GEL531262 February 16, 2021 Rev. 1
Transcript of GEL531262 February 16, 2021 Rev. 1
February 12, 2021
Mr. Scot Fitzgerald Central Plateau Cleanup Company MSIN R3-50 PO Box 1600 Richland, Washington 99352
Re: SAF W21-001 Work Order: 531262 SDG: GEL531262
Dear Mr. Fitzgerald:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for thesample(s) we received on January 05, 2021. This revised data report has been prepared and reviewed inaccordance with GEL’s standard operating procedures. Per PD, the VOA list was corrected to include missingcompounds.
Test results for NELAP or ISO 17025 accredited tests are verified to meet the requirements of those standards,with any exceptions noted. The results reported relate only to the items tested and to the sample as received bythe laboratory. These results may not be reproduced except as full reports without approval by the laboratory.Copies of GEL’s accreditations and certifications can be found on our website at www.gel.com.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needson time every time. We trust that you will find everything in order and to your satisfaction. If you have anyquestions, please do not hesitate to call me at (843) 556-8171, ext. 4505.
Sincerely,
PM_SIGN_HERE Heather Shaffer Project Manager
Purchase Order: 300071 -7H Chain of Custody: W21-001-208, W21-001-209, W21-001-211, W21-001-212, W21-001-213, W21-001-242,W21-001-243, W21-001-332 and W21-001-353 Enclosures
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Table of Contents
Problem and Discrepancy Report.....................................................3
Sample Issue Resolution.....................................................................5
Case Narrative....................................................................................7
Chain of Custody and Supporting Documentation.......................17
Data Review Qualifier Definitions..................................................29
Laboratory Certifications................................................................31
Volatile Analysis...............................................................................33
Case Narrative..........................................................................34
Sample Data Summary............................................................37
Quality Control Summary.......................................................41
Semi-Volatile Analysis......................................................................58
Case Narrative..........................................................................59
Sample Data Summary............................................................65
Quality Control Summary.......................................................75
Pesticide Analysis............................................................................128
Case Narrative........................................................................129
Sample Data Summary..........................................................133
Quality Control Summary.....................................................136
PCB Analysis...................................................................................145
Case Narrative........................................................................146
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Sample Data Summary..........................................................150
Quality Control Summary.....................................................152
Herbicide Analysis..........................................................................157
Case Narrative........................................................................158
Sample Data Summary..........................................................161
Quality Control Summary.....................................................163
Metals Analysis...............................................................................169
Case Narrative........................................................................170
Sample Data Summary..........................................................174
Quality Control Summary.....................................................179
General Chem Analysis..................................................................191
Case Narrative........................................................................192
Sample Data Summary..........................................................200
Quality Control Summary.....................................................211
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Problem andDiscrepancy Report
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Date Initiated:SDG Number:Laboratory:
PROBLEM AND DISCREPANCY (P&D) REPORTP&D Number:Rev. Number:
PD21-00750GELGEL53126202/11/2021
W21-001
SAMPLE EVENT INFORMATION
SAF NUM(S):
2
SAMPLE MATRIX:
SAMPLING INFORMATION
NUMBER OF SAMPLES:
WATER
Data Issues
TYPE:
CLASS:
ISSUE BACKGROUND
Missing sample data
The following samples are missing these requested analyte results:B3YLV5126-99-8 Chloroprene107-12-0 Ethyl cyanide
B3YLV9107-12-0 Ethyl cyanide
DESCRIPTION:
Please correct the issue and resubmit the hard copy and electronic copy data packages.PROPOSED RESOLUTION:
RESOLUTION
HEY, BE
SUBMITTED BY:
02/11/2021
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Sample Issue Resolution
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01/20/2021
0
SIR21-0145
Date Initiated:
Rev. Number:
SIR Number:SAMPLE ISSUE RESOLUTION (SIR) REPORT
W21-001SAF NUM(S):
SAMPLE EVENT INFORMATION
GELLABORATORY:
1
B3YLK7
WATERSAMPLE MATRIX:
SAMPLE NUMBERS:
NUMBER OF SAMPLES:
SAMPLING INFORMATION
GEL531262SDG NUM(S):
Quality Control Failure
Laboratory Issue
TYPE:
CLASS:
ISSUE BACKGROUND
For SVOA CHPRC sample 531262 005, the surrogate Nitrobenzene-d5 failed forrecovery at 38* (39%-112%). The sample was selected as QC for the MS and MSD.The MS and MSD were well within the acceptance criteria for all surrogates. Therewere no detects of target analytes in the sample. The sample was re-extracted out ofholding and met surrogate acceptance criteria. The sample was not selected as QC inthe re-extraction. Again there were no detects of target analytes in the sample.
DESCRIPTION:
RESOLUTION
Please advise if the lab should report the in hold our out of hold data.PROPOSED RESOLUTION:
Please report the out of hold data.FINAL RESOLUTION:
01/20/2021SHAFFER, H
SUBMITTED BY:
ACCEPTED BY:
CUTSFORTH, EC 01/20/2021
A-6003-640 (REV 4)Page 1 of 1
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Case Narrative
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Per PD, the VOA list was corrected to include missing compounds.
General Narrativefor
Central Plateau Cleanup Company (74393)SAF W21-001
SDG: GEL531262
February 12, 2021 Laboratory Identification: GEL Laboratories LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171
Summary
Sample receipt
The sample(s) arrived at GEL Laboratories, LLC, Charleston, South Carolina on January 05, 2021, for analysis.The samples were delivered with proper chain of custody documentation and signatures. All sample containersarrived without any visible signs of tampering or breakage. The client was notified of a QC issue for SVOAanalysis. Please refer to the enclosed SIR for further details.
Items of Note All efforts were made by the lab to meet any short hold times. Samples that were analyzed outsideof the initial hold time but still within 2X hold time will be noted in the lab case narrative.
Sample Identification The laboratory received the following samples:
LaboratoryIdentification
SampleDescription
531262001 B3YLJ9531262002 B3YLK4531262003 B3YKN8531262004 B3YLJ6531262005 B3YLK7531262006 B3YLV9531262007 B3YLV3531262008 B3YLV7531262009 B3YLV5531262010 B3YW14
Case Narrative
Sample analyses were conducted using methodology as outlined in GEL Laboratories, LLC (GEL) StandardOperating Procedures. Any technical or administrative problems during analysis, data review, and reduction arecontained in the analytical case narratives in the enclosed data package.
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Data Package
The enclosed data package contains the following sections: General Narrative, Chain of Custody and SupportingDocumentation, and data from the following fractions: GC Semivolatile Herbicide, GC Semivolatile PCB, GCSemivolatile Pesticide, GC/MS Semivolatile, GC/MS Volatile, General Chemistry and Metals.
We certify that this package is in compliance with the Analytical Laboratory Services for CH2M Hill PlateauRemediation Company Statement of Work, both technically and for completeness, including a full descriptionof, explanation of, and corrective actions for, any and all deviations, from either the analyses requested or thecase narrative requested. Release of the data contained in this data package deliverable has been authorized bythe Laboratory Analytical Manager (or designee) and the laboratory’s client services representative as verified bytheir signatures on this report.
PM_SIGN_HERE Heather Shaffer Project Manager
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Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
GC/MS Volatile Volatile Organic Compounds (VOC) by Gas Chromatograph/Mass Spectrometer All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information Matrix Spike/Matrix Spike Duplicate Recovery Statement The spike and/or spike duplicate (See Below) recoveries were not all within the acceptance limits. Therecoveries were similar. It is believed possible matrix interference has been demonstrated.
Sample Analyte Value
1204727711 (Non SDG 531113001PS)Carbon tetrachloride0* (63%-146%)
1204727712 (Non SDG 531113001PSD)Carbon tetrachloride0* (63%-146%)
GC/MS Semivolatile Analysis of Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Calibration Information CCV Requirements All Calibration Verification Standards (CCV) did not meet the acceptance criteria as outlined in Method8270D/E for sample 531262009 (B3YLV5) for one or more target analytes. The sample was re-analyzed on aninstrument that passed CCV acceptance criteria. The re-analysis confirmed the absence of the target analytes inthe samples. The data are therefore reported from the original analysis only for all target analytes. Quality Control (QC) Information Laboratory Control Sample (LCS) Recovery The LCS and/or LCSD (See Below) did not meet spike recovery acceptance criteria. The failures are known tobe poor responding analytes as stated per the Method. This may account for the low recoveries and the data werereported.
Sample Analyte Value
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1204726591 (LCS)1, 4-Dioxane42* (43%-70%)
MS/MSD Relative Percent Difference (RPD) Statement The relative percent difference (RPD) between the MS and MSD (See Below) did not meet acceptance limits. Asthe individual MS and MSD recoveries were within the acceptance limits, the failures had no adverse impact onthe reported sample data.
Sample Analyte Value
1204726592MS and 1204726593MSD (Non SDG 531212007)Benzo(k)fluorantheneRPD 61* (0%-54%)
Technical Information Sample Re-extraction/Re-analysis Sample 531262005 (B3YLK7) was re-extracted out of holding due to surrogate failure. The re-extraction met allsurrogate recovery acceptance criteria. The PM was notified and instructed the laboratory to report there-extraction data. Miscellaneous Information Manual Integrations Sample (See Below) required manual integration in order to properly identify one or more peaks and/or tocorrectly position the baseline as set in the calibration standard injections.
Sample Analyte Value
1204726592 (Non SDG 531212007MS)Perylene-d12Result 88.9ug/L
Analysis of Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information Laboratory Control Sample (LCS) Recovery The LCS and/or LCSD (See Below) did not meet spike recovery acceptance criteria. The failures are known tobe poor responding analytes as stated per the Method. This may account for the low recoveries and the data werereported.
Sample Analyte Value
1204731281 (LCS)4-Nitrophenol 12* (21%-110%)
Spike Recovery Statement The MS or MSD (See Below) recovered spiked analytes outside of the established acceptance limits. As similarrecoveries were displayed in the MS and MSD, the failures were attributed to sample matrix interference and thedata were reported.
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Sample Analyte Value
1204731282 (B3YMF0MS) 3, 3’-Dichlorobenzidine0* (38%-130%)
Benzo(a)pyrene 0* (42%-112%)
Benzo(b)fluoranthene 0* (43%-118%)
Benzo(k)fluoranthene 43* (46%-118%)
Tributylphosphate 0* (48%-149%)
1204731283 (B3YMF0MSD)3, 3’-Dichlorobenzidine0* (38%-130%)
Tributylphosphate 0* (48%-149%)
MS/MSD Relative Percent Difference (RPD) Statement The relative percent differences (RPD) for the MS and MSD, (See Below), were not within the acceptance limits.The failures were attributed to matrix interference. The data were reported.
Sample Analyte Value
1204731282MS and 1204731283MSD (B3YMF0)Benzo(a)pyrene RPD 200* (0%-78%)
Benzo(b)fluorantheneRPD 200* (0%-45%)
Benzo(k)fluorantheneRPD 81* (0%-54%)
Technical Information Holding Time Specifications Sample (See Below) was re-extracted out of holding due to surrogate failure. The re-extraction met all surrogaterecovery acceptance criteria. There were no detects of target analytes in either extraction. The PM was notifiedand instructed the laboratory to report the re-extraction data. The data have been qualified accordingly.
Sample Value
531262005 (B3YLK7)Received 05-JAN-21, within holding, prepped 15-JAN-21, out of holding 11-JAN-21
GC Semivolatile Pesticide Organochlorine Pesticides and Chlorinated Hydrocarbons All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Calibration Information Continuing Calibration Verification (CCV) Requirements Calibration verification standards (ICV or CCV) requirements have not been met for samples 531262009(B3YLV5) and 531262010 (B3YW14) in this batch in this SDG. One or more target analytes failed acceptancecriteria with a positive bias in the standards bracketing the samples in this SDG. These target analytes were notdetected above the PQL in the associated environmental samples; therefore, the non-compliance had no adverse
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effect on the data. Quality Control (QC) Information Matrix Spike (MS/MSD) Recovery Statement The matrix QC samples (See Below) did not meet spike recovery acceptance for Endrin due to instrumentpositive bias. This non-compliance had no adverse effects on the data as Endrin was not detected in theassociated environmental samples.
Sample Analyte Value
1204726581 (B3YLV5MS) Endrin 146* (35%-144%)
1204726582 (B3YLV5MSD)Endrin 152* (35%-144%)
Miscellaneous Information Additional Comments
The Toxaphene and/or Chlordane standards were analyzed for this SDG as a retention time marker and patternreference. A five-point calibration curve and calibration verification standard forms were not submitted in thedata package since Toxaphene and/or Chlordane were not detected in the client samples.
GC Semivolatile PCB Analysis of The Analysis of Polychlorinated Biphenyls by GC/ECD by ECD All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Technical Information Preparation/Analytical Method Verification All samples and QC in this batch were cleaned using alumina in order to remove oil and other high molecularweight interferences. All samples and QC in this batch were cleaned with activated copper in order to removesulfur. Miscellaneous Information Manual integrations Samples 1204733460 (MB), 1204733461 (LCS), 1204733464 (B3YW15MS), 1204733465 (B3YW15MSD) and531262010 (B3YW14) required manual integration to correctly position the baseline as set in the calibrationstandard injections and to properly identify one or more peaks. Additional Comments The column 1 has been chosen as the primary column. The data are reported from the column 1 for all samples inthis batch.
GC Semivolatile Herbicide
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Analysis of Chlorophenoxy Acid Herbicides by ECD All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Calibration Information Continuing Calibration Verification (CCV) Requirements The calibration verification standards (CCV) did not meet acceptance criteria. One or more target analytes failedacceptance criteria with a negative bias on one analytical column in the standards bracketing samples andassociated QC. The negative bias for the analytical data is a result of instrument response decreasing after theinitial calibration. The instrument response never decreased to a point where the target analytes would not bedetected. All analytes were within the established retention time windows for this method.
Metals Determination of Metals by ICP There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Determination of Metals by ICP-MS There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Mercury Analysis Using the Perkin Elmer Automated Mercury Analyzer There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable.
General Chemistry Carbon, Total Organic There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Cyanide, Total
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There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Total Organic Halogens (TOX) There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Ion Chromatography All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Technical Information Sample Dilutions The following samples 1204726518 (B3YKN8DUP), 1204726519 (B3YKN8PS), 531262001 (B3YLJ9),531262002 (B3YLK4) and 531262003 (B3YKN8) were diluted because target analyte concentrations exceededthe calibration range.
Analyte531262
001 002 003
Chloride 2X 2X 5X
Nitrate-N 2X 2X 5X
Sulfate 2X 2X 5X
Miscellaneous Information Manual Integrations Samples 1204726518 (B3YKN8DUP) and 531262003 (B3YKN8) were manually integrated to correctly positionthe baseline as set in the calibration standards. Sulfide, Total There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Alkalinity There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
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report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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Chain of Custody andSupporting
Documentation
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Data Review QualifierDefinitions
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GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 (843) 556−8171
Report Date: 21−JAN−21
Project Specific Qualifier Definitions for GEL Client Code: CPRC
Page 1 of 1
Qualifier Qualifier Definition Department Fraction
U
J
P
C
B
E
A
X
N
*
>
Z
B
D
E
M
o
S
T
W
B
Y
+
B
C
C
<
UX
o
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Value is estimatedAroclor target analyte with greater than 25% difference between column analyses.
Analyte has been confirmed by GC/MS analysis
The analyte was detected in both the associated QC blank and in the sample.
Concentration exceeds the calibration range of the instrument
The TIC is a suspected aldol−condensation product
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Spike Sample recovery is outside control limits.
Duplicate analysis not within control limits
Result greater than quantifiable range or greater than upper limit of the analysis range
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Results are reported from a diluted aliquot of sample.
Reported value is estimated due to interferences. See comment in narrative.
Duplicate precision not met.
Analyte failed to recover within LCS limits (0rganics only)
Reported value determined by the Method of Standard Additions (MSA)
Spike and/or spike duplicate sample recovery is outside control limits.
Post−digestion spike recovery for GFAA out of control limit. Sample absorbency < 50% of spike absorbency.
The analyte was detected in the associated method blank >/= MDC or >5% sample activity.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Correlation coefficient for Method of Standard Additions (MSA) is < 0.995
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of themeasured concentration and/or decision level for associated samples.Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of themeasured concentration and/or decision level for associated samples.Sample is below the EPA guidance level for Reactive Releasable Cyanide and/or Reactive Releasable Sulfide
Gamma Spectroscopy−−Uncertain identification
Analyte failed to recover within LCS limits
Organics
Organics
Organics
Organics
Organics
Organics
Inorganics
General Chemistry
Inorganics
Inorganics
Organics
Inorganics
Organics
Inorganics
Radiological
Inorganics
General Chemistry
Inorganics
General Chemistry
General Chemistry
Radiological
Radiological
Pesticide
Semi−Volatile
Metals
Metals
Metals
Rad
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28
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G: G
EL
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LaboratoryCertifications
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State CertificationAlabamaAlaska
Alaska Drinking WaterArkansas
CLIACalifornia Colorado
ConnecticutDoD ELAP/ ISO17025 A2LA
Florida NELAPForeign Soils Permit
GeorgiaGeorgia SDWA
HawaiiIdaho
Illinois NELAPIndiana
Kansas NELAPKentucky SDWA
Kentucky WastewaterLouisiana Drinking Water
Louisiana NELAPMaine
MarylandMassachusetts
Massachusetts PFAS ApprovMichigan
MississippiNebraskaNevada
New Hampshire NELAPNew Jersey NELAP
New MexicoNew York NELAP
North CarolinaNorth Carolina SDWA
North DakotaOklahoma
Pennsylvania NELAPPuerto Rico
S. Carolina RadiochemSanitation Districts of L
South Carolina ChemistryTennessee
Texas NELAPUtah NELAP
VermontVirginia NELAP
Washington
4220017−018
SC0001288−0651
42D09040462940
SC00012PH−01692567.01E87156
P330−15−00283, P330−15−00253SC00012
967SC00012SC00012200029
C−SC−01E−10332
9012990129LA024
03046 (AI33904)2019020
270M−SC012
Letter9976
SC00012NE−OS−26−13SC000122021−1
2054SC002
SC0001211501233
45709R−158
2019−16568−00485SC0001210120002925565110120001TN 02934
T104704235−21−19SC000122020−34
VT87156460202C780
List of current GEL Certifications as of 12 February 2021
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Volatile Analysis
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Case Narrative
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GC/MS Volatile Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
Product: Volatile Organic Compounds (VOC) by Gas Chromatograph/Mass Spectrometer Preparation Method: SW846 8260D Preparation Procedure: GL-OA-E-038 REV# 28 Preparation Batch: 2079129 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262006 B3YLV9 531262009 B3YLV5 1204727709 Method Blank (MB) 1204727710 Laboratory Control Sample (LCS) 1204727711 531113001(NonSDG) Post Spike (PS) 1204727712 531113001(NonSDG) Post Spike Duplicate (PSD) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and proceduresfor initial calibration, continuing calibration, instrument controls and process controls where applicable, with thefollowing exceptions. Quality Control (QC) Information Matrix Spike/Matrix Spike Duplicate Recovery Statement The spike and/or spike duplicate (See Below) recoveries were not all within the acceptance limits. The recoverieswere similar. It is believed possible matrix interference has been demonstrated.
Sample Analyte Value
1204727711 (Non SDG 531113001PS)Carbon tetrachloride 0* (63%-146%)
1204727712 (Non SDG 531113001PSD) Carbon tetrachloride 0* (63%-146%)
Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 33 of 214 SDG: GEL531262 Rev1
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(36 of 217)
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC002 Central Plateau Cleanup Company (74393)
Client SDG: GEL531262 GEL Work Order: 531262
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:E Concentration exceeds the calibration range of the instrumentJ The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal tothe IDL/MDL (as appropriate).Value is estimatedU Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
for
DL Indicates that sample is diluted. RA Indicates that sample is re-analyzed without re-extraction. RE Indicates that sample is re-extracted.
