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! UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION III

•*L Pool*-0 CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD

ANNAPOLIS, MARYLAND 21401(301) 266-9180

f-m?DATE : September 18, 1990

SUBJECT: Organic Data Validation for the Dupont Newport SiCase 14442

FROM : Dan SlizysRegion III Acting ES.AT DPO (3ES23)

TO : Randy SturgeonRegional Project Manager (3HW25)

THRU : Patricia J. Krantz, ChiefQuality Assurance Branch (3ES23)

Attached is the organic data review for the Dupont NewportSite (Case 14442) completed by the Region III EnvironmentalServices Assistance Team (ESAT) contractor under the directionof Region III ESD.

If you have any questions regarding this review, please callme.

Attachment

cc: Bruce Beach, Dynamac

TID File: O39OO817 Task 2083

AR309236

2568A RIVA ROADSUITE 300ANNAPOLIS, MD 21401

\->,A PHONE: 301-266-9887L •"• m ——MA.\Au£=S

DATE: 14 September 1990

SUBJECT: ORGANIC DATA VALIDATION FOR CASE 14442Site: Dupont Newport

FROM: DOUG McINNES ~ )J DON O'BRIENORGANIC DATA REVIEWER ORGANIC DATA REVIEWER

TO: DAN SLIZYSESAT DEPUTY PROJECT OFFICER (acting)

THRU: RICHARD DRESSER .' >vESAT TEAM MANAGER

OVERVIEW

Case 14442 consisted of two (2) water samples and four (4) soilsamples, submitted to NYTEST for volatile, semivolatile, andpesticide/PCB analyses. Included in this case was one (1) rinsateblank, and one (1) trip blank. Both blanks were analyzed forvolatiles only, as documented in the telephone logs included inAppendix F. The samples were analyzed as a Contract LaboratoryProgram (CLP) Routine Analytical Service (RAS).

SUMMARY

All samples were successfully analyzed for all target compounds.All instrument and method sensitivities were according to theContract Laboratory Program (CLP) Routine Analytical Service (RAS)protocol.

MINOR PROBLEMS

o Several compounds failed precision criteria-for initial and/orcontinuing calibrations. Quantitation limits for thesecompounds were qualified "UJ", and reported results werequalified "J", except when superseded by the "B" qualifier,denoting blank contamination. (See Appendix F).

of 3

NOTES

o The maximum concentration of contaminants found in the fieldblanks or method blanks are summarized in the table below. Allsamples with concentrations of common laboratory contaminantsless than ten times (<10X), or uncommon laboratory contaminantsless than five times (<5X) the blank concentration have beenqualified "B" in the data summary. (See Appendix F).

____Compound____ Concentration______

methylene chloride * 6 fJ.g/L or jug/Kgchloroform 10 M<?/L or M<?/Kg

* - Common Laboratory Contaminant

o The MS/MSD analyses had compounds other than the spikingcompounds or blank contaminants present. Following is a tableof results and precision estimates for these non-spikedcompounds:

MS/MSD Non-Spiked Compounds

______Concentration fug/Kg)Compound CDR60 CDR60MS CDR60MSD %RSD

di-n-butylphthalate 1400 2000 1500 20bis(2-ethylhexyl) 190 J 510 650 52

phthalate

%RSD - Percent Relative Standard Deviation

o The pesticide/PCB confirmation column linearity check hadrelative percent difference values for aldrin and 4,4'-DOTgreater than the ten percent (10%) QC limit. The laboratorynoted this problem in a telephone log to EPA, and was instructedthat no re-analysis of the samples was required. No data wasqualified based on this problem. (See Appendix F).

o The percent difference (%D) between the initial and continuingquantitation column calibrations for the pesticide compoundendosulfan II was slightly greater than the fifteen percent(15%) QC limit for the INDA standard analyzed on 07/28/90 at0256. Since no samples were analyzed after this standard, nodata has been affected. (See Appendix F).

of 3

o The reported Tentatively Identified compounds (TIC's) inAppendix D have been reviewed and accepted during datavalidation. (See Appendix D).

o During the initial volatiles calibrations the target compoundbenzene and the surrogate toluene-dS were noted by thelaboratory as having saturated the detector. (See theanalytical narrative included in Appendix F) . Due to thisproblem, these points are not present on the calibrationsummary, and were not used in quantitating reported results.The only effect this problem could have on the data is to reducethe calibration range for these two compounds, and since neithercompound was found at high concentrations for any sample, nodata has been affected. (See Appendix F).

All data for case 14442 were reviewed in accordance with theFunctional Guidelines for Evaluating Organic Analyses withModifications for use within Region III. The text of this reportaddresses only those problems affecting usability.

ATTACHMENTS

1) Appendix A - Glossary of Data Qualifiers2) Appendix B - Data Summary. These include:

(a) All positive results for target compounds with qualifiercodes where applicable.

(b) All unusable detection limits (qualified "R").3) Appendix C - Results as Reported by the Laboratory for All,

Target Compounds4) Appendix D - Reviewed and Corrected Tentatively Identified

Compounds5) Appendix E - Organic Regional Data Assessment Summary6) Appendix F - Support Documentation

DCN - DM009A06

SR309239

Appendix A

Glossary of Data Qualifiers

GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)

CODES, RELATING TO IDENTIFICATION(confidence concerning presence or absence of compounds):

IT = Not detected. The associated number indicates approximate sampleconcentration necessary to be detected.

(NO CODS) = Confirmed identification.

B = Net detected substantially above the level reported in laboratory or fieldblanks.

R = Unreliable result. Analyte may or may not be present in the sample.Supporting data necessary to confirm result.

N = Tentative identification. Consider present. Special methods may be neededto confirm its presence or absence in future'sampling efforts.

CODES RELATED TO QUANTITATION(can be used for both positive results and sample cuantitaticnlimits):

J « Analyte present. Reported value may not be accurate or precise.

X — Analyte present. Reported value may be biased high. Actual value isexpected to be lower.

L * Analyte present. Reported value may be biased low. Actual value isexpected to be higher.

UJ - Not detected, cuantitation limit may be inaccurate or imprecise.

UL = Not detected, cuantitation limit is probably higher.

OTHER CODES

Q » No analytical result.

revised 01/90

Appendix B

Data Summary Forms

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Appendix C

Results as Reported by the Laboratoryfor all Target Compounds

flR3'0925!

; 1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _____________

I If CDE56 |

Lab Name: NYTEST ENV INC_________ ConCract: 63-U3-0049 I____________I

Lab Code: NYTEST Case No.: 14442 SAS No.: ______ SOG No.: CDE55

Matrix: (soil/uatsr) UATER Lab Sample ID: 5256308__

Sample ut/vol: S.0 (g/mL) MJ._ Lab File ID: D2304

Level: (lou/med) LOU Date Received: 07/11/90

% Moisture: not dec. ___ Date Analyzed: 07/12/90

Column: (pack/cap) PACK Dilution Factor: 1.0___

i,D

LDD0

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L

1| 74-37-3 —————| 74-83-9 —————| 75-01-4 —————| 75-00-3 ————1 75-39-2 ————| 67-S4-1 ————| 75-15-0 —————| 75-35-4 —————| 75-34-3 —————| 540-59-0 ————| 67-56-3 —————| 107-06-2 ————1 TO n-5 -3

| 71-55-6 —————| 56-23-5 ————| 108-05-4 ————| 75-27-4 —————1 TO O T C

| 10061-01-5 ——| 79-01-6 —————| 124-48-1 ————| 79-00-5 —————| 71-43-2 —————1 10061-02-6 ——| 75-25-2 ————| 108-10-1 ————| 591-78-6 ————| 127-18-4 ————I TO i.i^rt ... =; ........ ..| 108-88-3 ————| 108-90-7 ————| 100-41-4 ————| 100-42-5 ————1 1330-20-7 ———1

—— Chlorome thane—— Srornome thane

Vinyl Chloride—— Chio roe thane— f-Methylene Chloride—— Acetone—— Carbon Oisulfide—— 1.1-Oichloroethene—— 1.1-0 ichlo roe thane—— 1,2-Dichloroethene (total).—— Chloroform—— 1.2-0 ichlo roe thane—— 2-Butanone—— 1,1,1-Tr ichlo roe thane—— Carbon Tetrachloride—— Vinyl Acetate—— Bromodichlorome thane—— 1.2-Dichlorooropane—— cis-1, 3-D ichlo ropropene—— Trichloroethene—— Dibromochlorome thane—— 1.1.2-Tr ichlo roe thane—— Benzene—— Trans-1 , 3-Qichloropropene ___—— Bromoform—— 4-Methyl-2-Pentanone—— 2-Hexanone—— Tetrachloroethene—— 1,1,2,2-Tetrachloroethane ___—— Toluene—— Chlo robenzene—— Ethylbenzene—— Styrene

Xvlenes (total)

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flR309252 000032

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1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _____________

I I| CDE57 |

Lab Name: NYTEST ENV _INC__________ Contract: S8-U8-0049 |_____________|

Lab Code: NYTEST, Case No.: 14442 SAS No.: ______ SDG No.: CDE56_

Matrix: (soil/water) SOIL Lab Sample ID: 5256001_____

Sample wt/vol: 5.0 (g/mL) G__ Lab File ID: D2317____

Level: (Icu/med) LOW Date Received: 07/11/90

% Moisture: not dec. _14 Date Analyzed: 07/13/90


CONCENTRATION UNITS:CAS NC. COMPOUND (ug/L or ug/Kg) UG/KG

74-37-3 ————74-33-3 —————75-01-4 ————75-00-3 ————75-09-2 ————67-64-1 —————75-15-3 ————75-35-4 —————75-34-3 ————540-53-0 ————67-66-3 ————107-0S-2 ————78-93-3 ————71-55-6 ————56-23-5 ————108-05-4 ————75-27-4 ————78-87-5 —————10061-01-5 ——79-01-6 ————124-48-1 ———79-00-5 ————71-43-2 ————10061-32-6 ——75-25-2 ————108-10-1 ———591-78-6 ———127-18-4 ————

108-88-3 ———108-90-7 ———100-41-4 ————| 100-42-5 ———1330-20-7 ——

1

—— Chlorome thane—— Bromcme thane—— Vinvl Chloride—— Chlo roe thane—— Methylene Chloride—— Acetone—— Carbon Oisuifide—— 1.1-Oichloroethene—— 1 , 1-Oichloroethane—— 1,2-Oichloroethene (total) __—— Chloroform—— 1,2-Dichlo roe thane—— 2-Butanone—— 1 . 1 . 1-Trichloroethane—— Carbon Tetrachloride—— Vinyl Acetate—— B romod ion lorome thane—— 1 . 2-DichloroDrooane—— cis-1.3-0ichloropropene—— Tr ichlo roe thene—— Oibromochlorometnane—— 1 , 1 . 2-Trichloroethane—— Benzene—— Trans-1 . 3-0 ichlo r op ropene——— B r orno f o rm—— 4-Methyl-2-Pentanone——— 2— Hexanone—— Tetrachlo roe thene——— 1 ,1,2, 2-Te trachloroethane ___——— Toluene——— Chlo robenzene—— Ethvlbenzene——— Stvrene—— Xvlenes (total)

121212126

126666661266

12666666666

12126666666

1IUIU|u|u|u|u|u|u|u|u|u|u|u|u|u|u|u|u|u|u|u|u|uiu|u|u|u|u|u|u|uiu|u|u1


AR309253 000044

IB EPA SAMPLE NO.SEMZVOLATZLE ORGANICS ANALYSIS DATA SHEET ____________

I| CDE57 |

Lab Name: NYTEST ENV INC__________ Contract: 68-W8-0049 I___________

Bn

Lab Code: NYTEST Case No.: 14442 SAS No.: ______ SDG No.: CDE56

Matrix: (soil/water) SOIL Lab Sample ID: 5256001

Sample wt/vol: 30.0 (g/mL) G__ Lab File ID: B1345

Level: (low/med) LOW Date Received: 07/11/90

% Moisture: not dec. _14 dec. ___ Date Extracted: 07/13/90

Extraction: (SepF/Cont/Sonc) SONC Date Analyzed: 08/02/90

i ; GPC Cleanup: (Y/N) N_ pH: 7.9 Dilution Factor: 1.00

CONCENTRATION UNITS:U CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG

C

l if!

108-95-2—————Phenol_________\__________\ 380 |U111-44-4—————bis (2-Chlo re ethyl) Ether____| 3S0 |U95-57-8——————2-Chlorophenol___________| 380 |U541-73-1—————1,3-Dichlorccenzene_______| 380 |U106-46-7—————1,4-Dichlorocenzene_______| 3S0 |U100-51-6—————Benzyl Alcohol___________| 380 |U95-50-1——————1,2-Dichlorobenzene_______| 380 |U95-48-7——————2-Methylphenol__^_________| 380 |U39638-32-9————bis (2-Chloroisopropyl) Ether_| 380 |U106-44-5——————4-Methylphenoi___________| 380 |U621-64-7—————N-Nitroso-Di-n-?ropylamine__| 380 |U67-72-1——————Hexachloroethane_________| 380 |U98-95-3——————Nitrobenzene____________| 380 |U78-59-1——————Isophorone_____________| 380 |U88-75-5——————2-Nitrophenol____________| 380 |U105-67-9—————2,4-Dimethylphenol________| 380 |U65-85-0——————Benzoic Acid_____________| 1900 |U111-91-1——————bis(2-Chloroethoxy)Methane__| 380 |U120-83-2——————2,4-Dichlorophenol________| 380 |U120-82-1—————1,2,4-Trichlorobenzene_____| 380 |U91-20-3——————Naphthalene_____________| 380 |U106-47-8—————4-Chloroaniline__________| 380 |U87-68-3——————Hexachlorobutadiene_______| 380 |U59-50-7——————4-Chloro-3-Methylphenol____| 380 |U91-57-6——————2-Methylnaphthalene_______| 130 |J77-47-4——————Hexachlorocyclopentadiene__| 380 |U88-06-2——————2,4,6-Trichlorophenol______| 380 |U95-95-4——————2,4,5-Trichlorophenol______| 1900 |U91-58-7——————2-Chlofonaphthalene_________\ 380 |U88-74-4——————2-Nitroaniline___________| 1900 |U131-11-3—————Dimethyl Phthalate________| 380 |U208-96-8—————Acenaphthylene___________i 380 |U606-20-2—————2,6-Dinitrotoluene________I 380 |U_________________________I_______I__!

FORM I SV-1 1/87 Rev.

