Full Kagetec MSDS - Kagetec Industrial Flooring

SAFETY DATA SHEET according to EC directive 2001/58/EC

Ethanol 96 vg. 1 % MEK Version 1.1 Print Date 13.06.2008 Revision Date 26.04.2006

R3769 1/7 EN

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information Trade name : ETHANOL 96 VG. 1 % MEK Supplier : Brenntag GmbH

Stinnes-Platz 1 DE 45472 Muelheim an der Ruhr

Responsible Department : Einkauf Technik Sicherheit (ETS) Telephone : +49 (0)208-7828-0 Telefax : +49 (0)208-7828-7299 Emergency telephone number

: +49 (0)208-7828-0

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature Preparation consisting of the following components:

Hazardous components ethanol Concentration: >= 95,00 % CAS-No.: 64-17-5 EC-No.: 200-578-6 Index-No.: 603-002-00-5 Classification: F; R11 butanone Concentration: < 2,50 % CAS-No.: 78-93-3 EC-No.: 201-159-0 Index-No.: 606-002-00-3 Classification: F; R11 Xi; R36 R66 R67 For the full text of the R phrases mentioned in this Section, see Section 16.

3. HAZARDS IDENTIFICATION

Risk advice to man and the environment F R11 Highly flammable.

Other information The product is classified and labelled in accordance with EC directives or respective national laws.

4. FIRST AID MEASURES

General advice : Remove victim from exposure, lie down. Take off all contaminated clothing immediately.

Inhalation : Move to fresh air. Oxygen, if needed. Skin contact : Wash off immediately with plenty of water. If skin irritation



R3769 2/7 EN

persists, call a physician. Eye contact : Rinse immediately with plenty of water, also under the eyelids,

for at least 15 minutes. Consult a physician. Ingestion : Clean mouth with water and drink afterwards plenty of water.

Consult a physician.

Notes to physician Hazards : Contains ethanol. Depending on the quantity and other

circumstances consumption of ethanol can lead to a state of mental excitement and subsequent intoxication with symptoms like loss of self-control, dizziness or vomiting.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Extinguishing media which must not be used for safety reasons

: high volume water jet

Specific hazards during fire fighting

: Vapours may form explosive mixtures with air. In case of fire hazardous decomposition products may be produced such as: Carbon oxides

Special protective equipment for fire-fighters

: Choose protective equipment according to size of fire. Wear self-contained breathing apparatus and full protective suit when necessary.

Additional advice : Cool closed containers exposed to fire with water spray.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Use personal protective equipment. Keep away from heat and sources of ignition. Avoid contact with skin and eyes. Do not breathe vapours or spray mist. Provide adequate ventilation. Evacuate personnel to safe areas.

Environmental precautions : Prevent entering sewers, basements and workpits Risk of explosion. Avoid subsoil penetration.

Methods for cleaning up : Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Treat recovered material as described in the section "Disposal considerations". After cleaning, flush away traces with water.

7. HANDLING AND STORAGE

Handling



R3769 3/7 EN

Advice on safe handling : Handle and open container with care. Vapours are heavier than air and may spread along floors. Use only in well-ventilated areas.

Advice on protection against fire and explosion

: In use, may form flammable/explosive vapour-air mixture. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. Use only explosion-proof equipment. Vapours are heavier than air and may spread along floors. Flash back possible over considerable distance.

Storage Requirements for storage areas and containers

: Keep in an area equipped with solvent resistant flooring. Keep containers tightly closed in a cool, well-ventilated place.

Advice on common storage : Store in accordance with the particular national regulations. German storage class : 3A: Flammable Liquids

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components with workplace control parameters

ethanol CAS-No.: 64-17-5 MAK: 960 mg/m3, 500 ppm, TRGS 900 Top limit: 4 If in compliance with the MAK and BAT values, then there should be no risk to the fetus.

TRGS 900

butanone CAS-No.: 78-93-3 MAK: 600 mg/m3, 200 ppm, TRGS 900 Top limit: =1= If in compliance with the MAK and BAT values, then there should be no risk to the fetus.

TRGS 900

Can be absorbed through the skin. TRGS 900 TWA: 600 mg/m3, 200 ppm, EU ELV STEL: 900 mg/m3, 300 ppm, EU ELV

Personal protective equipment Respiratory protection : Required, if exposure limit is exceeded (e.g. OEL);

Recommended Filter type:A Hand protection : solvent-resistant gloves (butyl-rubber); Protective gloves

should be replaced at first signs of wear.

Eye protection : Goggles giving complete protection to the eyes Body Protection : Protective work clothing Hygiene measures : Take off all contaminated clothing immediately. Avoid contact

with the skin and the eyes. Do not breathe vapours or spray mist. Keep away from food, drink and animal feedingstuffs.



R3769 4/7 EN

Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday.

Engineering measures Refer to protective measures listed in sections 7 and 8.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Form : liquid Colour : colourless Odour : alcoholic

Safety data Boiling point/range : ca. 78 °C Flash point : ca. 12 °C Explosive properties : Formation of explosive air/vapour mixtures is possible. Lower explosion limit : 3,5 %(V) Upper explosion limit : 15 %(V) Vapour pressure : ca. 60 mbar; 20 °C Density : 0,808 g/cm3; 20 °C Water solubility : completely miscible

10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks. Materials to avoid : strong acids and oxidizing agents; alkali metals Hazardous reactions : In use, may form flammable/explosive vapour-air mixture. General advice : No decomposition if stored and applied as directed.

11. TOXICOLOGICAL INFORMATION

Ingestion : ethanol: LD50 rat 6.200 mg/kg butanone: LD50 rat 3.300 mg/kg Inhalation : ethanol: LC50 rat 124,7 mg/l 4 h butanone: LC50 rat > 15 mg/l 6 h Skin Absorption : butanone: LD50 rabbit 6.400 - 8.000 mg/kg Skin contact : Prolonged skin contact may defat the skin and produce

dermatitis. Eye contact : Irritating to eyes.

Sensitization : No sensitizing effect known.

Further information : Exposure to ethanol may result in drowsiness and headache. Other symptoms may include stupor, nausea, mental excitement or depression, vomiting, flushing and coma. It can



R3769 5/7 EN

cause narcosis, impaired perception and incoordination. Ingestion of this compound can enhance the effects of several medicines like sedatives, tranquilizers, insulin, monoamine oxidase inhibitors, and antidepressants. Inhalation of aerosols may cause irritation to mucous membranes.

12. ECOLOGICAL INFORMATION

Elimination information (persistence and degradability) Biodegradability : Readily biodegradable Toxicity to fish : ethanol: LC50 Leuciscus idus melanotus 8.150 mg/l 48 h Toxicity to daphnia : ethanol:

EC50 Daphnia magna 9.268 - 14.221 mg/l 48 h Toxicity to algae : ethanol: EC0 scenedesmus quadricauda 5.000 mg/l 168 h

Further information on ecology Additional ecological information

: Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.

13. DISPOSAL CONSIDERATIONS

Product : Disposal together with normal waste is not allowed. Do not let product enter drains. Can be disposed of as a solid waste or burned in a suitable installation subject to local regulations.

packaging : Empty remaining contents. Do not burn, or use a cutting torch on, the empty drum. Risk of explosion. Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning. Clean container with water.

European Waste Catalogue Number

: No waste code according to the European Waste Catalogue can be assigned for this product, as the intended use dictates the assignment. The waste code is established in consultation with the regionl waste disposer.

14. TRANSPORT INFORMATION



R3769 6/7 EN

ADR : UN-No 1993 Class 3 Packaging group II Classification Code F1 ADR/RID-Labels 3 Risk No. 33 Description of the goods FLAMMABLE LIQUID, N.O.S.

(Ethyl methyl ketone (Methyl ethyl ketone), Ethanol) Special Provision 640D

RID : UN-No 1993 Class 3 Packaging group II Classification Code F1 ADR/RID-Labels 3 Risk No. 33 Description of the goods FLAMMABLE LIQUID, N.O.S.

(Ethyl methyl ketone (Methyl ethyl ketone), Ethanol) Special Provision 640D

IMDG : UN-No 1993 Class 3 Packaging group II ADR/RID-Labels 3 EmS F-E, S-E Description of the goods FLAMMABLE LIQUID, N.O.S.

(Ethyl methyl ketone (Methyl ethyl ketone), Ethanol)

15. REGULATORY INFORMATION

Labelling according to EC Directives The product is classified and labelled in accordance with EC directives or respective national laws.

F Highly flammable

R-phrase(s) R11 Highly flammable.

S-phrase(s) S 7 Keep container tightly closed.

S16 Keep away from sources of ignition - No smoking. S29 Do not empty into drains. S33 Take precautionary measures against static discharges.



R3769 7/7 EN

National legislation WGK (DE) : WGK:1; slightly water endangering; Self-classification

according VwVwS of 17 May 1999, Annex 4 Major Accident Hazard Legislation

: Falls under the German StörfallV. 7b

Regulation : Occupational restrictions: Take note of Dir 92/85/EEC on the safety and health of pregnant workers at work and of Dir 94/33/EC on the protection of young people at work.

16. OTHER INFORMATION

Full text of R-phrases referred to under sections 2 and 3: R11 Highly flammable. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.

Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use. This safety datasheet only contains information relating to safety and does not replace any product information or product specification. # Indicates updated section.

SAFETY DATA SHEET Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Germany

1.1 Product identifier

Product name :

1.2 Relevant identified uses of the substance or mixture and uses advised against

Not available.

1.3 Details of the supplier of the safety data sheet

:

:

:

:

:

:

:

:

1.4 Emergency telephone number

Supplier

Telephone number : +49-(0)173-6774799 (Only out of office hour)

2.1 Classification of the substance or mixture

Product definition : Mixture

Classification according to Directive 1999/45/EC [DPD]

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

Classification : F; R11 Xi; R36 R66, R67

: Highly flammable.

: Irritating to eyes. Repeated exposure may cause skin dryness or cracking. may cause drowsiness and dizziness.

Physical/chemical hazards

Human health hazards Vapours

See Section 16 for the full text of the R phrases or H statements declared above.

See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard symbol or symbols :

Indication of danger

Risk phrases

: Highly flammable, Irritant

: R11- Highly flammable. R36- Irritating to eyes. R66- Repeated exposure may cause skin dryness or cracking. R67- Vapours may cause drowsiness and dizziness.

Date of issue : 26.05.2011. MSDS no. : 120488 1/13

SECTION 2: Hazards identification

Sika Deutschland GmbH

Kornwestheimer Str. 103-107

70439 Stuttgart

Germany

+4971180090

+497118009321

[email protected]

+49-(0)173-6774799 (Only out of office hour)

Manufacturer/Distributor

Street/postbox

Town/City and Post Code

Country

Telephone no.

