Fact Sheet and Lab Reports for January 2021 PFAS testing ...
Transcript of Fact Sheet and Lab Reports for January 2021 PFAS testing ...
Fact Sheet and Lab Reports for Testing by WON in January 2021 Page 1 of 4 (ver. 03-10-2021)
Fact Sheet and Lab Reports for January 2021 PFAS testing by Waste Options Nantucket
The Town of Nantucket completed the first step of a Town-wide assessment of per- and
polyfluoroalkyl substances (PFAS). This assessment study identified the potential sources from
municipal facilities located island-wide. The effort also assisted with developing the “PFAS
Cycle” on Nantucket. The results are in the Town-wide PFAS Preliminary Assessment and
Planning Approach Report. The report also has key action items to move forward with steps to
develop approaches for controls and reductions of island-wide PFAS sources.
The Town recently began the second step of the Town-wide PFAS assessment by sampling
different media based on the study’s key action items and specific requirements of
Massachusetts Department of Environmental Protection (MassDEP). Currently, the Town with
CDM Smith is developing a Town-wide PFAS sampling and management strategy program to
further protect the Island community’s health, drinking water sources, and natural resources.
The second step of the Town-wide PFAS assessment is to collect samples and update the island-
wide “PFAS Cycle”. In January 2021, the Town’s contractor Waste Options Nantucket (WON)
collected three different sample media (types) for testing: co-compost, reclaimed soils, and
Wastewater Treatment Facility (WWTF) dewatered sludge (residuals). Nantucket Natural
Compost (co-compost) sampling was completed in line with the MassDEP Approval of Suitability
(AOS) permit. The lab reports attached to this Fact Sheet are as follows:
Material Tested Sample ID Sample Date Lab Job ID
Co-compost FC0127 1/27/2021 J69421-1
Reclaimed Soil RS0127 1/27/2021 J69426-1
Dewatered Sludge SC0127 1/27/2021 J69429-1
The PFAS levels in the January 2021 co-compost samples are similar to the PFAS levels in the
October 2020 co-compost samples, with PFAS levels in co-compost below the State of Maine’s
screening levels for Soil Beneficial Use. The single reclaimed soil PFAS sampling results are
below MassDEP reportable concentration for soil (RCS)-1 standards. There are no PFAS
regulatory guidelines and health standards for WWTF dewatered sludge at this time. Because
PFAS are or were used to manufacture common household and commercial products, it is not
uncommon to identify PFAS levels in WWTF dewatered sludge. All sampling results are further
discussed below.
Nantucket Natural Compost (Co-Compost): 2020 and 2021 Quarterly Sampling
MassDEP requires that any entity within Massachusetts that applies biosolids or biosolids-
containing products (like co-compost) to land have a MassDEP AOS permit per the provisions of
310 CMR 32.13.(11).
Fact Sheet and Lab Reports for Testing by WON in January 2021 Page 2 of 4 (ver. 03-10-2021)
Nantucket Natural Compost (co-compost) comes from organic Municipal Solid Waste
(compostable waste) from the residents and businesses of Nantucket. The co-compost also
includes dewatered sludge, which is an output from WWTFs that serve Nantucket.
The Municipal Solid Waste combined with dewatered sludge is processed through our large
industrial drum and then screened and further processed through the compost facility. The
product is then mixed with leaf/yard waste and windrowed outside for six months to finish.
WON is sampling the Nantucket Natural Compost (co-compost) as required by the AOS permit.
PFAS sampling every three months was recently added to the AOS permit requirements.
Sample collection and laboratory analysis is performed to meet MassDEP general PFAS
sampling and laboratory guidelines. MassDEP and U.S. Environmental Protection Agency do not
currently have PFAS standards for dewatered sludge, biosolids (treated sludge) or co-compost.
Since Massachusetts does not currently have PFAS standards that apply to Nantucket Natural
Compost (co-compost), we compared our results to the State of Maine’s screening levels that
apply to co-compost (Soil Beneficial Use) in 2020 and 2021. The levels of PFAS in Nantucket
Natural Compost (co-compost) during both sampling events were below the Maine screening
limits.
The bar chart below shows the Nantucket Natural Compost (co-compost) PFAS sampling results
compared to the Soil Beneficial Use screening levels from the Maine Solid Waste Management
Rules: Beneficial Use of Solid Wastes (2018). The compounds are perfluorooctanoic acid (PFOA),
perfluorooctanesulfonic acid (PFOS), and perflourobutanesulfonic acid (PFBS).
Nantucket Natural Compost (co-compost) PFAS levels are below Maine Soil Beneficial Use
screening levels in October 2020 and January 2021. We will continue to sample PFAS every
three months to comply with the AOS permit.
1.40
0.46
3.50
1.40
0.33
3.50
2.50
5.20
0.0
1.0
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PFOA PFBS PFOS
par
ts p
er
bill
ion
(n
g/g)
PFAS Levels in Nantucket Natural Compost compared to Maine Beneficial Use Screening Levels in nanograms per gram (ng/g)
Nantucket Co-Compost (10-28-2020) Nantucket Co-Compost (01-28-2021)
Maine Soil Beneficial Use Screening Levels
PFBS Maine screening
level is 1,900 ng/g
Fact Sheet and Lab Reports for Testing by WON in January 2021 Page 3 of 4 (ver. 03-10-2021)
Other Sample Media: January 2021 PFAS Assessment Sampling
The Town-wide PFAS Assessment and Planning Approach Report lists sampling for PFAS in
dewatered sludge and reclaimed soil as a key action item to further assess presence of PFAS at
Town facilities. In January 2021, WON collected:
- One sample of reclaimed soil stockpiled from the landfill mining program
- One sample of the dewatered sludge from the WWTF
MassDEP RCS-1 standards are used to assess reclaimed soil PFAS sampling results. There are no
PFAS regulatory guidelines and health standards for WWTF dewatered sludge at this time. The
results of both samples are discussed below.
Reclaimed Soil Stockpiles Sampling Results
Reclaimed soil is the soil that was separated from mined unlined landfill waste when Nantucket
had a landfill “mining” program from early 2000s-2019. This soil has been temporarily
stockpiled at the landfill facility while determining options for reuse. The Town would like to
use reclaimed soil as part of the landfill’s cover system for the lined landfill cells. Sampling the
reclaimed soil is a step towards deciding if the soil can be used for this purpose.
The bar chart below shows the Nantucket reclaimed soil PFAS sampling results compared to the
MassDEP RCS-1 standards. The compounds are PFOA, PFOS, perflourodecanoic acid (PFDA),
perflouroheptanoic acid (PFHpA), perflourohexanesulfonic acid (PFHxS), and perflouronanoic
acid (PFNA).
Nantucket reclaimed soil PFAS levels are below MassDEP RCS-1 soil standards. The Town and its
vendor WON will coordinate with MassDEP to determine next steps regarding additional
sampling and testing.
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0.19 0.190.042 0.041
0.19
2.00
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0.30 0.32
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PFOS PFOA PFDA PFHpA PFHxS PFNA
par
ts p
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bill
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(n
g/g)
PFAS Levels in Nantucket Reclaimed Soil compared to MassDEP RCS-1 Soil Standards in nanograms per gram (ng/g)
Nantucket Reclaimed Soil (01-28-2021) MassDEP RCS-1 Standards
Fact Sheet and Lab Reports for Testing by WON in January 2021 Page 4 of 4 (ver. 03-10-2021)
Wastewater Treatment Facility (WWTF) Dewatered Sludge Sampling Results
Dewatered sludge is an output from the WWTF, also known as residuals. Similar to the landfill
facility, the WWTF does not create or use PFAS-containing chemicals. PFAS levels in dewatered
sludge instead come from Nantucket residents and businesses through:
- Waste collection systems (sewers)
- Private septic systems
- Liquid waste from landfill leachate and private treatment systems
The bar chart below shows the Nantucket WWTF dewatered sludge PFAS sampling results.
There are no PFAS regulatory guidelines and health standards for dewatered sludge (WWTF
residuals) at this time. The compounds are PFOA, PFOS, and PFBS.
Because PFAS are or were used to manufacture common household and commercial products,
it is not uncommon to identify PFAS levels in WWTF dewatered sludge.
Next Steps
The Town is working with CDM Smith to better understand the presence of PFAS in all of its
facilities and operations. This effort is part of the Town-wide PFAS sampling and management
strategy program under development. The program aims to further protect the island’s
community health, drinking water sources, and natural resources.
In consideration of these recent sample results, we will be developing a targeted sampling
program to further assess PFAS presence island-wide. This information will help in identifying
source control and reduction strategies. The Town will provide program details to the
community as it progresses.
The Town will proactively complete key action items from the Town-wide Preliminary
Assessment and Planning Approach Report, including updates to the Town-wide PFAS Cycle.
Please check the Town’s PFAS website for updated information, fact sheets and answers to
frequently asked questions.
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6
0 40 80 120
PFBS
PFOS
PFOA
PFAS Levels in Nantucket Wastewater Treatment Facility Dewatered Sludge in nanograms per gram (ng/g)
PFAS level in parts per billion (ng/g)
ANALYTICAL REPORTEurofins TestAmerica, Sacramento880 Riverside ParkwayWest Sacramento, CA 95605Tel: (916)373-5600
Laboratory Job ID: 320-69421-1Client Project/Site: PFAS, MassDEP
For:Waste Options Nantucket LLC188 Madaket RdNantucket, Massachusetts 02554
Attn: Nathan Widell
Authorized for release by:2/12/2021 2:41:17 PM
Cesar Cortes, Project Manager I(916)[email protected]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements foraccredited parameters, exceptions are noted in this report. This report may not be reproducedexcept in full, and with written approval from the laboratory. For questions please contact theProject Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Waste Options Nantucket LLCProject/Site: PFAS, MassDEP
Laboratory Job ID: 320-69421-1
Page 2 of 19Eurofins TestAmerica, Sacramento
2/12/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
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Definitions/GlossaryJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Qualifiers
LCMSQualifier Description
B Compound was found in the blank and sample.
Qualifier
F1 MS and/or MSD recovery exceeds control limits.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Sacramento
Page 3 of 19 2/12/2021
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Case NarrativeClient: Waste Options Nantucket LLC Job ID: 320-69421-1Project/Site: PFAS, MassDEP
Job ID: 320-69421-1
Laboratory: Eurofins TestAmerica, Sacramento
Narrative
Receipt The samples were received on 1/28/2021 10:30 AM; the samples arrived in good condition, and where required, properly preserved and
on ice. The temperature of the cooler at receipt was 4.4º C.
Method 537 (modified)The matrix spike (MS) recovery for Perfluoroundecanoic acid (PFUnA) was outside control limits, preparation batch 320-459912 and analytical batch 320-460911. Non-homogeneity is suspected because the associated laboratory control sample (LCS) recovery was within
acceptance limits.
The following samples were light yellow in color (after extraction and final volume stage): FCO127 (320-69421-1), FCO127 MS (320-69421-1[MS]), FCO127 MSD (320-69421-1[MSD]) and FCO127 Dup (320-69421-2), preparation batch 320-459912.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Eurofins TestAmerica, SacramentoPage 4 of 19 2/12/2021
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Detection SummaryJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Client Sample ID: FCO127 Lab Sample ID: 320-69421-1
☼Perfluorobutanoic acid (PFBA)
RL
0.29 ng/g
MDL
0.041
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.27 537 (modified)
☼Perfluoropentanoic acid (PFPeA) 0.29 ng/g0.11 Total/NA10.49 537 (modified)
☼Perfluorohexanoic acid (PFHxA) 0.29 ng/g0.062 Total/NA11.1 537 (modified)
☼Perfluoroheptanoic acid (PFHpA) 0.29 ng/g0.043 Total/NA10.34 537 (modified)
☼Perfluorooctanoic acid (PFOA) 0.29 ng/g0.13 Total/NA11.4 537 (modified)
☼Perfluorononanoic acid (PFNA) 0.29 ng/g0.053 Total/NA10.46 537 (modified)
☼Perfluorodecanoic acid (PFDA) 0.29 ng/g0.032 Total/NA11.0 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 0.29 ng/g0.053 Total/NA10.34 F1 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 0.29 ng/g0.099 Total/NA10.42 537 (modified)
☼Perfluorotridecanoic acid (PFTriA) 0.29 ng/g0.075 Total/NA10.089 J 537 (modified)
☼Perfluorobutanesulfonic acid (PFBS) 0.29 ng/g0.037 Total/NA10.33 537 (modified)
☼Perfluorohexanesulfonic acid (PFHxS) 0.29 ng/g0.046 Total/NA10.11 J 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 0.74 ng/g0.29 Total/NA13.5 B 537 (modified)
Client Sample ID: FCO127 Dup Lab Sample ID: 320-69421-2
☼Perfluorobutanoic acid (PFBA)
RL
0.31 ng/g
MDL
0.043
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.23 537 (modified)
☼Perfluoropentanoic acid (PFPeA) 0.31 ng/g0.12 Total/NA10.46 537 (modified)
☼Perfluorohexanoic acid (PFHxA) 0.31 ng/g0.065 Total/NA11.1 537 (modified)
☼Perfluoroheptanoic acid (PFHpA) 0.31 ng/g0.045 Total/NA10.31 537 (modified)
☼Perfluorooctanoic acid (PFOA) 0.31 ng/g0.13 Total/NA11.1 537 (modified)
☼Perfluorononanoic acid (PFNA) 0.31 ng/g0.056 Total/NA10.40 537 (modified)
☼Perfluorodecanoic acid (PFDA) 0.31 ng/g0.034 Total/NA10.70 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 0.31 ng/g0.056 Total/NA10.23 J 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 0.31 ng/g0.10 Total/NA10.28 J 537 (modified)
☼Perfluorobutanesulfonic acid (PFBS) 0.31 ng/g0.039 Total/NA10.32 537 (modified)
☼Perfluorohexanesulfonic acid (PFHxS) 0.31 ng/g0.048 Total/NA10.092 J 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 0.77 ng/g0.31 Total/NA12.8 B 537 (modified)
Eurofins TestAmerica, Sacramento
This Detection Summary does not include radiochemical test results.
