FLAME RETARDANTS - Tri- · PDF filePolymeric flame retardants are sustainable products in...

FLAME RETARDANTS

Brominated Flame Retardants

Phosphorus Flame Retardants

Magnesium Flame Retardants

Nitrogen Flame Retardants

35

Br79.90

15

P30.97

12

Mg24.31

7

N14.01

ICL INDUSTRIAL PRODUCTS

Caring For Your Future Today

ICL Industrial Products (ICL-IP), which manufactures products to enhance safety and human well being, is the industrial chemicals sector of Israel Chemicals Limited (ICL). ICL-IP is the world’s largest producer of elemental bromine, and a leader in the production and marketing of bromine and bromine compounds, supplying over 33% of global demand. It also has a leading position in the manufacturing of phosphorus-based compounds for fire safety.

Resources and Quality

The Dead Sea, which has the world’s highest concentration of bromine, is a virtually unlimited source of supply. These rich natural resources, together with a highly professional workforce, enable ICL–IP to produce bromine and bromine-based chemicals as well as minerals of the highest quality, in the most efficient manner. Cutting-edge technology tamed by talented, knowledgeable and dedicated teams of individuals has further inspired ICL-IP to integrate the complementary chemistry of phosphorus.This has resulted in diverse eco-friendly uses in industries such as flame retardants, plasticizers, hydraulic fluids, organic intermediates, water treatment, pharmaceutical chemicals, stabilizers, curing activators, viscosity enhancers, refractory materials, etc.

Unique Customer Service

ICL–IP offers its customers the advantages of geographic proximity to major markets, internationally-based subsidiaries coordinating the supply of finished products to the customers’ doorstep, experienced technical support, and a workforce fully committed to quality and the protection of the environment.

Global Production and Marketing Facilities

ICL–IP operates the world’s largest elemental bromine production plant at the Dead Sea. The company’s bromine compounds plants in Israel and the Netherlands, along with Sinobrom, a JV in China, offer customer-oriented manufacturing facilities based on long-standing technological expertise. ICL-IP is the industry leader in the manufacture, distribution and service of phosphorus-based flame retardants, plasticizers, lubricants and hydraulic fluids, with production plants in the US, Germany and China. The company’s worldwide marketing subsidiaries are: ICL-IP Europe B.V., The Netherlands; ICL-IP Israel Sales Office; ICL-IP America Inc., USA; ICL-IP Japan Ltd., Japan; ICL Asia Ltd., Hong-Kong, ICL China, PR China and ICL Brazil, Brazil.

Safety, Ecology and Quality Assurance

Strict adherence to international regulations on safety and environmental issues are core policies at ICL-IP, whose major plants have been granted ISO 14001 and OHSAS 18001 accreditation for Environmental and Safety Management Systems. ICL-IP utilizes Total Quality Management, Lean and Six Sigma methodologies across its plants worldwide to ensure consistent quality and to achieve improvements in its processes. ICL-IP supports the goals of the new EU regulation, Registration, Evaluation, Authorization and Restriction of Chemicals (REACH Regulation, EC 1907/2006), which came into force on June 1, 2007. This regulation ensures the protection of human health and the environment, while minimizing animal testing and maintaining the competitiveness of the European chemical industry. ICL-IP will fully comply with the requirements of REACH, and all other regulatory systems worldwide, for all its existing and new flame retardants. Furthermore, ICL-IP has actively initiated and developed a program to reduce waste production and environmental emissions through a code of good practice known as the Voluntary Emission Control Action Program – VECAP.

Dear customer!This brochure is designed as a working tool for your needs in flame retardancy. We, at the Flame Retardant Business Unit (FR BU) of ICL–IP, offer the plastics industry the most effective flame retardants that help enhance consumer safety, while being committed to environmental concerns. We invite you to make use of this brochure, benefit from our wide range of flame retardant solutions and contact us for updates of current activities and future developments.

Response to needs of Markets and IndustriesThe FR BU takes an in-depth view of the plastic industry’s supply chain, so that its products and solutions are directly responsive to each market segment’s special needs and challenges. We continuously study and monitor the requirements and trends of these market segments, including those of their supporting industries, which enables us to offer a valuable contribution to our customers by meeting their current needs and future requirements.

Flame Retardants for Most ApplicationsUsing the vast natural resource of bromine and minerals in the Dead Sea, ICL-IP produces a series of high-quality flame retardant products, applicable to a wide range of plastics, polymers and polymer alloys. ICL-IP also offers the world’s most comprehensive range of phosphorus-based flame retardants, fire resistant plasticizers and hydraulic fluids for high demanding applications. Bromine- and Phosphorus-based flame retardants are considered as the two most efficient FR families, and in fact, constitute approximately 55% (in value) of total FR usage. ICL–IP’s portfolio also includes a few additional non-halogen- and non-phosphorus-based FRs such as high purity grades of Magnesium Hydroxide and Melamine Cyanurate.

Polyquel™, and SeriesAs a part of the FR BU’s focus on market needs, we have initiated a unique approach by developing tailormade solutions:• Polyquel™ is a new, fully active and dust-free polymeric flame retardant series, constituting a step

forward in complying with the industry’s most stringent environmental guidelines such as European REACH and US TSCA legislations.

• SaFRon® series for high demanding polyurethane foam applications.• TexFRon® series for high quality textile coating applications..

Polymeric Flame Retardants for SustainabilityPolymeric flame retardants are sustainable products in accordance with many national and international human health and environmental regulations. They have long been recognized as the safest and most “elegant” flame retardants of high molecular weight man-made materials. Non-leachingDue to their low solubility in water, polymeric flame retardants, once incorporated into the end-product plastic matrix, become integrated with the plastic and leaching is not expected to occur.Non-bio-accumulativeTheir high molecular weight makes them unlikely to penetrate through the cell membranes of living tissues. Non-bloomingFurthermore, they do not migrate to the surface of the plastic during aging, thus eliminating any potential blooming in the finished product.