Fax no.

e-mail address of person responsible for this SDS

Emergency telephone number

Sika® Primer-3 N

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Sika® Primer-3 N

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Germany

Safety phrases

Hazardous ingredients

Supplemental label

elements

: Not applicable.

:

:

ethyl acetate

Not applicable.

2.3 Other hazards

Other hazards which do not

result in classification : Not available.

Substance/mixture

Chemical family/

Characteristics

:

:

Mixture

Modified epoxy resin, containing solvent

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned a workplaceexposure limit and hence require reporting in this section.

Type


Classification Type

Product/ingredient name % 67/548/EEC Regulation (EC) No.

Identifiers 1272/2008 [CLP]

ethyl acetate >= 50 - < 75 F; R11 RRN: 01-2119475103-46 Xi; R36 EC: 205-500-4 R66, R67 CAS: 141-78-6 Index: 607-022-00-5

xylene >= 2.5 - < 10 R10 RRN: 01-2119488216-32 Xn; R20/21 EC: 215-535-7 Xi; R38 CAS: 1330-20-7 Index: 601-022-00-9

propan-2-ol >= 5 - < 10 F; R11 EC: 200-661-7 Xi; R36 CAS: 67-63-0 R67 Index: 603-117-00-0

ethylbenzene >= 1 - < 2.5 F; R11 RRN: 01-2119489370-35 Xn; R20 EC: 202-849-4 CAS: 100-41-4 Index: 601-023-00-4

methanol <3 F; R11 EC: 200-659-6 T; R23/24/25, CAS: 67-56-1 R39/23/24/25 Index: 603-001-00-X

Dibutyltin dilaurate >= 0.1 - < Muta. Cat. 3; R68 EC: 201-039-8 0.25 Repr. Cat. 2; R60,

R61

CAS: 77-58-7 T; R48/25 Xn; R22 Xi; R38 N; R50/53

See section 16 for the full text of the R-phrases declared above

Flam. Liq. 2, H225 [1] [2]

Eye Irrit. 2, H319 STOT SE 3, H336

Flam. Liq. 3, H226 [1] [2]

Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Irrit. 2, H315 Asp. Tox. 1, H304

Flam. Liq. 2, H225 [1] [2]

Eye Irrit. 2, H319 STOT SE 3, H336

Flam. Liq. 2, H225 [1] [2]

Acute Tox. 4, H332

Flam. Liq. 2, H225 [1] [2]

Acute Tox. 3, H301 Acute Tox. 3, H311 Acute Tox. 3, H331 STOT SE 1, H370

Acute Tox. 3, H301 [1] [2]

Skin Irrit. 2, H315

Eye Irrit. 2, H319

See Section 16 for the full text of the H statements declared above.

SECTION 3: Composition/information on ingredients

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SECTION 2: Hazards identification


[1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Occupational exposure limits, if available, are listed in Section 8.

4.1 Description of first aid measures

Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Inhalation : If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. Get medical attention if adverse health effects persist or are severe. Get medical attention if symptoms appear.

Wash skin thoroughly with soap and water or use recognised skin cleanser. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.

Do not induce vomiting unless directed to do so by medical personnel. Maintain an open airway. Seek immediate medical attention.

No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Skin contact :

Ingestion :

Protection of first-aiders :

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Eye contact

Inhalation

Skin contact

Ingestion

: Irritating to eyes.

:

:

:

Vapours may cause drowsiness and dizziness.

Defatting to the skin. May cause skin dryness and irritation.

No known significant effects or critical hazards.

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following: irritation watering redness

Inhalation : Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo

Adverse symptoms may include the following: irritation dryness cracking

No specific data.

Skin contact :

Ingestion :

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

: No specific treatment. Specific treatments


SECTION 4: First aid measures

Sika® Primer-3 N 26.05.2011 3/13

SECTION 3: Composition/information on ingredients


5.1 Extinguishing media

Suitable extinguishing

media

: Use dry chemical, CO2, water spray (fog) or foam.

Unsuitable extinguishing : Do not use water jet.

media

5.2 Special hazards arising from the substance or mixture

Hazards from the

substance or mixture

: Highly flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Hazardous thermal

decomposition products : Decomposition products may include the following materials:

carbon dioxide carbon monoxide

5.3 Advice for firefighters

Special protective actions

for fire-fighters : Promptly isolate the scene by removing all persons from the vicinity of the incident if

there is a fire. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical

incidents.

Special protective

equipment for fire-fighters :

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency

personnel

: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also Section 8 for additional information on hygiene measures.

6.2 Environmental

precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains

and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment.

Large spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment.

6.4 Reference to other

sections : See Section 1 for emergency contact information.

See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.


SECTION 6: Accidental release measures

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SECTION 5: Firefighting measures


7.1 Precautions for safe handling

Protective measures : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not breathe vapour or mist. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous.

Advice on general

occupational hygiene

: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

7.2 Conditions for safe storage, including any

incompatibilities

: Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well- ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental

contamination.

7.3 Specific end use(s)

Recommendations

Industrial sector specific solutions

:

:

Not available.

Not available.

8.1 Control parameters

Occupational exposure limits


Product/ingredient name Exposure limit values

ethyl acetate

xylene

propan-2-ol

ethylbenzene

methanol

TRGS900 AGW (Germany, 8/2010).

PEAK: 3000 mg/m³ 15 minute(s). PEAK: 800 ppm 15 minute(s). TWA: 1500 mg/m³ 8 hour(s). TWA: 400 ppm 8 hour(s).

TRGS900 AGW (Germany, 8/2010). Absorbed through skin. PEAK: 880 mg/m³ 15 minute(s). PEAK: 200 ppm 15 minute(s). TWA: 440 mg/m³ 8 hour(s). TWA: 100 ppm 8 hour(s).

TRGS900 AGW (Germany, 8/2010).

PEAK: 1000 mg/m³ 15 minute(s). PEAK: 400 ppm 15 minute(s). TWA: 500 mg/m³ 8 hour(s). TWA: 200 ppm 8 hour(s).

TRGS900 AGW (Germany, 8/2010). Absorbed through skin. TWA: 440 mg/m³ 8 hour(s). PEAK: 880 mg/m³ 15 minute(s). TWA: 100 ppm 8 hour(s).

PEAK: 200 ppm 15 minute(s).

TRGS900 AGW (Germany, 8/2010). Absorbed through skin. PEAK: 1080 mg/m³ 15 minute(s).

SECTION 8: Exposure controls/personal protection

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SECTION 7: Handling and storage


Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace procedures atmosphere or biological monitoring may be required to determine the effectiveness

of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Derived effect levels

No DELs available.

Predicted effect concentrations

No PECs available.

8.2 Exposure controls

Appropriate engineering

controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes,

mists, gases or dusts.

Eye/face protection :

Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates

this is necessary. Reference number EN 374. Suitable for short time use or protection against splashes: Butyl rubber/nitrile rubber gloves. (0,4 mm), breakthrough time <30 min. Contaminated gloves should be removed. Suitable for permanent exposure: Viton gloves (0.4 mm), breakthrough time >30 min.

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Use barrier skin cream.

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by

a specialist before handling this product.

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. organic vapour filter (Type A)

A1: < 1000 ppm; A2: < 5000 ppm; A3: < 10000 ppm

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Body protection :

Other skin protection :

Respiratory protection :

Environmental exposure

controls :


Sika® Primer-3 N 26.05.2011 6/13

SECTION 8: Exposure controls/personal protection PEAK: 800 ppm 15 minute(s).

TWA: 270 mg/m³ 8 hour(s). TWA: 200 ppm 8 hour(s).


9.1 Information on basic physical and chemical properties

Appearance

Physical state

Colour

Odour

Odour threshold

pH

Melting point/freezing point

Initial boiling point and boiling range

Flash point

Evaporation rate

Flammability (solid, gas)

Burning time

Burning rate

Upper/lower flammability or

explosive limits

:

:

:

:

:

:

:

Liquid.

Colourless to light yellow.

Faint odour.

Not available.

Not available.

Not available.

Not available.

:

:

:

:

:

:

Closed cup: -4°C

Not available.

Not available.

Not applicable.

Not applicable.

Lowest known value: Lower: 1% (xylene) Highest known value: Upper: 12% (propan-2-ol)

Highest known value: 10 kPa (75 mm Hg) (ethyl acetate)

Not available.

~0.98 g/cm3 [20°C (68°F)]

Not available.

Not available.

Not available.

Vapour pressure

Vapour density

Density

Relative density

Solubility(ies)

Partition coefficient: n- octanol/water

Auto-ignition temperature

Decomposition temperature

Viscosity

Explosive properties

Oxidising properties

:

:

:

:

:

:

:

:

:

:

:

427°C (ethyl acetate)

Not available.

Not available.

Not available.

Not available.

9.2 Other information

No additional information.

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of hazardous

reactions : Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

10.5 Incompatible materials : Highly reactive or incompatible with the following materials: oxidizing materials

10.6 Hazardous

decomposition products : Under normal conditions of storage and use, hazardous decomposition products

should not be produced.


SECTION 10: Stability and reactivity

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SECTION 9: Physical and chemical properties


11.1 Information on toxicological effects

Acute toxicity

Conclusion/Summary

Irritation/Corrosion

: Not available.

Conclusion/Summary

Sensitisation

Conclusion/Summary

Mutagenicity

Conclusion/Summary

Carcinogenicity

Conclusion/Summary

Reproductive toxicity

: Not available.

: Not available.

: Not available.

: Not available.


Product/ingredient name Result Species Score Exposure Observation

xylene propan-2-ol

ethylbenzene

methanol

Dibutyltin dilaurate

Eyes - Mild irritant

Eyes - Severe irritant

Skin - Mild irritant

Skin - Moderate irritant


Eyes - Moderate irritant










Skin - Severe irritant

Rabbit

Rabbit

Rat

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

Rabbit

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

87 milligrams

24 hours 5 milligrams

8 hours 60 microliters


100 Percent


10 milligrams

100 milligrams

500 milligrams

500 milligrams



40 milligrams



500 milligrams

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

Product/ingredient name Result Species Dose Exposure

ethyl acetate

xylene

propan-2-ol

ethylbenzene

methanol

Dibutyltin dilaurate

LC50 Inhalation Vapour

LD50 Dermal LD50 Oral LC50 Inhalation Gas.

LD50 Dermal LD50 Oral LD50 Dermal

LD50 Oral

LD50 Dermal

LD50 Oral

LC50 Inhalation Gas. LD50 Dermal

LD50 Oral

LD50 Oral

Rat

Rabbit Rat Rat

Rabbit Rat Rabbit

Rat

Rabbit

Rat

Rat Rabbit

Rat

Rat

1600 mg/l

>5000 mg/kg >5000 mg/kg 5000 ppm

>1700 mg/kg 4300 mg/kg 12800 mg/kg

5000 mg/kg

>5000 mg/kg

3500 mg/kg

64000 ppm 15800 mg/kg

5600 mg/kg

175 mg/kg

4 hours

- - 4 hours

- - -

-

-

-

4 hours -

-

-

Sika® Primer-3 N 26.05.2011 8/13

SECTION 10: Stability and reactivity

SECTION 11: Toxicological information


Conclusion/Summary

Teratogenicity

Conclusion/Summary

: Not available.

