G 1 Geology of Petroleum Systems

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    Geology ofPetroleum Systems

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    Petroleum Geology

    Objectives are to be able to:

    Discuss basic elements of Petroleum Systems Describe plate tectonics and sedimentary basins

    Recognize names of major sedimentary rock types Describe importance of sedimentary environmentsto petroleum industry

    Describe the origin of petroleum

    Identify hydrocarbon trap types Define and describe the important geologic

    controls on reservoir properties, porosity and

    permeability

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    Outline

    Petroleum Systems approach Geologic Principles and geologic time Rock and minerals, rock cycle, reservoir

    properties Hydrocarbon origin, migration and

    accumulation

    Sedimentary environments and facies;stratigraphic traps

    Plate tectonics, basin development, structuralgeology

    Structural traps

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    Petroleum System - A Definition

    A Petroleum System is a dynamic hydrocarbonsystem that functions in a restricted geologic

    space and time scale.

    A Petroleum System requires timely

    convergence of geologic events essential tothe formation of petroleum deposits.

    These Include:

    Mature source rock

    Hydrocarbon expulsionHydrocarbon migrationHydrocarbon accumulationHydrocarbon retention

    (modified from Demaison and Huizinga, 1994)

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    In order to have a commercial hydrocarbon

    prospect, several requirement must be met.There must be

    (1) a hydrocarbon source,

    (2) a reservoir rock, and

    (3) a trap

    Moreover, the relative time at which these

    features developed is important.

    The systematic assessment of these parameterand their affect on hydrocarbon occurrence is

    known as aPetroleum Systems approach to oil

    and gas evaluation.

    Petroleum Systems

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    Cross Section Of A Petroleum System

    Overburden Rock

    Seal Rock

    Reservoir Rock

    Source Rock

    Underburden Rock

    Basement Rock

    Top Oil Window

    Top Gas Window

    Geographic Extent of Petroleum System

    Petroleum Reservoir (O)

    Fold-and-Thrust Belt

    (arrows indicate relative fault motion)

    Essential

    Elements

    of

    Petroleum

    System

    (Foreland Basin Example)

    (modified from Magoon and Dow, 1994)

    O O

    Sed

    imentary

    BasinFill

    O

    Stratigraphic

    Extent ofPetroleum

    System

    Pod of Active

    Source Rock

    Extent of Prospect/FieldExtent of Play

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    This cross section shows the elements of a PetroleumSystem.

    Potential reservoir sandstones (yellow), deposited at thebasin margin, intertongue to the left with organic-rich sourcerocks.

    Owing to the increasing temperature with depth, the sourcerocks are mature for gas in the deep basin.

    Below the oil window, the source rocks are generating oil. Hydrocarbons migrate up the flank of the basin and

    accumulate in a trap (structural).

    The layer overlying the reservoir is a low-permeability seal. Inorder to have a commercial field/ prospect, the trap mustform prior to hydrocarbon migration, and the trap must have

    maintained its integrity.

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    Basic Geologic Principles

    Uniformitarianism Original Horizontality

    Superposition Cross-Cutting Relationships

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    The following are basic principles or laws are used to evaluate the

    relative ages and the relations among rock layers.

    Uniformitarianism -The present is the key to the past. Bystudying modern geologic processes, we can interpret pastgeologic events and rock-forming processes.

    Original Horizonality- Sedimentary layers are deposited ina horizontal or nearly horizontal position. If sedimentary

    layers are tilted or folded, they have been subjected todeforming stresses.

    Superposition- Younger sedimentary beds occur on top ofolder beds, unless they have been overturned or faulted.

    Cross-Cutting Relations- Any geologic feature that cutsanother geologic feature is younger than the feature that it

    cuts.

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    Cross-Cutting Relationships

    Angular Unconformity

    A

    B

    C

    D

    E

    F

    G

    HIJ

    K

    IgneousDike

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    Law of cross-cutting relationships.

    In the figure above, the igneous dike (F) is younger

    than layers A-E but older than layer G, because ageologic feature is younger than any other geologic

    feature that it cuts.

