GANPAT UNIVERSITY FACULTY OF SCIENCE TEACHING AND ... · Before studying synthetic dyes, all...

GANPAT UNIVERSITY

FACULTY OF SCIENCE

TEACHING AND EXAMINATION SCHEME Programme Bachelor of Science Branch/Spec. CHEMISTRY

Semester V

Teaching scheme Examination scheme (Marks) Subject

Subject Name

Credit

Hours (per week)

Theory

Practical

Code

Lecture(DT) Practical(Lab.) Lecture(DT) Practical(Lab.) CE SEE Total CE SEE Total

L TU Total P TW Total L TU Total P TW Total

UCHA 501 Inorganic 03 - 03 - - - 03 - 03 - - - 40 60 100 - - -

IOC Chemistry

UCHA 502 Organic 03 - 03 - - - 03 - 03 - - - 40 60 100 - - -

ORC Chemistry

UCHA 503 Physical 03 - 03 - - - 03 - 03 - - - 40 60 100 - - -

PHC Chemistry

UCHA 504 Structural - 03 - 03 - - - 03 - 03 - - - 40 60 100 - - -

SAC Analytical

Chemistry

USEB 505 Synthetic Dyes 02 - 02 - - - 02 - 02 - - - 40 60 100 - - -

SYD (OR)

UENA 505 Nanomaterials

NMN and

Nanotechnology

(OR)

USEB 505 FCT Forensic

Chemistry and

Toxicology

UENA 506 ENGLISH – V 02 - 02 - - - 02 - 02 - - - 40 60 100 - - -

ENG

UPCA 507 Practical Module - - - 06 - 06 - - - 12 - 12 - - - 80 120 200

PRA – V

Total 16 - 16 06 - 06 16 - 16 12 - 12 240 360 600 80 120 200

GANPAT UNIVERSITY

FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY

Semester V Version 1.0.0.0

Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013

Subject code UCHA 501 IOC Subject Name Inorganic Chemistry

Teaching scheme Examination scheme (Marks)

(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total

L TU P TW

Credit 3 -- -- -- 3 Theory 40 60 100

Hours 3 -- -- -- 3 Practical -- -- --

Pre-requisites:

Before studying Inorganic chemistry, all students have basic knowledge of inorganic and organic compounds, periodic table, molecular structure, Molecular orbital theories and knowledge related to UG level chemistry.

Learning Outcome:

Knowledge of reactions and mechanism of coordination compounds.

Introduction and classification of organometallic compounds.

Understanding of structure and bonding in organometallic compounds.

Knowledge of principle, types and prevention of corrosion.

Theory syllabus

Unit Content Hrs

1 Reaction mechanism of coordination compounds

Substitution reaction of square planar complexes

Reaction of Platinum II complexes, the trans effect, theories of trans effect, use of

synthesis in trans effect and analysis

Substitution reaction in octahedral complexes, Possible mechanism reactions, 15 Ligand displacement reaction in octahedral complexes, acid hydrolysis, Base

Hydrolysis

Electron transfer reaction, mechanism of redox reaction, mechanism of

substitution in square planar complexes

2 Organo Metallic Compounds

Definition

Types of O.M.C.

Classification 15

Nomenclature of O.M.C

Structure and bonding in dihapto and metal olefins complexes. e.g. Ziese’s salt complexes, Ferrocene structure

O.M.C. of Li and Al complexes

3 Corrosion

Principle of corrosion

Types of corrosion 15

(i) Wet corrosion

(ii) Galvanic corrosion

(iii) Atmospheric corrosion

(iv) Pitting corrosion (v) Inter granual corrosion (vi) Dezincification

Prevention of corrosion: Inhibitors- Definition, type and use of inhibitors.

Text Books 1 Valance and molecular structure by Cartmell and Flower. 2 Text book of Inorganic Chemistry by Durent and

Durent. Reference Books 1 Inorganic Chemistry by S. Chand 2 Advance Inorganic Chemistry Vol-II Satya Prakash (S.Chand) 3 Concise Inorganic chemistry by J.D.Lee. 4 Metalic Corrosion By M.N. Desai 5 Advance Inorganic Chemistry J.E. Huhee.

