Green Polymer AdditivesEmery Oleochemicals is committed to develop innovative, natural-based polymer...

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WE MAKE MATERIALS BETTER AND PROCESSING EASIER WITH INNOVATIVE ADDITIVE SOLUTIONS Green Polymer Additives

Transcript of Green Polymer AdditivesEmery Oleochemicals is committed to develop innovative, natural-based polymer...

Page 1: Green Polymer AdditivesEmery Oleochemicals is committed to develop innovative, natural-based polymer product solutions for lubricants, plasticizers and viscosity depressants, antistatic

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WE MAKE MATERIALS BETTER AND PROCESSING EASIER

WITH INNOVATIVE ADDITIVE SOLUTIONS

Green Polymer Additives

Page 2: Green Polymer AdditivesEmery Oleochemicals is committed to develop innovative, natural-based polymer product solutions for lubricants, plasticizers and viscosity depressants, antistatic

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EDENOL® and LOXIOL® are the plastics additives brand

names of Emery Oleochemicals. Our products are based on

natural resources for the processing of plastics materials.

The main product groups and functions we offer are:

Lubricants – Optimize the processing characteristics of

plastics materials. Our lubricants improve the rheology of

the polymer melt by reducing friction and resistance to flow

within the melt. >>> Positive influence on the mechanical

properties, machinery output and surface finish of the final

product.

Release Agents – Aid in the separation of a component

from its mold. >>> Positive effect on cycle time and surface

finish.

Special Plasticizers – Improve processability and

performance of plastics and synthetic rubbers. >>> Positive

influence on flexibility and durability of the final article.

Viscosity Regulators – Improve the flow of PVC paste

formulations. >>> Positive influence on processing

temperature and processability.

Antistatic Agents – Eliminate the buildup of a static

charge in the finished article.

>>> Positive effects including avoidance of dust pick-up,

handling problems as well as the risks associated with static

discharges.

Antifogging Agents – Prevent the formation of water

droplets on plastics film surfaces. >>> Positive effect on

visibility, quality and attractiveness of packaged products

and avoidance of damage to plants in growing tunnels.

Antiblocking/Slip Agents – Reduce the friction between

the polymer to polymer surface or processing equipment.

>>> Positive effect on production handling by preventing

adhesion.

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As a leader in the global polymer additive

industry, Emery Oleochemicals is committed

to offering high performance, natural-

based additives for plastics processing

including lubricants, plasticizers and viscosity

depressants, antistatic and antifogging

agents as well as release agents made from

sustainable materials. Our vertical integration

into renewable feedstock and our global

footprint provides our customers with a

reliable worldwide supply chain.

Emery Oleochemicals continues to invest

in research and new product development

to meet the high demands of plastics driven

markets, including the automotive, building

and construction, and packaging sectors.

SUSTAINABLE SOLUTIONS – EVEN BEFORE "GREEN" GOT IMPORTANT

NATURAL-BASED PRODUCTS Emery Oleochemicals is a pioneer in

developing innovative, high-performance

products from natural feedstocks. Catering to

the increasing demand for environmentally-

responsible solutions for many applications,

we also work closely with our global

customers to provide customized, sustainable

polymer solutions to meet specific technical

and performance requirements.

Our brand LOXIOL® was introduced in 1957, and

is associated with renewable-based polymer

additives since the beginning of the plastics

industry. Due to constant innovations, we conti-

nue to develop products that meet the increa-

sing requirements of today´s market demands.

For more information about Green Polymer Additives, please visit: https://greenpolymeradditives.emeryoleo.com/additives/

THE FIRST CHOICE IN SUSTAINABLE POLYMER ADDITIVES

% of renewable raw material content

in our products

50-100%

>25%

>50%34out of

products with a renewability

greater 50%

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Emery Oleochemicals is committed to

develop innovative, natural-based polymer

product solutions for lubricants, plasticizers

and viscosity depressants, antistatic and

antifogging agents, release agents and sur-

factants. Catering to the increasing demand

for environmentally-responsible solutions

for many applications, we also work closely

with our global customers to provide custo-

mized, sustainable polymer solutions to

meet specific technical and performance

requirements.

A state-of-the-art Green Polymer Additives

Global Technical Development Center (TDC)

located in Loxstedt, Germany serves as the

company’s Global Center of Excellence for its

Green Polymer Additives business. This TDC

facility covering 950 square meters has dedi-

cated laboratories for product development,

application testing and quality control.

Installation of a pilot plant at our Loxstedt

location also provides greater flexibility in

upscaling our products while shortening

the time-to-market for new product

development. In addition, expanded

manufacturing capabilities in Loxstedt allow

for the manufacture of dust free products

with improved flowability, called beads. By

using an innovative and resource-friendly

spray technology, the material has a smooth

surface and a narrow particle size distribution.

Dust formation is eliminated while main-

taining exactly the same specification as in

the common powder. Producing this dust-free

product is a hallmark for this facility.

RESEARCH AND INNOVATION

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CONTENT

ANTIFOGGING AGENTS 10

ANTISTATIC AGENTS 12

LUBRICANTS 14

RELEASE AGENTS 20

SLIP AND ANTIBLOCKING AGENTS 22

PLASTICIZERS 24

VISCOSITY REGULATORS 26

C-PVC APPLICATIONS 28

ANTIFOGGING AGENTS 32

ANTISTATIC AGENTS 34

LUBRICANTS/RELEASE AGENTS 36

PENTAERYTHRITOL ESTERS 38

SLIP AND ANTIBLOCKING AGENTS 40

PIM / ADDITIVE MANUFACTURING 42

IADDITIVES FOR PVC

IIADDITIVES FOR THERMOPLASTICS

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PLASTICIZERS 50

ADDITIONAL ADDITIVES 52

AZELAIC ACID 56

IVADDITIVES FOR ELASTOMERS

IIIADDITIVES FOR THERMOSETS

VAZELAIC ACID

LUBRICANTS/RELEASE AGENTS 46

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WE MAKE MATERIALSBETTER AND PROCESSINGEASIER WITH INNOVATIVEADDITIVE SOLUTIONS.

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IADDITIVES FOR PVC

IADDITIVES FOR PVC

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LOXIOL® antifogging agents prevent the

formation of water droplets on plastic film

surfaces. They improve the visibility, quality,

and attractiveness of packaged products

and help prevent damage to plants under

greenhouse films by inhibiting the formation

of water droplets. Our antifogging agents have

food contact approval, and are perfectly suited

for the food packaging industry.

Particularly in food packaging, our range of

antifogging additives enhances consumer

product appeal and shelf life while retaining

food quality.

Advantages of LOXIOL® antifogging

agents include:

� Optimization for applications in plastic films

� Highly efficient solutions

� Excellent transparency of the final product

� Food contact approval

� Availability of vegetable-derived products

Further information about partially bio-based

antifogging agents is available on page 33.