: Not available.

Information on the likely routes of exposure

Potential acute health effects

Eye contact

Inhalation

Skin contact

Ingestion

: Not available.

:

:

:

:

Irritating to eyes.

Vapours may cause drowsiness and dizziness.

Defatting to the skin. May cause skin dryness and irritation.

Can cause gastrointestinal disturbances.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following: irritation watering redness

Inhalation : Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo

Adverse symptoms may include the following: irritation dryness cracking

No specific data.

Skin contact :

Ingestion :

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects

Potential delayed effects

Long term exposure

Potential immediate effects

Potential delayed effects

: Not available.

: Not available.

: Not available.

: Not available.

Potential chronic health effects

Not available.

Conclusion/Summary

General

:

:

Not available.

Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.






Carcinogenicity

Mutagenicity

Teratogenicity

Developmental effects

Fertility effects

:

:

:

:

:

Other information : Not available.


Sika® Primer-3 N 26.05.2011 9/13

SECTION 11: Toxicological information


12.1 Toxicity

Conclusion/Summary : Not available.

12.2 Persistence and degradability

Conclusion/Summary : Not available.

12.3 Bioaccumulative potential

12.4 Mobility in soil

Soil/water partition coefficient (KOC)

Mobility

: Not available.

: Not available.

12.5 Results of PBT and vPvB assessment

PBT

vPvB

: Not applicable.

: Not applicable.

12.6 Other adverse effects : No known significant effects or critical hazards.

13.1 Waste treatment methods

Product

Methods of disposal : Completely emptied packagings can be given for recycling. Packaging containing remains of dangerous substances, as well as packagings disposed of remains can be unharmed eliminated in accordance with the regulations.

Completely emptied packagings may be given for recycling. Empty packaging may still contain hazardous residues. Empty packaging should be removed by a licensed

waste contractor.

Packaging :

Sika has agreed disposal contracts for all packaging which is brought into circulation in Germany.

For further details see www.sika.de


SECTION 14: Transport information

SECTION 13: Disposal considerations

Product/ingredient name LogPow BCF Potential

ethyl acetate

propan-2-ol ethylbenzene methanol

0.73

0.05 3.1 -0.82 to 0.66

-

- - -

low

low high low

Product/ingredient name Result Species Exposure

ethylbenzene

methanol

Acute LC50 150 to 200 mg/L Fresh water

Acute NOEC 88 ppm Fresh water

Acute LC50 3289 to 4395 mg/L Marine water

Fish

Fish

Daphnia

96 hours

96 hours

48 hours

Sika® Primer-3 N 26.05.2011 10/13

SECTION 12: Ecological information


14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC

Code

: Not available.

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

Substances of very high concern

None of the components are listed.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

VOC content (EU)

Other EU regulations

REACH Information:

: Not applicable.

: VOC (w/w): 66.34%

: All substances contained in Sika Products are - preregistered or registered by our upstream suppliers, and/or - preregistered or registered by Sika, and/or - excluded from the regulation, and/or - exempted from the registration.

Europe inventory : Not determined.

National regulations


Product/ingredient name

Carcinogenic

effects

Mutagenic effects

Developmental

effects

Fertility effects

Dibutyltin dilaurate - Muta. Cat. 3; R68 Repr. Cat. 2; R61 Repr. Cat. 2; R60

SECTION 15: Regulatory information

Sika® Primer-3 N 26.05.2011 11/13

SECTION 14: Transport information

ADR/RID - ADN/ADNR IMDG IATA

14.1 UN number

UN1866 UN1866 UN1866

14.2 UN proper

shipping name

Resin solution Resin solution Resin solution

14.3 Transport hazard class(es)

3 3 3

14.4 Packing group II II II

14.5 Environmental

hazards

No. No. No.

14.6 Special precautions for

user

Not available. Not available. Not available.

Additional

information

- Emergency schedules (EmS) -

F-E, S-E

Classification code F1


Hazard class for water

Technical instruction on

air quality control

: 2 according Appendix No. 4 (Gemäß VwVws vom 17. Mai 1999)

: TA-Luft Number 5.2.5: 64.3% TA-Luft Class I - Number 5.2.5: 2.3% TA-Luft Class III - Number 5.2.2: 0.2%

15.2 Chemical Safety

Assessment : This product contains substances for which Chemical Safety Assessments are still

required.

Indicates information that has changed from previously issued version.

Abbreviations and acronyms : ATE = Acute Toxicity Estimate

CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number

Full text of abbreviated H

statements : H224 Extremely flammable liquid and vapour.

H225

H226

H301 H304

H311

H312

H315

H319 H331

H332

H336

H370

Highly flammable liquid and vapour.

Flammable liquid and vapour.

Toxic if swallowed. May be fatal if swallowed and enters airways.

Toxic in contact with skin.

Harmful in contact with skin.

Causes skin irritation.

Causes serious eye irritation. Toxic if inhaled.

Harmful if inhaled.

May cause drowsiness or dizziness.

Causes damage to organs.

Full text of classifications

[CLP/GHS] : Acute Tox. 3, H301

Acute Tox. 3, H311

Acute Tox. 3, H331

Acute Tox. 4, H312 Acute Tox. 4, H332

Asp. Tox. 1, H304

Eye Irrit. 2, H319

Flam. Liq. 1, H224

Flam. Liq. 2, H225 Flam. Liq. 3, H226

Skin Irrit. 2, H315

STOT SE 1, H370

ACUTE TOXICITY: ORAL - Category 3

ACUTE TOXICITY: SKIN - Category 3

ACUTE TOXICITY: INHALATION - Category 3

ACUTE TOXICITY: SKIN - Category 4 ACUTE TOXICITY: INHALATION - Category 4

ASPIRATION HAZARD - Category 1

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2

FLAMMABLE LIQUIDS - Category 1

FLAMMABLE LIQUIDS - Category 2 FLAMMABLE LIQUIDS - Category 3

SKIN CORROSION/IRRITATION - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) [Narcotic effects] - Category 3

STOT SE 3, H336

Full text of abbreviated R

phrases : R11- Highly flammable.

R10- Flammable. R68- Possible risk of irreversible effects. R60- May impair fertility.

R61- May cause harm to the unborn child. R23/24/25- Also toxic by inhalation, in contact with skin and if swallowed. R39/23/24/25- Also toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. R48/25- Also toxic: danger of serious damage to health by prolonged exposure if swallowed. R20- Also harmful by inhalation. R22- Also harmful if swallowed. R20/21- Also harmful by inhalation and in contact with skin. R36- Irritating to eyes. R38- Irritating to skin.


SECTION 16: Other information

Sika® Primer-3 N 26.05.2011 12/13

SECTION 15: Regulatory information


R66- Repeated exposure may cause skin dryness or cracking. R67- Vapours may cause drowsiness and dizziness. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of classifications

[DSD/DPD]

: F - Highly flammable Muta. Cat. 3 - Mutagen category 3 Repr. Cat. 2 - Toxic to reproduction category 2 T - Toxic Xn - Harmful Xi - Irritant N - Dangerous for the environment

History

Date of printing

Date of issue

Date of previous issue

Notice to reader

:

: 26.05.2011.

: No previous validation.

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processing.


26.05.2011

Sika® Primer-3 N 26.05.2011 13/13

SECTION 16: Other information

/8

Safety data sheetaccording to 1907/2006/EC, Article 31

Printing date 05.03.2013 Revision: 30.08.2012Version number 8

36.0.2

1 Identification of the substance/mixture and of the company/undertaking

· Product identifier

· Trade name: INDUCRET-VK 5055 (A-Komponente)

· Article number: 555422· Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.

· Application of the substance / the preparation Epoxy coating

· Details of the supplier of the safety data sheet· Manufacturer/Supplier:SCHOMBURG ICS GmbHAquafinstr. 2-8D-32760 DetmoldGermany---------------------------------------------Tel: ++49 (0)5231/953-02Fax: ++49 (0)5231/953-390web: www.schomburg.com

· Informing department:Product Safety Department

Tel: ++49 (0)5231/953-193Fax: ++49 (0)5231/953-106email: [email protected]

2 Hazards identification

· Classification of the substance or mixture

· Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xi; Irritant

R36/38: Irritating to eyes and skin.

Xi; Sensitising

R43: May cause sensitisation by skin contact.

N; Dangerous for the environment

R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.

· Information concerning particular hazards for human and environment:The product may not leak out in sewerage system, stretch of water or soil.

· Classification system:The classification is in line with current EC lists. It is expanded, however, by information fromtechnical literature and by information furnished by supplier companies.

· Label elements

· Labelling according to EU guidelines:The product has been classified and labelled in accordance with EC Directives / Ordinance onHazardous Materials (GefStoffV)

· Code letter and hazard designation of product:Xi IrritantN Dangerous for the environment

· Hazard-determining components of labelling:reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight = 700)bisphenol-F-epoxy resinoxirane, mono[(C12-14-alkyloxy)methyl] derivs

(Contd. on page 2)

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Trade name: INDUCRET-VK 5055 (A-Komponente)

(Contd. of page 1)

36.0.2

· Risk phrases:36/38 Irritating to eyes and skin.43 May cause sensitisation by skin contact.51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

· Safety phrases:2 Keep out of the reach of children.24 Avoid contact with skin.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.37/39 Wear suitable gloves and eye/face protection.57 Use appropriate container to avoid environmental contamination.

· Special labelling of certain preparations:Contains epoxy constituents. See information supplied by the manufacturer.

· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

3 Composition/information on ingredients

· Chemical characterization: Mixtures· Description:Solvent- free preparation based on Bisphenol-A-Epichlorhydrin resin molecular weight ≤ 700.

· Dangerous components:

CAS: 25068-38-6NLP: 500-033-5

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (numberaverage molecular weight = 700)

Xi R36/38; Xi R43; N R51/53

Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319;Skin Sens. 1, H317

50-100%

CAS: 9003-36-5NLP: 500-006-8

bisphenol-F-epoxy resin Xi R36/38; Xi R43; N R51/53

Aquatic Chronic 2, H411; Eye Irrit. 2, H319; Skin Sens. 1,H317

2.5-10%

CAS: 68609-97-2EINECS: 271-846-8

oxirane, mono[(C12-14-alkyloxy)methyl] derivs Xi R38; Xi R43

Skin Irrit. 2, H315; Skin Sens. 1, H317

2.5-10%

· Additional information Contains epoxide-compounds. Note the index of the manufacturer.

4 First aid measures

· Description of first aid measures· General informationPersonal protection for the First Aider.It is possible to choke in case of vomiting in unconsciousness.Bring unconscious persons into a stable position on side.Keep the respiratory tract free (remove dentures and vomiting).Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppageof breathing: artificial respiration.Take up a doctor immediately!