GANPAT UNIVERSITY




Subject code UCHA 502 ORC Subject Name Organic Chemistry



L TU P TW

Credit 3 -- -- -- 3 Theory 40 60 100

Hours 3 -- -- -- 3 Practical -- -- --

Pre-requisites: Before studying organic chemistry, all students have basic knowledge of general organic chemistry.

Students should have the deep knowledge about the elementary organic chemistry at the UG level.

Learning Outcome: Understanding of stereochemistry and conformational analysis of various organic compounds. Knowledge of disaccharides and their structure determination. Understanding the chemistry of isoprenoids. Understanding substitution reactions at saturated carbon. Understanding the mechanism and stereochemistry of nucleophilic aliphatic substitution reactions. Introduction, types and mechanism of elimination reactions

Theory syllabus Unit Content Hrs

1 Stereochemistry

Conformational analysis of mono and di substituted cyclohexane’s

Molecular asymmetry as illustrated by allenes and diphenyls 15

Isomerism of oximes.

Determination of geometrical isomerism of Aldoxime.

Determination of geometrical isomerism of Ketoxime(Beckmann’s transformation)

2 Carbohydrates

Introduction of Disaccharides

Structure determination of 15

(1) Sucrose

(2) Maltose

(3) Lactose

Isoprenoids

Classification

General methods of structure determination

Isoprene rule

Constitution of Citral and α-Terpeneol and their synthesis

3 Nucleophilic substitution at saturated carbon atom

The reaction mechanism

Stereochemistry of nucleophilic substitution 15

Scope of nucleophilic substitution

Stereochemistry of SN1 and SN2 reaction

Relative reactivity in substitution

Solvent effect variation at carbon site

Relative leaving group activity

Neighboring group participation Competitive reactions. Elimination E1,E2 and E1cb mechanisms

Text Books

1 Organic chemistry by Morrison & Boyd Vth

Edition 2 Advance organic chemistry by R.K.Bansal.

1 Organic chemistry by I.L.Finar Vol I &.II Vth

Edition

2 Organic chemistry by pine, Hendrikson, Cram and Hammond IVth

edition... 3 Advanced organic chemistry by Jerry March.

4 Stereo chemistry: conformation and mechanism VIth

edition by P.S.Kalsi. 5 Organic chemistry of natural product Vol: I & II by Gurdeep R. Chatwal. 6 Advanced organic chemistry by Arun Bahal and B.S. Bahal. 7 Organic chemistry Vol, I, II, III by S.M.Mukherjee, S.P.Singh, R.P.Kapoor. 8 Stereo Chemistry by Nasipuri.

GANPAT UNIVERSITY




Subject code UCHA 503 PHC Subject Name Physical Chemistry



L TU P TW

Credit 3 -- -- -- 3 Theory 40 60 100

Hours 3 -- -- -- 3 Practical -- -- -- Pre-requisites:

Before learning Physical chemistry, student should aware about basic principles and theories of physical chemistry, thermodynamics, solutions, electrochemical cells, polymers and other UG level chemistry.

Learning Outcome: Understanding of electromotive force and related phenomena. Knowledge of statistical thermodynamics and partition function.

Understanding of macromolecules and their chemistry. Knowledge of determination of molecular masses of macromolecules.


1 Electro Motive Force

Chemical Cell: Without Transference with Transference Verification of

Concentration cell and it’s EMF equation.

