensure all potential ignition sources are excluded from the area while maintenance is
conducted.
Only appropriately qualified personnel to access confined spaces after a thorough risk
assessment has been completed.
Ensure breathing apparatus and P.P.E. is used where required for confined space entry.
Ensure an appropriately qualified observer is present with appropriate training in emergency
response.
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Manifest and Emergency Plan.
Locate the red weatherproof manifest box immediately adjacent the entry to the site from
the direction of approach of the emergency vehicles.
Ensure the manifest for the site is reviewed at regular intervals.
Provide an emergency plan and ensure training of workers in its use. Records of this training
are maintained on site.
Ensure the Emergency Plan for the site is reviewed at regular intervals.
Security:
Provide CCTV monitoring of the console area.
Provide safe haven behind counter for physical protection.
Provide duress button behind counter and within safe haven.
Provide training to console operators to help recognise suspicious behaviour.
Provide "dead man" system at console.
Fire extinguishers are visible from the console or security camera.
Fire extinguishers to be located in highly visible locations within the viewing range of the
security cameras.
Fire extinguishers are installed in a well-lit area.
Ensure fire fighting equipment is tested regularly to Australian Standards.
LPG Exchange Bottle Cages:
Locate LPG exchange bottle cages in an area with good ventilation, away from ignition
sources, and where they are unlikely to be struck by vehicle.
Provide heavy duty bollards around LPG exchange bottle cages.
Perform a visual check on LPG exchange bottles at delivery to ensure that all have factory
seals on their valves, also check for LPG odours.
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5. Methodology
Risks associated with the hazards identified in this report have been rated using a
frequency/severity matrix illustrated below.
RISK LEVEL GUIDE: FREQUENCY
SEV
ER
ITY
V LOW → EXTREME
0-3 Low, risk level acceptable, no
action required.
V L
OW
1 2 3 4 5
4-6 Medium, requires monitoring, may
require minor remedial action. 2 4 6 8 10
7-10 High, requires action. ↓ 3 6 9 12 15
11 + Unacceptable, activity must stop,
immediate action required. EX
TREM
E
4 8 12 16 20
5 10 15 20 25
Risks have been grouped into one or more of the following risk categories:
1. People - The risk is to any person who may be on site whether they are employees,
maintenance personnel or the general public accessing the site.
2. Property - The risk is to assets of the owner, operator, supplier or any person accessing the
site for any reason.
3. Environment - The risk poses potential harm to the environment including potentially harmful
emissions to air, water or ground. Risks can be both catastrophic, and systemic.
The Risk Assessment process is designed to minimise risks to people, property, and the environment
by the implementation of the following steps as outlined in AS/NZS ISO 31000 - Risk Management -
Principles and guidelines.
Identify all hazards
- Assess all the risks with the use of the hierarchy of control measures of:
- Elimination
- Substitution
- Engineering Controls
- Administration Controls
- Personal Protection Equipment
Document, maintain and monitor the control measures implemented on a regular basis to
ensure associated risks are kept to a minimum.
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6. Site Manifest
Tank/
Storage
No.
Type Description Capacity (litres) Average
Storage
(litres)
Type or category of
hazardous chemical
Equivalent
Dangerous Goods
Class/ Division/
Packaging Group
UN No. Hazchem
1/a Underground Automotive Ultimate Diesel
[Diesel]
50,000 47,500 Flammable Liquids
Category 4
C1 UN 3082 •3Z
1/b Underground Automotive Diesel
[Diesel]
40,000 38,000 Flammable Liquids
Category 4
C1 UN 3082 •3Z
1/c Underground AdBlue
[Diesel Exhaust Fluid]
20,000 19,000 N/A N/A N/A N/A
2/a Underground Automotive Ultimate Diesel
[Diesel]
60,000 57,500 Flammable Liquids
Category 4
C1 UN 3082 •3Z
2/b Underground Automotive Diesel
[Diesel]
50,000 47,500 Flammable Liquids
Category 4
C1 UN 3082 •3Z
3/a Underground Automotive Diesel
[Diesel]
60,000 57,500 Flammable Liquids
Category 4
C1 UN 3082 •3Z
3/b Underground Automotive Ultimate Diesel
[Diesel]
50,000 47,500 Flammable Liquids
Category 4
C1 UN 3082 •3Z
4/a Underground Premium Unleaded
Petrol(95 Octane)
40,000 38,000 Flammable Liquids
Category 2
3 PGII UN 1203 3[Y]E
4/b Underground Unleaded Petrol (91
Octane)
40,000 38,000 Flammable Liquids
Category 2
3 PGII UN 1203 3[Y]E
4/c Underground Ethanol Blended Unleaded
Petrol (E10)
30,000 28,500 Flammable Liquids
Category 2
3 PGII UN 1203 3[Y]E
5/a Underground Premium Unleaded
Petrol(98 Octane)
60,000 57,500 Flammable Liquids
Category 2
3 PGII UN 1203 3[Y]E
5/b Underground Automotive Ultimate Diesel
[Diesel]
50,000 47,500 Flammable Liquids
Category 4
C1 UN 3082 •3Z
6 Exchange bottle
cage (30 bottles)
Liquefied Petroleum Gas <528` <528 Flammable Gases
Category 1
2.1 UN 1075 2YE
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7 Small Package
Store
Miscellaneous Automotive
Fluids
270 270 Flammable Liquids
Category 4
C2 Varies Varies
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7. Hazard Identification and Risk Assessment
No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Section 1 - Operation
1.1 Vehicle
movements on
site
Dispenser is struck Dispenser requires repair or
replacement.
Spilt fuel is ignited causing
injury or death and
destruction of property.
People in vehicle are injured.
Vehicle is damaged.
Product is spilt to the
environment.
Level 8.
People.
Property.
Environment.
Install bollards around
dispensers to provide
mechanical protection.
Provide line marking and
directional signage on the
forecourt.
Shear valves and flame
arrestors are to be provided
at the dispenser bases.
Install spill containment
catchment area that drains
to a treatment system where
the spillage is contained
and dealt with in line with
specifically formulated
emergency procedures.
Dispensers are physically
protected.
Intent for the correct use of site is
made obvious through signage.
Risk of spill and explosion is
minimised by the installation of
shear valves.
Risk of fuel spill is minimised
through collection of spills by the
treatment system.
Level 2-3.
People.
Property.
Environment.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Tanker parked on
site is struck
Rupture of tanker
compartment causing major
spill.
Spilt fuel is ignited causing
injury or death and
destruction of property.
Damage to tanker trailer
requiring repair.
People in vehicle are injured
or killed.
Level 10.
People.
Property.
Environment.
Lower speed limit on site to
10km/hour.
Implement strict tanker
unloading operation
controls.
Fuel tanker driver to place
traffic cones from fill point
area and tanker.
Place signage at crossovers
warning entering traffic of
the presence of the tanker.
Close off any refuelling
positions within 4m of the
fuel tanker unloading
position.
Locate fill point within the
compound catchment area
that drains to a treatment
system where the spillage is
contained and dealt with in
line with specifically
formulated emergency
procedures.
Low speed of traffic on site allows
collisions to be avoided, allows
people time to get out of the
way of moving vehicles and
minimises the effects of collisions.
Entering traffic has plenty of
warning that there is a tanker on
site.
Visual cues are in place directing
traffic away from the tanker
location.
The physical presence of the
tanker vehicle also provides a
deterrent to irresponsible vehicle
operation on site.
Appropriate procedures and
physical controls are in place to
enable major spills to be
managed as safely as possible.
Risk of fuel spill is minimised
through collection of spills by the
treatment system.
Level 4.
People.
Property.
Tanker driver is
struck
Tanker driver is injured or
killed.
Level 10.
People.
Lower speed limit on site to
10km/hour.
Provide suitable driver
training as to traffic
awareness and unloading
procedures.
Provide tanker drivers with
high visibility clothing.
Low speed of traffic on site allows
collisions to be avoided, allows
people time to get out of the
way of moving vehicles and
minimises the effects of collisions.
Driver is visible and traffic is aware
of driver’s presence.
Level 5.
People.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Tanker transfer
hose is struck
Transfer hose is ruptured
causing major spill.
Spilt fuel is ignited causing
injury or death and
destruction of property.
Transfer hose is damaged
requiring repair or
replacement.
Level 8.
People.
Property.
Environment.
Implement strict tanker
unloading operation
controls.
Access to tanker hardstand
is to be secured so no
vehicle is allowed during
fuel unloading.
Fuel tanker driver to place
traffic cones 4m from fill
point area and tanker.
Place signage at crossovers
warning entering traffic of
the presence of the tanker.
Close off any refuelling
positions within of the fuel
tanker unloading position.
Tanker driver to stand by to
monitor fuel transfer
operation.
Locate fill point within the
compound catchment area
that drains to a treatment
system where the spillage is
contained and dealt with in
line with specifically
formulated emergency
procedures.
Entering traffic has plenty of
warning that there is a tanker on
site.
Visual cues are in place directing
traffic away from the tanker
location.
The physical presence of the
tanker vehicle also provides a
deterrent to irresponsible vehicle
operation on site.
Tanker driver is positioned such
that he is protected and can
direct traffic away from
unloading area.
Appropriate procedures and
physical controls are in place to
enable major spills to be
managed as safely as possible.
Risk of fuel spill is minimised
through collection of spills by the
treatment system.
Level 4.
People.
Property.
Environment.
Person using the
site or their vehicle
is struck.
Person is injured or killed.
Damage to private property
on site.
Level 10.
People.
Property.
Limit speed on site to
10km/h.
Low speed of traffic on site allows
collisions to be avoided, allows
people time to get out of the
way of moving vehicles and
minimises the effects of collisions.
Level 2-3.
People.
Property
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
1.2 Use of dispensers Smoking at
dispenser
Vapour ignites causing injury
or death and damage to
property.
Level 12.
People.
Property.
Provide statutory signage at
dispensers forbidding
smoking on site.
Console operator to shut
down dispenser if someone
is smoking at dispenser.
Provide CCTV monitoring at
refuelling position.
People are made aware of the
danger regarding smoking on
site.
The situation is able to be
controlled by the console
operator by shutting down the
dispenser.
Risk eliminated if there is no
smoking on site.
Level 1.
People.
Property.
Use of mobile
phone or potential
source of flame at
dispenser
Vapour ignites causing injury
or death and damage to
property.
User is distracted from the
task of fuelling.
Level 8.
People.
Property.
Provide statutory
signage/highly visible
signage at dispensers
forbidding use of mobile
phones or other potential
source of flame such as pilot
lights, gas refrigerators and
other electrical device at
dispensers
Console operator to shut
down dispenser if someone
is using a mobile phone or
other electronic device at
dispenser.
Provide CCTV monitoring at
refuelling position.
People are made aware of the
danger regarding the use of
mobile phones and other
electronic devices at dispenser.
The situation is able to be
controlled by the console
operator by shutting down the
dispenser.
Risk eliminated if there is no use of
mobile phones and other
electronic devices on site.
Level 1.
People.
Property.
Filling of non-
compliant
container(s)
Hydrocarbons may dissolve
container causing spillage
and releasing vapour.
Hydrocarbons may react
with container causing fire.
Level 6.
People.
Property.
Provide statutory signage at
dispensers forbidding the
filling of non-compliant
containers.
Console operator to shut
down dispenser if someone
is attempting to fill non-
compliant containers.
People are made aware of the
danger regarding the filling of
non-compliant container(s).
The situation is able to be
controlled by the console
operator.
Level 3.
People.
Property.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Misuse of nozzle or
leaving dispenser
unsupervised while
discharging fuel
Spillage of fuel onto
forecourt or people causing
fire hazard and risk of injury.
Damage to nozzle requiring
repair or replacement.
Release of vapour leading to
fire hazard and risk of injury
and damage to property.
Hydrocarbons could find
their way into waterways
causing environmental harm.
Level 9.
People.
Property.
Environment.
Provide highly visible
warning signage and
instructions at the dispenser.
Console operator to monitor
forecourt and shut down
dispenser is not used
appropriately.
Install nozzles with safety cut
out attitude valve
Remove latching
mechanism from nozzle.
Provide signage stating that
the latch is not to be locked
open and left unattended.
Provide readily accessible
spill kit on site.
The situation is able to be
controlled by the console
operator.
Risk of fuel spill is minimised
through collection of spills by the
treatment system.
Appropriate procedures and
physical controls are in place to
enable major spills to be
managed as safely as possible.
Level 4.
People.
Property.
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Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 19 of 39
No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Product spill onto
forecourt.
Slip hazard leading to risk of
injury.
Release of vapour leading to
fire hazard and risk of injury
and damage to property.
Hydrocarbons could find
their way into waterways
causing environmental harm.
Level 9.
People.
Property.
Environment.
Console operator to monitor
forecourt activity and
immediately clean up any
minor spill using the spill kit
readily accessible from the
dispenser.
If a major spill occurs,
operator to shut down site
and follow emergency
procedures.
Install a under canopy
catchment area that drains
to a treatment system where
the spillage is contained
and dealt with in line with
specifically formulated
emergency procedures.
Provide highly visible
warning signage and
instructions at the dispenser.
Any minor spills are contained
and removed quickly.
Risk of fuel spill is minimised
through collection of spills by the
treatment system.
Appropriate procedures and
physical controls are in place to
enable major spills to be
managed as safely as possible.
Level 6.
People.
Property.
Environment.
Drive-off fuel theft Loss of income. Level 8.
Property.
Console operator to monitor
forecourt activity for ‘drive
offs’.
Installation of CCTV
monitoring of refuelling
positions to capture ‘drive
offs’/theft.
If a ‘drive off ‘occurs the number
plate of the vehicle is recorded
and is likely to be witnessed.
Incident is recorded and
offenders are identified.
Level 4.
Property.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
1.3 Tanker
unloading
Minor fuel spill (up
to 20l.)
Vapour from spill could ignite
causing injury or damage to
property.
Hydrocarbons could find
their way into stormwater
system and waterways
causing environmental harm.
Level 6.
People.
Property.
Environment.
Provide an emergency spill
kit on site that is readily
accessible from the
dispensers. Provide training
on its use to site staff and
tanker drivers.
Fill points are to be located
within a spill safe fill box
draining back into the fuel
system.
Appropriate procedures and
physical controls are in place to
enable minor spills to be
managed as safely as possible.
Level 3.
People.
Property.
Environment.
Major fuel spill
(over 20l.)
Vapour from spill could ignite
causing injury or damage to
property.
Hydrocarbons could find
their way into stormwater
system causing a potential
explosive atmosphere within
pipework.
Hydrocarbons could find
their way into waterways
causing environmental harm.
Level 10.
People.
Property.
Environment.
Provide an emergency plan
and ensure training of
workers in its use.
Console operator to shut
down site and proceed with
emergency plan, evacuate
if necessary.
Ensure all fill points are
installed within the
catchment area that drains
to a treatment system.
Spillage is contained and
dealt with in line with
specifically formulated
emergency procedures.
Appropriate procedures and
physical controls are in place to
enable major spills to be
managed as safely as possible.
Level 5.
People.
Property.
Environment.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Incorrect product
introduced into
storage tank
Possible damage to private
property caused by use of
incorrect fuel.
Level 6.
Property.
Ensure tanker drivers are
trained in site-specific
conditions.
Fill points are clearly marked
to Australian Standards.
Provide tanker driver with
correct, up to date fill point
sketch.
Any discrepancy between
the fill point markers and the
fill point sketch to be notified
and fuel transfer is not to
proceed.
Tanker driver can clearly see the
product arrangement and has
the ability to cross check the fill
point arrangement.
Level 3.
Property
Storage tank is
overfilled
Potential fuel spillage
causing risk of ignition or
harm to the environment.
Lack of ullage space may
cause storage tank to
rupture due to thermal
expansion of hydrocarbon.
Level 9.
Property.
Environment.
Ensure product
reconciliation is performed
daily.
Provide accurately
calibrated tank dips or auto
tank gauging.
Tanker driver to confirm
product volumes prior to
performing a fuel transfer.
Provide overfill protection
within the tanks.
Overfilling of the tanks becomes
very difficult.
Level 3.
Property.
Environment.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
1.4 Console
operation
Robbery Physical and psychological
harm to the console
operator.
Loss of income.
Level 12.
People.
Property.
Provide CCTV monitoring of
the console area.
Provide safe haven behind
counter for physical
protection.
Provide duress button
behind counter and within
safe haven.
Provide training to console
operators to help recognise
suspicious behaviour.
Console operator has the means
to protect their self.
Level of security has a deterrent
effect.
Level 8.
People.
Property.
Operator is
incapacitated
during lone shift
Operator may be unable to
access emergency medical
help.
Potential for theft if there is
no one visibly on duty.
Level 8.
People.
Property.
Provide "dead man" system
at console.
In the case of incapacitation,
emergency services are notified
automatically, although the time
lapse still represents a risk.
Level 4.
People.
Property.
1.5 Maintenance
access to
dispensers
Maintenance
person being struck
by vehicle
Maintenance person could
be injured or killed.
Level 12.
People.
Ensure maintenance
personnel use traffic cones
and signage to barricade
off dispenser.
Ensure maintenance
personnel use high visibility
clothing while on site.
Ensure an appropriately
qualified observer is present
with appropriate training in
emergency response.
Ensure appropriate work
permits are obtained.
The work area and personnel are
highly visible to any traffic on site.
Level 4.
People.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Electrocution Maintenance person could
be injured or killed.
Equipment is damaged.
Level 12.
People.
Property.
Ensure any electrical work
done on dispensers is
performed by maintenance
personnel with suitable
qualifications and training.
Ensure appropriate work
permits are obtained.
Risks to maintenance personnel
and equipment are minimised
through the use of correctly
trained personnel and safe work
procedures.
Level 3.
People.
Property.
Exposure to
explosive
atmosphere within
dispenser housing
Maintenance person could
be injured or killed.