ADDITIVES FOR PVC

ANTIFOGGING AGENTS

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ANTIFOGGING AGENTS DESCRIPTIONDELIVERY

FORMDOSAGE

(phr)PVC-P PVC-U

FOOD CONTACT

APPROVAL*

LOXIOL® A 2 Fatty acid ester compound liquid 2.0-4.0 x x

LOXIOL® A 4 Fatty acid ester compound liquid 2.0-4.0 x x

LOXIOL® A 4 SPEZIAL Fatty acid ester compound liquid 2.0-4.0 x x

LOXIOL® A 7 Fatty acid ester compound liquid 2.0-3.5 x x

LOXIOL AF 80 Fatty acid ester; recommended for external application liquid x x x

Test Methology

A glass beaker is filled with water and covered with a film specimen, as shown in the images below. The temperature of water and

environment may vary depending on the specific requirements (hot/cold fog). Water starts condensing at the bottom side of the

film and the time-dependent antifogging grade is evaluated visually according to reference images shown below. Images 1-4 show

the formation of fog. In images 5-8, water droplets are agglomerating and form bigger drops. Images 9-12 show the formation of a

transparent layer of water. Antifogging grades as shown in images 10-11 are considered acceptable, and image12 excellent.

*Depending on regional regulations

IADDITIVES FOR PVC /// ANTIFOGGING AGENTS

1

5

9

2

6

10

3

7

11

4

8

12

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Emery Oleochemicals’ LOXIOL® antistatic

agents eliminate buildup of static charge on the

surface of finished products.

We offer internal antistatic agents for a

variety of polymers including PVC. LOXIOL®

antistatic agents prevent dust accumulation

and minimize the handling problems and risks

associated with static charge. These products

impart lasting performance and provide

superior aesthetics and clarity for a variety

of packaging needs. Applications include

consumer and industrial goods packaging,

flooring in technical environments, and

sensitive electronic components.

Advantages of LOXIOL® antistatic agents

include:

� Minimized risk of electrical discharge that

may cause fire or explosion

� Avoidance of electrical shock risk to

employees or consumers

� Reduced dust accumulation that affects

performance and appearance of plastic

products

� Improved handling during transportation,

packaging and storage

� Food contact approval

ADDITIVES FOR PVC

ANTISTATIC AGENTS

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WORKING PRINCIPLE OF INTERNAL ANTISTATIC AGENTS

Poly

mer

Fil

m

Phase 1

After the extrusion process, a homogeneous distribution of the antistatic agent is obtained.

Phase 2

Migration of the antistatic agent to the polymer surface begins.

Phase 3

The polymer surface is covered by antistatic agent after hours or days.

Phase 4

Moisture from the ambient air is attracted by the polar side of the antistatic agent giving the desired antistatic properties.

H2O

H2O

H2O

H2O

H2O

H2O

*ANTISTATIC AGENTS DESCRIPTIONDELIVERY

FORM

MELTING RANGE

(°C)

DOSAGE (phr)

PVC-P PVC-UFOOD

CONTACT APPROVAL*

LOXIOL® 3290 Fatty acid ester liquid - 2.0-3.0 x x

LOXIOL® 3366 Fatty acid ester liquid - 0.5-4.0 x x

LOXIOL® 3380 Mixture of ionic compounds and fatty acid ester liquid - 0.5-4.5 x x

LOXIOL® 80 X Mixture of anionic and non-ionic compounds liquid - 0.2-1.5 x x

LOXIOL® 93 P Anionic compound solid > 350 0.2-3.0 x x x

LOXIOL® VPA 1726 Fatty acid ester liquid - 1.0-3.0 x x

IADDITIVES FOR PVC /// ANTISTATIC AGENTS

*Depending on regional regulations

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ADDITIVES FOR PVC

LUBRICANTS

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LOXIOL® lubricants optimize the processing

characteristics of PVC and improve the

rheology of the polymer melt by reducing melt

viscosity and friction during processing.

We offer a wide range of bio-based internal

and external lubricants for a variety of

applications including calendering, extrusion,

and injection molding.

Advantages of LOXIOL® lubricants are:

� Positive effects on processing

� Low volatility and high compatibility

� Improved rheological properties

� Optimized machinery output

� Improved surface finish of final article

� Transparent and food contact application

options

� Product solutions with excellent cell

structure in foamed applications

IADDITIVES FOR PVC /// LUBRICANTS

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LUBRICANT DESCRIPTION INTERNAL - EXTERNALMELTING RANGE

(°C)

DOSAGE (phr)

TRANS-PARENT ARTICLE

PVC-P PVC-U

LOXIOL® G 53 C16/18 fatty alcohol ¢£££££££££ 52-56 0.5-1.5 x x

LOXIOL® G 11 Fatty acid ester ¢£££££££££ < -10* 0.5-1.5 x x x

LOXIOL® GH 4 Fatty acid ester compound ¢¢££££££££ 76-80 0.8-1.5 x x

LOXIOL® G 10 Fatty acid ester ¢¢££££££££ < 4* 0.5-2.5 x x

LOXIOL® G 10 V Fatty acid ester compound ¢¢££££££££ < 7* 0.5-2.5 x x

LOXIOL® G 13 Fatty acid ester £¢££££££££ < -10* 0.5-1.5 x x

LOXIOL® G 15 Hydrogenated castor oil £¢££££££££ 83-90 0.5-2.5 x x

LOXIOL® G 59 Fatty acid ester £¢££££££££ 68-72 0.5-2.0 x x

LOXIOL® G 60 C16/18 phthalate £¢££££££££ 44-48 0.5-3.0 x x

LOXIOL® G 62 Fatty acid ester £¢¢£££££££ 53-57 0.5-1.5 x

LOXIOL® G 63 Fatty acid ester £¢¢£££££££ 52-56 0.5-1.5 x

LOXIOL® P 728 Fatty acid ester £¢¢£££££££ 49-53 0.5-1.5 x

LOXIOL® G 16 Fatty acid ester ££¢£££££££ <0* 0.5-1.5 x x

LOXIOL® P 1141 Fatty acid ester compound ££¢£££££££ <0* 0.5-1.5 x x

LOXIOL® P 1206 Fatty acid ester ££¢£££££££ 56-60 0.5-1.5 x

LOXIOL® 895 Ethylene glycol distearate ££¢£££££££ 67-71 0.5-2.0 x

LOXIOL® 897 Ethylene glycol distearate ££¢£££££££ 62- 66 0.5-2.0 x

LOXIOL® G 41 Fatty acid ester ££¢¢££££££ 64-68 0.5-1.5 x

LOXIOL® G 40 Fatty acid ester ££¢¢££££££ < 7* 0.5-1.5 x x x

LOXIOL® G 32 Fatty acid ester £££¢¢£££££ 54-58 0.5-1.5 x

LOXIOL® G 34 R Fatty acid ester £££¢¢£££££ 54-58 0.5-1.5 x

LOXIOL® EP 218 Hydrogenated triglyceride ££££¢£££££ 59-63 0.2-0.5 x

LOXIOL® EP 3500 Ca-stearate ££££¢¢££££ 150-160 0.2-0.5 x x

LOXIOL® G 47 Fatty acid ester £££££¢££££ 62-66 0.5-1.0 x

LOXIOL® G 21 H 12-Hydroxystearic acid ££££££¢£££ 76-80 0.1-0.5 x x x

LOXIOL® G 20 Stearic acid ££££££¢¢££ 55-59 0.1-0.5 x x x

LOXIOL® G 71 S Complex ester £££££££¢££ < -20* 0.2-0.6 x x

LOXIOL® G 70 S High molecular weight poly ester £££££££¢¢£ 58-62 0.2-0.6 x x

LOXIOL® G 24 Fatty acid ester ££££££££¢£ 50-54 0.3-0.8 x x

LOXIOL® 2899 Fatty acid ester ££££££££¢¢ 65-69 0.3-0.8 x x

LOXIOL® G 25 Fatty acid ester ££££££££¢¢ 72-76 0.3-0.8 x x

LOXIOL® 2050 Paraffin wax ££££££££¢¢ 113-117 0.1-0.5 x x

LOXIOL® P 1508 PE wax £££££££££¢ 100-140 0.05-0.2 x

I ADDITIVES FOR PVC /// LUBRICANTS

*Pour point

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EXTERNAL LUBRICANTSOur external lubricants help to prevent sticking

of the hot polymer melt on metal surfaces

during calendering, extrusion, and other

processes.