Qualifier Definition Report
Signature: Name:
Date: Title:12 FEB 2021
Erin Haubert
Data Validator
Review/Validation
Page 34 of 214 SDG: GEL531262 Rev1
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Sample Data Summary
Page 35 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(38 of 217)
GEL Laboratories LLC
Volatile Certificate of Analysis
Sample Summary
February 12, 2021Report Date:
Page 1 of 1
SDG Number: GEL531262
Lab Sample ID: 531262006Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 08:12
75-01-4
67-64-1
75-35-4
75-15-0
75-09-2
156-60-5
75-34-3
78-93-3
156-59-2
67-66-3
71-55-6
56-23-5
107-06-2
71-43-2
71-36-3
79-01-6
108-10-1
108-88-3
79-00-5
127-18-4
108-90-7
100-41-4
106-46-7
107-12-0
109-99-9
1330-20-7
Vinyl chloride
Acetone
1,1-Dichloroethylene
Carbon disulfide
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Dichloroethane
2-Butanone
cis-1,2-Dichloroethylene
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Dichloroethane
Benzene
n-Butyl alcohol
Trichloroethylene
4-Methyl-2-pentanone
Toluene
1,1,2-Trichloroethane
Tetrachloroethylene
Chlorobenzene
Ethylbenzene
1,4-Dichlorobenzene
Propionitrile
Tetrahydrofuran
Xylenes (total)
0.333
1.74
0.333
1.67
1.67
0.333
0.333
1.67
0.333
0.333
0.333
0.333
0.333
0.333
21.1
0.333
1.67
0.333
0.333
0.333
0.333
0.333
0.333
1.67
1.67
1.00
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.333
1.74
0.333
1.67
1.67
0.333
0.333
1.67
0.333
0.333
0.333
0.333
0.333
0.333
21.1
0.333
1.67
0.333
0.333
0.333
0.333
0.333
0.333
1.67
1.67
1.00
1.00
5.00
1.00
5.00
5.00
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
50.0
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
5.00
5.00
3.00
10.0
20.0
10.0
5.00
5.00
10.0
10.0
5.00
5.00
5.00
5.00
5.00
5.00
10.0
5.00
5.00
5.00
5.00
5.00
10.0
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ RDL
Method: SW846 8260D GL-OA-E-038
Batch ID: 2079129 Inst: VOA9.I Dilution: 1SOP Ref:
Run Date: 01/07/2021 15:54 Analyst: WD1 5 mLPurge Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV9Client ID:
Prep Date: 01/07/2021 15:54
010721V9\9Z417.D Column: DB-624Data File:
Page 36 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(39 of 217)
GEL Laboratories LLC
Volatile Certificate of Analysis
Sample Summary
February 12, 2021Report Date:
Page 1 of 2
SDG Number: GEL531262
Lab Sample ID: 531262009Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 09:47
75-71-8
74-87-3
75-01-4
74-83-9
75-00-3
75-69-4
67-64-1
75-35-4
74-88-4
75-05-8
75-15-0
75-09-2
156-60-5
108-05-4
75-34-3
78-93-3
156-59-2
67-66-3
71-55-6
56-23-5
107-06-2
71-43-2
78-87-5
74-95-3
75-27-4
10061-01-5
108-10-1
108-88-3
10061-02-6
79-00-5
591-78-6
124-48-1
106-93-4
108-90-7
100-41-4
100-42-5
75-25-2
79-34-5
Dichlorodifluoromethane
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
Acetone
1,1-Dichloroethylene
Iodomethane
Acetonitrile
Carbon disulfide
Methylene chloride
trans-1,2-Dichloroethylene
Vinyl acetate
1,1-Dichloroethane
2-Butanone
cis-1,2-Dichloroethylene
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Dichloroethane
Benzene
1,2-Dichloropropane
Dibromomethane
Bromodichloromethane
cis-1,3-Dichloropropylene
4-Methyl-2-pentanone
Toluene
trans-1,3-Dichloropropylene
1,1,2-Trichloroethane
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
Ethylbenzene
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
0.355
0.333
0.333
0.337
0.333
0.333
1.74
0.333
1.67
8.33
1.67
1.67
0.333
1.67
0.333
1.67
0.333
0.340
0.333
1.98
0.333
0.333
0.333
0.333
0.333
0.333
1.67
0.333
0.333
0.333
1.67
0.333
0.333
0.333
0.333
0.333
0.333
0.333
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.355
0.333
0.333
0.337
0.333
0.333
1.74
0.333
1.67
8.33
1.67
1.67
0.333
1.67
0.333
1.67
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
1.67
0.333
0.333
0.333
1.67
0.333
0.333
0.333
0.333
0.333
0.333
0.333
1.00
1.00
1.00
1.00
1.00
1.00
5.00
1.00
5.00
25.0
5.00
5.00
1.00
5.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
5.00
1.00
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
10.0
10.0
10.0
10.0
10.0
10.0
20.0
10.0
10.0
100
5.00
5.00
5.00
50.0
10.0
10.0
5.00
5.00
5.00
3.00
5.00
5.00
5.00
10.0
5.00
5.00
10.0
5.00
5.00
5.00
20.0
5.00
5.00
5.00
4.00
5.00
5.00
5.00
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ RDL
Method: SW846 8260D GL-OA-E-038
Batch ID: 2079129 Inst: VOA9.I Dilution: 1SOP Ref:
Run Date: 01/07/2021 16:20 Analyst: WD1 5 mLPurge Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV5Client ID:
Prep Date: 01/07/2021 16:20
010721V9\9Z418.D Column: DB-624Data File:
Page 37 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(40 of 217)
GEL Laboratories LLC
Volatile Certificate of Analysis
Sample Summary
February 12, 2021Report Date:
Page 2 of 2
SDG Number: GEL531262
Lab Sample ID: 531262009Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 09:47
96-18-4
106-46-7
96-12-8
107-02-8
107-05-1
107-13-1
126-99-8
107-12-0
126-98-7
78-83-1
80-62-6
97-63-2
110-57-6
1330-20-7
630-20-6
1,2,3-Trichloropropane
1,4-Dichlorobenzene
1,2-Dibromo-3-chloropropane
Acrolein
Allyl chloride
Acrylonitrile
2-Chloro-1,3-butadiene
Propionitrile
Methacrylonitrile
Isobutyl alcohol
Methyl methacrylate
Ethyl methacrylate
trans-1,4-Dichloro-2-butene
Xylenes (total)
1,1,1,2-Tetrachloroethane
0.333
0.333
0.333
1.67
1.67
1.67
0.333
1.67
1.67
16.7
1.67
1.67
1.67
1.00
0.333
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.333
0.333
0.333
1.67
1.67
1.67
0.333
1.67
1.67
16.7
1.67
1.67
1.67
1.00
0.333
1.00
1.00
1.00
5.00
5.00
5.00
1.00
5.00
5.00
50.0
5.00
5.00
5.00
3.00
1.00
5.00
4.00
5.00
100
10.0
100
10.0
10.0
10.0
500
10.0
10.0
50.0
10.0
1.7
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ RDL
Method: SW846 8260D GL-OA-E-038
Batch ID: 2079129 Inst: VOA9.I Dilution: 1SOP Ref:
Run Date: 01/07/2021 16:20 Analyst: WD1 5 mLPurge Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV5Client ID:
Prep Date: 01/07/2021 16:20
010721V9\9Z418.D Column: DB-624Data File:
Page 38 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(41 of 217)
Quality ControlSummary
Page 39 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(42 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethylene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone
Parmname
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyMSIN R3-50
Richland, Washington
February 12, 2021Report Date:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 09:57
QC
43.8
45.4
43.1
44.4
44.9
44.4
47.3
41.2
45.4
43.2
45.0
45.3
203
NOM Sample Range
(80%-129%)
(72%-140%)
(69%-126%)
(74%-120%)
(76%-123%)
(73%-131%)
(72%-126%)
(64%-135%)
(78%-125%)
(72%-127%)
(73%-122%)
(76%-120%)
(55%-141%)
Qual
QC1204727710
REC%
88
91
86
89
90
89
95
82
91
86
90
91
81
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
LCS
531262Workorder:
PO Box 1600
RPD%
Page 1 of 15
Page 40 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(43 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
2-Hexanone
4-Methyl-2-pentanone
Acetone
Acetonitrile
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 09:57
QC
208
208
187
937
46.2
46.4
43.5
43.5
217
45.7
44.9
41.6
44.7
39.4
44.5
NOM Sample Range
(49%-158%)
(64%-128%)
(43%-164%)
(55%-127%)
(73%-120%)
(78%-135%)
(68%-131%)
(67%-133%)
(65%-132%)
(74%-145%)
(76%-120%)
(74%-125%)
(76%-126%)
(62%-131%)
(76%-132%)
Qual REC%
83
83
75
75
92
93
87
87
87
91
90
83
89
79
89
250
250
250
1250
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 2 of 15
Page 41 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(44 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Iodomethane
Methylene chloride
Styrene
Tetrachloroethylene
Toluene
Trichloroethylene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylenes (total)
cis-1,2-Dichloroethylene
cis-1,3-Dichloropropylene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 09:57
QC
45.0
48.5
44.7
226
39.3
44.0
47.7
45.7
46.5
44.9
200
42.0
135
44.8
45.1
NOM Sample Range
(75%-123%)
(55%-151%)
(76%-123%)
(69%-127%)
(68%-123%)
(72%-130%)
(72%-124%)
(74%-120%)
(74%-125%)
(73%-136%)
(62%-136%)
(68%-135%)
(66%-128%)
(76%-123%)
(78%-130%)
Qual REC%
90
97
89
90
79
88
95
91
93
90
80
84
90
90
90
50.0
50.0
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
250
50.0
150
50.0
50.0
531262Workorder:
RPD%
Page 3 of 15
Page 42 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(45 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
n-Butyl alcohol
trans-1,2-Dichloroethylene
trans-1,3-Dichloropropylene
1,2-Dichloroethane-d4
Bromofluorobenzene
Toluene-d8
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethylene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 09:57
01/07/21 11:12
QC
4390
45.6
44.3
48.7
49.9
50.3
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
NOM Sample Range
(61%-140%)
(75%-127%)
(78%-131%)
(71%-134%)
(70%-131%)
(74%-124%)
Qual
U
U
U
U
U
U
U
U
U
QC1204727709
REC%
88
91
89
97
100
101
5000
50.0
50.0
50.0
50.0
50.0
MB
531262Workorder:
**
**
**
RPD%
Page 4 of 15
Page 43 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(46 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone
2-Chloro-1,3-butadiene
2-Hexanone
4-Methyl-2-pentanone
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromodichloromethane
Bromoform
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 11:12
QC
0.333
0.333
0.333
1.67
0.333
1.67
1.67
1.74
8.33
1.67
1.67
1.67
0.333
0.333
0.333
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 5 of 15
Page 44 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(47 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethyl methacrylate
Ethylbenzene
Iodomethane
Isobutyl alcohol
Methacrylonitrile
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 11:12
QC
0.337
1.67
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.355
1.67
0.333
1.67
16.7
1.67
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 6 of 15
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
Methyl methacrylate
Methylene chloride
Propionitrile
Styrene
Tetrachloroethylene
Tetrahydrofuran
Toluene
Trichloroethylene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylenes (total)
cis-1,2-Dichloroethylene
cis-1,3-Dichloropropylene
n-Butyl alcohol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 11:12
QC
1.67
1.67
1.67
0.333
0.333
1.67
0.333
0.333
0.333
1.67
0.333
1.00
0.333
0.333
21.1
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 7 of 15
Page 46 of 214 SDG: GEL531262 Rev1
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(49 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
trans-1,2-Dichloroethylene
trans-1,3-Dichloropropylene
trans-1,4-Dichloro-2-butene
1,2-Dichloroethane-d4
Bromofluorobenzene
Toluene-d8
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethylene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 11:12
01/07/21 19:42
QC
0.333
0.333
1.67
48.7
47.8
50.8
41.8
39.3
45.4
45.9
41.1
38.5
47.5
41.0
45.6
NOM Sample
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Range
(71%-134%)
(70%-131%)
(74%-124%)
(70%-133%)
(66%-138%)
(52%-142%)
(68%-126%)
(67%-129%)
(62%-134%)
(68%-132%)
(56%-134%)
(72%-129%)
Qual
U
U
U
QC1204727711 531113001
REC%
97
96
102
84
79
91
92
82
77
95
82
91
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
PS
531262Workorder:
**
**
**
U
U
U
U
U
U
U
U
U
RPD%
Page 8 of 15
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(50 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone
2-Hexanone
4-Methyl-2-pentanone
Acetone
Acetonitrile
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 19:42
QC
42.4
43.9
42.3
211
223
219
188
944
43.1
45.5
41.7
45.3
198
331
42.5
NOM Sample
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
372
0.000
Range
(69%-132%)
(66%-129%)
(49%-125%)
(25%-143%)
(46%-132%)
(58%-131%)
(35%-148%)
(51%-136%)
(63%-124%)
(72%-140%)
(61%-136%)
(64%-137%)
(54%-137%)
(63%-146%)
(60%-122%)
Qual
E
REC%
85
88
85
84
89
88
75
76
86
91
83
91
79
0
85
50.0
50.0
50.0
250
250
250
250
1250
50.0
50.0
50.0
50.0
250
50.0
50.0
531262Workorder:
*
U
U
U
U
U
U
U
U
U
U
U
U
U
E
U
RPD%
Page 9 of 15
Page 48 of 214 SDG: GEL531262 Rev1
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Iodomethane
Methylene chloride
Styrene
Tetrachloroethylene
Toluene
Trichloroethylene
Trichlorofluoromethane
Vinyl acetate
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 19:42
QC
40.3
46.1
36.9
44.7
45.6
43.3
41.5
201
37.2
42.0
41.2
43.5
44.0
40.9
218
NOM Sample
0.000
4.18
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.83
0.000
0.000
Range
(65%-127%)
(66%-133%)
(50%-138%)
(69%-137%)
(70%-129%)
(39%-149%)
(57%-126%)
(62%-131%)
(62%-129%)
(56%-134%)
(57%-132%)
(60%-122%)
(66%-128%)
(66%-135%)
(51%-130%)
Qual REC%
81
84
74
89
91
87
83
81
74
84
82
87
82
82
87
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
250
531262Workorder:
U
J
U
U
U
U
U
U
U
U
U
U
J
U
U
RPD%
Page 10 of 15
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
Vinyl chloride
Xylenes (total)
cis-1,2-Dichloroethylene
cis-1,3-Dichloropropylene
n-Butyl alcohol
trans-1,2-Dichloroethylene
trans-1,3-Dichloropropylene
1,2-Dichloroethane-d4
Bromofluorobenzene
Toluene-d8
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 19:42
01/07/21 20:07
QC
36.6
126
41.4
44.7
4760
40.6
45.0
48.9
50.9
50.8
43.4
42.5
46.0
46.6
44.5
NOM Sample
0.000
0.000
0.000
0.000
0.000
0.000
48.4
48.8
51.0
0.000
0.000
0.000
0.000
0.000
Range
(58%-134%)
(48%-137%)
(60%-135%)
(67%-134%)
(57%-147%)
(65%-130%)
(69%-135%)
(71%-134%)
(70%-131%)
(74%-124%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
QC1204727712 531113001
4
8
1
2
8
REC%
73
84
83
89
95
81
90
98
102
102
87
85
92
93
89
50.0
150
50.0
50.0
5000
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
PSD
531262Workorder:
**
**
**
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 11 of 15
Page 50 of 214 SDG: GEL531262 Rev1
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(53 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
1,1-Dichloroethylene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone
2-Hexanone
4-Methyl-2-pentanone
Acetone
Acetonitrile
Benzene
Bromodichloromethane
Bromoform
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 20:07
QC
41.8
48.4
41.7
46.4
43.5
45.2
43.5
216
224
223
203
1030
44.8
47.0
43.5
NOM Sample
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Range
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
8
2
2
2
3
3
3
2
0
2
8
9
4
3
4
REC%
84
97
83
93
87
90
87
86
90
89
81
82
90
94
87
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
250
250
250
1250
50.0
50.0
50.0
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 12 of 15
Page 51 of 214 SDG: GEL531262 Rev1
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(54 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
Ethylbenzene
Iodomethane
Methylene chloride
Styrene
Tetrachloroethylene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 20:07
QC
46.2
215
349
43.9
40.4
48.4
37.0
45.5
46.3
43.6
42.7
222
41.0
43.8
42.4
NOM Sample
0.000
0.000
372
0.000
0.000
4.18
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Range
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
E
2
8
5
3
0
5
0
2
1
1
3
10
9
4
3
REC%
92
86
0
88
81
88
74
91
93
87
85
89
82
88
85
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
531262Workorder:
*
U
U
E
U
U
J
U
U
U
U
U
U
U
U
U
RPD%
Page 13 of 15
Page 52 of 214 SDG: GEL531262 Rev1
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(55 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Volatile-GC/MS2079129Batch
Toluene
Trichloroethylene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylenes (total)
cis-1,2-Dichloroethylene
cis-1,3-Dichloropropylene
n-Butyl alcohol
trans-1,2-Dichloroethylene
trans-1,3-Dichloropropylene
1,2-Dichloroethane-d4
Bromofluorobenzene
Toluene-d8
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
WD1 01/07/21 20:07
QC
44.7
45.8
41.2
208
36.9
130
44.3
45.6
4720
44.3
45.8
49.1
50.2
51.0
NOM Sample
0.000
2.83
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
48.4
48.8
51.0
Range
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(71%-134%)
(70%-131%)
(74%-124%)
Qual
The Qualifiers in this report are defined as follows:
3
4
1
5
1
3
7
2
1
9
2
REC%
89
86
82
83
74
87
89
91
94
89
92
98
100
102
50.0
50.0
50.0
250
50.0
150
50.0
50.0
5000
50.0
50.0
50.0
50.0
50.0
531262Workorder:
**
**
**
U
J
U
U
U
U
U
U
U
U
RPD%
Notes:
Page 14 of 15
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Parmname
Page 15 of 15
Units Anlst Date TimeQCNOM Sample RangeQual REC%
531262Workorder:
A
B
C
D
E
E
J
N
P
T
U
X
Y
Z
o
The TIC is a suspected aldol-condensation product
The analyte was detected in both the associated QC blank and in the sample.
Analyte has been confirmed by GC/MS analysis
Results are reported from a diluted aliquot of sample.
Concentration exceeds the calibration range of the instrument
Reported value is estimated due to interferences. See comment in narrative.
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Value is estimatedSpike Sample recovery is outside control limits.
Aroclor target analyte with greater than 25% difference between column analyses.
Spike and/or spike duplicate sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Analyte failed to recover within LCS limits (0rganics only)
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 54 of 214 SDG: GEL531262 Rev1
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GEL Laboratories LLC
Surrogate Recovery Report
Volatile
Report Date: February 12 2021
Page 1 of 1
SDG Number: GEL531262
Matrix Type: LIQUID
Surrogate Acceptance Limits
97 101 100
97 102 96
98 103 102
98 100 100
98 102 102
98 102 100
1204727710
1204727709
531262006
531262009
1204727711
1204727712
DCED4 %REC
TOL %REC
BFB %REC
Sample ID Client ID
LCS for batch 2079129
MB for batch 2079129
B3YLV9
B3YLV5
B3YT16PS
B3YT16PSD
1,2-Dichloroethane-d4
Toluene-d8
Bromofluorobenzene
(71%-134%)
(74%-124%)
(70%-131%)
DCED4
TOL
BFB
=
=
=
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values D Sample Diluted
Parmname
Page 55 of 214 SDG: GEL531262 Rev1
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(58 of 217)
Semi-Volatile Analysis
Page 56 of 214 SDG: GEL531262 Rev1
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(59 of 217)
Case Narrative
Page 57 of 214 SDG: GEL531262 Rev1
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GC/MS Semivolatile Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
Product: Analysis of Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry Analytical Method: SW846 3510C/8270E Analytical Procedure: GL-OA-E-009 REV# 45 Analytical Batch: 2078420 Preparation Method: SW846 3510C Preparation Procedure: GL-OA-E-013 REV# 34 Preparation Batch: 2078419
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262006 B3YLV9 531262009 B3YLV5 1204726590 Method Blank (MB) 1204726591 Laboratory Control Sample (LCS) 1204726592 531212007(NonSDG) Matrix Spike (MS) 1204726593 531212007(NonSDG) Matrix Spike Duplicate (MSD) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Calibration Information CCV Requirements All Calibration Verification Standards (CCV) did not meet the acceptance criteria as outlined in Method8270D/E for sample 531262009 (B3YLV5) for one or more target analytes. The sample was re-analyzed on aninstrument that passed CCV acceptance criteria. The re-analysis confirmed the absence of the target analytes inthe samples. The data are therefore reported from the original analysis only for all target analytes. Quality Control (QC) Information Laboratory Control Sample (LCS) Recovery The LCS and/or LCSD (See Below) did not meet spike recovery acceptance criteria. The failures are known tobe poor responding analytes as stated per the Method. This may account for the low recoveries and the data werereported.
Sample Analyte Value
1204726591 (LCS)1, 4-Dioxane42* (43%-70%)
Page 58 of 214 SDG: GEL531262 Rev1
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MS/MSD Relative Percent Difference (RPD) Statement The relative percent difference (RPD) between the MS and MSD (See Below) did not meet acceptance limits. Asthe individual MS and MSD recoveries were within the acceptance limits, the failures had no adverse impact onthe reported sample data.
Sample Analyte Value
1204726592MS and 1204726593MSD (Non SDG 531212007)Benzo(k)fluorantheneRPD 61* (0%-54%)
Technical Information Sample Re-extraction/Re-analysis Sample 531262005 (B3YLK7) was re-extracted out of holding due to surrogate failure. The re-extraction met allsurrogate recovery acceptance criteria. The PM was notified and instructed the laboratory to report there-extraction data. Miscellaneous Information Manual Integrations Sample (See Below) required manual integration in order to properly identify one or more peaks and/or tocorrectly position the baseline as set in the calibration standard injections.
Sample Analyte Value
1204726592 (Non SDG 531212007MS)Perylene-d12Result 88.9ug/L
Product: Analysis of Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry Analytical Method: SW846 3510C/8270E Analytical Procedure: GL-OA-E-009 REV# 45 Analytical Batch: 2081190 Preparation Method: SW846 3510C Preparation Procedure: GL-OA-E-013 REV# 34 Preparation Batch: 2081189
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262005 B3YLK7 1204731280 Method Blank (MB) 1204731281 Laboratory Control Sample (LCS) 1204731282 531763005(B3YMF0) Matrix Spike (MS) 1204731283 531763005(B3YMF0) Matrix Spike Duplicate (MSD) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls where
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applicable, with the following exceptions. Quality Control (QC) Information Laboratory Control Sample (LCS) Recovery The LCS and/or LCSD (See Below) did not meet spike recovery acceptance criteria. The failures are known tobe poor responding analytes as stated per the Method. This may account for the low recoveries and the data werereported.
Sample Analyte Value
1204731281 (LCS)4-Nitrophenol 12* (21%-110%)
Spike Recovery Statement The MS or MSD (See Below) recovered spiked analytes outside of the established acceptance limits. As similarrecoveries were displayed in the MS and MSD, the failures were attributed to sample matrix interference and thedata were reported.