Possible damage to
property.
Level 16.
People.
Property.
Ensure area around the
dispensers is adequately
ventilated and that there
are no vehicles parked
close by during
maintenance.
Ensure all potential ignition
sources are excluded from
the area.
Ensure appropriate work
permits are obtained.
Vapours are being dispersed.
The potential for ignition is greatly
reduced.
Level 6.
People.
Property.
1.6 Maintenance
entry into tanks
Exposure to
explosive
atmosphere
Maintenance person could
be injured or killed.
Possible damage to
property.
Level 10.
People.
Property.
Only appropriately qualified
personnel to access
confined spaces.
Ensure appropriate entry
and work permits are
obtained.
Ensure all safety clothing
and breathing apparatus
are used.
Ensure an appropriately
qualified observer is present
with appropriate training in
emergency response.
Risks to personnel are minimised
through the use of correctly
trained personnel and safe work
procedures.
Level 4.
People.
Property.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Inhalation of
vapour
Could result in various health
problems relating to
respiration and central
nervous system, potential for
fatality.
Level 10.
People.
Ensure breathing apparatus
is used.
Ensure an appropriately
qualified observer is present
with appropriate training in
emergency response.
Risks to personnel are minimised
through the use of appropriate
safety equipment and safe work
practices.
Level 4.
People.
Maintenance
person being struck
by vehicle
Maintenance person could
be injured or killed.
Level 12.
People.
Ensure maintenance
personnel use traffic cones
and signage to barricade
off dispenser.
Ensure maintenance
personnel use high visibility
clothing while on site.
Ensure an appropriately
qualified observer is present
with appropriate training in
emergency response.
Ensure appropriate work
permits are obtained.
The work area and personnel are
highly visible to any traffic on site.
Level 4.
People.
1.7 Customer safety Customer being
struck by tanker or
other vehicle
Customer could be injured or
killed
Level 12.
People.
Clearly identify entry to shop
with pedestrian line marking.
Limit speed on site to
10km/h.
Keep area clear of trip
hazards and unnecessary
items.
Provide CCTV monitoring at
forecourt.
Customer is visible and traffic is
aware.
Low speed of traffic on site allows
collisions to be avoided, allows
people time to get out of the
way of moving vehicles and
minimises the effects of collisions.
Activity at the forecourt is
monitored and the console
operator is made aware of
potential danger.
Level 5.
People.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
1.8
Manual Car
Wash
Chemical Handling
Eye & Skin irritation caused
by exposure from cleaning
chemicals
Level 6.
People
Eye wash available
Gloves available if required
(must be used for sensitive
skin)
Employees to be trained to
used equipment safely
Risk minimised by employee
training.
PPE available to minimise
exposure.
Eyewash can be administered to
avoid injury.
Level 4
People.
High pressure hose Injury to employees
Damage to Cars by loss of
pressure hose control
Level 6.
People
Property
Employees to be trained to
used equipment safely
Eye protection must be worn
Risk minimised by employee
training.
PPE available to minimise
exposure.
Level 4
People.
Property
Wet Surfaces Slips/Trips
Personal Injury
Level 8.
People
Slip resistant surfaces
(coarse broom finished
concrete).
Signage to restrict public
access.
Appropriate Safety
footwear.
Mechanical Sweep and
Scrub
Insure floors are well drained
to avoid water pooling
Work surface minimised to
reduce slipping.
Public access restricted.
PPE required.
Area clean of hazards by
mechanical sweeping to
minimise incidents.
Level 3.
People
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Electrocution Employee could be injured
or killed.
Equipment is damaged.
Level 12.
People.
Property.
Circuit RCD protected.
Equipment is serviced every
six months.
Safety training to employees
on how to operate
electrical equipment.
Minimise water where
electrical connections are
by means of safety
procedures
Risks to maintenance personnel
and equipment are minimised
through the use of correctly
trained personnel and safe work
procedures.
Level 3.
People.
Property
Vehicle Damage to vehicles driving
thru carwash
Damage to
buildings/surrounds from
vehicles
People being injured from
vehicles.
Level 9.
People.
Property
Speed limits in place.
Signage to restrict non-
employers from driving in &
to restrict pedestrian access.
Install speed bumps.
Install bollards.
Limited to employers only by use
of signage.
Speed bumps and limits enforced
to reduce speeds to harmful
accidents occurring.
Bollards in place to protect
surrounding buildings.
Level 3.
People.
Property
Section 2 – The Installation
2.1
Concrete
forecourt
Slippery surfaces
due to spillage
Possible slip and fall causing
injury.
Vehicle accessing the site
could lose control causing
possible injury to persons on
site or damage to property.
Level 8.
People.
Property.
Spill kits are provided on site
and are readily accessible
from the dispensers.
Ensure all staff is trained in
spill response.
Forecourt surfaces to be
designed to be slip resistant.
The time between a spill and
clean-up is minimised.
Surface provides as much grip as
possible.
Level 4.
People.
Property.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Trip hazard at kerbs Possible trip and fall causing
injury.
Level 8.
People.
Kerbs in paths of travel to be
painted in high visibility
colour (yellow).
Install indicators to Australian
Standards.
Minimise use of kerbs in
areas commonly used by
pedestrians.
Trip hazards are visible and their
number is minimised.
Level 3.
People.
2.2 Underground
fuel tanks and
pipework
Structural failure of
tanks and/or
pipework
Possibility of hydrocarbon
being spilt to ground causing
environmental harm.
Level 8.
Property.
Environment.
The liquid fuel tanks are
made from non-corrosive
materials.
Auto tank gauging and line
leak detection is to be
provided to tanks and
pipework.
Provide product
reconciliation procedures
(auto tank gauging, manual
dip).
Check tank excavation
observation wells regularly.
Should failure occur checks are in
place for product reconciliation,
leak detections, and the
surrounding area is being
monitored to minimise harm.
Level 3.
Property.
Environment.
2.3
Fire extinguishers
Misuse of
equipment
May cause extinguisher to
fail or run out during
emergency.
Fire extinguisher discharge
would require clean up.
Fire extinguisher would
require recharging.
Level 6.
Property.
Fire extinguishers are visible
from the console or security
camera.
Fire extinguishers are
installed in a well-lit area.
Fire extinguishers can be
monitored.
Location in well-lit area acts as a
deterrent to potential misuse.
Location where visible increases
likelihood of any misuse being
witnessed.
Level 4.
Property.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Theft of equipment Fire fighting equipment may
be unavailable during an
emergency.
Cost of replacing fire
extinguisher.
Level 6.
Property.
Fire extinguishers are visible
from the console or security
camera.
Fire extinguishers are
installed in a well-lit area.
Fire extinguishers can be
monitored.
Location in well-lit area acts as a
deterrent to potential theft.
Location where visible increases
likelihood of any theft being
witnessed.
Level 3.
Property.
Failure of
equipment
Personnel unable to respond
to a fire emergency causing
damage to property and
possible injury or death.
Level 8.
People.
Property.
Ensure fire fighting
equipment is tested
regularly to Australian
Standards.
If fire extinguishers are required
their correct operation is ensured.
Level 2.
Property.
Vandalism Fire extinguisher could fail
during emergency.
Level 6.
Property.
Fire extinguishers are visible
from the console or security
camera.
Fire extinguishers are
installed in a well-lit area.
Fire extinguishers can be
monitored.
Location in well-lit area acts as a
deterrent to potential vandals.
Location where visible increases
likelihood of any vandalism being
witnessed.
Level 3.
Property.
2.4
Tank vents
Vents being struck
by vehicle
Could result in injury and
damage to property.
Level 6.
People.
Property.
Vents are installed in a
protected area away from
vehicles in a landscaping
area of the site.
Install bollards around vents
to provide mechanical
protection.
It is very unlikely that the vents will
be struck.
Level 2.
Property.
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
Vapour igniting Could result in injury and
damage to property.
Level 8.
People.
Property.
Vents are installed away
from any potential ignition
source.
Vents are installed to
appropriate Australian
Standards.
Provide signage near the
vents forbidding smoking on
site.
Risk of ignition is minimal. Level 2.
Property.
Inhalation of
vapour
Vapour inhalation can result
in headaches, dizziness,
weakness, nausea, blurred
vision, shortness of breath
and effects to central
nervous system. Refer to
material safety data sheets.
Level 10.
People.
Vents are installed to
appropriate Australian
Standards.
Vents are installed in a well-
ventilated location.
The likelihood of vapour
inhalation is minimal.
Level 2.
People.
2.5 LPG exchange
bottle cages
LPG exchange
bottle cages being
struck by vehicle
Could result in explosion,
injury and damage to
property.
Level 10.
People.
Property.
Locate LPG exchange
bottles in an area unlikely to
be struck by vehicle.
Install bollards around LPG
exchange bottle cage and
cylinders to provide
mechanical protection.
The likelihood of LPG exchange
bottle cage and cylinders being
struck is minimal.
Level 3.
People.
Property.
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No Hazard Risks Consequences Risk Level
and Type
Action Re-assessment of Consequences Revised Risk
Level
LPG exchange
bottle leaking
Could result in explosion,
injury and damage to
property.
Level 10.
People.
Property.
LPG exchange bottles are
located in an area with
good ventilation.
LPG exchange bottles are
located away from ignition
sources.
Ensure statutory signage on
the LPG exchange bottle
cage forbidding smoking.
Perform a visual check on
LPG exchange bottles at
delivery to ensure that all
have factory seals on their
valves, also check for LPG
odours.
Good ventilation reduces the risk
of leaking gas pooling.
The likelihood of leaking LPG
exchange bottles being ignited is
reduced.
Level 3.
People.
Property.
2.6 Site Manifest An emergency
situation could
occur requiring
information of site
specific hazards.
Emergency services unable
to access site specific
information for the
hazardous chemical storage
in the event of an
emergency.
Level 8.
People.
Property.
Locate the red
weatherproof manifest box
immediately adjacent the
entry to the site from the
direction of approach of the
emergency vehicles.
Ensure the manifest for the
site is reviewed at regular
intervals.
The manifest is easy to find and
accessible.
The manifest is up to date with
product types and volumes
stored on site.
Level 3.
People.
Property.
2.7 Emergency Plan An emergency
situation could
occur requiring a
site specific
response.
Workers are unaware of
emergency response
procedures.
Level 8.
People.
Property.
Ensure the Emergency Plan
for the site is reviewed at
regular intervals.
Ensure workers on site are
trained in the Emergency
Plan and records of this
training are maintained on
site.
In the event of an incident,
workers know what procedures
are in place and how to respond
to minimise the effects of the
incident.
Level 3.
People.
Property.
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
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8. SEPP 33 Preliminary screening
Refer to SEPP 33 Preliminary screening report attached
Level 4 66 Clarence Street Sydney NSW Australia 2000 www.meinhardtgroup.com Tel: 61 (02) 9699 3088 Fax: 61 (02) 9319 7508
Introduction
This letter report sets out the results of the SEPP33 preliminary screening on the proposed service station
development at 6 Honeman Close, Huntingwood, NSW.
The Hazardous and Offensive Development Application Guidelines - Applying SEPP 33 (January 2011)
NSW Dept. of Planning (the guidelines) provides a risk screening method to assist in determining whether
a proposed development is potentially hazardous and thus determine whether SEPP 33 applies.
For development proposals classified as ‘potentially hazardous industry’ the policy establishes a
comprehensive test by way of a preliminary hazard analysis (PHA) to determine the risk to people,
property and the environment at the proposed location and in the presence of controls. SEPP 33 applies
to any proposals which fall under the policy’s definition of ‘potentially hazardous industry’ or ‘potentially
offensive industry’.
Hazard Identification – Preliminary Screening
To determine if a proposed facility is potentially hazardous a number of steps are followed using the risk
screening method given in the guideline.
The steps include;
o collate information;
o identify hazardous materials and the type of hazard;
o group and total by class, activity and location;
o compare with screening threshold;
o consider transportation issues; and
o determine whether SEPP 33 applies
A preliminary screen of the proposed development has found that the proposed service station
development at 6 Honeman Close, Huntingwood, NSW is “not potentially hazardous” as defined under
SEPP33.
29 May 2017
SEPP33 Preliminary Screen ; Project No. 117878 Proposed BP Service Station Development; 6 Honeman Close, Huntingwood, NSW (11034 SK009, Issue D 17/05/2017).
117878 - l01 - huntingwood sepp33 2
Assessment of Data. Table 1 displays hazardous materials to be stored on-site and quantities. Table 1: Material quantities and classifications.
Tank Material Classification Quantity
Mode of storage Volume (kL) Mass (tonnes)
T1a Diesel 3PGII 50 42# Underground tank
T1b Diesel 3PGII 40 34# Underground tank
T1c AdBlue - 20 - Underground tank
T2a Diesel 3PGII 60 50# Underground tank
T2b Diesel 3PGII 50 42# Underground tank
T3a Diesel 3PGII 60 50# Underground tank
T3b Diesel 3PGII 50 42# Underground tank
T4a ULP95 3PGIII 40 30* Underground tank
T4b ULP91 3PGIII 40 30* Underground tank
T4c E10 3PGIII 30 22* Underground tank
T5a ULP95 3PGIII 60 44* Underground tank
T5b Diesel 3PGII 50 42# Underground tank
# Specific gravity used was 0.84. *Specific gravity used was 0.737 As petrol and diesel belong to Class 3 Flammable liquids stored in the same general location, the
quantities are normally assessed as a whole. In this instance, since each tank compartment has
separate isolation valve the quantities can be treated separately. The greatest mass of fuel is
stored in tank compartments T2a and T3a and since each compartment has an isolation valve, the
screen will be conducted using the mass of diesel found in compartment T2a. As the diesel is to be
stored underground, the total mass is divided by 5 and multiplied by 0.95 to reflect 95% safe filling
limit ((50/5)0.95 = 9.5 Tonnes) for screening purposes.
The critical locations within the service station in terms of screening for diesel and petrol are the
location of the dispenser/pump positions and the tank fill points with respect to the site boundary.
The shortest distance to a site boundary is 20m between a fuel dispenser (diesel) and the
boundary (southern side). The fill point is approximately 40m from the closest boundary (southern
side). Undeveloped bushland adjoins on the southern and western boundaries. Reservoir Road
adjoins the eastern boundary and The Great Western Highway the northern boundary. Commercial
properties are located to the east beyond Reservoir Road and to the north beyond The Great
Western Highway.
The guidelines specify that for class 3PGII and 3PGIII chemicals (e.g. petrol and diesel), Figure 9
in the guidelines is to be used for screening purposes (Dept. Planning 1993).
Considering a total effective mass of 9.5 tonnes and a minimum distance of 20m from the adjoining
property, the proposal is not considered potentially hazardous for surrounding sensitive or
commercial uses.
117878 - l01 - huntingwood sepp33 3
Finally in consideration of the transportation issues, the number of vehicle movements were
considered against the transportation screening thresholds (Table 2 in the guidelines). The
expected deliveries of 3 per week are below the number required to trigger SEPP33.
Conclusions
A preliminary SEPP33 screen was carried out to assess the proposed service station development
at 6 Honeman Close, Huntingwood, NSW. The proposed service station was found to be non
hazardous for surrounding residential and commercial industrial uses as defined under SEPP33.
As the service station is bounded by roads to the north and east and the nearest adjoining property
to the diesel tank fill points and fuel dispensers is at least 20 m, the proposed service station is
considered non-hazardous and so will not be subject to SEPP33.
Should you have any queries regarding this report, please contact undersigned on
(02) 8252 0442.
Regards,
Meinhardt Infrastructure & Environment Pty Ltd
Dr. Santo Ragusa
Senior Associate Environment
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification and Risk Assessment Report - Fuel Based Activities Page 32 of 39
9. Appendix A - Legislation
The design, construction, operation and supply of Hazardous Chemicals to service stations in New
South Wales shall comply with, but not be limited to, the latest edition of the following legislation,
regulations, standards and codes.
New South Wales Occupational Health and Safety Regulation 2000
New South Wales Occupational Health and Safety Amendment (Dangerous Goods) Act
2003
New South Wales EPA – Protection of the Environment Operations Act
Australian Dangerous Goods Code 7th edition.
National Construction Code.
AS1692-2006 Tanks for flammable and combustible liquids.
AS1940-2004 The storage and handling of flammable and combustible liquids.
AS4897-2008 Design Installation and Operation of Underground Petroleum Storage Systems.
AS4977-2008 Petroleum Products - Pipeline, road tanker compartment and underground
tank identification.
AS/NZS60079.10.1-2009 Explosive atmospheres - Classification of areas - Explosive gas
atmospheres (IEC 60079-10-1, Ed.1.0(2008) MOD).
AS/NZS1841.5-2007 Portable fire extinguishers - Specific requirements for powder type
extinguishers.
AS2444-2001 Portable Fire Extinguishers and fire blankets
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 33 of 39
10. Appendix B - Proposed Site Plan
Refer to Proposed Site plan drawings attached
ISSUE
D FOR
scale
date
drawn
checked
job no.
dwg no.
issue
project description
drawing title
client
acn: 111 372 064 abn: 43 111 372 064
project address
DO NOT SCALE
Membership No. 563QBCC Lic. No. 1272165
COPYRIGHT © 2016
building designers'association of
queensland inc.
