General Info - Novacron Ls
Transcript of General Info - Novacron Ls
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Contents
Page
Innovative chemistry............................................................................................................................3
Benefits of the system.................................................................................................................... 45
Dye selection NOVACRON LS ...........................................................................................................6
Combination systems NOVACRON LS...............................................................................................7
A new standard of tinctorial strength...................................................................................................8
Comparison of build-up .......................................................................................................................9
Minimum salt .............................................................................................................................. 1014
Exhaustion / fixation ................................................................................................................... 1516
Application properties........................................................................................................................17
Influence of liquor ratio......................................................................................................................18
Migration method........................................................................................................................ 1921
Washing off .......................................................................................................................................22
Right First Time.......................................................................................................................... 2327
Dyeing auxiliaries ....................................................................................................................... 2830
Handling reactive dyes......................................................................................................................31
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NOVACRON LS
The NOVACRON LS dyes are innovative bi-reactive dyes, with very high tinctorial strength, for hot dyeing.
Highly compatible range for a wide shade spectrum.The NOVACRON LS concept is the first and unique low salt range on the market. Only 1/3 of the salt
amount required by standard reactive dyes is needed.All these properties play a great part in the outstanding reproducibility and environmentally orientedbehavior of the NOVACRON LS dyes.
Highlights of NOVACRON LS ...and what they mean for the dyer
Outstanding ecological properties
- fixation over 80%- drastically reduced salt usage (1/3 that ofreactive dyes available on the market)
Reduced costs and worries - fulfillingsevere environmental requirements
- much less dye in waste water and- much less salt in waste water, bothresulting in lower environmental costs
- less corrosion of machinery and concrete- much less salt in water positively impactsefficiency of biological water treatmentunit
Highly concentrated dyes withhomogenous application propertiesand outstanding reproducibility
- high tinctorial strength and fixationover 80%
- drastically reduced salt usage- low sensitivity to liquor ratio variations
- excellent compatibility of the dyes inthe range, on-tone build-up and verygood levelness
High productivity, right first timedyeings
- unique reproducibility lab to bulk and bulkto bulk
- fewer corrections, fewer re-dyeings- much reduced time for handling anddissolving of salt
- automation of salt dosing facilitated- lowercosts for storage and for disposal ofpackaging material