LOXIOL® G 24 is Emery Oleochemicals’

external lubricant based on 100 % renewable

sources. It is suitable for the extrusion of rigid

PVC pipes and profiles as well as for injection

molding of PVC.

Key features of LOXIOL® G 24 include:

� Effective external lubricant and

release agent

� Low volatility

� Thermal stability over a wide

temperature range

� 1:1 paraffin wax and replacement

� Suitable substitute for synthetic

Fischer-Tropsch wax

� Reliable supply chain

� High performance, complete lubricant

system when combined with LOXIOL® G 59

in Pb or Ca/Zn stabilized PVC formulations

INTERNAL LUBRICANTSOur internal lubricants help to reduce friction

and viscosity of the polymer melt. They also

improve the dispersion of fillers.

LOXIOL® G 59 is Emery Oleochemicals’

innovative internal lubricant with optimal

rheological properties and low volatility. It also

improves the plate-out behavior and therefore

reduces the cleaning cycle time. LOXIOL® G 59

is suitable for rigid PVC processing, and also

for a wide range of polymers. It optimizes the

surface properties of the end product, while it

also enhances the production process.

IADDITIVES FOR PVC /// LUBRICANTS

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COMBINATION LUBRICANTS

LOXIOL® combination lubricants embody

Green Polymer Additives’ expertise in PVC

formulation. Different internal and external

lubricants as well as other additives are com-

bined and tailored for specific applications.

LOXIOL® combination lubricants provide

the following benefits:

� Use of Green Polymer Additives’ formula-

tion knowledge

� Fixed ratio of single components increase

batch-to-batch stability in dryblending and

compounding

� Optimum distribution of low-dose compo-

nents in the lubricant blend

� Ready-to-use products eliminate the risk

of weighing errors for each components

� Reduction of lubricant dosing units needed

in dryblending

Typical applications for LOXIOL®

combination lubricants include:

� Rigid PVC sheets

� Rigid PVC calender films

� PVC compounding

LOXIOL® VPG 1781 is a typical external

lubricant for PVC-U sheets when an internal

lubricant such as LOXIOL® G 59 is used. It

provides excellent lubrication in the die and

helps create a smooth surface.

LOXIOL® G 78 V is an external lubricant and re-

lease agent for calendering PVC films. The pro-

duct is free of animal-derived materials and is

used even for pharmaceutical packaging films.

I ADDITIVES FOR PVC /// LUBRICANTS

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COMBINATIONLUBRICANT

DESCRIPTIONMELTING RANGE

(°C)

DOSAGE (phr)

TRANS-PARENT ARTICLE

PVC-P PVC-U

LOXIOL® 1020 Blend of strong external lubricants. Shows better compatibility with the PVC melt than hydrocarbon waxes such as polyethylene waxes. 49-54 0.3-0.8 x

LOXIOL® 1021 Lubricant combination to reduce plastification time of filled (min. 20 phr chalk, or more) PVC-U extrusion recipes. 150-170 0.1-0.5 x

LOXIOL® 1820Lubricant blend for extrusion of PVC-U sheets, both compact and foamed (freefoam, Celuka). Can be used as stand-alone lubricant, or behavior can be fine-tuned with internal/external lubricants.

123-127 0.5-1.5 x

LOXIOL® 3376Lubricant tailored for calendering of PVC-U films, as it combines strong internal lubrication with release effect. The high melting point reduces wall covering in the mixer. Montanic wax E replacement.

82-86 0.2-0.8 x x

LOXIOL® G 70 Combination of internal and external lubricants with release effect. 52-56  0,3 – 0,8 x

LOXIOL® G 71 Liquid combination of internal and external lubricants with release effect. Suitable for rigid, flexible and paste PVC. < -2* 0.3-1.0 x

LOXIOL® G 72 Lubricant combination similar in performance to LOXIOL® G 70, but more internal. 43-47 0.3-1.0 x x

LOXIOL® G 78 Lubricant blend for PVC-U especially in calendaring with outstanding release effect. Montanic wax OP replacement. 105-115 0.2-1.2 x x x

LOXIOL® G 78 V Vegetable-derived version of LOXIOL® G 78. Slightly higher dosage might be needed. Montanic wax OP replacement. 91-101 0.2-1.2 x x x

LOXIOL® GE 2063Blend of external lubricants containing an inorganic co-stabilizer. Used in combination with tin stabilizers, mainly for foamed PVC-U extrudates.

90-130 1.75-2.5 x

LOXIOL® GS 891Blend of internal lubricants. Improves material flow. Particularly suitable for PVC-U applications with demand for high Vicat temperature.

95-101 1.5-2.0 x

LOXIOL® P 1732 Lubricant combination with excellent release effect for PVC-U films. Montanic wax OP replacement. 100-115 0.2-1.2 x x x

LOXIOL® P 2072 Blend of lubricants for foamed PVC-U sheets in tin-stabilized formulations. 100-130 0.5-1.5 x

LOXIOL® P 621Combination of internal and external lubricants with release effect. Food contact compliant version of LOXIOL® G 70. Montanic wax E replacement.

78-82 0.2-0.8 x x

LOXIOL® VPG 1781Blend of external lubricants for foamed PVC-U sheets in tin-stabilized formulations. Compared to LOXIOL® P 2072, it is more external and is also used in calcium-zinc stabilized formulations.

90-100 0.8-1.2 x x

IADDITIVES FOR PVC /// LUBRICANTS

*Solidification point

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LOXIOL® release agents are used for

calendering and injection molding of rigid

and flexible PVC. They are also used for

paste processing, and they can improve the

extrusion behavior, since release agents also

work as external lubricants. However, external

lubricants do not necessarily work as release

agents.

LOXIOL® release agents migrate to the interface

of polymer and processing machine, depending

on the particular level of compatibility with the

polymer matrix. Often LOXIOL® release agents

for PVC are based on complex esters, which are

lubricants with a polymeric structure and a high

molecular weight.

ADDITIVES FOR PVC

RELEASE AGENTS

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RELEASE AGENTS DESCRIPTIONDELIVERY

FORM

MELTING RANGE

(°C)

DOSAGE (phr)

PVC-P PVC-U

EXTR

USI

ON

CA

LEN

DER

-IN

G

INJE

CTI

ON

M

OLD

ING

PAST

E

PRO

FILE

, SH

EET

PIPE

INJE

CTI

ON

M

OLD

ING

FILM

LOXIOL® G 24 Fatty acid ester solid 50-54 0.3-0.8 x x

LOXIOL® G 70 S Complex ester solid 58-62 0.2-0.6 x x x

LOXIOL® G 71 S Complex ester liquid < -20* 0.2-0.6 x x x x o

LOXIOL® G 72 Combination lubricant solid 43-47 0.3-1.0 o x

LOXIOL® G 78 Combination lubricant solid 105-115 0.2-1.2 o o o o x

LOXIOL® G 78 V Combination lubricant solid 91-101 0.2-1.2 o o o o x

LOXIOL® P 1732 Combination lubricant solid 100-115 0.2-1.2 o o o x

IADDITIVES FOR PVC /// RELEASE AGENTS

*Pour point o Suitable x Highly suitable

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The slip performance of a plastics material is

determined by its coefficient of friction (ASTM

D1894), while the antiblocking performance is

measured via the blocking load (ASTM D3354).