FULL SIZE @ A1
DEVE
LOPM
ENT A
PPRO
VAL
Studio 24/115 Wickham Street,PO Box 724,Fortitude Valley, QLD 4006T: 1800 616 760E: [email protected]: www.cadway.com.au
@ A1
9/06/2017 12:34:43 PM
C:\Users\jcroft\Documents\[email protected]
B
BP HUNTINGWOODSERVICE STATION
GREAT WESTERN HIGHWAY,HUNTINGWOOD,NSW, 2148
JOHN AND ANNAARCIDIACONO
PERSPECTIVES - SHEET 1
05/24/17
AC
JC
11034
11034 SK018
ISS
DATE
AMEN
DMEN
TCK
DA
02.06
.17IS
SUE
FOR
DA A
PPRO
VAL
JCB
09.06
.17IS
SUE
FOR
CLIE
NT A
PPRO
VAL
JC
@ A12 SERVICE STATION SITE ENTRY PERSPECTIVE
@ A11
INTERSECTION RESERVOIR ROAD AND GREAT WESTERN HIGHWAYPERSPECTIVE
CAR
CANO
PYSERVICESTATION
TRUC
K CA
NOPY
CAR WASH
ENTR
Y
475m²
MIDSIGN
CAR PARK(7)
136° 21' 00"29.64 m
112° 35' 15"121.52 m
BIN
STOR
E/PL
ANT
AREA
DUAL FILLPOINT
5x110KL TANK FARM
CAR
PARK
(11)
LANDSCAPING
FUEL VENTS
LANDSCAPING
DELIV
ERY
(REF
ER D
RAW
ING
1103
4-SK
014)
(REF
ER D
RAW
ING
1103
4-SK
014)
LINE OF ESTIMATED RMS ROAD RESUMPTION (TO BE CONFIRMED WITH RMS)
(REFER DRAWING11034-SK013)(REFER DRAWING 11034-SK014)
PROP
OSED
BOU
NDAR
Y
WEIGHBRIDGE
LANDSCAPING
LANDSCAPING
MID SIGN
SERVICE STATION ENTRY
SERVICE STATIONTRUCK EGRESS
SERVICE STATION CAR
ENTRY/EGRESS
AIR/WATER
PROPOSED BOUNDARY
CAR PARK(9)
SIGN
ISSUE
D FOR
scale
date
drawn
checked
job no.
dwg no.
issue
project description
drawing title
client
acn: 111 372 064 abn: 43 111 372 064
project address
DO NOT SCALE
Membership No. 563QBCC Lic. No. 1272165
COPYRIGHT © 2016
building designers'association of
queensland inc.
FULL SIZE @ A1
DEVE
LOPM
ENT A
PPRO
VAL
Studio 24/115 Wickham Street,PO Box 724,Fortitude Valley, QLD 4006T: 1800 616 760E: [email protected]: www.cadway.com.au
1 : 200 @ A1
9/06/2017 12:40:35 PM
C:\Users\jcroft\Documents\[email protected]
C
BP HUNTINGWOODSERVICE STATION
GREAT WESTERN HIGHWAY,HUNTINGWOOD,NSW, 2148
JOHN AND ANNAARCIDIACONO
STAGE 1 SITE PLAN
05/24/17
AC
JC
11034
11034 SK012 1 : 200 @ A11 CONCEPT MASTER PLAN
0 10m 20m1:200
ISS
DATE
AMEN
DMEN
TCK
DA
02.06
.17IS
SUE
FOR
DA A
PPRO
VAL
JCB
06.06
.17FL
OOR
PLAN
DET
AILS
JCC
09.06
.17IS
SUE
FOR
CLIE
NT A
PPRO
VAL
JC
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 34 of 39
11. Appendix C - Safety Data Sheets
Refer to Company Safety Data sheets attached
Material Safety Data Sheet
1 . Identification of the material and supplier
AdBlueProduct name
0000003947SDS no.
Product use Reactant for reducing NOx-emissions.
BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616
Technical Helpline Number: 1300 139 700www.bp.com.au
Supplier
1800 638 556EMERGENCY TELEPHONE NUMBER
Product code 0000003947
Hazards identification2 .
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.Statement of hazardous/dangerous nature
Composition/information on ingredients3 .
Water and Urea (31.8 - 33.2%)
This product does not contain any hazardous ingredients at or above regulated thresholds.
Skin contact
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses.Get medical attention if irritation occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation develops.
4 .
If inhaled, remove to fresh air. Get medical attention if symptoms appear. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Inhalation
Eye contact
First-aid measures
Ingestion Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Advice to doctor Treatment should in general be symptomatic and directed to relieving any effects.
Fire-fighting measures5 .
No action shall be taken involving any personal risk or without suitable training. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
Special fire-fighting procedures
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Protection of fire-fighters
Unusual fire/explosion hazards
In a fire or if heated, a pressure increase will occur and the container may burst.
Hazardous decomposition products
Combustion products may include the following: carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)nitrogen oxides
Extinguishing media
Suitable In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.
Do not use water jet.Not suitable
Date of issue 16 September 2013
Page: 1/5AdBlueProduct name Product code
Version 1 Format LanguageAustralia
0000003947
ENGLISH
(ENGLISH)(Australia)
6 . Accidental release measures
Environmental precautions
Personal precautions
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses,basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Put on appropriate personal protective equipment (see Section 8).
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,soil or air).
Large spill
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
Handling
Handling and storage
Storage
7 .
Put on appropriate personal protective equipment.
Store and use only in equipment/containers designed for use with this product. Keep away from heat and direct sunlight. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Store in accordance with local regulations. Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10).
Not suitable Prolonged exposure to elevated temperature.
8 . Exposure controls/personal protection
Occupational exposure limits No exposure standard allocated.
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits.
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.
The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.
Occupational exposure controls
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Biological Limit Values No biological limit allocated.
Personal protective equipment
Respiratory protective equipment is not normally required where there is adequate natural or local exhaust ventilation to control exposure.In case of insufficient ventilation, wear suitable respiratory equipment.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.
Respiratory protection
Use of protective clothing is good industrial practice.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.
Skin and body
Wear protective gloves if prolonged or repeated contact is likely.
The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.
Hand protection
Safety glasses with side shields.Eye protection
Exposure controls
Date of issue 16 September 2013
Page: 2/5AdBlueProduct name Product code
Version 1 Format LanguageAustralia
0000003947
ENGLISH
(ENGLISH)(Australia)
Physical and chemical properties9 .
Colour Clear. Colourless.
Physical state Liquid.
Odour Ammoniacal. [Slight]
Not available.Boiling point / range
Not available.Melting point / range
1094 kg/m³ (1.094 g/cm³) at 20°CDensity
Vapour density Not available.
Not available.Vapour pressure
Solubility Soluble in water.
<1Partition coefficient (LogKow)
pH 9.5
Relative density/Specific gravity
Not available.
Stability and reactivity10 .
The product is stable.Stability
Conditions to avoid Avoid contamination by any source including metals, dust and organic materials.
Incompatibility with various substances/Hazardous Reactions
No hazardous reactions identified.
Combustion products may include the following: carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)nitrogen oxides
Hazardous decomposition products
Toxicological information11 .Eyes No significant health hazards identified.
No significant health hazards identified.Skin
Inhalation No significant health hazards identified.
Ingestion of large quantities may cause nausea and diarrhoea.Ingestion
Other chronic toxicity data Overexposure to the inhalation of airborne droplets or aerosols may cause irritation of the respiratory tract.
Mutagenic effects No known significant effects or critical hazards.
No component of this product at levels greater than or equal to 0.1% is identified as a carcinogen by ACGIH, the International Agency for Research on Cancer (IARC), the European Commission (EC),or the National Occupational Health and Safety Commission (Australia).
Carcinogenic effects
Acute toxicity Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to dermatitis.
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its low volatility. May be harmful by inhalation if exposure to vapour, mists or fumes resulting from thermal decomposition products occurs.
Chronic toxicity
Ecological information
Ecotoxicity
12 .
Not classified as environmentally hazardous in accordance with the ‘Approved Criteria for Classifying Hazardous Substances’ [NOHSC (1008)/2004 as amended and adapted].
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient nameAdBlue <1 - low
Biodegradability
Persistence/degradability Expected to be biodegradable.
Mobility
Bioaccumulative potential
Soluble in water.
This product is not expected to bioaccumulate through food chains in the environment.
Date of issue 16 September 2013
Page: 3/5AdBlueProduct name Product code
Version 1 Format LanguageAustralia
0000003947
ENGLISH
(ENGLISH)(Australia)
Disposal considerations13 .
The generation of waste should be avoided or minimised wherever possible. Disposal of this product,solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way.Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal considerations /Waste information
No additional special precautions identified.Special Precautions for Landfill or Incineration
14 . Transport information
International transport regulations
Not classified as dangerous for transport (ADG, IMDG, ICAO/IATA).
No known special precautions required. See Section: "Handling and storage" for additional information.
Special precautions for user
Regulatory information15 .Standard Uniform Schedule of Medicine and Poisons
Not regulated.
ScheduleNo Listed Substance
Other regulations
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
Ingredient name
Control of Scheduled Carcinogenic Substances
Australia inventory (AICS)
Canada inventory
China inventory (IECSC)
Japan inventory (ENCS)
Korea inventory (KECI)
Philippines inventory (PICCS)
United States inventory (TSCA 8b)
REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.
Other information16 .
AMP = Acceptable Maximum PeakACGIH = American Conference of Governmental Industrial Hygienists, an agency that promulgates exposure standards.ADG = Australian Code for the Transport of Dangerous Goods by Road and RailADG Code = Australian Code for the Transport of Dangerous Goods by Road and RailCAS Number = Chemical Abstracts Service Registry NumberHAZCHEM Code = Emergency action code of numbers and letters which gives information to emergency services. Its use is required by the ADG Code for Dangerous Goods in bulk.ICAO = International Civil Aviation Organization.IATA = International Air Transport Association, the organization promulgating rules governing shipment of goods by air.IMDG = International Maritime Organization Rules, rules governing shipment of goods by water.IP 346 = A chemical screening assay for dermal toxicity. The European Commission has recommended that Method IP 346 be used as the basis for labelling certain lubricant oil base stocks for carcinogenicity. The EU Commission has stipulated that the classification as a carcinogen need not apply if it can be shown that the substance contains less than 3% DMSO extract as measured by IP 346. (See Note L, European Commission Directive 67/548/EEC as amended and adapted.)DMSO is a solvent.NOHSC = National Occupational Health & Safety Commission, AustraliaTWA = Time weighted averageSTEL = Short term exposure limitUN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods.
Key to abbreviations
History
Date of issue
Date of previous issue
Prepared by Product Stewardship
Notice to reader
16/09/2013.
No previous validation.
Date of issue 16 September 2013
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Version 1 Format LanguageAustralia
0000003947
ENGLISH
(ENGLISH)(Australia)
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from us.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken.
Date of issue 16 September 2013
Page: 5/5AdBlueProduct name Product code
Version 1 Format LanguageAustralia
0000003947
ENGLISH
(ENGLISH)(Australia)
Ultimate 98 petrol
SAFETY DATA SHEET
GHS product identifier
Section 1. Identification
Ultimate 98 petrol
Manufacturer
Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616
www.bp.com.au
Technical Helpline Number: 1300 139 700
1800 638 556EMERGENCY TELEPHONE NUMBER
Fuel for spark ignition engines. NOT for aviation use.For specific application advice see appropriate Technical Data Sheet or consult our company representative.
Use of the substance/mixture
0000002791Product code
0000002791SDS no.
Relevant identified uses of the substance or mixture and uses advised against
Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 1SKIN CORROSION/IRRITATION - Category 2GERM CELL MUTAGENICITY - Category 1BCARCINOGENICITY - Category 1BTOXIC TO REPRODUCTION (Fertility) - Category 2TOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
Signal word DANGER
Hazard statements H224 - Extremely flammable liquid and vapour.H315 - Causes skin irritation.H340 - May cause genetic defects.H350 - May cause cancer.H361 - Suspected of damaging fertility or the unborn child.H304 - May be fatal if swallowed and enters airways.H336 - May cause drowsiness or dizziness.
Hazard pictograms
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1%
General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.
Product name
Date of issue
Page: 1/15Ultimate 98 petrol
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.
P261 - Avoid breathing vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothingP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P240 - Ground/bond container and receiving equipment.P273 - Avoid release to the environment.
Response P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.P235 - Keep cool.P405 - Store locked up.
Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.
Other hazards which do not result in classification
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including leukaemia.
Supplemental label elements
Not applicable.
Section 3. Composition and ingredient information
Gasoline > 99 86290-81-5Contains:toluene < 20 108-88-3n-hexane < 5 110-54-3Benzene < 1 71-43-2tert-butyl methyl ether(MTBE) < 1 1634-04-42-methylpropan-2-ol < 1 75-65-0diisopropyl ether < 1 108-20-3Polycyclic aromatic hydrocarbons (PAHs) < 1 mixture
Ingredient name CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture
% (w/w)
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.
If inhaled, remove to fresh air. Get medical attention.
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Section 4. First aid measures
Eye contact
Inhalation
Description of necessary first aid measures
Product name
Date of issue
Page: 2/15Ultimate 98 petrol
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 4. First aid measures
Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.
Skin contact
Ingestion
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
Specific treatments No specific treatment.
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
See Section 11 for more detailed information on health effects and symptoms.
Section 5. Firefighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.
Extremely flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.
Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Special protective equipment for fire-fighters
In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Hazchem code 3YE
Product name
Date of issue
Page: 3/15Ultimate 98 petrol
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.
Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment. Collect spilled product by absorbing with specific floating absorbents. If possible, large spillages in open waters should be contained with floating barriers or other mechanical means.If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.
Large spill
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.
Small spill
Methods and material for containment and cleaning up
For non-emergency personnel
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Protective measures Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container.
Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Store and use away from heat, sparks, open flame
Precautions for safe handling
Product name
Date of issue
Page: 4/15Ultimate 98 petrol
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.
or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid exposure during pregnancy. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage.Never siphon by mouth.
Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hours. Issued/Revised:5/1996 TWA: 890 mg/m³ 8 hours. Issued/Revised:5/1996 STEL: 500 ppm 15 minutes. Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minutes. Issued/Revised: 5/1996
toluene Safe Work Australia (Australia). Absorbed through skin.
Section 8. Exposure controls and personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Product name
Date of issue
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Product code
Version 1 Format LanguageAustralia
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Section 8. Exposure controls and personal protection STEL: 574 mg/m³ 15 minutes. Issued/Revised: 8/2005 STEL: 150 ppm 15 minutes. Issued/Revised: 8/2005 TWA: 191 mg/m³ 8 hours. Issued/Revised:8/2005 TWA: 50 ppm 8 hours. Issued/Revised:8/2005
n-hexane Safe Work Australia (Australia). TWA: 72 mg/m³ 8 hours. Issued/Revised:11/2001 TWA: 20 ppm 8 hours. Issued/Revised:11/2001
Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hours.
Benzene Safe Work Australia (Australia). TWA: 3.2 mg/m³ 8 hours. Issued/Revised:4/2003 TWA: 1 ppm 8 hours. Issued/Revised:4/2003
tert-butyl methyl ether(MTBE) Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minutes. Issued/Revised: 4/2002 STEL: 75 ppm 15 minutes. Issued/Revised:4/2002 TWA: 92 mg/m³ 8 hours. Issued/Revised:4/2002 TWA: 25 ppm 8 hours. Issued/Revised:4/2002
2-methylpropan-2-ol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 150 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 100 ppm 8 hours. Issued/Revised:5/1995
diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 310 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 250 ppm 8 hours. Issued/Revised:5/1995
Appropriate engineering controls
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.
Product name
Date of issue
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0000002791
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Section 8. Exposure controls and personal protection
Hand protection Wear chemical resistant gloves.
Do not re-use gloves. Protective gloves must give suitable protection against mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use.
Recommended: splash gogglesEye/face protection
Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Skin protection
Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: nitrile rubber
Recommended: Gloves made from fluoroelastomer resistant to hydrocarbons and a wide range of chemicals.Wear a chemically resistant multi-layer laminate inner glove inside an outer nitrile glove. The purpose of the outer glove is to protect the inner glove from cuts and mechanical damage. The presence of aromatic hydrocarbons in the product will significantly shorten the length of time that nitrile gloves will provide protection. Do not re-use nitrile gloves if exposed to aromatic hydrocarbons.
Product name
Date of issue
Page: 7/15Ultimate 98 petrol
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(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 8. Exposure controls and personal protectionUse with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.Recommended: full-face mask
Respiratory protection
Recommended: Avoid breathing of vapours, mists or spray. Select and use respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist (Type P1) filters. Filter capacity and respirator type depends on exposure level.
Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337
Section 9. Physical and chemical properties
Physical state
Melting point
Vapour pressure
Relative density
Vapour density
Solubility
Not available.
Not available.
Hydrocarbon.Odour
pH
Pale Yellow.Colour
Evaporation rate Not available.
Auto-ignition temperature
Flash point
>350°C (>662°F)
Closed cup: <-40°C (<-40°F)
Not available.
Not available.
Viscosity
Not available.Odour threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point >30 to < 210°C (>86 to < 410°F)
Flammability (solid, gas)
Lower and upper explosive (flammable) limits
Lower: 1.4%Upper: 7.6%
Decomposition temperature Not available.
Liquid. Clear and Bright
Not applicable. Based on - Physical state
30 to 100 kPa (225 to 750 mm Hg)
750 kg/m³ (0.75 g/cm³)
insoluble in water.
Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C
Remarks Reid vapor pressure (RVP): 55 to 100 kPa (40 oC )
Not available.
Density
Product name
Date of issue
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Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Incompatible materials
Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.
Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.
Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Reactive or incompatible with the following materials: oxidising materials.
Section 11. Toxicological information
Information on likely routes of exposure
Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Ingestion
Skin contact Causes skin irritation.
No known significant effects or critical hazards.Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact Adverse symptoms may include the following:pain or irritationwateringredness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Gasoline Category 3 Not applicable. Narcotic effectstoluene Category 3 Not applicable. Narcotic effectsn-hexane Category 3 Not applicable. Narcotic effectsBenzene Category 3 Not applicable. Respiratory tract
irritation and Narcotic effects
tert-butyl methyl ether(MTBE) Category 3 Not applicable. Narcotic effectsdiisopropyl ether Category 3 Not applicable. Narcotic effects
Name Category
Name Category
toluene Category 2 Not determined hearing organsn-hexane Category 2 Inhalation peripheral nervous
systemBenzene Category 1 Not determined blood system
Aspiration hazard
Name Result
Gasoline ASPIRATION HAZARD - Category 1toluene ASPIRATION HAZARD - Category 1n-hexane ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Information on toxicological effects
Routes of entry anticipated: Dermal, Inhalation.