- very deep shades feasible economicallyand ecologically
- substantial savings on cost of salt and saltstorage
- no need for highly skilled personnel
Ideal for one bath dyeing of PES/CEL(LS Superfast)
- excellent suitability, thanks to the much
reduced amount of salt and the lowsensitivity to liquor ratio variations
- very robust process
Substantial time and cost saving
- short highly productive dyeing process(6 hours only)
- excellent reproducibility, even withoutskilled personnel
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Benefits of the system
A new standard of tinctorial strength
The first low-salt range
High fixation
Superior application properties for better reproducibility of the dyeings
Excellent range for dyeing PES/CEL blends in a one bath process: LS
Superfast
Molecular engineering
chromophore bridge chromophore
reactive group reactive group
2 reactive groups exclusive patentedbridge
2 chromophores
- medium reactivity
- stable fiber-dye linkage(thanks to two groups)
- gives molecule goodflexibility
- selected for maximumsolubility
- promote high affinity
- give high color strength
- allow improvement offastness or shade
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Benefits of the system
Degree of fixation / exhaust dyeing - LR 10:1 / 90% of exhaustion
monoreactive type NOVACRON LS dye
Dye-R
Dye-OH Dye-R-O-CEL
Fixation
70%
Hydrolysis
30%
Dye-R
Dye-OH Dye-R-O-CEL
Fixation
70%
Hydrolysis
30%
R2-Dye-R1
Fixation70%
Hydrolysis30%
HO-Dye-OH
R2-Dye-R1-O-CEL
Fixation
70%
Hydrolysis
30%
CEL-O-R2-Dye-OH
R2-Dye-OH
R2-Dye-R1
Fixation70%
Hydrolysis30%
HO-Dye-OH
R2-Dye-R1-O-CEL
Fixation
70%
Hydrolysis
30%
CEL-O-R2-Dye-OH
R2-Dye-OH
Dye not exhausted: 10.0%Dye fixed to CEL: 63.0%Dye hydrolyzed: 27.0%
Dye not exhausted: 10.0%Dye fixed to CEL: 81.9%Dye hydrolyzed: 8.1%
Fixation of a bireactive dye on cellulose
RR22--DyeDye --RR11CELCEL--OO
OHOHCELCEL--OO--DyeDye --OO--CELCEL
RR22--DyeDye --OO--CELCEL
RR22--DyeDye --OHOH
CELCEL--OO--DyeDye --RR11
HOHO--DyeDye --RR11
CELCEL--OO--DyeDye --OHOH
HOHO--DyeDye --OHOH
HOHO--DyeDye --OO--CELCEL
HOHO--DyeDye --OHOH
CELCEL--OO
OHOH
CELCEL--OO
OHOH
CELCEL--OO
OHOHRR22--DyeDye --RR11
CELCEL--OO
OHOHCELCEL--OO--DyeDye --OO--CELCEL
RR22--DyeDye --OO--CELCEL
RR22--DyeDye --OHOH
CELCEL--OO--DyeDye --RR11
HOHO--DyeDye --RR11
CELCEL--OO--DyeDye --OHOH
HOHO--DyeDye --OHOH
HOHO--DyeDye --OO--CELCEL
HOHO--DyeDye --OHOH
CELCEL--OO
OHOH
CELCEL--OO
OHOH
CELCEL--OO
OHOH
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Dye selection NOVACRONLS
Yellow LS-4G For bright yellow and green shades.No photochromism.
Yellow LS-R-01 For combination shades.
Orange LS-BR For combination shades with high light fastness.Especially for pale shades.No photochromism.
Scarlet LS-2G For combination shades.Basis for red and scarlet shades.
Red LS-6G Tinctorially strong red dye.Light fastness somewhat better than Scarlet LS-2G.
Red LS-B For combination shades.
Brilliant Blue LS-G Blue dye for brilliant blue shades.Blending dye for green and purple shades.
Blue LS-3R For combination shades.For combination dyeings with high light fastness.
Green LS-3B Economical basis for forest green and khaki shades.Basis for deep combination shades.
Navy LS-G For economical combination shades.Basis for navy shades.
Black LS-N-01 For deep blacks.
addition dyes:
Yellow NP No photochromism
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Combination systems NOVACRONLS
Trichromatic combinations for exhaust dyeing
Standard combinations
Yellow LS-R-01 / Orange LS-BRRed LS-B / Scarlet LS-2G / Blue LS-3R
For pale to medium shadesVery good light fastness
Yellow LS-R-01Orange LS-BR / Blue LS-3R
For dark shades / very economical
Yellow LS-R-01Scarlet LS-2G / Navy LS-G
Note:
Most golden yellow dyes, like Yellow LS-R-01 can show photochromism.The use of NOVACRON Yellow NP will lead to non photochromism dyeings.