Sample Analyte Value
1204731282 (B3YMF0MS) 3, 3’-Dichlorobenzidine0* (38%-130%)
Benzo(a)pyrene 0* (42%-112%)
Benzo(b)fluoranthene 0* (43%-118%)
Benzo(k)fluoranthene 43* (46%-118%)
Tributylphosphate 0* (48%-149%)
1204731283 (B3YMF0MSD)3, 3’-Dichlorobenzidine0* (38%-130%)
Tributylphosphate 0* (48%-149%)
MS/MSD Relative Percent Difference (RPD) Statement The relative percent differences (RPD) for the MS and MSD, (See Below), were not within the acceptance limits.The failures were attributed to matrix interference. The data were reported.
Sample Analyte Value
1204731282MS and 1204731283MSD (B3YMF0)Benzo(a)pyrene RPD 200* (0%-78%)
Benzo(b)fluorantheneRPD 200* (0%-45%)
Benzo(k)fluorantheneRPD 81* (0%-54%)
Technical Information Holding Time Specifications Sample (See Below) was re-extracted out of holding due to surrogate failure. The re-extraction met all surrogaterecovery acceptance criteria. There were no detects of target analytes in either extraction. The PM was notifiedand instructed the laboratory to report the re-extraction data. The data have been qualified accordingly.
Sample Value
531262005 (B3YLK7)Received 05-JAN-21, within holding, prepped 15-JAN-21, out of holding 11-JAN-21
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Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC002 Central Plateau Cleanup Company (74393)
Client SDG: GEL531262 GEL Work Order: 531262
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:J The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal tothe IDL/MDL (as appropriate).Value is estimatedT Spike and/or spike duplicate sample recovery is outside control limits. U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
for
DL Indicates that sample is diluted. RA Indicates that sample is re-analyzed without re-extraction. RE Indicates that sample is re-extracted.
Qualifier Definition Report
Signature: Name:
Date: Title:29 JAN 2021
Barbara Bailey
Data Validator
Review/Validation
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Sample Data Summary
Page 63 of 214 SDG: GEL531262 Rev1
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GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 1 of 4
SDG Number: GEL531262
Lab Sample ID: 531262005Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 10:43
62-75-9
110-86-1
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
95-50-1
108-60-1
100-51-6
95-48-7
65794-96-9
621-64-7
67-72-1
98-95-3
78-59-1
88-75-5
105-67-9
111-91-1
120-83-2
106-47-8
87-68-3
59-50-7
91-57-6
91-20-3
77-47-4
88-06-2
95-95-4
91-58-7
88-74-4
99-09-2
131-11-3
99-65-0
606-20-2
121-14-2
208-96-8
83-32-9
N-Methyl-N-nitrosomethylamine
Pyridine
Aniline
Phenol
bis(2-Chloroethyl) ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
bis(2-Chloro-1-methylethyl)ether
Benzyl alcohol
o-Cresol
m,p-Cresols
N-Nitrosodipropylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
2,4-Dichlorophenol
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Naphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
o-Nitroaniline
m-Nitroaniline
Dimethylphthalate
m-Dinitrobenzene
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
Acenaphthene
2.85
2.85
3.99
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.52
2.85
2.85
2.85
3.33
2.85
2.85
2.85
2.85
3.14
2.85
2.85
0.285
0.285
2.85
2.85
2.85
0.390
2.85
2.85
0.285
2.85
2.85
2.85
0.285
0.285
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
2.85
2.85
3.99
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.52
2.85
2.85
2.85
3.33
2.85
2.85
2.85
2.85
3.14
2.85
2.85
0.285
0.285
2.85
2.85
2.85
0.390
2.85
2.85
0.285
2.85
2.85
2.85
0.285
0.285
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
0.951
0.951
9.51
9.51
9.51
0.951
9.51
9.51
9.51
9.51
9.51
9.51
0.951
0.951
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2081190 Inst: MSD4.I Dilution: 1SOP Ref:
Run Date: 01/15/2021 16:19 Analyst: NM1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLK7Client ID:
Prep Date: Aliquot: Final Volume:01/15/2021 09:50 1051.99 mL 1 mL
s011521.B\s4A1509.D Column: DB-5msData File:
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GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 2 of 4
SDG Number: GEL531262
Lab Sample ID: 531262005Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 10:43
51-28-5
132-64-9
58-90-2
84-66-2
100-02-7
86-73-7
7005-72-3
100-01-6
534-52-1
DPA+NNDPA
101-55-3
118-74-1
87-86-5
88-85-7
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
129-00-0
85-68-7
117-81-7
56-55-3
218-01-9
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
123-91-1
109-06-8
10595-95-6
66-27-3
55-18-5
62-50-0
76-01-7
2,4-Dinitrophenol
Dibenzofuran
2,3,4,6-Tetrachlorophenol
Diethylphthalate
4-Nitrophenol
Fluorene
4-Chlorophenylphenylether
p-Nitroaniline
2-Methyl-4,6-dinitrophenol
diphenylamine+N-nitrosodiphenylamine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Dinoseb
Phenanthrene
Anthracene
Carbazole
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
Chrysene
Di-n-octylphthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
Dibenzo(a,h)anthracene
Benzo(ghi)perylene
1,4-Dioxane
2-Picoline
N-Nitrosomethylethylamine
Methyl methanesulfonate
N-Nitrosodiethylamine
Ethyl Methanesulfonate
Pentachloroethane
4.75
2.85
2.85
0.285
2.85
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
4.75
2.85
2.85
0.285
2.85
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
19.0
9.51
9.51
9.51
9.51
0.951
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
0.951
0.951
0.951
9.51
0.951
0.951
9.51
0.951
0.951
0.951
9.51
0.951
0.951
0.951
0.951
0.951
0.951
9.51
9.51
9.51
9.51
9.51
9.51
9.51
Diphenylamine122-39-4
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2081190 Inst: MSD4.I Dilution: 1SOP Ref:
Run Date: 01/15/2021 16:19 Analyst: NM1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLK7Client ID:
Prep Date: Aliquot: Final Volume:01/15/2021 09:50 1051.99 mL 1 mL
s011521.B\s4A1509.D Column: DB-5msData File:
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GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 3 of 4
SDG Number: GEL531262
Lab Sample ID: 531262005Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 10:43
930-55-2
98-86-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
1888-71-7
924-16-3
94-59-7
95-94-3
120-58-1
130-15-4
608-93-5
134-32-7
91-59-8
99-55-8
99-35-4
62-44-2
2303-16-4
92-67-1
82-68-8
23950-58-5
56-57-5
91-80-5
465-73-6
140-57-8
143-50-0
60-11-7
510-15-6
119-93-7
53-96-3
91-94-1
57-97-6
56-49-5
126-68-1
297-97-2
126-73-8
N-Nitrosopyrrolidine
Acetophenone
N-Nitrosomorpholine
o-Toluidine
N-Nitrosopiperidine
a,a-Dimethylphenethylamine
2,6-Dichlorophenol
Hexachloropropene
N-Nitrosodi-n-butylamine
Safrole
1,2,4,5-Tetrachlorobenzene
Isosafrole
1,4-Naphthoquinone
Pentachlorobenzene
1-Naphthylamine
2-Naphthylamine
5-Nitro-o-toluidine
1,3,5-Trinitrobenzene
Phenacetin
Diallate
4-Aminobiphenyl
Pentachloronitrobenzene
Pronamide
4-Nitroquinoline-1-oxide
Methapyrilene
Isodrin
Aramite
Kepone
p-(Dimethylamino)azobenzene
Chlorobenzilate
3,3'-Dimethylbenzidine
2-Acetylaminofluorene
3,3'-Dichlorobenzidine
7,12-Dimethylbenz(a)anthracene
3-Methylcholanthrene
Triethylphosphorothioate
Thionazin
Tributylphosphate
2.85
2.85
2.85
2.85
2.85
5.13
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.23
2.85
3.61
2.85
2.85
3.52
2.85
2.85
2.85
3.14
2.85
2.85
2.85
2.85
2.85
2.85
2.85
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
2.85
2.85
2.85
2.85
2.85
5.13
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.23
2.85
3.61
2.85
2.85
3.52
2.85
2.85
2.85
3.14
2.85
2.85
2.85
2.85
2.85
2.85
2.85
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2081190 Inst: MSD4.I Dilution: 1SOP Ref:
Run Date: 01/15/2021 16:19 Analyst: NM1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLK7Client ID:
Prep Date: Aliquot: Final Volume:01/15/2021 09:50 1051.99 mL 1 mL
s011521.B\s4A1509.D Column: DB-5msData File:
Page 66 of 214 SDG: GEL531262 Rev1
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GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 4 of 4
SDG Number: GEL531262
Lab Sample ID: 531262005Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 10:43
3689-24-5
298-02-2
60-51-5
298-04-4
298-00-0
56-38-2
52-85-7
106-50-3
70-30-4
120-82-1
Sulfotepp
Phorate
Dimethoate
Disulfoton
Methyl parathion
Parathion
Famphur
p-Phenylenediamine
Hexachlorophene
1,2,4-Trichlorobenzene
2.85
2.85
2.85
2.85
2.85
2.85
4.75
95.1
159
2.85
UX
UX
UX
UX
UX
UX
UX
UX
UX
UX
2.85
2.85
2.85
2.85
2.85
2.85
4.75
95.1
159
2.85
9.51
9.51
9.51
9.51
9.51
9.51
9.51
475
475
9.51
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2081190 Inst: MSD4.I Dilution: 1SOP Ref:
Run Date: 01/15/2021 16:19 Analyst: NM1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLK7Client ID:
Prep Date: Aliquot: Final Volume:01/15/2021 09:50 1051.99 mL 1 mL
s011521.B\s4A1509.D Column: DB-5msData File:
Page 67 of 214 SDG: GEL531262 Rev1
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(70 of 217)
GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 1 of 1
SDG Number: GEL531262
Lab Sample ID: 531262006Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 08:12
123-91-1 1,4-Dioxane 2.89U 2.89 9.64
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2078420 Inst: MSDA.I Dilution: 1SOP Ref:
Run Date: 01/06/2021 20:37 Analyst: LXA1 1 uLInj. Vol:
Units
ug/L
B3YLV9Client ID:
Prep Date: Aliquot: Final Volume:01/06/2021 04:59 1037.74 mL 1 mL
010621.s\SAa0620.D Column: DB-5msData File:
Page 68 of 214 SDG: GEL531262 Rev1
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(71 of 217)
GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 1 of 4
SDG Number: GEL531262
Lab Sample ID: 531262009Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 09:47
62-75-9
110-86-1
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
95-50-1
108-60-1
100-51-6
95-48-7
65794-96-9
621-64-7
67-72-1
98-95-3
78-59-1
88-75-5
105-67-9
111-91-1
120-83-2
106-47-8
87-68-3
59-50-7
91-57-6
91-20-3
77-47-4
88-06-2
95-95-4
91-58-7
88-74-4
99-09-2
131-11-3
99-65-0
606-20-2
121-14-2
208-96-8
83-32-9
N-Methyl-N-nitrosomethylamine
Pyridine
Aniline
Phenol
bis(2-Chloroethyl) ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
bis(2-Chloro-1-methylethyl)ether
Benzyl alcohol
o-Cresol
m,p-Cresols
N-Nitrosodipropylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
bis(2-Chloroethoxy)methane
2,4-Dichlorophenol
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Naphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
o-Nitroaniline
m-Nitroaniline
Dimethylphthalate
m-Dinitrobenzene
2,6-Dinitrotoluene
2,4-Dinitrotoluene
Acenaphthylene
Acenaphthene
2.85
2.85
4.00
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.52
2.85
2.85
2.85
3.33
2.85
2.85
2.85
2.85
3.14
2.85
2.85
0.285
0.285
2.85
2.85
2.85
0.390
2.85
2.85
0.285
2.85
2.85
2.85
0.285
0.285
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
2.85
2.85
4.00
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.52
2.85
2.85
2.85
3.33
2.85
2.85
2.85
2.85
3.14
2.85
2.85
0.285
0.285
2.85
2.85
2.85
0.390
2.85
2.85
0.285
2.85
2.85
2.85
0.285
0.285
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
0.951
0.951
9.51
9.51
9.51
0.951
9.51
9.51
9.51
9.51
9.51
9.51
0.951
0.951
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2078420 Inst: MSDA.I Dilution: 1SOP Ref:
Run Date: 01/06/2021 21:05 Analyst: LXA1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV5Client ID:
Prep Date: Aliquot: Final Volume:01/06/2021 04:59 1051.17 mL 1 mL
010621.s\SAa0621.D Column: DB-5msData File:
Page 69 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(72 of 217)
GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 2 of 4
SDG Number: GEL531262
Lab Sample ID: 531262009Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 09:47
51-28-5
132-64-9
58-90-2
84-66-2
100-02-7
86-73-7
7005-72-3
100-01-6
534-52-1
DPA+NNDPA
101-55-3
118-74-1
87-86-5
88-85-7
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
129-00-0
85-68-7
117-81-7
56-55-3
218-01-9
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
123-91-1
109-06-8
10595-95-6
66-27-3
55-18-5
62-50-0
76-01-7
2,4-Dinitrophenol
Dibenzofuran
2,3,4,6-Tetrachlorophenol
Diethylphthalate
4-Nitrophenol
Fluorene
4-Chlorophenylphenylether
p-Nitroaniline
2-Methyl-4,6-dinitrophenol
diphenylamine+N-nitrosodiphenylamine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Dinoseb
Phenanthrene
Anthracene
Carbazole
Di-n-butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
bis(2-Ethylhexyl)phthalate
Benzo(a)anthracene
Chrysene
Di-n-octylphthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
Dibenzo(a,h)anthracene
Benzo(ghi)perylene
1,4-Dioxane
2-Picoline
N-Nitrosomethylethylamine
Methyl methanesulfonate
N-Nitrosodiethylamine
Ethyl Methanesulfonate
Pentachloroethane
4.76
2.85
2.85
0.285
2.85
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
TU
U
U
U
U
U
U
U
U
U
U
U
U
U
4.76
2.85
2.85
0.285
2.85
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
0.285
2.85
2.85
2.85
2.85
2.85
2.85
2.85
19.0
9.51
9.51
9.51
9.51
0.951
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
0.951
0.951
0.951
9.51
0.951
0.951
9.51
0.951
0.951
0.951
9.51
0.951
0.951
0.951
0.951
0.951
0.951
9.51
9.51
9.51
9.51
9.51
9.51
9.51
Diphenylamine122-39-4
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2078420 Inst: MSDA.I Dilution: 1SOP Ref:
Run Date: 01/06/2021 21:05 Analyst: LXA1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV5Client ID:
Prep Date: Aliquot: Final Volume:01/06/2021 04:59 1051.17 mL 1 mL
010621.s\SAa0621.D Column: DB-5msData File:
Page 70 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(73 of 217)
GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 3 of 4
SDG Number: GEL531262
Lab Sample ID: 531262009Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 09:47
930-55-2
98-86-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
1888-71-7
924-16-3
94-59-7
95-94-3
120-58-1
130-15-4
608-93-5
134-32-7
91-59-8
99-55-8
99-35-4
62-44-2
2303-16-4
92-67-1
82-68-8
23950-58-5
56-57-5
91-80-5
465-73-6
140-57-8
143-50-0
60-11-7
510-15-6
119-93-7
53-96-3
91-94-1
57-97-6
56-49-5
126-68-1
297-97-2
126-73-8
N-Nitrosopyrrolidine
Acetophenone
N-Nitrosomorpholine
o-Toluidine
N-Nitrosopiperidine
a,a-Dimethylphenethylamine
2,6-Dichlorophenol
Hexachloropropene
N-Nitrosodi-n-butylamine
Safrole
1,2,4,5-Tetrachlorobenzene
Isosafrole
1,4-Naphthoquinone
Pentachlorobenzene
1-Naphthylamine
2-Naphthylamine
5-Nitro-o-toluidine
1,3,5-Trinitrobenzene
Phenacetin
Diallate
4-Aminobiphenyl
Pentachloronitrobenzene
Pronamide
4-Nitroquinoline-1-oxide
Methapyrilene
Isodrin
Aramite
Kepone
p-(Dimethylamino)azobenzene
Chlorobenzilate
3,3'-Dimethylbenzidine
2-Acetylaminofluorene
3,3'-Dichlorobenzidine
7,12-Dimethylbenz(a)anthracene
3-Methylcholanthrene
Triethylphosphorothioate
Thionazin
Tributylphosphate
2.85
2.85
2.85
2.85
2.85
5.14
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.23
2.85
3.62
2.85
2.85
3.52
2.85
2.85
2.85
3.14
2.85
2.85
2.85
2.85
2.85
2.85
2.85
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
2.85
2.85
2.85
2.85
2.85
5.14
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
2.85
3.23
2.85
3.62
2.85
2.85
3.52
2.85
2.85
2.85
3.14
2.85
2.85
2.85
2.85
2.85
2.85
2.85
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
9.51
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2078420 Inst: MSDA.I Dilution: 1SOP Ref:
Run Date: 01/06/2021 21:05 Analyst: LXA1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV5Client ID:
Prep Date: Aliquot: Final Volume:01/06/2021 04:59 1051.17 mL 1 mL
010621.s\SAa0621.D Column: DB-5msData File:
Page 71 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(74 of 217)
GEL Laboratories LLC
Semi-Volatile Certificate of Analysis
Sample Summary
January 28, 2021Report Date:
Page 4 of 4
SDG Number: GEL531262
Lab Sample ID: 531262009Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 09:47
3689-24-5
298-02-2
60-51-5
298-04-4
298-00-0
56-38-2
52-85-7
106-50-3
70-30-4
120-82-1
Sulfotepp
Phorate
Dimethoate
Disulfoton
Methyl parathion
Parathion
Famphur
p-Phenylenediamine
Hexachlorophene
1,2,4-Trichlorobenzene
2.85
2.85
2.85
2.85
2.85
2.85
4.76
95.1
159
2.85
U
U
U
U
U
U
U
U
U
U
2.85
2.85
2.85
2.85
2.85
2.85
4.76
95.1
159
2.85
9.51
9.51
9.51
9.51
9.51
9.51
9.51
476
476
9.51
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3510C/8270E GL-OA-E-009
Batch ID: 2078420 Inst: MSDA.I Dilution: 1SOP Ref:
Run Date: 01/06/2021 21:05 Analyst: LXA1 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV5Client ID:
Prep Date: Aliquot: Final Volume:01/06/2021 04:59 1051.17 mL 1 mL
010621.s\SAa0621.D Column: DB-5msData File:
Page 72 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(75 of 217)
Quality ControlSummary
Page 73 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(76 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
Parmname
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyMSIN R3-50
Richland, Washington
January 28, 2021Report Date:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:03
QC
41.4
38.8
35.2
33.3
34.0
20.9
51.7
49.5
50.6
45.0
37.9
50.8
53.3
NOM Sample Range
(41%-111%)
(43%-105%)
(40%-92%)
(40%-89%)
(42%-92%)
(43%-70%)
(51%-131%)
(58%-137%)
(60%-127%)
(58%-119%)
(46%-99%)
(28%-151%)
(55%-134%)
Qual
QC1204726591
REC%
83
78
70
67
68
42
103
99
101
90
76
102
107
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
LCS
531262Workorder:
PO Box 1600
*
RPD%
Page 1 of 51
Page 74 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(77 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Nitrophenol
3,3'-Dichlorobenzidine
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
Acenaphthene
Acenaphthylene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:03
QC
45.4
48.7
42.5
37.7
54.9
40.8
46.8
43.3
46.5
45.3
44.2
47.9
20.5
42.8
42.2
NOM Sample Range
(58%-124%)
(59%-126%)
(47%-108%)
(46%-107%)
(42%-149%)
(48%-104%)
(56%-115%)
(56%-137%)
(49%-114%)
(56%-118%)
(59%-122%)
(56%-120%)
(21%-110%)
(51%-109%)
(51%-108%)
Qual REC%
91
97
85
75
110
82
94
87
93
91
88
96
41
86
84
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 2 of 51
Page 75 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(78 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Acetophenone
Aniline
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
Butylbenzylphthalate
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenzo(a,h)anthracene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:03