A typical application for a slip agent is in

sealants for screw caps, i.e. to allow an easy

slip of the cap when opening a glass of canned

food. A typical application for an anti-block

agent is in unwinding a film roll or in denesting

of plastic cups, when adhesion of single plastic

layers needs to be minimized.

ADDITIVES FOR PVC

SLIP AND ANTI-BLOCKING AGENTS

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SLIP & ANTI-BLOCKING AGENT

DESCRIPTIONDELIVERY

FORM

MELTING RANGE

(°C)

DOSAGE (phr)

PVC-P PVC-U

EXTR

USI

ON

CA

LEN

DER

-IN

G

INJE

CTI

ON

M

OLD

ING

PAST

E

PRO

FILE

, SH

EET

PIPE

INJE

CTI

ON

M

OLD

ING

FILM

LOXIOL® E SPEZIAL Erucic acid amide solid 80-86 0.1-0.5 x x x x x x x x

LOXIOL® EBO SPEZIAL Ethylene-bis-oleamide solid 110-120 0.2-1.0 x x x x x x x

LOXIOL® EBS SPEZIAL Ethylene-bis-stearamide solid 141-147 0.05-2.0 x x x x x x x

LOXIOL® OA SPEZIAL Oleic acid amide solid 68-78 0.05-0.2 x x x x x x x x

LOXIOL® S SPEZIAL Stearic acid amide solid 95-105 0.1-0.8 x x

IADDITIVES FOR PVC /// SLIP AND ANTIBLOCKING AGENTS

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EDENOL® specialty plasticizers improve the

processability and performance of plastics.

They impart flexibility and durability to the

finished article. We offer a wide range of

plasticizers for high performance and technical

applications, including both polymeric and

monomeric plasticizers.

POLYMERIC PLASTICIZERS � Low migration and low volatility

� Various products with food contact approval

� Viscosity ranges from 650-67000 mPas at 20°C

� High permanence and weatherability

� Customized solutions available

MONOMERIC PLASTICIZERS � Excellent plasticizing properties

� Strong thermal and hydrolytic stability

ADDITIVES FOR PVC

PLASTICIZERS

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PLASTICIZER HIGH TEMPERATURE

DESCRIPTION PROPERTIESVISCOSITY RANGE

(20 °C; mPa·s)

EDENOL® T810T STAB C8/C10-Trimellitate

Premium high temperature monomeric plasticizer, stabilized with 0.5 % of inhibitor CAS-No. 6683-19-8 120-155

EDENOL® TOT STAB 2-Ethylhexyl trimellitate

Standard high temperature monomeric plasticizer, stabilized with 0.5 % of inhibitor CAS-No. 6683-19-8 approx. 300

PLASTICIZER LOW TEMPERATURE

DESCRIPTION PROPERTIESVISCOSITY RANGE

(20 °C; mPa·s)

EDENOL® DBS Dibutyl sebacate Food contact compliant monomeric plasticizer according to FDA, andalso EU food contact regulations 8-10

EDENOL® 888 Di-2-ethylhexyl sebacate Typical low temperature plasticizer for PVC 19-23

EDENOL® DOZ Di-2-ethylhexyl azelate

Alternative to DOS. Instead of using sebacic acid (C10 diacid) as a raw material, azelaic acid (C9 diacid) is made from readily available natural fats and oils. EDENOL® DOZ has exceptional low temperature performance.

18-24

PLASTICIZER POLYMERIC

DESCRIPTION PROPERTIESVISCOSITY RANGE

(20 °C; mPa·s)

EDENOL® 1208

Polymeric plasticizer

Polymeric plasticizers compliant with FDA and EU food contact regulations. A typical application is in plastisols for cap sealants. EDENOL® polymeric plasticizers with different viscosities can also be combined with monomeric plasticizers to achieve the optimum plasticizing and low-migration setup.

650-750

EDENOL® 1215 1000-1500

EDENOL® 1200 4000-6000

EDENOL® 1234 10000-13000

EDENOL® 1212Polymeric plasticizer

Food contact compliant polymeric plasticizers with higher polarity. Suitable for PVC and PVAc. Due to the higher polarity, the extraction resistance against fats and oils is further improved.

800-1200

EDENOL® 1235 6500-8500

EDENOL® 1225

Polymeric plasticizer

Polymeric plasticizers for technical applications. They show superior hydrolysis stability compared to food contact compliant alternatives. Potential applications include roof membranes and other PVC-P outdoor applications when high permanence is required in order to achieve resistance against migration and extraction of the plasticizer.EDENOL® 9789 has an outstanding viscosity, which requires special handling, and it is typically used in car wrap films to be released after years, leaving a clean and intact varnish behind.

2200-2700

EDENOL® 1250 4500-5500

EDENOL® 1233 SPEZIAL 10000-13000

EDENOL® 9789 approx. 67000

PLASTICIZER STABILIZING PROPERTIES

DESCRIPTION PROPERTIESVISCOSITY RANGE

(20 °C; mPa·s)

EDENOL® D 81 Epoxidized soybean oil Standard co-stabilizing plasticizer 450-650

EDENOL® B 316 SPEZIAL Epoxidized linseed oil

Stronger co-stabilizing plasticizer compared to epoxidized soybean oil due to a higher number of epoxy functions 1000-1400

IADDITIVES FOR PVC /// PLASTICIZERS

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EDENOL® viscosity regulators improve the

flow of PVC paste formulations by efficiently

reducing viscosity. These products aid in

deaeration of the paste system and exhibit low

volatility.

ADDITIVES FOR PVC

VISCOSITY REGULATORS

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VISCOSITY REGULATOR DESCRIPTION DELIVERY FORMVISCOSITY RANGE

(20 °C; mPa·s)DOSAGE

(phr)

EDENOL® 190 Fatty acid ester liquid 12-15 5-20

EDENOL® 192 Fatty acid ester liquid 15-17 5-20

EDENOL® 311 Fatty acid ester liquid 5-15 1-10

EDENOL® 1300 Fatty acid ester liquid 4-8 1-20

Applications of EDENOL®

viscosity regulators include:

DIP COATING � Gloves

� Electrical equipment, etc.

ROTATIONAL MOLDING � Toys

� Sporting equipment, etc.

SPRAY COATING � Automotive undercarriage coating

� Tray and box linings, etc.

SPREAD COATING � Flooring

� Tablecloths

� Tarpaulins

�Wall coverings

� Artificial leather, etc.

IADDITIVES FOR PVC /// VISCOSITY REGULATORS

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Emery Oleochemicals has developed high-

performance lubricants for C-PVC pipes,

fittings, plates and sheets.