Electrolyte concentration cell

Concentration cell without transference, Concentration cell with transference

Electrode concentration cell

Amalgam concentration cell, Gas Concentration Cell 15

Liquid –Liquid junction potential

Application of EMF measurements Determination of

Degree of hydrolysis of salt

Solubility of sparingly soluble salt

Stability constant of complex,

Dissociation constant of weak acid,

Numerical

2 Statistical Thermodynamics

Introduction

Combination and permutation

Probability

Sterling approximate formula (No Derivation) 15 Type of Statistics - Maxwell-Boltzmann

- Bose-Einstein Statistics

- Fermi-Dirac Statistics

Partition Function - Transnational Partition function

- Rotational Partition function

- Vibrational Partition function

Numerical

3 Macromolecules

Classification of Polymers

Tactility of polymers. ( Optical Isomers)

Polymerization reaction with example

- Addition Polymerization. ( Polyethylene, Polystyrene, PVC)

- Condensation Polymerization (Nylon-66, Dacron)

Mechanisms of Polymerization - Free radical chain Polymerization

- Anionic Polymerization

- Cationic Polymerization 15

Kinetics of Free radical chain Polymerization

Degree of Polymerization

Molar masses of Polymer - Number Average Molar Mass

- Weight Average Molar Mass

Determination of Molar Masses of Macro Molecules

- Viscosity Method

- Light Scattering Method

- Numerical

Text Books

1 Advance Physical Chemistry by Gurdeepraj.

2 Physical Chemistry (Question and Answer) by R. N. Madan, G.D. Tuli, S.Chand.

Reference Books

1 Principal of Physical Chemistry by Puri, Sharma, Pathania.

2 Chemical Thermodynamics by R.P. Rastogi and R.R.Mishra.

3 Physical chemistry by atkins.

4 Essentials of Physical Chemistry by B. S. Bahal, Arun Bahal, G.D.Tuli,

5 Physical Chemistry by P.W. Atkins, 5th

edn, Oxford 1994 7th

edn-2002.

6 Physical Chemistry by R.A. Albern and R.J.Silby, John Wiley 1995.

7 Physical Chemistry by G.H. Barrow, 5th

edn, Mac Graw Hill, 1988,6th

edn, 1996.

8 Physical Chemistry by W.J.Moore, 4th

edn, Orient Longmans 1969.

GANPAT UNIVERSITY




Subject code UCHA 504 SAC Subject Name Structural Analytical Chemistry



L TU P TW

Credit 3 -- -- -- 3 Theory 40 60 100

Hours 3 -- -- -- 3 Practical -- -- --

Pre-requisites:

Before learning analytical chemistry, student should aware about basic principles and theories of analytical chemistry, basics of spectroscopy, basics of volumetric analysis, and other UG level chemistry.

Learning Outcome:

Concept of symmetry and group theory.

Knowledge of point groups and multiplication tables.

Introduction, principle and applications of NMR spectroscopy.

Principle and applications of acid-base titration.

Theory syllabus

Unit Content Hrs

1 Symmetry of molecules

Symmetry elements & symmetry operations

Multiplications of symmetry operations

Multiplication table for C2v, C3v, C2h point groups only 15

Classification of schoonflies point groups

Determination of schoonflies point groups natations

Symmetry & optical activity

Symmetry property of orbital’s for C2v, C3v, C2h point groups

2 NMR spectroscopy

Introduction

Proton magnetic resonance (1H NMR) spectroscopy

Equivalent and non equivalent protons

Nuclear shielding & de-shielding

Chemical shift & molecular structure 15

Spin-spin splitting and coupling constant

Intensity of signal, Simplification of complex spectra

Interpretations of PMR spectra

Simple organic molecule such as ;

(1) Ethyl bromide (2) Ethanol (3) Acetaldehyde (4) 1,1,2-Try bromo ethane

(5) Ethyl acetate (6) Toluene (7) Acetophenone (8) Iso propyl Benzene (9) Acetic acid

(10) Phenitol

Numericals

3 Acid- base titration

Construction of titration curves

Feasibility of titration of poly protic acid Analysis of mixture of acid & base 15 Differential titration of alkalis

Gran’s plot

Buffers , buffer level , buffer range & buffer capacity

Text Books 1 Chemical application of group theory by F.A.Cotton 2 Chemical bonding and introduction by K.C.Patel, R.D.Patel and Raval

