GHS

GHSWhat is it and how will it affect me?

By Sheryl Hoffmann

The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals.

The GHS is a single internationally agreed system of

classification and labelling of chemicals, which was developed under the auspices of the United Nations.

The GHS includes harmonised criteria for:• the classification of physical hazards (such as

flammability), • health hazards (such as carcinogenicity) and • environmental hazards

What is the GHS?

How will I be affected?

The new Work Health and Safety Act, Regulations & Codes of Practice will come into effect, in all states in Australia.

All states will have the same legislation.

The Hazardous Substances part of this new legislation is based on GHS.

On 1st January 2012

The Purple Book

The Companion Guide

Different countries have different laws and regulations, as well as different definitions of what is hazardous, thus manufacturers need to produce different labels & MSDS’s for different countries. This is complex and costly and impacts on both protection for chemicals users and to trade.

Why was the GHS Developed?

enhance the protection of people and the environment by providing an internationally comprehensive system for chemical hazard communication;

provide a recognised framework for those countries without an existing system;

reduce the need for duplicative testing and evaluation of chemicals; and

facilitate international trade in chemicals whose hazards have been properly assessed and identified on an international basis.

What will be achieved?

How is the GHS to be applied?

Physical Hazards

Health Hazards Environmental Hazards

CLASSIFICATION

ExplosivesFlammable GasesFlammable AerosolsOxidizing GasesGases Under PressureFlammable LiquidsFlammable SolidsSelf-Reactive SubstancesPyrophoric Liquids

Physical Hazards Pyrophoric Solids Self-Heating

Substances Substances which, in

contact with water, emit flammable gases

Oxidizing Liquids Oxidizing Solids Organic Peroxides Corrosive to Metals

Acute Toxicity Skin Corrosion/Irritation Serous Eye Damage/Eye Irritation Respiratory or Skin Sensitization Germ Cell Mutagenicity Carcinogenicity Reproductive Toxicology Specific Target Organ Toxicity – Single Exposure Specific Target Organ Toxicity – Repeated

Exposure Aspiration Toxicity

Health Hazards

Hazardous to the Aquatic Environment

Acute aquatic toxicityChronic aquatic toxicity

Bioaccumulation potentialRapid degradability

Environmental Hazards

Acute Toxicity

COMMUNICATION

Labels

Safety Data Sheets (SDS)

Signal Words eg Danger (or Warning) Hazard Statements eg H224 Extremely flammable

liquid and vapour Precautionary Statements

Prevention eg P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.

Response eg P303 IF ON SKIN (or hair) Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

Storage eg P403 Store in a well-ventilated place. Keep cool.

Disposal eg P501 Dispose of contents/container to .... Hazard Pictogram

Label Elements

Explosive (Exploding bomb)

Flammability (Flame)

Gases under pressure (Gas cylinder)

Nine Hazard Pictograms

Oxidising (Flame over circle)

Chronic Health hazards (Health hazard)-includes carcinogens, reproductive toxins, mutagenic, specific target organ toxicity, and aspiration hazard


Corrosive (Corrosion)

Acute toxicity (Skull and crossbones)


Certain health Hazards(Exclamation mark) (e.g. sensitisers)

Environmental hazard (Environment)


Product Identifier (eg name) Proper Shipping name & UN Number (if Dangerous Good) The name, address & phone number of the Australian

importer or manufacturer Identity & proportions (if a mixture) Signal Word eg Danger or Warning Hazard Statement Hazard Pictogram Precautionary Statements Any other info eg first aid, emergency procedures Expiry date of the chemical if applicable

Label Information

Read label before use. Keep out of reach of children

FLAMMABLE LIQUID, TOXIC N.O.S (Flammosol)

UN 1992Contains:Hydrocarbon solvent 95%Toxicole 5% DANGER

Highly flammable liquid and vapour Toxic if swallowed Causes skin irritation

IF ON SKIN (or hair): Take off contaminated clothing and wash before re-use.

In case of fire: Use powder for extinction.

Rinse skin using plenty of soap and water. Keep away from sparks and open flames. – No smoking.

If skin irritation occurs: Get medical advice/attention. Keep container tightly closed.

IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.

Ground/bond container and receiving equipment.

Rinse mouth. Use explosion-proof electrical equipment.Use only non-sparking tools.Take precautionary measures against static discharge.

Store locked up in a well-ventilated place. Keep cool. Wear protective gloves and eye and face protection.

Wash hands thoroughly after handling.Dispose of contents/container in accordance with State regulations.

Do not eat, drink or smoke when using this product.

Refer to the Safety Data Sheet before use. Madeup Chemical Company, , , My State. Telephone: 1200 000 000 www.madeup-chemical-company.com.au

http://www.madeup-chemical-company.com.au/

The label must be written in English and include the following:

the product identifier, anda hazard pictogram and hazard statement that are consistent with the correct classification of the chemical.

