General Info - Novacron Ls

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    Contents

    Page

    Innovative chemistry............................................................................................................................3

    Benefits of the system.................................................................................................................... 45

    Dye selection NOVACRON LS ...........................................................................................................6

    Combination systems NOVACRON LS...............................................................................................7

    A new standard of tinctorial strength...................................................................................................8

    Comparison of build-up .......................................................................................................................9

    Minimum salt .............................................................................................................................. 1014

    Exhaustion / fixation ................................................................................................................... 1516

    Application properties........................................................................................................................17

    Influence of liquor ratio......................................................................................................................18

    Migration method........................................................................................................................ 1921

    Washing off .......................................................................................................................................22

    Right First Time.......................................................................................................................... 2327

    Dyeing auxiliaries ....................................................................................................................... 2830

    Handling reactive dyes......................................................................................................................31

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    NOVACRON LS

    The NOVACRON LS dyes are innovative bi-reactive dyes, with very high tinctorial strength, for hot dyeing.

    Highly compatible range for a wide shade spectrum.The NOVACRON LS concept is the first and unique low salt range on the market. Only 1/3 of the salt

    amount required by standard reactive dyes is needed.All these properties play a great part in the outstanding reproducibility and environmentally orientedbehavior of the NOVACRON LS dyes.

    Highlights of NOVACRON LS ...and what they mean for the dyer

    Outstanding ecological properties

    - fixation over 80%- drastically reduced salt usage (1/3 that ofreactive dyes available on the market)

    Reduced costs and worries - fulfillingsevere environmental requirements

    - much less dye in waste water and- much less salt in waste water, bothresulting in lower environmental costs

    - less corrosion of machinery and concrete- much less salt in water positively impactsefficiency of biological water treatmentunit

    Highly concentrated dyes withhomogenous application propertiesand outstanding reproducibility

    - high tinctorial strength and fixationover 80%

    - drastically reduced salt usage- low sensitivity to liquor ratio variations

    - excellent compatibility of the dyes inthe range, on-tone build-up and verygood levelness

    High productivity, right first timedyeings

    - unique reproducibility lab to bulk and bulkto bulk

    - fewer corrections, fewer re-dyeings- much reduced time for handling anddissolving of salt

    - automation of salt dosing facilitated- lowercosts for storage and for disposal ofpackaging material

    - very deep shades feasible economicallyand ecologically

    - substantial savings on cost of salt and saltstorage

    - no need for highly skilled personnel

    Ideal for one bath dyeing of PES/CEL(LS Superfast)

    - excellent suitability, thanks to the much

    reduced amount of salt and the lowsensitivity to liquor ratio variations

    - very robust process

    Substantial time and cost saving

    - short highly productive dyeing process(6 hours only)

    - excellent reproducibility, even withoutskilled personnel

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    Benefits of the system

    A new standard of tinctorial strength

    The first low-salt range

    High fixation

    Superior application properties for better reproducibility of the dyeings

    Excellent range for dyeing PES/CEL blends in a one bath process: LS

    Superfast

    Molecular engineering

    chromophore bridge chromophore

    reactive group reactive group

    2 reactive groups exclusive patentedbridge

    2 chromophores

    - medium reactivity

    - stable fiber-dye linkage(thanks to two groups)