· After inhalation Supply fresh air; consult doctor in case of symptoms.· After skin contactChange immediately contaminated clothes.Instantly wash with water and soap and rinse thoroughly.Don't use solvents to clean the skin.

· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.(Contd. on page 3)

GB

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(Contd. of page 2)

36.0.2

· After swallowingDo not induce vomiting; instantly call for medical help.Show the pack or the label to the doctor.

· Information for doctor· Most important symptoms and effects, both acute and delayedNo further relevant information available.

· Indication of any immediate medical attention and special treatment neededNo further relevant information available.

5 Firefighting measures

· Extinguishing media· Suitable extinguishing agentsCO2, extinguishing powder or water jet. Fight larger fires with water jet.

· Special hazards arising from the substance or mixtureFormation of poisonous gases during heating or in fires.

· Advice for firefighters· Protective equipment: Wear self-contained breathing apparatus.· Additional informationDispose of fire debris and contaminated fire fighting water in accordance with official regulations.

6 Accidental release measures

· Personal precautions, protective equipment and emergency proceduresEnsure adequate ventilationAvoid eye- and skin contact.Wear protective equipment. Keep unprotected persons away.Do not breath in vapour.Keep away from ignition sources

· Environmental precautions: Do not allow product to reach sewage system or water bodies.· Methods and material for containment and cleaning up:Absorb with liquid-binding, inflammable material (sand, diatomite, acid binders, universal binder).

· Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for information on disposal.

7 Handling and storage

· Handling· Precautions for safe handlingKeep containers tightly sealed.Work with fresh air supply, keep doors and windows open.Keep away from children.Keep away from heat and direct sunlight.

· Information about protection against explosions and fires:Keep ignition sources away - Do not smoke.

· Conditions for safe storage, including any incompatibilities· Storage· Requirements to be met by storerooms and containers:Store in cool location.Do not leave open containers.Do not store in common rooms.

· Information about storage in one common storage facility:Store away from foodstuffs.Please follow the rules of the VCI-Storage-Concept for chemicals.

(Contd. on page 4)

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(Contd. of page 3)

36.0.2

· Further information about storage conditions:Keep container tightly sealed.Store in cool, dry conditions in well sealed containers.Protect from frost.

· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems:It must be possible to wash the skin in the working area.Eye-wash bottle must be available.

· Control parameters· Components with critical values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.

· Additional information: The lists that were valid during the compilation were used as basis.

· Exposure controls· Personal protective equipment· General protective and hygienic measuresBefore starting work and after each break apply low-fat or fat-free skin cream on all uncovered partsof the body.Clean skin only with cleaning agent especially for epoxy resin.Don't use solvent for skin cleaning!Clean clothes which are contaminate with epoxi resin before unsing again.The usual precautionary measures should be adhered to in handling the chemicals.Instantly remove any soiled and impregnated garments.Wash hands during breaks and at the end of the work.Avoid contact with the eyes and skin.Do not eat, drink or smoke while working.

· Breathing equipment:Not necessary if room is well-ventilated.When the product is sprayed use respiration filter P2.

· Protection of hands: Gloves of butyl rubber.· Material of glovesButyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min

The selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.

· Eye protection: In case of splashing use protecting basket-glasses.· Body protection:Impervious protective clothingContaminated protection clothes must be cleaned carfully before reuse.In case of spraying use body-protection (apron of synthetic material and tightliy sealed face-protection).Use barrier cream for uncovered skin.

9 Physical and chemical properties

· Information on basic physical and chemical properties· General Information· Appearance:

Form: Liquid

(Contd. on page 5)

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(Contd. of page 4)

36.0.2

Colour: Colourless· Smell: Weak, characteristic

· Change in conditionMelting point/Melting range: Not determinedBoiling point/Boiling range: > 200 °C

· Flash point: 130 °C

· Self-inflammability: Product is not selfigniting.

· Danger of explosion: Product is not explosive.

· Density at 20 °C 1.12 g/cm³

· Solubility in / Miscibility withWater: Unsoluble

· Viscosity:dynamic at 20 °C: 1588 mPas

· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.

· Possibility of hazardous reactions Reacts violently with oxidizing agents· Conditions to avoid No further relevant information available.· Incompatible materials: Can react with acid and oxidizing agends.· Hazardous decomposition products: See item 5.3

11 Toxicological information

· Information on toxicological effects· Acute toxicity:

· LD/LC50 values that are relevant for classification:

25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number averagemolecular weight = 700)

Oral LD50 >5000 mg/kg (rats)

Dermal LD50 >2000 mg/kg (rats)

38640-62-9 Diisopropylnaphthalin-Isomere


Dermal LD50 >4500 mg/kg (rats)

Inhalative LC 50 5.64 mg/l (rats)

9003-36-5 bisphenol-F-epoxy resin


68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs


Dermal LD50 >4500 mg/kg (rabbit)· Primary irritant effect:· on the skin: Irritant for skin and mucous membranes.· on the eye: Irritant effect.· Sensitization: Sensitization possible by skin contact.

(Contd. on page 6)

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(Contd. of page 5)

36.0.2

· Additional toxicological information:The product shows the following dangers according to the calculation method of the General ECClassification Guidelines for Preparations as issued in the latest version:IrritantSensitizing

12 Ecological information

· Toxicity · Aquatic toxicity:


EC50 (24h) 3.6 mg/l (Daphnia magna)

LC50 (96h) 1.5 mg/l (rainbow trout)

38640-62-9 Diisopropylnaphthalin-Isomere

EC0 (72h) 0.15 mg/l (algae toxicity)

(48h) 0.16 mg/l (Daphnia (acute) oxicity)

LC 0 (96h) 0.5 mg/l (fish toxicity)

9003-36-5 bisphenol-F-epoxy resin

EC50 2 mg/l (Daphnia (acute) oxicity)

LC50/96h 2 mg/l (fish toxicity)

68609-97-2 oxirane, mono[(C12-14-alkyloxy)methyl] derivs

EC50 (48h) 1-10 mg/l (Daphnia magna)

EC50 (96h) 1-10 mg/l (fish toxicity) · Persistence and degradability


301B (Mod. Sturm) 12 % (-)· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Additional ecological information:· General notes:Water hazard class 2 (Self-assessment): hazardous for water.Do not allow product to reach ground water, water bodies or sewage system.Danger to drinking water if even small quantities leak into soil.

· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods· RecommendationTransfer to a permitted waste diposal institution.Must not be disposed of together with household garbage. Do not allow product to reach sewagesystem. · European waste catalogue

08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU)OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES,SEALANTS AND PRINTING INKS

(Contd. on page 7)

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(Contd. of page 6)

36.0.2

08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products)

08 04 09* waste adhesives and sealants containing organic solvents or other dangeroussubstances

· Uncleaned packagings:· Recommendation:Empty Containers with solid product rests can be supplied for recycling.Empty Containers including fluid product rests are hazardous waste.Disposal must be made according to official regulations.

14 Transport information

· UN-Number· ADR, IMDG, IATA UN3082

· UN proper shipping name· ADR 3082 ENVIRONMENTALLY HAZARDOUS

SUBSTANCE, LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxy resin(number averagemolecular weight<700), oxirane, mono[(C12-14-alkyloxy)methyl] derivs)

· IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxyresin(number average molecular weight<700),oxirane, mono[(C12-14-alkyloxy)methyl] derivs),MARINE POLLUTANT

· IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (bisphenol A-(epichlorhydrin); epoxyresin(number average molecular weight<700),oxirane, mono[(C12-14-alkyloxy)methyl] derivs)

· Transport hazard class(es)

· ADR, IMDG, IATA

· Class 9 Miscellaneous dangerous substances and articles.· Label 9

· Packing group· ADR, IMDG, IATA III

· Environmental hazards:· Marine pollutant: Yes

Symbol (fish and tree)· Special marking (ADR): Symbol (fish and tree)· Special marking (IATA): Symbol (fish and tree)

· Special precautions for user Warning: Miscellaneous dangerous substances andarticles.

· Kemler Number: 90· EMS Number: F-A,S-F

· Transport in bulk according to Annex II ofMARPOL73/78 and the IBC Code Not applicable.

(Contd. on page 8)

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(Contd. of page 7)

36.0.2

· Transport/Additional information:

· ADR· Limited quantities (LQ) 5L· Transport category 3 · Tunnel restriction code E

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· National regulations

· Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water.· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee forany specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrasesH315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H411 Toxic to aquatic life with long lasting effects.

R36/38 Irritating to eyes and skin.R38 Irritating to skin.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

· Department issuing data specification sheet: Environment protection department.· Contact: Mr. Guido Herfort

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36.0.2

1 Identification of the substance/mixture and of the company/undertaking

· Product identifier

· Trade name: INDUCRET-VK 5055 (B-Komponente)

· Article number: 555422B· Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.

· Application of the substance / the preparation hardener component

· Details of the supplier of the safety data sheet· Manufacturer/Supplier:SCHOMBURG ICS GmbHAquafinstr. 2-8D-32760 DetmoldGermany---------------------------------------------Tel: ++49 (0)5231/953-02Fax: ++49 (0)5231/953-390web: www.schomburg.com

· Informing department:Product Safety Department

Tel: ++49 (0)5231/953-193Fax: ++49 (0)5231/953-106email: [email protected]

2 Hazards identification

· Classification of the substance or mixture

· Classification according to Directive 67/548/EEC or Directive 1999/45/EC

C; Corrosive

R34: Causes burns.

Xn; Harmful

R21/22: Harmful in contact with skin and if swallowed.

Xi; Sensitising

R43: May cause sensitisation by skin contact.

R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.

· Information concerning particular hazards for human and environment:The product may not leak out in sewerage system, stretch of water or soil.The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.

· Classification system:The classification is in line with current EC lists. It is expanded, however, by information fromtechnical literature and by information furnished by supplier companies.

· Label elements

· Labelling according to EU guidelines:The product has been classified and labelled in accordance with EC Directives / Ordinance onHazardous Materials (GefStoffV)

· Code letter and hazard designation of product:C Corrosive

· Hazard-determining components of labelling:3-aminomethyl-3,5,5-trimethylcyclohexylamine

(Contd. on page 2)

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Trade name: INDUCRET-VK 5055 (B-Komponente)

(Contd. of page 1)

36.0.2

3,6,9-triazaundecamethylenediamine3,6-diazaoctanethylenediamin

· Risk phrases:21/22 Harmful in contact with skin and if swallowed.34 Causes burns.43 May cause sensitisation by skin contact.52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

· Safety phrases:2 Keep out of the reach of children.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical

advice.35 This material and its container must be disposed of in a safe way.36/37/39 Wear suitable protective clothing, gloves and eye/face protection.45 In case of accident or if you feel unwell, seek medical advice immediately (show the label

where possible).51 Use only in well-ventilated areas.61 Avoid release to the environment. Refer to special instructions/safety data sheets.

· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

3 Composition/information on ingredients

· Chemical characterization: Mixtures· Description: Mixture consisting of the following components.

· Dangerous components:

CAS: 68410-23-1 Polyaminaddukt Xi R41

Eye Dam. 1, H318

50-100%

CAS: 2855-13-2EINECS: 220-666-8

3-aminomethyl-3,5,5-trimethylcyclohexylamine C R34; Xn R21/22; Xi R43

R52/53

Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312;Skin Sens. 1, H317; Aquatic Chronic 3, H412

10-25%

CAS: 112-57-2EINECS: 203-986-2

3,6,9-triazaundecamethylenediamine C R34; Xn R21/22; Xi R43; N R51/53

Skin Corr. 1B, H314; Aquatic Chronic 2, H411; Acute Tox.4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317

10-25%

CAS: 112-24-3EINECS: 203-950-6

3,6-diazaoctanethylenediamin C R34; Xn R21; Xi R43

R52/53

Skin Corr. 1B, H314; Acute Tox. 4, H312; Skin Sens. 1, H317;Aquatic Chronic 3, H412

2.5-10%

· Additional information For the wording of the listed risk phrases refer to section 16.

4 First aid measures

· Description of first aid measures· General informationInstantly remove any clothing soiled by the product.Symptoms of poisoning may even occur after several hours; therefore medical observation for atleast 48 hours after the accident.

(Contd. on page 3)

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36.0.2

Personal protection for the First Aider.It is possible to choke in case of vomiting in unconsciousness.Bring unconscious persons into a stable position on side.Keep the respiratory tract free (remove dentures and vomiting).Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppageof breathing: artificial respiration.Take up a doctor immediately!

· After inhalationSupply fresh air or oxygen; call for doctor.Supply fresh air and call for doctor for safety reasons.In case of unconsciousness bring patient into stable side position for transport.

· After skin contactInstantly wash with water and soap and rinse thoroughly.Change immediately contaminated clothes.

· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.· After swallowingDrink copious amounts of water and provide fresh air. Instantly call for doctor.Show the pack or the label to the doctor.

· Information for doctor· Most important symptoms and effects, both acute and delayedNo further relevant information available.

· Indication of any immediate medical attention and special treatment neededNo further relevant information available.

5 Firefighting measures

· Extinguishing media· Suitable extinguishing agentsCO2, extinguishing powder or water jet. Fight larger fires with water jet.

· For safety reasons unsuitable extinguishing agents Water with a full water jet.· Special hazards arising from the substance or mixtureFormation of poisonous gases during heating or in fires.

· Advice for firefighters· Protective equipment: Wear self-contained breathing apparatus.· Additional informationDispose of fire debris and contaminated fire fighting water in accordance with official regulations.Follow the emergency-plan.Burst- and explosion-danger by increaseing pressure.In case of fire chill the container with water spray.

6 Accidental release measures

· Personal precautions, protective equipment and emergency proceduresBring persons out of danger.Wear protective equipment. Keep unprotected persons away.

· Environmental precautions: Do not allow product to reach sewage system or water bodies.· Methods and material for containment and cleaning up:Ensure adequate ventilation.Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

· Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for information on disposal.

GB

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36.0.2

7 Handling and storage

· Handling· Precautions for safe handling Keep away from children.· Information about protection against explosions and fires: No special measures required.

· Conditions for safe storage, including any incompatibilities· Storage· Requirements to be met by storerooms and containers: No special requirements.· Information about storage in one common storage facility:Please follow the rules of the VCI-Storage-Concept for chemicals.

· Further information about storage conditions:Keep container tightly sealed.Store in a locked cabinet and out of the reach of children.

· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems:It must be possible to wash the skin in the working area.Eye-wash bottle must be available.

· Control parameters· Components with critical values that require monitoring at the workplace:The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.

· Additional information: The lists that were valid during the compilation were used as basis.

· Exposure controls· Personal protective equipment· General protective and hygienic measuresThe usual precautionary measures should be adhered to in handling the chemicals.Instantly remove any soiled and impregnated garments.Avoid contact with the eyes and skin.Be sure to clean skin thoroughly after work and before breaks.

· Breathing equipment: Not required.· Protection of hands:Hand Protection: Nitril-rubber-latex-gloves.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of severalsubstances, the resistance of the glove material can not be calculated in advance and has thereforeto be checked prior to the application.

· Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.

· Eye protection:Tightly sealed safety glasses.In case of splashing use protecting basket-glasses.

· Body protection:Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece.Contaminated protection clothes must be cleaned carfully before reuse.

GB

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36.0.2

9 Physical and chemical properties

· Information on basic physical and chemical properties· General Information· Appearance:

Form: FluidColour: According to product specification

· Smell: Characteristic

· pH-value at 20 °C: 10

· Change in conditionMelting point/Melting range: Not determinedBoiling point/Boiling range: > 200 °C

· Flash point: > 100 °C

· Ignition temperature: 335 °C

· Self-inflammability: Product is not selfigniting.

· Danger of explosion: Product is not explosive.

· Steam pressure: Not determined.

· Density at 20 °C 0.97 g/cm³

· Solubility in / Miscibility withWater: Not miscible or difficult to mix

· Viscosity:dynamic at 20 °C: 150 mPas

· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity· Chemical stability· Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions known· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known

11 Toxicological information

· Information on toxicological effects· Acute toxicity:

· LD/LC50 values that are relevant for classification:

2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine

Oral LD50 1030 mg/kg (rats)· Primary irritant effect:· on the skin:Caustic effect on skin and mucous membranes.Irritant for skin and mucous membranes.

· on the eye: Strong caustic effect.· Sensitization: Sensitization possible by skin contact.· Additional toxicological information:The product shows the following dangers according to the calculation method of the General ECClassification Guidelines for Preparations as issued in the latest version:

(Contd. on page 6)

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36.0.2

HarmfulCorrosiveIrritantSwallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforationof esophagus and stomach.Sensitizing

12 Ecological information

· Toxicity · Aquatic toxicity:

2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine

EC/10/18h 1.120 mg/l (Pseudomas putida)

EC50 >50 mg/l (algae toxicity)

EC50 (48h) 23 mg/l (Daphnia magna)

LC 0 70 mg/l (Brachydanio rerio)· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.

· Ecotoxical effects:

112-24-3 3,6-diazaoctanethylenediamin

LC50 Akut 12 mg/l (water flea)· Remark: Harmful to fish· Additional ecological information:· General notes:Water hazard class 2 (Self-assessment): hazardous for water.Do not allow product to reach ground water, water bodies or sewage system.Must not reach sewage water or drainage ditch undiluted or unneutralized.Danger to drinking water if even small quantities leak into soil.Harmful to aquatic organisms

· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods· RecommendationMust not be disposed of together with household garbage. Do not allow product to reach sewagesystem. · European waste catalogue

08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU)OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES,SEALANTS AND PRINTING INKS

08 01 00 wastes from MFSU and removal of paint and varnish

08 01 11* waste paint and varnish containing organic solvents or other dangerous substances

· Uncleaned packagings:· Recommendation: Disposal must be made according to official regulations.

GB

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36.0.2

14 Transport information

· UN-Number· ADR, IMDG, IATA UN2735

· UN proper shipping name· ADR 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S.

(ISOPHORONEDIAMINE)· IMDG, IATA POLYAMINES, LIQUID, CORROSIVE, N.O.S.

(ISOPHORONEDIAMINE)

· Transport hazard class(es)

· ADR, IMDG, IATA

· Class 8 Corrosive substances.· Label 8

· Packing group· ADR, IMDG, IATA III

· Environmental hazards:· Marine pollutant: No

· Special precautions for user Warning: Corrosive substances.· Kemler Number: 80· EMS Number: F-A,S-B· Segregation groups Alkalis

· Transport in bulk according to Annex II ofMARPOL73/78 and the IBC Code Not applicable.

· Transport/Additional information:

· ADR· Limited quantities (LQ) 5L· Transport category 3 · Tunnel restriction code E

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· National regulations

· Water hazard class:Water hazard class 2 (Self-assessment): hazardous for water.The classification based on german instructions.

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee forany specific product features and shall not establish a legally valid contractual relationship.

· Relevant phrasesH302 Harmful if swallowed.H312 Harmful in contact with skin.H314 Causes severe skin burns and eye damage.H317 May cause an allergic skin reaction.

(Contd. on page 8)

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(Contd. of page 7)

36.0.2

H318 Causes serious eye damage.H411 Toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.

R21 Harmful in contact with skin.R21/22 Harmful in contact with skin and if swallowed.R34 Causes burns.R41 Risk of serious damage to eyes.R43 May cause sensitisation by skin contact.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

· Department issuing data specification sheet: Environment protection department.· Contact: Mr. Guido Herfort

GB

Material safety data sheet according to 2001/58/EG Trade name: KAGESOL EP-B950L Component A Product-no. 1950 L updated on 29.01.2005 Page 1/6 1. material-/preparation- and company name name : KAGESOL EP-B950L (component A) manufacturer : van Koetsveld & Grimberg GmbH, Röntgenstr. 7a, D-48599 Gronau telephone : +49/2562-26334 information section : coating, +49/2562-4700 2. composition/information about components chemical characteristics: formulated epoxy resin components CAS-No. hazard

symbols R-phrases part

bisphenol-A-epichlorhydrine resin with an average molecularweight < 700

25068-38-6 Xi, N -R36/38-R43-R51/53- 50 - 75 %

bisphenol-F-epoxyresin 9003-36-5 Xi, N -R36/38 -R43- -R51/53-

12 - 20 %

C12 - C14 aliphatic glycidylether

68609-97-2 Xi, N -R36/38-R43-R51/53- < 5 %

3. possible hazards Skin and eye irritant.

Skin contact can cause sensitization. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.

4. first -aid steps eye contact : Immediately flush eyes with running water for at least 15 minutes.

Consult eye doctor.

skin contact : Quickly remove contaminated clothing.. Rinse affected skin with mild cleaning solution in much water. If skin irritation persists or becomes infected consult a physician.

inhalation : Remove victim into fresh air. If feeling sick consult a physician.

swallowing : Do not induce vomiting. Give water in small amounts to drink (diluting effect). Immediately consult a physician.