OOC1SS

1C EPA SAMPLE NO.SEMTVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

I| CDE57 |

Lab Name: NYTEST ENV INC ________ Contract: 68-W8-0049 |

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SDG No.: CDE56

Matrix: (soil/water) SOIL Lab Sample ID: 5256001 ___

Sample wt/vol: 30.0 (g/mL) G __ Lab File 3D: B1345 ____

Li




GPC Cleanup: (Y/N) N_ pH: 7.9 Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q

99-09-2——————3-Nitroaniline.83-32-9——————Acenaphthene__51-28-5——————2,4-Dinitrophenol_100-02-7—————4-Nitrophenol___

-Dibenzofuran121-14-2—————2,4-Dinitrotoluene_84-66-2——————Diethylphthalate_| 7005-72-3—————4-Chlorophenyl-phenylether_____86-73-7——————Zluorene_____100-10-6—————4-Nitroaniline

f • | 534-52-1———•——4,6-Dinitro-2-Methylphenol__86-30-6——————N-Nitrosodiphenylamine (1)_101-55-3—————4-Bromophenyl-phenylether_118-74-1—————Hexachlorobenzene________87-86-5——————Pentachlorophenol_______85-01-8——————Phenanthrene___________120-12-7—————Anthracene_____________84-74-2——————Di-n-Butylphthalate______206-44-0—————Fluoran thene___________129-00-0—————Pyrene______;______________85-68-7——————Butylbenzylphthalate_____91-94-1——————3,3' -D ichlo robenzidine____56-55-3——————Benzo (a) Anthracene________218-01-9—————Chrysene______________117-81-7—————bis (2-Ethylhexyl) Phthalate__117-84-0—————Di-n-Octyl Phthalate_____205-99-2—————Benzo (b)Fluoranthene_____207-08-9—————Benzo (k)Fluoranthene_______50-32-8--—————Benzo (a) Pyrene__________

39-5—————Indeno (1,2,3-cd} Pyrene_53-70-3——————Dibenz (a, h) Anthracene_191-24-2—————-Benzo (g,h, i) Perylene_

I1900 |U380 |U1900 |U1900 |U380 |U380 |U380 |U380 |U380 |U1900 |U1900 |U380 It-380 |U380 IU1900 |U140 |J380 |U

1900 |380 |U380 It-380 iu770 |U380 |U380 |U220 |J380 |U380 |U380 |U380 |U380 |U380 |U380 |U

(1) - Cannot be separated from Diphenylamine

FORHisv-2 SR309255 1/87Rev-000189

10 EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SH^ET

Q

i i| CDE57 |

Lab Name: NYTEST ENV INC_________ Contract: 68-4J8-0049 |______________|



Sample wt/vol: 30__ (g/mL) _5__ Lab File ID: _________

Level: (low/med) LOU1 Date Received: 07/11/90


Extraction: (Sepr/Cont/Sonc) SONG Date Analyzed: 07/27/90

GPC Cleanup: (Y/N) N_ pH: 7.0 Dilution Factor: I_____

i;GP

...

0*.

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) US/KG

1| 319-34-6 ————| 319-35-7 ————| 319-36-8 ————| 58-89-9 ——— —| 76-44-8 —————| 309-00-2 ————| 1024-57-3 ———| 959-98-8 ————| 60-57-1 —————| 72-55-9 —————| 72-20-8 —————| 33213-65-9 ——| 72-54-8 —————| 1031-07-8 ———| 50-29-3 —————| 72-43-5- ————| 53494-70-5 — -| 5103-71-9 ———| 5103-74-2 ———| 8001-35-2 ———| 12674-11-2 ——| 11104-28-2 ——| 11141-16-5 ——| 53469-21-9 ——| 12672-29-6 ——| 11097-69-1 ——| 11096-82-5 ——1

—— aloha-BHC—— beta-3HC

delta BHC— — aamma-BHC (Lindane)—— Heptachlor—— Aldrin—— Heptachlor epoxide—— Endosulfan I—— Oieldrin—— 4. 4 '-DOE—— Endrin—— Endosulfan II—— 4 .4 '-ODD—— Endosulfan sulfate—— 4. 4 '-DOT—— Methoxychlor—— Endrin ketone—— aloha-Chlordane—— oamma-Chlordane—— Toxaohene—— Aroclor-1016—— Aroclor-1221—— Aroclor-1232—— Aroclor-1242—— Aroclor-1248—— Aroclor-1254—— Aroclor-1260

11 9.31 9.31 9.31 9.31 9.31 9.31 9.31 9.31 191 191 19I 191 191 19! 19I 931 191 93I 931 1901 93I 93I 931 93I 590I 190I 1901

1 1|u 1|u I|u Ilu 1|u I|U |iu I|u 1|u I|u 1|u I|u 1lu I|u Ilu Ilu Ilu I|u 1lu 1|u 1lu I|u Ilu I|u 11 1lu Ilu I1 1

FORM I PEST 1/87 Rev.AR309256 000376


I ————————————— I| CDE58 |

Lab Name: NYTEST ENV INC __________ Contract: 68-U8-0049 | _____________ |



Sample wt/vol: 5.0 (g/mL) J __ Lab File ID: D2318

Level: (low/med) LOU Date Received: 07/11/90


Column: (pack/cap) PACK_ Dilution Factor: 1.0___

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG

74-37-3———————Chloromethane____74-33-9———————Bromome thane_____75-31-4———————Vinyl Chloride •75-00-3———————Chlo roe thane_____75—39-2————————Matnylene Chloride_67-54-1———————Ac a tone__________75-15-0———————Carbon Oisulfide__75-35—4———————1. l-0ichloroethene_75-34-3———————1,1-D ichlo roe thane

13 |U13 |U13 |U13 |U6 |U

13 |U6 |U6 |U6 |U6 |U6 |U6 |U13 |U6 |U6 |U

13 |U6 |U6 |U

10061-01-5————cis-l,3-0ichloropropene____] 6 |U79-01-6———————Trichloroethen.e___________| 6 |U

IU|U|U|U|U|u|ululu|u|u|u|u|u

540-59-0——————1,2-Oichlo roe thene (total).67-56-3———————Chloroform_____________107-06-2——————1,2-Oichloroethane______78-93-3———————2-3utanone_____________71-55-6———————1.1,1-Trichloroe thane____56-23-5———————Carbon Tetrachloride_____108-05-4——————Vinyl Acetate___________75-27-4———————Brcmodichlorome thane_____78-87-5———————1,2-Dichloropropane______

124-48-1 ————

10061-02-6 ——TC * e ••»

108-10-1 ————591-78-6 ————127-13-4 ————79-34-5 —————108-88-3 ————108-90-7 ————100-41-4 ————100-42-5 ————1330-20-7 ———

—— Dibromochlorome thane—— 1.1.2-Tr ichlo roe thane—— Benzene—— Trans-1 , 3-Dichloropropene ___—— Bromoform

—— 2-Hexanone—— Tetrachlo roe thene—— 1 ,1,2, 2-Te trachloroethane ___—— Toluene—— Chlo robenzene—— Ethylbenzene—— Styrene—— Xylenes (total)

66666

13136666666


SR309257 000052-'

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

I| CDE53 |

Lab Name: NYTEST ENV INC _________ Contracts 68-W8-0049 |. ___________



Sample wt/vol: 30.0 (g/mL) G __ Lab File ID: B1346

nLevel: (low/med) LOW Date Received: 07/11/90



GPC Cleanup: (Y/N) N_ pH: 7.6 Dilution Factor: 1.00__


i.G

I I108-95-2 —————— Phenol __________________ | 420 |U111-44-4 ————— bis (2-Chloroethyl) Ether ____ | 420 |U95-57-8 —————— 2-Chlorophenol ___________ | 420 |U541-73-1 ————— 1,3-Dichlorobenzene _______ | 420 |U106-46-7 ————— 1,4-Dichlorobenzene _______ | 420 |U100-51-S ————— Benzyl Alcohol ____________ \ 420 |U95-50-1 —————— 1,2-Dichlorobenzene _______ | 420 |U95-48-7 —————— 2-Methylphenol ___________ | 420 |U

420 |U420 |U420 |U420 |U420 |U420 JU420 |U420 |U2000 |U420 |U420 |U420 |U420 |U420 |U420 |U420 |U420 |U420 |U420 JU2000 |U420 |U

39638-32-9————bis (2-Chloroisopropyl) Ether_106-44-5—————4-Methylphenol_________~_621-64-7—————N-Nitroso-Di-n-Propylamine__67-72-1——————Hexachloroe thane_________98-95-3——————Nitrobenzene____________78-59-1——————Isophorone______________88-75-5——————2-Nitrophenol____________105-67-9—————2,4-Dimethylphenol_______65-85-0———'•-——Benzole Acid____________111-91-1—————bis (2-Chloroethoxy JMethane__120-83-2—————2,4-Dichlorophenol ________120-82-1—————1,2,4-Trichlo robenzene_____91-20-3——————Naphthalene_____________106-47-8—————4-Chloroaniline__________87-68-3——————Hexachlorobutadiene_______59-50-7——————4-Chloro-3-Methylphenol____91-57-6——————2-Methylnaphthalene________77-47-4——————Hexachlorocyclopentadiene___88-06-2——————2,4,6-Trichlorophenol_____95-95-4——————2,4,5-Trichlorophenol_____91-58-7——————2-Chloronaphthalene_______88-74-4——————2-Nitroaniline___________131-11-3—————Dimethyl Phthalate________208-96-8——————Acenaphthylene___________606-20-2—————2,6-Dinitro toluene________

2000 IU420 |U420 |U420 |U

FORM I SV-1 1/87 Rev. •'

flR309258 OOC226

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

I I| CDE58 |

Lab Name: NYTEST BNV INC________ Contract: 68-W8-0049 |___________|



Sample wt/vol: 30.0 (g/mL) G__ Lab File ID: B1346____






99-09-2———83-32-9 ———— -51-23-5 ———— -100-02-7 ——— -132-54-9 ———m-id-2 ——— .*-** £,

84-65-2 ———7005-72-3 —— -86-73-7 ———100-10-6 ——— •534-52-1 ———86-30-6 ——— -m_55_-3 ___

*ml *J •*!

118-74-1 ——— -Q~7_QC_C

85-01-8 ——— •120-12-7 ———84-74-2 ——— •206-44-0 ———129-00-0 ——— -QC ZT Q "T

91-94-1 ———— •56-55-3 ———218-01-9 ——— •117-81-7 ———117-84-0 ——— •*)AC QQ *}

207-08-9 ———CT/~, ••} *> Q50-32-8 ——— —1 9 - 9-5 __ —53-70-3 ———191-24-2 ———

—— 3-Nitroaniline—— Acenaphthene—— 2 , 4-Dinitroohenol- —— 4-Nitroohenol—— Dibenzofuran

—— Diethvlphthalate—— 4-Chlorophenyl-phenylether __—— Fluorene—— 4 -Nitro aniline—— 4, 6-Dinitro-2-Methylphenol __

—— 4-Bromophenyl-phenylether ___—— Hexachlorobenzene—— Pentachlorophenol—— Phenanthrene—— Anthracene—— Di-n-Butvlphthalate—— F luo ran thene—— Pyrene

—— 3 , 3 ' -Dichlorobenzidine—— Benzo (a) Anthracene—— Chrvsene—— bis ( 2-Ethylhexyl ) Phthalate—— Di-n-Octyl Phthalate—— Benzo (b ) Fluoranthene—— Benzo ( k) Fluoranthene—— Benzo ( a ) Pyrene—— Indeno (1,2, 3-cd) Pyrene—— D ibenzf a, h) Anthracene—— Benzo (g,h,i)Perylene

20004202000200042042042042042020002000420 .420420200042042015004204204208404204201000420420420420420420420

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUiu|u1iuiuiuiuiuiu1iuiuiu|Uiu|uiu1

(1) - Cannot be separated from Diphenylaraine

FORM I SV-2 1/87 ReV<

000227

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____________

I I| CDE58 |

Lab Name: NYTEST ENV INC_________ Contract: 68-U8-0049 I____________I



Sample wt/vol: 3Q __ (g/mL) J3 __ Lab File ID: _______

n Level: (low/med) LOU Date Received: 07/11/90

% Moisture: not dec. _ 21 dec. ___ Date Extracted: 07/13/90I

Extraction: (SepF/Cont/Sonc) SONG Date Analyzed: 07/27/90. 3

-J GPC Cleanup: (Y/N) N _ pH : 7.0 Dilution Factor: J. ______

Cr~>U

f 1

y


| 319-84-6 ———1 w •-. y o 3 /| OiJ OD~"U"*

| 75-44-8 ————[ 339-00-2 — ——| 1324-57-3 ——[ 959-98-8 ———| 63-57-1 ——— —| 72-55-9 ————| 72-20-8 —— —| 33213-65-9 —| 72-54-8 ————I 1 t*'}*! f?t 7 P

| 50-29-3 ————| 72-43-5 ————| 53494-70-5 —| 5103-71-9 ——| 5103-74-2 ——| 8001-35-2 ——| 12674-11-2—| 11104-28-2 —| 11141-16-5 —| 53469-21-9 —| 12672-29-6 —| 11097-69-1 —| 11096-82-5 —1

—— alcha-BHC——— beta-BHC

~j.~T*--» our*

——— qamma-BHC (Lindane)——— Heptachlor

Aldrin— — Heptachlor eooxide——— Endosulfan I——— Dieldrin——— 4. 4 '-DOE——— Endrin——— Endosulfan II——— 4, 4 '-ODD——— Endosulfan sulfate——— 4 . 4 ' -DOT——— Methoxychlor——— Endrin ketone——— alpha-Chlordane——— qanma-Chlordane——— Toxaohene——— Aroclor-1016——— Aroclor-1221——— Aroclor-1232——— Aroclor-1242——— Aroclor-1248——— Aroclor-1254——— Aroclor-1260

101010101010101020202020 '202020

10020100100200100100130100100200200

1lu|ulu|u|u|ulu|ulu|ulu|u|u|ulu|ulu|ulu|ulu|ulu|ulululu1

FORM I PEST __R3flC)9Cn 1/87 RevAR30926000031

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______________

I| COE59 |

Lab Name: NYTEST ENV INC__________ Contract: 63-UJ8-0049 I_____________

Lab Code: NYTEST Case No.: 14442._ SAS No.: ______ SDG No.: CDE56_

Matrix: (soil/water) SOIL Lab Sample ID: 5256003__

Sample wt/vol: 5.0 (g/mL) G__ Lab File ID: D2319


% Moisture: not dec. _23 Data Analyzed: 07/13/90



| 74-37-3 ————| 74-83-9 — ———| 75-01-4 — ———| 75-00-3 ——— —| 75-09-2 ————[ 67-64-1 — ———| 75-15-0 ————| 75-35-4 —————| 75-34-3 —— — —

| 67-66-3 ————| 107-06-2 —— —| 78-93-3 ————| 71-55-6 —————| 56-23-5 ————| 108-05-4 ————| 75-27-4 ————| 78-87-5 —————| 10061-01-5 ——| 79-01-6 —————| 124-48-1 ———| 79-00-5 —————| 71-43-2 ————| 10061-02-6 ——| 75-25-2 ————| 108-10-1 ———| 591-78-6 ———| 127-18-4 ————

| 108-88-3 ————| 108-90-7 ———| 100-41-4 ————| 100-42-5 ———| 1330-20-7 ——1

—— Chlorome thane—— Srcmomethane—— Vinyl Chloride—— Chlo roe thane—— Methylene Chloride—— Acetone—— Carbon Oisulfide—— 1.1-0 ichlo roe thene—— 1.1-0 ichlo roe thane—— 1.2-Oichloroethene (total)—— Chloroform—— 1.2-0 ichlo roe thane—— 2-Butanone—— 1.1.1-Trichloroethane—— Carbon Tetrachloride—— Vinyl Acetate—— Bromodichlorome thane—— 1.2-Dichloroorooane——— cis-1. 3-0 ichlo ropropene—— Tr ichlo roe thene—— Oibromochlorome thane—— 1 . 1 . 2-Tr ichlo roe thane—— Benzene—— Trans-1 ,3-Oichloropropene ___—— B r omo f o rm—— 4-Methyl-2-Pentanone——— 2-Hexanone—— Tetrachlo roe thene——— 1 .1.2. 2-Te trachloroe thane—— Toluene——— Chlo robenzene—— Ethvlbenzene—— Styrene—— Xvlenes (total)