    - gives molecule goodflexibility

    - selected for maximumsolubility

    - promote high affinity

    - give high color strength

    - allow improvement offastness or shade

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    Benefits of the system

    Degree of fixation / exhaust dyeing - LR 10:1 / 90% of exhaustion

    monoreactive type NOVACRON LS dye

    Dye-R

    Dye-OH Dye-R-O-CEL

    Fixation

    70%

    Hydrolysis

    30%

    Dye-R

    Dye-OH Dye-R-O-CEL

    Fixation

    70%

    Hydrolysis

    30%

    R2-Dye-R1

    Fixation70%

    Hydrolysis30%

    HO-Dye-OH

    R2-Dye-R1-O-CEL

    Fixation

    70%

    Hydrolysis

    30%

    CEL-O-R2-Dye-OH

    R2-Dye-OH

    R2-Dye-R1

    Fixation70%

    Hydrolysis30%

    HO-Dye-OH

    R2-Dye-R1-O-CEL

    Fixation

    70%

    Hydrolysis

    30%

    CEL-O-R2-Dye-OH

    R2-Dye-OH

    Dye not exhausted: 10.0%Dye fixed to CEL: 63.0%Dye hydrolyzed: 27.0%

    Dye not exhausted: 10.0%Dye fixed to CEL: 81.9%Dye hydrolyzed: 8.1%

    Fixation of a bireactive dye on cellulose

    RR22--DyeDye --RR11CELCEL--OO

    OHOHCELCEL--OO--DyeDye --OO--CELCEL

    RR22--DyeDye --OO--CELCEL

    RR22--DyeDye --OHOH

    CELCEL--OO--DyeDye --RR11

    HOHO--DyeDye --RR11

    CELCEL--OO--DyeDye --OHOH

    HOHO--DyeDye --OHOH

    HOHO--DyeDye --OO--CELCEL

    HOHO--DyeDye --OHOH

    CELCEL--OO

    OHOH

    CELCEL--OO

    OHOH

    CELCEL--OO

    OHOHRR22--DyeDye --RR11

    CELCEL--OO

    OHOHCELCEL--OO--DyeDye --OO--CELCEL

    RR22--DyeDye --OO--CELCEL

    RR22--DyeDye --OHOH

    CELCEL--OO--DyeDye --RR11

    HOHO--DyeDye --RR11

    CELCEL--OO--DyeDye --OHOH

    HOHO--DyeDye --OHOH

    HOHO--DyeDye --OO--CELCEL

    HOHO--DyeDye --OHOH

    CELCEL--OO

    OHOH

    CELCEL--OO

    OHOH

    CELCEL--OO

    OHOH

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    Dye selection NOVACRONLS

    Yellow LS-4G For bright yellow and green shades.No photochromism.

    Yellow LS-R-01 For combination shades.

    Orange LS-BR For combination shades with high light fastness.Especially for pale shades.No photochromism.

    Scarlet LS-2G For combination shades.Basis for red and scarlet shades.

    Red LS-6G Tinctorially strong red dye.Light fastness somewhat better than Scarlet LS-2G.

    Red LS-B For combination shades.

    Brilliant Blue LS-G Blue dye for brilliant blue shades.Blending dye for green and purple shades.

    Blue LS-3R For combination shades.For combination dyeings with high light fastness.

    Green LS-3B Economical basis for forest green and khaki shades.Basis for deep combination shades.

    Navy LS-G For economical combination shades.Basis for navy shades.

    Black LS-N-01 For deep blacks.

    addition dyes:

    Yellow NP No photochromism

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    Combination systems NOVACRONLS

    Trichromatic combinations for exhaust dyeing

    Standard combinations

    Yellow LS-R-01 / Orange LS-BRRed LS-B / Scarlet LS-2G / Blue LS-3R

    For pale to medium shadesVery good light fastness

    Yellow LS-R-01Orange LS-BR / Blue LS-3R

    For dark shades / very economical

    Yellow LS-R-01Scarlet LS-2G / Navy LS-G

    Note:

    Most golden yellow dyes, like Yellow LS-R-01 can show photochromism.The use of NOVACRON Yellow NP will lead to non photochromism dyeings.

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    A new standard of tinctorial strength

    The first high conc reactive range in the world

    With 2% concentrated dye, the following reference depth is achieved:

    Customer benefits:

    Low transport costs

    Low inventory

    Excellent build-upDeep shades hitherto unattainable

    Yellow - 4GAverage competition

    Yellow LS-R-01Average competition

    Orange LS- BRAverage competition

    Scarlet LS - 2GAverage competition

    Red LS - BAverage competition

    Red LS - 6GAverage competition

    Brill. Blue LS - GAverage competition

    Blue LS - 3RAverage competition

    Navy - GAverage competition

    Black LS - N - 01Average competition

    0 0.4 0.8 1.2 1.6 2

    Yellow - 4GAverage competition

    Average competition

    - BRAverage competition

    Scarlet LS - 2GAverage competition

    Red LS - BAverage competition

    Red LS - 6GAverage competition

    Brill. Blue LS - GAverage competition

    Blue LS - 3RAverage competition

    Navy - GAverage competition

    Black LS - N - 01Average competition

    Yellow - 4GAverage competition

    Average competition

    - BRAverage competition

    Scarlet LS - 2GAverage competition

    Red LS - BAverage competition

    Red LS - 6GAverage competition

    Brill. Blue LS - GAverage competition

    Blue LS - 3RAverage competition

    Navy - GAverage competition

    Black LS - N - 01Average competition

    0 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 2

    Yellow - 4GAverage competition

    Average competition

    -Average competition

    Scarlet LS - 2GAverage competition

    Red LS - BAverage competition

    Red LS - 6GAverage competition

    Brill. Blue LS - GAverage competition

    Blue LS - 3RAverage competition

    Navy - GAverage competition

    Black LS - N - 01Average competition

    0 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 20 0.4 0.8 1.2 1.6 2

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    Minimum salt

    NOVACRON LS approach

    Customer benefits

    Easier handling

    Time saving

    Cost savings

    Easier washing off

    Environmental advantages

    The addition of salt is...time consuming and requires

    manpower

    This is the amount of salt usedwith conventional reactive dyes

    Time and cost savings, easierhandling: the great benefits of

    using NOVACRON LS

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    Minimum salt

    A deep shade is to be dyed on a 1000 kg jet at liquor ratio 10:1, requiring 10000 liters water and 80 g/l salt.

    Salt addition procedure

    (assuming a solubility of 250 g/l for common salt)

    800 l

    50 kg 50 kg 50 kg 50 kg

    addition tank

    salt salt saltsalt

    15 min

    800 l

    50 kg 50 kg 50 kg 50 kg

    addition tank

    salt salt saltsalt

    15 min

    800 l

    50 kg 50 kg 50 kg 50 kg

    addition tank

    salt salt saltsalt

    15 min

    800 l

    50 kg 50 kg 50 kg 50 kg

    addition tank

    salt salt saltsalt

    15 min

    The addition takes one hour!

    Are you going to continue wasting time?

    Or would you like to shorten your cycle?

    Minimum saltThe NOVACRON LS approach

    The same shade can be dyed with only 20 g/l salt, which means

    800 l

    50 kg 50 kg 50 kg 50 kg

    addition tank

    salt salt saltsalt

    The addition takes only 15 min!

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    Minimum salt

    Cost savings

    Conventional reactive dye NOVACRON LS

    Production/day 10000 kg CO 10000 kg CO

    Liquor ratio 15:1 15:1

    Amount of liquor 150000 litres 150000 litres

    Amount of salt g/l 80 g/l 20 g/l

    Total amount of salt/day 12000 kg 3000 kg

    Total amount of salt/year 3000000 kg 750000 kg

    Salt cost/year

    Common salt (US$ 0.10kg) 300000 US$ 75000 US$

    Glaubers salt (US$ 0.20kg) 600000 US$ 150000 US$

    Contribution of salt addition toreduction of recipe costs

    Approximately:10-20% lower

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    Minimum salt

    Easier washing off

    The principles of salt removal

    Salt removal is purely a question of dilution

    It is dependent on

    Carry-over from the last bath(normally 2-3 times the weight of the goods)

    Amount of water (liquor ratio)(the higher the liquor ratio, the more effective the salt removal)

    Soaping is most effective if the amount of salt does not exceed 1g/l. Up to now, two rinses were

    necessary to remove the salt.With NOVACRON LS dyes, which require less salt for dyeing, only one rinse is normally required.This means

    Time saving

    Removal of salt by rinsing (liquor ratio 10:1)

    Amount of salt in the rinsing baths:

    bath bath bath bath01

    23456789

    111111

    1

    CIBACRON LS - 20 g/l SaltReactiv Warm - 60 g/l SaltReactive Hot - 80 g/l Salt

    1For dyeing

    g/l

    bath bath bath bath01

    23456789

    111111

    1

    1

    23456789

    111111

    1

    CIBACRON LS - 20 g/l SaltReactiv Warm - 60 g/l SaltReactive Hot - 80 g/l Salt

    NOVACRON LS- 20 g/l SaltReactiv Warm - 60 g/l SaltReactive Hot - 80 g/l Salt

    1For dyeing

    g/l

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    Minimum salt

    Environmental safety

    Low salt concentrationin waste water dramatically reduced amount of salt (approx. of usual)