ICL-IP is promoting several ranges of brominated polymeric flame retardants for most applications:• FR-1025: brominated polyacrylate• F-2000 series: brominated epoxy polymers with a wide range of molecular weight• F-3000 series: end-capped brominated epoxy polymers with various molecular weights• FR-803P: brominated polystyrene• FR-122P: Brominated butadiene / styrene block copolymer.

SELECTION TABLE

BROMINATED FLAME RETARDANTS

FR-11

FR-122P

FR-245

FR-370

FR-513

FR-522

FR-613

FR-720

FR-803P

FR-1025

FR-1206

FR-1210 *

FR-1410

FR-1524

* Not sold in the US for most applications and in Europe if RoHS compliance is needed

APPLICATIONS

BROMINATED EPOXY FLAME RETARDANTS

F-2001

F-2200HM

F-2016

F-2100, F-2400

F-3014, F-3020

F-3100

TAILOR MADE FR SOLUTIONS

PolyquelTM 140

PolyquelTM 145

PolyquelTM 240, PolyquelTM 241

6605

series

HIPS

EPS /

XPS

ABS

Polye

thyle

ne

Polyp

ropy

lene

PBT

/ PET

Nylo

n =

Polya

mid

e

PC /

PC A

BS

Allo

ys

PVC

/ Fle

xible

Rubb

ers /

Elas

tom

ers

Epox

y Res

ins

Phen

olic

Resin

s

Unsa

tura

ted

Polye

ster

s

Flexib

le P

UF

Rigi

d PU

F

Chip

/ Pa

rticle

Boa

rds

Text

iles /

Fibe

rs

Late

x / A

dhes

ives

HIPS

/ PP

O

EPS /

XPS

ABS

Polye

thyle

ne

Polyp

ropy

lene

PBT

/ PET

Nylo

n =

Polya

mid

e

PC /

PC A

BS

Allo

ys

PVC

/ Fle

xible

Rubb

ers /

Elas

tom

ers

Epox

y Res

ins

Phen

olic

Resin

s

Unsa

tura

ted

Polye

ster

s

Flexib

le P

UF

Rigi

d PU

F

Chip

/ Pa

rticle

Boa

rds

Text

iles /

Fibe

rs

Late

x / A

dhes

ives

Cellu

losic

Plasti

c Com

posit

e

INORGANIC FLAME RETARDANTS

FR-20

FR-1120 (synergist)

FYROLFLEX™Fyrolflex RDP/ RDP-HP

Fyrolflex Sol-DP

PHOSPHORUS FLAME RETARDANTS

PHOSFLEX™

LINDOL™Lindol

Lindol XP Plus

Fyrol FR-2/ Fyrol 38 (low scorch version of Fyrol FR-2)

Fyrol HF-4

Fyrol HF-5 / HF-5HP

Fyrol 6

Fyrol A300TB

Fyrol PCF

Fyrol P26

Fyrol PNX

Fyrol PNX-LE (Low Emission)

FYROL™ SERIES

FOR MORE INFORMATION VISIT OUR WEBSITE: WWW.ICLFR.COM

PHOSFLEX™Phosflex 4

Phosflex T-BEP

Phosflex 31L/41L

Phosflex 375

Phosflex 71B

Phosflex 362

Phosflex 390

Phosflex 418

PRODUCTS & PROPERTIES

BROMINATED FLAME RETARDANTS

M.W. SPECIFICGRAVITY

BROMINECONTENT

MELTINGRANGE/POINT-

SOFTENING RANGE

TGA%WT. LOSS @ TEMP.

FR-11Ammonium bromideAPPLICATIONS: Chipboard, Wood Paper, Textile

NH4Br

CAS No. 12124-97-9

98 2.43 81% M.P.452°C

FR-122P ( polymer)Polymeric FRAPPLICATIONS: EPS and XPSADVANTAGES: non blooming, non leachable, low loading and good FR efficiency

CAS No. 1195978-93-8

100000 1.6 65% S. R.120-140

2% @ 243°C5% @ 257°C

10% @ 264°C

FR-245Tris(tribromophenoxy) triazineAPPLICATIONS: HIPS, ABSADVANTAGES: combination of good flow and impact, UV and thermal stability, non-blooming

Br Br

O N O Br

Br Br N N Br

O Br Br

BrCAS No. 25713-60-4

1067 2.44 67% M.P.230°C

2% @ 360°C5% @ 385°C

10% @ 400°C

FR-370Tris(tribromoneopentyl) phosphateAPPLICATIONS: PP, HIPS, ABS, XPS, Alloys, Adhesives, Fibers ADVANTAGES: UV and light stability, non-blooming

CH2Br |

O=P– OCH2–C–CH2Br |

CH2Br 3

CAS No. 19186-97-1

1018.5 2.30 70%(3% P)

M.P.181°C

1% @ 282°C5% @ 309°C

10% @ 319°C

FR-513Tribromoneopentyl alcoholAPPLICATIONS: PU rigid andflexible foams, FR intermediateADVANTAGES: meets high FRstandards, high thermal stability,non-leaching, reactive

CH2Br |

HO–CH2–C–CH2–Br |

CH2Br

CAS No. 36483-57-5

324.9 2.30 73% M.P.65°C

2% @ 135°C5% @ 152°C

10% @ 166°C

FR-522Dibromoneopentyl glycolAPPLICATIONS: UPE, PU rigid foamsADVANTAGES: high level of flame retardancy, light stability,transparency, reactive, non-leaching

CH2Br |

HO–CH2–C–CH2–OH |

CH2Br

CAS No. 3296-90-0

261.9 2.23 60% M.P.109.5°C

2% @ 200°C5% @ 225°C

10% @ 245°C

FR-613TribromophenolAPPLICATION: FR Intermediate, end capping of brominated epoxiesADVANTAGES: non-leaching

OHBr Br

Br

CAS No. 118-79-6

330.8 2.55 72% M.P.93°C

5% @ 120°C10% @ 132°C

FR-720Tetrabromobisphenol A -bis(2,3 dibromopropyl ether)APPLICATIONS: PP, HIPS, ABSADVANTAGES: good FR efficiency and thermal stability

Br CH3 Br

BrCH2CHCH2O C OCH2CHCH2Br Br CH3

Br Br Br

|

|| |

CAS No. 21850-44-2

943.2 2.30 68% M.R.113-117°C

1% @ 291°C5% @ 306°C

10% @ 313°C

BROMINATED AND BROMINATED EPOXY FLAME RETARDANTS M.W. SPECIFIC

GRAVITY BROMINECONTENT

MELTINGRANGE/POINT-

SOFTENING RANGE


FR-803P (polymer)Brominated polystyreneAPPLICATIONS: Nylon, PBT, PETADVANTAGES: good CTI, thermal stability, non-blooming

–CH–CH2– n

x=2.7

\ Brx

CAS No. 88497-56-7

600000 2.1 66%min.