131313136

136666661366

13666666666

13136666666

1lu|ulu|u|u

lululululululu|u|u|ulululu|ulu|ululululululululu|ululu|u1


flR30926l OOOQS2

IB EPA SAMPLE NO.SEMIVOLATZLE CRGANICS ANALYSIS DATA SHEET ____________

I I| CDE59 j

Lab Name: NYTEST ENV INC_________ Contract: 68-W8-0049 |___________|




D

CD


% Moisture: not dec. _23 dec. __ Date Extracted: 07/13/90


GPC Cleanup: (Y/N) N_ pH: 7_..8 Dilution Factor: 1.00


| 108-95-2—————Phenol________________i 111-44-4—————bis(2-Chlorcethyl)Ether_____| 95-57-8——————2-Chlorophenol__________| 541-73-1—————1,3-Dichlorobenzene______| 106-46-7—————1,4-Dichlorobenzene______| 100-51-6—————Benzyl Alcohol__________| 95-50-1——————1,2-Dichlorobenzene______| 95-48-7——————2-Methylphenol__________| 39638-32-9————bis (2-Chloroisopropyl)Ether_| 106-44-5—————4-Methylphenol__________621-64-7—————N-Nitroso-Di-n-?ropylamine__67-72-1——————Kexachloroethane________98-95-3——————Nitrobenzene___________78-59-1——————Isophorone____________88-75-5——————2-Nitrophenol___________| 105-67-9—————2,4-Dimethylphenol_I 65-85-0——————Benzoic Acid____111-91-1—————bis(2-Chloroethoxy)Methane_120-83-2—————2,4-Dichlorophenol______120-82-1—————1,2,4-Trichlorobenzene91-20-3——————Naphthalene___________106-47-8—————4-Chloroaniline________87-68-3——————Hexachlorobutadiene_____| 59-50-7-———4-Chloro-3-Methylphenol_| 91-57-6——————2-Methylnaphthalene____| 77-47-4—————Hexachlorocyclopentadiene_| 88-06-2——————2,4,6-Trichlorophenol___I 95-95-4——————2,4,5-Trichlorophenol___r j

f i I 91-58-7——————2-Chloronaphthalene88-74-4———————2-Nitroaniline| 131-11-3—————Dimethyl Phthalate.208-96-8—————Acenaphthylene_| 606-20-2—————2,6-DinitrotolueneI________________________——

430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U2100 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U430 |U

2100 |U430 |U2100 |U430 |U430 |U430 |U


. flR309262 OOC252

1C EPA SAMPLE NO.SEMIVOLATILE CRGANICS ANALYSIS DATA SHEET ____________

I I| CDE59 |

Lab Name: NYTEST ENV INC_________ Contract: 68-W8-0049 |____________|




LJ Level: (low/med) LOW Date Received: 07/11/90

D% Moisture: not dec. _23 dec. ___ Date Extracted: 07/13/90——

Extraction-. (SepF/Cont/Sonc) SONG Date Analyzed: 08/02/90

~> GPC Cleanup: (Y/N) N_ pK: 7.8 Dilution Factor: 1.00_ j

CONCENTRATION UNITS:CAS NO. CCMPOUND (ug/L or ug/Kg) UG/KG Q

rcc

99-09-2 ——— -83-32-9 ——— -51-28-5 ——— -100-02-7 ——— -132-54-9 —— -121-14-2 ——— -84-66-2 —— —7005-72-3 —— -86-73-7 ——— •100-10-6 ——— -jw*r *j ft j.QC_TC»_C ______

101-55-3 —— -118-74-1 ——— •87-86-5 ———85-01-8 ——— •120-12-7 ———84-74-2 ——— •206-44-0 ———129-00-0 ——— -85-68-7 ———91-94-1 ——— •56-55-3 ———218-01-9 ——— •117-81-7 ———117-84-0 ——— •205-99-2 ———207-08-9 ——— -50-32-8 ———193-39-5 ——— •53-70-3 —— -191-24-2 ——— -

—— 3-Nitroaniline- —— Acenaphther.s—— 2 . 4-Dinitrcchenol- —— 4-Nitrophenol—— Dibenzofuran- —— 2 , 4-Dinitro toluene—— Diethvlphthalate—— 4-Chlorophenyl-phenylether __—— Fluorene—— 4-Nitroaniline—— 4,S-Dinitro-2-Methylphenol __- —— N-Nitrosodiphenylamine ( 1 ) __—— 4-3romophenyl-phenylether __

—— Phenanthrene—— Anthracene

—— Fluoranthene—— Pyrene

—— 3 , 3 ' -Dichlorobenzidine-' —— Benzo ( a) Anthracene—— Chrysene—— bis ( 2-Ethylhexyl ) Phthalate __—— Di-n-Octyl Phthalate—— Benzo ( b ) Fluoranthene—— Benzo ( k) Fluoranthene—— Benzo ( a ) Pyrene—— Indeno (1,2, 3-cd) Pyrene—— Dibenz ( a , h ) Anthracene—— Benzo ( g, h , i ) Perylene

210043021002100430430430430430210021004304304302100430430

14004304304308604304301200430430430430430430430

1IUIUIUIUIUIUIUIUIU|uIUIUIUIUIUIUIU1IU|UIUiu|uiuiuiuiuiuiuiuiu1


FORM i sv-2 SR30926? 1/87 Rev'000253

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____________

I| COE59

Lab Name: NYTEST ENV INC______. Contract: S3-U8-0049 |_____________

Lab Code: NYTEST Casa No.: 14442 SAS No.: _____ SDG No.: CDE55


Sample wt/vol: 30 (g/mL) G___ Lab File ID: _______

Level: (low/med) LCU Data Received: 07/11/90


Extraction: (SepF/Ccnt/Sonc) SONC Date Analyzed: 07/27/90

GPC Cleanup: (Y/N) .N_ pH: 7.0 Dilution Factor: _1_____

y


1| 319-84-6 ————| 319-85-7 ————| 319-36-3 ————| 53-89-9 —————| 76-44-8 —————| 309-00-2 ————1 1 ffl^/1—— 7«n^—— _---

t nc n no o

|£T 1 C ™* -160— 5/ — 1 —————| 72-55-9 —————| 72-20-8 —————I 33213-65-9 ——| 72-54-8 —————| 1031-07-3 ———| 50-29-3 —————| 72-43-5 —————| 53494-70-5 ——| 5103-71-9 ———| 5103-74-2 ———| 8001-35-2 ———| 12674-11-2 ——| 11104-28-2 ——| 11141-16-5 ——| 53469-21-9 ——| 12S72-29-6 ——| 11097-69-1 ——| 11096-82-5 ——1

—— alpha-BHC—— beca-BHC—— delta-3HC—— qamma-BHC (Lindane)—— Heptachlor—— Aldrin—— Heotachlor epoxide—— Endosulfan I—— Oieldrin—— 4. 4 '-DOE—— Endrin—— Endosulfan II—— 4, 4 '-ODD—— Endosulfan sulfate—— 4. 4 '-DOT—— Methoxychlor—— Endrin ketone—— alpha-Chlordane—— qamma-Chlordane—— Toxaohene—— Aroclor-1016—— Aroclor-1221—— -Aroclor-1232—— Aroclor-1242—— Aroclor— 1248—— Aroclor-1254—— Aroclor-1260

10101010101010102121212121

' 212110021100100210100100100100100210210

1lu|u|uiulululululu|ulu|ulu|uluiulu|ulululululu|ulu|ulu1

11111111111111111111111111111

000393


I| CDE60 |

Lab Name: NYTEST ENV INC_________ Contract: 63-UJ8-0049 |____________



Sample wt/vol: 5.3 (g/mL) J3__ Lab File ID: D2320___



Column: (pack/cap) PACK Dilution Factor: 1.0f -H CONCENTRATION UNITS:

CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG

t :

r •I -4

0r

| 74-37-3 ————74-33-9 ————| 75-01-4 ———75-00-3 ————| 75-09-2 ———67-64-1 ————| 75-15-0 ———75-35-4 ————| 75-34-3 ———540-59-0 ———| 67-S6-3 ———| 107-06-2 ———1 " 7 O O*^ *^

| 71-55-6 ————| 56-23-5 ———| 108-05-4 ———| 75-27-4 ———1 TO O 7 n

| 10061-01-5-| 79-01-6 ———| 124-48-1 ——| 79_00_s ———| 71-43-2 ———| 10061-02-6—| 75-25-2 ———| 108-10-1 ———| 591-78-6 ——| 127-18-4 ———1 7T T4 5....J, .| 108-88-3 ———| 108-90-7 ——| 100-41-4 ———| 100-42-5 ——| 1330-20-7 —1

——— Chlorome thane——— Srcmcmethane——— Vinvl Chloride——— Chlo roe thane——— Methyiene Chloride——— Acatcne——— Carbon Oisulfida——— 1,1— 3 ichlo roe thene——— 1, 1-Oichloroethane——— 1,2-0 ichlo roe thene (total) __——— Chloroform——— 1 . 2-Oichlo roe thane——— 2-3utanone——— 1,1,1-Trichloroethane——— Carbon Tetrachloride——— Vinyl Acetate——— Bromod ichlo rome thane——— 1,2-Dichloropropane——— cis-1, 3-0 ichlo ropropene——— Tr ichlo roe thene——— Dibrcmochlo rome thane——— 1 , 1 ,2-Trichloroethane——— Benzene——— Trans-l,3-0ichlo ropropene ___——— B romoform— — 4-Methyl-2-Pentanone——— 2-Hexanone——— Tetrachloroe thene——— 1 ,1.2, 2-Te trachloroe thane——— Toluene——— Chlo robenzene——— Ethylbenzene——— Styrene——— Xylenes (total)

14141-i1-J7

147777771477

14777777777

14147777777

1lulululu]ululululululululululululuiu •|ululuiu|ululu|ulu|uiu|u|uiu|ulu


fiR309265000070

IB EPA SAMPLE NO.SEMIVOLATZLE ORGANICS ANALYSIS DATA SHEET ____________

| j| CDE60 |

Lab Name: NYTEST ENV INC________ Contract: 68-W8-0049 |___________




( iI *


% Moisture: not dec. _ 29 dec. ___ Date Extracted: 07/13/90• —— ——— ——————

Extraction: (SepF/Cont/Sonc) SONG * Date Analyzed: 08/02/90n; GPC Cleanup: (Y/N) N _ pH: 7.5 Dilution Factor: 1.00


D

i ;

t f*Q QC O

111-44-4 ———95-57-3 -— ——541-73-1 —— —106-46-7 —— —100-51-6 ————95-50-1 ————95-48-7 ————•3Q£-JQ_1O n

lflfi-dil-5 _____

621-64-7 — ——67-72-1 ————QQ_QC_O_

"7a_ QQ_ i ______pQ -TC C __

105-67-9 ————65-85-0 ————111-91-1 —— —120-83-2 ————120-82-1 —— —91-20-3 ————106-47-8 -----87-68-3 ————SsQ_c//t.. . »__....91-57-6 ————77-47-4 ————88-06-2 ————95-95-4 ————O1 _^Q_"7______

88-74-4 ————131-11-3 —— —208-96-8 — ——606-20-2 ———

— Phenol—— bis (2-Chiorcethyl) Ether—— 2-Chlorophenol—— 1 , 3-Dichlorobenzene—— 1 , 4-Dichlorocenzene

—— 1 , 2-Dichlorobenzene—— 2-Hethylphenol—— bis (2-Chloroisopropyl) Ether _— 4-Methylphenol— N-Nitroso-Di-n-Propylamine— Hexachloroethane— Nitrobenzene—— Isophorone—— 2-Nitrophenol—— 2 , 4-Dimethylphenol—— Benzoic Acid—— bis (2-Chloroethoxy)Me thane __—— 2 , 4-Dichloroohenol—— 1 . 2 , 4-Trichlorobenzene—— Naphthalene— 4-Chloroaniline—— Hexachlorobutadiene— 4-Chloro-3-Methylphenol— 2-Methvlnaphthalene

—— 2 . 4 , 6-Trichlorophenol—— 2 . 4 , 5-Trichlorophenol—— 2-Chloronachthalene—— 2-Nitroaniline—— Dimethyl Phthalate—— Acenaphthylene—— 2 . 6 -Dinitro toluene

1460 |U460 |U460 |U460 |U460 |U460 |U460 |U460 |U460 |U460 |U460 JU460 |U460 |U460 |U460 |U460 |U2300 |U460 |U460 |U460 |U460 |U460 |U460 |U460 |U460 |U460 |U460 |U2300 |U460 |U2300 |U460 |U460 |U460 |U

1

FORM I SV-1 - ~ „ __ _ 1/87 Rev.

«.R309266 OOC277

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

| CDE60Lab Name: NYTEST ENV INC ________ Contract: 63-W8-0049 |


Matrix: (soil/water) SOIL Lab Sample ID: 5256004 ___

Sample wt/vol: 30.0 (g/mL) G __ Lab File ID: B1348 ____



Extraction: (SepF/Cont/Sonc) SONG Date Analyzed: 08/02/90

GPC Cleanup: (Y/N) N__ pH: 7.5 Dilution Factor: 1.00


99-09-2 ———83-32-9 ——— -51-28-5 ——— -100-02-7 ——— -132-64-9 -——121-14-2 ——— -QA—CC *>

7005-72-3 —— -PC — "a_—oo / J— /100-10-6 ——— -t-;'5A-5'5-1 - ___•mJ- J <J 4f J.

86-30-5 ——— -101-55-3 ——118-74-1 ——— •87-86-5 —— —85-01-8 ——— •120-12-7 —— -84-74-2 ——— -206-44-0 ———129-00-0 ——— •QC £ Q T

91 ~Qd— 1 ___ •———C£ CC O

218-01-9 ——— •117-81-7 —— -117-84-0 ——— •n/_-\cr QQ o

207-08-9 ——— •50-32-8 ———193-39-5 ——— •53-70-3 ———191-24-2 ———

—— 3-Nitroaniline- —— Acenaphthene—— 2 , 4-Dinitroohenol—— 4-Nitrophenol—— Dibenzofuran—— 2 , 4-Dinitro toluene

—— 4-Chlorophenyl-phenylether—— Fluorene—— 4-Nitroaniline—— 4,6-Dinitro-2-Methylphenol __—— N-Nitrosodiphenylamine ( 1 ) __—— 4-Bromophenyl-phenylether __—— Hexachlorobenzene

—— Phenanthrene—— Anthracene—— Di-n-Butylphthalate—— Fluoranthene—— Pyrene—— Butylbenzylphthalate—— 3 , 3 ' -Dichlorobenzidine—— Benzo ( a ) Anthracene—— Chrysene—— bis ( 2-Ethylhexyl ) Phthalate __—— Di-n-Octyl Phthalate—— Benzo ( b ) Fluoranthene

—— Benzo ( a ) Pyrene—— Indeno (1,2, 3-cd ) Pyrene—— D ibenz( a, h) Anthracene—— Benzo ( g , h , i ) Pervlene

230046022002300460460460460460220023004604604602300460460

1400460460460930460460190460460460460460460460

1IUIUIUIUIU|u|uIUIUIUIUIUIUIUIUIUIU

IUiuiuiuiuiuuiu|uiuiuiu|uiu1


FORM I SV-2 H R J U 9 2 6 71/87 Rev.000278

10 ' EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET

| CDE60Lab Name: NYTEST ENV INC __________ Contract: 63-U8-0049 |


Matrix: (soil/water) SOIL Lab Sample ID: 52S6004

Sample wt/vol: J30__ (g/mL) G___ Lab File ID: _______

U Level: (low/med) LOU Date Received: 07/11/90

n% Moisture: not dec. _28 dec. ___ Date Extracted: 07/13/90——— ———


n; GPC Cleanup: (Y/N) .N_ , pH: 7.0 Dilution Factor: 1_____

n


31S-S4-6 ———319-35-7 ———319-36-3 — —58-39-9 ————7S-44-3 ————309-00-2 ———J. V C. »J / tj

959-98-8 ———60-57-1 ————72-55-9 ————V5 O f\ O

33213-65-9 —72-54-8 ————1031-07-8 ——50-29-3 ————72-43-5 ————53494-70-5 —5103-71-9 ——5103-74-2 ——8001-35-2 ——12674-11-2—11104-28-2 —11141-16-5 —53469-21-9 —12672-29-6 —11097-69-1 —11096-82-5 —

——— aioha-3HC——— beta-SHC——— delta-BHC——— aamma-BHC (Lindane)——— Heotachlor——— Aldrin——— Heotachlor epoxide——— Endosulfan I——— Oieldrin——— 4, 4 '-ODE——— Endrin—— Endosulfan II——— 4. 4 '-ODD——— Endosulfan sulfate——— 4, 4 '-DOT——— Methoxychlor——— Endrin ketone——— alona-Chlordane——— aamma-Chlordane——— Toxaohene——— Aroclor-1016——— Aroclor-1221——— Aroclor-1232—— Aroclor-1242——— Aroclor-1248——— Aroclor-1254——— Aroclor-12S0

111111111111111122222222222222

11022110110220110110110110110220220

|u|u|u|uI«J|ulu|uluiuiuiu|uiu|u|uluiu|ulu|uiu|u|u|u|u|u

FORM I PEST 1/87 Rev.

