FINAL REPORT IDavenport Works to characterize polychlorinated biphenyl (PCB) concentrations in fish...

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FINAL REPORT

165 ISite:

Break: 3-3

137551

Superfund

AN ASSESSMENT OF PCBCONCENTRATIONS IN FISH

MISSISSIPPI RIVERPOOL 15

1992

Prepared forAluminum Company of AmericaDavenport, Iowa

& o • • * • • • ,• :-&'•'.:•• '•• ' ' ; '•;; '<} • #5 Wo6dward-Clyd£

Woodward-Clyde Consultants357 Riverside Drive (37064)P.O. Box 680925 (37068-0925)Franklin, Tennessee

September 1993

' Woodward-Clyde w• Consultants

I

Engineering a science applied to the earth & its environment

' September 14, 1993

• Mr. Marshall SonksenAluminum Company of America4879 State Street

I Riverdale, Iowa 52722

_ Subject: Transmirtal of Final Report, "An Assessment of PCB Concentrations in Fish,• Mississippi River Pool 15, 1992"

File #9IN7201

Dear Mr. Sonksen:

I Please find enclosed three copies of the revised report, "An Assessment of PCBConcentrations in Fish, Mississippi River Pool 15, 1992." We appreciate the opportunity to

• assist ALCOA on this project.

Please contact us at 615/790-0003 if you have any questions or comments.

ISincerely,

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H:\ldhuntxO\wp51Trans.let\Scptember 14, I993\NSV

357 Riverside Drive (37064) « P.O. Bo/ I-J80925 (37063-0925) « r-ranMm. Tennessee!6ic;i 790-0003 • (R15 ) 790 0023

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FINAL REPORT

AN ASSESSMENT OF PCBCONCENTRATIONS IN FISH

MISSISSIPPI RIVERPOOL 15

1992

Prepared forAluminum Company of AmericaDavenport, Iowa

Woodward-Clyde

Woodward-Clyde Consultants357 Riverside Drive (37064)P.O. Box 680925 (37068-0925)Franklin, Tennessee

September 1993

Woodward-Cfyde• Consultants

II

AN ASSESSMENT OF PCB CONCENTRATIONS IN FISH

* MISSISSIPPI RIVER

I POOL 15

I 1992

I• Prepared for:

Aluminum Company of America

I Davenport, Iowa

I

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IPrepared by:

I Woodward-Clyde ConsultantsFranklin, Tennessee

ISeptember 1993

I

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Woodward-ClydeConsultants

Table of Contents

Page

Table of Contents i

List of Tables ii

List of Figures iii

1.0 EXECUTIVE SUMMARY 1-1

2.0 INTRODUCTION 2-1

3.0 METHODS 3-13.1 Site Delineation 3-13.2 Sample Collection 3-13.3 Sample Processing 3-2

4.0 SAMPLE HANDLING AND ANALYSIS 4-14.1 Sample Preparation 4-14.2 Laboratory Protocol 4-14.3 Laboratory QA/QC Program 4-3

5.0 RESULTS AND CONCLUSION 5-15.1 Results 5-15.2 Assessment of Data Useability 5-1

5.2.1 Precision 5-25.2.2 Bias 5-35.2.3 Representativeness 5-35.2.4 Completeness 5-35.2.5 Comparability 5-4

5.3 Data Analysis 5-5

6.0 REFERENCES 6-1

APPENDICESA. Field Data SheetsB. Laboratory Processing SheetsC. Chain-of-Custody FormsD. Analytical DataE. W-Test Results

4, I99JVNSV

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List of Tables

Table 1. Total Number of Target Species Collected by Site

Table 2a. Total Number of Target Species Collected by Electrofishing

Table 2a. Total Number of Target Species Collected by Hoop Nets

Table 3. Summary of SRM Analyses

Table 4. Summary of Field Duplicate Analyses

Table 5. Summary of Interlaboratory Analyses

Table 6. Summary of Matrix Spike Recoveries

Table 7. Variations in Sampling and Analytical Programs for 1988, 1990, and 1992

Table 8. Probability Distribution of Target Fish Analytical Datasets

Table 9. Minimum Unbiased Estimates of Mean PCB Concentrations (mg/kg) and 95percent Confidence Intervals

931AFSHA RmSqrtember 14. 1993VNSV

Woodward-Clyde• Consultants

• List of Figures

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• Figure 1. 1992 Fish Sampling Sites

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i.oEXECUTIVE SUMMARY

Woodward-Clyde Consultants was retained by the Aluminum Company of America (ALCOA)

Davenport Works to characterize polychlorinated biphenyl (PCB) concentrations in fish within

Pool 15 of the Mississippi River near Davenport, Iowa. Specifically, ALCOA requested

development and execution of a statistically valid protocol for assessing the concentration of

total PCB and Aroclors 1016, 1221, 1232, 1242, 1248, 1254 and 1260 in seven (7) fish

species at four (4) specific sites. The study was designed in accordance with the United

States Environmental Protection Agency's (EPA) stipulations in the Administrative Order of

Consent between ALCOA and EPA (Docket No. 90-F-0027). The objectives of the

Mississippi River Pool 15 Fish Sampling Investigation, as outlined by EPA, were "... to

determine the need to continue or expand current advisories, to evaluate the risk to human

health or the environment, and to determine if response actions for Pool 15 are necessary".

The Consent Order stated the level of concern was a concentration greater than 2.0 ppm total

PCBs.

The Consent Order concentration of 2.0 ppm total PCBs was exceeded by the upper 95

percent confidence interval (CI) of the mean filet PCB concentration for the following species

and sites:

Common Carp Sites 2, 3, and 4

River Carpsucker Site 2

The upper 95 percent CI of the mean PCB concentration in filets did not exceed 2.0 ppm

total PCB for the following species and sites:

Channel Catfish Sites 2, 3, 4 and 5

Common Carp Site 5

Freshwater Drum Sites 2, 3, 4 and 5

River Carpsucker Sites 3, 4 and 5

Smallmouth Buffalo Site 5

93IAFSHA RPTCeptcmbet 14. I993VNSV

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Due to inadequate sample size (n < 10), no statistical analyses were performed on flathead

catfish or shovelnose sturgeon for all the sites, or for smallmouth buffalo at Sites 2, 3 and

4. A summary of the upper 95 percent confidence intervals on the mean is presented in the

following table.

Species

Channel Catfish

Common Carp

Flathead Catfish

Freshwater Drum

River Carpsucker

Shovelnose Sturgeon

Smallmouth Buffalo

Upper 95 Percent Confidence Intervals

Site 2

1.46

3.37

0.90

3.43

Site 3

0.78

4.70

0.61

1.88

Site 4

0.97

2.07

0.98

1.69

SiteS

0.49

0.69

0.63

0.48

1.40

Shaded areas indicates exceedance of (he Consent Order criterion of 2.0 ppm Total FCB

, I993\NSV 1-2

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2.0

INTRODUCTION

Woodward-Clyde Consultants (WCC) was retained by the Aluminum Company of America

(ALCOA) Davenport Works to characterize polychlorinated biphenyl (PCB) concentrations

in fish within Pool 15 of the Mississippi River near Davenport, Iowa (Figure 1).

Specifically, ALCOA requested development and execution of a statistically valid protocol

for assessing the concentration of total PCB and Aroclors 1016, 1221, 1232, 1242, 1248,

1254 and 1260. The study was designed in accordance with the United States Environmental

Protection Agency's (EPA) stipulations in the Administrative Order of Consent between

ALCOA and EPA (Docket No. 90-F-0027).

The objectives of the Mississippi River Pool 15 Fish Sampling Investigation, as outlined by

EPA, were "... to determine the need to continue or expand current advisories, to evaluate

the risk to human health or the environment, and to determine if response actions for Pool

15 are necessary".

The areas of concern for the 1992 fish study were expanded from sampling sites identified

by EPA in the Consent Order. These sampling sites were extended toward the main channel

in order to increase the probability of capturing smallmouth buffalo and sturgeon. The

sampling sites are shown in Figure 1 and are identified in the following table:

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SITE

2

3

4

5

DESCRIPTION

Offshore from ALCOA'S closed lagoon, centered approximatelyfeet downstream from groundwater well MW 9

500

From the upstream power plant to ALCOA 's water intake

300 ft upstream from the mouth of Duck Creek downstream tomooring cells to the concrete discharge structure

located at the inlet on the downstream end of Campbells Island,extending across to the Illinois shore and downstream.

the

and

A more detailed site description is presented in Section 3.0.

The species of concern were:

1. common carp (Cyprinus carpio)2. flathead catfish (Pylodictis olivaris)3. channel catfish (Ictalurus punctatus)4. river carpsucker (Carpiodes carpio)5. shovelnose sturgeon (Scaphirhynchus platorynchus)6. shovelnose sturgeon eggs (when available)7. smallmouth buffalo (Ictiobus bubalus)8. freshwater drum (Aplodinotus grunniens).

This report summarizes sampling and analytical techniques used during this investigation and

presents the results of the analyses. Detailed descriptions of specific sampling and analytical

techniques are outlined in the 1992 Sampling and Analysis Plan (SAP) (WCC 1992). A

Quality Assurance Project Plan (QAPP) and a Health and Safety Plan (HSP) are located in

the appendices of the 1990 Sampling and Analysis Work Plan (YMA 1990).

2-2

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3.0

METHODS

3.1 SITE DELINEATION

Readily recognizable landmarks were chosen at the upstream and downstream boundaries of

each site. Site 2 was located along the Iowa shore of the Mississippi River adjacent to the

ALCOA facility, from approximately 200 feet downstream from Outfall 004 to 200 feet

downstream from Outfall 001. Site 3 was located on the Iowa side of Pool 15, and extended

from the upstream end of the power plant downstream to the ALCOA water intake. Site 4

began 300 feet upstream from the mouth of Duck Creek adjacent to the Iowa shore and

extended downstream to a concrete drain structure of the mooring cells. Sites 2, 3 and 4

were approximately 1,000 feet wide. Site 5 began at the inlet on the downstream end of

Campbells Island, and extended across to the Illinois shore and downstream to a chain link

fence across the pool from Alcoa's water intake pump house. This site was approximately

1,200 feet wide (Figure 1).

3.2 SAMPLE COLLECTION

Electrofishing, hoop nets and gill nets were used according to revised Standard Operating

Procedures (SOP) in the 1992 SAP. Attempts were made to collect ten (10) to fifteen (15)

specimens of each of the designated seven (7) species at each site.

Daily catch and effort expended to collect fish samples from each site were transmitted to

EPA on a daily basis. Collection efforts proceeded until verbal approval was received from

the EPA Project Manager to discontinue sampling. Field data sheets are provided in

Appendix A. The total number of specimens collected is presented in Table 1. Electrofishing

proved to be the most efficient technique (see Table 2a), with approximately 67 percent of

target fish collected using this method. Both alternating and direct current were used at

voltages ranging from 150 to 400 volts to produce sufficient amperage to immobilize target

species for collection.

3-1

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Most of the target species were concentrated in shallow water around nearshore structures

within fifty (50) feet from the shore. Baited hoop nets were positioned in deeper high-current

areas of each site. Smallmouth buffalo, river carpsucker and freshwater drum were the target

species using this gear. Hoop nets accounted for approximately 30 percent of the target

species collected (Table 2b). Gill nets were set in the deeper portions at each site to sample

areas not covered by the electrofishing boat. However, use of gill nets was suspended due

to large quantities of debris in the river which became entangled in the gear and enabled fish

to avoid capture. Gill nets accounted for approximately 3 percent of the target species

collected.

3.3 SAMPLE PROCESSING

Samples were processed promptly according to methods specified in the SAP. Scales were

removed from carp, carpsucker, freshwater drum and smallmouth buffalo. Each fish was

measured, weighed, tagged, wrapped in clean aluminum foil, placed in a plastic bag and

packed in a cooler of wet ice for shipping. Channel catfish and flathead catfish were

measured, weighed and tagged but were not skinned in the field.

3-2

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4.0

SAMPLE HANDLING AND ANALYSIS

4.1 SAMPLE PREPARATION

EPA Standard Operating Procedure (SOP) No. 3210.3A was used for the preparation of fish

samples. Whole fish samples were wrapped in aluminum foil and shipped on wet ice via

overnight carrier to the WCC lab in Franklin, Tennessee, for processing. At the lab, the

whole fish were unpacked, fileted, and the filets were diced and ground. Following

processing, the ground samples were subsampled, placed in labeled glass jars with teflon lids

and shipped to the primary analytical laboratory (WW Engineering & Science). At EPA's

request, preselected tissue samples were collected and delivered to Jacobs Engineering. Offal

samples and excess tissue were wrapped in aluminum foil, placed in freezer bags with

identification labels and archived at or below 4°C. Laboratory processing data sheets are

included in Appendix B.

Prior to processing each sample, instruments and equipment were decontaminated by washing

with detergent, rinsing with tap water and rinsing with methanol in accordance with the SAP.

An equipment rinsate blank was prepared each day by rinsing the decontaminated equipment

with laboratory grade distilled water into a precleaned glass jar with a Teflon cap. In

addition, fish blanks (rainbow trout - Oncorhynchus mykiss) were included to qualify any

contamination occurring during sample processing at the laboratory. The fish were purchased

from the Bob White Springs Trout Hatchery in Centerville, Tennessee. The fish blanks were

weighed, measured and processed using the same techniques for fish collected from Pool 15.

Following preparation, the fish tissue samples were delivered to WW Engineering & Science

(formerly American Analytical Laboratories) and Jacobs Engineering for analysis.

4.2 LABORATORY PROTOCOL

EPA Standard Operating Procedure EPA SOP No. 3420.2A was used for the analysis of

PCBs. Preliminary analytical results of standard reference materials indicated WW

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Engineering & Science and the EPA laboratories were comparable in quantifying PCB

concentrations. Therefore, no secondary laboratory was designated.

Upon delivery to the laboratory, the samples and chain-of-custody forms were signed over

to the laboratory receiving agent. The chain-of-custody forms accompanied the samples

throughout sample preparation, extraction and analysis to document handling (Appendix C).

4.3 LABORATORY QA/QC PROGRAM

The objective of the laboratory QA/QC program was to ensure that the data used in the

assessment were of the quality to satisfy the program objectives. The major components of

the laboratory QA/QC program included:

1) specific chain-of-custody protocol and archiving procedures;2) internal QC samples;3) external QC samples;4) quality assessment samples; and5) use of detailed, written SOPs for analytical methods.

Internal QC samples prepared by the analyst were run with each analytical batch. These

were then compared to the control limits during the run. Internal QC samples included (1)

calibration or reagent blanks, (2) detection limit QC check samples, (3) calibration QC check

samples, (4) analytical splits and (5) use of specific matrix standard reference materials

(SRMs).

External QC samples were used with the EPA laboratory to assess performance and to

minimize the potential for interlaboratory biases. This process included analysis of the filet

samples by the EPA laboratory, use of matrix blanks and blind samples.

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5.0

RESULTS AND CONCLUSION

5.1 RESULTS

Laboratory analytical data are included in Appendix D. The reported analytical data include

quantification of each Aroclor, percent lipids, and surrogate recoveries. Total PCB

concentrations reported by WW Engineering & Science were calculated by summing the

reported method detection limit and the reported concentrations of each detected Aroclor.

Total PCB concentrations for this report were recalculated using fifty percent of the reported

detection limit for Aroclors 1016, 1221, 1232, and 1242 plus reported concentration or

detection limit for Aroclors 1248, 1254 and 1260. Aroclors 1016, 1221, 1232, and 1242

were not detected in field samples. The recalculated total PCB concentrations used in

statistical analyses are presented in Table Dl-1 of Appendix D.

5.2 ASSESSMENT OF DATA USEABILITY

The laboratory results were thoroughly reviewed prior to inclusion of the data in the statistical

analysis. Each result was evaluated in terms of quantitative and qualitative characteristics.

Samples were spiked with a surrogate compound, decachlorobiphenyl (DCBP), to assess

analytical recovery rates. All samples in which the percent DCBP recovery was less than 43

percent or greater than 111 percent were reanalyzed if tissue was available for additional

analyses. The total PCB concentration reported for the rerun sample was used for statistical

calculations. WW Engineering and Science reported that method detection limits, accuracy

and precision levels were as specified in the laboratory protocol.

No detectable PCBs (detection limit = 0.065 ^g/L) were observed in equipment rinsate

blanks collected during laboratory processing. An initial fish blank was submitted to the

analytical lab prior to Pool 15 fish processing. The background level of total PCBs in this

blank was approximately 0.08 mg/kg. Daily fish blanks (11) were processed during the fish

sample preparation and none of the blank samples exceeded the initial background

concentration.

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The analytical results were evaluated for qualitative characteristics including precision, bias,

representativeness, completeness and comparability.

5.2.1 Precision

Precision is a measure of mutual agreement (closeness) among individual measurements of

the same property, usually under similar prescribed conditions. A range for assessing

precision of laboratory and interlaboratory samples was developed from analytical results of

SRM samples.

A total of 13 SRM samples were analyzed during the period of field sample analysis. The

relative standard deviation (RSD) was used to evaluate precision. The RSD, expressed as

a percent, was calculated by dividing the standard deviation of the sample set by the mean

and multiplying by 100. SRM data and RSD calculations are summarized in Table 3. The

RSD for the SRM samples was 13 percent.

Thirty field duplicate samples were submitted to the WW Engineering & Science laboratory

for analysis. The samples consisted of 15 common carp from Site 2 and 15 common carp

from Site 3. An additional blind duplicate of each of these samples was also submitted to the

laboratory, resulting in a total of three replicate analyses for each sample. The RSD was

calculated for each set of replicates as presented in Table 4. The RSDs ranged from 7

percent to 87 percent. The average RSD for the replicate samples was 23 percent. This

indicates that the laboratory analyses for the field samples was less precise than the analyses

for the SRM samples. i J"

Interlaboratory analyses between WW Engineering & Science laboratories and the EPA

laboratory were examined as shown in Table 5. The relative percent difference (RPD) was

calculated for each of the samples by dividing the difference between the sample

concentrations by the mean of the samples and multiplying by 100. The RPD expressed as

an absolute value ranged from 3 percent to 136 percent. The average RPD for

interlaboratory samples was 50 percent. The RSDs for the interlaboratory analyses were also

calculated. These are also presented in Table 5. The RSDs ranged from 2 percent to 96

percent. The average RSD was 36 percent. The precision between interlaboratory analyses

was lower than observed for the SRM analyses or the field analyses.

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5.2.2 Bias

Bias is a consistent deviation of measured values from the true value caused by systematic

errors in a procedure. Bias was evaluated based on the average percent recovery on matrix

spikes and surrogate compound spikes.

A total of 19 matrix spike samples were prepared by the laboratory by spiking field samples

with Aroclor 1248 or Aroclor 1254. A summary of the spiking concentrations and recoveries

is presented in Table 6. Matrix spike recoveries ranged from 53 percent to 106 percent. The

average matrix spike recovery was 80 percent. This suggests a potential negative bias from

the true concentration.

Each of the samples analyzed was also spiked with a surrogate compound (DCBP). Surrogate

recoveries are reported in Table Dl-1 of Appendix D. Surrogate recovery ranged from 46

percent to 111 percent. The average percent recovery on surrogate (DCBP) spiked samples

was 91 percent (coefficient of variation < 15 percent). This also suggests a minor negative

bias from the true concentration

5.2.3 Representativeness

Representativeness expresses the degree to which data accurately and precisely represent a

characteristic of a population, parameter variations at a sampling point, a process condition

or an environmental condition.

The sampling station summary sheets, SOPs and chain-of-custody forms were evaluated to

assure that the data were representative. Field identifications were verified in the laboratory.

The data are believed to be representative of the specified sampling locations in Pool 15.

5.2.4 Completeness

Completeness is a measure of the amount of valid data obtained from a measurement system

compared to the amount that was expected to be obtained under correct, normal conditions.

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The number of field specimens for common carp, channel catfish, river carpsucker, and

freshwater drum met study objectives. Analytical data were validated based on; 1)

examination of chain-of-custody forms for appropriate custody trail and documentation; 2)

verifying that surrogate recoveries for the analyses fell within the range of 43 percent to 111

percent, and; 3) reviewing reported laboratory results with laboratory personnel to identify

potential transcription errors.

All surrogate recoveries for field data were within the specified control limits of 43 percent

to 111 percent. Surrogate recoveries for 10 of the 13 SRM samples exceeded the specified

surrogate recovery control limits. This suggests a potential high bias for the reported SRM

concentrations.

Daily catch and effort expended to collect fish samples from each site were transmitted to

EPA on a daily basis. Collection efforts proceeded until verbal approval was received from

the EPA Project Manager to discontinue sampling. The number of samples collected was

considered 100 percent complete for the current sampling conditions for channel catfish,

common carp, freshwater drum and river carpsucker. For these species no analytical data

were excluded for use in statistical analyses. The data were complete for smallmouth buffalo

at site 5. Sample sizes were insufficient for statistical analyses of total PCBs for smallmouth

buffalo at sites 2, 3 and 4, and for shovelnose sturgeon and flathead catfish at all sites.

5.2.5 Comparability

Comparability expresses the confidence with which one data set can be compared to another.

Field and laboratory procedures were developed in the sampling and analysis plan to enable

statistical comparison of the mean (upper 95 percent confidence interval of the mean) to the

specified Consent Order standard of 2.0 mg/kg total PCBs in fish filets. Analytical results

for SRM samples were not statistically different (p=0.05) from preliminary results when

tested using analysis of variance. A printout of the statistical analyses is provided in

Appendix D.

The comparability of the data generated during 1992 to previous years (1988 and 1990) must

be considered due to evolution of the fish sampling and analysis program. The location and

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size of the sampling sites, and the analytical methodology, have been modified from year to

year to use knowledge gained during each sampling event and incorporate refinements in

analytical protocols. A summary of changes in the program that affect comparability of the

data is presented in Table 7.

The sampling area for each of the sites was increased from 1990 as compared to 1988. The

sampling sites in 1992 were the same as in 1990 (with the exception that one less background

site was sampled in 1992).

The detection limit and the manner that the detection limit was used in calculation of total

PCBs has also varied among the sampling programs. During 1988 and 1990 the detection

limit for the various Aroclors was generally 0.1 mg/kg, and in 1992 ranged from 0.02 to

0.07 mg/kg depending on the Aroclor.

During 1988 and 1990, total PCBs were calculated as the sum of the individual Aroclors,

with the detection limit being used for Aroclors for reported nondetect values. During 1992,

detection limits were lower than previous years as indicated previously. Total PCBs were

calculated using the detection limit (for reported nondetects) for Aroclors reported above the

detection limit for one or more samples, and 50 percent of the detection limit for Aroclors

reported below the detection limit for all samples.

5.3 DATA ANALYSIS

Following calculation of total PCB concentration per sample using EPA's methods, each

datatset containing 10 or more samples was statistically evaluated using the W-Test (Shapiro

and Wilk, 1965) to estimate the probability distribution (i.e., normal, lognormal or other).

The W-test is one of the most powerful tests for detecting departures from a hypothesized

normal or lognormal density function (Gilbert, 1987). The test is applicable to sample sizes

of less than fifty (<50). Application of the W-test on environmental datasets enables

selection of the appropriate Minimum Variance Unbiased Estimators of the mean (MVUE)

and variance for use in statistical interpretation of the data.

The results of the W-test are provided in Appendix E. The W-test is used to test the null

hypothesis that a given dataset is normally distributed. Of the 17 datasets tested, 10 were

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normally distributed and 7 were lognormally distributed. For this study, if W-test results

indicated that both the normal and lognormal distributions were probable, the normal

distribution was selected. The arithmetic mean and 95 percent confidence intervals on the

population mean are reported for normally distributed datasets. If datasets were lognormally

distributed, the MVUE and 95 percent confidence intervals on the population mean were

calculated (Gilbert, 1987). The selected probability distribution for each dataset is presented

in Table 8.

The total PCB concentrations calculated for each species at each site and the upper 95 percent

confidence intervals for the means are summarized in Table 9.

Based on the mean concentrations, calculated as requested by EPA, the Consent Order value

of 2.0 mg/kg total PCB concentration was exceeded by the upper 95 percent CI of the mean

filet PCB concentration for the following species and sites:

Common Carp Sites 2, 3 and 4

River Carpsucker Site 2

The upper 95 percent CI of the mean PCB concentration in filets did not exceed 2.0 ppm

total PCB for the following species and sites:

Channel Catfish Sites 2, 3, 4 and 5

Common Carp Site 5

Freshwater Drum Sites 2, 3, 4 and 5

River Carpsucker Sites 3, 4 and 5

Smallmouth Buffalo Site 5

No statistical analyses were performed on flathead catfish and shovelnose sturgeon at any of

the sites or for smallmouth buffalo at Sites 2, 3 and 4, due to inadequate sample sizes.

6.0

REFERENCES

• Woodward-Clyde• Consultants

IIII EPA, 1990. Administrative Order On Consent in the matter of Aluminum Company of

America, Riverdale, Iowa. Docket No. 90-F-0027. Environmental ProtectionAgency, Region VII, Kansas City, Kansas.

• v EPA, 1991. Standard operating procedure no. 3240.2A. Organochlorine pesticidesand PCBs. 35p.

I EPA, 1992. Standard operatiing procedure no. 3210.3A. Preparation of fish samplesfor pesticide/PCB analysis. 7 p.

• Gilbert, R. O. 1987. Statistical methods for environmental pollution monitoring. VanNostrand Reinhold Co., New York. 320 p.

• Cheaper, S. S. and M. B. Wilk. 1965. An analysis of variance test for normality(complete samples). Biometrika 52:591-611.

™ WCC. 1992. Fish Sampling and Analysis Plan for Mississippi River Pool 15.Woodward - Clyde Consultants, Franklin, Tennessee.

YMA. 1990. Fish Sampling and Analysis Work Plan Mississippi River Pool 15.Young-Morgan & Associates, Franklin, Tennessee.

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• Mfoodward-Clyde_ Consultants

TABLES

TABLE 1. TOTAL NUMBER OF TARGET SPECIES COLLECTED BY SITE

SPECIES

Channel Catfish

Common Carp

Flathead Catfish

Freshwater Drum

River Carpsucker

Shovelnose Sturgeon

Smallmouth Buffalo

NUMBER OF INDIVIDUALS COLLECTED

Site 2

15

15

0

15

15

0

5

Site 3

15

15

3

15

15

0

8

Site 4

15

15

1

15

15

0

1

Site5

10

15

1

15

10

0

10

Total

55

60

5

60

55

0

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TABLE 2A. TOTAL NUMBER OF TARGET SPECIES COLLECTED BYELECTROFISHING

SPECIES

Channel Catfish

Common Carp

Flathead Catfish

Freshwater Drum

River Carpsucker

Shovelnose Sturgeon

Smallmouth Buffalo

Number of Individuals Collected

Site 2

13

14

0

6

7

0

2

Site 3

15

15

3

5

10

0

2

Site 4

12

15

1

3

11

0

1

SiteS

7

15

0

5

5

0

6

Total

47

59

4

19

33

0

11

TABLE 2B. TOTAL NUMBER OF TARGET SPECIES COLLECTED BYHOOP NETS

SPECIES

Channel Catfish

Common Carp

Flathead Catfish

Freshwater Drum

River Carpsucker

Shovelnose Sturgeon

Smallmouth Buffalo

Number of Individuals Collected

Site 2

0

1

0

9

8

0

3

Site 3

0

0

0

10

5

0

6

Site 4

3

0

0

10

4

0

0

SiteS

3

0

1

7

5

0

4

Total

6

1

1

36

22

0

13Note: Total Catch by Gill Nets was two channel catfish (Site 2), two freshwater drum (Site 4) and three freshwater drum (Site 5).

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TABLE 3. SUMMARY OF SRM ANALYSES

SAMPLEID

SRM #12SRM f f l3

SRM #14SRM #15SRM #16SRM #17SRM #18SRM #26SRM #28SRM #29SRM #31SRM #32SRM #33

DATEEXTRACTED

12/12/9212/9/9210/30/92

11/24/92

12/13/9212/3/92

12/7/9211/17/92

10/26/92

11/17/9211/6/9212/11/92

10/19/92

DATEANALYZED

1/1/93

12/12/9212/8/92

12/8/92

1/5/9312/8/92

12/11/9212/8/92

12/8/92

12/4/9212/8/92

12/21/92

12/8/92

Lipros(%)

11.0016.7317.8113.8517.9317.0714.2415.3715.9715.7915.6213.9518.61

SURROGATE

RECOVERY(%)

1151301369715612910313812611413498148

Mean

StandardDeviation

RSD (%)

TOTAL

PCBs(mg/kg)

10.9216.6517.73

13.77

17.85

16.99

14.16

15.29

15.89

15.71

15.54

13.87

18.53

15.60

2.08

13.3

%RSD calculated as the standard deviation divided by the mean.

TABLE 4. SUMMARY OF FIELD DUPLICATE ANALYSES

Sample Duplicate Blind

Total Total Total Standard

SAMPLE I.D. PCBs PCBs PCBs Mean Deviation(mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg)

2-CC-l2-CC-2

2:CC-3

2-CC^

2-CC-5

2-CC-6 -"V^

2-CC-7 ..,' ,'V

2-CC-82-CC-9 X%2-CC-10 '' f ' ' c ,2-CC-ll - /'' i:

2-CC-l 2

2-CC-l 3

2-CC-14

2-CC-15

3-CG<l

3-CC-2

3-CC-33-CC-4

3-CC-53-CC-6

3-CC-7

3-CC-83-CC-9

3-CC-10

3-CC-ll

3-CC-12

3-CC-13

3-CC-14

3-CC-15

., c,

0.68^2.22

3.36

3.84

3.11

0.69

3.87

3.294.41

1.52

0.43

0.24

0.65

4.56

2.27

7.92

1.53

9.894.84

6.740.26

9.57

2.310.34

0.67

2.14

2.63

6.47

0.34

1.48

a?V "

0.80~-j^./2.18 /.«.'/',

3.51

3.63

3.51

0.79

4.26

3.61

6.91

1.26

0.75

3.15

0.44

2.09

1.56

5.40

1.22

4.953.55

3.780.36

7.99

2.22

0.68

0.83

2.53

3.23

6.51

0.43

1.06

£<?[)

0.92-^,',3.16 r-'/.4.41

2.75

3.73

1.04

4.46

4.16

5.65

1.12

2.33

2.91

0.41~

2.45

1.50

4.76

1.23

5.903.98

5.14

0.34

5.83

1.920.59

0.74

2.33

3.73

6.12

0.36

1.54

0.80

2.52

3.76

3.40

3.45

0.84

4.19

3.68

5.65

1.30

1.17

2.10,

0.50

3.03

1.77

6.03

1.33

6.914.12

5.22

0.32

7.79

2.15

0.53

0.74

2.33

3.19

6.36

0.37

1.36

0.120.55

0.57

0.58

0.31

0.18

0.30

0.44

1.25

0.21

1.01>

1.61- V

0.13

1.33

0.43

1.67

0.18

2.620.66

1.48

0.05

1.88

0.200.17

0.08

0.20

0.55

0.21

0.0~5~

0.26

RSD

14.8

22.1

15.1

17.0

9.121.9

7.212.0

22.1

15.9

, ^ 7 6 . 8

44.1

24.2

27.7

13.2

37.915.9

28.4

16.8

24.1

9.532.3

10.8

8.617.3

3.412.9

19.2


TABLE 5. SUMMARY OF INTERLABORATORY ANALYSES

Sample

2-CC-13

2-RCS-ll

3-CC-103^CCF-4

3-CC-ll3-CC-13

3-CC-33-CC-4

3-CC-5

3-CC-6

3-CC-7 .

3-FHC-l

3-FWD-6

3-RCS-10

3-RqS-ll

3-RCS-13

3-RCS^153-RCS-2

3-RCS-3

3-RCS-4

3-RCS-5

3-SMB-15

4-CC-8

4-RCS-14

5-CC-4

5-RCS-3

Total PCBs (mg/kg)

EPA WW

0.512.47

0.79 i0.366.80 s16.46 ,.

28.79 x.7.02 ,-8.04 -•0.24

12.04 ,1.20

C2.34'\

1.60

2.68 ,0.47

2.15 -9.47 ,,•

0.121.12 -'

25.32 */1. 77

3.06

1.531.660.54

0.541.65

0.750.352.336.497.424.195.260.31

8.780.71

2.17 /0.590.510.431.282.67

0.21

0.587.541.082.54

1.231.580.68

RPD

(%)-5.739.85.22.897.986.9118.050.441.8-25.5

31.351.3

7.592.2

136.18.9

50.9112.0

-54.563.5

108.248.4

18.621.7

4.9-23.0

RSD

(%)4.028.13.72.069.261.4

83.535.7

29.618.0

22.1

36.3

5.365.296.26.336.079.2

38.644.9

76.534.2

13.115.4

3.516.2

I *?•I T

WW = WW Engineering & Science

•.' V ^>/ ^

TABLE 6. SUMMARY OF MATRIX SPIKE RECOVERIES

Sample

2-CC-l-SPK2-CC-3-SPK2-CC-4-A-SPK

2-SMB--1-SPK3-CCF-15-SPK3-CC-l-SPK3-RCS-7-SPK4-CC-6-SPK4-CC-15-SPK4-FWD-12-SPK4-SMB-l-SPK5-CC-6-SPK5-CG-ll-SPK5-FHC-l-SPK5-FWD-3-SPK5-RCS-10-SPK5-SMB-3-SPK5-SMB-5-SPK

7-CC-A-2SP

SPIKEDAroclor

1254^1254, If124812481254") --ft1254 / U-'1254\ !>?

1254 '['•' ' '1254 }?!}1254/ ' I-12481254\ '"^1254 \ < c ' b

1254 \ * 'r-1254 U^1254/ 1 '"•1254) <^12481248

SPIKEDCONC.

(ug/g) i

1.001.00

$'-- 1.001^ 1.00

1.001.001.001,001.001.00

\i$ 1.001.001.001.001.001.001.00

1 1

;,* i-oo]2~ i.oo

TotalPCBs

(mg/kg)

p^ 5.4X0V-A 5.04

1.211.651.470.881.631.461.231.27

1.161.241.910.700.941.400.750.75

SpikeRecovery

(%)

' &\ 63 l.°4-•74- 65... 134/.5| 86 P.l^

.02 83'.^• 6 3 98 »S1. ' * '> 63 -1-3

68^87889365v/'811069853-7910060 v"87

Mean Recovery 80

531/,loO1/ ,

^•'/«?&' / ,U';

j'i /

TABLE 7. VARIATIONS IN SAMPLING AND ANALYTICAL PROGRAMS FOR 1988, 1990 AND 1992

YEARSITE

LOCATIONMETHOD DETECTION

LIMITCALCULATION OF TOTAL PCBs

1988 During 1988, site locations weresmaller in area than during subsequentyears. In addition, Site 6 in 1988 wasSite 5 in subsequent years. Futuresampling was not conducted at the1988 Site 5 location.

The method detection limit for individualPCB Aroclors during 1990 was generally0.1 mg/kg.

Total PCBs were calculated as the sum ofindividual Aroclors, using the detection limitfor Aroclors reported below the detectionlimit.

1990 The sampling area for each of the siteswas substantially increased during1990. An additional background sitewas also included (Site 1). Site 6during 1988 was redesignated as Site 5

The method detection limit for individualPCB Aroclors during 1990 was 0.1 mg/kg.

Total PCBs were calculated as the sum ofindividual Aroclors, using the detection limitfor Aroclors reported below the detectionlimit.

1992 Sampling sites during 1992 remainedthe same as sites during 1990.However, Site 1 was not sampledduring 1992.

The detection limit for individual PCBAroclors during 1992 was 0.02 to 0.03mg/kg for Aroclors 1232 and higher, and0.07 mg/kg and 0.06 mg/kg for Aroclors1016 and 1221, respectively.

Total PCBs were calculated as the sum ofindividual Aroclors, using the detection limit(for reported nondetects) for Aroclorsreported above the detection limit for one ormore samples, and one-half the detectionlimit for Aroclors reported below thedetection limit for all samples.

II

TABLE 8. PROBABILITY DISTRIBUTION OF TARGET FISH ANALYTICAL DATASETS

SPECIES

Channel Catfish

Common Carp

Flathead Catfish

Freshwater Drum

River Carpsucker

Shovelnose Sturgeon

Smallmouth Buffalo

DADAIST DISTRIBUTION

Site 2

Normal

Normal

n < 10

Lognormal

Lognormal

n < 10

n < 10

Site 3

Lognormal

Normal

n < 10

Lognormal

Lognormal

n < 10

n < 10

Site 4

Normal

Normal

n < 10

Normal

Normal

n < 10

n < 10

SiteS

Normal

Lognormal

n < 10

Normal

Normal

n < 10

Lognormal

TABLE 9. MINIMUM UNBIASED ESTIMATES OF MEAN PCB CONCENTRATIONS (mg/kg)AND 95 PERCENT CONFIDENCE INTERVALS

SPECIES

Channel Catfish

Common Carp

Flathead Catfish

•->

Freshwater Drum,

vs"^

River Carpsucker

Shovelnose Sturgeon

Smallmouth Buffalo

Mean95% CINumber

Mean95% CINumber

Mean95% CINumber

Mean;>-JRange-^

Number

Mean

Number

MeanRange

Number

MeanRange

Number

TOTAL PCB CONCENTRATION (mg/kg)

Site 2

1.19(0.91 - 1.46)

75

2.54(1.72-3.37)

75

0.65(0.40 - 0.90)

75

1.88(0.33-3.43)

75

0

„

(0.27 - 2.22)5

Site 3

0.59(0.40 - 0.78)

75

3.25(1.80-4.70)

75

{0.30-0.71}3

0.44(0.27-0.61)

75

1.12(0.36-1.83)

75

0_ _

(0.27 - 3.45)8

Site 4

0.77(0.58 - 0.97)

75

1.52(0.97 - 2.07)

75

{0.43}1

0.76(0.53 - 0.98)

75

1.16(0.64-1.69)

75-"

0_ _

(0.4)7

SiteS

0.41(0.32 - 0.49)

10

0.52(0.35 - 0.69)

75

{0.37}1

0.48(0.33 - 0.63)

75

0.38(0.28-0.48)

10

0

0.89(0.38 - 1.40)*

10

-" indicates insufficient sample size (n < 10)* 95 Percent Confidence Interval

1 Woodward-Clyde• Consultants

I• FIGURE

I

I

I

I

I

I

I

I

I

I

I

I

I

I

Riverdale

Rivercfale*. Park

^n^\

\

:*/:*' &- s? ' —490 //A; .J. .V

JELLS ISLAND /&.£/ STATE PARK/ />[ . J' • .•/ S

r i' >

SiteiS

\

j Winnebago\iand

: '34,Site 4

|W. f--^

Sitej^li*"-

-••x

Site 2

^

/

Y" ILLINOIS

[ 1-

BoatRamp

Figure 1. 1992Fish Sampling Sites.

Woodward-Clyde Consultants


I APPENDIX A

• Field Data Sheets

I

I

I

I

I

I

I

I

I

I

I

I

I

I

Project: ALCOA Davenport 1992 Fish Study Task: Fish Sampling and Initial Processing

Location: Pool 15 Mississippi River Recorder:

Collectors: Todd Hunt, Tim Thompson, Don Spires, Dave Karkkainen Checked by:

2-CC-l 57(3 //A/

2-CC-2

2-CC-3 •il2-CC-4

2-CC-5 •7552-CC-6

2-CC-7 552-CC-8 /0052-CC-9

2-CC-10

2-CC-l 1 v/2-CC-12

2-CC-l 3

2-CC-14

2-CC-15 >/

V- 2-CCF-l 3812-CCF-2

2-CCF-3

2-CCF^t

2-CCF-5

2-CCF-6

2-CCF-7

2-CCF-8

2-CCF-9 3^52-CCF-10

2-CCF-ll

2-CCF-12\L

2-CCF-13

2-CCF-14

2-CCF-15 37V

Project: ALCOA Davenport 1992 Fish Study

Location: Pool 15 Mississippi River

Collectors: Todd Hunt, Tim Thompson, Don Spires, Dave Karkkainen

>X::-:- ••.;:•'' :Sample:ID' '? .

2-FWD-l

2-FWD-2

2-FWD-3

2-FWD-4

2-FWD-5

2-FWD-6

2-FWD-7

2-FWD-8

2-FWD-9

2-FWD-10

2-FWD-l 1

\2-FWD-12

\-2-FWD-13

V2-FWD-14

V 2-FWD-15

2-FHC-l

2-FHC-2

2-FHC-3

2-FHC^»

2-FHC-5

2-FHC-6

2-FHC-7

2-FHC-8

2-FHC-9

2-FHC-10

2-FHC-l 1

2-FHC-l 2

2-FHC-13

2-FHC-14

2-FHC-l 5

. :;.;: ' Total ;Ojngtfi '.(mm) '.'f

•Z8S

3/0.1072/1X43.3/5-3V13zq3 /93W31,03543^83383/ Q .

''^i^f^^if^l2S0

V 0 &305~

37®B I <3>

385• V / 53G5HIS&$i-5S3(^60S3MSV95c;/0

Task: Fish Sampling and Initial Processing

Recorder: /}£fc'

Checked by:

", :-:-. iiectipn;;;:Kiethq<i:::::::-:

//A1

//

(V

<^T=

I1

^P-

1X/y/v

1;

:;::3B* ;ffisViiw i;S;?^.^CpnuHents/Dat^^

0-7-X9--9- X_

//

V

<2> 7- ^ r' '~ <3 _

<?7-/9-9^

107- Z0- 97.

4/

V1




•'•: y : iji'^S jimjple'-jpO :V-'':: • 'i?:.: ':

2-RCS-l

2-RCS-2

2-RCS-3

2-RCS-4

2-RCS-5

2-RCS-6

2-RCS-7

2-RCS-8

2-RCS-9

2-RCS-10

2-RCS-l 1

2-RCS-12

2-RCS-13

2-RCS-14

2-RCS-15

2-SNS-l

2-SNS-2

2-SNS-3

2-SNS^

2-SNS-5

2-SNS-6

2-SNS-7

2-SNS-8

2-SNS-9

2-SNS-10

2-SNS-ll

2-SNS-12

2-SNS-13

2-SNS-14

2-SNS-l 5

; To%::p'ri '.(mni;).;:::-:

33^>3/feW3^><f

35£>30Y

2>8&>3^/3

333

33(0

438

t-W3

373

36 9

370

^^•^«^fOst^::^ ':

H7<DL/l&

/Z70"7V0r^.5

3?e>5^3?

.5" ,2 5"l-i(f>£-

*v<as"

/ 39S-

/0>:>.S'

8V^

7V5"7t75


Recorder: $£fc

Checked by:

:•••• -SlieciSotf J&t&df;

HNi>

^F

\I/V/./V

s^

I-INr£"/=•

i. -

/-/A/

AVA/

%^Gdmmeni^5ate^^<Z>~7-ri-<?^

II

0-7- /</-<*•%.

V

<x>~K?a>33

-* .•

a>-7-,&- 9»

Q>7- 3)-lZL\Ion, v«-- •? >-

t3"-7- 2 1-^v



Collectors: Todd Hunt, Tim Thompson, Don Spires, Dave KarkkaLnen•:•••::-.-. :-.-:-x-.-.-.-:-:- ----:-: :•:.:•.•:-:•:-:•••••:•:-•::•••:•::-.•:-•::

2-SMB-l

2-SMB-2

^2-SMB-3 /

-/2-SMB-4

2-SMB-5

2-SMB-6

2-SMB-7

2-SMB-8

2-SMB-9

2-SMB-10

2-SMB-ll

2-SMB-12

2-SMB-13

2-SMB-14

2-SMB-15

:?;;:-::;TptM::Ongtli;Xmm):0:..;:.

37Z

3^j^3H'

V2-I -3/33

(^65~7^0/3V5/2.^0

9Y$-

.Task: Fish Sampling and Initial Processing

Recorder: fle^

Checked by:•:•.:.;•;;•;.•: ••::.•:::;.:•:" £-:; ;.-::v'.-:.'.-??.!.;v ..;

'. ': IGpllection 1 NJe jiHod ] .;

///ve/=

#N/ fAJ£/^

•:-.-.::_.-:_:_; .•y-.-':::': :::v: v -:>>!:>V!'":::'?V:x:;-':::-':;v.:

•::-::- ;;Coirj nts5p| to|i0-7- /^ffi:

J0T-^-?lL

lJ>

a>i-3i-Qi




fTo&l : t^gtti' '(rain) •; .•:•- CpJiection :Method •-'

3-CC-l r/37 n 70T t3-CC-2

3-CC-3 (37 - /? -72-

\

\/

3-CCA 6033-CC-5 5313-CC-6 6H4 s

3-CC-7

3-CC-8

3-CC-9 7V53-CC-10

3-CC-l 1

3-CC-12

3-CC-13 570 ( 8 H O3-CC-14 ins3-CC-15

V 3-CCF-l

3-CCF-2

3-CCF-3 72- 9^53-CCF-4

3-CCF-5

3-CCF-6

3-CCF-7 365

3-CCF-8

3-CCF-9 42.0 £2.03-CCF-10

3-CCF-ll

3-CCF-12

3-CCF-13

3-CCF-14

3-CCF-15

<£>7 - / & - <3-FWD-l 3353-FWD-2

V I

V

VII

3-FWD-3

3-FWD^t 5553-FWD-5

3-FWD-6 /-/A/ 07-.

3-FWD-7 t3-FWD-8 7.\3~YWD-9

07-

V3-FWD-10

V3-FWD-11 33)5V3-FWD-12

3-FWD-14

3-FWD-15 28 ^L

3-FHC-l -x-7853-FHC-2

3-FHC-3 4 4-3-FIKM

3-FHC-5

3-FHC-6

3-FHC-7

3-FHC-8

3-FHC-9

3-FHC-10

3-FHC-ll

3-FHC-12

3-FHC-13

3-FHC-14

3-FHC-15

IV

/

J3

y4-(,

7

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1 1



Collectors: Todd Hunt, Tim Thompson, Eton Spires, Dave Karkkainen

: . r;;>:.:.j;$MpIe;ini|:;:.;yv- :,

3-RCS-l

3-RCS-2

3-RCS-3

3-RCS-4

3-RCS-5

3-RCS-6

3-RCS-7

3-RCS-8

3-RCS-9

3-RCS-10

3-RCS-l 1

3-RCS-12

3-RCS-13

3-RCS-14

3-RCS-15

3-SNS-l

3-SNS-2

3-SNS-3

3-SNS^t

3-SNS-5

3-SNS-6

3-SNS-7

3-SNS-8

3-SNS-9

3-SNS-10

3-SNS-l 1

3-SNS-12

3-SNS-13

3-SNS-14

3-SNS-15

; ôtaiifengtiti^mm) ":?.,

•3M

3<JJ

^5?VO

Bî-2<4®

^^ /333

33k

3fT/

3P5"

•^J t f>

-Vtn/33<D

V/6

^vo-y9©^7c;V7o

5^5^65^5-5-

ô>5"

<-l(a(D

73'£

9.^<2)

</9<z>g^^r


Recorder: -yT 77) O/>7/? J^-,

Checked by:

gCoUection'; Method •;:'.

£f-

^ /

SF

&F

HN

tirl

s. 1

^/^

^^^^Â

. '•'-. ;;:• ;;| (^mments/Da te' v

(trr-i-2- 9Î

I07-J9-92

/'>^

(5^7 -y^-9i

<Dl-30>-q^

^ /

rf?7- r><U - «7 !11

Y;

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V1ii ->.• ^iIiiiiiIiiiII




3-SMB-l

3-SMB-2

3-SMB-3

\3-SMB-4

V3^MB-5.

^ 3-SMB-6

V3-SMB-7

\-3-SMB-8

3-SMB-9

3-SMB-10

3-SMB-l 1

3-SMB-12

3-SMB-13

3-SMB-14

3-SMB-15

':'!:!::-:iTot -.lJCil tK;(lIUD)!./:::;::

O "^ ?

3<9£"7/ ^

5^X1V3GV7XV5"S"3&1-

•mmm&m*m^m*'\!:ii«^gte :i;-;f;:;v^<y5-

^75

1 0*~/(Z>OTU*0

/2.a ^;w<2>/©/ 0^feo


Recorder: T'.-rTl^mO^c^

Checked by:

£TF

*Js

if /V

HW

1-

^

V-7-V-V?.

^l<2-7-'tl-V2_

07-^-Qr-9"i-

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Collectors: Todd Hunt, Tim Thompson, Don Spires, Dave Karkkainen Checked by:. . . . - • . . . . . . - - - . - v . : . - . : . . v •-.-,

. Total! Length' (mm) ':

V4-CC-1- 2o • 9^_

VCC-2

V4-CC-3 59 /\4-CC-4

V4-CC-5 V5GV4-CC-6

V4-CC-7

Vi-CC-8 .-36U4-CC-9 //55

WcC- 10

k-cc-ii ^.58V-4-CC-12

\ V4-CC-13

\/4-CC-14

V4-CC-15 \ f

4-CCF-l

4-CCF-2 5354-CCF-3 9054-CCF-4 271 5/ 04-CCF-5 9804-CCF-6 3574-CCF-7

4-CCF-8

4-CCF-9 33 \4-CCF-10

4-CCF-l 1

\M-CCF-12 5"4-CCF-13

4-CCF-14 3%4-CCF-15

;•'.-"-. " ::-:'-ov^;-: "lL::Tr\' .:-:.".:'---..;;.:;;:. lioample li/v .- :•;•?.:•?

^•4-FWD-l

V 4-FWD-2

Ui-FWD-3

4-FWD-4

4-FWD-5

4-FWD-6

4-FWD-7

4-FWD-8

4-FWD-9

4-FWD-10

4-FWD-ll

4-FWD-12

4-FWD-13

4-FWD-14

4-FWD-15

4-FHC-l

4-FHC-2

4-FHC-3

4-FHC-4

4-FHC-5

4-FHC-6

4-FHC-7

4-FHC-8

4-FHC-9

4-FHC-10

4-FHC-ll

4-FHC-l 2

4-FHC-l 3

4-FHC-l 4

4-FHC-l 5

;::;:.;::.;.Total Length;- (miii) ;.:. :

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Collectors: Todd Hunt, Tim Thompson, Don Spires, Dave Karkkainen• ••:•:•• :::.-: .-:•: ••: :• .. ::.-x:.- :.. ...;;: .•:-.•.••;: :V:";::':'v.- V- :'•. ::.-:-.•.•:•:•::•••••:>••:::•:::•:•:•.•••.• •:•'•'••'•:• ::.-•- '•-•'•'<- . :-:iK^;ffi$atfpIe;:ID/i;:i:»•:• •••: :•: . : :•. .-.-: . . . •- -.-.- . . *>: •:•.-.-.-.•.•: : .-;• • .- :•--•.•' :•

4-RCS-l

4-RCS-2

4-RCS-3

4-RCS^t

4-RCS-5

4-RCS-6

4-RCS-7

4-RCS-8

4-RCS-9

4-RCS-10

4-RCS-l 1

4-RCS-12

4-RCS-13

4-RCS-14

4-RCS-15

4-SNS-l

4-SNS-2

4-SNS-3

4-SNS^

4-SNS-5

4-SNS-6

4-SNS-7

4-SNS-8

4-SNS-9

4-SNS-10

4-SNS-l 1

4-SNS-12

4-SNS-13

4-SNS-14

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4-SMB-l

4-SMB-2

4-SMB-3

4-SMB-4

4-SMB-5

4-SMB-6

4-SMB-7

4-SMB-8

«MB-9

4-SMB-10

4-SMB-ll

4-SMB-12

4-SMB-13

4-SMB-14

4-SMB-15

'Total^Length' (mm) ,

3)G,

\'\ Weight (g)'

M^3

Task: Fish Sampling and Initial Processbe

Recorder: f)£/^-

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' Collection Metfiod , ;

eF' /Commentsfl6l^'"'^77- Li-- V^

•' : -• •. * .-.-. .-.-••:•.••>-• -.- •. :•••• • • • • • • ••••:".' •'-•

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5-CCF-5

5-CCF-6

5-CCF-7

5-CCF-8

5-CCF-9 8305-CCF-10

5-CCF-l 1

5-CCF-12

5-CCF-13

5-CCF-14

5-CCF-15

5-FWD-l

5-FWD-2

5-FWD-3

5-FWD-4

5-FWD-5

5-FWD-6

5-FWD-7

5-FWD-8

5-FWD-9

5-FWD-1C

5-FWD-l 1

5-FWD-12

5-FWD-13

5-FWD-14

5-FWD-15

5-FHC-l

5-FHC-2

5-FHC-3

5-FHC^t

5-FHC-5

5-FHC-6

5-FHC-7

5-FHC-8

5-FHC-9

5-FHC-10

5-FHC-l 1

5-FHC-l 2

5-FHC-13

5-FHC-14

5-FHC-l 5

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5-RCS-4

5-RCS-5

5-RCS-6

5-RCS-7

5-RCS-8

5-RCS-9

5-RCS-10

5-RCS-l 1

5-RCS-12

5-RCS-13

5-RCS-14

5-RCS-15

5-SNS-l

5-SNS-2

5-SNS-3

5-SNS^

5-SNS-5

5-SNS-6

5-SNS-7

5-SNS-8

5-SNS-9

5-SNS-10

5-SNS-ll

5-SNS-12

5-SNS-13

5^SNS-14

5-SNS-15

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Collectors: Todd Hunt,:iSi«Y?i:::!:- s5 -';;:"::i;;s"::;SS.S ;:¥>immswfreiDMzm• . :•:•>.•:-:•:••:;•: •:••-.•••:•:•: •-.-.•*•: x-: .-.•-*v-"**-: <i?v.f&:

5-SMB-l

5^SMB-2

5-SMB-3

5^SMB-4

5-SMB-5

5^SMB-6

5-SMB-7

5-SMB-S

5-SMB-9

5-SMB-10

5-SMB-ll

5-SMB-12

5-SMB-13

5-SMB-14

5-SMB-15

Tim Thompson, Don Spires, Dave Karkkainen

^^^fe4«p»&5Vf:: :!&f : ? ;(l™)»

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35-^-r^M i(e

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^&<D-70>£

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1^35"

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FACE Ro-rCDT-^-^P

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1


I APPENDIX B

• Laboratory Processing Data Sheets

I

I

I

I

I

I

I

I

I

I

I

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11I1P. fcvl

|M^>

0,

1 i*\>

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JLVj'I'T/V J^JLOJCl JTJCVVy V^XÔOJLL>\J J^/lLX/JL JCVyJCV-LVJL

1992Date: 17'7'f^Pane: / of j

Processors: Z I';M. MlrLrle. . Cbu&Data Recorder:

Sample ID

ff-/far- i-n4i2-.fi-5-CC't-071tifr-fl5~- ££ -3 ' 0 "7 lloi2~A

• ) * v.*' ™' / C_^ f / On / «^_ "" ^7

^^ f I* f* — O — /"") ^"^ * / ^y o xl

5- CC- 4 07/^2- /?

*^ ^ — ** (xi " Cx / /^ / •* ~ '^

^" - x^*X" //- /~i""7// Ô - /^/

5'CC-/0-a7/6^-/?

5.'CC' 5- oiiLrf^-a5'fCC-<i.'Oiltf*A

<> '&-•*- m/M-J-S'CC-lô-)i<jt2.f\

S-LC-lj-Oli tAzfl-

5~U;\3-inihei*A5-H-i*-.cnik*»A

? '*&T-J-07iWz-A

TL(mm)

WT

(8)

</7SM%M|Wo,/5g

flTfX

tolb5W

bled

IWj f /\0

t *7G f\

tt%

\octt

\kofr9^4V30

SEX

/#A#$J$?o

$$J??o

?(T? .

^^

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WHOLE

^0

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mô .4*bi-9*/.$55?SSL10$3 So

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. / 7 JT

*/86<///«/-420

^/3 ?1^/G9tH2

L/7$

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"4?<2n<\47(*116

-445k/y ?'174

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COMMENTSSplit sample (SS),

duplicate sample (DS), BlindSample (BS)andWt(g)

|O~0</ S(S\\ -f^ S040*

/OO, ^/ /- £«<

Sample Identification: Site Number - Species - Replicate - Date - Sample Destination - Type ,

Sample Destination/TypeAmerican Analytical Laboratory - A * •EMS- Heritage Laboratory - EDuplicate Sample - DS

For Example: 2-RCS-1-71592 Received for ProcessingSample No. 2-RCS-1-71592-A goes to American Analytical

2-RCS-1-71S92-E goes to EMS - Heritage2-RCS-1-71592- A-DS goes to American Analytical as a Duplicate Sample

Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592 - A goes to American Analytical as a blind Sample

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l-Processing Date only goes to American Analytical

III f

II

IIIIIIIIItIIfI

Date: //"Page: /_

IOWA FISH PROCESSING DATA FORM1992

of

Processors: f / \ -Data Recorder:

1*

(P

f

Sample ID

- 7- 07179^- A

TL(mm)

WT

(g)SEX

wl

3I

f

0-t-

6

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WHOLE

I ZO

Ho.

tfl

s<t<l

GROUND

5$

\ \ 0

llo$02

102

Sample Identification: Site Number - Specie! - Replicate - Date - Sample Destination - Type

Sample Destination/TypeAmerican Analytical Laboratory - AEMS- Heritage Laboratory - EDuplicate Sample - DS

For Example: 2-RCS-1-71592 Received for ProcessingSample No. 2-RCS-1-71592-A

2-RCS-1-71592-E2-RCS-1-71592-A-DS

Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-7I592 - A

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l-Processing Date


duplicate sample (DS), BlindSample (BS)and Wt(g)

goes to American Analyticalgoes to EMS - Heritagegoes to American Analytical as a Duplicate Sample

goes to American Analytical as a blind Sample

only goes to American Analytical

.TJU3JU.

I

Date : / ft ' 7 "

1992

of

11 41 ti i1 : '11if1111m

Processors: IjOu « ; \fQ£M \Data Recorder: ^ ^

Sample ID

<S" P A/£> ~&~ Q~?I7<Y<3:$

^CCF-^'Dim^ft

5-CCF-^- .07/79^

Z~Wb-7-0-?l79J-fl

5-£U)b-b-07l71xfi

TL(mm)

WT

(g)

^Vo(0oO

\]<d

73(*yjb

SEX

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FILET WT(g)

WHOLE

;Voi ^7 ^/

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Z^•:

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GROUND

?0/-fc^330Wo??

•

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duplicate sample (DS), BlindSample (BS)

..

1Sample Identification: Site Number - Species - Replicate - Date - Sample Destination - Type

fl Sample Destination/TypejH American Analytical Laboratory - A

EMS- Heritage Laboratory - EDuplicate Sample - DS

1 -For Example: 2-RCS-1-71592 Received for Processing

Sample No.2-RCS-1-71592-E2-RCS-1-71592-A-DS

Blind Samples are designated ai Site No. 7Sample No. 7-RCS-1-71592- A

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l-Processing Date

goes to EMS - Heritagegoes to American Analytical as a Duplicate Sample

11 J ij

11( , ^

1 $$.' - V

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1 *§ \ <d

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IOWA FISH JPKOCiiSSJLINU DATA JbUKJM1992

Date: £ C> ~ 7" ft?Page: / of /

Processors: J\}u&, 7rAC«, MicnfJloData Recorder: Li^j^^J

Sample ID

vcrF~/-PTO;?-/?3'KBT-V-07,?C&-j4_3'CC-^-:v97/f^?:^S-C-C-/-b7/^-/4^3 ^? '/* x^ *• 7" ~™i i o^5 o» t^Li W\* -S^S {£ \__) f / f f ^ *

1'PiOb-) -QlltfZ-ti

3- ' PfiJD-J-Olim-R3 " /\C,5 ' /" o7/<?9ft*A

5"' ^A/lh'/O *0'/l$ej2-ft

5.-qC JS-S-o7ftl2-A-

5-FtifrlD'Olim-flS'ttte'to-oms-dT'/?C^'y-07/^-/f

^£5-J-07/^-//S'/7^-/^^?^?^-^5"- FUJC>'//-o7/8?Z-tf

TL(mm)

WT

(g)

fe-7J

^llfo

Iff* /

</#

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^25?2ffi

J$l$n501/^tysjjL/3/5

SEX

cT

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WHOLE

ait*177'Cfif

<-/(yo<

1 fc^

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tf(*\1<(%

151^Xlt

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<M

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Wo\W

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COMMENTSSplit Simple (SS),

duplicate sample (DS), BlindSample (BS)andWl(g)

Sample Identification: Site Number - Species - Replicate - Date - Sample Destination - Type


For Example: 2-RCS-1-71592 Received for Processing .Sample No. • 2-RCS-1-71592-A goes to American Analytical

2-RCS-1-71592-E goes to EMS - Heritage2-RCS-1-71592-A-DS goes to American Analytical as a Duplicate Sample

Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592- A goes to American Analytical as a blind Sample

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l -Processing Date only goes to American Analytical

iUVYA DATA *UKML1992

i i

i111 i l*p

f *on

" 19 Î A>P

1 v^^ t^

• *Y

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Date: «?/ ' 7" 7^Pace: / of ^

Processors: /tli(fr\(fll(,! Uaucj . 1 f(4C^Data Recorder: L>' t*j " ^

Sample ID

J-CCT-- y ft- n?m *•://•

a-CCF-G^'?/??'?-^

^-cCF-ôT/ffcMI'C.rf^WMy./l3-C(F-*i'01iK2-tf2'CJC.P-l-OHTtf'A2 .'C£f=-f- 07/W2- ft

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2-FM>-</-o im2 '0

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TL(mm)

#

WT(g)

Sfi

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t|9b410

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Sample Destinalion/TypeAmerican Analytical Laboratory - AEMS- Heritage Laboratory - EDuplicate Sample - DS

For Example: 2-RCS-1-71592 Received for ProcessingSample No. 2-RCS-1-7I592-A goes to American Analytical

2-RCS-1-71592-E goes to EMS - Heritage2-RCS-1-71592- A-DS goes to American Analytical as a Duplicate Sample

Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592 - A goes to American Analytical as a blind Sample

III

' TT rX JL'AOJUL A J JU»^3LJL/TL JL'

IIIIIIIIIIIIIII

Date: ^?/" /'Page: ^

1992

of

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Processors: /t/i'cnf ll&i -i^X^ , Jf&CMData Recorder: t^i't**' "

Sample ID

2-Pk)fc.<r.-'0tm2-A-H'KftT'5'PWi-fr

TL(mm)

WT(g)

W2

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SEX

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WHOLE

/34^3^

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Sample IdentiGcation: Site Number - Species - Replicate - Date - Sample Destination - Type

Sample Destination/TypeAmerican Analytical Laboratoiy - A

"• EMS- Heritage Laboratory - EDuplicate Sample - DS

For Example: 2-RCS-1-71592 Received for Proce»sjngSample No. 2-RCS-1-71592-A

2-RCS-1-71592-E2-RCS- 1-71 592- A-DS

Blind Samples arc designated as Site No. 7Sample No. 7-RCS- 1-7 1592- A

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l -Processing Date

11Iff £>

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M£r-<r0z?w-/i.«-\ - t\^\\^)- i. ~0~1 1 ^f<^2.A

•^ ' /?C5 " 5 •• olwtf 3' ft

2' C^' 12- 0^l^^z~fl2'RcS-<0*OH?}2'fl-l'CC'ISJ.o1\tf2'b

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Ukt/y?*!

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0.70

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<JZ&152%% .(05/1Ôfa1*\l3«/D

'65^3*70

G^"C)5WV/"/ '%&>3&)3$v3/03^0

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COMMENTSSplit sample (SS).


I


Sample Destination/Type. American Analytical Laboratory - A



2-RCS-1-71592-E goes to EMS - Heritage2-RCS-1-71S92- A-DS goes to American Analytical as a Duplicate Sample

111I fI t^

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3-RCS-3-o1ltfWy5fl& -3~ oifflj?-A$~£wt> "3 "O"? i^^? /I

6'^<^t?-g -oieq^l3" FOO.D^.5- 07/^^'^

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2i-flCS-3-c>7ffl2-fii-FW^-blim-fl5:pn)b'1'0lfl1fr(l'o - /9 /* C _ (j f}~~)i <SQ') - r\

TL(mm)

WT(g)

/O/O

44k

^V7o

V^fe5V?

^^

SEX

?

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£

•£

J

2

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.£50v/<?JV^

2^1$3?3

1.30mzotf11033V

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31*^52 .

30(=>i f DMb

»IO

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Sample IdcntiGcalioa: Site Number - Species - Replicate - Date - Sample Destination - Type




Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592 - A goes to American Analytical as i blind Sample

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l-Proccssing Date only goes to American Analytical

III; i

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y-ftcs-s- outfit- fl

TL(mm)

WT

(g)SEX

FILET WT(g)

WHOLE GROUND

0

512

I

tf

90

<f

1%

COMMENTSSplil umple (SS),

duplicate «ample 03S), BlindSample (BS)andWt(g)

Sample IdeotiGcation: Site Number - Spccici - Replicate - Date - Sample Destination - Type



2-RCS-1-71592-E2-RCS-1-71592-A-DS

Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592-A

Blank Samples arc designated as Site No. 8 -RBTSample No. 8-RBT-l-Processing Date

I JUJVYA JPi JdL UAJLA JFU-KJYJL

1992

Ij1

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t i l l f \ / -i''Processors: MicJU'Alf; / LW</ ^ Irac<tData Recorder: t~-\Z&-' ^

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r-CCF't-07/f^-//

£f&3~FUMt£Ollcr£l

5~CCF-7-d7ISU^

3-cc-i$-oiim-AS - F H b - l - o l l W - f l2- £t- lo-mmwn. f C- //-/97/99O-/J

3-c.CF1-:3'o-?i^2-)i3'r6-J-o-?/^:/?3-6C-|2 'n ih^-/J-

"\-cCF--i- 0111?;- /?^'•F^D-/|-o7/7%-Al

j-ccf-y-o-7/w-^^-PWft^ -o inn-A-2-O»cnrtf;z-;4^?G4c3^/^-/-o7/î^-P^ô-o7m^-4

3-CC';i/-0-;/^_^

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WT(g)

W

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3c/ttfl*

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duplicate sample (DS), BlindSample (ES)andWt(g)

>ample Identification: Site Number - Species - Replicate - Date - Sample Destination - Type

Sample Destinationn'ypeAmerican Analytical Laboratory - AEMS- Heritage Laboratory - EDuplicate Sample - DS

For Example: 2-RCS-1-7I592 Received for ProcessingSample No. 2-RCS-1-71592-A goes to American Analytical


Blind Samples are designated ai Site No. 7Sample No. 7-RCS-1-71592- A goes to American Analytical as a blind Sample

1111 <*1 'i .#

1111111II1I11I

JLVyTT.M. JL'JiOAJL JL AVVy

Date: /'/J*A 7*Paee: <£ "of ^

Processors:Data Recorder:

Sample ID

3-cC-H -cr/cm-A;?-CC-9-07)?£?-/?S-Mb-M-fi'ulV'A

TL(mm)

WT

(E)

IWm31*

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9.(f?

^--liOOJU^VT A^rVX^li JL' \-f .IXUM.

1992

FILET WT(g)

WHOLE

Ytf(^30

M

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J&?&0fat?^

•

dupli

Sample Identification: Site Number - Speciei - Replicate - Date - Sample Destination - Type


For Example: 2-RCS- 1-7 1592 Received for PrecedingSample No. 2-RCS-F-71592-A goes to American Analytical

2-RCS-1-71592-E goei to EMS - Heritage2-RCS-1-71592-A-DS goei to American Analytical as a Duplicate Sample


Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l-Proccssing Dale only goes to American Analytical

1Date: ^5" 3u


1=I^1 V

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1 *

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ti-KKl'l-oitiV-A.\ """ C^ C-/ ^-3 (_-/ / jCL/frf '* I*

/J — f* I ~ I) "~' (~)/ //~\/2** rl '

^^ 'CC'J-07^2

4-cc-b'oijon-f\3-^Mfe-5-(ypDT3-ft

5^^-/5"(?7^7;^z-^ i^c - "" 1 - r^~i jf>Q') - /i_x -*)M tj I \J /•* vYX /7

(/-P«0-,2-o7^»-^^/' i p / ^ c r ^ / -/-) 7"7rfij- fi

TL(mm)

1

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(E)

w7/00

3Vfcivf

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/?&>110

titf

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a«720

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^•73

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967^^\1<l

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Sample IdcntiGcation: Site Number - Species - Replicate - Date - Sample Destination - Type


For Example: 2-RCS-1-71592 Received for Processing

I

Sample No. 2-RCS-1-71592-A2-RCS-1-71592-E2-RCS-1-71592-A-DS

Blind Samplea are designated as Site No. 7Sample No. 7-RCS-1-71592 - A

Blank Samples are designated ti Site No. 8 -RBTSample No. 8-RBT-1-Processing Date

goes to American Analytical •goei to EMS - Heritagegoes to American Analytical as a Duplicate Sample

11}1•

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3-5/46-t-0720?2*

3 ^_5/vi B ~ *./ - 0 i^c>ci2-^5--CCF- 1-071092-A

*!' £Wb' 3 • 0'7309o- ft3'SrfB'8-07&jl-fl

4 - Rc3-/-c?7j>ofc'-/?(/, p ^ G - { -OTxfla-At|- P\CS'<^? • £)72ol3~fl

H-FlOb- /-O720?a-/l<./.££•£-£- 07207-2-p

^-CCF \l'ol^^P(Z-SM&'S-OTzoK-A

^-pflb'I 'OlJtfy-ALl'RCS'4-v73>72:AZ'Srtt, -*l'-0%iote-fl*'Ffo-tl-V7JOV-A'^-CCF-3-^72072-/?

3~Pb}D- 1 5- 072072-^

3-PtJ-O ~/2 -Olzofa-flif - ^(^5-5 -o~?3t>7;2-/l

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,K(?

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Sample Destination/Type \.American Analytical Laboratory - A ^\^^EMS- Heritage Laboratory - E - \Duplicate Sample - DS



Blind Samples are designated as Site No. 7Sample No. 7-RCS- 1-7 1592- A goes to American Analytical as a blind Sample

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT-l -Processing Date only goes to American Analytical

II; j

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( f 'CCP -

TL(mm)

WT

(g)SEX

9

cf

(f

cf

(f

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WHOLE GROUND

100

foe?

33%






2-RCS-1-71592-E2-RCS-1-71592-A-DS

Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592-A

Blank Samples are designated u Site No. 8 -RBTSample No. 8-RBT-l-Proceising Date



American Analytical

111• {t

1 ^

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JLUWA JbK>J

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^-CC'/l'O7ô^-/|

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3--RCS'tl'07JOte-./lt mLS~'l-ol2tf1-fLt-6n-in-rrt'8&n3tx * \cx / • * •* t^ »^ *

^CCF-//:^/?^

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\VT

(g)

mfi&J//72

653/o603fo

/35t,tf/0

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•ff -£?

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fll)5t>8.'?</{,(ft)75/

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/ 7<Y

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2-RCS-1-71592-E goes to EMS - Heritage2-RCS- 1-7 1592- A-DS goes to American Analytical as a Duplicate Sample

Blind Samples are designated u Site No. 7Sample No. 7-RGS-1-71592 - A goes to American Analytical as a blind Sample

A1 VAIVIM.

1992I 1

ft11' /? 77/ttData Recorder: 6 /'Z.*1-

Sample ID

s-c&'l-onxK'fi£/-RC3~/0*072ji2'flif'G'te'.rt-o'frJb.flt/-HJQ-i~o7/?/?2-#VfiC$-7-o77ot?v?3-CCF -1 2' 07321 M

% ' C. Ct~ * /3"07^/^2~/9

3- RC$ ' 7- olxffi'fll'$M£-5'0?jm-fl

3'Rc3*/3-b7so12-AfrMC-2-o72W24

Z-bCt-lO'-07&fr4•? r>^~"^ /O "(j / ffûi^2~''i

3'RCS'./S'07tdb.q3'tcf-s-o'tfofrft^ ** (— ~ \ "* / o "0 /v-fiy^H3 — /? /** c* //^~i — f~^D /r\i^)~u'\\ OO / Lx L/ /•^L// •* n

.rccp-/V-a7/^-^»^ l\(Ô / / ^< / X 0~M-" A7

TL

(mm)

•« v

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"7*7 *^

5? "7") ^9

~7'7o-/f 0

311'tft/bfa(*7o2j>?J

93^fry$2

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110<\t<l37^1fr-3l(,

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Sample Destination/T,ype• American Analytical Laboratory - A



2-RCS-l -7 1 592-E goes to EMS - Heritage•2-RCS-1-7I592-A-DS goes to American Analytical as a Duplicate Sample

Blind Samples arc designated as Site No. 7Sample No. 7-RGS-1-71592- A goes to American Analytical as a blind Sample

Blank Samples arc designated as Site No. 8 -RBTSample No. 8-RBT-l -Processing Dale only goes to American Analytical

1II1. •,1 ill

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3*fltf-;</-o7,?DW-A

fCGF--/</^7^/7

3-Fb)D-l5-073tfl3-A

yKcS'l-viJOb-Q2-ACS-M-OK3W-A3-CCF-/3-07^?/?-/1tfrffib' 7-Ol3tf?-fl3'ftCS'& ' 07zcft2~fl3- /^C'^r 07*292-4

3'^cS'/;^/^-/?j"CCF'^o7^^//^f(t^lJ.-o1Z7fr*ft^- l^tOO- 5-- O"?^/??'/^

o - l?C5-'^? ' Q~lsoei'2'{\7 ~ r\C^O ' 1 5" ~ t? //? P/ J? "//

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(g)

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Sample Destination/TypeAmerican Analytical Laboratory - A ;


For Example: 2-RCS-I-71592 Received for ProcessingSample No. 2-RCS-1-71592-A goes to American Analytical


Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592- A goes to American Analytical u a blind Sample

Blank Samples are designated as Site No. 8 -RBTSample No. 8-RBT- 1 -Processing Date only goes to American Analytical

IIIIIII

AV^ f » r x X'iOJUL A -i.VVyVx.liOO.U.'XVJr }Jt\.lt\. JL'V^JVIVA

iii

iiiii

Date: tf .Page: /_

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/ 7//Wl

t.<1

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Sample ID

- f COD- 1- 012111 -

TL

(mm)WT(g)

f/SO

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501

dot

330

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WHOLE

132

$8

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loo* s(*4~- 4o ePA

uAQfonnA

Sample IdentiGcatioa: Site Number - Species - Replicate - Date - Sample Destination - Type

Sample Destination/Type^American Analytical Laboratory - AEMS- Heritage Laboratory - EDuplicate Sample - DS


2-RCS-1-71592-E2-RCS-1-71592- A-DS

Blind Samples are designated as Site No. 7Sample No. 7-RCS-1-71592 - A

Blank Samples are designated ax Site No. 8 -RBTSample No. 8-RBT-l-Processing Dale

goes to American Analyticalgoei to EMS - Heritagegoes to American Analytical as t Duplicate Sample

1111 *1 1*• \\{1 *I ^

1 <<*

1 #

1111111I1I

IOWA FISI

Date: T.^ 3u/4 (*•PaEe: 2 </ of 2

Processors: load , lf*\jS)or\

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Sample ID

</- Pwfl - /3 " 0 73113- A^ 'F l^D' /O 'O72I(J2-R

if- f(tib ' fa - 072132-fl( j -gC$- $-07jtfl- ft*/' F W D ' b "073 'fl2- (\

2-CCF-/4-0?J/V-fl<J-r-W£>'l5' ol2ll3-ft

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For Example: 2-RCS-1-71592 Received for ProcessingSample No. 2-RCS-1-71592-A ^^ goes to American Analytical

2-RCS-1-71592-E goes to EMS - Heritage2-RCS-l -7 1 592- A-DS goes to American Analytical as a Duplicate Sample

Blind Samples arc designated as Site No. 7Sample No. 7-RCS-1-71592 - A goes to American Analytical as a blind Sample

* Woodward-Clyde• Consultants

I APPENDIX C

• Chain-of-Custody Forms

I

I

I

I

I

I

I

I

I

I

I

I

I

I

CHAIN OF CUSTODY RECORD V" ' 1088

\\

OEIt PROJECT NAME

AMPLERS: (Signature)

SAMPLE/IDENTIFICATION

<v- cc. - f - (D 7/9 9 o

3- cc- 3 - CD 7/9 9 a

^ cc- 1 • <X>7 1 Q Q 2

3 • < : < • y - cD7 '9Q;>J c c- S - 3>7lc tc /y

=> cr- (~- ci>7ll93

3- c c - 7 - <l>7f<>93

~ ) . c c . x ~ 07,993

3 • cc- 9 - <J>7 /992

^ ) - c c ;© - 07/9<?a

3- C.C - M - 007/993

P- CC • 13 ' <Z>7 /97£

J- < : r - >3 - «• 7/9 9^

p. c ^ • /V - a>7/9<?a..RELINQUISHED BY: (Signature)

"RELINQUISHED BY:

RELINQUISHED BY:

(Signature)

(Signature)

DATE

l-? .AfP .<)Z

*\

DATE/TIME-

DATE/TIME

DATE/TIME

TIME

.3^

SAMPLE

TYPE

r . A M

> /

NUMBER

OF

CONTAINERS

i

„RECEIVED BY: (Signature)

RECEIVED BY: (Signature)

RECEIVED AT LAB BY: (Signature)

/ANALYSES REQUIRED/ ^*

/ / / / / / /WOODWARD-CLYDE CONSULTANTS/ / / / / / / P.O. BOX 680925/ / / / / / / FRANKLIN, TN 37068-0925

/ 7 7 / / / / (615)790-0003 FAX (615) 790-0023

/W///^

^

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fNr>c,v^iS P., F PA

^AeVVio r^ 1^1 o- 3 9 ' ^25 • 3 A

RELINQUISHED BY: (Signature)


DATE/TIME

DATE/TIME

DATE/TIME



GENERAL COMMENTS5 K ; pp*>c' v / A T F O F A

Distribution: Orijinal «nd Yellow copies accompany sample shipment to laboratoryPink copy retained by samplers. Yellow copy retained by laboratory. Laboratory returns White copy to samplers.

CHAIN OF CUSTODY RECORDor V 1089

JOB # PROJECT NAME

9/A/7cP<Z>/ X \ L C O A - X ASAMPLERS: (Signature)

OrYt ^--yr T. -Ttior* fsa rt

SAMPmiDENJIFICATION

3' Cc - f S-- <2>7/9 9JJ

,0- cc f - 1 - G > 7 i q ^2

3- c c f- 3 •• d 7 ( 9 9 2.

?• ce p- 3 - <D7f'<?<?2

„•>. cr.-r.-y - <*7,9<-o

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2 - C C * • • • & - ^7^95

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p- cc -s-- 0-7 w^a . '^>- CC/ : ' - *7 - <T>7t^^y

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p. ^c /r. /a _ fr+rrv-f

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DATE

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IIIIIIIIIIIIIIIIII

I

PESTICIDE REPORT

Attn: Todd HuntWoodward-Clyde

Lab Reference: f 7817Sample Received: 08/04/1992Report Date: 08/12/1992Sample ID: SUPER Q 5 RINSATE

Compound

PCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-1260Surrogate Recovery

Results (/jg/L)

< 0.1< 0.1< 0.1< 0.1< 0.1< 0.1< 0.174%

Approved

IIII

IIIIIIIIIIII

Page 3 of

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde

Lab Reference # 7817

Sample Received: 08/04/1992

• Report Date: 08/12/1992

Sample Matrix: WATER

PROJECT* 91N7201 ALCOA-IA-FISH STUDY

Sample ID Analysis Results

SUPER Q 6 RINSATE PCS ATTACHED

I ••American AnalyticalV V Laboratories

I " 155O- 37lh Sireei. N.E. • P.O. BOX 3898 • Cleveland.TN 37320-3898 • (615) 476-7766. Fax (615) 476-9217

PESTICIDE REPORT


Lab Reference: # 7817Sample Received: 08/04/1992Report Date: 08/12/1992Sample ID: SUPER Q 6 RINSATE

Compound


Results (pg/L)

<<<<<<<

0.10.10.10.10.10.10.1

75%

Approved By __ ^~TT

IIII

Page 4 of

LABORATORY REPORT

Attn: Todd Hunt

Woodward-C lyde

Lab Reference f 7817




PROJECT* 91N7201 ALCOA-IA-FISH STUDYI

ISample ID Analysis Results

• SUPER Q 7 RINSATE PCB ATTACHED

I

I

I

I

I

I

I

I *Surrogate recoveries outside established acceptable limits due tosample emulsification.

I

I

I

American AnalyticalLaboratories

155O - 37lh Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O-3898 • (615) 476-7766. Fax (615) 476-92 I 7

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT



Compound


Results (pg/L)

< 0.< 0.< 0.< 0.< 0.< 0.< 0.63%

*Surrogate recoveries outside established acceptable limits due tosample emulsification.

Approved B

IIII

IIIIIIIIIII

Page 5 of

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde







I SUPER Q 8 RINSATE PCB ATTACHED


I55O - 37th Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O-3898 • (615) 476-7766. Fax (615)476-9217

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT



Compound


Results

< 0.1< 0.1< 0.1< 0.1< 0.1< 0.1< 0.177%

(pg/L)

Approved By

IIII

IIIIIIIIIII

Page 6 of 8

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde


_ Sample Received: 08/04/1992



PROJECTS 91N7201 ALCOA-IA-FISH STUDYI


I SUPER Q 9 RINSATE PCB ATTACHED


155O - 37th Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O3898 • (615) 476-7766. Fax (615) 476-9217

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT



Compound


Results ( g/L)

<<<<<<<

0.10.10.10.10.10.10.1

82%

Approved B

IIII

IIIIIIIIIIII

Page 7 of

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde



I Report Date: 08/12/1992




SUPER Q 10 RINSATE PCB ATTACHED

I


155O-37lh Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O3898 • (615) 476-7766. Fax (615) 476-9217

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT



Compound


Results ( g/L)

< 0.1< 0.1< 0.1< 0.1< 0.1< 0.1< 0.183%

Approved B

IIII

IIIIIIIIIIII

Page 8 of

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde





PROJECT! 91N7201 ALCOA-IA-FISH STUDY



• BM|American Analytical^Laboratories

I I55O - 37th Sireet. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O3898 • (615) 476-7766. Fax (615) 476-92 17

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT



Compound


Results

< 0.1< 0.1< 0.1< 0.1< 0.1< 0.1< 0.189%

( g/L)

Approved

• Woodward-Clyde_ Consultants

I Fish Blank Data

I

I

I

I

I

I

I

I

I

I

I

I

I

I

I

IIIIIII

WW Engineering & ScienceA Summit Cumjiam A N A I, Y T I C A I, S E K V I C E S

LABORATORY REPORTAttn: Todd HuntWoodward-Clyde357 Riverside Dr.P.O. Box 680925Franklin TN 37064

Lab Reference f 8832Sample Received: 12/16/1992Report Date: 12/22/1992Sample Matrix: FISH

PROJECT# 91N7201 ALCOA-IA

athorized Release of Data:

Project Manager

8-RBT-1-71492-A

I Sample ID

I

I

I

I

I

I

I

I

I

I

I

Analysis Results

PCB

Lipids

ATTACHED

5.9 %

1 ,r> 50 - 3 7 I li S I r e e I N E . \> O li ox 3 8 !) 8 . (; I e v c I ;i n (I . T N U 7 3 2 0 - 3 K i) H . f> I 5 / 4 1 (i - 7 7 (i (i K ;i x -17(1-9217

IIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A IN! A I, Y T I C A I., S IS R V I C IS S

PESTICIDE REPORT:


Lab Reference: f 8832Sample Received: 12/16/1992Report Date: 12/22/1992Sample ID: 8-RBT-2-71492-A

Compound Results


<0.05<0.05<0.05<0.05<0.050.08<0.0585%

I 1 5 5 0 - , ' J 7 lh S t r e e t NK. PO Box I .U59H. C l e v e l a n d . TN 3 7 3 2 0 - 3 H 9 B . 0 1 5/4 7 <> - 7 7 ( i ( i F ; i x 4 7 0 - 9 2 1 7

I

II WW Engineering & Science

A Summil ton/any A N A L V T I C 3*911, 2 g^E Rl? I C E S

LABORATORY REPORT

IAttn: Todd Hunt

Woodward-Clyde


| Sample Received: 12/16/1992

Report Date: 12/22/1992

Sample Matrix: FISH

PROJECT* 91N7201 ALCOA-IA

8-RBT-2-071792-A PCB ATTACHED

Lipids 5.1 %

I

I

• Sample ID Analysis Results

I

I

I

I

I

I

I

I

I

I

I 1550 - 3 7 111 S U - c c t NK. IM) Box 3898. C l e v e l a n d . 'IN 3 7 3 2 0 - 3 8 !) 8 . 0 1 ">/ 4 7 (i - 7 7 (i (i V i \ \ - 1 7 ( 1 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A I, Y '[' I C A I, S K R V I C E S

PESTICIDE REPORT:


Lab Reference: # 8832Sample Received: 12/16/1992Report Date: 12/22/1992Sample ID: 8-RBT-2-071792-A

Compound Results


<0.05<0.05<0.05<0.05<0.050.03<0.0593%

1 5 5 0 - 3 7 111 Si r e e l NK. P () Box 3»9H. C I c v u I ;i n (I . T N 3 7 3 2 0 - HH 9 H . G 1 5/4 7 (i - 7 7 6 (> I-1 ;i x 4 1 6 - 9 2 I 7

IIII

IIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A L Y T I C A I. S E K V I C E S

PESTICIDE REPORT:


I Lab Reference: # 8832Sample Received: 12/16/1992Report Date: 12/22/1992

• Sample ID: 8-RBT-2-071792-A SPIKE

Compound Results

PCB-1248 97 % Recovery

Surrogate Recovery 93 % Recovery

1550 - 37th Si reel NK. IJ O Box 3898. C I c \ c 1 ;i nd . TN 37320-3808. fi I ">/4 7 0 - 7 7 (> fi I-1 ;i x -4 7 (i - !) 2 I 7

HW Engineering & ScienceA SummiL Company A N A L Y T I L* SfK R1?' I C E S

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde




Sample Matrix: FISH



8-RBT-3-071892-A PCS

Lipids

ATTACHED

5.6 %

1550 - 37th Street, N K . PO Box 3 8 9 t! . C I c v c I ;i n <l . TN 3 7 .'{ 2 0 - 3 8 !) H , 6 1 5/ 4 7 6 - 7 7 H (i K;i.\ 'I 7 G - !) 2 I 7

IIIIIIIIIIIIIIIIIII

W\V Engineering & ScienceA Summit Company A N A L Y T I C A L S E R V I C E S

PESTICIDE REPORT:



Compound


Results ( g/g)

<0.05<0.05<0.05<0.05<0.050.04<0.05101%

1 5 5 0 - 3 7 t tl S t r e e t N E . P O Box 3898. C I c v o I ;i n (I . T N 3 7 3 2 0 - 3 8 9 8 . (i I 5 / -I 7 (i - 7 7 fi f> K ;i x 47 0 - 9 2 I 7

II WW Engineering & Science -0 . , .,

A Summit a,m,*,,y A N A L Y T I C P#"f, * Sf E R1? I C IS S

II

IIIIIIIIIIIIII

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde


I Sample Received: 12/16/1992


Sample Matrix: FISH




Lipids 5.7 %

1 5 5 0 - 3 7 t h Si r e e l N K . PO Box 3808. C l e v e l a n d . TN 3 7 3 2 0 - 3 8 9 8 . G I 5/-4 7 6 - 7 7 (> (i K ; i x A 7 0 - 9 2 I 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summii Company A N A L Y T I C A L S li R V 1 C K S

PESTICIDE REPORT:



Compound Results


<0.05<0.05<0.05<0.05<0.050.05<0.0592%

1 5 5 0 - 3 7 III S t r e e t N IS . I'D U <> x H H 9 8 . C l e v e l a n d . T N 3 7 3 2 0 - !U(!) 8 . 0 I 5/-1 7 0 - 7 7 GO Fax - 1 7 0 - 9 2 1 7

II

HW Engineering & Science p 5 f ,4 Summit Company A l\ A L 1 I I C A9Tj 3 b R V I C E S

II

IIIIIIIIIIIIII

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde




Sample Matrix: FISH

PROJECT! 91N7201 ALCOA-IA



Lipids 9.8 %

1550 - 3 7 l l i S t r e e t N K . P O 15 o x 38 !) 8 . C I u v e I a M (I . TN 3 7 3 2 0 - 3 8 9 8 . 0 1 5 / 4 7 0 - 7 7 0 0 l ; i ; i . \ 4 7 0 - 0 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A I., Y T 1 C A L S K R V I C E S

PESTICIDE REPORT:



Compound


Results (pg/g)

<0.05<0.05<0.05<0.05<0.050.06<0.05108%

1 5 5 0 - 3 7 t h S l r u c l NE. P O Box 3 H 9 B . C I c. vc I ;i n (I . T N 3 7 3 2 0 - 3 H 0 8 . (! I 5/4 7 6 - 7 7 (i (i K ;i x -4 7 (> - 0 2 I 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A 1, Y T I C ifcgfc 6 <$f E Ri? I <; [;; s

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde

Lab Reference I 8832



Sample Matrix: FISH



8-RBT-6-072292-A PCB

Lipids

ATTACHED

7.9 %

1 5 5 0 - 3 7 t h Si re el. NE. PO 15 o x 3 8 !) M . C I <; v i: I ii n (1 . T N 3 7 3 2 0 - 3 8 9 8 , 0 I 5/4 7 0 - 7 7 0 <> K ; i . \ - 1 7 0 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

W\V Engineering & ScienceA Summil Company A N A I. Y T I C A I, S E R V I C E S

PESTICIDE REPORT:



Compound


Results (pg/g)

<0.05<0.05<0.05<0.05<0.050.060.02

104%

1 5 5 0 - 3 7 U i Si re el N K . PC) Box 3898. C 1 c v <; I ;i n d . TN 3 7 3 2 0 - 3 8 9 8 . (i 1 5/ I 7 0 - 7 7 (i (i l - ' : i . \ 4 7 0 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A L Y T I ( : R x? I C E S

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde




Sample Matrix: FISH

PROJECT! 91N7201 ALCOA-IA


8-RBT-7-072392-A PCB

Lipids

ATTACHED

8.6 %

1550 - 3 7 111 S tree I N E . IJ() Hox 3H9H. C l e v e l a n d . TIM 3 7 'J 2 0 - 3 8 <) 8 . fil 5/4 7 0 - 7 7 G (i F;ix 4 7 <> - 9 2 1 7

IIIIIIIIIIIIIIIIIII

W\\/ Engineering & ScienceA Summit Company A N A 1, Y T I 0 A L S E R V I C E S

PESTICIDE REPORT:



Compound


Results (pg/g)

<0.05<0.05<0.05<0.05<0.050.06<0.0594%

1 5 5 0 - 3 7 111 S t r e e t NE. PO Box 3 8 9 H , C I c. v e I ;i n (I . TN 3 7 3 2 0 - 3 8 9 8 . (il 5/4 7 0 - 7 7 G <> K ; i x 4 7 (i - 9 2 I 7

IWW Engineering & ScienceI

II

A Summit (jiinpany A N A I, Y T I CWT,8?? fE R1?' I C li', S

LABORATORY REPORT


Attn: Todd Hunt

Woodward-Clyde


| Sample Received: 12/16/1992

— Report Date: 12/22/1992

™ Sample Matrix: FISH

• PROJECT* 91N7201 ALCOA-IA

I8-RBT-8-072492-A PCB ATTACHED

I Lipids 4.4 %

I

I

I

I

I

I

I

I

I

I 1 5 5 0 - 3 7 Hi S t r e e I ME. PO Box l U i U H . C 1 c v c. I ;i n d . TN 3 7 3 2 0 - 3 8 9 8 . 0 1 5 / 4 7 0 - 7 7 0 0 K ; i . \ 4 1 (i - 9 2 1 7

IIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summil Company A N A I. Y T I C A I. S K R V I C K S

PESTICIDE REPORT:



Compound


Results

<0.05<0.05<0.05<0.05<0.050.02<0.0583%

I 1 5 5 0 - 3 7 t h Si. r e e l NE. IM) Box 3898. C I <: v u I ;i n <l . TN 3 7 3 2 0 - 3 8 9 8 . (i 1 !>/ 4 7 G - 7 7 (Hi K . - i x - 1 7 0 - 9 2 1 7

IIII

W\V Engineering & ScienceA Summit Company A N A I, V T I C f A^ 9 S f E R1*' 1 C K S

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde


J Sample Received: 12/16/1992


Sample Matrix: FISH


I

I

I Sample ID Analysis Results


I Lipids 11 %

I

I

I

I

I

I

I

I

I

I 1 5 5 0 - 3 7 Hi S t r e e 1. NE. I'O Box 3 H f) H . C I c. v c I ;i n (I . TN 3 7 3 2 (I - 3 8 it 8 . G I 5 / 4 7 G - 7 7 G G l<" ;i x 4 7 0 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A I, Y T I C A L S E R V 1 C K S

PESTICIDE REPORT:



Compound


Results (pg/g)

<0.05<0.05<0.05<0.05<0.050.07<0.05102%

1550 - 3 7 l h S t r e e t N K . P O B o x 3 898. C, I <: v e I ;i n (I . T N 3 7 3 2 0 - 3 8 <J 8 , 6 I r> / A 1 G - 7 7 (i (> l;i n x -4 7 (i - 9 2 I 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A L V T I I C E S

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde

Lab Reference * 8832



Sample Matrix: FISH



8-RBT-10-072792-A PCB

Lipids

ATTACHED

7.0 %

1 5 5 0 - 3 7 t h St. r e e l NE. P O Box 3 H 9 H . C l e v e l a n d . TN 3 7 3 2 0 - 3 8 !) R . (i 1 5/ 4 7 (i - 7 7 f> fi F ;i ,\ -1 7 G - 9 2 I 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A I, Y T I C A I- S li) R V I C E S

PESTICIDE REPORT:



Compound


Results (n<3/<3)

<0.05<0.05<0.05<0.05<0.050.070.02105%

1 5 5 0 - 37 th Si r e e l ME. PO Box ;< » 9 U . C l e v e l a n d . T N 3 7 3 2 0 - ;i H 9 H . <> I 5/4 7 0 - 7 7 0(1 F ; i \ 4 7 0 - 9 2 1 7

I_ \VW Engineering & ScienceM A Summit Company ANA 1, Y T I (7WLA19fE R *? I C li S

II

IIIIIIIIIIIIII

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde

Lab Reference f 8832



Sample Matrix: FISH




Lipids 6.06 %

1 5 5 0 - 3 7 Ih Si r e e l NE. PO 13 o x 3 B O H . C l e v e l a n d . TN 3 7 3 2 0 - 3 8 !) 8 . f> 1 5/4 7 6 - 7 7 (i (i K J I X 4 7 G - !l 2 I 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Sum/nil Company A N A I., Y T I G A L S K R V I C E S

PESTICIDE REPORT:



Compound


Results

<0.05<0.05<0.05<0.05<0.050.04<0.05102%

1 5 5 0 - 3 7 th Si. r ee l NE. P O Box 3 8 !) » . C I c vc. I ;i n tl . T N 3 7 3 2 0 - 3 H 0 8 . (i I 5/4 7 (i - 7 7 (H> Fax 4 7 ( 5 - 0 2 1 7

II

MW Engineering & ScienceA Summit Compan? ANA I., V T I CFWMJL2 S^E R *? I C E S

II

IIIIIIIIIIIIII

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde




Sample Matrix: FISH




Lipids 5.5 %

1 5 5 0 - 3 7 t h Si r ee l . N E . P O Box 3898. C l e v e l a n d . TN 3 7 3 2 0 - 3 R 9 8 , (> I 5/4 7 0 - 7 7 (i (i Kax - 4 7 6 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Comiany A N A L Y 'I' I C A I, S E R V I C E S

PESTICIDE REPORT:



Compound Results


<0.05<0.05<0.05<0.05<0.050.050.0280%

1 5 5 0 - 3 7 I li S 11- c c t ME. I' O Ho x :< 8 0 H , C I u v c I ;i n (I . T N 3 7 3 2 0 - H H <J 8 . K ii x - 1 7 0 - 9 2 1 7

IIIII

WW Engineering & ScienceA Summit Company ANA I.. V T I C A L S E R V I C E S

I

I

I

I

I

I

I

I

I

I

I

I

I

PESTICIDE REPORT:


Lab Reference: # 8832Sample Received: 12/16/1992Report Date: 12/22/1992Sample ID: REAGENT BLANK

Compound Results (/^g/g)

Surrogate Recovery 79%

- 3 7 111 S t r e e t IN! E . PC) U o x 3 8 OH. C 1 c vc I ;i ml . TIM 3 7 3 2 0 - 3 H 9 8 . G 1 !>/'! 7 G-7 7 (1G K 11 x -4 7 (» - !) 2 I 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit dampany A N A L Y T I C A L S LI R V I C K S

PESTICIDE REPORT:


Lab Reference: # 8832Sample Received: 12/16/1992Report Date: 12/22/1992Sample ID: LAB CONTROL

Compound


Results (pg/g)

<0.05<0.05<0.05<0.050.82<0.05<0.0569%

1 5 5 0 - 3 7 Ih S t r e e t NE. I'O Box 3 H ! ) H . C I <: v c I ;i n <l . TN 3 7 H 2 0 - SH9 8 . <> 1 5/4 7 G - 7 7 (i (i \- ;i x 4 7 6 - 0 2 I 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A L V T I C A I.. S I:'. K V I C E S

STATEMENT OF DATA QUALIFICATIONS

CLIENT: Woodward-Clyde

SOBMITTAL: 8832

X All analyses have been validated and comply with our QualityControl Program. No qualifications required.

The following analyses have been qualified for the reasons cited.

Sample No. (s): Parameter: Reason:

Explanation:

Sample No. (s): Parameter: Reason:

Explanation:

REASON

1. Sample integrity suspect upon receipt (explain).

2. Analysis performed beyond EPA established maximum allowable holding time.

3. Detection limit elevated due to matrix interferences.

4. Laboratory control sample value outside established acceptable limits.

5. Matrix spike sample value outside established acceptable limits.

6. Duplicate analysis value outside established acceptable limits.

7. Surrogate/internal standard recoveries outside established acceptablelimits.

8. Data point suspect due to potential laboratory contamination (explain).

9. Coelutes with the compound cited. Result may represent a combinationof both compounds.

10. other (explain).

NOTE: This document is included as part of the Analytical Report for theabove referenced submittal and must be retained as a permanent recordthereof.

1550 - 37th Strci-. I ME. IT) Box 3«98. (.'. I c vc I ;i n (I . TN !< 7 3 2 0 - H 0 !) 8 . (> I 5 / 4 7 (> - 7 7 (i (i K;i\ -4 7 (i - !) 2 I 7

' Woodward-Clyde_ Consultants

| Field Data

I

I

I

I

I

I

I

I

I

I

I

I

I

I

I

TABLE Al-1. 1992 DATA SUMMARY FOR PCBs IN FISH

ALL92DAT.XLS(9/iW3)P tge lo f l l

SAMPLE I.D. SPECIES

2-CCF-l

2-CCF-22-CCF-32-CCF-42-CCF-52-CCF-62-CCF-72-CCF-82-CCF-92-CCF-lO2-CCF-ll

2-CCF-l 22-CCF-l 32-CCF-l 4

2-CCF-l 52-CC-\ /2-CC-l-A^DS)2-CC-l-SPK7-CC-1-A-2 62-CC-22-CC-2-A-DS7-CC-2-A-22^CC-3 —2-CC-3-A-DS

2-CC-3-SPK7-CC-3-A-2

2-CC-42-CC-4-A-DS2-CC-4-SPK7-CC-4-A-2\2-CC-52-CC-5-A-DS7-CC-5-A-22-CC-62-CC-6-A-DS7-CC-6-A-22-CC-72-CC-7-A-DS7-CC-7-A-2

CCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCF

JX CC

CCCC

Ut',.s___J3C

CCCCCC

- — ccCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

SITE

222222222222222222222222222222222222222

DateExtracted

10-23-92

10-23-9210-23-9210-23-9210-23-9210-23-9210-26-9210-26-9210-26-9210-26-9210-26-9210-26-9210-26-9210-26-9210-26-9210-08-92

' 12-22-9210-19-9212-22-9210-08-9212-22-9212-22-9210-08-9212-20-9212-20-9212-20-9210-08-9212-22-9212-22-9212-22-9210-08-9212-20-9212-20-9210-08-9212-20-9212-20-9210-08-9212-20-9212-20-92

DateAnalyzed

11-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-921 1-25-92 _10-13-921-13-9310-20-921-13-9310-13-921-15-931-15-9310-13-92_

1-12-931-12-931-12-93...10-13-92

—1-13-931-13-931-13-93

10-13-921-12-931-12-9310-13-921-13-931-12-9310-13-921-12-931-12-93

Aroclor Concentration (mg/kg)

<<<<<<<<<<<<<<<<<<<<<<<<<

--X<<<<<<<<<<<<<

1016

0.07 •

0.07 •0.07 •

0.07

0.070.07

0.070.07

0.07

0.070.07

0.07

0.07

0.070.07

0.07

0.07

0.07

0.07

6.07

0.07

0.07

0.07

0.07

0.07

0.07

0.070.07

0.070.07

0.07

0.07

0.07

0.070.07

0.07

0.070.070.07

1221

= 0.06 •

; 0.06 <c 0.06 •

s 0.06 •

c 0.06' 0.06

« 0.06c 0.06

< 0.06< 0.06

<: 0.06

< 0.06

< 0.06< 0.06

<: 0.06

< 0.06

< 0.06

< 0.06

< 0.06< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06< 0.06

< 0.06< 0.06

< 0.06

< 0.06< 0.06

< 0.06

< 0.06< 0.06< 0.06

< 0.06

1232

c 0.02 <

: 0.02 «c 0.02 <

c 0.02 <

s 0.02 •= 0.02

< 0.02< 0.02

< 0.02< 0.02

= 0.02 •

< 0.02

< 0.02< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02< 0.02< 0.02

< 0.02

1242

: 0.02

: 0.02

: 0.02' 0.02

= 0.02c 0.02

= 0.02c 0.02

c 0.02c 0.02

c 0.02

f 0.02

< 0.02

< 0.02c 0.02

•c 0.02

< 0.02

< 0.02

< 0.02

< 0.02~< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02 _

< 0.02

< 0.02

< 0.02< 0.02

< 0.02

< 0.02

< 0.02< 0.02

< 0.02

< 0.02< 0.02< 0.02

< 0.02

1248

0.42

0.63

0.080.53

0.580.48

0.260.19

0.160.30

0.22

0.04

0.38

0.250.54

0-04

0~330.20

0.40

6.76

1.03

1.70

2.452.64

3.76

_ 3.37 .

;U5.1.51

(^TTi1.10

1.76

2.07

2.160.44

0.50

0.62

1.631.982.05

1254

0.56

1.05

0.311.011.34

0.81

1.010.76

0.330.690.44

0.40

0.60

0.370.74

(6"jfr>oL

p.04J0.35

" 1.270.911.16

<££0.641 34~ v

0.792.141.502.141.241.101.061.180.130.180.301.761.591.69

Total

PCBs

Total Surrogate

PCBs Recovery1260 (mg/kg) (mg/kg)

0.050.100.030.110.140.080.070.100.020.060.030.020.090.030..070,04 JJ'f

0.07 L <0.04 ,'0.08

0.100.15

0.21

~oiai~" '0.14

0.21 C

0.16

0.46

0.53.0.62

0.32

0.16

0.29

0.300.03

< 0.02

0.040.390.600.63

1.121.87

0.51

1.742.151.45

1.421.13

0.60

1.140.780.55

1.160.74

1.44

1)768

0.80

X3Z

t^t_i^m

2.222.18

-3-'-6^3.36~3.51

.5.40.

"4^3.84

(3.6335X)4'

2.753.11

3.51

3.730.69

0.791.043.87

4.264.46

1.12 y?1-8V//0.5K/O

\.14^^2.15 SK4TN

/1 .42 Jll.ll/

0"60\/\.\4S

0.78 \Sr

Q.Wr/

1.16*/0.74 -/^1.44 •/

.' (6.80 >

/ '//2.52

~\ 3.76

//

3.40

3.45

0.84

4.19

(%)

9195

'90^84

90929990808087941038578728867 -

9371679973761009666791045175989071949673102106

Lipids

4.84

7.952.01

10.11

6.857.38

5.946.44

2.686.03

5.724.315.47

6.98

6.26

9.9512.16

11.03

12.82

2.72

3.553.46

4.22

5.75

4.99

5.18

0.78

2.192.20

2.325.05

5.51

6.292.04

2.10

2.325.428.148.35

Spike

Recovery

63% Rec

(1254)

65% Rec

(1254)

86% Rec

(1248)

TABLE Al-1. 1992 DATA SUMMARY FOR PCBs IN FISH

ALL92DAT.XLSWVW)P«ge2ofll

SAMPLE I.D.

2-CC-8

2-CC-8-A-DS

7-CC-8-A-2

2-CC-9

2-CC-9-A-DS

7-CC-9-A-2

2-CC-10

2-CC-10-A-DS

7-CC-10-A-2

2-CC-ll

2-CC-ll-A-DS

7-CC-11-A-2

2-CC-12

2-CC-12-A-DS

7-CC-12-A-2

2-CC-13

2-CC-13-A-DS

7-CC-13-A-2

7-CC-13-A2SPK

2-CC-14

2-CC-14-A-DS

7-CC-14-A-2

2-CC-15

2-CC-15-A-DS

7-CC-15-A-2

2-FWD-l

2-FWD-l-Rep

2-FWD-2

2-FWD-3

2-FWD-4

2-FWD-5

2-FWD-6

2-FWD-7

2-FWD-8

2-FWD-9

2-FWD-10

2-FWD-l 1

2-FWD-12

2-FWD-I3

SPECIES

CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

FWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWD

SITE

222222222222222222222222222222222222222

Date

Extracted

10-08-92

12-20-92

12-20-92

10-08-92

12-20-92

12-20-92

10-08-92

12-20-92

12-20-92

10-08-92

12-20-92

12-20-92

10-08-92

12-20-92

12-20-92

10-23-92

12-19-92

12-19-92

12-19-92

10-23-92

12-19-92

12-19-92

10-23-92

12-19-92

12-19-92

10-26-92

10-26-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

Date

Analyzed

10-13-92 <

1-12-93 <

1-12-93 <

10-13-92 <

1-12-93 <

1-12-93 <

10-13-92 <

1-12-93 <

1-12-93 <

10-13-92 <

1-12-93 <

1-13-93 <

10-13-92 <

1-12-93 <

1-12-93 <

11-25-92 <

1-11-93 <

1-11-93 <

1-11-93 <

11-25-92 <

1-11-93 <1-11-93 <11-25-92 <1-11-93 <1-11-93 <11-30-92 <

11-25-92 <

11-26-92 <

11-26-92 <

11-26-92 <

11-26-92 <

11-26-92 <

11-26-92 <

11-26-92 <

11-26-92 <

11-26-92 •

11-26-92 <

1 1-26-92 <

1 1-26-92

Aroclor Concentration (mg/kg)

1016

0.07 <

0.07 <

0.07 <

0.07 <

0.07 <

0.07 <

0.07

0.07 •

0.07 •

0.07 •

0.07

0.07

0.07

0.07

0.07

: 0.07

: 0.07

: 0.07

: 0.07

c 0.07

: 0.07

: 0.07

: 0.07: 0.07

: 0.07

: 0.07

: 0.07

: 0.07

: 0.07

: 0.07

: 0.07

: 0.07

: 0.07: 0.07

: 0.07

: 0.07

c 0.07' 0.07: 0.07

1221

: 0.06 <: 0.06 «c 0.06 •: 0.06 •c 0.06 •

c 0.06 •

c 0.06

' 0.06c 0.06

c 0.06c 0.06

< 0.06c 0.06

= 0.06

< 0.06c 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06

< 0.06< 0.06

< 0.06

< 0.06< 0.06

< 0.06< 0.06

< 0.06< 0.06

1232

: 0.02 •

: 0.02 •

c 0.02c 0.02

c 0.02

c 0.02

c 0.02c 0.02

c 0.02c 0.02

< 0.02

< 0.02«: 0.02

« 0.02

< 0.02<: 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02< 0.02

< 0.02< 0.02

< 0.02

< 0.02< 0.02

< 0.02< 0.02< 0.02

1242

' 0.02

c 0.02

c 0.02

c 0.02

c 0.02

c 0.02< 0.02

< 0.02

< 0.02c 0.02

< 0.02

< 0.02< 0.02

< 0.02

< 0.02< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02

< 0.02< 0.02

< 0.02< 0.02

< 0.02

< 0.02

< 0.02< 0.02

< 0.02

< 0.02

< 0.02

< 0.02< 0.02

< 0.02

< 0.02

< 0.02< 0.02

< 0.02

1248

1.692.17

2.66

2.12

3.56

2.850.60

0.66

0.520.12

0.38

1.650.082.24

2.050.13

0.12

0.14

Q iD2.36

1.35

1.61

0.32

0.43

0.47

< 0.03

0.050.47

< 0.03

0.240.31

< 0.03

0.060.15

0.070.41

0.03

0.180.11

1254

1.34

1.10

1.14

1.72

2.31

1.95

0.79

0.430.34

0.210.23

0.490.06

0.660.61

0.38

0.21

0.160.34

1.88

0.53

0.60

1.63

0.820.71

0.11

0.30

0.580.11

0.50

0.49

0.18

0.21

0.220.11

0.55

0.090.390.25

1260

0.17

0.25

0.27

Total

PCBs

(mg/kg)

3.29

3.61

4.160.48 f 4.41

0.95

0.76

0.050.08

0.17

< 0.020.06

0.10< 0.02

0.160.16

0.05

< 0.02

< 0.02

0.100.23

0.12

0.15

0.23

0.22

0.23< 0.02

< 0.02

0.07

0.03

0.040.07

< 0.02

< 0.02< 0.02

< 0.020.08

< 0.020.05

< 0.02

6.91

v 5.65

^T.i2

1.261 1.12

0.430.752.33

0.243.15

2.91

0.650.44

0.41

1.54

4.56

2.09

2.45

2.27

1.56

1.50

0.25

0.46

1.200.26 !

0.86

^0.95

^032

0.37

0.480.28'-

1.12

0.230.70 I0.47 u

Total

PCBs

(mgfcg)

3.68

~ ~5.65

1.30\

1.17

2.10

0.50

3.03

1.77

oiT"_____ -

1.20

.' 0.26

0.860.95

0.32

0.37

0.48f 0.28

1.12

0.230.700.47

Surrogate

Recovery

1001019579907996868076771077881847783848880558686658310110697489895101869195998497101

Spike

Lipids Recovery

(%) (%)

10.89

11.1310.40

5.81

6.74

5.34

3.403.55

3.131.51

8.397.81

1.458.918.01

2.06

1.70

1.41

1.79 87%Rec

9.26 (1248)

8.70

8.18

1.54

1.31

1.224.07

4.07

7.22

1.369.11

6.37

8.20

3.484.18

4.44

10.38

0.625.868.19

TABLE Dl-1. 1992 DATA SUMMARY FOR PCBs IN FISH

ALL9JDAT.XLS(9/14/93)Page 1 of 11

SAMPLE I.D.

2-CCF-l2-CCF-22-CCF-32-CCF-42-CCF-52-CCF-62-CCF-72-CCF-82-CCF-92-CCF-102-CCF-ll2-CCF-l 22-CCF-132-CCF-142-CCF-l 52-CC-l2-CC-l -A-DS2-CC-l -SPK7-CC-1-A-22-CC-22-CC-2-A-DS7-CC-2-A-22-CC-32-CC-3-A-DS2-CC-3-SPK7-CC-3-A-22-CC-42-CC^-A-DS2-CC-4-SPK7-CC-*-A-22-CC-52-CC-5-A-DS7-CC-5-A-22-CC-62-CC-6-A-DS7-CC-6-A-22-CC-7

SPECIES

CCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

DateSITE Extracted

2 10-23-922 10-23-922 10-23-922 10-23-922 10-23-922 10-23-922 10-26-922 10-26-922 10-26-922 10-26-922 10-26-922 10-26-922 10-26-922 10-26-922 10-26-922 10-08-922 12-22-922 10-19-922 12-22-922 10-08-922 12-22-922 12-22-922 10-08-922 12-20-922 12-20-922 12-20-922 10-08-922 12-22-922 12-22-922 12-22-922 10-08-922 12-20-922 12-20-922 10-08-922 12-20-922 12-20-922 10-08-92

DateAnalyzed

11-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-9211-25-921 1-25-921 1-25-9211-25-9211-25-921 1-25-9211-25-9210-13-921-13-9310-20-921-13-93

10-13-921-15-931-15-93

10-13-921-12-931-12-931-12-9310-13-921-13-931-13-931-13-93

10-13-921-12-931-12-93

10-13-921-13-931-12-93

10-13-92

Aroclor Concentration (mg/kg)1016

0.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

1221

0.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

1232

0.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

1242

0.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

1248

0.420.630.080.530.580.480.260.190.160.300.220.040.380.250.540.040.330.20

.~ 0.40 -0.761.031.702.452.643.763.371.151.512.191.101.762.072.160.440.500.621.63

1254

0.561.050.311.011.340.811.010.760.330.690.440.400.600.370.740.51 -"0.32 ,-•1.040.35 -"1.270.911.16

(o774~>0.641.34 .

v2.79_-J2.141.502.141.241.101.061.180.130.180.301.76

TotalPCBs

1260 (mg/kx)

0.050.100.030.110.140.080.070.100.020.060.030.020.090.030.070.040.070.04

' 0.08 _0.100.150.21

I ' 11 0.14J0 .21l.O.loJ

0.460.530.620.320.160.290.300.030.020.040.39

1.121.870.511.742.151.451.421.130.601.140.780.551.160.741.44o.eTj0.80:

1.370.92 j2.222.183.163.363.515.404.413.843.635.042.753.113.513.730.690.791.043.87

TotalPCBs

(mg/kg)

1.121.870.511.742.151.451.421.130.601.140.780.551.160.741.440.80

2.52

3.76

3.40

3.45

0.84

4.19

SurrogateRecovery

(*)

919590849092999080808794

1038578728867937167997376

100966679

1045175989071949673

SpikeLipids Recovery

(%) (*)

4.847.952.01

10.116.857.385.946.442.686.035.724.315.476.986.269.95 A

12.16 Ip' '11.03 63%Rec12.822.72 (1254)3.553.464.225.75 v. ,'4.99 65%Rec5.18 (1254)0.782.192.20 86% Rec2.325.05 (1248)5.516.292-042.102.325.42

ALL92DAT.XLS(9/1<W3)Page 2 of 11

SAMPLE I.D.2-CC-7-A-DS7-CC-7-A-22-CC-82-CC-8-A-DS7-CC-8-A-22-CC-92-CC-9-A-DS7-CC-9-A-22-CC-102-CC-10-A-DS7-CC-10-A-22-CC-ll2-CC-ll-A-DS7-CC-11-A-22-CC-122-CC-12-A-DS7-CC-12-A-22-CC-132-CC-13-A-DS7-CC-13-A-27-CC-13-A2SPK2-CC-142-CC-14-A-DS7-CC-14-A-22-CC-152-CC-15-A-DS7-CC-15-A-22-FWD-l2-FWD-l-Rep2-FWD-22-FWD-32-FWTM2-FWD-52-FWD-62-FWD-72-FWD-82-FWD-92-FWD-102-FWD-ll

SPECIESCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

FWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWD

SITE222222222222222222222222222222222222222

DateExtracted12-20-9212-20-9210-08-9212-20-9212-20-9210-08-9212-20-9212-20-9210-08-9212-20-9212-20-9210-08-9212-20-9212-20-9210-08-9212-20-9212-20-9210-23-9212-19-9212-19-9212-19-9210-23-9212-19-9212-19-9210-23-9212-19-9212-19-9210-26-9210-26-9210-30-9210-30-9210-30-9210-30-9210-30-9210-30-9210-30-9210-30-9210-3C-9210-30-92

DateAnalyzed

1-12-931-12-93

10-13-921-12-931-12-93

10-13-921-12-931-12-93

10-13-921-12-931-12-93

10-13-921-12-931-13-93

10-13-921-12-931-12-93

11-25-921-11-931-11-931-11-93

11-25-921-11-931-11-93

11-25-921-11-931-11-93

11-30-9211-25-9211-26-9211-26-921 1-26-9211-26-9211-26-9211-26-9211-26-9211-26-9211-26-9211-26-92

Aroclor Concentration10160.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

12210.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mg/kg)12481.982.051.692.172.662.123.562.850.600.660.520.120.381.650.082.242.050.130.120.141.012.361.351.610.320.430.470.030.050.470.030.240.310.030.060.150.070.410.03

12541.591.691.341.101.141.722.311.950.790.430.340.210.230.490.060.660.610.380.210.160.341.880.530.601.630.820.710.110.300.580.110.500.490.180.210.220.110.550.09

Total Total SurrogatePCBs PCBs Recovery


1260 (mg/kg) (mg/kg) (%) (%) (%)0.600.630.170.250.270.480.950.760.050.080.170.020.060.100.020.160.160.050.020.020.100.230.120.150.230.220.230.020.020.070.030.040.070.020.020.020.020.080.02

4.264.463.293.614.164.416.915.651.521.261.120.430.752.330.243.152.910.650.440.411.544.562.092.452.271.561.500.250.461.200.260.860.950.320.370.480.281.120.23

3.68

5.65

1.30

1.17

2.10

0.50

3.03

1.77

0.35

1.200.260.860.950.320.370.480.281.120.23

102106100101957990799686807677

10778818477838488805586866583

10110697489895

1018691959984

8.148.35

10.8911.1310.405.816.745.343.403.553.131.518.397.811.458.918.012.061.701.411.79 87% Rec9.26 (1248)8.708.181.541.311.224.074.077.221.369.116.378.203.484.184.44

10.380.62

TABLE DM. 1992 DATA SUMMARY FOR PCBs IN FISH

ALL92DAT.XLS(.9/I4«)3)P»gt3ofll

SAMPLE I.D.2-FWD-122-FWD-132-FWD-142-FWD-152-RCS-l2-RCS-22-RCS-32-RCS-42-RCS-52-RCS-62-RCS-72-RCS-82-RCS-92-RCS-102-RCS-ll2-RCS-122-RCS-l 32-RCS-l 42-RCS-l 52-SMB-l2-SMB-l-SPK2-SMB-22-SMB-32-SMB-42-SMB-53-CCF-l3-CCF-23-CCF-33-CCF-43-CCF-53-CCF-63-CCF-73-CCF-83-CCF-93-CCF-103-CCF-ll3 -CCF- 123-CCF-l 33-CCF-14

SPECIESFWDFWDFWDFWDRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSSMBSMBSMBSMBSMBSMBCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCF

DateSITE Extracted

2 10-30-922 10-30-922 10-30-922 10-30-922 10-30-922 10-30-922 10-30-922 10-30-922 11-06-922 11-06-922 11-06-922 11-06-922 11-06-922 11-06-922 11-06-922 11-06-922 11-06-922 10-30-922 10-30-922 11-06-922 11-06-922 11-06-922 11-06-922 11-06-922 11-06-923 11-10-923 11-10-923 11-10-923 H-IO-923 11-10-923 11-10-923 11-10-923 11-10-923 li -10-923 11-10-923 11-10-923 11-17-923 11-17-923 11-17-92

DateAnalyzed11-26-921 1-26-9211-26-9211-26-9211-26-9211-26-9211-26-9211-26-9211-30-9211-30-9211-30-9211-30-9211-30-921 1-30-921 1-30-9212-01-921-15-93

11-26-9211-26-9212-01-9211-30-9212-01-9212-01-9212-01-9212-01-9212-21-9212-03-9212-03-9212-03-9212-03-9212-03-9212-03-9212-03-9212-03-9212-21-9212-02-9212-04-9212-04-9212-04-92

Aroclor Concentration (mg/kg)10160.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

12210.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12480.180.110.031.030.320.035.006.300.031.140.030.030.040.080.660.702.690.150.09

Cerp3>0.831.191.020.520.550.360.120.110.030.030.030.030.130.030.070.780.030.060.03

12540.390.250.210.780.410.101.671.690.141.080.280.110.180.220.820.961.770.280.250.130.270.860.820.620.520.180.240.180.210.580.270.160.720.160.141.130.250.250.14

12600.050.020.020.130.030.020.120.160.020.110.050.020.020.020.090.140.390.030.020.020.020.090.090.160.110.080.020.020.020.090.020.040.060.020.110.090.070.020.02

TotalPCBs

(mg/kg)0.700.470.352.030.85 1•P,24 '6.888.240.282.420.45""0.25'

Total SurrogatePCBs Recovery

(mg/kg) (%)0.70

, ) 0.47' 0.35

2.03', 0.85 ."J 0.24

6.888.240.282.420.45

;J.-Jo.250.32 Y 0.320.40^1.651.894.94

1 0.401.651.89

i 4.940.54\HM 0.540.44/ 0.44

'0.27'VW 0.27j ^L *? \ .'_

2.221

2.02ir-1.39 fL-270.700.460.400.350.780.410.311.000.300.402.080.440.420.28

1

2.22W 2.02-iN 1.39

1.270.700.460.400.350.780.410.311.000.300.402.080.440.420.28

9710167

110959095609695

108919997954799

1021018298

10193

1099780

11181

10890

1061031008290

102827573


5.868.194.058.393.621.735.864.193.223.196.212.544.251.642.600.927.169.027.022.272.46 83%Rec5.74 (1248)6.367.83

13.665.454.442.644.524.441.945.141.982.524.208.601.974.110.49

ALL92DAT.XLS<9/11W3)Pige4of l l

0.


SAMPLE I.D. SPECIES3-CCF-153-CCF-15-SPK3-CC-l3-CC-l-A-DS3-CC-l-SPKJ7-CC-1-A-3TccT7-CC-2-A-33-CC-2-A-DS3-CC-33-CC-3-A-DS7-CC-3-A-33-CC-43-CC-4-A-DS7-CC-4-A-33-CC-53-CC-5-A-DS7-CC-5-A-33-CC-63-CC-6-A-DS7-CC-0-A-33-CC-73-CC-7-A-DS7-CC-7-A-33-CC-83-CC-8-A-DS7-CC-8-A-33-CC-93-CC-9-A-DS7-CC-9-A-33-CC-103-CC-l 0-A-DS7-CC-10-A-33-CC-ll3-CC-l 1-A-DS7-CC-11-A-33-CC-l 23-CC-l 2- A-DS7-CC-12-A-3

CCFCCFCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

SITE3333333 "33333333333333333333333333333333

DateExtracted11-17-9211-17-9211-10-9212-19-9211-10-9212-19-9211-10-9212-19-9212-19-9211-10-9212-19-9212-19-9211-10-9212-19-9212-19-9211-10-9212-19-9212-19-9211-10-9212-19-9212-19-9211-10-9212-20-9212-19-9211-10-9212-20-9212-19-9211-10-9212-20-9212-19-9211-06-9212-22-9212-22-9211-06-9212-22-9212-22-9211-06-9212-22-9212-22-92

DateAnalyzed12-04-9212-04-9212-03-921-11-93'

12-03-921-11-93

1242-921-11-931-11-9312-03-921-11-931-11-93

12-03-921-11-931-11-93

12-03-921-11-931-11-93

12-03-921-11-931-11-931-20-931-12-931-11-93

12-03-921-12-931-11-93

12-03-921-12-931-11-93

12-01-921-13-931-13-93

12-01-921-13-931-13-93

12-01-921-13-931-13-93

Aroclor Concentration (mg/kg)10160.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

12210.060.060.06OX*0.06P_.Q60.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.02

""0.02 "0.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12480.210.036.864.690.034.060.94"0.760.705.662.803.802.491.652.034.992.803.810.030.030.038.016.634.801.841.931.620.180.420.250.180.270.291.441.821.652.112.753.08

12540.53.i.ji'

- <0.86C—0.54.1.330.54

~ " 0.460.330.413.521.801.652.061.501.531.490.761.040.120.220.201.251.080.800.350.180.190.060.150.230.360.350.240.580.560.490.390.330.49

Total Total SurrogatePCBs PCBs Recovery Lipids

SpikeRecovery

1260 (mg/kg) (mg/kg) (%) (%) (%)0.040.02O.fPN0.080.02 /0.08 ;

0.050.050.040.620.260.360.200.310.330.170.130.200.020.020.020.220.190.140.040.030.030.020.020.020.040.120.120.030.070.100.040.070.07

0.87 0.871.65T.92 6.035.40/1.474.761.53 1.331.221.239.89 6.914.955.904.84 4.123.553.986.74 5.223.785.140.26 0.320.360.349.57 7.797.995.832.31 2.152.221.920.34 0.530.680.590.67 0.740.830.742.14 2.332.532.332.63 3.193.233.73

779288738490897566945664827177

1045779839793906946

106916998

10873

102999991

106107889497

5.585.405.755.686.375.474.604.894.604.304.683.901.891.971.606.696.196.491.811.541.47

15.2112.9812.564.614.403.792.052.752.062.57

10.2310.133.263.413.273.543.384.07

98% Rec(1254)

63% Rec(1254)

ALL92DAT.XLS(9/1<W3)P«gc5of l l

SAMPLE I. D.3-CC-133-CC-13-A-DS7-CC-13-A-33-CC-143-CC-14-A-DS7-CC-14-A-33-CC-153-CC-15-A-DS7-CC-I5-A-33-FHC-l3-FHC-23-FHC-33-FWD-l3-FWD-23-FWD-33-FWD-43-FWD-53-FWD-63-FWD-73-FWD-83-FWD-93-FWD-103-FWE>-ll3-FWD-123-FWD-l 33-FWD-143-FWD-l 53-RCS-l3-RCS-23-RCS-33-RCS-43-RCS-53-RCS-63-RCS-73-RCS-7-SPK3-RCS-83-RCS-93-RCS-103-RCS-l 1

SPECIESCCCCCCCCCCCCCCCCCC

FHCFHCFHCFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCS

SITE333333333333333333333333333333333333333

DateExtracted11-06-9212-22-9212-22-9211-06-9212-22-9212-22-9211-06-9212-22-9212-22-9211-24-9211-24-9211-24-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-17-9211-24-9210-239210-19-9210-19-9210-19-9210-19-9210-19-9210-19-9210-30-9210-19-9210-19-9210-19-9210-19-92

DateAnalyzed12-03-921-13-931-13-93

12-01-921-13-931-13-93

12-01-921-13-931-13-93

12-07-9212-07-9212-07-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-05-9212-07-9211-25-9210-22-9210-22-9210-22-921-15-931-20-93

10-22-921 1-26-9210-22-9210-20-9210-20-9210-20-92


12210.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mg/kg)12483.444.104.100.030.030.030.610.440.690.250.090.170.050.140.150.030.041.340.050.030.030.210.030.150.030.050.030.881.510.030.295.060.030.030.030.040.120.190.18

12542.551.971.600.200.240.220.730.460.660.330.100.180.160.190.110.010.180.630:170.110.130.340.120.460.100.130.060.211.000.070.181.970.100.060.740.070.160.280.22

12600.390.350.330.020.070.020.050.070.100.040.020.020.020.070.020.020.020.110.020.020.020.040.020.070.020.020.020.050.070.020.020.420.020.020.020.020.020.030.03

TotalPCBs

(mg/kg)6.476.516.120.340.430.361.481.061.540.710.300.460.320.490.370.150.332.17^0.320.250.270.680.260.770.230.29


(mg/kg) (%)6.36

0.37

1.36

0.710.300.460.320.490.370.150.33

• 1 2.170.320.250.270.680.260.77

| 0.230.29

0.20 j[/ 0.20"i.232.670.210.587.5V0.240.200.880.21 ,0.39'0.590.51

1.23— 2.67

0.210.58

- 7.530.24

1 0.20* t I

0.210.390.590.51

90989490

101106997399

10090

1018894717072

10080777478827174849293847379

10877728678828385


(%) (%)4.594.984.923.363.713.513.893.463.671.250.500.414.415.602.010.295.98

12J554.425.552.958.405.396.354.082.772.551.277.410.793.114.931.100.980.88 68% Rec2.60 (1254)4.157.799.67

ALL92DAT.XLS(9/1'V93)P«g«6of l l


SAMPLE I.D.3-RCS-123-RCS-133-RCS-143-RCS-153-SMB-l3-SMB-23-SMB-33-SMB-43-SMB-53-SMB-63-SMB-73-SMB-84-CCF-l4-CCF-24-CCF-34-CCF^4-CCF-54-CCF-454-CCF-74-CCF-84-CCF-94-CCF-104-CCF-ll4-CCF-l 24-CCF-l 34-CCF-l 3-Dup4-CCF-l 44-CCF-l 54-CC-l4-CC-24-CC-34-CC-44-CC-54-CC-64-CC-6-SPK4-CC-74-CC-84-CC-94-CC-10

SPECnESRCSRCSRCSRCSSMBSMBSMBSMBSMBSMBSMBSMBCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCCCCCCCCCCCCCCCCCCCCC

DateSITE Extracted

3 10-19-923 10-19-923 10-19-923 10-19-923 12-03-923 12-03-923 12-03-923 12-03-923 12-03-923 12-03-923 12-03-923 12-03-924 12-03-924 12-03-924 12-03-924 12-03-924 12-07-924 12-07-924 12-07-924 12-07-924 12-07-924 12-07-924 12-07-924 12-07-924 12-07-924 12-22-924 12-07-924 12-07-924 12-03-924 12-03-924 12-03-924 12-03-924 12-03-924 12-03-924 12-03-924 12-03-924 12-07-924 12-07-924 12-07-92

DateAnalyzed10-20-9210-22-9210-22-9210-22-9212-09-9212-09-9212-09-921-15-9312-09-9212-09-921-15-93

12-09-9212-09-9212-09-9212-09-9212-09-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-921-15-931-13-93

12-20-9212-11-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-11-9212-11-9212-11-92


12210.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mg/kg)12481.500.100.140.460.030.070.540.260.532.041.770.030.220.220.340.150.840.050.470.390.160.060.170.280.190.030.170.130.851.980.391.150.150.830.031.240.871.170.34

12540.610.220.280.680.130.220.460.500.351.080.160.140.480.230.220.240.650.240.480.500.270.110.500.400.380.230.300.600.581.380.840.480.050.621.490.751.211.060.23

12600.070.020.030.060.030.070.120.230.110.240.110.040.080.030.060.040.130.040.100.070.040.020.110.050.100.040.030.150.130.360.250.150.020.130.020.160.370.230.06

TotalPCBs

(mg/kg)2.270.430.541.28

TotalPCBs

Jmg/kg)2.270.430.541.28

b.27~~ OT27"Y0.451.21\1.0811.08 ,3.45 ;2.13 '

0.451.21 1

, 1.08M 1.08 1

3.452.13

SurrogateRecovery

80888774869994

10498

11086

0.29_ .0.29 j 980.870.570.710.521.710.411.131.040.560.270.870.820.750.38 l0.580.971.653.801.571.870.311.671.632.242.542.550.71

0.870.570.710.521.710.411.131.040.560.270.870.820.57

l l0.580.971.653.801.571.870.311.67

2.242.542.550.71

9010110694

10710711010410797

10210910810510788

100104979878

10098

102109107104


9.055.283.601.471.829.177.44

11.4210.5613.7115.687.372.407.006.097.505.406.368.234.694.270.983.034.43

13.4811.997.220.755.839.664.331.599.429.868.93 87% Rec

10.02 (1254)7.999.172.42

ALL92DAT.XLS(9/l4/93)P«ge7of l l


SAMPLE I.D.

4-CC-ll4-CC-124-CC-134-CC-144-CC-154-CC-15-SPK4-FHC-l4-FWD-l4-FWD-24-FWD-34-FWD-44-FWD-54-FWD-64-FWD-74-FWD-84-FWD-94-FWD-104-FWD-ll4-FWD-l 24-FWD-12-SPK4-FWD-134-FWD-l 44-FWD-l 54-RCS-l4-RCS-24-RCS-34-RCS-44-RCS-54-RCS-64-RCS-74-RCS-84-RCS-94-RCS-104-RCS-l 14-RCS-124-RCS-l 34-RCS-l 44-RCS-154-SMB-l-A

SPECIES

CCCCCCCCCCCC

FHCFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDFWDRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSSMB

SITE

444444444444444444444444444444444444444

DateExtracted

12-07-9212-07-9212-07-9212-07-9212-07-9212-07-9211-24-9211-24-9211-24-9211-24-9211-24-9211-24-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9211-24-9211-24-9211-24-9211-24-9211-24-9211-24-9211-24-9211-24-9211-24-9212-09-9212-09-9212-09-9212-09-9212-09-9212-09-9202-12-93

DateAnalyzed

12-12-9212-12-9212-12-9212-11-9212-11-9212-11-9212-07-9212-07-9212-08-9212-08-9212-08-9212-08-9212-12-9212-12-921-20-93

12-20-9212-12-921-20-93

12-12-9212-12-9212-20-9212-12-9212-12-9212-07-9212-07-9212-07-9212-07-9212-07-9212-07-9212-07-9212-07-9212-07-9212-12-9212-12-9212-12-9212-12-9212-12-9212-21-9202-12-93

Aroclor Concentration1016

0.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

1221

0.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

1232

0.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

1242

0.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mg/kg)1248

0.830.180.060.350.300.030.110.110.110.450.590.130.140.100.070.170.500.030.070.030.160.210.660.210.310.670.151.571.040.250.030.030.070.280.661.180.200.530.08

1254

0.470.260.110.160.441.320.210.400.080.410.470.160.340.160.330.380.670.370.161.090.520.210.810.110.100.650.161.471.030.410.040.100.120.310.391.020.640.630.17

1260

0.100.040.020.040.090.020.020.150.020.040.120.030:130.040.040.040.140.070.020.020.040.050.120.020.020.180.030.270.16O.TT0.030.020.020.050.060.160.300.290.06

TotalPCBs

(mg/kg)1.480.570.270.630.921.460.43_0.750.290.991.270.400.700.390.530.68 ,1.40 *-0.550.341.230.810.561.680.430.521.590~433.402.32

~~ 0.87

Total Surrogate

PCBs Recovery(mg/kg) (%)

1.480.570.270.630.92

0.43""•6.75

0.290.991.270.400.700.390.530.68

•' 1.400.550.34

| 0.811 0.56\J 1.68

0.430.521.590.433.402.320.87

0.19, , ,0.19M /\ /0.24^ v 0.240.30..

" 0.731.202^51 31.540.40

0.300.731.202.451.231.540.40

10810310210610110194978786909199

10065

10810283

110104104100111829487888989977574

102104HO94899290

Lipids

(%)6.312.301.864.664.996.081.47

12.011.313.847.747.292.712.166.997.857.217.496.526.857.145.597.891.631.532.321.534.343.965.740.450.451.261.365.613.431.013.162.24

SpikeRecovery

(%)

88% Rec(1254)

93% Rec(1254)


ALL«DATXLS(9/14«P3)PugeSof l l

SAMPLE I.D.4-SMB-l-SPK5-CCF-l5-CCF-25-CCF-35-CCF-45-CCF-4-DUP5-CCF-55-CCF-65-CCF-75-CCF-85-CCF-95-CCF-105-CC-l5-CC-25-CC-35-CC-45-CC-55-CC-65-CC-6-SPK5-CC-75-CC-85-CC-95-CC-105-CC-ll5-CC-il-SPK5-CC-l 25-CC-l 35-CC-145-CC-l 55-FHC-l5-FHC-l-SPK5-FWD-l5-FWD-25-FWD-35-FWD-3-SPK5-FWD-45-FWD-55-FWD-5-DUP5-FWD-6

SPECIESSMBCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCFCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

FHCFHCFWDFWDFWDFWDFWDFWDFWDFWD

SITE455555555555555555555555555555555555555

DateExtracted02-12-931-20-93

12-11-9212-11-9212-11-9212-11-9212-12-9212-12-9212-12-9212-12-9212-12-9212-12-9212-09-9212-09-9212-09-9212-18-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-11-9212-12-9212-12-9212-12-9212-12-9212-12-9212-12-921-20-93

12-12-92

DateAnalyzed02-12-931-20-9312-21-9212-21-9212-21-9212-21-921-01-931-01-931-01-931-01-931-07-931-07-93

12-12-9212-12-9212-20-9212-21-9212-21-9212-21-9212-21-9212-21-9212-21-9212-21-9212-21-9212-21-9212-21-9212-22-9212-21-9212-21-9212-21-9212-21-9212-21-921-07-931-07-931-07-931-07-931-14-931-20-931-20-931-14-93


12210.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mg/kg)12480.680.030.100.030.030.030.030.030.030.030.080.060.110.070.100.100.050.030.030.170.160.030.030.030.030.120.230.200.030.030.030.030.150.040.030.030.520.370.09

12540.480.320.290.370.160.190.150.120.190.300.360.090.420.180.310.950.140.211.020.140.170.200.020.051.100.230.320.260.030.201.180.110.290.030.560.250.670.530.42

Total Total SurrogatePCB« PCBs Recovery Lipids

SpikeRecovery

1260 (mg/kg) (mg/kg) (%) (%) {%)0.020.050.090.020.050.050.020.020.020.020.040.020.150.040.040.440.050.060.020.030.050.040.020.020.020.100.050.100.360.060.610.030.030.020.020.040.100.080.10

1.270.490.570.510.330.350.290.260.330.440.570.260.770.370.531.580.320.391.160.430.460.360.160.181.240.540.680.640.510.371.910.250.560.180.700.411.371.060.70

0.490.570.510.34

0.290.260.330.440.570.260.770.370.531.580.320.39

0.430.460.360.160.18

0.540.680.640.510.37

0.250.560.18

0.411.22

0.70

7467

1069384968878

10389

1079684

10093999396

10099

105102969897

1081031051079994

1031079871

1018870

106

1.645.644.390.550.57ND1.871.235.412.32

11.852.541.644.545.733.863.501.542.106.097.266.822.303.743.99

10.444.705.205.072.402.201.037.320.801.53

12.198.407.81

12.27

65% Rec

81% Rec(1254)

105% Rec(1254)

98% Rec

53% Rec(1254)

ALL92DAT.XLS(9n4/93)Pigc9ofll


SAMPLE I.D.5-FWD-75-FWD-85-FWD-95-FWD-105-FWD-ll5-FWD-125-FWD-135-FWD-145-FWD-155-RCS-l5-RCS-25-RCS-35-RCS-t5-RCS-55-RCS-5-DUP5-RCS-65-RCS-75-RCS-85-RCS-95-RCS-105-RCS-l 0-SPK5-SMB-l5-SMB-25-SMB-35-SMB-3-SPK5-SMB-45-SMB-55-SMB-5-SPK5-SMB-65-SMB-75-SMB-85-SMB-95-SMB-107-CC-1-A-27-CC-1-A-37-CC-2-A-27-CC-2-A-37-CC-3-A-27-CC-3-A-3

SPECIES

FWDFWDFWDFWDFWDFWDFWDFWDFWDRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSRCSSMBSMBSMBSMBSMBSMBSMBSMBSMBSMBSMBSMBCCCCCCCCCCCC

SITE

555555555555555555555555555555555232323

DateExtracted

12-12-9212-12-9212-12-9212-12-9212-12-9212-12-9212-12-9212-12-9212-12-9212-13-9212-13-9212-13-9212-13-9212-13-921-20-93

12-13-9212-13-9212-13-9212-13-9212-13-9212-18-9212-13-9212-13-9212-13-9212-13-9212-13-9212-13-9212-18-9212-13-9212-13-9212-13-9212-13-9212-13-9212-22-9212-19-9212-22-9212-19-9212-20-9212-19-92

DateAnalyzed

1-15-931-07-931-07-931-07-931-07-931-08-931-08-931-08-931-15-931-05-931-05-931-05-931-06-931-14-931-20-931-05-931-05-931-05-931-08-931-05-931-08-931-05-931-08-931-05-931-05-931-08-931-05-931-08-931-06-931-08-931-08-931-08-931-07-931-13-931-11-931-15-931-11-931-12-931-11-93


0.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

1221

0.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

1232

0.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

1242

0.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mg/kg)12480.100.130.080.070.100.030.030.110.070.030.050.100.160.040.030.040.040.050.120.070.820.410.900.030.031.240.030.630.030.110.130.130.080.404.061.700.763.373.80

1254

0.230.310.230.170.120.130.060.170.500.080.170.410.240.130.170.260.120.170.110.190.011.960.510.261.260.780.100.010.120.320.190.120.090.350.541.160.330.791.65

Total Total SurrogatePCBs PCBs Recovery Lipids

SpikeRecovery

1260 (mg/kg) (mg/kg) (%) (%) (%)0.090.020.090.030.020.020.020.030.120.020.020.080.080.020.030.040.020.030.030.020.020.350.110.030.020.100.020.020.020.070.030.020.020.080.080.210.050.160.36

0.500.550.490.350.330.270.200.400.770.220.330.670.570.280.320.430.270.330.340.370.942.801.610.401.402.210.240.750.260.580.430.360.280.924.763.161.224.415.90

0.500.550.490.350.330.270.200.400.770.220.330.670.570.30

0.430.270.330.340.37

2.801.610.40

2.210.24

0.260.580.430.360.280.924.763.161.224.415.90

10410810687

1098783

10510695

106107111997894

10310392

11083

10864

10110477

10773

107848394

107939099759664

7.709.543.731.935.613.060.474.18

12.961.952.972.846.672.361.471.132.142.407.884.505.485.978.483.924.18

16.512.14ND

5.6514.0612.917.575.08

12.825.473.464.895.183.90

75% Rec

100% Rec(1254)

60% Rec(1248)

ALL92DAT.XLS<9/14/93)PagelOofll

SAMPLE I.D.

7-CC-4-A-27-CC-4-A-37-CC-5-A-27-CC-5-A-37-CC-6-A-27-CC-6-A-37-CC-7-A-27-CC-7-A-37-CC-8-A-27-CC-8-A-37-CC-9-A-27-CC-9-A-37-CC-10-A-27-CC-10-A-37-CC-11-A-27-CC-11-A-37-CC-12-A-27-CC-12-A-37-CC-13-A-27-CC-13-A2SPK7-CC-13-A-37-CC-14-A-27-CC-14-A-37-CC-15-A-27-CC-15-A-3LAB CONTROLLAB CONTROLLAB CONTROLLAB CONTROLLAB CONTROLLAB CONTROLLAB CONTROLLAB CONTROLRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANK

SPECIESCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC

LABLABLABLABLABLABLABLABREBREBREBREBREBREB

SITE

2323232323232323232232323

LABLABLABLABLABLABLABLABREBREBREBREBREBREB

DateExtracted

12-22-9212-19-9212-20-9212-19-9212-20-9212-19-9212-20-9212-19-9212-20-9212-19-9212-20-9212-19-9212-20-9212-22-9212-20-9212-22-9212-20-9212-22-9212-19-9212-19-9212-22-9212-19-9212-22-9212-19-9212-22-9212-07-9212-13-92

1-20-9312-18-9212-22-9212-18-9212-19-9212-20-9211-06-9212-09-9212-03-9210-19-9211-10-9210-30-92

DateAnalyzed

-13-93-11-93-12-93-11-93-12-93-11-93-12-93-11-93-12-93-11-93-12-93-11-93-12-93-13-93

1-13-931-13-931-12-931-13-931-11-931-11-931-13-931-11-931-13-931-11-931-13-93

12-12-921-05-931-20-931-15-931-13-93

12-21-921-11-931-13-93

11-30-9212-12-9212-08-9210-20-9212-02-9211-26-92


0.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

1221

0.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mg/kg)1248

1.102.032.163.810.620.032.054.802.661.622.850.250.520.291.651.652.053.080.141.014.101.610.030.470.690.030.030.031.150.030.620.540.030.030.030.030.030.030.03

1254

1.241.531.181.040.300.201.690.801.140.191.950.230.340.240.490.490.610.490.160.341.600.600.220.710.660.871.110.860.010.800.010.010.710.010.010.010.010.010.01

Total Total SurrogatePCBs PCB« Recovery Ljpids

SpikeRecovery

1260 (mg/kg) (me/kg) (%) (%) (%)

0.320.330.300.200.040.020.630.140.270.030.760.020.170.120.100.100.160.070.020.100.330.150.020.230.100.020.020.020.020.020.020.020.020.020.020.020.020.020.02

2.753.983.735.141.040.344.465.834.161.925.650.591.120.742.332.332.913.730.411.546.122.450.36

.50

.54

.01

.25

.00

.270.940.740.660.850.150.150.150.150.150.15

2.753.983.735.141.040.344.465.834.161.925.650.591.120.742.332.332.913.730.41

6.122.450.361.501.541.011.251.001.270.940.740.660.850.150.150.150.150.150.15

517790799693

10646956979738099

107107849784889486

106839989

10679

112906589

10410310498959086

2.321.606.296.492.321.478.35

12.5610.403.795.342.063.13

10.137.813.278.014.071.411.794.928.183.511.223.670.010.000.01

-0.440.000.000.000.000.0 10.000.000.000.000.00

87% REC(1248)

87% Rec1 1 1 % Rec86% Rec115% Rec80% Rec62% Rec54% Rec71% Rec

ALL92DAT.XL«9/1*<)3)P i g e l l o f l l

SAMPLE I.D.RE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKRE. BLANKSRM #12SRM #13SRM #14SRM #15SRM #16SRM #17SRM #18SRM #26SRM #28SRM #29SRM #31SRM #32SRM #33

SPECIESREBREBREBREBREBREBREBREBREBREBREBREBSRMSRMSRMSRMSRMSRMSRMSRMSRMSRMSRMSRMSRM

SITEREBREBREBREBREBREBREBREBREBREBREBREBSRMSRMSRMSRMSRMSRMSRMSRMSRMSRMSRMSRMSRM

DateExtracted12-07-9210-26-9212-12-9210-08-9212-13-9212-22-921-20-93

11-17-9212-19-9211-24-9212-11-9212-20-9212-12-9212-09-9210-30-9211-24-9212-13-9212-03-9212-07-9211-17-9210-26-9211-17-9211-06-9212-11-9210-19-92

DateAnalyzed12-11-9211-25-921-1-93

10-13-921-05-931-13-931-20-93

12-04-921-11-93

12-07-9212-21-921-13-931-01-93

12-12-9212-08-9212-08-921-05-93

12-08-9212-11-9212-08-9212-08-9212-04-9212-08-9212-21-9212-08-92

Aroclor Concentration10160.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.070.07

12210.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.060.06

12320.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

12420.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.020.02

(mx/kg)12480.030.030.030.030.030.030.030.030.030.030.030.03

10.8011.4011.709.19

13.0011.009.80

10.4010.6011.1010.107.83

12.20

12540.010.010.010.010.010.010.010.010.010.010.010.010.014.355.093.873.505.073.624.124.444.224.605.345.45

12600.020.020.020.020.020.020.020.020.020.020.020.020.020.810.850.621.260.830.650.680.760.300.750.610.79

TotalPCB»

(mg/kg)0.150.150.150.150.150.150.150.150.150.150.150.15

10.9216.6517.7313.7717.8516.9914.1615.2915.8915.7115.5413.8718.53


(mg/kg) (%)0.150.150.150.150.150.150.150.150.150.150.150.15

10.9216.6517.7313.7717.8516.9914.1615.2915.8915.7115.5413.8718.53

NS86

103NS

102899189799297

10511513013697

15612910313812611413498

148


(%) (%)0.000.00

-0.010.000.010.000.380.000.010.000.010.00

22.5116.3215.4323.8122.0217.3318.2213.1819.9213.5317.2116.3320.11

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit Company A N A i, Y T i c \ i, s i;; K v i c; K s

WOODWARD CLYDE

PCB'B in Fieh Tissue

Samples Received September 18, 1992

September 24, 1992

Unito mg/Kg (ppm)

SAMPLE I.D.

2-CCF-l

2-CCF-2

2-CCF-3

2-CCF-4

2-CCF-5

2-CCT-6

2-CCP-J

2-CCF-8

2-CCF-9

2-CCF-10

2-CCF-l 1

2-CCF-12

2-CCF-13

2-CCP-14

2-CCF-15

2-CC-l

2-CC-l-A-DS

2-CC-l-SPK

2-CC-2

2-CC-2-A-DS

2-CC-3

2-CC-3-A-DS

2-CC-3-SPK

2-CC-4

2-CC-4-A-DS

2-CC-4-SPX

2-CC-5

2-CC-5-A-DS

2-CC-6

2-CC-6-A-DS

2-CC-7

2-CC-7-A-DS

2-CC-8

2-CC-8-A-DS

2-CC-9

2-CC-9-A-DS

2-CC-10

2-CC-10-A-DS

2-CC-ll

2-CC-ll-A-DS

2-CC-12

2-CC-12-A-DS

2-CC-13

2-CC-l 3 -A-DS

EXTRCTED

10-23-92

10-23-92

10-23-92

10-23-92

10-23-92

10-23-92

10-26-92

10-26-92

10-26-92

10-26-92

10-26-92

10-26-92

10-26-92

10-26-92

10-26-92

10-08-92

12-22-92

10-19-92

10-08-92

12-22-92

10-08-92

12-20-92

12-20-92

10-08-92

12-22-92

12-22-92

10-08-92

12-20-92

10-08-92

12-20-92

10-08-92

12-20-92

10-08-92

12-20-92

10-08-92

12-20-92

10-06-92

12-20-92

10-08-92

12-20-92

10-08-92

12-20-92

10-23-92

12-19-92

ANALYZED

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

11-25-92

10-13-92

1-13-93

10-20-92

10-11-92

1-15-93

10-13-92

1-12-93

1-12-93

10-13-92

1-13-93

1-13-93

10-13-92

1-12-93

10-13-92

1-13-93

10-13-92

1-12-93

10-13-92

1-12-93

10-13-92

1-12-93

10-13-92

1-12-93

10-13-92

1-12-93

10-13-92

1-12-93

11-25-92

1-11-93

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0«

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0«

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0fi

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<o.oe<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

0.42

0.63

0.08

0.53

0.58

0.48

0.26

0.19

0.16

0.30

0.22

0.04

0.38

0.25

0.54

0.04

0.33

0.20

0.76

1.03

2.45

2.64

3.76

1.15

1.51

2.19

1.76

2.07

0.44

0.50

1.63

1.98

1.69

2.17

2.12

3.56

0.60

0.66

0.12

0.38

0.08

2 . 2 4

0.13

0.12

1254

0.56

1.05

0.31

1.01

1.34

0.81

1.01

0.76

0.33

0.69

0.44

0.40

0.60

0.37

0.74

0.51

0.32

1.04

1.27

0.91

0.74

0.64

1.34

2.14

l.SO

2.14

1.10

1.06

0.13

0.18

1.76

1.59

1.34

1.10

1.72

2.31

0.79

0 .43

0.21

0.23

0.06

0.66

0.38

0.21

1260

O.OS

0.10

0.03

0.11

0.14

0.08

0.07

0.10

0.02

0.06

0.03

0.02

0.09

0.03

0.07

0.04

0.07

0.04

0.10

0.15

0.08

0.14

0.21

0.46

0.53

0.62

0.16

0.29

0.03

<0.02

0.39

0.60

0.17

0.25

0.48

0.95

0.05

o.oe<0.02

0.06

<0.02

0.16

0.05

<0.02

Page 1 of 10

TOTAL

PCB

1.20

1.95

0.59

1.82

2.23

1.54

1.51

1.22

0.68

1.22

0.86

0.63

1.24

0.62

1.52

0.76

0.89

1.45

2.30

2.26

3.44

3.59

5.48

3.92

3.71

5.12

3.19

3.59

0.77

0.87

3.95

4 . 3 4

3.37

3.69

4 .49

6.99

1.61

1.34

0.52

0.84

0.31

3.23

0 .73

0.52

SURR

REC

91

95

90

84

90

92

99

90

80

80

87

94

103

85

78

72

88

67

71

67

73

76

100

66

79

104

75

98

71

94

73

102

100

101

79

90

96

86

76

77

78

61

77

83

PERCENT SPR

LIPIDS

4 .84

7.95

2.01

10.11

6. 85

7.38

5.94

6 . 4 4

2 .68

6 .03

5.72

4.31

5.47

6.98

6 . 2 6

9 .95

12.16

11.03

2.72

3.55

4 . 2 2

5.75

4 . 9 9

0.78

2.19

2.20

5.05

5.51

2 .04

2.10

5.42

8.14

10.89

11.13

5.81

6.74

3.40

3.55

1.51

8.39

1.45

8.91

2.06

1.70

REC

63t Rec

( 1 2 5 4 )

65* Rec

(1254)

Set Rec

(1248)

1550 - 3 7 . t h - S t r e e t NE. PO Box 3898. C l e v e l a n d . TN 3 7 3 2 0 - ,'i 8 9 8 . (i I ~>/4 76 - 7 7 66 Fax 4 7 6 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Siininiil Comiiany ANA I, Y T I C A I, S E R V I C ID S

WOODWARD CLYDE

PCB'e in Fish Tissue


September 24, 1992

Units ing/Kg (ppn)

AROCLOR

SAMPLE I.D.

2-CC-14

2-CC-14-A-DS

2-CC-15

2-CC-15-A-DS

2-FWD-l

2-FWD-l-Rep

2-FTO-2

2-FWD-3

2-FWD-4

2-FWD-5

2-FWD-S

2-FWD-7

2-FWD-8

2-PUD-9

2-rwD-io2 -PHD- 11

2-PVD-12

2-FWD-13

2-FTO-14

2-FWD-15

2-RCS-l

2-RCS-2

2-RCS-3

2-RCS-4

2-RCS-5

2-RCS-6

2-RCS-7

Z-RCS-8

2-RCS-9

2-RCS-10

2-RCS-ll

2-RCS-12

2-RCS-13

2-RCS-14

2-RCS-15

2-SHB-l

2-SMB-l-SPK

2-SKB-2

2 -SHE -3

2-SMB-4

2-SMB-5

EX1RCTED

10-23-92

12-19-92

10-23-92

12-19-92

10-26-92

10-26-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

10-30-92

11-06-92

11-06-92

11-06-92

11-06-92

11-06-92

11-06-92

11-06-92

11-06-92

11-06-92

10-30-92

10-30-92

11-06-92

11-06-92

11-06-92

11-06-92

11-06-92

11-06-92

ANALYZED

11-2S-92

1-11-93

11-25-92

1-11-93

11-30-92

11-25-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-26-92

11-30-92

11-30-92

11-30-92

11-30-92

11-30-92

11-30-92

11-30-92

12-01-92

1-15-93

11-26-92

11-26-92

12-01-92

11-30-92

12-01-92

12-01-92

12-01-92

12-01-92

1016

<0.07

•C0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

•CO. 02

<0.02

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

2.36

1.35

0.32

0.43

<0.03

0.05

0.47

<0.03

0.24

0.31

<0.03

0.06

0.15

0.07

0.41

0.03

0.18

0.11

<0.03

1.03

0.32

<0.03

5.00

6.30

<0.03

1.14

<0.03

<0.03

0.04

0.08

0.66

0.70

2.69

0.15

0.09

<0.03

0.83

1.19

1.02

0.52

0.55

1254

1.68

0.53

1.63

0.82

0.11

0.30

0.58

0.11

0.50

0.49

0.18

0.21

0.22

0.11

0.55

0.09

0.39

0.25

0.21

0.78

0.41

0.10

1.67

1.69

0.14

1.08

0.28

0.11

0.18

0.22

0.62

0.96

1.77

0.28

0.25

0.13

0.27

0.86

0.82

0.62

0.52

1260

0.23

0.12

0.23

0.22

<0.02

<0.02

0.07

0.03

0.04

0.07

<0.02

<0.02

<0.02

<0.02

0.08

<0.02

0.05

<0.02

<0.02

0.13

0.03

<0.02

0.12

0.16

<0.02

0.11

0.05

<0. 02

0.02

<0.02

0.09

0.14

0.39

0.03

0.02

<0.02

<0.02

0.09

0.09

0.16

0.11

Page 2 of 10

TOTAL

PCB

4.64

2.17

2.35

1.64

0.33

0.54

1.29

0.34

0.95

1.04

0.40

0.46

0.56

0.37

1.21

0.31

0.79

0.55

0.43

2.11

0.93

0.32

6.96

8.32

0.36

2.50

0.53

0.33

0.41

0.49

1.74

1.97

5.02

0.63

0.53

0.35

1.29

2.31

2.10

1.47

1.35

SURR

REC

80

55

86

65

101

106

97

48

96

95

101

86

91

95

99

84

97

101

67

110

95

90

95

60

96

95

108

91

99

97

95

47

99

102

101

82

98

101

93

109

97

PERCENT SPK

LIPIDS REC

9.26

8.70

1.S4

1.31

4.07

4.07

7.22

1.36

9.11

6.37

8.20

3.48

4.18

4.44

10.38

0.62

5.86

8.19

4.05

6.39

3.62

1.73

5.86

4.19

3.22

3.19

6.21

2.54

4.25

1.64

2.60

0.92

7.16

9.02

7.02

2.27

2.46 83t Rec

5.74 (1248)

6.36

7.83

13.66

1550 - 3 7 . H i - S t r e e t N E . P O B o x 3898. C l e v e l a n d . T I M 3 7 3 2 0 - 3 8 9 8 . G 1 5 / 4 7 G - 7 7 6 G F a x 4 7 G - 9 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Sutiimil (lomtmny A N A I, V 'I1 I C A L S E R V I C E S

WOODWARD CLYDE

PCB'o in Fiah Tiooue


September 24, 1992

Unite log/Kg (ppm)

SAMPLE I.D.

3-CCF-l

3-CCF-2

3-CCF-3

3-CCF-4

3-CCF-5

3-CCF-S

3-CCF-7

3-CCF-8

3-CCF-9

3-CCP-10

3-CCT-ll

3-CCF-12

3-CCP-13

3-CCF-14

3-CCF-15

3-CCF-15-SPK

3-CC-l

3-CC-l-A-DS

3-CC-l-SPK

3-CC-2

3-CC-2-A-DS

3-CC-3

3-CC-3-A-DS

3-CC-4

3-CC-4-A-DS

3-CC-S

3-CC-5-A-DS

3-CC-6

3-CC-6-A-DS

3-CC-7

3-CC-7-A-DS

3-CC-8

3-CC-8-A-DS

3-CC-9

3-CC-9-A-DS

3-CC-10

3-CC-10-A-DS

3-CC-ll

3-CC-ll-A-DS

3-CC-12

3-CC-12-A-DS

3-CC-13

3-CC-13-A-DS

EXTRCTED

11-10-92

11-10-92

11-10-92

11-10-92

11-10-92

11-10-92

11-10-92

11-10-92

11-10-92

11-10-92

11-10-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-10-92

12-19-92

11-10-92

11-10-92

12-19-92

11-10-92

12-19-92

11-10-92

12-19-92

11-10-92

12-19-92

11-10-92

12-19-92

11-10-92

12-20-92

11-10-92

12-20-92

11-10-92

12-20-92

11-06-92

12-22-92

11-06-92

12-22-92

11-06-92

12-22-92

11-06-92

12-22-92

ANALYZED

12-21-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-21-92

12-02-92

12-04-92

12-04-92

12-04-92

12-04-92

12-04-92

12-03-92

1-11-93

12-03-92

12-02-92

1-11-93

12-03-92

1-11-93

12-03-92

1-11-93

12-03-92

1-11-93

12-03-82

1-11-93

1-20-93

1-12-93

12-03-92

1-12-93

12-03-92

1-12-93

12-01-92

1-13-93

12-01-92

1-13-93

12-01-92

1-13-93

12-03-92

1-13-93

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

•C0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

•CO. 07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

•CO. 07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0. 06

<0.06

<0.06

<0.0£

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0<

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

•CO. 02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

0.36

0.12

0.11

<0.03

<0.03

<0.03

<0.03

0.13

<0.03

0.07

0.78

<0.03

0.06

<0.03

0.21

<0.03

6.86

4.69

<0.03

0.94

0.70

5.66

2.80

2.49

1.65

4.99

2.80

<0.03

<0.03

8.01

6.63

1.84

1.93

0.18

0.42

0.18

0.27

1.44

1.82

2.11

2.75

3.44

4.10

1254

0.16

0.24

0.18

0.21

0.58

0.27

0.16

0.72

0.16

0.14

1.13

0.25

0.25

0.14

0.53

1.51

0.86

0.54

1.33

0.46

0.41

3.52

1.80

2.06

1.50

1.49

0.76

0.12

0.22

1.25

1.08

0.35

0.18

0.06

0.15

0.36

0.3S

0.58

0.56

0.39

0.33

2.55

1.97

1260

0.08

<0.02

0.02

0.02

0.09

0.02

0.04

0.06

<0.02

0.11

0.09

0.07

<0.02

<0.02

0.04

<0.02

0.11

0.08

<0.02

0.05

0.04

0.62

0.26

0.20

0.31

0.17

0.13

<0.02

•C0.02

0.22

0.19

0.04

0.03

<0.02

<0.02

0.04

0.12

0.03

0.07

0.04

0.07

0.39

0.35

Page 3 of 10

TOTAL

PCB

0.79

0.55

0.48

0.43

0.87

0.49

0.40

1.08

0.38

0.49

2.17

0.52

0.50

0.36

0.95

1.73

8.00

5.48

1.55

1.62

1.32

9.97

5.03

4.92

3.63

6.62

3.86

0.34

0.44

9.65

8.07

2.40

2.31

0.43

0.76

0.75

0.91

2.22

2.62

2.71

3.32

6.55

6.59

SURR

REC

80

111

81

108

90

106

103

100

82

90

102

82

75

73

77

92

88

73

84

89

66

94

56

82

71

104

57

63

97

90

69

106

91

98

108

102

99

91

106

86

94

90

98

PERCENT SPK

LIPIDS

5.45

4.44

2.64

4.52

4.44

1.94

5.14

1.98

2.52

4.20

8.60

1.97

4.11

0.49

5.58

5.40

5.75

5.68

6.37

4.60

4.60

4.30

4.68

1.89

1.97

6.69

6.19

1.81

1.54

15.21

12.98

4.61

4.40

2.05

2.75

2.57

10.23

3.26

3.41

3.54

3.38

4.59

4.98

REC

981 Rec

(1254)

63t Rec

(1254)

1550 - 37.Hi. S i r e e l NE. PO l i o x 3898. C l e v e l a n d . TN 3 7 3 2 0 - 3 8 9 8 . ( i I f > / 4 7 G - 7 7 66 Fax 4 7 0 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

HW Engineering & ScienceA Siimniil A N A L Y T I C A L , S E R V I C E S

WOODWARD CLYDE

PCB'a in Fish Tiaeue


September 24, 1992

Unite mg/Kg (ppm)

SAMPLE I.D.

3-CC-14

3-CC-14-A-DS

3-CC-15

3-CC-1S-A-DS

3-FBC-l

3-FBC-2

3-FHC-3

3-FWD-l

3-FWD-2

3-FWD-3

3-FHD-4

3-FWD-5

3-FWD-6

3-FHD-7

3-PWD-6

3-FWD-9

3-FWD-10

3-FVTO-ll

3-FWD-12

3-FWD-13

3-FWD-14

3-FWD-15

3-RCS-l

3-RCS-2

3-RCS-3

3-RCS-4

3-RCS-5

3-RCS-6

3-RCS-7

3-RCS-7-SPK

3-RCS-8

3-RCS-9

3-RCS-10

3-RCS-ll

3-RCS-12

3-RCS-13

3-RCS-l 4

3-RCS-15

EXTRCTED

11-06-92

12-22-92

11-06-92

12-22-92

11-24-92

11-24-92

11-24-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-17-92

11-24-92

10-23-92

10-19-92

10-19-92

10-19-92

10-19-92

10-19-92

10-19-92

10-30-92

10-19-92

10-19-92

10-19-92

10-19-92

10-19-92

10-19-92

10-19-92

10-19-92

ANALYZED

12-01-92

1-13-93

12-01-92

1-13-93

12-07-92

12-07-92

12-07-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-05-92

12-07-92

11-25-92

10-22-92

10-22-92

10-22-92

1-15-93

1-20-93

10-22-92

11-26-92

10-22-92

10-20-92

10-20-92

10-20-92

10-20-92

10-22-92

10-22-92

10-22-92

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

•CO. 02

<0.02

<0.02

1248

<0.03

<0.03

0.61

0.44

0.25

0.09

0.17

0.05

0.14

0.15

<0.03

0.04

1.34

0.05

<0.03

<0.03

0.21

<0.03

0.15

<0.03

0.05

<0.03

o.ee1.51

<0.03

0.29

5.06

<0.03

<0.03

<0.03

0.04

0.12

0.19

0.18

1.50

0.10

0.14

0.46

1254

0.20

0.24

0.73

0.46

0.33

0.10

0.18

0.16

0.19

0.11

<0.01

0.18

0.63

0.17

0.11

0.13

0.34

0.12

0.46

0.10

0.13

0.06

0.21

1.00

0.07

o.ie1.97

0.10

0.06

0.74

0.07

0.16

0.28

0.22

0.61

0.22

0.28

0.68

1260

0.02

0.07

0.05

0.07

0.04

<0.02

<0.02

<0.02

0.07

<0.02

<0.02

0.02

0.11

<0.02

<0.02

<0.02

0.04

<0.02

0.07

<0.02

<0.02

<0.02

0.05

0.07

<0.02

<0.02

0.42

0.02

<0.02

<0.02

<0.02

0.02

0.03

0.03

0.07

0.02

0.03

0.06

Page 4 of 10

TOTAL

PCB

0.42

0.51

1.56

1.14

0.79

0.38

0.54

0.40

0.57

0.45

<0.23

0.41

2.25

0.41

0.33

0.35

0.76

0.34

0.85

0.32

0.37

0.28

1.31

2.75

0.29

0.66

7.62

0.32

0.28

0.96

0.30

0.47

0.67

0.60

2.35

0.51

0.62

1.37

SURR

REC

90

101

99

73

100

90

101

88

94

71

70

72

100

80

77

74

78

82

71

74

84

92

93

84

73

79

106

77

72

86

78

82

83

85

80

88

87

74

PERCENT SPK

LJPIDS REC

3.36

3.71

3.89

3.46

1.25

0.50

0.41

4.41

5.60

2.01

0.29

5.98

12.05

4.42

5.55

2.95

8.40

5.39

6.35

4.08

2.77

2.55

1.27

7.41

0.79

3.11

4.93

1.10

0.98

0.88 681 Rec

2.60 (1254)

4.15

7.79

9.67

9.05

5.28

3.60

1.47

1 5 5 0 - 3 7 .1 h - S t r e e t NE. PO Box 3 8 9 8 . C l e v e l a n d . TN 3 7 3 2 0 - 3 8 9 8 . 6 1 5 / 4 7 G - 7 7 C C Fax 4 7 6 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

MW Engineering & ScienceA Summit Cotn/xtny A N A I, Y T I C A L S E R V I C E S

WOODWARD CLYDE

PCS' a in Fiah Tiasue


September 24, 1S92

Unita log/Kg (ppm)

SAMPLE I.D.

3-SMB-l

3-SKB-2

3-SMB-3

3-EKB-4

3-SMB-S

3-SHB-6

J-SMB-7

3-SKB-8

4-CCT-l

4-CCF-2

4-CCF-3

4-CCF-4

4-CCT-5

4-CCP-6

4-CCP-7

4-CCT-8

4-CCF-9

4-CCF-10

4-CCF-ll

4-CCF-12

4-CCF-13

4-CCF-13-Dup

4-CCP-14

4-CCF-15

4-CC-l

4-CC-2

4-CC-3

4-CC-4

4-CC-5

4-CC-6

4-CC-6-SPK

4-CC-7

4-CC-8

4-CC-9

4-CC-10

4-CC-ll

4-CC-12

4-CC-13

4-CC-14

4-CC-15

4-CC-15-SPK

EXTRCTED

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-22-92

12-07-92

12-07-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-03-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

ANALYZED

12-09-92

12-09-92

12-09-92

1-15-93

12-09-92

12-09-92

1-15-93

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

1-15-93

1-13-93

12-20-92

12-11-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-11-92

12-11-92

12-11-92

12-12-92

12-12-92

12-12-92

12-11-92

12-11-92

12-11-92

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.0«

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

.<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

0.03

0.07

0.54

0.26

0.53

2.04

1.77

<0.03

0.22

0.22

0.34

0.15

O.B4

0.05

0.47

0.39

0.16

0.06

0.17

0.28

0.19

<0.03

0.17

0.13

0.85

1.98

0.39

1.15

0.15

0.83

<0.03

1.24

0.87

1.17

0.34

0.83

0.18

0.06

0.35

0.30

<0.03

1254

0.13

0.22

0.46

0.50

0.35

1.08

0.16

0.14

0.48

0.23

0.22

0.24

0.65

0.24

0.48

0.50

0.27

0.11

0.50

0.40

0.38

0.23

0.30

0.60

0.58

1.38

0.84

0.48

0.05

0.62

1.49

0.75

1.21

1.06

0.23

0.47

0.26

0.11

0.16

0.44

1.32

1260

0.03

0.07

0.12

0.23

0.11

0.24

0.11

0.04

0.08

0.03

0.06

0.04

0.13

0.04

0.10

0.07

0.04

<0.02

0.11

0.05

0.10

0.04

0.03

0.15

0.13

0.36

0.25

0.15

0.02

0.13

<0.02

0.16

0.37

0.23

0.06

0.10

0.04

0.02

0.04

0.09

<0.02

Page 5 of

TOTAL

PCB

0.36

0.53

1.29

1.16

1.16

3.53

2.21

0.38

0.95

0.65

0.79

0.60

1.79

0.50

1.22

1.13

0.64

0.36

0.95

0.90

0.84

0.47

0.67

1.05

1.73

3.89

1.65

1.95

0.39

1.75

1.71

2.32

2.62

2.63

0.80

1.57

0.65

0.36

0.72

1.00

1.54

SURR

REC

86

99

94

104

98

110

86

98

90

101

106

94

107

107

110

104

107

97

102

109

108

105

107

88

100

104

97

98

78

100

98

102

109

107

104

108

103

102

106

101

101

10

PERCENT SPK

LIPIDS

1.82

9.17

7.44

11.42

10.56

13.71

15.68

7.37

2.40

7.00

6.09

7.50

5.40

6.36

8.23

4.69

4.27

0.98

3.03

4.43

13.48

11.99

7.22

0.75

5.83

9.66

4.33

1.59

9.42

9.86

8.93

10.02

7.99

9.17

2.42

6.31

2.30

1.86

4.66

4.99

6.08

REC

87» Rec

(1254)

88» Rec

(1254)

1 5 5 0 - 37.lh- S i red N E . P O B o x 3 8 9 8 . C l e v e l a n d . T N 3 7 3 2 0 - 3 8 9 8 . 0 1 5 / 1 7 6 - 7 7 6 6 F a x 4 7 6 - 9 2 1 7

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit A N A L Y T I C A L S E R V I C E S

WOODWARD CLYDE

PCB's in Fiah Tissue


September 24, 1992

Units ing/Kg (ppm)

SAMPLE I.D.

4-FHC-l

4-FWD-l

4-PWD-2

4-FWD-3

4-FWD-4

4-FWD-S

4-FWD-6

4-FWD-7

4-FWD-8

4-FWD-9

4-FWD-10

4-FWD-ll

4-FWD-l 2

4-FWD-12-SPK

4-FWD-13

4-FWD-l 4

4-FWD-15

4-RCS-l

4-RCS-2

4-RCS-3

4-RCS-4

4-RCS-5

4-RCS-6

4-RCS-7

4-RCS-8

4-RCS-9

4-RCS-10

4-RCS-ll

4-RCS-l 2

4-RCS-l 3

4-RCS-l 4

4-RCS-l 5

4-SHB-l-A

4-SMB'l-SPK

S-CCF-1

S-CCF-2

5-CCT-3

5-CCF-4

5-CCF-4-DUP

5-CCF-5

5-CCF-6

5-CCF-7

EXTRCTED

11-24-92

11-24-92

11-24-92

11-24-92

11-24-92

11-24-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

11-24-92

11-24-92

11-24-92

11-24-92

11-24-92

11-24-92

11-24-92

11-24-92

11-24-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

12-09-92

02-12-93

02-12-93

1-20-93

12-11-92

12-11-92

12-11-92

12-11-92

12-12-92

12-12-92

12-12-92

ANALYZED

12-07-92

12-07-92

12-08-92

12-08-92

12-08-92

12-08-92

12-12-92

12-12-92

1-20-93

12-20-92

12-12-92

1-20-93

12-12-92

12-12-92

12-20-92

12-12-92

12-12-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-07-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

12-21-92

02-12-93

02-12-93

1-20-93

12-21-92

12-21-92

12-21-92

12-21-92

1-01-93

1-01-93

1-01-93

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<O.O7

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<o.o£<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0«

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<o.oe<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0£

<0.06

<o.oe<0.0£

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.t)2

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

0.11

0.11

0.11

0.45

O.S9

0.13

0.14

0.10

0.07

0.17

0.50

0.03

0.07

<0.03

0.16

0.21

0.66

0.21

0.31

0.67

0.15

1.57

1.04

0.25

<0.03

<O.O3

0.07

0.26

0.66

1.16

0.20

0.53

0.08

0.68

0.03

0.10

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

1254

0.21

0.40

0.08

0.41

0.47

0.16

0.34

0.16

0.33

0.38

0.67

0.37

0.16

1.09

0.52

0.21

0.61

0.11

0.10

0.65

0.16

1.47

1.03

0.41

0.04

0.10

0.12

0.31

0.39

1.02

0.64

0.63

0.17

0.48

0.32

0.29

0.37

0.16

0.19

0.15

0.12

0.19

1260

O.02

0.15

<0.02

0.04

0.12

0.03

0.13

0.04

0.04

0.04

0.14

0.07

0.02

<0.02

0.04

0.05

0.12

<0.02

<0.02

0.18

0.03

0.27

0.16

0.12

0.03

<O.02

<0.02

0.05

0.06

0.16

0.30

0.29

0.06

0.02

0.05

0.09

<0.02

0.05

0.05

<0.02

<0.02

0.02

Page 6 of 10

TOTAL

PCB

0.51

0.83

0.38

1.07

1.35

0.49

0.78

0.47

0.61

0.76

1.48

0.63

0.43

1.31

0.89

0.64

1.76

0.51

0.60

1.67

0.51

3.48

2.40

0.95

0.27

0.32

0.38

0.61

1.28

2.53

1.31

1.62

0.48

1.35

0.57

0.65

0.59

0.41

0.44

0.37

0.34

0.41

EURR

REC

94

97

87

86

$0

91

99

100

65

108

102

63

110

104

104

100

111

82

94

87

88

89

69

97

75

74

102

104

110

94

69

92

9

74

67

106

93

84

96

68

78

103

PERCENT SPK

LIPIDS

1.47

12.01

1.31

3.64

7.74

7.29

2.71

2.16

£.99

7.85

7.21

7.49

6.52

6.85

7.14

5.59

7.89

1.63

1.53

2.32

1.53

4.34

3.96

5.74

0.45

0.45

1.26

1.36

5.£1

3.43

1.01

3.16

2.24

1.64

5.64

4.39

0.55

0.57

ND

1.B7

1.23

5.41

REC

93* Rec

(1254)

65t Rec

(1248)

1 5 5 0 - 3 7tlu S t ree t . NE. PO Box 3 8 9 8 . C l e v e l a n d . TN 3 7 3 2 0 - 3 8 9 8 . G 1 5 / 1 7 G - 7 7 G 6 Fax 4 7 G - 9 2 1 /

I'^A.

_ WW Engineering & Science^m A Summit (A

IIIIIIIIIIIIIIIII

A N A I, V T I C A L S E R V I C E S

WOODWARD CLYDE

PCB'a in Fish Tissue

Samples Received September IB, 1992

September 24, 1992

Units ing/Kg (ppm)

SAMPLE I.D.

5-CCF-B

5-CCF-9

5-CCF-10

S-CC-1

5-CC-2

5-CC-3

S-CC-4

5-CC-5

5-CC-6

S-CC-6-SPK

S-CC-7

5-CC-8

5-CC-9

S-CC-10

S-CC-11

S-CC-11-SPK

5-CC-12

5-CC-13

5-CC-14

5-CC-15

S-FHC-1

S-FHC-1-SPK

5-FWD-l

S-PHD-2

5-FHD-3

S-FWD-3-SPK

S-FWD-4

S-FWD-5

5-PWD-S-DUP

5-PWD-6

5-FWD-7

S-FWD-8

5-FHD-9

S-FHD-10

5-PWD-ll

5-FVD-12

5-FWD-13

5-FWD-l 4

5-FWD-15

EXTRCTED

12-12-92

12-12-92

12-12-92

12-09-92

12-09-92

12-09-92

12-18-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-11-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

1-20-93

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

12-12-92

ANALYZED

1-01-93

1-07-93

1-07-93

12-12-92

12-12-92

12-20-92

12-21-92

12-21-92

12-21-92

12-21-92

12-21-92

12-21-92

12-21-92

12-21-92

12-21-92

12-21-92

12-22-92

12-21-92

12-21-92

12-21-92

12-21-92

12-21-92

1-07-93

1-07-93

1-07-93

1-07-93

1-14-93

1-20-93

1-20-93

1-14-93

1-15-93

1-07-93

1-07-93

1-07-93

1-07-93

1-08-93

1-08-93

1-08-93

1-15-93

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

•CO. 07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0fi

<0.06

<0.0«

<0.06

<0.06

<0.06

<0.06

<0.06

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<0.06

<0.06

<0.06

<0.0£

<0.06

<0.06

<o.oe<0.06

<0.06

<0.06

<0.06

<o.oe<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

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<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

<0.03

0.08

0.06

0.11

0.07

0.10

0.10

O.OS

<0.03

<0.03

0.17

0.16

<0.03

<0.03

<0.03

<0.03

0.12

0.23

0.20

<0.03

<0.03

<0.03

<0.03

0.1S

0.04

<0.03

0.03

0.52

0.37

0.09

0.10

0.13

0.08

0.07

0.10

<0.03

<0.03

0.11

0.07

1254

0.30

0.36

0.09

0.42

0.18

0.31

0.95

0.14

0.21

1.02

0.14

0.17

0.20

0.02

0.05

1.10

0.23

0.32

0.26

0.03

0.20

1.18

0.11

0.29

0.03

0.56

0.25

0.67

0.53

0.42

0.23

0.31

0.23

0.17

0.12

0.13

0.06

0. 17

0.50

1260

<0.02

0.04

<0.02

0.15

0.04

0.04

0.44

0.05

0.06

<0.02

0.03

0.05

0.04

<0.02

<0.02

<0.02

0.10

0.05

0.10

0.36

0.06

0.61

0.03

0.03

<0.02

<0.02

0.04

0.10

0.08

0.10

0.09

0.02

0.09

0.03

<0.02

<0.02

<0.02

0.03

0.12

Page 7 of

TOTAL

PCB

0.52

0.65

0.34

0.85

0.46

0.62

1.66

0.41

0.47

1.24

0.51

0.55

0.44

0.24

0.27

1.32

0.62

0.77

0.73

0.59

0.46

1.99

0.34

0.64

0.27

0.78

0.49

1.46

1.15

0.78

0.59

0.63

0.57

0.43

0.41

0.35

0.28

0.48

0.86

SURR

REC

89

107

96

84

100

93

99

93

96

100

99

105

102

96

98

97

108

103

105

107

99

94

103

107

98

71

101

88

70

106

104

108

106

87

109

87

83

105

106

10

PERCENT SPK

LIPIDS

2.32

11.85

2.54

1.64

4.S4

5.73

3.86

3.50

1.54

2.10

6.09

7.26

6.82

2.30

3.74

3.99

10.44

4.70

5.20

5.07

2.40

2.20

1.03

7.32

0.80

1.53

12.19

8.40

7.81

12.27

7.70

9.54

3.73

1.93

5.61

3.06

0.47

4.18

12.96

REC

8 It Rec

(1254)

105t Rec

(1254)

98t Rec

(1254)

S3t Rec

(1254)

1 5 5 0 - 37 - th - S l r cc l NE. PO Box 3 8 9 8 . C l e v e l a n d , TN 3 7 3 2 0 - 3 8 9 8 . (i 1 5/4 7 G - 7 7 G 0 T ; ix 4 7 0 - 9 2 1 7

IIIIIIiIIIIIIIIIIII

WW Engineering & ScienceA Summit Com/Kiiiy A N A I. Y T I C A L S K R V

WOODWARD CLYDE

PCB'B in Fish Tissue


September 24, 1992

Units mg/Kg (ppm)

SAMPLE I.D.

5-RCS-l

5-RCS-2

S-RCS-3

5-RCS-4

5-RCfi-S

5-RCS-5-DUP

S-RCS-6

5-RCS-7

5-RCS-8

5-RCS-9

S-RCS-10

5-RCS-10-SPK

5-EHB-l

5-SMB-2

S-SKB-3

S-SKB-3-SPK

S-SMB-4

S-SMB-5

5-SKB-5-SPK

S-SHB-6

5-SHB-7

5-SKB-8

5-SMB-9

5-SMB-10

7-CC-1-A-2

7-CC-1-A-3

7-CC-2-A-2

7-CC-2-A-3

7-CC-3-A-2

7-CC-3-A-3

7-CC-4-A-2

7-CC-4-A-3

7-CC-5-A-2

7-CC-S-A-3

7-CC-6-A-2

7-CC-6-A-3

7-CC-7-A-2

7-CC-7-A-3

7-CC-8-A-2

7-CC-8-A-3

7-CC-9-A-2

7-CC-9-A-3

7-CC-10-A-2

EXTRCTED

12-13-92

12-13-92

12-13-92

12-13-92

12-13-92

1-20-93

12-13-92

12-13-92

12-13-92

12-13-92

12-13-92

12-18-92

12-13-92

12-13-92

12-13-92

12-13-92

12-13-92

12-13-92

12-18-92

12-13-92

12-13-92

12-13-92

12-13-92

12-13-92

12-22-92

12-19-92

12-22-92

12-19-92

12-20-92

12-19-92

12-22-92

12-19-92

12-20-92

12-19-92

12-20-92

12-19-92

12-20-92

12-19-92

12-20-92

12-19-92

12-20-92

12-19-92

12-20-92

ANALYZED

1-05-93

1-05-93

1-05-93

1-06-93

1-14-93

1-20-93

1-05-93

1-05-93

1-05-93

1-08-93

1-05-93

1-08-93

1-05-93

1-08-93

1-05-93

1-05-93

1-08-93

1-05-93

l-OB-93

1-06-93

1-08-93

1-08-93

1-08-93

1-07-93

1-13-93

1-11-93

1-15-93

1-11-93

1-12-93

1-11-93

1-13-93

1-11-93

1-12-93

1-11-93

1-12-93

1-11-93

1-12-93

1-11-93

1-12-93

1-11-93

1-12-93

1-11-93

1-12-93

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.0£

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

<0.03

0.05

0.10

0.16

0.04

<0.03

0.04

0.04

0.05

0.12

0.07

0.82

0.41

0.90

<0.03

<0.03

1.24

0.03

0.63

<0.03

0.11

0.13

0.13

0.08

0.40

4.06

1.70

0.76

3.37

3.80

1.10

2.03

2.16

3.81

0.62

<0.03

2.05

4.80

2.66

1.62

2.85

0.25

0.52

1254

0.08

0.17

0.41

0.24

0.13

0.17

0.26

0.12

0.17

0.11

0.19

<0.01

1.96

0.51

0.26

1.26

0.78

0.10

<0.01

0.12

0.32

0.19

0.12

0.09

0.35

0.54

1.16

0.33

0.79

1.65

1.24

1.53

1.18

1.04

0.30

0.20

1.69

0.80

1.14

0.19

1.9S

0.23

0.34

1260

<0.02

<0.02

0.08

0.08

<0.02

0.03

0.04

0.02

0.03

0.03

0.02

<0.02

0.35

0.11

0.03

<0.02

0.10

<0.02

<0.02

<0.02

0.07

0.03

<0.02

<0.02

0.08

0.08

0.21

0.05

0.16

0.36

0.32

0.33

0.30

0.20

0.04

<0.02

0.63

0.14

0.27

0.03

0.76

0.02

0.17

Page 6 of 10

TOTAL

PCS

0.30

0.41

0.76

0.65

0.36

0.40

0.51

0.35

0.41

0.43

0.45

1.02

2.89

1.69

0.49

1.48

2.29

0.30

0.83

0.34

0.67

0.52

0.44

0.36

1 .00

4.85

3.24

1.31

4.49

5.98

2.83

4.06

3.81

5.22

1.13

0.42

4.54

5.91

4.24

2.01

5.73

0.67

1.20

SURR

REC

95

106

107

111

99

78

94

103

103

92

110

83

108

64

101

104

77

107

73

107

84

83

94

107

93

90

99

75

96

64

51

77

90

79

96

93

106

46

95

69

79

73

80

PERCENT SPK

LIPIDS

1.95

2.97

2.84

6.67

2.36

1.47

1.13

2.14

2.40

7.88

4.50

5.48

5.97

8.48

3.92

4.18

16.51

2.14

ND

5.65

14.06

12.91

7.57

5.08

12.82

5.47

3.46

4.89

5.18

3.90

2.32

1.60

6.29

6.49

2.32

1.47

8.35

12.56

10.40

3.79

5.34

2.06

3.13

REC

751 Rec

(1248)

1001 Rec

(1254)

601 Rec

(1248)

1 5 5 0 - 37.Hi- Sired NE. PO Box 3 8 9 8 . C l e v e l a n d . T N 3 7 3 2 0 - :* 0 9 0 . 0 1 5 / 4 7 0 - 7 7 6 0 Fax 4 7 6 - 9 2 I/

IIIIIIIIIIIIIIIIIII

WW Engineering & ScienceA Summit (A A N A I, V T I C A L S K R V I C K S

WOODWARD CLYDE

PCB'a in Fish Tissue

Samples Received September IB, 1992

September 24, 1992

Units mg/Kg (ppm)

SAMPLE I.D.

7-CC-10-A-3

7-CC-11-A-2

7-CC-11-A-3

7-CC-12-A-2

7-CC-12-A-3

7-CC-13-A-2

7-CC-13-A2SP

7-CC-13-A-3

7-CC-14-A-2

7-CC-14-A-3

7-CC-15-A-2

7-CC-15-A-3

LAB CONTROL

LAB CONTROL

LAB CONTROL

LAB CONTROL

LAB CONTROL

LAB CONTROL

LAB CONTROL

LAB CONTROL

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

R£. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

RE. BLANK

EXTRCTED

12-22-92

12-20-92

12-22-92

12-20-92

12-22-92

12-19-92

12-19-92

12-22-92

12-19-92

12-22-92

12-19-92

12-22-92

12-07-92

12-13-92

1-20-93

12-18-92

12-22-92

12-18-92

12-19-92

12-20-92

11-06-92

12-09-92

12-03-92

10-19-92

11-10-92

10-30-92

12-07-92

10-26-92

12-12-92

10-08-92

12-13-92

12-22-92

1-20-93

11-17-92

12-19-92

11-24-92

12-11-92

12-20-92

ANALYZED

1-13-93

1-13-93

1-13-93

1-12-93

1-13-93

1-11-93

1-11-93

1-13-93

1-11-93

1-13-93

1-11-93

1-13-93

12-12-92

1-05-93

1-20-93

1-15-93

1-13-93

12-21-92

1-11-93

1-13-93

11-30-92

12-12-92

12-08-92

10-20-92

12-02-92

11-26-92

12-11-92

11-25-92

1-1-93

10-13-92

1-05-93

1-13-93

1-20-93

12-04-92

1-11-93

12-07-92

12-21-92

1-13-93

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07 .

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

•cO.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

0.29

1.65

1.65

2.05

3.08

0.14

1.01

4.10

1.61

<0.03

0.47

0.69

<0.03

<0.03

<0.03

1.15

<0.03

0.62

0.54

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

<0.03

12S4

0.24

0.49

0.49

0.61

0.49

0.16

0.34

1.60

0.60

0.22

0.71

0.66

0.87

1.11

0.86

<0.01

0.80

<0.01

<0.01

0.71

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

<0.01

1260

0.12

0.10

0.10

0.16

0.07

<0.02

0.10

0.33

0.15

<0.02

0.23

0.10

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

Page 9 of 10

TOTAL

PCB

0.82

2.41

2.41

0.94

3.81

0.49

1.62

6.20

2.53

0.44

1.58

1.62

1.09

1.33

1.08

1.35

1.02

0.82

0.74

0.93

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

<0.23

SURR

REC

99

107

107

84

97

84

88

94

86

106

83

99

89

106

79

112

90

65

89

104

103

104

98

95

90

86

US

86

103

MS

102

89

91

89

79

92

97

105

PERCENT SPK

L1PIDS REC

10.13

7.81

3.27

8.01

4.07

1.41

1.79 871 REC.

4.92 (1248)

8.18

3.51

1.22

3.67

0.01 87» Rec

0.00 1111 Rec

0.01 86* Rec

-0.44 1151 Rec

0.00 80t Rec

0.00 621 Rec

0.00 541 Rec

0.00 71» Rec

0.01

0.00

0.00

0.00

0.00

0.00

0.00

0.00

-0.01

0.00

0.01

0.00

0.38

0.00

0.01

0.00

0.01

0.00

1550 - 3 7.1 h- Si re cl NE. PO Box 3098. C l e v e l a n d . TN 3 7 3 2 0 - 3 8 9 H . ( i I 3/4 7 6 - 7 7 GO \ - i \ x 4 7 G - 9 2 I 7

IIIIIIIIIIIIIIIIIII

W\V Engineering & ScienceA Summit Company A N A I. Y T I C A I, S K R V I (;

WOODWARD CLYDE

PCB'o in Fish Tissue

Sample o Received September 18, 1992

September 24, 1992

Units mg /Kg (ppm)

SAMPLE I.D.

SRH 112

SRM 113

SRM 114

SRM 115

SRM 116

SRM 117

SRM 118

SRM 126

SRM 126

SRM 129

SRM 131

SRM 132

ERM 133

EXTRCTED

12-12-92

12-09-92

10-30-92

11-24-92

12-13-92

12-03-92

12-O7-92

11-17-92

10-26-92

11-17-92

11-06-92

12-11-92

10-19-92

ANALYZED

1-01-93

12-12-92

12-08-92

12-08-92

1-05-93

12-08-92

12-11-92

12-08-92

12-08-92

12-04-92

12-08-92

12-21-92

12-08-92

1016

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

<0.07

1221

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

<0.06

1232

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

AROCLOR

1242

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

<0.02

1248

10.80

11.40

11.70

9.19

13.00

11.00

9.80

10.40

10.60

11.10

10.10

7. 83

12.20

12S4

<0.01

4.35

S.09

3.87

3.50

5.07

3.62

4.12

4.44

4.22

4.60

5.34

5.45

1260

<0.02

0.81

0.85

0.62

1.26

0.83

0.65

0.68

0.76

0.30

0.75

0.61

0.79

Page 10 of

TOTAL

PCB

11.00

16.73

17.81

13.85

17.93

17.07

14.24

15.37

15.97

15.79

15.62

13.95

18.61

SURR

REC

115

130

136

97

156

129

103

138

126

114

134

98

148

10

PERCENT SPK

LIPIDS REC

22.51

16.32

15.43

23.81

22.02

17.33

18.22

13.18

19.92

13.53

17.21

16.33

20.11

1 5 5 0 - 37.Hi- S t r e e t NG. I'O Box 3 H J J H . C I c v c 1 a n cl . TN :! 7 3 2 0 - :U( 9 8 . (i I ;W 4 7 0 - 7 7 f> 6 l r ; i . \ 4 7 0 - 9 2 1 7

11111111111111111

!•

TABLE Dl-2. ANALYSIS OF VARIANCE BETWEEN

SRM SRMScries I* Series 11**(mg/kg) (mg/kg) Anova: Single-Factor

12.78 10.9213.88 16.65 Summary11.63 17.7314.59 13.77 Groups Count Sum

12.88 17.8514.34 16.99 Column! 13 202.835

16.44 14.16 Column 2 7 96.54

15.2915.89 ANOVA15.7115.54 Source of Variation13.87 ss df18.53 Between Group 14.92707727 1

Within Groups 66.21871648 18

Total 81.14579375 19

* Extracted and Analyzed from July 29 to August 3, 1992*• Extracted and Analyzed from October 19, 1992, to January' 5, 1993

?d0$RW92 XLS(9/I4«3VNSV:<y


SRM ANALYSES

Average Variance

15.6027 4.3110

13.7914 2.4145

hiS F P -value Fern

. 14.9271 4.0576 0.0592 4.41393.6788

IIIIIIIIIIIIIIIIIII


APPENDIX DAnalytical Data

Note: Total PCB concentrations reported by WW Engineering and Science werecalculated by summing the reported method detection limit and the reportedconcentrations of each detected Aroclor. Total PCB concentrations for thisreport were recalculated using fifty percent of the reported detection limit forAroclors 1012, 1221, 1232, and 1242 plus reported concentration or detectionlimit for Aroclors 1248, 1252 and 1260. Aroclors 1012, 1221, 1232, and 1242were not detected in field samples. The total PCB concentrations used instatistical analyses are presented in Table Dl-1.


I Equipment Rinsate Data

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American Analytical Laboratories, Inc.I55O- 37lh Street. N.E. • P.O. BOX 3898 • Cleveland.TN 37320-3898 • (615) 476-7766. Fax (615)476-9217

LABORATORY REPORTAttn: Todd HuntWoodward-ClydeP. O. Box 1647357 Riverside DriveFranklin TN 37064

Authorized Release of DataLab Reference f 7737Sample Received: 07/21/1992Report Date: 07/28/1992 Maurice Smith, Ph.D.Sample Matrix: WATER Senior Chemist

PROJECT: IOWA FISH STUDY


SUPER-Q START PCB ATTACHED

Method: EPA-8080Date extracted: 07/21/1992Date analyzed: 07/23/1992

Approved By:

a member of Summit Environmental Group. Inc.

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT

Attns Todd HuntWoodward-Clyde

Lab Reference: # 7737Sample Received: 07/21/1992Report Date: 07/28/1992Sample ID: SUPER-Q START

Compound Results (jjg/L)

PCB-1016 <0.065PCB-1221 <0.065PCB-1232 <0.065PCB-1242 <0.065PCB-1248 <0.065PCB-1254 <0.065PCB-1260 <0.065Surrogate Recovery 88%

Approved By:

IIIIIIIIIIIIIIIIIII


Authorized Release of Data:Lab Reference fSample Received:Report Date:Sample Matrix:

773707/21/199207/28/1992WATER

Maurice Smith, Ph.D.Senior Chemist



SOPER-Q 1 RINSATE PCB ATTACHED


ApprovedAmerican AnalyticalLaboratories

I 55O-37lh Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O-3898 • (615) 476-7766. Fax (615)476-9217

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT


Lab Reference: # 7737Sample Received: 07/21/1992Report Date: 07/28/1992Sample ID: SUPER-Q 1 RINSATE

Compound Results (yg/L)


Approved By:

IIIIIIIIIIIIIIIIIII


Lab Reference i 7737Sample Received: 07/21/1992Report Date: 07/28/1992Sample Matrix: WATER


Sample ID Analysis

SUPER-Q 2 RINSATE PCS


Approved By:

Authorized Release of Data:

JJ\*MMaiirice Smith, Ph.D.Senior Chemist

Results

ATTACHED


155O - 37lh Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O3898 • (61 5) 476-7766. Fax (615) 476-92 1 7

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT


Lab Reference: i 7737Sample Received: 07/21/1992Report Date: 07/28/1992Sample ID: SUPER-Q 2 RINSATE

Compound Results (pg/L)


Approved By:


Lab Reference * 7737Sample Received: 07/21/1992Report Date: 07/28/1992Sample Matrix: WATER


Authorized Release of Data:

IA /*A!n Ar t JflJuMaurice Smith, Ph.D.Senior Chemist


SUPER-Q 3 RINSATE PCB ATTACHED


Approved By:American AnalyticalLaboratories

155O - 37lh Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O-3898 • (61 5) 476-7766. Fax (6 15) 476-92 I 7

IIIIIIIIIIIIIIIII

PESTICIDE REPORT


Lab Reference: # 7737Sample Received: 07/21/1992Report Date: 07/28/1992Sample ID: SUPER-Q 3 RINSATE

Compound Results ( g/L)


I

IIIIIIIIIIIIIIIIIII

American Analytical Laboratories, Inc.I55O- 37th Street. N.E. • P.O. BOX 3898 • Cleveland.TN 3732O-3898 • (615)476-7766. lrax (615) 476-921 i

LABORATORY REPORTAttn: Todd HuntWoodward-ClydeP.O. Box 680925Franklin TN 37068

Authorized Release of Data:Lab Reference * 7817Sample Received: 08/04/1992Report Date: 08/12/1992 Maurice Smith, Ph.D.Sample Matrix: WATER Senior Chemist




*Surrogate recoveries outside established acceptable limits due tosample emulsification.

Approved By:

a member of Summit Environmental Group. Inc.

IIIIIIIIIIIIIIIIIII

PESTICIDE REPORT



Compound


Results (pg/L)

<<<<<<<

0.10.10.10.10.10.10.1

61%

*Surrogate recoveries outside established acceptable limits due tosample eraulsification.

Approved By:

IIII

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Page 2 of

LABORATORY REPORT

Attn: Todd Hunt

Woodward-Clyde







I SUPER Q 5 RINSATE PCS ATTACHED

• ••American AnalyticalV V Laboratories

I 155O - 37th Street, N.E. • P.O. BOX 3898 • Cleveland.TN 3732O-3898 • (615) 476-77GC. Fax (615) 476-9217


IIIIIIIIIIIIIIII

APPENDIX E

W-test Results

IIIIIIIIIIIIIIIIIII

Site 2, Common Carp

Untransformed Data1 0.50002 0.80003 0.84004 1.17005 1.30006 1.77007 2.10008 2.5200 ^9 3.0300 ^, o $ !10 3.4000 ,0 < '""

11 3.4500 f 1 A 112 3.6800 \ -I ' '13 3.7600 "14 4.190015 5.6500

0: 31.2708 W: 0.9554

The population has a normal distribution.The U value, 0.9554 is greater than the 0.50quant He level of 0.9500 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 2, Common Carp

Transformed Data - LN(x)123l>56789101112131415

D.6931D.22313.1744

3.15703.26243.57103.7419J.9243

.1086

.2238

.2384

.3029

.3244

.4327

.7317

D: 7.1861 U: 0.9405

The population has a lognormal distribution. [ LN(x) ]The U value. 0.9405 is greater than the 0.10quantile level of 0.9010 for 15 sanples.

IIIIIIIIIIIIIIIIIII

Site 2, Common Carp

Transformed Data - LN(x+1)123456789101112131415

0.40550.58780.60980.77470.83291.01881.13141.25851.39381.48161.49291.54331.56021.64671.8946

D: 2.8344 U: 0.9554

The population has a lognormal distribution. [ LN(x+1) ]The U value, 0.9554 is greater than the 0.50quant He level of 0.9500 for 15 samples.

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Site 2, Channel Catfish 2-2-

Untransfortned Data12345678910111213H15 i

D.5100D.55009.60003.7400D.78001.12001.1300.UOO.1600.4200.4400.4500.7400.8700!.1500

D: 3.4719 U: 0.9571

The population has a normal distribution.The W value, 0.9571 is greater than the 0.50quantile level of 0.9500 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 2, Channel Catfish

Transformed Data - LN(x)12345678910111213U15

-0.6733-0.5978-0.5108-0.3011-0.24850.11330.12220.13100.14840.35070.36460.37160.55390.62590.7655

D: 2.8711 W: 0.9472

The population has a lognormat distribution. [ LM(x) ]The U value, 0.9472 is greater than the 0.10quantile level of 0.9010 for 15 samples.

IIIIIIIIIIIIIIIIIII


Transformed Data - LN(x+1)

12345678910111213U15

0.41210.43830.47000.55390.57660.75140.75610.76080.77010.88380.89200.89611.00801.05431.1474

D: 0.7343 U: 0.9588

The population has a lognormal distribution. [ LN(x+1) 1The U value, 0.9588 is greater than the 0.50quant lie level of 0.9500 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 2, Freshwater Drum

Untransfonned Data

1234567B9101112131415

0.23000.26000.28000.32000.35000.35000.37000.47000.48000.70000.86000.9SOO1.12001.20002.0300

D: 3.4552 U: 0.8123

The data is not normally distributed.

IIIIIIIIIIIIIIIIIII

Site 2, Freshwater Drum -, J

Transformed Data - LN(x)123456789101112131415

-1.4697-1.3471-1.2730-1.1394-1.0498-1.0498-0.9943-0.7550-0.7340-0.3567-0.1508-0.05130.11330.18230.7080

D: 6.0453 U: 0.9366

The population has a lognormal distribution. [ LN(x) ]The U value, 0.9366 is greater than the 0.10quantile level of 0.9010 for 15 samples.

Transformed Data - LN(x+1)12345678910111213H15

0.20700.23110.24690.27760.30010.30010.31480.38530.39200.53060.62060.66780.75140.78851.1086

• Site 2, Freshwater Drum i7,4

IIIIIIIIIIIIIIIIII

D: 0.9616 W: 0.8758

The population has a lognormal distribution. [ LN(x-M) ]The U value, 0.8758 is greater than the 0.02quant He level of 0.8550 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 2, River Carpsucker n

Untransformed Data123456789101112131415

0.24000.25000.28000.32000.40000.44000.45000.54000.85001.65001.89002.42004.94006.88008.2400

D: 94.4948 U: 0.7168

The date is not normally distributed.

IIIIIIIIIIIIIIIIIII

Site 2, River Carpsucker °>-

Transformed Data - LN(x)1234567e9101112131415

-1.4271-1.3863-1.2730-1.1394-0.9163-0.8210-0.7985-0.6162-0.16250.50080.63660.88381.59741.9286

2.1090

0: 21.5385 U: 0.8927

The population has a lognormal distribution. [ LN(x) ]

The U value, 0.8927 is greater than the 0.05quantile level of 0.8810 for 15 samples.

I Site 2, River Carpsucker

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1 0.21512 0.22313 0.24694 0.2776

5 0.33656 0.3646

7 0.37168 0.4318

9 0.615210 0.974611 1.061312 1.229613 1.781714 2.064315 2.2235

0: 6.8718 U: 0.8222

The data is not lognonnally distributed. [ LN(x+1) ]

Untransformed Data1 0.27002 1.27003 1.39004 2.02005 2.2200

0: 2.3449 U: 0.9303

The population has a no mat distribution.The U value, 0.9303 is greater than the 0.50quantite level of 0.9270 for 5 samples.

J Site 2, Smallmouth Buffalo 2.

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Transformed Data - LN(x)1 -1.30932 0.23903 0.32934 0.70315 0.7975

D: 2.8949 U: 0.7899

The population has a lognormal distribution. [ LN(x) ]The U value, 0.7899 is greater than the 0.05quant He level of 0.7620 for 5 samples.

I Site 2, Smallmouth Buffalo

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Transformed Data - LN(x+1)1 0.23902 0.81983 0.87134 1.10535 1.1694

D: 0.5414 U: 0.8723

The population has a lognonnal distribution. [ LN(x-M) ]The U value, 0.8723 is greater than the 0.10quantile level of 0.8060 for 5 samples.

J Site 2, Smallmouth Buffalo

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Site 3, Common Carp ->

Untransfonned Data123456789101112131415

0.32000.37000.53000.74001.33001.36002.15002.33003.19004.12005.22006.03006.36006.91007.7900

D: 95.9418 U: 0.9028

The population has a normal distribution.The U value, 0.9028 is greater than the 0.10quantile level of 0.9010 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 3, Common Carp

Transformed Data - LN(x)12345678910111213U15

-1.1394-0.9943-0.6349-0.30110.28520.30750.76550.84591.16001.41591.65251.79671 .85001 .93302.0528

D: 16.8806 U: 0.9201

The population has a lognonnal distribution. [ LN(x) ]The U value, 0.9201 is greater than the 0.10quantile level of 0.9010 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 3, Common Carp


3

4

5

6

7

8

9

10

11

12

13

u ;15 2

3.2776

D.3148

D.4253

3.5539

J.8459

D.8587

1.U74

.2030

.4327

.6332

.8278

.9502

.9961

'.0681

1.1736

D: 6.3972 W: 0.9254

The population has a lognonnal distribution. [ LN(x+1) ]The U value. 0.9254 is greater than the 0.10quantile level of 0.9010 for 15 samples.

IIIIIIIIIIIIIIIIIII



34

56

7

8

9

1011

12

1314

15

0.2800

0.3000

0.3100

0.3SOO

0.4000

0.4000

0.4100

0.4200

0.4400

0.4600

0.7000

0.7800

0.8700

1.0000

2.0800

D: 2.9957 W: 0.6825




-1.2730-1.2040-1.1712-1.0498-0.9163-0.9163-0.8916-0.8675-0.8210-0.7765-0.3567-0.2485-0.13930.00000.7324

D: 4.2593 U: 0.8803

The population has a lognormal distribution. [ LN(x) ]The U value. 0.8803 is greater than the 0.02quant He level of 0.8550 for 15 samples.

IIIIIIIIIIIIIIIIIII


Transformed Data - LN(x+1)12345678910111213U15

0.24690.26240.2700

0.30010.33650.33650.34360.35070.36460.37840.53060.57660.62590.69311.1249

D: 0.7588 U: 0.7784

The data is not lognormally distributed. [ LN(x+1) ]

Untransfonned Data1 0.30002 0.46003 0.7100

0: 0.0854 U: 0.9842


I Site 3, Flathead Catfish

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Transformed Data - LN(x)1 -1.2MO2 -0.77653 -0.3425

0: 0.3711 W: 1.0000

| Site 3, Flathead Catfish ?,

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* The population has a lognonnal distribution. [ LN(x) ]The U value. 1.0000 is greater than the 0.50

H quantile level of 0.9590 for 3 samples.

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Transformed Data - LN(x+1)1 0.26242 0.37843 0.5365

D: 0.0379 W: 0.9922

The population has a lognonnal distribution. [ LN(x+1) ]The U value, 0.9922 is greater than the 0.50quant He level of 0.9590 for 3 samples.

I Site 3, Flathead Catfish

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Untransfonned Data12345678910111213H15

0.15000.20000.23000.25000.26000.27000.29000.32000.32000.33000.37000.49000.68000.77002.1700

D: 3.4967 W: 0.5691


IIIIIIIIIIIIIIIIIII



3

4

5

6

7

8

910

11

12

13

14

15

--

-

-

-

-

-

-

.8971

.6094

.4697

.3863

.3471

.3093

.2379

.1394

-1.1394

-1.1087

-0.9943

-0.7133

-0.3857

-0.2614

0.7747

D: 6.0210 U: 0.8751

The population has a lognonnal distribution. [ LM(x) ]The U value, 0.8751 is greater than the 0.02quantile level of 0.8550 for 15 samples.

IIIIIIIIIIIIIIIIIII



12345678910111213H15

0.13980.18230.20700.22310.23110.23900.25460.27760.27760.28520.31480.39880.51880.57101.1537

D: 0.8860 U: 0.6866

The data is not lognormally distributed. [ LM(x+1) ]

Site 3, River Carpsucker

Untransformed Data12345678910111213H15

0.20000.21000.21000.24000.39000.43000.51000.54000.58000.59001.23001.28002.27002.67007.5300

D: 50.1294 U: 0.5907


IIIIIIIIIIIIIIIIIII



-1.6094-1.5606-1.5606-1.4271-0.9416-0.8440-0.6733-0.6162-0.5447

-0.52760.20700.24690.81980.98212.0189

D: 15.8969 U: 0.9180

The population has a lognonnal distribution. [ LN(x) ]The U value. 0.9180 is greater than the 0.10quantile level of 0.9010 for 15 samples.

IIIIIIIIIIIIIIIIIII



0.18230.19060.19060.21510.32930.35770.41210.43180.4574

0.46370.80200.82421.18481 .30022.1436

D: 4.1825 U: 0.7924

The data is not lognonnally distributed. C LN(x+1) ]

Untransformed Data1 0.27002 0.29003 0.45004 1.08005 1.08006 1.21007 2.13008 3.4500

0: 8.1956 U: 0.8499



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Transformed Data - LN(x)1 -1.3093

2 -1.23793 -0.79854 0.07705 0.07706 0.19067 0.75618 1.2384

D: 5.9111 U: 0.9304

The population has a lognonnal distribution. [ LM(x) ]The U value. 0.9304 is greater than the 0.10quantile level of 0.8510 for 8 samples.


3

4

5

6

7

8

0.2390

0.2546

0.37160.7324

0.7324

0.7930

1.1410

1.4929

D: 1.3496 U: 0.9175

The population has a lognormal distribution. [ LN(x+1) ]The U value, 0.9175 is greater than the 0.10quantile level of 0.8510 for 8 samples.


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Site 4, Common Carp

Untransformed Data

12345678910111213U15

0.27000.31000.57000.63000.71000.92001.48001.57001.65001 .67001 .87002.24002.54002.55003.8000

D: 13.7214 W: 0.9418

The population has a normal distribution.The U value, 0.9418 is greater than the 0.10quant lie level of 0.9010 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 4, Common Carp >'

Transformed Data - LN(x)12345678910111213K15

-1.3093-1.1712-0.5621-0.4620-0.3425-0.08340.3920

0.45110.50080.51280.6259

0.80650.93220.9361

1 .3350

D: 8.7428 U: 0.9416

The population has a lognormal distribution. [ LH(x) ]The U value, 0.9416 is greater than the 0.10quant fie level of 0.9010 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 4, Common Carp


0.23900.27000.45110.48860.53650.65230.90830.94390.97460.98211.05431.17561.26411.26691.5686

0: 2.1914 U: 0.9641

The population has a lognonnal distribution. [ LN(x+1) ]The U value, 0.9641 is greater than the 0.50quant He level of 0.9500 for 15 samples.

IIIIIIIIIIIIIIIIIII


Untransformed Data12345678910111213U15

0.27000.41000.52000.56000.57000.57000.58000.71000.82000.87000.8700

0.97001.04001.13001.7100

D: 1.7543 W: 0.9160


IIIIIIIIIIIIIIIIIII



-1.3093

-0.8916-0.6539-0.5798-0.5621-0.5621-0.5447-0.3425-0.1985-0.1393-0.1393-0.03050.03920.12220.5365

D: 2.8610 U: 0.9827

The population has a lognonnal distribution. [ LN(x) ]The U value, 0.9827 is greater than the 0.50quantUe level of 0.9500 for 15 samples.

IIIIIIIIIIIIIIIII


Transformed Data - LM(x-M)123456789101112131415

0.23900.34360.41870.4447

0.45110.45110.4574

0.53650.59880.62590.62590.67800.71290.75610.9969

0: 0.4946 U: 0.9664

The population has a lognoraal distribution. [ LM(x+1) ]The U value, 0.9664 is greater than the 0.50quant He level of 0.9SOO for 15 samples.

IIIIIIIIIIIIIIIIIII

U (-'Site 4, Freshwater Drum

Untransfortned Data12345678910111213H15

0.29000.34000.39000.40000.53000.55000.56000.68000.70000.75000.81000.99001.27001.4000

1.6800

D: 2.3822 U: 0.8996

The population has a normal distribution.The U value, 0.8996 is greater than the 0.05quant fie level of 0.8810 for 15 samples.

IIIIIIIIIIIIIIII

Site 4, Freshwater Drum V d


-1.2379-1.0788-0.9416-0.9163-0.6349-0.5978-0.5798-0.3857-0.3567-0.2877-0.2107-0.01010.23900.33650.5188

D: 3.8455 U: 0.9780

The population has a lognonnal distribution. [ LN(x) ]The U value. 0.9780 is greater than the 0.50quantile level of 0.9500 for 15 samples.

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Transformed Data - LN(x+1)12345678910111213H15

0.25460.29270.32930.3365

0.42530.43830.44470.51880.53060.55960.59330.68810.81980.8755

0.9858

D: 0.6763 U: 0.9414



Untransfortned Data

12

34

56

7891011

12

1314

15

0.1900

0.2400

0.30000.4300

0.43000.52000.73000.87001.20001.2300

1.5400

1 .5900

2.3200

2.4500

3.4000

D: 12.6343 U: 0.8886

The population has a normal distribution.

The U value, 0.8886 is greater than the 0.05quanttie level of 0.8810 for 15 samples.

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Transformed Data - LH(x)12345678910111213U15

-1.6607-1.4271-1.2040-0.8440-0.8440-0.6539-0.3147-0.13930.18230.20700.43180.46370.84160.89611.2238

0: 11.1631 V: 0.9708

The population has a lognocmal distribution. [ LH(x) ]The U value, 0.9708 is greater than the 0.50quant He level of 0.9500 for 15 sanples.

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Transformed Data - LN(x-M)12345678910111213H15

0.17400.21510.26240.35770.35770.41870.54810.62590.78850.80200.93220.95171.20001.23841.4816

D: 2.3302 U: 0.9459


IIIIIIIIIIIIIIIIIII

Site 5, Common Carp

Untransfonned Data

12345678910111213U15

0.16000.18000.32000.36000.37000.39000.43000.46000.51000.53000.54000.64000.68000.77001.5800

0: 1.5876 W: 0.7771


IIIIIIIIIIIIIIIIIII

Site 5, Common Carp

Transformed Data - LN(x)

12

3

4

5

6

7

8

9

10

11

12

13

14

15

-1.8326-1.7148-1.1394-1.0217-0.9943-0.9416-0.8440-0.7765-0.6733-0.6349-0.6162-0.4463-0.3857-0.26140.4574

0: 4.3708 U: 0.9609

The population has a lognormat distribution. [ LN(x> ]

The U value. 0.9609 is greater than the 0.50

quant He level of 0.9500 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 5, Common Carp

Transformed Data - LM(x+1)12345678910111213U15

0.14840.16550.27760.30750.31480.32930.35770.37840.41210.42530.43180.49470.51880.57100.9478

D: 0.5101 W: 0.8797

The population has a lognormal distribution. [ LN(x+1) ]The U value, 0.8797 is greater than the 0.02quant fie level of 0.8550 for 15 samples.

IIIIIIIIIIIIIIIIIII

Site 5, Channel Catfish / ,'1


0.26000.26000.29000.33000.34000.44000.49000.51000.57000.5700

D: 0.1390 U: 0.8841


I Site 5, Channel Catfish , am '-y

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Transformed Data - LN(x)1 -1.34712 -1.34713 -1.23794 -1.10875 -1.07886 -0.82107 -0.71338 -0.67339 -0.562110 -0.5621

0: 0.8898 U: 0.8869

The population has a lognormal distribution. [ LN(x) ]The U value, 0.8869 is greater than the 0.10quant He level of 0.8690 for 10 samples.

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Transformed Data - LM(x+1)1 0.23112 0.23113 0.25464 0.28S25 0.29276 0.36467 0.39888 0.41219 0.451110 0.4511

0: 0.0701 U: 0.8852


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Site 5, Freshwater Drum 4.

Untransformed Data

123456789101112131415

0.18000.20000.25000.27000.33000.35000.40000.41000.49000.50000.55000.56000.70000.77001.2200

0: 1.0080 U: 0.8780


IIIIIIIIIIIIIIIIIII

Site 5, Freshwater Drum J


3

4

5

6

7

8

9

10

11

12

1314

15

-1.7148

-1.6094

-1.3863

-1.3093

-1.1087

-1.0498

-0.9163

-0.8916

-0.7133

-0.6931

-0.5978

-0.5798

-0.3567

-0.2614

0.1989

D: 3.8022 U: 0.9916

The population has a lognormal distribution. [ LN(x) ]

The U value. 0.9916 is greater than the 0.50quant He level of 0.9SOO for 15 samples.

IIIIIIIIIIIIIIIIIII



3

4

56

7

8

9

10

11

12

13

H

15

0.16550.18230.22310.23900.28520.30010.33650.34360.39880.40550.43830.44470.53060.57100.7975

0: 0.3901 U: 0.9354


IIIIIIIIIIIIIIiIIII

Site 5, River Carpsucker ,5


0.22000.27000.30000.33000.33000.34000.3700

0.43000.57000.6700

D: 0.1734 U: 0.8776


Transformed Data -1 -1.51412 -1.30933 -1.2040

4 -1.10875 -1.10876 -1.0788

7 -0.99438 -0.84409 -0.562110 -0.4005

D: 1.0054 U: 0.9500

The population has a lognormal distribution. [The U value, 0.9500 is greater than the 0.50quantile level of 0.9380 for 10 samples.


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56

78

9

10

0.19890.23900.26240.28520.28520.2927

0.31450.3577

0.45110.5128

D: 0.083S U: 0.9007


I

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The population has a lognormal distribution. [ LN(x+1) ]The U value, 0.9007 is greater than the 0.10

• quant fie level of 0.8690 for 10 samples.

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0.24000.26000.28000.36000.40000.43000.58001.61002.21002.8000

D: 7.9218 W: 0.7416



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Transformed Data - LM(x)1 -1.4271

2 -1.34713 -1.27304 -1.0217

5 -0.9163

6 -0.8440

7 -0.5447

8 0.4762

9 0.7930

10 1.0296

D: 7.7043 U: 0.8440

The population has a lognormal distribution. [ LN(x) ]The U value, 0.8440 is greater than the 0.05quant fie level of 0.8420 for 10 senples.

J Site 5, Smallmouth Buffalo

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Transformed Data - lN(x+1)1 0.21512 0.23113 0.24694 0.30755 0.33656 0.35777 0.45748 0.95949 1.166310 1.3350

D: 1.6180 W: 0.7783

The data Is not lognormally distributed. [ LN(x+1) ]

• Site 5, Smallmouth Buffalo

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FINAL REPORT IDavenport Works to characterize polychlorinated biphenyl (PCB) concentrations in fish...

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Transcript of FINAL REPORT IDavenport Works to characterize polychlorinated biphenyl (PCB) concentrations in fish...