Gelatine liquid-solid transition
Transcript of Gelatine liquid-solid transition
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0.5µm
Gelatin :
liquid for Tm>32°C
solid for Tg< 28°C
For T<Tg gelatin presents : aging and memory effects
at 10%wt concentration after a cooling at 26°C it takes ~2h to solidify
In our experiment we use
10%wt concentration in water
Gelatin liquid-solid transition
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Gelatin Gelatin : liquid for Tm>32°C solid for Tg< 28°C 38°C
Trapping laser
Trapped glass particle R=1µm
For T<Tg gelatin presents : aging and memory effects
at 10%wt concentration after a cooling at 26°C it takes ~2h to solidify
Liquid
Gelatin liquid-solid transition
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Gelatin Gelatin : liquid for Tm>32°C solid for Tg< 28°C 26°C
Trapping laser
Trapped glass particle R=1µm
For T<Tg gelatin presents : aging and memory effects
at 10%wt concentration after a cooling at 26°C it takes ~2h to solidify
solid
Gelatin liquid-solid transition
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Gelatin 26°C
Trapping laser
Trapped glass particle R=1µm
Gelatin : liquid for Tm>32°C solid for Tg< 28°C
Infrared Laser switched on for a few minutes
Gelatin liquid-solid transition (heating)
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RL
A drop of liquid of radius RL=5 µm is formed
Gelatin 26°C The temperature around the focus grows till 38°C and the gel melts
Infrared Laser switched on for a few minutes
Gelatin liquid-solid transition (heating)
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RL
Gelatin 26°C
At t=1ms after the switch off we obtain:
A drop of an unstable liquid at 26°C inside a stable solid
The infrared laser is switched off and the liquid drop cools very fast
Trapped glass particle R=1µm
Gelatin liquid-solid transition(quench)
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RL
Gelatin 26°C Drop of an unstable liquid at 26°C inside a stable solid
What happens ?
How long does it take to solidify ?
Does the transition start from the frontier ?
What is the nature of the bead fluctuations inside the drop ?
Gelatin liquid-solid transition(quench)
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RL
Gelatin 26°C
Drop of the unstable liquid at 26°C inside the stable solid
Dynamics of the bead
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Dynamics of the bead
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From equipartition
Time evolution of the variance
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From equipartition
Time evolution of the variance
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The applied oscillating force
The linear response
Motion of a Brownian particle trapped by a laser Beam
Viscoelastic Langevin dynamics
Elastic modulus
Viscosity
Active microrheology
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The gel forms in about 30 min
Time evolution of the viscous and elastic modulusI. Pure viscousII. Negligible elasticityIII. Logarithmic growth of G’ etG’’
Gelatine liquid-solid transition
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Heat Fluctuations
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Gel elasticity
Heat Fluctuations
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Gel elasticity
Heat Fluctuations
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Gel elasticity
Heat Fluctuations
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glicerol
gelatin
Energy PDF
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Mean heat
Energy PDF and mean heat
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FT fixes the symmetries of the PDF
Fluctuation theorem
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FT fixes the symmetries of the PDF
What is the value ?
Fluctuation theorem
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Using the experimental observation that P(x) are GaussianOne gets from a simple model in the limit of large τ :
Data analysis
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Using the experimental observation that P(x) are GaussianOne gets from a simple model in the limit of large τ :
Data analysis
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Using the experimental observation that P(x) are GaussianOne gets from a simple model in the limit of large τ :
from which
Data analysis
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glicerol
gelatin
Energy PDF
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Similar relations have been theoretically derived :
Comparisons with other results
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Similar relations have been theoretically derived :
A) In the stationary case for the heat flux between two reservoirs at different temperatures
TH TC
heat flux
Comparisons with other results
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Similar relations have been theoretically derived :
A) In the stationary case for the heat flux between two reservoirs at different temperatures
TH TC
heat flux
B) In the non-stationary case during the aging of spin glasses
Comparisons with other results
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From Fluctuation Theorem
is the entropy production rate of the relaxation process
Comparing this result with numerical data of aging spin-glasses
Aging can be interpreted as an heat transfer (cooling) of the slow modes towards the heat bath
What this is useful for ?
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The liquid-solid transition is studied inside a drop of liquid after a very fast quench.