Page 5 of 19 2/12/2021
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Client Sample ResultsJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID: 320-69421-1Client Sample ID: FCO127Matrix: SolidDate Collected: 01/27/21 12:00
Percent Solids: 67.3Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) 0.27 J 0.29 0.041 ng/g ☼ 02/08/21 19:58 02/10/21 22:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.29 0.11 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluoropentanoic acid (PFPeA) 0.49
0.29 0.062 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorohexanoic acid (PFHxA) 1.1
0.29 0.043 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluoroheptanoic acid (PFHpA) 0.34
0.29 0.13 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorooctanoic acid (PFOA) 1.4
0.29 0.053 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorononanoic acid (PFNA) 0.46
0.29 0.032 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorodecanoic acid (PFDA) 1.0
0.29 0.053 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluoroundecanoic acid (PFUnA)
0.34 F1
0.29 0.099 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorododecanoic acid (PFDoA)
0.42
0.29 0.075 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorotridecanoic acid (PFTriA) 0.089 J
0.29 0.037 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorobutanesulfonic acid (PFBS)
0.33
0.29 0.029 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND
0.29 0.046 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorohexanesulfonic acid (PFHxS)
0.11 J
0.74 0.29 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorooctanesulfonic acid (PFOS)
3.5 B
0.29 0.029 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorononanesulfonic acid (PFNS) ND
0.29 0.057 ng/g 02/08/21 19:58 02/10/21 22:39 1☼Perfluorodecanesulfonic acid (PFDS) ND
13C4 PFBA 63 25 - 150 02/08/21 19:58 02/10/21 22:39 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 113 02/08/21 19:58 02/10/21 22:39 125 - 150
13C2 PFHxA 95 02/08/21 19:58 02/10/21 22:39 125 - 150
13C4 PFHpA 90 02/08/21 19:58 02/10/21 22:39 125 - 150
13C4 PFOA 92 02/08/21 19:58 02/10/21 22:39 125 - 150
13C5 PFNA 93 02/08/21 19:58 02/10/21 22:39 125 - 150
13C2 PFDA 70 02/08/21 19:58 02/10/21 22:39 125 - 150
13C2 PFUnA 77 02/08/21 19:58 02/10/21 22:39 125 - 150
13C2 PFDoA 58 02/08/21 19:58 02/10/21 22:39 125 - 150
13C2 PFTeDA 37 02/08/21 19:58 02/10/21 22:39 125 - 150
13C3 PFBS 119 02/08/21 19:58 02/10/21 22:39 125 - 150
18O2 PFHxS 91 02/08/21 19:58 02/10/21 22:39 125 - 150
13C4 PFOS 100 02/08/21 19:58 02/10/21 22:39 125 - 150
General ChemistryRL MDL
Percent Moisture 32.7 0.1 0.1 % 01/29/21 16:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 01/29/21 16:28 1Percent Solids 67.3
Lab Sample ID: 320-69421-2Client Sample ID: FCO127 DupMatrix: SolidDate Collected: 01/27/21 12:00
Percent Solids: 60.6Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) 0.23 J 0.31 0.043 ng/g ☼ 02/08/21 19:58 02/10/21 23:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.31 0.12 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluoropentanoic acid (PFPeA) 0.46
0.31 0.065 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorohexanoic acid (PFHxA) 1.1
Eurofins TestAmerica, Sacramento
Page 6 of 19 2/12/2021
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Client Sample ResultsJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID: 320-69421-2Client Sample ID: FCO127 DupMatrix: SolidDate Collected: 01/27/21 12:00
Percent Solids: 60.6Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)RL MDL
Perfluoroheptanoic acid (PFHpA) 0.31 0.31 0.045 ng/g ☼ 02/08/21 19:58 02/10/21 23:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.31 0.13 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorooctanoic acid (PFOA) 1.1
0.31 0.056 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorononanoic acid (PFNA) 0.40
0.31 0.034 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorodecanoic acid (PFDA) 0.70
0.31 0.056 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluoroundecanoic acid (PFUnA)
0.23 J
0.31 0.10 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorododecanoic acid (PFDoA)
0.28 J
0.31 0.079 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorotridecanoic acid (PFTriA) ND
0.31 0.039 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorobutanesulfonic acid (PFBS)
0.32
0.31 0.031 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND
0.31 0.048 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorohexanesulfonic acid (PFHxS)
0.092 J
0.77 0.31 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorooctanesulfonic acid (PFOS)
2.8 B
0.31 0.031 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorononanesulfonic acid (PFNS) ND
0.31 0.060 ng/g 02/08/21 19:58 02/10/21 23:06 1☼Perfluorodecanesulfonic acid (PFDS) ND
13C4 PFBA 55 25 - 150 02/08/21 19:58 02/10/21 23:06 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 98 02/08/21 19:58 02/10/21 23:06 125 - 150
13C2 PFHxA 84 02/08/21 19:58 02/10/21 23:06 125 - 150
13C4 PFHpA 77 02/08/21 19:58 02/10/21 23:06 125 - 150
13C4 PFOA 84 02/08/21 19:58 02/10/21 23:06 125 - 150
13C5 PFNA 82 02/08/21 19:58 02/10/21 23:06 125 - 150
13C2 PFDA 67 02/08/21 19:58 02/10/21 23:06 125 - 150
13C2 PFUnA 68 02/08/21 19:58 02/10/21 23:06 125 - 150
13C2 PFDoA 58 02/08/21 19:58 02/10/21 23:06 125 - 150
13C2 PFTeDA 43 02/08/21 19:58 02/10/21 23:06 125 - 150
13C3 PFBS 103 02/08/21 19:58 02/10/21 23:06 125 - 150
18O2 PFHxS 83 02/08/21 19:58 02/10/21 23:06 125 - 150
13C4 PFOS 83 02/08/21 19:58 02/10/21 23:06 125 - 150
General ChemistryRL MDL
Percent Moisture 39.4 0.1 0.1 % 01/29/21 16:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 01/29/21 16:28 1Percent Solids 60.6
Eurofins TestAmerica, Sacramento
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Isotope Dilution SummaryJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl SubstancesPrep Type: Total/NAMatrix: Solid
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150)
PFBA PFPeA PFHxA C4PFHA PFOA PFNA PFDA PFUnA
63 113 95 90 92 93 70 77320-69421-1
Percent Isotope Dilution Recovery (Acceptance Limits)
FCO127
64 109 92 9689 99 72 74320-69421-1 MS FCO127 MS
56 110 86 8888 90 68 74320-69421-1 MSD FCO127 MSD
55 98 84 8477 82 67 68320-69421-2 FCO127 Dup
60 68 63 7568 69 71 65LCS 320-459912/2-A Lab Control Sample
79 93 91 9890 91 93 92MB 320-459912/1-A Method Blank
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
58 37 119 91 100320-69421-1
Percent Isotope Dilution Recovery (Acceptance Limits)
FCO127
61 40 116 10096320-69421-1 MS FCO127 MS
60 42 112 9492320-69421-1 MSD FCO127 MSD
58 43 103 8383320-69421-2 FCO127 Dup
72 69 64 6667LCS 320-459912/2-A Lab Control Sample
95 95 91 8788MB 320-459912/1-A Method Blank
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA = 13C5 PFPeA
PFHxA = 13C2 PFHxA
C4PFHA = 13C4 PFHpA
PFOA = 13C4 PFOA
PFNA = 13C5 PFNA
PFDA = 13C2 PFDA
PFUnA = 13C2 PFUnA
PFDoA = 13C2 PFDoA
PFTDA = 13C2 PFTeDA
C3PFBS = 13C3 PFBS
PFHxS = 18O2 PFHxS
PFOS = 13C4 PFOS
Eurofins TestAmerica, Sacramento
Page 8 of 19 2/12/2021
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QC Sample ResultsJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 320-459912/1-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
RL MDL
Perfluorobutanoic acid (PFBA) ND 0.20 0.028 ng/g 02/08/21 19:58 02/10/21 22:21 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
ND 0.0770.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoropentanoic acid (PFPeA)
ND 0.0420.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorohexanoic acid (PFHxA)
ND 0.0290.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoroheptanoic acid (PFHpA)
ND 0.0860.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorooctanoic acid (PFOA)
ND 0.0360.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorononanoic acid (PFNA)
ND 0.0220.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorodecanoic acid (PFDA)
ND 0.0360.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoroundecanoic acid (PFUnA)
ND 0.0670.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorododecanoic acid (PFDoA)
ND 0.0510.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorotridecanoic acid (PFTriA)
ND 0.0250.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorobutanesulfonic acid (PFBS)
ND 0.0200.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoropentanesulfonic acid
(PFPeS)
ND 0.0310.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorohexanesulfonic acid (PFHxS)
0.370 J 0.200.50 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorooctanesulfonic acid (PFOS)
ND 0.0200.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorononanesulfonic acid (PFNS)
ND 0.0390.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorodecanesulfonic acid (PFDS)
13C4 PFBA 79 25 - 150 02/10/21 22:21 1
MB MB
Isotope Dilution
02/08/21 19:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
93 02/08/21 19:58 02/10/21 22:21 113C5 PFPeA 25 - 150
91 02/08/21 19:58 02/10/21 22:21 113C2 PFHxA 25 - 150
90 02/08/21 19:58 02/10/21 22:21 113C4 PFHpA 25 - 150
98 02/08/21 19:58 02/10/21 22:21 113C4 PFOA 25 - 150
91 02/08/21 19:58 02/10/21 22:21 113C5 PFNA 25 - 150
93 02/08/21 19:58 02/10/21 22:21 113C2 PFDA 25 - 150
92 02/08/21 19:58 02/10/21 22:21 113C2 PFUnA 25 - 150
95 02/08/21 19:58 02/10/21 22:21 113C2 PFDoA 25 - 150
95 02/08/21 19:58 02/10/21 22:21 113C2 PFTeDA 25 - 150
91 02/08/21 19:58 02/10/21 22:21 113C3 PFBS 25 - 150
88 02/08/21 19:58 02/10/21 22:21 118O2 PFHxS 25 - 150
87 02/08/21 19:58 02/10/21 22:21 113C4 PFOS 25 - 150
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-459912/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorobutanoic acid (PFBA) 2.00 2.14 ng/g 107 76 - 136
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 2.00 1.98 ng/g 99 69 - 129
Perfluorohexanoic acid (PFHxA) 2.00 2.08 ng/g 104 71 - 131
Perfluoroheptanoic acid (PFHpA) 2.00 2.07 ng/g 103 71 - 131
Perfluorooctanoic acid (PFOA) 2.00 1.84 ng/g 92 72 - 132
Perfluorononanoic acid (PFNA) 2.00 2.16 ng/g 108 73 - 133
Perfluorodecanoic acid (PFDA) 2.00 2.12 ng/g 106 72 - 132
Perfluoroundecanoic acid
(PFUnA)
2.00 2.17 ng/g 109 66 - 126
Perfluorododecanoic acid
(PFDoA)
2.00 2.13 ng/g 107 71 - 131
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-459912/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorotridecanoic acid
(PFTriA)
2.00 2.04 ng/g 102 71 - 131
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluorobutanesulfonic acid
(PFBS)
1.77 1.88 ng/g 106 69 - 129
Perfluoropentanesulfonic acid
(PFPeS)
1.88 2.03 ng/g 108 66 - 126
Perfluorohexanesulfonic acid
(PFHxS)
1.82 1.76 ng/g 97 62 - 122
Perfluorooctanesulfonic acid
(PFOS)
1.86 2.15 ng/g 116 68 - 141
Perfluorononanesulfonic acid
(PFNS)
1.92 2.04 ng/g 106 72 - 132
Perfluorodecanesulfonic acid
(PFDS)
1.93 2.09 ng/g 109 71 - 131
13C4 PFBA 25 - 150
Isotope Dilution
60
LCS LCS
Qualifier Limits%Recovery
6813C5 PFPeA 25 - 150
6313C2 PFHxA 25 - 150
6813C4 PFHpA 25 - 150
7513C4 PFOA 25 - 150
6913C5 PFNA 25 - 150
7113C2 PFDA 25 - 150
6513C2 PFUnA 25 - 150
7213C2 PFDoA 25 - 150
6913C2 PFTeDA 25 - 150
6413C3 PFBS 25 - 150
6718O2 PFHxS 25 - 150
6613C4 PFOS 25 - 150
Client Sample ID: FCO127 MSLab Sample ID: 320-69421-1 MSMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorobutanoic acid (PFBA) 0.27 J 2.89 3.30 ng/g 105 76 - 136☼
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 0.49 2.89 3.33 ng/g 98 69 - 129☼
Perfluorohexanoic acid (PFHxA) 1.1 2.89 4.37 ng/g 112 71 - 131☼
Perfluoroheptanoic acid (PFHpA) 0.34 2.89 3.49 ng/g 109 71 - 131☼
Perfluorooctanoic acid (PFOA) 1.4 2.89 4.42 ng/g 104 72 - 132☼
Perfluorononanoic acid (PFNA) 0.46 2.89 3.72 ng/g 112 73 - 133☼
Perfluorodecanoic acid (PFDA) 1.0 2.89 4.34 ng/g 114 72 - 132☼
Perfluoroundecanoic acid
(PFUnA)
0.34 F1 2.89 4.21 F1 ng/g 134 66 - 126☼
Perfluorododecanoic acid
(PFDoA)
0.42 2.89 3.36 ng/g 102 71 - 131☼
Perfluorotridecanoic acid
(PFTriA)
0.089 J 2.89 2.70 ng/g 90 71 - 131☼
Perfluorobutanesulfonic acid
(PFBS)
0.33 2.56 3.39 ng/g 120 69 - 129☼
Perfluoropentanesulfonic acid
(PFPeS)
ND 2.72 2.49 ng/g 92 66 - 126☼
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: FCO127 MSLab Sample ID: 320-69421-1 MSMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorohexanesulfonic acid
(PFHxS)
0.11 J 2.63 2.54 ng/g 92 62 - 122☼
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluorooctanesulfonic acid
(PFOS)