Advantages of these products include:

� Superior in production of bright, white

end products

� Outstanding glossy surface properties

� Lowest influence on the Vicat softening

point

� Increased productivity and cost savings

by improved long run properties

� Reduced cleaning and change over time

due to very low plate-out occurrences

� Food contact approval

ADDITIVES FOR PVC

C-PVC APPLICATIONS

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PRODUCT FUNCTION DESCRIPTIONMELTING

RANGE (°C)DOSAGE

(phr)

APPLICATION

FOO

D C

ON

TAC

T A

PPRO

VA

L*

PIPES FITTINGS SHEETS

LOXIOL® 2307 Release Agent Combination lubricant 80-90 0.1-1.2 X X

LOXIOL® 2308 Improves flow Fatty acid ester 54-58 0.5-1.5 X X

LOXIOL® 2309 Internal Lubricant Fatty acid ester 58-62 0.5-2.0 X X

LOXIOL® 2310 Preventing plate-out Fatty acid 76-80 0.2-1.0 X X X

LOXIOL® 2311 Internal Lubricant Fatty acid ester 68-72 0.5-2.0 Calendering X

LOXIOL® 2312 External Lubricant Complex ester 58-62 0.2-1.0 Extrusion X

LOXIOL® 2313 Release Agent Paraffin wax 113-117 0.1-0.5 X X

LOXIOL® 2314 Internal Lubricant Fatty acid ester compound 76-80 0.8-1.5 X X

IADDITIVES FOR PVC /// C-PVC APPLICATIONS

*Depending on regional regulations

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EMERY OLEOCHEMICALS'POLYMER ADDITIVES ARESUITABLE FOR A MULTITUDE OF POLYMER APPLICATIONS

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IIADDITIVES FOR THERMOPLASTICS

IIADDITIVES FOR THERMOPLASTICS

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Fogging is the undesired formation of small

water droplets on the surface of films that are

used in food packaging and for greenhouses.

In both cases, there is a rather high difference

in temperature and relative humidity between

both sides of the film. This leads to condensati-

on of water, which becomes visible as fogging.

Fogging becomes a problem because it redu-

ces the transparency of the film. Packed food

is less visible, and plants in greenhouses have

less access to sunlight. In food packaging,

water can damage sensitive goods such as

mushrooms. Plants in greenhouses can be

damaged by bundled light, as water droplets

work as a lens.

Antifogging agents solve these issues by al-

tering the surface energy of plastics and/or

water. They inhibit the formation of water dro-

plets to create a homogeneous, transparent

water layer.

Our solutions address common issues with

traditional agricultural films by enabling light-

transmission and limiting the onset of water

droplets, therefore avoiding damage to plants

in growing tunnels.

ADDITIVES FOR THERMOPLASTICS

ANTIFOGGING AGENTS

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ANTIFOGGING AGENT

DESCRIPTIONDELIVERY

FORMDOSAGE

(%)

FOOD CONTACT

APPROVAL*

POLYMERS

PC

PE

PET

/ PB

T

PLA

PP PS

PU SB

LOXIOL® A 2 Fatty acid ester compound liquid 2.0-4.0 x x

LOXIOL® A 4 Fatty acid ester compound liquid 2.0-4.0 x x

LOXIOL® A 7 Fatty acid ester compound liquid 2.0-3.5 x x

LOXIOL® G 10 V Fatty acid ester compound liquid 0.5-2.5 x x

LOXIOL® AF 90 Fatty acid ester liquid 0.5-2.0 x x x

LOXIOL® AF 80 Fatty acid ester; recommen-ded for external application liquid 0.05-0.2 x x x x x x x

Internal vs. External Antifogging Agents

While the internal application is standard, Emery Oleochemicals' Green Polymer Additives product portfolio includes antifogging

agents for internal and external application.

LOXIOL® external antifogging agents are applied to the ready film as an aqueous or aqueous/alcoholic solution by spraying or dipping.

This method is highly flexible compared to internal antifogging agents as small lots of film can be equipped with an antifogging agent

without changing anything in the upstream processes of the film production. Furthermore, the amount of antifogging agent that is

needed for a proper effect is much lower compared to internal application.

The crucial advantage of internal antifogging agents over external ones is that internal antifogging agents provide a self-healing effect.

That means, an antifogging agent that has been removed from the film surface can be restored by additive migration from the reservoir

in the film. This is not the case for externals.

All above mentioned products are primarily internal antifogging agents. However, they are also suitable for external application.

IIADDITIVES FOR THERMOPLASTICS /// ANTIFOGGING AGENTS

*Depending on regional regulations

WITHOUT

Antifogging Agent.Water droplets scatter the light.

WITH

Antifogging Agent.Film with even water layer is transparent.

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LOXIOL® antistatic agents prevent dust

accumulation and minimize the handling

problems and risks associated with static

charge. These products impart lasting

performance and provide superior aesthetics

and clarity for a variety of packaging needs.

Applications include consumer and industrial

goods packaging, flooring in technical

environments, and sensitive electronic

components.

Advantages of Emery Oleochemicals’

antistatic agents include:

� Minimized risk of electrical discharge that

may cause fire or explosion

� Avoidance of electrical shock risk to

employees or consumers

� Reduced dust accumulation that affects

performance and appearance of plastic

products

� Improved handling during transportation,

packaging and storage

ADDITIVES FOR THERMOPLASTICS

ANTISTATIC AGENTS

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EXTERNALANTISTATIC AGENT

DESCRIPTIONDELIVERY

FORM

MELTING RANGE

(°C)

DOSAGE (%)

POLYMERS

ABS

PA

PC

PE

PET

/ PB

T

PLA

PMM

A*

POM

PP PS *

PU SAN

SB

LOXIOL® 1852

Aqueous emulsion of ionic and nonionic compounds

liquid - 0.1-1.0 x x x x x x x x x x x x x

INTERNALANTISTATIC AGENT

DESCRIPTIONDELIVERY

FORM

MELTING RANGE

(°C)

DOSAGE (%)

POLYMERS

ABS

PA

PC

PE

PET

/ PB

T

PLA

PMM

A*

POM

PP PS *

PU SAN

SB

LOXIOL® 80 XMixture of anionic and non-ionic compounds

liquid - 0.2-1.5 x x x x x x x x x x x

LOXIOL® 93 P Anionic compound solid > 350 0.2-3.0 x x x x x x x x x

LOXIOL® 1010 EU Lauric acid diethanolamide solid 38-42 0.1-2.0 x x

LOXIOL® 3366 Fatty acid ester liquid - 0.5-4.0 x x x

LOXIOL® 3380Mixture of ionic compounds and fatty acid ester

liquid - 0.5-4.5 x x x x x x x x x x

LOXIOL® 8312 High-mono GMS solid 67-71 0.2-1.5 x x

LOXIOL® 8314 High-mono GMS solid 67-71 0.2-1.5 x x

LOXIOL® EP 55 Fatty acid ester solid 64-68 0.2-4.0 x x

LOXIOL® VPA 1726 Fatty acid ester liquid - 1.0-3.0 x x x x x

Internal vs. External Antistatic Agents

While the antistatic agent is added during the

plastics processing for internal applications,

external antistatic agents can be applied onto

the surface of the finished plastics part. For

external applications, LOXIOL® 1852 is most

suitable.

IIADDITIVES FOR THERMOPLASTICS /// ANTISTATIC AGENTS

*Suitable, clouding possible at eLevated dosages

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LOXIOL® lubricants improve the flow of the

polymer melt by reducing the friction of the

polymer molecules both to each other and

to the surface of the processing machine.

The shares of both factors determining the

overall friction depend on the compatibility of

polymer and lubricant and on the dosage. The

differentiation from a release agent is often

blurred, as the higher the dosage is, the more

lubricant accumulates at the contact area to

the processing machine.

The table represents proven technology. In

case a lubricant-polymer combination is not

marked, the lubricant still can provide a benefit

depending on the respective application.