1 Application of group theory to chemistry by Bhattacharya 2 Symmetry in chemistry by Jafle and Orchin 3 Advance inorganic chemistry by cotton & Wilkinson 4 Basic principles of spectroscopy by R.Chand 5 Organic chemistry Vol. 1 by S.M.Mukherji, S.P.Shingh, Kapoor 6 Spectroscopy organic compounds VIth edition by P.S.kalsi 7 Organic chemistry by Morrison and Boyd 8 Spectrometric identification of organic compounds IVth edition by Silverstain, Bassler and Morrill. 9 Application of absorption spectroscopy of organic compounds by John R. Dyer

10 Spectroscopic method in organic chemistry Vth edition by Dudley H. Williams & Ian Fleming 11 Physical methods for chemist Ruwssell S. Drago 12 Organic spectroscopy by Williams & Kemp 13 Organic spectroscopy by V.R.Dani 14 Qualitative Analysis R.A.Day & A.L.Underwood 15 Analytical Chemistry G.D. Christain 16 Fundamentals of Analytical Chemistry D.A.Skoog, D.M. West & F.J.Holler 17 Principales of Analytical Chemistry J.H. Kennedy 18 Analytical Chemistry – Principals & Techniques L.G.Hargis

GANPAT UNIVERSITY



Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013 Subject code USEB 505 SYD Subject Name Synthetic Dyes


(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total L TU P TW

Credit 2 -- -- -- 2 Theory 40 60 100

Hours 2 -- -- -- 2 Practical -- -- --

Pre-requisites:

Before studying synthetic dyes, all students have basic knowledge of general organic chemistry and synthetic chemistry.

Students should have the deep knowledge about the elementary organic chemistry at the UG level.

Learning Outcome:

Introduction and classification of dyes.

Understanding of the terms related to colour and dyes.

Knowledge of Synthesis and applications of various dyes.

Theory syllabus

Unit Content Hrs

1 Introduction

Synthetic Dyes

Chromophores, Chromogens, Auxochrome, Bathochromic shift, Hypochromic shift

Difference between Dyes and Pigments 15

Classification of Dyes

- According to constitution

- According to method of coloring the fibres

Optical Brightners

2 Synthesis and uses

Congo Red

Eosin

Alizarin

Crystal violet

Indigo 15

Sefronine –T

Methylene Blue

Ereochrom Black –T

Rhodamine

Rosanilin

Text Books

1 Synthetic Dyes by Venkatramanan

2 Synthetic Dyes by G.R.Chatwal

Reference Books

1 Synthetic Dyes and Drugs by O.P.Agrawal 2 Synthetic Dyes by O. D. Tyagi & M. Yadav 3 Sanshlesit Rangako, Granth Nirman Board

GANPAT UNIVERSITY



Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013 Subject code UENA506NMN Subject Nanomaterials and Nanotechnology

Name



Credit 2 -- -- -- 2 Theory 40 60 100 Hours 2 -- -- -- 2 Practical -- -- --

Pre-requisites: Before studying nanomaterials and nanotechnology, all students have basic knowledge of general

chemistry, structural chemistry and spectroscopy.

Learning Outcome:

Knowledge of preparation of nanomaterials.

Analysis of nanomaterials.

Knowledge of SEM, STM and TEM techniques.

Understanding the use of XRD, Auger emission spectroscopy and STM techniques.

Applications of nanomaterials.

Theory syllabus

Unit Content Hrs

1 Introduction and preparation 15 Introduction to Nanomaterials, Optical, magnetic and chemical properties of

Nanomaterials,

Preparation of Nanoparticles: Chemical Approaches: Chemical reduction;

Sonochemical

Synthesis; Sol-Gel Synthesis; Self-assembly. Physical Approaches: Aerosol spray;

Gas

Condensation; Laser vaporization and Vapour deposition; Sputtering.