Potential acute health effects
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Section 11. Toxicological information
This product contains n-hexane. Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. Animal studies have also shown that n-hexane overexposure may cause testicular injury. However, animal studies conducted with commercial hexane, containing 53% n-hexane, showed neither peripheral nervous system damage nor testicular injury at inhalation exposures up to 9000 ppm. Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce serious central nervous system effects, including unconsciousness, and possibly death.
General
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity
May cause genetic defects.Mutagenicity
Suspected of damaging the unborn child.Teratogenicity
Developmental effects No known significant effects or critical hazards.
Fertility effects Suspected of damaging fertility.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:nausea or vomitingreduced foetal weightincrease in foetal deathsskeletal malformations
Adverse symptoms may include the following:irritationrednessreduced foetal weightincrease in foetal deathsskeletal malformations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Eye contact
Vapour, mist or fume may irritate the nose, mouth and respiratory tract.
If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.
Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Inhalation
Skin contact
Ingestion
Gasoline - Excess exposure to vapors may produce headaches, dizziness, nausea,drowsiness, irritation of eyes, nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.
In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause
Other information
Product name
Date of issue
Page: 10/15Ultimate 98 petrol
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Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 11. Toxicological informationthese kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects.Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard.The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.
Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.
Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.
Gasoline: Additional toxicity information on the components:
Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very high levels can result in unconsciousness and death.
Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic exposures to high levels of benzene have been reported to cause adverse blood effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however, exposure to higher dosage levels resulted in a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not altered in rats exposed to benzene at the same level. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.
Toluene: Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material. Deliberate inhalation of high concentrations of toluene has been linked to damage of the brain, liver and kidney. Inhalation of very high concentrations of toluene, such as in cases of solvent abuse, has resulted in sudden death which may be a result of cardiac arrhythmia or central nervous system depression. Mental and/or growth retardation has been reported in children of women who deliberately inhale toluene during pregnancy (usually at thousands of ppm). Foetal developmental toxicity was observed when pregnant rats were exposed to toluene at levels of 1500 ppm. Maternal toxicity was also observed at this concentration. Prolonged, high level exposure to toluene in laboratory animals
Product name
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0000002791
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Section 11. Toxicological informationhas resulted in hearing loss. Exposure studies in rats have resulted in adverse effects on the kidney, liver and central nervous system. Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired colour vision and decreased performance in some neurobehavioural tests.There are occupational studies which report an association between inhalation exposure to toluene and adverse effects on reproduction including spontaneous abortion. The methodology of these studies and the reliability of the results have been questioned. In a two-generation study in rats, inhalation of toluene at levels up to 2000 ppm did not produce adverse effects on fertility or reproductive performance.
Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapour becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.
Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations; however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.
Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations,but no malformations. Because of the high exposure levels used in these studies,we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.
Xylene and its isomers are not genotoxic.
Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.
Ethylbenzene - The National Toxicology Program (NTP) conducted a 13-week inhalation study with male and female rats and mice at exposure concentrations ranging from 100 to 1000 ppm ethylbenzene. No rats or mice died during the study.Kidney, liver, and lung weights were increased in the exposed rats, while weight increases were observed only in the livers of exposed mice. Treatment-related histopathologic changes were not observed in any tissues of rats and mice.NTP also exposed male and female rats and mice by inhalation to 0, 75, 250, or 750 ppm ethylbenzene for 2 years. There was a statistically significant increase in the number of kidney tumors in male and female rats at 750 ppm. There were also increased incidences of lung tumors in male mice and liver tumors in female mice that were statistically significant at 750 ppm. Except for the male rat kidney tumors,the incidence of the tumors were within the range observed for non-exposed animals from other studies conducted by NTP. The significance of these findings to humans is unknown. Ethylbenzene is not genotoxic. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and found it to be possibly carcinogenic to humans (Group 2B).
Ethylbenzene is not genotoxic.
Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits.Ingestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye
Product name
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Section 11. Toxicological informationirritation. Naphthalene exposure has been associated with cataracts in animals and humans.
Section 12. Ecological information
Mobility Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Gasoline - - Inherent
Persistence and degradability
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.
Expected to be biodegradable. Non-persistent per IMO criteria
Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods
Special Precautions for Landfill or Incineration
No additional special precautions identified.
Section 14. Transport information
MOTOR SPIRIT or GASOLINE or PETROLMARINE POLLUTANT
3
MOTOR SPIRIT or GASOLINE or PETROL
UN1203
3
UN1203
IMDG IATA
UN number
UN proper shipping name
Transport hazard class(es)
ADG
UN1203
MOTOR SPIRIT or GASOLINE or PETROL
3
Product name
Date of issue
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Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 14. Transport informationII II
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules (EmS)F-E; S-E
The environmentally hazardous substance mark may appear if required by other transportation regulations.
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of Marpol and the IBC Code
Yes. No.
Not available.
MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gasoline and spirits
Proper shipping name
II
No.
Hazchem code3YE
Initial emergency response guide14
Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
International lists
National inventory
REACH Status
Canada inventory
Australia inventory (AICS) Contact local supplier or distributor.
China inventory (IECSC) At least one component is not listed.
Japan inventory (ENCS) At least one component is not listed.
Korea inventory (KECI) At least one component is not listed.
Philippines inventory (PICCS)
At least one component is not listed.
For the REACH status of this product please consult your company contact, as identified in Section 1.
Taiwan Chemical Substances Inventory (TCSI)
Not determined.
Not scheduled When packed in containers having capacity of greater than 20 litres.
S5. When packed in containers having capacity of less than 20 litres. Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.
United States inventory (TSCA 8b)
Not determined.
Product name
Date of issue
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Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
Section 16. Any other relevant information
09/11/2016
History
Date of printing
Date of issue/Date of revision
Version
Prepared by
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2
09/11/2016
No previous validation
1
Procedure used to derive the classification
Classification Justification
Flam. Liq. 1, H224 Expert judgmentSkin Irrit. 2, H315 Expert judgmentMuta. 1B, H340 Expert judgmentCarc. 1B, H350 Expert judgmentRepr. 2, H361 (Fertility) Expert judgmentRepr. 2, H361 (Unborn child) Expert judgmentSTOT SE 3, H336 Expert judgmentAsp. Tox. 1, H304 Expert judgment
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.
Product Stewardship
Product name
Date of issue
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Product code
Version 1 Format LanguageAustralia
0000002791
(Australia)
09/11/2016
BP Ultimate Diesel
SAFETY DATA SHEET
GHS product identifier
Section 1. Identification
BP Ultimate Diesel
Manufacturer
Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616
www.bp.com.au
Technical Helpline Number: 1300 139 700
1800 638 556EMERGENCY TELEPHONE NUMBER
Fuel for compression ignition diesel engines.Use of the substance/mixture
0000002790Product code
0000002790SDS no.
Relevant identified uses of the substance or mixture and uses advised against
Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 4ACUTE TOXICITY (inhalation) - Category 4SKIN CORROSION/IRRITATION - Category 2CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bone marrow,liver and thymus) - Category 2ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
Signal word DANGER
Hazard statements H227 - Combustible liquid.H332 - Harmful if inhaled.H315 - Causes skin irritation.H351 - Suspected of causing cancer.H304 - May be fatal if swallowed and enters airways.H373 - May cause damage to organs through prolonged or repeated exposure.(bone marrow, liver, thymus)
Hazard pictograms
Precautionary statements
GHS label elements
General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.
Product name
Date of issue
Page: 1/13BP Ultimate Diesel
ENGLISH
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.
P260 - Do not breathe vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment.P273 -Avoid release to the environment.
Response P314 - Get medical attention if you feel unwell.P308 + P313 - IF exposed or concerned: Get medical attention.P304 + P340 + P312 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting.P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water.Take off contaminated clothing. Wash contaminated clothing before reuse.P332 + P313 - If skin irritation occurs: Get medical attention.
Storage P405 - Store locked up.P403 - Store in a well-ventilated place.P235 - Keep cool.
Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.
Other hazards which do not result in classification
This material may contain significant quantities of polycyclic aromatic hydrocarbons,some of which have been shown by experimental studies to induce skin cancer.Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency.See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data Sheet.
Supplemental label elements
Not applicable.
Section 3. Composition and ingredient information
Fuels, diesel > 95 68334-30-5Alkanes, C10-20-branched and linear 0 - 20 928771-01-1
Ingredient name CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture
% (w/w)
May also contain small quantities of proprietary performance additives. Contains small quantities of polycyclic aromatic hydrocarbons (PAHs).
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.
If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Get medical attention.
Section 4. First aid measures
Eye contact
Inhalation
Description of necessary first aid measures
Product name
Date of issue
Page: 2/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 4. First aid measures
Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.
Skin contact
Ingestion
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful with extensive subcutaneous necrosis.Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes.
Specific treatments No specific treatment.
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
See Section 11 for more detailed information on health effects and symptoms.
Section 5. Firefighting measures
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.
Combustible liquid. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.
In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.
Extinguishing media
Suitable extinguishing media
Unsuitable extinguishing media
Do not use water jet.
Product name
Date of issue
Page: 3/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 5. Firefighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.
Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Special protective equipment for fire-fighters
Special protective actions for fire-fighters
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.
Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment.Collect spilled product by absorbing with specific floating absorbents. If possible,large spillages in open waters should be contained with floating barriers or other mechanical means. If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.
Large spill
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.
Small spill
Methods and material for containment and cleaning up
For non-emergency personnel
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".
Product name
Date of issue
Page: 4/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
As a precaution, tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging)and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks). Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Avoid contact of spilt material and runoff with soil and surface waterways. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container.Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment.Use only non-sparking tools. Do not breathe vapour or mist. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not swallow. Aspiration hazard if swallowed.Can enter lungs and cause damage. Never siphon by mouth.
Precautions for safe handling
Fuels, diesel ACGIH TLV (United States). Absorbed through skin. TWA: 100 mg/m³, (measured as total hydrocarbons) 8 hours. Issued/Revised:1/2007 Form: Inhalable fraction and vapor
Section 8. Exposure controls and personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
Product name
Date of issue
Page: 5/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 8. Exposure controls and personal protection
Hand protection Wear chemical resistant gloves.
Protective gloves must give suitable protection against mechanical risks (i.e.abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis.The frequency of replacement will depend upon the circumstances of use.
Chemical splash goggles.Eye/face protection
Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Skin protection
Recommended: Nitrile gloves.
Product name
Date of issue
Page: 6/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 8. Exposure controls and personal protection
Use with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.
Respiratory protection
Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Recommended: If ventilation is inadequate, use respirator that will protect against organic vapour and dust/mist.
Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337
Section 9. Physical and chemical properties
Physical state
Melting point
Vapour pressure
Relative density
Vapour density
Solubility
Liquid.
Not available.
Not available.
MildOdour
pH
Clear and BrightColour
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >61.5°C (>142.7°F) [Pensky-Martens.]
Not available.
Not available.
Viscosity
Not available.Odour threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point 108 to 380°C (226.4 to 716°F)
Flammability (solid, gas)
Lower and upper explosive (flammable) limits
Lower: 0.5%Upper: 7.5%
Decomposition temperature Not available.
Not applicable. Based on - Physical state
0.1 kPa (0.755 mm Hg)
820 to 850 kg/m³ (0.82 to 0.85 g/cm³) at 15°C
Very slightly soluble in water
Kinematic: 2 to 4.5 mm2/s (2 to 4.5 cSt) at 40°C
0.83
Density
Product name
Date of issue
Page: 7/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Incompatible materials
Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.
Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.
Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Reactive or incompatible with the following materials: oxidising materials.
Section 11. Toxicological information
Acute toxicity
Fuels, diesel LC50 Inhalation Dusts and mists Rat 4.1 mg/l 4 hours LD50 Dermal Rabbit >4300 mg/kg -LD50 Dermal Rabbit >4300 mg/kg -LD50 Oral Rat 17900 mg/kg -LD50 Oral Rat 7600 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Fuels, diesel Positive - Dermal -Unspecified
Mouse - 2 years
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary Suspected of causing cancer.
Mutagenicity
Fuels, diesel OECD 471 Experiment: In vitro PositiveSubject: Non-mammalian species
Equivalent to OECD 476
Experiment: In vitro Negative
Subject: Mammalian-AnimalCell: Germ
not guideline Experiment: In vivo NegativeSubject: UnspecifiedCell: Somatic
Product/ingredient name Test Experiment Result
Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.
Irritation/Corrosion
Fuels, diesel Skin - Irritation Rabbit - - -Skin - Irritation Rabbit - - -Eyes - Non-irritating to the eyes.
Rabbit - - -
Eyes - Non-irritating to the eyes.
Rabbit - - -
Product/ingredient name Result Score Exposure Observation
Skin Causes skin irritation.
Sensitisation
Fuels, diesel skin Guinea pig Not sensitisingskin Guinea pig Not sensitising
Product/ingredient name Route of exposure
Species Result
Species
Information on toxicological effects
Product name
Date of issue
Page: 8/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 11. Toxicological informationReproductive toxicity
Product/ingredient name Maternal toxicity
Fertility Developmental toxin
Species
Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are not met.Fertility: Not classified. Based on available data, the classification criteria are not met.Effects on or via lactation: Not classified. Based on available data, the classification criteria are not met.
Dose Exposure
Fuels, diesel - - Negative Rat Dermal 20 days- - Negative Rat Dermal 10 days- - Negative Rat Dermal 10 days
Information on likely routes of exposure
Inhalation Harmful if inhaled.
Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Ingestion
Skin contact Causes skin irritation.
No known significant effects or critical hazards.Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:nausea or vomiting
Adverse symptoms may include the following:irritationredness
Eye contact Adverse symptoms may include the following:pain or irritationwateringredness
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Specific target organ toxicity (repeated exposure)
Name Category
Fuels, diesel Category 2 Not determined bone marrow, liver and thymus
Aspiration hazard
Name Result
Fuels, diesel ASPIRATION HAZARD - Category 1Alkanes, C10-20-branched and linear ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential acute health effects
Eye contact Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.
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Date of issue
Page: 9/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 11. Toxicological information
May cause damage to organs through prolonged or repeated exposure. Vapour,mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.
General
Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity
No known significant effects or critical hazards.Mutagenicity
No known significant effects or critical hazards.Teratogenicity
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Numerical measures of toxicity
Inhalation (dusts and mists) 2.211 mg/l
Route ATE value
Acute toxicity estimates
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer. Vapour, mist or fume may irritate the nose,mouth and respiratory tract.
If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.
As with all such products containing potentially harmful levels of polycyclic aromatic hydrocarbons, prolonged or repeated skin contact may eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Inhalation
Skin contact
Ingestion
Section 12. Ecological informationToxicity
Fuels, diesel EL50 >1000 mg/l Nominal Fresh water Micro-organism 40 hours NOELR 3.217 mg/l Nominal Fresh water
Micro-organism 40 hours
Acute EL50 22 mg/l Nominal Fresh water
Algae 72 hours
Acute EL50 210 mg/l Nominal Fresh water
Daphnia 48 hours
Acute EL50 68 mg/l Nominal Fresh water
Daphnia 48 hours
Acute ErL50 78 mg/l Nominal Fresh water
Algae 72 hours
Acute LL50 65 mg/l Nominal Fresh water
Fish 96 hours
Acute LL50 21 mg/l Nominal Fresh water
Fish 96 hours
Acute NOELR 10 mg/l Nominal Fresh water
Algae 72 hours
Acute NOELR 1 mg/l Nominal Fresh water
Algae 72 hours
Acute NOELR 46 mg/l Nominal Fresh water
Daphnia 48 hours
Chronic NOEL 0.083 mg/l Nominal Fresh water
Fish 14 days
Chronic NOELR 0.2 mg/l Nominal Fresh water
Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary Toxic to aquatic life with long lasting effects.
Product name
Date of issue
Page: 10/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 12. Ecological information
Mobility Spillages may penetrate the soil causing ground water contamination. This material may accumulate in sediments.
Bioaccumulative potential
Persistence and degradability
Fuels, diesel OECD 301 F 60 % - Readily - 28 days 30 mg/l -OECD 301 F 57.5 % - Not readily - 28 days 25 mg/l -Equivalent to EPA OTS 796.3100
35 % - Not readily - 28 days 5 mg/l -
Product/ingredient name Test DoseResult Inoculum
Conclusion/Summary Non-persistent per IMO criteria
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.
Partially biodegradable.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods
Special Precautions for Landfill or Incineration
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty packaging and should not be removed.
Section 14. Transport information
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)
UN3082UN3082
IMDG IATA
UN number
UN proper shipping name
ADG
Not regulated.
-
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Date of issue
Page: 11/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 14. Transport information9
III
9
III
This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
Emergency schedules (EmS)F-A, S-F
This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of Marpol and the IBC Code
Yes. Yes.
Not available.
MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gas oils, including ship's bunkers
Proper shipping name
-
-
No.
RemarksCombustible liquid Class C1 (AS 1940).
Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
International lists
National inventory
REACH Status
Canada inventory At least one component is not listed.
Australia inventory (AICS) Contact supplier for regulatory information.
China inventory (IECSC) Not determined.
Japan inventory (ENCS) At least one component is not listed.
Korea inventory (KECI) At least one component is not listed.
Philippines inventory (PICCS)
Not determined.
For the REACH status of this product please consult your company contact, as identified in Section 1.
Taiwan Chemical Substances Inventory (TCSI)
Not determined.
Not scheduled
Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.