Material safety data sheet according to 2001/58/EG Trade name: KAGESOL EP-B950L Component A Product-no. 1950 L updated on 29.01.2005 Page 2/6 5. steps for fire fighting special danger : In case of fire carbonmonoxide and other gases or steams which are

hazardous to human health can be given off in addition to carbondioxide and water. In particular beware of development of nitrous gases.

protective gear : Use respiratory equipment with independent air supply.

right fire extinguishers : Water mist / low pressure stream, dry chemical fire extinguisher (BC- powder), foam, carbondioxide

wrong fire extinguishers : High pressure jet. 6. steps by unintentional release personal precautions : Avoid skin and eye contact. Insure proper ventilation. Wear protective

clothing.

environmental safety precautions :

Do not drain into water, sewersystem or soil.

cleaning methods : Large amounts: Treat the leaking product with drysweep material to control spreading and pump it up. Small amounts: Spread drysweep material (sand etc.) over leaking product and dispose off properly.

additional instructions : For disposal see section 13. 7. handling and storage advices for safe handling : Use only in well ventilated areas.

advices for protection against fire and explosion :

No special methods required.

storage : Store in closed original container between 10 – 20°C . Store in dry well ventilated room away from easy inflammable materials and acids.

8. exposition limit and personal protective gear danger level of components in relation to work area (Germany): none

Material safety data sheet according to 2001/58/EG Trade name: KAGESOL EP-B950L Component A Product-no. 1950 L updated on 29.01.2005 Page 3/6 personal protective gear

respiratory equipment : Usually not necessary. Combination filter A/ P2 if used for spray / mist application.

eye protection : Close fitting goggles.

hand protection : Long sleeved butyl rubber or nitril protective gloves.

body protection : To prevent body contact wear rubber or plastic apron / appropriate arm protection.

hygiene rules : Quickly remove contaminated clothing. Use skin protection cream before work. Wash hands after work day ends and before breaks. Never eat, drink or smoke while working.

9. physical and chemical properties state of aggregation : liquid colour : coloured smell : weak distinct smell

facts relevant to security

boiling temperature : > 200°C at 1013 hpa

flash point : 130°C (DIN 51758)

thermal decomposition : > 200°C

vapor pressure : < 0,001 hPa at 20°C

density : 1.13 g/cm3 at 20°C (DIN 51757)

solubility in water : insoluble at 20°C

viscosity : 800 - 1100 mPas at 25°C 10. stability and reactivity dangerous reactions : Can react with amines and mercaptans by developing large quantities

of heat. Strong reaction with acids.

dangerous decomposition products :

None, if stored and handled properly.

Material safety data sheet according to 2001/58/EG Trade name: KAGESOL EP-B950L Component A Product-no. 1950 L updated on 29.01.2005 Page 4/6 11. information about toxicology acute toxicity (lethal doses) LD50 oral, rat: dose : approx. 10ml/kg general information about acute or other toxicity irritation effect on skin/eyes Low molecular epoxy resins and glycidylether are proven skin irritant in

animal tests.

sensitization : Low molecular epoxy resins and glycidylether are proven sensitizing agents in animal tests.

practical experiences: Low molecular epoxy resins have been proven to cause eye and skin irritation Allergic skin reactions were also observed.

12. information about the ecology methods of disposal:

biological degradability: estimation: not easy bio-degradable

ecological toxicity:

acute fish toxicity LD50: dose : 1..10mg/l/96h

acute daphnae toxicity EC50:

dose : 1..10mg/l/48h

further information about ecology: Liquid epoxy resins based on bisphenol A and bisphenol F, as well as

many reactive thinners are considered environmentally unsafe by the Association of Plastic Manufacturers in Europe (APME).Data for classification were in the range of the above.

13. notice about disposal product : Burn under observation of the official laws in special refuse incinerating

plant.

code of disposal : 080102 old paints and varnishes containing no chlorinated solvents

packing material : Reusable after cleaning. Dispose cleaning solvent like product.

Material safety data sheet according to 2001/58/EG Trade name: KAGESOL EP-B950L Component A Product-no. 1950 L updated on 29.01.2005 Page 5/6 14. information about transportation UN3082 Environmentally hazardous substance, liquid, n.o.s. (epoxy resin) Landtransport ADR/RID/GGVSE classification : 9 packing group : III packing /tank instructions : P001, IBC03, LP01, R001, T4, LGBV Seatransport IMDG/GGVSee

Not a hazardous substance according to national and international transportation regulations. Airtransport ICAO/IATA Classification : 9 Packing group : III Packing instruction : 914 15. regulations characterize according to EG regulations and its adjustments and changes. hazard symbols : (Xi) irritant, (N) environmentally dangerous

R-phrases : R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms. May have long-term adverse effects

in the aquatic environment.

S-phrases : S28 After contact with skin, wash immediately with plenty of water and

soap. S37/39 Wear suitable gloves and eye/face protection.

S61 Avoid release to the environment. Refer to special instructions/safety data sheets.

dangerous components : bisphenol-A-epichlorhydrine resin with an average molecular weight < 700

bisphenol-F-epoxyresin

national regulations (Germany): waterpollutant class : (2) water pollutant (self judgement)

VbF : no classification

Material safety data sheet according to 2001/58/EG Trade name: KAGESOL EP-B950L Component A Product-no. 1950 L updated on 29.01.2005 Page 6/6 16. further instructions In general we recommend you to pay attention to the following data sheets for secure handling of epoxy resin and -hardener. Data sheet M 004: Irritant/caustics materials Data sheet M 023: Manufacture of polyester- and epoxy resins. (published by the occupation association of the chemical industry) These instructions are based on up to date knowledge and experience. The security data sheet describes the safety requirements for products. Manufacturer claims no responsibility for variances in data. No legal obligation can be deducted from the above mentioned properties.

Material safety data sheet according to 2001/58/EG Trade name: KAGESOL EP-B950L Component B Product-no. 1950 L updated on 29/01/2005 Page 1/6

1. material-/preparation- and company name name : KAGESOL EP-B950L (component B) manufacturer : van Koetsveld & Grimberg GmbH, Röntgenstr. 7a, D-48599 Gronau telephone : +49/2562-26334 information section : coating, +49/2562-4700 2. composition / information about components chemical characteristics: modified polyamine components

CAS-No. hazard symbols R-phrases part

isophoronediamine 2855-13-2 C -R21/22-R34-R43- -R52/53-

12 - 22 %

tetraethylene-pentamine

112-57-2 C, N -R21/22-R34-R43- -R51/53

4 - 8 %

benzylalcohol 100-51-6 Xn -R20/22- 3 - 7 % 3. possible hazards Harmful in contact with skin and if swallowed.

Causes burns. Skin contact can cause sensitization.

4. first -aid steps eye contact : Immediately flush eyes with running water for at least 15 minutes.

Consult eye doctor.

skin contact : Quickly remove contaminated clothing.. Rinse affected skin with mild cleaning solution in much water. If skin irritation persists or becomes infected consult a physician.

inhalation : Remove victim into fresh air. If feeling sick consult a physician.

swallowing : Do not induce vomiting. Give water in small amounts to drink (diluting effect). Immediately consult a physician.

notice for physician : Treat chemical burns like burn wounds.


5. steps for fire fighting special danger : In case of fire carbonmonoxide and other gases or steams which are

hazardous to human health can be given off in addition to carbondioxide and water. In particular beware of development of nitrous gases.

protective gear : Use respiratory equipment with independent air supply.

right fire extinguishers : Water mist / low pressure stream, dry chemical fire extinguisher (BC- powder), foam, carbondioxide

wrong fire extinguishers : High pressure jet. 6. steps by unintentional release personal precautions : Avoid skin and eye contact. Insure proper ventilation. Wear protective

clothing.

environmental safety precautions :

Do not drain into water, sewersystem or soil.

cleaning methods : Large amounts: Treat the leaking product with drysweep material to control spreading and pump it up. Small amounts: Spread drysweep material (sand etc.) over leaking product and dispose off properly.

additional instructions : For disposal see section 13. 7. handling and storage advices for safe handling : Use only in well ventilated areas.

advices for protection against fire and explosion :

Keep away from all sources of ignition – No smoking.

storage : Store in closed original container between 10 - 20°C in dry well ventilated room.


8. exposition limit and personal protective gear danger level of components in relation to work area (Germany): none personal protective gear

respiratory equipment : Gasfilter type A, if technical precautions for suction are not efficient. Combination filter A/ P2 if used for spray / mist application.

eye protection : Close fitting goggles.

hand protection : Long sleeved butyl rubber or nitril protective gloves.

body protection : To prevent body contact wear rubber or plastic apron / appropriate arm protection.

hygiene rules : Quickly remove contaminated clothing. Use skin protection cream before work. Wash hands after work day ends and before breaks. Never eat, drink or smoke while working.

9. physical and chemical properties state of aggregation : liquid color : uncolored ore yellowish smell : smell of amine

facts relevant to security boiling start : approx. 135°C at 1013 hpa

flash point : approx. 88°C (DIN 51758)

thermic decomposition : > 250°C

density : 0.96 g/cm3 at 20°C (DIN 51757)

solubility in water : partially soluble

pH-value : 12 (dispersed in water, 50 %) at 20°C

viscosity : 230 - 300 mPas at 23°C 10. stability and reactivity dangerous reactions : Strong reaction with acids and epoxy resins.

dangerous decomposition products :

None, if stored and handled properly.


11. information about toxicology acute toxicity (lethal doses) LD50 oral, rat: dose : 200 - 2000 mg/kg acute toxicity (primary irritation effect, sensitization) irritation effect on skin, rabbit: result : caustic irritation effect on eye, rabbit: result : caustic further informations : Based on the content of corrosive substances the product can be

corrosive in contact with skin and eyes. Based on the content of substances causing allergic reactios in animal tests the product can cause sensitization in contact with skin.

12. information about the ecology There is no ecological data at this point. Avoid penetration of product

into sewer, water and soil. The informations mentioned below are valid for isophoronediamine.

fishtoxicity LC50: (goldorfe)

185 mg/l/48h

daphnia toxicity EC50 : (Daphnia magna Straus)

42 mg/l/24h

alge toxicity EC50 : (Scenedesmus subspicat)

37 mg/l/72h

bacteria toxicity EC50 : > 100 mg/l 13. notice about disposal

product : Burn under observation of the official laws in special incinerating plant.

code of disposal : 080102 old paints and varnishes containing no chlorinated solvents

packing material : Reusable after cleaning. Dispose cleaning solvent like product.


14. information about transportation UN2735 amines liquid, corrosive n.o.s. (isophoronediamine) Landtransport ADR/RID/GGVSE classification : 8 packing group : III packing/tank instructions : P001, IBC03, LP01, R001, T7, L4BN

Seatransport IMDG/GGVSee classification : 8 packing group : III EmS-No. : 8-05 Marine pollutant : yes MFAG-No. (first) : 320

Airtransport ICAO/IATA classification : 8 packing group : III packing instruction pass. : 818 Packing instruction cao : 820 15. regulations characterize according to EG guideline 88/379/EWG and its adjustments and changes. hazard symbol : (C) corrosive

R-phrases : R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitization by skin contact.

R52/53 Harmful to aquatic organisms. May have long-term adverse effects in the aquatic environment.

S-phrases : S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S28 After contact with skin, wash immediately with plenty of water and soap.