AR309268CQ~399


I I| CDE62 |

Lab Name: NYTEST ENV INC _________ Contract: 68-U8-0049 | _____________ |

Lab Code: NYTEST Case No.: 14442 SAS No.: ______ SOS No.: CDE56

Matrix: (soil/water) UATER Lab Sample ID: 5256007

Sample wt/vol: 5.0 (g/mL) .ML _ Lab File ID: D2305

Level: (low/med) LOUl Date Received: 07/11/90




1| 74-87-3 — — —I * M- sJ W -^

1 75-01-4 —————| 75-00-3 — — —-| 75-09-2 — — —[ 67-64-1 —— ——| 75-15-0 —————1 75-35-4 —————| 75-34-3 —————| 540-59-0 ————1 <TT CC 1

\ 107-06-2 ————

1 71-55-6 —————| 56-23-5 —————| 108-05-4 ————| 75-27-4 —————| 78-87-5 —————| 10061-01-5 ——1 79-01-6 —————| 124-48-1 ————| 79-00-5 —————j 71-43-2 —————| 10061-02-6 ——| 75-25-2 —————| 108-10-1 ————| 591-78-6 ————1 127-18-4 ————| 79-34-5 —————[ 108-88-3 ————| 108-90-7 ————| 100-41-4 —— ——1 100-42-5 ————| 1330-20-7 — ——1

—— Chlo rome thane—— Sromcme thane—— Vinyl Chloride—— Chlo roe thane

—— Acetone—— Carbon Disulfide—— 1,1-Oichio roe thene—— 1,1-0 ichlo roe thane—— 1,2-Dichloroethene (total)—— Chloroform—— 1 . 2-0 ichlo roe thane—— 2-8utanone—— 1,1,1-Tr ichlo roe thane—— Carbon Tetrachloride—— Vinyl Acetate—— Bromodichlo rome thane—— 1.2-OichloroproDane—— cis-1, 3-D ichlo ropropene—— Trichlo roe thene—— Dibromochlo rome thane—— 1.1.2-Tr ichlo roe thane—— Benzene—— Trans— 1 , 3— Oichloropropene ___—— Bromoform—— 4 -Me thy 1-2— Pentanone—— 2-Hexanone—— Tetrachlo roe thene—— 1,1,2,2-Tetrachloroethane ___—— Toluene—— Chlo robenzene—— Ethylbenzene—— Styrene—— Xylenes (total)

101010105

1055551051055

10555555555

1010S555555

1lu|u|ulululululu|u|u1|ulu

.lululu|ulu|u|u|u|uiu|u|u|u|u|u|u|u|u|u|u|u1


30.9269 00097S

Appendix D

Reviewed and CorrectedTentatively Identified Compounds

SR309270

D0

IE EPAVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS || CDE56

Lab Name: NYTEST ENV INC _________ Contract: 68-118-0049 |

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SOG No.: CDE56

Matrix: (soil/water) WATER Lab Sample ID: 5256003

Sample wt/vol: 5.0 (g/mL) JJL__ Lab File ID: D2304



Column (pack/cap) PACK Dilution Factor: 1.0___

1J CONCENTRATION UNITS:

Number TICs found: _1 (ug/L or ug/Kg) UG/L

j:

Li

1| CAS NUMBER|______ ————1 1-1

COMPOUND NAME.. . - - -

UNKNOWN

1RT |

===H14.44 |

1

EST. CONC.

5.0

Q

a

FORM I VOA-TIC 1/87 Rev.

BR30927I Q00033

Q0

i;G

Qn

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _____________


Lab Name: NYTEST, ENV INC_________ Contract: 68-WS-0049 I____________

Lab Code: NYTEST Case No.: 14442_ SAS No.: ______ SDG No.: CDE56_


Sample wt/vol: 5.0 (g/mL) J3__ Lab File ID: D2317

Level: (low/med) LQU Date Received: 07/11/90



CONCENTRATION UNITS:Number TICs found: _0 (ug/L or ug/Kg) _UG/KG

CAS NUMBER I COMPOUND NAME I RT I EST. CONC. | Q

FORM I VOA-TIC 1/S7 Rev.

flR309272 000045

Qn

r,o0

u

IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET


Lab Name: NYTEST ENV INC ________ Contract: 68-W8-0049 |


Matrix: (soil/water) SOIL Lab Sample ID: 5256001 __

Sample wt/vol: 30.0 (g/mL) G __ Lab File ID: B1345 ___


% Moisture: not dec. _14 dec. __ Date Extracted: 07/13/90


'•» GPC Cleanup: (Y/N) N_ pH: 7.9 Dilution Factor: 1.00

CONCENTRATION UNITS:Number TICs found: 20 (ug/L or ug/Kg) UG/KG

CAS NUMBER

1.2.3.4.5.6.7.a.9.10.11.12.13.14.15.16.17.18.19.20.

COMPOUND NAME

| UNKNOWNUNKNOWN[UNKNOWNUNKNOWN[UNKNOWN AROMATICUNKNOWN[UNKNOWNUNKNOWN[UNKNOWNUNKNOWN[UNKNOWNUNKNOWN[UNKNOWNUNKNOWN[UNKNOWNUNKNOWN[UNKNOWN ALKANEUNKNOWN ALKANE[UNKNOWN ALKANEUNKNOWN ALKANE

I

RT

4.074.084.174.384.834.885.075.125.185.576.37

• 6.428.9911.4011.99'30.8932.0933.2234.3235.51

1EST. CC1IC. | Q.„„.,„.„. |..».

1700 |J2220 |J1500 ]J2S0 |J1200 |J400 |J210 |J750 |J420 |J2300 |J980 |J2530 |J1200 |J560 |J260 |J200 |J390 |J360 |J300 |J410 |J

1

FORM I SV-TI® n o ~ _ 1/87 Rev.

C00190

o

LD

0

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ____________

TENTATIVELY IDENTIFIED COMPOUNDS | || CDE58 |

Lab Name: NYTEST ENV INC_________ Contract: 63-U8-0049 |____________|

Lab Code: NYTEST Case No.: 14442 SAS No.: ______ SOG No.: CDE5S

Matrix: (soil/water) SOIL Lab Sample ID: 52S6002_____

Sample wt/vol: 5.0 (g/mL) G__ Lab File ID: D2318____


n % Moisture: not dec. _ 21 Date Analyzed: 07/13/90LJ

Column (pack/cap) PACK Dilution Factor: 1.0 ___

CONCENTRATION UNITS:Number TICs found: _ 1 (ug/L or ug/Kg) UG/KG

CAS NUMBER

1.

COMPOUND NAME

FREON

RT

14.80

1| EST. CONC.i

1 45

11 Q

U1


000053

IF . , ,- EPA SAMPLE NO.SZMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________


Lab Name: NYTEST ENV INC________ Contract: 68-W8-0049 |___________|


Matrix: (soil/water) SOIL Lab Sample ID: 5256002____


l-* Level: (low/med) LOW Date Received: 07/11/90

"1 % Moisture: not dec. _21 dec. ___ Date Extracted: 07/13/90


' GPC Cleanup: (Y/N) N_ pH: 7.6 Dilution Factor: 1.00


i | CAS NUMBER | COMPOUND NAME | RT | EST. CCNC. | Q

1. (UNKNOWN | 4.07 | 4800 |J2. [UNKNOWN | 4.12 | 1800 |J3. [UNKNOWN | 4.38 | 250 |J4. |UNKNOWN | 4.83 | 1200 |J5. [UNKNOWN | 5.05 | 180 |Js. IUNKNOWN I 5.13 | 710 |j7. [UNKNOWN I s.is | 410 |j8. [UNKNOWN I 5.53 | 2300 |J9. [UNKNOWN | 6.38 | 10000 |J

10. IUNKNOWN I 3.99 I 1200 |j11. (UNKNOWN I 35.47 | 200 |J

FORM I SV-TIC 1/87 Rev.

^309275 COC22S

I j

U

DI ;

tj

QD


TENTATIVELY IDENTIFIED COMPOUNDS |1 CDE59 |

Lab Name: NYTEST ENV INC_________ Contract: 68-W8-0049 I_________

Lab Code: NYTEST Case No.: 14442_ SAS No.: _____ SOG No.: COE5S.


Sample wt/vol: 5.0 (g/mL) G__ Lab File ID: D2319




CONCENTRATION UNITS:Number TICs found: _0 (ug/L or ug/Kg) UG/KG

a ( . . . . (

| CAS,NUMBER | COMPOUND NAME 1 RT • | E3T. CONC. | Q |

v_ FORM I VOA-TIC 1/87 Rev.

flR.309276L

Q0

D

iJr i

IF EPA SAMPLE NO.SEMiyOLATZLE ORGANICS ANALYSIS DATA SHEET •__________


Lab Name: NYTEST ENV INC________ Contract: 68-W8-0049 |___________|

Lab Code: NYTEST Case No.: 14442 SAS No.: __ SDG No.: CDE56








CAS NUMBER

1.2.3.4.5.6.7.8.9.10.

11

| UNKNOWN[UNKNOWN[UNKNOWN| UNKNOWN[UNKNOWN[UNKNOWN[UNKNOWN[UNKNOWNIUNKNOWN[UNKNOWN1

1COMPOUND NAME | RT

| 4.08| 4.38| 4.83

ALKENE | 5.12ALKENE | 5.17

| 5.53| 6.37| 9.02| 11.45| 12.071

EST. CONC.

88002601200630440

210036001100460210

11 Q1—— »UIJIJuIJIJuuuIJ1

FORM I SV-TIC 1/87 Rev.

/9R309277 COC254

Qn



Lab Name: NYTEST ENV INC__________ Contract: 68-U8-0049 |_____________|



Sample wt/vol: 5.0 (g/mL) J__ Lab File ID: D2320______



Column (pack/cap) PACK_ Dilution Factor: 1.0___


CAS NUMBER | COMPOUND NAME | RT | EST. CONC. | Q |


0000'71

IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ___________


Lab Name: NYTEST ENV INC_________ Contract: 68-W8-0049 |____________|

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SDG No.: CDB56


Sample wt/vol: 30.0 (g/mL) G__ Lab File ID: B1348_____






CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.

1| COMPOUND NAME

[UNKNOWN(UNKNOWN[UNKNOWN[UNKNOWN[UNKNOWN[UNKNOWN[UNKNOWN[UNKNOWN ALKENEIUNKNOWN ALKENE(UNKNOWNIUNKNOWNIUNKNOWNIUNKNOWN(UNKNOWN(UNKNOWN(UNKNOWN1

RT

4.054.124.384.574.854.935.075.135.205.536.336.389.0211.4012.0015.62

1EST. CONC. | Q

=S = S33 = = = = = 3S = = 1 3=S=SS3

1900 |J5300 |J430 |J220 |J1500 |J450 |J260 |J950 |J6104 (J2500 |J18000 |J11000 |J1300 |J520 |J230 IJ560 |J

1

FORM I SV-TIC aors^^^--- 1/87 Rev.flR309279000279

0G

P


TENTATIVELY IDENTIFIED COMPOUNDS \\ CDE62

Lab Name: NYTEST_ENV INC_________ Contract: 63-U8-0049_ |____________

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SDG No.: CDE5S_

Matrix: (soil/water) UJATER Lab Sample ID: 5256007

Sample wt/vol: 5.0 (g/mL) JIL Lab File ID: D2305




CONCENTRATION UNITS:Number TICs found: _0 (ug/L or ug/Kg) UG/L

CAS NUMSER COMPOUND NAME_ . . . . . . . . . . .

1 1RT | E3T. CONC. | Q

1 1

FORM .1 VOA-TIC - 1/87 Rev.

1R309280 000079

Appendix E

Organic Regional Data Assessment Summary

. SR30928I

Vr/j < jT« .Nj Page 1 of 5

DPO: [ ] ACTION [X] FYI Region__IIj^^

ORGANIC REGIONAL DATA ASSESSMENT SUMMARY

CASE NO: 14442SDG NO: CDE56SOW: 2/88NO. OF SAMPLES: 2

REVIEWER: ESAT

1. HOLDING TIMES

2 . GC-MS TUNE/GC PERFORMANCE

3 . INITIAL CALIBRATIONS

4. CONTINUING CALIBRATION

5. FIELD BLANKS (F=NOT APPLI'

6. LABORATORY BLANKS

7 . SURROGATES

8. MATRIX SPIKE/DUPLICATES

9. REGIONAL QC (F=NOT APPLIC.

10. INTERNAL STANDARDS

11. COMPOUND IDENTIFICATION

12. COMPOUND QUANTITATION

13 . SYSTEM PERFORMANCE

14. OVERALL ASSESSMENT

O = No problems or minor probX * No more than about 5% of

estimated or unusable.M = More than about 5% of theZ = More than about 5% of theA - DPO action requested; use

DPO ACTION ITEMS:

LABORATORY : NYTESTDATA USER: LISA VIDULICHREVIEW COMPLETION DATE: 09 / 11/90MATRIX: WATER

VGA BNA PEST

O

O

X

M

CABLE) 0

O

0

O

ABLE) F

O

O

ooM

lems that do not affect data usabilitythe data points are qualified as either

data points are qualified as estimated.data points are qualified as unusable.in conjunction with one of the above codes.

OTHER

-•

AREAS OF CONCERN:

n%__________ ^

-. i-\ /*\ f~\RJ:U)9282DOCUMENTATION ATTACHED (See Followina Pacres)

J] • Page 2 of 5

PO: [ ] ACTION [X] FYI Region III

ORGANIC REGIONAL DATA ASSESSMENT SUMMARY

CASE NO: 14442_____________ LABORATORY: NYTEST____________SDG NO: CDE56 _________ DATA USER: LISA VIDULICHSOW: 2/88______________ REVIEW COMPLETION DATE: 09/11/90NO. OF SAMPLES:__4___________ MATRIX: SOIL________

REVIEWER: ESAT

VOA BNA PEST OTHER

1. HOLDING TIMES O O O

2. GC-MS TUNE/GC PERFORMANCE O O O

3. INITIAL CALIBRATIONS 0 M O

4. CONTINUING CALIBRATION X 0 0

5. FIELD 'BLANKS (F=NOT APPLICABLE) O F F

6. LABORATORY BLANKS O O __O_

SURROGATES O O __0_

8. MATRIX SPIKE/DUPLICATES 0 O __Q_

9. REGIONAL QC (F=NOT APPLICABLE) F F __O_

10. INTERNAL STANDARDS 0 O

11. COMPOUND IDENTIFICATION O O __0_

12. COMPOUND QUANTITATION O O __O_

13. SYSTEM PERFORMANCE 0 O __Q_

14. OVERALL ASSESSMENT X M O

o = No problems or minor problems that do not affect data usabilityX = No more than about 5% of the data points are qualified as either

estimated or unusable.M = More than about 5% of the data points are qualified as estimated.Z = More than about 5% of the data points are qualified as unusable.A = DPO action requested; use in conjunction with one of the above codes.