    Low colorationof waste water very high exhaustion rate

    very high fixation rate

    Low environmental impactof application andwaster water disposal environmentally safe productsformulation with only small amounts ofharmless products

    Unique repeatability of dyeings

    Savings of chemicals, energy, time

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    Exhaustion / fixation

    (1SD on CO n. merc. - liquor ratio 10:1)

    % exhausted % fixedYellow LS-4G 88 78Yellow LS-R-01 91 78Orange LS-BR 91 80Scarlet LS-2G 93 81Red LS-6G 93 80Red LS-B 91 78Brilliant Blue LS-G 80 74Blue LS-3R 90 83Green LS-3B 90 82Navy LS-G 93 82Black LS-N-01 82 77

    The importance of high fixation

    Increased yield

    Improved reproducibility of the dyeings

    Easier washing off

    Improved waste water quality

    0 20 40 60 80 100

    Black LS-N-01

    Navy LS-G

    Green LS-3B

    Blue LS-3R

    Brill. Blue LS-G

    Red LS-B

    Red LS-6G

    Scarlet LS-2G

    Orange LS-BR

    Yellow LS-R-01

    Yellow LS-4G

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    Exhaustion / fixation

    Ecology

    conventional dyes60% fixation

    NOVACRON LS (bireactive)80% fixation

    600 g on the fiber + 33% 800 g on the fiber

    1 kg dye 1 kg dye

    400 g in the waste water - 50% 200 g in the waste water

    Application properties

    Huntsman established very stringent selection criteria for NOVACRON LS dyes in terms of applicationproperties.

    NOVACRON LS - a homogenous range

    Optimum compatibility of the dyes

    On-tone shade build-up

    A robust system

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    Customer benefits

    Right First Time

    Level dyeing performance

    Tolerates small variations to the required dyeing conditions without impairing theshade

    The NOVACRON LS range incorporates a combination of valuable application properties not yet offered byany other reactive dye range on the market.

    NOVACRON LS - unique features

    Extremely low salt requirements

    Non-sensitivity to variations in liquor ratio

    Non-sensitivity to variations in fixation temperature

    Customer benefits

    Easy shade matching

    Outstanding reproducibility of the dyeings

    Fewer shade corrections and re-dyeings

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    Influence of liquor ratio

    6:1 8:1 10:1 15:1 20:1 25:1 30:1

    60

    65

    70

    75

    80

    85

    90

    95

    100

    CIBACRON LS

    reactive warm

    reactive hot

    reactive VS - low aff.

    % Yield

    Liquor ratio

    The NOVACRON LS dyes give

    BETTER REPRODUCIBILITY

    Because they tolerate some degree of variations in liquor ratio without a marked effect on yield.

    They are highly suitable for dyeing operations using more than one type of equipment or if actual

    loads differ from specified loads.

    NOVACRON LS

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    Migration method

    Note salt quality

    Either common salt or Glaubers salt anhydrous can be used. Glaubers salt can occasionally have a marked

    acid reaction. If this occurs, the amount of fixing alkali has to be increased accordingly. Sea salt and impure

    common salt contain soluble alkaline earth ions.

    If Glaubers salt cryst. (Na2SO4.10 H2O) is used, the amount of salt must be doubled.

    90

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    -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

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    A/C B D E

    C F

    25 40 75 85 100 130 min0 45

    Fixation phaseMigration

    phase

    Dye

    add.

    Add. +

    distributionof salt andaux.

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    A/C B D E

    C F

    25 40 75 85 100 130 min0 45

    Fixation phaseMigration

    phase

    Dye

    add.

    Add. +

    distributionof salt andaux.