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A new standard of tinctorial strength
The first high conc reactive range in the world
With 2% concentrated dye, the following reference depth is achieved:
Customer benefits:
Low transport costs
Low inventory
Excellent build-upDeep shades hitherto unattainable
Yellow - 4GAverage competition
Yellow LS-R-01Average competition
Orange LS- BRAverage competition
Scarlet LS - 2GAverage competition
Red LS - BAverage competition
Red LS - 6GAverage competition
Brill. Blue LS - GAverage competition
Blue LS - 3RAverage competition
Navy - GAverage competition
Black LS - N - 01Average competition
0 0.4 0.8 1.2 1.6 2
Yellow - 4GAverage competition
Average competition
- BRAverage competition
Scarlet LS - 2GAverage competition
Red LS - BAverage competition
Red LS - 6GAverage competition
Brill. Blue LS - GAverage competition
Blue LS - 3RAverage competition
Navy - GAverage competition
Black LS - N - 01Average competition
Yellow - 4GAverage competition
Average competition
- BRAverage competition
Scarlet LS - 2GAverage competition
Red LS - BAverage competition
Red LS - 6GAverage competition
Brill. Blue LS - GAverage competition
Blue LS - 3RAverage competition
Navy - GAverage competition
Black LS - N - 01Average competition
0 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 2
Yellow - 4GAverage competition
Average competition
-Average competition
Scarlet LS - 2GAverage competition
Red LS - BAverage competition
Red LS - 6GAverage competition
Brill. Blue LS - GAverage competition
Blue LS - 3RAverage competition
Navy - GAverage competition
Black LS - N - 01Average competition
0 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 2
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Minimum salt
NOVACRON LS approach
Customer benefits
Easier handling
Time saving
Cost savings
Easier washing off
Environmental advantages
The addition of salt is...time consuming and requires
manpower
This is the amount of salt usedwith conventional reactive dyes
Time and cost savings, easierhandling: the great benefits of
using NOVACRON LS
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Minimum salt
A deep shade is to be dyed on a 1000 kg jet at liquor ratio 10:1, requiring 10000 liters water and 80 g/l salt.
Salt addition procedure
(assuming a solubility of 250 g/l for common salt)
800 l
50 kg 50 kg 50 kg 50 kg
addition tank
salt salt saltsalt
15 min
800 l
50 kg 50 kg 50 kg 50 kg
addition tank
salt salt saltsalt
15 min
800 l
50 kg 50 kg 50 kg 50 kg
addition tank
salt salt saltsalt
15 min
800 l
50 kg 50 kg 50 kg 50 kg
addition tank
salt salt saltsalt
15 min
The addition takes one hour!
Are you going to continue wasting time?
Or would you like to shorten your cycle?
Minimum saltThe NOVACRON LS approach
The same shade can be dyed with only 20 g/l salt, which means
800 l
50 kg 50 kg 50 kg 50 kg
addition tank
salt salt saltsalt
The addition takes only 15 min!
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Minimum salt
Cost savings
Conventional reactive dye NOVACRON LS
Production/day 10000 kg CO 10000 kg CO
Liquor ratio 15:1 15:1
Amount of liquor 150000 litres 150000 litres
Amount of salt g/l 80 g/l 20 g/l
Total amount of salt/day 12000 kg 3000 kg
Total amount of salt/year 3000000 kg 750000 kg
Salt cost/year
Common salt (US$ 0.10kg) 300000 US$ 75000 US$
Glaubers salt (US$ 0.20kg) 600000 US$ 150000 US$
Contribution of salt addition toreduction of recipe costs
Approximately:10-20% lower
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Minimum salt
Easier washing off
The principles of salt removal
Salt removal is purely a question of dilution
It is dependent on
Carry-over from the last bath(normally 2-3 times the weight of the goods)
Amount of water (liquor ratio)(the higher the liquor ratio, the more effective the salt removal)
Soaping is most effective if the amount of salt does not exceed 1g/l. Up to now, two rinses were
necessary to remove the salt.With NOVACRON LS dyes, which require less salt for dyeing, only one rinse is normally required.This means
Time saving
Removal of salt by rinsing (liquor ratio 10:1)
Amount of salt in the rinsing baths:
bath bath bath bath01
23456789
111111
1
CIBACRON LS - 20 g/l SaltReactiv Warm - 60 g/l SaltReactive Hot - 80 g/l Salt
1For dyeing
g/l
bath bath bath bath01
23456789
111111
1
1
23456789
111111
1
CIBACRON LS - 20 g/l SaltReactiv Warm - 60 g/l SaltReactive Hot - 80 g/l Salt
NOVACRON LS- 20 g/l SaltReactiv Warm - 60 g/l SaltReactive Hot - 80 g/l Salt
1For dyeing
g/l
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Minimum salt
Environmental safety
Low salt concentrationin waste water dramatically reduced amount of salt (approx. of usual)
Low colorationof waste water very high exhaustion rate
very high fixation rate
Low environmental impactof application andwaster water disposal environmentally safe productsformulation with only small amounts ofharmless products
Unique repeatability of dyeings
Savings of chemicals, energy, time
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Exhaustion / fixation
(1SD on CO n. merc. - liquor ratio 10:1)
% exhausted % fixedYellow LS-4G 88 78Yellow LS-R-01 91 78Orange LS-BR 91 80Scarlet LS-2G 93 81Red LS-6G 93 80Red LS-B 91 78Brilliant Blue LS-G 80 74Blue LS-3R 90 83Green LS-3B 90 82Navy LS-G 93 82Black LS-N-01 82 77
The importance of high fixation
Increased yield
Improved reproducibility of the dyeings
Easier washing off
Improved waste water quality
0 20 40 60 80 100
Black LS-N-01
Navy LS-G
Green LS-3B
Blue LS-3R
Brill. Blue LS-G
Red LS-B
Red LS-6G
Scarlet LS-2G
Orange LS-BR
Yellow LS-R-01
Yellow LS-4G
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Exhaustion / fixation
Ecology
conventional dyes60% fixation
NOVACRON LS (bireactive)80% fixation
600 g on the fiber + 33% 800 g on the fiber
1 kg dye 1 kg dye
400 g in the waste water - 50% 200 g in the waste water
Application properties
Huntsman established very stringent selection criteria for NOVACRON LS dyes in terms of applicationproperties.
NOVACRON LS - a homogenous range
Optimum compatibility of the dyes
On-tone shade build-up
A robust system
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Customer benefits
Right First Time
Level dyeing performance
Tolerates small variations to the required dyeing conditions without impairing theshade
The NOVACRON LS range incorporates a combination of valuable application properties not yet offered byany other reactive dye range on the market.
NOVACRON LS - unique features
Extremely low salt requirements
Non-sensitivity to variations in liquor ratio
Non-sensitivity to variations in fixation temperature
Customer benefits
Easy shade matching
Outstanding reproducibility of the dyeings
Fewer shade corrections and re-dyeings
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Influence of liquor ratio
6:1 8:1 10:1 15:1 20:1 25:1 30:1
60
65
70
75
80
85
90
95
100
CIBACRON LS
reactive warm
reactive hot
reactive VS - low aff.
% Yield
Liquor ratio
The NOVACRON LS dyes give
BETTER REPRODUCIBILITY
Because they tolerate some degree of variations in liquor ratio without a marked effect on yield.
They are highly suitable for dyeing operations using more than one type of equipment or if actual
loads differ from specified loads.
NOVACRON LS
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Migration method
Note salt quality
Either common salt or Glaubers salt anhydrous can be used. Glaubers salt can occasionally have a marked
acid reaction. If this occurs, the amount of fixing alkali has to be increased accordingly. Sea salt and impure
common salt contain soluble alkaline earth ions.
If Glaubers salt cryst. (Na2SO4.10 H2O) is used, the amount of salt must be doubled.
90
80
70
60
50
40
30
176
194
86
104
122
140
158
20
30
40
50
60
70
80
90
100
-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135
68
86
104
122
140
158
176
194
212
A/C B D E
C F
25 40 75 85 100 130 min0 45
Fixation phaseMigration
phase
Dye
add.
Add. +
distributionof salt andaux.
90
80
70
60
50
40
30
176
194
86
104
122
140
158
20
30
40
50
60
70
80
90
100
-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135
68
86
104
122
140
158
176
194
212
A/C B D E
C F
25 40 75 85 100 130 min0 45
Fixation phaseMigration
phase
Dye
add.
Add. +
distributionof salt andaux.