Conclusions
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The liquid-solid transition is studied inside a drop of liquid after a very fast quench.
a) The fluctuations of heat are asymmetric, i.e. the dynamics transfer heat towards the bath
b) The Fluctuation Theorem is satisfied in a non-stationary regime
Conclusions
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The liquid-solid transition is studied inside a drop of liquid after a very fast quench.
a) The fluctuations of heat are asymmetric, i.e. the dynamics transfer heat towards the bath
b) The Fluctuation Theorem is satisfied in a non-stationary regime
c) The Fluctuation Dissipation Theorem is violated
Conclusions
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Fluctuations and Linear response
0<t<15s 75<t<90s
S(f, t)
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Fluctuations and Linear response
0<t<15s 75<t<90s
S(f, t)
S(f, t) =2kB T
πfIm[R(f, t)] in equilibrium
FDT
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Fluctuations and Linear response
0<t<15s 75<t<90s
S(f, t)
S(f, t) �= 2kB T
πfIm[R(f, t)] out of equilibrium
FDT is violated in our experiment
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� ∞
0
�S(f, t)− 2kB T
πfIm{R(f, t)}
�df =
2Qt,∆t
k
Fluctuations and Linear response
0<t<15s 75<t<90s
S(f, t)
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� ∞
0
�S(f, t)− 2kB T
πfIm{R(f, t)}
�df =
2Qt,∆t
k
Fluctuations and Linear response
0<t<15s 75<t<90s
S(f, t)
heat dissipated in the time interval [t,t+Δt]
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� ∞
0
�S(f, t)− 2kB T
πfIm{R(f, t)}
�df =
2Qt,∆t
k
Fluctuations and Linear response
0<t<15s 75<t<90s
S(f, t)
heat dissipated in the time interval [t,t+Δt]
As in the generalized FDT for NESS the extra additive term is related to the heat flux. (Chetrite, Gawedzki, Seifert Speck, Maes, Lipiello, Corberi)
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The liquid-solid transition is studied inside a drop of liquid after a very fast quench.
Conclusions
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The liquid-solid transition is studied inside a drop of liquid after a very fast quench.
a) The fluctuations of heat are asymmetric, i.e. the dynamics transfer heat towards the bath
b) The Fluctuation Theorem is satisfied in a non-stationary regime
Conclusions
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The liquid-solid transition is studied inside a drop of liquid after a very fast quench.
a) The fluctuations of heat are asymmetric, i.e. the dynamics transfer heat towards the bath
b) The Fluctuation Theorem is satisfied in a non-stationary regime
c) The Fluctuation Dissipation Theorem is violated. The amount of the violation is related to the heat flux as for the
Generalized FDT for NESS.
Conclusions
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RL
t(s)
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Experiment in gelatine at 10%wt sol-gel transition at 28°C
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The stochastic resonance and Fluctuation Theorem
Brownian particle trapped by two laser beams P.Jop. A. Petrosian, S. Ciliberto, Eur. Phys. Lett. 81, 50005 (2008)
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The stochastic resonance and Fluctuation Theorem
Brownian particle trapped by two laser beams P.Jop. A. Petrosian, S. Ciliberto, Eur. Phys. Lett. 81, 50005 (2008)
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The stochastic resonance and Fluctuation Theorem
Brownian particle trapped by two laser beams P.Jop. A. Petrosian, S. Ciliberto, Eur. Phys. Lett. 81, 50005 (2008)
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The stochastic resonance and Fluctuation Theorem
Brownian particle trapped by two laser beams P.Jop. A. Petrosian, S. Ciliberto, Eur. Phys. Lett. 81, 50005 (2008)
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The stochastic resonance and Fluctuation Theorem
Brownian particle trapped by two laser beams P.Jop. A. Petrosian, S. Ciliberto, Eur. Phys. Lett. 81, 50005 (2008)
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The non linear potential
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The non linear potential
f=0.1Hz
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Stochastic Resonance
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Fluctuation Theorem for W
f=0.25Hz and τ= n / f
k BT
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Fluctuation Theorem for Q
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Theoretical comparison
A. Imparato, P. Jop, A. Petrosyan and S. Ciliberto, J. Stat. Mech. (2008) P10017
PDF of the heat computed on a single period : (initial phase=0) (averaged over different initial phases)
Experimental dataTheoretical prediction based on Fokker-Planck equation
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Conclusions on FT (partial)
We have studied the energy fluctuations of a harmonic oscillator driven out of equilibrium by an external force.
We have measured the finite time corrections for SSFT and compared to the theoretical predictions. TFT is instead verifed for all times.
The ‘’ trajectory dependent entropy ‘’ has been measured and we checked that SSFT is verified for all times for the ‘’total
entropy’’.
We have shown that in this specific example the ‘’total entropy’’ takes into account only the entropy produced by the external driving, without the entropy fluctuations at equilibrium.
We have applied also SSFT to the strongly non-linear case of the stochastic resonance
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