United States inventory (TSCA 8b)
All components are listed or exempted.
Product name
Date of issue
Page: 12/13BP Ultimate Diesel
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Product code
Version 2 Format LanguageAustralia
0000002790
(Australia)
18/04/2016
Section 16. Any other relevant information
18/04/2016
History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2
18/04/2016
07/04/2016
2
Procedure used to derive the classification
Classification Justification
Flam. Liq. 4, H227 On basis of test dataAcute Tox. 4, H332 Calculation methodSkin Irrit. 2, H315 Calculation methodCarc. 2, H351 Calculation methodSTOT RE 2, H373 (bone marrow, liver and thymus) Calculation methodAsp. Tox. 1, H304 Calculation method
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.
Product Stewardship
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Date of issue
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0000002790
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18/04/2016
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SAFETY DATA SHEET
GHS product identifier
Section 1. Identification
Premium Unleaded 95
Manufacturer
Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616
www.bp.com.au
Technical Helpline Number: 1300 139 700
1800 638 556EMERGENCY TELEPHONE NUMBER
Fuel for spark ignition engines. NOT for aviation use.For specific application advice see appropriate Technical Data Sheet or consult our company representative.
Use of the substance/mixture
0000002734Product code
0000002734SDS no.
876Historic SDS no.
Relevant identified uses of the substance or mixture and uses advised against
Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 1SKIN CORROSION/IRRITATION - Category 2GERM CELL MUTAGENICITY - Category 1BCARCINOGENICITY - Category 1BTOXIC TO REPRODUCTION (Fertility) - Category 2TOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
Signal word DANGER
Hazard statements H224 - Extremely flammable liquid and vapour.H315 - Causes skin irritation.H340 - May cause genetic defects.H350 - May cause cancer.H361 - Suspected of damaging fertility or the unborn child.H304 - May be fatal if swallowed and enters airways.H336 - May cause drowsiness or dizziness.
Hazard pictograms
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1%
General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.
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Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.
P261 - Avoid breathing vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothingP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P240 - Ground/bond container and receiving equipment.P273 - Avoid release to the environment.
Response P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.P235 - Keep cool.P405 - Store locked up.
Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.
Other hazards which do not result in classification
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including leukaemia.
Supplemental label elements
Not applicable.
Section 3. Composition and ingredient information
Gasoline > 99 86290-81-5Contains:toluene < 20 108-88-3n-hexane < 5 110-54-3Benzene < 1 71-43-2tert-butyl methyl ether(MTBE) < 1 1634-04-42-methylpropan-2-ol < 1 75-65-0diisopropyl ether < 1 108-20-3Polycyclic aromatic hydrocarbons (PAHs) < 1 mixture
Ingredient name CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture
% (w/w)
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.
If inhaled, remove to fresh air. Get medical attention.
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Section 4. First aid measures
Eye contact
Inhalation
Description of necessary first aid measures
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Section 4. First aid measures
Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.
Skin contact
Ingestion
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
Specific treatments No specific treatment.
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
See Section 11 for more detailed information on health effects and symptoms.
Section 5. Firefighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.
Extremely flammable liquid and vapour. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.
Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Special protective equipment for fire-fighters
In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Hazchem code 3YE
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.
Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment. Collect spilled product by absorbing with specific floating absorbents. If possible, large spillages in open waters should be contained with floating barriers or other mechanical means.If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.
Large spill
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.
Small spill
Methods and material for containment and cleaning up
For non-emergency personnel
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Protective measures Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container.
Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Store and use away from heat, sparks, open flame
Precautions for safe handling
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Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.
or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid exposure during pregnancy. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage.Never siphon by mouth.
Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hours. Issued/Revised:5/1996 TWA: 890 mg/m³ 8 hours. Issued/Revised:5/1996 STEL: 500 ppm 15 minutes. Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minutes. Issued/Revised: 5/1996
toluene Safe Work Australia (Australia). Absorbed through skin.
Section 8. Exposure controls and personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls and personal protection STEL: 574 mg/m³ 15 minutes. Issued/Revised: 8/2005 STEL: 150 ppm 15 minutes. Issued/Revised: 8/2005 TWA: 191 mg/m³ 8 hours. Issued/Revised:8/2005 TWA: 50 ppm 8 hours. Issued/Revised:8/2005
n-hexane Safe Work Australia (Australia). TWA: 72 mg/m³ 8 hours. Issued/Revised:11/2001 TWA: 20 ppm 8 hours. Issued/Revised:11/2001
Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hours.
Benzene Safe Work Australia (Australia). TWA: 3.2 mg/m³ 8 hours. Issued/Revised:4/2003 TWA: 1 ppm 8 hours. Issued/Revised:4/2003
tert-butyl methyl ether(MTBE) Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minutes. Issued/Revised: 4/2002 STEL: 75 ppm 15 minutes. Issued/Revised:4/2002 TWA: 92 mg/m³ 8 hours. Issued/Revised:4/2002 TWA: 25 ppm 8 hours. Issued/Revised:4/2002
2-methylpropan-2-ol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 150 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 100 ppm 8 hours. Issued/Revised:5/1995
diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 310 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 250 ppm 8 hours. Issued/Revised:5/1995
Appropriate engineering controls
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.
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Section 8. Exposure controls and personal protection
Hand protection Wear chemical resistant gloves.
Do not re-use gloves. Protective gloves must give suitable protection against mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use.
Recommended: splash gogglesEye/face protection
Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Skin protection
Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: nitrile rubber
Recommended: Gloves made from fluoroelastomer resistant to hydrocarbons and a wide range of chemicals.Wear a chemically resistant multi-layer laminate inner glove inside an outer nitrile glove. The purpose of the outer glove is to protect the inner glove from cuts and mechanical damage. The presence of aromatic hydrocarbons in the product will significantly shorten the length of time that nitrile gloves will provide protection. Do not re-use nitrile gloves if exposed to aromatic hydrocarbons.
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Section 8. Exposure controls and personal protectionUse with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.Recommended: full-face mask
Respiratory protection
Recommended: Avoid breathing of vapours, mists or spray. Select and use respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist (Type P1) filters. Filter capacity and respirator type depends on exposure level.
Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337
Section 9. Physical and chemical properties
Physical state
Melting point
Vapour pressure
Relative density
Vapour density
Solubility
Not available.
Not available.
Hydrocarbon.Odour
pH
Pale Yellow.Colour
Evaporation rate Not available.
Auto-ignition temperature
Flash point
>350°C (>662°F)
Closed cup: <-40°C (<-40°F)
Not available.
Not available.
Viscosity
Not available.Odour threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point >30 to < 210°C (>86 to < 410°F)
Flammability (solid, gas)
Lower and upper explosive (flammable) limits
Lower: 1.4%Upper: 7.6%
Decomposition temperature Not available.
Liquid. Clear and Bright
Not applicable. Based on - Physical state
30 to 100 kPa (225 to 750 mm Hg)
750 kg/m³ (0.75 g/cm³)
insoluble in water.
Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C
Remarks Reid vapor pressure (RVP): 55 to 100 kPa (40 oC )
Not available.
Density
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Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Incompatible materials
Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.
Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.
Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Reactive or incompatible with the following materials: oxidising materials.
Section 11. Toxicological information
Information on likely routes of exposure
Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Ingestion
Skin contact Causes skin irritation.
No known significant effects or critical hazards.Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact Adverse symptoms may include the following:pain or irritationwateringredness
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Gasoline Category 3 Not applicable. Narcotic effectstoluene Category 3 Not applicable. Narcotic effectsn-hexane Category 3 Not applicable. Narcotic effectsBenzene Category 3 Not applicable. Respiratory tract
irritation and Narcotic effects
tert-butyl methyl ether(MTBE) Category 3 Not applicable. Narcotic effectsdiisopropyl ether Category 3 Not applicable. Narcotic effects
Name Category
Name Category
toluene Category 2 Not determined hearing organsn-hexane Category 2 Inhalation peripheral nervous
systemBenzene Category 1 Not determined blood system
Aspiration hazard
Name Result
Gasoline ASPIRATION HAZARD - Category 1toluene ASPIRATION HAZARD - Category 1n-hexane ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Information on toxicological effects
Routes of entry anticipated: Dermal, Inhalation.
Potential acute health effects
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Section 11. Toxicological information
This product contains n-hexane. Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. Animal studies have also shown that n-hexane overexposure may cause testicular injury. However, animal studies conducted with commercial hexane, containing 53% n-hexane, showed neither peripheral nervous system damage nor testicular injury at inhalation exposures up to 9000 ppm. Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce serious central nervous system effects, including unconsciousness, and possibly death.
General
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity
May cause genetic defects.Mutagenicity
Suspected of damaging the unborn child.Teratogenicity
Developmental effects No known significant effects or critical hazards.
Fertility effects Suspected of damaging fertility.
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:nausea or vomitingreduced foetal weightincrease in foetal deathsskeletal malformations
Adverse symptoms may include the following:irritationrednessreduced foetal weightincrease in foetal deathsskeletal malformations
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Eye contact
Vapour, mist or fume may irritate the nose, mouth and respiratory tract.
If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.
Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Inhalation
Skin contact
Ingestion
Gasoline - Excess exposure to vapors may produce headaches, dizziness, nausea,drowsiness, irritation of eyes, nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.
In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause
Other information
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Section 11. Toxicological informationthese kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects.Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard.The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.
Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.
Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.
Gasoline: Additional toxicity information on the components:
Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very high levels can result in unconsciousness and death.
Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic exposures to high levels of benzene have been reported to cause adverse blood effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however, exposure to higher dosage levels resulted in a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not altered in rats exposed to benzene at the same level. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.
Toluene: Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material. Deliberate inhalation of high concentrations of toluene has been linked to damage of the brain, liver and kidney. Inhalation of very high concentrations of toluene, such as in cases of solvent abuse, has resulted in sudden death which may be a result of cardiac arrhythmia or central nervous system depression. Mental and/or growth retardation has been reported in children of women who deliberately inhale toluene during pregnancy (usually at thousands of ppm). Foetal developmental toxicity was observed when pregnant rats were exposed to toluene at levels of 1500 ppm. Maternal toxicity was also observed at this concentration. Prolonged, high level exposure to toluene in laboratory animals
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Section 11. Toxicological informationhas resulted in hearing loss. Exposure studies in rats have resulted in adverse effects on the kidney, liver and central nervous system. Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired colour vision and decreased performance in some neurobehavioural tests.There are occupational studies which report an association between inhalation exposure to toluene and adverse effects on reproduction including spontaneous abortion. The methodology of these studies and the reliability of the results have been questioned. In a two-generation study in rats, inhalation of toluene at levels up to 2000 ppm did not produce adverse effects on fertility or reproductive performance.
Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapour becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.
Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations; however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.
Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations,but no malformations. Because of the high exposure levels used in these studies,we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.
Xylene and its isomers are not genotoxic.
Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.
Ethylbenzene - The National Toxicology Program (NTP) conducted a 13-week inhalation study with male and female rats and mice at exposure concentrations ranging from 100 to 1000 ppm ethylbenzene. No rats or mice died during the study.Kidney, liver, and lung weights were increased in the exposed rats, while weight increases were observed only in the livers of exposed mice. Treatment-related histopathologic changes were not observed in any tissues of rats and mice.NTP also exposed male and female rats and mice by inhalation to 0, 75, 250, or 750 ppm ethylbenzene for 2 years. There was a statistically significant increase in the number of kidney tumors in male and female rats at 750 ppm. There were also increased incidences of lung tumors in male mice and liver tumors in female mice that were statistically significant at 750 ppm. Except for the male rat kidney tumors,the incidence of the tumors were within the range observed for non-exposed animals from other studies conducted by NTP. The significance of these findings to humans is unknown. Ethylbenzene is not genotoxic. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and found it to be possibly carcinogenic to humans (Group 2B).
Ethylbenzene is not genotoxic.
Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits.Ingestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye
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Section 11. Toxicological informationirritation. Naphthalene exposure has been associated with cataracts in animals and humans.
Section 12. Ecological information
Mobility Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Gasoline - - Inherent
Persistence and degradability
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.
Expected to be biodegradable. Non-persistent per IMO criteria
Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods
Special Precautions for Landfill or Incineration
No additional special precautions identified.
Section 14. Transport information
MOTOR SPIRIT or GASOLINE or PETROLMARINE POLLUTANT
3
MOTOR SPIRIT or GASOLINE or PETROL
UN1203
3
UN1203
IMDG IATA
UN number
UN proper shipping name
Transport hazard class(es)
ADG
UN1203
MOTOR SPIRIT or GASOLINE or PETROL
3
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Section 14. Transport informationII II
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules (EmS)F-E; S-E
The environmentally hazardous substance mark may appear if required by other transportation regulations.
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of Marpol and the IBC Code
Yes. No.
Not available.
MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gasoline and spirits
Proper shipping name
II
No.
Hazchem code3YE
Initial emergency response guide14
Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
International lists
National inventory
REACH Status
Canada inventory At least one component is not listed.
Australia inventory (AICS) Contact local supplier or distributor.
China inventory (IECSC) At least one component is not listed.
Japan inventory (ENCS) At least one component is not listed.
Korea inventory (KECI) At least one component is not listed.
Philippines inventory (PICCS)
At least one component is not listed.
For the REACH status of this product please consult your company contact, as identified in Section 1.
Taiwan Chemical Substances Inventory (TCSI)
Not determined.
Not scheduled When packed in containers having capacity of greater than 20 litres.
S5. When packed in containers having capacity of less than 20 litres. Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.
United States inventory (TSCA 8b)
Not determined.
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Section 16. Any other relevant information
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History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2
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No previous validation
1
Procedure used to derive the classification
Classification Justification
Flam. Liq. 1, H224 Expert judgmentSkin Irrit. 2, H315 Expert judgmentMuta. 1B, H340 Expert judgmentCarc. 1B, H350 Expert judgmentRepr. 2, H361 (Fertility) Expert judgmentRepr. 2, H361 (Unborn child) Expert judgmentSTOT SE 3, H336 Expert judgmentAsp. Tox. 1, H304 Expert judgment
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.
Product Stewardship
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Unleaded 91
SAFETY DATA SHEET
GHS product identifier
Section 1. Identification
Unleaded 91
regular unleaded petrolOther means of identification
Manufacturer
Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616
www.bp.com.au
Technical Helpline Number: 1300 139 700
1800 638 556EMERGENCY TELEPHONE NUMBER
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning agent.For specific application advice see appropriate Technical Data Sheet or consult our company representative.
Use of the substance/mixture
0000002733Product code
0000002733SDS no.
875; 0000002889Historic SDS no.
Relevant identified uses of the substance or mixture and uses advised against
Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 1SKIN CORROSION/IRRITATION - Category 2GERM CELL MUTAGENICITY - Category 1BCARCINOGENICITY - Category 1BTOXIC TO REPRODUCTION (Unborn child) - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
Signal word DANGER
Hazard statements H224 - Extremely flammable liquid and vapour.H315 - Causes skin irritation.H340 - May cause genetic defects.H350 - May cause cancer.H361 - Suspected of damaging the unborn child.H304 - May be fatal if swallowed and enters airways.H336 - May cause drowsiness or dizziness.
Hazard pictograms
Precautionary statements
GHS label elements
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Section 2. Hazard(s) identification
Prevention P201 - Obtain special instructions before use.P261 - Avoid breathing vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothingP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P240 - Ground/bond container and receiving equipment.P273 - Avoid release to the environment.
Response P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.P235 - Keep cool.P405 - Store locked up.
Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.
Other hazards which do not result in classification
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including leukaemia.
General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.
Supplemental label elements
Not applicable.
Section 3. Composition and ingredient information
Gasoline >90 86290-81-5Contains:Benzene <1 71-43-2tert-butyl methyl ether(MTBE) <1 1634-04-42-methylpropan-2-ol <1 75-65-0diisopropyl ether <1 108-20-3Polycyclic aromatic hydrocarbons (PAHs) <1 mixture
Ingredient name CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture
% (w/w)
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon numbers predominantly between C4 and C12. May contain oxygenates. May also contain small quantities of proprietary performance additives.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.
If inhaled, remove to fresh air. Get medical attention.
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Section 4. First aid measures
Eye contact
Inhalation
Description of necessary first aid measures
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Section 4. First aid measures
Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.
Skin contact
Ingestion
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
Specific treatments No specific treatment.
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
See Section 11 for more detailed information on health effects and symptoms.
Section 5. Firefighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.
Extremely flammable liquid and vapour. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Liquid will float and may reignite on surface of water.
Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Special protective equipment for fire-fighters
In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.
Extinguishing media
Do not use water jet.
Suitable extinguishing media
Unsuitable extinguishing media
Special protective actions for fire-fighters
Hazchem code 3YE
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use explosion-protected equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.
Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. In case of small spillages in closed waters (i.e. ports), contain product with floating barriers or other equipment.Collect spilled product by absorbing with specific floating absorbents. If possible,large spillages in open waters should be contained with floating barriers or other mechanical means. If this is not possible, control the spreading of the spillage, and collect the product by skimming or other suitable mechanical means. The use of dispersants should be advised by an expert, and, if required, approved by local authorities. Collect recovered product and other contaminated materials in suitable tanks or containers for recycle, recovery or safe disposal.
Large spill
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use explosion-protected equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.
Small spill
Methods and material for containment and cleaning up
For non-emergency personnel
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Protective measures Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container.
Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges. Avoid contact of spilt material and runoff with soil and surface waterways. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not
Precautions for safe handling
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Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is explosion-protected (i.e. will not produce sparks). Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.
in use. Do not reuse container. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid exposure during pregnancy. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage.Never siphon by mouth.
Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hours. Issued/Revised:5/1996 TWA: 890 mg/m³ 8 hours. Issued/Revised:5/1996 STEL: 500 ppm 15 minutes. Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minutes. Issued/Revised: 5/1996
Benzene Safe Work Australia (Australia).