Characterization techniques for Nanomaterials-I

Particle size Analyzer (Laser scattering), Optical Microscopy: Scanning Electron

Microscopy

(SEM), Transmission Electron Microscopy (TEM), Scanning Tunnel Microscopy

(STM).

2 Characterization techniques for Nanomaterials-II 15 X-ray Diffraction (XRD), Auger Emission Spectroscopy, Electron Spectroscopy for

Chemical analysis (ESCA)

Application of Nanomaterials:

Applications Solar energy conversion and catalysis, Polymers with a special

architecture, Liquid crystalline systems, Applications in displays and other devices,

Advanced organic materials for data storage, Photonics, Chemical and biosensors,

Nan medicine and Nan biotechnology.

Reference Books

1 Introduction to Nanotechnology: Charles P. Poole, Jr. and Frank J. Owens; Wiley Student Edition, 2008

2 Nanobiotechnology, Concepts, Applications and perspectives: C. M. Niemeyer and C. A.

Mirkin,WILEY-VCH, Verlag GmbH & Co, 2004.

3 Nanostructures and Nanomaterials: Synthesis, Properties and Applications: G. Cao, ICP,

London, 2004

4 Nanotechnology - Molecularly Designed Materials: G. M. Chow and K. E. Gonslaves;

(American chemical society)

5 Optical Properties of semiconductor nanocrystals: S. P. Gaponenko, Cambridge University

Press,1980.

6 Nanostructures & Nanomaterials: Synthesis, Properties & Applications: G. Cao, Imperial

College Press, 2004.

7 Nano - The essentials: T. Pradeep, Tata Mc Graw Hill, New Delhi, 2007.

8 Nano materials: J. Dutta & H. Hofman.

9 “NANOTECHLOGY-basic science and emerging technologies: Mick Wilson, Kamali

Kannagara et.al., University of new south wales press ltd,2008.

10 Nanotechnology: Mark Ratner and Daniel Ratner, Pearson Education.

11 Nanomaterials: A.K. Bandyopadhyay; New Age International Publishers.

GANPAT UNIVERSITY




Subject code USEB 505 FCT Subject Name Forensic Chemistry and Toxicology



Credit 2 -- -- -- 2 Theory 40 60 100

Hours 2 -- -- -- 2 Practical -- -- --

Pre-requisites:

Before studying forensic chemistry, all students have basic knowledge of general organic, analytical and inorganic chemistry.

Learning Outcome:

Understanding the chemistry of forensic science.

Understanding the analysis of forensic chemicals.

Understanding the roll of police and forensic scientist.

Theory syllabus

Unit Content Hrs

1 Introduction of Forensic science, Law, Crime 15 Introduction Definition, and Scope of Forensic Science

History and development, Needs and Principles

Police and Forensic sciences Laboratory

Definition, Theories and Prevention of Crime

Structure of Police, Police & Forensic Scientist

Relationship with reference to Crime Investigation

2 Forensic Chemistry & Toxicology 15 Introduction of Forensic chemistry

Types of cases received for analysis

Overview of Forensic chemical analysis

Forensic analysis of Beverages

- Alcoholic Beverages (Alcohol, Chloroform)

- Non-Alcoholic Beverages

Examination of Chemicals (Phenolphthalein) used in Bribe Trap cases

Analysis of Adulterated Food

Introduction of Toxicology

Classification of Toxicology

Extraction of Poisons

Analysis of Poisons

Reference Books

1 Forensic science in criminal investigation and trials, 4th

edition by Dr.B.R.Sharma, Universal

law Publishing co. pvt. ltd.

GANPAT UNIVERSITY



Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013 Subject code UENA506ENG Subject Name ENGLISH – V



Credit 2 -- -- -- 2 Theory 40 60 100 Hours 2 -- -- -- 2 Practical -- -- --

Pre-requisites: Students should have basic knowledge of English Language and grammar. Students should have ability to speak and write correct sentences in their day to day language.

Students should be familiar with correct usage of language.

Learning Outcome: Development of presentation skills and personality development. Drafting of advertisements for various purpose. Development of communication skills.