S.R.265-324°C

2% @ 340°C5% @ 358°C

10% @ 374°C

FR-1025 (polymer)Brominated polyacrylateAPPLICATIONS: PBT, Nylon, AlloysADVANTAGES: excellent thermalaging, CTI, good impact, compatibility with fiber reinforcement and recycling

—CH2—CH—n |

C=O Br\ /Br |

O —CH2— —Br Br/ \Br

CAS No. 59447-57-3

600000 2.50 71% M.R.190-220°C

2% @ 320°C5% @ 330°C

10% @ 335°C

FR-1206HexabromocyclododecaneAPPLICATIONS: EPS, XPSADVANTAGES: high purity, low loading and good FR efficiency

Br\ /Br

Br/ / \ \Br Br Br

CAS No. 3194-55-6

641.7 2.18 73% M.R.175-185°C

2% @ 243°C5% @ 247°C

10% @ 249°C

FR-1210*Decabromodiphenyl oxideAPPLICATIONS: HIPS, PE, PP, ABS,PBT, UPE, Epoxy, Nylon 6, TextilesADVANTAGES: FR efficiency, exceptional thermal stability and multi-purpose.

Br\ /BrBr— —O Br/ \Br

Br\ /Br — —Br Br/ \Br

CAS No. 1163-19-5

959.2 3.45 83% M.P.305°C

1% @ 322°C5% @ 362°C

10% @ 385°C

FR-1410Decabromodiphenyl ethaneAPPLICATIONS: HIPS, PE, PP, PBT, nylon, UPE, EpoxyADVANTAGES: FR efficiency, exceptional thermal stability and multi-purpose

Br BrC CH H

H H

Br Br

Br Br

Br Br

Br Br

CAS No 84852-53-9

971.2 3.25 82% M.P.>350

2% @ 322°C5% @ 345°C

10% @ 360°C

FR-1524Tetrabromobisphenol-AAPPLICATIONS: Epoxy, Polycarbonate Resins, ABSADVANTAGES: high reactivity, lowcolor, high clarity, good FR efficiencygood solubility

/Br — —OH \Br

Br\ CH3 |

HO— —C |

Br/ CH3

CAS No. 79-94-7

543.7 2.17 58.5% M.P.181°C

2% @ 262°C5% @ 284°C

10% @ 301°C

* Not sold in the US for most applications and in Europe if RoHS compliance is needed

F-2000 SERIES - Brominated Epoxy - Low molecular weight

F-2001APPLICATIONS: Unsaturated polyester and vinyl ester resinsADVANTAGES: High UV stability, solubilty in styrene

/Br OH |

— —O CH \ / \

\Br CH2 CH2— — n

Br\ CH3 |

—O— —C |

Br/ CH3

CAS No. 68928-70-1

1000 1.80 49-51% M.R.60-70°C

1% @ 280°C5% @ 320°C

10% @ 340°C

F-2200 HM (Proprietary)APPLICATIONS: XPS, HIPS,PolyolefinsADVANTAGES: Thermal stabilizer, corrosion resistant, processing aid

/Br OH |

— —O CH \ / \


Br\ CH3 |

—O— —C |

Br/ CH3

CAS No. 3072-84-2

700 1.80 48% M.R.108-118°C

1% @ 289°C5% @ 326°C

10% @ 343°C



BROMINATED EPOXY FLAME RETARDANTS


BROMINECONTENT

SOFTENINGRANGE/TG


F-2000 SERIES - Brominated Epoxy polymer*

CAS No. 68928-70-1

F-2016 (polymer)APPLICATION: ABSADVANTAGES: good processability, high thermal and UV stability, non-blooming

1600 1.80 50% S.R.105-121°C

2% @ 328°C5% @ 348°C

10% @ 363°C

F-2100L (polymer)APPLICATIONS: PBT, PC/ABSADVANTAGES: high thermal and UV stability, non-blooming, non corrosive, excellent processability

10000 1.80 52% 170-190°C 1% @ 355°C5% @ 364°C

10% @ 361°C

F-2100 (polymer)APPLICATIONS: PBT, PC/ABSADVANTAGES: high thermal and UV stability, non-blooming, non-corrosive, excellent processability

20000 1.80 52% S.R.180-205°C

1% @ 350°C5% @ 357°C

10% @ 361°C

F-2100H (polymer)APPLICATIONS: PBT, PET, Alloys (PC/ABS)ADVANTAGES: good mechanical, physical and flow properties, high thermal and UV stability

25000 1.80 52% Tg130-150°C

2% @ 348°C5% @ 355°C

10% @ 359°C

F-2400E (polymer)APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABSADVANTAGES: high thermal and UV stability, non-blooming, excellent processability

32000 1.80 53% Tg145-155°C

2% @ 345°C5% @ 352°C

10% @ 357°C

F-2400 (polymer)APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABSADVANTAGES: high thermal and UV stability, non-blooming, excellent processability

50000 1.80 53% Tg145-155°C

2% @ 345°C5% @ 352°C

10% @ 357°C

F-2400H (polymer)APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABSADVANTAGES: high thermal and UV stability, non-blooming, excellent processability

58000 - 68000

1.80 53% Tg145-155°C

2% @ 345°C5% @ 352°C

10% @ 357°C

F-3000 SERIES - End capped Brominated Epoxy*

F-3014APPLICATIONS: HIPS, ABSADVANTAGES: good processability, non-blooming, high thermal and UV stability, good HDT impact strength, low metal adhesion CAS No. 158725-44-1