Section 8. Exposure controls and personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls and personal protection TWA: 3.2 mg/m³ 8 hours. Issued/Revised:4/2003 TWA: 1 ppm 8 hours. Issued/Revised:4/2003
Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hours.
diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 310 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 250 ppm 8 hours. Issued/Revised:5/1995
2-methylpropan-2-ol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minutes. Issued/Revised: 5/1995 STEL: 150 ppm 15 minutes. Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hours. Issued/Revised:5/1995 TWA: 100 ppm 8 hours. Issued/Revised:5/1995
tert-butyl methyl ether(MTBE) Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minutes. Issued/Revised: 4/2002 STEL: 75 ppm 15 minutes. Issued/Revised:4/2002 TWA: 92 mg/m³ 8 hours. Issued/Revised:4/2002 TWA: 25 ppm 8 hours. Issued/Revised:4/2002
Recommended: splash gogglesEye/face protection
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
Appropriate engineering controls
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Skin protection
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Section 8. Exposure controls and personal protectionHand protection
Use with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.Recommended: full-face mask
Wear chemical resistant gloves.
Protective gloves must give suitable protection against mechanical risks (i.e.abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis.The frequency of replacement will depend upon the circumstances of use.
Respiratory protection
Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall
Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: nitrile rubber
Recommended: Gloves made from fluoroelastomer resistant to hydrocarbons and a wide range of chemicals.Wear a chemically resistant multi-layer laminate inner glove inside an outer nitrile glove. The purpose of the outer glove is to protect the inner glove from cuts and mechanical damage. The presence of aromatic hydrocarbons in the product will significantly shorten the length of time that nitrile gloves will provide protection. Do not re-use nitrile gloves if exposed to aromatic hydrocarbons.
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Product code
Version 3 Format LanguageAustralia
0000002733
(Australia)
01/09/2016
Section 8. Exposure controls and personal protectionRecommended: Avoid breathing of vapours, mists or spray. Select and use
respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist (Type P1) filters. Filter capacity and respirator type depends on exposure level.
Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337
Section 9. Physical and chemical properties
Physical state
Melting point
Vapour pressure
Relative density
Vapour density
Solubility
Not available.
Not available.
Hydrocarbon.Odour
pH
Pale Yellow. to Pale Red.Colour
Evaporation rate Not available.
Auto-ignition temperature
Flash point
>350°C (>662°F)
Closed cup: <-40°C (<-40°F)
Not available.
Not available.
Viscosity
Not available.Odour threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point >30 to 210°C (>86 to 410°F)
Flammability (solid, gas)
Lower and upper explosive (flammable) limits
Lower: 1.4%Upper: 7.6%
Decomposition temperature Not available.
Liquid. Clear and Bright
Not applicable. Based on - Physical state
30.1 to 100.3 kPa (225.6 to 752 mm Hg)
710 to 750 kg/m³ (0.71 to 0.75 g/cm³)
insoluble in water.
Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C
Remarks Reid vapor pressure (RVP): 55 to 100 kPa (40 oC )
Not available.
Density
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Incompatible materials
Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.
Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.
Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Reactive or incompatible with the following materials: oxidising materials.
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0000002733
(Australia)
01/09/2016
Section 11. Toxicological information
Acute toxicity
Gasoline LC50 Inhalation Vapour Rat >7630 mg/m³ Nominal
4 hours
LC50 Inhalation Vapour Rat >5610 mg/m³ analytical
4 hours
LD50 Dermal Rabbit >2000 mg/kg -LD50 Oral Rat >5000 mg/kg -
diisopropyl ether LC50 Inhalation Vapour Rat 40.5 mg/m³ 1 hoursLD50 Dermal Rabbit 2000 mg/kg -LD50 Oral Rat 8470 mg/kg -
2-methylpropan-2-ol LD50 Oral Rabbit 3559 mg/kg -LD50 Oral Rat 2743 mg/kg -
tert-butyl methyl ether(MTBE)
LC50 Inhalation Vapour Rat 85 mg/l 4 hours
LD50 Dermal Rat >2000 mg/kg -LD50 Oral Rat >2000 mg/kg -
Product/ingredient name Result Species Dose Exposure
Mutagenicity
Gasoline Equivalent to OECD 476
Experiment: In vitro Negative
Subject: Mammal - species unspecified
Equivalent to OECD 471
Experiment: In vitro Negative
Subject: Non-mammalian speciesEPA OPPTS 870.5395 Experiment: In vivo Negative
Subject: UnspecifiedCell: Germ
Equivalent to OECD 475
Experiment: In vivo Negative
Subject: UnspecifiedCell: Germ
tert-butyl methyl ether(MTBE)
EU B 13/14 Experiment: In vitro Negative
Subject: Non-mammalian speciesOECD 471 Experiment: In vitro Negative
Subject: Non-mammalian speciesOECD 476 Experiment: In vitro Negative
Subject: Non-mammalian speciesEquivalent to OECD 473
Experiment: In vitro Negative
Subject: Non-mammalian speciesEquivalent to OECD 486
Experiment: In vivo Negative
Subject: UnspecifiedCell: Somatic
Product/ingredient name Test Experiment Result
Irritation/Corrosion
Gasoline Skin - Irritant Rabbit - - -Eyes - Non-irritating to the eyes.
Rabbit - - -
tert-butyl methyl ether(MTBE)
Skin - Irritation Rabbit - - -
Eyes - Non-irritating to the eyes.
Rabbit - - -
Product/ingredient name Result Score Exposure Observation
Skin Causes skin irritation.
Species
Information on toxicological effects
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0000002733
(Australia)
01/09/2016
Section 11. Toxicological information
Carcinogenicity
Gasoline Negative - Inhalation -Unspecified
Rat - 113 weeks
Negative - Dermal -Unspecified
Mouse - 102 weeks
tert-butyl methyl ether(MTBE)
Positive - Inhalation -Unspecified
Rat - 2 years
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary May cause cancer
Equivalent to EPA OPPTS 870.5385
Experiment: In vivo Negative
Subject: UnspecifiedCell: Somatic
Equivalent to EPA OPPTS 798.5385
Experiment: In vivo Negative
Subject: UnspecifiedCell: Somatic
Conclusion/Summary May cause genetic defects.
Reproductive toxicity
Product/ingredient name Maternal toxicity
Fertility Developmental toxin
Species Dose Exposure
Gasoline - Negative - Rat Inhalation 2 generation
- - Negative Rat Inhalation 14 daystert-butyl methyl ether(MTBE)
- Negative - Rat Inhalation 2 generation
- - Negative Rat Inhalation 9 days
Information on likely routes of exposure
Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Skin contact Causes skin irritation.
No known significant effects or critical hazards.Eye contact
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Gasoline Category 3 Not applicable. Narcotic effectsBenzene Category 3 Not applicable. Respiratory tract
irritation and Narcotic effects
diisopropyl ether Category 3 Not applicable. Narcotic effectstert-butyl methyl ether(MTBE) Category 3 Not applicable. Narcotic effects
Name Category
Name Category
Benzene Category 1 Not determined blood system
Aspiration hazard
Name Result
Gasoline ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Route of exposure
Target organs
Routes of entry anticipated: Dermal, Inhalation.
Potential acute health effects
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0000002733
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Section 11. Toxicological informationIrritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Ingestion
Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce serious central nervous system effects, including unconsciousness, and possibly death.
General
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity
May cause genetic defects.Mutagenicity
Suspected of damaging the unborn child.Teratogenicity
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:nausea or vomitingreduced foetal weightincrease in foetal deathsskeletal malformations
Adverse symptoms may include the following:irritationrednessreduced foetal weightincrease in foetal deathsskeletal malformations
Eye contact Adverse symptoms may include the following:pain or irritationwateringredness
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Eye contact
Vapour, mist or fume may irritate the nose, mouth and respiratory tract.
If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.
Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.
Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Inhalation
Skin contact
Ingestion
Gasoline - Excess exposure to vapors may produce headaches, dizziness, nausea,drowsiness, irritation of eyes, nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.
In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related
Other information
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Version 3 Format LanguageAustralia
0000002733
(Australia)
01/09/2016
Section 11. Toxicological informationkidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause these kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects.Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard.The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.
Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.
Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.
Gasoline: Additional toxicity information on the components:
Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very high levels can result in unconsciousness and death.
Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic exposures to high levels of benzene have been reported to cause adverse blood effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however, exposure to higher dosage levels resulted in a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not altered in rats exposed to benzene at the same level. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.
Toluene: Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material. Deliberate inhalation of high concentrations of toluene has been linked to damage of the brain, liver and kidney. Inhalation of very high concentrations of toluene, such as in cases of solvent abuse, has resulted in sudden death which may be a result of cardiac arrhythmia or central nervous system depression. Mental and/or growth retardation has been reported in children
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Section 11. Toxicological informationof women who deliberately inhale toluene during pregnancy (usually at thousands of ppm). Foetal developmental toxicity was observed when pregnant rats were exposed to toluene at levels of 1500 ppm. Maternal toxicity was also observed at this concentration. Prolonged, high level exposure to toluene in laboratory animals has resulted in hearing loss. Exposure studies in rats have resulted in adverse effects on the kidney, liver and central nervous system. Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired colour vision and decreased performance in some neurobehavioural tests.There are occupational studies which report an association between inhalation exposure to toluene and adverse effects on reproduction including spontaneous abortion. The methodology of these studies and the reliability of the results have been questioned. In a two-generation study in rats, inhalation of toluene at levels up to 2000 ppm did not produce adverse effects on fertility or reproductive performance.
Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapour becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.
Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations; however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.
Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations,but no malformations. Because of the high exposure levels used in these studies,we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.
Xylene and its isomers are not genotoxic.
Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.
Ethylbenzene - The National Toxicology Program (NTP) conducted a 13-week inhalation study with male and female rats and mice at exposure concentrations ranging from 100 to 1000 ppm ethylbenzene. No rats or mice died during the study.Kidney, liver, and lung weights were increased in the exposed rats, while weight increases were observed only in the livers of exposed mice. Treatment-related histopathologic changes were not observed in any tissues of rats and mice.NTP also exposed male and female rats and mice by inhalation to 0, 75, 250, or 750 ppm ethylbenzene for 2 years. There was a statistically significant increase in the number of kidney tumors in male and female rats at 750 ppm. There were also increased incidences of lung tumors in male mice and liver tumors in female mice that were statistically significant at 750 ppm. Except for the male rat kidney tumors,the incidence of the tumors were within the range observed for non-exposed animals from other studies conducted by NTP. The significance of these findings to humans is unknown. Ethylbenzene is not genotoxic. The International Agency for Research on Cancer (IARC) has evaluated ethylbenzene and found it to be possibly carcinogenic to humans (Group 2B).
Ethylbenzene is not genotoxic.
Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits.
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0000002733
(Australia)
01/09/2016
Section 11. Toxicological informationIngestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye irritation. Naphthalene exposure has been associated with cataracts in animals and humans.
Section 12. Ecological informationToxicity
Gasoline Acute EC50 15.41 mg/l Nominal Fresh water
Micro-organism 40 hours
Acute EL50 3.1 mg/l Nominal Fresh water
Algae 72 hours
Acute EL50 3.7 mg/l Nominal Fresh water
Algae 96 hours
Acute EL50 4.5 mg/l Nominal Fresh water
Daphnia 48 hours
Acute LL50 10 mg/l Nominal Fresh water
Fish 96 hours
Acute LL50 8.2 mg/l Nominal Fresh water
Fish 96 hours
Acute NOELR 0.5 mg/l Nominal Fresh water
Algae 72 hours
Acute NOELR 0.5 mg/l Nominal Fresh water
Daphnia 48 hours
Chronic EL50 10 mg/l Nominal Fresh water
Daphnia 21 days
Chronic EL50 >40 mg/l Nominal Fresh water
Daphnia 21 days
Chronic EL50 10 mg/l Nominal Fresh water
Fish 21 days
Chronic LL50 5.2 mg/l Nominal Fresh water
Fish 14 days
Chronic NOELR 2.6 mg/l Nominal Fresh water
Daphnia 21 days
Chronic NOELR 16 mg/l Nominal Fresh water
Daphnia 21 days
Chronic NOELR 2.6 mg/l Nominal Fresh water
Fish 14 days
Chronic NOELR 2.6 mg/l Nominal Fresh water
Fish 21 days
Chronic PNEC >0.4 mg/kg soil, plants -tert-butyl methyl ether(MTBE) Acute EC50 472 mg/l Fresh water Daphnia 48 hours
Acute LC50 200 mg/l Marine water Crustaceans 96 hours Acute LC50 672 mg/l Fresh water Fish 96 hours Acute LC50 574 mg/l Marine water Fish 96 hours Chronic NOEC 26 mg/l Marine water Crustaceans 28 days Chronic NOEC 51 mg/l Fresh water Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary Toxic to aquatic life with long lasting effects.
Persistence and degradability
Product/ingredient name Test DoseResult Inoculum
Expected to be biodegradable. Non-persistent per IMO criteria
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0000002733
(Australia)
01/09/2016
Section 12. Ecological information
Mobility Spillages may penetrate the soil causing ground water contamination.
LogPow BCF Potential
Bioaccumulative potential
Product/ingredient name
Gasoline 2 to 7 - highBenzene 2.13 11 lowdiisopropyl ether 2.4 - low2-methylpropan-2-ol 0.317 - lowtert-butyl methyl ether(MTBE) 1.04 - low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Gasoline - - Inherent
tert-butyl methyl ether(MTBE) not guideline 100 % - 1.25 days - -Modelled data 61 to 69 % - 151 days - -OECD 301 D 9.24 % - Not readily - 28 days - -OECD 301 D 1.8 % - Not readily - 28 days - -OECD 301 D 0 % - Not readily - 28 days - -Modelled data 0 % - 250 days - -
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods
Special Precautions for Landfill or Incineration
No additional special precautions identified.
Section 14. Transport information
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Version 3 Format LanguageAustralia
0000002733
(Australia)
01/09/2016
Section 14. Transport information
MOTOR SPIRIT or GASOLINE or PETROLMARINE POLLUTANT
3
II
MOTOR SPIRIT or GASOLINE or PETROL
UN1203
3
II
UN1203
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules (EmS)F-E,S-E
The environmentally hazardous substance mark may appear if required by other transportation regulations.
IMDG IATA
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of Marpol and the IBC Code
Yes. No.
Not available.
MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gasoline and spirits
Proper shipping name
ADG
UN1203
MOTOR SPIRIT or GASOLINE or PETROL
3
II
No.
Hazchem code3YE
Initial emergency response guide14
Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons
Model Work Health and Safety Regulations - Scheduled Substances
Ingredient name Schedule
No listed substance -
International lists
National inventory
REACH Status
Canada inventory At least one component is not listed.
Australia inventory (AICS) Contact local supplier or distributor.
China inventory (IECSC) At least one component is not listed.
Japan inventory (ENCS) At least one component is not listed.
Korea inventory (KECI) At least one component is not listed.
For the REACH status of this product please consult your company contact, as identified in Section 1.
Not scheduled. When packed in containers having capacity of greater than 20 litres.
S5. When packed in containers having capacity of less than 20 litres.
Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.
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Version 3 Format LanguageAustralia
0000002733
(Australia)
01/09/2016
Section 15. Regulatory informationPhilippines inventory (PICCS)
At least one component is not listed.
Taiwan Chemical Substances Inventory (TCSI)
Not determined.
United States inventory (TSCA 8b)
Not determined.
Section 16. Any other relevant information
01/09/2016
History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2
01/09/2016
29/06/2016
3
Procedure used to derive the classification
Classification Justification
Flam. Liq. 1, H224 Expert judgmentSkin Irrit. 2, H315 Expert judgmentMuta. 1B, H340 Expert judgmentCarc. 1B, H350 Expert judgmentRepr. 2, H361 (Unborn child) Expert judgmentSTOT SE 3, H336 Expert judgmentAsp. Tox. 1, H304 Expert judgment
Product Stewardship
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Version 3 Format LanguageAustralia
0000002733
(Australia)
01/09/2016
Section 16. Any other relevant informationAll reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.
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Product code
Version 3 Format LanguageAustralia
0000002733
(Australia)
01/09/2016
Material Safety Data Sheet
1 . Identification of the material and supplier
BP Unleaded 91 with up to 10% EthanolProduct name
E10, E10MSynonyms
0000002889SDS no.
Product use Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning agent.
BP Australia Pty Ltd (ABN 53 004 085 616)717 Bourke StreetDocklands VIC 3008Australia Tel: +61 (03) 9268 4111Fax: +61 (03) 9268 3321
Supplier
1800 638 556EMERGENCY TELEPHONE NUMBER
Product code 0000002889
Hazards identification2 .
HAZARDOUS SUBSTANCE. DANGEROUS GOODS.Statement of hazardous/dangerous nature
R12- Extremely flammable.R45- May cause cancer.R46- May cause heritable genetic damage.R63- Possible risk of harm to the unborn child.R65- Also harmful: may cause lung damage if swallowed.R38- Irritating to skin.R67- Vapours may cause drowsiness and dizziness.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Risk phrases
S2- Keep out of the reach of children.S16- Keep away from sources of ignition - No smoking.S23- Do not breathe gas/fumes/vapour/spray.S24- Avoid contact with skin.S29- Do not empty into drains.S36/37- Wear suitable protective clothing and gloves.S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).S61- Avoid release to the environment. Refer to special instructions/safety data sheet.S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Safety phrases
Composition/information on ingredients3 .
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon numbers predominantly between C4 and C12. May contain oxygenates. May also contain small quantities of proprietary performance additives.
Gasoline 86290-81-5 > 90Ethanol 64-17-5 < 10
Contains:Toluene 108-88-3 5 - 15Benzene 71-43-2 < 1tert-butyl alcohol 75-65-0 < 1tert-butyl methyl ether 1634-04-4 < 1diisopropyl ether 108-20-3 < 1Polycyclic aromatic hydrocarbons (PAHs) mixture < 1
Ingredient name CAS no. %
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Skin contact
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse.Get medical attention immediately.