1 Great Expectations by Charles Dickens 08

2 Great Expectations by Charles Dickens 08

3 Presentation Skills & Personality Building 09

Finding out about Environment,

Preparing Text,

Element of body language,

Use of Visual Aids in Presentation

Grooming etiquettes

Avoiding boredom factors in a presentation

4 Drafting an advertisement 05

Essentials of drafting an advertisement

Advertisement for Job Recruitment

Advertisement Marketing a Product

Reference Books

1 Great Expectations by Charles Dickens

2 Business Communication by Urmila Rai & S. M. Rai

3 Business Communication by Rodha Doctor and Aspi Doctor

GANPAT UNIVERSITY



Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013 Subject code UPCA 507 PRA Subject

Practical Module-V

Name



Credit -- -- 6 -- 6 Theory -- -- -- Hours -- -- 12 -- 12 Practical -- 200 200

Pre-requisites:

Before performing these practicals, students have basic knowledge of laboratory chemicals, organic and inorganic compounds and their properties, chemical kinetics and conductometry, apparatus and

instruments which are used in performing chemistry practicals.

Learning Outcome:

Practical knowledge of determination of metals using gravimetric and volumetric analysis.

Synthesis of various inorganic compounds.

Separation and qualitative analysis of organic compounds.

Conductometric titrations and colorimetric estimations.

Determination of order of reactions.

Practical syllabus

Inorganic Chemistry Practical

(A) Alloy (Minimum three)

1) Brass alloy ------- Zn (Gravimetric) and Cu (Volumetric)

2) German silver alloy ------Ni (Gravimetric) and Cu (Volumetric)

3) Bronze alloy ------Sn (Gravimetric) and Cu (Volumetric)

(B) Synthesis by convention method (Minimum Seven)

1) Ferrous Sulphate or Green vitriol (FeSO4 7H2O)

2) Sodium cobaltinitrate Na3 [Co(NO2)6] 3) Tetra amine cupric Sulphate

4) Hexa thio urea plumbous nitrate

5) Cuprous chloride

6) Tetra oxalato Ferrate

7) Tetra oxalato Chromate

8) Sodium Thio Sulphate from Na2SO3

Organic Chemistry Practical

Qualitative Analysis (Minimum 10)

Analysis of an organic mixture containing two components using water, NaHCO3, NaOH, HCl for

Separation /or using distillation process for separation and identification with the Preparation of Suitable derivatives.

Soluble Components:- Oxalic Acid, Succinic Acid, Resorcinol, Urea, Thio Urea Separation of two components from Organic Mixture Such as…. Solid-Solid ------Mixture

Solid- Liquid -------Mixture Liquid-Liquid ------ Mixture [Liquid component must be neutral in nature]

Physical Chemistry Practical

[A] Instruments: (Minimum 06)

1. To determine normality and amount of HCl and CH3COOH in the given solution by Conductometry titration against 0.2N (exact) NaOH solution.

2. To determine the solubility product and solubility of sparingly soluble

salts PbSO4 by Conductometry. 3. To determine Normality and amount of each acid in the given

mixture of HCl + CH3COOH by pH metrically. 4. To determine the strength of strong and weak acid in a given mixture by

Potentiometric titration using 0.1 N NaOH 5. To determine the concentration of Nickel in the given solution by Colorimetric estimation.

6. To determine the concentration of unknown solution from given KMnO4 solution by Calorimetry. [B] Kinetics & Distributions: (Minimum 04) 7. To determine the order of the reaction between K2S2O8 and KI. 8. To determine the order of the reaction between H2O2 and HI. 9. To determine the distribution coefficient of Iodine between CCl4/CHCl3.& water at a given temperature. 10. To study the distribution of Benzoic acid between Benzene and water at room temperature and prove

the dimerization of Benzoic acid in Benzene.

GANPAT UNIVERSITY FACULTY OF SCIENCE TEACHING AND ... · Before studying synthetic dyes, all...

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