QC
41.7
34.0
45.8
46.0
43.1
45.2
40.6
46.9
37.5
44.4
51.9
46.4
46.1
34.9
43.0
NOM Sample Range
(50%-111%)
(43%-103%)
(56%-110%)
(60%-112%)
(55%-110%)
(54%-111%)
(44%-133%)
(54%-117%)
(40%-100%)
(54%-118%)
(55%-120%)
(59%-116%)
(55%-122%)
(50%-125%)
(42%-130%)
Qual REC%
83
68
92
92
86
90
81
94
75
89
104
93
92
70
86
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 3 of 51
Page 76 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(79 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
N-Methyl-N-nitrosomethylamine
N-Nitrosodipropylamine
N-Nitrosopyrrolidine
Naphthalene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:03
QC
46.5
48.6
48.0
48.8
46.5
46.2
35.4
34.6
30.6
42.4
43.3
24.7
44.2
46.8
40.5
NOM Sample Range
(55%-122%)
(60%-121%)
(62%-123%)
(54%-121%)
(56%-111%)
(51%-118%)
(39%-103%)
(30%-95%)
(36%-90%)
(48%-128%)
(58%-113%)
(32%-84%)
(49%-118%)
(59%-119%)
(49%-103%)
Qual REC%
93
97
96
98
93
92
71
69
61
85
87
49
88
94
81
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 4 of 51
Page 77 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(80 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Pyridine
Tributylphosphate
bis(2-Chloro-1-methylethyl)ether
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Nitroaniline
o-Cresol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:03
QC
40.6
53.8
46.4
17.3
44.8
13.7
53.5
37.2
40.6
39.3
36.5
46.7
34.7
50.8
37.3
NOM Sample Range
(55%-110%)
(42%-132%)
(56%-110%)
(12%-90%)
(43%-122%)
(25%-90%)
(61%-135%)
(42%-115%)
(56%-108%)
(47%-108%)
(47%-118%)
(48%-117%)
(39%-95%)
(55%-140%)
(39%-102%)
Qual REC%
81
108
93
35
90
27
107
74
81
79
73
93
69
102
75
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 5 of 51
Page 78 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(81 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
o-Nitroaniline
p-Nitroaniline
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
p-Terphenyl-d14
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3,5-Trinitrobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:03
01/06/21 15:08
QC
46.4
65.1
108
43.8
41.5
39.2
32.8
37.0
3.00
3.00
3.00
3.00
3.00
3.00
3.00
NOM Sample Range
(59%-123%)
(52%-149%)
(37%-132%)
(39%-112%)
(11%-79%)
(39%-112%)
(15%-85%)
(24%-129%)
Qual
U
U
U
U
U
U
U
QC1204726590
REC%
93
130
108
88
41
78
33
74
50.0
50.0
100
50.0
100
50.0
100
50.0
MB
531262Workorder:
**
**
**
**
**
**
RPD%
Page 6 of 51
Page 79 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(82 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
1,4-Naphthoquinone
1-Naphthylamine
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Acetylaminofluorene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
3.00
3.00
3.00
3.00
3.00
3.00
3.00
5.00
3.00
3.00
3.00
3.00
0.410
3.00
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 7 of 51
Page 80 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(83 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
2-Methylnaphthalene
2-Naphthylamine
2-Nitrophenol
2-Picoline
3,3'-Dichlorobenzidine
3,3'-Dimethylbenzidine
3-Methylcholanthrene
4-Aminobiphenyl
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
4-Nitroquinoline-1-oxide
5-Nitro-o-toluidine
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
0.300
3.00
3.00
3.00
3.00
3.30
3.00
3.00
3.00
3.00
3.30
3.00
3.00
3.80
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 8 of 51
Page 81 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(84 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
7,12-Dimethylbenz(a)anthracene
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Anthracene
Aramite
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
Butylbenzylphthalate
Carbazole
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
3.00
0.300
0.300
3.00
4.20
0.300
3.70
0.300
0.300
0.300
0.300
0.300
3.00
0.300
0.300
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 9 of 51
Page 82 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(85 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Chlorobenzilate
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Diallate
Dibenzo(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethoate
Dimethylphthalate
Dinoseb
Disulfoton
Ethyl Methanesulfonate
Famphur
Fluoranthene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
3.00
0.300
0.300
0.300
3.00
0.300
3.00
0.300
3.00
0.300
3.00
3.00
3.00
5.00
0.300
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 10 of 51
Page 83 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(86 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Indeno(1,2,3-cd)pyrene
Isodrin
Isophorone
Isosafrole
Kepone
Methapyrilene
Methyl methanesulfonate
Methyl parathion
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
0.300
3.00
3.00
3.00
3.00
167
3.00
0.300
3.00
3.50
3.00
3.00
3.00
3.00
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 11 of 51
Page 84 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(87 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
N-Methyl-N-nitrosomethylamine
N-Nitrosodi-n-butylamine
N-Nitrosodiethylamine
N-Nitrosodipropylamine
N-Nitrosomethylethylamine
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Naphthalene
Nitrobenzene
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
0.300
3.00
3.00
3.00
3.00
3.40
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 12 of 51
Page 85 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(88 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Phenacetin
Phenanthrene
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Sulfotepp
Thionazin
Tributylphosphate
Triethylphosphorothioate
a,a-Dimethylphenethylamine
bis(2-Chloro-1-methylethyl)ether
bis(2-Chloroethoxy)methane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
3.00
0.300
3.00
3.00
3.00
0.300
3.00
3.00
3.00
3.00
3.00
3.00
5.40
3.00
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 13 of 51
Page 86 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(89 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Dinitrobenzene
m-Nitroaniline
o-Cresol
o-Nitroaniline
o-Toluidine
p-(Dimethylamino)azobenzene
p-Nitroaniline
p-Phenylenediamine
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
QC
3.00
0.300
3.00
3.70
3.00
3.00
3.00
3.00
3.00
3.00
3.00
100
81.0
35.1
35.7
NOM Sample Range
(37%-132%)
(39%-112%)
(11%-79%)
Qual
U
U
U
U
U
U
U
U
U
U
U
U
REC%
81
70
36
100
50.0
100
531262Workorder:
**
**
**
RPD%
Page 14 of 51
Page 87 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(90 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Nitrobenzene-d5
Phenol-d5
p-Terphenyl-d14
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 15:08
01/06/21 16:57
QC
31.8
25.9
28.2
83.0
72.2
64.4
59.9
61.1
48.9
107
99.3
102
89.3
75.6
114
NOM Sample
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
5.00
Range
(39%-112%)
(15%-85%)
(24%-129%)
(35%-117%)
(29%-111%)
(33%-101%)
(31%-97%)
(37%-90%)
(29%-96%)
(43%-134%)
(49%-125%)
(47%-130%)
(49%-119%)
(40%-111%)
(25%-154%)
Qual
QC1204726592 531212007
REC%
64
26
56
75
65
58
54
55
44
96
89
92
80
68
103
50.0
100
50.0
111
111
111
111
111
111
111
111
111
111
111
111
MS
531262Workorder:
**
**
**
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 15 of 51
Page 88 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(91 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Nitrophenol
3,3'-Dichlorobenzidine
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
Acenaphthene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:57
QC
109
89.2
98.3
84.6
70.4
118
80.3
87.0
96.2
95.5
92.7
87.0
97.3
67.7
86.5
NOM Sample
3.00
3.00
3.00
0.410
3.00
3.00
0.300
3.00
3.00
3.00
3.00
3.30
3.00
3.00
0.300
Range
(49%-136%)
(48%-129%)
(49%-126%)
(36%-120%)
(42%-113%)
(30%-145%)
(37%-109%)
(42%-120%)
(38%-130%)
(43%-121%)
(42%-123%)
(41%-126%)
(47%-122%)
(20%-98%)
(43%-118%)
Qual REC%
98
80
88
76
63
106
72
78
87
86
83
78
88
61
78
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 16 of 51
Page 89 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(92 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Acenaphthylene
Acetophenone
Aniline
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
Butylbenzylphthalate
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:57
QC
84.8
77.8
69.9
93.9
94.6
87.5
62.3
102
53.8
77.4
89.0
109
95.9
95.1
46.0
NOM Sample
0.300
3.00
4.20
0.300
0.300
0.300
0.300
0.300
0.300
3.00
0.300
0.300
0.300
0.590
0.300
Range
(39%-120%)
(39%-118%)
(35%-114%)
(46%-117%)
(48%-118%)
(42%-112%)
(43%-118%)
(32%-121%)
(46%-118%)
(35%-115%)
(43%-124%)
(47%-127%)
(47%-121%)
(45%-124%)
(38%-128%)
Qual REC%
76
70
63
85
85
79
56
92
48
70
80
98
86
85
41
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
RPD%
Page 17 of 51
Page 90 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(93 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Dibenzo(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
N-Methyl-N-nitrosomethylamine
N-Nitrosodipropylamine
N-Nitrosopyrrolidine
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:57
QC
107
94.1
99.5
97.7
97.7
94.6
95.0
67.5
66.0
56.4
106
81.3
55.9
81.4
89.6
NOM Sample
0.300
3.00
0.300
0.300
0.300
0.300
3.00
3.00
3.00
3.00
0.300
3.50
3.00
3.00
3.00
Range
(33%-131%)
(46%-117%)
(49%-128%)
(50%-130%)
(44%-121%)
(44%-119%)
(46%-116%)
(24%-102%)
(18%-89%)
(27%-95%)
(35%-130%)
(42%-116%)
(27%-101%)
(36%-121%)
(52%-127%)
Qual REC%
96
85
90
88
88
85
86
61
59
51
95
73
50
73
81
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 18 of 51
Page 91 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(94 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Pyridine
Tributylphosphate
bis(2-Chloro-1-methylethyl)ether
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Nitroaniline
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:57
QC
75.9
75.4
120
95.8
46.1
88.0
44.8
112
69.5
77.6
71.4
76.9
94.5
74.6
105
NOM Sample
0.300
3.00
3.00
0.300
3.00
0.300
3.00
3.00
3.00
3.00
3.00
0.870
3.00
3.70
3.00
Range
(34%-104%)
(44%-119%)
(36%-139%)
(48%-112%)
(23%-71%)
(39%-120%)
(22%-103%)
(48%-149%)
(32%-122%)
(41%-118%)
(39%-112%)
(37%-120%)
(41%-118%)
(35%-112%)
(39%-149%)
Qual REC%
68
68
108
86
41
79
40
101
63
70
64
68
85
67
95
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
RPD%
Page 19 of 51
Page 92 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(95 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
o-Cresol
o-Nitroaniline
p-Nitroaniline
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
p-Terphenyl-d14
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 16:57
01/06/21 17:25
QC
75.9
96.4
138
219
87.1
91.2
73.4
87.2
67.8
95.0
92.1
86.4
82.1
83.5
67.9
NOM Sample
3.00
3.00
3.00
73.8
30.3
25.2
27.3
18.4
20.8
3.00
3.00
3.00
3.00
3.00
3.00
Range
(37%-107%)
(25%-141%)
(39%-149%)
(37%-132%)
(39%-112%)
(11%-79%)
(39%-112%)
(15%-85%)
(24%-129%)
(0%-44%)
(0%-48%)
(0%-51%)
(0%-52%)
(0%-51%)
(0%-74%)
Qual
QC1204726593 531212007
13
24
29
31
31
32
REC%
68
87
124
99
78
41
66
39
61
86
83
78
74
75
61
111
111
111
222
111
222
111
222
111
111
111
111
111
111
111
MSD
531262Workorder:
**
**
**
**
**
**
U
U
U
U
U
U
U
U
U
RPD%
Page 20 of 51
Page 93 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(96 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Nitrophenol
3,3'-Dichlorobenzidine
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 17:25
QC
123
117
118
110
92.0
129
125
110
113
97.1
95.5
125
96.7
116
99.0
NOM Sample
3.00
3.00
3.00
3.00
3.00
5.00
3.00
3.00
3.00
0.410
3.00
3.00
0.300
3.00
3.00
Range
(0%-69%)
(0%-78%)
(0%-79%)
(0%-42%)
(0%-42%)
(0%-106%)
(0%-42%)
(0%-43%)
(0%-78%)
(0%-50%)
(0%-78%)
(0%-86%)
(0%-53%)
(0%-69%)
(0%-55%)
Qual
14
17
14
21
19
12
13
21
14
14
30
5
18
28
3
REC%
111
106
106
99
83
116
112
99
102
87
86
112
87
104
89
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 21 of 51
Page 94 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(97 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 17:25
QC
104
112
101
110
80.3
97.9
96.3
99.9
83.7
103
103
96.4
96.9
110
101
NOM Sample
3.00
3.00
3.30
3.00
3.00
0.300
0.300
3.00
4.20
0.300
0.300
0.300
0.300
0.300
0.300
Range
(0%-78%)
(0%-41%)
(0%-76%)
(0%-77%)
(0%-110%)
(0%-47%)
(0%-49%)
(0%-46%)
(0%-47%)
(0%-49%)
(0%-46%)
(0%-78%)
(0%-45%)
(0%-58%)
(0%-54%)
Qual
9
19
15
12
17
12
13
25
18
9
8
10
44
8
61
REC%
94
101
91
99
72
88
87
90
75
93
93
87
87
99
91
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U *
RPD%
Page 22 of 51
Page 95 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(98 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Benzyl alcohol
Butylbenzylphthalate
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenzo(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 17:25
QC
97.2
97.8
120
104
105
87.8
117
107
112
110
110
108
104
86.2
77.4
NOM Sample
3.00
0.300
0.300
0.300
0.590
0.300
0.300
3.00
0.300
0.300
0.300
0.300
3.00
3.00
3.00
Range
(0%-75%)
(0%-48%)
(0%-82%)
(0%-47%)
(0%-47%)
(0%-80%)
(0%-60%)
(0%-78%)
(0%-50%)
(0%-50%)
(0%-49%)
(0%-47%)
(0%-75%)
(0%-47%)
(0%-92%)
Qual
23
9
10
8
10
63
9
13
12
12
12
13
9
24
16
REC%
87
88
108
94
94
79
105
96
101
99
99
97
93
78
70
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
RPD%
Page 23 of 51
Page 96 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(99 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
N-Methyl-N-nitrosomethylamine
N-Nitrosodipropylamine
N-Nitrosopyrrolidine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Pyridine
Tributylphosphate
bis(2-Chloro-1-methylethyl)ether
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 17:25
QC
77.2
113
102
77.4
105
115
96.1
97.3
137
104
59.9
94.9
42.3
124
90.2
NOM Sample
3.00
0.300
3.50
3.00
3.00
3.00
0.300
3.00
3.00
0.300
3.00
0.300
3.00
3.00
3.00
Range
(0%-104%)
(0%-57%)
(0%-43%)
(0%-34%)
(0%-102%)
(0%-36%)
(0%-54%)
(0%-79%)
(0%-82%)
(0%-47%)
(0%-42%)
(0%-53%)
(0%-70%)
(0%-72%)
(0%-81%)
Qual
31
7
23
32
25
24
24
25
13
8
26
8
6
10
26
REC%
69
102
92
70
94
103
87
88
123
94
54
85
38
112
81
111
111
111
111
111
111
111
111
111
111
111
111
111
111
111
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 24 of 51
Page 97 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(100 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2078420Batch
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Nitroaniline
o-Cresol
o-Nitroaniline
p-Nitroaniline
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
p-Terphenyl-d14
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/06/21 17:25
QC
96.2
96.0
84.9
102
94.1
117
97.7
108
155
254
98.3
127
94.0
113
74.4
NOM Sample
3.00
3.00
0.870
3.00
3.70
3.00
3.00
3.00
3.00
73.8
30.3
25.2
27.3
18.4
20.8
Range
(0%-44%)
(0%-45%)
(0%-49%)
(0%-79%)
(0%-38%)
(0%-74%)
(0%-42%)
(0%-79%)
(0%-80%)
(37%-132%)
(39%-112%)
(11%-79%)
(39%-112%)
(15%-85%)
(24%-129%)
Qual
21
29
10
8
23
11
25
12
12
REC%
87
86
76
92
85
106
88
97
139
114
88
57
85
51
67
111
111
111
111
111
111
111
111
111
222
111
222
111
222
111
531262Workorder:
**
**
**
**
**
**
U
U
J
U
U
U
U
U
U
RPD%
Page 25 of 51
Page 98 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(101 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:51
QC
43.8
41.1
40.1
38.3
39.1
26.9
48.8
44.7
50.0
45.1
36.5
47.9
48.7
20.9
45.9
NOM Sample Range
(41%-111%)
(43%-105%)
(40%-92%)
(40%-89%)
(42%-92%)
(43%-70%)
(51%-131%)
(58%-137%)
(60%-127%)
(58%-119%)
(46%-99%)
(28%-151%)
(55%-134%)
(58%-124%)
(59%-126%)
Qual
QC1204731281
REC%
88
82
80
77
78
54
98
89
100
90
73
96
97
105
92
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
50.0
LCS
531262Workorder:
RPD%
Page 26 of 51
Page 99 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(102 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Nitrophenol
3,3'-Dichlorobenzidine
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:51
QC
46.0
39.6
54.1
42.3
45.8
49.3
46.5
41.2
48.2
47.7
6.22
44.4
44.4
45.6
40.3
NOM Sample Range
(47%-108%)
(46%-107%)
(42%-149%)
(48%-104%)
(56%-115%)
(56%-137%)
(49%-114%)
(56%-118%)
(59%-122%)
(56%-120%)
(21%-110%)
(51%-109%)
(51%-108%)
(50%-111%)
(43%-103%)
Qual
J
REC%
92
79
108
85
92
99
93
82
96
95
12
89
89
91
81
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
*
RPD%
Page 27 of 51
Page 100 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(103 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
Butylbenzylphthalate
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenzo(a,h)anthracene
Dibenzofuran
Diethylphthalate
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:51
QC
46.2
49.4
44.9
46.8
47.0
49.2
34.0
49.4
48.4
47.3
44.6
39.8
43.4
48.1
48.1
NOM Sample Range
(56%-110%)
(60%-112%)
(55%-110%)
(54%-111%)
(44%-133%)
(54%-117%)
(40%-100%)
(54%-118%)
(55%-120%)
(59%-116%)
(55%-122%)
(50%-125%)
(42%-130%)
(55%-122%)
(60%-121%)
Qual REC%
92
99
90
94
94
98
68
99
97
95
89
80
87
96
96
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 28 of 51
Page 101 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(104 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Dimethylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
N-Methyl-N-nitrosomethylamine
N-Nitrosodipropylamine
N-Nitrosopyrrolidine
Naphthalene
Nitrobenzene
Pentachlorophenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:51
QC
48.2
46.5
48.3
44.6
38.2
33.7
35.7
45.7
42.3
30.8
45.9
51.3
42.1
44.9
50.8
NOM Sample Range
(62%-123%)
(54%-121%)
(56%-111%)
(51%-118%)
(39%-103%)
(30%-95%)
(36%-90%)
(48%-128%)
(58%-113%)
(32%-84%)
(49%-118%)
(59%-119%)
(49%-103%)
(55%-110%)
(42%-132%)
Qual REC%
96
93
97
89
76
67
71
91
85
62
92
103
84
90
102
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 29 of 51
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(105 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Phenanthrene
Phenol
Pyrene
Pyridine
Tributylphosphate
bis(2-Chloro-1-methylethyl)ether
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Nitroaniline
o-Cresol
o-Nitroaniline
p-Nitroaniline
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:51
QC
46.9
14.6
53.3
26.4
49.9
41.7
45.8
41.5
42.8
47.3
32.0
51.0
35.9
50.7
56.2
NOM Sample Range
(56%-110%)
(12%-90%)
(43%-122%)
(25%-90%)
(61%-135%)
(42%-115%)
(56%-108%)
(47%-108%)
(47%-118%)
(48%-117%)
(39%-95%)
(55%-140%)
(39%-102%)
(59%-123%)
(52%-149%)
Qual REC%
94
29
107
53
100
83
92
83
86
95
64
102
72
101
112
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
RPD%
Page 30 of 51
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(106 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
p-Terphenyl-d14