4 .
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Inhalation
Eye contact
First-aid measures
Ingestion If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention.
Advice to doctor Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment.Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
Fire-fighting measures5 .
DO NOT FIGHT FIRE WHEN IT REACHES MATERIAL. Withdraw from fire and let it burn. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move people out of line-of-sight of the scene and away from windows.
Special fire-fighting procedures
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Protection of fire-fighters
Unusual fire/explosion hazards
Extremely flammable liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard.
Hazchem code 3YE
Hazardous decomposition products
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Extinguishing media
Suitable In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.
Do not use water jet.Not suitable
6 . Accidental release measures
Environmental precautions
Personal precautions
Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area.Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Large spill
Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Small spill
Handling
Handling and storage
Storage
7 .
Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not ingest. If ingested, do not induce vomiting. Avoid contact with skin and clothing. Use only with adequate ventilation. Do not breathe vapour or mist. Keep away from heat, sparks and flame. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Avoid contact of spilt material and runoff with soil and surface waterways. Wash thoroughly after handling.
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Store and use only in equipment/containers designed for use with this product. Do not remove warning labels from containers.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an oxygen concentration of at least 20% volume.
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Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use.
This product must be handled in compliance with Australian Standard: The storage and handling of flammable and combustible liquids [Standard 1940-2004 as amended and adapted].
Additional information-Storage
8 . Exposure controls/personal protection
Ingredient name Occupational exposure limits
Ethanol Safe Work Australia (Australia). TWA: 1880 mg/m³ 8 hour(s). Issued/Revised: 5/1995 TWA: 1000 ppm 8 hour(s). Issued/Revised: 5/1995
Benzene Safe Work Australia (Australia). TWA: 3.2 mg/m³ 8 hour(s). Issued/Revised: 4/2003 TWA: 1 ppm 8 hour(s). Issued/Revised: 4/2003
Toluene Safe Work Australia (Australia). Absorbed through skin. STEL: 574 mg/m³ 15 minute(s). Issued/Revised: 8/2005 STEL: 150 ppm 15 minute(s). Issued/Revised: 8/2005 TWA: 191 mg/m³ 8 hour(s). Issued/Revised: 8/2005 TWA: 50 ppm 8 hour(s). Issued/Revised: 8/2005
tert-butyl alcohol Safe Work Australia (Australia). STEL: 455 mg/m³ 15 minute(s). Issued/Revised: 5/1995 STEL: 150 ppm 15 minute(s). Issued/Revised: 5/1995 TWA: 303 mg/m³ 8 hour(s). Issued/Revised: 5/1995 TWA: 100 ppm 8 hour(s). Issued/Revised: 5/1995
tert-butyl methyl ether Safe Work Australia (Australia). STEL: 275 mg/m³ 15 minute(s). Issued/Revised: 4/2002 STEL: 75 ppm 15 minute(s). Issued/Revised: 4/2002 TWA: 92 mg/m³ 8 hour(s). Issued/Revised: 4/2002 TWA: 25 ppm 8 hour(s). Issued/Revised: 4/2002
diisopropyl ether Safe Work Australia (Australia). STEL: 1300 mg/m³ 15 minute(s). Issued/Revised: 5/1995 STEL: 310 ppm 15 minute(s). Issued/Revised: 5/1995 TWA: 1040 mg/m³ 8 hour(s). Issued/Revised: 5/1995 TWA: 250 ppm 8 hour(s). Issued/Revised: 5/1995
Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia). TWA: 0.2 mg/m³ 8 hour(s).
Gasoline ACGIH TLV (United States). TWA: 300 ppm 8 hour(s). Issued/Revised: 5/1996 TWA: 890 mg/m³ 8 hour(s). Issued/Revised: 5/1996 STEL: 500 ppm 15 minute(s). Issued/Revised: 5/1996 STEL: 1480 mg/m³ 15 minute(s). Issued/Revised: 5/1996
For information and guidance, the ACGIH values are included. For further information on these please consult your supplier.
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits.Ensure that eyewash stations and safety showers are close to the workstation location.All chemicals should be assessed for their risks to health and appropriate control measures put in place to prevent or adequately control exposure. A hierarchy of control measures exists (e.g.elimination, substitution, general ventilation, containment, systems of work, changing the process or activity) that must be considered before use of personal protective equipment. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible. The above information is provided to
Occupational exposure controls
Biological Limit Values Benzene :S-Phenylmercapturic acid in urine - End of shift: 25 µg/g creatinine (ACGIH)t,t-Muconic acid in urine - End of shift: 500 µg/g creatinine (ACGIH)
Polycyclic aromatic hydrocarbons (PAHs): 1-Hydroxypyrene (1-HP) in urine (with hydrolysis) - End of shift at end of workweek: Nonquantitative (ACGIH)ACGIH “Nonquantitative” Biological Exposure Indices (BEI®): Biological monitoring should be considered for this compound based on the review; however, a specific BEI® could not be determined due to insufficient data.
Whilst specific OELs for certain components are included in this SDS, it should be noted that other components of the preparation will be present in any mist, vapour or dust produced. For this reason, the specific OELs may not be applicable to the product and are provided for guidance purposes.
Exposure controls
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assist the customer in conducting its own assessment of risk to the health and safety of workers for the substance or preparation, and protection of the environment.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.
Hygiene measures
Personal protective equipment
Use only with adequate ventilation. Avoid breathing of vapours, mists or spray. Select and use respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure standards then the use of the following is recommended: Approved respirator with organic vapour and dust/mist filters. Filter capacity and respirator type depends on exposure level.
Respiratory protection
Do not get on skin or clothing. Wear clothing and footwear that cannot be penetrated by chemicals or oil. Wear face shield.
Skin and body
Wear gloves that cannot be penetrated by chemicals or oil.
The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.
Hand protection
Safety glasses with side shields.Eye protection
Physical and chemical properties9 .
Auto-ignition temperature >350°C (>662°F)
Flash point <-40 °C (Closed cup) Pensky-Martens.
Colour Purple. or Red.
Physical state Liquid.
Odour Gasoline [Strong]
30 to 210°C (86 to 410°F)Boiling point / range
Not available.Melting point / range
750 kg/m³ (0.75 g/cm³)Density
Vapour density Not available.
Not available.Vapour pressure
Solubility insoluble in water.
pH Not available.
Relative density/Specific gravity
Not available.
Viscosity Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C
Stability and reactivity10 .
The product is stable.Stability
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Incompatibility with various substances/Hazardous Reactions
Reactive or incompatible with the following materials: oxidising materials.
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Hazardous decomposition products
Toxicological information11 .
Eyes Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Skin
Inhalation Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled. May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.Ingestion
Gasoline as a mixture is classified as a 2B (possible human) carcinogen by IARC.Gasoline engine exhaust is classified as possibly carcinogenic to humans by IARC (2B). This classification is based primarily on animal and in vitro studies of gasoline engine exhaust condensates/extracts. Studies of the gaseous exhaust stream in animals did not provided sufficient evidence for classification as a carcinogen.
Exposure to benzene may result in effects to the hematopoietic system causing blood disorders including anaemia and leukaemia.Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.IARC assessment: benzene - carcinogenic to humans (Group 1)
Carcinogenic effects
Effects and symptoms
Chronic toxicity
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Mutagenic effects Contains material which may cause heritable genetic effects. (Benzene)
Other information Contains material which may cause birth defects based on animal data. (Toluene)
Excess exposure to vapors may produce headaches, dizziness, nausea, drowsiness, irritation of eyes,nose and throat and central nervous system depression. Aspiration of this material into the lungs can cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.
In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals cause these kidney effects only in the male rat. Further studies have discovered the means by which the physiology of the male rat uniquely predispose it to these effects. Consequently, the Risk Assessment Forum of the Environmental Protection Agency has recognized that these responses are not predictive of a human health hazard. The liver tumors that were increased in the high-dose female mice are likewise of questionable significance because of their high spontaneous occurrence even without chemical exposure and because the rate of their occurrence is accelerated by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g., phenobarbital).Thus, the significance of the mouse liver tumor response in terms of human health is questionable.
Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.
Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous system effects, including unconsciousness, and possibly death.
Gasoline: Additional toxicity information on components.
Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs.Studies in occupationally exposed individuals indicate that toluene exposure has been associated with impaired color vision and decreased performance in some neurobehavioral tests.Prolonged high level exposure to toluene or xylene has caused some degree of hearing loss in experimental animals.Inhalation of very high concentrations of gasoline vapors and some of its components can result in cardiac sensitization and irregular heartbeats, leading to potentially fatal changes in heart rhythms.Injection of adrenaline-like agents may enhance this effect.
Ecological information
Ecotoxicity
12 .
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Biodegradability
Persistence/degradability The biodegradability of this material has not been determined.
Mobility
Bioaccumulative potential
Spillages may penetrate the soil causing ground water contamination.
This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
Disposal considerations13 .
The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal considerations /Waste information
No additional special precautions identified.Special Precautions for Landfill or Incineration
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14 . Transport information
International transport regulations
ADG Classification
Regulatory information
UN number Proper shipping name Class PG* Additional information
UN 1203 PETROL 3 II Hazchem code3YE
Initial emergency response guide14
Label
IMDG Classification
UN 1203 Gasoline or Motor Spirit.Marine pollutant
3 II Emergency schedules (EmS)F-E, S-E
-II3Gasoline or Motor SpiritUN 1203IATA/ICAO Classification
PG* : Packing group
No known special precautions required. See Section: "Handling and storage" for additional information.
Special precautions for user
Regulatory information15 .Standard for the Uniform Scheduling of Medicines and Poisons
5
ScheduleBenzene Schedule: 2. when used as a
feedstock containing more than 50% of benzene by volume
Other regulations
All components are listed or exempted.
Not determined.
At least one component is not listed.
Not determined.
At least one component is not listed.
Not determined.
Not determined.
Ingredient name
Control of Scheduled Carcinogenic Substances
Australia inventory (AICS)
Canada inventory
China inventory (IECSC)
Japan inventory (ENCS)
Korea inventory (KECI)
Philippines inventory (PICCS)
United States inventory (TSCA 8b)
REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.
Other information16 .
AMP = Acceptable Maximum PeakACGIH = American Conference of Governmental Industrial Hygienists, an agency that promulgates exposure standards.ADG = Australian Code for the Transport of Dangerous Goods by Road and RailADG Code = Australian Code for the Transport of Dangerous Goods by Road and RailCAS Number = Chemical Abstracts Service Registry NumberHAZCHEM Code = Emergency action code of numbers and letters which gives information to emergency services. Its use is required by the ADG Code for Dangerous Goods in bulk.ICAO = International Civil Aviation Organization.IATA = International Air Transport Association, the organization promulgating rules governing shipment of goods by air.IMDG = International Maritime Organization Rules, rules governing shipment of goods by water.IP 346 = A chemical screening assay for dermal toxicity. The European Commission has recommended that Method IP 346 be used as the basis for labelling certain lubricant oil base stocks for carcinogenicity. The EU Commission has stipulated that the classification as a carcinogen need
Key to abbreviations
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not apply if it can be shown that the substance contains less than 3% DMSO extract as measured by IP 346. (See Note L, European Commission Directive 67/548/EEC as amended and adapted.)DMSO is a solvent.NOHSC = National Occupational Health & Safety Commission, AustraliaTWA = Time weighted averageSTEL = Short term exposure limitUN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods.
History
Date of issue
Date of previous issue
Prepared by Product Stewardship
Notice to reader
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from us.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken.
05/10/2012.
10/02/2011.
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Automotive Diesel Fuel
SAFETY DATA SHEET
GHS product identifier
Section 1. Identification
Automotive Diesel Fuel
G10, BP 10 ppm diesel fuel,Ultra Low Sulphur diesel Fuel, Automotive Diesel Fuel AD 20 , AD40, ALPINE DIESEL, Biodiesel B5
Other means of identification
Manufacturer
Supplier BP Australia Pty LtdLevel 17, 717 Bourke StreetDocklands, Victoria 3008ABN 53 004 085 616
www.bp.com.au
Technical Helpline Number: 1300 139 700
1800 638 556EMERGENCY TELEPHONE NUMBER
Fuel for compression ignition diesel engines.Use of the substance/mixture
0000002718Product code
0000002718SDS no.
AD0K1Historic SDS no.
Relevant identified uses of the substance or mixture and uses advised against
Section 2. Hazard(s) identificationFLAMMABLE LIQUIDS - Category 4ACUTE TOXICITY (inhalation) - Category 4SKIN CORROSION/IRRITATION - Category 2CARCINOGENICITY - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bone marrow,liver and thymus) - Category 2ASPIRATION HAZARD - Category 1
Classification of the substance or mixture
Signal word DANGER
Hazard statements H227 - Combustible liquid.H332 - Harmful if inhaled.H315 - Causes skin irritation.H351 - Suspected of causing cancer.H304 - May be fatal if swallowed and enters airways.H373 - May cause damage to organs through prolonged or repeated exposure.(bone marrow, liver, thymus)
Hazard pictograms
Precautionary statements
GHS label elements
General P103 - Read label before use.P102 - Keep out of reach of children.P101 - If medical advice is needed, have product container or label at hand.
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Section 2. Hazard(s) identificationPrevention P201 - Obtain special instructions before use.
P260 - Do not breathe vapour.P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment.P273 -Avoid release to the environment.
Response P314 - Get medical attention if you feel unwell.P308 + P313 - IF exposed or concerned: Get medical attention.P304 + P340 + P312 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting.P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water.Take off contaminated clothing. Wash contaminated clothing before reuse.P332 + P313 - If skin irritation occurs: Get medical attention.
Storage P405 - Store locked up.P403 - Store in a well-ventilated place.P235 - Keep cool.
Disposal P501 - Dispose of contents and container in accordance with all local, regional,national and international regulations.
Other hazards which do not result in classification
This material may contain significant quantities of polycyclic aromatic hydrocarbons,some of which have been shown by experimental studies to induce skin cancer.Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency.See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data Sheet.
Supplemental label elements
Not applicable.
Section 3. Composition and ingredient information
Fuels, diesel > 95 68334-30-5Alkanes, C10-20-branched and linear 0 - 20 928771-01-1
Ingredient name CAS number
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Substance/mixture
Occupational exposure limits, if available, are listed in Section 8.
Mixture
% (w/w)
May contain Fatty Acid Methyl Esters (FAME). May also contain small quantities of proprietary performance additives.Contains small quantities of polycyclic aromatic hydrocarbons (PAHs).
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.Check for and remove any contact lenses. Get medical attention.
If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Get medical attention.
Section 4. First aid measures
Eye contact
Inhalation
Description of necessary first aid measures
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Section 4. First aid measures
Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Clean shoes thoroughly before reuse. Drench contaminated clothing with water before removing. This is necessary to avoid the risk of sparks from static electricity that could ignite contaminated clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly footwear, must be discarded. Get medical attention.
Skin contact
Ingestion
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
Note: High Pressure ApplicationsInjections through the skin resulting from contact with the product at high pressure constitute a major medical emergency. Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful with extensive subcutaneous necrosis.Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may force the product considerable distances along tissue planes.
Specific treatments No specific treatment.
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed, if necessary
See Section 11 for more detailed information on health effects and symptoms.
Section 5. Firefighting measures
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Combustion products may include the following:carbon dioxidecarbon monoxideother hazardous substances.
Combustible liquid. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.
Extinguishing media
Suitable extinguishing media
Unsuitable extinguishing media
Do not use water jet.
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Section 5. Firefighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk.Use water spray to keep fire-exposed containers cool.
Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.
Special protective equipment for fire-fighters
Special protective actions for fire-fighters
Hazchem code 3z
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses,basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilt product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.
Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment. Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.
Large spill
Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.
Small spill
Methods and material for containment and cleaning up
For non-emergency personnel
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Avoid contact of spilt material and runoff with soil and surface waterways. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container.Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment.Use only non-sparking tools. Do not breathe vapour or mist. Avoid exposure -
Precautions for safe handling
Product name
Date of issue
Page: 4/13Automotive Diesel Fuel
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
As a precaution, tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. When the product is pumped (e.g. during filling, discharge or ullaging)and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks). Explosive air/vapour mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated will create a flammability or explosion hazard. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work.
obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not swallow. Aspiration hazard if swallowed.Can enter lungs and cause damage. Never siphon by mouth.
Fuels, diesel ACGIH TLV (United States). Absorbed through skin. TWA: 100 mg/m³, (measured as total hydrocarbons) 8 hours. Issued/Revised:1/2007 Form: Inhalable fraction and vapor
Section 8. Exposure controls and personal protection
Ingredient name Exposure limits
Appropriate engineering controls
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls)have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.The final choice of protective equipment will depend upon a risk assessment. It is
Control parameters
Occupational exposure limits
Product name
Date of issue
Page: 5/13Automotive Diesel Fuel
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(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 8. Exposure controls and personal protection
Hand protection
Use with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory
Wear chemical resistant gloves.
Protective gloves must give suitable protection against mechanical risks (i.e.abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis.The frequency of replacement will depend upon the circumstances of use.
Chemical splash goggles.Eye/face protection
Respiratory protection
Skin protection Use of protective clothing is good industrial practice.Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required.Wear suitable protective clothing.Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing. For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static.When there is a risk of ignition wear inherently fire resistant protective clothes and gloves.Work clothing / overalls should be laundered on a regular basis. Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes.When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Recommended: overall
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
important to ensure that all items of personal protective equipment are compatible.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures
Individual protection measures
Skin protection
Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Recommended: Nitrile gloves.
Product name
Date of issue
Page: 6/13Automotive Diesel Fuel
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 8. Exposure controls and personal protectionequipment. Safety procedures should be developed for each intended application.Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.