LOXIOL® release agents improve the injection

molding and calendering process by reducing

friction and allowing more efficient processing.

Our release agents help to minimize cycle

times and support continuous production.

Advantages of LOXIOL® release agents

include:

� Improved surface finish

� Prevention of surface defects caused by the

separation process

� Reduced machine wear and cleaning

frequency

� Minimized scrap

ADDITIVES FOR THERMOPLASTICS

LUBRICANTS/ RELEASE AGENTS

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PRODUCT DESCRIPTIONMELTING RANGE

(°C)

DOSAGE (%)

ABS / PS SAN / SB

PA / TPU PCPE PP

PET / PBTPLA

POM

Lubr

ican

t

Rele

ase

Age

nt

Lubr

ican

t

Rele

ase

Age

nt

Lubr

ican

t

Rele

ase

Age

nt

Lubr

ican

t

Rele

ase

Age

nt

Lubr

ican

t

Rele

ase

Age

nt

Lubr

ican

t

Rele

ase

Age

nt

EDENOL® 194 / 1 Fatty acid ester - 0.2-0.5 x

LOXIOL® 3571 Fatty acid ester - 0.5-1.5 x

LOXIOL® 3591 Combination lubricant 106-110 0.2-1.5 x

LOXIOL® 3820 Fatty acid ester - 0.2-0.5 x

LOXIOL® 8312 High-mono GMS 67-71 0.2-1.0 x x x x x x x x x

LOXIOL® 8314 High-mono GMS 67-71 0.2-1.0 x x x x x x x x x

LOXIOL® E SPEZIAL Erucic acid amide 80-86 0.1-0.5 x x x x

LOXIOL® EBS SPEZIAL Ethylene-bis-stearamide 141-147 0.05-2.0 x x x x

LOXIOL® EP 3500 Ca-stearate 150 -160 0.2-0.5 x x x x x

LOXIOL® EP 55 Fatty acid ester 64-68 0.5-1.0 x x x

LOXIOL® EP 8578 Pentaerythritol tetra stearate 60-65 0.1-1.5 x x x

LOXIOL® EP-PTS Fatty acid ester 54-58 0.2-0.5 x x x

LOXIOL® G 10 V Fatty acid ester compound < 7* 0.5-2.5 x

LOXIOL® G 12 Fatty acid ester 60-64 0.2-4.0 x

LOXIOL® G 15 Hydrogenated castor oil 83-90 0.5-2.5 x

LOXIOL® G 20 Stearic acid 55-59 0.1-0.5 x x x

LOXIOL® G 32 Fatty acid ester 54-58 1.0-1.5 x x x x x x x x

LOXIOL® G 34 R Fatty acid ester 54-58 0.5-1.5 x x

LOXIOL® G 40 Fatty acid ester - 0.5-1.5 x x x x

LOXIOL® G 53 C16/18 fatty alcohol 52-56 0.5-1.5 x x x

LOXIOL® G 70 S Complex ester 58-62 0.2-0.6 x x

LOXIOL® G 71 S Complex ester < -20* 0.2-0.6 x

LOXIOL® G 78 Combination lubricant 105-115 0.2-1.2 x x x

LOXIOL® G 78 V Combination lubricant 91-101 0.2-1.2 x x x

LOXIOL® OA SPEZIAL Oleic acid amide 68-78 0.05-0.2 x x

LOXIOL® P 1206 Fatty acid ester 56-60 0.5-1.5 x x x x

LOXIOL® P 728 Fatty acid ester 49-53 0.5-1.5 x x x x x

LOXIOL® P 861 / 3.5 Pentaerythritol tetra stearate 60-64 0.1-1.0 x x x x

LOXIOL® P 861 / 3.5 SPEZIAL Pentaerythritol tetra stearate 60-64 0.1-1.0 x x x x

IIADDITIVES FOR THERMOPLASTICS /// LUBRICANTS/RELEASE AGENTS

*Pour point

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Pentaerythritol Esters

Pentaerythritol esters with long chain

fatty acids such as stearic acid, also called

pentaerythritol tetrastearate or simply PETS,

are a class of polymer additives with a strong

release effect. They are typically used in

polycarbonate and ABS polymers, but also in

PET, PA and other plastics. These release agents

have extremely low volatility, a minimum

influence on the transparency of the finished

article and excellent thermostability.

ADDITIVES FOR THERMOPLASTICS

PENTA- ERYTHRITOL ESTERS

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PENTAERYTHRITOL ESTERS DESCRIPTIONHYDROXYL

VALUE(mg KOH/g)

MELTING RANGE (°C)

DOSAGE (%)

LOXIOL® P 861 / 3.5 PETS ester for numerous polymers and applications 20-37 60-64 0.1-1.0

LOXIOL® P 861 / 3.5 SPEZIAL PETS ester with tighter color specification for high-level transparent applications 20-37 60-64 0.1-1.0

LOXIOL® VPG 861 PETS with low hydroxyl value for high-level transparent applications 0-12 64-68 0.1-1.0

LOXIOL® EP 8578 PETS specialty ester with low hydroxyl value for PC, ABS and associated blends 0-12 60-65 0.1-1.0

LOXIOL® PTS Economic PETS ester for opaque and colored applications 10-35 54-58 0.1-1.0

The different grades of LOXIOL®

pentaerythritol esters produced by Emery

Oleochemicals offer similar benefits.

When feeding an injection molding machine

or an extruder using plastics compounds

that contain LOXIOL® pentaerythritol esters,

improved feed behavior are achieved and

granules are prevented from melting in

the feed zone (bridge formation). LOXIOL®

pentaerythritol esters also have a favorable

influence on the tool filling speed by lowering

friction.

As release agents, these additives prevent the

polymer melt from sticking to the hot machine

parts and facilitate mold release at higher

temperatures. Even in a mold with a complex

geometry, parts can be demolded easily.

LOXIOL® pentaerythritol esters also improve

the surface properties of the finished articles.

IIADDITIVES FOR THERMOPLASTICS /// PENTAERTHRITOL ESTERS

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Emery Oleochemicals’ LOXIOL® antiblocking

and slip agents reduce friction between

layers of plastic material as well as between

plastics and processing equipment. Emery

Oleochemicals’ natural-based polymer

additives effectively improve production by

preventing adhesion, especially in winding of

film rolls, bag production, and other packaging

operations.

Advantages of LOXIOL® anti-block

and slip agents product line includes:

� A variety of products suitable for extrusion

� Grades formulated for high transparency

applications

� Cost effective and highly concentrated

systems

ADDITIVES FOR THERMOPLASTICS

SLIP ANDANTIBLOCKING AGENTS

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SLIP AND ANTI-BLOCKING AGENTS

DESCRIPTIONDELIVERY

FORM

MELTING RANGE

(°C)

DOSAGE (%)

POLYMERS

ABS

PA

PC

PE

PET

/ PB

T

PLA

PMM

A

POM

PP PS

PU /

TPU

SAN

SB

LOXIOL® E SPEZIAL Erucic acid amide solid 80-86 0.1-0.5 x x x x x x x x x x x

LOXIOL® EBS SPEZIAL Ethylene-bis-stearamide solid 141-147 0.05-1.0 x x x x x x x x x x x

LOXIOL® OA SPEZIAL Oleic acid amide solid 68-78 0.05-0.2 x x x x x x x x x x x

LOXIOL® S SPEZIAL Stearic acid amide solid 95-105 0.1-0.8 x x

IIADDITIVES FOR THERMOPLASTICS /// SLIP AND ANTIBLOCKING AGENTS

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Powder Injection Molding (PIM) is an ideal

method to form complex metal (MIM) or

ceramic (CIM) parts in large quantities.