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3,5-Trinitrobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
1,4-Naphthoquinone
1-Naphthylamine
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:51
01/15/21 15:22
QC
97.5
45.7
46.4
42.9
32.7
46.6
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
NOM Sample Range
(37%-132%)
(39%-112%)
(11%-79%)
(39%-112%)
(15%-85%)
(24%-129%)
Qual
U
U
U
U
U
U
U
U
U
QC1204731280
REC%
98
91
46
86
33
93
100
50.0
100
50.0
100
50.0
MB
531262Workorder:
**
**
**
**
**
**
RPD%
Page 31 of 51
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(107 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Acetylaminofluorene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Naphthylamine
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
3.00
3.00
3.00
3.00
3.00
5.00
3.00
3.00
3.00
3.00
0.410
3.00
3.00
0.300
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 32 of 51
Page 105 of 214 SDG: GEL531262 Rev1
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(108 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
2-Nitrophenol
2-Picoline
3,3'-Dichlorobenzidine
3,3'-Dimethylbenzidine
3-Methylcholanthrene
4-Aminobiphenyl
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
4-Nitroquinoline-1-oxide
5-Nitro-o-toluidine
7,12-Dimethylbenz(a)anthracene
Acenaphthene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
3.00
3.00
3.00
3.30
3.00
3.00
3.00
3.00
3.30
3.00
3.00
3.80
3.00
3.00
0.300
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 33 of 51
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(109 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Acenaphthylene
Acetophenone
Aniline
Anthracene
Aramite
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
Butylbenzylphthalate
Carbazole
Chlorobenzilate
Chrysene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
0.300
3.00
4.20
0.300
3.70
0.300
0.300
0.300
0.300
0.300
3.00
0.300
0.300
3.00
0.300
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 34 of 51
Page 107 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(110 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Di-n-butylphthalate
Di-n-octylphthalate
Diallate
Dibenzo(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethoate
Dimethylphthalate
Dinoseb
Disulfoton
Ethyl Methanesulfonate
Famphur
Fluoranthene
Fluorene
Hexachlorobenzene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
0.300
0.300
3.00
0.300
3.00
0.300
3.00
0.300
3.00
3.00
3.00
5.00
0.300
0.300
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 35 of 51
Page 108 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(111 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Hexachlorophene
Hexachloropropene
Indeno(1,2,3-cd)pyrene
Isodrin
Isophorone
Isosafrole
Kepone
Methapyrilene
Methyl methanesulfonate
Methyl parathion
N-Methyl-N-nitrosomethylamine
N-Nitrosodi-n-butylamine
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
3.00
3.00
3.00
167
3.00
0.300
3.00
3.50
3.00
3.00
3.00
3.00
3.00
3.00
3.00
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 36 of 51
Page 109 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(112 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
N-Nitrosodiethylamine
N-Nitrosodipropylamine
N-Nitrosomethylethylamine
N-Nitrosomorpholine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
Naphthalene
Nitrobenzene
Parathion
Pentachlorobenzene
Pentachloroethane
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
3.00
3.00
3.00
3.00
3.00
3.00
0.300
3.00
3.00
3.00
3.00
3.40
3.00
3.00
0.300
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 37 of 51
Page 110 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(113 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Phenol
Phorate
Pronamide
Pyrene
Pyridine
Safrole
Sulfotepp
Thionazin
Tributylphosphate
Triethylphosphorothioate
a,a-Dimethylphenethylamine
bis(2-Chloro-1-methylethyl)ether
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
3.00
3.00
3.00
0.300
3.00
3.00
3.00
3.00
3.00
3.00
5.40
3.00
3.00
3.00
0.300
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 38 of 51
Page 111 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(114 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Dinitrobenzene
m-Nitroaniline
o-Cresol
o-Nitroaniline
o-Toluidine
p-(Dimethylamino)azobenzene
p-Nitroaniline
p-Phenylenediamine
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1 01/15/21 15:22
QC
3.00
3.70
3.00
3.00
3.00
3.00
3.00
3.00
3.00
100
68.9
32.4
34.9
31.2
23.3
NOM Sample Range
(37%-132%)
(39%-112%)
(11%-79%)
(39%-112%)
(15%-85%)
Qual
U
U
U
U
U
U
U
U
U
U
REC%
69
65
35
62
23
100
50.0
100
50.0
100
531262Workorder:
**
**
**
**
**
RPD%
Page 39 of 51
Page 112 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(115 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
p-Terphenyl-d14
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
NM1
LXA1
01/15/21 15:22
01/18/21 20:00
QC
33.8
78.6
68.8
66.1
61.7
63.0
57.1
96.3
93.9
97.7
86.0
71.3
102
98.5
37.2
NOM Sample
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
5.00
3.00
3.00
Range
(24%-129%)
(35%-117%)
(29%-111%)
(33%-101%)
(31%-97%)
(37%-90%)
(29%-96%)
(43%-134%)
(49%-125%)
(47%-130%)
(49%-119%)
(40%-111%)
(25%-154%)
(49%-136%)
(48%-129%)
Qual
QC1204731282 531763005
REC%
68
79
69
66
62
63
57
96
94
98
86
71
102
99
93
50.0
100
100
100
100
100
100
100
100
100
100
100
100
100
40.0
MS
531262Workorder:
**
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 40 of 51
Page 113 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(116 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Nitrophenol
3,3'-Dichlorobenzidine
4-Bromophenylphenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:00
QC
92.4
80.1
76.1
107
75.5
89.0
6.00
90.4
89.7
84.5
89.0
63.6
81.4
79.0
77.8
NOM Sample
3.00
0.410
3.00
3.00
0.300
3.00
3.00
3.00
3.00
3.30
3.00
3.00
0.300
0.300
3.00
Range
(49%-126%)
(36%-120%)
(42%-113%)
(30%-145%)
(37%-109%)
(42%-120%)
(38%-130%)
(43%-121%)
(42%-123%)
(41%-126%)
(47%-122%)
(20%-98%)
(43%-118%)
(39%-120%)
(39%-118%)
Qual
TU
REC%
92
80
76
107
76
89
0
90
90
85
89
64
81
79
78
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
531262Workorder:
*
U
U
U
U
U
U
TU
U
U
U
U
U
U
U
U
RPD%
Page 41 of 51
Page 114 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(117 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Aniline
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
Butylbenzylphthalate
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenzo(a,h)anthracene
Dibenzofuran
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:00
QC
75.2
86.4
88.4
0.600
0.600
88.3
42.6
78.3
97.0
88.0
89.1
94.6
49.9
92.9
86.2
NOM Sample
4.20
0.300
0.300
0.300
0.300
0.300
0.300
3.00
0.300
0.300
0.300
0.300
0.300
0.300
3.00
Range
(35%-114%)
(46%-117%)
(48%-118%)
(42%-112%)
(43%-118%)
(32%-121%)
(46%-118%)
(35%-115%)
(43%-124%)
(47%-127%)
(47%-121%)
(45%-124%)
(38%-128%)
(33%-131%)
(46%-117%)
Qual
TU
TU
T
REC%
75
86
88
0
0
88
43
78
97
88
89
95
50
93
86
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
531262Workorder:
*
*
*
U
U
U
TU
TU
U
TU
U
U
U
U
U
U
U
U
RPD%
Page 42 of 51
Page 115 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(118 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
N-Methyl-N-nitrosomethylamine
N-Nitrosodipropylamine
N-Nitrosopyrrolidine
Naphthalene
Nitrobenzene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:00
QC
92.8
90.9
87.4
87.4
90.4
62.5
52.0
57.8
86.2
78.0
64.1
80.1
91.0
73.2
73.9
NOM Sample
0.300
0.300
0.300
0.300
3.00
3.00
3.00
3.00
0.300
3.50
3.00
3.00
3.00
0.300
3.00
Range
(49%-128%)
(50%-130%)
(44%-121%)
(44%-119%)
(46%-116%)
(24%-102%)
(18%-89%)
(27%-95%)
(35%-130%)
(42%-116%)
(27%-101%)
(36%-121%)
(52%-127%)
(34%-104%)
(44%-119%)
Qual REC%
93
91
87
87
90
62
52
58
86
78
64
80
91
73
74
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Pyridine
Tributylphosphate
bis(2-Chloro-1-methylethyl)ether
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Nitroaniline
o-Cresol
o-Nitroaniline
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:00
QC
103
91.2
50.3
85.7
55.8
6.00
70.9
82.9
72.7
85.5
93.9
78.3
100
79.6
93.0
NOM Sample
3.00
0.300
3.00
0.300
3.00
3.00
3.00
3.00
3.00
0.300
3.00
3.70
3.00
3.00
3.00
Range
(36%-139%)
(48%-112%)
(23%-71%)
(39%-120%)
(22%-103%)
(48%-149%)
(32%-122%)
(41%-118%)
(39%-112%)
(37%-120%)
(41%-118%)
(35%-112%)
(39%-149%)
(37%-107%)
(25%-141%)
Qual
TU
REC%
103
91
50
86
56
0
71
83
73
85
94
78
100
80
93
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
531262Workorder:
*
U
U
U
U
U
TU
U
U
U
U
U
U
U
U
U
RPD%
Page 44 of 51
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
p-Nitroaniline
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
p-Terphenyl-d14
1,2,4,5-Tetrachlorobenzene
1,2,4-Trichlorobenzene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,4-Dioxane
2,3,4,6-Tetrachlorophenol
2,4,5-Trichlorophenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:00
01/18/21 20:27
QC
123
188
82.4
105
72.0
95.3
68.1
90.9
79.3
76.4
71.8
72.9
69.7
110
107
NOM Sample
3.00
57.7
41.9
30.9
38.4
26.8
15.9
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
Range
(39%-149%)
(37%-132%)
(39%-112%)
(11%-79%)
(39%-112%)
(15%-85%)
(24%-129%)
(0%-44%)
(0%-48%)
(0%-51%)
(0%-52%)
(0%-51%)
(0%-74%)
(0%-69%)
(0%-78%)
Qual
QC1204731283 531763005
14
14
14
15
15
20
13
13
REC%
123
94
82
53
72
48
68
91
79
76
72
73
70
110
107
100
200
100
200
100
200
100
100
100
100
100
100
100
100
100
MSD
531262Workorder:
**
**
**
**
**
**
U
U
U
U
U
U
U
U
U
RPD%
Page 45 of 51
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dichlorophenol
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Nitrophenol
3,3'-Dichlorobenzidine
4-Bromophenylphenylether
4-Chloro-3-methylphenol
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:27
QC
110
98.3
81.9
117
113
42.6
105
92.9
87.7
120
86.9
105
6.00
103
101
NOM Sample
3.00
3.00
3.00
5.00
3.00
3.00
3.00
0.410
3.00
3.00
0.300
3.00
3.00
3.00
3.00
Range
(0%-79%)
(0%-42%)
(0%-42%)
(0%-106%)
(0%-42%)
(0%-43%)
(0%-78%)
(0%-50%)
(0%-78%)
(0%-86%)
(0%-53%)
(0%-69%)
(0%-55%)
(0%-78%)
(0%-41%)
Qual
TU
11
13
14
14
13
14
13
15
14
12
14
16
N/A
13
12
REC%
110
98
82
117
113
107
105
93
88
120
87
105
0
103
101
100
100
100
100
100
40.0
100
100
100
100
100
100
100
100
100
531262Workorder:
*
U
U
U
U
U
U
U
U
U
U
U
U
TU
U
U
RPD%
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
4-Chloroaniline
4-Chlorophenylphenylether
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Aniline
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Benzyl alcohol
Butylbenzylphthalate
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:27
QC
98.8
101
72.5
93.2
90.3
90.4
89.0
97.9
99.1
91.8
95.4
102
100
91.3
120
NOM Sample
3.30
3.00
3.00
0.300
0.300
3.00
4.20
0.300
0.300
0.300
0.300
0.300
0.300
3.00
0.300
Range
(0%-76%)
(0%-77%)
(0%-110%)
(0%-47%)
(0%-49%)
(0%-46%)
(0%-47%)
(0%-49%)
(0%-46%)
(0%-78%)
(0%-45%)
(0%-58%)
(0%-54%)
(0%-75%)
(0%-48%)
Qual
16
13
13
13
13
15
17
12
11
200
200
14
81
15
21
REC%
99
101
72
93
90
90
89
98
99
92
95
102
100
91
120
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
531262Workorder:
U
U
U
U
U
U
U
U
U
TU
TU
U
TU
U
U
*
*
*
RPD%
Page 47 of 51
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenzo(a,h)anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:27
QC
99.0
99.9
107
108
107
98.3
105
104
95.2
99.6
102
72.5
70.9
66.9
104
NOM Sample
0.300
0.300
0.300
0.300
0.300
3.00
0.300
0.300
0.300
0.300
3.00
3.00
3.00
3.00
0.300
Range
(0%-82%)
(0%-47%)
(0%-47%)
(0%-80%)
(0%-60%)
(0%-78%)
(0%-50%)
(0%-50%)
(0%-49%)
(0%-47%)
(0%-75%)
(0%-47%)
(0%-92%)
(0%-104%)
(0%-57%)
Qual
12
11
13
74
14
13
13
13
9
13
12
15
31
15
18
REC%
99
100
107
108
107
98
105
104
95
100
102
72
71
67
104
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
531262Workorder:
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 48 of 51
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
Isophorone
N-Methyl-N-nitrosomethylamine
N-Nitrosodipropylamine
N-Nitrosopyrrolidine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Pyridine
Tributylphosphate
bis(2-Chloro-1-methylethyl)ether
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:27
QC
91.9
77.3
94.3
107
86.0
87.7
116
102
57.5
106
69.7
6.00
83.5
96.6
85.4
NOM Sample
3.50
3.00
3.00
3.00
0.300
3.00
3.00
0.300
3.00
0.300
3.00
3.00
3.00
3.00
3.00
Range
(0%-43%)
(0%-34%)
(0%-102%)
(0%-36%)
(0%-54%)
(0%-79%)
(0%-82%)
(0%-47%)
(0%-42%)
(0%-53%)
(0%-70%)
(0%-72%)
(0%-81%)
(0%-44%)
(0%-45%)
Qual
TU
16
19
16
16
16
17
13
11
13
21
22
N/A
16
15
16
REC%
92
77
94
107
86
88
116
102
57
106
70
0
83
97
85
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
531262Workorder:
*
U
U
U
U
U
U
U
U
U
U
U
TU
U
U
U
RPD%
Page 49 of 51
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatile-GC/MS2081190Batch
bis(2-Ethylhexyl)phthalate
diphenylamine+N-nitrosodiphenylamine
m,p-Cresols
m-Nitroaniline
o-Cresol
o-Nitroaniline
p-Nitroaniline
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
p-Terphenyl-d14
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LXA1 01/18/21 20:27
QC
113
107
88.8
115
90.3
105
140
212
94.1
124
84.4
111
87.6
NOM Sample
0.300
3.00
3.70
3.00
3.00
3.00
3.00
57.7
41.9
30.9
38.4
26.8
15.9
Range
(0%-49%)
(0%-79%)
(0%-38%)
(0%-74%)
(0%-42%)
(0%-79%)
(0%-80%)
(37%-132%)
(39%-112%)
(11%-79%)
(39%-112%)
(15%-85%)
(24%-129%)
Qual
The Qualifiers in this report are defined as follows:
27
13
13
14
13
12
13
REC%
113
107
89
115
90
105
140
106
94
62
84
55
88
100
100
100
100
100
100
100
200
100
200
100
200
100
531262Workorder:
A
B
C
The TIC is a suspected aldol-condensation product
The analyte was detected in both the associated QC blank and in the sample.
Analyte has been confirmed by GC/MS analysis
**
**
**
**
**
**
U
U
U
U
U
U
U
RPD%
Notes:
Page 50 of 51
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Parmname
Page 51 of 51
Units Anlst Date TimeQCNOM Sample RangeQual REC%
531262Workorder:
D
E
E
J
N
P
T
U
X
Y
Z
o
Results are reported from a diluted aliquot of sample.
Concentration exceeds the calibration range of the instrument
Reported value is estimated due to interferences. See comment in narrative.
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Value is estimatedSpike Sample recovery is outside control limits.
Aroclor target analyte with greater than 25% difference between column analyses.
Spike and/or spike duplicate sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Analyte failed to recover within LCS limits (0rganics only)
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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GEL Laboratories LLC
Surrogate Recovery Report
Semi-Volatile
Report Date: January 28 2021
Page 1 of 1
SDG Number: GEL531262
Matrix Type: LIQUID
Surrogate Acceptance Limits
36 26 64 70 81 56
41 33 78 88 108 74
41 39 66 78 99 61
57 51 85 88 114 67
28 22 59 64 75 37
34 26 69 76 84 35
35 23 62 65 69 68
46 33 86 91 98 93
46 30 87 93 96 68
53 48 72 82 94 68
62 55 84 94 106 88
1204726590
1204726591
1204726592
1204726593
531262006
531262009
1204731280
1204731281
531262005
1204731282
1204731283
2FP %REC
PHL %REC
NBZ %REC
FBP %REC
TBP %REC
TPH %REC
Sample ID Client ID
MB for batch 2078419
LCS for batch 2078419
400RIS414WA110MS
400RIS414WA110MSD
B3YLV9
B3YLV5
MB for batch 2081189
LCS for batch 2081189
B3YLK7
B3YMF0MS
B3YMF0MSD
2-Fluorophenol
Phenol-d5
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d14
(11%-79%)
(15%-85%)
(39%-112%)
(39%-112%)
(37%-132%)
(24%-129%)
2FP
PHL
NBZ
FBP
TBP
TPH
=
=
=
=
=
=
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values D Sample Diluted
Parmname
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Pesticide Analysis
Page 126 of 214 SDG: GEL531262 Rev1
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(129 of 217)
Case Narrative
Page 127 of 214 SDG: GEL531262 Rev1
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GC Semivolatile Pesticide Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
Product: Organochlorine Pesticides and Chlorinated Hydrocarbons Analytical Method: SW846 3535A/8081B Analytical Procedure: GL-OA-E-041 REV# 20 Analytical Batch: 2078412 Preparation Method: SW846 3535A Preparation Procedure: GL-OA-E-070 REV# 11 Preparation Batch: 2078411
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262009 B3YLV5 531262010 B3YW14 1204726579 Method Blank (MB) 1204726580 Laboratory Control Sample (LCS) 1204726581 531262009(B3YLV5) Matrix Spike (MS) 1204726582 531262009(B3YLV5) Matrix Spike Duplicate (MSD) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Calibration Information Continuing Calibration Verification (CCV) Requirements Calibration verification standards (ICV or CCV) requirements have not been met for samples 531262009(B3YLV5) and 531262010 (B3YW14) in this batch in this SDG. One or more target analytes failed acceptancecriteria with a positive bias in the standards bracketing the samples in this SDG. These target analytes were notdetected above the PQL in the associated environmental samples; therefore, the non-compliance had no adverseeffect on the data. Quality Control (QC) Information Matrix Spike (MS/MSD) Recovery Statement The matrix QC samples (See Below) did not meet spike recovery acceptance for Endrin due to instrumentpositive bias. This non-compliance had no adverse effects on the data as Endrin was not detected in theassociated environmental samples.
Sample Analyte Value
1204726581 (B3YLV5MS) Endrin 146* (35%-144%)
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1204726582 (B3YLV5MSD)Endrin 152* (35%-144%)
Miscellaneous Information Additional Comments
The Toxaphene and/or Chlordane standards were analyzed for this SDG as a retention time marker and patternreference. A five-point calibration curve and calibration verification standard forms were not submitted in thedata package since Toxaphene and/or Chlordane were not detected in the client samples. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC002 Central Plateau Cleanup Company (74393)
Client SDG: GEL531262 GEL Work Order: 531262
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:J The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal tothe IDL/MDL (as appropriate).Value is estimatedT Spike and/or spike duplicate sample recovery is outside control limits. U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
for
DL Indicates that sample is diluted. RA Indicates that sample is re-analyzed without re-extraction. RE Indicates that sample is re-extracted.