3.5 B 2.69 6.41 ng/g 110 68 - 141☼
Perfluorononanesulfonic acid
(PFNS)
ND 2.78 2.37 ng/g 85 72 - 132☼
Perfluorodecanesulfonic acid
(PFDS)
ND 2.79 2.45 ng/g 88 71 - 131☼
13C4 PFBA 25 - 150
Isotope Dilution
64
MS MS
Qualifier Limits%Recovery
10913C5 PFPeA 25 - 150
9213C2 PFHxA 25 - 150
8913C4 PFHpA 25 - 150
9613C4 PFOA 25 - 150
9913C5 PFNA 25 - 150
7213C2 PFDA 25 - 150
7413C2 PFUnA 25 - 150
6113C2 PFDoA 25 - 150
4013C2 PFTeDA 25 - 150
11613C3 PFBS 25 - 150
9618O2 PFHxS 25 - 150
10013C4 PFOS 25 - 150
Client Sample ID: FCO127 MSDLab Sample ID: 320-69421-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorobutanoic acid (PFBA) 0.27 J 2.89 3.29 ng/g 104 76 - 136 0 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) 0.49 2.89 3.16 ng/g 92 69 - 129 5 30☼
Perfluorohexanoic acid (PFHxA) 1.1 2.89 4.57 ng/g 120 71 - 131 5 30☼
Perfluoroheptanoic acid (PFHpA) 0.34 2.89 3.37 ng/g 105 71 - 131 4 30☼
Perfluorooctanoic acid (PFOA) 1.4 2.89 4.41 ng/g 103 72 - 132 0 30☼
Perfluorononanoic acid (PFNA) 0.46 2.89 3.79 ng/g 115 73 - 133 2 30☼
Perfluorodecanoic acid (PFDA) 1.0 2.89 4.40 ng/g 116 72 - 132 1 30☼
Perfluoroundecanoic acid
(PFUnA)
0.34 F1 2.89 3.91 ng/g 123 66 - 126 7 30☼
Perfluorododecanoic acid
(PFDoA)
0.42 2.89 3.36 ng/g 102 71 - 131 0 30☼
Perfluorotridecanoic acid
(PFTriA)
0.089 J 2.89 2.61 ng/g 87 71 - 131 3 30☼
Perfluorobutanesulfonic acid
(PFBS)
0.33 2.56 3.45 ng/g 122 69 - 129 2 30☼
Perfluoropentanesulfonic acid
(PFPeS)
ND 2.72 2.47 ng/g 91 66 - 126 1 30☼
Perfluorohexanesulfonic acid
(PFHxS)
0.11 J 2.63 2.56 ng/g 93 62 - 122 1 30☼
Perfluorooctanesulfonic acid
(PFOS)
3.5 B 2.69 6.72 ng/g 121 68 - 141 5 30☼
Perfluorononanesulfonic acid
(PFNS)
ND 2.78 2.53 ng/g 91 72 - 132 7 30☼
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: FCO127 MSDLab Sample ID: 320-69421-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorodecanesulfonic acid
(PFDS)
ND 2.79 2.57 ng/g 92 71 - 131 5 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
13C4 PFBA 25 - 150
Isotope Dilution
56
MSD MSD
Qualifier Limits%Recovery
11013C5 PFPeA 25 - 150
8613C2 PFHxA 25 - 150
8813C4 PFHpA 25 - 150
8813C4 PFOA 25 - 150
9013C5 PFNA 25 - 150
6813C2 PFDA 25 - 150
7413C2 PFUnA 25 - 150
6013C2 PFDoA 25 - 150
4213C2 PFTeDA 25 - 150
11213C3 PFBS 25 - 150
9218O2 PFHxS 25 - 150
9413C4 PFOS 25 - 150
Method: D 2216 - Percent Moisture
Client Sample ID: FCO127Lab Sample ID: 320-69421-1 DUMatrix: Solid Prep Type: Total/NAAnalysis Batch: 456913
Percent Moisture 32.7 27.3 % 18 20
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Percent Solids 67.3 72.7 % 8 20
Eurofins TestAmerica, Sacramento
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QC Association SummaryJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
LCMS
Prep Batch: 459912
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid SHAKE320-69421-1 FCO127 Total/NA
Solid SHAKE320-69421-2 FCO127 Dup Total/NA
Solid SHAKEMB 320-459912/1-A Method Blank Total/NA
Solid SHAKELCS 320-459912/2-A Lab Control Sample Total/NA
Solid SHAKE320-69421-1 MS FCO127 MS Total/NA
Solid SHAKE320-69421-1 MSD FCO127 MSD Total/NA
Analysis Batch: 460911
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 537 (modified) 459912320-69421-1 FCO127 Total/NA
Solid 537 (modified) 459912320-69421-2 FCO127 Dup Total/NA
Solid 537 (modified) 459912MB 320-459912/1-A Method Blank Total/NA
Solid 537 (modified) 459912LCS 320-459912/2-A Lab Control Sample Total/NA
Solid 537 (modified) 459912320-69421-1 MS FCO127 MS Total/NA
Solid 537 (modified) 459912320-69421-1 MSD FCO127 MSD Total/NA
General Chemistry
Analysis Batch: 456913
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid D 2216320-69421-1 FCO127 Total/NA
Solid D 2216320-69421-2 FCO127 Dup Total/NA
Solid D 2216320-69421-1 DU FCO127 Total/NA
Eurofins TestAmerica, Sacramento
Page 13 of 19 2/12/2021
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Lab ChronicleClient: Waste Options Nantucket LLC Job ID: 320-69421-1Project/Site: PFAS, MassDEP
Client Sample ID: FCO127 Lab Sample ID: 320-69421-1Matrix: SolidDate Collected: 01/27/21 12:00
Date Received: 01/28/21 10:30
Analysis D 2216 TCS01/29/21 16:281 TAL SAC456913
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: FCO127 Lab Sample ID: 320-69421-1Matrix: SolidDate Collected: 01/27/21 12:00
Percent Solids: 67.3Date Received: 01/28/21 10:30
Prep SHAKE AP02/08/21 19:58 TAL SAC459912
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.05 g 10.00 mL
Analysis 537 (modified) 1 460911 02/10/21 22:39 RS1 TAL SACTotal/NA
Client Sample ID: FCO127 Dup Lab Sample ID: 320-69421-2Matrix: SolidDate Collected: 01/27/21 12:00
Date Received: 01/28/21 10:30
Analysis D 2216 TCS01/29/21 16:281 TAL SAC456913
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: FCO127 Dup Lab Sample ID: 320-69421-2Matrix: SolidDate Collected: 01/27/21 12:00
Percent Solids: 60.6Date Received: 01/28/21 10:30
Prep SHAKE AP02/08/21 19:58 TAL SAC459912
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.32 g 10.00 mL
Analysis 537 (modified) 1 460911 02/10/21 23:06 RS1 TAL SACTotal/NA
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
Page 14 of 19 2/12/2021
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Accreditation/Certification SummaryClient: Waste Options Nantucket LLC Job ID: 320-69421-1Project/Site: PFAS, MassDEP
Laboratory: Eurofins TestAmerica, SacramentoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
Alaska (UST) 17-020State 01-20-21 *
ANAB Dept. of Defense ELAP L2468 01-20-24
ANAB Dept. of Energy L2468.01 01-20-21 *
ANAB ISO/IEC 17025 L2468 01-20-21 *
Arizona State AZ0708 08-11-21
Arkansas DEQ State 88-0691 06-17-21
California State 2897 01-31-22
Colorado State CA0004 08-31-21
Connecticut State PH-0691 06-30-21
Florida NELAP E87570 06-30-21
Georgia State 4040 01-29-22
Hawaii State <cert No.> 01-29-22
Illinois NELAP 200060 03-17-21
Kansas NELAP E-10375 02-01-21 *
Louisiana NELAP 01944 06-30-21
Maine State CA00004 04-14-22
Michigan State 9947 01-29-21 *
Nevada State CA000442021-2 07-31-21
New Hampshire NELAP 2997 04-18-21
New Jersey NELAP CA005 06-30-21
New York NELAP 11666 04-01-21
Ohio State 41252 01-29-22
Oregon NELAP 4040 01-29-21 *
Pennsylvania NELAP 68-01272 03-31-21
Texas NELAP T104704399-19-13 06-01-21
US Fish & Wildlife US Federal Programs 58448 07-31-21
USDA US Federal Programs P330-18-00239 07-31-21
Utah NELAP CA000442019-01 02-28-21
Vermont State VT-4040 04-16-21
Virginia NELAP 460278 03-14-21
Washington State C581 05-05-21
West Virginia (DW) State 9930C 12-31-21
Wisconsin State 998204680 08-31-21
Wyoming State Program 8TMS-L 01-28-19 *
Eurofins TestAmerica, Sacramento
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 15 of 19 2/12/2021
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Method SummaryJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL SAC
ASTMD 2216 Percent Moisture TAL SAC
SW846SHAKE Shake Extraction with Ultrasonic Bath Extraction TAL SAC
Protocol References:
ASTM = ASTM International
EPA = US Environmental Protection Agency
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
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Sample SummaryJob ID: 320-69421-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
320-69421-1 FCO127 Solid 01/27/21 12:00 01/28/21 10:30
320-69421-2 FCO127 Dup Solid 01/27/21 12:00 01/28/21 10:30
Eurofins TestAmerica, Sacramento
Page 17 of 19 2/12/2021
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Login Sample Receipt Checklist
Client: Waste Options Nantucket LLC Job Number: 320-69421-1
Login Number: 69421
Question Answer Comment
Creator: Thompson, Sarah W
List Source: Eurofins TestAmerica, Sacramento
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact. 1462290, 1462291
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins TestAmerica, SacramentoPage 19 of 19 2/12/2021
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ANALYTICAL REPORTEurofins TestAmerica, Sacramento880 Riverside ParkwayWest Sacramento, CA 95605Tel: (916)373-5600
Laboratory Job ID: 320-69426-1Client Project/Site: PFAS, MassDEP
For:Waste Options Nantucket LLC188 Madaket RdNantucket, Massachusetts 02554
Attn: Nathan Widell
Authorized for release by:2/12/2021 4:13:17 PM
Cesar Cortes, Project Manager I(916)[email protected]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements foraccredited parameters, exceptions are noted in this report. This report may not be reproducedexcept in full, and with written approval from the laboratory. For questions please contact theProject Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Waste Options Nantucket LLCProject/Site: PFAS, MassDEP
Laboratory Job ID: 320-69426-1
Page 2 of 25Eurofins TestAmerica, Sacramento
2/12/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
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Definitions/GlossaryJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Qualifiers
LCMSQualifier Description
*5+ Isotope dilution analyte is outside acceptance limits, high biased.
Qualifier
B Compound was found in the blank and sample.
F1 MS and/or MSD recovery exceeds control limits.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
GlossaryThese commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Sacramento
Page 3 of 25 2/12/2021
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Case NarrativeClient: Waste Options Nantucket LLC Job ID: 320-69426-1Project/Site: PFAS, MassDEP
Job ID: 320-69426-1
Laboratory: Eurofins TestAmerica, Sacramento
Narrative
Receipt The samples were received on 1/28/2021 10:30 AM; the samples arrived in good condition, and where required, properly preserved and
on ice. The temperature of the cooler at receipt was 4.4º C.
Method 537 (modified)The matrix spike / matrix spike duplicate (MS/MSD) recoveries for Perfluoropentanesulfonic acid (PFPeS) were outside control limits, preparation batch 320-458457 and analytical batch 320-459298. Sample matrix interference are suspected because the associated
laboratory control sample (LCS) recovery was within acceptance limits.
Several Isotope Dilution Analyte (IDA) recoveries are above the method recommended limit: R0127 (Rinsate) (320-69426-3). Quantitation by isotope dilution generally precludes any adverse effect on data quality due to elevated IDA recoveries.
The following sample yielded less than required volume (250 mL's): R0127 (Rinsate) (320-69426-3). Elevated reporting limits are
provided.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Eurofins TestAmerica, SacramentoPage 4 of 25 2/12/2021
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Detection SummaryJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Client Sample ID: RS0127 Lab Sample ID: 320-69426-1
☼Perfluorobutanoic acid (PFBA)
RL
0.20 ng/g
MDL
0.029
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.077 537 (modified)
☼Perfluorohexanoic acid (PFHxA) 0.20 ng/g0.043 Total/NA10.063 J 537 (modified)
☼Perfluoroheptanoic acid (PFHpA) 0.20 ng/g0.030 Total/NA10.042 J 537 (modified)
☼Perfluorooctanoic acid (PFOA) 0.20 ng/g0.088 Total/NA10.19 J 537 (modified)
☼Perfluorononanoic acid (PFNA) 0.20 ng/g0.037 Total/NA10.19 J 537 (modified)
☼Perfluorodecanoic acid (PFDA) 0.20 ng/g0.022 Total/NA10.19 J 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 0.20 ng/g0.037 Total/NA10.16 J 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 0.20 ng/g0.068 Total/NA10.10 J 537 (modified)
☼Perfluorotridecanoic acid (PFTriA) 0.20 ng/g0.052 Total/NA10.055 J 537 (modified)
☼Perfluorobutanesulfonic acid (PFBS) 0.20 ng/g0.025 Total/NA10.034 J 537 (modified)
☼Perfluorohexanesulfonic acid (PFHxS) 0.20 ng/g0.032 Total/NA10.041 J 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 0.51 ng/g0.20 Total/NA11.3 B 537 (modified)
Client Sample ID: RS0127 Dup Lab Sample ID: 320-69426-2
☼Perfluorononanoic acid (PFNA)
RL
0.24 ng/g
MDL
0.042
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.089 537 (modified)
☼Perfluorodecanoic acid (PFDA) 0.24 ng/g0.026 Total/NA10.18 J 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 0.24 ng/g0.042 Total/NA10.11 J 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 0.24 ng/g0.079 Total/NA10.086 J 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 0.59 ng/g0.24 Total/NA11.0 B 537 (modified)
Client Sample ID: R0127 (Rinsate) Lab Sample ID: 320-69426-3
No Detections.
Eurofins TestAmerica, Sacramento
This Detection Summary does not include radiochemical test results.