1400 1.90 60% S.R.87-105°C

2% @ 293°C5% @ 330°C

10% @ 350°C

F-3020 (polymer)APPLICATIONS: HIPS, ABSADVANTAGES: good processability, nonblooming, hight thermal and UV stability, good HDT impact strength, low metal adhesion CAS No. 135229-48-0

2000 1.90 56% S.R.105-120°C

2% @ 290°C5% @ 318°C

10% @ 349°C

F-3100 (polymer)APPLICATIONS: PBT, Nylon, Alloys, ABSADVANTAGES: processing - aid, excellent flow properties, non-blooming low metal adhesion and good thermal and UV stability CAS No. 135229-48-0

15000 1.90 53% S.R.180-220°C

2% @ 343°C5% @ 352°C

10% @ 358°C

* Molecular weight can be tailored to specific requirements

/Br OH |

— —O CH \ / \


Br\ CH3 |

—O— —C |

Br/ CH3

OH |

CH / \ Br CH2 CH2 Br | / \ | /O O\

/ \ / \Br Br Br C / \ H3C CH3 n

OH |

CH / \ Br CH2 CH2 Br | / \ | /O O\

/ \ / \ Br Br Br


SPECIFICGRAVITY

PHOSPHORUSCONTENT

CHLORINECONTENT

VISCOSITYmPa.s - 25°C


FYROL™ SERIES

Fyrol FR-2/Fyrol 38*Tris (1,3-dichloroisopropyl) phosphateAPPLICATIONS: Flexible PU foam, epoxy resin and phenolics, unsaturated polyestersADVANTAGES: Excellent processing, good thermal and hydrolytic stability, low fogging* Fyrol 38 is a low scorch version of Fyrol FR-2

O CH2Cl|| /P–O–CH \ CH2Cl 3

CAS No. 13674-87-8

1.52 7.1% 49.0% 1800 2% @ 205°C5% @ 225°C

10% @ 240°C

Fyrol HF-4Proprietary halogen-free flame retardantAPPLICATIONS: Flexible PU foamADVANTAGES: Excellent processing, low viscosity, low scorch.

Proprietary stabilized flame retardant

1.18 8.5% 70 2% @ 215°C5% @ 235°C

10% @ 250°C

Fyrol HF-5 / HF-5HPProprietary halogen-free FR additiveAPPLICATIONS: Flexible PUFADVANTAGES: FR efficiency, low viscosity, low fogging and low VOC emissions

Proprietary

1.3 14% 900 2% @ 169°C5% @ 213°C

10% @ 259°C

Fyrol 6Diethyl N,N bis (2-hydroxyethyl) amino-methylphosphonateAPPLICATIONS: Reactive non halogen FR for rigid PU foam and urethane elastomersADVANTAGES: Excellent for spray, pour-in-place systems and slab foams permanency in PU foams

O C2H4–OH || /

C2H5–O–P–CH2–N | \

O C2H4–OH |

C2H5

CAS No. 2781-11-5

1.16 12.0% 200 5% @ 170°C10% @ 195°C

Fyrol A300TBProprietary chloralkyl phosphate blendAPPLICATIONS: Flexible PU foam for automotive applicationsADVANTAGES: Easy processing, meeting the fogging requirement of the automotive industry

Proprietary chloroalkyl phosphate ester blend

1.48 7.1% 47% 1050 2% @ 195°C5% @ 215°C

10% @ 235°C

Fyrol PCFTris 2-chloroisopropyl phosphate.APPLICATIONS: Isocyanurate and rigid PU foams, flexible PU foam (BS5852), unsaturated polyesters and phenolicsADVANTAGES: Excellent thermal and hydrolytic stability, low viscosity

O CH2Cl|| /P–O–CH \ CH3 3

CAS No. 13674-84-5

1.29 9.5% 32.5% 65 2% @ 145°C5% @ 165°C

10% @ 180°C

Fyrol P26ProprietaryAPPLICATIONS: PE, PP, PBT, nylon, UPE, EpoxyADVANTAGES: FR efficiency, FR synergist, high thermal stability and transparency

Proprietary

1.31 26% not melting solid

2% @ 295°C5% @ 310°C

10% @ 320°C




SPECIFICGRAVITY

PHOSPHORUSCONTENT

VISCOSITYmPa.s - 25°C

MELTING RANGE


FYROL™ SERIES

Fyrol PNXOligomeric ethyl ethylene phosphateAPPLICATIONS: Flexible PU foam, paper treatmentADVANTAGES: very high efficiency, low VOC/FOG

O O || ||

C2H5–O–P–O–(CH2)2–O–P–O–C2H5 | n |

O O | |

C2H5 C2H5

CAS No. 184538-58-7

1.31 19% 1000 2% @ 185°C5% @ 215°C

10% @ 235°C

Fyrol PNX-LE (Low Emission)Modified oligomeric ethyl ethylene phosphateAPPLICATIONS: Flexible PU foam, ADVANTAGE: Low emission version of Fyrol PNX, low fogging/VOC for automotive

CAS No. 184538-58-7

1.31 19% 2250 2% @ 185°C5% @ 215°C

10% @ 235°C

FYROLFLEX™ SERIESFyrolflex RDP/RDH-HPResorcinol bis(diphenyl phosphate)APPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, styrenics, phenolic laminatesADVANTAGES: High efficiency, high thermal stability

O ||

–O–P–O\ |

O |

O ||

/O–P–O– n |

O |

CAS No. 125997-21-9

1.31 10.7% 105 @ 55°C 2% @ 290°C5% @ 325°C

10% @ 360°C

Fyrolflex Sol-DPProprietary aromatic phosphateAPPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, UL94/V-2 ABS, processing aid for engineering resinsADVANTAGES: Easy to handle solid free-flowing powder, high efficiency and good hydrolytic stability

Proprietary free-flowing powder, dust free powder

1.30 10.7% M.P.105-108°C

2% @ 300°C5% @ 335°C

10% @ 350°C

PHOSFLEX™ SERIES

Phosflex 4Tributyl phosphate APPLICATIONS: De-airing additive, extraction agent in metal and phosphoric acid production, high-boiling solvent for inks and paints.ADVANTAGE: Low viscosity

