Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon:...

37
Fariborz Parhizgar Institute for research in Fundamental Science 1

Transcript of Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon:...

Page 1: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Fariborz ParhizgarInstitute for research in Fundamental Science

1

Page 2: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Intro.

•Transistors (From Ge to C)• Importance of Graphene

Model

•monolayer Graphene•Bilayer Graphene

conclusion

•Bilayer: a good condidatefor FET

2

Page 3: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

GeC

3

Page 4: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Smallsize

Highmobility

2 importantProperties

that atransistorsmust have

4

Page 5: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

5

Page 6: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

6

Page 7: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Wallace Phys. Rev. 104, 666Geim et. al. Nat. Mat. 6, 183

7

Page 8: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Carbon: smallest atom in group 4

sp2 orbitals which makes σ-bondpz Orbital which makes π-bond

2 2 2:1 2 2C S S P

8

Page 9: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Goodcondidate to

maketransistors

Crystalupto nm

sizes

Highmobility

~ 105

cm2/Vs

9

Page 10: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

MonolayerGraphene

10

Page 11: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Honeycomb lattice is not a Bravious Lattice

� Hoping of PZ Orbitals

† . .ij i jij

H t C C H C< >

= +å

11

Page 12: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Taking Fourier Transform:

1 2

( )

*( ),

( ) [1 ]

pA A

B Bp

ik a ik a

E f kH

f k E

f k e e

y yy y

g × ×

æ öæ ö æ öç ÷=ç ÷ ç ÷ç ÷è ø è øè ø

= + +r rr r

r

r

r

1 2 2 1( ) 3 2cos 2cos 2cos ( )pE k E k a k a k a a= ± + × + × + -r r rr r r r

12

.,( ) iik ri

ic k c ea a=å

Page 13: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Two independent K-Point

13

Page 14: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Expanding the function f(k):

� massless Dirac Fermions

�Where is the Pauli matrix for pseudospins

( ) ( )'F x y

Kf k v k ik

= ± íî

H =

ˆ.k

H ks=år

r

s

( ) FE k v k=610 / / 300Fv m s c: :

14

Page 15: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Absence of e-backscattering:

Castro Neto et. Al. Rev. Mod. Phys. 81,109

ˆ.k

H ks=år

r

( ) ( )( )

( ) ( )( )

( )

1 11( )2 2

1 1( )

' '2 21

( )2

x y x y

x y x y

x y

i k x k y i k x k yI i i

i q x k y i q x k yII i i

i k x k yIII i

rr e ese se

a br e es e s e

tr ese

j p j

q p q

j

y

y

y

+ - +

-

+ - +

-

+

æ ö æ ö= +ç ÷ ç ÷

è ø è øæ ö æ ö

= +ç ÷ ç ÷è ø è øæ ö

= ç ÷è ø

10sgn( ), ' sgn( ), tan ( / )y xs E s E V k qq -= = - =

15

Page 16: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Quasi particles can not be trappedyour PC will not turn off

16

Page 17: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

BilayerGraphene

17

Page 18: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Most possible config.

18

Page 19: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

† †, , , , 1, , 2, ,

† †4 1, , 2, , 4 2, , 1, ,

†3 1, , 2, ,

( . .) ( . .)

( . .) ( . .)

( . .)

m i m j j jij m j

i j i jij m ij m

i jij m

H t a b H C t a a H C

tv a b H C tv a b H C

tv b b H C

s s s ss s

s s s ss s

s ss

^< >

< > < >

< >

= - + - +

- + - +

- +

å å

å å

å

19

Page 20: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

T.Chakraborty et. Al. advance in phys. April 2010

20

Page 21: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Fourier transform:*

4* *

† 4 3*

4*

4 3

( ) ( )( ) ( ) ( )

( ) ( )( ) ( )

( ) ( ) ( )k

f k t v f kf k v f k v f k

H k kt v f k f k

v f k v f k f k

^

^

æ öDç ÷

Dç ÷= Y Yç ÷-Dç ÷ç ÷-Dè ø

å

† † † † †1, , 1, , 2, , 2, ,( ) ( , , , )k k k kk a b a bs s s sY =

3.

1( ) ( )iik d

Fi

f k t e v q q=

= Få ;

21

Page 22: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Dispersion Relation:

� Independent of

2 22 2 2 2 2 2 2 4( ) / 4

2 4t Vv p v p V t te ^

^ ^= + + - + +

( )kF

22

Page 23: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

We go to2-bandmodel

LowEnergy is

preferable

Smaller is(usually)simpler

23

Page 24: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

In low energy limit ( ):

0

/ 2 0 00 / 2 0 0

0 / 2 00 0 0 / 2

V tV

Kt V

V

^

^

æ öç ÷ç ÷=ç ÷-ç ÷

-è ø

4*

41

4

4

0 0( ) 0 00 0

0 0

i i

i

i i

i i

pe v pef k v pe

Kv pe pe

v pe pe

f f

f

f f

f f

-

-

-

æ öç ÷ç ÷= ç ÷ç ÷ç ÷è ø

32

3

0 0 0 00 0 00 0 0 00 0 0

i

i

v peK

v pe

f

f

=

-

æ öç ÷ç ÷ç ÷ç ÷è ø

0 1 2H K K K= + +

te ^<<

24

Page 25: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

using degenerate 2nd order perturbation:

McCann et. al. PRL 96, 086805

Nilsson et. al. PRB 78, 045405

20 0 0 0 2 0 0 1 1 1 1 0

0

1' [ ] ' 'l P HP l l P K K P l l P K P PK P lE K

l l= + +-

† 2 †

32

1 00 ( ) 010 12 2( ) 0 0low

VH vm

p pp p

æ ö æ ö æ ö-= + +ç ÷ ç ÷ ç ÷-è øè ø è ø

25

Page 26: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

T.Chakraborty et. Al. advance in phys. April 2010

26

Page 27: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Experimental evidence of the gap:

Ohta et. al. Science 313, 951

27

Page 28: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Low energy band with the gap:

at momentum:

2 22 2 2 2 2 2 2 4( ) / 4

2 4t Vv p v p V t te ^

^ ^= + + - + +

2 2

t VUV t

^

^

=+

%

2 222

2 2 2

24

V tVpv V t

^

^

+=

+

.2V eV:

28

Page 29: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Gate VoltageChange the

Fermienergy.

Using Dualgated BLG:

2 tuningparameter

29

Page 30: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

30

Page 31: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

BilayerFET

31

Page 32: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Digital Electronics

Pseudospintronics

Terahertz Technology

Infrared nanophotonics

32

Page 33: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

SLG isGapless

On/offratio ~ 5

We needGap

33

Page 34: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Uniaxial Strain

Substrate Interaction

Lateral Confinement

Biased BLG

34

Page 35: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Advantages

•Gap~Hundereds of meV•High On/Off ratio

Disadvantages

•Low mobility•Undesirable shape

35

Page 36: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

Gap upto .3eV

On/off ratio: (100-2000)

Nano lett. 2010,10,715

36

Page 37: Graphene field Effect Transistorsphysics.ipm.ac.ir/courses/pdfseminar1/parhizgar1.pdf · Carbon: smallest atom in group 4 sp2 orbitals which makes σ-bond p z Orbital which makes

� Thanks for yourattention