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Client Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID: 320-69426-1Client Sample ID: RS0127Matrix: SolidDate Collected: 01/27/21 12:30
Percent Solids: 91.2Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) 0.077 J 0.20 0.029 ng/g ☼ 02/08/21 19:58 02/10/21 23:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.20 0.079 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluoropentanoic acid (PFPeA) ND
0.20 0.043 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorohexanoic acid (PFHxA) 0.063 J
0.20 0.030 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluoroheptanoic acid (PFHpA) 0.042 J
0.20 0.088 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorooctanoic acid (PFOA) 0.19 J
0.20 0.037 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorononanoic acid (PFNA) 0.19 J
0.20 0.022 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorodecanoic acid (PFDA) 0.19 J
0.20 0.037 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluoroundecanoic acid (PFUnA)
0.16 J
0.20 0.068 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorododecanoic acid (PFDoA)
0.10 J
0.20 0.052 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorotridecanoic acid (PFTriA) 0.055 J
0.20 0.025 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorobutanesulfonic acid (PFBS)
0.034 J
0.20 0.020 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND
0.20 0.032 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorohexanesulfonic acid (PFHxS)
0.041 J
0.51 0.20 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorooctanesulfonic acid (PFOS)
1.3 B
0.20 0.020 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorononanesulfonic acid (PFNS) ND
0.20 0.040 ng/g 02/08/21 19:58 02/10/21 23:16 1☼Perfluorodecanesulfonic acid (PFDS) ND
13C4 PFBA 64 25 - 150 02/08/21 19:58 02/10/21 23:16 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 105 02/08/21 19:58 02/10/21 23:16 125 - 150
13C2 PFHxA 92 02/08/21 19:58 02/10/21 23:16 125 - 150
13C4 PFHpA 84 02/08/21 19:58 02/10/21 23:16 125 - 150
13C4 PFOA 90 02/08/21 19:58 02/10/21 23:16 125 - 150
13C5 PFNA 84 02/08/21 19:58 02/10/21 23:16 125 - 150
13C2 PFDA 80 02/08/21 19:58 02/10/21 23:16 125 - 150
13C2 PFUnA 79 02/08/21 19:58 02/10/21 23:16 125 - 150
13C2 PFDoA 74 02/08/21 19:58 02/10/21 23:16 125 - 150
13C2 PFTeDA 73 02/08/21 19:58 02/10/21 23:16 125 - 150
13C3 PFBS 105 02/08/21 19:58 02/10/21 23:16 125 - 150
18O2 PFHxS 85 02/08/21 19:58 02/10/21 23:16 125 - 150
13C4 PFOS 89 02/08/21 19:58 02/10/21 23:16 125 - 150
General ChemistryRL MDL
Percent Moisture 8.8 0.1 0.1 % 01/29/21 16:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 01/29/21 16:28 1Percent Solids 91.2
Lab Sample ID: 320-69426-2Client Sample ID: RS0127 DupMatrix: SolidDate Collected: 01/27/21 12:30
Percent Solids: 81.7Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) ND 0.24 0.033 ng/g ☼ 02/08/21 19:58 02/10/21 23:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.24 0.090 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluoropentanoic acid (PFPeA) ND
0.24 0.049 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorohexanoic acid (PFHxA) ND
Eurofins TestAmerica, Sacramento
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Client Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID: 320-69426-2Client Sample ID: RS0127 DupMatrix: SolidDate Collected: 01/27/21 12:30
Percent Solids: 81.7Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)RL MDL
Perfluoroheptanoic acid (PFHpA) ND 0.24 0.034 ng/g ☼ 02/08/21 19:58 02/10/21 23:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.24 0.10 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorooctanoic acid (PFOA) ND
0.24 0.042 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorononanoic acid (PFNA) 0.089 J
0.24 0.026 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorodecanoic acid (PFDA) 0.18 J
0.24 0.042 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluoroundecanoic acid (PFUnA)
0.11 J
0.24 0.079 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorododecanoic acid (PFDoA)
0.086 J
0.24 0.060 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorotridecanoic acid (PFTriA) ND
0.24 0.029 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorobutanesulfonic acid (PFBS) ND
0.24 0.024 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND
0.24 0.036 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorohexanesulfonic acid (PFHxS) ND
0.59 0.24 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorooctanesulfonic acid (PFOS)
1.0 B
0.24 0.024 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorononanesulfonic acid (PFNS) ND
0.24 0.046 ng/g 02/08/21 19:58 02/10/21 23:43 1☼Perfluorodecanesulfonic acid (PFDS) ND
13C4 PFBA 61 25 - 150 02/08/21 19:58 02/10/21 23:43 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 102 02/08/21 19:58 02/10/21 23:43 125 - 150
13C2 PFHxA 96 02/08/21 19:58 02/10/21 23:43 125 - 150
13C4 PFHpA 84 02/08/21 19:58 02/10/21 23:43 125 - 150
13C4 PFOA 94 02/08/21 19:58 02/10/21 23:43 125 - 150
13C5 PFNA 90 02/08/21 19:58 02/10/21 23:43 125 - 150
13C2 PFDA 83 02/08/21 19:58 02/10/21 23:43 125 - 150
13C2 PFUnA 80 02/08/21 19:58 02/10/21 23:43 125 - 150
13C2 PFDoA 77 02/08/21 19:58 02/10/21 23:43 125 - 150
13C2 PFTeDA 75 02/08/21 19:58 02/10/21 23:43 125 - 150
13C3 PFBS 109 02/08/21 19:58 02/10/21 23:43 125 - 150
18O2 PFHxS 88 02/08/21 19:58 02/10/21 23:43 125 - 150
13C4 PFOS 87 02/08/21 19:58 02/10/21 23:43 125 - 150
General ChemistryRL MDL
Percent Moisture 18.3 0.1 0.1 % 01/29/21 16:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 01/29/21 16:28 1Percent Solids 81.7
Lab Sample ID: 320-69426-3Client Sample ID: R0127 (Rinsate)Matrix: WaterDate Collected: 01/27/21 12:30
Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) ND 6.7 3.2 ng/L 02/03/21 19:00 02/06/21 00:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.7 0.66 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluoropentanoic acid (PFPeA) ND
2.7 0.78 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorohexanoic acid (PFHxA) ND
2.7 0.34 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluoroheptanoic acid (PFHpA) ND
2.7 1.1 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorooctanoic acid (PFOA) ND
2.7 0.36 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorononanoic acid (PFNA) ND
2.7 0.42 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorodecanoic acid (PFDA) ND
2.7 1.5 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluoroundecanoic acid (PFUnA) ND
Eurofins TestAmerica, Sacramento
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Client Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID: 320-69426-3Client Sample ID: R0127 (Rinsate)Matrix: WaterDate Collected: 01/27/21 12:30
Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)RL MDL
Perfluorododecanoic acid (PFDoA) ND 2.7 0.74 ng/L 02/03/21 19:00 02/06/21 00:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2.7 1.8 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorotridecanoic acid (PFTriA) ND
2.7 0.27 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorobutanesulfonic acid (PFBS) ND
2.7 0.77 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorohexanesulfonic acid (PFHxS) ND
2.7 0.43 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorodecanesulfonic acid (PFDS) ND
2.7 0.73 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorooctanesulfonic acid (PFOS) ND
2.7 0.40 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluoropentanesulfonic acid
(PFPeS)
ND
2.7 0.50 ng/L 02/03/21 19:00 02/06/21 00:24 1Perfluorononanesulfonic acid (PFNS) ND
13C4 PFBA 168 *5+ 25 - 150 02/03/21 19:00 02/06/21 00:24 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 168 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
13C2 PFHxA 178 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
13C4 PFHpA 173 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
13C4 PFOA 177 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
13C5 PFNA 168 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
13C2 PFDA 175 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
13C2 PFUnA 152 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
13C2 PFDoA 147 02/03/21 19:00 02/06/21 00:24 125 - 150
13C2 PFTeDA 131 02/03/21 19:00 02/06/21 00:24 125 - 150
13C3 PFBS 143 02/03/21 19:00 02/06/21 00:24 125 - 150
18O2 PFHxS 149 02/03/21 19:00 02/06/21 00:24 125 - 150
13C4 PFOS 153 *5+ 02/03/21 19:00 02/06/21 00:24 125 - 150
Eurofins TestAmerica, Sacramento
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Isotope Dilution SummaryJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl SubstancesPrep Type: Total/NAMatrix: Solid
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150)
PFBA PFPeA PFHxA C4PFHA PFOA PFNA PFDA PFUnA
64 105 92 84 90 84 80 79320-69426-1
Percent Isotope Dilution Recovery (Acceptance Limits)
RS0127
62 100 89 8679 83 78 76320-69426-1 MS RS0127 MS
71 115 105 9785 93 83 83320-69426-1 MSD RS0127 MSD
61 102 96 9484 90 83 80320-69426-2 RS0127 Dup
60 68 63 7568 69 71 65LCS 320-459912/2-A Lab Control Sample
79 93 91 9890 91 93 92MB 320-459912/1-A Method Blank
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
74 73 105 85 89320-69426-1
Percent Isotope Dilution Recovery (Acceptance Limits)
RS0127
74 70 99 8182320-69426-1 MS RS0127 MS
83 80 106 9191320-69426-1 MSD RS0127 MSD
77 75 109 8788320-69426-2 RS0127 Dup
72 69 64 6667LCS 320-459912/2-A Lab Control Sample
95 95 91 8788MB 320-459912/1-A Method Blank
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA = 13C5 PFPeA
PFHxA = 13C2 PFHxA
C4PFHA = 13C4 PFHpA
PFOA = 13C4 PFOA
PFNA = 13C5 PFNA
PFDA = 13C2 PFDA
PFUnA = 13C2 PFUnA
PFDoA = 13C2 PFDoA
PFTDA = 13C2 PFTeDA
C3PFBS = 13C3 PFBS
PFHxS = 18O2 PFHxS
PFOS = 13C4 PFOS
Method: 537 (modified) - Fluorinated Alkyl SubstancesPrep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150)
PFBA PFPeA PFHxA C4PFHA PFOA PFNA PFDA PFUnA
69 47 88 84 96 97 113 101320-69397-A-1-E MS
Percent Isotope Dilution Recovery (Acceptance Limits)
Matrix Spike
77 53 97 10897 105 111 113320-69397-A-1-F MSD Matrix Spike Duplicate
168 *5+ 168 *5+ 178 *5+ 177 *5+173 *5+ 168 *5+ 175 *5+ 152 *5+320-69426-3 R0127 (Rinsate)
103 98 106 114109 111 114 112LCS 320-458457/2-A Lab Control Sample
100 99 105 109107 112 114 110LCSD 320-458457/3-A Lab Control Sample Dup
94 94 100 10499 105 104 99MB 320-458457/1-A Method Blank
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
91 93 67 85 94320-69397-A-1-E MS
Percent Isotope Dilution Recovery (Acceptance Limits)
Matrix Spike
98 94 71 10193320-69397-A-1-F MSD Matrix Spike Duplicate
147 131 143 153 *5+149320-69426-3 R0127 (Rinsate)
102 103 102 103103LCS 320-458457/2-A Lab Control Sample
Eurofins TestAmerica, Sacramento
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Isotope Dilution SummaryJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
111 106 101 97 102LCSD 320-458457/3-A
Percent Isotope Dilution Recovery (Acceptance Limits)
Lab Control Sample Dup
105 94 96 10095MB 320-458457/1-A Method Blank
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA = 13C5 PFPeA
PFHxA = 13C2 PFHxA
C4PFHA = 13C4 PFHpA
PFOA = 13C4 PFOA
PFNA = 13C5 PFNA
PFDA = 13C2 PFDA
PFUnA = 13C2 PFUnA
PFDoA = 13C2 PFDoA
PFTDA = 13C2 PFTeDA
C3PFBS = 13C3 PFBS
PFHxS = 18O2 PFHxS
PFOS = 13C4 PFOS
Eurofins TestAmerica, Sacramento
Page 10 of 25 2/12/2021
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 320-458457/1-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
RL MDL
Perfluorobutanoic acid (PFBA) ND 5.0 2.4 ng/L 02/03/21 18:59 02/05/21 22:03 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
ND 0.492.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluoropentanoic acid (PFPeA)
ND 0.582.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorohexanoic acid (PFHxA)
ND 0.252.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluoroheptanoic acid (PFHpA)
ND 0.852.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorooctanoic acid (PFOA)
ND 0.272.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorononanoic acid (PFNA)
ND 0.312.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorodecanoic acid (PFDA)
ND 1.12.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluoroundecanoic acid (PFUnA)
ND 0.552.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorododecanoic acid (PFDoA)
ND 1.32.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorotridecanoic acid (PFTriA)
ND 0.202.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorobutanesulfonic acid (PFBS)
ND 0.572.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorohexanesulfonic acid (PFHxS)
