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Material Certification

MATERIAL SAFETY DATA SHEET

polyamide - KOPA

1. PRODUCT & COMPANY IDENTIFICATION

PRODUCT PolyamideTRADE NAME KOPA, KN3322V0LMANUFACTURER Kolon Ind.,Inc.ADDRESS Kolon Tower, 1-23, Byulyang-Dong, Kwacheon-City

Kyunggi-Do, S.KoreaPHONE +822-3677-3614FAX +822-3677-3556

2. COMPOSITION / INFORAMTION ON INGREDIENTS

CHEMICAL NAME Polymer : poly[imino(1-oxo-1,6-hexanediyl)]Addtive : Melamine-Cyanurate

CHEMICAL FORMULA Polymer : [CO(CH2)5NH]nAddtive : (Melamine-Cyanurate): C3H3(NH2)3.C3N3(OH)3

GENERAL NAME polyamide 6ABBREVIATION NAME PA6, N6CAS NO. Polymer : 25038-54-4

Addtive : (Melamine-Cyanurate): 37640-57-6SUBSTANCE( ),MISTURE( O No class & No numberTSCA Registered

3. HAZARDS IDENTIFICATION

INHALATION Long term inharating its dust, pneumoconiosis can be occured

SKIN Allergic can be occured, depending personal constitution

EYE The cornea can be injured when it contacts directly.

INGESTION N.A * N.A : Not Applicable

4. FIRST-AID MEASURES

INHALATION - In case inhalating the gas during work, get out of there and breath fresh air. - When excessivly, after doing above measure and take a measure with doctorSKIN CONTACT - Cool it with proper water, when you touch the molten flow. - Don't remove it forcibly, when it is attached very critically - In allergic conditon, wash it with clean water and soap - With injured, go to doctor for treatment

EYE CONTACT

KOLON

- If it is not hot, wash eye with flowing, clean water - Don't rub eye, wash it with blink - If hot melten contacts, go to doctor immediately for treatment

INGESTION - Vomit it after drinking several cups of water if not hot material - In case of hot material, drinking clean water and take a measure from doctor

5. FIRE-FIGHTING MEASURES

Extinguish knack - Occupy safty distance, and spray an extinguisher of fiber - If there is not available extingusher, use sand or hydrant - Firefighter should wear proper protective equipment - Take the people shelter who are near by. - The harzard gas can be occured when combusting Gas can be occured : Carbon Dioxide Carbon Monooxide

- Note, sometimes water might be not available, when extinguishing

A KIND OF EXTINGUISHMENT - ABC POWDER, HARON EXTINGUISHMENT, SAND, CARBONDIOXIDE, WATER, etc

6. ACCIDENTAL RELEASE MEASURES

MEASURES FOR HANDLING PERSONNEL - Shut off all sources of ignition : no flames, no smoking in area

MEASURES FOR ENVIRONMENTAL EFFECTS - Take away in assortment - Don't discharge to river

MEASURES WHEN HANDLING SPILLED SUBSTANCES - Keep it saperately after having it sweeped

7. HANDLING AND STORAGE

HANDLING

Exposure control for handling personnelUse only in the well-ventilated areasDon't breathe dustWhen using, don't somke and don't have igniter

Protective measures against & explosionShut off all gas polot and electrical(spark or hot wire)ignites and other sources of ignition during use and until all vapors(odors) are gone.Don't expose it to dust or foreign substancePrevent it from any friction or shock

Prevent build-up of electostatic charges (e-g . by grounding)In case of fire and/or explosion, don't breathe fumes.

OthersAvoid rough handling or droppingDon't flush to sewer or waterways.Don't mix with : In a molding machine : acids

STORAGE

Make it packed to prevent the moistureKeep away from heat, steam pipe or sunlight.Incompatibility (Specific materials to be avoided) : acids, bases, oxydizing agents, water

8. EXPOSURE CONTROL / PERSONAL PROTECTION

CONTROL PARAMETERS

CONTENT PA6ACGIH TWA 10mg/m3OSHA respirable fract 5mg/m3

Total Dust 15mg/m3

FACILITY CONTROLIn case the material is powder state, use it in shut covered building

PERSONAL PROTECTIVE EQUIPMENT

Respiratory protectionFor most conditions, no respiratory protection should needed.But, in dusty atmosphers, use an approved dust respirator.