Emery Oleochemicals can supply a polyamide

based binder system as a ready-to-use solution

to be compounded with the powder to make

the feedstock. We can also supply the single

ingredients for customers who want to tailor

the binder composition to their specific

requirements.

LOXIOL® 2472 lowers the melting temperature

and improves the flowability of selected

polyamides, while LOXIOL® G 20 works as a

release agent for the feedstock.

After the forming process, solvent debinding

is done with acetone before going into thermal

debinding and sintering. Polyamides as binder

backbone provide a much better strength

both of green and brown parts compared to

polyolefines used in most catalyst or water

debinding systems.

ADDITIVES FOR THERMOPLASTICS

PIM /ADDITIVE MANU- FACTURING

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PRODUCT DESCRIPTION FUNCTIONMELTING RANGE

(°C)

DOSAGE (%)

LOXIOL® 2472 Propietary ester Lowers the melting temperature and improves the flowability of selected polyamides 71-75 50-70

LOXIOL® G 20 Stearic acid Release agent for the feedstock 55-59 max. 10

POWDER INJECTION MOLDING

Emery Oleochemicals’ binder system has

proved since the 1990s to be highly suitable for

different iron and steel powders, heavy metals

such as tungsten, porcelain, oxide ceramics

(aluminum oxide, zirconium oxide), non-oxide

ceramics (aluminum nitride, silicon nitride,

silicon carbide) and cemented carbides.

The correct choice and ratio of the binder

ingredients enable the user to cover different

powder types as well as different process

types. In addition to PIM, our binder system is

also successfully used for sheet extrusion and

additive manufacturing.

IIADDITIVES FOR THERMOPLASTICS /// PIM / ADDITIVE MANUFACTURINNG

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IIIADDITIVES FOR THERMOSETS

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In the production of thermosets, it is important

to inhibit exudation of additives during the

formation of the polymeric network.

LOXIOL® PF 320 is a complex lubricant blend

tailored for phenolic resins. LOXIOL® PF 320

counteracts the heat formation caused by

friction. Even at low dosage levels, it lowers

the melt viscosity and simultaneously, the

adhesion to the mold while increasing output

rates.

LOXIOL® release agents for thermosets are only

used internally, and should not be applied on

the mold surface.

ADDITIVES FOR THERMOSETS

LUBRICANTS / RELEASE AGENTS

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PRODUCT DESCRIPTIONDELIVERY

FORM

MELTING RANGE

(°C)

DOSAGE (%)

LOXIOL® 3571 Internal release agent preferably for reaction injection molding of polyurethane; it also provides benefits in fiber reinforced epoxy resins liquid - 0.5-1.5

LOXIOL® G 71 S Internal release agent preferably for fiber reinforced epoxy resins; it also provides benefits in reaction injection molding of polyurethane liquid < -20* 0.2-0.6

LOXIOL® EP 3500 Calcium stearate as mold release agent for phenolic resins solid 150-160 0.2-0.5

LOXIOL® PF 320

High melting lubricant for phenol formaldehyde resins, preferably in injection molding, but also in press and transfer molding processes. Provides excellent flow behavior and mild release properties. Can be combined with metal soaps in order to provide a stronger mold release effect

solid 105-109 0.5-1.5

LOXIOL® S SPEZIAL Stearic acid amide suitable as lubricant for phenolic resins solid 95-105 0.1-0.8

LOXIOL® UF 100

Melamine derivative for application preferably in urea-formaldehyde resins, but also melamine-formaldehyde resins. LOXIOL® UF 100 lowers the viscosity and improves the flow of the resin. As LOXIOL® UF 100 is able to react with the resin components and thus to integrate into the polymeric network, the risk of blooming is minimized

solid 47-51 0.2-1.5

IIIADDITIVES FOR Thermosets /// Lubricants / Release Agents

*Pour point

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IVADDITIVES FOR ELASTOMERS

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EDENOL® specialty plasticizers improve the

processability and performance of plastics.

They impart flexibility and durability to the

finished article. We offer a wide range of

plasticizers for high-performance and technical

applications, including both polymeric

plasticizers and monomeric plasticizers.

POLYMERIC PLASTICIZERS � Low migration and low volatility

� Various products with food contact approval

� Viscosity ranges from 650-13000 mPas at 20°C

� High permanence and weatherability

� Customized solutions available

MONOMERIC PLASTICIZERS � Excellent plasticizing properties

� Strong thermal and hydrolytic stability

ADDITIVES FOR ELASTOMERS

PLASTICIZERS

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PLASTICIZER HIGH TEMPERATURE

DESCRIPTION FUNCTION

EDENOL® T810T STAB C8/C10-Trimellitate

An exceptional high temperature plasticizer for NBR, NBR-PVC, HNBR, CR, CM, CSM and Vamac compounds. It is characterized by extremely low volatility, good resistance to extraction by water and low migration into other polymers. It also confers good low temperature properties particularly after heat ageing.

EDENOL® TOT STAB 2-Ethylhexyl trimellitateAn excellent high temperature plasticizer for NBR, NBR-PVC, HNBR, CR, CM and CSM compounds. It is characterized by low volatility, good resistance to extraction by water and low migration into other polymers.

PLASTICIZER LOW TEMPERATURE

DESCRIPTION FUNCTION

EDENOL® 102 Fatty acid ester An excellent low temperature plasticizer for NBR, NBR-PVC, CR, ACM and ECO compounds. Good compression set properties particularly at low temperature.

EDENOL® 111 Butyl carbitol adipateAn excellent low temperature plasticizer for a wide variety of rubbers including NBR, NBR-PVC, HNBR, CM, CSM, ACM and ECO. Due to its low volatility, EDENOL® 111 is effective over a broad range of temperatures.

EDENOL® 123 Butyl carbitol formal An exceptional low temperature plasticizer for NBR, NBR/PVC and CR compounds.

EDENOL® 181 Di-(2-butoxy triglycol) adipate

A high-performance plasticizer for many synthetic rubbers particularly HNBR, ECO, ACM and Vamac. An effective plasticizer over a wide range of temperatures.

EDENOL® 888 Di-2-ethylhexyl sebacate An excellent low temperature plasticizer for NBR, NBR-PVC, CR , CSM and CM compounds. It also demonstrates low volatility and good resistance to extraction by water.

EDENOL® DBS Dibutyl sebacate An excellent, well-known low temperature plasticizer for NBR, NBR-PVC and CR compounds. Relatively high volatility

EDENOL® DOZ Di-2-ethylhexyl azelateAlternative to DOS. Instead of using sebacic acid (C10 diacid) as a raw material, azelaic acid (C9 diacid)is used, which is made from readily available natural fats and oils. EDENOL® DOZ has exceptional low temperature performance.

POLYMERIC PLASTICIZER

DESCRIPTION FUNCTION

EDENOL® 206

Polymeric plasticizer

Polymeric plasticizers compliant with FDA and EU food contact regulations. Excellent oil and solvent resistant plasticizers for NBR, NBR-PVC, HNBR, CR, CSM and CM compounds. Low migration with many polymers and good high temperature properties. Useful for many oil and solvent resistant applications.