    This is an important law for determining the relativeages of geologic features.

    According to the Law of Superposition,layer I is

    older than layer J, and the rocks beneath the

    unconformity are older from left to right.

    From the Principle of Original Horizonality, we

    infer that layers A through F have been

    deformed.

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    Disconformity An unconformity in which the beds above and below

    are parallel

    Angular Unconformity An unconformity in which the older bed intersect the

    younger beds at an angle

    Nonconformity An unconformity in which younger sedimentaryrocks overlie older metamorphic or intrusive

    igneous rocks

    Types of Unconformities

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    Sedimentary rock are deposited in successivelayers that record the history of their time,

    much like the pages in history book. However, the rock record is never complete. Missing layers (gaps in time) result in

    unconformities. An unconformity is a surface of non-deposition

    or erosion that separates younger rocks from

    older rocks. The previous slide shows an angular

    unconformity.

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    Correlation

    Establishes the age equivalence of rocklayers in different areas

    Methods: Similar lithology

    Similar stratigraphic section

    Index fossils

    Fossil assemblages Radioactive age dating

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    0

    50

    100

    150

    200

    250

    300

    350

    400

    450

    500

    550

    600

    0

    10

    20

    30

    40

    50

    60

    Cry

    ptozoic

    (Prec

    ambrian)

    Phanerozoic

    Quaternary

    Tertiary

    Cretaceous

    Jurassic

    Triassic

    Permian

    Pennsylvanian

    Mississippian

    Devonian

    Silurian

    Ordovician

    Cambrian

    Millions

    ofyearsago

    Million

    sofyearsago

    Billion

    sofyearsago

    0

    1

    2

    3

    4

    4.6

    Paleocene

    Eocene

    Oligocene

    Miocene

    Pliocene

    Pleistocene

    Recent

    Quaternary

    pe

    riod

    Tertiary

    period

    Eon Era Period Epoch

    Geologic Time Chart

    Pale

    ozoic

    Mesozoic

    C

    enozoicEra

    Initially, the geologic time scale was

    developed on the basis of relativegeologic ages, using fossil assemblages

    and the laws of superposition, cross-

    cutting relations, etc. Subsequently,

    absolute ages were assigned to the timescale on the basis of radioactive dating.

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    Rocks

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    Classification of Rocks

    SEDIMENTARY

    Rock-forming

    process

    Sourceof

    material

    IGNEOUS METAMORPHIC

    Molten materials in

    deep crust and

    upper mantle

    Crystallization

    (Solidification of melt)

    Weathering and

    erosion of rocks

    exposed at surface

    Sedimentation, burial

    and lithification

    Rocks under high

    temperatures

    and pressures in

    deep crust

    Recrystallization due to

    heat, pressure, or

    chemically active fluids

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    The Rock Cycle

    Magma

    Metamorphic

    Rock

    SedimentaryRock

    Igneous

    Rock

    Sediment

    Heat and Pressure

    Weathering,Transportationand Deposition

    a

    n

    i

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    Siltstone, mudand shale

    ~75%

    Sedimentary Rock Types

    Relative abundanceSandstone

    and conglomerate

    ~11%

    Limestone and

    dolomite

    ~13%

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    Quartz Crystals

    Naturally OccurringSolid

    Generally Formed byInorganic Processes

    Ordered InternalArrangement of Atoms(Crystal Structure)

    Chemical Compositionand Physical PropertiesFixed or Vary WithinA Definite Range

    Minerals - Definition

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    Average Detrital Mineral

    Composition of Shale and Sandstone

    Mineral Composition Shale (%) Sandstone (%)

