GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE...
Transcript of GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE...
![Page 1: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/1.jpg)
GAS CEMS
EXTRACTIVE
COLD DRY HOT WET DRY DILUTION
IN-STACK
OUT OF
STACK
IN-SITU
PROBE/ POINT
CROSS
STACK
Gaseous CEMS technology
![Page 2: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/2.jpg)
SO2
NOx
CO
CO2
Condenser
Analyzers
Output Signal to
DAS
Calibration gas supplyto analyzers
Drain
Heatedfilter
Probe(at stack)
Heated sample line
Pump
Cold Dry stack monitoring
![Page 3: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/3.jpg)
SO2
NOx
CO
O2
Analyzers
Output Signal to
DAS
Calibration gas supplyto analyzers
Heatedfilter
Probe(at stack)
Heated Sample Line
Heated Pump
Hot Extractive stack monitoring
![Page 4: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/4.jpg)
SO2
NOx
CO
Probe Controller& Sequencer
Analyzers
Output Signal
to DAS
Cal gas supply
Dilution probe
Walk-in shelter
Probe(at stack)
Unheated Tubing bundle for Dilution Air to probe, Vacuum, Calibration, Diluted sample
Scrubber FiltersPlant instrument air
or from compressor
Dryer
Extractive Dilution stack monitoring
![Page 5: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/5.jpg)
The Heated Tube is to start from the Probe and continue till the NafionDryer. There should be no Cold Spots.
Air to Nafion Drier should be moisture free – Dry.
Line should be checked and Leakage free Line should be ensured
Dry extraction- stack monitoring
![Page 6: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/6.jpg)
In-situ stack monitoring
POINT SYSTEM- IR/UV
SO2/NOx/CO/CO2/O2
SO2/ NOx/ CO/CO2/NH3
PATH SYSTEM- DOAS
NH3 / HCL / HF /CO/CO2
PATH SYSTEM- TDLS
![Page 7: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/7.jpg)
Need: Certified- zero gas, span gas, calibration gas cylinder
1. Manual Calibration:A person physically opens the Calibration cylinders and lets thegasses pass through the Analyser, and once the readings in theAnalyser has stabilised, calibration is done by correcting the drift.
2. Automatic Calibration:This is termed so that the calibration is performed by the AnalyserAutomatically. Automatic Calibration can be triggered in 2 ways-time based or by external input.
Some Analysers are equipped with calibration Cuvette (pre-filled inthe with zero and Span gases) which comes in light path.
Calibration
![Page 8: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/8.jpg)
Methods for Gaseous CEMS
> Simple Non- Dispersive Infrared (NDIR)
> Luft Detector NDIR
> Photoacoustic Detector
> Gas Filter Correlation (GFC) NDIR
> Differential Optical Absorption Spectroscopy (DOAS)
> Fourier Transform Infrared Spectroscopy (FTIR)
> Non Dispersive Ultraviolet (NDUV)
> Flame Photometric
> Chemiluminescence Analysers
> Derivative Spectroscopy
Electrochemical cells <
Conductivity Analyser
Flame Ionisation Detector (FID)
Photo Ionisation Detector (PID)
Gas Chromatography
Mass Spectrometry
Ion-Mobility Spectrometry
Potentiometric Analysis
High Temperature Electrochemical Cells
Zirconium Oxide (ZrO2)
Paramagnetic Analysers (Thermomagnetic, Differenetial Pressure, Automatic null Balance)
Electrochemical Fuel Cells
<
<
<
<
<
<
<
<
<
<
<
Optical methods Non- optical methods
![Page 9: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/9.jpg)
Methods for other Flue Gas Characteristics
Pitot tubeAveraging differential pressure probesThermal sensing systemsUltrasonic flow monitorsTime-of-flightBalance techniqueStack VenturiVortex shedding flow metersPneumatic bridge flow metersElectrodynamic cross-correlation
Non dispersive IR photometry (NDIR)Dispersive photometry in-situAutomatic psychrometry.
Thermocouples or Resistance thermometers.
Electronic pressure transducersLiquid-in-glass manometers
Flow Rate
Water Vapour
Pressure
Temperature
![Page 10: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/10.jpg)
• Flue gas characteristics: Temperature, Moisture, Dew Point, Dust content, Presence of corrosive components
• The Range of the Analyser (2.5 times of limit or 125% of maximum emission value)
• The Area Classification (Safe Area or in Zone)• Maintenance requirement of the Analyser▸ Measuring location▸ Analyzer mounting position▸ Calibration ports on the stack▸ Platform availability▸ Wall thickness of stack▸ Double- or single-walled stack▸ Coated or not coated stack▸ Stack material▸ Insulation thickness▸ Power supply▸ Signal distribution▸ Instrument air availability
Key points for Selection of analyzer
![Page 11: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/11.jpg)
Operation Options for CEMS
Rotary Kiln without co-processing
PM CEMS Insitu
FTIR based hot wet technique to measure CO, CO2, SO2, NO, NO2, (HCl)*, (HF)*, (NH3)*, VOC, H2O, etc.
(FID for THC) & O2 Analysers can be added *in-situ laser based method may be preferred for lower concentration.
Hot wet extractive gaseous CEMS Preferable as given above.
Paramagnet for O2When NOx-SNCR implanted NH3 must be measured on the stack preferably with TDLAS/ FTIR NDIR / NDUV/ FTIR for multigas analysis (SO2, NOx)
Rotary Kiln with co-processing of Wastes
PM CEMSFTIR based hot wet technique to measure CO, CO2, SO2, NO, NO2,(HCl)*, (HF)*, (NH3)*, VOC, H2O, etc. (FID for THC) & O2 Analysers can be added *in-situ laser based method may be preferred for lower concentration.
Hot wet extractive gaseous CEMS Preferable as given above.
Paramagnet for O2 When NOx-SNCR implanted NH3 must be measured on the stack preferably with TDLAS/ FTIR NDIR / NDUV/ FTIR for multigas analysis (SO2, NOx)
CEMS technology options for Cement industry
![Page 12: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/12.jpg)
CEMS: A Technical Guidance Manual
![Page 13: GAS CEMS IN-SITU EXTRACTIVEcdn.cseindia.org/userfiles/Gaseous-CEMS-Technology.pdfGAS CEMS EXTRACTIVE COLD DRY HOT WET DRY DILUTION IN-STACK OUT OF STACK IN-SITU PROBE/ POINT CROSS](https://reader033.fdocuments.in/reader033/viewer/2022053004/5f081b1c7e708231d4205da4/html5/thumbnails/13.jpg)
Industry Training on CEMS and CEQMS
Thank you