O||

P–O–C4H9 3

CAS No. 126-73-8

0.98 11.7% 5 2% @ 115°C5% @ 135°C

10% @ 150°C

Phosflex T-BEPTris(butoxyethyl) phosphateAPPLICATIONS: Emulsions of floor finishes, leveling agent in latex paints, processing aid for acrylonitrile rubber, antiblock agent for cast polyurethanesADVANTAGE: Low viscosity

O||

P–O–(CH2)2–O–C4H9 3

CAS No. 78-51-3

1.02 7.8% 12 2% @ 170°C5% @ 200°C

10% @ 225°C

Phosflex 31L/41LIsopropylated triphenyl phosphate mixture APPLICATIONS: PVC film and sheeting compounds, PVC plastisols.ADVANTAGES: High thermal stability, good solvating properties

O ||

–O–P–O– CH3

n \ /

CH / H3C

3-n

CAS No. 68937-41-7

1.18 8.3% 60 2% @ 210°C5% @ 230°C

10% @ 245°C


SPECIFICGRAVITY

PHOSPHORUSCONTENT

VISCOSITYmPas - 25°C


Phosflex 375Proprietary plasticizer blend of alkyl diphenyl phosphate and triaryl phosphate ester.APPLICATIONS: PVC films and sheeting compounds, PVC plastisols. ADVANTAGES: Blended alternative FR plasticizer for isopropylated TPPs, excellent FR

1.15 8.3% 48 2% @ 219°C5% @ 240°C

10% @ 257°C

Phosflex 71Bt-Butylated triphenyl phosphate mixtureAPPLICATIONS: Plasticizer for PVC and PVC foams, polyvinyl acetate emulsion, FR for modified HIPSADVANTAGE: High thermal stability

O ||

–O–P–O– CH3

n \ /

C / \ H3C CH3

3-n

CAS No. 56803-37-3 and 65652-41-7 and 78-33-1

1.18 8.5% 70 2% @ 215°C5% @ 235°C

10% @ 250°C

Phosflex 3622-ethylhexyl diphenyl phosphateAPPLICATIONS: Plasticizer for PVC (plastisols, textile coatings), and vinyl/nitrile rubber foamed alloys, cellulosic polymers, PMMA, PSADVANTAGES: Good performance at low temperature, low smoke, FDA approved in coatings for food packaging.

O C2H5 || |

–O–P–O–CH2–CH–(CH2)3–CH3

2

CAS No. 1241-94-7

1.09 8.5% 18 2% @ 180°C5% @ 200°C

10% @ 210°C

Phosflex 390Isodecyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting, foamed vinyl/nitrile rubber alloys, wire insulation, coatings for apparel and upholstery, polyvinyl acetate adhesives ADVANTAGES: Good performance at low temperature, low smoke

O ||

–O–P–O–C10H21

2

CAS No. 29761-21-5

1.07 7.9% 26 2% @ 205°C5% @ 220°C

10% @ 235°C

Phosflex 418Linear alkyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting and wire insulation ADVANTAGES: Excellent plasticizing efficiency at low temperature, low smoke and low volatility

O ||

–O–P–O–(CH2)11-13–CH3

2

CAS No 27460-02-2,142474-86-0

and 56827-92-0

1.04 7.2% 24 5% @ 215°C10% @ 235°C

LINDOL™ SERIES

Lindol & Lindol XP PlusTri(m,p-cresyl) phosphate mixtureAPPLICATIONS: Plasticizer for PVC, synthetic rubber, cellulosic films, FR for phenolic laminatesADVANTAGE: High efficiency

O||

P–O– \ CH3 3

CAS No. 1330-78-5

1.17 8.4% 65 2% @ 220°C5% @ 235°C

10% @ 250°C

PHOS-CHEK™ SERIES

Phos-Chek™ products are efficient intumescent Flame Retardants for application in paints, coatings, polyolefins, polyurethanes andthermosets. Selected ICL-IP Subsidiaries have distribution agreements with ICL - Performance Products LP, the producer ofPhos-Chek™.For more information, visit the website: www.phoschek.comor contact one of the following addresses: [email protected], [email protected]



MINERAL AND NITROGEN FLAME RETARDANTS


AVG.PARTICLE

SIZE

BULKDENSITY

kg/m3


INORGANIC FLAME RETARDANTS

FR-20Magnesium HydroxideGRADES:S5 (BET 5 m2/g) uncoated or coatedS7 (BET 7 m2/g) uncoated or coatedS10 (BET 10 m2/g) uncoated or coatedAPPLICATIONS: Wire and Cables, Electrical connectors, TPO for roofing, Foils and sheets, LD and HDPE, PP, Soft PVC, PAADVANTAGES: excellent smoke suppressant, acid scavenger, thermal stability, The following coating and surface treatments are available: stearic acid, vinyl silane, aminosilane, polymeric.

Mg(OH)2

CAS No. 1309-42-8

58.3 2.36

1.8-2.2 µm1.5-1.8 µm1.1-1.4 µm

0.5-0.7 2% @ 370°C5% @ 385°C

10% @ 402°C

FR-1120Calcium Borateon on a silicate carrier.APPLICATIONS: Antimony Trioxidereplacement in polyolefins, polyamides, styrenics and polyesters. Zinc Borate replacement in polyolefins and PVC.ADVANTAGES: Highly cost-efficient.