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Migration method
for CO
90
80
70
60
50
40
30
176
194
86
104
122
140
158
20
30
40
50
60
70
80
90
100
-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135
68
86
104
122
140
158
176
194
212
A/C B D E
C F
25 40 75 85 100 130 min0 45
dispensed or in portions
Salt and alkali recommendations / soda ash
B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see
pages
28-30
C Salt g/l 10 10 - 15 15 - 20 20 - 25 25 - 30D Soda ash g/l 3 3 3 - 3.5 3.5 - 4 4 - 4.5E Soda ash g/l 7 7 7 - 7.5 7.5 - 8 8 - 9
Salt and alkali recommendations / soda ash + caustic soda
B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see
pages28-30
C Salt g/l 10 10 - 15 15 - 20 20 - 25 25 - 30D Soda ash g/l 5 5 5 5 5E NaOH 36B ml/l 1 1 - 1.25 1.25-1.5 1.5-1.75 1.75 - 2
NaOH 36B / 66Tw
For very dark shades (>2.5%) and black the salt and alkali recommendation areC 40 g/l Salt or C 40 g/l SaltD 15 g/l Soda ash D 5 g/l Soda ash
E 2.5 ml/l NaOH 36B
If the liquor ratio is below 6:1 the amount of alkali has to be increased.
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Migration method
for CO merc. and viscose
90
80
70
60
50
40
30
176
194
86
104
122
140
158
20
30
40
50
60
70
80
90
100
-5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165
68
86
104
122
140
158
176
194
212
A B D E
C F
25 40 75 105 115 160 min0 50 65
C
130
dispensed or in portions
Salt and alkali recommendations / soda ash
B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see
pages28-30
C Salt g/l 10 10 - 15 15 - 17.5 17.5 - 20 20 - 25D Soda ash g/l 3 3 3 - 3.5 3.5 - 4 4 - 4.5E Soda ash g/l 7 7 7 - 7.5 7.5 - 8 8 - 9
Salt and alkali recommendations / sodium bicarbonate + soda ash
B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see
pages28-30
C Salt g/l 10 10 - 15 15 - 17.5 17.5 - 20 20 - 25
D Sod. bicarbonate g/l 2 2 2 2 2E Soda ash g/l 10 10 10 - 11 11 - 12 12 - 13.5
For very dark shades (>2.5%) and black the salt and alkali recommendation areC 30 g/l Salt or C 30 g/l SaltD 15 g/l Soda ash D 2 g/l Sod. bicarbonate
E 15 g/l Soda ash
If the liquor ratio is below 6:1 the amount of alkali has to be increased.
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Washing off
Rinse for 10 min at 50C/122F One rinse is sufficient if liquor ratio is 10:1 oraboveRinse twice if liquor ratio is below 10:1 orgive intermittent / overflow rinse
Neutralize for 10 min at 70C/158F with 0.7 - 1% acetic acid
Soap for 10 min at 95C/203F In hard water areas it is advisable to add1 - 2 g/l ERIOPON R LIQ.
Soap for 10 min at 95C/203F A second soaping operation is recommendedfor dark shades
Rinse for 10 min at 70C/158F
Rinse for 10 min cold One rinse is sufficient if liquor ratio is 10:1 oraboveRinse twice if liquor ratio is below 10:1 orgive intermittent / overflow rinse
and if required:
Aftertreat for 20 min with ALBAFIXECO/WFF at 40C/104FpH 6-7 with acetic acid
Recommended for deep shades(approx. 1.5 - 2 SD)Can be combined with softeners
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Right First Time
Influence of process variation
fixation time
Dyeing at liquor ratio 10:1
Influence of a lkali add ition
Influence of salt addition
Influence of fixation time
Influence of fixing temperature
Influence of exhaustion time
Influence of liquor ratio
Salt
AlkaliCIBACRON LS
exhaustion time
90C
80C
70C
fixation time
Dyeing at liquor ratio 10:1
Influence of a lkali add ition
Influence of salt addition
Influence of fixation time
Influence of fixing temperature
Influence of exhaustion time
Influence of liquor ratio
Salt
AlkaliCIBACRON LS
exhaustion time
90C
80C
70C
fixation time
Dyeing at liquor ratio 10:1
Influence of a lkali add ition
Influence of salt addition
Influence of fixation time
Influence of fixing temperature
Influence of exhaustion time
Influence of liquor ratio
Salt
AlkaliCIBACRON LS
exhaustion time
90C
80C
70C