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    Migration method

    for CO

    90

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    -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135

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    A/C B D E

    C F

    25 40 75 85 100 130 min0 45

    dispensed or in portions

    Salt and alkali recommendations / soda ash

    B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see

    pages

    28-30

    C Salt g/l 10 10 - 15 15 - 20 20 - 25 25 - 30D Soda ash g/l 3 3 3 - 3.5 3.5 - 4 4 - 4.5E Soda ash g/l 7 7 7 - 7.5 7.5 - 8 8 - 9

    Salt and alkali recommendations / soda ash + caustic soda

    B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see

    pages28-30

    C Salt g/l 10 10 - 15 15 - 20 20 - 25 25 - 30D Soda ash g/l 5 5 5 5 5E NaOH 36B ml/l 1 1 - 1.25 1.25-1.5 1.5-1.75 1.75 - 2

    NaOH 36B / 66Tw

    For very dark shades (>2.5%) and black the salt and alkali recommendation areC 40 g/l Salt or C 40 g/l SaltD 15 g/l Soda ash D 5 g/l Soda ash

    E 2.5 ml/l NaOH 36B

    If the liquor ratio is below 6:1 the amount of alkali has to be increased.

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    Migration method

    for CO merc. and viscose

    90

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    30

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    -5 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165

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    A B D E

    C F

    25 40 75 105 115 160 min0 50 65

    C

    130

    dispensed or in portions

    Salt and alkali recommendations / soda ash

    B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see

    pages28-30

    C Salt g/l 10 10 - 15 15 - 17.5 17.5 - 20 20 - 25D Soda ash g/l 3 3 3 - 3.5 3.5 - 4 4 - 4.5E Soda ash g/l 7 7 7 - 7.5 7.5 - 8 8 - 9

    Salt and alkali recommendations / sodium bicarbonate + soda ash

    B NOVACRON LS % < 0.5 0.5 - 1 1 - 1.5 1.5 - 2 2 - 2.5A Auxiliaries see

    pages28-30

    C Salt g/l 10 10 - 15 15 - 17.5 17.5 - 20 20 - 25

    D Sod. bicarbonate g/l 2 2 2 2 2E Soda ash g/l 10 10 10 - 11 11 - 12 12 - 13.5

    For very dark shades (>2.5%) and black the salt and alkali recommendation areC 30 g/l Salt or C 30 g/l SaltD 15 g/l Soda ash D 2 g/l Sod. bicarbonate

    E 15 g/l Soda ash

    If the liquor ratio is below 6:1 the amount of alkali has to be increased.

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    Washing off

    Rinse for 10 min at 50C/122F One rinse is sufficient if liquor ratio is 10:1 oraboveRinse twice if liquor ratio is below 10:1 orgive intermittent / overflow rinse

    Neutralize for 10 min at 70C/158F with 0.7 - 1% acetic acid

    Soap for 10 min at 95C/203F In hard water areas it is advisable to add1 - 2 g/l ERIOPON R LIQ.

    Soap for 10 min at 95C/203F A second soaping operation is recommendedfor dark shades

    Rinse for 10 min at 70C/158F

    Rinse for 10 min cold One rinse is sufficient if liquor ratio is 10:1 oraboveRinse twice if liquor ratio is below 10:1 orgive intermittent / overflow rinse

    and if required:

    Aftertreat for 20 min with ALBAFIXECO/WFF at 40C/104FpH 6-7 with acetic acid

    Recommended for deep shades(approx. 1.5 - 2 SD)Can be combined with softeners

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    Right First Time

    Influence of process variation

    fixation time

    Dyeing at liquor ratio 10:1

    Influence of a lkali add ition

    Influence of salt addition

    Influence of fixation time

    Influence of fixing temperature

    Influence of exhaustion time

    Influence of liquor ratio

    Salt

    AlkaliCIBACRON LS

    exhaustion time

    90C

    80C

    70C

    fixation time

    Dyeing at liquor ratio 10:1

    Influence of a lkali add ition

    Influence of salt addition

    Influence of fixation time

    Influence of fixing temperature

    Influence of exhaustion time

    Influence of liquor ratio

    Salt

    AlkaliCIBACRON LS

    exhaustion time

    90C

    80C

    70C

    fixation time

    Dyeing at liquor ratio 10:1

    Influence of a lkali add ition

    Influence of salt addition

    Influence of fixation time

    Influence of fixing temperature

    Influence of exhaustion time

    Influence of liquor ratio

    Salt

    AlkaliCIBACRON LS

    exhaustion time

    90C

    80C

    70C

    fixation time

    Dyeing at liquor ratio 10:1

    Influence of a lkali add ition

    Influence of salt addition

    Influence of fixation time

    Influence of fixing temperature

    Influence of exhaustion time

    Influence of liquor ratio

    Salt

    AlkaliCIBACRON LS

    exhaustion time

    90C

    80C

    70C

    fixation time

    Dyeing at liquor ratio 10:1

    Influence of a lkali add ition

    Influence of salt addition

    Influence of fixation time

    Influence of fixing temperature

    Influence of exhaustion time

    Influence of liquor ratio

    Salt

    AlkaliCIBACRON LS

    exhaustion time

    90C

    80C

    70C

    fixation time

    Dyeing at liquor ratio 10:1

    Influence of a lkali add ition

    Influence of salt addition

    Influence of fixation time

    Influence of fixing temperature

    Influence of exhaustion time

    Influence of liquor ratio

    Salt

    AlkaliCIBACRON LS

    exhaustion time

    90C

    80C

    70C

    NOVACRON LS

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    Right First Time

    Color difference from standard original

    Shade acceptability

    In the illustration, shades (A, B) falling in the center ellipse (bulls eye) are not visually different from eachother.Points within the outer ellipse (C) are within trace tolerances of the standard, i.e., a trained observer wouldperceive a small shade difference (with difficulty).Points falling outside the outer ellipse (D) represent distinct and therefore unacceptable shade differencesfrom the standard.

    Center point = standard (original)

    Strength variations

    Strength variations below 45% can hardly be perceived, even by a trained observer.

    A

    C

    D

    B

    -1.5

    -1.0

    -0.5

    0.0

    0.5

    1.0

    1.5

    -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5dC*

    dH*

    yellower

    bluer

    brighterduller

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    Right First Time

    Pale shade Standard migration 90/70C method 194/158F0.011% NOVACRON Yellow LS-R-01 Exht. time 90 min / fixation time 40 min0.035% NOVACRON Orange LS-BR 10 g/l salt0.025% NOVACRON Blue LS-3R 10 g/l soda ash

    StandardA 20% salt I 20% alkaliB + 20% salt J + 20% alkaliC 15 exhaustion K 15 fixationD + 15 exhaustion L + 15 fixationF 5C (65C/149F) M 8:1 liquor ratioG + 5C (75C/167F) N 12:1 liquor ratio

    0.02

    0.03

    0.04

    0.05

    0.06

    0.07

    0.08

    0.09

    0.10

    A B C D F G I J K L M N

    Stren

    gth

    (RD)

    Samples Standard - 10% +10%

    JFMB

    K

    D C

    AN

    G

    L

    I

    -1.5

    -1.0

    -0.5

    0.0

    0.5

    1.0

    1.5

    -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5

    dC*

    dH*

    yellower

    redder

    brighterduller

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    Right First Time

    Medium shade Standard migration 90/70C method 194/158F0.500% NOVACRON Yellow LS-R-01 Exht. time 90 min / fixation time 40 min0.400% NOVACRON Red LS-B 15 g/l salt0.200% NOVACRON Blue LS-3R 10 g/l soda ash

    StandardA 20% salt I 20% alkaliB + 20% salt J + 20% alkaliC 15 exhaustion K 15 fixationD + 15 exhaustion L + 15 fixationF 5C (65C/149F) M 8:1 liquor ratioG + 5C (75C/167F) N 12:1 liquor ratio

    0.00

    0.10

    0.20

    0.30

    0.400.50

    0.60

    0.70

    0.80

    0.90

    1.00

    A B C D F G I J K L M N

    Strength

    (RD)

    Samples Standard -10% +10%

    J

    F

    M

    B

    K

    DC

    A

    NG

    L

    I

    -1.5

    -1.0

    -0.5

    0.0

    0.5

    1.0

    1.5

    -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5

    dC*

    dH*

    ye

    llower

    redder

    brighterduller

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    Right First Time

    Dark shade Standard migration 90/70C method 194/158F0.600% NOVACRON Yellow LS-R-01 Exht. time 90 min / fixation time 40 min1.400% NOVACRON Scarlet LS-2G 40 g/l salt1.300% NOVACRON Navy LS-G 15 g/l soda ash