DPO ACTION ITEMS:

AREAS OF CONCERN:

DOCUMENTATION ATTACHED (See Following Paaes) 511309283

of 5

ORGANIC REGIONAL DATA ASSESSMENT SUMMARY NOTESCASE 14442 SDG CDE56 (water samples)

Item 3A - During the initial volatiles calibrations thetarget compound benzene and the surrogate toluene-d8 were noted by the laboratory as havingsaturated the detector. (See the analyticalnarrative included in Appendix F). Due to thisproblem, these points are not present on thecalibration summary, and were not used inquantitating reported results. The only effectthis problem could have on the data is to reducethe calibration range for these two compounds, andsince neither compound was found at highconcentrations for any sample, no data has beenaffected. (See Appendix F).

Item 3B - The volatile compound acetone had a percentrelative standard deviation (%RSD) greater thanthe QC limit of thirty percent (30%).

Item 4A - Several volatile compounds failed precisioncriteria for the continuing calibrations. (SeeTable I in Appendix F).

Item 5A - The maximum concentration of contaminants found inthe method blanks are summarized in the tablebelow. (See Appendix F).

____Compound____ Concentration______

methylene chloride * 6chloroform 10


Item 5B - Insufficient sample was sent to the analytical labto allow analysis of field blanks forsemivolatiles or pesticide/PCB's as documented inthe telephone log included in Appendix F.

Item 14A - The reported Tentatively Identified Compounds(TIC's) in Appendix D have been reviewed andaccepted during data validation. (See AppendixD).

8R309281*

of 5

ORGANIC REGIONAL DATA ASSESSMENT SUMMARY NOTESCASE 14442 SDG CDE56 (soil samples)

Item 2A - The pesticide/PCB confirmation column linearitycheck had relative percent difference values foraldrin and 4,4'-DOT greater than the ten percent(10%) QC limit. The laboratory noted this problemin a telephone log to EPA, and was instructed thatno re-analysis of the samples was required. No

• data was qualified based on this problem. (SeeAppendix F).

Item 3A - During the initial volatiles calibrations thetarget compound benzene and the surrogate toluene-d8 were noted by the laboratory as havingsaturated the detector. (See the analyticalnarrative included in Appendix F). Due to thisproblem, these points are not present on thecalibration summary, and were not used inquantitating reported results. The only effectthis problem could have on the data is to reducethe calibration range for these two compounds, andsince neither compound was found at highconcentrations for any sample, no data has beenaffected. (See Appendix F).

Item 3B - Several semivolatile compounds failed precisioncriteria for the initial calibration. (SeeTable I in Appendix F).

Item 4A - The volatile compounds 1,2-dichloroethane and 2-hexanone failed precision criteria in thecontinuing calibration. (See Table I inAppendix F).

Item 4B - One of the INDA continuing calibration standardsfor the quantitation column had a percentdifference (%D) value for endosulfan II sightlygreater than the QC limit, as compared with theinitial calibration values. Since no pesticidecompounds were found in any of the soil samples nodata has been affected. (See Appendix F).

flR309285

of 5

ORGANIC REGIONAL DATA ASSESSMENT SUMMARY NOTESCASE 14442 SDG CDE56 (soil samples)

Item 5A - The maximum concentration of contaminants found inthe field blanks are summarized in the tablebelow. (See Appendix F).

______Compound____ Concentration_______

methylene chloride * 6 /zg/Kgchloroform 10


Item 5B - Insufficient sample was sent'to the analytical labto allow analysis of field blanks forsemivolatiles or pesticide/PCB's as documented inthe telephone log included in Appendix F.

Item 8A - The semivolatile MS/MSD analyses of sample CDE60had two (2) out of twenty-two (22) spikerecoveries outside of the QC limits. (SeeAppendix F).

Item 8B - The pesticide/PCB MS/MSD analyses of sample CDE60had one (1) out of twelve (12) spike recoveriesoutside of the QC limits. (See Appendix F).

Item 8C - The MS/MSD analyses had compounds other than thespiking compounds or blank contaminants present.Following is a table of results and precisionestimates for these non-spiked compounds:

MS/MSD Non-Spiked Compounds

____Concentration fug/Kg)Compound CDR60 CDR60MS CDR60MSD %RSD

di-n-butylphthalate 1400 2000 1500 20bis(2-ethylhexyl) 190 J 510 650 52

phthalate

%RSD - Percent Relative Standard Deviation

Item 14A - The reported Tentatively Identified Compounds(TIC's) in Appendix D have been reviewed andaccepted during data validation. (See AppendixD).

DCN - DM009A07

fiR309286

Appendix F

Support Documentation

AR3Q9287

TA2L2 I

237_3CHH2rML PSOTSCTIOS AGSSCT REGION inON CUTLI23S

mS H2L COMPOUNDSSSIAS .TO. ._____caaraACToa '

! ~r.szr-~sr.ii D1 ..j— r/-—\<c.i! Chlcr^sethar.e

1 7---.v' (--,-„,, .i .j a! C'r.l r-: eel-are! Mec'-vlece Chloride! Acetcsa! Career, Diaulfide! l , 1-D ichlo r"2«siiene! 1 , ''-Dichlorcethar.e! Total-i ,2-Dichlcr"3echsse! Chic:") for-! 1 . i-îchlcroeth^-s! i-^tancrie! 1 1 •(_-"— •• n«: 0-.^_»'"U-t-,_,! Carbor. Tetr-icnlcride! Vir.vL Acetate1 5- -,c-l,- >,1 -jj-^â-w-jâ

L 1 ,2-:Dic::lonor>3?af*eL Gis-1 , ''-DishiorctjnceseI T~ ' ~-1 0,.-,e *•*_,„_,

! D-'bncoc'"1 orc-"»zi:a£'»! 1 . 1 . S-TriohloroethaseL Benzene! trar-3-1 , 3— DichlcroorooeneI BronofoETsL tt-Methvl-3-3ents2one! 2-Hexar.oneL Tetrachloroethesa' 1 ,_1 . 2, 2-""etrach'roroethanei Toluene! Chloro'oer.ra"e! Ethvlber.zer.e! Stvrer.e! Total Xvl -r.es

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T12L2 I oage_Aof

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TA2L2 I pas«_±.of_

z:r7i?.c-iME:iTAL PROTECTION AGENCI REGION niCALIBRATION OUTLIERS

S2.I7CLATILE H2L COMPOUNDS (Part 1 of 2)__________CONTRACTOR ______yO/X Tg-S/____________

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TA2L2 I page 7 of

E:r7iRCNMz:iTAL PROTECTION ACZNCT BSSIOM inCALIBRATION CUTLIERS

, , SEMI7CLATILE H2L COMPOUNDS (Part 2 of 2}CASE)SAS .To.___j_l_____-______CONTRACTOR_____/i/

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SR30929i

page j of

DEFINITION OF CODES USED IN TABLE I

I s %RSD exceeded 30% in the initial calibration, positive results arequalified "J", and quantitation limits are qualified "UJ".

C — %D exceeded 25% in the continuing calibration. Positive results arequalified "J", and quantitation limits are qualified "UJ".

F = RF less than 0.05 in all calibrations. All quantitation limits arequalified "R".

+ - The "B" qualifier, denoting blank contamination, supersedes the qualifierissued in this table.

L = The "L" qualifier, denoting low bias of results, supersedes the qualifierissued in this table.

R - The "R" qualifier, denoting unusable results, supersedes the qualifierissued in this table.

BR309292

— 6A• VOLATILE ORGANICS INITIAL CALIBRATION DATAt..

Lab Name: NYTcST ENV INC_________ Contract: 63-U3-0049

Lab Cods; NYTEST Case No.: _1£££2_ SAS No.: ______ SOG No.: CDE5S

Instrument ID: JD_____ Calibration Oate(s): 36/19/90 06/19/90

Matrix:(soil/uatar) SOIL Level:(lou/med) LQU Column:(pack/cap) PACK

Min RRF for S?CC(#) » 0.300 (0.250 for Bromoform) Max %RSO for CCC(*) - 30.0%

i;

n

p

LAB FILE ID: RRF20 =« D2097_____ RRF50 » D2096RRF100= D2098____ RRF150= D2099_____ RRF200= D2100

I I I I I I __ I %COMPOUND |RRF20 [RRF50 | RRF1001RRF1501RRF2001 RRF | RSD

Chloromethane____________# 1.822| 1.875| 1.57S| l.S7S| 1.71l[ 1.732| 6.9#jSromomethane____________| 2.93SJ 2.82S| 2.652) 2.728| 2.523) 2.753| 4.7|

, ., (Vinyl Chloride___________* 2.757) 2.S75| 2.670) 2.7S0| 2.583| 2.709| 1.7*__, IChloroethana____________| l.S70| 1.557) 1.533| 1.718) 1.771) 1.S80) 4.2|

|Methylene Chloride_______| 3.401) 2.157) 2.011) 2.167) 2.188| 2.387) 23.9)lAcatone_________________| 0.532) 0.337) 0.348) 0.353) 0.365) 0.397) 19.4)|Carbon Disulfide_________| 4.374) 4.625) 4.626) 5.133) 5.563) 4.865) 9.9)|l,l-0ichloroethene_______* 1.621) 1.654) 1.564) 1.691) 1.729) 1.652) 3.8*|l,l-0ichloroethane_______* 4.145) 4.046) 3.843) 4.206) 4.383) 4.125) 4.3*11,2-Oichlorcetnene (total)_| 3.534| 3.453) 3.420) 3.795) 3.887) 3.S38) 5.6)[Chloroform_______________* 3.977) 3.804) 3.730) 4.112J 4.134) 3.951) 4.5"|l,2-Dichloroethane_______| 2.097| 2.106) 2.037) 2.212) 2.207) 2.132) 3.S)

D)2-3utanone______________| 0.129) 0.145) 0.147) 0.155) 0.1S7) 0.149) 9.4)|l,l,l-Trichloroethane_____| 0.582) 0.575) 0.539) 0.571) 0.556) 0.565) 3.1)|Carbon Tetrachloride______) 0.519) 0.531) 0.503) 0.540) 0.529) 0.524) 2.7|(Vinyl Acetata___________| 1.197) 1.159) 1.127) 1.132) 0.906) 1.104) 10.4|(Bromodichloromethane______| 0.648) 0.568) 0.626) 0.669) 0.650) 0.652) 2.7)11,2-Dichloropropane______* 0.662) 0.567) 0.622) 0.674) 0.555) 0.656) 3.1*|cis-1.3-0ichloropropene___| 0.908) 3.907) 0.874) 0.963) 0.939) 0.919) 3.9|iTrichloroethene_________| 0.606) 0.597) 0.549) 0.590) 0.584) 0.585) 3.7||Dibromochloromethane_____| 0.494J 0.510) 0.518) 0.574) 0.552) 0.530) 6.2)11.1,2-Trichloroethane____| 0.562) 0.493) 0.491) 0.543) Q-^Tgl 0.523) 5.9|(Benzene_________________| 1.344) 1.325) 1.302') 1.469)£___J 1.350) 5.5))Trans-l,3-Oichloropropene_) 0.401) 0.415) 0.412) 0.472) 07461) 0.432) 7.4)|Bromoform_______________* 0.375) 0.394) 0.412) 0.443) 0.425) 0.411) 6.8*|4-Methyl-2-?entanone______| 0.483) 0.466) 0.417) 0.443) 0.474) 0.457) 5.8)|2-Hexanone______________| 0.341) 0.238) 0.226) 0.239) 0.281) 0.265) 17.9)iTetrachloroethene________| 0.498) 0.499) 0.459) 0.496) 0.497) 0.490) 3.5)11,1,2,2-Tetrachloroethane_# 0.722) 0.757) 0.748) 0.825) 0.835) 0.777) 6.4*|Toluene________________* 0.910) 0.911) 0.841) 0.919) 0.938) 0.904J 4.1*(Chlorobenzene__________t 1.214) 1.177) 1.068) 1.164) 1.173) 1.159) 4.7#(Ethylbenzene____________* 0.557) 0.567) 0.515) 0.557) 0.555) 0.554) 4.0*jStyrene_________________| 1.025) 1.084) 0.929) 1.033) 1.037) 1.022) 5.5||Xylenes (total)_________| 0.624) 0.620) 0.564) 0.611) 0.627) 0.609) 4.3)

lToluene-d3______________| 1.549) 1.373) 1.597) 1.599|C___2| 1.530) 7.0)IBFB_______________I 0.940) 0.320) 0.942) 0.935) 0.933) 0.915) s.s)|l,2-0ichloroethane-d4_____| 1.954) 1.789) 2.184) 2.157) 2.225) 2.062) 9.0)I_______________________I_____!_____I_____!_____I_____I_____!____I

FORM yi VOA 1 87 Rev*

000089

7AVOLATILE CONTINUING CALIBRATION CHECK

Lab Name: NYTEST ENV INC__________ Contract: 63-U3-3349

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SOG No.: CDE5S _

Instrument ID: 0_____ Calibration date: 07/13/90 Time: 0835

Lab File ID: D2315____ Init. Calib. Oata(s): 06/19/90 06/19/90

Matrix:(soil/water) SOIL Level:(low/med) LOU Column:(pack/cap) PACK

Min RRF50 for SPCC(#) = 0.300 (0.250 for Bromoform) Max %0 for CCC(*) - 25.0%

I _ I ICOMPOUND | RRF [RRF50 ) %0

*

IChloromethane____________* 1.732) 1.686) 2.7 #ISromomethane____________| 2.753) 2.95l| -7.2 |[Vinyl Chloride___________* 2.709[ 2.477) 8.6JChloroethane____________| 1.530) 1.470) 12.5|Methylene Chloride_______| 2.387) 2.185) 8.4[Acatons_________________| 0.397) 0.362) 8.8(Carbon Disulfide_________| 4.8S5| 4.529) 5.9|l,l-0ichloroethene________* l.S52| 1.707) -3.3|l,l-0ichloroethane________* 4.125) 4.175) -1.2)l,2-Dichloroethene (total)_| 3.538) 3[Chloroform______________* 3.951) 4|l,2-0ichloroethane________| 2.132)[2-3utanone______________) 0.149))l,l,l-Trichloroethane_____| 0.565) 0.653|-17.4[Carbon Tetrachloride______| 0.524) 0.627|-19.7[Vinyl Acetata____________| 1.104) 1.102) 0.2| Sromodichlorcmetnane______| 0.552) 0.695) —6.6|l,2-0ichloropropane______* 0.556) 0.629) 4.1|cis-l,3-0ichloropropene___| 0.919) 0.873) 5.0(Trichloroethene__________) 0.585) 0.519) -5.8[Oibromochloromethane______| 0.530) 0.539) -1.7|l,l,2-Trichloroethane_____) 0.523) 0.497) 5.0|Benzene________________| 1.360) 1.320) 2.9)Trans-l,3-Oichloropropene_| 0.432) 0.418) 3.2iBromoform_______________# 0.411) 0.445) -8.3 *|4-Methyl-2-Pentanone______| 0.457) 0.5111-11,-8|2-Hexanone______________) 0.265) 0.155| 4lT?|Tetrachloroethene________| 0.490) 0.5871-157811,1,2,2-Tetrachloroethane_* 0.777) 0.778) -0.1 #[Toluene________________* 0.904) 0.961) -6.3|Chlorobenzene____________* 1.159) 1.30l|-12.3 *|Ethylbenzene____________* 0.554) 0.62S)-13.0StvreneXvlenes (total)

