Gluability Variation of - World Bamboo Pannipa.pdf · 26.78. 25.82; 24.38. 23.40; 24.99. 24.07;...

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Pannipa Chaowana Materials Science and Engineering School of Engineering and Resources Walailak University, Thailand Gluability Variation of Dendrocalamus asper for Bamboo Composites “9 th World Bamboo Congress” 11 April 2012 University of Antwerp, Antwerp, Belgium

Transcript of Gluability Variation of - World Bamboo Pannipa.pdf · 26.78. 25.82; 24.38. 23.40; 24.99. 24.07;...

  • Pannipa

    Chaowana

    Materials Science and Engineering School of Engineering and Resources

    Walailak

    University, Thailand

    Gluability

    Variation of Dendrocalamus

    asper

    for Bamboo Composites

    “9th

    World Bamboo Congress”11 April 2012

    University of Antwerp, Antwerp, Belgium

  • Introduction

  • Figure

    Culm

    characteristic of D. asper

    Internode

    NodeDiaphragm

    2 cm25 cm

    Culm-wall thickness

    2 cm

  • Figure

    Microstructure of D. asper

    Outer surface

    Inner surface

    Metaxylem

    vessel Phloem

    Parenchyma cells

    Fiber cells

    Fiber cells

  • Outer layer

    Middle layer

    Inner layer

    Horizontal direction Vertical direction

    Figure

    Variation of microstructure of bamboo culm

    Top

    Middle

    Bottom

  • Table

    Variation of chemical composition of D. asper

    Chemical compositions

    Top Middle Bottom

    Node Internode Node Internode Node Internode

    Holocellulose 75.65 76.72 76.36 77.36 75.59 76.31

    Alphacellulose 67.07 67.33 68.53 67.67 68.59 69.64

    Lignin 30.08 26.47 30.86 27.19 30.41 27.21

    Ash 2.29 1.07 1.95 0.95 1.59 0.92Alco.+Benzene

    Solubility 5.55 7.44 6.67 6.18 3.75 5.85

    Hot WaterSolubility 7.39 9.63 7.51 8.36 6.47 8.86

    Cold Water Solubility 5.10 6.87 5.43 14.05 4.23 6.50

    1% NaOHSolubility 26.78 25.82 24.38 23.40 24.99 24.07

    Source: Kamthai, S. 2003. Alkaline sulfite pulping and ECF-

    bleaching of sweet bamboo (Dendrocalamus

    asper

    Backer). M.S. Thesis, Kasetsart

    University, Thailand

  • Objectives

    To determine the pH value and buffer capacity in each location of bamboo culms

    To investigate the surface wettability through contact angle measurement

    To measure the effective penetration of liquid adhesive into bamboo in different locations and surfaces of the culms.

  • Materials

    D. apser

    culms were cut from plantation in Thailand.

  • Methods and Results

    pH value and buffer capacity

    Bottom

    Middle

    Top

    Bamboo powder

    Soaked in distilled water and then stirred

    Titrated with

    0.01 N H2

    SO40.01 N NaOH

    Record the pH change after acid or alkaline addition

  • Figure

    The initial pH value of D. asper

    in relation to the culm

    location

  • Figure

    The pH changes of D. asper, in relation to the culm

    location, during the acid and alkaline addition.

    0.01 N H2 SO4 (ml) 0.01 N NaOH (ml)

    2550

    Acid addition

    Alkaline addition

  • Wettability

    Bottom

    Middle

    Top

    Outer surface

    Inner surface

    Culm

    wall surface

    Bamboo

    Distilled water

    Measure the contact angle after drop the distilled

    water on bamboo surface

  • Figure

    Average value of contact angle of D. asper, separated by culm

    location and surface

  • Adhesive penetration

    Bottom

    Middle

    Top

    Outer surface

    Inner surface

    Culm

    wall surface

    Image and measure the average adhesive penetration into bamboo surface

    Bamboo

    UF adhesive layer

    X1 X2 X3

  • Figure

    Average value of adhesive penetration on the surface of D. asper, separated by culm

    location and surface

  • Conclusions

    The pH value of D. asper

    is on acid side. It does not vary

    along the location of the culm.

    Buffer capacity of D. asper

    is more stable toward alkaline

    rather than acid. There are slightly differences in the values along the culm

    location.

    Wettability

    of D. asper

    decreases from the bottom to the top

    part of the culm. Furthermore, wettability

    of bamboo culm outer surface is found to be lower than inner part.

    The adhesive penetration of D. asper

    at different culm

    location and surface is signification different from one other. The penetration also decreases from the bottom to the top part of the culm. Moreover, the penetration on culm

    inner surface is

    greater than that of outer and the culm

    wall surface.

  • Further forecasts

    The appropriate layer structure for production of

    Laminated Bamboo Lumber and Plybamboo

  • Figure

    The possibility of layered structure on laminated bamboo lumber and plybamboo

    manufacture

    Type 1 Type 2 Type 2

  • The further study of the density varitaion

    of bamboo strand that influence on physical and mechanical properties of Oriented Strand Board and Oriented Strand Lumber

  • Acknowledgements

    School of Engineering and Resources, Walialk

    University, Thailand

    Wood Science and Engineering Research Unit, Walilak

    University

    Dynea

    Krabi, Co., Ltd

  • Thank you for your attention

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