EDENOL® 210

EDENOL® 240

EDENOL® 299

EDENOL® 202

Polymeric plasticizer

Polymeric plasticizers for technical applications. They show superior hydrolysis stability compared with food contact compliant alternatives. Excellent oil and solvent resistant plasticizers for NBR, NBR-PVC, HNBR, CR, CSM and CM compounds. Low migration with many polymers and good high temperature properties. Useful for many oil and solvent resistant applications.

EDENOL® 222

EDENOL® 298

IVADDITIVES FOR ELASTOMERS /// PLASTICIZER

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52

The LOXIOL® product portfolio for elastomers

includes antistatic agents, lubricants, release

agents and slip agents, with all additives being

dosed into the compound, and not on the

mold surface (external application). These

products are not only ideal for compounders

of rubbers and other elastomers, but also for

manufacturers of specialized additive blends

for these applications.

A widely used antistatic agent in rubber

is LOXIOL® 3380. It provides an effective

protection against static charge.

LOXIOL® P 861/3.5 and LOXIOL® G 20 are proven

as a release agents for elastomers. LOXIOL®

lubricants and fatty acid amide slip agents

complete the additive portfolio for elastomers.

ADDITIVES FOR ELASTOMERS

ADDITIONALADDITIVES

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53

PRODUCT DESCRIPTIONANTI-

STATIC AGENT

LUB RI-CANT

RELEASE AGENT

SLIP AGENT

DELIVERY FORM

MELTING RANGE

(°C)

DOSAGE (phr)

LOXIOL® 3366 Fatty acid ester x liquid - 0.5-4.0

LOXIOL® 3380 Mixture of ionic compounds and fatty acid ester x liquid - 0.5-4.5

LOXIOL® 3820 Fatty acid ester x liquid - 0.2-0.5

LOXIOL® E SPEZIAL Erucic acid amide x x solid 80-86 0.1-0.5

LOXIOL® EBS SPEZIAL Ethylene-bis-stearamide x x solid 141-147 0.05-2.0

LOXIOL® EP 3500 Ca-stearate x solid 150-160 0.2-0.5

LOXIOL® G 20 Stearic acid x solid 55-59 0.1-0.5

LOXIOL® G 70 S Complex ester x solid 58-62 0.2-0.6

LOXIOL® G 78 Combination lubricant x solid 105-115 0.2-1.2

LOXIOL® G 78 V Combination lubricant x solid 91-101 0.2-1.2

LOXIOL® OA SPEZIAL Oleic acid amide x x solid 68-78 0.05-0.2

LOXIOL® P 1732 Combination lubricant x solid 100-115 0.2-1.2

LOXIOL® P 728 Fatty acid ester x x solid 49-53 0.5-1.5

LOXIOL® P 861 / 3.5 Pentaerythritol tetra stearate x x solid 60-64 0.1-1.0

LOXIOL® S SPEZIAL Stearic acid amide x x solid 95-105 0.1-0.8

IVADDITIVES FOR ELASTOMERS /// ADDITIONAL ADDITIVES

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54

EMEROX® AZELAIC ACIDCan be utilized for a wide range of applications that include nylon, engineering plastics, polyamide hot melts, urethane elastomers as well as polyester films and adhesives.

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55

VAZELAIC ACID

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56

Polymeric Building Blocks

EMEROX® azelaic acid is produced via Emery

Oleochemicals’ proprietary ozonolysis

technology which uses the powerful reactivity

of ozone to cleave oleic acid into azelaic and

pelargonic acid. EMEROX® 1144 azelaic acid

was developed specifically for the preparation

and modification of high molecular weight

polymers. The unique characteristics make it

an excellent choice for linear polyamides that

are formed by the reaction of EMEROX® azelaic

acid with diamines. These polyamides use

either EMEROX® 1144 as the principal dibasic

acid component (e.g. PA 6,9 Nylon) or as a

dibasic acid modifier.

The introduction of EMEROX® 1144, a linear

nine-carbon structure, improves the polymer

low-temperature impact strength without

sacrificing high temperature performance

of linear polyamides. Furthermore, linear

polyamides utilizing EMEROX® 1144 enable

products that possess excellent abrasion

resistance, low water absorption and high

impact resistance.

Functional esters of EMEROX® 1144 can be

used as components in urethane and as a

source of soft segments in co-polyester fibers,

imparting good low temperature performance

with hydrolytic resistance.

AZELAIC ACID

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PRODUCT CHEMISTRY DESCRIPTION

EMEROX® 1110Azelaic Acid

Standard technical grade

EMEROX® 1144 Polymer grade with excellent color/color stability and low monomer content

EMEROX® azelaic acids, a linear nine carbon

dicarboxylic acid, derived from natural,

renewable sources can be utilized for a wide

range of applications that include nylon

engineering plastics and fibers, polyamide hot

melts, urethane elastomers as well polyester

films and adhesives.

EMEROX® azelaic acid is extremely versati-

le offering a good balance of properties and

unique molecule attributes extended to

derivatives. Key features include:

� Excellent flexibility

� Improved polymer low-temperature

impact strength, without sacrificing high

temperature performance

� Excellent hydrolysis resistance

� Low water absorption

� High impact resistance

� Improved solubility characteristics

� Outstanding low temperature properties

VADDITIVES FOR EMEROX AZELAIC ACID /// AZEALIC ACID

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CREATING VALUEA|Awww.emeryoleo.com

CREATING VALUE FOR OUR CUSTOMERS, ANYWHERE IN THE WORLD.

Global Network

Emery Oleochemicals' operations are supported by a global workforce and an extensive distribution network covering over 50 countries

worldwide. Our technical and industry experts located around the world are ready to help you select the best product to meet your

specific requirements.

The availability of our products is subject to regional demand and regulations. Certifications associated with food contact approval are

determined by regional requirements. Detailed information and food contact certifications are available upon request.

Contact us today and discover why Emery Oleochemicals should be your First Choice in Sustainable Polymer Additives.

London

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60CREATING VALUE | www.emeryoleo.com

Disclaimer: The content in this document is provided on an “as is” and “as available” basis purely for informational purposes and does not constitute any warranty, whether express,implied or statutory, including but not limited to warranties or guarantees of merchantability, fi tness or suitability for a particular purpose nor any representations of a bindingnature. EMERY OLEOCHEMICALS EXPRESSLY DISCLAIMS ANY RESPONSIBILITY FOR THE SUITABILITY OF THE PRODUCTS FOR ANY SPECIFIC OR PARTICULAR PURPOSESINTENDED BY THE USER. Suggestions for the use and application of the products and guide formulations are solely for informational purposes only and you are advised to carryout any necessary steps to test the suitability of the products for your intended processes and purposes. You are solely responsible for compliance with all applicable laws andregulations in use of the products including any third party intellectual property rights and shall continue to bear all liability or risk arising from use of the products. All indicationsmarked with a TM or ® symbol are trademarks belonging to legal entities within the Emery Oleochemicals group of companies unless otherwise indicated.

Release 02/2020 | Subject to alteration & errors and omissions excepted.

Emery Oleochemicals GmbHPaul-Thomas-Strasse 5640599 Düsseldorf, GermanyT | +49 211 5611 2000E | [email protected]

Emery Oleochemicals LLC4900 Este AvenueCincinnati, Ohio, 45232 USAT | +1 513 762 2500E | [email protected]

Emery Oleochemicals (M) Sdn BhdLot 4, Jalan Perak, Kawasan Perusahaan42500 Telok Panglima Garang,Selangor, MalaysiaT |+603 3326 8686E | [email protected]