Qualifier Definition Report
Signature: Name:
Date: Title:25 JAN 2021
Jimin Cao
Data Validator
Review/Validation
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Sample Data Summary
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GEL Laboratories LLC
Pesticide Certificate of Analysis
Sample Summary
January 8, 2021Report Date:
Page 1 of 1
SDG Number: GEL531262
Lab Sample ID: 531262009Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 09:47
319-84-6
58-89-9
76-44-8
309-00-2
319-85-7
319-86-8
1024-57-3
5103-74-2
5103-71-9
72-55-9
959-98-8
60-57-1
72-20-8
33213-65-9
72-54-8
50-29-3
7421-93-4
1031-07-8
53494-70-5
72-43-5
8001-35-2
alpha-BHC
gamma-BHC (Lindane)
Heptachlor
Aldrin
beta-BHC
delta-BHC
Heptachlor epoxide
trans-Chlordane
cis-Chlordane
4,4'-DDE
Endosulfan I
Dieldrin
Endrin
Endosulfan II
4,4'-DDD
4,4'-DDT
Endrin aldehyde
Endosulfan sulfate
Endrin ketone
Methoxychlor
Toxaphene
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.0100
0.00665
0.0100
0.0100
0.0100
0.0100
0.0100
0.00665
0.0100
0.0100
0.0500
0.150
U
U
U
U
U
U
U
U
U
U
U
U
TU
U
U
U
U
U
U
U
U
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.00665
0.0100
0.00665
0.0100
0.0100
0.0100
0.0100
0.0100
0.00665
0.0100
0.0100
0.0500
0.150
0.0200
0.0200
0.0200
0.0200
0.0200
0.0200
0.0200
0.0200
0.0200
0.0400
0.0200
0.0400
0.0400
0.0400
0.0400
0.0400
0.0400
0.0400
0.0400
0.200
0.500
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.500
0.050
0.100
0.050
0.050
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.500
2.00
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ RDL
Method: SW846 3535A/8081B GL-OA-E-041
Batch ID: 2078412 Inst: ECDAA.I Dilution: 1SOP Ref:
Run Date: 01/08/2021 14:12 Analyst: LOF 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YLV5Client ID:
Prep Date: Aliquot: Final Volume:01/08/2021 05:35 1000 mL 5 mL
Column
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Column:010821\eAa0816.D
010821\eAa0816.D
Data File: 1 RTX-CLP
2 RTX-CLP
Page 132 of 214 SDG: GEL531262 Rev1
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GEL Laboratories LLC
Pesticide Certificate of Analysis
Sample Summary
January 8, 2021Report Date:
Page 1 of 1
SDG Number: GEL531262
Lab Sample ID: 531262010Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 08:04
319-84-6
58-89-9
76-44-8
309-00-2
319-85-7
319-86-8
1024-57-3
5103-74-2
5103-71-9
72-55-9
959-98-8
60-57-1
72-20-8
33213-65-9
72-54-8
50-29-3
7421-93-4
1031-07-8
53494-70-5
72-43-5
8001-35-2
alpha-BHC
gamma-BHC (Lindane)
Heptachlor
Aldrin
beta-BHC
delta-BHC
Heptachlor epoxide
trans-Chlordane
cis-Chlordane
4,4'-DDE
Endosulfan I
Dieldrin
Endrin
Endosulfan II
4,4'-DDD
4,4'-DDT
Endrin aldehyde
Endosulfan sulfate
Endrin ketone
Methoxychlor
Toxaphene
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00952
0.00633
0.00952
0.00952
0.00952
0.00952
0.00952
0.00633
0.00952
0.00952
0.0476
0.143
U
U
U
U
U
U
U
U
U
U
U
U
TU
U
U
U
U
U
U
U
U
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00633
0.00952
0.00633
0.00952
0.00952
0.00952
0.00952
0.00952
0.00633
0.00952
0.00952
0.0476
0.143
0.0190
0.0190
0.0190
0.0190
0.0190
0.0190
0.0190
0.0190
0.0190
0.0381
0.0190
0.0381
0.0381
0.0381
0.0381
0.0381
0.0381
0.0381
0.0381
0.190
0.476
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.500
0.050
0.100
0.050
0.050
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.500
2.00
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ RDL
Method: SW846 3535A/8081B GL-OA-E-041
Batch ID: 2078412 Inst: ECDAA.I Dilution: 1SOP Ref:
Run Date: 01/08/2021 15:02 Analyst: LOF 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YW14Client ID:
Prep Date: Aliquot: Final Volume:01/08/2021 05:35 1050 mL 5 mL
Column
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Column:010821\eAa0819.D
010821\eAa0819.D
Data File: 1 RTX-CLP
2 RTX-CLP
Page 133 of 214 SDG: GEL531262 Rev1
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Quality ControlSummary
Page 134 of 214 SDG: GEL531262 Rev1
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(137 of 217)
GEL Laboratories LLC
Surrogate Recovery Report
Pesticide
Report Date: January 8 2021
Page 1 of 1
SDG Number: GEL531262
Matrix Type: LIQUID
Surrogate Acceptance Limits
68 67 87 93
64 64 88 91
72 71 89 91
77 76 88 90
79 78 92 95
77 75 84 88
1204726579
1204726580
531262009
1204726581
1204726582
531262010
4CMX 1%REC #
4CMX 2%REC #
DCB 1%REC #
DCB 2%REC #
Sample ID Client ID
MB for batch 2078411
LCS for batch 2078411
B3YLV5
B3YLV5MS
B3YLV5MSD
B3YW14
4cmx
Decachlorobiphenyl
(28%-114%)
(27%-124%)
4CMX
DCB=
=
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values D Sample Diluted
Parmname
Page 135 of 214 SDG: GEL531262 Rev1
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-Pesticide2078412Batch
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
Heptachlor
Heptachlor epoxide
Parmname
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyMSIN R3-50
Richland, Washington
January 25, 2021Report Date:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/08/21 12:50
QC
1.06
0.982
1.06
0.313
1.21
0.451
1.16
1.00
1.54
1.15
1.17
0.404
0.448
NOM Sample Range
(42%-125%)
(42%-116%)
(42%-131%)
(21%-116%)
(48%-126%)
(45%-125%)
(42%-126%)
(49%-133%)
(39%-138%)
(31%-126%)
(54%-131%)
(43%-123%)
(47%-128%)
Qual
QC1204726580
REC%
84
79
85
63
97
90
93
80
124
92
94
81
90
1.25
1.25
1.25
0.500
1.25
0.500
1.25
1.25
1.25
1.25
1.25
0.500
0.500
LCS
531262Workorder:
PO Box 1600
RPD%
Page 1 of 7
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-Pesticide2078412Batch
Methoxychlor
alpha-BHC
beta-BHC
cis-Chlordane
delta-BHC
gamma-BHC (Lindane)
trans-Chlordane
4cmx
Decachlorobiphenyl
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
Dieldrin
Endosulfan I
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/08/21 12:50
01/08/21 12:33
QC
4.58
0.439
0.467
0.478
0.481
0.450
0.467
0.635
0.882
0.0400
0.0400
0.0400
0.0200
0.0400
0.0200
NOM Sample Range
(51%-135%)
(47%-130%)
(43%-120%)
(48%-132%)
(48%-135%)
(46%-130%)
(42%-121%)
(28%-114%)
(27%-124%)
Qual
J
U
U
U
U
U
U
QC1204726579
REC%
92
88
93
96
96
90
93
64
88
5.00
0.500
0.500
0.500
0.500
0.500
0.500
1.00
1.00
MB
531262Workorder:
**
**
RPD%
Page 2 of 7
Page 137 of 214 SDG: GEL531262 Rev1
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-Pesticide2078412Batch
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
alpha-BHC
beta-BHC
cis-Chlordane
delta-BHC
gamma-BHC (Lindane)
trans-Chlordane
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/08/21 12:33
QC
0.0400
0.0400
0.0400
0.0400
0.0400
0.0200
0.0200
0.200
0.500
0.0200
0.0200
0.0200
0.0200
0.0200
0.0200
NOM Sample RangeQual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
REC%
531262Workorder:
RPD%
Page 3 of 7
Page 138 of 214 SDG: GEL531262 Rev1
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(141 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-Pesticide2078412Batch
4cmx
Decachlorobiphenyl
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
Heptachlor
Heptachlor epoxide
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/08/21 12:33
01/08/21 14:29
QC
0.671
0.868
1.22
1.18
1.24
0.300
1.31
0.504
1.26
1.03
1.83
1.18
1.19
0.468
0.515
NOM Sample
0.0400
0.0400
0.0400
0.0200
0.0400
0.0200
0.0400
0.0400
0.0400
0.0400
0.0400
0.0200
0.0200
Range
(28%-114%)
(27%-124%)
(30%-130%)
(28%-122%)
(30%-135%)
(15%-120%)
(32%-132%)
(30%-131%)
(31%-129%)
(35%-141%)
(35%-144%)
(20%-128%)
(37%-135%)
(33%-130%)
(36%-133%)
Qual
T
QC1204726581 531262009
REC%
67
87
98
94
99
60
105
101
101
82
146
94
96
94
103
1.00
1.00
1.25
1.25
1.25
0.500
1.25
0.500
1.25
1.25
1.25
1.25
1.25
0.500
0.500
MS
531262Workorder:
*
**
**
U
U
U
U
U
U
U
U
TU
U
U
U
U
RPD%
Page 4 of 7
Page 139 of 214 SDG: GEL531262 Rev1
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(142 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-Pesticide2078412Batch
Methoxychlor
alpha-BHC
beta-BHC
cis-Chlordane
delta-BHC
gamma-BHC (Lindane)
trans-Chlordane
4cmx
Decachlorobiphenyl
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
Dieldrin
Endosulfan I
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/08/21 14:29
01/08/21 14:45
QC
4.69
0.478
0.508
0.528
0.532
0.490
0.504
0.764
0.879
1.23
1.22
1.29
0.266
1.34
0.511
NOM Sample
0.200
0.0200
0.0200
0.0200
0.0200
0.0200
0.0200
0.712
0.889
0.0400
0.0400
0.0400
0.0200
0.0400
0.0200
Range
(40%-143%)
(33%-130%)
(30%-128%)
(31%-138%)
(35%-136%)
(37%-132%)
(29%-132%)
(28%-114%)
(27%-124%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
Qual
QC1204726582 531262009
0
3
4
12
2
1
REC%
94
96
102
106
106
98
101
76
88
98
97
103
53
107
102
5.00
0.500
0.500
0.500
0.500
0.500
0.500
1.00
1.00
1.25
1.25
1.25
0.500
1.25
0.500
MSD
531262Workorder:
**
**
U
U
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 5 of 7
Page 140 of 214 SDG: GEL531262 Rev1
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(143 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-Pesticide2078412Batch
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Endrin ketone
Heptachlor
Heptachlor epoxide
Methoxychlor
alpha-BHC
beta-BHC
cis-Chlordane
delta-BHC
gamma-BHC (Lindane)
trans-Chlordane
4cmx
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/08/21 14:45
QC
1.29
1.04
1.89
1.27
1.21
0.481
0.530
4.75
0.495
0.503
0.538
0.545
0.504
0.512
0.779
NOM Sample
0.0400
0.0400
0.0400
0.0400
0.0400
0.0200
0.0200
0.200
0.0200
0.0200
0.0200
0.0200
0.0200
0.0200
0.712
Range
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(28%-114%)
Qual
T
2
1
3
7
2
3
3
1
3
1
2
2
3
2
REC%
103
83
152
101
97
96
106
95
99
101
108
109
101
102
78
1.25
1.25
1.25
1.25
1.25
0.500
0.500
5.00
0.500
0.500
0.500
0.500
0.500
0.500
1.00
531262Workorder:
*
**
U
U
TU
U
U
U
U
U
U
U
U
U
U
U
RPD%
Page 6 of 7
Page 141 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(144 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-Pesticide2078412Batch
Decachlorobiphenyl
Parmname
Page 7 of 7
Units
ug/L
Anlst Date Time
LOF 01/08/21 14:45
QC
0.917
NOM Sample
0.889
Range
(27%-124%)
Qual
The Qualifiers in this report are defined as follows:
REC%
921.00
531262Workorder:
A
B
C
D
E
E
J
N
P
T
U
X
Y
Z
o
The TIC is a suspected aldol-condensation product
The analyte was detected in both the associated QC blank and in the sample.
Analyte has been confirmed by GC/MS analysis
Results are reported from a diluted aliquot of sample.
Concentration exceeds the calibration range of the instrument
Reported value is estimated due to interferences. See comment in narrative.
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Value is estimatedSpike Sample recovery is outside control limits.
Aroclor target analyte with greater than 25% difference between column analyses.
Spike and/or spike duplicate sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Analyte failed to recover within LCS limits (0rganics only)
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
**
RPD%
Notes:
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PCB Analysis
Page 143 of 214 SDG: GEL531262 Rev1
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(146 of 217)
Case Narrative
Page 144 of 214 SDG: GEL531262 Rev1
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GC Semivolatile PCB Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
Product: Analysis of The Analysis of Polychlorinated Biphenyls by GC/ECD by ECD Analytical Method: 8082_PCB_GC Analytical Procedure: GL-OA-E-040 REV# 25 Analytical Batch: 2082298 Preparation Method: SW846 3535A Preparation Procedure: GL-OA-E-037 REV# 7 Preparation Batch: 2082295
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262010 B3YW14 1204733460 Method Blank (MB) 1204733461 Laboratory Control Sample (LCS) 1204733464 531292004(B3YW15) Matrix Spike (MS) 1204733465 531292004(B3YW15) Matrix Spike Duplicate (MSD) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Technical Information Preparation/Analytical Method Verification All samples and QC in this batch were cleaned using alumina in order to remove oil and other high molecularweight interferences. All samples and QC in this batch were cleaned with activated copper in order to removesulfur. All reported analyte detections in client and quality control samples were within the established retentiontime windows. Reported analyte concentrations were confirmed on dissimilar columns. Miscellaneous Information Manual integrations Samples 1204733460 (MB), 1204733461 (LCS), 1204733464 (B3YW15MS), 1204733465 (B3YW15MSD) and531262010 (B3YW14) required manual integration to correctly position the baseline as set in the calibrationstandard injections and to properly identify one or more peaks. Additional Comments The column 1 has been chosen as the primary column. The data are reported from the column 1 for all samples inthis batch. Certification Statement
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Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC002 Central Plateau Cleanup Company (74393)
Client SDG: GEL531262 GEL Work Order: 531262
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
for
DL Indicates that sample is diluted. RA Indicates that sample is re-analyzed without re-extraction. RE Indicates that sample is re-extracted.
Qualifier Definition Report
Signature: Name:
Date: Title:25 JAN 2021
Jimin Cao
Data Validator
Review/Validation
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Sample Data Summary
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GEL Laboratories LLC
PCB Certificate of Analysis
Sample Summary
January 20, 2021Report Date:
Page 1 of 1
SDG Number: GEL531262
Lab Sample ID: 531262010Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 08:04
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
0.0316
0.0316
0.0316
0.0316
0.0316
0.0316
0.0316
U
U
U
U
U
U
U
0.0316
0.0316
0.0316
0.0316
0.0316
0.0316
0.0316
0.0950
0.0950
0.0950
0.0950
0.0950
0.0950
0.0950
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: 8082_PCB_GC GL-OA-E-040
Batch ID: 2082298 Inst: ECD8A.I Dilution: 1SOP Ref:
Run Date: 01/19/2021 10:27 Analyst: JXM 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YW14Client ID:
Prep Date: Aliquot: Final Volume:01/18/2021 06:15 1052.22 mL 1 mL
Column
1
1
1
1
1
1
1
Column:011921.b\e8a1923.D
011921.b\e8a1923.D
Data File: 1 Description: RTX-CLP
2 PEST2
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Quality ControlSummary
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GEL Laboratories LLC
Surrogate Recovery Report
PCB
Report Date: January 20 2021
Page 1 of 1
SDG Number: GEL531262
Matrix Type: LIQUID
Surrogate Acceptance Limits
53 59 85 104
53 58 87 106
59 63 83 99
55 58 85 102
48 50 64 87
1204733460
1204733461
531262010
1204733464
1204733465
4CMX 1%REC #
4CMX 2%REC #
DCB 1%REC #
DCB 2%REC #
Sample ID Client ID
MB for batch 2082295
LCS for batch 2082295
B3YW14
B3YW15MS
B3YW15MSD
4cmx
Decachlorobiphenyl
(30%-113%)
(34%-130%)
4CMX
DCB=
=
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values D Sample Diluted
Parmname
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-PCB2082298Batch
Aroclor-1016
Aroclor-1260
4cmx
Decachlorobiphenyl
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
4cmx
Decachlorobiphenyl
Parmname
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyMSIN R3-50
Richland, Washington
January 25, 2021Report Date:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
JXM 01/19/21 08:24
01/19/21 08:00
QC
0.634
0.682
0.106
0.174
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.106
0.171
NOM Sample Range
(38%-100%)
(46%-110%)
(30%-113%)
(34%-130%)
(30%-113%)
(34%-130%)
Qual
U
U
U
U
U
U
U
QC1204733461
QC1204733460
REC%
63
68
53
87
53
85
1.00
1.00
0.200
0.200
0.200
0.200
LCS
MB
531262Workorder:
PO Box 1600
**
**
**
**
RPD%
Page 1 of 3
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-PCB2082298Batch
Aroclor-1016
Aroclor-1260
4cmx
Decachlorobiphenyl
Aroclor-1016
Aroclor-1260
4cmx
Decachlorobiphenyl
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
JXM 01/19/21 11:10
01/19/21 11:25
QC
0.598
0.686
0.109
0.170
0.563
0.641
0.0958
0.128
NOM Sample
0.0333
0.0333
0.101
0.133
0.0333
0.0333
0.101
0.133
Range
(28%-107%)
(32%-122%)
(30%-113%)
(34%-130%)
(0%-27%)
(0%-29%)
(30%-113%)
(34%-130%)
Qual
QC1204733464 531292004
QC1204733465 531292004
The Qualifiers in this report are defined as follows:
6
7
REC%
60
69
55
85
56
64
48
64
1.00
1.00
0.200
0.200
1.00
1.00
0.200
0.200
MS
MSD
531262Workorder:
A
B
C
D
E
E
J
N
P
T
U
X
The TIC is a suspected aldol-condensation product
The analyte was detected in both the associated QC blank and in the sample.
Analyte has been confirmed by GC/MS analysis
Results are reported from a diluted aliquot of sample.
Concentration exceeds the calibration range of the instrument
Reported value is estimated due to interferences. See comment in narrative.
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Value is estimatedSpike Sample recovery is outside control limits.
Aroclor target analyte with greater than 25% difference between column analyses.
Spike and/or spike duplicate sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
**
**
**
**
U
U
U
U
RPD%
Notes:
Page 2 of 3
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOM Sample RangeQual REC%
531262Workorder:
Y
Z
o
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Analyte failed to recover within LCS limits (0rganics only)
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Herbicide Analysis
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Case Narrative
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GC Semivolatile Herbicide Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
Product: Analysis of Chlorophenoxy Acid Herbicides by ECD Analytical Method: SW846 3535A/8151A Analytical Procedure: GL-OA-E-011 REV# 25 Analytical Batch: 2079808 Preparation Method: SW846 3535A Preparation Procedure: GL-OA-E-079 REV# 2 Preparation Batch: 2079807
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262010 B3YW14 1204728730 Method Blank (MB) 1204728731 Laboratory Control Sample (LCS) 1204728732 531262010(B3YW14) Matrix Spike (MS) 1204728733 531262010(B3YW14) Matrix Spike Duplicate (MSD) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Calibration Information Continuing Calibration Verification (CCV) Requirements The calibration verification standards (CCV) did not meet acceptance criteria. One or more target analytes failedacceptance criteria with a negative bias on one analytical column in the standards bracketing samples andassociated QC. The negative bias for the analytical data is a result of instrument response decreasing after theinitial calibration. The instrument response never decreased to a point where the target analytes would not bedetected. All analytes were within the established retention time windows for this method. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC002 Central Plateau Cleanup Company (74393)
Client SDG: GEL531262 GEL Work Order: 531262
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:P Aroclor target analyte with greater than 25% difference between column analyses.U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
for
DL Indicates that sample is diluted. RA Indicates that sample is re-analyzed without re-extraction. RE Indicates that sample is re-extracted.
Qualifier Definition Report
Signature: Name:
Date: Title:27 JAN 2021
Barbara Bailey
Data Validator
Review/Validation
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Sample Data Summary
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GEL Laboratories LLC
Herbicide Certificate of Analysis
Sample Summary
January 25, 2021Report Date:
Page 1 of 1
SDG Number: GEL531262
Lab Sample ID: 531262010Matrix: WATER
Date Received: 01/05/2021 09:55
Date Collected: 01/04/2021 08:04
75-99-0
1918-00-9
93-65-2
94-74-6
120-36-5
94-75-7
93-72-1
93-76-5
94-82-6
88-85-7
Dalapon
Dicamba
MCPP
MCPA
Dichlorprop
2,4-D
2,4,5-TP
2,4,5-T
2,4-DB
Dinoseb
1.67
0.0833
16.7
16.7
0.0833
0.0833
0.0833
0.0833
0.0923
0.0833
U
PU
U
U
U
U
U
U
U
U
1.67
0.0833
16.7
16.7
0.0833
0.0833
0.0833
0.0833
0.0923
0.0833
5.00
0.250
50.0
50.0
0.250
0.250
0.250
0.250
0.250
0.250
Client: CPRC002 Project: CPRC0W21001
CAS No. Parmname ResultQualifier MDL/LOD PQL/LOQ
Method: SW846 3535A/8151A GL-OA-E-011
Batch ID: 2079808 Inst: ECD3A.I Dilution: 1SOP Ref:
Run Date: 01/12/2021 09:04 Analyst: LOF 1 uLInj. Vol:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
B3YW14Client ID:
Prep Date: Aliquot: Final Volume:01/11/2021 05:41 1000 mL 10 mL
Column
1
1
1
1
1
1
1
1
1
1
Column:011221HERB\E3a1207.D
011221HERB\E3a1207.D
Data File: 1 CLPesticides
2 CLPesticides
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Quality ControlSummary
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GEL Laboratories LLC
Surrogate Recovery Report
Herbicide
Report Date: January 25 2021
Page 1 of 1
SDG Number: GEL531262
Matrix Type: LIQUID
Surrogate Acceptance Limits
73 83
88 91
76 86
90 94
78 81
1204728730
1204728731
531262010
1204728732
1204728733
DCAA 1%REC #
DCAA 2%REC #
Sample ID Client ID
MB for batch 2079807
LCS for batch 2079807
B3YW14
B3YW14MS
B3YW14MSD
2,4-Dichlorophenylacetic acid (46%-144%)DCAA =
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values D Sample Diluted
Parmname
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-HERB2079808Batch
2,4,5-T
2,4,5-TP
2,4-D
2,4-DB
Dalapon
Dicamba
Dichlorprop
Dinoseb
MCPA
MCPP
2,4-Dichlorophenylacetic acid
2,4,5-T
2,4,5-TP
Parmname
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyMSIN R3-50
Richland, Washington
January 25, 2021Report Date:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/12/21 08:39
01/12/21 08:14
QC
2.00
1.93
1.88
1.98
19.4
1.82
1.84
1.34
194
203
4.39
0.0833
0.0833
NOM Sample Range
(62%-139%)
(63%-137%)
(58%-138%)
(52%-149%)
(43%-136%)
(59%-130%)
(63%-133%)
(23%-109%)
(52%-130%)
(43%-128%)
(46%-144%)
Qual
U
U
QC1204728731
QC1204728730
REC%
100
96
94
99
97
91
92
67
97
101
88
2.00
2.00
2.00
2.00
20.0
2.00
2.00
2.00
200
200
5.00
LCS
MB
531262Workorder:
PO Box 1600
**
RPD%
Page 1 of 4
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-HERB2079808Batch
2,4-D
2,4-DB
Dalapon
Dicamba
Dichlorprop
Dinoseb
MCPA
MCPP
2,4-Dichlorophenylacetic acid
2,4,5-T
2,4,5-TP
2,4-D
2,4-DB
Dalapon
Dicamba
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/12/21 08:14
01/12/21 09:30
QC
0.0833
0.0923
1.67
0.0833
0.0833
0.0833
16.7
16.7
3.66
2.05
1.96
1.91
1.98
22.6
1.91
NOM Sample
0.0833
0.0833
0.0833
0.0923
1.67
0.0833
Range
(46%-144%)
(35%-149%)
(39%-151%)
(42%-140%)
(40%-149%)
(32%-142%)
(38%-140%)
Qual
U
U
U
U
U
U
U
U
QC1204728732 531262010
REC%
73
103
98
96
99
113
94
5.00
2.00
2.00
2.00
2.00
20.0
2.00
MS
531262Workorder:
**
U
U
U
U
U
PU
RPD%
Page 2 of 4
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-HERB2079808Batch
Dichlorprop
Dinoseb
MCPA
MCPP
2,4-Dichlorophenylacetic acid
2,4,5-T
2,4,5-TP
2,4-D
2,4-DB
Dalapon
Dicamba
Dichlorprop
Dinoseb
MCPA
MCPP
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
LOF 01/12/21 09:30
01/12/21 09:55
QC
1.85
1.52
196
273
4.48
2.00
1.84
2.01
1.97
22.4
1.80
2.19
1.26
193
262
NOM Sample
0.0833
0.0833
16.7
16.7
3.78
0.0833
0.0833
0.0833
0.0923
1.67
0.0833
0.0833
0.0833
16.7
16.7
Range
(40%-143%)
(12%-122%)
(38%-139%)
(34%-139%)
(46%-144%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
(0%-30%)
Qual
QC1204728733 531262010
3
6
5
0
1
5
17
18
2
4
REC%
92
76
98
137
90
100
92
101
99
112
89
109
63
96
131
2.00
2.00
200
200
5.00
2.00
2.00
2.00
2.00
20.0
2.00
2.00
2.00
200
200
MSD
531262Workorder:
**
U
U
U
U
U
U
U
U
U
PU
U
U
U
U
RPD%
Page 3 of 4
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Semi-Volatiles-HERB2079808Batch
2,4-Dichlorophenylacetic acid
Parmname
Page 4 of 4
Units
ug/L
Anlst Date Time
LOF 01/12/21 09:55
QC
3.88
NOM Sample
3.78
Range
(46%-144%)
Qual
The Qualifiers in this report are defined as follows:
REC%
785.00
531262Workorder:
A
B
C
D
E
E
J
N
P
T
U
X
Y
Z
o
The TIC is a suspected aldol-condensation product
The analyte was detected in both the associated QC blank and in the sample.
