Gas phase Oxidation of Hg - Amherstgis.amherstma.gov/data/springnearc2010/C_Session3_0115... ·...

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Transcript of Gas phase Oxidation of Hg - Amherstgis.amherstma.gov/data/springnearc2010/C_Session3_0115... ·...

Page 1: Gas phase Oxidation of Hg - Amherstgis.amherstma.gov/data/springnearc2010/C_Session3_0115... · 2010. 5. 21. · 3.3 17 40 3.1 2.4 Week 90.7 97.3 94 84.5 97.3 98.3 103.7 97.6 96 95.1
Page 2: Gas phase Oxidation of Hg - Amherstgis.amherstma.gov/data/springnearc2010/C_Session3_0115... · 2010. 5. 21. · 3.3 17 40 3.1 2.4 Week 90.7 97.3 94 84.5 97.3 98.3 103.7 97.6 96 95.1
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Important Reactions:

• Gas phase Oxidation of Hg0 by ozone and OH·

• Aqueous reduction of Hg2+ by sulfite (SO3

2-)

• Aqueous complexation of Hg2+ to soot, to form Hg(p)

Driscoll, C.T., D. Evers, K.F. Lambert, N. Kamman, T. Holsen, Y-J. Han, C. Chen, W. Goodale, T. Butler, T. Clair, and R. Munson. Mercury Matters: Linking Mercury Science with Public Policy in the Northeastern United States. Hubbard Brook Research Foundation. 2007. Science Links Publication. Vol. 1, no. 3.

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Driscoll, C.T., D. Evers, K.F. Lambert, N. Kamman, T. Holsen, Y-J. Han, C. Chen, W. Goodale, T. Butler, T. Clair, and R. Munson. Mercury Matters: Linking Mercury Science with Public Policy in the Northeastern United States. Hubbard Brook Research Foundation. 2007. Science Links Publication. Vol. 1, no. 3.

Page 5: Gas phase Oxidation of Hg - Amherstgis.amherstma.gov/data/springnearc2010/C_Session3_0115... · 2010. 5. 21. · 3.3 17 40 3.1 2.4 Week 90.7 97.3 94 84.5 97.3 98.3 103.7 97.6 96 95.1
Page 6: Gas phase Oxidation of Hg - Amherstgis.amherstma.gov/data/springnearc2010/C_Session3_0115... · 2010. 5. 21. · 3.3 17 40 3.1 2.4 Week 90.7 97.3 94 84.5 97.3 98.3 103.7 97.6 96 95.1
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Over 100 Sites

Measures Hg concentration in

precipitation and total weekly wet deposition

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Avg. Concentration: 3.88 ng/L

Total Wet deposition: 1798. ng/m2

Extrapolated annual deposition: 4721. ng/m2

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Mean from July 22, 2009 to March 17, 2010: 1.508 ng/m3.

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Ambient Readings at

Bunker:

~1.5 ng/m3

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Ambient Readings at

Bunker:

~1.5 ng/m3

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Extrapolated annual deposition at MDN Site: 4721. ng/m2

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HYSPLIT4

Sample Back-Trajectory

Residence Time Probability Plot (2009)

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All of August High Concentration Events

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