    StandardA 20% salt I 20% alkaliB + 20% salt J + 20% alkaliC 15 exhaustion K 15 fixationD + 15 exhaustion L + 15 fixationF 5C (65C/149F) M 8:1 liquor ratioG + 5C (75C/167F) N 12:1 liquor ratio

    0.50

    1.00

    1.50

    2.00

    2.50

    3.00

    3.50

    4.00

    A B C D F G I J K L M N

    Strength

    (RD)

    Samples Standard -10% +10%

    J

    F

    M

    BK

    D

    C

    A

    N

    G

    LI

    -1.5

    -1.0

    -0.5

    0.0

    0.5

    1.0

    1.5

    -1.5 -1.0 -0.5 0.0 0.5 1.0 1.5

    dC*

    dH*

    ye

    llower

    bluer

    brighterduller

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    Dyeing auxiliaries

    The use of dyeing auxiliaries is highly recommended to achieve fully satisfactory dyeing results.

    Benefits of dyeing auxiliaries

    To improve levelness and appearance

    Products for penetrating / de-aerating / defoamingDyeing lubricants

    To avoid problems caused by impurities in the dyebath

    Dyebath conditionersSpecial products

    To improve fastness

    Soaping agentCationic fastness improvers

    Huntsman offers highly effective products that give optimum results in bulk working.

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    Dyeing auxiliaries

    Penetrating/de-aerating/defoaming

    Products Effects Benefits

    0.10.5 g/lALBATEX FFCslightly anionic

    penetrationaccelerant

    - silicone containing product with de-aerating effect anddurable antifoaming action

    - very stable to high alkali and electrolyte concentrationsideal for machines with short liquor or air streamtechnology

    0.30.5 g/l

    ALBAFLOW SFPLUSnonionic

    penetrationaccelerant

    - mineral oil free product with reinforced foam controlproperties

    - APEO and solvent free

    - contains no silicone oil, no silicate

    - good stability to electrolyte and shear

    0.31 g/l

    ALBAFLOW

    CIRanionic

    penetrationaccelerant

    - APEO- and solvent free de-aerating agent with wettingproperties and durable antifoam properties

    - instant penetration of goods, especially recommended forcirculating liquor dyeing machines

    - stable in acid and alkaline media- promotes constant liquor flow, hence inside-outsidelevelness and reduced risk of channeling

    0.10.5 g/l

    ALBAFLOW JETanionic

    penetrationaccelerant

    - APEO- and solvent free product with durable antifoamingaction

    - very stable to high alkali and electrolyte concentrations- specially recommended for jet and overflow machineswith short liquor or air stream technology alternative

    Special products

    Products Effects Benefits

    13 g/lLYOPRINT RGanionic

    reductionprotectant

    - protects reactive dyes against reduction during dyeing

    0.52 g/l

    ALBATEX DBCanionic

    dispersingagent

    Ca inactivation

    - dyebath conditioner: prevents precipitation of Ca, Mg inthe water or on the textile

    - promotes levelness of the dyeing and improves theappearance of the dyed goods

    - binds metal ions (Fe, Cu) in the water

    0.52 g/lALBATEX CO

    anionic

    protectivecolloid

    Ca inactivation

    - avoids precipitation of Ca, Mg in the water or on thetextile

    - promotes levelness of the dyeing and improves theappearance of the dyed goods- keeps impurities from unpretreated cotton in stabledispersion

    0.53 g/l

    ALBATEX DSanionic

    polymericdispersant andprotectivecolloid

    - dyebath conditioner: prevents precipitation of Ca, Mg in

    the water or on the textile- promotes the levelness of the dyeing and improves theappearance of the dyed goods

    - binds heavy metal ions in the water

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    Special products

    Products Effects Benefits

    0.52 g/l

    ALBAFLUID

    C/CDanionic/nonionic

    lubricant - reduces creasing in piece dyeing- markedly reduces textile-to-textile friction

    - prevents cracks and abrasion marks- no adverse effect on the stability of the dyebath- no retarding effect