Decanted Substances

Flammosol

Highly flammable liquid and vapour Toxic if swallowed Causes skin irritation

Decanted Label

If the product identifier of an unlabelled chemical is not known, this should be clearly marked on the container, for example by attaching a label to the container with the statement: Caution - Do Not Use - Unknown Substance.

Containers Found Without Correct Labelling

Original label on a consumer is sufficient if it is reasonably foreseeable that the hazardous chemical will be used in the workplace only:

in a quantity that is consistent with consumer household use, and

in a way that is consistent with consumer household use, and

in a way that is incidental to the nature of the work carried out by a worker using the chemical

Consumer Products

Work Health and Safety Act (final version released 26 Nov 2010) Work Health and Safety Regulations – Chapter 7: Hazardous Chemicals(draft released 7th Dec 2010) Priority Code of Practices (draft released 7th Dec 2010) Labelling of Workplace Hazardous Chemicals Code of Practice Preparation of Safety Data Sheets for Hazardous Chemicals Code of

Practice Additional Code of Practices to be released in 2011 Chemicals - General Risk Management Chemicals - Storage and Handling of dangerous goods

LEGISLATION

Register

SDS

Labelling

RESPONSIBILITIES

7.1.23 Hazardous chemicals register

(1) A person conducting a business or undertaking at a workplace must maintain a register of hazardous chemicals used, handled or stored at the workplace.

Register

(2) The register must include:(a) a list of hazardous chemicals used, handled or stored; and(b) the current safety data sheet for each chemical listed

Register

(3) The person must ensure that the register is readily available to:

(a) a worker involved in using, handling or storing a hazardous chemical; and

(b) anyone else who is likely to be affected by a hazardous chemical at the workplace.

Register

Code of PracticePreparation of Safety Data Sheets for Hazardous Chemicals Code of Practice

ChemWatchChemWatch can produce GHS Safety Data Sheet but WHS Regulations 7.1.21 clearly state the SDS must be obtained from the Australian manufacturer or importer.

Safety Data Sheets (SDS)

Section 1 - Identification: Product identifier and identity for the chemical;

Section 2 – Hazard(s) identification; Section 3 - Composition and information on

ingredients;Section 4 - First-aid measures;Section 5 - Fire-fighting measures;Section 6 - Accidental release measures;Section 7 - Handling and storage, including how

the chemical may be safely used; Section 8 - Exposure controls and personal

protection;

A safety data sheet must include:

Section 9 - Physical and chemical properties;

Section 10 - Stability and reactivity; Section 11 - Toxicological information; Section 12 - Ecological information; Section 13 - Disposal considerations; Section 14 - Transport information; Section 15 - Regulatory information; Section 16 - Any other relevant

information.

A safety data sheet must include:

Manufacturers and importers Ensure that the chemical is correctly labelled. However, you may not need to relabel a

hazardous chemical if it is a consumer product that retains its original label, and the chemical is only used in workplaces in household quantities and in a way that is incidental to the nature of the work activities undertaken by any worker who uses the chemical.

Labelling

SuppliersMust not supply a hazardous chemical to a

workplace if the supplier knows, or ought reasonably to know, that the chemical is not correctly labelled.

Labelling

Person who is conducting a business or undertaking

Ensure that any hazardous chemical that is used, handled or stored at the workplace is correctly labelled, in accordance with Schedule 9 of the WHS Regulations, except where:◦ the hazardous chemical is a consumer product,

retaining its original label and only used in workplaces in household quantities and in a way that is incidental to the nature of the work, or

◦ a hazardous chemical is in transit.

Labelling


Ensure that a hazardous chemical is correctly labelled if the chemical is manufactured at the workplace; or transferred or decanted from the chemical’s original container at the workplace.

NB: Manufacture includes the activities of packing, repacking, formulating, blending, mixing, making, remaking and synthesising.

Labelling


Ensure, so far as reasonably practicable, that containers are correctly labelled while holding a hazardous chemical.

Ensure that containers that are labelled for holding a hazardous chemical are used only for the use, handling or storage of the hazardous chemical.

Labelling


The above three duties do not apply if the hazardous chemical is used immediately after being put into the container and the container is thoroughly cleaned after the chemical has been used, handled or stored so it is in a condition it would be in if the container had never contained the chemical.

Ensure, so far as is reasonably practicable, that a hazardous chemical in pipe work is identified by a label, sign or another way on or near the pipe work.

Labelling

GHS Classification = Physical + Health + Environmental Hazards

Signal Words, Hazard Statement & Precautionary Statements

GHS Pictograms Register Safety Data SheetsLabel

SUMMARY

Has links to UN GHS documents, including the Companion Guide & the Purple Book

http://safeworkaustralia.gov.au/SafetyInYourWorkplace/HazardousSubstancesAndDangerousGoods/GHS/Pages/GHS.aspx

Safe Work Australia Website

GHS

Documents

Transcript of GHS