Toluene-da8FB1.2-0 ichlo roethane-d4

1.022)0.609)

1.530)0.915)2.062)

1

1.040) -1.80.675|-10.8

1.513) 1.10.882) 3.62.138) -3.7

1

FORM vii VOA Q p 3 g g o g K 1/87 Rev>

OOG134

0Q.*LIIi

f

i .

r

6AVOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name: NYTEST ENV INC_________ Contract: 68- 8-0049


Instrument ID: 0_____ Calibration Data(s): 06/29/90 06/20/90

Matrix:(soil/water) UATER Level:(low/med) LOU Column:(pack/cap) PACK

Min RRF for SPCC(*) =- 0.300 (0.250 for Bromoform) Max %RSO for CCC(*) - 30.0%

|LAB FILE ID: RRF20 - D2101 - RRF50 « D2192 I|RRF130= D2103______ RRF150= D2104______ RRF200- D2135

I I I I ICOMPOUND |RRF20 |RRF50 )RRF100|RRF150[RRF200|

ICnloromethane___________* 1.754) 1.999)| Bromomethane____________| 2.545) 2.818)[Vinyl Chloride______' 2.539[ 2.622|[Chloroethane____________| 1.550) 1.547)[Methylene Chloride_______| 2.707) 2.332|[Acatcne________________| 0.753) 0.631)[Carbon Oisulfida_________| 4.438) 4.887|[1,1-Oichloroethena_______* 1.547) 1.642)Il.l-Dichloroetnane * 4.000) 4.111))l,2-0ichloroethene (total)_| 3.436) 3.511)[Chloroform_____________* 3.794) 3.899)11,2-Oichloroethane______| 2.062) 2.173)

C|2-3utanone_____________| 0.235) 0.190)|l,l,l-Tricnloroethane____| 0.533) 0.532)[Carbon Tetrachloride_____) 0.512) 0.532|(Vinyl Acetate___________| 0.840) 0.800)| Bromodichloromethane_____| 0.655) 0.574)|l,2-Dichloropropane______* 0.672) 0.576)|cis-l,3-0ichloropropene___| 0.917) 0.901)

["" [Trichloroethene_________| 0.600) 0.588)'. _ | Dibromochloromethane_____| 0.496) 0.493)

|l,l,2-Trichloroethane____| 0.524) 0.475)[Benzene________________| 1.326) 1.336)|Trans-l,3-Oichloropropene_| 0.419) 0.433)iSromoform______________# 0.411) 0.370)| 4-Methyl-2-Pentanone_____) 0.571) 0.443) 0| 2-Hexanone_______________| 0.330) 0.234)iTetrachloroethene________| 0.506) 0.468111,1,2,2-Tetrachloroethane_* 0.824) 0.690) 0.678(Toluene_________________* 0.923) 0.886) 0.904[Chlorobenzene__________# 1.252) 1.124) 1.129(Ethylbenzene___________* 0.640) 0.561) 0.550) 0.578)Styrene______[Xylenes (total)

| Toluene-d8_IBFB ~

, 2-Oicnloroethane-d4

0.6620.5500.9230.5910.5240.5001.364)0.436

1.066) 0.973) 0.980) 1.0590.634) 0.584) 0.599) 0.644) 0.651) 0.622)

1.629) 1.340) 1.725) 1.542) £__-} 1 1-559) 10.5)1.0S2) 0.809) 1.008) 0.881) 0.887) 0.929) 11.l|

_____ 2.107) 1.829) 2.263) 1.903) 1.954) 2.011) 8.6)I___________________————— _____I_____I_____I_____I_____I_____I____I

FORM yi VOA $^309295 1/87 Rev*OOC090

7AVOLATILE CONTINUING CALIBRATION CHECK

Lab Name: NYTEST ENV INC_________ Contract: 63-U8-0049

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SDG No.: CDE5S_

Instrument ID: 0_____ Calibration data: 07/12/90 Time: 0835___

Lab File ID: D2300_____ Init. Calib. Oata(s): 36/23/90 06/20/90

Matrix:(soil/watar) WATER Level:(lou/med) LOU Column:(pack/cap) PACK

Min RRF50 for S?CC($) = 0.300 (0.250 for Brcmoform) Max %0 for CCC(*) » 25.0%

I

|1,2-OichloroethaneI 2-3utanone______|l,l,l-Trichloroethane(Carbon Tetrachloride|Vinyl AcetateISrcmcdichlcrcmethane

1 i 11,2-Oichloropropane,| cis-l,3-0ichloropropene,| Trichloroethene__|Oibromochloromethane|l,1.2-Trichloroethane| Benzene|Trans-l,3-Dichloropropene| Bromoform_______________)4-Methyl-2-Pantanone!2-Hexanone______iTetrachloroethene|1,1,2,2-Tetrachloroethane_# 0[Toluene________________* 0|Chlorobenzene___________# 1|Ethylbenzene__| Styrene______|Xylenes (total)I|Toluene-d8______________| 1.559) 1.440) 7.6IBFB______________| 0.929) 0.820) 11.7|l,2-0ichloroethane-d4_____) 2.011) 2.096) -4.2I______________________I____I_____I____

| COMPOUND

IChloromethane___________* 1.320) 1.960) -7.7 1 1/1>/K D "T| Bromomethane____________| 2.734) 2.743) -0.3 /]_ ip" £~ L|Vinyl Chloride. - -, -,« = t _. *«^i .,« « „ t-y t> ^? o|Chloroethana_[Methylene Chloride.|Acatone___[Carbon Oisuifide|1,1-Oichloroethene11,1-Oichloraa thane,|1,2—Oichloroethene|Chloroform______

FORM VII VOA 1/87 Rev.

SR309296000133

63SEMIVOLATILS ORGANICS INITIAL CALIBRATION DATA

t

Lab Name: NTTEST ENV INC________ Contract: 68-W8-0049

Lab Code: NYTSST Case No.: 14442 SAS No.: _____ SDG No.: CDE56

Instrument ID: B_____ Calibration Date(s): 07/31/90 07/31/93

Min RKF for SPCC(S) - 0.050 Max %RSD for CCC(*} - 30.0%

[LAB FIL3 ID: RRE20 - B1328 RRF50 - B1329 j(RRF80 » B1330_____ RRF120- B1331_____ RRF160- B1332

I I I I I I I _ I % II COMPOUND )RRF20 JRRF50 |RRF80 |RRF120)RRF160) RRF ) RSD |

| Phenol________________* 1.753) 1.639) 1.496) 1.365) 1.383) 1.538) 11.S*|bis(2-Chloroethyl)Ether___| 1.607) 1.638) 1.467) 1.341) 1.290) 1.469) 10.6)[2-Chlorochenol_________| 1.426) 1.441) 1.256) 1.137) 1.082) 1.263) 12.9)11,3-Dichlorobenzene______| 1.556) 1.442) 1.226) 1.128) 1.029) 1.276) 17.1)|l,4-Dichlorobenzene______* 1.573) 1.399) 1.202) 1.109) 1.036) 1.264) 17.4*(Benzyl Alcohol__________| 0.963( 0.953| 0.850( 0.792J 0.749| 0.861| 11.1))l,2-Dichlorobenzene______[ 1.600) 1.479) 1.275] 1.157) 1.060) 1.315) 16.9)12-Methylphenol__________| 1.3S2) 1.231) 0.984) 0.908| 0.825) 1.062) 21.3)|bis(2-Chloroiscpropyl)Stherj 4.172| 4.153) 3.552) 3.291) 2.959) 3.625) 14.8)14-Methylphenol_________| 1.244) 1.014) 0.857) 0.789) 0.723) 0.925) 22.5||N-Nitroso-Di-n-?ropylanine_* 1.534) 1.442) 1.215) 1.090) 0.998) 1.265) 19.3*(Hexachloroethane_______I) 0.793) 0.756) 0.649) 0.582) 0.516) 0.659) 17.6)|Nitrobenzene__________| 0.534) 0.510) 0,448) 0.390) 0.373) 0.452) 15.41[Isophorone_____________| 1.051) 0.947) 0.869) 0.767) 0.789) 0.885), 13.2J)2-Nitrophenol__________* 0.271) 0.253) 0.230) 0.198) 0.197) 0.231) 14.6*(2,4-Dimethylphenol______| 0.409) 0.394) 0.357) 0.314) 0.310) 0.357) 12.6)[Benzoic Acid___________) | 0.221) 0.212) 0.198) 0.224) 0.214) 5.5))bis(2-Chloroethoxy)Methane_| 0.6S3) 0.598) 0.528) .0.460) 0.444) 0.539) 17.2)|2,4-Dichlorophenol_______* 0.380) 0.342) 0.279) 0.239) 0.231) 0.294) 22.1*11,2,4-Trichlorobenzene___| 0.409) 0.361) 0.314) 0.263) 0.251) 0.320) 20.8)|Naphthalene_____________) 1.154) 0.929) 0.779) 0.681) 0.534) 0.835) 25.3))4-Chloroaniline________| 0.540) 0.457) 0.400) 0.350) 0.329) 0.415) 20.61|Hexachlorobutadiene_____* 0.258) 0.218) 0.184) 0.158) 0.148) 0.193) 23.4*14-Chloro-3-Methylphenol___* 0.465) 0.407) 0.350) 0.308) 0.291) 0.364) 19.8*12-Methylnaphthalene______) 0.750) 0.592) 0.488) 0.432) 0.407) 0.534) 26.3)|Hexachlorocyclopentadiene_* 0.371) 0.321) 0.349) 0.324) 0.287) 0.330) 9.6*|2,4,6-Trichlorophenol____* 0.501) 0.459) 0.374) 0.340) 0.309) 0.397) 20.4*12,4,5-Trichlorophenol____| I 0.437) 0.412) 0.366) 0.335) 0.400) 16.5)12-Chloronaphthalene______| 1.395) 1.138) 0.943) 0.836) 0.775) 1.017) 24.8)12-Nitroaniline_________| | 0.824) 0.707) 0.641) 0.612) 0.695) 13.5)(Dimethyl Phthalate______| 1.955) 1.742) 1.440) 1.357) 1.221) 1.545) 19.31(Acenaphthylene_________| 2.202) 1.455) 1.158) 1.017| 0.902) 1.3491 Q877j>|2,6-Dinitrotoluene______| 0.741) 0.598) 0.585) 0.536) 0.498) 0.612| 17.1|13-Nitroaniline_________| | 0.541) 0.461) 0.425) 0.398) 0.457) 13.6|lAcenaphthene___________* 1.449) 1.145) 0.924) 0.818) 0.736) 1.014) 28.3*|2,4-Dinitrophenol______^_* I 0.128) 0.140) 0.135) 0.148) 0.138) 6.1*14-Nitrophenol__________* I 0.143) 0.136) 0.124) 0.121) 0.132) 9.3*I_____________________I____I____I____I____I____!____I___I

FORM VI SV-1 AR309297 1/87 Rev.r? n n 1 n

6CSEMIVOLATILS ORGANICS INITIAL CALIBRATION DATA

Lab Name: NYTEST SNV INC________ Contract: 68-W8-0049

Lab Code: NYTSST Case No.: 14442 SAS No.: _____ SuG No.: CDE56

Instrument ID: B_____ Calibration Date(s): 07/31/90 07/31/90

Min RRF" for SPCC(*) - 0.050 Max %RSD for CCC(*) - 30.0%

ILAB FILS ID: RSF20 » B1323 RRF50 - B1329 ~————|RRF80 - B1330 RRF120- B1331_____ RRF160- B1332

1| COMPOUND1(Dibenzofuran1 2 , 4-Dinitrotoluene| Diethylphthalate1 4-Chlorophenyl-phenylether_1 Fluorene1 4-Nitroaniline1 4, S-Dinitro-2-Methylphenol_| N-Nitroscdiphenylamine ( 1 } _) 4-3romo?henyl-phenylether _| Kexachlorobenzane1 Pentachlorophenol1 PhenanthreneI AnthraceneI Di-n-Butylphthalata1 Fluoranthene *1 Pyrene1 Butylbenzylphthalate1 3 , 3 ' -Dichlorobenzidine ___1 Benzo ( a ) Anthracene1 Chrysene| bis ( 2-3thylhexyl ) Phthalate_iDi-n-Octyl PhthalateI Benzo (b ) FluorantheneI Benzo ( k ) FluorantheneI Benzo (a) Pyrene) Indeno (1,2, 3-cd) Pyrene ___I D ibenz ( a , h ) AnthraceneI Benzo (g,h,i)Perylene1 9. ..9.9, ,.__-,,-.„, -

) Nitrobenzene-d5I 2-Fluorobiphenyl|Terphenyl-dl41 Phenol-d51 2-FluorophenolI 2 , 4 , 6-Tribromophenol1

1 1RRF20 |..-.— 12.141)0.741)2.213)0.673)1.354)

!1

* 0.592)0.283)0.403[

11.233)1.302)2.089)1.419)4.55-))2.869)0.327)2.264)1.034)2.553)

" 2.381)1.455)1.155)1.057)0.9SS)0.852)0.948)

0,524)1.529)3.008)1,687)1.092)0.444)

1

1 1 1 __ 1 % 1RRF50 |RRF80 | RRF 120) RRF 150 | RRF ) RSD j«™. | ——— . „„ | „„.. | ««« | „.„ |1.718) 1.407) 1.250) 1.1131 1.525) 26.9)0.699) 0.535 0.536) 0.493) 0.512) 17.1)1.955) 1.513) 1.443) 1.292| 1.7061 22. 1|0.420| 0.317) 0.273) 0.22S) 0.382|(4|7|J0.890) 0.633) 0.508) 0.517) 0.810) (gtTI)0.433) 0.415) 0.387) 0.371) 0.414) 1270|0.155) 0.144 0.133) 0.1301 0.141) 8.1)0.435) 0'.393 0.359) 0.312) 0.423) 26.9"0.231) 0.135 0.1651 0.146) 0.202| 27. 3|0.318( 0.258 0.230| 0.204| 0.283| 28.1)0.132) 0.153 0.144) 0.134) 0.1551 13.4*0.936) 0.764 0.6361 0.6151 0.848! 29. 3|0.972) 0.798 0.712) 0.525) 0 . 882 | <30_J}1.652) 1.333 1.198) 1.062) 1.459) 28.1)1.110) 0.898 0.800) 0.687) 0.983) 29.4*4.295) 4.044 3.867) 3.862) 4.146) 8.1)1.759) 1.321) 1.196) 1.006) 1 . 530 1 (45_J>0.304) 0.300) .0.294) 0.334) 0.312) 5.6)1.493) 1.242) 1.169) 1.109) 1.456|<527p1.091) 1.055 1.016) 1.022) 1.044) 2.9)1.235) 1.026 0.966) 0.999) 1 . 353 ) (jjO-Tj)2.435) 2.347) 2.355) 2.436) 2.391) 1.8*1.460) 1.412) 1.355) 1.404) 1.418) 3.0|1.393) 1.292 1.372) 1.422) 1.327) 8.1)1.230) 1.230) 1.244) 1.275) 1.219) 7.2*1.283) 1.219) 1.210) 1.238) 1.183) 10.5)1.118| 1.06S 1.073) 1.106) 1.043) 10.5)1.199) 1.143) 1.145) 1.181) 1.123) 9.0)

0.524) 0.464) 0.412) 0.412) 0.467) 12.0)1.215) 0.978) 0.879) 0.792) 1.079) 27. 6|2.313) 2.045) 1.901) 1.852) 2.224| 21. 3|1.707) 1.494) 1.374) 1.311) 1.515) 11. 8)1.146) 1.011) 0.951) 0.901) 1.020) 9.8|0.411) 0.341 0.300) 0.272) 0.354) 20.51