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheet.

dangerous components : isophoronediamine tetraethylenepentamine

national regulations (Germany):

waterpollutant class : (2) water pollutant (self judgement according to german regulations) VbF : no classification


16. further instructions

In general we recommend you to pay attention to the following data sheet for secure handling of epoxy resin and -hardener. Data sheet M 004: Irritant/corrosive agents

Data sheet M 023: Manufacture of polyester- and epoxy resins. (published by the occupation association of the chemical industry) R-phrases mentioned in chapter 2:

R20/22 Harmful by inhalation and if swallowed. R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms may cause long-term adverse effects in the aquatic environment.

These instructions are based on up to date knowledge and experience. The safety data sheet describes the safety requirements for products. Manufacturer claims no responsibility for variances in data. No legal obligation can be deducted from the above mentioned properties.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : 7M3665S073891 KG FLEX A. Date: 19.01.09 Revision date: 02.07.08 page: 1/6 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Product Name and Code : KG FLEX A. ca. RAL 7038 achatgrau 7M3665S073891 MV 1:1 KG FLEX B.

Use of the substance/preparation:

Name of the company: brocolor LACKFABRIK GmbH Henschelstr. 2 D-48599 Gronau Phone of the company: +49(0)2562-911-0 Fax: +49(0)2562-911-200 e-mail: [email protected] Emergency phone : +49(0)40-547799-0 2. HAZARDS IDENTIFICATION Danger classification : Xi Irritant N Dangerous for the environment

36/38 Irritating to eyes and skin. 43 May cause sensitisation by skin contact. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The preparation may be a skin sensitiser. It may also be a skin irritant and repeated contact may increase this effect. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical family: Basis: Epoxidh.,Lösungsmittel kleiner 5%

Substances presenting a health or environmental hazard: EINECS-No. Names R-phrases Symb. Conc. REACH registration number 500-033-5 reaction product: bisphenol A-(epichlorhydrin); epoxy resin 25068-38-6 (number average molecular weight <= 700) 36/38-43-51/53 Xi,N 50 - 100 271-846-8 oxirane, mono[(C12-14-alkyloxy)methyl] derivs 68609-97-2 38-43 Xi 2.5 - 10 231-545-4 silica 7631-86-9 -- * < 2.5

See full text of phrases under chapter 16. * Substance with a common (EC) occupational exposure limit value. 4. FIRST AID MEASURES General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation : Remove to fresh air, keep patient warm and at rest, if breathing is irregular or stopped, administer artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin contact : Remove contaminated clothing. Wash skin thorougly with soap and water or use recognised skin cleanser. Do not use solvents or thinners.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : 7M3665S073891 KG FLEX A. Date: 19.01.09 Revision date: 02.07.08 page: 2/6 Ingestion : If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Recommended: alcohol resistant foam, CO2, powders, waterspray. Not to be used: waterjet. Recommendations: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in container for disposal according to local regulations (see section 13). Do not allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance with local regulations. 7. HANDLING AND STORAGE Handling. Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Preparation may charge electrostatically: always use earthing leads when transferring from one container to another. Operators should wear anti- static footwear and clothing and floors should be of the conducting type. Keep container tightly closed. Isolate from sources of heat, sparks and open flame. No sparking tools should be used. Avoid skin and eye contact. Avoid inhalation of dust,particulates and spray mist arising from the application of this preparation. Avoid inhalation of dust from sanding. Smoking, eating and drinking should be prohibited in application area. For personal protection see Section 8. Never use pressure to empty : container is not a pressure vessel. Always keep in containers of same material as the original one. Comply with the health and safety at work laws. Storage. Although the storage and use of this product is not subject to specific statutory requirements, observation of the principles of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations as appropriate will be seen as good industrial practice in meeting the general duties of the Health and Safety at Work Act. Observe label precautions. Store between 15 and 30 ˚C in a dry, well ventilated place away from sources of heat and direct sunlight. Keep away from sources of ignition. Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : 7M3665S073891 KG FLEX A. Date: 19.01.09 Revision date: 02.07.08 page: 3/6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.

Exposure Limits. Occupational exposure limit for : EINECS-No. Names STEL LTEL 231-545-4 silica MAK 4.0 mg/m3

Personal Protection. Respiratory protection: If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators. Hand protection: For prolonged or repeated handling, use Nitril gloves. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Eye protection: Use safety eyewear designed to protect against splash of liquids. Skin protection: Personnel should wear anti-static clothings made of natural fibre or of high temperature resistant synthetic fiber. 9. PHYSICAL AND CHEMICAL PROPERTIES General information appearance : liquid colour : see product name odour : typical Important health, safety and environmental information Flash point : 99 ˚C DIN 53213 Ignition temperature : n.a. ˚C Lower explosion limit : n.a. Vol.% Upper explosion limit : n.a. Vol.% Vapour pressure at 20 ˚C: 0.00 mbar Specific gravity at 20 ˚C: 1.33 g/cm³ Water solubility : insoluble Viscosity at 20 ˚C: 180 s 8 mm DIN 53211 Solvent-separation test : < 3 % ADR/RID Percent volatile by weight : 0 % 10. STABILITY AND REACTIVITY Stable under recommended storage and handling conditions (See section 7). When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke, oxides of nitrogen etc. Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. 11. TOXICOLOGICAL INFORMATION There are no data available on the preparation itself. The preparation has been assessed following the conventional methos of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See Chapter 3 and 15 for details.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : 7M3665S073891 KG FLEX A. Date: 19.01.09 Revision date: 02.07.08 page: 4/6 Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Based on the properties of the epoxy constituent(s) and considering toxicological data on similar preparations, this preparation may be a skin sensitiser and an irritant. It contains low molecular weight epoxy constituents which are irritating to eyes, mucous membrane and skin. Repeated skin contact may lead to irritation and to sensitisation, possibly with cross-sensitisation to other epoxies. Skin contact with the preparation and exposure to spray mist and vapour should be avoided.

Summarized evaluation of the CMR properties: EINECS-No. Names Classification REACH registration number The components in this formulation do not meet the criteria for classification as CMR category 1 or 2. 12. ECOLOGICAL INFORMATION The product should not be allowed to enter drains or water courses.

Results of PBT assessment: EINECS-No. Names Classification REACH registration number The components in this formulation do not meet the criteria for classification as PBT or vPvB.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is classified for eco- toxicological properties accordingly. See Section 2 and 15 for details. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses. Wastes and emptied containers should are to be deposited according to the official rules. Code of waste Waste Designation: 080111 waste paint and varnish containing organic solvents or other dangerous substances

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : 7M3665S073891 KG FLEX A. Date: 19.01.09 Revision date: 02.07.08 page: 5/6 14. TRANSPORT INFORMATION Transport only in accordance with ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport. ADR/RID Class: 9 Hazard label(s): 9 UN-No: 3082 ADR hazard: 90 Transport document name: Environmentally hazardous substance, liquid, n.o.s. contains: Bisphenol A Epoxy Resin Packing group: III IMDG Class: 9 Hazard label(s): 9 EmS: F-A, S-F UN-No: 3082 Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. contains: Bisphenol A Epoxy Resin Packing group: III marine pollutant: n.a. ICAO/IATA Class: 9 Hazard label(s): 9 UN No: 3082 Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. contains: Bisphenol A Epoxy Resin Packing group: III 15. REGULATORY INFORMATION Chemical Safety Assessment: EINECS-No. Names REACH registration number

In accordance with requirements of the Classification Packaging and Labelling of Dangerous Preparations Regulations (1999/45/EC). The product is labelled as follows: Danger classification : Xi Irritant N Dangerous for the environment

Contains: reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700) oxirane, mono[(C12-14-alkyloxy)methyl] derivs

R-phrases: 36/38 Irritating to eyes and skin. 43 May cause sensitisation by skin contact. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-phrases:

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : 7M3665S073891 KG FLEX A. Date: 19.01.09 Revision date: 02.07.08 page: 6/6 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 37 Wear suitable gloves. 38 In case of insufficient ventilation, wear suitable respiratory equipment. 61 Avoid release to the environment. Refer to special instructions/safety data sheets. 23 Do not breathe vapour.

Special provisions concerning the labelling of preparations: 92 Contains epoxy constituents. See information supplied by the manufacturer. This information is provided by the present Safety Data Sheet.

Information of VOC-properties: VOC(g/l) DIN ISO 11890: 0 VOC(g/l) ASTM D-3960-1: 0

16. OTHER INFORMATION Full text of R-phrases with no. appearing in section 3: 36/38 Irritating to eyes and skin. 43 May cause sensitisation by skin contact. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 38 Irritating to skin.

The information of this SDS is based on the present state of our knowledge and on current EU and national laws. The product is not to be used for other purposes than those specified under section 1 without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this SDS is meant as a description of the safety requirements of our product: it is not to be considered as a guarantee of the products’ properties.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : H129-1 KG FLEX B * Date: 19.01.09 Revision date: 02.01.08 page: 1/6 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Product Name and Code : KG FLEX B * H129-1

Use of the substance/preparation:

Name of the company: brocolor LACKFABRIK GmbH Henschelstr. 2 D-48599 Gronau Phone of the company: +49(0)2562-911-0 Fax: +49(0)2562-911-200 e-mail: [email protected] Emergency phone : +49(0)40-547799-0 2. HAZARDS IDENTIFICATION Danger classification : C Corrosive

20/22 Harmful by inhalation and if swallowed. 34 Causes burns. 43 May cause sensitisation by skin contact. 53 May cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical family: Basis: Amin/Amid

Substances presenting a health or environmental hazard: EINECS-No. Names R-phrases Symb. Conc. REACH registration number 202-013-9 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 22-36/38 Xn 2.5 - 10 203-550-1 4-methylpentan-2-one 108-10-1 11-20-36/37-66 Xn,F < 2.5 Nonylphenol 25154-52-3 22-34-50-53 C,N 10 - 25 Tetradecylamin 61788-46-3 35 C 2.5 - 10 Trimethylhexamethylendiamin 25620-58-0 22-34-43-52-53 C 2.5 - 10

See full text of phrases under chapter 16. 4. FIRST AID MEASURES General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation : Remove to fresh air, keep patient warm and at rest, if breathing is irregular or stopped, administer artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin contact : Remove contaminated clothing. Wash skin thorougly with soap and water or use recognised skin cleanser. Do not use solvents or thinners.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : H129-1 KG FLEX B * Date: 19.01.09 Revision date: 02.01.08 page: 2/6 Ingestion : If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Recommended: alcohol resistant foam, CO2, powders, waterspray. Not to be used: waterjet. Recommendations: Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in container for disposal according to local regulations (see section 13). Do not allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance with local regulations. 7. HANDLING AND STORAGE Handling. Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Preparation may charge electrostatically: always use earthing leads when transferring from one container to another. Operators should wear anti- static footwear and clothing and floors should be of the conducting type. Keep container tightly closed. Isolate from sources of heat, sparks and open flame. No sparking tools should be used. Avoid skin and eye contact. Avoid inhalation of dust,particulates and spray mist arising from the application of this preparation. Avoid inhalation of dust from sanding. Smoking, eating and drinking should be prohibited in application area. For personal protection see Section 8. Never use pressure to empty : container is not a pressure vessel. Always keep in containers of same material as the original one. Comply with the health and safety at work laws. Storage. Although the storage and use of this product is not subject to specific statutory requirements, observation of the principles of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations as appropriate will be seen as good industrial practice in meeting the general duties of the Health and Safety at Work Act. Observe label precautions. Store between 15 and 30 ˚C in a dry, well ventilated place away from sources of heat and direct sunlight. Keep away from sources of ignition. Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : H129-1 KG FLEX B * Date: 19.01.09 Revision date: 02.01.08 page: 3/6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.

