Fire Hazard Properties of Flammable Liquids

Reaffirmed July 1992Supersedes: September 1979

and D.S. 7-19S September 1979Revised September 1998

of 106

FIRE HAZARD PROPERTIES OFFLAMMABLE LIQUIDS, GASES AND VOLATILE SOLIDS

Table of ContentsPage

1.0 GENERAL INFORMATION ..................................................................................................................... 31.1 Scope ................................................................................................................................................ 31.2 Purpose .......................................................................................................................................... 31.3 Definitions of Fire Hazard Properties .............................................................................................. 31.4 Extinguishing Methods .................................................................................................................... 71.5 Suggested Hazard Identification ..................................................................................................... 91.6 Additional Information .................................................................................................................... 111.7 Indexing .......................................................................................................................................... 11

2.0 APPENDIX ............................................................................................................................................ 122.1 Labeling Requirements For Hazardous Materials Shipping Containers ....................................... 122.2 Chlorinated Solvents ..................................................................................................................... 13

List of TablesFire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids Table ........................................ 14

Factory MutualProperty Loss Prevention Data Sheets 7-19N

©1992 Factory Mutual Engineering Corp. All rights reserved. No part of this document may be reproduced, stored in a retrieval system,or transmitted, in whole or in part, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without writtenpermission of Factory Mutual Engineering Corp.

Valid through January 2000

The material in this data sheet is copyrighted by the NFPA and has been reprinted by specialpermission. Factory Mutual (FM) comments and exceptions are included in boldface, following eachNFPA section to which they apply. The tables that are part of this NFPA document are included asan attachment to the text.

This edition of NFPA 325M, Fire Hazard Properties of Flammable Liquids, Gases and Volatile Solids, wasprepared by the Technical Committee on Classification and Properties of Flammable Liquids, released by theCorrelating Committee on Flammable Liquids, and acted on by the National Fire Protection Association, Inc.at its fall meeting held November 12–14, 1990, in Miami, Florida. It was issued by the Standards Councilon January 11, 1991, with an effective date of February 8, 1991, and supersedes all previous editions.

The 1991 edition of this document has been approved by the American National Standards Institute.

Changes other than editorial are indicated by a vertical rule in the margin of the pages on which they appear.These lines are included as an aid to the user in identifying changes from the previous edition.

Vertical rules (identifying revisions) do not appear in this data sheet due to the numbers of revisionsfrom the 1979 version.

Origin and Development of NFPA 325M

The first edition of NFPA 325M was presented to the Association in 1930. Successively revised and enlargededitions were published in 1935, 1941, 1945, 1947, 1951, 1954, 1960, 1965, 1969, 1977 and 1984.

This 1991 edition is an amended version of the 1984 edition. The major change is a complete rewrite ofthe explanatory material that is presented in Chapter 1. Several new entries were also added, and a numberof existing entries have been updated with new or additional data. These are indicated by a vertical rule inthe left-hand margin.

This document is not a code, standard or recommended practice, as these terms are defined by NFPA. Itis only a compilation of basic fire protection properties of various material, prefaced by an explanation of theproperties covered. The data contained have been collected from numerous authoritative sources, includingthe U.S. Bureau of Mines, Factory Mutual Research Corporation, and Underwriters Laboratories, as wellas from the manufacturers of the materials. The originating source of the data is on file at NFPA headquartersand may be obtained upon request.

The table presented here summarizes available data on the fire hazard properties of about 1,500 substances,listed alphabetically by their chemical name. In addition, about 500 synonyms are listed alphabetically andcross-referenced to their proper entries.

The values for any given property are representative and deemed suitable for general use. Where differencesexist in reference sources, the value selected for inclusion in this compilation is conservative. Slightdifferences are to be expected between data sources due to differences in the purity of test samples, minordifferences in test apparatus, and minor differences in technique and observation. In almost all cases, theseminor variations have little practical significance. Where there is difference of opinion as to the actual valueof a property of a given material or where the validity of the data presented is questioned, further tests shouldthen be conducted on representative samples of the specific material in question by a qualified testinglaboratory.

NFPA Standard No. 325M-1991

Copyright by NFPA and reprinted by special permission.

National Fire Protection Association

7-19N Fire Hazard Properties Factory Mutual Property Loss Prevention Data Sheets

©1992 Factory Mutual Engineering Corp. All rights reserved.


RELATED STANDARDS. There are a number of references to other NFPA standards. In most instances,Factory Mutual has its own corresponding standard that should take precedence.

NFPA 325M

Fire Hazard Properties of Flammable Liquids,Gases and Volatile Solids

1991 Edition

GENERAL INFORMATION

1.1 Scope

This manual applies to flammable liquids, flammable gases and volatile flammable solids.

1.2 Purpose

The purpose of this manual is to provide the user with basic fire hazard information on the materials coveredby the scope.

1.3 Definitions of Fire Hazard Properties

1.3.1 No single fire hazard property, such as flash point or ignition temperature, should be used to describeor appraise the fire hazard or fire risk of a material, product, assembly or system under actual fire conditions.The fire hazard properties given in this manual have been determined under controlled laboratory conditionsand may properly be used to measure or describe the response of materials, products, assemblies or systemsunder these conditions. Properties measured under these conditions may be used as an element of a firerisk assessment only when such assessment takes into account all of the factors that are pertinent to theevaluation of the fire hazard of a given situation.

1.3.2 The pertinent literature seldom mentions the degree of purity of the material being tested; even boilingpoint or melting point data are frequently missing. These data, if available, would permit judging the purityof the material and, hence, the reliance to be placed on the values reported, particularly with respect to flashpoint and flammable range. Finally, it must be remembered that there is little industrial use of high puritymaterials. As a consequence of these considerations, no values of purity are given in this compilation. Themelting points and boiling points should be regarded as approximations.

1.3.3 Flash Point. The flash point of a liquid is the minimum temperature at which the liquid gives off sufficientvapor to form an ignitible mixture with air near the surface of the liquid or within the test vessel used. By‘‘ignitible mixture’’ is meant a mixture that is within the flammable range (between the upper and lower limits)and, thus, is capable of propagation of flame away from the source of ignition. Some evaporation takes placebelow the flash point, but not in quantities sufficient to form an ignitible mixture. Flash point applies mostlyto flammable and combustible liquids, although certain solids, such as camphor and naphthalene, that slowlyvolatilize at ordinary room temperature, or certain liquids, such as benzene, that freeze at relatively hightemperatures, will exhibit a flash point in the solid state.

The flash points given in this manual are, for the most part, closed cup flash points. Where the only availabledata is based on open cup tests, this is designated by the initials ‘‘oc’’ after the entry. In the case of someof the older data in this manual, it could not be determined whether a closed cup or open cup procedure hadbeen used. In these cases, it has been assumed that the data is based on closed cup tests. For furtherinformation on the flash point test procedures used, see NFPA 321, Standard on Basic Classification ofFlammable and Combustible Liquids.

A flammable liquid does not burn itself, but rather the vapors from the liquid burn. The rate at whichdifferent liquids vaporize varies greatly, depending on their vapor pressure. Vaporization increaseswith rises in temperature, and a flammable liquid at elevated temperature is more hazardous than thesame liquid at ambient temperature if accidentally released or normally exposed to the atmosphere.

Many flammable liquids have flash points at or below room temperatures and are normally coveredby a layer of flammable vapors. These flammable vapors can combine with air to form a flammablevapor-air zone near the liquid that will ignite immediately if an ignition source is present.

Fire Hazard Properties 7-19NFactory Mutual Property Loss Prevention Data Sheets



Fire Point. The lowest temperature at which a liquid in an open container will give off enough vaporsto continue to burn once ignited is the fire point. It is generally slightly above the open-cup flashpoint.

1.3.4 Ignition Temperature. The ignition temperature of a substance, whether solid, liquid or gas, is theminimum temperature required to cause self-sustained combustion, independently of the heating or heatedelement. Ignition temperatures observed under one set of conditions may differ markedly from thoseobserved under another set of conditions. For this reason, ignition temperatures should be regarded asapproximations.

Some of the variables known to affect ignition temperature are: the percentage of the gas or vapor in themixture, the shape and size of the test vessel, the rate and duration of heating, the kind and temperature ofthe ignition source, and catalytic or other effects of materials that may be present. As there are manydifferences in ignition temperature test methods, such as the size and shape of the test vessel, the materialof construction of the test vessel, method and rate of heating, residence time, and method of flame detection,it is not surprising that reported ignition temperatures may differ for the same material.

The phrase ‘‘independently of the heating or heated element’’ should be construed to mean in theabsence of a spark or flame.

The majority of the data reported in this manual has been obtained by one of two methods: ASTM D286and ASTM D2155. Both have been withdrawn by the American Society for Testing and Material. ASTM D2155has been replaced by ASTM E659, Standard Test Method for Autoignition Temperatures of Liquid hemicals.An earlier test method, ASTM D2883, Test Method for Reaction Threshold Temperature of Liquid and SolidMaterials, provides for the study of autoignition phenomena at reduced and elevated pressures. Federal TestMethod Standard 791B, Method 5050, is another current test method that provides for the measurementof autoignition properties in the same terms used by the ASTM procedures.

Previous test methods relied only on visual detection of flame. Consequently, the ignition temperaturesobtained by these procedures were the minimum temperatures at which hot-flame ignition occurred. Thecurrent test methods employ thermoelectric flame detection, thus permitting the detection of nonluminous orbarely luminous reactions that were difficult or impossible to detect by the older procedures. As a result, thefollowing terms have come into use:

Hot-Flame Ignition. A rapid, self-sustaining, sometimes audible gas-phase reaction of the sample or itsdecomposition products with an oxidant. A readily visible yellow or blue flame usually accompanies thereaction.

Cool-Flame Ignition. A relatively slow, self-sustaining, barely luminous gas-phase reaction of the sample orits decomposition products with an oxidant. Cool flames are visible only in a darkened area.

Pre-Flame Reaction. A slow, nonluminous gas-phase reaction of the sample or its decomposition productswith an oxidant.

Catalytic Reaction. A relatively fast, self-sustaining, energetic, sometimes luminous, sometimes audiblereaction that occurs as a result of the catalytic action of any substance on the sample or its decompositionproducts, in admixture with an oxidant.

Non-Combustive Reaction. A reaction other than combustion or thermal degradation that is undergone bycertain substances when they are exposed to heat. Thermal polymerization is an example of this type ofreaction.

Reaction Threshold. The lowest temperature at which any reaction of the sample or its decompositionproducts occurs, for any sample/oxidant ratio.

Autoignition Temperature (AIT). The currently accepted term for the Hot-Flame Ignition Temperature.

Cool-Flame Reaction Threshold (CFT). The lowest temperature at which cool-flame ignitions are observedfor a particular system. Previously undefined.

Preflame-Reaction Threshold (RTT). The lowest temperature at which exothermic gas-phase reactions areobserved for a particular system. Previously undefined.




Previously, reported ignition temperatures, including those given in this manual, have corresponded roughlyto the autoignition temperature (AIT), provided that proper allowances were made for empirical differencesin the measurement technique. In the future, it is expected that CFT and RTT will routinely be reported. Bothare lower than AIT and are significant factors to be evaluated in the assessment of the overall ignition riskof a given system. Cool flames are self-sustaining, exothermic ignition reactions that, under proper circum-stances, may act as the initiator of more energetic hot-flame reactions. Pre-flame reactions have the capacity,under adiabatic or near adiabatic conditions, to elevate the temperature of a fuel/air mixture to the point wherecool- or hot-flame ignition may occur.

As an illustration of the effects of test methods, the ignition temperature of hexane, as determined by threedifferent methods, are 437°F (225°C), 637°F (336°C) and 950°F (510°C). The effect of percentagecomposition is shown by the following ignition temperatures for pentane: 1018.4°F (548.4°C) at 1.5%, 935.6°F(502.4°C) at 3.75% and 888.8°F (476.3°C) at 7.65%. The following ignition temperatures for carbon disulfidedemonstrate the effect of the size of the test vessel: 248°F (120°C) in a 200 ml flask, 230°F (110°C) in a1 liter flask and 205°F (96°C) in a 10 liter flask. The effect of the material of construction of the test vesselis shown by the following ignition temperatures for benzene: 1060°F (572°C) in a quartz vessel and 1252°F(678°C) in an iron vessel.

The ignition temperature of a combustible solid is influenced by the rate of air flow, rate of heating and sizeof the sample. Small sample tests have shown that, as the rate of air flow or the rate of heating is increased,the ignition temperature decreases to a minimum value, then increases.

Susceptibility to Spontaneous Ignition. Many flammable liquids combine readily with the oxygen inthe air at ordinary temperatures and give off heat. When these materials are present in waste, rubbishor other material under conditions in which heat is produced faster than it is dissipated, thetemperature rises and ignition may occur.

1.3.5 Flammable (Explosive) Limits. In the case of gases or vapors that form flammable mixtures with air,oxygen or other oxidizers, such as chlorine and nitrous oxide, there is a minimum concentration of the materialbelow which propagation of flame does not occur. Similarly, there is a maximum concentration above whichpropagation of flame does not occur. These boundary mixtures, which, if ignited, will just propagate flame,are known as the ‘‘lower and upper flammable or explosive limits’’ and are usually expressed as percent byvolume of the material in air (or other oxidant). In popular terms, a mixture below the lower flammable limit(LFL) is too ‘‘lean’’ to burn, while a mixture above the upper flammable limit (UFL) is too ‘‘rich’’ to burn.

The values for the flammable limits given in this manual are based on atmospheric temperatures andpressures, unless otherwise indicated. There will be considerable variation in flammable limits at tempera-tures and pressures above or below ambient. The general effect of an increase in temperature or pressure isto decrease the lower limit and to increase the upper limit, i.e., broaden the range between the two limits.A decrease in the temperature or pressure has the opposite effect. In most cases, the values given in thismanual represent the concentration limits over which hot-flame ignitions have been observed. If cool-flameignitions are considered, wider flammable ranges are observed.

Research has shown that flammability limits are not a fundamental combustion property but depend on manyvariables, including the surface-to-volume ratio of the test vessel, the direction of air flow and the velocityof air flow. In some experiments conducted at laminar flow velocities, the upper limit increased with increas-ing flow velocity reached a maximum that was independent of the diameter of the test vessel, then decreasedas flow became turbulent. The lower limit has been unaffected by air flow rate.

ASTM E681 is the current test method for determining flammable limits. However, much of the data wereobtained in small diameter tubes with ignition at the bottom so that flame propagation was upward. For mosthydrocarbons, this method is appropriate. However, for highly oxygenated, aminated or halogenatedmaterials, larger diameter equipment is required to avoid quenching of the flame. Larger diameter testequipment or more energetic ignition sources may better reflect real world burning conditions.

The terms ‘‘flammable limits’’ and ‘‘explosive limits’’ are interchangeable.

The range of concentration between the lower flammable limit and the upper flammable limit is known asthe ‘‘flammable range,’’ also referred to and synonymous with ‘‘explosive range.’’ All concentrations of a gasor vapor in air that lie between the flammable limits are ignitible.




If a flammable vapor or gas-air mixture within the flammable limits is confined and ignited, anexplosion results. Many common flammable liquids and gases have very wide explosive ranges. Thatof carbon disulfide is 1 to 50% and that of hydrogen is 4 to 75%, which shows that only very leanor unusually rich mixtures of these materials in air have no explosion potential.

1.3.6 Specific Gravity. The specific gravity of a substance is the ratio of the weight of that substance to theweight of an equal volume of another substance. In this manual, the other substance is water. The valuesgiven in this manual for specific gravity are rounded to the nearest tenth. For materials whose specific gravityis from 0.95 to 1.0, the value is shown as 1.0-. For materials whose specific gravity is from 1.0 to 1.05, thevalue is given as 1.0+. In a few cases, such as fuel oils, where the percentage composition of the substancevaries, specific gravity is given as less than (<) or greater than (>) 1.

Most flammable liquids will float on water where they can burn freely and flow over a large area. Othersare heavier than water and water will float on them and extinguish a fire. The specific gravity of aflammable liquid is important in determining the proper type of fire extinguishing agent and whetheroverflow drains on open tanks of flammable liquids or other special precautions are needed.

1.3.7 Vapor Density. The vapor density of a substance is the ratio of the weight of a volume of pure vaporor gas (no air present) to an equal volume of dry air at the same temperature and pressure. It is calculatedas the ratio of the molecular weight of the substance to the molecular weight of air, 29. A vapor density of lessthan 1 indicates that the substance is lighter than air and will tend to rise in a relatively calm atmosphere.A vapor density of greater than 1 indicates that the substance is heavier than air and may travel along gradelevel for a considerable distance to a source of ignition and flash back, assuming the gas or vapor isflammable.

The vapors of all flammable liquids are heavier than air. This is the reason why flash fires in flammablevapors often cover large areas and travel long distances along the floor or ground, and why venti-lating outlets should be located near the floor level. Many combustible gases, by contrast, are lighterthan air and require ventilation from near the ceiling.

1.3.8 Boiling Point. The boiling point of each liquid is given at a pressure of 14.7 psia (760 mm). Wherean accurate boiling point is not available for a specific entry or where a specific entry is actually a mixtureof components and does not have a constant boiling point, the boiling point given is the 10% distillation pointas determined by ASTM D86, Standard Method of Test for Distillation of Petroleum Products.

The lower the boiling point, the more volatile and therefore the more hazardous a flammable liquid.

1.3.9 Melting Point. Melting points are reported in this manual for most materials that melt at 70°F (21°C)or higher. However, the melting point is not available for some of these materials.

The melting point is important in materials that are solid at ordinary temperatures but assume thecharacteristics of flammable liquids when melted, such as naphthalene, tallow and similarsubstances.

1.3.10 Water Solubility. Water solubility data are reported only for those materials for which reliable informa-tion is available, due to the lack of uniformity with which water solubility data are reported in the literature,and the conflicting statements that sometimes accompany these data. Where such data is reported in thismanual, ‘‘No’’ indicates that the material’s solubility is less than 10 grams per 100 milliliters (ml) of water;‘‘Slight’’ indicates solubility is between 10 and 24 grams per 100 ml of water; ‘‘Yes’’ indicates solubility of 25or more grams per 100 ml of water.

‘‘No,’’ ‘‘Very Slight,’’ ‘‘Slight,’’ and ‘‘Yes’’ are sometimes used without definition in the literature to describewater solubility. In those cases where doubt exists as to a material’s solubility in water, tests should beconducted.

Information on the degree to which a material is soluble in water is useful in determining effective extinguish-ing methods and agents. For example, alcohol-resistant fire fighting foams are usually recommended forwater-soluble flammable and combustible liquids. Also, fires involving water-soluble liquids can beextinguished by dilution with water, although this method is not commonly used because of the amount ofwater needed to dilute most flammable liquids to the point of noncombustibility and because of the danger offrothing if the liquid is heated to the boiling point of water, 212°F (100°C).




Water solubility may also be referred to as water miscibility.

When mixed with water, liquids that are water-miscible are conductors of electricity and cannotaccumulate static charges.

1.4 Extinguishing Methods

1.4.1 General. The extinguishing methods commonly used for fires involving flammable liquids are suitablefor use on fires involving most of the materials listed in this manual. Carbon dioxide, dry chemical, foam,and vaporizing liquid extinguishing agents have all been found to be suitable for use on flammable liquid firesof moderate size, such as in dip tanks or small spills of no appreciable depth. The following comments applyto other extinguishing methods that have been found effective for the control or extinguishment of someflammable liquid fires.

Water spray or fog can be particularly effective on fires involving flammable liquids and volatile solids whoseflash points exceed 100°F (37.8°C). However, with liquids whose flash points exceed 212°F (100°C), frothingmay occur. For information on the installation of water spray protection for flammable and combustibleliquids, see NFPA 15, Standard for Water Spray Fixed Systems for Fire Protection.

Although fires in liquids having flash points below 150°F (66°C) may be extinguished with water sprayunder certain conditions, FM recognizes water spray only for liquids having flash points at or above150°F (66°C).

Automatic sprinklers are similar to water spray systems in extinguishing effectiveness. Their principal valueis in absorbing the heat from the fire and keeping the surroundings cool until the flammable liquids fire eitherburns out or is extinguished by other means. Automatic sprinklers have a good record of fire control ingarages, in paint and oil rooms, and in storage areas where liquids are kept in closed containers. In someindustries that use water-soluble liquids, such as the distilled spirits industry, sprinkler systems have beenused to achieve protection and extinguishment with excellent results. Where automatic sprinklers are usedto protect open tanks, overflow drains are necessary to prevent sprinkler discharge from overflowing the tankand spreading burning liquid to others parts of the property. For further information on automatic sprinklers,see NFPA 13, Standard for the Installation of Sprinkler Systems.

FM does not equate sprinklers to water spray in extinguishing effectiveness. Standard sprinkler sys-tems will usually extinguish fire in liquids having flash points above 200°F (93°C). Although both stan-dard sprinklers and water spray-nozzles will not normally extinguish fires in low flash point liquids,these devices will reduce the intensity of burning and protect buildings and equipment from severedamage.

Hose streams, both spray and straight streams, are frequently used to cool tanks, containers and equipmentfrom the heat of an exposing fire. They are also used for washing burning spills away from areas where theburning liquid could ignite other material. However, hose streams may also spread and extend the spill fire,if improperly used. Also, hose streams applied to open containers of burning liquid will only serve to spreadthe fire, either by splashing the burning liquid out of the container or by causing frothing of the liquid.

Use of automatic-closing covers on open tanks or equipment containing flammable or combustible liquid isalso effective in fire control and extinguishment. The covers should be operated by a fusible link, with amanual override. Such covers are suitable for any size tank except where objects being dipped or conveyorsystems may prevent tight closing of the cover.

1.4.2 Selecting an Extinguishing Method. The selection of the extinguishing method used should be madewith some degree of caution. Flowing fires, such as may be caused by a leaking overhead pipe with burningliquid on the ground, are always difficult to extinguish. The amount of extinguishing agent and its rate andmethod of application must be carefully chosen in relation to the size and type of fire anticipated and may callfor special engineering judgment. The use of approved extinguishing equipment is also a major consideration.

The chemical and physical properties of the material involved will also affect the choice of extinguishingmethod and agent. Standard fire fighting foam cannot be used on fires involving water-soluble flammableliquids; the liquid destroys the foam blanket. Those properties that affect extinguishment were taken intoconsideration when selecting the methods given for each material in the column headed ‘‘Extinguishing




Methods.’’ The following information describes the properties of the material that dictate the numericallydesignated entries in this column.

1 Water May Be Ineffective. This precaution applies to materials that have a flash point below 100°F(37.8°C). Obviously, the lower the flash point, the less effective the water will be. However, water canbe used on low-flash point liquids when applied as a spray to absorb heat and to protect exposed materialor structures. Much of the effectiveness of using water spray, particularly from hose lines, will dependon the method of application. With proper selection of nozzles, even gasoline spill fire can beextinguished when several coordinated hose streams are used to sweep the flames from the surfaceof the burning liquid. Water has also been used to extinguish fires involving water-soluble flammableliquids by cooling and diluting the liquid. The distilled spirits industry has been especially successful inusing water to control and extinguish fires of this type.

Thus, the phrase ‘‘water may be ineffective’’ indicates that, although water can be used to cool and protectexposed material, water may not be capable of extinguishing the fire unless used under favorableconditions by experienced fire fighters trained in fighting all types of flammable liquids fires.

2 Water or Foam May Cause Frothing. This statement applies to liquids having flash points above 212°F(100°C) and is included only as a precaution. It does not indicate that water or fire fighting foam shouldnot be used. The frothing may be violent and could endanger any fire fighters located too close to theburning liquid, particularly when solid streams of water are directed onto the hot, burning liquid. On theother hand, a carefully applied water spray has frequently been used to achieve extinguishment bydeliberately causing frothing only on the surface of the liquid; the foaming action blankets the surfaceof the liquid and extinguishes the fire by excluding oxygen. This tactic is especially successful with highviscosity liquids. For example, certain asphalts have a low-flash point solvent added for fluidity, butbecause of the relatively high viscosity, frothing action is able to achieve fire control and extinguishment.

3 Water May Be Used to Blanket Fire. This statement is applicable to those liquids that have a specificgravity of 1.1 or greater and are not water-soluble. However, the water must be gently applied to thesurface of the liquid, preferably with a fine spray or fog nozzle.

4 Water May Be Ineffective, Except as a Blanket. This statement is used as a warning for liquids whoseflash points are below 100°F (37.8°C) and applies only to those liquids that have a specific gravity of1.1 or greater and are not water-soluble. Here again, the water must be gently applied to the surface ofthe liquid.

5 Alcohol Foam. Alcohol-resistant fire fighting foam is recommended for use on all water-soluble liquidsor polar solvent-type liquids, except for those that are only ‘‘very slightly’’ soluble. Certain judgmentfactors are introduced, however, since ordinary fire fighting foam may be used on some liquids that areonly ‘‘slightly’’ soluble, particularly if the foam is applied at higher-than-normal application rates.Conversely, some flammable liquids, such as the higher molecular weight alcohols and amines, willdestroy alcohol-resistant foams, even when applied at very high rates. Foams should not be used onwater-reactive materials.

Some recently developed alcohol-resistant foams have been listed for use on both polar and nonpolarliquids. These ‘‘multipurpose’’ foams are suitable for use on nearly all flammable liquids except thosethat are water-reactive and are preferred for flammable liquid fires because they greatly minimize theproblems of foam selection. Fire fighting foam suppliers should be consulted for recommendationsregarding types of foam and application rates.

6 Stop Flow of Gas. For fires involving flammable gases, the best procedure is to stop the flow of thegas before attempting extinguishment of the fire. To extinguish the fire while allowing continued flow ofthe gas is extremely dangerous; an explosive cloud of gas/air mixture may be created that, if ignited,may cause far more damage than the original fire. Extinguishing the flame using carbon dioxide or drychemical may be desirable to allow immediate access to valves to shut off the flow of gas, but this mustbe done carefully. In many cases, it will be preferable to allow continued burning, while protectingexposures with water spray, until the flow of gas can be stopped.




1.5 Suggested Hazard Identification

1.5.1 The increased use of chemicals, many of which introduced hazards other than flammability, led tothe need for a simple hazard identification system that could be immediately recognized by emergencyresponse personnel. This need led to the development of the NFPA 704 Hazard Identification System,otherwise known as the NFPA 704 diamond. This system is completely described in NFPA 704, StandardSystem for the Identification of the Fire Hazards of Materials. The system provides simple, readily recognizedand easily understood markings that give, at a glance, a general idea of the inherent hazards of the materialand the order of severity of these hazards as they relate to fire protection, exposure and control. Thesystem’s objectives are to provide an appropriate alert signal and on-the-spot information to safeguard thelives of both public and private emergency response personnel. The system also assists in planning for effec-tive fire fighting operations and may be used by plant design engineers and plant protection and safety per-sonnel.

The system identifies the hazards of a material in terms of three categories: ‘‘Health,’’ ‘‘Flammability,’’ and‘‘Reactivity.’’ It indicates the order of severity of these hazards by means of a numerical rating of 0, indicat-ing no special hazard, to 4, indicating extreme hazard. The three hazard categories were selected afterstudying about 35 inherent and environmental hazards of materials that could affect fire fighting opera-tions. The five degrees of hazard were decided upon as necessary to give the required information. Finally,the system had to be relatively simple and readily understood.

While the system is basically simple in application, the hazard evaluation required for the use of the systemin a specific location must be made by experienced, technically competent persons. Their judgment mustbe based on factors that encompass a knowledge of the inherent hazards of different materials, including theextent of change in behavior to be anticipated under conditions of fire exposure and control.

1.5.2 Degrees of Hazard. The columns under ‘‘Suggested Hazard Identification’’ in this manual give the NFPA704 severity ratings for each of the hazard categories for which information was available. Blank spacesindicate that sufficient information was not available for a severity rating to be assigned. It should be under-stood that the assignment of the ratings is based on judgment and that extenuating circumstances in plantsand processes may dictate a change in any individual rating.

The following commentary on the degrees of hazard are an interpretation of the information contained inNFPA 704, and are specifically related to fire fighting. See NFPA 704 for more detailed information.

Note: The hazard identification rating definitions below and the actual ratings in the text are based ondefinitions from the 1985 edition of NFPA 704. Materials have not been rated using the new definitionsappearing in the 1990 edition of NFPA 704.

1.5.3 Health Hazard Rating. In general, the health hazard in fire fighting is that of a single exposure thatmay vary from a few seconds to as much as an hour. The physical exertion demanded in fire fightingoperations or other emergencies may be expected to intensify the effects of any exposure. Only hazardsarising out of the inherent properties of the material are considered. The following information on the fivedegrees of hazard are based on the information in NFPA 704 and relate to the protective equipment normallyavailable to fire fighters.

4 Materials that, on very short exposure, could cause death or major residual injury, including those thatare too dangerous to be approached without specialized protective equipment. A few whiffs of the vaporor gas can cause death, or contact with the vapor or liquid may be fatal, if it penetrates the fire fighter’snormal protective gear. The normal full protective clothing and breathing apparatus available to thetypical fire fighter will not provide adequate protection against inhalation or skin contact with thesematerials.

3 Materials that, on short exposure, could cause serious temporary or residual injury, including thoserequiring protection from all bodily contact. Fire fighters may enter the area only if they are protectedfrom all contact with the material. Full protective clothing, including self-contained breathing apparatus,coat, pants, gloves, boots, and bands around legs, arms and waist, should be provided. No skin surfaceshould be exposed.




2 Materials that, on intense or continued (but not chronic) exposure, could cause temporary incapacitationor possible residual injury, including those requiring the use of respiratory protective equipment thathas an independent air supply. These materials are hazardous to health, but areas may be entered freelyif personnel are provided with full-face mask, self-contained breathing apparatus that provide completeeye protection.

1 Materials that, on exposure, would cause irritation but only minor residual injury, including those requiringthe use of an approved air-purifying respirator. These materials are only slightly hazardous to healthand only breathing protection is needed.

0 Materials that, on exposure under fire conditions, offer no hazard beyond that of ordinary combustiblematerial.

1.5.4 Flammability Hazard Rating. Susceptibility to ignition and burning is the basis for assigning the degreeof hazard within this category. The method of attacking the fire is influenced by this susceptibility factor. Forfurther information, refer to Section 1-4, Extinguishing Methods. The following information is based on thedefinitions of Flamma-bility Hazard Rating contained in NFPA 704.

4 This degree includes flammable gases, pyrophoric liquids and Class IA flammable liquids. The preferredmethod of fire attack is to stop the flow of material or to protect exposures while allowing the fire toburn itself out.

3 This degree includes Class IB and IC flammable liquids and materials that can be easily ignited underalmost all normal temperature conditions. Water may be ineffective in controlling or extinguishing firesin such materials.

2 This degree includes materials that must be moderately heated before ignition will occur and includesClass II and IIIA combustible liquids and solids and semi-solids that readily give off ignitable vapors.Water spray may be used to extinguish fires in these materials because the materials can be cooledbelow their flash points.

1 This degree includes materials that must be preheated before ignition will occur, such as Class IIIBcombustible liquids and solids and semi-solids whose flash point exceeds 200°F (93.4°C), as well asmost ordinary combustible materials. Water may cause frothing if it sinks below the surface of the burningliquid and turns to steam. However, a water fog that is gently applied to the surface of the liquid willcause frothing that will extinguish the fire.

0 This degree includes any material that will not burn.

1.5.5 Reactivity Hazard Rating. The assignment of the degree of reactivity hazard is based on the potentialof the material to release energy either by itself or when in contact with water. In assigning this rating, fireexposure was considered, along with exposure to shock and pressure. The following information is based onthe definitions of Reactivity Hazard Rating contained in NFPA 704.

4 This degree includes those materials that, in themselves, are readily capable of detonation, explosivedecomposition or explosive reaction at normal temperatures and pressures. This includes materialsthat are sensitive to localized mechanical or thermal shock. If a material having this Reactivity HazardRating is involved in an advanced or massive fire, the area should be immediately evacuated.

3 This degree includes materials that, in themselves, are capable of detonation, explosive decomposi-tion, or explosive reaction, but require a strong initiating source or heating under confinement. Thisincludes materials that are sensitive to thermal and mechanical shock at elevated temperatures, andpressures and materials that react explosively with water. Fires involving these materials should be foughtfrom a protected location.

2 This degree includes materials that are normally unstable and readily undergo violent chemical change,but are not capable of detonation. This includes materials that can undergo chemical change with rapidrelease of energy at normal temperatures, and pressures and materials that can undergo violentchemical changes at elevated temperatures and pressures. This also includes materials that may reactviolently with water or that may form potentially explosive mixtures with water. In advanced or massive




fires involving these materials, fire fighting should be done from a safe distance or from a protectedlocation.

1 This degree includes materials that are normally stable, but that may become unstable at elevatedtemperatures and pressures, and materials that will react with water with some release of energy, butnot violently. Fires involving these materials should be approached with caution.

0 This degree includes materials that are normally stable, even under fire exposure conditions, and thatdo not react with water. Normal fire fighting procedures may be used.

1.5.6 Additional Markings. The fourth space in the NFPA 704 rating is reserved for the use of two specialsymbols: OX, to denote materials that are oxidizing agent, and W, to denote materials that are water-reactive.

1.6 Additional Information

1.6.1 Mixtures with Oxygen. Unless otherwise indicated, all values in this manual are based on testsconducted in normal air. For mixtures involving enriched oxygen atmospheres, the values may differ and anincrease in hazard is probable.

1.6.2 Mixtures of Materials. Mixtures of two or more materials may have different fire hazard properties thanany of the components. Although it is common practice to base the fire hazard of a mixture on that of themost hazardous component, consideration should be given to testing the mixture itself.

1.6.3 Mists and Froths. In finely divided form, such as a mist or spray, liquids can be ignited at tempera-tures considerably below their flash point. As in the case of vapors, the droplets of mist or spray must bepresent at a minimum concentration. Similarly, froths may be ignited at temperatures below the flash point.

1.7 Indexing

1.7.1 The materials in this manual are listed alphabetically by the name considered to be the most common.Other names and synonyms are indexed to this common name.

1.7.2 The following prefixes are considered to be a part of the name of the material. As such, they aregenerally not hyphenated and are used to alphabetically index the material when they appear at the beginningof the name.

BisDiHexa

IsoMonoPenta

TetraTriTris

1.7.3 The prefix ‘‘mono’’ is often omitted. Thus, monochlorobenzene is frequently referred to as chloroben-zene. This manual uses the more common form. The alternate form is not given unless it is also frequentlyused.

1.7.4 The following prefixes are not considered to be part of the name of the material. As such, they arehyphenated, but they are not used to alphabetically index the material.

o— (ortho)m— (meta)p— (para)n— (normal)sec— (secondary)tert— (tertiary)

d— (dextro)l— (levulo)N— (nitro)α— (alpha)β— (beta)γ— (gamma)

These prefixes may be written out in full, as in paradichlorobenzene. In this manual, they are usually abbre-viated. Thus, paradichlorobenzene appears in this manual as p-dichlorobenzene and is indexed under D.In accordance with custom, the prefix n-, for ‘‘normal,’’ is omitted, unless it appears in the middle of a name.

1.7.5 The prefixes ‘‘cis’’ and ‘‘trans’’ may be placed either at the beginning or the end of a name. In thismanual, they are always listed at the end.




2.0 APPENDIX

2.1 Labeling Requirements For Hazardous Materials Shipping Containers

The Hazardous Materials Transportation Act charges the Secretary of Transportation with the respon-sibility to protect the nation adequately against the risks to life and property that are inherent in thetransportation of hazardous materials in commerce. This responsibility is met through the issuanceand enforcement of the Hazardous Materials Regulations of the Department of Transportation by Air,Rail, Highway, Water and Military Explosives by Water Including Specifications for Shipping Contain-ers, which is currently referred to in the Code of Federal Regulations as Title 49—Transportation.These regulations cover labeling, placarding and shipping container specifications for hazardousmaterials transportation and apply to all such interstate shipments and also to intrastate shipmentsby common carriers engaged in interstate or foreign commerce.

These regulations require labeling of shipping containers with Department of Transportation (DOT)labels that include but are not limited to the following:

Red: Flammable liquids with closed-cup flash points less than 141°F (60.5°C) and flammablecompressed gases.

Red & White Vertical Stripes: Flammable solids

Yellow: Oxidizing materials (e.g., chlorates, permanganates, peroxides, nitrates) and organicperoxides (e.g., benzoyl peroxide, MEK peroxide)

White & Black (Half & Half): Corrosive liquids and solids including acids and alkalines

Green: Nonflammable compressed gases.

Special labels are also required for poisonous substances, explosives, etiologic agents (i.e.,biomedical materials), spontaneously combustible materials and radioactive materials.

It is important to recognize that this labeling system has many limitations, particularly for evaluatingthe storage and handling hazards of these materials.

The absence of a label does not necessarily mean that the material is nonhazardous. Nor does thepresence of a label necessarily provide sufficient information about the hazardous contents or thedegree of hazard for some materials. One example is the labeling requirements for flammable/combustible liquids.

A flammable liquid is defined by Title 49 as a liquid with a close-cup flash point less than or equalto 141°F (60.5°C). A combustible liquid is defined as a liquid with a closed-cup flash point greater than141°F (60.5°C) and less than or equal to 200°F (93°C). A mixture of flammable and combustible liquidsis defined as a flammable liquid if more than 1% of the mixture has a flash point less than 141°F(60.5°C). DOT flammable liquid labels are required by Title 49 for all liquids meeting the abovedefinition. A DOT label is not required when:

1. The container size is limited. Up to 1 gal (4 l) containers do not require labels depending on theirpackaging.

2. The liquid is a consumer commodity and meets the above criteria for limited quantities.

3. The liquid is an alcoholic beverage with a container size up to 1 gal (4 l).

4. The liquid is an aqueous solution of alcohol with 24% or less alcohol and at least 50% water. Thissolution is considered a combustible liquid.

5. The liquid has a flash point greater than 141°F (60.5°C), combustible liquid.

The above definition and labeling requirements for flammable liquids highlight the need for carefulevaluation of these materials. The DOT labeling ignores combustible liquids and flammable liquids insmall containers or consumer commodities. The labeling may also overstate the hazard created bya liquid (e.g., 30% alcohol—water solution is considered a flammable liquid, however, the actualhazard is less than acetone which would have the same DOT label). Also, DOT labels should not be




used to classify liquids for evaluation with FM data sheets since the definitions are different.

Some other examples of the limitations of the DOT labeling system are:

1. Some material shipping containers may require labels that do not indicate recognized hazardouscharacteristics of the material. One example is anhydrous ammonia. DOT labeling requires a green‘‘nonflammable compressed gas’’ label on anhydrous ammonia containers instead of a red‘‘flammable gas’’ label. This is due to the definition of a ‘‘flammable gas’’ in Title 49, (i.e., ‘‘is ignitableat 14.7 psia [1 bar a] when in a mixture of 13% or less by volume with air.’’) Anhydrous ammoniahas a LEL of 15% and is considered by FM to be a flammable gas.

2. DOT labels do not indicate the degree of hazard for certain classes of materials. For example, alloxidizing materials and organic peroxides are marked with their respective hazard class label, despitethe wide variation in hazard among materials within these general hazard classes.

3. DOT labels are not required on containers that are used to transfer materials within a plant. Lackof a label on a container may only indicate it is not shipped off the plant grounds. It may still containhazardous materials.

2.2 Chlorinated Solvents

Some chlorinated solvents presently used in industry have confusing flammability properties. Threespecific liquids are trichloroethane, trichloroethylene and methylene chloride. Each of these liquidshas a flammable range, however, they do not have flash points. The existence of a flammable rangealone would seem to indicate that the liquids could create an explosion hazard when heated. Theirchemical structure indicates that they will burn; however, the fire severity (i.e., heat of combustionand heat release rate) is significantly less than that for ordinary hydrocarbons or alcohols. FM losshistory does not contain either an equipment or room explosion caused by any of these liquids.

Due to their very limited fire severity and the lack of any loss history, these three chlorinated solventsshould not be considered as creating a fire or explosion hazard.




Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids Table

FlashPoint

°F (°C)

IgnitionTemp.°F (°C)

FlammableLimits

Percent by Vol. Sp. Gr.(Water

=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble

See Introduction for Suggested

Extin-guishingMethods

HazardIdentification

Lower Upper HealthFlam-

mabilityReac-tivity

Abalyn See Methyl Abietate.

Acetal -5 446 1.6 10.4 0.8 4.1 215 Slight 1 2 3 0

CH3CH(OC2H5)2 (-21) (230) (102) 5

(Acetaldehydediethylacetal)

Acetaldehyde -38 347 4.0 60 0.8 1.5 70 Yes 1 2 4 2

CH3CHO (-39) (175) (21) 5

(Acetic Aldehyde)

(Ethanal) Note: Polymerizes. See Hazardous Chemicals Data.

Acetaldehydediethylacetal See Acetal.

Acetaldol See Aldol.

Acetanilide 337 985 ±10

1.21 4.65 582 3 1

CH3CONHC6H5 (169) (530) (306)

(oc)

Note: Melting point 237 (114).

Acetic Acid, Glacial 103 867 4.0 19.9 @ 1.0+ 2.1 245 Yes 5 2 2 1

CH3COOH (39) (463) 200 (93,4) (118)

Note: See Hazardous Chemicals Data.

Acetic Acid, Water Solutions(Ethanoic Acid)

Note: Ordinary acetic acid is the same as glacial acetic acid with water.The properties of ordinary acetic acid depend upon the strengtn ofthe solution. In concentrated form its properties approach those ofglacial acetic acid. In dilute solution it is nonhazardous.

Yes

Acetic Acid, Isopropyl Ester See Isopropyl Acetate.

Acetic Acid, Methyl Ester See Methyl Acetate.

Acetic Acid, n-Propyl Ester See Propyl Acetate.

Acetic Aldehyde See Acetaldehyde.

Acetic Anhydride 120 600 2.7 10.3 1.1 3.5 284 Yes 5 2 2 1

(CH3CO)2O (49) (316) (140)

(Ethanoic Anhydride) Note: See Hazardous Chemicals Data.

Acetic Ester See Ethyl Acetate.

Acetic Ether See Ethyl Acetate.

Acetoacetanilide 365 1.1@ Slight 5 2 1 0

CH3COCH2CONHC6H5 (185) melting 2

(oc) point


o-Acetoacet Anisidide 325 1.1@ 7.0 No 2 2 1 0

CH3COCH2CONHC6H4OCH3 (168) melting

(oc) point

Note: Melting point 187.9 (87).

Acetoacet-para-Phenetide 325 1.0+ Decomposes 2 2 1 1

CH3COCH2CONHC6H4OCH2CH3 (163)

Note: Melting point 210-219 (99-104).

Acetoacet-ortho-Toluidide 320 Decomposes 2 2 1 1

CH3COCH2CONHC6H4CH3 (160)


m-Acetoacet Xylidide 340 1.2 Slight 5 2 1 0

CH3COCH2CONHC6H3(CH3)2 (171) 2

(oc)


Acetoacetic Acid, Ethyl Ester See Ethyl Acetoacetate.

Acetoethylamide See N-Ethylacetamide.

Acetone -4 869 2.5 12.8 0.8 2.0 133 Yes 1 1 3 0

CH3COCH3 (-20) (465) (56) 5

(Dimethyl Ketone)

(2-Propanone)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Acetone Cyanohydrin 165 1270 2.2 12.0 0.9 2.9 248 Yes 5 4 1 2

(CH3)2C(OH)CN (74) (688) (120)

(2-Hydroxy-2-Methyl Propionitrile) Decomposes


Acetonitrile 42 975 3.0 16.0 0.8 1.4 179 Yes 1 2 3 0

CH3CN (6) (524) (82) 5

(Methyl Cyanide) (oc)


Acetonyl Acetone 174 920 1.0- 3.9 378 Yes 5 1 1 0

(CH2COCH3)2 (79) (499) (192)

(2,5-Hexanedione)

Acetophenone 170 1058 1.0+ 4.1 396 No 1 2 0

C6H5COCH3 (77) (570) (202)

(Phenyl Methyl Ketone)

p-Acetotoluidide 334 1.2 5.4 583 No 2 1

CH3CONHC6H4CH3 (168) (306)

Acetyl Acetone See 2,4-Pentanedione.

Acetyl Chloride 40 734 1.1 2.7 124 ViolentDecom-position

Do notuse

wateror

foam.

3 3 2

CH3COCl (4) (390) (51)

(Ethanoyl Chloride) Note: See Hazardous Chemicals Data.

Acetylene Gas 581 2.5 100 0.9 -118 No 6 1 4 3

CH CH (305) (-83)

(Ethine)

(Ethyne) Note: Low pressure. Acetylene dissolved in acetone in closed cylinders can carry a 2 reactivity.

See Hazardous Chemicals Data.

Acetylene Dichloride-cis See Dichloroethylene-cis.

Acetylene Dichloride-trans See Dichloroethylene-trans.

N-Acetyl Ethanolamine 355 860 1.1 304-308 Yes 5 1 1 1

CH3C:ONHCH2CH2OH (179) (460) (151-153) 2

[N-(2-Hydroxyethyl) (oc) @ 10 mm

acetamide] Decomposes

N-Acetyl Morpholine 235 1.1 Decomposes Yes 5 2 1 1

CH3CONCH2CH2OCH2CH2 (113) 2

Acetyl Oxide See Acetic Anhydride.

Acetyl Peroxide 1.2 4.1 Explodes on Slight 1 2 4

25% solution heating

in Dimethyl Phthalate Note: See Hazardous Chemicals Data.

(CH3CO)2O2

Acetylphenol See Phenyl Acetate.

Acrolein -15 428 2.8 31 0.8 1.9 125 Yes 1 3 3 2

CH2:CHCHO (-26) (220) (52) 5

(Acrylic Aldehyde) Unstable


Acrolein Dimer 118 1.1 304 Yes 5 1 2 1

(CH2:CHCHO)2 (48) (151)

(oc)


Acrylic Acid (Glacial) 122 820 2.4 8.0 1.1 2.5 287 Yes 5 3 2 2

CH2CHCOOH (50) (438) (142)

(oc)

Note: Polymerizes. See Hazardous Chemicals Data.

Acrylic Aldehyde See Acrolein.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Acrylonitrile 32 898 3.0 17 0.8 1.8 171 Yes 1 4 3 2

CH2:CHCN 0 (481) (77) 5

(Vinyl Cyanide) (oc)

(Propenenitrile)


Adipic Acid 385 788 1.37 5.04 509 No 1 0

HOOC(CH2)4COOH (196) (420) (265)

@ 100 mm

Adipic Ketone See Cyclopentanone.

Adiponitrile 200 1.0- 563 Slight 5 4 2 0

NC(CH2)4CN (93) (295)

(oc)


Adipoyl Chloride 162 257-262 5 2 2 0

(-CH2CH2COCl)2 (72) (125-128)

(Adipyl Chloride) @ 11 mm

Adipyldinitrile 199 0.96 3.73 563 No 4 2

CN(CH2)4CN (93) (295)

(Adiponitrile) (oc)

(Tetramethylene Dicyanide)

Alcohol See Ethyl Alcohol, Methyl Alcohol, Denatured Alcohol, etc.

Aldol 150 482 1.1 3.0 174-176 Yes 5 3 2 2

CH3CH(OH)CH2CHO (66) (250) (79-80)

(3-Hydroxybutanal) (oc) @ 12 mm

(β-Hydroxybuteraldehyde) Decomposes

@ 176 (80)

Allyl Acetate 72 705 0.9 3.45 219 No 5 1 3 0

CH3COCH2CH:CH2 (22) (374) (104) 1

(oc)

Allyl Alcohol 70 713 2.5 18.0 0.9 2.0 206 Yes 1 3 3 0

CH2:CHCH2OH (21) (378) (97) 5


Allylamine -20 705 2.2 22 0.8 2.0 128 Yes 1 3 3 1

CH2:CHCH2NH2 (-29) (374) (53) 5

(2-Propenylamine) Note: See Hazardous Chemicals Data.

Allyl Bromide 30 563 4.4 7.3 1.4 4.2 160 No 5 3 3 1

CH2:CHCH2Br (-1) (295) (71) 4

(3-Bromopropene)

Allyl Caproate 150 0.9 367-370 No 5 1 2 0

CH3(CH2)4COOCH2CH:CH2 (66) (186-188)

(Allyl Hexanoate)

(2-Propenyl Hexanoate)

Allyl Chloride -25 737 2.9 11.1 0.9 2.6 113 No 5 3 3 1

CH2:CHCH2Cl (-32) (485) (45)

(3-Chloropropene)

Allyl Chlorocarbonate See Allyl Chloroformate.

Allyl Chloroformate 88 1.1 4.2 223-237 No 5 3 3 1

CH2:CHCH2OCOCl (31) (106-114) 4

(Allyl Chlorocarbonate)


Allyl Diglycol Carbonate See Diethylene Glycol Bis (Allylcarbonate).

Allylene See Propyne.

Allyl Ether 20 0.8 3.4 203 Slight 5 3 3 2

(CH2:CHCH2)2O (-7) (95) 1

(Diallyl Ether) (oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Allylidene Diacetate 180 1.1 225 No 3 2 2 1

CH2:CHCH(OCOCH3)2 (82) (107)

(oc) @ 50 mm

Allyl Isothiocyanate See Mustard Oil.

Allylpropenyl See 1,4-Hexadiene.

Allyl Trichloride See 1,2,3-Trichloro Propane.

Allyl Trichlorosilane 95 1.2 6.05 243 1 3 3 2

CH2:CHCH2SiCl3 (35) (117.5)

(oc)

Allyl Vinyl Ether See Vinyl Allyl Ether.

Alpha Methyl Pyridine See Picoline-alpha.

Aminobenzene See Aniline.

2-Aminobiphenyl See 2-Biphenylamine.

1-Aminobutane See Butylamine.

2-Amino-1-Butanol 165 0.9 3.1 352 Yes 5 2 2 0

CH3CH2CHNH2CH2OH (74) (178)

(oc)

Aminocyclohexane See Cyclohexylamine.

1-Aminodecane See Decylamine.

Amino Ethane See Ethylamine.

2-Aminoethanol See Ethanolamine.

1-Amino-4-Ethoxybenzene See p-Phenetidine.

β-Aminoethyl Alcohol See Ethanolamine.

(2-Aminoethyl) Ethanolamine 270 695 1.0+ 470 Yes 5 2 1 0

NH2C2H4NHC2H4OH (132) (368) (243) 2

4-(2-Aminoethyl)-Morpholine 1.0 4.5 395.6 Yes 5 2 2 0

C2H4OC2H4NC2H4NH2 (202.8)

1-(2-Aminoethyl)-Piperazine 200 1.0- 4.4 432 Yes 5 2 2 0

H2NC2H4NCH2CH2NHCH2CH2 (93) (222)

(oc)

1-Aminoheptane See Heptylamine.

α-Aminoisopropyl Alcohol See 1-Amino-2-Propanol.

2-Amino-4-Methyl-pentane See 1,3-Dimethylbutylamine.

2-Amino-2-Methyl-1-Propanol 153 0.9 3.0 329 Yes 5 2 2 0

(CH3)2C(NH2)CH2OH (67) (165)

1-Aminooctane See Octylamine.

2-Aminopentane See sec-Amylamine.

p-Aminophenetole See p-Phenetidine.

(m-Aminophenyl) MethylCarbinol

315 1.1 423 Yes 5 2 1 0

NH2C6H4[CH(OH)CH3] (157) (217) 2

(m-Amino-α-Methyl-benzyl Alcohol) (oc) @ 100 mm

3-Aminopropanol 175 < 1.0 363-367 Yes 5 3 2 0

H2N(CH2)3OH (80) (184-186)

(oc)

1-Amino-2-Propanol 171 705 1.0- 2.6 320 Yes 5 2 2 0

NH2CH2CHOHCH3 (77) (374) (160)

(α-Aminoisopropyl Alcohol)

(Isopropanolamine)

N-(3-Aminopropyl)Cyclohexylamine

175 0.9 5.4 Yes 5 2 2 0

C6H11NHC3H6NH2 (79)

(oc)

N-(3-Aminopropyl) Morpholine 220 1.0- 438 Yes 5 2 1 0

C2H4OC2H4N(CH2)3NH2 (104) (226) 2

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Ammonia, Anhydrous Gas 1204 15 28 0.7@ 0.6 -28 Yes 6 3 1* 0

NH3 (651) -33°C (-33)

Note: See Hazardous Chemicals Data.*This gas is ‘‘1’’ instead of ‘‘4’’ because it is hard to burn.

Amoxybenzene See Amyl Phenyl Ether.

Amyl Acetate 60 680 1.1 7.5 0.9 4.5 300 Slight 1 1 3 0

CH3COOC5H11 (16) (360) (149) 5

(1-Pentanol Acetate) (Und. Lab. Class 55-60)

Comm. 70

(21)

sec-Amyl Acetate 89 0.9 4.5 249 Slight 1 1 3 0

CH3COOCH(CH3)(CH2)2)CH3 (32) (121) 5

(2-Pentanol Acetate)

Amyl Alcohol 91 572 1.2 10.0 0.8 3.0 280 Slight 5 1 3 0

CH3(CH2)3CH2OH (33) (300) @ 212 (138)

(1-Pentanol) (Und. Lab. Class40)

(100)

sec-Amyl Alcohol 94 650 1.2 9.0 0.8 3.0 245 Slight 1 1 3 0

CH3CH2CH2CH(OH)CH3 (34) (343) (118) 5

(Diethyl Carbinol) (Und. Lab. Class 40-45)

Amylamine 30 2.2 22 0.8 3.0 210 Yes 1 3 3 0

C5H11NH2 (-1) (99) 5

(Pentylamine)

sec-Amylamine 20 0.7 3.0 198 Yes 5 2 3 0

CH3(CH2)2CH(CH3)NH2 (-7) (92) 1

(2-Aminopentane)

(Methylpropylcarbinylamine)

p-tert-Amylaniline 215 0.9 498-504 No 2 3 1 0

(C2H5)(CH2)2CC6H4NH2 (102) (259-262)

Amylbenzene 150 0.8- 5.1 365 No 1 2 0

C6H5C5H11 (66) 0.9 (185)

(Phenylpentane) (oc)

Amyl Bromide 90 1.2 128-9 No 4 1 3 0

CH3CH2CH2CH2CH2Br (32) (53-54)

(1-Bromopentane) @ 746 mm

Amyl Butyrate 135 0.9 5.46 365 No 5 1 2 0

C5H11OOCC3H7 (57) (185)

Amyl Carbinol See Hexyl Alcohol.

Amyl Chloride 55 500 1.6 8.6 0.9 3.7 223 No 1 1 3 0

CH3(CH2)3CH2Cl (13) (260) (106)

(1-Chloropentane) (oc)

tert-Amyl Chloride 653 1.5 7.4 1.4 3.7 187 No 3 1 3 0

CH3CH2CCl(CH3)CH3 (345) (86)

Amyl Chlorides (Mixed) 38 0.9 185-228 No 1 1 3 0

C5H11Cl (3) (85-109)

(oc)

Amylcyclohexane 462 0.8 395 1 0

C5H11C6H11 (239) (202)

Amylene See 1 -Pentene.

β-Amylene-cis < -4 0.66 2.42 99 0 4

C2H5CH:CHCH3 (< -20) (37)

(2-Pentene-cis)

β-Amylene-trans < -4 0.67 2.42 97 0 4

C2H5CH:CHCH3 (< -20) (36)

(2-Pentene-trans)

Amylene Chloride See 1,5-Dichloropentane.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Amyl Ether 135 338 0.8- 5.5 374 No 5 1 2 0

C5H11OC5H11 (57) (170) 0.9 (190)

(Diamyl Ether) (oc)

(Pentyloxypentane)

Amyl Formate 79 0.9 4.0 267 No 1 1 3 0

HCOCC5H11 (26) (131)

Amyl Lactate 175 1.0- 5.5 237-239 Very 1 2 0

C2H5OCOOCH2CH(CH3)C2H5 (79) (114-115) slight

@ 36 mm

Amyl Laurate 300 0.9 554-626 No 2 0 1 0

C11H23COOC5H11 (149) (290-330)

Amyl Maleate 270 1.0- 518-599 No 2 0 1 0

(CHCOOC5H11)2 (132) (270-315)

Amyl Mercaptan (n) 65 0.8 3.59 260 2 3

C5H11SH (18) (127)

(1-Pentanethiol) (oc)

Amyl Mercaptans (Mixed) 65 0.8 176-257 No 1 2 3 0

CH3(CH2)4SH (18) (80-125)

(oc)


Amyl Naphthalene 255 1.0- 550 No 2 0 1 0

C10H7C5H11 (124) (288)

(oc)

Amyl Nitrate 118 1.0- 306-315 No 2 2 0 OX

CH3(CH2)4NO3 (48) (153-157)

(oc)

Amyl Nitrite 410 0.9 4.0 220 Slight 5 1 2

CH3(CH2)4NO2 (210) (104)

Amyl Oleate 366 0.9 392-464 No 2 0 1 0

C17H33COOC5H11 (186) (200-240)

@ 20 mm

Amyl Oxalate 245 1.0- 464-523 No 2 0 1 0

(COOC5H11)2 (118) (240-273)

(Diamyl Oxalate)

o-Amyl Phenol 219 1.0- 455-482 Slight 5 2 1 0

C5H11C6H4OH (104) (235-250) 2

(oc)

p-tert-Amyl Phenol See Pentaphen.

p-sec-Amylphenol 270 1.0- 482-516 No 2 1 1 0

C5H11C6H4OH (132) (250-269)

2-(p-tert-Amylphenoxy) ethanol 280 1.0+ 567-590 No 2 1 1 0

C5H11C6H4OCH2CH2OH (138) (297-310)

2-(p-tert-Amylphenoxy) ethylLaurate

410 0.9 464-500 2 0 1 0

C11H23COO(CH2)2OC6H4C5H11 (210) (240-260)

@ 6 mm

p-tert-Amylphenyl Acetate 240 1.0- 507-511 2 0 1 0

CH3COOC6H4C5H11 (116) (264-266)

p-tert-Amylphenyl Butyl Ether 275 0.9 540-550 No 2 0 1 0

C5H11C6H4OC4H9 (135) (282-288)

Amyl Phenyl Ether 185 0.9 5.7 421-444 No 0 2 0

CH3(CH2)4OC6H5 (85) (216-229)

(Amoxybenzene)

p-tert-Amylphenyl Methyl Ether 210 0.9 462-469 0 1 0

C5H11C6H4OCH3 (99) (239-243)

Amyl Phthalate See Diamyl Phthalate.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Amyl Propionate 106 712 0.9 275-347 No 0 2 0

C2H5COO(CH2)4CH3 (41) (378) (135-175)

(Pentyl Propionate) (oc)

Amyl Salicylate 270 1.1 512 No 2 0 1 0

HOC6H4COOC5H11 (132) (267)

Amyl Stearate 365 0.9 680 No 2 0 1 0

CH3(CH2)16COOC5H11 (185) (360)

(oc)

Amyl Sulfides, Mixed 185 0.9 338-356 No 2 2 0

C5H11S (85) (170-180)

(oc)

Amyl Toluene 180 0.9 400-415 No 2 2 0

C5H11C6H4CH3 (82) (204-213)

(oc)

Amyl Trichlorosilane 145 1.1 334 3 2 2

C5H11SiCl3 (63) (168)

(oc)

Amyl Xylyl Ether 205 0.9 480-500 No 2 1 0

C5H11OC6H3(CH3)2 (96) (249-260)

(oc)

Aniline 158 1139 1.3 1.1 1.0+ 3.2 364 Slight 5 3 2 0

C6H5NH2 (70) (615) (184)

(Aminobenzene) Note: See Hazardous Chemicals Data.

(Phenylamine)

Aniline Hydrochloride 380 1.22 4.46 473 3 1

C6H5NH2HCl (193) (245)

(oc)


2-Anilinoethanol 305 1.1 547 Very 2 2 1 0

C6H5NHCH2CH2OH (152) (286) slight

(β-Anilinoethanol Ethoxyaniline) (oc)

(β-Hydroxyethylaniline)

β-Anilinoethanol Ethoxyaniline See 2-Anilinoethanol.

o-Anisaldehyde See o-Methoxy Benzaldehyde.

o-Anisidine 244 1.1 435 No 5 2 1 0

H2NC6H4OCH3 (118) (224) 2

(2-Methoxyaniline) (oc)

Anisole 125 887 1.0- 3.7 309 No 1 2 0

C6H5OCH3 (52) (475) (154)

(Methoxybenzene) (oc)

(Methyl Phenyl Ether)

Anol See Cyclohexanol.

Anthracene 250 1004 0.6 1.24 6.15 644 0 1

(C6H4CH)2 (121) (540) (340)


Anthraquinone 365 1.44 7.16 716 No 0 1

C6H4(CO)2C6H4 (185) (380)


Artificial Almond Oil See Benzaldehyde.

Asphalt (Cutback) < 50 No 2 0 3 0

(< 10)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Asphalt, Liquid-Medium Curing 100 (min) Grades MC-30 and MC-70 No 2 0 2 0

(38)

(oc)

150 (min) Grades MC-250; MC-800; and MC-3000

(66)

(oc)

Asphalt, Liquid-Rapid Curing 80 (min) Grades RC-250; RC-800; and RC-3000 No 2 0 3 0

(27)

(oc)

Asphalt, Liquid-Slow Curing 150+ Grade SC-70 No 2 0 2 0

(66)

(oc)

175+ Grade SC-250 0 2 0

(79)

(oc)

200+ Grade SC-800 0 1 0

(93)

(oc)

225+ Grade SC-3000 0 1 0

(107)

(oc)

Asphalt (Typical) 400+ 905 1.0- > 700 No 2 0 1 0

(Petroleum Pitch) (204+) (485) 1.1 (> 371)

Aziridine See Ethyleneimine.

Azobisisobutyronitrile 147 Decomposes No 3 2

N:CC(CH3)2N:NC(CH3)2C:N (64)


Azole See Pyrrole.

Banana Oil See Isoamyl Acetate.

Benzaldehyde 145 377 1.1 3.7 355 No 3 2 2 0

C6H5CHO (63) (192) (179)

(Artificial Almond Oil)

(Benzenecarbonal)

Benzedrine < 212 0.93 4.67 392 0 1

C6H5CH2CH(CH3)NH2 (< 100) (200)

(1-Phenyl Isopropyl Amine)

Benzene 12 928 1.2 7.8 0.9 2.8 176 No 1 2 3 0

C6H6 (-11) (498) (80)

(Benzol) Note: See Hazardous Chemicals Data.

Benzenecarbonal See Benzaldehyde.

Benzene Carbonyl Chloride See Benzoyl Chloride.

Benzine See Petroleum Ether.

Benzocyclobutene 95 477 0.96 306

(35) (247) (152)

Benzoic Acid 250 1058 1.27 4.21 482 Slight 2 1

C6H5COOH (121) (570) (250)


Benzol See Benzene.

Benzol Diluent -25 450 1.0 7.0 < 1 140-210 No 1 2 3 0

(-32) (232) (60-99)

Note: Flash point and ignition temperature will vary depending on the manufacturer.

p-Benzoquinone 100-200 1040 1.3 3.7 Sublimes No 1 2 1

C6H4O2 (38-93) (560)

(Quinone) Note: Melting point 234-237 (112-114).




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Benzotrichloride 260 412 1.4 429 No 2 3 1 0

C6H5CCl3 (127) (211) (221)

(Toluene,a,a,a-Trichloro)

(Phenyl Chloroform)

Benzotrifluoride 54 1.2 5.0 216 No 4 4 3 0

C6H5CF3 (12) (102)


Benzoyl Chloride 162 1.2 4.9 387 Decomposes 3 2 1

C6H5COCl (72) (197)

(Benzene Carbonyl Chloride) Decomposes inwater.


Benzyl Acetate 195 860 1.1 417 Slight 5 1 1 0

CH3COOCH2C6H5 (90) (460) (214) 2

Benzyl Alcohol 200 817 1.0+ 403 Slight 5 2 1 0

C6H5CH2OH (93) (436) (206) 2

(Phenyl Carbinol)

Benzyl Benzoate 298 896 1.1 614 No 2 1 1 0

C6H5COOCH2C6H5 (148) (480) (323)

Benzyl Butyl Phthalate 390 1.1 698 No 2 1 1 0

C4H9COOC6H4COOCH2C6H5 (199) (370)

(Butyl Benzyl Phthalate)

Benzyl Carbinol See Phenethyl Alcohol.

Benzyl Chloride 153 1085 1.1 1.1 4.4 354 No 3 2 2 1

C6H5CH2Cl (67) (585) (179)

(α-Chlorotoluene) Note: See Hazardous Chemicals Data.

Benzyl Cyanide 235 1.0+ 452 No 5 2 1 0

C6H5CH2CN (113) (233.5) 2

(Phenyl Acetonitrile) (oc)

(α-Tolunitrile)

N-Benzyldiethylamine 170 0.9 405-420 2 2 0

C6H5CH2N(C2H5)2 (77) (207-216)

(oc)

Benzyl Ether See Dibenzyl Ether.

Benzyl Mercaptan 158 1.06 4.28 383 2 2

C6H5CH2SH (70) (195)

(α-Toluenethiol)

Benzyl Salicilate >212 1.2 406 No 5 1 1 0

OHC6H4COOCH2C6H5 (>100) (208)

(Salycilic Acid Benzyl Ester)

Bicyclohexyl 165 473 0.7 @ 5.1 @ 0.9 5.7 462 Slight 5 1 2 0

[CH2(CH2)4CH]2 (74) (245) 212 302 (239)

(Dicyclohexyl) (100) (150)

Biphenyl 235 1004 0.6 @ 5.8 @ 1.2 489 No 2 2 1 0

C6H5C6H5 (113) (540) 232 311 (254)

(Diphenyl) (111) (155)

(Phenylbenzene) Note: Melting point 158 (70).

2-Biphenylamine 842 5.8 570 No 2 2 1 0

NH2C6H4C6H5 (450) (299)

(2-Aminobiphenyl) Note: Melting point 121 (49).

Bis (p-tert-Butylphenyl) phenylPhosphate

482 1.1 500-527 No 2 1 0

(C4H9C6H4O)2POOC6H5 (250) (260-275)

@ 5 mm

Bis [2-(2-Chloroethoxy) ethyl]Ether

>250 1.2 237 Slight 5 2 1 0

(CH2ClCH2OCH2CH2)2O (>121) (114) 2

(Tetraglycol Dichloride)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Bis (2-Chloroethyl) Ether 131 1.2 4.9 353 Very 2 2 0

(CH2ClCH2)2O (55) (178) slight

(Chlorex)

Bis (2-Chloroethyl) Formal 230 1.2 425 Very 5 2 1 0

CH2(OCH2CH2Cl)2 (110) (218) slight 2

(Di-(2-Chloroethyl) Formal) (oc)

(2,2-Dichloroethyl Formal)

Bis ( β-Chloroisopropyl) Ether See Dichloroisopropyl Ether.

Bis-Diethylene Glycol MonoethylEther Phthalate

405 1.1 500 5 1 1 0

C6H4(COOC2H4OC2H4OC2H5)2 (207) (260) 2

Bis (2,4-Dimethylbutyl) Maleate 290 0.9 394 No 2 1 1 0

[(CH3)2CHCH2CH(CH3OCOCH:]2 (143) (201)

(Di(Methylamyl) Maleate) (oc) @ 50 mm

N,N1-Bis-(1,4-Dimethyl-pentyl)p-Phenylenediamine

347 770 0.9 5 2 1 0

C6H4[NHCH(CH3)CH2CH2CH(CH3)2]2 (175) (410) 2

1,3-Bis (Ethylamino) Butane See N,N-Diethyl-1,3-Butanediamine.

Bis (2-Ethylhexyl) Amine 270 0.8 537 Slight 5 3 1 0

[C4H9CH(C2H5)CH2]2NH (132) (281) 2

(Diethylhexylamine) (oc)

(Dioctylamine)

Bis (2-Ethylhexyl)-Ethanolamine 280 0.9 421 Slight 5 1 1 0

[C4H9CH(C2H5)CH2]2NC2H4OH (138) (216) 2

(Diethylhexylethanolamine) @ 50 mm

Bis (2-Ethylhexyl) Maleate 365 0.9 408 No 5 0 1 0

C8H17OCOCH:CHCOOC8H17 (185) (209) 2

(Di(2-Ethylhexyl) Maleate) @ 10 mm

Bis (2-Ethylhexyl) PhosphoricAcid

385 1.0- No 5

[C4H9CH(C2H5)CH]2HPO4 (196) 2

(Di(2-Ethylhexyl) Phosphoric Acid) (oc)

Bis (2-Ethylhexyl) Succinate 315 0.9 495 Slight 5 0 1 0

(C10H19O2)2 (157) (257) 2

(Di(2-Ethylhexyl) Succinate) @ 50 mm

N,N-Bis (1-Methylheptyl)Ethylenediamine

>400 0.8 424 No 2 0 1 0

HC(CH3)(C6H13)NHCH2CH2-NHCH(CH3)(C6H13)

(>204) (218)

@ 43 mm

Bis ( β-Methylpropyl) Amine See Diisobutylamine.

Bis (2,2,4-Trimethyl-pentanediolisobutyrate)Diglycolate

383 1.1 639 2 0 1 0

C28H27O9 (195) (337)

(oc)

Blast-furnace Gas See Gas.

Borneo Camphor See Borneol.

Borneol 150 1.0+ 413 No 2 2 0

C10H17OH (66) (212)

(Borneo Camphor) Sublimes

Boron Trifluoride Etherate 147 1.1 259 Decomposes 3 2 1

CH3CH2O(BF3)CH2CH3 (64) (126) Decomposes in water.

(oc)

Brandy See Ethyl Alcohol and Water.

Brazil Wax See Carnauba Wax.

Bromobenzene 124 1049 1.5 5.4 313 No 3 2 2 0

C6H5Br (51) (565) (156)

(Phenyl Bromide)

1-Bromo Butane See Butyl Bromide.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

4-Bromodiphenyl 291 592 No 2 2 1 0

C6H5C6H4Br (144) (311)

Bromoethane See Ethyl Bromide.

Bromomethane See Methyl Bromide.

1-Bromopentane See Amyl Bromide.

3-Bromopropene See Allyl Bromide.

o-Bromotoluene 174 1.4 5.9 359 No 3 2 2 0

BrC6H4CH3 (79) (182)

p-Bromotoluene 185 1.4 5.9 363 No 3 2 2 0

BrC6H4CH3 (85) (184)

Bronzing Liquid May be below 80 (27). No

1,3-Butadiene Gas 788 2.0 12.0 1.9 24 No 6 2 4 2

CH2:CHCH:CH2 (420) (-4)

(Erythrene)


Butadiene Monoxide < -58 0.9 2.4 151 1 2 3 2

CH2:CHCHOCH2 (< -50) (66)

(Vinylethylene Oxide)

Butanal See Butyraldehyde.

Butanal Oxime See Butyraldoxime.

Butane -76 550 1.9 8.5 2.0 31 No 6 1 4 0

CH3CH2CH2CH3 (-60) (287) (-1)

1,3-Butanediamine 125 0.9 3.0 289-302 Yes 5 3 2 0

NH2CH2CH2CHNH2CH3 (52) (143-150)

(1,3-Diaminobutane) (oc)

1,2-Butanediol 104 1.0 3.1 381 Slight 5 1 2 0

CH3CH2CHOHCH2OH (40) (194)

(1,2-Dihydroxybutane)

(Ethylethylene Glycol)

1,3-Butanediol See β-Butylene Glycol.

1,4-Butanediol 250 1.0+ 3.1 442 Yes 2 1 1 0

HOCH2CH2CH2CH2OH (121) (228) 5

(oc)


2,3-Butanediol 756 1.0+ 363 Yes 5 1 1 0

CH3CHOHCHOHCH3 (402) (184)

2,3-Butanedione 80 1.0- 3.0 190 Yes 5 1 3 0

CH3COCOCH3 (27) (88)

(Diacetyl)

1-Butanethiol 35 0.8 3.1 208 Slight 5 2 3 0

CH3CH2CH2CH2SH (2) (98) 1

(Butyl Mercaptan)

2-Butanethiol -10 0.8 3.11 185 No 5 2 3 0

C4H9SH (-23) (85) 1

(sec-Butyl Mercaptan)

1-Butanol See Butyl Alcohol.

2-Butanol See sec-Butyl Alcohol.

2-Butanone See Methyl Ethyl Ketone.

2-Butenal See Crotonaldehyde.

1-Butene Gas 725 1.6 10.0 1.9 21 No 6 1 4 0

CH3CH2CH:CH2 (385) (-6)

(α-Butylene)

2-Butene-cis Gas 617 1.7 9.0 0.6 1.9 38.7 6 1 4 0

CH3CH:CHCH3 (325) (4)

2-Butene-trans Gas 615 1.8 9.7 1.9 -34 No 6 1 4 0

CH3CH:CHCH3 (324) (1)

(β-Butylene)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Butenediol 263 1.1 3.0 286-300 Yes 2 1 1 0

HOCH2CH:CHCH2OH (128) (141-149) 5

(2-Butene-1,4-Diol) (oc) @ 20 mm


2-Butene-1,4-Diol See Butenediol.

2-Butene Nitrile See Crotononitrile.

Butoxybenzene See Butyl Phenyl Ether

1-Butoxybutane See Dibutyl Ether.

2,β-Butoxyethoxyethyl Chloride 190 1.0 6.1 392-437 2 2 0

C4H9CH2CH2OCH2CH2Cl (88) (200-225)

1-(Butoxyethoxy)-2-Propanol 250 509 0.9 445 Yes 5 2 1 0

CH3CH(OH)CH2OC2H4OC2H4C2H5 (121) (265) (229) 2

(oc)

Butoxyethyl Diglycol Carbonate See Diethylene Glycol Bis (2-Butoxyethyl Carbonate).

β-Butoxyethyl Salicylate 315 1.0+ 367-378 No 2 0 1 0

OCH6H4OOCH2CH2OC4H9 (157) (186-192)

Butoxyl See 3-Methoxybutyl Acetate.

N-Butyl Acetamide 240 0.9 455-464 2 2 1 0

CH3CONHC4H9 (116) (235-240)

N-Butylacetanilide 286 1.0- 531-538 No 2 2 1 0

CH3(CH2)3N(C6H5)COCH3 (141) (277-281)

Butyl Acetate 72 797 1.7 7.6 0.9 4.0 260 Slight 1 1 3 0

CH3COOC4H9 (22) (425) (127) 5

(Butylethanoate)

sec-Butyl Acetate 88 1.7 9.8 0.9 4.0 234 Slight 1 1 3 0

CH3COOCH(CH3)C2H5 (31) (112) 5

(oc)

Butyl Acetoacetate 185 1.0- 5.5 417 Slight 5 1 2 0

CH3COCH2COO(CH2)3CH3 (85) (214)

(oc)

Butyl Acetyl Ricinoleate 230 725 0.9 428 No 2 2 1 0

C17H32(OCOCH3)(COOC4H9) (110) (385) (220)

Butyl Acrylate 84 559 1.7 9.9 0.9 4.4 260 No 2 2 2

CH2:CHCOOC4H9 (29) (292) (127)

Polymerizes

Butyl Alcohol 98 650 1.4 11.2 0.8 2.6 243 No 1 1 3 0

CH3(CH2)2CH2OH (37) (343) (117) 5

(1-Butanol)

(Propylcarbinol)

(Propyl Methanol)

sec-Butyl Alcohol 75 761 1.7 @ 9.8 @ 0.8 2.6 201 Slight 1 1 3 0

CH3CH2CHOHCH3 (24) (405) 212 212 (94) 5

(2-Butanol) (100) (100)

(Methyl Ethyl Carbinol)

tert-Butyl Alcohol 52 892 2.4 8.0 0.8 2.6 181 Yes 1 1 3 0

(CH3)2COHCH3 (11) (478) (83) 5

(2-Methyl-2-Propanol)

(Trimethyl Carbinol)

Butylamine 10 594 1.7 9.8 0.8 2.5 172 Yes 1 2 3 0

C4H9NH2 (-12) (312) (78) 5

(1-Amino Butane)

sec-Butylamine 16 0.72 2.52 145 3 3

CH3CH2CH(NH2)CH3 (-9) (63)

tert-Butylamine 716 1.7 @ 8.9 @ 0.7 2.5 113 Yes 5 2 4 0

(CH3)3C:NH2 (380) 212 212 (45)

(100) (100)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Butylamine Oleate 150 0.9 Yes 5 3 2 0

C17H33COONH3C4H9 (66)

(oc)

tert-ButylaminoethylMethacrylate

205 0.9 5.5 200-221 No 2 1 0

(CH3)3CNHC2H4OOCC(CH3):CH2 (96) (93-105)

(oc)

N-Butylaniline 225 0.9 465 Slight 5 3 1 0

C6H5NHC4H9 (107) (241) 2

(oc)

Butylbenzene 160 770 0.8 5.8 0.9 4.6 356 No 2 2 0

C6H5C4H9 (71) (410) (180)

(oc)

sec-Butylbenzene 126 784 0.8 6.9 0.9 4.6 344 No 2 2 0

C6H5CH(CH3)C2H5 (52) (418) (173)

tert-Butylbenzene 140 842 0.7 @ 5.7 @ 0.9 4.6 336 No 2 2 0

C6H5C(CH3)3 (60) (450) 212 212 (169)

(oc) (100) (100)

Butyl Benzoate 225 1.0 482 No 2 1 1 0

C6H5COOC4H9 (107) (250)

(oc)

Butyl Benzyl Phthalate See Benzyl Butyl Phthalate.

2-Butylbiphenyl > 212 806 7.26 ~554 0 1

C6H5.C6H4.C4H9 (>100) (430) (~290)

Butyl Bromide 65 509 2.6 @ 6.6 @ 1.3 4.7 215 No 4 2 3 0

CH3(CH2)2CH2Br (18) (265) 212 212 (102)

(1-Bromo Butane) (100) (100)

Butyl Butyrate 128 0.9 5.0 305 Slight 5 2 2 0

CH3(CH2)2COOC4H9 (53) (152)

(oc)

Butylcarbamic Acid, Ethyl Ester See N-Butylurethane.

tert-Butyl Carbinol 98 0.8 3.0 237 Slight 1 2 3 0

(CH3)3CCH2OH (37) (114) 5

(2,2-Dimethyl-1-Propanol)

Butyl Carbitol See Diethylene Glycol Monobutyl Ether.

4-tert-Butyl Catechol 266 1.0+ 545 No 2 2 1 0

(OH)2C6H3C(CH3)3 (130) (285)

Butyl Chloride 15 464 1.8 10.1 0.9 3.2 170 No 1 2 3 0

C4H9Cl (-9) (240) (77)

(1-Chlorobutane)

sec-Butyl Chloride < 32 0.87 3.20 155 2 3

CH3CHClC2H5 (< 0) (68)

(2-Chlorobutane)

tert-Butyl Chloride < 32 0.87 3.20 124 2 3

(CH3)3CCl (< 0) (51)

(2-Chloro-2-Methyl-Propane)

4-tert-Butyl-2-Chlorophenol 225 1.1 453-484 No 2 2 1 0

ClC6H3(OH)C(CH3)3 (107) (234-251)

tert-Butyl-m-Cresol 116 1.0- 451-469 No 2 2 0

C6H3(C4H9)(CH3)OH (47) (233-243)

p-tert-Butyl-o-Cresol 244 1.0- 278-280 No 2 2 1 0

(OH)C6H3CH3C(CH3)3 (118) (137-138)

Butylcyclohexane 475 0.8 352-356 0 0

C4H9C6H11 (246) (178-180)

(1-Cyclohexylbutane)

sec-Butylcyclohexane 531 0.8 351 0 0

CH3CH2CH(CH3)C6H11 (277) (177)

(2-Cyclohexylbutane)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

tert-Butylcyclohexane 648 0.8 333-336 0 0

(CH3)3CC6H11 (342) (167-169)

N-Butylcyclohexylamine 200 0.8 409 Slight 5 2 1 0

C6H11NH(C4H9) (93) (209)

(oc)

Butylcyclopentane 480 0.8 314 0 0

C4H9C5H9 (250) (157)

Butyldecalin 500 2 1 1 0

C4H9C10H17 (260)

tert-Butyldecalin 640 2 1 1 0

C4H9C10H17 (338)

N-Butyldiethanolamine 245 1.0- 504 Yes 5 2 1 0

C4H9N(C2H4OH)2 (118) (262) 2

(oc)

tert-Butyldiethanolamine 285 1.0- 329-338 Yes 2 2 1 0

C8H10NO2 (141) (165-170) 5

[2,2-(tert-Butylimino) Diethanol] (oc) @ 33 mm


Butyl Diglycol Carbonate See Diethylene Glycol Bis (Butyl Carbonate).

α-Butylene See 1-Butene.

β-Butylene See 2-Butene-trans.

γ-Butylene See 2-Methylpropene.

α-Butylene Glycol 194 1.01 3.10 377 0 2

C2H5CHOHCH2OH (90) (192)

(1,2-Butanediol)

β-Butylene Glycol 250 743 1.0 399 Yes 5 1 1 0

CH3CH(OH)CH2CH2OH (121) (395) (204) 2

(1,3-Butanediol)

Butylene Glycol (pseudo) 185 1.01 3.10 356 0 2

CH3(CHOH)2CH3 (85) (180)

(2,3-Butanediol) (oc)

(Dihydroxy Butane 2,3)

2,3-Butylene Oxide 5 822 1.5 18.3 0.83 2.49 149 Slight 2 3 2

CH3HCOCHCH3 (-15) (439) (65)

1,2-Butylene Oxide -7 822 1.7 19 0.8 2.2 145 Yes 5 2 3 2

H2COCHCH2CH3 (-22) (439) (63) 1


Butyl Ethanedioate See Butyl Oxalate.

N-Butyl Ethanolamine 170 0.9 4.0 377 Yes 5 1 2 0

CH3(CH2)3NHCH2CH2OH (77) (192)

(oc)

Butyl Ether See Dibutyl Ether.

Butylethylacetaldehyde See 2-Ethylhexanal.

Butyl Ethylene See 1-Hexene.

Butyl Ethyl Ether See Ethyl Butyl Ether.

Butyl Formate 64 612 1.7 8.2 0.9 3.5 225 Yes 1 2 3 0

HCOOC4H9 (18) (322) (107) 5

(Butyl Methanoate)

(Formic Acid, Butyl Ester)

Butyl Glycolate 142 1.01 4.45 ~356 0 2

CH2OHCOOC4H9 (61) (~180)

tert-Butyl Hydroperoxide < 80 orabove

0.9 Slight 5 1 4 4 OX

(CH3)3COOH (< 27)

Note: May explode. See Hazardous Chemicals Data.

2,2-(Butylimino) Diethanol See tert-Butyldiethanolamine.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

n-Butyl Isocyanate 66 0.9 3.00 235 Reacts 5 3 2 2

CH3(CH2)3NCO (19) (113)

(Butyl Isocyanate)

Butyl Isovalerate 127 0.87 5.45 302 0

C4H9OOCCH2CH(CH3)2 (53) (150)

Butyl Lactate 160 720 1.0- 5.0 320 Slight 5 1 2 0

CH3CH(OH)COOC4H9 (71) (382) (160)

(oc)

Butyl Mercaptan See 1-Butanethiol.

tert-Butyl Mercaptan See 2-Methyl-2-Propanethiol.

Butyl Methacrylate 126 0.9 4.9 325 No 2 2 0

CH2:C(CH3)COO(CH2)3CH3 (52) (163)

(oc)

Butyl Methanoate See Butyl Formate.

N-Butyl Monoethanolamine 170 0.9 4.0 378 Yes 5 1 2 0

C4H9NHC2H4OH (77) (192)

(oc)

Butyl Naphthalene 680 No 2 1 1 0

C4H9C10H7 (360)

Butyl Nitrate 97 1.0+ 4.1 277 No 1 1 3 3

CH3(CH2)3ONO2 (36) (136)

2-Butyloctanol 230 0.8 486 No 2 1 1 0

C6H13CH(C4H9)CH2OH (110) (252)

Butyl Oleate 356 0.9 440.6-442.4 No 2 0 1 0

C17H33COOC4H9 (180) (227-228)

(oc) @ 15 mm

Butyl Oxalate 265 1.0- 472 No 2 0 1 0

(COOC4H9)2 (129) (244)

(Butyl Ethanedioate) (oc)

tert-Butyl Peracetate < 80 Explodes onheating.

No 1 2 3 4

diluted with 25 of benzene (< 27)

CH3CO(O2)C(CH3)3 Note: Rapid decomposition at 200 (93). See Hazardous Chemicals Data.

tert-Butyl Perbenzoate >190 1.0+ Explodes onheating.

No 1 3 4 OX

C6H5COOOC(CH3)3 (> 88)

(oc)


tert-Butyl Peroxypivalate >155 Explodes onheating.

No 0 3 4 OX

diluted with 25 of mineral spirits (> 68)

(CH3)3COOCOC(CH3)3 (oc)

Note: Rapid decomposition at 90 (32). See Hazardous Chemicals Data.

β-(p-tert-Butyl Phenoxy) Ethanol 248 1.0+ 293-313 No 2 0 1 0

(CH3)3CC6H4OCH2CH2OH (120) (145-156)

(oc)

β-(p-tert-Butylphenoxy) EthylAcetate

324 1.0+ 579-585 No 2 0 1 0

(CH3)3CC6H4OCH2CH2OCOCH3 (162) (304-307)

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Butyl Phenyl Ether 180 0.9 5.2 410 No 1 2 0

CH3(CH2)3OC6H5 (82) (210)

(Butoxybenzene) (oc)

4-tert-Butyl-2-Phenylphenol 320 1.0+ 385-388 No 2 1 1 0

C6H5C6H3OHC(CH3)3 (160) (196-198)

Butyl Phosphate 295 0.98 9.12 559 3 1

PO4(C4H9)3 (146) (293)

(Tributyl Phosphate) (oc)

Butyl Phthalyl Butyl Glycolate 390 1.1 653 No 2 1 1 0

C6H4(COO)2(C4H9)CH2COOC4H9 (199) (345)

(oc)

Butyl Propionate 90 799 0.9 4.5 295 No 1 2 3 0

C2H5COOC4H9 (32) (426) (146)

Butyl Ricinoleate 230 0.9 790 No 2 1 1 0

C18H33O3C4H9 (110) (421)

Butyl Sebacate 353 0.9 653 No 2 1 1 0

[(CH2)4COOC4H9]2 (178) (345)

(oc)

Butyl Stearate 320 671 0.9 650 No 2 1 1 0

C17H35COOC4H9 (160) (355) (343)

tert-Butylstyrene 177 1 2.7 0.9 426 No 2 2 2

(81) (219)

TCC

tert-Butyl Tetralin 680 2 2 1 0

C4H9C10H11 (360)

Butyl Trichlorosilane 130 1.2 6.5 300 No 3 2 2 0

CH3(CH2)3SiCl3 (54) (149)

(oc)

N-Butylurethane 197 0.9 5.0 396-397 No 2 0

CH3(CH2)3NHCOOC2H5 (92) (202-203)

(Butylcarbamic Acid, Ethyl Ester)

(Ethyl Butylcarbamate)

Butyl Vinyl Ether See Vinyl Butyl Ether.

2-Butyne < -4 1.4 0.69 1.86 81 4

CH3CCCH3 (< -20) (27)

(Crotonylene)

Butyraldehyde -8 425 1.9 12.5 0.8 2.5 169 No 1 2 3 0

CH3(CH2)2CHO (-22) (218) (76)

(Butanal)

(Butyric Aldehyde) Note: See Hazardous Chemicals Data.

Butyraldol 165 0.9 280 Slight 5 2 2 0

C8H16O2 (74) (138)

(oc) @ 50 mm

Butyraldoxime 136 0.9 3.0 306 Slight 5 2 2 0

C4H8NOH (58) (152)

(Butanal Oxime)

Butyric Acid 161 830 2.0 10.0 1.0- 3.0 327 Yes 5 2 2 0

CH3(CH2)2COOH (72) (443) (164)


Butyric Acid, Ethyl Ester See Ethyl Butyrate.

Butyric Aldehyde See Butyraldehyde.

Butyric Anhydride 180 535 0.9 5.8 1.0- 5.4 388 Decomposes 5 1 2 1

[CH3(CH2)2CO]2O (54) (279) (196)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Butyric Ester See Ethyl Butyrate.

Butyrolactone 209 1.1 399 Yes 5 0 1 0

CH2CH2CH2COO (98) (204)

(oc)

Butyrone See 4-Heptanone.

Butyronitrile 76 935 1.65 0.8 2.4 243 Slight 5 3 3 0

CH3CH2CH2CN (24) (501) (117)

(oc)

Camphor 150 871 0.6 3.5 1.0- 5.24 399 No 0 2 0

C10H16O (66) (466) (204)

(Gum Camphor)

Camphor Oil (light) 117 0.9 347-392 No 2 2 0

(Liquid Camphor) (47) (175-200)

Caproaldehyde See Hexanol.

Caproic Acid 215 716 0.9 400 No 2 2 1 0

(CH3)(CH2)4COOH (102) (380) (204)

(Hexanoic Acid) (oc)

Caprylaldehyde 125 0.8 4.4 335 Very 2 2 0

CH3(CH2)6CHO (52) (168) slight

(Caprylic Aldehyde)

(Octanal)

Caprylic Aldehyde See Caprylaldehyde

Caprylyl Chloride 180 1.0- 5.6 384 Decomposes 5 3 2 1

CH3(CH2)6COCl (82) (196)

Carbitol See Diethylene Glycol Monoethyl Ether.

Carbolic Acid See Phenol.

Carbon Bisulfide See Carbon Disulfide.

Carbon Disulfide -22 194 1.3 50.0 1.3 2.6 115 No 4 2 3 0

CS2 (-30) (90) (46)

(Carbon Bisulfide) Note: See Hazardous Chemicals Data.

Carbon Monoxide Gas 1128 12.5 74 1.0 -314 Slight orvery

slight,2, 3ml

per 100ml

6 2 4 0

CO (609) (-192)

Carbon Oxysulfide Gas 12 29 2.1 -58 6 3 4 1

COS (-50)

(Carbonyl Sulfide)

Carbonyl Sulfide See Carbon Oxysulfide.

Carnauba Wax 540 1.0- No 2 0 1 0

(Brazil Wax) (282)


Castor Oil 445 840 1.0- 595 No 2 0 1 0

(Ricinus Oil) (229) (449) (313)

Castor Oil (Hydrogenated) 401 No 2 0 1 0

(C18H35O3)3C3H5 (205)

Cellulose Nitrate Wet withAlcohol

55 No 1 2 3 3

(Nitrocellulose) (13) 5


Cetane See Hexadecane.

China Wood Oil See Tung Oil.

Chlorex See Bis (2-chloroethyl) Ether.

Chlorine Monoxide Gas 23.5 100 Explodes Yes 3 4 3

Cl2O @ 39 (4) Explodes on heating.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Chloroacetic Acid 259 > 932 1.58 3.26 372 Yes 3 1 0

CH2ClCOOH (126) (> 500) (189)

Chloroaceto Phenone 244 1.32 5.32 477 No 2 1 0

C6H5COCH2Cl (118) (247)

(Phenacyl Chloride)

2-Chloro-4,6-di-tert-Amylphenol 250 1.0+ 320-354 2 2 1 0

(C5H11)2C6H2ClOH (121) (160-179)

@ 22 mm

Chloro-4-tert-Amylphenol 225 1.1 487-509 2 2 1 0

C5H11C6H3ClOH (107) (253-265)

2-Chloro-4-tert-AmylphenylMethyl Ether

230 1.1 7.3 518-529 2 1 1 0

C5H11C6H3ClOCH3 (110) (270-276)

p-Chlorobenzaldehyde 190 1.2 417 Slight 5 2 2 0

ClC6H4CHO (88) (214)


Chlorobenzene 82 1099 1.3 9.6 1.1 3.9 270 No 4 2 3 0

C6H5Cl (28) (593) (132)

(Chlorobenzol)

(Monochlorobenzene) Note: See Hazardous Chemicals Data.

(Phenyl Chloride)

Chlorobenzol See Chlorobenzene.

Chlorobenzotrifluoride 117 1.35 6.24 282 2 0

ClC6H4CF3 (47) (139)

o-Chlorobenzotrifluoride 138 1.4 6.2 306 2 2 1

ClC6H4CF3 (59) (152)

(o-Chloro-α,α,α-trifluorotoluene)

Chlorobutadiene See 2-Chloro-1,3-Butadiene.

2-Chloro-1,3-Butadiene -4 4.0 20.0 1.0 3.0 138 Slight 1 2 3 0

CH2:CCl:CH:CH2 (-20) (59) 5

(Chlorobutadiene)

(Chloroprene)

1-Chlorobutane See Butyl Chloride.

2-Chlorobutene-2 -3 2.3 9.3 0.9 3.1 143-159 Very 1 2 3 0

CH3CCl:CHCH3 (-19) (62-71) slight

Chlorodiethylaluminum See Diethylaluminum Chloride.

Chlorodinitrobenzene See Dinitrochlorobenzene.

Chloroethane See Ethyl Chloride.

2-Chloroethanol 140 797 4.9 15.9 1.2 2.8 264-266 Yes 5 3 2 0

CH2ClCH2OH (60) (425) (129-130)

(2-Chloroethyl Alcohol)

(Ethylene Chlorohydrin)

Chloroethyl Acetate 129 1.2 4.2 293 No 3 2 2 0

C2H4ClOOCCH3 (54) (145)

2-Chloroethyl Acetate 151 1.2 4.2 291 No 3 2 2 0

CH3COOCH2CH2Cl (66) (144)

2-Chloroethyl Alcohol See 2-Chloroethanol.

Chloro-4-Ethylbenzene 147 1.0+ 4.9 364 No 1 2 0

C2H5C6H4Cl (64) (184)

Chloroethylene See Vinyl Chloride.

2-Chloroethyl Vinyl Ether See Vinyl 2-Chloroethyl Ether.

2-Chloroethyl-2-Xenyl Ether 320 1.1 613 Slight 2 1 0

C6H5C6H4OCH2CH2Cl (160) (323) 5

1-Chlorohexane 95 0.9 4.2 270 No 1 3 0

CH3(CH2)4CH2Cl (35) (132)

(Hexyl Chloride)

Chloroisopropyl Alcohol See 1-Chloro-2-Propanol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Chloromethane See Methyl Chloride.

1-Chloro-2-Methyl Propane See Isobutyl Chloride.

1-Chloronaphthalene 250 >1036 1.2 5.6 505 No 2 1 1 0

C10H7Cl (121) (>558) (263)

2-Chloro-5-Nitrobenzotrifluoride 275 1.6 446 2 1 3

C6H3CF3(2-Cl, 5-NO2) (135) (230)

(2-Chloro-α,α,α-Trifluoro-5-Nitrotoluene)

1-Chloro-1-Nitroethane 133 1.3 3.8 344 Slight 5 2 3

C2H4NO2Cl (56) (173)

(oc)

1-Chloro-1-Nitropropane 144 1.2 4.3 285 Slight 5 2 3

CHNO2ClC2H5 (62) (141)

(oc)

2-Chloro-2-Nitropropane 135 1.2 4.3 273 Slight 2 3

CH3CNO2ClCH3 (57)(oc)

(134)

Explodes uponrapid heating

Explodes onheating

1-Chloropentane See Amyl Chloride.

β-Chlorophenetole 225 1.1 306-311 Slight 5 1 0

C6H5OCH2CH2 (107) (152-155) 2

(β-Phenoxyethyl Chloride)

o-Chlorophenol 147 1.3 347 Slight 5 3 2 0

ClC6H4OH (64) (175)

p-Chlorophenol 250 1.31 4.43 428 3 1 0

C6H4OHCl (121) (220)

2-Chloro-4-Phenylphenol 345 < 1 613 Slight 2 2 1 0

C6H5C6H3ClOH (174) (323) 5


Chloroprene See 2-Chloro-1, 3-Butadiene.

1-Chloropropane See Propyl Chloride.

2-Chloropropane See Isopropyl Chloride.

2-Chloro-1-Propanol 125 1.1 3.3 271-273 Yes 5 2 2 0

CH3CHClCH2OH (52) (133-134)

(β-Chloropropyl Alcohol)

(Propylene Chlorohydrin)

1-Chloro-2-Propanol 125 1.1 3.3 261 Yes 5 2 2 0

CH2ClCHOHCH3 (52) (127)

(Chloroisopropyl Alcohol) (oc)

(sec-Propylene Chlorohydrin)

1-Chloro-1-Propene See 1-Chloropropylene.

3-Chloropropene See Allyl Chloride.

α-Chloropropionic Acid 225 932 1.3 352-374 Yes 5 1 0

CH3CHClCOOH (107) (500) (178-190) 2

3-Chloropropionitrile 168 1.1 3.0 348.8 Yes 5 2 1

ClCH2CH2CN (76) (176)

Decomposes

2-Chloropropionyl Chloride 88 1.3 0.12 230 Reacts

(31) (110)

β-Chloropropyl Alcohol See 2-Chloro-1-Proponol.

1-Chloropropylene < 21 4.5 16 0.9 95-97 1 2 4 2

CH3CH:CHCl (< -6) (35-36)

(1-Chloro-1-Propene)

2-Chloro Propylene < -4 4.5 16 0.93 2.63 73 2 4 0

CH3CCl:CH2 (< -20) (23)

(β-Chloropropylene)

(2-Chloropropene)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2-Chloropropylene Oxide See Epichlorohydrin.

γ-Chloropropylene Oxide See Epichlorohydrin.

Chlorotoluene 126 1.08 4.37 320 2 2 0

C6H4ClCH3 (52) (160)

(Tolyl Chloride) (oc)

α-Chlorotoluene See Benzyl Chloride.

Chlorotrifluoroethylene See Trifluorochloroethylene.

2-Chloro- α,α,α-Trifluoro-5-Nitrotoluene

See 2-Chloro-5-Nitrobenzotrifluoride.

o-Chloro- α,α,α-Trifluorotoluene See o-Chlorobenzotrifluoride.

Cimene See Dipentene.

Cinnamene See Styrene

Citral 195 0.9 197-199 No 5 0 2 0

(CH3)2C:CH(CH2)2C(CH3):CHCHO (91) (92-93)

(3,7-Dimethyl-2,6-Octadienal)

(Geranial)

Citronellel 165 0.9 117 No 5 0 2 0

(CH3)2C:CH(CH2)2CH(CH3)CH2CHO (74) (47)

(3,7-Dimethyl-6-Octenal)

(Rhodinal)

Citronellol 205 0.85 227 No 5 0 1 0

(CH3)2C:CH(CH2)2CH(CH3)(CH2)2OH (96) (108.4)

(3,7-Dimethyl-6-Octen-1-ol)

Cleaning Solvent, StoddardSolvent

>100 444 0.8 No 0 2 0

(>38) (229)

Cleaning Solvents, 140 (60) 138.2 453.2 0.8 @ 0.8 Initial No 0 2 0

Class (59) (234) 302 357.8

orhigher

orhigher

(150) (181)or

higher

Coal Gas See Gas.

Coal Oil See Fuel Oil No. 1.

Coal Tar Light Oil < 80 < 1 No 2 3 0

(< 27)

Coal Tar Pitch 405 >1 No 2 0 1 0

(207)

Cobalt Naphtha 121 529 0.9 No 1 2 0

(Cobalt Naphthenate) (49) (276)

Cobalt Naphthenate See Cobalt Naphtha.

Cocoanut Oil 420 0.9 No 2 0 1 0

(216)

Refined 548

(287)

Crude 420

(216)


Cod Liver Oil 412 0.9 No 2 0 1 0

(211)

Collodion < 0 1 1 4 0

C12H16O6(NO3)4C13H17O7(NO3)3 (< -18) 5

Solution of NitratedCellulose in Ether-Alcohol

Cologne Spirits See Ethyl Alcohol.

Columbian Spirits See Methyl Alcohol.

Colza Oil See Rape Seed Oil.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Corn Oil 490 740 0.9 No 2

(254) (393) 2 0 1 0

Cooking 610 < 1

(321)

(oc)

Cottonseed Oil Refined 486 650 0.9 No 2

(252) (343)

Cooking 610 < 1 No 2 0 1 0

(321)

(oc)

Creosote Oil 165 637 >1 382-752 No 3 2 2 0

(74) (336) (194-400)

o-Cresol 178 1110 1.4 @ 1.1 3.7 376 No 3 3 2 0

CH3C6H4OH (81) (599) 300 (191)

(Cresylic Acid) (149)

(o-Hydroxytoluene) Note: Melting point 88 (31).

(o-Methyl Phenol) See Hazardous Chemicals Data.

m- or p-Cresol 187 1038 1.1 @ 1.0 395 No 3 1 0

CH3C6H4OH (86) (558) 302 (201)

(150)

Note: Melting point of meta: 53.6 (12); of para: 94.6 (35).


p-Cresyl Acetate 195 1.1 5 1 2 0

CH3C6H4OCOCH3 (91)

(p-Tolyl Acetate)

Cresyl Diphenyl Phosphate 450 1.2 734 2 0 1 0

(C6H5O)2[(CH3)2C6H4O]PO4 (232) (390)

Cresylic Acid See o-Cresol.

Crotonaldehyde 55 450 2.1 15.5 0.9 2.4 216 Slight 1 3 3 2

CH3CH:CHCHO (13) (232) (102) 5

(2-Butenal)

(Crotonic Aldehyde)

(Propylene Aldehyde) Note: See Hazardous Chemicals Data.

Crotonic Acid 190 745 1.0- 3.0 372 Yes 5 3 2 0

CH3CH:CHCOOH (88) (396) @ (189)

(oc) 176

Note: Melting point 162 (72). (80)

Crotonic Aldehyde See Crotonaldehyde.

Crotononitrile < 212 0.8 2.3 230-240.8 No 1 0

CH3CH:CHCN (< 100) (110-116)

(2-Butenenitrile)

Crotonyl Alcohol 81 660 4.2 35.3 0.85 2.49 250 To 16 3 2

CH3CH:CHCH2OH (27) (349) (121)

(2-Buten-1-ol)

(Crotyl Alcohol)

1-Crotyl Bromide 4.6 12.0 4.66 2 3 2

CH3CH:CHCH2Br

(1-Bromo-2-Butene)

1-Crotyl Chloride 4.2 19.0 3.13 2 3 2

CH3CH:CHCH2Cl

(1-Chloro-2-Butene)

Cumene 96 795 0.9 6.5 0.9 4.1 306 No 2 3 0

C6H5CH(CH3)2 (36) (424) (152)

(Cumol)

(2-Phenyl Propane)

(Isopropyl Benzene)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Cumene Hydroperoxide 175 Explodes on Slight 1 2 4 OX

C6H5C(CH3)2OOH (79) heating.


Cumol See Cumene.

Cyanamide 286 1.07 1.45 500 4 1 3

NH2CN (141) (260)

Decomposes


2-Cyanoethyl Acrylate 255 1.1 4.3 Polymerizes No 2 2 1 1

CH2CHCOOCH2CH2CN (124)

(oc)

N-(2-Cyanoethyl) 255 0.9 5.2 No 2 2 1 0

Cyclohexylamine (124)

C6H11NHC2H4CN (oc)

Cyanogen Gas 6.6 32 1.8 -6 6 4 4 2

(CN)2 Note: See Hazardous Chemicals Data. (-21)

Cyclamen Aldehyde 190 1.0- 5 2 0

(CH3)2CHC6H4CH(CH3)CH2CHO (88)

(Methyl Para-IsopropylPhenyl Propyl Aldehyde)

Cyclobutane Gas 1.8 1.9 55 No 6 1 4 0

C4H8 (13)

(Tetramethylene)

1,5,9-Cyclododecatriene 160 0.9 448 No 2 0

C12H18 (71) (231)

Cycloheptane < 70 1.1 6.7 0.81 3.39 246 0 3 0

CH2(CH2)5CH2 (< 21) (119)

Cyclohexane -4 473 1.3 8 0.8 29 179 No 1 1 3 0

C6H12 (-20) (245) (82)

(Hexahydrobenzene)

(Hexamethylene)

1,4-Cyclohexane Dimethanol 332 600 1.0- 525 Yes 5 1 0

C8H16O2 (167) (316) (274) 2

(CHDM)

Cyclohexanethiol 110 0.95 4.00 315-319 No 5 2 0

C6H11SH (43) (157-159)

(Cyclohexylmercaptan)

Cyclohexanol 154 572 1.0- 3.5 322 Slight 5 1 2 0

C6H11OH (68) (300) (161)

(Anol) Note: Melting point 75 (24).

(Hexalin)

(Hydralin)

Cyclohexanone 111 788 1.1 @ 9.4 0.9 3.4 313 Slight 5 1 2 0

C6H10O (44) (420) 212 (156)

(Pimelic Ketone) (100)

Cyclohexene < 20 471 0.8 2.8 181 No 1 1 3 0

CH2CH2CH2CH2CH:CH (< -7) (244) (83)

3-Cyclohexene-1-Carboxaldehyde

See 1,2,3,6-Tetrahydrobenzaldehyde.

Cyclohexenone ∆ 93 3.3 313 1 1 3 0

C6H8O (34) (156)

Cyclohexyl Acetate 136 635 1.0- 4.9 350 No 1 2 0

CH3CO2C6H11 (58) (335) (177)

(Hexalin Acetate)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Cyclohexylamine 88 560 0.9 3.4 274 Yes 1 2 3 0

C6H11NH2 (31) (293) (134) 5

(Amino Cyclohexane)

(Hexahydroaniline) Note: See Hazardous Chemicals Data.

Cyclohexylbenzene 210 0.9 459 No 2 1 0

C6H5C6H11 (99) (237)

(Phenylcyclohexane) (oc)

Cyclohexyl Chloride 90 0.99 4.08 288 2 3 0

CH2(CH2)4CHCl (32) (142)

(Chlorocyclohexane)

Cyclohexylcyclohexanol 270 1.0- 304-313 No 2 0 1 0

C6H11C6H10OH (132) (151-156)

Cyclohexyl Formate 124 1.01 4.42 324 2 0

CH2(CH2)4HCOOCH (51) (162)

Cyclohexylmethane See Methylcyclohexane.

o-Cyclohexylphenol 273 1.0+ 298 Slight 5 2 1 0

C6H11C6H4OH (134) (148) 2

Note: Melting point 116 (47). @ 10 mm

Cyclohexyltrichlorosilane 196 1.2 7.5 406 No 3 2 2 1

C6H11SiCl3 (91) (208)

(oc)

1,5-Cyclooctadiene 95 0.9 3.66 304 No 1 3 0

C8H10 (35) (151)

Cyclopentane < 20 682 1.5 0.7 2.4 121 No 1 1 3 0

C5H10 (< -7) (361) (49)

Cyclopentene -20 743 0.8 2.35 111 1 1 3 1

CH:CHCH2CH2CH2 (-29) (395) (44)

Cyclopentanol 124 0.95 2.97 286 0 2 0

CH2(CH2)3CHOH (51) (141)

Cyclopentanone 79 0.9 2.3 267 Slight 1 2 3 0

OCCH2CH2CH2CH2 (26) (131) 5

(Adipic Ketone)

Cyclopropane Gas 928 2.4 10.4 1.5 -29 No 6 1 4 0

(CH2)3 (498) (-34)

(Trimethylene)

p-Cymene 117 817 0.7 @ 5.6 0.9 4.6 349 No 2 2 0

CH3C6H4CH(CH3)2 (47) (436) 212 (176)

Tech. 127 833 (100) 5.6

(4-Isopropyl-1-Methyl Benzene) (53) (445)

DDS See Dimethyldichlorosilane.

Decaborane 176 0.9 416 Slight 3 2 1

B10H14 (80) (213)

Note: Melting point 211.5 (100). Note: See Hazardous Chemicals Data.

Decahydronaphthalene 136 482 0.7 @ 4.9 @ 0.9 4.8 382 No 2 2 0

C10H18 (58) (250) 212 212 (194)

(Decalin) (100) (100)

Decahydronaphthalenetrans 129 491 0.7 5.4 0.87 4.77 369 0 2 0

C10H18 (54) (255) (187)

Decalin See Decahydronaphthaiene.

Decane 115 410 0.8 5.4 0.7 4.9 345 No 0 2 0

CH3(CH2)8CH3 (46) (210) (174)

Decanol 180 550 0.8 5.5 444.2 No 0 2 0

CH3(CH2)8CH2OH (82) (288) (229)

(Decyl Alcohol) (oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1-Decene < 131 455 0.74 4.84 342 0 2 0

CH3(CH2)7CH:CH2 (< 55) (235) (172)

Decyl Acrylate 441 0.9 316 Very 2 2 1 0

CH3(CN2)9OCOCH:CH2 (227) (158) slight

(oc) @ 50 mm

Decyl Alcohol See Decanol.

Decylamine 210 0.8 429 Slight 5 2 1 0

CH3(CH2)9NH2 (99) (221)

(1-Aminodecane)

Decylbenzene 225 0.9 491-536 No 2 2 1 0

C10H21C6H5 (107) (255-280)

tert-Decylmercaptan 190 0.9 6.0 410-424 2 2 0

C10H21SH (88) (210-218)

Decylnaphthalene 350 0.9 635-680 No 2 1 1 0

C10H21C10H7 (177) (335-360)

Decyl Nitrate 235 1.0- 261 No 2 1 0

CH3(CH2)9ONO2 (113) (127)

(oc) @ 11 mm

Dehydroacetic Acid 315 690 518 No 2 1 1 0

CH3C:CHC(O)-CH(COCH3)C(O)O (157) (366) (270)

(oc)

(DHA) Note: Melting point 228-232 (109-111).

(Methylacetopyranone)

Denatured Alcohol 60 750 0.8 1.6 175 Yes 1 0 3 0

(16) (399) (79) 5

Government Formula

CD-5 60-62

(16-17)

CD-5A 60-61

(15.5-16)

CD-10 49-59

(9-15)

SD-1 57

(14)

SD-2B 56

(13)

SD-3A 59

(15)

SD-13A < 19

(< -7)

SD-17 60

(16)

SD-23A 35

(2)

SD-30 59

(15)

SD-39B 60

(16)

SD-39C 59

(15)

SD-40M 59

(15)

Deuterium Gas 5 75 6 0 4 0

D2

(Heavy Hydrogen)

Diacetone See Diacetone Alcohol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Diacetone Alcohol 148 1118 1.8 6.9 0.9 4.0 328 Yes 5 1 2 0

CH3COCH2C(CH3)2OH (64) (603) (164)

Acetone-free 136 1190

(58) (643)

Commercial 148 1118

(64) (603)

(Diacetone)

(4-Hydroxy-4-Methyl-2-Pentanone)

Diacetyl See 2,3-Butanedione.

Diallyl Ether See Allyl Ether.

Diallyl Phthalate 330 1.1 554 No 2 2 1 0

C6H4(CO2C3H5)2 (166) (290)

1,3-Diaminobutane See 1,3-Butanediamine.

1,3-Diamino-2-Propanol 270 1.1 266 Yes 2 2 1 0

NH2CH2CHOHCH2NH2 (132) (130) 5

1,3-Diaminopropane See 1 ,3-Propanediamine.

Diamylamine 124 0.8 5.4 356 Slight 5 3 2 0

(C5H11)2NH (51) (180)


Diamylbenzene 225 0.9 491-536 No 2 0 1 0

(C5H11)2C6H4 (107) (255-280)

(oc)

Diamylbiphenyl 340 1.0- 687-759 No 2 0 1 0

C5H11(C6H4)2C5H11 (171) (364-404)

(Diaminodiphenyl)

Di-tert-Amylcyclohexanol 270 0.9 554-572 No 2 0 1 0

(C5H11)2C6H9OH (132) (290-300)

Diamyldiphenyl See Diamylbiphenyl.

Diamylene 118 0.8 302 0 2 0

C10H20 (48) (150)

(oc)

Diamyl Ether See Amyl Ether.

Diamyl Maleate 270 1.0- 505-572 No 2 0 1 0

(CHCOOC5H11)2 (132) (263-300)

Diamyl Naphthalene 315 0.9 624 No 2 0 1 0

C10H6(C5H11)2 (159) (329)

(oc)

2,4-Diamylphenol 260 0.9 527 No 2 2 1 0

(C5H11)2C6H3OH (127) (275)

(oc)

Di-tert-Amylphenoxy Ethanol 300 1.0- 615 No 2 0 1 0

C6H3(C5H11)2OC2H4OH (149) (324)

(oc)

Diamyl Phthalate 245 1.0 475-490 No 2 0 1 0

C6H4(COOC5H11)2 (118) (246-254)

(Amyl Phthalate) @ 50 mm

Diamyl Sulfide 185 0.9 338-356 No 2 2 0

(C5H11)2S (85) (170-180)

(oc)

o-Dianisidine 403 8.43 1 0

[NH2(OCH3)C6H3]2 (206)

(o-Dimethoxybenzidine) Note: Melting point 297 (147).

Dibenzyl Ether 275 1.0 568 No 2 0 1 0

(C6H5CH2)2O (135) (298)

(Benzyl Ether)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Diborane Gas 100- 0.8 88 1.0- 6 3 4 3

B2H6 125 Reacts violently withhalogenated extinguishingagents.

(38-52)

Note: Ignites spontaneously in moist air.


Dibutoxy Ethyl Phthalate 407 1.1 437 No 5 0 1 0

C6H4(COOC2H4OC4H9)2 (208) (225) 2

(oc)

Dibutoxymethane 140 0.8 330-370 No 0 2 0

CH2(OC4H9)2 (60) (166-188)


Dibutoxy Tetraglycol 305 0.9 635 Slight 2 2 1 0

(C4H9OC2H4OC2H4)2O (152) (335) 5

(Tetraethylene Glycol Dibutyl Ether) (oc)

N,N-Dibutylacetamide 225 0.9 469-482 2 0 1 0

CH3CON(C4H9)2 (107) (243-250)

Dibutylamine 117 1.1 0.8 4.5 322 Slight 5 3 2 0

(C4H9)2NH (47) (161)

Di-sec-Butylamine 75 0.8 4.5 270-275 Yes 5 3 3 0

[C2H5(CH3)CH]2NH (24) (132-135)

(oc)

Dibutylaminoethanol 200 0.9 432 No 3 2 0

(C4H9)2NC2H4OH (93) (222)

(oc)

1-Dibutylamino-2-Propanol See Dibutylisopropanolomine.

N,N-Dibutylaniline 230 0.9 505-527 No 2 3 1 0

C6H5N(CH2CH2CH2CH3)2 (110) (263-275)

Di-tert-Butyl-p-Cresol 261 495-511 No 2 0 1 0

C6H2(C4H9)2(CH3)OH (127) (257-266)


Dibutyl Ether 77 382 1.5 7.6 0.8 4.5 286 No 1 2 3 0

(C4H9)2O (25) (194) (141) 5

(1-Butoxybutane)

(Butyl Ether) Note: See Hazardous Chemicals Data.

2,5-Di-tert-Butylhydroquinone 420 790 No 2 1 1 0

[C(CH3)3]2C6H2(OH)2 (216) (421)

(DTBHQ) (oc)


Dibutyl Isophthalate 322 No 2 0 1 0

C6H4(CO2C4H9)2 (161)

N,N1-Di-sec-Butyl-p-Phenylenediamine

270 625 0.6 @ 0.9 5 2 1 0

C6H4[-NHCH(CH3)CH2CH3]2 (132) (329) 329 2

Dibutylisopropanolamine 205 0.8 444 Slight 5 2 1 0

CH3CHOHCH2N(C4H9)2 (96) (229)

(oc)

Dibutyl Maleate 285 1.0- Decomposes 2 1 1 0

(-CHCO2C4H9)2 (141)

(oc)

Dibutyl Oxalate 220 1.0+ 472 No 2 0 1 0

C4H9OOCCOOC4H9 (104) (244)

Di-tert-Butyl Peroxide 65 0.8 231 Slight 1 3 2 4 OX

(CH3)3COOC(CH3)3 (18) (111)

(oc)





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Dibutyl Phosphite 120 1.0- 239 No 3 2 0

(C4H9O)2P(O)H (49) (115)

Dibutyl Phthalate 315 757 0.5 @ 1.0+ 644 No 2 0 1 0

C6H4(CO2C4H9)2 (157) (402) 456 (340)

(Dibutyl-o-Phthalate) (235)

Dibutyl Sebacate 353 690 0.44 1.0- 650 No 2 0 1 0

[(CH2)4COOC4H9]2 (178) (365) @ (343)

(Decanedioic Dibutyl Ester) (oc) 469

(243)

N,N-Dibutyl Stearamide 420 0.9 343-347 No 2 0 1 0

C17H35CON(C4H9)2 (216) (173-175)

@ 0.4 mm

n-Dibutyl Tartrate 195 544 1.1 650 No 5 0 2 0

(COOC4H9)2(CHOH)2 (91) (284) (343)

(Dibutyl-d-2,3-Dihydroxybutanedioate)

N,N-Dibutyltoluene-sulfonamide 330 1.1 392 2 0 1 0

CH3C6H4SO3N(C4H9)2 (166) (200)

@ 10 mm

Dicaproate See Triethylene Glycol.

Dicapryl Phthalate 395 1.0- 9.8 441-453 No 2 0 1 0

C6H4[COOCH(CH3)C6H13]2 (202) (227-234)

@ 4.5 mm

Dichloroacetyl Chloride 151 5.1 225-226 Decomposes 5 3 2 1

CHCl2COCl (66) (107-108)

(Dichloroethanoyl Chloride)

3,4-Dichloroaniline 331 522 No 2 3 1 0

NH2C6H3Cl2 (166) (272)

(oc)



o-Dichlorobenzene 151 1198 2.2 9.2 1.3 5.1 356 No 3 2 2 0

C6H4Cl2 (66) (648) (180)

(o-Dichlorobenzol) Note: See Hazardous Chemicals Data.

p-Dichlorobenzene 150 1.5 5.1 345 No 3 2 2 0

C6H4Cl2 (66) (174)


o-Dichlorobenzol See o-Dichlorobenzene.

2,3-Dichlorobutadiene-1,3 50 694 1.0 12.0 1.2 4.24 212 No 1 3 3 2

CH2:C(Cl)C(Cl):CH2 (10) (368) (100)

1,2-Dichlorobutane 527 4.38 2 2 0

CH3CH2CHClCH2Cl (275)

1,4-Dichlorobutane 126 1.1 4.4 311 No 3 2 2 0

CH2ClCH2CH2CH2Cl (52) (155)


2,3-Dichlorobutane 194 1.1 4.4 241-253 2 2 0

CH3CHClCHClCH3 (90) (116-123)

(oc)

1,3-Dichloro-2-Butene 80 1.2 4.31 262 No 1 3 3 2

CH2ClCH:CClCH3 (27) (128)

3,4-Dichlorobutene-1 113 1.1 4.31 316 3 2 1

CH2ClCHClCHCH2 (45) (158)

1,3-Dichlorobutene-2 80 4.3 258 1 2 3 0

CH2ClCH:CClCH3 (27) (126)

Dichlorodimethylsilane See Dimethyldichlorosilane.

1,1-Dichloroethane See Ethylidene Dichloride.

1,2-Dichloroethane See Ethylene Dichloride.

Dichloroethanoyl Chloride See Dichloroacetyl Chloride.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1,1-Dichloroethylene See Vinylidene Chloride.

sym-Dichloroethylene

1,2-Dichloroethylene 36 860 5.6 12.8 1.3 3.4 119 No 4 2 3 2

ClCH:CHCl (2) (460) (48)

Note: Exists as cis andtrans isomers.

2,21-Dichloroethyl Ether 131 696 2.7 1.2 4.93 352 No 5 2 2 0

ClCH2CH2OCH2CH2Cl (55) (369) (178)


2,2-Dichloroethyl Formal See Bis(2-Chloroethyl) Formal.

Di-(2-Chloroethyl) Formal See Bis(2-Chloroethyl) Formal.

1,3-Dichloro-2,4-Hexadiene 168 2 0

CH2ClCH:CClCH:CHCH3 (76)

Dichloroisopropyl Ether 185 1.1 6.0 369 No 3 2 2 0

ClCH2CH(CH3)OCH(CH3)CH2Cl (85) (187)

[Bis (β-Chloroisopropyl) Ether] (oc)

2,2-Dichloro Isopropyl Ether 185 1.11 5.90 369 2 2 0

[ClCH2CH(CH3)]2O (85) (187)

[Bis (2-Chloro-1-Methylethyl Ether] (oc)

Dichloromethane See Methylene Chloride.

1,1-Dichloro-1-Nitro Ethane 168 1.4 5.0 255 No 3 2 2 3

CH3CCl2NO2 (76) (124)

(oc)

1,1-Dichloro-1-Nitro Propane 151 1.3 5.5 289 Slight 5 2 2 3

C2H5CCl2NO2 (66) (143)

(oc)

Dichloropentanes 106 1.0+ 4.8 266 No 2 2 0

(Mixed) (41) (130)

C5H10Cl2 (oc)

1,5-Dichloropentane >80 1.1 4.9 352-358 No 4 2 3 0

CH2Cl(CH2)3CH2Cl (>27) (178-181)

(Amylene Chloride) (oc)

(Pentamethylene Dichloride)

2,4-Dichlorophenol 237 1.4@ 5.6 410 Slight 5 1 0

Cl2C6H3OH (114) 140 (210) 2

(oc) (60)


1,2-Dichloropropane See Propylene Dichloride.

1,3-Dichloro-2-Propanol 165 1.4 4.4 346 Slight 5 2 2 0

CH2ClCHOHCH2Cl (74) (174)

(oc)

1,3-Dichloropropene 95 5.3 14.5 1.2 3.8 219 No 2 3 0

CHCl:CHCH2Cl (35) (104)

2,3-Dichloropropene 59 2.6 7.8 1.2 3.8 201 Slight 3 3 0

CH2CClCH2Cl (15) (94)

(TCC)

Dichlorosilane -35 136 4.1 99 1.2 3.5 47 Yes Avoid 3 4 2

H2SiCl2 (36) water.

α,β-Dichlorostyrene 225 No 2 2 1 2

C6H5CCl:CHCl (107)

(oc)

Dicyclohexyl See Bicyclohexyl.

Dicyclohexylamine >210 0.9 496 Slight 5 3 1 0

(C6H11)2NH (>99) (258)

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Dicyclopentadiene 90 937 1.0- 342 No 1 1 3 1

C10H12 (32) (503) (172)

(oc)


Didecyl Ether 419 10.3 0 1 0

(C10H21)2O (215)

(Decyl Ether)

Diesel Fuel Oil 100 No 0 2 0

No. 1-D Min.

(38)

or

Legal


No. 2-D Min.

(52)

or

Legal


No. 4-D Min.

(54)

or

Legal

Diethanolamine 342 1224 1.1 514 Yes 5 1 1 0

(HOCH2CH2)2NH (172) (662) (268) 2

(oc)


1,2-Diethoxyethane See Diethyl Glycol.

Diethylacetaldehyde See 2-Ethylbutyraldehyde.

Diethylacetic Acid See 2-Ethylbutyric Acid.

N,N-Diethylacetoacetamide 250 1.0- 5.4 Decomposes Yes 2 0 1 0

CH3COCH2CON(C2H5)2 (121) 5

(oc)

Diethyl Acetoacetate 170 1.0- 6.4 412-424 Very 2 2 0

CH3COC(C2H5)2COOC2H5 (77) (211-218) slight

Decomposes

Diethylaluminum Chloride 3 3 3

(C2H5)2AlCl Do not use water, foam orhalogenated extinguishing

agents.

(Chlorodiethylaluminum) Note: Ignites spontaneously in air.


Diethylaluminum Hydride 3 3

(C2H5)2AlH Do not use water, foam orhalogenated extinguishing

agents.

Note: Ignites spontaneously in air.

Diethylamine -9 594 1.8 10.1 0.7 2.5 134 Yes 5 2 3 0

(C2H5)2NH (-23) (312) (57) 1


2-Diethyl (Amino) Ethanol See N,N-Diethylethanolamine.

2-(Diethylamino) Ethyl Acrylate 195 0.9 5.9 DecomposesDecomposes 2 2 1

CH2:CHCOOCH2CH2HN(CH3CH2)2 (91)

(oc)

3-(Diethylamino)-Propylamine 138 0.8 4.5 337 Yes 5 2 2 0

(C2H5)2NCH2CH2CH2NH2 (59) (169)

(N,N-Diethyl-1,3-Propanediamine) (oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

N,N-Diethylaniline 185 1166 1.0- 5.0 421 Slight 5 3 2 0

C6H5N(C2H5)2 (85) (630) (216)

(Phenyldiethylamine)

o-Diethyl Benzene 135 743 0.9 4.6 362 No 2 2 0

C6H4(C2H5)2 (57) (395) (183)

m-Diethyl Benzene 133 842 0.9 4.6 358 No 2 2 0

C6H4(C2H5)2 (56) (450) (181)

p-Diethyl Benzene 132 806 0.7 6.0 0.9 4.6 358 No 2 2 0

C6H4(C2H5)2 (55) (430) (181)

N,N-Diethyl-1,3-Butanediamine 115 0.8 5.0 354-365 Yes 5 2 2 0

C2H5NHCH2CH2CHN(C2H5)CH3 (46) (179-185)

[1,3-Bis(ethylamino) Butane] (oc)

Di-2-Ethylbutyl Phthalate 381 1.0+ 662 No 5 0 1 0

C6H4[COOCH2CH(C2H5)2]2 (194) (350) 2

(oc)

Diethyl Carbamyl Chloride 325-342 369-374 Yes 5 2 1 2

(C2H5)2NCOCl (163-172)

(187-190) 2

(oc)

Diethyl Carbinol See sec-Amyl Alcohol.

Diethyl Carbonate 77 1.0- 4.1 259 No 1 2 3 1

(C2H5)2CO3 (25) (126)

(Ethyl Carbonate)

Diethylcyclohexane 120 464 0.8 @ 6.0 @ 0.8 344 2 2 0

C10H20 (49) (240) 140 230 (173)

(60) (110)

1,3-Diethyl-1,3-Diphenyl Urea 302 1.1 620 2 1 1 0

[(C2H5)(C6H5)N]2CO (150) (327)


Diethylene Diamine 144 299 Yes

(62) (150)

Diethylene Dioxide See p-Dioxane.

Diethylene Glycol 255 435 1.1 472 Yes 5 1 1 0

O(CH2CH2OH)2 (124) (224) (244) 2

(2,2-Dihydroxyethyl Ether)

Diethylene Glycol Bis(Allylcarbonate)

378 1.1 320 No 2 1 1 0

(CH2:CHCH2OCOOCH2CH2)2O (192) (160)

(Allyl Diglycol Carbonate) (oc) @ 2 mm

Diethylene Glycol Bis(2-Butyoxyethyl Carbonate)

379 1.1 392-403 Slight 5 1 1 1

[CH3(CH2)3O(CH2)2OOCOCH2CH2]2O(193) (200-206) 2

(Butoxyethyl Diglycol Carbonate) @ 2 mm

Diethylene Glycol Bis (ButylCarbonate)

372 1.1 327 Slight 5 1 1 1

[CH3(CH2)3OOCOCH2CH2]2O (189) (164) 2

(Butyl Diglycol Carbonate) @ 2 mm

Diethylene Glycol Bis(Phenylcarbonate)

460 1.2 437-444 No 2 0 1 1

(C6H5OOCOCH2CH2)2O (238) (225-229)

(Phenyl Diglycol Carbonate) @ 2 mm

Diethylene Glycol n-Butyl Ether 230 442 1.0- 448 Yes 5 1 1 0

C4H9OC2H4OC2H4OH (110) (228) (231) 2

(Butoxy Diethylene Glycol) (oc)

Diethylene Glycol Butyl EtherAcetate

241 563 0.98 7.05 475 1 0

CH3COO(C2H4O)2C4H9 (116) (295) (246)

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Diethylene Glycol Diacetate 275 1.1 482 Yes 5 1 1 0

(CH3COOC2H4)2O (135) (250) 2

(oc)

Diethylene Glycol Dibenzoate 450 1.2@ 457 Yes 5 0 1 0

(C6H5COOCH2CH2)2O (232) 68 (236) 2

(20) @ 5 mm

Diethylene Glycol Dibutyl Ether 245 590 0.9 493 Slight 5 1 1 0

C4H9O(C2H4O)2C4H9 (118) (310) (256) 2

(Dibutoxy Diethylene Glycol)

Diethylene Glycol Diethyl Ether 180 0.9 5.6 372 Yes 5 1 2 0

CH3(CH2OCH2)3CH3 (82) (189)

(oc)

Diethylene Glycol DiethylLevulinate

340 1.14 10.4 0 1 0

(CH3COC2H4COOC2H4)2O (171)

Diethylene Glycol Dimethyl Ether 153 0.95 324 Yes 5 1 2 1

CH3OCH2CH2OCH2CH2OCH3 (67) (162)

Diethylene Glycol Dipropionate 260 1.1 491-529 Slight 5 1 1 0

(C2H5COOC2H4)2O (127) (255-276) 2

Diethylene Glycol Ethyl Ether 196 1.2 9.0 1.0 4.65 396 Yes 5 1 1 0

C2H5OC2H4OC2H4OH (91) (202)

Diethylene Glycol Ethyl EtherPhthalate

406 1.12 13.7 >500 0 1 0

C6H4[COO(C2H4O)2C2H5]2 (208) (>260)

(Bis[2-(Ethoxyethoxy)-Ethyl] Phthalate)

(Carbitol Phthalate)

Diethylene Glycol Methyl Ether 205 465 1.38 22.7 1.04 4.14 379 2 2 0

CH3OC2H4OC2H4OH (96) (240) (193)

(2-(2-Methoxyethoxy) Ethanol) (oc)

Diethylene Glycol Methyl EtherAcetate

180 1.04 5.59 410 0 2 0

CH3COOC2H4OC2H4OCH3 (82) (210)

(oc)

Diethylene Glycol MonobutylEther

172 400 0.85 24.6 1.0- 5.6 448 Yes 5 1 2 0

C4H9OCH2CH2OCH2CH2OH (78) (204) (231)

Diethylene Glycol MonobutylEther Acetate

240 570 0.76 10.7 1.0- 476 Slight 5 1 1 0

C4H9O(CH2)2O(CH2)2OOCCH3 (116) (298.9) (247) 2

Diethylene Glycol MonoethylEther

201 400 1.2 @ 23.5 1.0- 396 Yes 5 1 1 0

CH2OHCH2OCH2CH2OC2H5 (94) (204) 275 @ (202)

(135) 360

(182)

Diethylene Glycol MonoethylEther Acetate

225 680 1.0 @ 19.4 1.0+ 424 Yes 5 1 1 0

C2H5O(CH2)2O(CH2)2OOCCH3 (107) (360) 275 @ (218) 2

(oc) (135) 365

(185)

Diethylene Glycol MonoisobutylEther

222 452-485 0.98 10.7 1.0- 422-437 Yes 5 1 1 0

(CH3)2CHCH2O(CH2)2O(CH2)2OH (106) (233-252)

(217-225) 2

Diethylene Glycol MonomethylEther

205 1.0+ 381 Yes 5 1 1 0

CH3O(CH2)O(CH2)2OH (96) (194)

(oc)

Diethylene Glycol Mono-MethylEther Formal

310 1.0+ 581 Yes 5 1 1 0

CH2(CH3OCH2CH2OCH2CH2O)2 (154) (305) 2

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Diethylene Glycol Phthalate 343 1.1 Yes 5 0 1 0

C6H4[COO(CH2)2OC2H5]2 (173) 2

Diethylene Oxide See Tetrahydrofuran.

Diethylene Triamine 208 676 2 6.7 1.0- 3.56 404 Yes 5 3 1 0

NH2CH2CH2NHCH2CH2NH2 (98) (358) (207) 2

(oc)


N,N-Diethylethanolamine 140 608 0.9 4.0 324 Yes 5 3 2 0

(C2H5)2NC2H4OH (60) (320) (162)

(2-(Diethylamino) Ethanol) (oc)

Diethyl Ether See Ethyl Ether.

N,N-Diethylethylenediamine 115 0.8 4.0 293 Yes 5 3 2 0

(C2H5)2NC2H4NH2 (46) (145)

(oc)

Diethyl Fumarate 220 1.0+ @ 442 Slight 5 1 1 0

C2H5OCOCH:CHCOOC2H5 (104) 68 (217) 2

(20)

Diethyl Glycol 95 401 0.84 4.07 252 Slight 3 0

(C2H5OCH2)2 (35) (205) (122)

(1,2-Diethoxyethane)

Di-2-Ethylhexyl Adipate 385 0.9 783 No 5 0 1 0

C4H8[COOCH2CH(C2H5)C4H9]2 (196) (417) 2

(Dioctyl Adipate)

(DOA)

Diethylhexylamine See Bis(2-Ethylhexyl) Amine.

Diethylhexylethanolamine See Bis(2-Ethylhexyl) Ethanolamine.

Di(2-Ethylhexyl) Maleate See Bis(2-Ethylhexyl) Maleate.

Di(2-Ethylhexyl) Phosphoric Acid See Bis(2-Ethylhexyl) Phosphoric Acid.

Di(2-Ethylhexyl) Succinate See Bis(2-Ethylhexyl) Succinate.

Diethyl Ketone 55 842 1.6 0.8 3.0 217 Slight 1 1 3 0

C2H5COC2H5 (13) (450) (103) 5

(3-Pentanone) (oc)

N,N-Diethyllauramide >150 0.9 8.8 331-351 No 2 0

C11H23CON(C2H5)2 (>66) (166-177)

(oc) @ 2 mm

Diethyl Maleate 250 662 1.1 438 No 2 1 1 0

(-CHCO2C2H5)2 (121) (350) (226)

(oc)

Diethyl Malonate 200 1.1 390 No 3 0 1 0

CH2(COOC2H5)2 (93) (199)

(Ethyl Malonate) (oc)

Diethyl Oxide See Ethyl Ether.

3,3-Diethylpentane 554 0.7 5.7 0.8 4.4 295 No 0 3 0

CH3CH2C(C2H5)2CH2CH3 (290) (146)

Diethyl Peroxide Explodeson

heating.

2.3 0.8 7.7 Explodes onheating.

4 4

C2H5OOC2H5

Diethyl Phthalate 322 855 0.7 @ 1.1 565 No 2 0 1 0

C6H4(COOC2H5)2 (161) (457) 368 (296)

(oc) (186)

p-Diethyl Phthalate See Diethyl Terephthalate.

N,N-Diethyl-1,3-Propanediamine See 3-(Diethylamino) Propylamine.

2,2-Diethyl-1,3-Propanediol 215 0.9 @ 320 Yes 5 2 1 0

HOCH2C(C2H5)2CH2OH (102) 142 (160) 2

(oc) (61) @ 50 mm





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Diethyl Selenide 2.5 1.2 4.7 226 No 2 0

(C2H5)2Se (108)

N,N-Diethylstearamide 375 0.9 246-401 No 2 0 1 0

C17H35CON(C2H5)2 (191) (119-205)

@ 1 mm

Diethyl Succinate 195 1.0+ 421 Slight 5 1 1 0

(CH2COOCH2CH3)2 (90) (216) 2

Diethyl Sulfate 220 817 1.2 Decomposes,giving Ethyl

Ether

No,slight

decom-position

5 3 1 1

(C2H5)2SO4 (104) (436) Note: See Hazardous Chemicals Data. 2

(Ethyl Sulfate)

Diethyl Tartrate 200 1.2 536 Yes 5 0 1 0

CHOHCOO(C2H5)2 (93) (280)

Diethyl Terephthalate 243 1.1 576 No 2 0 1 0

C6H4(COOC2H5)2 (117) (302)

(p-Diethyl Phthalate) Note: Melting point 112 (44).

3,9-Diethyl-6-tridecanol See Heptadecanol.

Diethylzinc 0 3 3W

(C2H5)2Zn


Do not use water, foam orhalogenated extinguishing

agents.

(Zinc Diethyl) See Hazardous Chemicals Data.

Difluoro-1-Chloroethane Gas 6.2 17.9 4 4 0

CF2ClCH3 (-16)

(R-142B)

(1-Chloro-1,1-Difluoroethane)

Diglycol Chlorformate 295 256-261 2 0 1 0

O:(CH2CH2OCOCl)2 (146) (124-127)

(oc) @ 5 mm

Diglycol Chlorohydrin 225 1.2 387 Yes 5 0 1 0

HOCH2CH2OCH2CH2Cl (107) (197) 2

(oc)

Diglycol Diacetate 255 1.1 6.5 482 Yes 2 0 1 0

(CH3COOCH2CH2)2:O (124) (250) 5

Diglycol Dilevulinate 340 1.1 Yes 2 0 1

[CH2CH2OOC(CH2)2COCH3]2:O (171) 5

Diglycol Laurate 290 1.0- 559-617 2 0 1 0

C16H32O4 (143) (293-325)

Dihexyl See Dodecane.

Dihexylamine 220 0.8 451-469 No 2 2 1 0

[CH3(CH2)5]2NH (104) (233-243)

(oc)

Dihexyl Ether See Hexyl Ether.

Dihydropyran 0 0.9 2.9 186 Slight 5 2 3 0

CH2CH2CH2:CHCHO (-18) (86)

o-Dihydroxybenzene 260 1.34 3.79 473 Slight 1 0

C6H4(OH)2 (127) (245)

(Pyrocatechol)

p-Dihydroxybenzene 329 959 1.36 3.81 547 1 0

C6H4(OH)2 (165) (515) (286)

(Hydroquinone) Note: Melting point 338 (170).

1,2-Dihydroxybutane See 1,2-Butanediol.

2,2-Dihydroxyethyl Ether See Diethylene Glycol.

2,5-Dihydroxyhexane See 2,5-Hexanediol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Diisobutylaluminum Hydride 3 3

[(CH3)2CHCH2]2AIH Note: Ignites spontaneously in air. Do not use water, foam orhalogenated extinguishing

agents.

Diisobutylamine 85 0.7 273-286 No 5 3 3 0

[(CH3)2CHCH2]2NH (29) (134-141) 1

[Bis (β-Methylpropyl) Amine]

Diisobutyl Carbinol 165 0.8 @ 6.1 @ 0.8 5.0 353 No 5 1 2 0

[(CH3)2CHCH2]2CHOH (74) 212 212 (178)

(Nonyl Alcohol) (100) (100)

Diisobutylene See 2,4,4-Trimethyl-1-Pentene.

Diisobutylene 23 736 0.8 4.8 0.7 3.87 214 1 1 3 0

(CH3)3CCH2C(CH3):CH2 (-5) (391) (101)

(2,4,4-Trimethyl-I2-Pentane)

Diisobutyl Ketone 120 745 0.8 @ 7.1 @ 0.8 4.9 335 No 1 2 0

[(CH3)2CHCH2]2CO (49) (396) 200 200 (168)

(2,6-Dimethyl-4-Heptanone) (93) (93)

(Isovalerone)

Diisobutyl Phthalate 365 810 0.4 @ 1.0+ 621 No 5 0 1 0

C6H4[COOCH2CH(CH3)2]2 (185) (432) 448 (327) 2

(oc)

Diisodecyl Adipate 225 0.9 660 2 0 1 0

C10H21O2C(CH2)4CO2C10H21 (107) (349)

(oc)

Diisodecyl Phthalate 450 755 0.3 @ 1.0- 482 No 5 0 1 0

C6H4(COOC10H21)2 (232) (402) 508 (250) 2

(oc)

Diisooctyl Phthalate 450 1.0- 698 No 2 0 1 0

(C8H17COO)2C6H4 (232) (370)

Diisopropanolamine 260 705 1.0- 480 Yes 5 2 1 0

[CH3CH(OH)-CH2]2NH (127) (374) (249) 2

(oc)

Diisopropyl See 2,3-Dimethylbutane.

Diisopropylamine 30 600 1.1 7.1 0.7 3.5 183 Yes 1 3 3 0

[(CH3)2CH]2NH (-1) (316) (84) 5

(oc)


Diisopropyl Benzene 170 840 0.9 5.6 401 No 0 2 0

[(CH3)2CH]2C6H4 (77) (449) (205)

(oc)

N,N-Diisopropylethanolamine 175 0.9 5.0 376 No 1 2 0

[(CH3)2CH]2NC2H4OH (79) (191)

(oc)

Diisopropyl Ether See Isopropyl Ether.

Diisopropyl Maleate 220 1.0+ 444 Slight 5 1 1 0

(CH3)2CHOCOCH:CHCOOCH(CH3)2

(104) (229) 2

(oc)

Diisopropylmethanol See 2,4-Dimethyl-3-Pentanol.

Diisopropyl Peroxydicarbonate Note: Rapid decomposition at 53 (12). Melting Point46-50 (8-10).

Explodes onheating.

No 0 4.00 4 OX

(CH3)2CHOCOOCOOCH(CH3)2 See Hazardous Chemicals Data.

Diketene 93 1.1 2.9 261 Decomposes 5 2 2 2

CH2:CCH2C(O)O (34) (127)

(Vinylaceto-β-Lactone) Note: See Hazardous Chemicals Data.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2,5-Dimethoxyaniline 302 735 518 Yes 2 2 1 0

NH2C6H3(OCH3)2 (150) (391) (270)

(oc)


2,5-Dimethoxychlorobenzene 243 5.9 460-467 Slight 2 2 1 0

C8H9ClO2 (117) (238-242) 5

1,2-Dimethoxyethane See Ethylene Glycol Dimethyl Ether.

Dimethoxyethyl Phthalate 410 750 0.7 @ 1.2 644 No 5 0 1 0

C6H4(COOCH2CH2OCH3)2 (210) (399) 440 (340) 2

[Bis(2-methoxyethyl) Phthalate] (oc) (227)

Dimethoxymethane See Methylal.

Dimethoxy Tetraglycol 285 1.0+ 528 Yes 2 1 1 0

CH3OCH2(CH2OCH2)3CH2OCH3 (141) (276) 5

(Tetraethylene Glycol DimethylEther)

(oc)

Dimethylacetamide 158 914 1.8 @ 11.5 1.0 330 Yes 5 2 2 0

(CH3)2NC:OCH3 (70) (490) 212 @ (165)

(DMAC) (oc) 320

Dimethylamine Gas 752 2.8 14.4 1.6 45 Yes 6 3 4 0

(CH3)2NH (400) (7)


2-(Dimethylamino) Ethanol 105 563 0.9 3.1 272 Yes 1 2 2 0

(CH3)2NCH2CH2OH (41) (295) (133) 5

(Dimethylethanolamine) (oc)

2-(Dimethylamino) EthylMethacrylate

165 0.9 5.4 207 Yes 5 2 2 0

C8H15NO2 (74) (97)

(oc) @ 40 mm

Note: Polymerizes.

3-(Dimethylamino)-propionitrile 149 0.86 3.35 338 2 1

(CH3)2NC2H4CN (65) (170)

(oc)

3-(Dimethylamino)-propylamine 100 0.8 3.5 278 Yes 5 3 2 0

(CH3)2N(CH2)3NH2 (38) (137)

(oc)

Di(Methylamyl) Maleate See Bis(2,4-Dimethylbutyl) Maleate.

N,N-Dimethylaniline 145 700 1.0- 4.2 379 Slight 5 3 2 0

C6N5N(CH3)2 (63) (371) (193)

C.P. 165

(74) (Und. Lab. Class 20-25)

o-Dimethylaniline See o-Xylidine.

Dimethyl Anthranilate 195 11 1 2 0

CH3OOCC6H4NHCH3 (91)

(N-Methyl Methyl Anthranilate)

1,2-Dimethylbenzene See o-Xylene.

1,3-Dimethylbenzene See m-Xylene.

1,4-Dimethylbenzene See p-Xylene.

Dimethylbenzylcarbinyl Acetate 205 1.0- 1 1 0

C6H5CH2C(CH3)2OOCCH3 (96)

(alpha, alpha-DimethylphenethylAcetate)


2,2-Dimethylbutane -54 761 1.2 7.0 0.6 3.0 122 No 1 1 3 0

(CH3)3CCH2CH3 (-48) (405) (50)

(Neohexane)

2,3-Dimethylbutane -20 761 1.2 7.0 0.7 3.0 136 No 1 1 3 0

(CH3)2CHCH(CH3)2 (-29) (405) (58)

(Diisopropyl)

1,3-Dimethylbutanol See Methyl Isobutyl Carbinol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2,3-Dimethyl-1-Butene < -4 680 0.68 2.91 133 0 3 0

CH3CH(CH3)C(CH3):CH2 (< -20) (360) (56)

2,3-Dimethyl-2-Butene < -4 753 0.71 2.91 163 0 3 0

CH3C(CH3):C(CH3)2 (< -20) (401) (73)

1,3-Dimethylbutyl Acetate 113 0.9 5.0 284-297 Slight 5 1 2 0

CH3COOCH(CH3)CH2CH(CH3)2 (45) (140-147)

1,3-Dimethylbutylamine 55 0.7 3.5 223-228 No 1 2 3 0

CH3CHNH2(CH2)CH(CH3)2 (13) (106-109)

(2-Amino-4-Methylpentane) (oc)

Dimethyl Carbinol See Isopropyl Alcohol.

Dimethyl Carbonate See Methyl Carbonate.

Dimethyl Chloracetal 111 450 1.0+ 259-270 2 2 0

ClCH2CH(OCH3)2 (44) (232) (126-132)

Dimethylcyanamide 160 0.88 2.42 320 4 2 1

(CH3)2NCN (71) (160)

1,2-Dimethylcyclohexane 579 0.8 3.87 260 No 0 0

(CH3)2C6H10 (304) (127)

1,3-Dimethylcyclohexane ~50 583 0.8 3.87 ~256 No 1 0 3 0

(CH3)2C6H10 (10) (306) (124)

(Hexahydroxylene)

1,4-Dimethylcyclohexane 52 579 0.8 3.9 248 No 1 1 3 0

(CH3)2C6H10 (11) (304) (120)

(Hexahydroxylol)

1,4-Dimethylcyclohexanecis 61 255 0 3 0

C6H10(CH3)2 (16) (124)

1,4-Dimethylcyclohexanetrans 51 246 0 3 0

C6H10(CH3)2 (11) (119)

Dimethyl Decalin 184 455 0.7 @ 5.3 @ 1.0 455 0 2 0

C10H16(CH2)2 (84) (235) 200 300 (235)

(93) (149)

Dimethyldichlorosilane < 70 3.4 > 9.5 1.1 4.4 158 Decomposes 3 3 1

(CH3)2SiCl2 (< 21) (70) Decomposes in water.

(Dichlorodimethylsilane)

Dimethyl-o,o-Dichlorovinyl-2,2-Phosphate (Technical)

350 248 Slight 5 3 1

(CH3O)2P(O)OCH:CCl2 (DDVP) (177) (oc) (120)@ 14 mm

2

Dimethyldioxane 75 0.9 4.0 243 Slight 1 2 3 0

CH3CHCH2OCH2(CH3)CHO (24) (117) 5

(oc)

1,3-Dimethyl-1,3-Diphenylcyclobutane

289 1.0 - @ 585-588 No 2 0 1 0

(C6H5CCH3)2(CH2)2 (143) 122 (307-309)

Note: Melting point 120 (49). (50)

Dimethylene Oxide See Ethylene Oxide.

N,N-Dimethylethanolamine See 2-(Dimethylamino) Ethanol.

Dimethyl Ether See Methyl Ether.

Dimethyl Ethyl Carbinol See 2-Methyl-2-Butanol.

2,4-Dimethyl-3-Ethylpentane 734 0.74 4.43 279 0 3 0

CH3CH(CH3)CH(CH2H5)CH(CH3)2 (390) (137)

(3-Ethyl-2,4-Dimethylpentane)

N,N-Dimethylformamide 136 833 2.2 @ 15.2 0.9 2.5 307 Yes 5 1 2 0

HCON(CH3)2 (58) (445) 212 (153)

(100)

2,5-Dimethylfuran 45 0.9 3.3 200 Slight 1 2 3 0

OC(CH3):CHCH:C(CH3) (7) (93) 5

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Dimethyl Glycol Phthalate 369 1.8 446 2 0 1 0

C6H4[COO(CH2)2OCH3]2 (187) (230)

3,3-Dimethylheptane 617 0.73 4.43 279 0 3 0

CH3(CH2)3C(CH3)2CH2CH3 (325) (137)

2,6-Dimethyl-4-Heptanone See Diisobutyl Ketone.

2,3-Dimethylhexane 45 820 0.7 3.9 237 No 1 0 3 0

CH3CH(CH3)CH(CH3)C2H5CH3 (7) (438) (114)

(oc)

2,4-Dimethylhexane 50 0.7 3.9 229 No 1 0 3 0

CH3CH(CH3)CH(CH3)C2H5CH3 (10) (109)

(oc)

Dimethyl Hexynol 135 0.85 4.35 302 0 2 0

C4H9CCH3(OH)CCH (57) (150)

(3,5-Dimethyl-1-Hexyn-3-ol) (oc)

1,1-Dimethylhydrazine 5 480 2 95 0.8 2.0 145 Yes 5 3 3 1

(CH3)2NNH2 (-15) (249) (63) 1

(Dimethylhydrazine,Unsymmetrical)

Dimethylhydrazine-Unsymmetrical

See 1,1 -Dimethylhydrazine.

Dimethylisophthalate 280 No 2 0 1 0

CH3OOCC6H4COOCH3 (138)


N,N-Dimethyliso-propanolamine 95 0.9 3.6 257 Yes 1 2 3 0

(CH3)2NCH2CH(OH)CH3 (35) (125) 5

(oc)

Dimethyl Ketone See Acetone.

Dimethyl Maleate 235 1.2 393 No 2 1 1 0

(-CHCOOCH3)2 (113) (201)

(oc)

2,6-Dimethylmorpholine 112 0.9 4.0 296 Yes 5 2 2 0

CH(CH3)CH2OCH2CH(CH3)NH (44) (147)

(oc)

2,3-Dimethyloctane < 131 437 0.74 4.91 327 0 2 0

CH3(CH2)4CH(CH3)CH(CH3)CH3 (< 55) (225) (164)

3,4-Dimethyloctane < 131 0.75 4.91 324 0 2 0

C3H7CH(CH3)CH(CH3)C3H7 (< 55) (162)

2,3-Dimethylpentaldehyde 94 0.8 3.9 293 1 2 3 0

CH3CH2CH(CH3)CH(CH3)CHO (34) (145)

(oc)

2,3-Dimethylpentane < 20 635 1.1 6.7 0.7 3.5 194 No 1 0 3 0

CH3CH(CH3)CH(CH3)CH2CH3 (< -7) (335) (90)

2,4-Dimethylpentane 10 0.7 3.5 177 No 1 0 3 0

(CH3)2CHCH2CH(CH3)2 (- 12) (81)

2,4-Dimethyl-3-Pentanol 120 0.8 4.0 284 Very 0 2 0

(CH3)2CHCHOHCH(CH3)2 (49) (140) slight

(Diisopropylmethanol)

Dimethyl Phthalate 295 915 0.9 @ 1.2 540 No 2 0 1 0

C6H4(COOCH3)2 (146) (490) 358 (282)

(180)

Dimethylpiperazine-cis 155 0.92 3.94 329 2 2 0

C6H14N2 (68) (165)

(oc)

2,2-Dimethylpropane Gas 842 1.4 7.5 2.5 49 No 6 0 4 0

(CH3)4C (450) (9)

(Neopentane)

2,2-Dimethyl-1-Propanol See tert-Butyl Carbinol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2,5-Dimethylpyrazine 147 0.99 3.72 311 Yes 2 0

CH3C:CHN:C(CH3)CH:N (64) (155)

(oc)

Dimethyl Sebacate 293 1.0- 565 2 0 1 0

[-(CH2)4COOCH3]2 (145) (296)

(Methyl Sebacate) (oc)


Dimethyl Sulfate 182 370 1.3 4.4 370 Very 3 4 2 0

(CH3)2SO4 (83) (188) (188) slight

(Methyl Sulfate) (oc)


Dimethyl Sulfide < 0 403 2.2 19.7 0.8 2.1 99 Slight 1 2 4 0

(CH3)2S (< -18) (206) (37)


Dimethyl Sulfoxide 203 419 2.6 42 1.1 372 Yes 5 1 1 0

(CH3)2SO (95) (215) (189)

(oc)


Dimethyl Terephthalate 308 965 543 No 5 1 1 0

C6H4(COOCH3)2 (153) (518) (284) 2

(Dimethyl-1,4-Benzene-Dicarboxylate) (DMT)

(oc)

2,4-Dinitroaniline 435 1.6 No 2 3 1 3

(NO2)2C6H3NH2 (224)


1,2-Dinitro Benzol 302 1.57 5.79 604 3 1 4

C6H4(NO2)2 (150) (318)

(o-Dinitrobenzene) Note: Melting point 244 (118).

Dinitrochlorobenzene 382 2.0 22 1.7 599 No 2 3 1 4

C6H3Cl(NO2)2 (194) (315)

(Chlorodinitrobenzene) Note: Melting point 109 (43).


2,4-Dinitrotoluene 404 1.52 6.27 572 3 1 3

(NO2)2C6H3CH3 (207) (300)


Dioctyl Adipate 402 710 0.4 @ 0.9 680 No 5 0 1 0

[-(CH2)2COOCH2CH(C2H5)C4-H9]2 (206) (377) 467 (360) 2

[Bis(2-Ethylhexyl) Adipate] (oc) (242)

[Di(2-Ethylhexyl) Adipate]

Dioctylamine See Bis(2-Ethylhexyl) Amine.

Dioctyl Azelate 440 705 0.3 @ 0.9 709 No 5 0 1 0

(CH2)7[COOCH2CH(C2H5)C4H9]2 (227) (374) 510 (376) 2

[Bis(2-Ethylhexyl) Azelate] (oc) (266)

[Di(2-Ethylhexyl) Azelate]

Dioctyl Ether >212 401 0.82 8.36 558 0 1 0

(C8H17)2O (>100) (205) (292)

(Octyl Ether)

Dioctyl Phthalate 420 735 0.3 @ 1.0- No 2 0 1 0

C6H4[CO2CH2CH(C2H5)C4H9]2 (215) (390) 474

[Di(2-Ethylhexyl) Phthalate][Bis(2-Ethylhexyl) Phthalate]

(oc) (245)

p-Dioxane 54 356 2.0 22 1.0+ 3.0 214 Yes 1 2 3 1

OCH2CH2OCH2CH2 (12) (180) (101) 5

(Diethylene Dioxide)Note: See Hazardous Chemicals Data.

Dioxolane 35 1.1 2.6 165 Yes 1 2 3 2

OCH2CH2OCH2 (2) (74) 5

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Dipentene 113 458 0.7 @ 6.1 @ 0.9 4.7 339 No 0 2 0

C10H16 (45) (237) 302 302 (170)

(Cinene) (150) (150)

(Limonene)

Diphenyl See Biphenyl.

Diphenylamine 307 1173 1.2 575 No 2 3 1 0

(C6H5)2NH (153) (634) (302)

(Phenylaniline) Note: Melting point 127 (53).

1,1-Diphenylbutane >212 851 0.98 7.26 561 0 1 0

(C6H5)2CHC3H7 (>100) (455) (294)

1,3-Diphenyl-2-buten-1-one See Dypnone.

Diphenyldichlorosilane 288 1.2 581 Yes 2 3 1 0

(C6H5)2SiCl2 (142) (305)

Diphenyldodecyl Phosphite 425 1.0+ No 2 0 1 0

(C6H5O)2POC10H21 (218)

(oc)

Melting point 64 (18).

1,1-Diphenylethane (uns) >212 824 1.0 6.29 546 0 1 0

(C6H5)2CHCH3 (>100) (440) (286)

1,2-Diphenylethane (sym) 264 896 1.0 6.29 544 0 1 0

C6H5CH2CH2C6H5 (129) (480) (284)

Diphenyl Ether See Diphenyl Oxide.

Diphenylmethane 266 905 1.0 508 No 2 1 1 0

(C6H5)2CH2 (130) (485) (264)

(Ditane) Note: Melting point 79 (26).

Diphenyl (o-Xenyl) Phosphate 437 1.2 482-545 2 0 1 0

(C6H5O)2PO(OC6H4C6H5) (225) (250-285)

@ 5 mm

Diphenyl Oxide 239 1144 0.7 6.0 1.1 496 No 2 1 1 0

(C6H5)2O (115) (618) (258)

(Diphenyl Ether) Note: Melting point 81 (27).

1,1-Diphenylpentane >212 824 0.97 7.74 586 0 1 0

(C6H5)2CHC4H9 (>100) (440) (308)

1,1-Diphenylpropane >212 860 0.97 6.77 541 0 1 0

CH3CH2CH(C6H5)2 (>100) (460) (283)

Diphenyl Phthalate 435 1.3 761 No 2 0 1 0

C6H4(COOC6H5)2 (224) (405)


Dipropylaluminum Hydride 3 3

(C3H7)2AlH Do not use water, foam orhalogenated extinguishing

agents.


Dipropylamine 63 570 0.7 3.5 229 No 1 3 3 0

(C3H7)2NH (17) (299) (109)

(oc)

Dipropylene Glycol 250 1.0+ 4.63 449 Yes 2 0 1 0

[CH3CHOHCH2]2O (121) (232) 5

(oc)

Dipropylene Glycol Methyl Ether 186 1.1 3.0 1.0 5.11 408 Partly 0 2 0

CH3OC3H6OC3H6OH (86) @ (209)

200°C

Dipropyl Ether See n-Propyl Ether.

Dipropyl Ketone See 4-Heptanone.

Ditane See Diphenylmethane.

Ditridecyl Phthalate 470 1.0- 547 2 0 1 0

C6H4(COOC13H27)2 (243) (286)

(oc) @ 5 mm




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Divinyl Acetylene < -4 2.69 183 3 3

(CCH:CH2)2 (< -20) (84)

(1,5-Hexadien-3-yne)

Divinylbenzene 169 0.7 6.2 0.9 392 No 2 2 2

C6H4(CH:CH2)2 (76) (200)

(oc)

Divinyl Ether < -22 680 1.7 27 0.8 2.4 102 No 1 2 3 2

(CH2:CH)2O (< -30) (360) (39)

(Ethenyloxyethene)

(Vinyl Ether) Note: See Hazardous Chemicals Data.

Di(o-Xenyl) Phenyl Phosphate 482 1.2 545-626 2 0 1 0

(C6H5C6H4)2PO(OC6H5) (250) (285-330)

@ 5 mm

Dodecane 165 397 0.6 0.8 5.9 421 No 0 2 0

CH3(CH2)10CH3 (74) (203) (216)

(Dihexyl)

1-Dodecanethiol 262 0.8 289 No 5 2 1 0

CH3(CH2)11SH (128) (143) 2

(Dodecyl Mercaptan) (oc) @ 15 mm

(Lauryl Mercaptan)

1-Dodecanol 260 527 0.8 491 No 2 0 1 0

CH3(CH2)11OH (127) (275) (255)

(Lauryl Alcohol)

Dodecyl Benzene (Crude) 285 0.9 554-770 No 2 1 1 0

C6H5C12H25 (290-410)

(Alkane)

(Detergent Alkylate)

Dodecyl Bromide See Lauryl Bromide.

Dodecylene ( α) < 212 491 0.76 5.81 406 0 1 0

C16H21CH:CH2 (< 100) (255) (208)

(1-Dodecane)

Dodecyl Mercaptan See 1-Dodecanethiol. Note: See Hazardous Chemicals Data.

tert-Dodecyl Mercaptan 205 0.9 428-451 No 2 1 0

C12H25SH (96) (220-233)

(oc)

4-Dodecyloxy-2-Hydroxy-Benzophenone

498 715 No 2 1 0

C25H34O3 (254) (379)


Dodecyl Phenol 325 0.9 9.0 597-633 No 2 0 1 0

C12H25C6H4OH (163) (314-334)

(oc)

Dypnone 350 1.1 475 Slight 2 1 1 0

C6H5COCH:C(CH3)C6H5 (177) (246) 5

(1,3-Diphenyl-2-Buten-1-one) (oc) @ 50 mm

Eicosane >212 450 0.79 9.75 651 1 0

C20H42 (>100) (232) (344)

Epichlorohydrin 88 772 3.8 21.0 1.2 3.2 239 Yes 5 3 2 1

CH2CHOCH2Cl (31) (411) (115)

(2-Chloropropylene Oxide)(γ-Chloropropylene Oxide)


1,2-Epoxyethane See Ethylene Oxide.

Erythrene See 1,3-Butadiene.

Ethanal See Acetaldehyde.

Ethane Gas 882 3.0 12.5 1.0 -128 No 6 1 4 0

CH3CH3 (472) (-89)

1,2-Ethanediol See Ethylene Glycol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1,2-Ethanediol Diformate 200 1.2 345 Decomposes 1 2 0

HCOOCH2CH2OOCH (93) (174) Decomposes in water.

(Ethylene Formate) (oc)

(Ethylene Glycol Diformate)

(Glycol Diformate)

Ethanethiol See Ethyl Mercaptan.

Ethanoic Acid See Acetic Acid.

Ethanoic Anhydride See Acetic Anhydride.

Ethanol See Ethyl Alcohol.

Ethanolamine 186 770 3.0 23.5 1.0+ 2.1 342 Yes 5 2 2 0

NH2CH2CH2OH (86) (410) @ 140°C (172)

(2-Amino Ethanol)

(β-Aminoethyl Alcohol)

Ethanoyl Chloride See Acetyl Chloride.

Ethene See Ethylene.

Ethenyl Ethanoate See Vinyl Acetate.

Ethenyloxyethene See Divinyl Ether.

Ether See Ethyl Ether.

Ethine See Acetylene.

Ethoxyacetylene <20 0.8 2.4 124 No 1 2 3 1

C2H5OC:CH (< -7) (51)

Ethoxybenzene 145 1.0- 4.2 342 No 0 2 0

C6H5OC2H5 (63) (172)

(Ethyl Phenyl Ether)

(Phenetole)

2-Ethoxy-3,4-Dihydro-2-Pyran 111 1.0- 289 Very 2 2 1

C7H12O2 (44) (143) slight

(oc)

2-Ethoxy Ethanol See Ethylene Glycol Monoethyl Ether.

2-Ethoxyethyl Acetate 117 716 1.7 1.0- 4.6 313 Yes 5 2 2 0

CH3COOCH2CH2OC2H5 (47) (380) (156)

(Ethyl Glycol Acetate)

3-Ethoxypropanal 100 0.98 3.52 275 2 2 0

C2H5OC2H4CHO (38) (135)

(3-Ethoxypropionaldehyde)

1-Ethoxypropane See Ethyl Propyl Ether.

3-Ethoxypropionaldehyde 100 0.9 3.5 275 Yes 5 2 3 0

C2H5OCH2CH2CHO (38) (135)

3-Ethoxypropionic Acid 225 1.0+ 426 Yes 5 2 1 0

C2H5OCH2CH2COOH (107) (219) 2

Ethoxytriglycol 275 1.0+ 492 Yes 2 0 1 0

C2H5O(C2H4O)3H (135) (256) 5

(Triethylene Glycol, Ethyl Ether) (oc)

Ethyl Abietate 352 1.0+ 662 No 2 0 1 0

C19H29COOC2H5 (178) (350)

(oc)

N-Ethylacetamide 230 0.9 401 Yes 5 1 1 0

CH3CONHC2H5 (110) (205) 2

(Acetoethylamide)

N-Ethyl Acetanilide 126 0.9 5.6 400 No 0 2 0

CH3CON(C2H5)(C6H5) (52) (204)

Ethyl Acetate 24 800 2.0 11.5 0.9 3.0 171 Slight 1 1 3 0

CH3COOC2H5 (-4) (426) (77) 5

(Acetic Ester)

(Acetic Ether)

(Ethyl Ethanoate)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Ethyl Acetoacetate 135 563 1.4 @ 95 @ 1.0+ 4.5 356 Slight 5 2 2 0

C2H5CO2CH2COCH3 (57) (295) 200 350 (180)

(Acetoacetic Acid, Ethyl Ester) (93) (176)

(Ethyl 3-Oxobutanoate)

Ethyl Acetyl Glycolate 180 1.09 5.04 ~365 No 0 2 0

CH3COOCH2COOC2H5 (82) (~185)

(Ethyl Glycolate Acetate)

Ethyl Acrylate 50 702 1.4 14 0.9 3.5 211 Slight 1 2 3 2

CH2:CHCOOC2H5 (10) (372) (99) 5

(oc)


Ethyl Alcohol 55 685 3.3 19 0.8 1.6 173 Yes 1 0 3 0

C2H5OH (13) (363) (78) 5

(Grain Alcohol, Cologne Spirits, Ethanol)

Ethyl Alcohol and Water 96% 62

(17)

95% 63

(17)

80% 68

(20)

70% 70

(21)

60% 72

(22)

50% 75

(24)

40% 79

(26)

30% 85

(29)

20% 97

(36)

10% 120

(49)

5% 144

(62)

Ethylaluminum Dichloride 3 3 3

C2H5AlCl2 (Dichloroethylaluminum) Do not use water, foam orhalogenated extinguishing

agents.

Notes: Fumes vigorously in air. May ignite spontaneously.

Ethylaluminum Sesquichloride -4 1.1 297 3 3

(C2H5)3Al2Cl3 (-20) (147) Do not use water, foam orhalogenated extinguishing

agents.


Ethylamine <0 725 3.5 14.0 0.8 1.6 62 Yes 1 3 4 0

C2H5NH2 (< -18) (385) (17) 5

70 aqueous solution

(Aminoethane) Note: See Hazardous Chemicals Data.

Ethyl Amino Ethanol 160 0.92 3.06 322 2 0

C2H5NHC2H4OH (71) (161)

[2-(Ethylamino)ethanol] (oc)

Ethylaniline 185 1.0- 4.2 401 No 3 2 0

C2H5NH(C6H5) (85) (205)

(oc)





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Ethylbenzene 70 810 0.8 6.7 0.9 3.7 277 No 1 2 3 0

C2H5C6H5 (21) (432) (136)

(Ethylbenzol)

(Phenylethane) Note: See Hazardous Chemicals Data.

Ethyl Benzoate 190 914 1.0+ 414 No 1 1 0

C6H5COOC2H5 (88) (490) (212)

Ethylbenzol See Ethylbenzene.

Ethyl Benzoylacetate 285 1.1 291-298 No 2 0 1 0

C6H5COCH2COOC2H5 (141) (144-148)

(oc)

Ethylbenzylaniline 284 <932 1.0+ 594 No 5 2 1 0

C6H5N(C2H5)CH2C6H5 (140) (500) (312) 2

(oc) Slight

decomp.

Ethyl Borate 52 0.9 5.0 233 Decomposes 2 3 0

(C2H5)3BO3 (11) (112)

Ethyl Bromide None 952 6.8 8.0 1.4 3.8 100 Slight 1 2 1 0

C2H5Br (511) (38)

(Bromoethane)

Ethyl Bromoacetate 118 1.5 318 No 3 2 0

BrCH2COOC2H5 (48) (159)

2-Ethylbutanol See 2-Ethylbutyraldehyde.

Ethyl Butanoate See Ethy Butyrate.

2-Ethyl-1-Butanol See 2-Ethylbutyl Alcohol.

2-Ethyl-1-Butene < -4 599 0.69 2.90 144 0 3 0

(C2H5)2C:CH2 (< -20) (315) (62)

3-(2-Ethylbutoxy) Propionic Acid 280 1.0- 392 No 2 2 1 0

CH3CH2CH(C2H5)CH2-OCH2CH2COOH

(138) (200)

(oc) @ 100 mm

2-Ethylbutyl Acetate 130 0.9 5.0 324 No 1 2 0

CH3COOCH2CH(C2H5)2 (54) (162)

(oc)

2-Ethylbutyl Acrylate 125 0.9 180 No 2 2 0

CH2:CHCOOCH2CH(C2H5)C2H5 (52) (82)

(oc) @ 10 mm

2-Ethylbutyl Alcohol 135 0.8 3.5 301 No 1 2 0

(C2H5)2CHCH2OH (57) (149)

(2-Ethyl-1-Butanol) (oc)

Ethylbutylamine 64 0.7 3.5 232 No 1 3 3 0

CH3CH2CH2CH2NHCH3CH2 (18) (111)

(oc)

Ethyl Butylcarbamate See N-Butylurethane.

Ethyl Butyl Carbonate 122 0.9 5.0 275 2 2 1

(C2H5)(C4H9)CO3 (50) (135)

Ethyl Butyl Ether 40 0.8 3.7 198 Slight 1 2 3 0

C2H5OC4H9 (4) (92) 5

(Butyl Ethyl Ether)

2-Ethyl Butyl Glycol 180 0.90 5.05 386 0 2 0

(C2H5)2CHCH2OC2H4OH (82) (197)

[2-(2-Ethylbutoxy)ethanol] (oc)

Ethyl Butyl Ketone 115 0.8 4.0 299 No 1 2 0

C2H5CO(CH2)3CH3 (46) (148)

(3-Heptanone) (oc)

2-Ethyl-2-Butyl-1,3-Propanediol 280 0.9@ 352 Yes 2 2 1 0

HOCH2C(C2H5)(C4H9)CH2OH (138) 122°F (178) 5

(oc) (50°C) @ 50 mm





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2-Ethylbutyraldehyde 70 1.2 7.7 0.8 3.5 242 No 1 2 3 1

(C2H5)2CHCHO (21) (117) 5

(Diethyl Acetaldehyde) (oc)

(2-Ethylbutanal)

Ethyl Butyrate 75 865 0.9 4.0 248 No 1 0 3 0

CH3CH2CH2COOC2H5 (24) (463) (120) 5

(Butyric Acid, Ethyl Ester)

(Butyric Ester)

(Ethyl Butanoate)

2-Ethylbutyric Acid 210 752 0.9 380 Slight 5 2 1 0

(C2H5)2CHCOOH (99) (400) (193)

(Diethyl Acetic Acid) (oc)

2-Ethylcaproaldehyde See 2-Ethylhexanal.

Ethyl Caproate 120 0.9 4.97 333 No 5 2 2 0

C5H11COOC2H5 (49) (167)

(Ethyl Hexoate)

(Ethyl Hexanoate)

Ethyl Caprylate 175 0.9 405-408 No 5 2 2 0

CH3(CH2)6COOC2H5 (79) (207-209)

(Ethyl Octoate)

(Ethyl Octanoate)

Ethyl Carbonate See Diethyl Carbonate.

Ethyl Chloride -58 966 3.8 15.4 0.9 2.2 54 Slight 1 2 4 0

C2H5Cl (-50) (519) (12)

(Chloroethane)

(Hydrochloric Ether)

(Muriatic Ether) Note: See Hazardous Chemicals Data.

Ethyl Chloroacetate 147 1.2 295 No 3 3 0

ClCH2COOC2H5 (64) (146)

(oc)

Ethyl Chlorocarbonate See Ethyl Chloroformate.

Ethyl Chloroformate 61 932 1.1 3.7 201 Decomposes 3 1

ClCOOC2H5 (16) (500) (94)

(Ethyl Chlorocarbonate)

(Ethyl Chloromethanoate)

Ethyl Chloromethanoate See Ethy Chloroformate.

Ethyl Crotonate 36 0.9 3.9 282 No 1 2 3 0

CH3CH:CHCOOC2H5 (2) (139)

Ethyl Cyanoacetate 230 1.1 401-408 2 2 1 0

CH2CNCOOC2H5 (110) (205-209)

Ethylcyclobutane <4 410 1.2 7.7 2.9 160 No 1 3 0

C2H5C4H7 (< -16) (210) (71)

Ethylcyclohexane 95 460 0.9 6.6 0.8 3.9 269 No 1 3 0

C2H5C6H11 (35) (238) (132)

N-Ethylcyclohexylamine 86 0.8 4.4 Slight 1 3 3 0

C6H11NHC2H5 (30) 5

(oc)

Ethylcyclopentane <70 500 1.1 6.7 0.8 3.4 218 1 3 0

C2H5C5H9 (<21) (260) (103)

Ethyl Decanoate >212 0.9 469 No 5 0 1 0

C9H19COOC2H5 (>100) (243)

(Ethyl Caprate)

Ethyl Dichlorosilane 30 1.1 4.45 168 Yes 1 3 3 0

C2H5SiHCl2 (-1) (75.5)

N-Ethyldiethanolamine 280 1.0+ 487 Yes 2 2 1 0

C2H5N(C2H4OH)2 (138) (253) 5

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Ethyl Dimethyl Methane See Isopentane.

Ethylene Gas 842 2.7 36.0 1.0 -155 Yes 6 1 4 2

H2C:CH2 (450) (-104)

(Ethene) Note: See Hazardous Chemicals Data.

Ethylene Acetate See Glycol Diacetate.

Ethylene Carbonate 290 351 Yes 2 2 1 1

OCH2CH2OCO (143) (177) 5

(oc) @ 100 mm


Ethylene Chlorohydrin See 2-Chloroethanol.

Ethylene Cyanohydrin 265 1.1 445 Yes 2 2 1 1

CH2(OH)CH2CN (129) (229) 5

(Hydracrylonitrile) (oc) Decomposes


Ethylenediamine 104 725 2.5 12.0 0.9 2.1 241 Yes 5 3 2 0

H2NCH2CH2NH2 (40) (385) @100°C

(116)

Anydrous 150 1.0-

76% (66) 239-252 Yes 5

(oc) (115-122)

Ethylene Dichloride 56 775 6.2 16 1.3 3.4 183 No 4 2 3 0

CH2ClCH2Cl (13) (413) (84)

(1,2-Dichloroethane)

(Glycol Dichloride) Note: See Hazardous Chemicals Data.

Ethylene Dicyanide See Succinonitrile.

2,2-Ethylenedioxydiethanol See Triethylene Glycol.

Ethylene Formate See 1,2-Ethanediol Diformate.

Ethylene Glycol 232 748 3.2 1.1 387 Yes 5 1 1 0

HOC2H4OH (111) (398) (197) 2

(1,2-Ethanediol)

(Glycol)

Ethylene Glycol N-Butyl Ether 150 1.1 10.6 0.897 4.10 340 Yes 5 1 2 0

HOCH2CH2OC4H9 (66) (171)

Ethylene Glycol Diacetate See Glycol Diacetate.

Ethylene Glycol Dibutyl Ether 185 0.8 399 No 5 1 2 0

C4H9OC2H4OC4H9 (85) (204)

Ethylene Glycol Diethyl Ether 95 406 0.8 4.07 251 Slight 5 1 3 0

C2H5OCH2CH2OC2H5 (35) (122) 1

(oc)

Ethylene Glycol Diformate See 1,2-Ethanediol Diformate.

Ethylene Glycol Dimethyl Ether 29 395 0.9 174 Slight 5 2 2 0

CH3O(CH2)2OCH3 (-2) (202) (79)

(1,2-Dimethoxyethane) @ 630 mm

Ethylene Glycol Ethylbutyl Ether 180 0.9 386 No 5 1 2 0

(C2H5)2CHCH2OCH2CH2OH (85) (197)

(oc)

Ethylene Glycol Ethylhexyl Ether 230 0.9 442 No 5 0 1 0

C4H9CH(C2H5)CH2OCH2CH2OH (110) (228) 2

(oc)

Ethylene Glycol Isopropyl Ether 92 0.9 3.58 289 Yes 5 1 3 0

(CH3)2CHOCH2CH2OH (33) (143) 1

(oc)

Ethylene Glycol Monoacetate 215 1.1 357 Yes 5 0 1 0

CH2OHCH2OOCCH3 (102) (181) 2

(Glycol Monoacetate) (oc)

Ethylene Glycol Monoacrylate 220 1.1 410 Yes 5 2 1 1

CH2:CHCOOC2H4OH (104) (210) 2

(2-Hydroxyethylacrylate) (oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Ethylene Glycol MonobenzylEther

265 665 1.1 493 No 5 2 1 0

C6H5CH2OCH2CH2OH (129) (352) (256) 2

(oc)

Ethylene Glycol Monobutyl Ether 143 460 1.1 @ 12.7 0.9 4.1 340 Yes 5 2 2 0

C4H9O(CH2)2OH (62) (238) 200 @ (171)

(2-Butoxyethanol) (93) 275

(135)

Ethylene Glycol Monobutyl EtherAcetate

160 645 0.88 8.54 0.9 377 No 5 1 2 0

C4H9O(CH2)2OOCCH3 (71) (340) @ @ (192)

200 275

(93) (135)

Ethylene Glycol Monoethyl Ether 110 455 1.7 @ 15.6 0.9 3.0 275 Yes 5 2 2 0

HOCH2CH2OC2H5 (43) (235) 200 @ (135)

(2-Ethoxyethanol) (93) 200

(93)

Ethylene Glycol Monoethyl EtherAcetate

124 715 1.7 1.0- 4.72 313 Yes 5 1 2

CH3COOCH2CH2OC2H5 (52) (379) (156)

(Cellosolve Acetate)

Ethylene Glycol MonoisobutylEther

136 540 1.2 @ 9.4 @ 0.9 4.1 316-323 Yes 5 2 2

(CH3)2CHCH2OCH2CH2OH (58) (282) 200 275 (158-162)

(93) (135)

Ethylene Glycol MonomethylEther

102 545 1.8 @ 14 @ 1.0- 2.6 255 Yes 5 2 2 0

CH3OCH2CH2OH (39) (285) STP STP (124)

(2-Methoxyethanol)

Ethylene Glycol MonomethylEther Acetal

200 1.0- 405 Yes 5 1 2

CH3CH(OCH2CH2OCH3)2 (93) (207)

(oc)

Ethylene Glycol MonomethylEther Acetate

120 740 1.5 @ 12.3 1.0+ 4.1 293 Yes 5 1 2

CH3O(CH2)2OOCCH3 (49) (392) 200 @ (145)

(93) 200

(93)

Ethylene Glycol MonomethylEther Formal

155 1.0- 5.65 394 Yes 5 1 2

CH2(OCH2CH2OCH3)2 (68) (201)

(oc)

Ethylene Glycol Phenyl Ether 260 1.1 4.8 473 No 2 0 1 0

C6H5OC2H4OH (127) (245)

(2-Phenoxyethanol)

Ethylenimine 12 608 3.3 54.8 0.8 1.5 132 Yes 5 3 3 2

NHCH2CH2 (-11) (320) (56)

(Aziridine)Note: See Hazardous Chemicals Data.

Ethylene Oxide -20 1058 3.0 100 0.9 1.5 51 Yes 1 2 4 3

CH2OCH2 with No Air (11) Vapors explosive.

(Dimethylene Oxide)

(1,2-Epoxyethane)

(Oxirane) Note: See Hazardous Chemicals Data.

Ethyl Ethanoate See Ethyl Acetate.

N-Ethylethanolamine 160 0.9 3.0 322 Yes 5 1 2 0

C2H5NHC2H4OH (71) (161)

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Ethyl Ether -49 356 1.9 36.0 0.7 2.6 95 Slight 1 2 4 1

C2H5OC2H5 (-45) (180) (35) 5

(Diethyl Ether)

(Diethyl Oxide)

(Ether)

(Ethyl Oxide) Note: See Hazardous Chemicals Data.

Ethylethylene Glycol See 1,2-Butanediol.

Ethyl Fluoride 0.72 1.66 -36 4 0

C2H5F @ 7.2 (-38)

(1-Fluoroethane) atm

Ethyl Formate -4 851 2.8 16.0 0.9 2.6 130 No 1 2 3 0

HCO2C2H5 (-20) (455) (54) 5

(Ethyl Methanoate)

(Formic Acid, Ethyl Ester)

Ethyl Formate (ortho) 86 0.90 5.11 291 0 3 0

(C2H5O)3CH (30) (144)

(Triethyl Orthoformate)

Ethyl Glycol Acetate See 2-Ethoxyethyl Acetate.

2-Ethylhexaldehyde See 2-Ethylhexanal.

2-Ethylhexanal 112 375 0.85 7.2 @ 0.8 4.4 325 Very 2 2 1

C4H9CH(C2H5)CHO (44) (190) @ 275 (163) slight

(Butylethylacetaldehyde) 200 (135)

(2-Ethylcaproaldehyde) (93)

(2-Ethylhexaldehyde)

2-Ethyl-1,3-Hexanediol 260 680 0.9 472 Slight 2 1 1 0

C3H7CH(OH)CH(C2H5)CH2OH (127) (360) (244) 5

(oc)

2-Ethylhexanoic Acid 245 700 0.8 6.0 0.9 5.0 440 No 2 1 1 0

C4H9CH(C2H5)COOH (118) (371) (227)

(2-Ethyl Hexoic Acid) (oc)

2-Ethylhexanol 164 448 0.88 9.7 0.8 4.5 359 Slight 5 2 2 0

C4H9CH(C2H5)CH2OH (73) (231) (182)

(2-Ethylhexyl Alcohol)

(Octyl Alcohol)

2-Ethylhexenyl See 2-Ethyl-3-Propylacrolein.

2-Ethylhexoic Acid See 2-Ethylhexanoic Acid.

2-Ethylhexyl Acetate 160 515 0.76 8.14 0.9 5.9 390 No 2 2 0

CH3COOCH2CH(C2H5)C4H9 (71) (268) (199)

(Octyl Acetate)

2-Ethylhexyl Acrylate 180 485 0.9 266 No 2 2 2

CH2:CHCOOCH2CH(C2H5)C4H9 (82) (252) (130)

(oc) @ 50 mm

2-Ethylhexylamine 140 0.8 4.5 337 Yes 5 2 2 0

C4H9CH(C2H5)CH2NH2 (60) (169)

(oc)

N-2-(Ethylhexyl) Aniline 325 0.9 379 No 2 3 1 0

C6H5NHCH2CH(C2H5)C4H9 (163) (193)

(oc) @ 50 mm

2-Ethylhexyl Chloride 140 0.9 5.1 343 No 2 2 0

C4H9CH(C2H5)CH2Cl (60) (173)

(oc)

N-(2-Ethylhexyl)-cyclohexylamine 265 0.8 342 No 2 2 1 0

C6H11NH[CH2CH(C2H5)C4H9] (129) (172)

(oc) @ 50 mm

2-Ethylhexyl Ether 235 0.8 517 No 2 1 1 0

[C4H9CH(C2H5)CH2]2O (113) (269)

2-Ethylhexyl Vinyl Ether See Vinyl-2-Ethylhexyl Ether.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1,1-Ethylidene Dichloride 2 5.4 11.4 1.2 135-138 Slight 4 2 3 0

CH3CHCl2 (- 17) (57-59) 5

(1,1-Dichloroethane)

1,2-Ethylidene Dichloride 55 824 6.2 16 1.25 3.42 183 2 3 0

ClCH2CH2Cl (13) (440) (84)

Ethyl Isobutyrate <70 0.87 4.0 230 0 3 0

(CH3)2CHCOOC2H5 (<21) (110)

2-Ethylisohexanol 158 600 0.8 343-358 1 2

(CH3)2CHCH2CH(C2H5)CH2OH (70) (316) (173-181)

(2-Ethyl Isohexyl Alcohol)

(2-Ethyl-4-Methyl Pentanol)

Ethyl Lactate 115 752 1.5 @ 1.0+ 4.1 309 Yes 5 2 2 0

CH3CHOHCOOC2H5 (46) (400) 212 (154)

Tech. 131 (100)

(55)

Ethyl Malonate See Diethyl Malonate.

Ethyl Mercaptan < 0 572 2.8 18.0 0.8 2.1 95 No 1 2 4 0

C2H5SH (< -18) (300) (35)

(Ethanethiol)

(Ethyl Sulfhydrate)

Ethyl Methacrylate 68 0.9 3.9 239-248 No 1 2 3 0

CH2:C(CH3)COOC2H5 (20) (115-120)

(Ethyl Methyl Acrylate) (oc)

Ethyl Methanoate See Ethyl Formate.

Ethyl Methyl Acrylate See Ethyl Methacrylate.

Ethyl Methyl Ether See Methyl Ethyl Ether.

7-Ethyl-2-Methyl-4-Hendecanol 285 0.8 507 Very 2 0 1 0

C4H9CH(C2H5)C2H4- (141) (264) slight

CHOHCH2CH(CH3)2 (oc)

Ethyl Methyl Ketone See Methyl Ethyl Ketone.

4-Ethylmorpholine 90 0.9 4.0 280 Yes 1 2 3 0

CH2CH2OC2H4NCH2CH3 (32) (138) 5

(oc)

1-Ethylnaphthalene 896 1.02 5.39 496 0 1 0

C10H7C2H5 (480) (258)

Ethyl Nitrate 50 4.0 1.1 3.1 190 No 4 2 3 4

CH3CH2ONO2 (10) (88)

(Nitric Ether)

Ethyl Nitrite -31 194 4.0 50. 0.9 2.6 63 No 2 4 4

C2H5ONO (-35) (90) (17)

(Nitrous Ether) Decomposes


3-Ethyloctane 446 0.74 4.91 333 0 2 0

C5H11CH(C2H5)C2H5 (230) (167)

4-Ethyloctane 445 0.74 4.91 328 0 2 0

C4H9CH(C2H5)C3H7 (229) (164)

Ethyl Orthosilicate See Ethyl Silicate.

Ethyl Oxalate 168 1.1 5.0 367 Slight 0 2 0

(COOC2H5)2 (76) (186) gradual

(Oxalic Ether) decom-

(Diethyl Oxalate) position

Ethyl Oxide See Ethyl Ether.

Ethyl 3-Oxobutanoate See Ethyl Acetoacetate.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

p-Ethylphenol 219 1.0- 426 Slight 5 2 1 0

HOC6H4C2H5 (104) @140°F

(219) 2

(60°C)


Ethyl Phenylacetate 210 1.0+ 529 No 0 1

C6H5CH2COOC2H5 (99) (276)

Ethyl Phenyl Ether See Ethoxybenzene.

Ethyl Phenyl Ketone 210 1.01 4.63 425 1 0

C2H5COC6H5 (99) (218)

(Propiophenone) (oc)


Ethyl Phosphate See Triethyl Phosphate.

Ethyl Phthalyl Ethyl Glycolate 365 1.2 608 Yes 2 0 1 0

C2H5OCOC6H4OCOCH2OCOC2H5 (185) (320) 5

Ethyl Propenyl Ether >19 0.8 158 1 2 3 1

CH3CH:CHOCH2CH3 (>-7) (70)

(oc)

Ethyl Propionate 54 824 1.9 11 0.9 3.5 210 No 1 3 0

C2H5COOC2H5 (12) (440) (99)

2-Ethyl-3-Propylacrolein 155 0.9 4.4 347 No 5 2 2 1

C3H7CH:C(C2H5)CHO (68) (175)

(2-Ethylhexenal) (oc)

2-Ethyl-3-Propylacrylic Acid 330 0.9 450 Slight 2 2 1 1

C3H7CH:C(C2H5)COOH (166) (232) 5

(oc)

Ethyl Propyl Ether <-4 1.7 9.0 0.8 147 Yes 5 1 3 0

C2H5OC3H7 (<-20) (64)

(1-Ethoxypropane)

Ethyl Silicate 125 0.9 7.2 334 Decomposes 2 2 0

(C2H5)4SiO4 (52) (168)

(Ethyl Orthosilicate) (oc)

(Tetraethyl Orthosilicate)

Ethyl Sulfate See Diethyl Sulfate.

Ethyl Sulfhydrate See Ethyl Mercaptan.

m-Ethyltoluene 896 0.88 4.15 322 2 0

CH3C6H4C2H5 (480) (161)

(1-Methyl-3-Ethylbenzene)

o-Ethyltoluene 824 0.88 4.15 329 2 0

CH3C6H4C2H5 (440) (165)


p-Ethyltoluene 887 0.88 4.15 324 2 0

CH3C6H4C2H5 (475) (162)


Ethyl p-Toluene Sulfonamide 260 1.3 208 2 1 0

C7H7SO2NHC2H5 (127) (98)

@ 745 mm

Ethyl p-Toluene Sulfonate 316 1.2 345 No 2 1 0

C7H7SO3C2H5 (158) (174)

Ethyltrichloro Silane 72 1.2 208 1 3 3 0

CH3CH2SiCl3 (22) (98)

(oc) @ 745 mm

Ethyl Vinyl Ether See Vinyl Ethyl Ether.

Ethyne See Acetylene.

Fish Oil 420 No 2 0 1 0

(216)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Fluorobenzene 5 1.03 3.31 185 3 0

C6H5F (-15) (85)

Formal See Methylal.

Formalin See Formaldehyde.

Formaldehyde Gas 795 7.0 73 1.0 -3 Yes 6 2 4 0

HCHO 185 (424) (-19)

37% Methanol-free (85) 214 5 2 2 0

(101)

37%, 15% Methanol 122 2 2

(Formalin) (50)

(Methylene Oxide) Note: See Hazardous Chemicals Data.

Formamide 310 1.1 410 Yes 2 2 1

HCONH2 (154) (210)

(oc) Decomposes

Formic Acid 156 1004 1.2 1.6 213 Yes 5 3 2 0

HCOOH (69) (539) (101)

90% Solution 122 813 18 57

(50) (434)


Formic Acid, Butyl Ester See Butyl Formate.

Formic Acid, Ethyl Ester See Ethyl Formate.

Formic Acid, Methyl Ester See Methyl Formate.

Fuel Oil No. 1 100-162 410 0.7 5 <1 304-574 No 0 2 0

(Kerosene) (43-72) (210) (151-301)

(Range Oil)

(Coal Oil)

Fuel Oil No. 2 126-204 494 <1 No 0 2 0

(52-96) (257)

Fuel Oil No. 4 142-240 505 <1 No 0 2 0

(61-116) (263)

Fuel Oil No. 5 <1 No 0 2 0

Light 156-336

(69-169)

Heavy 160-250

(71-121)

Fuel Oil No. 6 150-270 765 1± No 0 2 0

(66-132)

(407)

2-Furaldehyde See Furfural.

Furan <32 2.3 14.3 0.9 2.3 88 No 1 1 4 1

CH:CHCH:CHO (<0) (31)

(Furfuran)

Furfural 140 600 2.1 19.3 1.2 3.3 322 Slight 5 2 2 0

OCH:CHCH:CHCHO (60) (316) (161)

(2-Furaldehyde)(Furfuraldehyde)(Furol)


Furfuraldehyde See Furfural.

Furfuran See Furan.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Furfuryl Acetate 185 1.1 4.8 356-367 No 3 1 2 1

OCH:CHCH:CCH2OOCCH3 (85) (180-186)

Furfuryl Alcohol 167 915 1.8 16.3 1.1 3.4 340 Yes 5 1 2 1

OCH:CHCH:CCH2OH (75) (491) (171)

(oc)

Furfurylamine 99 1.05 3.35 295 3 0

C4H3OCH2NH2 (37) (146)

(oc)

Furol See Furfural.

Fusel Oil See Isoamyl Alcohol.

Gas, Blast Furnace 35 74 6 2 4 0

Gas, Coal Gas 5.3 32 6 2 4 0

Gas, Coke-Oven 4.4 34 6 2 4 0

Gas, Natural 900-1170

3.8- 13- 6 1 4 0

(Natural Gas) (482-632)

6.5 17

Gas, Oil Gas 4.8 32.5 6 2 4 0

Gas, Producer 20-30 70-80 6 2 4 0

Gas, Water 7.0 72 6 2 4 0

Gas, Water (Carbureted) 5.6 46.2 6 2 4 0

Gas Oil 150+ 640 0.5 5.0 <1 500-700 No 0 2 0

(66+) (338) (260-371)

Gasoline -45 1.4 7.6 0.8 3-4 100-400 No 1 1 3 0

C5H12 to C9H20 (-43) (38-204)

56-60 Octane -45 536 1.4 7.6

(-43) (280)

73 Octane 1.4 7.6

92 Octane 1.5 7.6

100 Octane -36 853 1.4 7.4

(-38) (456)

Note: Values may vary considerably for different grades of gasoline.

Gasoline -50 824 1.3 7.1 1 3 0

100-130 (Aviation Grade) (-46) (440)

(approx.)

Gasoline -50 880 1.2 7.1 1 3 0

115-145 (Aviation Grade) (-46) (471)

(approx.)

Gasoline (Casinghead) 0 No 1 1 4 0

(-18)

or less

Geraniol >212 0.9 446 No 5 0 1 0

(CH3)2C:CH(CH2)2C(CH3):CHCH2OH (>100) (230)

(trans-3,7-Dimethyl-2,6-Octadien-1-ol)

Geranyl Acetate >212 0.9 468-473 No 5 0 1 0

CH3COOC10H17 (>100) (242-245)

(Geraniol Acetate)

Geranyl Butyrate >212 0.9 304 No 5 0 1 0

C3H7COOC10H17 (>100) (151)

(Geraniol Butyrate)

Geranyl Formate 185 0.9 235 No 5 0 2 0

HCOOC10H17 (85) (113)

(Geraniol Formate)

Geranyl Propionate >212 0.9 5 0 1 0

C2H5COOC10H17 (> 100)

(Geraniol Propionate)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Gin See Ethyl Alcohol and Water.

Glucose Pentapropionate 509 1.2 401 No 2 1 1 0

C6H7O6(COC2H5)5 (265) (205)

(Pentapropionyl Glucose) @ 2 mm

(Tetrapropionyl GlucosylPropionate)

Glycerine 390 698 1.3 3.1 340 Yes 2 1 1 0

HOCH2CHOHCH2OH (199) (370) (171) 5

(Glycerol)

α,β-Glycerin Dichlorohydrin 200 1.4 360 Yes 5 2 1 0

CH2ClCHClCH2OH (93) (182)

Glycerol See Glycerine.

Glyceryl Triacetate 280 812 1.0 @ 1.2 496 Slight 2 1 1 0

(C3H5)(OOCCH3)3 (138) (433) 373 (258) 5

(Triacetin) (189)

Glyceryl Tributyrate 356 765 0.5 @ 1.0+ 597 No 5 0 1 0

C3H5(OOCC3H7)3 (180) (407) 406 (314) 2

(Tributyrin) (oc) (208)

(Butyrin)

(Glycerol Tributyrate)

Glyceryl Trichlorohydrin See 1,2,3-Trichloropropanc.

Glyceryl Trinitrate See Nitroglycerine.

Glyceryl Tripropionate 332 790 0.8 @ 1.1 540 No 5 0 1 0

(C2H5COO)3C3H5 (167) (421) 367 (282) 2

(Tripropionin) (oc)

Glycidyl Acrylate 141 779 1.1 4.4 135 No 0 2 0

CH2:CHCOOCH2CHCH2O (61) (415) (57)

(oc) @ 2 mm

Glycol See Ethylene Glycol.

Glycol Benzyl Ether 264 662 1.07 5.20 493 No 0 1 0

C6H5CH2OCH2CH2OH (129) (350) (256)

(2-Benzyloxyethanol) (oc)

Glycol Diacetate 191 900 1.6 8.4 1.1 375 Slight 5 1 1 0

(CH2OOCCH3)2 (88) (482) (191)

(Ethylene Acetate)

(Ethylene Glycol Diaceate)

Glycol Dichloride See Ethylene Dichloride.

Glycol Diformate See 1,2-Ethanediol Diformate.

Glycol Dimercaptoacetate 396 1.3 280 No 5 2 1 0

(HSCH2C:OOCH2-)2 (202) (138) 2

(GDMA) 1.2 mm

Glycol Monoacetate See Ethylene Glycol Monoacetate.

Grain Alcohol See Ethyl Alcohol.

Heavy Hydrogen See Deuterium.

Hendecane 149 0.7 5.4 384 No 1 0 2 0

CH3(CH2)9CH3 (65) (196)

(Undecane) (oc)

Heptadecanol 310 0.8 588 No 2 0 1 0

C4H9CH(C2H5)C2H4 (154) (309)

CH(OH)C2H4CH(C2H5)2 (oc)

(3,9-Diethyl-6-Tridecanol) Note: Melting point 130 (54).

Heptane 25 399 1.05 6.7 0.7 3.5 209 No 1 1 3 0

CH3(CH2)5CH3 (-4) (204) (98)

2-Heptanol 160 0.8 4.0 320 No 0 2 0

CH3(CH2)4CH(OH)CH3 (71) (160)

3-Heptanol 140 0.8 4.0 313 Slight 5 0 2 0

CH3CH2CH(OH)C4H9 (60) (156)

3-Heptanone See Ethyl Butyl Ketone.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

4-Heptanone 120 0.8 3.9 290 No 2 2 0

(C3H7)2CO (49) (143)

(Butyrone)

(Dipropyl Ketone)

1-Heptene See Heptylene.

3-Heptene (mixed cis and trans) 21 0.7 3.39 203 No 1 0 3 0

C3H7CH:CHC2C5 (-6) (95)

(3-Heptylene)

Heptylamine 130 0.8 4.0 311 Slight 5 2 2 0

CH3(CH2)6NH2 (54) (155)

(1-Aminoheptane) (oc)

Heptylene <32 500 0.7 3.39 201 No 0 3 0

C5H11CH:CH2 (<0) (260) (94)

(1-Heptene)

Heptylene-2-trans <32 0.7 3.34 208 0 3 0

C4H9CH:CHCH3 (<0) (98)

(2-Heptene-trans)

Hexachlorobutadiene 1130 8.99 2 1 1

CCl2:CClCCl:CCl2 (610)

Hexachloro Diphenyl Oxide 1148 13.0 2 1 1

(C6H2Cl3)2O (620)

[Bis(Trichlorophenyl) Ether]

Hexadecane >212 396 0.8@ 7.8 549 No 0 1 0

CH3(CH2)14CH3 (>100) (202) 68 (287)

(Cetane) Note: Melting point 68 (20). (20)

tert-Hexadecanethiol 265 0.9 298-307 No 2 0 1 0

C16H33SH (129) (148-153)

(Hexadecyl-tert-Mercaptan) (oc) @ 11 mm

Hexadecylene-1 >212 464 0.78 7.72 525 No 0 1 0

CH3(CH2)13CH:CH2 (>100) (240) (274)

(1-Hexadecene)

Hexadecyl-tert-Mercaptan See tert-Hexadecanethiol.

Hexadecyltrichlorosilane 295 1.0- 516 Yes 2 3 1 0

C16H33SiCl3 (146) (269)

2,4-Hexadienal 154 1.3 8.1 0.9 339 Very 2 2 0

CH3CH:CHCH:CHC(O)H (68) (171) slight

(oc)

1,4-Hexadiene -6 2.0 6.1 0.7 2.8 151 No 1 0 3 0

CH3CH:CHCH2CH:CH2 (-21) (66)

(Allylpropenyl)

Hexahydroaniline See Cyclohexylamine.

Hexahydrobenzene See Cyclohexane.

Hexahydropyridine See Piperidine.

Hexahydrotoluene See Methylcyclohexane.

Hexahydroxylol See 1,4-Dimethylcyclohexane.

Hexaldehyde See Hexanal.

Hexalin See Cyclohexanol.

Hexalin Acetate See Cyclohexyl Acetate.

Hexamethylene See Cyclohexane.

Hexanal 90 0.8 3.6 268 No 1 2 3 1

CH3(CH2)4CHO (32) (131)

(Caproaldehyde) (oc)

(Hexaldehyde)

Hexane -7 437 1.1 7.5 0.7 3.0 156 No 1 1 3 0

CH3(CH2)4CH3 (-22) (225) (69)

(Hexyl Hydride)

1,2-Hexanediol See Hexylene Glycol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2,5-Hexanediol 230 1.0- 429 Yes 2 2 1 0

CH3CH(OH)CH2CH2CH(OH)CH3 (110) (221) 5

(2,5-Dihydroxyhexane)

2,5-Hexanedione See Acetonyl Acetone.

1,2,6-Hexanetriol 375 1.1 352 Yes 2 1 1 0

HOCH2CH(OH)(CH2)3CH2OH (191) (178) 5

(oc) @ 5 mm

Hexanoic Acid See Caproic Acid.

1-Hexanol See Hexyl Alcohol.

2-Hexanone See Methyl Butyl Ketone.

3-Hexanone 95 ~1 ~8 0.82 3.46 253 1 3 0

C2H5COC3H7 (35) (123)

(Ethyl n-Propyl Ketone) (oc)

1-Hexene <20 487 0.7 3.0 146 No 1 1 3 0

CH2:CH(CH2)3CH3 (<-7) (253) (63)

(Butyl Ethylene)

2-Hexene (Mixed cis and transisomers)

<20 473 0.7 3.0 155 No 1 1 3 0

CH3CH:CH(CH2)2CH3 (<-7) (245) (68)

2-Hexene-cis <-4 0.69 2.90 156 0 3 0

C3H7CH:CHCH3 (<-20) (69)

3-Hexenol-cis 130 0.85 3.45 313 Slight 5 1 2 0

CH3CH2CH:CHCH2CH2OH (54) (156)

(3-Hexen-l-ol)

(Leaf Alcohol)

Hexone See Methyl Isobutyl Ketone.

Hexyl Acetate 113 0.9 5.0 285 No 5 1 2 0

(CH3)2CH(CH2)3OOCCH3 (45) (141)

(Methylamyl Acetate)

Hexyl Alcohol 145 0.8 3.5 311 Slight 5 1 2 0

CH3(CH2)4CH2OH (63) (155)

(Amyl Carbinol)

(1-Hexanol)

sec-Hexyl Alcohol 136 0.81 3.53 284 0 2 0

C4H9CH(OH)CH3 (58) (140)

(2-Hexanol)

Hexylamine 85 0.8 3.5 269 Slight 1 2 3 0

CH3(CH2)5NH2 (29) (132) 5

(oc)

Hexyl Chloride See 1-Chlorohexane.

Hexyl Cinnamic Aldehyde >212 1.0- 486 5 1 0

C6H13C(CHO):CHC6H5 (>100) (252)

(Hexyl Cinnamaldehyde)

Hexylene Glycol 215 0.9 385 2 1 1 0

CH2OHCHOH(CH2)3CH3 (102) (196)

(1,2-Hexanediol) (oc)

Hexyl Ether 170 365 0.8 6.4 440 No 2 2 0

C6H13OC6H13 (77) (185) (227)

(Dihexyl Ether) (oc)

Hexyl Hydride See Hexane.

Hexyl Methacrylate 180 0.9 5.9 388-464 0 2 0

C6H13OOCC(CH3):CH2 (82) (198-240)

(oc)

Hexyl Methyl Ketone See 2-Octanone.

Hydracrylonitrile See Ethylene Cyanohydrin.

Hydralin See Cyclohexanol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Hydrazine (Anhydrous) 100 2.9 98 1.0+ 1.1 236 Yes 3 3 2

H2NNH2 (38) (113) Vapors explosive.

Ignition temperatures vary widely in contact with iron rust 74 (23); black iron 270 (132);stainless steel 313 (156); glass 518 (270). Note: See Hazardous Chemicals Data.

Hydrindane 565 0.9 318 5 0

C9H16 (296) (159)

(Hexahydroindane)

(Octahydroindene)

Hydrochloric Ether See Ethyl Chloride.

Hydrocyanic Acid-96% 0 1000 5.6 40.0 0.7 0.9 79 Yes 4 4 2

HCN (- 18) (538) (26) Vapors extremely toxic.

(Prussic Acid)

(Hydrogen Cyanide) Note: See Hazardous Chemicals Data.

Hydrogen Gas 932 4.0 75 0.1 -422 Slight 6 0 4 0

H2 (500) (-252)


Hydrogen Cyanide See Hydrocyanic Acid.

Hydrogen Sulfide Gas 500 4.0 44.0 1.2 -76 Yes 6 3 4 0

H2S (260) (-60)


Hydroquinone 329 960 1.3 547 No 5 2 1 0

C6H4(OH)2 (165) (516) (286) 2

(HQ)

(Quinol)

(Hydroquinol)

HydroquinoneDi-(β-Hydroxyethyl) Ether

435 875 365-392 @ Slight 2 1 0

C6H4(-OCH2CH2OH)2 (224) (468) 0.3 mm

(185-200)


Hydroquinone Monomethyl Ether 270 790 1.5 475 No 2 1 0

CH3OC6H4OH (132) (421) (246)

(HQMME) (oc)

(4-Methoxy Phenol)

(Para-Hydroxyanisole) Note: Melting point 126 (52).

o-Hydroxybenzaldehyde See Salicylaldehyde.

3-Hydroxybutanal See Aldol.

β-Hydroxybutyraldehyde See Aldol.

Hydroxycitronellal >212 0.9 201-205 Slight 5 1 0

(CH3)2C(OH)(CH2)3CH(CH3)CH2CHO(>100) (94-96)

(Citronellal Hydrate) @ 1 mm

(3,7-Dimethyl-7-Hydroxyoctanal)

N-(2-Hydroxyethyl)-acetamide See N-Acetyl Ethanolamine.

2-Hydroxyethyl Acrylate 214 1.8 1.1 410 Yes 2 1 2

(HEA) (101) @100°C

(210)

β-Hydroxyethylaniline See 2-Anilinoethanol.

N-(2-Hydroxyethyl)Cyclohexylamine

249 Yes 2 3 1 0

C6H11NHC2H4OH (121) 5

(oc)


(2-Hydroxyethyl)-Ethylenediamine

275 1.0+ 460-464 Yes 2 1 1 0

CH2OHCH2NHCH2CH2NH2 (135) (238-240) 5

4-(2-Hydroxyethyl) Morpholine 210 1.1 437 Yes 5 2 1 0

CH2H4OC2H4NC2H4OH (99) (225)

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1-(2-Hydroxyethyl) Piperazine 255 1.1 4.5 475 Yes 2 0 1 0

HOCH2CH2- (124) (246) 5

NCH2CH2NHCH2CH2 (oc)

n-(2-Hydroxyethyl)Propylenediamine

260 1.0- 465 Yes 2 2 1 0

CH3CH(NHC2H4OH)CH2NH2 (127) (241) 5

(oc)

Hydroxylamine Explodes 1.2 158 Yes 1 3 3

NH2OH @ 265 (70)

(Oxammonium) (129)



4-Hydroxy-4-Methyl-2-Pentanone See Diacetone Alcohol.

2-Hydroxy-2-methyl-propionitrile See Acetone Cyanohydrin.

Hydroxypropyl Acrylate See Propylene Glycol Monoacrylate.

o-Hydroxytoluene See o-Cresol.

Ionone Alpha ( α-Ionone) >212 0.9 259-262 Slight 5 1 0

C(CH3)2CH2CH2CH:C(CH3)- (>100) (126-128)

CHCH:CHC(CH3):O@ 12 mm

(α-Cyclocitrylideneacetone)

[4-(2,6,6-Trimethyl-2-Cyclohexen-1-yl)-3-Buten-2-one]

Ionone Beta ( β-Ionone) >212 0.9 284 No 5 1 0

C(CH3)2CH2CH2CH2- (>100) (140)

C(CH3):CCHCHC(CH3):O @ 18 mm

(β-Cyclocitrylidene-acetone)[4-(2,6,6-Trimethyl-1-

Cyclohexen-1-yl)-3-Buten-2-one]

Iron Carbonyl 5 1.45 6.74 221 2 3 1

Fe(CO)5 (-15) (105)

Isano Oil 1.0- 1 3

Exothermic reaction above 502 (261) may become explosive. May explodeabove 502 (261).

Isoamyl Acetate 77 680 1.0 @ 7.5 0.9 4.5 290 Slight 5 1 3 0

CH3COOCH2CH2CH(CH3)2 (25) (360) 212 (143) 1

(Banana Oil) (100)

(3-Methyl-1-Butanol Acetate)

(2-Methyl Butyl Ethanoate)

Isoamyl Alcohol 109 662 1.2 9.0 @ 0.8 3.0 270 Slight 5 1 2 0

(CH3)2CHCH2CH2OH (43) (350) 212 (132)

(Isobutyl Carbinol) (100)

(Fusel Oil)

(3-Methyl-1-Butanol)

tert-Isoamyl Alcohol See 2-Methyl-2-Butanol.

Isoamyl Butyrate 138 0.88 5.45 352 2

C3H7CO2(CH2)2CH(CH3)2 (59) (178)

(Isopentyl Butyrate)

Isoamyl Chloride <70 1.5 7.4 0.89 3.67 212 3

(CH3)2CHCH2CH2Cl (<21) (100)

(1-Chloro-3-Methylbutane)

Isobornyl Acetate 190 1.0- 428-435 No 5 1 2 0

C10H17OOCCH3 (88) (220-224)

Isobutane Gas 860 1.8 8.4 2.0 11 No 6 1 4 0

(CH3)3CH (460) (-12)

(2-Methylpropane)

Isobutyl Acetate 64 790 1.3 10.5 0.9 4.0 244 No 5 1 3 0

CH3COOCH2CH(CH3)2 (18) (421) (118) 1

(β-Methyl Propyl Ethanoate)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Isobutyl Acrylate 86 800 0.9 4.42 142-145 5 1 3 1

(CH3)2CHCH2OOCCH:CH2 (30) (427) (61-63) 1

(oc) @ 15 mm

Isobutyl Alcohol 82 780 1.7 @ 10.6 @ 0.8 2.6 225 Yes 5 1 3 0

(CH3)2CHCH2OH (28) (415) 123 202 (107) 1

(Isopropyl Carbinol) (51) (94)

(2-Methyl-1-Propanol)

Isobutylamine 15 712 0.7 2.5 150 Yes 5 2 3 0

(CH3)2CHCH2NH2 (-9) (378) (66) 1

Isobutylbenzene 131 802 0.8 6.0 0.9 4.6 343 No 2 2 0

(CH3)2CHCH2C6H5 (55) (427) (173)

Isobutyl Butyrate 122 0.87 5.0 315 0 2

C3H7CO2CH2CH(CH3)2 (50) (157)

Isobutyl Carbinol See Isoamyl Alcohol.

Isobutyl Chloride <70 2.0 8.8 0.9 3.2 156 2 3 0

(CH3)2CHCH2Cl (<21) (69)

(1-Chloro-3-Methyl-propane)

Isobutylcyclohexane 525 0.8 336 0 0

(CH3)2CHCH2C6H11 (274) (169)

Isobutylene See 2-Methylpropene.

Isobutyl Formate < 70 608 ~1.7 ~8 0.88 3.52 208 3

HCOOCH2CH(CH3)2 (< 21) (320) (98)

Isobutyl Heptyl Ketone 195 770 0.8 412-426 No 5 2 2 0

(CH3)2CHCH2COCH2-CH(CH3)CH2CH(CH3)2

(91) (410) (211-219)

(2,6,8-Trimethyl-4-Nonanone) (oc)

Isobutyl Isobutyrate 101 810 0.96 7.59 0.9 4.97 291-304 No 5 0 2 0

(CH3)2CHCOOCH2CH(CH3)2 (38) (432) (144-151)

Isobutyl Phenylacetate >212 1.0 477 5 0 1 0

(CH3)2CHCH2OOCCH2C6H5 (>100) (247)

Isobutyl Phosphate 275 0.98 9.12 302 1

PO4(CH2CH(CH3)2)3 (135) (150)

(Triisobutyl Phosphate) (oc) @ 20 mm

Isobutyl Vinyl Ether See Vinyl Isobutyl Ether.

Isobutyraldehyde -1 385 1.6 10.6 0.8 2.5 142 Slight 5 2 3 1

(CH3)2CHCHO (-18) (196) (61) 1

(2-Methylpropanal)

Isobutyric Acid 132 900 2.0 9.2 1.0- 3.0 306 Yes 5 1 2 0

(CH3)2CHCOOH (56) (481) (152)

Isobutyric Anhydride 139 625 1.0 6.2 1.0- 5.5 360 Decomposes 5 1 2 1

[(CH3)2CHCO]2O (59) (329) (182)

Isobutyronitrile 47 900 0.8 2.38 214-216 Slight 5 3 3 0

(CH3)2CHCN (8) (482) (101-102) 1

(2-Methylpropanenitrile)

(Isopropylcyanide)

Isodecaldehyde 185 0.8 5.4 387 No 0 2 0

C9H19CO (85) (197)

(oc)

Isodecane 410 0.73 4.91 333 0 2 0

C7H15CH(CH3)2 (210) (167)

(2-Methylnonane)

Isodecanoic Acid 300 0.9 5.9 489 No 2 0 1 0

C9H19COOH (149) (254)

(oc)

Isodecanol, Mixed Isomers 220 0.8 5.5 428 No 2 0 1 0

C10H21OH (104) (220)

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Isoevgenol >212 1.1 514 No 5 0 1 0

(CH3CHCH)C6H3OHOCH3 (>100) (268)

(1-Hydroxy-2-Methoxy-4-Propenylbenzene)

Isoheptane <0 1.0 6.0 0.7 3.45 194 No 1 0 3 0

(CH3)2CHC4H9 (-18) (90)

(2-Methylhexane)(Ethylisobutylmethane)

Isoheptane, Mixed Isomers <0 428 1.0 6.0 0.7 176-195 No 1 1 3 0

(<-18) (220) (80-91)

Isohexane < - 20 507 1.0 7.0 0.7 134-142 No 1 1 3 0

(Mixture of Hexane Isomers) (< - 29) (264) (57-61)

tert-Isohexyl Alcohol 115 0.77 3.53 252 2 0

C2H5(CH3)C(OH)C2H5 (46) (122)

(3-Methyl-3-Pentanol)

Isooctane 40 784 0.7 3.94 210 No 1 0 3 0

(CH3)2CHCH2C(CH3)3 (4.5) (418) (99)

(2,2,4-Trimethylpentane) (oc)

Isooctanoic Acid 270 738 0.9 5.0 428 No 2 0 1 0

(Mixed isomers) (132) (392) (220)

C6H15COOH (oc) Decomposes

Isooctenes <20 0.7 3.87 190-200 1 0 3 0

C8H16 (-7) (88-93)

Isooctyl Alcohol 180 0.8 83-91 No 5 0 2 0

C7H15CH2OH (82) (182-195)

(Isooctanol) (oc)

Isooctyl Nitrate 205 1.0- 106-109 No 1

C8H17NO3 (96) (41-43)

(oc) @ 1 mm

Isooctyl Vinyl Ether See Vinyl Isooctyl Ether.

Isopentaldehyde 48 0.8 2.97 250 Slight 5 2 3 0

(CH3)2CHCH2CHO (9) (121) 1

(oc)

Isopentane < - 60 788 1.4 7.6 0.6 82 No 1 1 4 0

(CH3)2CHCH2CH3 (< -51) (420) (28)

(2-Methylbutane)

(Ethyl Dimethyl Methane)

Isopentanoic Acid 781 0.9 361 No 1 0

(CH3)2CHCH2COOH (416) (183)

(Isovaleric Acid)

Isophorone 184 860 0.8 3.8 0.9 419 Slight 2 2 0

COCHC(CH3)CH2C(CH3)2CH2 (84) (460) (215)

Isophthaloyl Chloride 356 1.4 6.9 529 No 2 1 0

C6H4(COCl)2 (180) (276)

(m-Phthalyl Dichloride) (oc)


Isoprene - 65 743 1.5 8.9 0.7 2.4 93 No 1 2 4 2

CH2:C(CH3)CH:CH2 (- 54) (395) (34)

(2-Methyl-1,3-Butadiene)

Isopropanol See Isopropyl Alcohol.

Isopropanolamine See 1-Amino-2-Propanol.

Isopropenyl Acetate 60 808 0.9 3.5 207 Slight 5 2 3 0

CH3COOC(CH3):CH2 (16) (431) (97) 1

(1-Methylvinyl Acetate)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Isopropenyl Acetylene <19 0.7 2.3 92 Slight 1 2 4 2

CH2:C(CH3)C:CH (< - 7) (33) 5

(oc)

2-Isopropoxypropane See Isopropyl Ether.

3-Isopropoxypropionitrile 155 0.9 3.9 149 Slight 5 1 2 1

(CH3)2CHOCH2CH2CN (68) (65)

@ 10 mm

Isopropyl Acetate 35 860 1.8 @ 8 0.9 3.5 194 Slight 5 1 3 0

(CH3)2CHOOCCH3 (2) (460) 100 (90) 1

(38)

Isopropyl Alcohol 53 750 2.0 12.7 @ 0.8 2.1 181 Yes 5 1 3 0

(CH3)2CHOH (12) (399) 200 (83) 1

(Isopropanol) (93)

(Dimethyl Carbinol)

(2-Propanol) 57

87.9% iso (14)

Isopropylamine -35 756 0.7 2.0 89 Yes 5 3 4 0

(CH3)2CHNH2 (-37) (402) (32) 1

(oc)

Isopropylbenzene See Cumene.

Isopropyl Benzoate 210 1.0+ 426 No 1 1

C6H5COOCH(CH3)2 (99) (219)

Isopropyl Bicyclohexyl 255 446 0.5 @ 4.1 @ 0.9 530-541 2 0 1 0

C15H28 (124) (230) 302 400 (277-283)

(150) (204)

2-Isopropylbiphenyl 285 815 0.5 @ 3.2 @ 1.0- 518 2 0 1 0

C15H16 (141) (435) 347 392 (270)

(175) (200)

Isopropyl Carbinol See Isobutyl Alcohol.

Isopropyl Chloride -26 1100 2.8 10.7 0.9 2.7 95 Very 1 2 4 0

(CH3)2CHCl (-32) (593) (35) slight

(2-Chloropropane)

Isopropylcyclohexane 541 0.8 310 1 0

(CH3)2CHC6H11 (283) (154.5)

(Hexahydrocumene)

(Normanthane)

Isopropylcyclohexylamine 93 0.8 4.9 No 1 3 3 0

C6H11NHCHC2H6 (34)

(oc)

Isopropyl Ether -18 830 1.4 7.9 0.7 3.5 156 Very 5 2 3 1

(CH3)2CHOCH(CH3)2 (-28) (443) (69) slight 1

(2-Isopropoxypropane)

(Diisopropyl Ether) Note: See Hazardous Chemicals Data.

Isopropylethylene See 3-Methyl-1-Butene.

Isopropyl Formate 22 905 0.9 3.0 153 Slight 2 3 0

HCOOCH(CH3)2 (-6) (485) (67)

(Isopropyl Methanoate)

4-Isopropylheptane 491 0.87 3.04 155 0 2 0

C3H7CH(C3H7)C3H7 (255) (68)

(m-Dihydroxybenzene)

Isopropyl-2-Hydroxypropanoate See Isopropyl Lactate.

Isopropyl Lactate 130 1.0- 4.2 331-334 Yes 5 2 2 0

CH3CHOHCCOCH(CH3)2 (54) (166-168)

(Isopropyl-2-Hydroxypropionate) (oc)

Isopropyl Methanoate See Isopropyl Formate.

4-Isopropyl-1-Methyl Benzene See p-Cymene.

Isopropyl Vinyl Ether See Vinyl Isopropyl Ether.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Isovalerone See Diisobutyl Ketone.

Jet Fuels 110-150 400-550 0 2 0

Jet A and Jet A-1 (43-66) (204-288)

Jet Fuels -10 to+30

1 3 0

Jet B (-23 to -1)

Jet Fuels -10 to+30

464 1.3 8.0 1 3 0

JP-4 (-23 to -1) (240)

Jet Fuels 95-145 475 0 2 0

JP-5 (35-63) (246)

(approx.)

Jet Fuels 100 446 0.6 3.7 0.8 <1 250 No

JP-6 (38) (230) (121)

(oc)

Katchung Oil See Peanut Oil (cooking).

Kerosene See Fuel Oil No. 1.

Kerosene, Deodorized See Ultrasene.

Lactonitrile 171 0.98 2.45 361 Yes 4 2 1

CH3CH(OH)CN (77) (183)

Lanolin 460 833 < 1 No 2 0 1 0

(Wool Grease) (238) (445)

Lard Oil (Commercial or Animal) 395 833 <1 No 2 0 1 0

No. 1 (202) (445)

440

(227)

Lard Oil (Pure) 500 0.9 No 2 0 1 0

No. 2 (260)

Mineral 419

(215)

404

(207)

Lauryl Alcohol See 1-Dodecanol.

Lauryl Bromide 291 1.0+ 356 No 2 1 1 0

CH3(CH2)10CH2Br (144) (180)

(Dodecyl Bromide) @ 45 mm

Lauryl Mercaptan See 1-Dodecanethiol.

Linalool (Ex Bois de Rose;Synthetic)

160 0.9 383-390 No 5 2 0

(CH3)2C:CHCH2CH2C(CH3)-OHCA:CH2

(71) (195-199)

(3,7-Dimethyl-1,6-Octadiene-3-01)

Linseed Oil, Raw 432 650 0.9 600+ No 2 0 1 0

(222) (343) (316+)

Boiled 403

(206)

Liquid Camphor See Camphor Oil (light).

Lubricating Oil, Mineral 300-450 500-700 <1 680 No 2 0 1 0

(Paraffin Oil, includes Motor Oil) (149-232)

(260-371)

(360)

Lubricating Oil, Spindle 169 478 <1 No 0 2 0

(Spindle Oil) (76) (248)

Lubricating Oil, Turbine 400 700 <1 No 2 0 1 0

(Turbine Oil) (204) (371)

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Lynalyl Acetate (Ex Bois deRose; Synthetic)

185 0.9 226-230 No 5 2 0

(CH3)2C:CHCH2CH2C(-OOCCH3)CH:CH2

(85) (108-110)

(Bergamol)

Maleic Anhydride 215 890 1.4 7.1 0.9 396 Slight 5 3 1 1

(COCH)2O (102) (477) (202) 2



Marsh Gas See Methane.

Menhaden Oil 435 828 0.9 No 2 0 1 0

(Pogy Oil) (224) (442)

2-Mercaptoethanol 165 1.1 2.7 315 Yes 5 2 2

HSCH2CH2OH (74) (157)

(oc)

Mesitylene See 1,3,5-Trimethylbenzene.

Mesityl Oxide 87 652 1.4 7.2 0.9 3.4 266 Slight 1 3 3 0

(CH3)2CCHCOCH3 (31) (344) (130) 5


Metaldehyde 97 subl. No 1 1 3 1

(C2H4O)4 (36) 233-240

(112-116)

α-Methacrolein See 2-Methylpropenal.

Methacrylic Acid 171 154 1.6 8.8 1.0+ 2.97 316 Yes 5 3 2 2

CH2:C(CH3)COOH (77) (68) (158)

(oc)

Note: Polymerizes.


Methacrylonitrile 34 2 6.8 0.8 2.3 194 Slight 2 3 2

C4H5N (1.1) (90)

(TCC)

Methallyl Alcohol 92 0.9 2.5 237 Slight 1 2 3 0

CH2C(CH3)CH2OH (33) (114) 5

Methallyl Chloride 11 3.2 8.1 0.9 3.1 162 No 1 2 3 1

CH2C(CH3)CH2Cl (-12) (72) 5

Methane Gas 999 5.0 15.0 0.6 -259 No 6 1 4 0

CH4 (537) (-162)

(Marsh Gas)

Methanol See Methyl Alcohol.

Methanethiol See Methyl Mercaptan.

Methox See Methoxy Ethyl Phthalate.

o-Methoxybenzaldehyde 104 1.1 275 No 2 2 1 0

CH3OC6H4CHO (40) (135)

(o-Anisaldehyde) (oc)

Methoxybenzene See Anisole.

3-Methoxybutanol 165 0.9 3.6 322 Yes 5 1 2 0

CH3CH(OCH3)CH2CH2OH (74) (161)

(oc)

3-Methoxybutyl Acetate 170 1.0- 5.0 275-343 Slight 5 1 2 0

CH3OCH(CH3)CH2CH2OOCCH3 (77) (135-173)

(Butoxyl)

3-Methoxybutyraldehyde 140 0.94 3.52 262 0 2 0

CH3CH(OCH3)CH2CHO (60) (128)

(Aldol Ether)

2-Methoxyethanol See Ethylene Glycol Monomethyl Ether.

2-Methoxyethyl Acrylate 180 1.01 4.49 142 0 2 0

C2H3COOC2H4OCH3 (82) (61)

(oc) @ 17 mm




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Methoxy Ethyl Phthalate 275 1.2 376-412 2 0 1 0

(Methox) (135) (191-211)

3-Methoxypropionitrile 149 0.92 2.94 320 4 2 1

CH3OC2H4CN (65) (160)

(oc)

3-Methoxypropylamine 90 0.86 3.07 241 2 3 0

CH3OC3H6NH2 (32) (116)

Methoxy Triglycol 245 1.0+ 480 Yes 5 0 1 0

CH3O(C2H4O)3H (118) (249) 2

(Triethylene Glycol, (oc)

Methyl Ether)

Methoxytriglycol Acetate 260 1.1 266 Yes 2 0 1 0

CH3COO(C2H4O)3CH3 (127) (130) 5

(oc)

Methyl Abietate 356 1.0+ 680-689 No 2 0 1 0

C19H29COOCH3 (180) (360-365)

(Abalyn) (oc) Decomposes

Methyl Acetate 14 850 3.1 16 0.9 2.8 140 Yes 1 1 3 0

CH3COOCH3 (-10) (454) (60) 5

(Acetic Acid Methyl Ester)

(Methyl Acetic Ester)

Methyl Acetic Ester See Methyl Acetate.

Methyl Acetacetate 170 536 1.1 4.0 338 Yes 5 2 2 0

CH3CO2CH2COCH3 (77) (280) (170)

p-Methyl Acetophenone 205 1.0- 439 No 5 0 1 0

CH3C6H4COCH3 (96) (226)

(Methyl para-Tolyl Ketone)

(p-Acetotoluene)

Methylacetylene See Propyne.

α-Methylacrolein See 2-Methylpropenal.

Methyl Acrylate 27 875 2.8 25 1.0- 3.0 176 Very 1 2 3 2

CH2:CHCOOCH3 (-3) (468) (80) slight

(oc)

Note: Polymerizes.


Methylal -26 459 2.2 13.8 0.9 2.6 111 Yes 1 2 3 2

CH3OCH2OCH3 (-32) (237) (44) 5

(Dimethoxymethane) (Formal) (oc)

Methyl Alcohol 52 867 6.0 36 0.8 1.1 147 Yes 1 1 3 0

CH3OH (11) (464) (64) 5

(Methanol)

(Wood Alcohol)

(Columbian Spirits)

Methylaluminum Sesquibromide Note: Ignites spontaneously in air. 3 3

(CH3)3Al2Br3 Do not use water, foam orhalogenated extinguishing

agents.

Methylaluminum Sesquichloride Note: Ignites spontaneously in air. 3 3

(CH3)3Al2Cl3 Do not use water, foam orhalogenated extinguishing

agents.

Methylamine Gas 806 4.9 20.7 1.0 21 Yes 6 3 4 0

CH3NH2 (430) (-6)


2-(Methylamino) Ethanol See N-Methylethanolamine.

Methylamyl Acetate See Hexyl Acetate.

Methylamyl Alcohol See Methyl Isobutyl Carbinol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Methyl Amyl Ketone 102 740 1.1 @ 7.9 @ 0.8 3.9 302 Slight 5 1 2 0

CH3CO(CH2)4CH3 (39) (393) 151 250 (150)

2-Heptanone (66) (121)

2-Methylaniline See o-Toluidine.

4-Methylaniline See p-Toluidine.

Methyl Anthranilate >212 1.2 275 Slight 5 0 1 0

H2NC6H4CO2CH3 (>100) @ 15 mm

(Methyl-ortho-Amino Benzoate) (135)

(Nevoli Oil, Artificial)

Methylbenzene See Toluol.

Methyl Benzoate 181 1.1 4.7 302 No 3 0 2 0

C6H5COOCH3 (83) (150)

(Niobe Oil)

α-Methylbenzyl Alcohol See Phenyl Methyl Carbinol.

α-Methylbenzylamine 175 1.0- 4.2 371 Slight 5 2 2 0

C6H5CH(CH3)NH2 (79) (188)

(oc)

α-Methylbenzyl Dimethyl Amine 175 0.9 5.2 384 Slight 5 2 2 0

C6H5CH(CH3)N(CH3)2 (79) (196)

(oc)

α-Methylbenzyl Ether 275 1.0 548 No 2 2 1 0

C6H5CH(CH3)OCH(CH3)C6H5 (135) (287) 5

(oc)

2-Methylbiphenyl 280 936 1.0+ 492 2 0

C6H5C6H4CH3 (137) (502) (255)

(oc)

Methyl Borate <80 0.9 3.6 156 Decomposes 2 3 1

B(OCH3)3 (<27) (69)

(Trimethyl Borate)

Methyl Bromide Practi 999 10 16.0 1.7 3.3 38.4 No 3 1 0

CH3Br cally (537) (4)

(Bromomethane) non-flammable


2-Methyl-1,3-Butadiene See Isoprene

2-Methylbutane See Isopentane

3-Methyl-2-Butanethiol 37 0.85 3.59 230 No 5 2 3 0

C5H11SH (3) (110) 1

(sec-Isoamyl Mercaptan) (oc)

2-Methyl-1-Butanol 122 725 0.8 3.0 262 Slight 5 2 2 0

CH3CH2CH(CH3)CH2OH (50) (385) (128)

(oc)

2-Methyl-2-Butanol 67 819 1.2 9.0 0.8 3.0 215 Slight 5 1 3 0

CH3CH2(CH3)2COH (19) (437) (102) 1

(tert-Isoamyl Alcohol)

(Dimethyl Ethyl Carbinol)

3-Methyl-1-Butanol See Isoamyl Alcohol.

3-Methyl-1-Butanol Acetate See Isoamyl Acetate.

2-Methyl-1-Butene <20 0.7 2.4 88 No 1 2 4 0

(Technical Grade) (< - 7) (31)

CH2:C(CH3)CH2CH3

2-Methyl-2-Butene <20 0.7 2.4 101 Slight 1 2 3 0

(CH3)2C:CCHCH3 (< -7) (38) 5

(Trimethylethylene)

3-Methyl-1-Butene <20 689 1.5 9.1 0.6 2.4 68 No 1 2 4 0

(CH3)2CHCH:CH2 (< -7) (365) (20)

(Isopropylethylene)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

N-Methylbutylamine 55 0.7 3.0 196 Yes 1 3 3 0

CH3CH2CH2CH2NHCH3 (13) (91) 5

(oc)

2-Methyl Butyl Ethanoate See Isoamyl Acetate.

Methyl Butyl Ketone 77 795 8 0.8 3.5 262 Slight 1 2 3 0

CH3CO(CH2)3CH3 (25) (423) (128) 5

(2-Hexanone)

3-Methyl Butynol 77 0.9 2.9 218 Yes 1 2 3 0

(CH3)2C(OH)C:CH (25) (103) 5

(oc)

2-Methylbutyraldehyde 49 0.8 2.97 198-199 No 5 2 3 0

CH3CH2CH(CH3)CHO (9) (92-93) 1

(oc)


Methyl Butyrate 57 0.9 3.5 215 Slight 1 2 3 0

CH3OOCCH2CH2CH3 (14) (102) 5

Methyl Carbonate 66 1.1 3.1 192 Slight 1 2 3 1

CO(OCH3)2 (19) (89) 5

(Dimethyl Carbonate) (oc)

Methyl Cellosolve ~111 1.7 8.2 1.0 4.07 292 Yes 0 2 0

Acetate (~44) (144)

CH3COOC2H4OCH3

(2-Methoxyethyl Acetate)

Methyl Chloride -50 1170 8.1 17.4 1.8 -11 Slight 6 2 4 0

CH3Cl (632) (-24)

(Chloromethane) Note: See Hazardous Chemicals Data.

Methyl Chloroacetate 135 7.5 18.5 1.2 3.8 266 Very 2 2 1

CH2ClCOOCH3 (57) (130) slight

(Methyl Chloroethanoate) (oc)

Methyl Chloroethanoate See Methyl Chloroacetate.

Methyl para-Cresol 140 1.0- 4.21 5 2 0

CH3C6H4OCH3 (60)

(p-Methylanisole)

(p-Cresyl Methyl Ether,p-Methoxy Toluene)

Methyl Cyanide See Acetonitrile.

Methylcyclohexane 25 482 1.2 6.7 0.8 3.4 214 No 1 2 3 0

CH2(CH2)4CHCH3 (-4) (250) (101)

(Cyclohexylmethane)(Hexahydroxytoluene)

2-Methylcyclohexanol 149 565 0.9 3.9 329 Slight 5 2 0

C7H13OH (65) (296) (165)

3-Methylcyclohexanol ~158 563 0 2 0

CH3C6H10OH (~70) (295)

4-Methylcyclohexanol 158 563 0.9 3.9 343 Slight 5 2 0

C7H13OH (70) (295) (173)

Methylcyclohexanone 118 0.9 3.9 325 No 2 0

C7H12O (48) (163)

4-Methylcyclohexene 30 0.8 3.3 217 No 1 1 3 0

CH:CHCH2CH(CH3)CH2CH2 (-1) (103)

(oc)

Methylcyclohexyl Acetate 147 0.9 351-381 1 2 0

C9H16O2 (64) (177-194)

Methyl Cyclopentadiene 120 833 1.3 @ 7.6 @ 0.9 163 1 2 1

C6H8 (49) (445) 212 212 (73)

(100) (100)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Methylcyclopentane <20 496 1.0 8.35 0.8 2.9 161 No 1 2 3 0

C6H12 (< - 7) (258) (72)

2-Methyldecane 437 0.74 5.39 374 0 2 0

CH3(CH2)7CH(CH3)2 (225) (190)

Methyldichlorosilane 15 >600 6.0 55 1.1 3.97 106 Yes 1 3 3 2

CH3HSiCl2 (-9) (316) (41)


N-Methyldiethanolamine 260 1.0+ 464 Yes 2 1 1 0

CH3N(C2H4OH)2 (127) (240) 5

(oc)

1-Methyl-3,5-Diethyl-benzene 851 0.86 5.12 394 0 2 0

(CH3)C6H3(C2H5)2 (455) (201)

(3,5-Diethyltoluene)

Methyl Dihydroabietate 361 1.0+ 689-698 2 1 1 0

C19H31COOCH3 (183) (365-370)

Methylene Chloride None 1033 13 23 1.3 2.9 104 Slight 2 1 0

CH2Cl2 (556) (40)

(Dichloromethane)


Methylenedianiline 428 1.1 748-750 Slight 2 3 1 0

H2NC6H4CH2C6H4NH2 (220) (398-399)

(MDA) @ 78 mm

(p,p -Diaminodi-Phenylmethane)


Methylene Diisocyanate 185 1 2 1

CH2(NCO)2 (85)

(oc)

Methylene Oxide See Formaldehyde.

N-Methylethanolamine 165 0.9 2.6 319 Yes 5 2 2 0

CH3NHCH2CH2OH (74) (159)

(2-(Methylamino) Ethanol) (oc)

Methyl Ether Gas 662 3.4 27.0 1.6 -11 Yes 6 2 4 1

(CH3)2O (350) (-24)

(Dimethyl Ether)

(Methyl Oxide)

Methyl Ethyl Carbinol See sec-Butyl Alcohol.

2-Methyl-2-Ethyl-1,3-Dioxolane 74 0.9 4.0 244 No 1 2 3 0

(CH3)(C2H5)COCH2CH2O (23) (118)

(oc)

Methyl Ethylene Glycol See Propylene Glycol.

Methyl Ethyl Ether -35 374 2.0 10.1 0.7 2.1 51 Yes 1 2 4 1

CH3OC2H5 (-37) (190) (11) 5

(Ethyl Methyl Ether) Note: See Hazardous Chemicals Data.

2-Methyl-4-Ethylhexane < 70 536 ~0.7 0.72 4.43 273 0 3 0

(CH3)2CHCH2CH(C2H5)2 (<21) (280) (134)

(4-Ethyl-2-Methylhexane)

3-Methyl-4-Ethylhexane 75 0.72 4.43 284 0 3 0

C2H5CH(CH3)CH(C2H5)2 (24) (140)

(3-Ethyl-4-Methylhexane)

Methyl Ethyl Ketone 16 759 1.4 @ 11.4 @ 0.8 2.5 176 Yes 1 1 3 0

C2H5COCH3 (-9) (404) 200 200 (80) 5

(2-Butanone) (93) (93)

(Ethyl Methyl Ketone)

Methyl Ethyl Ketoxime 156-170 0.9 3.0 306-307 Slight 5 2 0

CH3C(C2H5):NOH (69-77) (152-153)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2-Methyl-3-Ethylpentane <70 860 0.72 3.94 241 0 3 0

(CH3)2CHCH(C2H5)2 (<21) (460) (116)

(3-Ethyl-2-Methylpentane)

2-Methyl-5-Ethyl-piperidine 126 0.8 4.4 326 Slight 5 2 2 0

NHCH(CH3)CH2CH2CH(C2H5)CH2 (52) (163)

(oc)

2-Methyl-5-Ethylpyridine 155 1.1 6.6 0.9 4.2 353 Slight 5 3 2 0

N:C(CH3)CH:CHC(C2H5):CH (68) (178)

(oc)

Methyl Eugenol 210 1.0+ 196-203 No 5 0 1 0

(CH3O)2C6H3CH2CH:CH2 (99) (91-95)

(4-Allyl-1,2-Dimethoxy-benzene)

(4-Allyl Veratrole)

(1,2-Dimethoxy-4-Allyl-benzene)

(Eugenyl Methyl Ether)

Methyl Formate -2 840 4.5 23 1.0- 2.1 90 Yes 1 2 4 0

CH3OOCH (-19) (449) (32) 5

(Formic Acid, Methyl Ester)

(Methyl Methanoate) Note: See Hazardous Chemicals Data.

2-Methylfuran -22 0.9 144-147 No 1 2 3 1

C4H3OCH3 (-30) (62-64)

(Sylvan)

Methyl Glycol Acetate 111 4.6 1 2 0

CH2OHCHOHCH2CO2CH3 (44)

(Propylene Glycol Acetate)

Methyl Heptadecyl Ketone 255 329 No 2 0 1 0

C17H35COCH3 (124) (165)

Note: Melting point 127 (53) @ 3 mm

Methylheptenone 135 0.9 4.35 343-345 No 5 1 2 0

(CH3)2C:CH(CH2)2COCH3 (57) (173-174)

(6-Methyl-5-Hepten-2-one)

Methyl Heptine Carbonate 190 0.9 5 2 0

CH3(CH2)4C:CCOOCH3 (88)

(Methyl 2-Octynoate)

Methyl Heptyl Ketone 140 680 0.9 @ 5.9 @ 0.8 @ 4.9 361-383 No 0 2 0

C7H15COCH3 (60) (360) 180 313 86 (183-195)

(5-Methyl-2-Octanone) (82) (156) (30)

2-Methylhexane <0 536 0.68 3.46 194 0 3 0

(CH3)2CH(CH2)3CH3 (< - 18) (280) (90)

3-Methylhexane 25 536 0.69 3.46 198 0 3 0

CH3CH2CH(CH3)CH2CH2CH3 (-4) (280) (92)

Methyl Hexyl Ketone 125 0.8 4.41 344 No 5 0 2 0

CH3COC6H13 (52) (173.5)

(2-Octanone)

(Octanone)

Methylhydrazine 17 382 2.5 92 0.9 1.6 190 Slight 1 3 3

CH3NHNH2 (-8) (194) (88) 5

Methyl-3-Hydroxybutyrate 180 1.1 4.1 347 Yes 5 1 2 0

CH3CHOHCH2COOCH3 (82) (175)

(oc)

Methyl Ionone >212 0.9 291 No 5 0 1 0

C14H22O (>100) (144)

(Irone) @ 16 mm

Methyl Isoamyl Ketone 96 375 1.0 @ 8.2 @ 0.8 3.9 294 No 1 2 0

CH3COCH2CH2CH(CH3)2 (36) (191) 200 200 (146)

(93) (93)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Methyl Isobutyl Carbinol 106 1.0 5.5 0.8 266-271 Slight 5 2 2 0

CH3CHOHCH2CHCH3CH3 (41) (130-133)

(1,3-Dimethylbutanol)

(4-Methyl-2-Pentanol)

(Methylamyl Alcohol)

Methylisobutylcarbinol Acetate See 4-Methyl-2-Pentanol Acetate.

Methyl Isobutyl Ketone 64 840 1.2 @ 8.0 @ 0.8 3.5 244 Slight 5 2 3 0

CH3COCH2CH(CH3)2 (18) (448) 200 200 (118) 1

(Hexone) (93) (93)

(4-Methyl-2-Pentanone)

Methyl Isopropenyl Ketone 1.8 9.0 2.9 208 2 0

CH2COC:CH2(CH3) (98)

Methyl Isocyanate 19 994 5.3 26 1.0- 1.97 102 Yes 5 2 3 3

CH3NCO (-7) (534) (39)

(Methyl Carbonimide)

Methyl Iso Eugenol >212 1.1 504-507 No 5 0 1 0

CH3CH:CHC6H3(OCH3)2 (>100) (262-264)

(Propenyl Guaiacol)

Methyl Lactate 121 725 2.2 @ 1.1 3.6 293 Yes 1 2 0

CH3CHOHCOOCH3 (49) (385) 212 (145) Decomposes

(100)

Methyl Mercaptan 3.9 21.8 0.9 1.7 42.4 Yes 5 2 4 0

CH3SH (6)

(Methanethiol)

β-Methyl Mercapto-propionaldehyde

142 491 1.03 3.60 ~329 2 0

CH3SC2H4CHO (61) (255) (~165)

(3-(Methylthio) Propionaldehyde)

Methyl Methacrylate 50 1.7 8.2 0.9 3.6 212 Very 1 2 3 2

CH2:C(CH3)COOCH3 (10) (100) slight

(oc)

Note: Polymerizes.


Methyl Methanoate See Methyl Formate.

4-Methylmorpholine 75 0.9 3.5 239 Yes 1 2 3 0

C2H4OC2H4NCH3 (24) (115) 5

1-Methylnaphthalene 984 1.0+ 472 No 2 2 0

C10H7CH3 (529) (244)

Methyl Nonyl Ketone 192 0.8@ 5.9 433 No 0 2 0

C9H19COCH3 (89) 86 (223)

(30)

Methyl Oxide See Methyl Ether.

Methyl Pentadecyl Ketone 248 313 No 2 0 1 0

C15H31COCH3 (120) (156)

@ 3 mm

2-Methyl-1,3-Pentadiene < - 4 0.72 2.83 169 0 3 0

CH2:C(CH3)CH:CHCH3 (< -20) (76)

4-Methyl-1,3-Pentadiene -30 0.7 168 No 1 0 3 1

CH2:CHCH2:C(CH3)2 (-34) (76)

Methylpentaldehyde 68 0.8 3.5 243 Very 1 2 3 1

CH3CH2CH2C(CH3)HCHO (20) (117) slight

(Methyl Pentanal)(oc)

Methyl Pentanal See Methylpentaldehyde.

2-Methylpentane <20 583 1.2 7.0 0.7 3.0 140 No 1 1 3 0

(CH3)2CH(CH2)2CH3 (<-7) (306) (60)

(Isohexane)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

3-Methylpentane <20 532 1.2 7.0 0.7 3.0 146 No 1 1 3 0

CH3CH2CH(CH3)CH2CH3 (<-7) (278) (63)

2-Methyl-1,3-Pentanediol 230 1.0- 419 2 2 1 0

CH3CH2CH(OH)CH(CH3)CH2OH (110) (215)

2-Methyl-2,4-Pentanediol 205 0.92 4.07 385 Yes 0 1 0

(CH3)2C(OH)CH2CH(OH)CH3 (96) (196)

(oc)

2-Methylpentanoic Acid 225 712 0.9 4.0 381 No 2 0 1 0

C3H7CH(CH3)COOH (107) (378) (194)

(oc)

2-Methyl-1-Pentanol 129 590 1.1 9.65 0.8 3.5 298 No 0 2 0

CH3(CH2)2CH(CH3)CH2OH (54) (310) (148)

4-Methyl-2-Pentanol See Methyl Isobutyl Carbinol.

4-Methyl-2-Pentanol 110 660 0.9 5.83 0.9 5.0 295 Very 1 2 0

Acetate (43) (349)

}(146) slight

CH3COOCH(CH3)CH2CH(CH3)2 (oc) @ 212

(Methylisobutylcarbinol Acetate) (100)

4-Methyl-2-Pentanone See Methyl Isobutyl Ketone.

2-Methyl-1-Pentene <20 572 0.7 2.9 143 1 1 3 0

CH2:C(CH3)CH2CH2CH3 (<-7) (300) (62)

4-Methyl-1-Pentene <20 572 0.7 2.9 129 1 1 3 0

CH2:CHCH2CH(CH3)2 (<-7) (300) (54)

2-Methyl-2-Pentene <20 0.7 2.9 153 1 1 3 0

(CH3)2C:CHCH2CH3 (<-7) (67)

4-Methyl-2-Pentene <20 0.7 133-137 1 1 3 0

CH3CH:CHCH(CH3)2 (<-7) (56-58)

3-Methyl-1-Pentynol 101 0.9 3.4 250 Yes 5 1 2 0

(C2H5)(CH3)C(OH)C:CH (38) (121)

(oc)

o-Methyl Phenol See o-Cresol.

Methyl Phenylacetate 195 1.1 424 No 5 0 2 0

C6H5CH2COOCH3 (91) (218)

Methylphenyl carbinol 200 1.0+ 399 Slight 5 0 2 0

C6H5CH(CH3)OH (93) (204)

(α-Methylbenzyl Alcohol)(Styralyl Alcohol)(sec-Phenethyl Alcohol)

Methyl Phenyl Carbinyl Acetate 195 1.0+ No 5 0 2 0

C6H5CH(CH3)OOCH3 (91)

(α-Methyl-Benzyl Acetate)(Styralyl Acetate)(sec-Phenylethyl Acetate)(Phenyl Methylcarbinyl Acetate)

Methyl Phenyl Ether See Anisole

Methyl Phthalyl Ethyl 380 1.2 590 No 2 2 1 0

Glycolate (193) (310)

CH3COOC6H4COOCH2COOC2H5 (oc)

1-Methyl Piperazine 108 0.9 3.5 280 Yes 5 2 2 0

CH3NCH2CH2NHCH2CH2 (42) (138)

(oc)

2-Methylpropanal See Isobutyraldehyde.

2-Methylpropane See Isobutane.

2-Methyl-2-Propanethiol <-20 0.8 3.1 149-153 No 1 2 3 0

(CH3)3CSH (<-29) (65-67)

(tert-Butyl Mercaptan)

2-Methyl Propanol-1 See Isobutyl Alcohol.

2-Methyl-2-Propanol See tert-Butyl Alcohol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2-Methylpropenal 35 0.8 2.4 154 Yes 1 3 3 2

CH2:C(CH3)CHO (2) (68) 5

(Methacrolein) (oc)

(α-Methyl Acrolein)

2-Methylpropene Gas 869 1.8 9.6 1.9 20 No 6 1 4 0

CH2:C(CH3)CH3 (465) (-7)

(γ-Butylene)

(Isobutylene)

Methyl Propionate 28 876 2.5 13 0.9 3.0 176 No 1 1 3 0

CH3COOCH2CH3 (-2) (469) (80)

Methyl Propyl Acetylene <14 0.73 2.83 185 3

CH3C2H4CCCH3 (<-10) (85)

(2-Hexyne)

Methyl Propyl Carbinol 105 0.8 3.0 247 No 0 2 0

CH3CHOHC3H7 (41) (119)

(2-Pentanol)

Methylpropylcarbinylamine See sec-Amylamine.

Methyl n-Propyl Ether <-4 0.91 2.56 102 0 3 0

CH3OC3H7 (<-20) (39)

Methyl Propyl Ketone 45 846 1.5 8.2 0.8 3.0 216 Slight 1 2 3 0

CH3COC3H7 (7) (452) (102) 5

(2-Pentanone)

2-Methylpyrazine 122 1.02 3.25 2 2 0

N:C(CH3)CH:NCH:CH (50)

(oc)

2-Methyl Pyridine See 2-Picoline.

Methylpyrrole 61 0.9 2.8 234 No 1 2 3 1

N(CH3)CH:CHCH:CH (16) (112)

Methylpyrrolidine 7 0.8 2.9 180 Slight 5 2 3 1

CH3NC4H8 (-14) (82) 1

1-Methyl-2-Pyrrolidone 204 655 1.0+ 3.4 396 Yes 5 2 1 0

CH3NCOCH2CH2CH2 (96) (346) (202)

(n-Methyl-2-Pyrrolidone)(oc)

Methyl Salicylate 205 850 1.2 432 No 2 1 1 0

HOC6H4COOCH3 (96) (454) (222)

(Oil of Wintergreen)

(Gaultheria Oil)

(Betula Oil)

(Sweet-Birch Oil)

Methyl Stearate 307 0.9 421 No 2 0 1 0

C17H35COOCH3 (153) (216)

α-Methylstyrene 129 1066 1.9 6.1 0.9 329-331 No 1 2 1

1-Methylethenyl Benzine (54) (574) (165-166)

1-Methyl-1-phenylethene

Methylstyrene See Vinyl Toluene.

CH2CHC6H4CH3

(Vinyl Toluene)

Methyl Sulfate See Dimethyl Sulfate.

2-Methyltetrahydrofuran 12 0.9 3.0 176 Slight 1 2 3 0

C4H7OCH3 (-11) (80) 5

Methyl Toluene Sulfonate 306 315 No 2 2 1 0

CH3C6H4SO3CH3 (152) (157)

(oc) @ 8 mm





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Methyltrichlorosilane 15 >760 7.6 >20 1.29 5.16 151 3 3 2

CH3SiCl3 (-9) (>404) (66)

(Methyl Silico Chloroform)

(Trichloromethylsilane)

Methyl Undecyl Ketone 225 0.8 248 No 2 1 1 0

C11H23COCH3 (107) (120)

(2-Tridecanone)

2-Methylvaleraldehyde 62 390 0.8 3.45 240 5 1 3 0

C6H12O (17) (199) (116) 1

1-Methylvinyl Acetate See Isopropenyl Acetate.

Methyl Vinyl Ether See Vinyl Methyl Ether.

Methyl Vinyl Ketone 20 915 2.1 15.6 2.4 177 1 3 3 2

CH3COCH:CH2 (-7) (491) (81)

Mineral Oil 380 0.8-0.9 680 No 2 0 1 0

(193) (360)

(oc)

Mineral Seal Oil Typical 275 0.8 480-680 No 0 2 0

(Signal Oil) (135) (249-360)

(oc)

Mineral Spirits 104 473 0.8 @ 0.8 3.9 300 No 0 2 0

Mineral Spirits, 360° (40) (245) 212 (149)

End Point (182) (100)

Mineral Wax See Wax, Ozocerite.

Monochlorobenzene See Chlorobenzene.

Morpholine 98 555 1.4 11.2 1.0 3.0 262 Yes 5 2 3 0

OC2H4NHCH2CH2 (37) (290) (128)

(oc)

Note: Decomposes at 489 (250).


Muriatic Ether See Ethyl Chloride.

Mustard Oil 115 1.0+ 3.4 304 No 3 2 0

C3H5N:C:S (46) (151)

(Allyl Isothiocyanate)

Naphtha 49° Be-Coal Tar Type 107 531 No 2 2 0

(42) (277)

Naphtha, Petroleum See Petroleum Ether.

Naphtha, Safety Solvent See Cleaning Solvent.

Naphtha V.M. & P., 50° Flash (10) 50 450 0.9 6.7 <1 4.1 240-290 No 1 1 3 0

(10) (232) (116-143)


Naphtha V.M. & P., High Flash 85 450 1.0 6.0 <1 4.3 280-350 No 1 1 3 0

(29) (232) (138-177)


Naphtha V.M. & P., Regular 28 450 0.9 6.0 <1 212-320 No 1 1 3 0

(-2) (232) (100-160)


Naphthalene 174 979 0.9 5.9 1.1 4.4 424 No 2 2 0

C10H8 (79) (526) (218)

(White Tar) Note: Melting point 176 (80).


β-Naphthol 307 1.22 4.98 545 1 0

C10H7OH (153) (285)

(β-Hydroxy Naphthalene)

(2-Naphthol) Note: Melting point 253 (123).

1-Naphthylamine 315 1.2 572 No 2 2 1 0

C10H7NH2 (157) (300)





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Natural Gas See Gas.

Neatsfoot Oil 470 828 0.9 No 2 0 1 0

(243) (442)


Neohexane See 2,2-Dimethylbutane.

Neopentane See 2,2-Dimethylpropane.

Neopentyl Glycol 265 750 1.1 410 Yes 2 1 1 0

HOCH2C(CH3)2CH2OH (129) (399) (210)

(2,2-Dimethyl 1,3 (oc)

Propanediol)


Nickel Carbonyl <-4 2 1.32 5.89 110 4 3 3

Ni(CO)4 (<-24) (43)

Nicotine 471 0.7 4.0 1.0 5.6 475 Yes 2 4 1 0

C10H14N2 (244) (246) 5

Niobe Oil See Methyl Benzoate.

Nitric Ether See Ethyl Nitrate.

2,2’,2‘‘-Nitrilotriethanol See Triethanolamine.

1,1’,1’’-Nitrilotri-2-propanol See Triisopropanolamine.

p-Nitroaniline 390 1.44 4.77 637 3 1 3

NO2C6H4NH2 (199) (336)


Nitrobenzene 190 900 1.8 @ 1.2 4.3 412 No 3 3 2 0

C6H5NO2 (88) (482) 200 (211)

(Nitrobenzol) (93)

(Oil of Mirbane)


1,3-Nitrobenzotrifluoride 217 1.44 6.59 397 1

C6H4NO2CF3 (103) (203)

(α,α,α-Trifluoronitro-toluene) (oc)

Nitrobenzol See Nitrobenzene.

Nitrobiphenyl 290 1.2 626 No 2 2 1 0

C6H5C6H4NO2 (143) (330)

Nitrocellulose See Cellulose Nitrate.

Nitrochlorobenzene 261 1.5 457 No 2 3 1 1

C6H4ClNO2 (127) (236)



p-Nitrochlorobenzene 261 1.37 5.44 468 2 1 3

C6H4ClNO2 (127) (242)

(1-Chloro-4-Nitro-benzene)


Nitrocyclohexane 190 1.07 4.46 403 2 2 3

CH2(CH2)4CHNO2 (88) (206)

(oc) Decomposes

Nitroethane 82 778 3.4 1.1 2.6 237 Slight 4 1 3 3

C2H5NO2 (28) (414) (114) 5 Explodes on heating.


Nitroglycerine Explodes 518 1.6 502 No 2 2 4

C3H5(NO3)3 (270) (261)

(Glyceryl Trinitrate) Explodes

Nitromethane 95 785 7.3 1.1 2.1 214 Slight 1 1 3 3

CH3NO2 (35) (418) (101) 5

Note: May detonate under high temperature

and pressure conditions.





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1-Nitronaphthalene 327 1.3 579 No 2 1 1 0

C10H7NO2 (164) (304)


1-Nitropropane 96 789 2.2 1.0 3.1 268 Slight 5 1 3 1

CH3CH2CH2NO2 (36) (421) (131) May explode onheating.


2-Nitropropane 75 802 2.6 11.0 1.0- 3.1 248 Slight 5 2 3 1

CH3CH(NO2)CH3 (24) (428) (120) May explode onheating.

(sec-Nitropropane) Note: See Hazardous Chemicals Data.

sec-Nitropropane See 2-Nitropropane.

Nitrotoluene See p-Nitrotoluol.

m-Nitrotoluene 223 1.16 4.73 450 2 1 4

C6H4CH3NO2 (106) (232)


o-Nitrotoluene 223 1.16 4.73 432 2 1 4

C6H4CH3NO2 (106) (222)

Note: Melting point 25 (-4).

p-Nitrotoluene 223 1.3 461 No 2 3 1 0

NO2C6H4CH3 (106) (238)

Note: Melting point 125(52).


2-Nitro-p-toluidine 315 1.31 5.25 2 1 4

CH3C6H3(NH2)NO2 (157)


Nitrous Ether See Ethyl Nitrite.

Nonadecane >212 446 0.79 9.27 628 0 1 0

CH3(CH2)17CH3 (>100) (230) (331)


Nonane 88 401 0.8 2.9 0.7 4.4 303 No 1 0 3 0

C9H20 (31) (205) (151)

Nonane (iso) 428 0.71 4.43 290 0 3 0

C6H13CH(CH3)2 (220) (143)

(2-Methyloctane)

Nonane (iso) 428 0.72 4.43 291 0 3 0

C5H11CH(CH3)C2H5 (220) (144)

(3-Methyloctane)

Nonane (iso) 437 0.72 4.43 288 0 3 0

C4H9CH(CH3)C3H7 (225) (142)

(4-Methyloctane)

Nonene 78 0.7 4.35 270-290 No 1 0 3 0

C9H18 (26) (132-143)

(Nonylene) (oc)

Nonyl Acetate 155 0.9 6.4 378 Very 5 1 2 0

CH2COOC9H19 (68) (192) slight

Nonyl Alcohol See Diisobutyl Carbinol.

Nonylbenzene 210 0.9 468-486 No 0 1 0

C9H19C6H5 (99) (242-252)

tert-Nonyl Mercaptan 154 0.9 5.53 370-385 No 5 2 2 0

C9H19SH (68) (188-196)

(oc)

Nonylnaphthalene <200 0.9 8.8 626-653 No 0 2 0

C9H19C10H7 (<93) (330-345)

Nonylphenol 285 1.0- 559-567 Very 2 2 1 0

C6H4(C9H19)OH (141) (293-297) slight 5




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2,5-Norbornadiene -6 0.9 3.17 193 No 1 3 1

C7H8 (-21) (89)

(NBD)

Octadecane >212 441 0.78 8.73 603 0 1 0

C18H38 (>100) (227) (317)


Octadecylene α >212 482 0.79 8.71 599 0 1 0

CH3(CH2)15CH:CH2 (>100) (250) (315)

(1-Octadecene) Note: Melting point 64 (18).

Octadecyltrichlorosilane 193 1.0 716 Yes 3 2 2

C18H37SiCl3 (89) (380)

(Trichlorooctadecylsilane)

Octadecyl Vinyl Ether See Vinyl Octadecyl Ether.

Octanal See Caprylaldehyde.

Octane 56 403 1.0 6.5 0.7 3.9 258 No 1 0 3 0

CH3(CH2)6CH3 (13) (206) (126)

1-Octanethiol 156 0.85 5.04 390 No 5 2 2 0

C8H17SH (69) (199)

(n-Octyl Mercaptan) (oc)

1-Octanol See Octyl Alcohol.

2-Octanol 190 0.8 4.5 363 No 1 2 0

CH3CHOH(CH2)5CH3 (88) (184)

1-Octene 70 446 0.7 3.9 250 No 1 1 3 0

CH2:C7H14 (21) (230) (121)

(oc)

2-Octene (Mixed cis and transisomers)

70 0.7 3.9 257 No 1 1 3 0

CH3CH:CHC5H11 (21) (125)

(oc)

Octyl Acetate See 2-Ethylhexyl Acetate.

Octyl Alcohol 178 0.8 4.5 381 No 1 2 0

CH3(CH2)6CH2OH (81) (194)

(1-Octanol)

Octylamine 140 0.8 4.5 338 Slight 5 2 2 0

CH3(CH2)6CH2NH2 (60) (170)

(1-Aminooctane)

tert-Octylamine 91 1.41 4.46 284 3 0

(CH3)3CCH2C(CH3)2NH2 (33) (140)

(1, 1,3,3-Tetramethyl-butylamine) (oc)

Octyl Chloride 158 0.9 5.1 359 No 1 2 0

CH3(CH2)7Cl (70) (182)

Octylene Glycol 230 635 0.9 475 No 2 1 1 0

[CH3(CH2)2CHOH]2 (110) (335) (246)

tert-Octyl Mercaptan 115 0.8 5.0 318-329 No 2 2 0

C8H17SH (46) (159-165)

(oc)

p-Octylphenyl Salicylate 420 780 2 1 1 0

C21H26O3 (216) (416)

(oc)


Oil of Mirbane See Nitrobenzene.

Oil of Wintergreen See Methyl Salicylate.

Oleic Acid 372 685 0.9 547 No 2 0 1 0

C8H17CH:CH(CH2)7COOH (189) (363) (286)

(Red Oil)

Distilled 364

(184)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Oleo Oil 450 0.9 464 No 2 0 1 0

(232) (240)

Olive Oil 437 650 0.9 No 2 0 1 0

(Sweet Oil) (225) (343)

Oxalic Ether See Ethyl Oxalate.

Oxammonium See Hydroxylamine.

Oxirane See Ethylene Oxide.

Palm Butter See Palm Oil.

Palm Kernel Oil 398 0.9 No 2 0 1 0

(Palm Nut Oil) (203)


Palm Nut Oil See Palm Kernel Oil.

Palm Oil 323 600 0.9 No 2 0 1 0

(Palm Butter) (162) (316)


Paraffin Oil 444 2 0 1 0

(See also Lubricating Oil) (229)

Paraformaldehyde 158 572 7.0 73 Slight 5 2 1 0

HO(CH2O)nH (70) (300)



Paraldehyde 96 460 1.3 1.0- 4.5 255 Slight 1 2 3 1

(CH3CHO)3 (36) (238) (124) 5

(oc)



Peanut Oil 540 833 0.9 No 2 0 1 0

Cooking (282) (445)

(Katchung Oil)

Pentaborane 0.42 0.6 2.2 140 1 3 3 2

B5H9 (60) Reacts violently withhalogenatedextinguishing agents.

Note: Ignites spontaneously in air. See Hazardous Chemicals Data.

Pent-Acetate 98 0.9 260 No 1 2 3 0

Mixture of Isomeric Amyl Acetatesand Amyl Alcohols

(37) (127)

1,3-Pentadiene (cis and transmix)

-20 0.7 2.35 -45 No 1 0 4 2

CH2:CHCH:CHCH3 (-29) (-43)

(Piperylene)

1,2,3,4,5-Pentamethyl Benzene95%

200 800 est 0.9 449 No 2 0

C6H(CH3)5 (93) (427) (232)

(Pentamethylbenzene)

Pentamethylene Dichloride See 1,5-Dichloropentane.

Pentamethylene Glycol See 1,5-Pentanediol.

Pentamethylene Oxide -4 0.9 3.0 178 Yes 1 2 3 1

O(CH2)4CH2 (-20) (81) 5

(Tetrahydropyran)

Pentanal See Valeraldehyde.

Pentane < -40 500 1.5 7.8 0.6 2.5 97 No 1 1 4 0

CH3(CH2)3CH3 (< -40) (260) (36)

1,5-Pentanediol 265 635 1.0- 468 Yes 2 1 1 0

HO(CH2)5OH (129) (335) (242) 5

(Pentamethylene Glycol) (oc)

2,4-Pentanedione 93 644 1.0- 3.5 284 Yes 5 2 2 0

CH3COCH2COCH3 (34) (340) (140)

(Acetyl Acetone)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Pentanoic Acid 205 752 0.9 3.5 366 Very 2 1 0

C4H9COOH (96) (400) (186) slight

(Valeric Acid) (oc)

1-Pentanol See Amyl Alcohol.

2-Pentanol See Methyl Propyl Carbinol.

3-Pentanol 105 815 1.2 9.0 0.8 3.0 241 Slight 5 1 2 0

CH3CH2CH(OH)CH2CH3 (41) (435) (116)

(tert-n-Amyl Alcohol)

1-Pentanol Acetate See Amyl Acetate.

2-Pentanol Acetate See sec-Amyl Acetate.

2-Pentanone See Methyl Propyl Ketone.

3-Pentanone See Diethyl Ketone.

Pentaphen 232 0.9 482 No 2 2 1 0

C5H11C6H4OH (111) (250)

(p-tert-Amyl Phenol) (oc)


Pentapropionyl Glucose See Glucose Pentapropionate.

1-Pentene 0 527 1.5 8.7 0.7 2.4 86 1 1 4 0

CH3(CH2)2CH:CH2 (- 18) (275) (30)

(Amylene) (oc)

1-Pentene-cis See β-Amylene-cis.

2-Pentene-trans See β-Amylene-trans.

Pentylamine See Amylamine.

Pentyloxypentane See Amyl Ether.

Pentyl Propionate See Amyl Propionate.

1-Pentyne < -4 0.69 2.35 104 3 3

HCCC3H7 (< -20) (40)

(n-Propyl Acetylene)

Peracetic Acid Diluted with 60%acetic acid

105 221 Yes 3 2 4

CH3COOOH (41) (105) Explodes onheating.

Note: Decomposes violently at 230 (110).


Perchloroethylene,Tetrachloroethylene

None None None 1.6 5.8 250 No 2 0 0

Cl2C=CCl2 (121)

Perhydrophenanthrene 475 0.9 187-192 0

C14H24 (246) (86-89)

(Tetradecahydro Phenanthrene)

Perilla Oil 522 0.9 No 2 0 1 0

(272)

Petroleum, Crude 20-90 <1 No 1 1 3 0

(-7 to32)

Petroleum Ether <0 550 1.1 5.9 0.6 2.5 95-140 No 1 1 4 0

(Benzine) (< -18) (288) (35-60)

(Naphtha, Petroleum)

Petroleum Pitch See Asphalt (Typical).

Petroleum Sulfonate 400 No 2 0 1 0

(204)

(oc)

β-Phellandrene 120 ~0.9 4.68 340 No 0 2 0

CH2:CCH:CHCH[CH(CH3)2]CH2CH2 (49) (171)

(p-Mentha-1 (7), 2-Diene)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Phenanthrene 340 1.1 644 No 2 1 0

(C6H4CH)2 (171) (340)

(Phenanthrin) (oc)


Phenethyl Alcohol 205 1.0+ 430 No 2 1 1 0

C6H5CH2CH2OH (96) (221)

(Benzyl Carbinol)

(Phenylethyl Alcohol)

o-Phenetidine 239 442-446 No 5 2 1 0

H2NC6H4OC2H5 (115) (228-230) 2

(2-Ethoxyaniline) (oc)

(o-Amino-Phenetole)

p-Phenetidine 241 1.1 378-484 Very 2 2 1 0

C2H5OC6H4NH2 (116) (192-251) slight

(1-Amino-4-Ethoxybenzene)

(p-Aminophenetole)

Phenetole See Ethoxybenzene.

Phenol 175 1319 1.8 8.6 1.1 3.2 358 Yes 5 3 2 0

C6H5OH (79) (715) (181)

(Carbolic Acid) Note: See Hazardous Chemicals Data.

Melting point 108 (42).

2-Phenoxyethanol See Ethylene Glycol, Phenyl Ether.

Phenoxy Ethyl Alcohol 250 1.11 4.77 468 0 1 0

C6H5O(CH2)2OH (121) (242)

(2-Phenoxyethanol) (oc)

(Phenyl Cellosolve) Note: Melting point 58 (14).

N-(2-Phenoxyethyl) Aniline 338 1.1 396 No 2 1 1 0

C6H5O(CH2)3NHC6H5 (170) (202)

β-Phenoxyethyl Chloride See β-Chlorophenetole.

Phenylacetaldehyde 160 1.0+ 383 No 5 1 2 0

C6H5CH2CHO (71) (195)

(α-Toluic Aldehyde)

Phenyl Acetate 176 1.1 4.7 384 Slight 5 1 2 0

CH3COOC6H5 (80) (196)

(Acetylphenol)

Phenylacetic Acid >212 1.1 504 Yes 5 1 1 0

C6H5CH2COOH (>100) (262)

(α-Toluic Acid) Note: Melting point 169-171 (76-77).

Phenylamine See Aniline.

N-Phenylaniline See Diphenylamine.

Phenylbenzene See Biphenyl.

Phenyl Bromide See Bromobenzene.

1-Phenyl-2-Butene 160 0.9 4.6 346 2 0

C6H5CH2CH:CHCH3 (71) (174)

(oc)

Phenyl Carbinol See Benzyl Alcohol.

Phenyl Chloride See Chlorobenzene.

Phenylcyclohexane See Cyclohexylbenzene.

Phenyl Didecyl Phosphite 425 0.9 2 0 1 0

(C6H5O)P(OC10H21)2 (218)

(oc)

N-Phenyldiethanolamine 385 730 0.7 1.1 376 No 2 1 1 0

C6H5N(C2H4OH)2 (196) (387) (191)

(oc)


Phenyldiethylamine See N,N-Diethylaniline.

Phenyl Diglycol Carbonate See Diethylene Glycol Bis (Phenylcarbonate).




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Phenyl Di-o-Xenyl Phosphate 482 1.2 545-626 No 2 0 1 1

(C12H9O)2POOC6H5 (250) (285-330)

o-Phenylenediamine 313 1.5 3.73 513 1 0

NH2C6H4NH2 (156) (267).

(1,2-Diaminobenzene) Note: Melting point 284 (140).

Phenylethane See Ethylbenzene.

N-Phenylethanolamine 305 1.1 545 Slight 2 2 1 0

C6H5NHC2H4OH (152) (285) 5

(oc)


Phenylethyl Acetate ( β) 230 1.03 5.67 435 0 1 0

C6H5CH2CH2OOCCH3 (110) (224)

(oc)

Phenylethyl Alcohol See Phenethyl Alcohol.

Phenylethylene See Styrene.

N-Phenyl-N-Ethylethanolamine 270 685 0.8 1.0+ 514 Slight 2 2 1 0

C6H5N(C2H5)C2H4OH (132) (362) (268) 5

(oc) @ 740 mm

Phenylhydrazine 190 1.1 Decomposes Slight 5 3 2 0

C6H5NHNH2 (88)

Phenylmethane See Toluol.

Phenylmethyl Ethanol Amine 280 1.07 5.22 378 2 1 0

C6H5N(CH3)C2H4OH (138) (192)

(2-(N-Methylaniline)-Ethanol) (oc) @ 100 mm

Phenyl Methyl Ketone See Acetophenone.

4-Phenylmorpholine 220 1.1 518 Slight 5 2 1 0

C6H5NC2H4OCH2CH2 (104) (270) 2

(oc)

Phenylpentane See Amylbenzene.

o-Phenylphenol 255 986 1.2 547 Slight 5 1 1 0

C6H5C6H4OH (124) (530) (286) 2


Phenylpropane See Propylbenzene.

2-Phenylpropane See Cumene.

Phenylpropyl Alcohol 212 1.0+ 426 No 5 0 1 0

C6H5(CH2)3OH (100) (219)

(Hydrocinnamic Alcohol)

(3-Phenyl-l-propanol)

(Phenylethyl Carbinol)

Phenyl Propyl Aldehyde 205 1.0+ 5 1 0

C6H5CH2CH2CHO (96)

(3-Phenylpropionaldehyde)

(Hydrocinnamic Aldehyde)

Phenyl Toluene o >212 923 1.01 5.82 500 1 0

C6H5C6H4CH3 (>100) (495) (260)

(2-Methylbiphenyl)

Phenyl Trichloro Silane 196 1.32 7.36 394 3 2 0

C6H5SiCl3 (91) (201)

(Trichloro(phenyl)silane) (oc)

Phorone 185 0.9 4.8 388 No 2 2 0

(CH3)2CCHCOCHC(CH3)2 (85) (198)

(oc)


Phosphine Gas 212 0.57 1.17 -126 3 4 1

PH3 (100) @ 20 atm (-88)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Phthalic Acid 334 1.59 5.73 552 0 1 1

C6H4(COOH)2 (168) (289) Forms anhydride

Note: Melting point 376 (191). (Dust explosion hazard.)

Phthalic Anhydride 305 1058 1.7 10.5 1.5 543 No 2 2 1 0

C6H4(CO)2O (152) (570) (284)


m-Phthalyl Dichloride See Isophthaloyl Chloride.

2-Picoline 102 1000 1.0- 3.2 262 No 2 2 0

CH3C5H4N (39) (538) (128)

(2-Methylpyridine) (oc)

4-Picoline 134 1.0- 3.2 292 Yes 5 2 2 0

CH3C5H4N (57) (144)

(oc)

Pimelic Ketone See Cyclohexanone.

Pinane 523 0.7 @ 7.2 @ 0.8 336 0 0

C10H18 (273) 320 320 (151)

(160) (160)

α-Pinene 91 491 0.9 4.7 312 No 1 1 3 0

C10H16 (33) (255) (156)

Pine Oil 172 0.9 367-439 No 0 2 0

Steam Distilled (78) (186-226)

138

(59)

Pine Pitch 285 1.1 490 No 2 0 1 0

(141) (254)


Pine Tar 130 671 208 No 0 2 0

(54) (355) (98)

Pine Tar Oil 144 0.9 No 0 2 0

(Wood Tar Oil) (62)

Piperazine 178 1.1 3.0 294 Slight 5 2 2 0

HNCH2CH2NHCH2CH2 (81) (146)

(oc)

Piperidine 61 0.9 3.0 223 Yes 1 2 3 3

(CH2)5NH (16) (106) 5

(Hexahydropyridine)

Pogy Oil See Menhaden Oil.

Polyamyl NaphthaleneMixture of Polymers

360 0.9 667-747 No 2 0 1 0

(182) (353-397)

(oc)

Polyethylene Glycols 360-550 Yes 5 0 1 0

OH(C2H5O)nC2H4OH (182-287)

2

(oc)

Polyoxyethylene Lauryl Ether >200 0.95 0 1 0

C12H25O(OCH2CH2)nOH (> 93)

Polypropylene Glycols 365 1.0+ Decomposes 5 0 1 0

OH(C3H6O)nC3H6OH (185) 2

(oc)

Polyvinyl AlcoholMixture of Polymers

175 Yes 5 0 2 0

(79)

(oc)

Poppy Seed Oil 491 0.9 No 2 0 1 0

(255)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Potassium Xanthate 205 9.6 1.56 5.53 392 Yes 2 1 0

KS2C-OC2H5 (96) (200)

Decomposes

Propanal -22 405 2.6 17 0.8 2.0 120 Slight 1 2 3 1

CH3CH2CHO (-30) (207) (49) 5

(Propionaldehyde) Note: See Hazardous Chemicals Data.

Propane Gas 842 2.1 9.5 1.6 -44 No 6 1 4 0

CH3CH2CH3 (450) (-42)

1,3-Propanediamine 75 0.9 2.6 276 Yes 1 2 3 0

NH2CH2CH2CH2NH2 (24) (136) 5

(1,3-Diaminopropane) (oc)

(Trimethylenediamine)

1,2-Propanediol See Propylene Glycol.

1,3-Propanediol See Trimethylene Glycol.

1-Propanol See Propyl Alcohol.

2-Propanol See Isopropyl Alcohol.

2-Propanone See Acetone.

Propanoyl Chloride See Propionyl Chloride.

Propargyl Alcohol 97 0.97 1.93 239 3 3 3

HCCCH2OH (36) (115)

(2-Propyn-1-ol) (oc)

Propargyl Bromide 50 615 3.0 1.57 4.10 192 4 3 4

HCCCH2Br (10) (324) (89)

(3-Bromopropyne) Note: See Hazardous Chemicals Data.

Propene See Propylene.

2-Propenylamine See Allylamine.

Propenyl Ethyl Ether <20 0.8 1.3 158 1 2 3 0

CH3CH:CHOCH2CH3 (< -7) (70)

(oc)

β-Propiolactone 165 2.9 1.1 2.5 311 Yes 5 0 2 0

C3H4O2 (74) (155)

Propionaldehyde See Propanal.

Propionic Acid 126 870 2.9 12.1 1.0- 2.5 297 Yes 5 2 2 0

CH3CH2COOH (52) (465) (147)


Propionic Anhydride 145 545 1.3 9.5 1.0+ 4.5 336 Decomposes 2 2 1

(CH3CH2CO)2O (63) (285) (169) Decomposes in water.

Propionic Nitrile 36 3.1 0.78 1.90 207 Yes 4 3 1

CH3CH2CN (2) (97)

(Propionitrile)

Propionyl Chloride 54 1.1 3.2 176 Decomposes 1 3 3 1

CH3CH2COCl (12) (80) Decomposes in water.

(Propanoyl Chloride)

Propyl Acetate 55 842 1.7 @ 8 0.9 3.5 215 Slight 1 1 3 0

C3H7OOCCH3 (13) (450) 100 (102) 5

(Acetic Acid, n-Propyl Ester) (38)

Propyl Alcohol 74 775 2.2 13.7 0.8 2.1 207 Yes 1 1 3 0

CH3CH2CH2OH (23) (412) (97) 5

(1-Propanol)

Propylamine -35 604 2.0 10.4 0.7 2.0 120 Yes 1 3 3 0

CH3(CH2)2NH2 (-37) (318) (49) 5


Propylbenzene 86 842 0.8 6.0 0.9 4.1 319 No 1 2 3 0

C3H7C6H5 (30) (450) (159)

(Phenylpropane)

2-Propybiphenyl > 212 833 6.77 ~536 0 1 0

C6H5C6H4C3H7 (> 100) (445) (~280)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

n-Propyl Bromide 914 1.35 4.34 160 2 3 0

C3H7Br (490) (71)

(1-Bromopropane)

n-Propyl Butyrate 99 0.87 4.49 290 0 3 0

C3H7COOC3H7 (37) (143)

Propyl Carbinol See Butyl Alcohol.

Propyl Chloride <0 968 2.6 11.1 0.9 2.7 115 Very 1 2 3 0

C3H7Cl (< - 18) (520) (46) slight

(1-Chloropropane)

Propyl Chlorothiolformate 145 1.1 4.8 311 No 2 2 0

C3H7SCOCl (63) (155)

Propylcyclohexane 478 0.8 313-315 0 0

H7C3C6H11 (248) (156-157)

Propylcyclopentane 516 0.8 269 0 0

C3H7C5H9 (269) (131)

(1-Cyclopentylpropane)

Propylene Gas 851 2.0 11.1 1.5 -53 No 6 1 4 1

CH2:CHCH3 (455) (-47)

(Propene) Note: See Hazardous Chemicals Data.

Propylene Aldehyde See Crotonaldehyde.

Propylene Carbonate 275 1.2 468 Yes 2 1 1 0

OCH2CH2CH2OCO (135) (242) 5

(oc)

Propylene Chlorohydrin See 2-Chloro-1-Propanol.

sec-Propylene Chlorohydrin See 1-Chloro-2-Propanol.

Propylenediamine 92 780 0.9 2.6 246 Yes 1 2 3 0

CH3CH(NH2)CH2NH2 (33) (416) (119) 5

(oc)

Propylene Dichloride 60 1035 3.4 14.5 1.2 3.9 205 No 4 2 3 0

CH3CHClCH2Cl (16) (557) (96)

(1,2-Dichloropropane)

Propylene Glycol 210 700 2.6 12.5 1.0+ 2.62 370 Yes 5 0 1 0

CH3CHOHCH2OH (99) (371) (188)

(Methyl Ethylene Glycol)

(1,2-Propanediol)

Propylene Glycol Acetate See Methyl Glycol Acetate.

Propylene Glycol Isopropyl Ether 110 0.86 283 Yes

(43) (140)

Propylene Glycol Methyl Ether 90 1.6 13.8 0.92 3.11 248 Yes 0 3 0

CH3OCH2CHOHCH3 (32) (120)

(1-Methoxy-2-propanol)

Propylene Glycol Methyl EtherAcetate

108 1.5 7.0 0.966 4.6 295 Slight 5 0 2 0

(99 Pure) (42) @200°C (146)

Propylene Glycol Monoacrylate 207 1.4 1.05 4.5 410 Yes 5 3 1 2

CH2:CHCOO(C3H6)OH (97) @100°C

(210)

(Hydroxypropyl Acrylate)

Propylene Oxide -35 840 2.3 36 0.83 2.0 94 Yes 1 2 4 2

OCH2CHCH3 (-37) (449) (35) 5


n-Propyl Ether 70 370 1.3 7.0 0.75 3.53 194 3 0

(C3H7)2O (21) (188) (90)

(Dipropyl Ether)

Propyl Formate 27 851 0.9 3.0 178 Slight 1 2 3 0

HCOOC3H7 (-3) (455) (81) 5

Propyl Methanol See Butyl Alcohol.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Propyl Nitrate 68 347 2 100 1.1 231 Slight 1 2 4 3 OX

CH3CH2CH2NO3 (20) (175) (111) 5 May explode on heating.

Propyl Propionate 175 0.9 4.0 245 No 1 3 0

CH3CH2COOCH2CH2CH3 (79) (118)

(oc)

Propyltrichlorosilane 98 1.2 6.12 254 Yes 1 3 3 1

(C3H7)SiCl3 (37) (123.5)


Propyne Gas 1.7 1.4 -10 6 2 4 2

CH3CCH (-23)

(Allylene)

(Methylacetylene)

Prussic Acid See Hydrocyanic Acid.

Pseudocumene See 1,2,4-Trimethylbenzene.

Pyridine 68 900 1.8 12.4 1.0- 2.7 239 Yes 1 2 3 0

CH<(CHCH)2>N (20) (482) (115) 5


Pyroxylin Solution 80 No 1 1 3 0

(27)

May be below.

Pyrrole 102 1.0- 2.3 268 No 2 2 0

(CHCH)2NH (39) (131)

(Azole)

Pyrrolidine 37 0.9 2.5 186-189 Yes 5 2 3 1

NHCH2CH2CH2CH2 (3) (86-87) 1

(Tetrahydropyrrole)

2-Pyrrolidone 265 1.1 2.9 473 Yes 2 2 1 0

NHCOCH2CH2CH2 (129) (245) 5

(oc)


Quenching Oil 365 0.9 No 2 0 1 0

(185)

Quinoline 896 1.1 4.5 460 No 2 1 0

C6H4N:CHCH:CH (480) (238)

Range Oil See Fuel Oil No. 1.

Rape Seed Oil 325 836 0.9 No 2 0 1 0

(Colza Oil) (163) (447)

Red Oil See Oleic Acid.

Resorcinol 261 1126 1.4 @ 1.28 3.80 531 1 0

C6H4(OH)2 (127) (608) 392 (277)

(Dihydroxybenzol) (200)


Rhodinol >212 0.9 237-239 No 0 1 0

CH2:C(CH3)(CH2)3CH(CH3)(CH2)2OH (>100) (114-115)

@ 12 mm

Ricinus Oil See Castor Oil.

Rosin Oil 266 648 1.0- >680 No 2 0 1 0

(130) (342) (>360)

Rum See Ethyl Alcohol and Water.

Salicylaldehyde 172 1.2 384 Slight 5 0 2 0

HOC6H4CHO (78) (196)

(o-Hydroxybenzaldehyde)

Salicylic Acid 315 1004 1.1 @ 1.5 4.8 Sublimes No 2 0 1 0

HOC6H4COOH (157) (540) 392 @ 169

(200) (76)





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Safrole 212 1.1 451 No 1 0

C3H5C6H3O2CH2 (100) (233)

(4-allyl-1,2-Methylenedioxy-benzene)

Santalol > 212 1.0- ~572 No 1 0

C15H24O (> 100) (~300)

(Arheol)

Sesame Oil 491 0.9 No 2 0 1 0

(255)

Signal Oil See Mineral Seal Oil, Typical.

Silane Gas Pyrophoric 1.3 -169 Slight Avoid 1 4 2

SiH4 halon

(Silicon Hydride)

Soy Bean Oil 540 833 0.9 No 2 0 1 0

(282) (445)

Sperm Oil No. 1 428 586 0.9 No 2 0 1 0

(220) (308)

No. 2 460

(238)

Spindle Oil See Lubricating Oil, Spindle.

Stearic Acid 385 743 0.8 726 No 2 1 1 0

CH3(CH2)16COOH (196) (395) (386)


Stearyl Alcohol 842 0.8 410 No 0 0

CH3(CH2)17OH (450) (210)

(1-Octadecanol) @ 15 mm


Straw Oil 315-361 No 2 0 1 0

(157-183)

Styrene 88 914 0.9 6.8 0.9 3.6 295 No 1 2 3 2

C6H5CH:CH2 (31) (490) (146)

(Cinnamene)

(Phenylethylene) Note: Polymerizes.

(Vinyl Benzene) See Hazardous Chemicals Data.

Styrene Oxide 165 929 1.1 2 2 0

C6H5CHOCH2 (74) (498)

(oc)

Succinonitrile 270 1.0- 2.1 509-513 Yes 2 1 0

NCCH2CH2CN (132) (265-267) 5

(Ethylene Dicyanide) Note: Melting point 130 (54).

Sulfolane 350 1.3 545 Yes 2 2 1 0

CH2(CH2)3SO2 (177) (285)

(Tetrahydrothiophene-1,1-Dioxide) (oc)

(Tetramethylene Sulfone)


Sulfur 405 450 1.8 832 No

(207) (232) (445)

Sulfur Chloride 245 453 1.7 280 Decomposes 2 1 2

S2Cl2 (118) (234) (138) Decomposes in water.


Sweet Oil See Olive Oil.

Sylvan See 2-Methylfuran.

Tallow 509 0.9 No 2 0 1 0

(265)


Tallow Oil 492 0.9 No 2 0 1 0

(256)





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Tannic Acid 390 980 Decomposes Yes 2 0 1 0

(HO)3C6H2CO2C6H2(OH)2COOH (199) (527) 392

(Tannin) (oc) (200)

(Digallic Acid)

Tartaric Acid (d, l) 410 797 1.76 5.18 0 1 0

(CHOHCO2H)2 (210) (425)

(oc)


Terephthalic Acid 500 925 1.5 Sublimes No 2 0 1 0

C6H4(COOH)2 (260) (496) above

(para-Phthalic Acid) (oc) 572

(TPA) (300)

(Benzene-para-Dicarboxylic Acid)

Terephthaloyl Chloride 356 498 Yes 2 3 1 0

C6H4(COCl)2 (180) (259)

(Terephthalyl Dichloride)

(p-Phthalyl Dichloride)

(1,4-Benzenedicarbonyl Chloride) Note: Melting point 175 (79).

o-Terphenyl 325 1.1 630 No 2 0 1 0

(C6H5)2C6H4 (163) (332)

(oc)

m-Terphenyl 375 1.2 685 No 2 0 1 0

(C6H5)2C6H4 (191) (363)

(oc)


Terpineol 195 0.9 417-435 No 0 2 0

C10H17OH (91) (214-224)

(Terpilenol)

Terpinyl Acetate 200 1.0- 428 Slight 5 0 2 0

C10H17OOCCH3 (93) (220) 2

Tetraamylbenzene 295 0.9 608-662 No 2 0 1 0

(C5H11)4C6H2 (146) (320-350)

1,1,2,2-Tetrabromoethane 635 2.97 11.9 275 3 0 1

CHBr2CHBr2 (335) (135)

(Acetylene Tetrabromide)

Tetrachlorobenzene 311 1.7 475 No 2 0 1 0

C6H2Cl4 (155) (246)

1,2,4,5-Tetrachlorobenzene 311 1.86 472 No 1 1 0

C6H12Cl4 (155) (245)

Tetradecane 212 392 0.5 0.8 487 No 0 1 0

CH3(CH2)12CH3 (100) (200) (253)

Tetradecanol 285 0.8 507 No 2 0 1 0

C14H29OH (141) (264)

(oc)

1-Tetradecene 230 455 0.8 6.8 493 No 2 0 1 0

CH2:CH(CH2)11CH3 (110) (235) (256)

tert-Tetradecyl Mercaptan 250 0.9 496-532 5 2 1 0

C14H29SH (121) (258-278) 2

Tetraethoxypropane 190 1.12 6.70 621 0 2 0

(C2H5O)4C3H4 (88) (327)

(oc)

Tetra (2-Ethylbutyl) Silicate 335 0.9 460 No 2 1 1 0

[C2H5CH(C2H5)CH2O]4Si (168) (238)

(oc) @ 50 mm

Tetraethylene Glycol 360 1.1 6.7 Decomposes Yes 2 1 1 0

HOCH2(CH2OCH2)3CH2OH (182) 5

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Tetraethylene Glycol, DibutylEther

See Dibutoxy Tetraglycol.

Tetraethylene Glycol, DimethylEther

See Dimethoxy Tetraglycol.

Tetraethylene Pentamine 325 610 1.0- 631 Yes 2 2 1 0

H2N(C2H4NH)3C2H4NH2 (163) (321) (333) 5

(oc)

Tetra (2-Ethylhexyl) Silicate 390 0.9 No 2 1 1 0

[C4H9CH(C2H5)CH2O]4Si (199)

(oc)

Tetraethyl Lead, Compounds 200 1.8 1.6 8.6 Decomposes No 3 2 3

Pb(C2H5)4 (93) above

Note: See Hazardous Chemicals Data. 230 (110)

Tetraethyl Orthosilicate See Ethyl Silicate.

Tetrafluoroethylene Gas 392 10.0 50.0 1.5 3.87 -105 No 3 4 3

F2C:CF2 (200) (-76)

(TFE)

(Perfluoroethylene)


Tetraglycol Dichloride See Bis[2-(2-Chloroethoxy) Ethyl] Ether.

1,2,3,6-Tetrahydrobenzaldehyde 135 1.0- 3.8 328 Slight 5 2 2 0

CH2CH:CHCH2CH2CHCHO (57) (164)

(3-Cyclohexene-1-Carboxaldehyde)(oc)

endo-Tetrahydrodicyclo-pentadiene

523 0.9 379 0

C10H16 (273) (193)

(Tricyclodecane)


Tetrahydrofuran 6 610 2 11.8 0.9 2.5 151 Yes 1 2 3 1

OCH2CH2CH2CH2 (-14) (321) (66) 5

(Diethylene Oxide)(Tetramethylene Oxide)


Tetrahydrofurfuryl Alcohol 167 540 1.5 9.7 1.1 352 Yes 5 2 2 0

C4H7OCH2OH (75) (282) (178)

(oc) @ 743 mm

Tetrahydrofurfuryl Oleate 390 0.9 392-545 No 2 1 1 0

C4H7OCH2OOCC17H33 (199) (200-285)

@ 16 mm

Tetrahydronaphthalene 160 725 0.8 @ 5.0 @ 1.0- 4.6 405 No 1 2 0

C6H2(CH3)2C2H4 (71) (385) 212 302 (207)

(Tetralin) (100) (150)

Tetrahydropyran See Pentamethylene Oxide.

Tetrahydropyran-2-Methanol 200 1.0+ 4.0 368 Yes 5 1 2 0

OCH2CH2CH2CH2CHCH2OH (93) (187)

(oc)

Tetrahydropyrrole See Pyrrolidine.

Tetralin See Tetrahydronaphthalene.

1,1,3,3-Tetramethoxypropane 170 1.0- 361 Yes 5 0 2 0

[(CH3O)2CH]2CH2 (77) (183)

1,2,3,4-Tetramethylbenzene 95% 166 800 0.9 399-401 No 0 2 0

C6H2(CH3)4 (74) est. (204-205)

(Prehnitene) (427)

1,2,3,5-Tetramethylbenzene85.5%

160 800 0.9 387-389 No 0 2 0

C6H2(CH3)4 (71) est. (197-198)

(Isodurene) (427)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1,2,4,5-Tetramethylbenzene 95% 130 0.8 @ 4.6 385 No 0 2 0

C6H2(CH3)4 (54) 178 (196)

(Durene) (81)


Tetramethylene See Cyclobutane.

Tetramethyleneglycol 734 1.0+ 230 Yes 5 0 1 0

CH2OH(CH2)2CH2OH (390) (110)

Tetramethylene Oxide See Tetrahydrofuran.

Tetramethyl Lead, Compounds 100 1.6 6.5 Decomposes No 3 3 3

Pb(CH3)4 (38) above

Note: See Hazardous Chemicals Data. 212

(100)

2,2,3,3-Tetramethyl Pentane <70 806 0.8 4.9 0.7 4.4 273 0 3 0

(CH3)3CC(CH3)2CH2CH3 (<21) (430) (134)

2,2,3,4-Tetramethylpentane <70 0.74 4.43 270 0 3 0

(CH3)3CCH(CH3)CH(CH3)2 (<21) (132)

Tetramethyl Tin <70 1.9 1.3 6.2 172 No 3 2 0

Sn(CH3)4 (<21) (78)

Tetraphenyl Tin 450 1.5 14.7 795 No 2 3 1 0

(C6H5)4Sn (232) (424)


Tetrapropionyl GlucosylPropionate

See Glucose Pentapropionate.

Thialdine 200 1.1 Decomposes Slight 5 2 2 1

SCH(CH3)SCH(CH3)NHCHCH3 (93)

(oc)


2,2-Thiodiethanol 320 1.2 540 Yes 5 1 1 0

(HOCH2CH2)2S (160) (282) 2

(Thiodiethylene Glycol) (oc)

Thiodiethylene Glycol See 2,2-Thiodiethanol.

Thiodiglycol 320 568 1.2 541 Yes 2 2 1 0

(CH2CH2OH)2S (160) (298) (283)

(Thiodiethylene Glycol)

(Beta-bis-Hydroxyethyl Sulfide)

(Dihydroxyethyl Sulfide)

Thiophene 30 1.1 2.9 184 No 1 2 3 0

SCH:CHCH:CH (-1) (84)

1,4-Thioxane 108 1.12 3.59 300 2 2 0

O(CH2CH2)2S (42) (149)

(1,4-Oxathiane)

Toluene 40 896 1.1 7.1 0.9 3.1 231 No 1 2 3 0

C6H5CH3 (4) (480) (111)

(Methylbenzene)

(Phenylmethane)

(Toluol) Note: See Hazardous Chemicals Data.

Toluene-2,4-Diisocyanate 260 0.9 9.5 1.2 6.0 484 No 3 1 1

CH3C6H3(NCO)2 (127) (251) Reacts exothermicaliy

Note: See Hazardous Chemicals Data. with water.

p-Toluenesulfonic Acid 363 295 Yes 2 3 1 1

C6H4(SO3H)(CH3) (184) (140)

@ 20 mm

Note: Melting point 220 (104.5).

Toluhydroquinone 342 875 545 Yes 2 1 0

C6H3(OH)2CH3 (172) (468) (285)

(Methylhydroquinone) (oc)





FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

o-Toluidine 185 900 1.0- 3.7 392 No 3 2 0

CH3C6H4NH2 (85) (482) (200)

(2-Methylaniline)


p-Toluidine 188 900 1.0- 3.9 392 No 3 2 0

CH3C6H4NH2 (87) (482) (200)

(4-Methylaniline) Note: Melting point 111 (44).


Toluol See Toluene.

meta-Tolydiethanolamine 400 740 0.6 No 2 2 1 0

(HOC2H4)2NC6H4CH3 (204) (393)

(MTDEA) (oc)


2,4-Tolylene Diisocyanate See Toluene-2,4-Diisocyanate.

o-Tolyl Phosphate See Tri-o-Cresyl Phosphate.

o-Tolyl p-Toluene Sulfonate 363 1.2 2 1 1 0

C14H14O3S (184)

Transformer Oil 295 0.9 No 2 0 1 0

(Transil Oil) (146)

(oc)

Transil Oil See Transformer Oil.

Triacetin See Glyceryl Triacetate.

Triamylamine 215 0.8 453 No 2 2 1 0

(C5H11)3N (102) (234)

(oc)


Triamylbenzene 270 0.9 575 No 2 0 1 0

(C5H11)3C6H3 (132) (302)

(oc)

Triamyl Borate 180 0.8 9.4 430 1 2 0

B(C5H11O)3 (82) (221)

(oc)

Tributylamine 187 0.8 6.4 417 No 2 2 0

(C4H9)3N (86) (214)

(oc)


Tri-n-Butyl Borate 200 0.85 7.94 446 3 2 1

B(OC4H9)3 (93) (230)

(oc)

Tributyl Citrate 315 695 1.0+ 450 No 2 0 1 0

C3H4(OH)(COOC4H9)3 (157) (368) (232)

Tributyl Phosphate 295 1.0- 560 No 2 2 1 0

(C4H9)3PO4 (146) (293)

(oc)

Tributylphosphine 392 473 No 0 1 0

(C4H9)3P (200) (245)

Tributyl Phosphite 248 0.9 244-250 Decom-poses

2 1 1

(C4H9)3PO3 (120) (118-121)

(oc) @ 7 mm

1,2,4-Trichlorobenzene 222 1060 2.5 6.6 1.5 415 No 3 2 1 0

C0H3Cl3 (105) (571)

}

(213)

@ 302 (150)

1,1,1-Trichloroethane None 7.5 12.5 1.32 4.55 165 No 2 1 0

CH3CCl3 (74)

(Methyl Chloroform)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Trichloroethylene None 788 8 10.5 1.5 4.5 188 No 2 1 0

ClHC:CCl2 (420) @ 25°C (87)

7.8 52

@100°C

Note: See NFPA 49, Hazardous Chemicals Data.

1,2,3-Trichloropropane 160 3.2 12.6 1.4 5.1 313 No 3 3 2 0

CH2ClCHClCH2Cl (71) @120°C

@150°C

(156)

(Allyl Trichloride)

(Glyceryl Trichlorohydrin)

Trichlorosilane 7 1.3 4.7 89 Decomposes 3 4 2

HSiCl3 (-14) (32)

(oc)

Tri-o-Cresyl Phosphate 437 725 1.2 770 No 2 2 1 0

(CH3C6H4)3PO4 (225) (385) (410)

(o-Tolyl Phosphate) Decomposes

Tridecanol 250 0.8 6.9 525 No 2 0 1 0

CH3(CH2)12OH (121) (274)

(oc)


2-Tridecanone See Methyl Undecyl Ketone.

Tridecyl Acrylate 270 0.9 302 No 2 1 1 0

CH2:CHCOOC13H27 (132) (150)

(oc) @ 10 mm

Tridecyl Alcohol 180 0.8 485-503 5 0 2 0

C12H25CH2OH (82) (252-262)

(Tridecanol) (oc)


Tridecyl Phosphite 455 0.9 356 No 2 0 1 0

(C10H21O)13P (235) (180)

(oc) @ 0.1 mm

Triethanolamine 354 1.1 5.1 650 Yes 2 2 1 1

(CH2OHCH2)3N (179) (343) 5

(2,2’,2‘‘-Nitrilotriethanol)

1,1,3-Triethoxyhexane 210 0.9 7.5 271 No 1 1 0

CH(OC2H5)2CH2CH(OC2H5)C8H7 (99) (133)

(oc) @ 50 mm

Decomposes

@ 760 mm

Triethylaluminum Note: Ignites spontaneously in air 3 3 3

(C2H5)3AI Do not use water, foam, orhalogenated extinguishing

agents.

Triethylamine 16 480 1.2 8.0 0.7 3.5 193 No 1 2 3 0

(C2H5)3N (-7) (249) (89) 5

(oc)

1,2,4-Triethylbenzene 181 56 0.9 5.6 423 No 2 0

(C2H5)3C6H3 (83) @115°C

(217)

(oc)

Triethylborane Note: Ignites spontaneously in air. 1 3 3

(C2H5)3B Do not use halogenatedextinguishing agents.

Triethyl Citrate 303 1.1 561 Very 2 0 1 0

HOC(CH2CO2C2H5)CO2C2H5 (151) (294) slight




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Triethylene Glycol 350 700 0.9 9.2 1.1 5.2 546 Yes 2 1 1 0

HOCH2(CH2OCH2)2CH2OH (177) (371) (286) 5

(Dicaproate) (oc)

(2,2-Ethylenedioxy-diethanol)

Triethylene Glycol Diacetate 345 1.1 572 Yes 5 0 1 0

CH3COO(CH2CH2O)3COCH3 (174) (300) 2

(TDAC) (oc)

Triethylene Glycol, DimethylEther

232 1.0- 4.7 421 2 1 1 0

CH3(OCH2)3OCH3 (111) (216)

(oc)

Triethylene Glycol, Ethyl Ether See Ethoxytriglycol.

Triethylene Glycol, Methyl Ether See Methoxy Triglycol.

Triethyleneglycol MonobutylEther

290 1.0+ 270 Yes 5 0 1 0

C4H9O(C2H4O)3H (143) (132) 2

Triethylenetetramine 275 640 1.0- 532 Yes 2 3 1 0

H2NCH2(CH2NHCH2)2CH2NH2 (135) (338) (278) 5

Triethyl Phosphate 240 850 1.1 408-424 Yes 5 0 1 1

(C2H5)3PO4 (115) (454) (209-218) 2

(Ethyl Phosphate) (oc)

Trifluorochloroethylene Gas 8.4 16.0 1.31 @ 4.02 -18 6 4 0

CF2:CFCl 5.7 (-28)

(R-1113) atm

(Chlorotrifluoroethylene)

Triglycol Dichloride 250 1.2 466 No 2 2 1 0

ClCH2(CH3OCH2)2CH2Cl (121) (241)

(oc)

Trihexyl Phosphite 320 0.9 275-286 Decomposes 1 0

(C6H13)3PO3 (160) (135-141) Decomposes in water.

(oc) @ 2 mm

Triisobutylaluminum Note: May ignite spontaneously in air. 3 3

[(CH3)2CHCH2]3AI Do not use water, foam orhalogenated extinguishing

agents.

Triisobutyl Borate 185 0.84 7.94 413 3 2 1

B(OC4H9)3 (85) (212)

(oc)

Triisopropanolamine 320 608 1.0- 584 Yes 2 2 1 0

[(CH3)2COH]3N (160) (320) (307) 5

(1,1’,1’’-Nitrolotri-2-propanol) (oc)

Triisopropylbenzene 207 0.9 495 No 0 1 0

C6H3(CH3CHCH3)3 (97) (237)

(oc)

Triisopropyl Borate 82 0.82 6.49 288 3 3 1

(C3H7O)3B (28) (142)

Trilauryl Trithiophosphite 398 0.9 2 0 1 0

[CH3(CH2)11S]3P (203)

(oc)

Trimethylaluminum Note: Ignites spontaneously in air. 3 3

(CH3)3AI Do not use water, foam orhalogenated extinguishing

agents.

Trimethylamine Gas 374 2.0 11.6 2.0 38 Yes 6 2 4 0

(CH3)3N (190) (3)


1,2,3-Trimethylbenzene 111 878 0.8 6.6 0.89 4.15 349 0 2 0

C6H3(CH3)3 (44) (470) (176)

(Hemellitol)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

1,2,3-Trimethylbenzene 90.5 128 895 0.9 4.1 347-351 No 0 2 0

C6H3(CH3)3 (53) (479) (175-177)

(Hemimellitine 90.5)

1,2,4-Trimethylbenzene 112 932 0.9 6.4 0.87 4.15 329 No 0 2 0

C6H3(CH3)3 (44) (500) (165)

(Pseudocumene)

1,3,5-Trimethylbenzene 122 1039 0.9 4.1 328 No 0 2 0

C6H3(CH3)3 (50) (559) (164)

(Mesitylene)

Trimethyl Borate See Methyl Borate.

2,2,3-Trimethylbutane <32 774 0.69 3.46 178 0 3 0

(CH3)3C(CH3)CHCH3 (<0) (412) (81)

(Triptane-an isomer of Heptane)

2,3,3-Trimethyl-1-Butene <32 707 0.71 3.39 172 0 3 0

(CH3)3CC(CH3):CH2 (<0) (375) (78)

(Heptylene)

Trimethyl Carbinol See tert-Butyl Alcohol.

Trimethylchlorosilane -18 0.9 3.75 135 Yes 1 3 3 2

(CH3)3SiCl (-28) (57)

1,3,5-Trimethylcyclohexane 597 0.8 283 0 0

(CH3)3C6H9 (314) (139)

(Hexahydromesitylene)

Trimethylcyclohexanol 165 0.9 4.9 388 No 2 2 0

CH(OH)CH2C(CH3)2CH2CH(CH3)CH2 (74) (198)

(oc)

3,3,5-Trimethyl-1-Cyclohexanol 190 0.9 4.9 388 Slight 5 2 2 0

CH2CH(CH3)CH2C(CH3)2CH2CHOH (88) (198)

(oc)

Trimethylene See Cyclopropane.

Trimethylenediamine See 1,3-Propanediamine.

Trimethylene Glycol 752 1.1 2.6 417 Yes 5 1 0

HO(CH2)3OH (400) (214)

(1,3-Propanediol)

Trimethylethylene See 2-Methyl-2-Butene.

2,5,5-Trimethylheptane <131 527 0.73 4.91 304 0 2 0

C2H5C(CH3)2(CH2)2CH(CH3)2 (<55) (275) (151)

2,2,5-Trimethylhexane 55 0.7 4.4 255 No 1 2 3 0

(CH3)3C(CH2)2CH(CH3)2 (13) (124)

(oc)

3,5,5-Trimethylhexanol 200 0.8 381 No 2 2 0

CH3C(CH3)2CH2CH(CH3)CH2CH2OH (93) (194)

(oc)

2,4,8-Trimethyl-6-Nonanol 199 0.82 6.43 491 0 2 0

C4H9CH(OH)C7H15 (93) (255)

(2,6,8-Trimethyl-4-nonanol) (oc)

2,6,8-Trimethyl-4-Nonanol 200 0.8 438 No 2 2 0

(CH3)2CHCH2CH(OH)CH2CH (93) (226)

(CH3)CH2CH(CH3)2 (oc)

2,6,8-Trimethyl-4-Nonanone 195 0.8 6.3 425 No 2 2 0

(CH3)2CHCH2CH(CH3)CH2 (91) (218)

COCH2CH(CH3)2 (oc)

Trimethylolpropane Triacrylate 300 1.5 392 2 0 1 0

C2H5C(CH2OCOCHCH2)3 (149) (200)

(oc)

2,2,3-Trimethylpentane <70 745 0.72 3.94 230 0 3 0

CH3CH2CH(CH3)C(CH3)3 (<21) (346) (110)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

2,2,4-Trimethylpentane 10 779 1.1 6.0 0.7 3.9 211 No 1 3 0

(CH3)3CCH2CH(CH3)2 (-12) (415) (99)

2,3,3-Trimethylpentane <70 797 0.73 3.94 239 0 3 0

CH3CH2C(CH3)2CH(CH3)2 (<21) (425) (115)

2,2,4-Trimethyl-1,3-Pentanediol 235 655 0.9 419-455 No 2 0 1 0

(CH3)2CHCH(OH)C(CH3)2CH2OH (113) (346) (215-235)

(oc)


2,2,4-Trimethyl pentanediolDiisobutyrate

250 795 0.5 @ 0.9 9.9 536 2 0 1 0

C16H30O4 (121) (424) 342 (280)

(oc) (172)

2,2,4-Trimethyl-1,3-Pentanediol 248 740 0.6 @ 4.2 @ 1.0- 356-360 No 2 0 1 0

Isobutyrate (120) (393) 300 393 125 mm

(CH3)2CHCH(OH)C(CH3)2- (oc) (149) (201) (180-182)

CH2OOCCH(CH3)2

2,2,4-TrimethylpentanediolIsobutyrate Benzoate

325 1.0 167 2 0 1 0

C19H28O4 (163) (75)

(oc) @ 10 mm

2,3,4-Trimethyl-1-pentene <70 495 7.2 3.87 214 0 3 0

H2C:C(CH3)CH(CH3)CH(CH3)2 (<21) (257) (101)

2,4,4-Trimethyl-1-pentene 23 736 0.8 4.8 0.7 3.8 214 No 1 2 3 0

CH2:C(CH3)CH2C(CH3)3 (-5) (391) (101)

(Diisobutylene)

2,4,4-Trimethyl-2-pentene 35 581 0.7 3.8 221 No 1 2 3 0

CH3CH:C(CH3)C(CH3)3 (2) (305) (105)

(oc)

3,4,4-Trimethyl-2-pentene <70 617 0.74 3.87 234 0 3 0

(CH3)3CC(CH3):CHCH3 (<21) (325) (112)

Trimethyl Phosphite 130 1.0+ 4.3 232-234 No 0 2 0

(CH3O)3P (54) (111-112)

(oc)

Trioctyl Phosphite 340 0.9 212 No 2 0 1 0

(C8H17O)3P (171) (100)

[Tris (2-Ethylhexyl) Phosphite] (oc) @ 0.01 mm

Trioxane 113 777 3.6 29 239 Slight 5 2 2 0

OCH2OCH2OCH2 (45) (414) (115)

(oc) Sublimes


Triphenylmethane >212 1.01 8.43 678 0 1 0

(C6H5)3CH (>100) (359)


Triphenyl Phosphate 428 1.3 750 No 2 2 1 0

(C6H5)3PO4 (220) (399)


Triphenylphosphine See Triphenylphosphorus.

Triphenyl Phosphite 425 1.2 311-320 No 2 0 1 0

(C6H5O)3PO3 (218) (155-160)

(oc) @ 0.1 mm

Triphenylphosphorus 356 9.0 711 No 2 0 1 0

(C6H5)3P (180) (377)

(Triphenylphosphine) (oc)


Tripropyl Aluminum Note: Ignites spontaneously in air. 3 3

(C3H7)3Al Do not use waten foam orhalogenated extinguishing

agents.




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Tripropylamine 105 0.8 4.9 313 Very 2 2 0

(CH3CH2CH2)3N (41) (156) slight

(oc)

Tripropylene 75 0.7 4.35 271-288 1 0 3 0

C9H18 (24) (133-142)

(Propylene Trimer) (oc)

Tripropylene Glycol 285 1.0+ 514 Yes 2 0 1 0

H(OC3H6)3OH (141) (268)

Tripropylene Glycol Methyl Ether 250 0.97 7.12 470 0 1 0

HO(C3H6O)2C3H6OCH3 (121) (243)

Tris (2-Ethylhexyl) Phosphite See Trioctyl Phosphite.

Tung Oil 552 855 0.9 No 2 0 1 0

(China Wood Oil) (289) (457)


Turbine Oil See Lubricating Oil, Turbine.

Turbo Fuels See Jet Fuels.

Turkey Red Oil 476 833 1.0- Yes 2 0 1 0

(247) (445) 5

Turpentine 95 488 0.8 <1 300 No 1 1 3 0

(35) (253) (149)

Ultrasene 175 No 1 2 0

(Kerosene, Deodorized) (79)

Undecane See Hendecane.

2-Undecanol 235 0.8 437 No 2 1 1 0

C4H9CH(C2H5)C2H4CH(OH)CH3 (113) (225)

(oc)

UnsymmetricalDimethylhydrazine

See 1,1-Dimethylhydrazine.

Valeraldehyde 54 432 0.8 3.0 217 No 1 1 3 0

CH3(CH2)3CHO (12) (222) (103)

(Pentanal) (oc)

Valeric Acid See Pentanoic Acid.

Vinyl Acetate 18 756 2.6 13.4 0.9 3.0 161 Slight 1 2 3 2

CH2:CHOOCCH3 (-8) (402) (72) 5

(Ethenyl Ethanoate) Note: Polymerizes. See Hazardous Chemicals Data.

Vinylaceto- β-Lactone See Diketene.

Vinyl Acetylene 21 100 0.68 @ 1.80 41 4 3

CH2:CHCCH 1.7 (5)

(1-Buten-3-yne) atm

Spont.

decomposition

Vinyl Allyl Ether <68 0.8 153 Very 1 2 3 2

CH2:CHOCH2CH2O(CH2)3CH3 (<20) (67) slight

(Allyl Vinyl Ether) (oc)

Vinylbenzene See Styrene.

Vinylbenzylchloride 220 1.1 444 No 2 2 1

ClCH2C6H4CH:CH2 (104) (229)

(oc)

Vinyl Bromide None 986 9 15 1.5 3.7 60 No 2 0 1

(530) (15.8)

Vinyl Butyl Ether 15 437 0.8 3.5 202 Slight 1 2 3 2

CH2:CHOC4H9 (-9) (255) (94) 5

(Butyl Vinyl Ether) (oc)

Vinyl Butyrate 68 1.4 8.8 0.9 4.0 242 Slight 1 2 3 2

CH2:CHOCOC3H7 (20) (117) 5

(oc)




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Vinyl 2-Chloroethyl Ether 80 1.0+ 3.7 228 Slight 1 2 3 2

CH2:CHOCH2CH2Cl (27) (109) 5

(2-Chloroethyl Vinyl Ether) (oc)

Vinyl Chloride -108.4 882 3.6 33.0 .91 2.2 7 No 6 2 4 1

CH2CHCl (-78) (472) (-14)

(Chloroethylene) (oc)


Vinyl Crotonate 78 0.9 4.0 273 Slight 1 2 3 2

CH2:CHOCOCH:CHCH3 (26) (134) 5

(oc)

Vinyl Cyanide See Acrylonitrile.

4-Vinyl Cyclohexene 61 517 0.8 3.7 266 1 0 3 2

C8H12 (16) (269) (130)

Vinyl Ether See Divinyl Ether.

Vinyl Ethyl Alcohol 100 4.7 34 0.84 2.49 233 Yes 0 2 0

CH2:CH(CH2)2OH (38) (112)

(3-Buten-1-ol)

Vinylethylene Oxide See Butadiene Monoxide.

Vinyl Ethyl Ether <-50 395 1.7 28 0.8 2.5 96 No 1 2 4 2

CH2:CHOC2H5 (<-46) (202) (36) 5

(Ethyl Vinyl Ether)

Vinyl 2-Ethylhexoate 165 0.9 6.0 365 No 2 2 2

CH2:CHOCOCH(C2H5)C4H9 (74) (185)

(oc)

Vinyl 2-Ethylhexyl Ether 135 395 0.8 5.4 352 Slight 5 2 2 2

C10H20O (57) (202) (178)

(2-Ethylhexyl Vinyl Ether) (oc)

2-Vinyl-5-Ethylpyridine 200 0.9 248 No 2 2 2

N:C(CH:CH2)CH:CHC(C2H5):CH (93) (120)

(oc) @ 50 mm

Vinyl Fluoride Gas 2.6 21.7 -97.5 Slight 6 1 4 2

CH2:CHF (-72)

Vinylidene Chloride -19 1058 6.5 15.5 1.2 3.4 89 No 4 2 4 2

CH2:CCl2 (-28) (570) (32)

(1,1-Dichloroethylene) Note: Polymerizes. See Hazardous Chemicals Data.

Vinylidene Fluoride Gas 5.5 21.3 -122.3 Slight 6 1 4 2

CH2:CF2 (-86)

Vinyl Isobutyl Ether 15 0.8 3.5 182 Slight 1 2 3 2

CH2:CHOCH2CH(CH3)CH3 (-9) (83) 5

(Isobutyl Vinyl Ether)

Vinyl Isooctyl Ether 140 0.8 5.4 347 No 1 2 0

CH2:CHO(CH2)5CH(CH3)2 (60) (175)

(Isooctyl Vinyl Ether)

Vinyl Isopropyl Ether -26 522 3.0 133 1 2 4 2

CH2:CHOCH(CH3)2 (-32) (272) (56) 5

(Isopropyl Vinyl Ether)

Vinyl 2-Methoxyethyl Ether 64 0.90 3.52 228 0 3 0

CH2:CHOC2H4OCH3 (18) (109)

(1-Methoxy-2-Vinyloxyethane) (oc)

Vinyl Methyl Ether Gas 549 2.0 43 Slight 6 2 4 2

CH2:CHOCH3 (287) (6)

(Methyl Vinyl Ether)

Vinyl Octadecyl Ether 350 0.8 297-369 No 2 0 1 0

CH2:CHO(CH2)17CH3 (177) (147-187)

(Octadecyl Vinyl Ether) Note: Melting point 82.4 (28). @ 5 mm




FlashPoint

°F (°C)


FlammableLimits


=1)

VaporDensity(Air=1)

BoilingPoint

°F (°C)Water

Soluble





mabilityReac-tivity

Vinyl Propionate 34 0.9 3.3 203 Slight 1 2 3 2

CH2:CHOCOC2H5 (1) (95) 5

(oc)

1-Vinylpyrrolidone 209 1.0+ 3.8 205 Yes 5 0 1 0

CH2:CHNCOCH2CH2CH2 (98) (96)

(oc) @ 14 mm

(Vinyl-2-Pyrrolidone)

Vinyl-2-Pyrrolidone See 1-Vinylpyrrolidone.

Vinyl Toluene 127 1000 0.8 11.0 0.9 4.08 334 No 2 2 1

CH3C6H4CH:CH2 (53) (538) (168)


Vinyl Trichlorosilane 70 1.3 5.61 195 1 3 3 2

CH2:CHSiCl3 (21) (91)

(oc)

Water Gas See Gas.

Wax, Microcrystalline >400 0.9 2 0 1 0

(>204)

Wax, Ozocerite 236 0.9 No 2 0 1 0

(Mineral Wax) (113)

Wax, Paraffin 390 473 0.9 >700 No 2 0 1 0

(199) (245) (>371)


Whale Oil 446 800 0.9 No 2 0 1 0

(230) (427)

Whiskey See Ethyl Alcohol and Water.

White Tar See Naphthalene.

Wines See Ethyl Alcohol and Water.

Sherry and Port

High

Wood Alcohol See Methyl Alcohol.

Wood Tar Oil See Pine Tar Oil.

Wool Grease See Lanolin.

m-Xylene 81 982 1.1 7.0 0.9 3.7 282 No 1 2 3 0

C6H4(CH3)2 (27) (527) (139)

(1,3-Dimethylbenzene) Note: See Hazardous Chemicals Data.

o-Xylene 90 867 0.9 6.7 0.9 3.7 292 No 1 2 3 0

C6H4(CH3)2 (32) (463) (144)

(1,2-Dimethylbenzene)

(o-Xylol) Note: See Hazardous Chemicals Data.

p-Xylene 81 984 1.1 7.0 0.9 3.7 281 No 1 2 3 0

C6H4(CH3)2 (27) (528) (138)

(1,4-Dimethylbenzene) Note: See Hazardous Chemicals Data.

o-Xylidine 206 1.0 1.0- 435 No 3 1 0

C6H3(CH3)2NH2 (97) (224)

(o-Dimethylaniline) Note: See Hazardous Chemicals Data.

o-Xylol See o-Xylene.

Zinc Diethyl See Diethylzinc.

Zinc Stearate 530 788 1.1 0 1 0

Zn18H35O2 (277) (420)

(oc)




Fire Hazard Properties of Flammable Liquids

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