1 I I I I

(1) Cannot be separated from Diphenylamine

RR309298

7BSEMT/OLATILS CONTINUING CALIBRATION CHECK

Lab Name: NYTEST SNV INC________ Contract: 63-W8-0049


Instrument ID: B_____ Calibration date: 08/02/90 Time: 0944

Lab File ID: B1343____ Init. Calib. Date(s): 07/31/90 07/31/90

Min RRF50 for S?CC(*} = 0.050 Max %D for CCC(*) - 25.0%

_4

•

B

0QnV.-.m

-I 1 COMPOUND | RRF |RRF50 | %DJ | _-_._.__,._________,.*-*__-»-,_____-.____ I — — - —____, I __________ I ____I 3 33i3i3s3 —•—*——•3S33ssai3 3»53;M5M3i3—isc j xsacs aR i *Baos33B I 33931x33

[Phenol ________* 1.538) 1.780)-15.7T 1 bis (2-Chloroethyl) Ether___| 1.469) 1.671)-13.8

\2-Chlorophenol.|1,3-Dichlorobenzene______)1,4-Dichlorobenzene______[Benzyl Alcohol_________|1,2-Dichlorobenzene______|2-MethyLphenol_________|bis(2-Chloroiscpropyl)Ether|4-Methylphenol_________

1.263) 1.429|-12.71.27S| 1.408|-10.31.254) 1.4191-12.30.861) 0.9501-10.31.315) 1.434) -9.01.062) 1.244|-17.13.626) 3.867) -6.60.925) 1.090|-17.8

|N-Nitroso-Di-n-?ropylamir.e__ 1.266) 1.431)-13.00.6591 0.778|-18.10.452| 0.5251-15.20.885) 0.991|-12.00.231) 0.2541-14.30.357) 0.404|-13.20.214) 0.223) -4.20.539) 0.637J-1S.20.294) 0.334|-13.S0.320) 0.3521-10.00.835) 0.9711-16.30.415) 0.479|-15.4

|Hexachlorobutadiene_____* 0.193) 0.208) -7.814-Chloro-3-Methylphenol__* 0.364) 0.413)-13.512-Methylnaphthalene_____| 0.534) 0.600)-12.4|Hexachlorocyclopentadiene_* 0.330) 0.341) -3.3|2,4,S-Trichlorophenol____* 0.397) 0.455)-14.6

|Hexachloroethane_______|Nitrobenzene__________|Isophorone____________| 2-Nitrophenol____________|2,4-Dimethylphenol_____[Benzoic Acid___________[ bis (2-Chloroethoxy )Methar.e_|2,4-Dichlorophenol________|1,2,4-Trichlorobenzene__|Naphthalene__________I4-Chloroaniline______

|2,4,5-Trichlorophenol_)2-Chloronaphthalene__|2-Nitroaniline_____(Dimethyl Phthalate__|Acenaphthylene_____|2,6-Dinitrotoluene__13-Nitroaniline______

0.400) 0.493|-23.31.017) 1.174)-15.40.596) 0.832|-19.51.545) 1.693) -9.61.349) 1.605|-19.00.612) 0.6981-14.10.457) 0.549J-20.1

| Acenaphthene___________* 1.014) 1.1781-16.2)2,4-Dinitrophenol_______* 0.138) 0.111) 19.6 *14-Nitrophenol___________* 0.132| 0.137| -3.8 *I_____________________I____I____I____1

FORM VII SV-1

7CSEMIVOLATILE CONTINUING CALIBRATION CHECK

Lab Name: NYTEST ENV INC________ Contract: 68-W8-0049

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SD<3 No.: CDE56

Instrument ID: B_____ Calibration data: 08/02/90 Time: 0944

Lab File ID: B1343____ Init. Calib. Date(s): 07/31/90 07/31/90

Min ERF50 for S?CC(*) - 0.050 Max %D for CCC(*) - 25.0%

1 1| COMPOUND |

(Dibenzofuran ' 1|2.4-Dinitrotoluene 1| D ie thvlphthalate 11 4-Chlorophenyl-phenylether_|iFluorene 1| 4-Nitroaniline 1| 4,6-Dinitro-2-Methylphenol_J|N-Nitrosodiphenylamir_e (!)__*1 4-3rcmophenyl-phenylether _ |IHexachlorobenzene 1i ? entachlo rccheno 1 *1 Phenanthrene 11 Anthracene 1i Di-n-Butylphthalate 11 Fluoranthene *1 Pyrene 11 Butvlbenzylphthalate 11 3 , 3 ' -Dichlorobenzidine ___ |1 Benzo (a) Anthracene |1 Chrvsene 1| b is ( 2-Ethylhexyl ) Phthalate.. |iDi-n-Octyl Phthalate *[ Benzo (b) Fluoranthene |1 Benzo (k)Fluoranthene 11 Benzo fa) Pyrene *| Indeno (1,2, 3-cd ) Pyrene . ||Dibenz(a,h)Anthracene |1 Benzo (g,h,i)Perylene 1| «M««-3,««MMMSM=3W1 Nitrobenzene-d5 |1 2-Fluorobiphenyl 11 Terphenyl-dl4 1lPhenol-d5 11 2-Fluorophenol |1 2 , 4 , 6-Tribromophenol 11 1

__ 1 1RRF |RRF50 | %D______ i _ _ .____ i ___»»» | .»»,. [ »»»1.526) 1.714)-12.30.612) 0.698|-14.11.706) 1.967|-15.30.382) 0.448|-17.30.810) 0.9661-19.30.414| 0.427| -3.10.141| 0.144| -2.10.428) 0.487|-13.30.202) 0.2341-15.80.283) 0.327|-15.60.155) 0.1761-13.60.8431 0.967|-14.00.882) 0.980|-11.11.4691 1.692J-15.20.983) 1.056) -7.44.146) 3.999) 3.51.630) 1.994|-22.30.312) 0.269) 13.81.455) 1.541) -5.81.044) 1.110) -6.31.358) 1.414) -4.12.391) 2.537) -6.11.418) 1.478) -4.21.327) 1.516|-14.21.219) 1.344)-10.31.183) 1.304|-10.21.043) 1.149 |-10.21.123) 1.268|-12.9

0.467) 0.5381-15.21.079) 1.2171-12.82.224| 2.3611 -6.21.5151 1.7831-17.71.020) 1.2151-19.10.354] 0.410|-15.8

1 1

(1) Cannot be separated from Diphenylamine

$> Z) £ z.

cC

flR309300FORM VTT sv-2 1/87 .Rev.. n rt

3DSOIL SEMIVOLATILE MATRZZ SPIKE/MATRIX SPIKS DUPLICATE RECOVERY

Lab Name: NYTEST BNV INC________ Contract: 68-W8-0049

: NYTEST Case No.: 14442 SAS No.: _____ SDG No.: CDE56

Matrix Spike - EPA Sample No.: CDE60_________ Level: {low/med) LOW

COMPOUND

Phenol2-Chlorophenol1 . 4-DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene_4-Chloro-3-methylphenolAcenaphthene4-Nitrophenol2, 4-Dinitro toluene ___PsntachlorophenolPvrene

SPIKEADDED(ug/Kg)

93809380469046904690938046909380469093304690

SAMPLE | MS! CONCENTRATION | CONCENTRATION

( ug/Kg) J { ug/Kg)-,3, 33 ^mmmaxsKm 1 m — ——

0 |0 |0 |0 |0 |0 |0 |0 |0 |0 |0 |

1

51604830275029502560450027404230251030301360

MS | QC j| % | LIMITS |REC *| REC. |

55 (26- 90)51 125-102)59 |2S 104 |63 |41 126|55 138 107|48 |26 103153 [31-137145 (11-114|54 |28- 89)32 |17-109)(29)* 1 35-142 1^ 1 1

)MPOUND

Phenol2-Chlorophenol1 , 4-D ichlorobenzene ___N-Nitroso-di-n-prop. (1)1,2, 4-Trichlorobenzene_4-Chloro-3-methylphenolAc enanh thene4-Nitrophenol2, 4-Dinitro toluene ___PentachlorophenolPvrene

SPIKE | MSDADDED ) CONCENTRATION(ug/Kg) | (ug/Kg)....—..I. ..„,...„.,9380 | 51109380 | 47404690 | 28004690 | 30404690 | 25709330 | 44004690 | 26309380 | 46904690 | 25109380 | 32504690 | 1320

1

MSD%REC *,..„,54516065574756505435©*

%RPD #—— ——

20-2-3-424

-110-94

1QC LIMITS |RPD | REC. 1

35 |26- 90 150 I25-102J27 |28 104138 |41 126 |23 |38 107 |33 126 103J19 |31-137150 | 11-114|47 (28- 89J47 |17-109|36 | 35-142{

1 1

(1) N-Nitroso-di-n-propylamine

# Column to be used to flag recovery and RPD values with an asterisk* Values outside of QC limits

RPDs _0_ out of 11 outside limitsSpike Recovery: _2_ out of 22 outside limits

FORM III SV-2

000183

3FSOIL PESTICIDE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY


Lab Code: NYTEST Case No.: 13442 SAS No.: _____ SOG No.: CDE55

Matrix Spike - EPA Sample No.: CDE50_____ Level: (low/med) LOU

"COMPOUND

gamma— 8HC (Lindane) ___HeotacnlorAldrinDisldrinEndrin4, 4 '-DOT

SPIKEADDED(ug/Kg)

37.137.137.192.592.692.5

| SAMPLE| CONCENTRATION1 (ug/Kg)

•1

1 01 0

1 01 01

MSCONCENTRATION

(ug/Kg)

13.531.747.392.687.145.2

MS | QC |% | LIMITS]

REC #| REC. |

50 ) 46-127)85 | 35-130 ]

123 | 34-132|100 (31-134]94 | 42-139|49 (23-134]

1 1

COMPOUND

gamma-BHC (Lindane) _HeotachlorAldrinDieldrinEndrin4, 4 '-DOT

| SPIKE| ADDED1 (ug/Kg)

_l 37.1| 37.1| 37.1| 92.6| 92. S| 92.61

MSD |; CONCENTRATION)

(ug/Kg) |1'

12.0 |23.3 |47.3 172.5 |68.3 |

1 30.5 11

MSO%

REC ft,

\22)"53128787433

%RPO #

43310242439

QCRPO

503143384550

1LIMITS || REC. |

|46-127|)35-130|| 34-132)|31-134|1 42-139 || 23-13 4 |1 1

# Column to be used to flag recovery and RPO values with an asterisk

• j * Values outside of QC limits

O R P D : _0 out of _6 outside limitsSpike Recovery: _1 out of 12 outside limits

i"'.' COMMENTS:

AR309302FORM III PEST-2 • 8/87 Rev.

000373

fl

0

n

80PESTICIDE EVALUATION STANDARDS SUMMARY

Lab Name: NYTEST ENV INC_________ Contract: _____________04_9_

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SOQ No.; CDE56

Instrument ID: HP5380 • QC Column ID: D8-1701

Dates of Analyses: 08/01/90 to 08/02/90

Evaluation Check for Linearity

PESTICIDE

AldrinEndrin4,4' -DOT ___08C

CALIBRATIONFACTOREVAL MIX A

5600000546000043300005100000

i CALIBRATION| FACTOR) EVAL MIX B

| 6670000| 5300000| 4900000| 54200091

CALIBRATIONFACTOREVAL MIX C

———— —————| 8420000655000065300005710000

%RSD |«/- 110.0%) |• i ~^ • I2^^ i9.4 |

5*6 |1

"^ (1) If > 10.0% RSO, plot a standard curve and determine the ngf^ far each sample in that set from the curve.

Evaluation Check for 4,4'-DOT/Endrin Breakdown(percent breakdown expressed as total degradation)

111| INITIAL

01 I EVAL MIX B02) EVAL MIX B

1

DATEANALYZED

08/01/9008/02/90

| TIME| ANALYZED

= )___=____11 2303| 12211

| ENDRIN11

1| 3.91 4.71

4,4'-DDT|COMBINED1 (2)I

17.1 |6.5 1

1

(2) See Form instructions.

AR309303FORM VIII PEST-1 8/87 Rev.

r-

9PESTICIDE/PCS STANDARDS SUMMARY


Lab Code: NYTEST Case No.: 14442 SAS No.: ______ SDQ No.: CDE56

Instrument ID: HP5390 QC Column ID: D8-508

1| COMPOUND11)alpha-8HCIbeta-BHC ____|delta-8HC ___| garrma— 3HC ___|Heptachlor1 Aldrin|He?t. epoxide|E.-dosulfan I_lOisldrin|4.4'-DDE[Endrin ____[Er.dosulfan II| 4 , 4 ' -000 ____|Endo. sulfate| 4 , 4 ' -DOT ____| Methoxychlor_| Endrin ketone|a. Chlordane_|g. Chlordane_) Toxaphene ___|Aroclor-1016_|Aroclor-1221_)Aroclor-1232_)Aroclor-1242_|Aroclor-1248~)Aroclor-1254__)Aroclor-1260~1

OATE(S). OF FROM: 07/27/90ANALYSIS TO: 07/27/90TIME(S) OF FROM: 1425ANALYSIS TO: 2107

) RT |RT | WINOOU (CALIBRATION

( FROM ( TO | FACTOR

11.89| 11.801 11.98[ 544000013.53| 13.391 13.S1| 266000014.74) 14.63) 14.85) 227000013.25) 13.15) 13.37) 520000014.35) 14.25) 14.46) 488000015.47) 15.38) 15.55) 464000017.39) 17.20) 17.43) 335000018.43| 1S.32| 13.54( 328000019.41| 19.31) 19.51) 263000019.13| 19.02| 19.24| 300000020.57( 20.46) 20.53[ 2170000 .21.12) 21.02) 21.22) 194000020.86) 20.75) 20.97[ 158000022.51| 22.41| 22.61) 128000021.79) 21.53) 21.89) 170000024.91) 24.82) 25.00) 54000025.48) 25.381 25.53) 218000018.33) 18.22) 18.44) 476000017.82) 17.70) 17.94) 464000021.24) 21.10) 21.33) 9300014.43) 14.33) 14.53) 29900011.76) 11.66) 11.86) 9330014.43) 14.33) 14.53) 13200014.391 14.29| 14.49) 25000017.53) 17.43) 17.53) 16300021.77) 21.68) 21.86) 14300023.50) 23.39) 23.61) 247000

1 1 I

DATE OF ANALYSIS 07/28/90TIME OF ANALYSIS 0256EPA SAMPLE NO.(STANDARD) INOA

RT

13.2614.3615.4717.3018.4319.41

21.12

21.7924.90

CALIBRATION ) QNT | %0FACTOR

500000046300004523000305000028500002250000

1623000

1530000600300

Y/N

YYYYYY

Y

YY

3.84.12.69.0

13.114.5

/O(is.s/

10.06.3

Under QNT Y/N: enter Y if quantitation was performed, N if not performed.%0 must be less than or equal to 15.0% for quantisation, and less thanor equal to 20.0% for confirmation.

Note: Determining that no compounds were found above the CRDL is a form ofquantitation, and therefore at least one column must meet the 15.0% criteria.

For multicomponent analytes, the single largest peak that is characteristicof the component should bs used to establish retention time and %0.Identification of such analytes is based primarily on pattern recognition.

page 1 of 2FORM IX PES$ H 0093U4 8/87 Rev.

8

r\i

ri.,

0n

10 EPA SAMPLE NO.PESTICIDE/PCS IDENTIFICATION _____________

I ]| COE57 |

Lab Name: NYTEST ENV INC_________ Contract: 68-U8-0049 | !