fixation time
Dyeing at liquor ratio 10:1
Influence of a lkali add ition
Influence of salt addition
Influence of fixation time
Influence of fixing temperature
Influence of exhaustion time
Influence of liquor ratio
Salt
AlkaliCIBACRON LS
exhaustion time
90C
80C
70C
fixation time
Dyeing at liquor ratio 10:1
Influence of a lkali add ition
Influence of salt addition
Influence of fixation time
Influence of fixing temperature
Influence of exhaustion time
Influence of liquor ratio
Salt
AlkaliCIBACRON LS
exhaustion time
90C
80C
70C
fixation time
Dyeing at liquor ratio 10:1
Influence of a lkali add ition
Influence of salt addition
Influence of fixation time
Influence of fixing temperature
Influence of exhaustion time
Influence of liquor ratio
Salt
AlkaliCIBACRON LS
exhaustion time
90C
80C
70C
NOVACRON LS
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Right First Time
Color difference from standard original
Shade acceptability
In the illustration, shades (A, B) falling in the center ellipse (bulls eye) are not visually different from eachother.Points within the outer ellipse (C) are within trace tolerances of the standard, i.e., a trained observer wouldperceive a small shade difference (with difficulty).Points falling outside the outer ellipse (D) represent distinct and therefore unacceptable shade differencesfrom the standard.
Center point = standard (original)
Strength variations
Strength variations below 45% can hardly be perceived, even by a trained observer.
A
C
D
B
-1.5
-1.0
-0.5
0.0
0.5
1.0
1.5
-1.5 -1.0 -0.5 0.0 0.5 1.0 1.5dC*
dH*
yellower
bluer
brighterduller
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Right First Time
Pale shade Standard migration 90/70C method 194/158F0.011% NOVACRON Yellow LS-R-01 Exht. time 90 min / fixation time 40 min0.035% NOVACRON Orange LS-BR 10 g/l salt0.025% NOVACRON Blue LS-3R 10 g/l soda ash
StandardA 20% salt I 20% alkaliB + 20% salt J + 20% alkaliC 15 exhaustion K 15 fixationD + 15 exhaustion L + 15 fixationF 5C (65C/149F) M 8:1 liquor ratioG + 5C (75C/167F) N 12:1 liquor ratio
0.02
0.03
0.04
0.05
0.06
0.07
0.08
0.09
0.10
A B C D F G I J K L M N
Stren
gth
(RD)
Samples Standard - 10% +10%
JFMB
K
D C
AN
G
L
I
-1.5
-1.0
-0.5
0.0
0.5
1.0
1.5
-1.5 -1.0 -0.5 0.0 0.5 1.0 1.5
dC*
dH*
yellower
redder
brighterduller
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Right First Time
Medium shade Standard migration 90/70C method 194/158F0.500% NOVACRON Yellow LS-R-01 Exht. time 90 min / fixation time 40 min0.400% NOVACRON Red LS-B 15 g/l salt0.200% NOVACRON Blue LS-3R 10 g/l soda ash
StandardA 20% salt I 20% alkaliB + 20% salt J + 20% alkaliC 15 exhaustion K 15 fixationD + 15 exhaustion L + 15 fixationF 5C (65C/149F) M 8:1 liquor ratioG + 5C (75C/167F) N 12:1 liquor ratio
0.00
0.10
0.20
0.30
0.400.50
0.60
0.70
0.80
0.90
1.00
A B C D F G I J K L M N
Strength
(RD)
Samples Standard -10% +10%
J
F
M
B
K
DC
A
NG
L
I
-1.5
-1.0
-0.5
0.0
0.5
1.0
1.5
-1.5 -1.0 -0.5 0.0 0.5 1.0 1.5
dC*
dH*
ye
llower
redder
brighterduller
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Right First Time
Dark shade Standard migration 90/70C method 194/158F0.600% NOVACRON Yellow LS-R-01 Exht. time 90 min / fixation time 40 min1.400% NOVACRON Scarlet LS-2G 40 g/l salt1.300% NOVACRON Navy LS-G 15 g/l soda ash
StandardA 20% salt I 20% alkaliB + 20% salt J + 20% alkaliC 15 exhaustion K 15 fixationD + 15 exhaustion L + 15 fixationF 5C (65C/149F) M 8:1 liquor ratioG + 5C (75C/167F) N 12:1 liquor ratio
0.50
1.00
1.50
2.00
2.50
3.00
3.50
4.00
A B C D F G I J K L M N
Strength
(RD)
Samples Standard -10% +10%
J
F
M
BK
D
C
A
N
G
LI
-1.5
-1.0
-0.5
0.0
0.5
1.0
1.5
-1.5 -1.0 -0.5 0.0 0.5 1.0 1.5
dC*
dH*
ye
llower
bluer
brighterduller
-
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Dyeing auxiliaries
The use of dyeing auxiliaries is highly recommended to achieve fully satisfactory dyeing results.