Eye ProtectionWear protective eyeglasses or chemical safety goggles.

Hand, skin and body protectionWear suitable protective clothing.Wear suitable glove.

9. PHYSICAL & CHEMICAL PROPERTIES

Appearance Pellet form solids Odor NoneDensity 1.16 Boiling Point NoneMelting Point 220 Vapor pressure NoneVapor density None Solubility(%)Volatility None in water : insoluble

in others : N.A

10. STABILITY & REACTIVITY

Chemical reactivityIn general condition it is safe.

Condition to be avoided

Mixture with acids or bases.Exposure of water

Harzard Gases from combustionMono-oxide, Carbon dioxide

This product is considered a stable material under normal and anticipated storageThe mixture of air and dust can be explusion.

11. TOXICOLOGICAL INFORMATION

Acute toxicity N.ASub-chronic toxicity N.AChronic toxicity N.ACarcinogenic effects N.AMutagenic effects N.AIrritant properties Occuring gas can be irritantAllergenic & sensitizing effects N.ATeratogenic effects N.A

12. ECOLOGICAL INFORMATIONBiodegradability N.ABioaccumulation N.AFish toxicity N.A

13. DISPOSAL CONSIDERATIONDon't dump into sewers, on the ground or into any body of water.Dispose to an authorized waste collection point.

14. TRANSPORT INFORMATIONAvoid wetting or rough handling so that the packaging will not be damaged.I n case the bags are damaged an the pellets are scattered, pay attention so that no one will slip and fall.All of the materials that have spilled shall be repidly collected.

15. REGULATORY INFORMATION

Regulatory informationThe finished product made by this material can be regulated by korean law of harzard control,

law of food hygienics, the Drugs.

It can be regulated by law of nation or region itself in outside korea.

Other regulatory informationThe Kolon Industries Inc. is not able to check up the regulatory information in regard to the substances in youcountry or region, therefore, we request this matter would be filled by your resposibility. Regulatory informatiowith regard to this substance in you country or region should be examined by your own responsibility.Ensure this material in compliance with federal requirements and ensure conformity to local requlations.

16. OTHER INFORMATION

The information related to this specific material may not be valid for using in combination with any othermaterials or with any other process. Kindly, note that the matter is uses's responsibility.The information herein given is good faith, but no warranty, expressed or implied, is made.Please consult Kolon for further information.

To the best of our knowledge, the information contained here in is accurate, however, neither Kolon norany subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herin. Final determination of suitability of any material is the sole responsibility of user.All materials may present unknown hazards and should be used in caution. Although certain harzards are described herein, we can't guarantee that these are the only hazards exist.This information contained in this data sheet represents the best information currently available to us.But, no warranty is made with respect to its completeness and we assume no liability resulting from its use. It is advised to make their own tests to determinate the safety and suitability of each product of combination for their own purposes.

S A F E T Y

1/1

TECHNYL® 2021SW Date : 01/03/2003 Version : 4 Cancels and replaces version : 3

1 Product and company identification

Product Name : TECHNYL 2021SW Supplier

Name : Rhodia Polyamide

Address : 3rd Fl. Kangnam B/D 1321-1, Seocho-Dong, Seocho-Gu, Seoul 137-070, Korea

Telephone number : 82-52-231-0921(QA) / 82-2-2186-2500(Head Office)

Telefax number : 82-52-231-0992(QA) / 82-2-3474-7363(Head Office)

2 Composition / information on ingredients

>>PREPARATION :

Chemical nature : Product based on Polyamide 66.(CAS : 32131-17-2) Non-halogen flame retardant

Usually contains lubricants and protectors.

>>Further information : Semi-processed polymer.

3 Hazard identification

MOST IMPORTANT HAZARDS : Adverse human health effect :

Physical and chemical hazards : - Further hazards Do not present any specified hazards, provided it is handled in

accordance with the supplier’s proposed method of use.

Classification/Specific hazards : According to EEC criteria, this product is not classified as a “hazardous preparation.

S A F E T Y

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4 First-aid measures

Inhalation : Not specifically applicable . Skin contact : Not specifically applicable. However, in the event of fire, molten product may cause thermal burns. In this case : Rinse with plenty of water. DO NOT remove clothing(since it may stick to the skin) Call a doctor immediately. Eye contact : Not specifically applicable . Ingestion : Not specifically applicable.

5 Fire-fighting measures Extinguishing method :

- Suitable : All extinguishable agents can be used(water, form, powders, carbon dioxide, sand, etc)

- Not suitable : None. If there is a fire close by, use suitable extinguishing agents. Specific hazards : Harmful or toxic vapors are released. Combustible product, melts on heating. Risk of fire spreading due to the flow of liquid which is already alight Specific fire fighting methods : Cool the molten products. Protection of fire-fighters : Self-contained breathing apparatus

6 Accidental release measures Personal precautions : Prevent the product from spreading into the environment Environmental precautions : This product does not present any particular risk for the Environment. Method for cleaning up : .

- Recovery : Recover the product by vacuuming/shoveling or swelling.

- Cleaning/Decontamination : Sweep

S A F E T Y

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7 Handling and storage

HANDLING

- Technical measure : Does not require any specific or particular measures.

- Safe handling advice : Do not overheat the product.

STORAGE . - Technical measure : Does not require any specific or particular technical measures.

- Recommended storage

conditions : Store: - Away from any flames. - Protected from humidity and bad weather conditions

Incompatible products : Oxidizing materials Packaging : The product is packaged in paper bag lined with Al foil. Packaging materials

- Recommended Cardboard

8 Exposure controls / personal protection Engineering measures : The product, as is, does not require any specific/particular measures provided it is handled in accordance with good industrial hygiene and safety practice. During the transformation process : Extraction to remove vapors at their source. Occupational exposure limits : Does not require any specific or particular measures.

- Limits(France) : No specific limits.

- Limits(Germany) : No specific limits.

- Limits(USA/A.C.G.I.H.) : No specific limits. Personal protective equipments : Does not require any specific or particular technical measures.

- Skin and body protection : No specific/particular action required for this product. Comply with good occupational hygiene practice. Further Information : The product (as is) or during its use, does not produce dust. The difference components and fillers are incorporated in the bulk of the polymer.

S A F E T Y

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9 Physical and chemical properties APPEARANCE

- Physical state : Solid

- Form : Pellets.

- Color : Depends on the pigments Odor : none to very slight. pH : Not applicable Specific temperatures : Does not require any specific or particular technical measures.

- Melting : Melting range 255~265 Decomposition temperature : > 350 Flammability characteristics

- Flash point : > 400(Closed cup)

- Auto-ignition temperature : > 450(Spontaneous ignition temperature) Oxidizing properties : Non oxidizing material according to EEC criteria. Solubility :

- in water : Practically insoluble.

- in organic solvents : Insoluble in common organic solvents. 10 Stability and reactivity

Stability : Stable under normal conditions of use. Hazardous reactions :

- Conditions to avoid : No dangerous reactions known under normal conditions of use - Hazardous decomposition

products : On combustion or on thermal decomposition (pyrolysis) releases : Toxic gases

(Carbon Oxides, CO+CO2) (Nitrogen Oxides, NOx) (Hydrogen Cyanide)

S A F E T Y

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11 Toxicological information Local effects :

(- No data) : Given the physical state of the product (as supplied) this is not applicable Further information : Does not present any particular risk, on handling under normal conditions of good occupational hygiene practice.

12 Ecological information

Behavior in the environment

- Persistence/Degradability : Persisting product

- Destination of the product : Ultimate destination of the product : SOIL.

13 Disposal considerations

WASTE FROM RESIDUES :

- Destruction/Disposal : Recycle the material as far as possible. If it proves necessary to grind the product in order to recycle it, Take it all necessary precautions to prevent the formation and Spread of dust. Not recycled product : May be disposed of with non hazardous industrial waste. Incinerate at a accordance with relevant local regula tions. CONTAMINATED PACKAGING :

- Decontamination/Cleaning : Not applicable.

- Destruction/Disposal : Depending on local facilities recycle the cardboard packaging, or incinerate it at an approved site. NOTE : The user’s attention is drawn to the possible existence of local regulations regarding disposal.

S A F E T Y

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14 Transport information INTERNATIONAL REGULATIONS : LAND :

- Rail/Road (RID/ADR) : Not restricted Sea (IMO/IMDG) : Not restricted Air (ICAO-IATA) : Not restricted NOTE : The above regulations prescriptions are those valid on the date of publications of this sheet.

Given the possible evolution of transport regulations for Hazardous materials, it would be advisable to check their validity with your sales office. 15 Regulatory information

LABELING :

- Korea regulations : Mandatory labeling(self-classification) of hazardous preparations : Stimulus material NOTE : The regulatory information given above only indicators the principle regulations specifically applicable to the product

described in the “Material Safety Data Sheet”. The user’s attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16 Other information

Uses ::

- Recommended use : Manufacturer of articles by injection and extrusion.

- Prohibited use : For special application e.g. in medicine, surgery, or the food industry, obtain further information form the manufacturer. Registration numbers : The polymers are not listed in the EINECS inventory.

All the other constituents of this preparation are registered in the EINECS inventory.

S A F E T Y

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This safety data sheet should be used in conjunction with technical sheets. It does not replace them. The Information given is based on our knowledge of this product, at the time of publication. It is given in good faith. The attention of the user is drawn to the possible risks incurred by using the product for any other purpose other than that for which it was intended. This does not in any way excuse the user from knowing and applying all the regulations governing his Activity. It is the sole responsibility of the user to take all precautions required in handling the products. The aim of the mandatory regulations mentioned is to help the user to fulfill his obligations regarding the use of hazardous products. This information is not exhaustive. This does not exonerate the user from ensuring that regal obligations, other than those mentioned, relating to the use and storage of the products, do not exist. This is solely his responsibility.

제정일자Esta. Date 1993. 01. 12 H O U S I N G Q C 공 정 도

Product＆process Chart (HOUSING)= = = = = = = = = = = = = = = = = = = = = = = = = = = = =

작성일자 : 1995. 10. 26 작성부서 : 품질관리실 작 성 자 : 이 재 학D A T E : 1995. 10. 26 D E P T .: Quality Control Written By : MR.J H LEE

결재

APR'D

작 성WRIT'N

검 토CHK'D

승 인APR'D

개정일자Rev. Date 1995. 10. 26

L.J.H A.J.I시행일자Effect.Date 1995. 10. 26

문서번호File. NO Q - M - 001

NO공정명ProcessName

흐름도사용설비/장비Equipment

공 정 관 리 (Mgt Of Process) 검 사 관 리 (Mgt Of Inspection)관련표준Standardize부공정

Sub Process주공정

Main Process항 목I T E M

관리기준Mgt.Rule

검사항목ITEM

검사방식Method

판정기준Judgement

01

02

03

04

05

06

07

원자재 입고IncomingMaterial

수입 검사IncomingInspection

사출 성형Injection

공정 검사Process Test

포 장Package

출하 검사OutgoingTest

보 관Storage

사 출 기Ejector

저울,Sealing기Digital ScalePacker

V/C,공구현미경V/C,TOOL M/S

형체력(Shape)Dry Hopper온도(Dry Hopper Temp)OIL 온도(OIL Temp)OIL량(Quantity of Oil)AIR 공급량(Air Pressure)

수량(Quantity)포장상태(State of Package)

작업표준Std Of Work

포장관리규칙PackageRegalation

겉모양(Shape)물성(Certificateof Propertied)

겉모양(Shape)

겉모양(Shape)치수(Dimension)형합성(Matching)

체크검사Check

체크검사Check

체크검사(Check)계수조정형샘플링MIL-STD-105D


수입검사 규격Std Of IncomingInspection

공정 검사 규격Std Of Process

Test

출하검사 규격Std Of Outgoing

Test

YSI-101-003

YSI-091-004

YSI-102-001

YSP-152

YSI-102-100

제정일자Esta. Date 1993. 01. 12 W A F E R Q C 공 정 도

Product＆process Chart (WAFER)= = = = = = = = = = = = = = = = = = = = = = = = = = = = =


결재

APR'D

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문서번호File. NO Q - M - 002







검사항목ITEM

검사방식Method


01

02

03

04

05

06

07



사출 성형Injection


포 장Package


보 관Storage

사 출 기Ejector



형체력(Shape)Dry Hopper온도(Dry Hopper Temp)OIL 온도(OIL Temp)OIL량(Quantity of Oil)AIR 공급량(Air Pressure)




겉모양(Shape)물성(Certificateof Propertied)

겉모양(Shape)


체크검사Check

체크검사Check





Test


Test

YSI-101-003

YSI-091-004

YSI-102-001

YSP-152

YSI-102-100

제정일자Esta. Date 1993. 01. 12 T E R M I N A L Q C 공 정 도

Product＆process Chart (TERMINAL)= = = = = = = = = = = = = = = = = = = = = = = = = = = = =


결재

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문서번호File. NO Q - P - 001







검사항목ITEM

검사방식Method


01

02

03

04

05

06

07



PRESS타발Press


포 장Package


보 관Storage

사 출 기Ejector



유압 OIL량(Oil Pressure)AIR 공급량(Air Pressure)원재료 및 간지 풀림(Winding)수량 CHECK SENSOR(Counter Sensor)금형 이상 유무(State of press Tool)타발유 도포(Oil Injection)OIL 냉각장치(Oil Cooler)




겉모양(Shape)치수(Dimension)도금두께(Coating Thickness)물성(Certificatesof Propertied)납땜성(Solderability)



체크검사Check





Test


Test

YSI-101-003

YSI-091-004

YSI-102-001

YSP-152

YSI-102-100

제정일자Esta. Date 1993. 01. 12 P I N Q C 공 정 도

Product＆process Chart (PIN)= = = = = = = = = = = = = = = = = = = = = = = = =


결재

APR'D

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검사항목ITEM

검사방식Method


01

02

03

04

05

06

07



PIN 타발Pin Cutting


포 장Package

보 관Storage

외주도금Plating Vendor

사 출 기Ejector

저울Digital Scale

V/C,납땜조V/C,Solder Port

원재료 풀림상태(MATERIAL WINDING)CAM고정상태(STATE OF CAM)PUNCH고정상태(STATE OF PUNCH)FEEDING 동작상태(FEEDING)CHIP가루발생(CHIP OCCURANCE)BEARING 및 GEAR 동작상태(BEARING, & GEAR)




겉모양(Shape)치수(Dimension)물성(Certificatesof Propertied)

겉모양(Shape)치수(Dimension)

겉모양(Shape)치수(Dimension)납땜성(Solderability)

체크검사Check





Test

수입검사 규격Std Of Incoming

Test

YSI-101-003

YSI-091-004

YSI-102-001

YSP-152

YSI-102-100

YSI-101-003

제정일자Esta. Date 1993. 01. 12 T E R M I N A L A S S ' Y Q C 공 정 도

Product＆process Chart (Terminal Ass'y)= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =


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문서번호File. NO Q - A - 002







검사항목ITEM

검사방식Method


01

02

03

04

05

06

도금핀 입고WAFER 입고Incoming PlatedPin & WAFER

조 립Ass'y

공정 검사ProcessTest

포 장Package

보 관Storage

출하검사OutgoingTest

조립기(ASS'Y M/C)

공구현미경,V/C(Tool M/C),V/CPush Pull Gage통전기(Short Checker)

저울(DigitalScale)

Sealing기(Packer)

납땜조(Solder Port)P.P.Gage, V/CmΩ/ meter내전압 시험기(Puncture Tester)

Terminal 이송(Terminal Feeding)Housing 이송(Housing Feeding)Terminal Detector동작상태(Terminal Detector Function)Terminal휨(Terminal Camber)SENSOR 동작(Sensor function)PIN DETECTOR 동작상태(Pin Detector Function)


작업표준STD OF WORK


겉모양(Shape)치수(Dimension)납땜성(Solderability)PIN유지력(Pin retention)

겉모양(Shape)치수(Dimension)형합성(Matching)납땜성(Solderability)PIN 유지력(Pin retention)

전수검사(Test of TotalCheck)체크검사(CHECK)

체크검사(CHECK)계수조정형샘플링MIL-STD-105D


Test


Test

YSI-091-006

YSI-102-003

YSP-152

YSI-102-100

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