Recommended: If ventilation is inadequate, use respirator that will protect against organic vapour and dust/mist.
Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716Gloves:AS/NZS 2161.1Eye protection:AS/NZS 1336 and AS/NZS 1337
Section 9. Physical and chemical properties
Physical state
Melting point
Vapour pressure
Relative density
Vapour density
Solubility
Liquid.
Not available.
Not available.
MildOdour
pH
Water white to straw including fluorescent green, blue or yellow.Colour
Evaporation rate Not available.
Auto-ignition temperature
Flash point
240°C (464°F)
Closed cup: >61.5°C (>142.7°F) [Pensky-Martens.]
Not available.
Not available.
Viscosity
Not available.Odour threshold
Partition coefficient: n-octanol/water
Appearance
Boiling point 180 to 380°C (356 to 716°F)
Flammability (solid, gas)
Lower and upper explosive (flammable) limits
Lower: 0.5%Upper: 7.5%
Decomposition temperature Not available.
Not applicable. Based on - Physical state
0.1 kPa (0.755 mm Hg)
820 to 850 kg/m³ (0.82 to 0.85 g/cm³) at 15°C
Not available.
Kinematic: 2 to 4.5 mm2/s (2 to 4.5 cSt) at 40°C
0.83
Density
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Incompatible materials
Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerisation will not occur.
Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.
Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Reactive or incompatible with the following materials: oxidising materials.
Product name
Date of issue
Page: 7/13Automotive Diesel Fuel
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(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 11. Toxicological information
Acute toxicity
Fuels, diesel LC50 Inhalation Dusts and mists Rat 4.1 mg/l 4 hours LD50 Dermal Rabbit >4300 mg/kg -LD50 Dermal Rabbit >4300 mg/kg -LD50 Oral Rat 17900 mg/kg -LD50 Oral Rat 7600 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Fuels, diesel Positive - Dermal -Unspecified
Mouse - 2 years
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary Suspected of causing cancer.
Mutagenicity
Fuels, diesel OECD 471 Experiment: In vitro PositiveSubject: Non-mammalian species
Equivalent to OECD 476
Experiment: In vitro Negative
Subject: Mammalian-AnimalCell: Germ
not guideline Experiment: In vivo NegativeSubject: UnspecifiedCell: Somatic
Product/ingredient name Test Experiment Result
Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.
Reproductive toxicity
Product/ingredient name Maternal toxicity
Fertility Developmental toxin
Species
Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are not met.Fertility: Not classified. Based on available data, the classification criteria are not met.Effects on or via lactation: Not classified. Based on available data, the classification criteria are not met.
Dose Exposure
Fuels, diesel - - Negative Rat Dermal 20 days- - Negative Rat Dermal 10 days- - Negative Rat Dermal 10 days
Irritation/Corrosion
Fuels, diesel Skin - Irritation Rabbit - - -Skin - Irritation Rabbit - - -Eyes - Non-irritating to the eyes.
Rabbit - - -
Eyes - Non-irritating to the eyes.
Rabbit - - -
Product/ingredient name Result Score Exposure Observation
Skin Causes skin irritation.
Sensitisation
Fuels, diesel skin Guinea pig Not sensitisingskin Guinea pig Not sensitising
Product/ingredient name Route of exposure
Species Result
Species
Information on toxicological effects
Product name
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(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 11. Toxicological information
Information on likely routes of exposure
Inhalation Harmful if inhaled.
Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Ingestion
Skin contact Causes skin irritation.
No known significant effects or critical hazards.Eye contact
May cause damage to organs through prolonged or repeated exposure. Vapour,mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer. Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.
General
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness
Adverse symptoms may include the following:nausea or vomiting
Adverse symptoms may include the following:irritationredness
Eye contact Adverse symptoms may include the following:pain or irritationwateringredness
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Specific target organ toxicity (repeated exposure)
Name Category
Fuels, diesel Category 2 Not determined bone marrow, liver and thymus
Aspiration hazard
Name Result
Fuels, diesel ASPIRATION HAZARD - Category 1Alkanes, C10-20-branched and linear ASPIRATION HAZARD - Category 1
Route of exposure
Target organs
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential acute health effects
Eye contact
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer. Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.Vapour, mist or fume may irritate the nose, mouth and respiratory tract.
If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and drowsiness.
Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume may cause stinging, redness and watering of the eyes.
As with all such products containing potentially harmful levels of polycyclic aromatic hydrocarbons, prolonged or repeated skin contact may eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Inhalation
Skin contact
Ingestion
Product name
Date of issue
Page: 9/13Automotive Diesel Fuel
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 11. Toxicological informationSuspected of causing cancer. Risk of cancer depends on duration and level of exposure.
Carcinogenicity
No known significant effects or critical hazards.Mutagenicity
No known significant effects or critical hazards.Teratogenicity
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Numerical measures of toxicity
Inhalation (dusts and mists) 1.895 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological informationToxicity
Fuels, diesel EL50 >1000 mg/l Nominal Fresh water Micro-organism 40 hours NOELR 3.217 mg/l Nominal Fresh water
Micro-organism 40 hours
Acute EL50 22 mg/l Nominal Fresh water
Algae 72 hours
Acute EL50 210 mg/l Nominal Fresh water
Daphnia 48 hours
Acute EL50 68 mg/l Nominal Fresh water
Daphnia 48 hours
Acute ErL50 78 mg/l Nominal Fresh water
Algae 72 hours
Acute LL50 65 mg/l Nominal Fresh water
Fish 96 hours
Acute LL50 21 mg/l Nominal Fresh water
Fish 96 hours
Acute NOELR 10 mg/l Nominal Fresh water
Algae 72 hours
Acute NOELR 1 mg/l Nominal Fresh water
Algae 72 hours
Acute NOELR 46 mg/l Nominal Fresh water
Daphnia 48 hours
Chronic NOEL 0.083 mg/l Nominal Fresh water
Fish 14 days
Chronic NOELR 0.2 mg/l Nominal Fresh water
Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary Toxic to aquatic life with long lasting effects.
Persistence and degradability
Fuels, diesel OECD 301 F 60 % - Readily - 28 days 30 mg/l -OECD 301 F 57.5 % - Not readily - 28 days 25 mg/l -Equivalent to EPA OTS 796.3100
35 % - Not readily - 28 days 5 mg/l -
Product/ingredient name Test DoseResult Inoculum
Conclusion/Summary Non-persistent per IMO criteria
Partially biodegradable.
Product name
Date of issue
Page: 10/13Automotive Diesel Fuel
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(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 12. Ecological information
Mobility Spillages may penetrate the soil causing ground water contamination. This material may accumulate in sediments.
Bioaccumulative potential
Soil/water partition coefficient (KOC)
Not available.
Mobility in soil
This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal methods
Special Precautions for Landfill or Incineration
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty packaging and should not be removed.
Section 14. Transport information
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)
9
III
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (Fuels, diesel)
UN3082
9
III
UN3082
IMDG IATA
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Environmental hazards
Yes. Yes.
ADG
Not regulated.
-
-
-
No.
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Date of issue
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Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 14. Transport informationThis product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
Emergency schedules (EmS)F-A, S-F
This product is not regulated as a dangerous good when transported in sizes of ≤5 L or ≤5 kg, provided the packagings meet the general provisions of 5.0.2.4.1, 5.0.2.6.1.1 and 5.0.2.8.
Additional information
Special precautions for user
Transport in bulk according to Annex II of Marpol and the IBC Code
Not available.
MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gas oils, including ship's bunkers
Proper shipping name
RemarksCombustible liquid Class C1 (AS 1940).
Hazchem code3Z
Initial emergency response guide47
Section 15. Regulatory informationStandard Uniform Schedule of Medicine and Poisons
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
International lists
National inventory
REACH Status
Canada inventory All components are listed or exempted.
Australia inventory (AICS) All components are listed or exempted.
China inventory (IECSC) Not determined.
Japan inventory (ENCS) Not determined.
Korea inventory (KECI) Not determined.
Philippines inventory (PICCS)
Not determined.
For the REACH status of this product please consult your company contact, as identified in Section 1.
Taiwan Chemical Substances Inventory (TCSI)
All components are listed or exempted.
Not scheduled
Consumer products - This product is exempt per Appendix A of the SUSMP. Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National Code of Practice for labelling of workplace substances.
United States inventory (TSCA 8b)
All components are listed or exempted.
Product name
Date of issue
Page: 12/13Automotive Diesel Fuel
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Section 16. Any other relevant information
07/04/2016
History
Date of printing
Date of issue/Date of revision
Version
Notice to reader
Date of previous issue
Indicates information that has changed from previously issued version.
Key to abbreviations ADG = Australian Dangerous GoodsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)NOHSC = National Occupational Health and Safety CommissionSTEL = Short term exposure limitSUSMP = Standard Uniform Schedule of Medicine and PoisonsUN = United NationsTWA = Time weighted averageVOC = Volatile Organic CompoundSADT = Self-Accelerating Decomposition TemperatureVaries = may contain one or more of the following 101316-69-2, 101316-70-5,101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,72623-87-1, 74869-22-0, 90669-74-2
07/04/2016
07/04/2016
1
Procedure used to derive the classification
Classification Justification
Flam. Liq. 4, H227 On basis of test dataAcute Tox. 4, H332 Calculation methodSkin Irrit. 2, H315 Calculation methodCarc. 2, H351 Calculation methodSTOT RE 2, H373 (bone marrow, liver and thymus) Calculation methodAsp. Tox. 1, H304 Calculation method
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available.Alteration of this document is strictly prohibited.
Product Stewardship
Product name
Date of issue
Page: 13/13Automotive Diesel Fuel
ENGLISH
(ENGLISH)
Product code
Version 1 Format LanguageAustralia
0000002718
(Australia)
07/04/2016
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 35 of 39
12. Appendix D - Enviropacific Services Fuel Experience
Enviropacific Services has contributed to the success of hundreds of convenience store, service
station, truck stop, highway service centre and retail food projects throughout Australia. Since 1989
our architectural design abilities have been well known within the retail petroleum industry. Our
project list boasts major oil companies, government organisations and independent operators alike
and currently shows in excess of 900 projects, the vast majority of these Oil Industry projects.
As an experienced service station design consultancy, our clients have access to the latest ideas
and innovations as they happen within the industry. Enviropacific Services is at the forefront of
many of these innovations. We aim to give our clients “something special”, something the market
will notice and admire. The Enviropacific Services design skills and attention to detail has been
recognized by many BDAQ State and Regional Design Awards. We are currently working with
clients in Queensland, New South Wales and Victoria on numerous service station, convenience
store and highway service centre projects.
Fuel system design and services co-ordination is another area of extensive experience for
Enviropacific Services. We have delivered scores of highly successful projects. We were, for
example, engaged as fuel system designers for the four Major BP highway service centres
completed in 2001 in Queensland. These are some of the largest retail petroleum facilities in
Australia and have set a new benchmark for highway service centres in this country.
Enviropacific Services, as a registered nationwide building design practice, performs a Lead
Consultant role in most projects we are involved with. As a sub-consultant, we also provide
specialist service station and fuel system design and certification services. Another project role
Enviropacific Services performs is that of the architectural documentation consultant working within
the project design team, under the control of the leader consultant.
High quality project design coordination is a priority for all Enviropacific Services projects. All
services and design drawings from all consultants should read together without error or conflicting
information. This is our goal and although many acknowledge its importance, few actual achieve
consistent success. At Enviropacific Services coordination is not simply a concept – it is an
OBSESSION!
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 36 of 39
13. Appendix E - Enviropacific Services Fuel Industry Clients
Enviropacific Services oil Industry clients include (independent operators excluded):
• BP Australia • Caltex Australia • Pacific Petroleum
Products
• Avis Australia
• Air BP • Woolworths Ltd • United Petroleum • ECL Fuelquip
• Reliance
Petroleum
• Caltex Energy • Advance Petroleum • Gilbarco
• Westoil Petroleum • Central Petroleum
Queensland
• Independent Fuel
Supplies
• JF TA
• AA Petroleum • Matilda Petroleum • Ergon Energy • Tank Solutions
• Jasbe Petroleum • Qld Fuels Group • Energex • Lanskey
Constructions
• SEQ Fuel Supplies • Shell Australia (Go
Gas)
• Emerald Shire Council • Petroleum
Constructions
• Central Petroleum
Queensland
• Rampage Pty Ltd • Night Owl
Convenience Stores
• Castrol • Pacific Fuels • Swap n’ Go
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 37 of 39
14. Appendix G - Enviropacific Services Fuel Industry Projects
Below are details of a select number of Oil Industry projects that Enviropacific Services has provided
design services for:
Project Scope Client Site Scope of Services Project
Value
Brisbane Area
Fuel System Design BP Australia Pty
Ltd
Caboolture North & South Proposed twin highway
service centres & WBC
counter upgrades
$25m
Fuel System Design BP Australia Pty
Ltd
Coomera, Staplyton Proposed twin highway
service centres & WBC
counter upgrades
$25m
Lead Consultant BP Australia Pty
Ltd
Whinstanes, Hendra Office Fitouts $250k
Architectural
Design
BP Australia Pty
Ltd
Helensvale, Major Modifications $500k
Architectural
Design
Fuel System Design
BP Australia Pty
Ltd
Various Sites including Ferny
Grove, Springwood,
Maroochydore, Hamilton,
Virginia, Bribie Island, Palms
Corner, Oxenford, Morayfield,
Loganholme, Aspley,
Narangba, Labrador, Moggill
Road, Blacksoil, Nerang,
Chinderah South (NSW)
Connect Upgrades, Juice
Offers, Wild Bean
Upgrades, Major
Modifications, Raze &
Rebuilds, Café Zips
$30m
Fuel System
Certification
Woolworths
Petroleum
Various Sites including
Chermside, Bowen, Mackay,
Dalby, Noosaville, Gladstone,
Gympie
Fuel System License
Compliance Checks
$5m
Lead Consultant United
Petroleum
Ayr, Springfield, Crestmead,
Maryborough
New Service Station
Developments and Fuel
System Upgrades
$5m
Lead Consultant
Swap ‘N’ Go Hemmant LPG Cylinder Processing
Plant
-
Fuel System Design
Shell Engineering Tewantin, Burleigh Waters,
Victoria Point, Toowoomba,
Loganholme, Kallangur
Autogas Installation $1m
Lead Consultant South East
Queensland
Fuels
Yatala Proposed Truck Refuelling
Facility and Unmanned
Refuelling facility
$300k
Lead Consultant PHF East Brisbane, Wamuran Autogas and Pump &
Tank Layout
$1m
Master Planning Colin Loel
Architects
Gateway Motorway, Nundah Highway Service Centre $8m
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 38 of 39
Fuel System Design Pratt & Whitney Eagle Farm Fuel Farm and Spill Trench $500k
Fuel System Design PECC Burbank, Eagle Farm Proposed Diesel
Refuelling Facility
$250k
Lead Consultant Pinnaroo Estate Rainbow Waters Resort Multi Residential
Documentation
$25m
Lead Consultant Freedom Fuels Inala, Beenleigh, Acacia
Ridge
Food Offer Revitalisation $1m
Fuel System Design Caltex Carseldine Service Station $1m
Master Planning Hallmark
Properties
Plainland Highway Service
Centre
Highway Service Centre $6m
Sydney Area
Lead Consultant XL Development
Group
Newcastle Proposed Truck Stop $6m
Architectural
Design
Merino
Properties
Golburn Proposed Service Station
Development
$5m
Architectural
Design
Jasbe Petroleum Auburn, Silverwater, Oakes,
Baulkham Hills, Warwick Farm,
Lansvale, Willoughby
Raise & Rebuilds $10m
Lead Consultant Westoil
Petroleum
Young, Lithgow, Mudgee Retail Network Review &
Revitalisation
$3m
Fuel System
Designer
GOGAS
Australia
Strathfield, Terrigal, Berkshire
Park, Buladelah
Autogas Installation $500k
Melbourne Area
Lead Consultant Jasbe Petroleum Frankston (Big Pine) Proposed Service Station
Redevelopment
$2m
Lead Consultant Jasbe Petroleum Highbluff Proposed Service Station
Redevelopment
$1m
Lead Consultant AA Petroleum Pakenham Zip/Connect Upgrade $2m
Architectural
Documentation
and Coordination
BP Australia Pty
Ltd (MEL)
Standards ST29, ST31 Drawings -
Lead Consultant AA Petroleum Oakleigh, Burwood East Proposed Service Station
Redevelopment
$2.5m
Lead Consultant Morphic Capital Longworry Proposals for twin
Highway Service Stations
$12m
Architectural
Design
Jasbe Petroleum Supremacy, Lyndhurst, Service Station Interior
Fitouts
$10m
Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 39 of 39
Lead Consultant Rampage
Enterprises Pty
Ltd
Rockbank Proposal for twin Highway
Service Stations
$15m
Fuel System Design Advance
Petroleum
Geelong Depot Upgrade to existing diesel
facility
$250k
Darwin Area
Architectural
Design
BP Australia Pty
Ltd
Nightcliff Raise & Rebuild -
Architectural
Design
BP Australia Pty
Ltd
Ludmilla Raise & Rebuild -
Architectural
Design
Gilbarco RAAF Base Tindal As Constructed $5.5m
Perth Area
Fuel System Design Cronin
Construction
Star Track Fuel System & Autogas
facilities
$500k
Townsville Area
Fuel System Design BP Australia Pty
Ltd
BP Cluden Truck stop Truck Stop $8m
Lead Consultant BP Australia Pty
Ltd
BP Express Aitkenvale Service Station $3m
Lead Consultant BP Australia Pty
Ltd
BP Southern gateway Service Station $1.5m
Please visit our Company Website at www.cadway.com.au for additional information about
Enviropacific Services, our expertise, experience and previous project involvement.