Benefits of dyeing auxiliaries
To improve levelness and appearance
Products for penetrating / de-aerating / defoamingDyeing lubricants
To avoid problems caused by impurities in the dyebath
Dyebath conditionersSpecial products
To improve fastness
Soaping agentCationic fastness improvers
Huntsman offers highly effective products that give optimum results in bulk working.
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Dyeing auxiliaries
Penetrating/de-aerating/defoaming
Products Effects Benefits
0.10.5 g/lALBATEX FFCslightly anionic
penetrationaccelerant
- silicone containing product with de-aerating effect anddurable antifoaming action
- very stable to high alkali and electrolyte concentrationsideal for machines with short liquor or air streamtechnology
0.30.5 g/l
ALBAFLOW SFPLUSnonionic
penetrationaccelerant
- mineral oil free product with reinforced foam controlproperties
- APEO and solvent free
- contains no silicone oil, no silicate
- good stability to electrolyte and shear
0.31 g/l
ALBAFLOW
CIRanionic
penetrationaccelerant
- APEO- and solvent free de-aerating agent with wettingproperties and durable antifoam properties
- instant penetration of goods, especially recommended forcirculating liquor dyeing machines
- stable in acid and alkaline media- promotes constant liquor flow, hence inside-outsidelevelness and reduced risk of channeling
0.10.5 g/l
ALBAFLOW JETanionic
penetrationaccelerant
- APEO- and solvent free product with durable antifoamingaction
- very stable to high alkali and electrolyte concentrations- specially recommended for jet and overflow machineswith short liquor or air stream technology alternative
Special products
Products Effects Benefits
13 g/lLYOPRINT RGanionic
reductionprotectant
- protects reactive dyes against reduction during dyeing
0.52 g/l
ALBATEX DBCanionic
dispersingagent
Ca inactivation
- dyebath conditioner: prevents precipitation of Ca, Mg inthe water or on the textile
- promotes levelness of the dyeing and improves theappearance of the dyed goods
- binds metal ions (Fe, Cu) in the water
0.52 g/lALBATEX CO
anionic
protectivecolloid
Ca inactivation
- avoids precipitation of Ca, Mg in the water or on thetextile
- promotes levelness of the dyeing and improves theappearance of the dyed goods- keeps impurities from unpretreated cotton in stabledispersion
0.53 g/l
ALBATEX DSanionic
polymericdispersant andprotectivecolloid
- dyebath conditioner: prevents precipitation of Ca, Mg in
the water or on the textile- promotes the levelness of the dyeing and improves theappearance of the dyed goods
- binds heavy metal ions in the water
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Special products
Products Effects Benefits
0.52 g/l
ALBAFLUID
C/CDanionic/nonionic
lubricant - reduces creasing in piece dyeing- markedly reduces textile-to-textile friction
- prevents cracks and abrasion marks- no adverse effect on the stability of the dyebath- no retarding effect
0.52 g/l
ALBAFLUID Uanionic/nonionic
lubricant - for very sensitive fabrics- prevents crack marks and creases- no adverse effect on the stability of the dyebath- no retarding effect- excellent for heavy goods
Soaping
Products Effects Benefits
0.52 g/lERIOPON R LIQ.anionic
washing agent - speeds up release and outward diffusion of dyehydrolysates, even in hard water- prevents renewed uptake of dye hydrolysates- inactivates water hardness ions and ensures maximumfastness properties
- low foaming
Note on all dyeing auxiliariesAmount required depends on specific conditions, e.g. type of fabric, quality of process water, type of machinery.