CAS No. 13701-64-9

2.6 6 µm 0.6-0.7 2% @ 253°C5% @ 319°C

10% @ 392°C

POLYQUEL™, AND SERIES TAILOR-MADE SOLUTIONS

HIPS

/ PP

O

EPS /

XPS

ABS

Polye

thyle

ne

Polyp

ropy

lene

PBT

/ PET

Nylo

n =

Polya

mid

e

PC /

PC A

BS

Allo

ys

PVC

/ Fle

xible

Rubb

ers /

Elas

tom

ers

Epox

y Res

ins

Phen

olic

Resin

s

Unsa

tura

ted

Polye

ster

s

Flexib

le P

UF

Rigi

d PU

F

Chip

/ Pa

rticle

Boa

rds

Text

iles /

Fibe

rs

Late

x / A

dhes

ives

Cellu

losic

Plasti

c Com

posit

e

POLYQUEL™, AND SERIESDDDDDD

POLYQUEL™ 140 PPPPPPEEEEEE

DPOLYQUEL™ 145

P

DD

POLYQUEL™ 240 & 241 PPUU

E 6605E

9000 and 3000 SeriesT

PE

P Series TP

Polyquel™ series, fully active and dust-free polymeric FR systems, is a step forward to more Eco-reliable and Sustainable Fire Safety.The range of and Series is a milestone offering continuously innovative solutions to the identified needs of customers. These tailor-made solutions address specific targets related to fire safety, easier handling, low corrosion, high flow, light and UV stability and/or antimony trioxide free products.The FR BU’s solutions are opening up new fields of application.The following table shows some of our new commercial Polyquel™, and :

Strengths:U - UV stabilityA - Antimony oxide freeE - FR efficiencyT - Thermal stability

D - Dust-freeP - Polymer & Non-blooming

APPLICATIONS

THERMOPLASTICS AND STYRENIC ALLOYS

HIPS V-2

Sol-DP FR-720 FR-1410 FR-245 FR-370

PROPERTIES

THERMAL STABILITY ✓✓✓ ✓✓ ✓✓✓ ✓✓✓ ✓✓

MELT FLOW ✓✓✓ ✓✓✓ ✓ ✓✓

FR EFFICIENCY ✓✓✓ ✓✓ ✓✓

IMPACT ✓ ✓✓✓ ✓ ✓ ✓✓✓

UV / LIGHT STABILITY ✓✓ ✓ ✓✓ ✓✓✓

HEAT DISTORTION TEMP. ✓ ✓ ✓✓

NON-BLOOMING ✓✓ ✓✓ ✓✓ ✓✓

COST EFFICIENCY ✓✓ ✓✓ ✓✓ ✓✓

DUST-FREE ✓✓✓


HIPS V-1/V-0

FR-1410 FR-245 F-3000 PolyquelTM 240 PolyquelTM 241

PROPERTIES

THERMAL STABILITY ✓✓✓ ✓✓✓ ✓✓ ✓✓✓ ✓✓✓

MELT FLOW ✓✓ ✓✓✓ ✓

FR EFFICIENCY ✓✓ ✓✓✓ ✓ ✓✓ ✓✓

IMPACT ✓✓ ✓✓✓ ✓✓ ✓✓

UV / LIGHT STABILITY ✓✓ ✓✓ ✓✓✓ ✓✓✓

HEAT DISTORTION TEMP. ✓✓ ✓✓✓ ✓ ✓✓✓ ✓✓✓

NON-BLOOMING ✓✓ ✓✓✓ ✓✓✓ ✓✓✓

COST EFFICIENCY ✓✓✓ ✓✓✓ ✓

RECYCLING ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

DUST-FREE ✓✓✓ ✓✓✓

✓ good✓✓ very good✓✓✓ excellent

APPLICATIONS

THERMOPLASTICS AND STYRENIC ALLOYS


PC/ABS and HIPS/PPO alloys V-1/V-0

FyrolflexRDP /RDP-HP

FyrolflexSol-DP

Phosflex71B

F-3000

PROPERTIES

PHOSPHORUS (P)/BROMINE (Br) BASED P P P Br

THERMAL STABILITY ✓✓ ✓✓ ✓ ✓✓✓

MELT FLOW ✓✓ ✓✓ ✓✓✓ ✓

FR EFFICIENCY ✓✓✓ ✓✓✓ ✓✓ ✓✓✓

IMPACT ✓✓ ✓✓ ✓ ✓✓✓

UV / LIGHT STABILITY ✓✓✓ ✓✓✓ ✓✓✓ ✓✓

HYDROLYTIC STABILITY ✓✓ ✓✓ ✓✓✓

HEAT DISTORTION TEMP. ✓ ✓ ✓✓✓

NON-PLATE-OUT ✓✓ ✓✓✓ ✓ ✓✓✓

COST EFFICIENCY ✓✓ ✓ ✓✓ ✓✓✓

LIQUID/SOLID HANDLING Liquid Solid Liquid Solid

ABS V-1/V-0

FR-1524 FR-245 F-2000 FR-1410 F-3000 PolyquelTM 240

PolyquelTM 241

PROPERTIES

THERMAL STABILITY ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

MELT FLOW ✓✓✓ ✓ ✓✓ ✓ ✓✓ ✓

FR EFFICIENCY ✓✓✓ ✓✓ ✓✓✓ ✓✓✓ ✓ ✓✓ ✓✓

IMPACT ✓✓✓ ✓✓ ✓ ✓✓ ✓✓

UV / LIGHT STABILITY ✓✓ ✓✓✓ ✓✓ ✓✓✓ ✓✓✓

HEAT DISTORTION TEMP. ✓✓✓ ✓✓ ✓✓ ✓ ✓✓✓ ✓✓✓

NON-BLOOMING ✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

COST EFFICIENCY ✓✓✓ ✓✓✓ ✓ ✓✓ ✓

RECYCLING ✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

DUST-FREE ✓✓✓ ✓✓✓

POLYOLEFINS

PP

FR-370* FR-720 FR-1210** FR-1410 FR-1025 FR-20 PolyquelTM 140

PROPERTIES

THERMAL STABILITY ✓ ✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

PROCESSABILITY ✓✓ ✓ ✓✓✓ ✓✓✓

FR EFFICIENCY ✓✓ ✓✓ ✓✓✓ ✓✓✓

IMPACT ✓✓✓ ✓✓✓ ✓✓ ✓✓

UV / LIGHT STABILITY ✓✓✓ ✓ ✓ ✓✓ ✓✓ ✓✓

NON-BLOOMING ✓✓ ✓✓✓ ✓✓✓

COST EFFICIENCY ✓✓ ✓✓ ✓✓

RATING V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0 V - 0 / V - 2

PE

FR-720 FR-1210* FR-1410 FR-1025 FR-20 PolyquelTM 145

PROPERTIES

THERMAL STABILITY ✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

MELT FLOW ✓✓✓ ✓✓

FR EFFICIENCY ✓✓ ✓ ✓✓✓ ✓✓

IMPACT ✓✓✓ ✓✓ ✓

UV / LIGHT STABILITY ✓ ✓ ✓✓ ✓✓ ✓✓✓

NON-BLOOMING ✓✓✓ ✓✓✓

COST EFFICIENCY ✓✓ ✓✓ ✓✓

DUST-FREE V - 0 / V - 2 ✓✓✓


* FR-370 is recommended for production of inherently flame retarded PP multifilaments and fibers.** Not sold in the US for most applications nor in Europe if RoHS compliance is needed

* Not sold in the US for most applications nor in Europe if RoHS compliance is needed


APPLICATIONS

ENGINEERING PLASTICS

POLYAMIDENon reinforced PA 6 and 6,6 V-O

FR-803P FR-1025 FR-1410 F-2400 FR-20

PROPERTIES

THERMAL STABILITY ✓✓✓ ✓ ✓✓ ✓✓

MELT FLOW ✓✓✓ ✓✓

FR EFFICIENCY ✓ ✓ ✓✓✓

IMPACT ✓✓✓ ✓✓ ✓

COMPARATIVE TRACKING INDEX ✓✓ ✓ ✓✓✓

THERMAL AGING ✓✓ ✓✓✓ ✓

RECYCLING ✓ ✓✓✓ ✓ ✓

UV / LIGHT STABILITY ✓✓ ✓✓✓ ✓✓✓

HEAT DISTORTION TEMP. ✓ ✓✓ ✓✓ ✓✓ ✓✓✓

NON-BLOOMING ✓✓✓ ✓✓✓ ✓✓✓

COST EFFICIENCY ✓✓ ✓✓✓ ✓

POLYAMIDEGlass reinforced PA 6 and 6,6 V-0

FR-803P FR-1025 FR-1410 F-2400 F-3100

PROPERTIES

THERMAL STABILITY ✓✓✓ ✓ ✓✓ ✓✓

MELT FLOW ✓ ✓✓✓ ✓✓✓ ✓✓

FR EFFICIENCY ✓✓ ✓✓ ✓✓✓ ✓✓

IMPACT ✓ ✓✓✓ ✓✓ ✓✓

COMPARATIVE TRACKING INDEX ✓✓ ✓ ✓

THERMAL AGING ✓✓ ✓✓✓ ✓ ✓

RECYCLING ✓✓ ✓✓

UV / LIGHT STABILITY ✓✓ ✓✓✓ ✓✓

HEAT DISTORTION TEMP. ✓✓ ✓✓✓ ✓✓ ✓✓ ✓✓

NON-BLOOMING ✓✓✓ ✓✓✓ ✓✓✓

COST EFFICIENCY ✓ ✓✓✓ ✓ ✓✓


PVC & TEXTILE ADHESIVES COATING (TAC)

FLEXIBLE PVC

Phosflex31L/41L

Phosflex375

Phosflex71B

Phosflex362

Phosflex390

Lindol

PROPERTIES

FR EFFICIENCY ✓✓✓ ✓✓ ✓✓✓ ✓ ✓ ✓✓✓

PLASTICIZING PERFORMANCE ✓✓ ✓✓ ✓ ✓✓✓ ✓✓✓ ✓✓

LOW TEMPERATURE FLEXIBILITY ✓ ✓✓ ✓ ✓✓✓ ✓✓✓ ✓✓

LOW SMOKE ✓ ✓✓ ✓ ✓✓✓ ✓✓✓ ✓

LOW VOLATILITY/SURFACE MIGRATION ✓✓ ✓✓ ✓✓✓ ✓ ✓ ✓✓

LOW SMELL ✓ ✓✓ ✓✓✓ ✓ ✓ ✓

CHEMICAL RESISTANCE (OIL FATS) ✓✓✓ ✓✓ ✓✓✓ ✓ ✓ ✓✓✓

FOOD APPROVAL ✓*

COST EFFICIENCY ✓✓ ✓✓ ✓✓✓ ✓ ✓

ENGINEERING PLASTICS

PBT V-0

FR-1025 F-3100 F-2000series

FR-803P FR-1410FR-1025& F-2000

series

PROPERTIES

THERMAL STABILITY ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓ ✓✓

MELT FLOW ✓✓✓ ✓✓✓ ✓to✓✓ ✓✓

FR EFFICIENCY ✓✓ ✓ ✓ ✓ ✓✓

IMPACT ✓✓✓ ✓✓ ✓✓ ✓✓✓

COMPARATIVE TRACKING INDEX ✓✓ ✓✓✓ ✓✓

THERMAL AGING ✓✓✓ ✓ ✓ ✓✓

RECYCLING ✓✓✓ ✓✓ ✓✓

UV / LIGHT STABILITY ✓✓ ✓✓ ✓✓✓ ✓✓

HEAT DISTORTION TEMP. ✓✓ ✓✓✓ ✓✓✓

NON-BLOOMING ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

COST EFFICIENCY ✓ ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓

* FDA Contact in coatings for confectionary applications



APPLICATIONS

TEXTILE ADHESIVES & COATING (TAC)

TAC

BACK COATING9001 9025 9020

FyrolflexRDP

FyrolFR-2

PROPERTIES

PHOSPHORUS (P)/BROMINE (Br) BASED Br Br Br/P P P+Cl

FR EFFICIENCY ✓✓ ✓✓ ✓✓✓ ✓ ✓

TRANSPARENCY ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓✓

LOW MELTING TEMPERATURE ✓✓✓ ✓✓✓ ✓✓✓

SOLID (S)/LIQUID (L)/WATER DISPERSION (WD)

S WD WD L L

LOW FOGGING ✓✓ ✓✓✓ ✓✓✓ ✓✓ ✓

COST EFFICIENCY ✓✓✓ ✓✓ ✓✓ ✓✓ ✓✓

COATING/PADDING9001 9025 9020 P P+

SOLID (S)/LIQUID (L) S L L L L

SELECTION MATRIX

COTTON + +

POLYESTER + + + + +

POLYESTER/COTTON + + + + +

PROPERTIES

FR EFFICIENCY ✓✓✓ ✓✓✓ ✓✓✓ ✓✓ ✓✓✓

TRANSPARENCY ✓ ✓ ✓✓ ✓✓

WASH DURABILITY ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓✓

SOFT HAND ✓✓ ✓✓

LOW FOGGING ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓

LOW MELTING TEMPERATURE ✓✓✓ ✓✓✓ ✓✓✓

POLYMERIC ✓✓✓ ✓✓✓

COST EFFICIENCY ✓✓ ✓✓ ✓✓ ✓✓ ✓✓

TEXTILE EXHAUSTION & ADHESIVE APPLICATIONS

3000 provides flame retardancy to synthetic fibers, yarns and fabrics. 3000 is most suitable for polyester when soak and wash durable FR properties are required.


PLASTIC FOAMS

RIGID PUF

Fyrol 6 Fyrol PCF6605

FR-513*

PROPERTIES

LOW VISCOSITY ✓✓ ✓ Solid*

FR EFFICIENCY ✓ ✓ ✓✓✓ ✓✓✓

SYSTEM STABILITY ✓✓✓ ✓✓✓ ✓✓✓

REACTIVE ✓✓✓ ✓✓ ✓✓✓

COST EFFICIENCY ✓✓✓ ✓✓ ✓✓✓

EPS / XPSExpanded and extruded polystyrene foams for building, construction and packaging industries are available in many forms:Sheets (thermal insulation), Profiles (decorative), Molded shapes (packaging).ICL-IP offers several flame retardants to match market needs in the various applications:

FR-1206 ILM• High purity• Lower melting range• Processing-aid during extrusion of profile or sheet

FR-1206 IHM• Designed primarily for flame-retarded EPS• High purity• Readily soluble in styrene monomer• Enables good control of the particle size distribution of the beads

FR-122P• Polymeric FR• FR efficiency similar to FR-1206• Non-leaching and non-blooming

F-2200HM and FR-370• Proprietary co-FR for XPS applications• Heat /UV stabilized applications• Processing-aid effect

FLEXIBLE PUF

FyrolFR-2

FyrolHF-4

Fyrol 38 FyrolA300TB

FyrolPCF

FyrolPNX

FR-513*

PROPERTIES

LOW VISCOSITY ✓✓✓ ✓ ✓✓✓ Solid*

FR EFFICIENCY ✓✓ ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓✓

LOW SCORCH ✓✓ ✓

LOW FOGGING ✓✓ ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓✓

COMPRESSION SET ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓

REACTIVE ✓✓✓

COST EFFICIENCY ✓✓ ✓✓ ✓✓ ✓✓✓ ✓ ✓✓✓

* Also supplied in heated isocontainer

* Also supplied in heated isocontainer



ICL - INDUSTRIAL PRODUCTS

7/20

13

Visit our Website: www.iclfr.comAdditional links: www.icl-ip.com • www.phoschek.com • www.bsef.com

GLOBAL PRESENCE

Although the information and recommendations set forth herein (hereinafter “Information”) are presented in good faith and believed to be correct as of the date hereof, ICL INDUSTRIAL PRODUCTS. makes no representations as to the completeness, accuracy, quality or suitability of any information for any purpose. The use of the Information supplied herein shall be subject to and conditioned on that the persons receiving it and making use of it will make their own determination as to its safety and suitability for their purposes and applicable laws and other statutory demands prior to acquisitions, importations, exportations, transportations, implementations or uses of any kind. In no event will ICL INDUSTRIAL PRODUCTS. be responsible for damages of any nature whatsoever resulting, directly or indirectly, from the use or reliance upon Information.NO REPRESENTAT IONS OR WARRANT IES , E ITHER EXPRESSED OR IMPL IED OF MERCHANTAB IL ITY, F ITNESS FOR A PART ICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.

Head Office

ICL-IPMakleff House, 12 Kroitzer St., P.O.B. 180Beer Sheva 84101, IsraelTel: +972 8 629 7608 Fax: +972 8 629 7846E-mail: [email protected]

Europe

ICL-IP Europe B.V.Fosfaatweg 48, 1013 BM AmsterdamThe Netherlands, or P.O. Box 4651000 AL Amsterdam, The NetherlandsTel: +31 20 800 5800 Fax: +31 20 800 5805E-mail: [email protected]

North America and Mexico

ICL-IP America Inc. 622 Emerson Road, Suite 500St. Louis, Missouri 63141, USATel: +1 877 661 4272 Fax: +1 314 983 7610E-mail: [email protected]

South America

ICL Brasil Ltda.Av. Major Sylvio de Magalhaes Padilha, 5200Ed. Dallas Cj.22, 05693-000 Sao Paulo SP, BrazilTel: +55 11 2155 4539 Fax: +55 11 2155 4507E-mail: [email protected]

Asia PacificChina

ICL CHINARoom 908 Times Square Office TowerNo 93 Middle Huai Hai RoadShanghai 200021, ChinaTel: +86 21 5386 3322 Fax: +86 21 5386 3336E-mail: [email protected]

Japan

ICL-IP Japan Ltd.Sumitomo Fudosan Iidabashi Building, 5th fl. 2-3-21, Koraku, Bunkyo-ku, Tokyo 112-0004, JapanTel: +81 3 6801 8430 Fax: +81 3 6801 6970E-mail: [email protected]

Other Asia Pacific

ICL Asia Ltd.Room 2301, 23/F, Allied Kajima Building,138 Gloucester Road, Wanchai, Hong KongTel: +852 2827 7761 Fax: +852 2824 1502E-mail: [email protected]

Other parts of the World

ICL-IP Israel Sales OfficeMakleff House, 12 Kroitzer St., P.O.B. 180Beer Sheva 84101, IsraelTel: +972 8 629 7633 Fax: +972 8 629 7819E-mail: [email protected]

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