    0.52 g/l

    ALBAFLUID Uanionic/nonionic

    lubricant - for very sensitive fabrics- prevents crack marks and creases- no adverse effect on the stability of the dyebath- no retarding effect- excellent for heavy goods

    Soaping

    Products Effects Benefits

    0.52 g/lERIOPON R LIQ.anionic

    washing agent - speeds up release and outward diffusion of dyehydrolysates, even in hard water- prevents renewed uptake of dye hydrolysates- inactivates water hardness ions and ensures maximumfastness properties

    - low foaming

    Note on all dyeing auxiliariesAmount required depends on specific conditions, e.g. type of fabric, quality of process water, type of machinery.

    Aftertreatment with ALBAFIX ECO/WFF

    Products Effects Benefits

    13%

    ALBAFIX ECOcationic

    wet fastnessimprover

    - formaldehyde-free- zinc-free- prevents migration after dyeing- protects dye/fiber bond of reactive dyes against acidhydrolysis and thermocracking

    - no adverse effect on handle

    13%

    ALBAFIX WFFcationic

    wet fastnessimprover

    - formaldehyde-free- prevents migration after dyeing- protects dye/fiber bond of reactive dyes against acidhydrolysis and thermocracking

    - little influence on light fastness and shade- no adverse effect on handle

    Goods dyed to medium and deep shades should be aftertreated following washing off

    Method: aftertreatment with ALBAFIX ECO/WFF at 40C/104F for 20-30 min. pH 67 adjusted with acetic acid. Thegoods are then hydroextracted and dried without rinsing.

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    Handling reactive dyes

    NOVACRON LS dyes present no special risk to health if the usual hygiene and safety rules for handling

    chemicals are observed in storage, handling and use. Ingestion, inhalation, and skin and eye contact must be

    avoided. Any application restrictions indicated on the informative labels should also be observed.For information on toxicology and ecology, please see the relevant Safety Data Sheets.

    www.huntsman.com/textile_effects

    Copyright 2007 Huntsman. All rights reserved.

    All trademarks mentioned are either property of or licensed to Huntsman Corporation or an affiliate thereof in one ore more but not all countries.

    IMPORTANT: The following supersedes Buyers documents. Sales of the product described herein (Product) are subject to the general terms and conditions of sale of either HuntAdvanced Materials LLC, or its appropriate affiliate. Huntsman warrants that at the time and place of delivery all Products sold to Buyer shall conform to the specifications provided to BuHuntsman.

    While the information and recommendations included in this publication are, to the best of Huntsmans knowledge, accurate as of the date of publication, NOTHING CONTAINED HE(EXCEPT AS SET FORTH ABOVE REGARDING CONFORMANCE WITH SPECIFICATIONS PROVIDED TO BUYER BY HUNTSMAN) IS TO BE CONSTRUED AS A REPRESENTATIOWARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURP

    NONINFRINGEMENT OF ANY INTELLECTUAL PROPERTY RIGHTS, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, ANDBUYER ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTSUBSTANCES.

    No statements or recommendations made herein are to be construed as a representation about the suitability of any Product for the particular application of Buyer or user or as an inducemeinfringe any patent or other intellectual property right. Buyer is responsible to determine the applicability of such information and recommendations and the suitability of any Product for itsparticular purpose, and to ensure that its intended use of the Product does not infringe any intellectual property rights.

    The Product may be or become hazardous. The Buyer should obtain Material Safety Data Sheets and Technical Data Sheets from Huntsman containing detailed information on Product haand toxicity, together with proper shipping, handling and storage procedures for the Product, and should comply with all applicable governmental laws, regulations and standards relating handling, use, storage, distribution and disposal of, and exposure to the Product. Buyer shall also take all steps necessary to adequately inform, warn and familiarize its employees, agents, and indirect customers and contractors who may handle or be exposed to the Product of all hazards pertaining to and proper procedures for safe handling, use, storage, transportatiodisposal of and exposure to the Product, and the containers or equipment in which the Product may be handled, shipped or stored.

    Please note that products may differ from country to country. If you have any queries, kindly contact your local Huntsman representative.Huntsman is a member of:

    (Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers)