Handbook of Optical Constants of Solids III

Edited by

EDWARD D. PAUK

Institute for Physical Science and Technology University of Maryland

College Park, Maryland

Academic Press San Diego London Boston

New York Sydney Tokyo Toronto

Contents

List of Contributors Preface

X l l l

xvii

Part I DETERMINATION OF OPTICAL CONSTANTS

Chap te r 1 Introductory Remarks EDWARD D. PALIK

I. Introduction П. The Chapters

Ш. The Critiques IV. The Tables V. The Figures of the Tables

VI. Corrections, Additions, and Comments References

3 4 5 5 5 6

12

Chap te r 2 Determination of the Far-Infrared Optical Constants of Solids by Dispersive Fourier Transform Spectroscopy T. J. PARKER, K. A. MASLIN, a n d G. MIRJALIU

I. Introduction II. The Materials

Acknowledgment References

13

13 20 55 55

Chapte r 3 Photothermal/Photoacoustic Spectroscopic Measurements of Optical Absorption Coefficients in Semiconductors 59 ANDREAS MANDEUS

I. Introduction 59 II. Photoacoustic Spectroscopy (PAS) 60

III. Photopyroelectric Spectroscopy (PPES) 67 IV Measurements of a(A) in Semiconductors using

Photoacoustic/Photothermal Techniques 69 Acknowledgments 94 References 94

v

VI Contents

Chapter 4 Photothermal Deflection Measurements of the Extinction Coefficient к MATTHEW E. BRIGGS

I. Introduction II. Photothermal Deflection

Ш. Conclusions Acknowledgments References

99

99 103 116 117 117

Chapter 5 Determination of Optical Constants by Briiiouin Scattering HACENE BOUKARI and NICHOLAS LAGAKOS

I. Definition of Notation II. Introduction

Ш. Background on Briiiouin Scattering Technique IV. Equations for Measurement of the Index of Refraction V. Fabry-Perot Interferometers

VI. Discussion VII. Briiiouin Scattering in Thin Slabs and Optical Fibers

Vni. Special Case of Transparent Thin Slabs IX. Briiiouin Scattering in Optical Fibers

References

121

121 122 123 125 128 128 134 135 146 153

Chapter 6 Doped n-Type Silicon (n-Si) MARK AUSLENDER and SHLOMO HAVA

I. Introduction П. Contributions to Dielectric Function: Optical Properties versus

Optical Constants III. Semiclassical Theory of Free-Carrier Contribution to the Dielectric

Function: The Drude Approximation IV. Free-Carrier Contribution to the Dielectric Function in Quantum

Absorption Regime: Generalized Drude Approach V Experimental Data Overview

VI. Generalized Drude Approximation for n-Si VII. Tabulation of Optical Constants of Doped n-Si

References

155

155

156

158

159 162 166 171 185

Chapter 7 Optical Parameters for the Materials in HOC I, HOC II, and HOC III EDWARD D. PAUK

I. Introduction П. The Parameters

References

187

187 187 225

VII

Part II CRITIQUES

Subpart 1 Metals

Introduction to the Data for Several Metals 233 DAVID W. LYNCH a n d W. R. HUNTER

I. Introduction 233 References 235

П. Magnesium (Mg) 235 References 235

Ш. Titanium (Ti) 240 References 241

IV. Manganese (Mn) 249 References 250

V. Ruthenium (Ru) 253 References 254

VI. Indium (In) 261 References 262

VII. Tin (Sn) 268 References 269

Vni. Antimony (Sb) 274 References 275

IX. Rhenium (Re) 278 References 279

Optical Constants of Eight Rare-Earth Elements 287 L. WARD

287 292 293 294 297 298 300 301 302 303

341

References 344

Zirconium Nitride (ZrN), Hafnium Nitride (HfN) 351 CARL G. RIBBING a n d ARNE ROOS

References 358

I. II.

Ш. rv. V.

VI. VII. VIII. K .

Introduction Cerium (Ce) Samarium (Sm) Gadolinium (Gd) Terbium (Tm) Dysprosium (Dy) Erbium (Er) Thulium (Tm) Ytterbium (Yb) References

Cesium (Cs) T. INAGAKI a n d E. T. ARAKAWA

viii Contents

Subpart 2 Semiconductors

Aluminum Nitride (AIN) 373 S. LOUGHIN a n d R. H. FRENCH References 377

Bismuth Silicon Oxide (Bi12Si020) and Bismuth Germanium Oxide (Bi12Ge020) 403 E. D. PAUK References 408

Boron Nitride (BN) 425 GARY L. DOLL References 429

Cadmium Germanium Arsenide (CdGeAs2) 445 J. С RIFE References 448

Copper Gallium Sulfide (CuGaS2) 459 J. С RIFE References 462

Gallium Selenide (GaSe) 473 DAVID F. EDWARDS References 477

Gallium Telluride (GaTe) 489 DAVID F. EDWARDS References 491

Iron Pyrite (FeS2) 507 E. D. PAUK References 511

Silicon (Si) Revisited (1.1-1.3 eV) 519 J O N GEIST References 524

Contents ix

Silicon (Si) Revisited (1.4-6.0 eV) 531 DAVID F. EDWARDS

References 533

Silicon-Germanium Alloys ( S i ^ _x ) Revisited 537 J. HUMÜCEK

References 538

Silver Chloride (AgCI), Silver Bromide (AgBr), Silver Iodide (Agl) 553 MASATO TAZAWA a n d ARMAND HADNI

References 556

Silver Gallium Selenide (AgGaSe2) and Silver Gallium Sulfide (AgGaS2) 573 LUIS ARTUS

References 577

Zinc Arsenide (Zn3As2) 595 J. MISIEWICZ a n d К. JEZIERSKI References 596

Zinc Phosphide (Zn3P2) 609 J. MISIEWICZ a n d K. JEZIERSKI References 612

Zinc Germanium Phosphide (ZnGeP2) 637 J. С RIFE References 640

Subpart 3 Insulators

Aluminum Oxide (Al203) Revisited 653 MICHAEL E. THOMAS a n d WILLIAM J. TROPF References 657

Barium Fluoride (BaF2) 683 MICHAEL E. THOMAS a n d WILLIAM J. TROPF References 686

Calcium Carbonate, Calcite (CaCo3) 701 WILLIAM J. TROPF

References 703

Cesium Bromide (CsBr) 717 W. J. MOORE

References 719

Cesium Chloride (CsCI) 731 JOHN E. ELDRIDGE

References 733

Cesium Fluoride (CsF) 743 JOHN E. ELDRIDGE

References 745

Beta-Gallium Oxide (ß-Ga203) 753 DAVID F. EDWARDS

References 755

Lead Fluoride (PbF2) 761 MÄRCIA A. F. DESTRO a n d ALVARO J. DAMIÄO

References 766

Lithium Tantalate (LiTa03) 777 FRANQOIS GERVAIS a n d VICENTE FONSECA

References 780

Potassium Iodide (Kl) 807 MICHAEL E. THOMAS

References 810

Potassium Niobate (KNb03) 821 IVAN BIAGGIO

References 825

Rubidium Bromide (RbBr) 845 IVAN OHÜDAL a n d MILOSLAV OHUDAL

References 848

Contents XI

Rubidium Iodide (Rbl) 857 IVAN OHUDAL and DANIEL FRANTA

References 861

Sodium Nitrate (NaN03) 871 EDWARD D. PAUK and R. KHANNA

References 873

Strontium Fluoride (SrF2) 883 MICHAEL E. THOMAS

References 886

Orthorhombic Sulfur (a-S) 899 KIRK A. FULLER, HARRY D. DOWNING, and MARVIN R. QUERRY

References 905

Cubic Thallium(l) Halides 923 WILLIAM J. TROPF

References 931

Yttrium Aluminum Garnet (¥3А15012) 963 WILLIAM J. TROPF References 966

Zircon (ZrSi04) 987 EDWARD D. PAUK and R. KHANNA References 989