Analyte has been confirmed by GC/MS analysis
Results are reported from a diluted aliquot of sample.
Concentration exceeds the calibration range of the instrument
Reported value is estimated due to interferences. See comment in narrative.
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Value is estimatedSpike Sample recovery is outside control limits.
Aroclor target analyte with greater than 25% difference between column analyses.
Spike and/or spike duplicate sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Analyte failed to recover within LCS limits (0rganics only)
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
**
RPD%
Notes:
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Metals Analysis
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Case Narrative
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Metals Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
Product: Determination of Metals by ICP Analytical Method: SW846 3005A/6010D Analytical Procedure: GL-MA-E-013 REV# 31 Analytical Batch: 2078388 Product: Determination of Metals by ICP-MS Analytical Method: SW846 3005A/6020B Analytical Procedure: GL-MA-E-014 REV# 34 Analytical Batch: 2078392 Product: Mercury Analysis Using the Perkin Elmer Automated Mercury Analyzer Analytical Method: 7470_HG_CVAA Analytical Procedure: GL-MA-E-010 REV# 38 Analytical Batch: 2081170 Preparation Method: SW846 3005A Preparation Procedure: GL-MA-E-006 REV# 14 Preparation Batches: 2078387 and 2078391 Preparation Method: SW846 7470A Prep Preparation Procedure: GL-MA-E-010 REV# 38 Preparation Batch: 2081169 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262007 B3YLV3 531262008 B3YLV7 1204726533 Method Blank (MB)ICP 1204726534 Laboratory Control Sample (LCS) 1204726537 531262007(B3YLV3L) Serial Dilution (SD) 1204726535 531262007(B3YLV3S) Matrix Spike (MS) 1204726536 531262007(B3YLV3SD) Matrix Spike Duplicate (MSD) 1204726543 Method Blank (MB)ICP-MS 1204726544 Laboratory Control Sample (LCS) 1204726547 531262007(B3YLV3L) Serial Dilution (SD) 1204726545 531262007(B3YLV3S) Matrix Spike (MS) 1204726546 531262007(B3YLV3SD) Matrix Spike Duplicate (MSD) 1204731219 Method Blank (MB)CVAA 1204731220 Laboratory Control Sample (LCS) 1204731223 531262007(B3YLV3L) Serial Dilution (SD) 1204731221 531262007(B3YLV3D) Sample Duplicate (DUP) 1204731222 531262007(B3YLV3S) Matrix Spike (MS)
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The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and proceduresfor initial calibration, continuing calibration, instrument controls and process controls where applicable, with thefollowing exceptions. Calibration Information ICSA/ICSAB Statement For the ICP-MS analysis, the ICSA solution contains analyte concentrations which are verified trace impuritiesindigenous to the purchased standard. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC002 Central Plateau Cleanup Company (74393)
Client SDG: GEL531262 GEL Work Order: 531262
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:* Duplicate analysis not within control limitsB The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equalto the IDL/MDL (as appropriate).D Results are reported from a diluted aliquot of sample.N Spike Sample recovery is outside control limits.U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
forQualifier Definition Report
Signature: Name:
Date: Title:25 JAN 2021
Edmund Frampton
Team Leader
Review/Validation
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Sample Data Summary
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METALS−1−
INORGANICS ANALYSIS DATA PACKAGE
GEL Laboratories LLC
SDG No: METHOD TYPE:
SAMPLE ID:
CLIENT ID:
CONTRACT:
MATRIX:
DATE RECEIVEDLEVEL:
%SOLIDS:
Analyte Result Qual M*Run Date
AnalyticalRun
Low
GEL531262
531262007
B3YLV3
CPRC0W21001
WATER
05−JAN−21
0
7429−90−5
7440−36−0
7440−38−2
7440−39−3
7440−41−7
7440−42−8
7440−43−9
7440−70−2
7440−47−3
7440−48−4
7440−50−8
7439−89−6
7439−92−1
7439−95−4
7439−96−5
7439−97−6
7439−98−7
7440−02−0
7440−09−7
7782−49−2
7440−22−4
7440−23−5
7440−24−6
7440−28−0
7440−29−1
7440−31−5
7440−61−1
7440−62−2
7440−66−6
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Thorium
Tin
Uranium
Vanadium
Zinc
42.8
1.00
2.00
39.6
0.200
15.0
0.300
43600
4.80
0.300
2.36
77.4
0.500
13700
3.05
0.0670
10.5
4.13
4380
5.51
0.300
11300
176
0.600
0.700
1.00
0.962
21.0
3.30
19.3
1.00
2.00
0.670
0.200
15.0
0.300
50.0
3.00
0.300
0.300
30.0
0.500
110
1.00
0.0670
0.200
0.600
50.0
2.00
0.300
100
2.00
0.600
0.700
1.00
0.0670
1.00
3.30
01/14/21 23:38
01/14/21 23:38
01/14/21 23:38
01/14/21 23:38
01/14/21 23:38
01/15/21 17:46
01/14/21 23:38
01/14/21 17:42
01/14/21 23:38
01/14/21 23:38
01/14/21 23:38
01/14/21 17:42
01/14/21 23:38
01/14/21 17:42
01/14/21 23:38
01/14/21 07:50
01/14/21 23:38
01/14/21 23:38
01/14/21 17:42
01/14/21 23:38
01/14/21 23:38
01/14/21 17:42
01/14/21 23:38
01/14/21 23:38
01/14/21 23:38
01/14/21 23:38
01/14/21 23:38
01/14/21 17:42
01/14/21 23:38
B
U
U
U
U
U
B
U
B
U
B
U
U
U
U
U
U
MS
MS
MS
MS
MS
P
MS
P
MS
MS
MS
P
MS
P
MS
AV
MS
MS
P
MS
MS
P
MS
MS
MS
MS
MS
P
MS
210114−3
210114−3
210114−3
210114−3
210114−3
011521−2
210114−3
011421−1
210114−3
210114−3
210114−3
011421−1
210114−3
011421−1
210114−3
011421W1−4
210114−3
210114−3
011421−1
210114−3
210114−3
011421−1
210114−3
210114−3
210114−3
210114−3
210114−3
011421−1
210114−3
SW846
DF
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
CRDL AnalystAnalytical
Batch
DATE COLLECTED
MDL
2078387
2078391
50
50
mL
mL
50
50
mL
mL
01/06/21
01/06/21
Prep Batch
Initial wt./vol. Units Final wt./vol. Units Date
Prep Information:
50.0
3.00
5.00
4.00
0.500
50.0
1.00
200
10.0
1.00
2.00
100
2.00
300
5.00
0.200
1.00
2.00
150
5.00
1.00
300
10.0
2.00
2.00
5.00
0.200
5.00
20.0
PRB
PRB
PRB
PRB
PRB
HSC
PRB
HSC
PRB
PRB
PRB
HSC
PRB
HSC
PRB
MTM1
PRB
PRB
HSC
PRB
PRB
HSC
PRB
PRB
PRB
PRB
PRB
HSC
PRB
2078392
2078392
2078392
2078392
2078392
2078388
2078392
2078388
2078392
2078392
2078392
2078388
2078392
2078388
2078392
2081170
2078392
2078392
2078388
2078392
2078392
2078388
2078392
2078392
2078392
2078392
2078392
2078388
2078392
04−JAN−21BASIS:
2078388
2078392
AnalyticalBatch
SM1
SM1
Analyst
As Received
SW846 3005A
SW846 3005A
Prep Method
PQL
50.0
3.00
5.00
4.00
0.500
50.0
1.00
200
10.0
1.00
2.00
100
2.00
300
5.00
0.200
1.00
2.00
150
5.00
1.00
300
10.0
2.00
2.00
5.00
0.200
5.00
20.0
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
CAS
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METALS−1−
INORGANICS ANALYSIS DATA PACKAGE
GEL Laboratories LLC
2081169 20 mL 20 mL 01/13/212081170 AXS5SW846 7470A Prep
*Analytical Methods:
P
MS
AV
SW846 3005A/6010D
SW846 3005A/6020B
SW846 7470A
Page 174 of 214 SDG: GEL531262 Rev1
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METALS−1−
INORGANICS ANALYSIS DATA PACKAGE
GEL Laboratories LLC
SDG No: METHOD TYPE:
SAMPLE ID:
CLIENT ID:
CONTRACT:
MATRIX:
DATE RECEIVEDLEVEL:
%SOLIDS:
Analyte Result Qual M*Run Date
AnalyticalRun
Low
GEL531262
531262008
B3YLV7
CPRC0W21001
WATER
05−JAN−21
0
7429−90−5
7440−36−0
7440−38−2
7440−39−3
7440−41−7
7440−42−8
7440−43−9
7440−70−2
7440−47−3
7440−48−4
7440−50−8
7439−89−6
7439−92−1
7439−95−4
7439−96−5
7439−97−6
7439−98−7
7440−02−0
7440−09−7
7782−49−2
7440−22−4
7440−23−5
7440−24−6
7440−28−0
7440−29−1
7440−31−5
7440−61−1
7440−62−2
7440−66−6
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Molybdenum
Nickel
Potassium
Selenium
Silver
Sodium
Strontium
Thallium
Thorium
Tin
Uranium
Vanadium
Zinc
19.3
1.00
2.00
39.0
0.200
15.0
0.300
43800
4.65
0.300
1.57
30.0
0.500
13700
1.00
0.0670
10.3
3.56
4330
5.47
0.300
11300
177
0.600
0.700
1.00
0.943
20.8
3.30
19.3
1.00
2.00
0.670
0.200
15.0
0.300
50.0
3.00
0.300
0.300
30.0
0.500
110
1.00
0.0670
0.200
0.600
50.0
2.00
0.300
100
2.00
0.600
0.700
1.00
0.0670
1.00
3.30
01/14/21 23:56
01/14/21 23:56
01/14/21 23:56
01/14/21 23:56
01/14/21 23:56
01/15/21 17:59
01/14/21 23:56
01/14/21 17:56
01/14/21 23:56
01/14/21 23:56
01/14/21 23:56
01/14/21 17:56
01/14/21 23:56
01/14/21 17:56
01/14/21 23:56
01/14/21 08:02
01/14/21 23:56
01/14/21 23:56
01/14/21 17:56
01/14/21 23:56
01/14/21 23:56
01/14/21 17:56
01/14/21 23:56
01/14/21 23:56
01/14/21 23:56
01/14/21 23:56
01/14/21 23:56
01/14/21 17:56
01/14/21 23:56
U
U
U
U
U
U
B
U
B
U
U
U
U
U
U
U
U
U
MS
MS
MS
MS
MS
P
MS
P
MS
MS
MS
P
MS
P
MS
AV
MS
MS
P
MS
MS
P
MS
MS
MS
MS
MS
P
MS
210114−3
210114−3
210114−3
210114−3
210114−3
011521−2
210114−3
011421−1
210114−3
210114−3
210114−3
011421−1
210114−3
011421−1
210114−3
011421W1−4
210114−3
210114−3
011421−1
210114−3
210114−3
011421−1
210114−3
210114−3
210114−3
210114−3
210114−3
011421−1
210114−3
SW846
DF
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
CRDL AnalystAnalytical
Batch
DATE COLLECTED
MDL
2078387
2078391
50
50
mL
mL
50
50
mL
mL
01/06/21
01/06/21
Prep Batch
Initial wt./vol. Units Final wt./vol. Units Date
Prep Information:
50.0
3.00
5.00
4.00
0.500
50.0
1.00
200
10.0
1.00
2.00
100
2.00
300
5.00
0.200
1.00
2.00
150
5.00
1.00
300
10.0
2.00
2.00
5.00
0.200
5.00
20.0
PRB
PRB
PRB
PRB
PRB
HSC
PRB
HSC
PRB
PRB
PRB
HSC
PRB
HSC
PRB
MTM1
PRB
PRB
HSC
PRB
PRB
HSC
PRB
PRB
PRB
PRB
PRB
HSC
PRB
2078392
2078392
2078392
2078392
2078392
2078388
2078392
2078388
2078392
2078392
2078392
2078388
2078392
2078388
2078392
2081170
2078392
2078392
2078388
2078392
2078392
2078388
2078392
2078392
2078392
2078392
2078392
2078388
2078392
04−JAN−21BASIS:
2078388
2078392
AnalyticalBatch
SM1
SM1
Analyst
As Received
SW846 3005A
SW846 3005A
Prep Method
PQL
50.0
3.00
5.00
4.00
0.500
50.0
1.00
200
10.0
1.00
2.00
100
2.00
300
5.00
0.200
1.00
2.00
150
5.00
1.00
300
10.0
2.00
2.00
5.00
0.200
5.00
20.0
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
CAS
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(178 of 217)
METALS−1−
INORGANICS ANALYSIS DATA PACKAGE
GEL Laboratories LLC
2081169 20 mL 20 mL 01/13/212081170 AXS5SW846 7470A Prep
*Analytical Methods:
P
MS
AV
SW846 3005A/6010D
SW846 3005A/6020B
SW846 7470A
Page 176 of 214 SDG: GEL531262 Rev1
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(179 of 217)
Quality ControlSummary
Page 177 of 214 SDG: GEL531262 Rev1
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS2078392Batch
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Manganese
Molybdenum
Nickel
Parmname
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyMSIN R3-50
Richland, Washington
January 25, 2021Report Date:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB 01/14/21 23:34
QC
2000
48.3
46.2
48.5
57.7
48.6
48.4
47.3
47.2
50.6
47.1
48.9
47.3
NOM Sample Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
QC1204726544
REC%
100
96.5
92.4
97.1
115
97.2
96.8
94.7
94.4
101
94.2
97.8
94.7
2000
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
LCS
531262Workorder:
PO Box 1600
RPD/D%
Page 1 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS2078392Batch
Selenium
Silver
Strontium
Thallium
Thorium
Tin
Uranium
Zinc
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB 01/14/21 23:34
01/14/21 23:31
QC
46.6
49.7
47.4
48.6
49.8
49.2
50.0
47.3
19.3
1.00
2.00
0.670
0.200
0.300
3.00
NOM Sample Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
U
U
U
U
U
U
U
QC1204726543
REC%
93.2
99.5
94.8
97.2
99.6
98.4
100
94.5
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
MB
531262Workorder:
RPD/D%
Page 2 of 11
Page 179 of 214 SDG: GEL531262 Rev1
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS2078392Batch
Cobalt
Copper
Lead
Manganese
Molybdenum
Nickel
Selenium
Silver
Strontium
Thallium
Thorium
Tin
Uranium
Zinc
Aluminum
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB 01/14/21 23:31
01/14/21 23:41
QC
0.300
0.300
0.500
1.00
0.200
0.600
2.00
0.300
2.00
0.600
0.700
1.00
0.0670
3.30
2110
NOM Sample
42.8
Range
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
U
U
U
U
U
QC1204726545 531262007
REC%
1032000MS
531262Workorder:
B
RPD/D%
Page 3 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS2078392Batch
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Manganese
Molybdenum
Nickel
Selenium
Silver
Strontium
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB 01/14/21 23:41
QC
49.5
50.0
88.2
57.6
50.1
54.1
48.5
50.4
50.7
51.3
61.9
52.1
53.6
50.6
227
NOM Sample
1.00
2.00
39.6
0.200
0.300
4.80
0.300
2.36
0.500
3.05
10.5
4.13
5.51
0.300
176
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual REC%
98
96.3
97.3
115
100
98.7
96.8
96.1
101
96.5
103
96
96.1
101
102
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
531262Workorder:
U
U
U
U
B
U
U
B
U
RPD/D%
Page 4 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS2078392Batch
Thallium
Thorium
Tin
Uranium
Zinc
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB 01/14/21 23:41
01/14/21 23:45
QC
48.9
51.0
50.2
52.1
48.8
2190
51.1
50.3
91.4
59.6
50.9
55.5
49.2
50.4
51.6
NOM Sample
0.600
0.700
1.00
0.962
3.30
42.8
1.00
2.00
39.6
0.200
0.300
4.80
0.300
2.36
0.500
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
QC1204726546 531262007
3.59
3.34
0.636
3.52
3.52
1.57
2.47
1.34
0.0694
1.72
REC%
97.6
101
99.8
102
93.1
107
101
97
104
119
102
101
98.2
96.1
103
50.0
50.0
50.0
50.0
50.0
2000
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
MSD
531262Workorder:
U
U
U
U
B
U
U
U
U
B
U
U
RPD/D%
Page 5 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS2078392Batch
Manganese
Molybdenum
Nickel
Selenium
Silver
Strontium
Thallium
Thorium
Tin
Uranium
Zinc
Aluminum
Antimony
Arsenic
Barium
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB 01/14/21 23:45
01/14/21 23:52
QC
53.0
62.6
53.2
54.5
51.3
232
50.1
52.7
51.7
53.5
49.0
96.5
5.00
10.0
8.03
NOM Sample
3.05
10.5
4.13
5.51
0.300
176
0.600
0.700
1.00
0.962
3.30
42.8
0.484
1.83
39.6
Range
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
DU
DU
DU
D
QC1204726547 531262007
3.19
1.06
2.07
1.79
1.51
2.03
2.41
3.23
2.9
2.49
0.264
N/A
N/A
N/A
1.33
REC%
99.8
104
98.2
98.1
103
111
100
104
103
105
93.4
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
SDILT
531262Workorder:
B
U
U
U
U
U
B
U
U
RPD/D%
Page 6 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS2078392Batch
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Manganese
Molybdenum
Nickel
Selenium
Silver
Strontium
Thallium
Thorium
Tin
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB 01/14/21 23:52
QC
1.00
1.50
15.0
1.50
0.504
2.50
5.00
2.07
0.837
10.0
1.50
33.4
3.00
3.50
5.00
NOM Sample
0.00700
0.0130
4.80
0.0920
2.36
0.0140
3.05
10.5
4.13
5.51
0.0100
176
0.0960
0.562
0.324
Range
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
DU
DU
DU
DU
BD
DU
DU
D
BD
DU
DU
D
DU
DU
DU
N/A
N/A
N/A
N/A
7.01
N/A
N/A
1.41
1.45
N/A
N/A
5.12
N/A
N/A
N/A
REC%
531262Workorder:
U
U
B
U
U
B
U
U
U
U
RPD/D%
Page 7 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis - ICPMS
Metals Analysis-ICP
2078392
2078388
Batch
Batch
Uranium
Zinc
Boron
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
Boron
Calcium
Iron
Magnesium
Potassium
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
PRB
HSC
01/14/21 23:52
01/15/21 17:43
01/14/21 17:39
01/15/21 17:39
01/14/21 17:35
QC
0.207
16.5
487
4990
4960
4920
4820
5140
494
15.0
50.0
30.0
110
50.0
NOM Sample
0.962
2.26
Range
(0%-20%)
(0%-20%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
D
DU
U
U
U
U
U
QC1204726534
QC1204726533
7.59
N/A
REC%
97.4
99.8
99.2
98.4
96.4
103
98.9
500
5000
5000
5000
5000
5000
500
LCS
MB
531262Workorder:
U
RPD/D%
Page 8 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis-ICP2078388Batch
Sodium
Vanadium
Boron
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
Boron
Calcium
Iron
Magnesium
Potassium
Sodium
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
HSC 01/14/21 17:35
01/15/21 17:49
01/14/21 17:46
01/15/21 17:52
01/14/21 17:49
QC
100
1.00
530
48100
4840
18200
9090
16000
506
534
48400
4770
17900
8940
16100
NOM Sample
15.0
43600
77.4
13700
4380
11300
21.0
15.0
43600
77.4
13700
4380
11300
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
U
U
QC1204726535 531262007
QC1204726536 531262007
0.77
0.771
1.51
1.63
1.63
0.569
REC%
103
N/A
95.3
89.9
94.1
92.5
97
104
N/A
93.8
84
91.2
94.4
500
5000
5000
5000
5000
5000
500
500
5000
5000
5000
5000
5000
MS
MSD
531262Workorder:
U
B
U
B
RPD/D%
Page 9 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis-ICP
Metals Analysis-Mercury
2078388
2081170
Batch
Batch
Vanadium
Boron
Calcium
Iron
Magnesium
Potassium
Sodium
Vanadium
Mercury
Mercury
Mercury
Mercury
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
HSC
MTM1
01/14/21 17:49
01/15/21 17:55
01/14/21 17:52
01/14/21 07:52
01/14/21 07:45
01/14/21 07:43
01/14/21 07:54
QC
502
75.0
8420
150
2630
814
2160
4.17
0.200
2.00
0.200
1.99
NOM Sample
21.0
14.6
43600
77.4
13700
4380
11300
21.0
0.200
0.200
Range
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(80%-120%)
(75%-125%)
Qual
DU
D
DU
D
D
D
BD
U
U
QC1204726537 531262007
QC1204731221 531262007
QC1204731220
QC1204731219
QC1204731222 531262007
0.84
N/A
3.52
N/A
3.69
7.19
4.63
.491
N/A
REC%
96.1
99.8
99.7
500
2.00
2.00
SDILT
DUP
LCS
MB
MS
531262Workorder:
U
B
U
U
RPD/D%
Page 10 of 11
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Metals Analysis-Mercury2081170Batch
Mercury
Parmname
Page 11 of 11
Units
ug/L
Anlst Date Time
MTM1 01/14/21 07:59
QC
1.00
NOM Sample
-0.0220
Range
(0%-10%)
Qual
DUQC1204731223 531262007
The Qualifiers in this report are defined as follows:
N/A
REC%
SDILT
531262Workorder:
*
+
B
C
D
E
M
N
S
U
W
X
Y
Z
Duplicate analysis not within control limits
Correlation coefficient for Method of Standard Additions (MSA) is < 0.995
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (as appropriate).
Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of the measuredconcentration and/or decision level for associated samples.Results are reported from a diluted aliquot of sample.