    Clay Minerals

    Quartz

    Feldspar

    Rock Fragments

    Carbonate

    Organic Matter,Hematite, andOther Minerals

    60

    30

    4

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    The Physical and Chemical Characteristics

    of Minerals Strongly Influence theComposition of Sedimentary Rocks

    Quartz

    Feldspar

    Calcite

    Mechanically and Chemically Stable

    Can Survive Transport and Burial

    Nearly as Hard as Quartz, but

    Cleavage Lessens Mechanical Stability

    May be Chemically Unstable in Some

    Climates and During Burial

    Mechanically Unstable During Transport

    Chemically Unstable in Humid Climates

    Because of Low Hardness, Cleavage, and

    Reactivity With Weak Acid

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    Some Common Minerals

    Silicates

    Oxides Sulfides Carbonates Sulfates Halides

    Non-Ferromagnesian(Common in Sedimentary Rocks)

    Anhydr i teGypsum

    HaliteSylvi te

    Aragoni teCalciteDolomiteFe-DolomiteAnker i te

    Pyr i teGalenaSphaler i te

    Ferromagnesian(not common in sedimentary rocks)

    HematiteMagnet i te

    QuartzMuscovite (mica)Feldspars

    Potassium feldspar (K-spar)OrthoclaseMicroc l ine, etc.

    PlagioclaseAlbi te (Na-r ich - common) throughAno rth i te (Ca-r ich - not common)

    OlivinePyroxene

    AugiteAmphibole

    HornblendeBiotite (mica)

    Red = Sedimentary Ro ck-Forming Minerals

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    The Four Major Components

    Framework Sand (and Silt) Size Detrital Grains

    Matrix Clay Size Detrital Material

    Cement Material precipitated post-depositionally,

    during burial. Cements fill pores and replaceframework grains

    Pores

    Voids between above components

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    Norphlet Sandstone, Offshore Alabama, USA

    Grains are About =< 0.25 mm in Diameter/Length

    PRF KF

    P

    KF = PotassiumFeldspar

    PRF = Plutonic RockFragment

    P = Pore

    Potassium Feldspar isStained Yellow With a

    Chemical Dye

    Pores are ImpregnatedWith Blue-Dyed Epoxy

    CEMENT

    Sandstone Composition

    Framework Grains

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    Scanning Electron Micrograph

    Norphlet Formation, Offshore Alabama, USA

    Pores Provide the

    Volume to ContainHydrocarbon Fluids

    Pore Throats Restrict

    Fluid Flow

    Pore

    Throat

    Porosity in Sandstone

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    Secondary Electron Micrograph

    Jurassic Norphlet SandstoneHatters Pond Field, Alabama, USA (Photograph by R.L. Kugler)

    Illite

    SignificantPermeabilityReduction

    NegligiblePorosityReduction

    Migration ofFines Problem

    High IrreducibleWater Saturation

    Clay Minerals in Sandstone Reservoirs

    Fibrous Authigenic Illite

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    Secondary Electron Micrograph

    Jurassic Norphlet Sandstone

    Offshore Alabama, USA (Photograph by R.L. Kugler)

    Occurs as ThinCoats on DetritalGrain Surfaces

    Occurs in SeveralDeeply BuriedSandstones WithHigh ReservoirQuality

    Iron-RichVarieties ReactWith Acid

    ~ 10 m

    Clay Minerals in Sandstone Reservoirs

    Authigenic Chlorite

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    Secondary Electron Micrograph

    Carter SandstoneNorth Blowhorn Creek Oil Unit

    Black Warrior Basin, Alabama, USA

    Significant PermeabilityReduction

    High Irreducible WaterSaturation

    Migration of FinesProblem

    (Photograph by R.L. Kugler)

    Clay Minerals in Sandstone Reservoirs

    Authigenic Kaolinite

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    100

    10

    1

    0.1

    0.01 0.01

    0.1

    1

    10

    100

    1000

    2 6 10 14 2 6 10 14 18

    Pe

    rmeability(m

    d)

    Porosity (%)

    Authigenic Illite Authigenic Chlorite

    (modified from Kugler and McHugh, 1990)