ND 0.542.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorooctanesulfonic acid (PFOS)
ND 0.322.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorodecanesulfonic acid (PFDS)
ND 0.302.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluoropentanesulfonic acid
(PFPeS)
ND 0.372.0 ng/L 02/03/21 18:59 02/05/21 22:03 1Perfluorononanesulfonic acid (PFNS)
13C4 PFBA 94 25 - 150 02/05/21 22:03 1
MB MB
Isotope Dilution
02/03/21 18:59
Dil FacPrepared AnalyzedQualifier Limits%Recovery
94 02/03/21 18:59 02/05/21 22:03 113C5 PFPeA 25 - 150
100 02/03/21 18:59 02/05/21 22:03 113C2 PFHxA 25 - 150
99 02/03/21 18:59 02/05/21 22:03 113C4 PFHpA 25 - 150
104 02/03/21 18:59 02/05/21 22:03 113C4 PFOA 25 - 150
105 02/03/21 18:59 02/05/21 22:03 113C5 PFNA 25 - 150
104 02/03/21 18:59 02/05/21 22:03 113C2 PFDA 25 - 150
99 02/03/21 18:59 02/05/21 22:03 113C2 PFUnA 25 - 150
105 02/03/21 18:59 02/05/21 22:03 113C2 PFDoA 25 - 150
94 02/03/21 18:59 02/05/21 22:03 113C2 PFTeDA 25 - 150
96 02/03/21 18:59 02/05/21 22:03 113C3 PFBS 25 - 150
95 02/03/21 18:59 02/05/21 22:03 118O2 PFHxS 25 - 150
100 02/03/21 18:59 02/05/21 22:03 113C4 PFOS 25 - 150
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-458457/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
Perfluorobutanoic acid (PFBA) 40.0 40.2 ng/L 101 76 - 136
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 40.0 39.3 ng/L 98 71 - 131
Perfluorohexanoic acid (PFHxA) 40.0 40.4 ng/L 101 73 - 133
Perfluoroheptanoic acid (PFHpA) 40.0 40.2 ng/L 101 72 - 132
Perfluorooctanoic acid (PFOA) 40.0 39.1 ng/L 98 70 - 130
Perfluorononanoic acid (PFNA) 40.0 40.9 ng/L 102 75 - 135
Perfluorodecanoic acid (PFDA) 40.0 43.1 ng/L 108 76 - 136
Perfluoroundecanoic acid
(PFUnA)
40.0 43.9 ng/L 110 68 - 128
Perfluorododecanoic acid
(PFDoA)
40.0 43.0 ng/L 107 71 - 131
Eurofins TestAmerica, Sacramento
Page 11 of 25 2/12/2021
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-458457/2-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
Perfluorotridecanoic acid
(PFTriA)
40.0 40.9 ng/L 102 71 - 131
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluorobutanesulfonic acid
(PFBS)
35.4 36.9 ng/L 104 67 - 127
Perfluorohexanesulfonic acid
(PFHxS)
36.4 35.4 ng/L 97 59 - 119
Perfluorooctanesulfonic acid
(PFOS)
37.1 38.1 ng/L 103 70 - 130
Perfluorodecanesulfonic acid
(PFDS)
38.6 38.9 ng/L 101 71 - 131
Perfluoropentanesulfonic acid
(PFPeS)
37.5 38.5 ng/L 103 66 - 126
Perfluorononanesulfonic acid
(PFNS)
38.4 39.2 ng/L 102 75 - 135
13C4 PFBA 25 - 150
Isotope Dilution
103
LCS LCS
Qualifier Limits%Recovery
9813C5 PFPeA 25 - 150
10613C2 PFHxA 25 - 150
10913C4 PFHpA 25 - 150
11413C4 PFOA 25 - 150
11113C5 PFNA 25 - 150
11413C2 PFDA 25 - 150
11213C2 PFUnA 25 - 150
10213C2 PFDoA 25 - 150
10313C2 PFTeDA 25 - 150
10213C3 PFBS 25 - 150
10318O2 PFHxS 25 - 150
10313C4 PFOS 25 - 150
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 320-458457/3-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
Perfluorobutanoic acid (PFBA) 40.0 41.3 ng/L 103 76 - 136 3 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) 40.0 38.6 ng/L 96 71 - 131 2 30
Perfluorohexanoic acid (PFHxA) 40.0 39.6 ng/L 99 73 - 133 2 30
Perfluoroheptanoic acid (PFHpA) 40.0 40.9 ng/L 102 72 - 132 2 30
Perfluorooctanoic acid (PFOA) 40.0 40.2 ng/L 100 70 - 130 3 30
Perfluorononanoic acid (PFNA) 40.0 40.4 ng/L 101 75 - 135 1 30
Perfluorodecanoic acid (PFDA) 40.0 38.9 ng/L 97 76 - 136 10 30
Perfluoroundecanoic acid
(PFUnA)
40.0 36.6 ng/L 92 68 - 128 18 30
Perfluorododecanoic acid
(PFDoA)
40.0 41.3 ng/L 103 71 - 131 4 30
Perfluorotridecanoic acid
(PFTriA)
40.0 40.3 ng/L 101 71 - 131 1 30
Perfluorobutanesulfonic acid
(PFBS)
35.4 37.2 ng/L 105 67 - 127 1 30
Perfluorohexanesulfonic acid
(PFHxS)
36.4 37.4 ng/L 103 59 - 119 5 30
Eurofins TestAmerica, Sacramento
Page 12 of 25 2/12/2021
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 320-458457/3-AMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
Perfluorooctanesulfonic acid
(PFOS)
37.1 38.2 ng/L 103 70 - 130 0 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Perfluorodecanesulfonic acid
(PFDS)
38.6 39.4 ng/L 102 71 - 131 1 30
Perfluoropentanesulfonic acid
(PFPeS)
37.5 40.1 ng/L 107 66 - 126 4 30
Perfluorononanesulfonic acid
(PFNS)
38.4 37.1 ng/L 97 75 - 135 6 30
13C4 PFBA 25 - 150
Isotope Dilution
100
LCSD LCSD
Qualifier Limits%Recovery
9913C5 PFPeA 25 - 150
10513C2 PFHxA 25 - 150
10713C4 PFHpA 25 - 150
10913C4 PFOA 25 - 150
11213C5 PFNA 25 - 150
11413C2 PFDA 25 - 150
11013C2 PFUnA 25 - 150
11113C2 PFDoA 25 - 150
10613C2 PFTeDA 25 - 150
10113C3 PFBS 25 - 150
9718O2 PFHxS 25 - 150
10213C4 PFOS 25 - 150
Client Sample ID: Matrix SpikeLab Sample ID: 320-69397-A-1-E MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
Perfluorobutanoic acid (PFBA) 31 36.8 59.0 ng/L 76 76 - 136
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 57 36.8 95.8 ng/L 105 71 - 131
Perfluorohexanoic acid (PFHxA) 35 36.8 72.1 ng/L 101 73 - 133
Perfluoroheptanoic acid (PFHpA) 39 36.8 78.5 ng/L 107 72 - 132
Perfluorooctanoic acid (PFOA) 23 36.8 58.2 ng/L 97 70 - 130
Perfluorononanoic acid (PFNA) 8.8 36.8 48.5 ng/L 108 75 - 135
Perfluorodecanoic acid (PFDA) 7.2 36.8 42.7 ng/L 96 76 - 136
Perfluoroundecanoic acid
(PFUnA)
ND 36.8 42.2 ng/L 115 68 - 128
Perfluorododecanoic acid
(PFDoA)
ND 36.8 41.7 ng/L 113 71 - 131
Perfluorotridecanoic acid
(PFTriA)
ND 36.8 39.1 ng/L 106 71 - 131
Perfluorobutanesulfonic acid
(PFBS)
1.5 J 32.5 39.3 ng/L 117 67 - 127
Perfluorohexanesulfonic acid
(PFHxS)
1.1 J 33.5 35.1 ng/L 102 59 - 119
Perfluorooctanesulfonic acid
(PFOS)
5.0 34.1 41.0 ng/L 105 70 - 130
Perfluorodecanesulfonic acid
(PFDS)
ND 35.4 31.5 ng/L 89 71 - 131
Perfluoropentanesulfonic acid
(PFPeS)
ND F1 34.5 47.4 F1 ng/L 137 66 - 126
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Matrix SpikeLab Sample ID: 320-69397-A-1-E MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
Perfluorononanesulfonic acid
(PFNS)
ND 35.3 36.3 ng/L 103 75 - 135
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
13C4 PFBA 25 - 150
Isotope Dilution
69
MS MS
Qualifier Limits%Recovery
4713C5 PFPeA 25 - 150
8813C2 PFHxA 25 - 150
8413C4 PFHpA 25 - 150
9613C4 PFOA 25 - 150
9713C5 PFNA 25 - 150
11313C2 PFDA 25 - 150
10113C2 PFUnA 25 - 150
9113C2 PFDoA 25 - 150
9313C2 PFTeDA 25 - 150
6713C3 PFBS 25 - 150
8518O2 PFHxS 25 - 150
9413C4 PFOS 25 - 150
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-69397-A-1-F MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
Perfluorobutanoic acid (PFBA) 31 36.8 60.6 ng/L 80 76 - 136 3 30
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) 57 36.8 93.1 ng/L 97 71 - 131 3 30
Perfluorohexanoic acid (PFHxA) 35 36.8 71.2 ng/L 99 73 - 133 1 30
Perfluoroheptanoic acid (PFHpA) 39 36.8 76.1 ng/L 101 72 - 132 3 30
Perfluorooctanoic acid (PFOA) 23 36.8 57.2 ng/L 94 70 - 130 2 30
Perfluorononanoic acid (PFNA) 8.8 36.8 45.6 ng/L 100 75 - 135 6 30
Perfluorodecanoic acid (PFDA) 7.2 36.8 48.7 ng/L 113 76 - 136 13 30
Perfluoroundecanoic acid
(PFUnA)
ND 36.8 40.1 ng/L 109 68 - 128 5 30
Perfluorododecanoic acid
(PFDoA)
ND 36.8 43.2 ng/L 117 71 - 131 4 30
Perfluorotridecanoic acid
(PFTriA)
ND 36.8 40.1 ng/L 109 71 - 131 2 30
Perfluorobutanesulfonic acid
(PFBS)
1.5 J 32.5 39.7 ng/L 117 67 - 127 1 30
Perfluorohexanesulfonic acid
(PFHxS)
1.1 J 33.5 34.4 ng/L 100 59 - 119 2 30
Perfluorooctanesulfonic acid
(PFOS)
5.0 34.2 41.8 ng/L 108 70 - 130 2 30
Perfluorodecanesulfonic acid
(PFDS)
ND 35.5 34.4 ng/L 97 71 - 131 9 30
Perfluoropentanesulfonic acid
(PFPeS)
ND F1 34.5 49.3 F1 ng/L 143 66 - 126 4 30
Perfluorononanesulfonic acid
(PFNS)
ND 35.3 37.4 ng/L 106 75 - 135 3 30
13C4 PFBA 25 - 150
Isotope Dilution
77
MSD MSD
Qualifier Limits%Recovery
Eurofins TestAmerica, Sacramento
Page 14 of 25 2/12/2021
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-69397-A-1-F MSDMatrix: Water Prep Type: Total/NAAnalysis Batch: 459298 Prep Batch: 458457
13C5 PFPeA 25 - 150
Isotope Dilution
53
MSD MSD
Qualifier Limits%Recovery
9713C2 PFHxA 25 - 150
9713C4 PFHpA 25 - 150
10813C4 PFOA 25 - 150
10513C5 PFNA 25 - 150
11113C2 PFDA 25 - 150
11313C2 PFUnA 25 - 150
9813C2 PFDoA 25 - 150
9413C2 PFTeDA 25 - 150
7113C3 PFBS 25 - 150
9318O2 PFHxS 25 - 150
10113C4 PFOS 25 - 150
Client Sample ID: Method BlankLab Sample ID: MB 320-459912/1-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
RL MDL
Perfluorobutanoic acid (PFBA) ND 0.20 0.028 ng/g 02/08/21 19:58 02/10/21 22:21 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
ND 0.0770.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoropentanoic acid (PFPeA)
ND 0.0420.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorohexanoic acid (PFHxA)
ND 0.0290.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoroheptanoic acid (PFHpA)
ND 0.0860.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorooctanoic acid (PFOA)
ND 0.0360.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorononanoic acid (PFNA)
ND 0.0220.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorodecanoic acid (PFDA)
ND 0.0360.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoroundecanoic acid (PFUnA)
ND 0.0670.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorododecanoic acid (PFDoA)
ND 0.0510.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorotridecanoic acid (PFTriA)
ND 0.0250.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorobutanesulfonic acid (PFBS)
ND 0.0310.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorohexanesulfonic acid (PFHxS)
0.370 J 0.200.50 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorooctanesulfonic acid (PFOS)
ND 0.0390.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorodecanesulfonic acid (PFDS)
ND 0.0200.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluoropentanesulfonic acid
(PFPeS)
ND 0.0200.20 ng/g 02/08/21 19:58 02/10/21 22:21 1Perfluorononanesulfonic acid (PFNS)
13C4 PFBA 79 25 - 150 02/10/21 22:21 1
MB MB
Isotope Dilution
02/08/21 19:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
93 02/08/21 19:58 02/10/21 22:21 113C5 PFPeA 25 - 150
91 02/08/21 19:58 02/10/21 22:21 113C2 PFHxA 25 - 150
90 02/08/21 19:58 02/10/21 22:21 113C4 PFHpA 25 - 150
98 02/08/21 19:58 02/10/21 22:21 113C4 PFOA 25 - 150
91 02/08/21 19:58 02/10/21 22:21 113C5 PFNA 25 - 150
93 02/08/21 19:58 02/10/21 22:21 113C2 PFDA 25 - 150
92 02/08/21 19:58 02/10/21 22:21 113C2 PFUnA 25 - 150
95 02/08/21 19:58 02/10/21 22:21 113C2 PFDoA 25 - 150
95 02/08/21 19:58 02/10/21 22:21 113C2 PFTeDA 25 - 150
91 02/08/21 19:58 02/10/21 22:21 113C3 PFBS 25 - 150
88 02/08/21 19:58 02/10/21 22:21 118O2 PFHxS 25 - 150
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 320-459912/1-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
13C4 PFOS 87 25 - 150 02/10/21 22:21 1
MB MB
Isotope Dilution
02/08/21 19:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-459912/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorobutanoic acid (PFBA) 2.00 2.14 ng/g 107 76 - 136
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 2.00 1.98 ng/g 99 69 - 129
Perfluorohexanoic acid (PFHxA) 2.00 2.08 ng/g 104 71 - 131
Perfluoroheptanoic acid (PFHpA) 2.00 2.07 ng/g 103 71 - 131
Perfluorooctanoic acid (PFOA) 2.00 1.84 ng/g 92 72 - 132
Perfluorononanoic acid (PFNA) 2.00 2.16 ng/g 108 73 - 133
Perfluorodecanoic acid (PFDA) 2.00 2.12 ng/g 106 72 - 132
Perfluoroundecanoic acid
(PFUnA)
2.00 2.17 ng/g 109 66 - 126
Perfluorododecanoic acid
(PFDoA)
2.00 2.13 ng/g 107 71 - 131
Perfluorotridecanoic acid
(PFTriA)
2.00 2.04 ng/g 102 71 - 131
Perfluorobutanesulfonic acid
(PFBS)
1.77 1.88 ng/g 106 69 - 129
Perfluorohexanesulfonic acid
(PFHxS)
1.82 1.76 ng/g 97 62 - 122
Perfluorooctanesulfonic acid
(PFOS)
1.86 2.15 ng/g 116 68 - 141
Perfluorodecanesulfonic acid
(PFDS)
1.93 2.09 ng/g 109 71 - 131
Perfluoropentanesulfonic acid
(PFPeS)
1.88 2.03 ng/g 108 66 - 126
Perfluorononanesulfonic acid
(PFNS)
1.92 2.04 ng/g 106 72 - 132
13C4 PFBA 25 - 150
Isotope Dilution
60
LCS LCS
Qualifier Limits%Recovery
6813C5 PFPeA 25 - 150
6313C2 PFHxA 25 - 150
6813C4 PFHpA 25 - 150
7513C4 PFOA 25 - 150
6913C5 PFNA 25 - 150
7113C2 PFDA 25 - 150
6513C2 PFUnA 25 - 150
7213C2 PFDoA 25 - 150
6913C2 PFTeDA 25 - 150
6413C3 PFBS 25 - 150
6718O2 PFHxS 25 - 150
6613C4 PFOS 25 - 150
Eurofins TestAmerica, Sacramento
Page 16 of 25 2/12/2021
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: RS0127 MSLab Sample ID: 320-69426-1 MSMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorobutanoic acid (PFBA) 0.077 J 2.14 2.48 ng/g 112 76 - 136☼
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) ND 2.14 2.17 ng/g 101 69 - 129☼
Perfluorohexanoic acid (PFHxA) 0.063 J 2.14 2.26 ng/g 103 71 - 131☼