Exposure Limits. Occupational exposure limit for : EINECS-No. Names STEL LTEL 203-550-1 4-methylpentan-2-one 100.0 50.0 ppm

Personal Protection. Respiratory protection: If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators. Hand protection: For prolonged or repeated handling, use Nitril gloves. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Eye protection: Use safety eyewear designed to protect against splash of liquids. Skin protection: Personnel should wear anti-static clothings made of natural fibre or of high temperature resistant synthetic fiber. 9. PHYSICAL AND CHEMICAL PROPERTIES General information appearance : liquid colour : see product name odour : typical Important health, safety and environmental information Flash point : 120 ˚C DIN 53213 Ignition temperature : 448 ˚C Lower explosion limit : 1.2 Vol.% Upper explosion limit : 8.0 Vol.% Vapour pressure at 20 ˚C: 0.40 mbar Specific gravity at 20 ˚C: 0.97 g/cm³ Water solubility : insoluble Viscosity at 20 ˚C: 80 s 4 mm DIN 53211 Solvent-separation test : < 3 % ADR/RID Percent volatile by weight : 2 % 10. STABILITY AND REACTIVITY Stable under recommended storage and handling conditions (See section 7). When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide, smoke, oxides of nitrogen etc. Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. 11. TOXICOLOGICAL INFORMATION There are no data available on the preparation itself. The preparation has been assessed following the conventional methos of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See Chapter 3 and 15 for details.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : H129-1 KG FLEX B * Date: 19.01.09 Revision date: 02.01.08 page: 4/6 Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage.

Summarized evaluation of the CMR properties: EINECS-No. Names Classification REACH registration number The components in this formulation do not meet the criteria for classification as CMR category 1 or 2. 12. ECOLOGICAL INFORMATION The product should not be allowed to enter drains or water courses.

Results of PBT assessment: EINECS-No. Names Classification REACH registration number The components in this formulation do not meet the criteria for classification as PBT or vPvB.

The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and is classified for eco- toxicological properties accordingly. See Section 2 and 15 for details. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses. Wastes and emptied containers should are to be deposited according to the official rules. Code of waste Waste Designation: 080111 waste paint and varnish containing organic solvents or other dangerous substances 14. TRANSPORT INFORMATION Transport only in accordance with ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport. ADR/RID Class: 8 Hazard label(s): 8 UN-No: 2735 ADR hazard: 80 Transport document name: Amines, liquid, corrosive, n.o.s. contains: Trimethylhexamethylendiamin 4-Nonyl-phenol Packing group: III

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : H129-1 KG FLEX B * Date: 19.01.09 Revision date: 02.01.08 page: 5/6 IMDG Class: 8 Hazard label(s): 8 EmS: F-A, S-B UN-No: 2735 Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. contains: Trimethylhexamethylendiamin 4-Nonyl-phenol Packing group: III marine pollutant: n.a. ICAO/IATA Class: 8 Hazard label(s): 8 UN No: 2735 Proper shipping name: Amines, liquid, corrosive, n.o.s. contains: Trimethylhexamethylendiamin 4-Nonyl-phenol Packing group: III 15. REGULATORY INFORMATION Chemical Safety Assessment: EINECS-No. Names REACH registration number

In accordance with requirements of the Classification Packaging and Labelling of Dangerous Preparations Regulations (1999/45/EC). The product is labelled as follows: Danger classification : C Corrosive

Contains: Nonylphenol Tetradecylamin Trimethylhexamethylendiamin

R-phrases: 20/22 Harmful by inhalation and if swallowed. 34 Causes burns. 43 May cause sensitisation by skin contact. 53 May cause long-term adverse effects in the aquatic environment.

S-phrases: 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 38 In case of insufficient ventilation, wear suitable respiratory equipment. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 51 Use only in well-ventilated areas. 61 Avoid release to the environment. Refer to special instructions/safety data sheets. 23 Do not breathe vapour.

Special provisions concerning the labelling of preparations: n.a.

Material Safety Data Sheet according to the Regulation 1907/2006/EC (Annex II) Product Name : H129-1 KG FLEX B * Date: 19.01.09 Revision date: 02.01.08 page: 6/6 Information of VOC-properties: VOC(g/l) DIN ISO 11890: 19 VOC(g/l) ASTM D-3960-1: 19

16. OTHER INFORMATION Full text of R-phrases with no. appearing in section 3: 22 Harmful if swallowed. 36/38 Irritating to eyes and skin. 11 Highly flammable. 20 Harmful by inhalation. 36/37 Irritating to eyes and respiratory system. 66 Repeated exposure may cause skin dryness or cracking. 34 Causes burns. 50 Very toxic to aquatic organisms. 53 May cause long-term adverse effects in the aquatic environment. 35 Causes severe burns. 43 May cause sensitisation by skin contact. 52 Harmful to aquatic organisms.

The information of this SDS is based on the present state of our knowledge and on current EU and national laws. The product is not to be used for other purposes than those specified under section 1 without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this SDS is meant as a description of the safety requirements of our product: it is not to be considered as a guarantee of the products’ properties.

Safety Data Sheet Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Germany

Identification of the substance/preparation Product name or Trade name :

Use of the substance/preparation : Chemical product for construction and industry

Company/undertaking identification

The product is not classified as dangerous according to Directive 1999/45/EC and its amendments. See section 11 for more detailed information on health effects and symptoms.

Chemical family/ Characteristics

: Modified polyphosphate

[1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit Occupational exposure limits, if available, are listed in section 8.

First-aid measures Inhalation Ingestion

::

Obtain medical attention if symptoms occur. Do not induce vomiting unless directed to do so by medical personnel. open airway. Seek immediate medical attention.

Maintain an

Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Obtain medical attention if symptoms occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Eye contact :



Ingredient name CAS number % EC number Classification

tetrapotassium pyrophosphate pentasodium hydrogen C,C',C''- nitrilotris(methylphosphonate) See section 16 for the full text of the R- phrases declared above

7320-34-5 2235-43-0

10-20 1-5

230-785-7 218-791-8

Xi; R36 [1] Xi; R36 [1]

3. COMPOSITION/INFORMATION ON INGREDIENTS

2. HAZARDS IDENTIFICATION

Manufacturer/Distributor : Street/postbox : Town/City and Post Code : Country : Telephone no. : Fax no. : e-mail address of person : responsible for this SDS Emergency telephone number :

Sika Deutschland GmbH Kornwestheimer Str. 103-107 70439 Stuttgart DE +4971180090 +497118009321 [email protected]

+49-(0)173-6774799 (Only out of office hour)

Sika® Verzögerer VZ 10

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

See section 11 for more detailed information on health effects and symptoms.

Extinguishing media Suitable Not suitable

Special exposure hazards Hazardous combustion products

::::

Use an extinguishing agent suitable for the surrounding fire. None known. In a fire or if heated, a pressure increase will occur and the container may burst.Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides phosphorus oxides metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

:

Personal precautions : Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Put on appropriate personal protective equipment (see section8). Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container.

Environmental precautions :

Large spill :

Small spill :

Handling : Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Avoid contact with eyes, skin and clothing. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

Storage :

Packaging materials Recommended : Use original container.


7. HANDLING AND STORAGE

6. ACCIDENTAL RELEASE MEASURES

5. FIRE-FIGHTING MEASURES

Sika® Verzögerer VZ 10 20.05.2009 2/5


Exposure limit values

Recommended monitoring procedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Exposure controls Occupational exposure controls

: Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. No special measures required. hemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: Butyl rubber/nitrile rubber gloves. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Use barrier skin cream. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Hygiene measures :

Respiratory protection Hand protection :

Eye protection

Skin protection :

Environmental exposure controls

:

General information Appearance Form Colour Odour

:::

Liquid. Colourless. Characteristic.

Important health, safety and environmental informationpH Flash point Density Solubility

: 10 : Closed cup: >100°C (>212°F) : ~1.11 g/cm3 [20°C (68°F)] : Soluble in the following materials: water


9. PHYSICAL AND CHEMICAL PROPERTIES

Ingredient name Occupational exposure limits No exposure limit value known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Stability Conditions to avoid Materials to avoid Hazardous decomposition products

: The product is stable.:::

No specific data. No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Potential acute health effects Inhalation Ingestion Skin contact Eye contact

Chronic effects

::::

:

May cause irritation. Can cause gastrointestinal disturbances. May cause skin irritation. May cause eye irritation.


Environmental effects : Avoid contact of spilt material and runoff with soil and surface waterways. Do not empty into drains; dispose of this material and its container in a safe way.

Methods of disposal : Completely emptied packagings can be given for recycling. Packaging containing remains of dangerous substances, as well as packagings disposed of remains can be unharmed eliminated in accordance with the regulations.

Completely emptied packagings may be given for recycling. Empty packaging may still contain hazardous residues. Empty packaging should be removed by a licensed

waste contractor.

Sika has agreed disposal contracts for all packaging which is brought into circulation in Germany.

Packaging :

For further details see www.sika.de

International transport regulations

ADR Not regulated. Proper shipping name

IMDG Not regulated. Marine pollutant

IATA Not regulated.

:

: No.


14. TRANSPORT INFORMATION

13. DISPOSAL CONSIDERATIONS

12. ECOLOGICAL INFORMATION

11. TOXICOLOGICAL INFORMATION


10. STABILITY AND REACTIVITY

EU regulations Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC (including amendments) and take into account the intended product use.

Classification VOC content (EU)

National regulations

Hazard class for water

: This product is not classified according to EU legislation. : VOC (w/w): 0%

: 1 Appendix No. 4 (Gemäß VwVws vom 17. Mai 1999)

Full text of classifications referred to in sections 2 and 3 Full text of classifications referred to in sections 2 and 3

: R36- Irritating to eyes.

: Xi - Irritant

History Date of printing Date of issue Date of previous issue

:::

20.05.2009. No previous validation.

Indicates information that has changed from previously issued version. Notice to reader

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to any use and processing.


18.02.2013

16. OTHER INFORMATION


15. REGULATORY INFORMATION

Full Kagetec MSDS - Kagetec Industrial Flooring

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