    Effects of Clays on Reservoir Quality

    I fl f Cl Mi l

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    Dispersed Clay

    Clay Lamination

    Structural Clay(Rock Fragments,

    Rip-Up Clasts,Clay-Replaced Grains)

    fe

    fe

    fe

    ClayMinerals

    Detrital QuartzGrains

    Influence of Clay-Mineral

    Distribution on Effective Porosity

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    Diagenesis

    CarbonateCemented

    OilStained

    Diagenesis is the Post-Depositional Chemical andMechanical Changes thatOccur in Sedimentary Rocks

    Some Diagenetic Effects IncludeCompactionPrecipitation of CementDissolution of Framework

    Grains and Cement

    The Effects of Diagenesis MayEnhance or Degrade ReservoirQuality

    Whole Core

    Misoa Formation, Venezuela

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    Fluids Affecting Diagenesis

    Precipitation

    Subsidence

    CH4,CO2,H2S

    Petroleum

    Fluids

    Meteoric

    Water

    MeteoricWater

    COMPACTIONAL

    WATER

    EvapotranspirationEvaporation

    Infiltration

    Water Table

    Zone of abnormal pressure

    Isotherms

    (modified from from Galloway and Hobday, 1983)

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    Thin Section Micrograph - Plane Polarized Light

    Avile Sandstone, Neuquen Basin, Argentina

    Dissolution of

    Framework Grains

    (Feldspar, for

    Example) and

    Cement may

    Enhance the

    Interconnected

    Pore System

    This is CalledSecondary Porosity

    Pore

    Quartz Detrital

    Grain

    Partially

    Dissolved

    Feldspar

    (Photomicrograph by R.L. Kugler)

    Dissolution Porosity

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    Hydrocarbon Generation,

    Migration, and Accumulation

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    Organic Matter in Sedimentary Rocks

    Reflected-Light Micrograph

    of Coal

    Vitrinite

    Kerogen

    Disseminated Organic Matter inSedimentary Rocks That is Insolublein Oxidizing Acids, Bases, andOrganic Solvents.

    VitriniteA nonfluorescent type of organic materialin petroleum source rocks derivedprimarily from woody material.

    The reflectivity of vitrinite is one of the

    best indicators of coal rank and thermalmaturity of petroleum source rock.

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    Interpretation of Total Organic Carbon (TOC)

    (based on early oil window maturity)HydrocarbonGenerationPotential

    TOC in Shale(wt. %)

    TOC in Carbonates(wt. %)

    Poor

    Fair

    Good

    Very Good

    Excellent

    0.0-0.5

    0.5-1.0

    1.0-2.0

    2.0-5.0

    >5.0

    0.0-0.2

    0.2-0.5

    0.5-1.0

    1.0-2.0

    >2.0

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    Schematic Representation of the Mechanism

    of Petroleum Generation and Destruction

    (modified from Tissot and Welte, 1984)

    Organic Debris

    Kerogen

    Carbon

    Initial Bitumen

    Oil and Gas

    Methane

    Oil Reservoir

    MigrationThermal Degradation

    Cracking

    Diagenesis

    Catagenesis

    MetagenesisProgre

    ssiveBurialan

    dHeating

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    Incipient Oil Generation

    Max. Oil Generated

    Oil Floor

    Wet Gas Floor

    Dry Gas Floor

    Max. Dry GasGenerated

    (modified from Foster and Beaumont, 1991, after Dow and OConner, 1982)

    VitriniteReflectance(Ro

    )%

    Weight%

    CarboninKero

    gen

    SporeColo

    rationIndex(S

    CI)

    Pyr

    olysisT

    (C)

    max

    0.2

    0.3

    0.40.5

    4.0

    3.0

    2.0

    1.3

    1

    2

    3

    4

    56

    789

    10

    430

    450

    465

    65

    70

    75

    80

    85

    90

    95

    0.60.70.80.91.01.2

    OIL

    WetGas

    DryGas

    Comparison of Several Commonly Used

    Maturity Techniques and Their Correlation

    to Oil and Gas Generation Limits

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    Reservoirrock

    Seal

    Migration route

    Oil/watercontact (OWC)

    Hydrocarbonaccumulation

    in thereservoir rock

    Top of maturity

    Source rock

    Fault(impermeable)