Perfluoroheptanoic acid (PFHpA) 0.042 J 2.14 2.25 ng/g 103 71 - 131☼
Perfluorooctanoic acid (PFOA) 0.19 J 2.14 2.44 ng/g 105 72 - 132☼
Perfluorononanoic acid (PFNA) 0.19 J 2.14 2.47 ng/g 106 73 - 133☼
Perfluorodecanoic acid (PFDA) 0.19 J 2.14 2.46 ng/g 106 72 - 132☼
Perfluoroundecanoic acid
(PFUnA)
0.16 J 2.14 2.73 ng/g 120 66 - 126☼
Perfluorododecanoic acid
(PFDoA)
0.10 J 2.14 2.33 ng/g 104 71 - 131☼
Perfluorotridecanoic acid
(PFTriA)
0.055 J 2.14 2.08 ng/g 95 71 - 131☼
Perfluorobutanesulfonic acid
(PFBS)
0.034 J 1.89 2.12 ng/g 110 69 - 129☼
Perfluoropentanesulfonic acid
(PFPeS)
ND 2.01 1.71 ng/g 85 66 - 126☼
Perfluorohexanesulfonic acid
(PFHxS)
0.041 J 1.95 1.87 ng/g 94 62 - 122☼
Perfluorooctanesulfonic acid
(PFOS)
1.3 B 1.99 3.34 ng/g 105 68 - 141☼
Perfluorononanesulfonic acid
(PFNS)
ND 2.06 2.06 ng/g 100 72 - 132☼
Perfluorodecanesulfonic acid
(PFDS)
ND 2.07 2.14 ng/g 104 71 - 131☼
13C4 PFBA 25 - 150
Isotope Dilution
62
MS MS
Qualifier Limits%Recovery
10013C5 PFPeA 25 - 150
8913C2 PFHxA 25 - 150
7913C4 PFHpA 25 - 150
8613C4 PFOA 25 - 150
8313C5 PFNA 25 - 150
7813C2 PFDA 25 - 150
7613C2 PFUnA 25 - 150
7413C2 PFDoA 25 - 150
7013C2 PFTeDA 25 - 150
9913C3 PFBS 25 - 150
8218O2 PFHxS 25 - 150
8113C4 PFOS 25 - 150
Client Sample ID: RS0127 MSDLab Sample ID: 320-69426-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorobutanoic acid (PFBA) 0.077 J 2.01 2.37 ng/g 114 76 - 136 5 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) ND 2.01 1.90 ng/g 95 69 - 129 13 30☼
Perfluorohexanoic acid (PFHxA) 0.063 J 2.01 2.12 ng/g 102 71 - 131 6 30☼
Perfluoroheptanoic acid (PFHpA) 0.042 J 2.01 2.20 ng/g 108 71 - 131 2 30☼
Perfluorooctanoic acid (PFOA) 0.19 J 2.01 2.16 ng/g 98 72 - 132 12 30☼
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: RS0127 MSDLab Sample ID: 320-69426-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460911 Prep Batch: 459912
Perfluorononanoic acid (PFNA) 0.19 J 2.01 2.32 ng/g 106 73 - 133 6 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluorodecanoic acid (PFDA) 0.19 J 2.01 2.48 ng/g 114 72 - 132 1 30☼
Perfluoroundecanoic acid
(PFUnA)
0.16 J 2.01 2.68 ng/g 125 66 - 126 2 30☼
Perfluorododecanoic acid
(PFDoA)
0.10 J 2.01 2.15 ng/g 102 71 - 131 8 30☼
Perfluorotridecanoic acid
(PFTriA)
0.055 J 2.01 2.06 ng/g 100 71 - 131 1 30☼
Perfluorobutanesulfonic acid
(PFBS)
0.034 J 1.77 2.15 ng/g 120 69 - 129 2 30☼
Perfluoropentanesulfonic acid
(PFPeS)
ND 1.88 1.58 ng/g 84 66 - 126 7 30☼
Perfluorohexanesulfonic acid
(PFHxS)
0.041 J 1.83 1.83 ng/g 98 62 - 122 2 30☼
Perfluorooctanesulfonic acid
(PFOS)
1.3 B 1.86 3.46 ng/g 118 68 - 141 3 30☼
Perfluorononanesulfonic acid
(PFNS)
ND 1.93 1.94 ng/g 101 72 - 132 6 30☼
Perfluorodecanesulfonic acid
(PFDS)
ND 1.93 2.03 ng/g 105 71 - 131 5 30☼
13C4 PFBA 25 - 150
Isotope Dilution
71
MSD MSD
Qualifier Limits%Recovery
11513C5 PFPeA 25 - 150
10513C2 PFHxA 25 - 150
8513C4 PFHpA 25 - 150
9713C4 PFOA 25 - 150
9313C5 PFNA 25 - 150
8313C2 PFDA 25 - 150
8313C2 PFUnA 25 - 150
8313C2 PFDoA 25 - 150
8013C2 PFTeDA 25 - 150
10613C3 PFBS 25 - 150
9118O2 PFHxS 25 - 150
9113C4 PFOS 25 - 150
Method: D 2216 - Percent Moisture
Client Sample ID: RS0127Lab Sample ID: 320-69426-1 DUMatrix: Solid Prep Type: Total/NAAnalysis Batch: 456914
Percent Moisture 8.8 8.3 % 6 20
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Percent Solids 91.2 91.7 % 0.5 20
Eurofins TestAmerica, Sacramento
Page 18 of 25 2/12/2021
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QC Association SummaryJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
LCMS
Prep Batch: 458457
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3535320-69426-3 R0127 (Rinsate) Total/NA
Water 3535MB 320-458457/1-A Method Blank Total/NA
Water 3535LCS 320-458457/2-A Lab Control Sample Total/NA
Water 3535LCSD 320-458457/3-A Lab Control Sample Dup Total/NA
Water 3535320-69397-A-1-E MS Matrix Spike Total/NA
Water 3535320-69397-A-1-F MSD Matrix Spike Duplicate Total/NA
Analysis Batch: 459298
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 537 (modified) 458457320-69426-3 R0127 (Rinsate) Total/NA
Water 537 (modified) 458457MB 320-458457/1-A Method Blank Total/NA
Water 537 (modified) 458457LCS 320-458457/2-A Lab Control Sample Total/NA
Water 537 (modified) 458457LCSD 320-458457/3-A Lab Control Sample Dup Total/NA
Water 537 (modified) 458457320-69397-A-1-E MS Matrix Spike Total/NA
Water 537 (modified) 458457320-69397-A-1-F MSD Matrix Spike Duplicate Total/NA
Prep Batch: 459912
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid SHAKE320-69426-1 RS0127 Total/NA
Solid SHAKE320-69426-2 RS0127 Dup Total/NA
Solid SHAKEMB 320-459912/1-A Method Blank Total/NA
Solid SHAKELCS 320-459912/2-A Lab Control Sample Total/NA
Solid SHAKE320-69426-1 MS RS0127 MS Total/NA
Solid SHAKE320-69426-1 MSD RS0127 MSD Total/NA
Analysis Batch: 460911
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 537 (modified) 459912320-69426-1 RS0127 Total/NA
Solid 537 (modified) 459912320-69426-2 RS0127 Dup Total/NA
Solid 537 (modified) 459912MB 320-459912/1-A Method Blank Total/NA
Solid 537 (modified) 459912LCS 320-459912/2-A Lab Control Sample Total/NA
Solid 537 (modified) 459912320-69426-1 MS RS0127 MS Total/NA
Solid 537 (modified) 459912320-69426-1 MSD RS0127 MSD Total/NA
General Chemistry
Analysis Batch: 456914
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid D 2216320-69426-1 RS0127 Total/NA
Solid D 2216320-69426-2 RS0127 Dup Total/NA
Solid D 2216320-69426-1 DU RS0127 Total/NA
Eurofins TestAmerica, Sacramento
Page 19 of 25 2/12/2021
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Lab ChronicleClient: Waste Options Nantucket LLC Job ID: 320-69426-1Project/Site: PFAS, MassDEP
Client Sample ID: RS0127 Lab Sample ID: 320-69426-1Matrix: SolidDate Collected: 01/27/21 12:30
Date Received: 01/28/21 10:30
Analysis D 2216 TCS01/29/21 16:281 TAL SAC456914
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: RS0127 Lab Sample ID: 320-69426-1Matrix: SolidDate Collected: 01/27/21 12:30
Percent Solids: 91.2Date Received: 01/28/21 10:30
Prep SHAKE AP02/08/21 19:58 TAL SAC459912
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.38 g 10.00 mL
Analysis 537 (modified) 1 460911 02/10/21 23:16 RS1 TAL SACTotal/NA
Client Sample ID: RS0127 Dup Lab Sample ID: 320-69426-2Matrix: SolidDate Collected: 01/27/21 12:30
Date Received: 01/28/21 10:30
Analysis D 2216 TCS01/29/21 16:281 TAL SAC456914
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: RS0127 Dup Lab Sample ID: 320-69426-2Matrix: SolidDate Collected: 01/27/21 12:30
Percent Solids: 81.7Date Received: 01/28/21 10:30
Prep SHAKE AP02/08/21 19:58 TAL SAC459912
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.21 g 10.00 mL
Analysis 537 (modified) 1 460911 02/10/21 23:43 RS1 TAL SACTotal/NA
Client Sample ID: R0127 (Rinsate) Lab Sample ID: 320-69426-3Matrix: WaterDate Collected: 01/27/21 12:30
Date Received: 01/28/21 10:30
Prep 3535 VP02/03/21 19:00 TAL SAC458457
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 185.2 mL 10.00 mL
Analysis 537 (modified) 1 459298 02/06/21 00:24 S1M TAL SACTotal/NA
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
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Accreditation/Certification SummaryClient: Waste Options Nantucket LLC Job ID: 320-69426-1Project/Site: PFAS, MassDEP
Laboratory: Eurofins TestAmerica, SacramentoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
Alaska (UST) 17-020State 01-20-21 *
ANAB Dept. of Defense ELAP L2468 01-20-24
ANAB Dept. of Energy L2468.01 01-20-21 *
ANAB ISO/IEC 17025 L2468 01-20-21 *
Arizona State AZ0708 08-11-21
Arkansas DEQ State 88-0691 06-17-21
California State 2897 01-31-22
Colorado State CA0004 08-31-21
Connecticut State PH-0691 06-30-21
Florida NELAP E87570 06-30-21
Georgia State 4040 01-29-22
Hawaii State <cert No.> 01-29-22
Illinois NELAP 200060 03-17-21
Kansas NELAP E-10375 02-01-21 *
Louisiana NELAP 01944 06-30-21
Maine State CA00004 04-14-22
Michigan State 9947 01-29-21 *
Nevada State CA000442021-2 07-31-21
New Hampshire NELAP 2997 04-18-21
New Jersey NELAP CA005 06-30-21
New York NELAP 11666 04-01-21
Ohio State 41252 01-29-22
Oregon NELAP 4040 01-29-21 *
Pennsylvania NELAP 68-01272 03-31-21
Texas NELAP T104704399-19-13 06-01-21
US Fish & Wildlife US Federal Programs 58448 07-31-21
USDA US Federal Programs P330-18-00239 07-31-21
Utah NELAP CA000442019-01 02-28-21
Vermont State VT-4040 04-16-21
Virginia NELAP 460278 03-14-21
Washington State C581 05-05-21
West Virginia (DW) State 9930C 12-31-21
Wisconsin State 998204680 08-31-21
Wyoming State Program 8TMS-L 01-28-19 *
Eurofins TestAmerica, Sacramento
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 21 of 25 2/12/2021
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Method SummaryJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL SAC
ASTMD 2216 Percent Moisture TAL SAC
SW8463535 Solid-Phase Extraction (SPE) TAL SAC
SW846SHAKE Shake Extraction with Ultrasonic Bath Extraction TAL SAC
Protocol References:
ASTM = ASTM International
EPA = US Environmental Protection Agency
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
Page 22 of 25 2/12/2021
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Sample SummaryJob ID: 320-69426-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
320-69426-1 RS0127 Solid 01/27/21 12:30 01/28/21 10:30
320-69426-2 RS0127 Dup Solid 01/27/21 12:30 01/28/21 10:30
320-69426-3 R0127 (Rinsate) Water 01/27/21 12:30 01/28/21 10:30
Eurofins TestAmerica, Sacramento
Page 23 of 25 2/12/2021
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Login Sample Receipt Checklist
Client: Waste Options Nantucket LLC Job Number: 320-69426-1
Login Number: 69426
Question Answer Comment
Creator: Thompson, Sarah W
List Source: Eurofins TestAmerica, Sacramento
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact. 1462290, 1462291
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
FalseSample bottles are completely filled. R0127 (Rinsate) - reporting limits adjsuted accordinlgy.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins TestAmerica, SacramentoPage 25 of 25 2/12/2021
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ANALYTICAL REPORTEurofins TestAmerica, Sacramento880 Riverside ParkwayWest Sacramento, CA 95605Tel: (916)373-5600
Laboratory Job ID: 320-69429-1Client Project/Site: PFAS, MassDEP
For:Waste Options Nantucket LLC188 Madaket RdNantucket, Massachusetts 02554
Attn: Nathan Widell
Authorized for release by:2/12/2021 4:26:20 PM
Cesar Cortes, Project Manager I(916)[email protected]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements foraccredited parameters, exceptions are noted in this report. This report may not be reproducedexcept in full, and with written approval from the laboratory. For questions please contact theProject Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Waste Options Nantucket LLCProject/Site: PFAS, MassDEP
Laboratory Job ID: 320-69429-1
Page 2 of 19Eurofins TestAmerica, Sacramento
2/12/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
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Definitions/GlossaryJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Qualifiers
LCMSQualifier Description
*5- Isotope dilution analyte is outside acceptance limits, low biased.
Qualifier
B Compound was found in the blank and sample.
F1 MS and/or MSD recovery exceeds control limits.
F2 MS/MSD RPD exceeds control limits
I Value is EMPC (estimated maximum possible concentration).
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
GlossaryThese commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Sacramento
Page 3 of 19 2/12/2021
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Case NarrativeClient: Waste Options Nantucket LLC Job ID: 320-69429-1Project/Site: PFAS, MassDEP
Job ID: 320-69429-1
Laboratory: Eurofins TestAmerica, Sacramento
Narrative
Receipt The samples were received on 1/28/2021 10:30 AM; the samples arrived in good condition, and where required, properly preserved and
on ice. The temperature of the cooler at receipt was 4.4º C.
Method 537 (modified)The method blank for preparation batch 320-459644 and analytical batch 320-460135 contained Perfluorooctanesulfonic acid (PFOS) above the reporting limit (RL). Associated samples were not re-extracted and/or re-analyzed because results were greater than 10X the
value found in the method blank.
The "I" qualifier means the transition mass ratio for the indicated analytes were outside of the established ratio limits. The qualitative identification of the analytes have some degree of uncertainty. However, analyst judgment was used to positively identify the analytes.
The matrix spike (MS) recovery for preparation batch 320-459644 and analytical batch 320-460135 was outside control limits for
Perfluorotridecanoic acid (PFTrDA). Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS) recovery was within acceptance limits.
The matrix spike / matrix spike duplicate (MS/MSD/DUP) precision for preparation batch 320-459644 and analytical batch 320-460135 was outside control limits for Perfluorotridecanoic acid (PFTrDA). Sample matrix interference and/or non-homogeneity are suspected.
The Isotope Dilution Analyte (IDA) recovery is below the method recommended limit for 13C2 PFTeDA: SC0127 (320-69429-1) and SC0127 MS (320-69429-1[MS]). Generally, data quality is not considered affected if the IDA signal-to-noise ratio is greater than 10:1, which is achieved for all IDA in the sample. The sample was re-extracted with concurring results; therefore, the best set of data have been reported.
The IDA recovery is below the method recommended limit for 13C2 PFDoA: SC0127 MS (320-69429-1[MS]). Generally, data quality is not considered affected if the IDA signal-to-noise ratio is greater than 10:1, which is achieved for all IDA in the MS.
Due to the matrix, the initial volume used for the following samples deviated from the standard procedure: SC0127 (320-69429-1), SC0127 MS (320-69429-1[MS]), SC0127 MSD (320-69429-1[MSD]) and SC0127 Dup (320-69429-2). Sample were prepped at 0.5g (versus 5). The reporting limits (RLs) have been adjusted proportionately, preparation batch 320-459644.
The following samples were light yellow in color (after extraction): SC0127 (320-69429-1), SC0127 MS (320-69429-1[MS]), SC0127 MSD
(320-69429-1[MSD]) and SC0127 Dup (320-69429-2), preparation batch 320-459644.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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Detection SummaryJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Client Sample ID: SC0127 Lab Sample ID: 320-69429-1
☼Perfluorobutanoic acid (PFBA)
RL
8.9 ng/g
MDL
1.3
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J2.6 537 (modified)
☼Perfluorohexanoic acid (PFHxA) 8.9 ng/g1.9 Total/NA12.5 J 537 (modified)
☼Perfluorooctanoic acid (PFOA) 8.9 ng/g3.8 Total/NA16.0 J 537 (modified)
☼Perfluorononanoic acid (PFNA) 8.9 ng/g1.6 Total/NA13.7 J 537 (modified)
☼Perfluorodecanoic acid (PFDA) 8.9 ng/g0.98 Total/NA115 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 8.9 ng/g1.6 Total/NA13.3 J 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 8.9 ng/g3.0 Total/NA13.7 J 537 (modified)
☼Perfluorobutanesulfonic acid (PFBS) 8.9 ng/g1.1 Total/NA116 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 22 ng/g8.9 Total/NA195 B 537 (modified)
☼Perfluorodecanesulfonic acid (PFDS) 8.9 ng/g1.7 Total/NA12.4 J I 537 (modified)
Client Sample ID: SC0127 Dup Lab Sample ID: 320-69429-2
☼Perfluorobutanoic acid (PFBA)
RL
9.2 ng/g
MDL
1.3
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J3.0 537 (modified)
☼Perfluorohexanoic acid (PFHxA) 9.2 ng/g1.9 Total/NA12.3 J 537 (modified)
☼Perfluorooctanoic acid (PFOA) 9.2 ng/g3.9 Total/NA17.7 J I 537 (modified)
☼Perfluorononanoic acid (PFNA) 9.2 ng/g1.7 Total/NA14.0 J 537 (modified)
☼Perfluorodecanoic acid (PFDA) 9.2 ng/g1.0 Total/NA116 537 (modified)
☼Perfluoroundecanoic acid (PFUnA) 9.2 ng/g1.7 Total/NA12.6 J 537 (modified)
☼Perfluorododecanoic acid (PFDoA) 9.2 ng/g3.1 Total/NA14.2 J 537 (modified)
☼Perfluorobutanesulfonic acid (PFBS) 9.2 ng/g1.1 Total/NA13.2 J 537 (modified)
☼Perfluorooctanesulfonic acid (PFOS) 23 ng/g9.2 Total/NA168 I B 537 (modified)
☼Perfluorodecanesulfonic acid (PFDS) 9.2 ng/g1.8 Total/NA13.0 J I 537 (modified)
Eurofins TestAmerica, Sacramento
This Detection Summary does not include radiochemical test results.
Page 5 of 19 2/12/2021
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Client Sample ResultsJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID: 320-69429-1Client Sample ID: SC0127Matrix: SolidDate Collected: 01/27/21 11:30
Percent Solids: 20.7Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) 2.6 J 8.9 1.3 ng/g ☼ 02/08/21 06:41 02/09/21 18:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
8.9 3.4 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluoropentanoic acid (PFPeA) ND
8.9 1.9 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorohexanoic acid (PFHxA) 2.5 J
8.9 1.3 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluoroheptanoic acid (PFHpA) ND
8.9 3.8 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorooctanoic acid (PFOA) 6.0 J
8.9 1.6 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorononanoic acid (PFNA) 3.7 J
8.9 0.98 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorodecanoic acid (PFDA) 15
8.9 1.6 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluoroundecanoic acid (PFUnA)
3.3 J
8.9 3.0 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorododecanoic acid (PFDoA)
3.7 J
8.9 2.3 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorotridecanoic acid (PFTriA) ND F1 F2
8.9 1.1 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorobutanesulfonic acid (PFBS)
16
8.9 0.89 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND
8.9 1.4 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorohexanesulfonic acid (PFHxS) ND
22 8.9 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorooctanesulfonic acid (PFOS)
95 B
8.9 0.89 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorononanesulfonic acid (PFNS) ND
8.9 1.7 ng/g 02/08/21 06:41 02/09/21 18:16 1☼Perfluorodecanesulfonic acid (PFDS)
2.4 J I
13C4 PFBA 47 25 - 150 02/08/21 06:41 02/09/21 18:16 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 57 02/08/21 06:41 02/09/21 18:16 125 - 150
13C2 PFHxA 75 02/08/21 06:41 02/09/21 18:16 125 - 150
13C4 PFHpA 82 02/08/21 06:41 02/09/21 18:16 125 - 150
13C4 PFOA 98 02/08/21 06:41 02/09/21 18:16 125 - 150
13C5 PFNA 100 02/08/21 06:41 02/09/21 18:16 125 - 150
13C2 PFDA 94 02/08/21 06:41 02/09/21 18:16 125 - 150
13C2 PFUnA 73 02/08/21 06:41 02/09/21 18:16 125 - 150
13C2 PFDoA 33 02/08/21 06:41 02/09/21 18:16 125 - 150
13C2 PFTeDA 24 *5- 02/08/21 06:41 02/09/21 18:16 125 - 150
13C3 PFBS 68 02/08/21 06:41 02/09/21 18:16 125 - 150
18O2 PFHxS 73 02/08/21 06:41 02/09/21 18:16 125 - 150
13C4 PFOS 77 02/08/21 06:41 02/09/21 18:16 125 - 150
General ChemistryRL MDL
Percent Moisture 79.3 0.1 0.1 % 02/01/21 10:52 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 02/01/21 10:52 1Percent Solids 20.7
Lab Sample ID: 320-69429-2Client Sample ID: SC0127 DupMatrix: SolidDate Collected: 01/27/21 11:30
Percent Solids: 21.4Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl SubstancesRL MDL
Perfluorobutanoic acid (PFBA) 3.0 J 9.2 1.3 ng/g ☼ 02/08/21 06:41 02/09/21 18:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
9.2 3.5 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluoropentanoic acid (PFPeA) ND
9.2 1.9 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorohexanoic acid (PFHxA) 2.3 J
Eurofins TestAmerica, Sacramento
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Client Sample ResultsJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID: 320-69429-2Client Sample ID: SC0127 DupMatrix: SolidDate Collected: 01/27/21 11:30
Percent Solids: 21.4Date Received: 01/28/21 10:30
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)RL MDL
Perfluoroheptanoic acid (PFHpA) ND 9.2 1.3 ng/g ☼ 02/08/21 06:41 02/09/21 18:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
9.2 3.9 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorooctanoic acid (PFOA) 7.7 J I
9.2 1.7 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorononanoic acid (PFNA) 4.0 J
9.2 1.0 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorodecanoic acid (PFDA) 16
9.2 1.7 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluoroundecanoic acid (PFUnA)
2.6 J
9.2 3.1 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorododecanoic acid (PFDoA)
4.2 J
9.2 2.3 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorotridecanoic acid (PFTriA) ND
9.2 1.1 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorobutanesulfonic acid (PFBS)
3.2 J
9.2 0.92 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluoropentanesulfonic acid
(PFPeS)
ND
9.2 1.4 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorohexanesulfonic acid (PFHxS) ND
23 9.2 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorooctanesulfonic acid (PFOS)
68 I B
9.2 0.92 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorononanesulfonic acid (PFNS) ND
9.2 1.8 ng/g 02/08/21 06:41 02/09/21 18:43 1☼Perfluorodecanesulfonic acid (PFDS)
3.0 J I
13C4 PFBA 63 25 - 150 02/08/21 06:41 02/09/21 18:43 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
13C5 PFPeA 67 02/08/21 06:41 02/09/21 18:43 125 - 150
13C2 PFHxA 74 02/08/21 06:41 02/09/21 18:43 125 - 150
13C4 PFHpA 85 02/08/21 06:41 02/09/21 18:43 125 - 150
13C4 PFOA 94 02/08/21 06:41 02/09/21 18:43 125 - 150
13C5 PFNA 96 02/08/21 06:41 02/09/21 18:43 125 - 150
13C2 PFDA 86 02/08/21 06:41 02/09/21 18:43 125 - 150
13C2 PFUnA 79 02/08/21 06:41 02/09/21 18:43 125 - 150
13C2 PFDoA 28 02/08/21 06:41 02/09/21 18:43 125 - 150
13C2 PFTeDA 38 02/08/21 06:41 02/09/21 18:43 125 - 150
13C3 PFBS 74 02/08/21 06:41 02/09/21 18:43 125 - 150
18O2 PFHxS 75 02/08/21 06:41 02/09/21 18:43 125 - 150
13C4 PFOS 75 02/08/21 06:41 02/09/21 18:43 125 - 150
General ChemistryRL MDL
Percent Moisture 78.6 0.1 0.1 % 02/01/21 10:52 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.1 0.1 % 02/01/21 10:52 1Percent Solids 21.4
Eurofins TestAmerica, Sacramento
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Isotope Dilution SummaryJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl SubstancesPrep Type: Total/NAMatrix: Solid
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150) (25-150)
PFBA PFPeA PFHxA C4PFHA PFOA PFNA PFDA PFUnA
47 57 75 82 98 100 94 73320-69429-1
Percent Isotope Dilution Recovery (Acceptance Limits)
SC0127
64 68 77 9988 105 93 80320-69429-1 MS SC0127 MS
64 62 76 9986 91 102 76320-69429-1 MSD SC0127 MSD
63 67 74 9485 96 86 79320-69429-2 SC0127 Dup
74 80 80 9689 99 101 101LCS 320-459644/2-A Lab Control Sample
67 73 73 9085 92 87 89MB 320-459644/1-A Method Blank
Lab Sample ID Client Sample ID (25-150) (25-150) (25-150) (25-150) (25-150)
PFDoA PFTDA C3PFBS PFHxS PFOS
33 24 *5- 68 73 77320-69429-1
Percent Isotope Dilution Recovery (Acceptance Limits)
SC0127
23 *5- 8 *5- 77 8077320-69429-1 MS SC0127 MS
27 33 69 8076320-69429-1 MSD SC0127 MSD
28 38 74 7575320-69429-2 SC0127 Dup
113 92 76 7472LCS 320-459644/2-A Lab Control Sample
107 97 69 7066MB 320-459644/1-A Method Blank
Surrogate Legend
PFBA = 13C4 PFBA
PFPeA = 13C5 PFPeA
PFHxA = 13C2 PFHxA
C4PFHA = 13C4 PFHpA
PFOA = 13C4 PFOA
PFNA = 13C5 PFNA
PFDA = 13C2 PFDA
PFUnA = 13C2 PFUnA
PFDoA = 13C2 PFDoA
PFTDA = 13C2 PFTeDA
C3PFBS = 13C3 PFBS
PFHxS = 18O2 PFHxS
PFOS = 13C4 PFOS
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 320-459644/1-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460135 Prep Batch: 459644
RL MDL
Perfluorobutanoic acid (PFBA) ND 0.20 0.028 ng/g 02/08/21 06:41 02/09/21 17:58 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
ND 0.0770.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluoropentanoic acid (PFPeA)
ND 0.0420.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorohexanoic acid (PFHxA)
ND 0.0290.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluoroheptanoic acid (PFHpA)
ND 0.0860.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorooctanoic acid (PFOA)
ND 0.0360.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorononanoic acid (PFNA)
ND 0.0220.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorodecanoic acid (PFDA)
ND 0.0360.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluoroundecanoic acid (PFUnA)
ND 0.0670.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorododecanoic acid (PFDoA)
ND 0.0510.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorotridecanoic acid (PFTriA)
ND 0.0250.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorobutanesulfonic acid (PFBS)
ND 0.0200.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluoropentanesulfonic acid
(PFPeS)
ND 0.0310.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorohexanesulfonic acid (PFHxS)