Reported value is estimated due to interferences. See comment in narrative.
Duplicate precision not met.
Spike Sample recovery is outside control limits.
Reported value determined by the Method of Standard Additions (MSA)
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Post-digestion spike recovery for GFAA out of control limit. Sample absorbency < 50% of spike absorbency.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
U
RPD/D%
Notes:
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General Chem Analysis
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Case Narrative
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General Chemistry Technical Case Narrative
Central Plateau Cleanup Company SDG #: GEL531262
Work Order #: 531262
Product: Carbon, Total Organic Analytical Method: SW846 9060A Analytical Procedure: GL-GC-E-093 REV# 16 Analytical Batch: 2078356 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262004 B3YLJ6 531262005 B3YLK7 531262007 B3YLV3 1204726481 Method Blank (MB) 1204726482 Laboratory Control Sample (LCS) 1204726484 531262007(B3YLV3) Sample Duplicate (DUP) 1204726485 531262007(B3YLV3) Post Spike (PS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this reportmet the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuingcalibration, instrument controls and process controls where applicable.
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Product: Cyanide, Total Analytical Method: 9012_CYANIDE Analytical Procedure: GL-GC-E-095 REV# 22 Analytical Batch: 2078517 Preparation Method: 9012_CYANIDE Preparation Procedure: GL-GC-E-067 REV# 23 Preparation Batch: 2078516 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262004 B3YLJ6 531262005 B3YLK7 531262007 B3YLV3 1204726747 Method Blank (MB) 1204726748 Laboratory Control Sample (LCS) 1204726749 531262004(B3YLJ6) Sample Duplicate (DUP) 1204726750 531262004(B3YLJ6) Matrix Spike (MS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this reportmet the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuingcalibration, instrument controls and process controls where applicable.
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Product: Total Organic Halogens (TOX) Analytical Method: 9020_TOX Analytical Procedure: GL-GC-E-007 REV# 16 Analytical Batch: 2078942 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262004 B3YLJ6 531262005 B3YLK7 531262007 B3YLV3 1204727378 Method Blank (MB) 1204727379 Laboratory Control Sample (LCS) 1204727380 531262004(B3YLJ6) Sample Duplicate (DUP) 1204727381 531262004(B3YLJ6) Matrix Spike (MS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and proceduresfor initial calibration, continuing calibration, instrument controls and process controls where applicable, with thefollowing exceptions. Miscellaneous Information Additional Comments A pair of nitrate wash blanks is analyzed at the start of the batch. Although they are designated as ICB, they areperformed for calculating purposes only. The value of the nitrate wash blanks are averaged and subtracted from allsamples. Neither of these values should exceed 0.6 ug Cl. The PQL limit typically applied to ICB results does notapply in this application, since the results are used only to determine background concentrations and are subtractedfrom all calculated results. Breakthrough effect Breakthrough effect: If the value for a sample is greater than the reporting limit (10 ug/L), the result for the secondslug should not be greater than 25% of the combined value of the first and second slug. Results which do not meetthese criteria are designated with a "Fail" comment in the Breakthrough effect column on the Logbook page; however,the "fail" designation is not applicable for samples with a result of less than 10 ug/L.
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Product: Ion Chromatography Analytical Method: 9056_ANIONS_IC Analytical Procedure: GL-GC-E-086 REV# 29 Analytical Batch: 2078303 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262001 B3YLJ9 531262002 B3YLK4 531262003 B3YKN8 1204726398 Method Blank (MB) 1204726399 Laboratory Control Sample (LCS) 1204726518 531262003(B3YKN8) Sample Duplicate (DUP) 1204726519 531262003(B3YKN8) Post Spike (PS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and proceduresfor initial calibration, continuing calibration, instrument controls and process controls where applicable, with thefollowing exceptions. Technical Information Sample Dilutions The following samples 1204726518 (B3YKN8DUP), 1204726519 (B3YKN8PS), 531262001 (B3YLJ9), 531262002(B3YLK4) and 531262003 (B3YKN8) were diluted because target analyte concentrations exceeded the calibrationrange. Dilutions may be required for many reasons, including to minimize matrix interferences or to bring over rangetarget analyte concentrations into the linear calibration range.
Analyte531262
001 002 003
Chloride 2X 2X 5X
Nitrate-N 2X 2X 5X
Sulfate 2X 2X 5X
Miscellaneous Information Manual Integrations Samples 1204726518 (B3YKN8DUP) and 531262003 (B3YKN8) were manually integrated to correctly position thebaseline as set in the calibration standards.
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Product: Sulfide, Total Analytical Method: 4500D_SULFIDE Analytical Procedure: GL-GC-E-052 REV# 11 Analytical Batch: 2080120 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262004 B3YLJ6 531262005 B3YLK7 531262007 B3YLV3 1204729314 Method Blank (MB) 1204729315 Laboratory Control Sample (LCS) 1204729316 531262004(B3YLJ6) Post Spike (PS) 1204729319 531262004(B3YLJ6) Post Spike Duplicate (PSD) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this reportmet the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuingcalibration, instrument controls and process controls where applicable.
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Product: Alkalinity Analytical Method: 2320_ALKALINITY Analytical Procedure: GL-GC-E-033 REV# 13 Analytical Batch: 2078293 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 531262004 B3YLJ6 531262005 B3YLK7 531262006 B3YLV9 531262007 B3YLV3 1204726385 Laboratory Control Sample (LCS) 1204726386 531262004(B3YLJ6) Sample Duplicate (DUP) 1204726387 531262004(B3YLJ6) Matrix Spike (MS) 1204726512 531262005(B3YLK7) Sample Duplicate (DUP) 1204726513 531262005(B3YLK7) Matrix Spike (MS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this reportmet the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuingcalibration, instrument controls and process controls where applicable. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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(199 of 217)
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC002 Central Plateau Cleanup Company (74393)
Client SDG: GEL531262 GEL Work Order: 531262
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:B The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equalto the IDL/MDL (as appropriate).D Results are reported from a diluted aliquot of sample.U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
forQualifier Definition Report
Signature: Name:
Date: Title:27 JAN 2021
Aubrey Kingsbury
Data Validator
Review/Validation
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Sample Data Summary
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(201 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Ion Chromatography
2078303
2078303
1346
1925
ug/Lug/Lug/Lug/Lug/L
01/05/21
01/05/21
LXA2
LXA2
500100400200800
11222
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262001WATER04-JAN-21 08:5505-JAN-21
B3YLJ9 CPRC0W21001Project:CPRC002Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
33.033.013466.0266
1
2
BUDDD
FluorideNitrite-NChlorideNitrate-NSulfate
9056_ANIONS_IC: COMMON "As Received"26233.0
147006780
35400
The following Analytical Methods were performed:
12
Method Description 9056_ANIONS_IC9056_ANIONS_IC
Analyst Comments
Notes:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
Page 199 of 214 SDG: GEL531262 Rev1
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(202 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Ion Chromatography
2078303
2078303
1417
1956
ug/Lug/Lug/Lug/Lug/L
01/05/21
01/05/21
LXA2
LXA2
500100400200800
11222
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262002WATER04-JAN-21 08:0405-JAN-21
B3YLK4 CPRC0W21001Project:CPRC002Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
33.033.013466.0266
1
2
BUDDD
FluorideNitrite-NChlorideNitrate-NSulfate
9056_ANIONS_IC: COMMON "As Received"27133.0
168006350
34200
The following Analytical Methods were performed:
12
Method Description 9056_ANIONS_IC9056_ANIONS_IC
Analyst Comments
Notes:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
Page 200 of 214 SDG: GEL531262 Rev1
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(203 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Ion Chromatography
2078303
2078303
1448
2027
ug/Lug/Lug/Lug/Lug/L
01/05/21
01/05/21
LXA2
LXA2
500100
1000500
2000
11555
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262003WATER04-JAN-21 10:4305-JAN-21
B3YKN8 CPRC0W21001Project:CPRC002Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
33.033.0335165665
1
2
BUDDD
FluorideNitrite-NChlorideNitrate-NSulfate
9056_ANIONS_IC: COMMON "As Received"26433.0
271001040056400
The following Analytical Methods were performed:
12
Method Description 9056_ANIONS_IC9056_ANIONS_IC
Analyst Comments
Notes:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
Page 201 of 214 SDG: GEL531262 Rev1
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(204 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Carbon Analysis
Flow Injection Analysis
Halogen Analysis
Spectrometric Analysis
Titration and Ion Analysis
2078356
2078517
2078942
2080120
2078293
0918
0901
2340
1638
1638
ug/Lug/Lug/Lug/Lug/L
ug/L
ug/L
ug/L
ug/Lug/Lug/Lug/L
01/06/21
01/07/21
01/12/21
01/11/21
01/13/21
TSM
AXH3
RMJ
RXB5
RXB5
10001000100010001000
5.00
10.0
500
4000400040004000
11111
1
1
1
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262004WATER04-JAN-21 08:5505-JAN-21
B3YLJ6 CPRC0W21001Project:CPRC002Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
330330330330330
1.67
3.33
33.0
1450145014501450
1
2
3
4
5
UUBBU
U
B
U
UU
Total Organic Carbon #1Total Organic Carbon #2Total Organic Carbon #3Total Organic Carbon #4Total Organic Carbon Average
Cyanide, Total
Total Organic Halogens
Total Sulfide
Alkalinity, Total as CaCO3Bicarbonate alkalinity (CaCO3)Carbonate alkalinity (CaCO3)Hydroxide alkalinity as CaCO3
9060_TOC: COMMON "As Received"
9012_CYANIDE (TOTAL): COMMON "As Received"
9020_TOX: COMMON "As Received"
4500_Sulfide: COMMON "As Received"
2320_ALKALINITY: GW 01 "As Received"
330330330330330
1.67
6.52
33.0
113000113000
14501450
1.00
The following Prep Methods were performed:
9012_CYANIDE SW846 9010C Prep 01/07/21 20785160821AXH3
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
12345
Method Description SW846 9060A9012_CYANIDE9020_TOX4500D_SULFIDE2320_ALKALINITY
Analyst Comments
Notes:
Page 202 of 214 SDG: GEL531262 Rev1
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(205 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262004B3YLJ6 CPRC0W21001Project:
CPRC002Client ID:Sample ID:
PO Box 1600
Client Sample ID:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
Page 203 of 214 SDG: GEL531262 Rev1
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(206 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Carbon Analysis
Flow Injection Analysis
Halogen Analysis
Spectrometric Analysis
Titration and Ion Analysis
2078356
2078517
2078942
2080120
2078293
0957
0904
0122
1642
1643
ug/Lug/Lug/Lug/Lug/L
ug/L
ug/L
ug/L
ug/Lug/Lug/Lug/L
01/06/21
01/07/21
01/13/21
01/11/21
01/13/21
TSM
AXH3
RMJ
RXB5
RXB5
10001000100010001000
5.00
10.0
500
4000400040004000
11111
1
1
1
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262005WATER04-JAN-21 10:4305-JAN-21
B3YLK7 CPRC0W21001Project:CPRC002Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
330330330330330
1.67
3.33
33.0
1450145014501450
1
2
3
4
5
UBBBB
U
B
U
UU
Total Organic Carbon #1Total Organic Carbon #2Total Organic Carbon #3Total Organic Carbon #4Total Organic Carbon Average
Cyanide, Total
Total Organic Halogens
Total Sulfide
Alkalinity, Total as CaCO3Bicarbonate alkalinity (CaCO3)Carbonate alkalinity (CaCO3)Hydroxide alkalinity as CaCO3
9060_TOC: COMMON "As Received"
9012_CYANIDE (TOTAL): COMMON "As Received"
9020_TOX: COMMON "As Received"
4500_Sulfide: COMMON "As Received"
2320_ALKALINITY: GW 01 "As Received"
330354379363349
1.67
4.96
33.0
111000111000
14501450
1.00
The following Prep Methods were performed:
9012_CYANIDE SW846 9010C Prep 01/07/21 20785160821AXH3
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
12345
Method Description SW846 9060A9012_CYANIDE9020_TOX4500D_SULFIDE2320_ALKALINITY
Analyst Comments
Notes:
Page 204 of 214 SDG: GEL531262 Rev1
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(207 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262005B3YLK7 CPRC0W21001Project:
CPRC002Client ID:Sample ID:
PO Box 1600
Client Sample ID:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
Page 205 of 214 SDG: GEL531262 Rev1
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(208 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Titration and Ion Analysis
20782931650ug/Lug/Lug/Lug/L
01/13/21RXB54000400040004000
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262006WATER04-JAN-21 08:1205-JAN-21
B3YLV9 CPRC0W21001Project:CPRC002Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
1450145014501450
1
UU
Alkalinity, Total as CaCO3Bicarbonate alkalinity (CaCO3)Carbonate alkalinity (CaCO3)Hydroxide alkalinity as CaCO3
2320_ALKALINITY: GW 01 "As Received"353000353000
14501450
The following Analytical Methods were performed:
1Method Description
2320_ALKALINITYAnalyst Comments
Notes:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
Page 206 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(209 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Carbon Analysis
Flow Injection Analysis
Halogen Analysis
Spectrometric Analysis
Titration and Ion Analysis
2078356
2078517
2078942
2080120
2078293
1036
0905
0221
1643
1652
ug/Lug/Lug/Lug/Lug/L
ug/L
ug/L
ug/L
ug/Lug/Lug/Lug/L
01/06/21
01/07/21
01/13/21
01/11/21
01/13/21
TSM
AXH3
RMJ
RXB5
RXB5
10001000100010001000
5.00
10.0
500
4000400040004000
11111
1
1
1
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262007WATER04-JAN-21 09:4705-JAN-21
B3YLV3 CPRC0W21001Project:CPRC002Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
330330330330330
1.67
3.33
33.0
1450145014501450
1
2
3
4
5
UUUUU
U
U
U
UU
Total Organic Carbon #1Total Organic Carbon #2Total Organic Carbon #3Total Organic Carbon #4Total Organic Carbon Average
Cyanide, Total
Total Organic Halogens
Total Sulfide
Alkalinity, Total as CaCO3Bicarbonate alkalinity (CaCO3)Carbonate alkalinity (CaCO3)Hydroxide alkalinity as CaCO3
9060_TOC: COMMON "As Received"
9012_CYANIDE (TOTAL): COMMON "As Received"
9020_TOX: COMMON "As Received"
4500_Sulfide: COMMON "As Received"
2320_ALKALINITY: GW 01 "As Received"
330330330330330
1.67
3.33
33.0
114000114000
14501450
1.00
The following Prep Methods were performed:
9012_CYANIDE SW846 9010C Prep 01/07/21 20785160821AXH3
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
12345
Method Description SW846 9060A9012_CYANIDE9020_TOX4500D_SULFIDE2320_ALKALINITY
Analyst Comments
Notes:
Page 207 of 214 SDG: GEL531262 Rev1
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(210 of 217)
Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: January 27, 2021
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyCompany :MSIN R3-50
Richland, Washington 99352
Address :
SAF W21-001Project:
531262007B3YLV3 CPRC0W21001Project:
CPRC002Client ID:Sample ID:
PO Box 1600
Client Sample ID:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
Page 208 of 214 SDG: GEL531262 Rev1
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(211 of 217)
Quality ControlSummary
Page 209 of 214 SDG: GEL531262 Rev1
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(212 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Carbon Analysis
Flow Injection Analysis
Halogen Analysis
2078356
2078517
2078942
Batch
Batch
Batch
Total Organic Carbon Average
Total Organic Carbon Average
Total Organic Carbon Average
Total Organic Carbon Average
Cyanide, Total
Cyanide, Total
Cyanide, Total
Cyanide, Total
Total Organic Halogens
Parmname
Mr. Scot FitzgeraldContact:
Central Plateau Cleanup CompanyMSIN R3-50
Richland, Washington
January 27, 2021Report Date:
Units
ug/L
ug/L
ug/L
mg/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
TSM
AXH3
RMJ
01/06/21 11:15
01/06/21 07:21
01/06/21 07:11
01/06/21 11:54
01/07/21 09:02
01/07/21 08:55
01/07/21 08:54
01/07/21 09:03
01/13/21 00:01
QC
1000
9460
1000
11.4
1.67
53.5
1.67
105
3.70
NOM Sample
1000
0.118
1.67
1.67
6.52
Range
(80%-120%)
(75%-125%)
(80%-120%)
(75%-125%)
(+/-10.0)
Qual
U
U
U
U
B
QC1204726484 531262007
QC1204726482
QC1204726481
QC1204726485 531262007
QC1204726749 531262004
QC1204726748
QC1204726747
QC1204726750 531262004
QC1204727380 531262004
N/A
N/A
55.2
REC%
94.6
113
107
105
10000
10.0
50.0
100
DUP
LCS
MB
PS
DUP
LCS
MB
MS
DUP
531262Workorder:
PO Box 1600
U
U
U
U
B ^
RPD%
Page 1 of 5
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(213 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Halogen Analysis
Ion Chromatography
2078942
2078303
Batch
Batch
Total Organic Halogens
Total Organic Halogens
Total Organic Halogens
Chloride
Fluoride
Nitrate-N
Nitrite-N
Sulfate
Chloride
Fluoride
Nitrate-N
Nitrite-N
Sulfate
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
RMJ
LXA2
01/12/21 23:18
01/12/21 22:58
01/13/21 00:43
01/05/21 20:58
01/05/21 17:53
01/05/21 20:58
01/05/21 17:53
01/05/21 20:58
01/05/21 12:10
QC
93.7
3.33
93.5
27200
262
10400
33.0
56300
4570
2250
2270
2330
9290
NOM Sample
6.52
27100
264
10400
33.0
56400
Range
(80%-120%)
(75%-125%)
(0%-20%)
(+/-500)
(0%-20%)
(0%-20%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
Qual
U
D
B
D
U
D
QC1204727379
QC1204727378
QC1204727381 531262004
QC1204726518 531262003
QC1204726399
0.322
0.647
0.168
N/A
0.0896
REC%
93.7
87
91.3
90.2
90.9
93.1
92.9
100
100
5000
2500
2500
2500
10000
LCS
MB
MS
DUP
LCS
531262Workorder:
B
D
B
D
U
D
^
RPD%
Page 2 of 5
Page 211 of 214 SDG: GEL531262 Rev1
Revision #1 12-FEB-2021GEL531262 February 16, 2021 Rev. 1
(214 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Ion Chromatography
Spectrometric Analysis
2078303
2080120
Batch
Batch
Chloride
Fluoride
Nitrate-N
Nitrite-N
Sulfate
Chloride
Fluoride
Nitrate-N
Nitrite-N
Sulfate
Total Sulfide
Total Sulfide
Total Sulfide
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
ug/L
ug/L
mg/L
Anlst Date Time
LXA2
RXB5
01/05/21 11:40
01/05/21 21:29
01/05/21 18:24
01/05/21 21:29
01/05/21 18:24
01/05/21 21:29
01/11/21 16:38
01/11/21 16:36
01/11/21 16:40
QC
67.0
33.0
33.0
33.0
133
10.4
2.57
4.50
2.51
21.3
418
33.0
0.458
NOM Sample
5.42
0.264
2.08
0.000
11.3
-0.000559
Range
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
(80%-120%)
(75%-125%)
Qual
U
U
U
U
U
D
D
D
B
U
B
QC1204726398
QC1204726519 531262003
QC1204729315
QC1204729314
QC1204729316 531262004
REC%
99.6
92.3
96.8
100
100
105
114
5.00
2.50
2.50
2.50
10.0
400
0.400
MB
PS
LCS
MB
PS
531262Workorder:
D
B
D
U
D
U
RPD%
Page 3 of 5
Page 212 of 214 SDG: GEL531262 Rev1
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(215 of 217)
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Spectrometric Analysis
Titration and Ion Analysis
2080120
2078293
Batch
Batch
Total Sulfide
Alkalinity, Total as CaCO3
Bicarbonate alkalinity (CaCO3)
Carbonate alkalinity (CaCO3)
Hydroxide alkalinity as CaCO3
Alkalinity, Total as CaCO3
Bicarbonate alkalinity (CaCO3)
Carbonate alkalinity (CaCO3)
Hydroxide alkalinity as CaCO3
Alkalinity, Total as CaCO3
Alkalinity, Total as CaCO3
Alkalinity, Total as CaCO3
Parmname Units
mg/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
RXB5
RXB5
01/11/21 16:41
01/13/21 16:39
01/13/21 16:45
01/13/21 16:36
01/13/21 16:41
01/13/21 16:47
QC
0.424
112000
112000
1450
1450
111000
111000
1450
1450
109000
221000
216000
NOM Sample
-0.000559
113000
113000
1450
1450
111000
111000
1450
1450
113000
111000
Range
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(80%-120%)
(75%-125%)
(75%-125%)
Qual
B
U
U
U
U
QC1204729319 531262004
QC1204726386 531262004
QC1204726512 531262005
QC1204726385
QC1204726387 531262004
QC1204726513 531262005
7.6
1.06
1.06
N/A
N/A
0.358
0.358
N/A
N/A
REC%
106
109
108
105
0.400
100000
100000
100000
PSD
DUP
DUP
LCS
MS
MS
531262Workorder:
U
U
U
U
U
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Parmname
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Units Anlst Date TimeQCNOM Sample RangeQual
The Qualifiers in this report are defined as follows:
REC%
531262Workorder:
<
>
B
C
D
E
N
U
X
Y
Z
Sample is below the EPA guidance level for Reactive Releasable Cyanide and/or Reactive Releasable Sulfide
Result greater than quantifiable range or greater than upper limit of the analysis range
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (as appropriate).
Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of the measuredconcentration and/or decision level for associated samples.Results are reported from a diluted aliquot of sample.
Reported value is estimated due to interferences. See comment in narrative.
Spike Sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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