    Generation, Migration, and

    Trapping of Hydrocarbons

    C S ti Of A P t l S t

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    Cross Section Of A Petroleum System

    Overburden Rock

    Seal Rock

    Reservoir Rock

    Source Rock

    Underburden Rock

    Basement Rock

    Top Oil Window

    Top Gas Window

    Geographic Extent of Petroleum System

    Petroleum Reservoir (O)

    Fold-and-Thrust Belt

    (arrows indicate relative fault motion)

    Essential

    Elements

    of

    Petroleum

    System

    (Foreland Basin Example)

    (modified from Magoon and Dow, 1994)

    O O

    Sedimentary

    B

    asinFill

    O

    Stratigraphic

    Extent ofPetroleum

    System

    Pod of Active

    Source Rock

    Extent of Prospect/FieldExtent of Play

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    Hydrocarbon Traps

    Structural traps

    Stratigraphic traps

    Combination traps

    Structural Hydrocarbon Traps

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    Structural Hydrocarbon Traps

    Salt

    Diapir

    Oil/Water

    Contact

    GasOil/Gas

    Contact

    Oil

    ClosureOilShale Trap

    Fracture Basement

    (modified from Bjorlykke, 1989)

    Fold Trap

    Oil

    Salt

    Dome

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    Anticlinal Theory

    Gas

    Oil

    Water

    Petroleum Accumulates in Structural Closure

    Tar sand near Redden Oklahoma (Atoka County)

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    Oil

    Sandstone Shale

    Hydrocarbon Traps - Dome

    Gas

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    Fault Trap

    Oil / Gas

    Stratigraphic Hydrocarbon Traps

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    Oil/Gas

    Oil/Gas

    Oil/Gas

    Stratigraphic Hydrocarbon Traps

    Uncomformity

    Channel Pinch Out

    (modified from Bjorlykke, 1989)

    Unconformity Pinch out

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    AsphaltTrap

    Water

    Meteoric

    Water

    Biodegraded

    Oil/Asphalt

    Partly

    Biodegraded Oil

    Hydrodynamic Trap

    Shale

    Oil

    Water

    Hydrostatic

    Head

    (modified from Bjorlykke, 1989)

    Other Traps

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    Heterogeneity

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    Reservoir Heterogeneity in Sandstone

    Heterogeneity May

    Result From:

    Depositional Features

    Diagenetic Features

    (Whole Core Photograph, Misoa

    Sandstone, Venezuela)

    Heterogeneity

    Segments Reservoirs

    Increases Tortuosity of

    Fluid Flow

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    Reservoir Heterogeneity in Sandstone

    Heterogeneity Also May

    Result From:

    Faults

    Fractures

    Faults and Fractures may

    be Open (Conduits) or

    Closed (Barriers) to Fluid

    Flow

    (Whole Core Photograph, Misoa

    Sandstone, Venezuela)

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    Bounding

    Surface

    Bounding

    Surface

    Eolian Sandstone, Entrada Formation, Utah, USA

    Geologic Reservoir Heterogeneity

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    Scales of Investigation Used inReservoir Characterization

    Gigascopic

    Megascopic

    Macroscopic

    Microscopic

    Well Test

    Reservoir ModelGrid Cell

    Wireline LogInterval

    Core Plug

    GeologicalThin Section

    Relative Volume

    1

    1014

    2 x 1012

    3 x 107

    5 x 102

    300 m

    50 m

    300 m

    5 m 150 m

    2 m

    1 m

    cm

    mm - m

    (modified from Hurst, 1993)

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    Stages In The Generation ofAn Integrated Geological Reservoir Model

    Log AnalysisWell Test Analysis

    Core Analysis

    Regional GeologicFramework

    DepositionalModel

    DiageneticModel

    IntegratedGeologic Model

    Applications Studies

    Model TestingAnd Revision

    StructuralModel

    FluidModel

    (As Needed)

    (As Needed)

    Geologic Activities

    Reserves EstimationSimulation