0.519 0.200.50 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorooctanesulfonic acid (PFOS)
ND 0.0200.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorononanesulfonic acid (PFNS)
ND 0.0390.20 ng/g 02/08/21 06:41 02/09/21 17:58 1Perfluorodecanesulfonic acid (PFDS)
13C4 PFBA 67 25 - 150 02/09/21 17:58 1
MB MB
Isotope Dilution
02/08/21 06:41
Dil FacPrepared AnalyzedQualifier Limits%Recovery
73 02/08/21 06:41 02/09/21 17:58 113C5 PFPeA 25 - 150
73 02/08/21 06:41 02/09/21 17:58 113C2 PFHxA 25 - 150
85 02/08/21 06:41 02/09/21 17:58 113C4 PFHpA 25 - 150
90 02/08/21 06:41 02/09/21 17:58 113C4 PFOA 25 - 150
92 02/08/21 06:41 02/09/21 17:58 113C5 PFNA 25 - 150
87 02/08/21 06:41 02/09/21 17:58 113C2 PFDA 25 - 150
89 02/08/21 06:41 02/09/21 17:58 113C2 PFUnA 25 - 150
107 02/08/21 06:41 02/09/21 17:58 113C2 PFDoA 25 - 150
97 02/08/21 06:41 02/09/21 17:58 113C2 PFTeDA 25 - 150
69 02/08/21 06:41 02/09/21 17:58 113C3 PFBS 25 - 150
66 02/08/21 06:41 02/09/21 17:58 118O2 PFHxS 25 - 150
70 02/08/21 06:41 02/09/21 17:58 113C4 PFOS 25 - 150
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-459644/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460135 Prep Batch: 459644
Perfluorobutanoic acid (PFBA) 2.00 2.11 ng/g 105 76 - 136
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) 2.00 1.86 ng/g 93 69 - 129
Perfluorohexanoic acid (PFHxA) 2.00 1.99 ng/g 100 71 - 131
Perfluoroheptanoic acid (PFHpA) 2.00 2.03 ng/g 102 71 - 131
Perfluorooctanoic acid (PFOA) 2.00 1.84 ng/g 92 72 - 132
Perfluorononanoic acid (PFNA) 2.00 1.94 ng/g 97 73 - 133
Perfluorodecanoic acid (PFDA) 2.00 1.95 ng/g 97 72 - 132
Perfluoroundecanoic acid
(PFUnA)
2.00 2.22 ng/g 111 66 - 126
Perfluorododecanoic acid
(PFDoA)
2.00 1.93 ng/g 97 71 - 131
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-459644/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460135 Prep Batch: 459644
Perfluorotridecanoic acid
(PFTriA)
2.00 2.24 ng/g 112 71 - 131
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Perfluorobutanesulfonic acid
(PFBS)
1.77 1.73 ng/g 98 69 - 129
Perfluoropentanesulfonic acid
(PFPeS)
1.88 1.79 ng/g 96 66 - 126
Perfluorohexanesulfonic acid
(PFHxS)
1.82 1.68 ng/g 92 62 - 122
Perfluorooctanesulfonic acid
(PFOS)
1.86 2.39 ng/g 129 68 - 141
Perfluorononanesulfonic acid
(PFNS)
1.92 2.01 ng/g 105 72 - 132
Perfluorodecanesulfonic acid
(PFDS)
1.93 2.01 ng/g 104 71 - 131
13C4 PFBA 25 - 150
Isotope Dilution
74
LCS LCS
Qualifier Limits%Recovery
8013C5 PFPeA 25 - 150
8013C2 PFHxA 25 - 150
8913C4 PFHpA 25 - 150
9613C4 PFOA 25 - 150
9913C5 PFNA 25 - 150
10113C2 PFDA 25 - 150
10113C2 PFUnA 25 - 150
11313C2 PFDoA 25 - 150
9213C2 PFTeDA 25 - 150
7613C3 PFBS 25 - 150
7218O2 PFHxS 25 - 150
7413C4 PFOS 25 - 150
Client Sample ID: SC0127 MSLab Sample ID: 320-69429-1 MSMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460135 Prep Batch: 459644
Perfluorobutanoic acid (PFBA) 2.6 J 96.6 108 ng/g 109 76 - 136☼
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluoropentanoic acid (PFPeA) ND 96.6 95.7 ng/g 99 69 - 129☼
Perfluorohexanoic acid (PFHxA) 2.5 J 96.6 104 ng/g 105 71 - 131☼
Perfluoroheptanoic acid (PFHpA) ND 96.6 103 ng/g 107 71 - 131☼
Perfluorooctanoic acid (PFOA) 6.0 J 96.6 105 ng/g 102 72 - 132☼
Perfluorononanoic acid (PFNA) 3.7 J 96.6 97.8 ng/g 97 73 - 133☼
Perfluorodecanoic acid (PFDA) 15 96.6 123 ng/g 112 72 - 132☼
Perfluoroundecanoic acid
(PFUnA)
3.3 J 96.6 106 ng/g 106 66 - 126☼
Perfluorododecanoic acid
(PFDoA)
3.7 J 96.6 94.7 ng/g 94 71 - 131☼
Perfluorotridecanoic acid
(PFTriA)
ND F1 F2 96.6 52.5 F1 ng/g 54 71 - 131☼
Perfluorobutanesulfonic acid
(PFBS)
16 85.4 103 ng/g 103 69 - 129☼
Perfluoropentanesulfonic acid
(PFPeS)
ND 90.6 95.0 ng/g 105 66 - 126☼
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: SC0127 MSLab Sample ID: 320-69429-1 MSMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460135 Prep Batch: 459644
Perfluorohexanesulfonic acid
(PFHxS)
ND 87.9 88.5 ng/g 92 62 - 122☼
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Perfluorooctanesulfonic acid
(PFOS)
95 B 89.7 186 ng/g 102 68 - 141☼
Perfluorononanesulfonic acid
(PFNS)
ND 92.8 98.0 ng/g 106 72 - 132☼
Perfluorodecanesulfonic acid
(PFDS)
2.4 J I 93.2 81.0 ng/g 84 71 - 131☼
13C4 PFBA 25 - 150
Isotope Dilution
64
MS MS
Qualifier Limits%Recovery
6813C5 PFPeA 25 - 150
7713C2 PFHxA 25 - 150
8813C4 PFHpA 25 - 150
9913C4 PFOA 25 - 150
10513C5 PFNA 25 - 150
9313C2 PFDA 25 - 150
8013C2 PFUnA 25 - 150
23 *5-13C2 PFDoA 25 - 150
8 *5-13C2 PFTeDA 25 - 150
7713C3 PFBS 25 - 150
7718O2 PFHxS 25 - 150
8013C4 PFOS 25 - 150
Client Sample ID: SC0127 MSDLab Sample ID: 320-69429-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460135 Prep Batch: 459644
Perfluorobutanoic acid (PFBA) 2.6 J 94.7 110 ng/g 114 76 - 136 2 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Perfluoropentanoic acid (PFPeA) ND 94.7 98.0 ng/g 103 69 - 129 2 30☼
Perfluorohexanoic acid (PFHxA) 2.5 J 94.7 103 ng/g 106 71 - 131 1 30☼
Perfluoroheptanoic acid (PFHpA) ND 94.7 104 ng/g 110 71 - 131 0 30☼
Perfluorooctanoic acid (PFOA) 6.0 J 94.7 99.4 ng/g 99 72 - 132 5 30☼
Perfluorononanoic acid (PFNA) 3.7 J 94.7 111 ng/g 113 73 - 133 12 30☼
Perfluorodecanoic acid (PFDA) 15 94.7 112 ng/g 102 72 - 132 10 30☼
Perfluoroundecanoic acid
(PFUnA)
3.3 J 94.7 108 ng/g 111 66 - 126 2 30☼
Perfluorododecanoic acid
(PFDoA)
3.7 J 94.7 112 ng/g 115 71 - 131 17 30☼
Perfluorotridecanoic acid
(PFTriA)
ND F1 F2 94.7 104 F2 ng/g 110 71 - 131 66 30☼
Perfluorobutanesulfonic acid
(PFBS)
16 83.8 105 ng/g 107 69 - 129 2 30☼
Perfluoropentanesulfonic acid
(PFPeS)
ND 88.9 98.6 ng/g 111 66 - 126 4 30☼
Perfluorohexanesulfonic acid
(PFHxS)
ND 86.2 88.4 ng/g 94 62 - 122 0 30☼
Perfluorooctanesulfonic acid
(PFOS)
95 B 87.9 178 ng/g 94 68 - 141 5 30☼
Perfluorononanesulfonic acid
(PFNS)
ND 91.0 97.4 ng/g 107 72 - 132 1 30☼
Eurofins TestAmerica, Sacramento
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QC Sample ResultsJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: SC0127 MSDLab Sample ID: 320-69429-1 MSDMatrix: Solid Prep Type: Total/NAAnalysis Batch: 460135 Prep Batch: 459644
Perfluorodecanesulfonic acid
(PFDS)
2.4 J I 91.3 84.4 ng/g 90 71 - 131 4 30☼
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
13C4 PFBA 25 - 150
Isotope Dilution
64
MSD MSD
Qualifier Limits%Recovery
6213C5 PFPeA 25 - 150
7613C2 PFHxA 25 - 150
8613C4 PFHpA 25 - 150
9913C4 PFOA 25 - 150
9113C5 PFNA 25 - 150
10213C2 PFDA 25 - 150
7613C2 PFUnA 25 - 150
2713C2 PFDoA 25 - 150
3313C2 PFTeDA 25 - 150
6913C3 PFBS 25 - 150
7618O2 PFHxS 25 - 150
8013C4 PFOS 25 - 150
Method: D 2216 - Percent Moisture
Client Sample ID: SC0127Lab Sample ID: 320-69429-1 DUMatrix: Solid Prep Type: Total/NAAnalysis Batch: 457422
Percent Moisture 79.3 79.8 % 0.7 20
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Percent Solids 20.7 20.2 % 3 20
Eurofins TestAmerica, Sacramento
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QC Association SummaryJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
LCMS
Prep Batch: 459644
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid SHAKE320-69429-1 SC0127 Total/NA
Solid SHAKE320-69429-2 SC0127 Dup Total/NA
Solid SHAKEMB 320-459644/1-A Method Blank Total/NA
Solid SHAKELCS 320-459644/2-A Lab Control Sample Total/NA
Solid SHAKE320-69429-1 MS SC0127 MS Total/NA
Solid SHAKE320-69429-1 MSD SC0127 MSD Total/NA
Analysis Batch: 460135
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 537 (modified) 459644320-69429-1 SC0127 Total/NA
Solid 537 (modified) 459644320-69429-2 SC0127 Dup Total/NA
Solid 537 (modified) 459644MB 320-459644/1-A Method Blank Total/NA
Solid 537 (modified) 459644LCS 320-459644/2-A Lab Control Sample Total/NA
Solid 537 (modified) 459644320-69429-1 MS SC0127 MS Total/NA
Solid 537 (modified) 459644320-69429-1 MSD SC0127 MSD Total/NA
General Chemistry
Analysis Batch: 457422
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid D 2216320-69429-1 SC0127 Total/NA
Solid D 2216320-69429-2 SC0127 Dup Total/NA
Solid D 2216320-69429-1 DU SC0127 Total/NA
Eurofins TestAmerica, Sacramento
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Lab ChronicleClient: Waste Options Nantucket LLC Job ID: 320-69429-1Project/Site: PFAS, MassDEP
Client Sample ID: SC0127 Lab Sample ID: 320-69429-1Matrix: SolidDate Collected: 01/27/21 11:30
Date Received: 01/28/21 10:30
Analysis D 2216 TCS02/01/21 10:521 TAL SAC457422
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: SC0127 Lab Sample ID: 320-69429-1Matrix: SolidDate Collected: 01/27/21 11:30
Percent Solids: 20.7Date Received: 01/28/21 10:30
Prep SHAKE HJA02/08/21 06:41 TAL SAC459644
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.54 g 10.00 mL
Analysis 537 (modified) 1 460135 02/09/21 18:16 S1M TAL SACTotal/NA
Client Sample ID: SC0127 Dup Lab Sample ID: 320-69429-2Matrix: SolidDate Collected: 01/27/21 11:30
Date Received: 01/28/21 10:30
Analysis D 2216 TCS02/01/21 10:521 TAL SAC457422
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: SC0127 Dup Lab Sample ID: 320-69429-2Matrix: SolidDate Collected: 01/27/21 11:30
Percent Solids: 21.4Date Received: 01/28/21 10:30
Prep SHAKE HJA02/08/21 06:41 TAL SAC459644
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.51 g 10.00 mL
Analysis 537 (modified) 1 460135 02/09/21 18:43 S1M TAL SACTotal/NA
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
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Accreditation/Certification SummaryClient: Waste Options Nantucket LLC Job ID: 320-69429-1Project/Site: PFAS, MassDEP
Laboratory: Eurofins TestAmerica, SacramentoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
Alaska (UST) 17-020State 01-20-21 *
ANAB Dept. of Defense ELAP L2468 01-20-24
ANAB Dept. of Energy L2468.01 01-20-21 *
ANAB ISO/IEC 17025 L2468 01-20-21 *
Arizona State AZ0708 08-11-21
Arkansas DEQ State 88-0691 06-17-21
California State 2897 01-31-22
Colorado State CA0004 08-31-21
Connecticut State PH-0691 06-30-21
Florida NELAP E87570 06-30-21
Georgia State 4040 01-29-22
Hawaii State <cert No.> 01-29-22
Illinois NELAP 200060 03-17-21
Kansas NELAP E-10375 02-01-21 *
Louisiana NELAP 01944 06-30-21
Maine State CA00004 04-14-22
Michigan State 9947 01-29-21 *
Nevada State CA000442021-2 07-31-21
New Hampshire NELAP 2997 04-18-21
New Jersey NELAP CA005 06-30-21
New York NELAP 11666 04-01-21
Ohio State 41252 01-29-22
Oregon NELAP 4040 01-29-21 *
Pennsylvania NELAP 68-01272 03-31-21
Texas NELAP T104704399-19-13 06-01-21
US Fish & Wildlife US Federal Programs 58448 07-31-21
USDA US Federal Programs P330-18-00239 07-31-21
Utah NELAP CA000442019-01 02-28-21
Vermont State VT-4040 04-16-21
Virginia NELAP 460278 03-14-21
Washington State C581 05-05-21
West Virginia (DW) State 9930C 12-31-21
Wisconsin State 998204680 08-31-21
Wyoming State Program 8TMS-L 01-28-19 *
Eurofins TestAmerica, Sacramento
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
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Method SummaryJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL SAC
ASTMD 2216 Percent Moisture TAL SAC
SW846SHAKE Shake Extraction with Ultrasonic Bath Extraction TAL SAC
Protocol References:
ASTM = ASTM International
EPA = US Environmental Protection Agency
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL SAC = Eurofins TestAmerica, Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600
Eurofins TestAmerica, Sacramento
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Sample SummaryJob ID: 320-69429-1Client: Waste Options Nantucket LLC
Project/Site: PFAS, MassDEP
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
320-69429-1 SC0127 Solid 01/27/21 11:30 01/28/21 10:30
320-69429-2 SC0127 Dup Solid 01/27/21 11:30 01/28/21 10:30
Eurofins TestAmerica, Sacramento
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Login Sample Receipt Checklist
Client: Waste Options Nantucket LLC Job Number: 320-69429-1
Login Number: 69429
Question Answer Comment
Creator: Thompson, Sarah W
List Source: Eurofins TestAmerica, Sacramento
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact. 1462290, 1462291
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
N/ASample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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