Aftertreatment with ALBAFIX ECO/WFF
Products Effects Benefits
13%
ALBAFIX ECOcationic
wet fastnessimprover
- formaldehyde-free- zinc-free- prevents migration after dyeing- protects dye/fiber bond of reactive dyes against acidhydrolysis and thermocracking
- no adverse effect on handle
13%
ALBAFIX WFFcationic
wet fastnessimprover
- formaldehyde-free- prevents migration after dyeing- protects dye/fiber bond of reactive dyes against acidhydrolysis and thermocracking
- little influence on light fastness and shade- no adverse effect on handle
Goods dyed to medium and deep shades should be aftertreated following washing off
Method: aftertreatment with ALBAFIX ECO/WFF at 40C/104F for 20-30 min. pH 67 adjusted with acetic acid. Thegoods are then hydroextracted and dried without rinsing.
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Handling reactive dyes
NOVACRON LS dyes present no special risk to health if the usual hygiene and safety rules for handling
chemicals are observed in storage, handling and use. Ingestion, inhalation, and skin and eye contact must be
avoided. Any application restrictions indicated on the informative labels should also be observed.For information on toxicology and ecology, please see the relevant Safety Data Sheets.
www.huntsman.com/textile_effects
Copyright 2007 Huntsman. All rights reserved.
All trademarks mentioned are either property of or licensed to Huntsman Corporation or an affiliate thereof in one ore more but not all countries.
IMPORTANT: The following supersedes Buyers documents. Sales of the product described herein (Product) are subject to the general terms and conditions of sale of either HuntAdvanced Materials LLC, or its appropriate affiliate. Huntsman warrants that at the time and place of delivery all Products sold to Buyer shall conform to the specifications provided to BuHuntsman.
While the information and recommendations included in this publication are, to the best of Huntsmans knowledge, accurate as of the date of publication, NOTHING CONTAINED HE(EXCEPT AS SET FORTH ABOVE REGARDING CONFORMANCE WITH SPECIFICATIONS PROVIDED TO BUYER BY HUNTSMAN) IS TO BE CONSTRUED AS A REPRESENTATIOWARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURP
NONINFRINGEMENT OF ANY INTELLECTUAL PROPERTY RIGHTS, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, ANDBUYER ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTSUBSTANCES.
No statements or recommendations made herein are to be construed as a representation about the suitability of any Product for the particular application of Buyer or user or as an inducemeinfringe any patent or other intellectual property right. Buyer is responsible to determine the applicability of such information and recommendations and the suitability of any Product for itsparticular purpose, and to ensure that its intended use of the Product does not infringe any intellectual property rights.
The Product may be or become hazardous. The Buyer should obtain Material Safety Data Sheets and Technical Data Sheets from Huntsman containing detailed information on Product haand toxicity, together with proper shipping, handling and storage procedures for the Product, and should comply with all applicable governmental laws, regulations and standards relating handling, use, storage, distribution and disposal of, and exposure to the Product. Buyer shall also take all steps necessary to adequately inform, warn and familiarize its employees, agents, and indirect customers and contractors who may handle or be exposed to the Product of all hazards pertaining to and proper procedures for safe handling, use, storage, transportatiodisposal of and exposure to the Product, and the containers or equipment in which the Product may be handled, shipped or stored.
Please note that products may differ from country to country. If you have any queries, kindly contact your local Huntsman representative.Huntsman is a member of:
(Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers)