FIITJEE...JEE-MAIN-2020 (8th Jan-Second Shift)-PCM-4 FIITJEE Ltd., FIITJEE House, 29 -A, Kalu Sarai,...

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FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com. FIITJEE Solutions to JEE(Main)-2020 PHYSICS, CHEMISTRY & MATHEMATICS Time Allotted: 3 Hours Maximum Marks: 300 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose. Important Instructions : 1. The test is of 3 hours duration. 2. This Test Paper consists of 75 questions. The maximum marks are 300. 3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics having 25 questions in each part of equal weightage out of which 20 questions are MCQs and 5 questions are numerical value based. Each question is allotted 4 (four) marks for correct response. 4. (Q. No. 01 – 20, 26 – 45, 51 – 70) contains 60 multiple choice questions which have only one correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong answer. 5. (Q. No. 21 – 25, 46 – 50, 71 – 75) contains 15 Numerical based questions with answer as numerical value. Each question carries +4 marks for correct answer. There is no negative marking. 6. Candidates will be awarded marks as stated above in instruction No.3 for correct response of each question. One mark will be deducted for indicating incorrect response of each question. No deduction from the total score will be made if no response is indicated for an item in the answer box. 7. There is only one correct response for each question. Marked up more than one response in any question will be treated as wrong response and marked up for wrong response will be deducted accordingly as per instruction 6 above. Paper - 1 Test Date: 8 th January 2020 (Second Shift)

Transcript of FIITJEE...JEE-MAIN-2020 (8th Jan-Second Shift)-PCM-4 FIITJEE Ltd., FIITJEE House, 29 -A, Kalu Sarai,...

Page 1: FIITJEE...JEE-MAIN-2020 (8th Jan-Second Shift)-PCM-4 FIITJEE Ltd., FIITJEE House, 29 -A, Kalu Sarai, Sarvapriya Vihar, New Delhi 110016, Ph 46106000, 26569493, Fax 26513942website:

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com.

FIITJEE Solutions to JEE(Main)-2020

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours

Maximum Marks: 300

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

Important Instructions:

1. The test is of 3 hours duration. 2. This Test Paper consists of 75 questions. The maximum marks are 300. 3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics

having 25 questions in each part of equal weightage out of which 20 questions are MCQs and 5 questions are numerical value based. Each question is allotted 4 (four) marks for correct response.

4. (Q. No. 01 – 20, 26 – 45, 51 – 70) contains 60 multiple choice questions which have only one correct

answer. Each question carries +4 marks for correct answer and –1 mark for wrong answer. 5. (Q. No. 21 – 25, 46 – 50, 71 – 75) contains 15 Numerical based questions with answer as numerical

value. Each question carries +4 marks for correct answer. There is no negative marking. 6. Candidates will be awarded marks as stated above in instruction No.3 for correct response of each

question. One mark will be deducted for indicating incorrect response of each question. No deduction from the total score will be made if no response is indicated for an item in the answer box.

7. There is only one correct response for each question. Marked up more than one response in any

question will be treated as wrong response and marked up for wrong response will be deducted accordingly as per instruction 6 above.

Paper - 1

Test Date: 8th January 2020 (Second Shift)

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PART – A (PHYSICS) 1. A simple pendulum is being used to determine the vale of gravitational acceleration g at

a certain place. The length of the pendulum is 25.0 cm and a stop watch with 1 s resolution measures the time taken for 40 oscillations to be 50 s. The accuracy in g is:

(A) 4.40% (B) 2.40% (C) 3.40% (D) 5.40%

2. A Carnot engine having an efficiency of 110

is being used as a refrigerator. If the work

done on the refrigerator is 10 J, the amount of heat absorbed from the reservoir at lower temperature is:

(A) 99 J (B) 100 J (C) 1 J (D) 90 J 3. Consider two charged metallic spheres S1 and S2 of radii R1 and R2, respectively. The

electric fields E1 (on S1) and E2 (on S2) on their surfaces are such that E1/E2 = R1/R2. Then the ratio of V1 (on S1) / V2 (on S2) of the electrostatic potentials on each sphere is:

(A) (R1/R2)2 (B) 3

1

2

RR

(C) (R2/R1) (D) R1/R2 4. As shown in the figure, a battery of emf is

connected to an inductor L and resistance R in series. The switch is closed at t = 0. The total charge that flows from the battery, between t = 0 and t = tc (tc is the time constant of the circuit) is

(A) 2

LeR (B) 2

L 11eR

(C) 2R

eL (D) 2

LR

5. A very long wire ABADMNDC is shown in figure carrying

current I. AB and BC parts are straight, long and at right angle. At D wire forms a circular turn DMND of radius R. AB, BC parts are tangential to circular turn at N and D. Magnetic field at the centre of circle is:

(A) 0I2R (B) 0I 1

2 R 2

(C) 0I ( 1)2 R

(D) 0I 12 R 2

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6. A uniform sphere of mass 500 g rolls without slipping on a plane horizontal surface with its centre moving at a speed of 5.00 cm/s. Its kinetic energy is:

(A) 8.75 × 10–4 J (B) 8.75 × 10–3 J (C) 6.25 × 10–4 J (D) 1.13 × 10–3 J 7. In a double-slit experiment, at a certain point on the screen the path difference between

the two interfering waves is 1 th8

of a wavelength. The ratio of the intensity of light at that

point to that at the centre of a bright fringe is: (A) 0.672 (B) 0.568 (C) 0.760 (D) 0.853 8. A particle of mass m is dropped from a height h above the ground. At the same time

another particle of same mass is thrown vertically upwards from the ground with a speed of 2gh. If they collide head-on completely inelastically, the time taken for the combined mass to

reach the ground, in units of hg

is:

(A) 12

(B) 12

(C) 34

(D) 32

9. A particle moves such that its position vector ˆ ˆr (t) cos i sin tj

where is a constant

and t is time. Then which of the following statements is true for the velocity v(t) and

acceleration a (t)

of the particle: (A) v

is perpendicular to r

and a

is directed towards the origin.

(B) v

and a

both are parallel to r

(C) v

is perpendicular to r

and a

is directed away from the origin.

(D) v

and a

both are perpendicular to r

10. Consider a mixture of n moles of helium gas and 2n moles of oxygen gas (molecules

taken to be rigid) as an ideal gas. It CP/CV value will be (A) 19/13 (B) 40/27 (C) 67/45 (D) 23/15 11. A capacitor is made of two square plats

each of side ‘a’ making a very small angle a between them, as shown in figure. The capacitance will be close to:

(A) 2

0 a a1d d

(B) 2

0 a a1d 4d

(C) 2

0 a 3 a1d 2d

(D) 2

0 a a1d 2d

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12. Two liquids of densities 1 and 2(2 = 21) are filled up behind a square wall of inside 10 m as shown in figure. Each liquid has a height of 5 m. The ratio of the forces due to these liquids exerted on upper part MN to that at the lower part NO is (Assume that the liquids are not mixing):

(A) 1/2 (B) 1/4 (C) 2/3 (D) 1/3

13. A plane electromagnetic wave of frequency 25 GHz is propagating in vacuum along the

z-direction. At a particular point in space and time, the magnetic field is given by 8 ˆB 5 10 j T.

The corresponding electric field E

is (speed of light c = 3 × 108 ms–1)

(A) –1.66 × 10–16 i V / m (B) –15 i V / m (C) 15 i V / m (D) 1.66 × 10–16 i V / m 14. An electron (mass m) with initial velocity 0 0

ˆ ˆv v i v j is in an electric field 0

ˆE E k.

If 0 is initial de-Broglie wavelength of electron, its de-Broglie wavelength at time t is given by

(A) 02 2 2

02 2

0

e E t1m v

(B) 02 2 2

2 20

e E t2m v

(C) 02 2 2

2 20

2e E t1m v

(D) 02 2 2

2 20

e E t12m v

15. A transverse wave travels on a taut steel wire wit a velocity of v when tension in it is

2.06 × 104 N. When the tension is changed to T, the velocity changed to v/2. The value of T is close to:

(A) 10.2 × 102 N (B) 30.5 × 104 N (C) 5.15 × 103 N (D) 2.50 × 104 N 16. An object is gradually moving away from the focal point of a concave mirror along the

axis of the mirror. The graphical representation of the magnitude of linear magnification (m) versus distance of the object from the mirror (x) is correctly given by (Graphs are drawn schematically and are not to scale)

(A)

(B)

(C)

(D)

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17. A particle of mass m and charge q is released from rest in a uniform electric field. If there is no other force on the particle, the dependence of its speed v on the distance x travelled by it is correctly given by (graphs are schematic and not drawn to scale)

(A)

(B)

(C)

(D)

18. As shown in figure when a spherical cavity (centered

at O) of radius 1 is cut out of a uniform sphere of radius R (centred at C), the centre of mass of remaining (shaded) part of sphere is at G, i.e. on the surface of the cavity. R can be determined by the equation:

(A) (R2 + R + 1) (2 – R) = 1 (B) (R2 + R – 1) (2 – R) = 1 (C) (R2 – R + 1) (2 – R) = 1 (D) (R2 – R – 1) (2 – R) = 1 19. In the given circuit, value of Y is (A) 0 (B) 1 (C) toggles between 0 and 1 (D) will not execute

20. A galvanometer having a coil resistance 100 gives a full scale deflection when a

current of 1 mA is passed through it. What is the value of the resistance which can convert this galvanometer into a voltmeter giving full scale deflection for a potential difference of 10 V.

(A) 9.9 k (B) 7.9 k (C) 10 k (D) 8.9 k

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21. A ball is dropped form the top of a 100 m high tower on a planet. In the last 1 s2

before

hitting the ground, it covers a distance of 19 m. Acceleration due to gravity (in ms–2) near the surface on that planet is _________.

22. The first member of the Balmer series of hydrogen atom has a wavelength of 6561 Å.

The wavelength of the second member of the Balmer series (in nm) is _________. 23. The series combination of two batteries, both of the same emf 10 V, but different internal

resistance of 20 and 5 , is connected to the parallel combination of two resistors 30 and R . The voltage difference across the battery of internal resistance 20 is zero, the value of R (in ) is _________.

24. An asteroid is moving directly towards the centre of the earth. When at a distance of 10

R (R is the radius of the earth) from he earths centre, it has a speed of 12 km/s. Neglecting the effect of earths atmosphere, what will be the speed of the asteroid when it hits the surface of the earth (escape velocity form the earth is 11.2 km/s)? Given your answer to the nearest integer in kilometer/s _________.

25. Three containers C1, C2 and C3 have water at different temperatures. The table below

shows the final temperature T when different amounts of water (given in liters) are taken from each container and mixed (assume no loss of heat during the process)

C1 C2 C3 T

1 2 __ 60°C

__ 1 2 30°C

2 __ 1 60°C

1 1 1

The value of (in °C to the nearest integer) is _________.

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PART –B (CHEMISTRY) 26. The increasing order of the atomic radii of the following elements is: (a) C (b) O (c) F (d) Cl (e) Br (A) (a) < (b) < (c) < (d) < (e) (B) (d) < (c) < (b) < (a) < (e) (C) (c) < (b) < (a) < (d) < (e) (D) (b) < (c) < (d) < (a) < (e)

27. Kjeldahl's method cannot be used to estimate nitrogen for which of the following

compounds?

(A) (B) C6H5NH2 (C) C6H5NO2 (D) CH3CH2 – C N

28. Consider the following plots of rate constant versus 1T

for four different reactions. Which

of the following order is correct for the activation energies of these reactions?

(A) Ec > Ea > Ed > Eb (B) Eb > Ed > Ec > Ea (C) Ea > Ec > Ed > Eb (D) Eb > Ea > Ed > Ec 29. For the following Assertion and Reason, the correct option is :

Assertion : The pH of water increase with increase in temperature. Reason : The dissociation of water into H+ and OH– is an exothermic reaction (A) assertion is not true, but reason is true (B) both assertion and reason are false (C) but the reason is not the correct explanation for the assertion (D) both assertion and reason are true, and the reason is the correct explanation for the

assertion 30. White phosphorus on reaction with concentrated NaOH solution in an inert atmosphere

of CO2 gives phosphine and compound (X). (X) on acidification with HCl gives compound (Y). The basicity of compound (Y) is :

(A) 2 (B) 4 (C) 3 (D) 1

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31. The major product [B] in the following sequence is :

32. Among (a) – (d), the complexes that can display geometrical isomerism are: (a) [Pt(NH3)3]Cl+ (b) [Pt(NH3)Cl5]–

(c) [Pt(NH3)2Cl(NO2)] (d) [Pt(NH3)4ClBr]2+ (A) (d) and (a) (B) (c) and (d) (C) (b) and (c) (D) (a) and (b) 33. For the following Assertion and Reason, the correct option is : Assertion: For hydrogenation reactions, the catalytic activity increases from Group 5 to

Group 11 metals with maximum activity shown by Group 7-9 elements. Reason : The reactants are most strongly adsorbed on group 7-9 elements. Both

assertion and reason are true and the reason is the correct

(A) Assertion is not true, but reason is true (B) Both assertion and reason are false (C) but the reason is not the correct explanation for the assertion (D) Both assertion and reason are true, and the reason is the correct explanation for the

assertion

34. The major product in the following reaction is

(A)

(B)

(C)

(D)

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35. Among the reactions (a)-(d), the reaction(s) that does/do not occur in the blast furnace during the extraction of iron is/are:

(a) 2 3CaO SiO CaSiO (b) 2 3 3 4 23Fe O CO 2Fe O CO

(c) 2 3FeO SiO FeSiO (d) 21FeO Fe O2

(A) (c) and (d) (B) (a) (C) (a) and (d) (D) (d) 36. A metal (A) on heating in nitrogen gas gives compound B. B on treatment with H2O gives

a colourless gas which when passed through CuSO4 solution gives a dark blue-violet coloured solution. A and B respectively, are:

(A) Mg and Mg(NO3)2 (B) Na and NaNO3 (C) Mg and Mg3N2 (D) Na and Na3N 37. Two monomers in maltose are: (A) -D-glucose and -D-galactose (B) -D-glucose and -D-glucose (C) -D-glucose and -D-glucose (D) -D-glucose and -D-Fructose 38. The correct order of the calculated spin-only magnetic moments of complexes (A) to (D)

is : (a) Ni(CO)4 (b) [Ni(H2O)6]Cl2 (c) Na2[Ni(CN)4] (d) PdCl2(PPh3)2 (A) (c) (d) < (b) < (a) (B) (a) (c) < (b) (d) (C) (a) (c) (d) < (b) (D) (c) < (d) < (b) < (a) 39. An unsaturated hydrocarbon X absorbs two hydrogen molecules on catalytic

hydrogenation, and also gives following reaction:

(A)

O

(B)

(C)

(D)

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40. Hydrogen has three isotopes (a), (b) and (c). If the number of neutron(s) in (a), (b) and (c) respectively, are (x), (y) and (z), the sum of (x), (y) and (z) is:

(A) 4 (B) 3 (C) 2 (D) 1 41. Which of the following compound is likely to show both Frenkel and Schottky defects in

its crystalline form? (A) CsCl (B) AgBr (C) ZnS (D) KBr 42. Arrange the following bonds according to their average bond energies in descending

order: C–Cl, C–Br, C–F, C–I (A) C–F > C–Cl > C–Br > C–I (B) C–I > C–Br > C–Cl > C–F (C) C–Cl > C–Br > C–I > C–F (D) C–Br > C–I > C–Cl > C–F 43. Preparation of Bakelite proceeds via reactions: (A) Electrophilic substitution and dehydration (B) Condensation and elimination (C) Electrophilic addition and dehydration (D) Nucleophilic addition and dehydration 44. The radius of the second Bohr orbit, in terms of the Bohr radius, a0, in Li2+ is

(A) 04a3

(B) 02a9

(C) 02a3

(D) 04a9

45. Among the compounds A and B with molecular formula C9H18O3, A is having higher

boiling point the B. The possible structures of A and B are:

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46. Complexes (ML5) of metals Ni and Fe have ideal square pyramidal and trigonal bipyramidal geometries, respectively. The sum of the 90°, 120° and 180° L-M-L angles in the two complexes is _______

47. At constant volume, 4 mol of an ideal gas when heated from 300 K to 500 K changes its internal energy by 5000 J. The molar heat capacity at constant volume is ____

48. In the following sequence of reactions the maximum number of atoms present in molecule 'C' in one plane is

49.

50. NaClO3 is used, even in spacecraft, to produce O2. The daily consumption of pure O2 by

a person is 492L at 1 atm, 300 K. How much amount of NaClO3, in grams, is required to produce O2 for the daily consumption of a person at 1 atm, 300 K? .

NaClO3(s) + Fe(s) O2(g) + NaCl(s) + FeO(s) R = 0.082 L atm mol–1 K–1

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PART–C (MATHEMATICS)

51. If the 10th term of an A.P. is 120

and its 20th term is 1 ,10

then the sum of its first 200

terms is:

(A) 100 (B) 1504

(C) 11002

(D) 50

52. Which of the following statement is a tautology? (A) ~ p ~ q p q (B) ~ p ~ q p q

(C) p ~ q p q (D) ~ p ~ q p q 53. The mean and variance of 20 observations are found to be 10 and 4, respectively. On

rechecking, it was found that an observation 9 was incorrect and the correct observation was 11. Then the correct variance is:

(A) 4.02 (B) 3.98 (C) 4.01 (D) 3.99

54. The mirror image of the point (1, 2, 3) in a plane is 7 4 1, ,3 3 3

. Which of the

following points lies on this plane? (A) (1, –1, 1) (B) (1, 1, 1) (C) (–1, –1, –1) (D) (–1, –1, 1)

55. If a hyperbola passes through the point P (10, 16) and it has vertices at 6, 0 then the equation of the normal to it at P is:

(A) 2x 5y 100 (B) x 3y 58 (C) 3x 4y 94 (D) x 2y 42

56. If a line, y mx c is a tangent to the circle, 2 2x 3 y 1 and it is perpendicular to

a line 1L , where 1L is the tangent to the circle, 2 2x y 1 at the point 1 1,2 2

; then:

(A) 2c 7c 6 0 (B) 2c 6c 7 0 (C) 2c 6c 7 0 (D) 2c 7c 6 0 57. The area (in sq. units) of the region 2x,y R y 3 2x , is

(A) 323

(B) 293

(C) 313

(D) 343

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58. Let S be the set of all functions : 0,1 R, which are continuous on 0,1 and

differentiable on (0, 1). Then for every in S, there exists ac 0,1 , depending on f, such that:

(A) f c f 1 1 c f ' c (B) f c f 1 1 c f ' c

(C) f c f 1 f ' c (D) f 1 f c

f ' c1 c

59. Let ˆ ˆ ˆa i 2 j k

and ˆ ˆ ˆb i j k

be two vectors. If c

is a vector such that b c b a

and c.a 0,

then c.b

is equal to:

(A) 12

(B) 32

(C) –1 (D) 12

60. Let f : 1,3 R be a function defined by 2

x xf x ,

1 x

where [x] denotes the greatest

integer x . Then the range of f is:

(A) 2 4,5 5

(B) 2 1 3 4, ,5 2 5 5

(C) 3 4,5 5

(D) 2 3 3 4, ,5 5 4 5

61. Let 1 i 32

. If

1002k

k 0a 1

and

1003k

k 0b ,

then a and b are the roots of

the quadratic equation: (A) 2x 101x 100 0 (B) 2x 102x 101 0 (C) 2x 102x 101 0 (D) 2x 101x 100 0

62. x

0x 0

t sin 10 t dtlim

x

is equal to:

(A) 0 (B) 110

(C) 15

(D) 110

63. The system of linear equations x 2y 2z 5 2 x 3y 5z 8 4x y 6z 10 has: (A) no solution when 8 (B) infinitely many solutions when 2 (C) no solution when 2 (D) a unique solution when 8

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64. If and be the coefficients of 4x and 2x respectively in the expansion of

6 62x x 1 x x 1 , then:

(A) 30 (B) 60 (C) 132 (D) 60 65. The differential equation of the family of curves, 2x 4b y b ,b R , is:

(A) xy" y ' (B) 2x y ' x 2yy '

(C) 2x y ' x 2yy ' (D) 2x y ' 2yy ' x 66. The length of the perpendicular from the origin, 0n the normal to the curve,

2 2x 2xy 3y 0 at the point (2, 2) is:

(A) 2 2 (B) 4 2 (C) 2 (D) 2

67. If 2 2

A9 4

and 1 0

I ,0 1

then 110A is equal to:

(A) 4I A (B) A 6I (C) A 4I (D) 6I A

68. Let A and B be two events such that the probability that exactly one of them occurs is 25

and the probability that A or B occurs is 1,2

then the probability of both of them occur

together is: (A) 0.01 (B) 0.10 (C) 0.20 (D) 0.02

69. If 2

3 21

dxI2x 9x 12x 4

, then:

(A) 21 1I16 9

(B) 21 1I9 8

(C) 21 1I8 4 (D) 21 1I

6 2

70. Let S be the set of all real roots of the equation, x x x x3 3 1 2 3 1 3 2 . Then

S: (A) contains at least four elements (B) is a singleton (C) is an empty set (D) contains exactly two elements

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71. Let f x be a polynomial of degree 3 such that f 1 10, f 1 6 , f x has a

critical point at x 1 and f ' x has a critical point at x = 1. Then f x has a local minima at x =________

72. Let aline y mx m 0 intersect the parabola, 2y x at a point P, other than the

origin. Let the tangent to it at P meet the x – axis at the point Q. If area OPQ 4 sq. units, then m is equal to ____________.

73. The sum 7

n 1

n n 1 2n 14

is equal to _____________.

74. The number of 4 letter words (with or without meaning) that can be formed from the

eleven letters of the word ‘EXAMINATION’ is ____________________.

75. If 2 sin 1

71 cos2

and 1 cos2 1 ,

2 10

, 0,2

, then tan 2 is equal

to __________.

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JEE (Main) – 2020

ANSWERS

PART –A (PHYSICS)

1. A 2. D 3. A 4. A

5. D 6. A 7. D 8. D

9. A 10. A 11. D 12. B

13. C 14. A 15. C 16. D

17. D 18. B 19. A 20. A

21. 8.00 or 2888.00 22. 486 23. 30

24. 16 25. 50

PART –B (CHEMISTRY)

26. C 27. C 28. A 29. B

30. D 31. D 32. B 33. A

34. A 35. A 36. C 37. C

38. C 39. D 40. B 41. B

42. A 43. A 44. A 45. D

46. 20.00 47. 6.25 48. 13.00 49. 2.15

50. 2130.00

PART–C (MATHEMATICS)

51. C 52. B 53. D 54. B

55. A 56. C 57. A 58. NA

59. A 60. B 61. B 62. A

63. C 64. C 65. C 66. A

67. B 68. B 69. B 70. B

71. 3 72. 0.5 73. 504 74. 2454

75. 1

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HINTS AND SOLUTIONS PART A – PHYSICS

1. A

Sol. T 1 g LT 2 g L

g 2 T L 1 0.12g T L 50 25.0

= 4.4% 2. D Sol. For Carnot engine using as refrigerator

12

2

TW Q 1T

It is given 110

2

1

T1T

2

1

T 9T 10

So, Q2 = 90 J (as W = 10 J) 3. A

Sol. 1 1

2 2

E rE r

2

1 1 1 1 1 1

2 2 2 2 2 2

V E r r r rV E r r r r

4. A

Sol. cT

0

q idt

c

C

T

t /T1

c c c

C 0

et ; T T e T1R RT

21 L L;

R e R R e

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5. D Sol. 0 0 0 0 01 2 3 4

B B B B B

o o o o0 0 0i i isin 90 sin 45 (sin 45 sin 90 )4 R 2R 4 R

= 0 0 0i i i1 11 14 R 2R 4 R2 2

= 0i 1 11 2 14 R 2 2

= 0 0i i 12 24 R 2 R 2

6. A Sol. K.E. of the sphere = Translational K.E + Rotational

K.E.

= 2

22

1 Kmv 12 R

K = Radius of gyration

21 1 5 21

2 2 100 5

435 10 J4

7. D

Sol. 20I I cos

2

2 2

0

2 xI cos cosI 2 8

0

II

= 0.853

8. D

Sol. Time for collision 1ht2gh

After t1

A 1ghV 0 gt2

and B 11V 2gh gt gh 22

at the time f collision i fP P

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A B fmV mV 2mV

fgh 1gh 2 2V2 2

Vf = 0

and height from ground = 21

1 h 3hh gt h2 4 4

So time =

3h3h42

g 2g

9. A Sol. ˆ ˆr cos t i sin tj

dr ˆ ˆv ( sin t i cos tj)dt

2dv ˆ ˆa (cos ti sin tj)dt

2a r

a

is antiparallel to r

v r ( sin t cos t cos t sin t) 0

So, V r

10. A

Sol. 1 2

1 2

1 p 2 pmix

1 v 2 v

n c n cn c n c

5 7n R 2n R2 23 5n R 2n R2 2

5 14 193 10 13

11. D

Sol. 0adxdcd x

a00

ac ln(d x)

= 2

0 0a aa aln 1 1d d 2d

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12. B

Sol. 1

2

F 1F 4

13. C

Sol. E cB

E = B × c = 15 N/c 14. A

Sol. Initially 00

hm 2 v

Velocity as a function of time = 00 0

eEˆ ˆ ˆv i v j tkm

So wavelength 2 2

2 200 2

he Em 2v tm

02 2

202 2

0

e E1 t2m v

15. C Sol. v T

4

1 1

2 2

v T v 2.06 10v T (v / 2) T

42.06 10T N

4

= 0.515 × 104 N

16. D Sol. At focus, magnification is . 17. D

Sol. 2 2qEV xm

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18. B

Sol. 31

4M R3

; 32

4M (1) ( )3

1 1 2 2com

1 2

M X M XXM M

3 3

3 3

4 4R 0 (1) ( ) [R 1]3 3 (2 R)4 4R (1) ( )

3 3

3(R 1) (2 R)(R 1)

(R 1)

2(R 1) 2 R

(R 1) (R R 1)

(R2 + R + 1) (2 – R) = 1 Alternative: Mremaining (2 – R) = Mcavity (1 – R) (R3 – 13) (2 – R) = 13 [R – 1] (R2 + R + 1) (2 – R) = 1 19. A Sol. Y AB A

AB A AB A = 0 + 0 = 0 20. A Sol. Vg = ig Rg = 0.1 V V = 10 V

gg

VR R 1V

= 100 × 99 = 9.9 K 21. 8.00 or 2888.00 Sol. Area of shaded trapezium

=

1g t t12 19

2 2

…(1)

21 gt 1002

…(2)

200tg

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1g 2t 762

2004 1g76

g 2

g = 8 m/s2 22. 486

Sol. 22 21 2

1 1 1RZn n

22 2

1

1 1 1 5RR(1)362 3

22 2

2

1 1 1 3RR(1)162 4

2

1

2027

220 656127

Å = 4860 Å

= 486 nm 23. 30 Sol. V1 = 1 – I, r1 0 = 10 – I × 20 i = 0.5 A V2 = 2 – ir2 = 10 – 0.5 × 5 V2 = 7.5 V

7.5 7.50.530 x

0.5 = 0.25 + 7.5x

7.5 7.50.25 ; x 30x 0.25

24. 16 Sol. KEi + PEi = KEf + PEf

2 20

1 GMm 1 GMmmu mv2 10R 2 R

2 20

2GM 1v u 1R 10

20

9 GMv u5 R

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2

2 9 (11.2)125 2

2144 0.9(11.2) 256.896

= 16.028 km/s 16 25. 50 Sol. 11 + 22 = (1 + 2) 60 1 + 22 = 180 …(1) 0 × 1 + 1 × 2 + 2 × 3 = (1 + 2) 30 2 + 23 = 90 …(2) 2 × 1 + 0 × 2 + 1 × 3 = (2 + 1) 60 21 + 3 = 180 …(3) and 1 + 2 + 3 = (1 + 1 + 1) …(4) from (1) + (2) + (3) 31 + 32 + 33 = 450 1 + 2 + 3 = 150 From (4) equation 150 = 3 = 50°C

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PART –B (CHEMISTRY) 26. C

Sol. Generally in a period L R Atomic radius decreases and in a Group T B Atomic radius increases.

27. C Sol. Kjedahl’s method cannot be used to Test nitrogen in nitro and diazo present in ring

because nitrogen in nitro cannot convert into Ammonium sulphate. 28. A

Sol. EaRTk Ae

EaLog LogA2.303RT

EaSlope2.303RT

Slope c > a > d > b Ec > Ea > Ed > Eb 29. B Sol. kw = [H+][OH–] Tkw For pure water [H+] = [OH–] kw = [H–]2 [H+] = kw on increasing T kw [H+] pH Dissociation of H2O is endothermic 2H O H OH H ve

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30. D Sol.

31. D Sol.

32. B Sol. [Pt(NH3)2Cl(NO2)] & [Pt(NH3)4ClBr]2+ [M A2 BC] type [M A4 BC] type 33. A

Sol. For hydrogenation reaction catalytic activity increase because reactants are more strongly adsorbed on group 7-9 element, So Assertion & Reason both are correct.

34. A Sol.

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35. A Sol.

36. C Sol.

37. C Sol. Maltose on hydrolysis give 2 mole of -D-glucose, because in maltose glucosidic linkage

is present in between C1 & C4 of -D-glucose. 38. C Sol.

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39. D Sol.

40. B Sol.

41. B Sol. AgBr show both Frenkel and Schottky defect. 42. A Sol.

43. A

Sol. Formation of Bakelite follows electrophillic substitution of phenol and formaldehyde followed by dehydration.

44. A Sol.

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45. D Sol. A is having higher boiling point than B. in case of A inter molecular H-bonding is possible

while in case of B. intermolecular H-bonding is not possible hence have lower boiling point.

46. 20.00 Sol.

47. 6.25 Sol. U = ncv T 5000 = 4 Cv(500 - 300) Cv = 6.25 J k–1 mol–1

48. 13.00 Sol.

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49. 2.15 Sol.

50. 2130.00 Sol. Moles of NaCl3 = mole of O2

Mole of O2 = PV 1 492 20 moleRT 0.082 300

Mass of NaClO3 = 20 106.5 = 2130 g

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PART–C (MATHEMATICS) 51. C

Sol. 101T a 9d

20 ………..(i)

201T a 19d

10 …………..(ii)

1 1a ,d200 200

200200 2 199 201 1S 100

2 200 200 2 2

52. B Sol. p q ~ p ~ q p ~ q ~ p ~ q p q ~ p ~ q p q T T F F T F T T T F F T T F T T F T T F F T T T F F T T T F F T 53. D

Sol. ix10

20 ………….(i)

2ix

100 420

…………(ii)

2ix 104 20 2080

Actual mean 200 9 11 20220 20

Variance 22080 81 121 202

20 20

22120 10.1 106 102.01 3.9920

54. B

Sol. d.r of normal to the plane 10 10 10, ,3 3 3

Midpoint of P and Q is 2 1 4, ,3 3 3

equation of plane x y z 1

55. A Sol. Vertex is at 6, 0 a 6

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Let the hyperbola is 2 2

2 2x y 1a b

Putting point P (10, 16) on the hyperbola

2100 256 136 b

2b 144

hyperbola is 2 2x y 1

36 144

equation of normal is 2 2

2 2

1 1

a x b y a bx y

putting we get 2x 5y 100 56. C

Sol. Slope of tangent to 2 2x y 1 at 1 1,2 2

2 2x y 1 1 1,2 2

2 2x y 1 2x 2yy ' 0 2

xy ' 1y

y mx c is a tangent of 2 2x y 1 So y x c

now distance of (3, 0) from y x c is c 3 12

2c 6c 9 2 2c 6c 7 0 57. A Sol. Point of intersection of 2y x and y 2x 3 is obtained by

2x 2x 3 0 x 3,1

So, area 1

2

3

3 2x x dx

2 2 3 31 3 1 33 4 2

2 3

28 3212 83 3

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58. NA Sol. NA 59. A Sol. a b c a b a

a.b c a.a b a.b a

ˆ ˆ ˆ ˆ ˆ ˆ4c 6 i j k 4 i 2 j k

ˆ ˆ ˆ4c 2i 2 j 2k

1 ˆ ˆ ˆc i j k2

1b.c2

60. B

Sol.

2

2

x ; x 1,2x 1f x

2x ; x 2, 3x 1

f x is a decreasing function

2 1 6 4y , ,5 2 10 5

61. B Sol. 3 6,b 1 ....... 101

2 4 198 00a 1 1 ........

1012

2 2

1 1 11 1

1 1

Equation 2x 101 1 x 101 1 0

2x 102x 101 0 62. A Sol. Using L’ Hospital

x 0

x sin 10xlim 0

1

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63. C

Sol. 2 2

D 2 3 54 6

D 8 2 for 2

1

5 2 2D 8 3 5

10 2 6

5 18 10 2 48 50 2 16 30 40 4 28 0 No solution for 2 64. C

Sol. 2 36 6 6 4 2 6 2 2 6 20 2 4 62 C x C x x 1 C x x 1 C x 1

6 6 4 2 4 2 2 4 62 x 15 x x 15x x 2x 1 1 3x 3x x

6 4 22 32x 48x 18x 1

96 and 36 132 65. C

Sol. x2x 4by ' b

2y '

So, differential equation is 2

2 2x xx .yy y

2 2

2 2x x dy dyx .y x 2y xy y dx dx

66. A Sol. 2 2x 2xy 3y 0

2 2x 3xy xy 3y 0 x y x 3y 0 x y 0 x 3y 0 (2, 2) satisfy x y 0 Normal x y 4

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Hence x y 4

Perpendicular distance from origin 0 0 4 2 22

0 0 4 2 22

67. B

Sol. Characteristics equation of matrix ‘A’ is 22 x 20 x 6x 10 0

9 4 x

2A 6A 10I 0 110A A 6I 68. B

Sol. P (exactly one) 25

2P A P B 2P A B5

1P A B2

1P A P B P A B2

1 2 5 4 1P A B2 5 10 10

69. B

Sol. 3 2

1f x2x 9x 12x 4

2

33 2 2

6x 18x 121f ' x2

2x 9x 12x 4

3

3 2 2

6 x 1 x 2

2 2x 9x 12x 4

1 1f 1 , f 23 8

1 1I3 8

70. B Sol. Let x3 t

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t t 1 2 t 1 t 2

t a x3 a 3x log a so singleton set 71. 3 Sol. Let 3 2f x ax bx cx d

1a4

35d4

3b4

9c4

3 2f x a x 3x 9x d

23f ' x x 2x 34

f ' x 0 x 3, 1

local minima exist at x = 3 72. 0.5 Sol. 22ty x t

2Q t ,0

2

2

0 0 11 t t 1 42

t 0 1

3t 8

t 2 t 0

1m2

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73. 504

Sol. 7

3 2

n 1

1 2n 3n n4

21 7.8 7.8.15 7.82 3

4 2 6 2

1 2 49 16 28 15 284

1 1568 420 28 5044

74. 2454 Sol. EXAMINATION 2N, 2A, 2I, E, X, M, T, O

Case I All the different so 84

8!P 8.7.6.5 16804!

Case II 2 same and 2 different so 3 71 2

4!C . C . 3.21.12 7562!

Case III 2 same and 2 same so 32

4!C . 3.6 182!.2!

Total = 1680 + 756 + 18 = 2454 75. 1

Sol. 2 sin 1

72 cos

and 2 sin 1

2 10

1tan7

1sin10

1tan3

1 22. 33 3tan2 1 8 419 9

4 211 3

tan tan2 287 4tan 2 11 3 251 tan tan2 1 .7 4 26