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SOQ No.: CDE56

QC Column ID (1): D8-608 ' GC Column ID (2): DB-1701

4 Instrument ID (1): HP5890 Instrument ID (2): HP5880

Lab Sample ID: 5256001_____O| 4. Lab File ID: •_____ (only if confirmed by GCMS)

PESTICIDE/PCB RETENTION TIME RT WINDOW QUANT? GC/MS?OF STANDARD (Y/N) (Y/N)FROM TO

01 Aroclor-1243 Column 1 17.53 17.43 17.63 Y N

02 Column 2 12.25 12.23 12.29 N N

Comments:

page 1 of 1FORM x PEST «R309305 1/87 Rev"

C00413


I I| V81KD7 |

Lab Name: NYTEST ENV_INC_________ Contract: 68-U18-0049 |____________1

Lab Code: NYTEST Case No.: _}_________ SAS No.: ______ SOQ No.: J___E56_

Matrix: (soil/water) WATER Lab Sample ID: V8LKD7_____

Sample wt/vol: 5.3 (g/mL) JU.__ Lab File ID: D2301

Level: (low/med) LOU! Date Received: ____

G

flp


Column: (pack/cap) PACK, Dilution Factor: 1.3___


| 74-87-3 ———74-83-9 ———| 75-31-4 ———75-00-3 — — •

67-64-1 ———| 75-15-0 ———75-35-4 ———| 75-34-3 ———540-59-3 ——| 67-66-3 ———137-36-2 ——

1 7P O*5 O

71-55-6 ———1 ^ ff " "P

108-35-4 ——| 75-27-4 ———78-87-5 ———| 10361-31-5-79-01-6 ———

) 124-48-1 ——| 79_0g_5 ———| 71-43-2 ———| 10361-32-6-| 75-25-2 ———| 138-10-1 ——| 591-78-6 —| 127-18-4 ——1 7n ... ji,..| 108-88-3 ——| 138-93-7 ——| 133-41-4 ——| 103-42-5 ——| 1330-20-7—1

———— Chlo rome thane———— Bromome thane———— VinvL Chlorida———— Chlo roe thane———— Mathvlane Chloride———— A c e to n e———— Carbon Oisulfide———— 1,1-0 ichlo roe thene———— 1.1-Oichloroethane———— 1,2-Oichloroethene (total) __———— Chloroform———— 1,2-Dicnloroethane———— 2-3utanone• ———— 1 . 1 . 1-Tricnloroe thane———— Carbon Tetracnloride———— Vinvl Acetate———— 8 romod ichlo rome thane———— 1 , 2-Dichloropropane———— cis-1, 3-D ichlo ropropene ____———— Tr ichlo roetherie———— Qibromochlo rome thane———— 1,1,2— Tr ichlo roe thane———— Benzene———— Trans-1, 3-D ichlo rooropene———— B r omo f o rm———— 4-Methyl-2-Pentanone———— 2-Hexanone———— Tetrachlo roe thene———— 1,1,2,2-Tetrachloroethane ___———— Toluene———— Chlo robenzene———— Ethylbenzene———— Styrene———— Xylenes (total)

13131313

135c5c551355

13555555555

10135555555

1lulu-IUlulu-IUlu|ulu-lululululu|u|ulu|uluIU|u|u|u|u|uIU|u|u|u|ulu|u|ulu


flR3°9306 000152

Q

r1

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______________

TENTATIVELY IDENTIFIED COMPOUNDS | |- _. . | VBLKD7 |

Lab Name: NYTEST ENV INC_________ Contract: 68-408-0049 | ___ I


Matrix: (soil/water) WATER Lab Sample ID: VBLKD7

Sample wt/vol: 5.3 (g/mL) ML_ Lab File ID: JD2301.

Level: (low/med) LOW Date Received: ____



nCONCENTRATION UNITS:

Number TICs found: _ 0 (ug/L or ug/Kg) UG/L

CAS NUMBER | COMPOUND NAME | RT | EST. CONC. | Q |


5R309307 000153

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______________

I| VBLKD8 |

Lab Name: NYTEST ENV INC_________ Contract: 63-U8-0049 |____________

Lab Code: NYTEST Case No.: 144A2 SAS No.: ______ SOG No.: CDE56

Matrix: (soil/watar) SOIL Lab Sample ID: VSLKD8___

Sample wt/vol: 5.3 (g/mL) G__ Lab File ID: D231S



Column: (pack/cap) PACK Dilution Factor: 1.3

n


j 74-37-3 — —— — -| 74_S3_g _____| 75-31-4 — — — —| 75-38-3 —————I 7^- ftQ ~>-_. rr

| 57-64-1 -— ——| 75-15-3 — — — —| 75 35 41 7 -. i, n ,.>\ C .1 (3 CO ft

\ 67-66-3 —————| 107-06-2 ————| 78-93-3 ————— -| 71-55-6 —————| 56-23-5 —————| 108-35-4 — — —| 75-27-4 —————IT O OT C

| 10361-01-5 — —[ 79-31-6 — — —— -| 124-48-1 ————| 79-03-5 —————| 71-43-2 —————| 13361-02-6 ———I7C *7C •t

\ 108-13-1 —— ——| 591-78-6 — ———( 127-18-4 ————| 79-34 5| 108-88-3 ————\ 108-90-7 ————| 100-41-4 ————| 100-42-5 — ——( 1330-23-7 ——— -1

—— Chlo roma thane—— Brcmcme thane—— Vinyl Chloride—— Chlo roe thane—— MsthyLsne Chloride—— Acatone—— Carbon Disulfide—— 1,1-Dichlc roe thene—— 1.1-Oichloroethane—— 1,2-Oichloroethene (total)—— Chloroform—— 1 ,2-Oichloroethane—— 2-Butanone—— 1 . 1 , 1-Tr ichlo roe thane—— Carbon Tetrachloride—— Vinyl Acetate—— Bromodicnlo rome thane—— 1.2-OichlorooroDane—— cis-1.3-0ichlo ropropene— Trichlo roe thene—— Dibromochlo rome thane—— 1,1.2-Tr ichlo roe thane—— Benzene—— Trans-1 , 3-Oichloropropene ___—— Bromoform—— 4-Metnyl-2— Pentanone—— 2-Hexanone—— Tetrachlo roe thene—— 1,1,2,2-Tetrachloroethane ___—— Toluene—— Chlo robenzene— Ethylbenzene—— Styrene— Xylenes (total)

101013105

135555551355

10555555555

13105555555

1lululu|ulululululululululululu|ulululu|ulululululululululululululu|u1

FORM I VOA 1/87 Rev

- BR309308

c.Qn-


TENTATIVELY IDENTIFIED COMPOUNDS j |' | VBLKD8 [

Lab Name: NYTgST ENV INC_________ Contract: 63-U8-3049 )____________|

Lab Code: NYTEST Case No.: 14442._ SAS No.: ______ SDG No.: CDE56_

Matrix: (soil/water) SOIL Lab Sample ID: V8LKD8______

Sample wt/vol: 5.3 (g/mL) G___ Lab File ID: D2316

Level: (low/med) LOW . Date Received: ____

n% Moisture: not dec. ___ Date Analyzed: 07/13/90———

*' Column (pack/cap) PACK Dilution Factor: 1.3___

n-J CONCENTRATION UNITS:

Number TICs found: _0 (ug/L or ug/Kg) UG/KG

CAS NUMBER1

COMPOUND NAME | RT--_. . .. . . i

1

EST. CONC. | Qi ...

1


flR309309 OOC161

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET —————————————

I I| CDE60MS |

Lab Name: NYTEST ENV INC_________ Contract: 63-U8-0049 | ———————————— I

Lab Code: NYTEST Casa No.: 14442 SAS No.: ______ SDG No.: ___________


Sample wt/vol: 5.3 (g/mL) G___ Lab File ID: D2321


% Moisture: not dec. _28 Oats Analyzed: 37/13/93



1| 74-37-3 ———| 74-83-9 ———| 75-3 1-4 — ~| 75-33-3 ———| 75-09-2 ———| 67-64-1 ———| 75-15-3 -——| 75-35-4 ———| 75-34-3 ———1 ^A&I .^n ...a.,, ,| 67-65-3 ———| 107-36-2 ——| 78-93-3 ———| 71-55-6 ———| 56-23-5 ———| 138-35-4 ——| 75-27-4 ———| 78-87-5 ———| 13361-31-5-( 79-31-6 ———| 124-48-1 ——

( 71-43-2 ———| 10361-02-6-| 75-25-2 ———| 138-13-1 ——| 591-78-5 ——| 127-18-4 ——

| 138-88-3 ——| 138-90-7 ——[ 100-41-4 ——| 130-42-5 ——| 1330-23-7—1

1———— Chlo rome thane——— Brcrnomethane I——— Vinvl Chloride——— Chloroetnane 1———— Metnylane Chloride———— Acatone———— Carbon Disulfide———— 1.1-0 ichlo roe thene——— — 1.1-0 ichlo roe thane———— 1,2-Dichloroethene (total)———— Chloroform——— 1.2-Dichlo roe thane———— 2-3utanone———— 1,1,1-Trichloroethane———— Carbon Tetrachlorida——— Vinvl Acetate———— Bromodichlo rome thane——— l.2-0ichloropropane———— cis-1. 3-D ichlo ropropene———— Tr ichlo roe thene———— Dibromochloromethane •———— 1.1,2-Tr ichlo roe thane———— Benzene——— Trans-1 , 3-Oichloropropene ___——— Bromoform———— 4-Methyl-2-Pentanone——— 2-Hexanone———— Tetracnlo roe thene———— 1 ,1,2, 2-Te trachlo roe thane ___———— Toluene———— Chlo robenzene— — — Ethylbenzene———— Styrene

Xylenes (total)

141414147

14777777147

1477777

777

14147777777

1

1luIU|u|ulu|u|u|u|u|ululu|ulu|u|ulu|ulu|uluiu|u|ulu|u|u|u|u|u|u|ulu|u1


ftR3093IO • .000168


I| CDE60MSD

Lab Name: NYTEST ENV INC_________ Contract: 68-UJ3-0049 |____________


Matrix: (soil/watsr) SOIL Lab Sample ID: 5256336__

Sample wt/vol: 5.3 (g/mL) J__ Lab File ID: D2322


D% Moisture: not dec. _28 Date Analyzed: 07/13/90———


i;•L

Qn


74 87 3~7 A OO f\

75-31-4 —————75-30-3 —————75-39-2 ————67-54-1 —————75-15-0 —————75-35-4 —————75-34-3 —————543-59-3 ————67—65—3 — — — — —137-36-2 ————78-93-3 —————71-55-6 —————55-23-5 —————•i no ac n

75-27-4 ————78-87-5 —————13361-01-5 ——79-31-6 —————124-48-1 ————79-33-5 —————71-43-2 —————13361-32-6 ——75-25-2 —————138 13-1591-78-6 ————127-18-4 ————79-34-5 ————138-B8-3 ————138-93-7 ————133-41-4 ————103-42-5 ————1333-23-7 ———

—— Chlo rome thane—— Brcmomethane—— Vinvl Chloride—— Chloroe thana—— ilethylene Chloride—— Acatone—— Carbon Oisuifide—— 1,1-Oichlo roe thene—— 1 ,1-Oichloroethane—— 1,2-Oichlorcethene (total) __—— Chloroform—— 1,2-0 ichlo roe thane—— 2— autanone—— 1.1.1-Tr ichlo roe thane—— Carbon Tetrachloride—— Vinyl Acetate—— Bromod ichlo rome thane—— 1.2-Dichlorooropane—— cis-l,3-Dichlo ropropene—— Tr ichlo roe thene—— Dibromocnlo rome thane—— 1 , 1 , 2-Trichloroe thane—— Sanzene—— Tr ans-1, 3-D ichlo roorooene—— Bromoform—— 4-Methyl-2— Pentanone—— 2-Hexanone—— Tetrachloroe thene—— 1 .1.2. 2-Te trachloroethane—— Toluene—— Chlo robenzene—— Ethylbenzene—— Stvrene—— Xvlenes (total)

141414147

147777771477

14777777777

14147777777

1lululululu|ulu|ulu|ulu|ululu|uiulu|u|u|u|u|ulululululu|uiuiulu|ululu1


8R3093H 000174

IB EPA SAMPLE NO.SEMIVOLATILS ORGANICS ANALYSIS DATA SHEET ____________

I 1| SBLX2 1

Lab Name: NYTSST ENV INC_________ Contract: 68-W8-0049 |____________|

Lab Code: NYTEST_ Case No.: 14442 SAS No.: _____ SDG No.: CDE56

Matrix: (soil/water) SOIL Lab Sample ID: SBLK2______

Sample wt/vol: 30.0 (g/aiL) G__ Lab File ID: B1344

Level: (low/med) LOW Date Received: _____

% Moisture: not dec. __ dec. ___ Date Extracted: 07/13/90


GPC Cleanup: (Y/N) _J_ pH: 7.0 Dilution Factor: 1.00


108-95-2 ——— •111-44-4 ——— -95-57-8 ——— -541-73-1 ——— -10S-46-7 ——— •100-51-6 ——— -95-50-1 ———95-43-7 ——— -

105-44-5 ——— -621-54-7 —— -67-72-1 ——— -

78-59-1 ——— -83-75-5 ————105-67-9 ——— •65-85-0 ————111-91-1 ——— -120-83-2 ———120-82-1 ——— •91-20-3 ————106-47-8 ——— •

59-50-7 ———— •91-57-6 ————77-47-4 ——— •OO f C.

95-95-4 ——— -91-53-7 ———88-74-4 ——— •131-11-3 ———208-96-8 ——— -606-20-2 ———

—— Phenol—— bis ( 2-Chloroethyl ) Ether—— 2-Chlorophenol—— 1,3-Dichlorobenzene—— 1 , 4-Dichlorobenzene• — Benzyl Alcohol—— 1,2-Dichlorobenzene—— 2-Methylphenol—— bis (2-Chloroisopropyl) Ether _—— 4-Methylphenol—— N-Nitroso-Di-n-Propylaraine—— Hexachlorcethane—— Nitrobenzene—— Isophorone—— 2-Nitrophenol—— 2 , 4-Dimethylphenol—— Benzoic Acid—— bis ( 2-Chloroethoxy) Me thane—— 2 , 4-Dichlorophenol—— 1,2, 4-Tr ichlorobenzene—— Naphthalene—— 4-Chloroaniline—— Hexachlorobutadiene—— 4-Chloro-3-Methylphenol ____—— 2-Methylnaphthalene—— Hexachlorocyclopentadiene ___—— 2 , 4 , 6-Trichlorophenol—— 2 , 4 , 5-Trichlorophenol—— 2-Chloronaphthalene—— 2-Nitroaniline—— Dimethyl Phthalate—— Acenaphthylene—— 2r6-Dinitrotoluene .

330330330330330330330330330330330330330330330330160033033033033033033033033033033016003301600330330330

1IUIUIU

IUIUIUIUIUIU

iuIUIUIUIUiuIUIUIUIU|uiuiu|uiuiuiuiuiuiuiu|u1

FORM I SV-1 a D O H Q O t o 1/37 Rev.AR30.93I2000345

1C EPA SAMPLE NO.SEMTVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

- - I I'• • • | SBLK2 |

Lab Name: NYTEST ENV INC________ Contract: 68-W8-0049 |___________

Lab Code:. NYTEST Case No.: 14442 SAS No.: _____ SDG No.: CDB56

Matrix: (soil/water) SOIL Lab Sample ID: SBLK2



i:

% Moisture: not dec. __ dec. __ Date Extracted: 07/13/90


GPC Cleanup: (Y/N) N_ pK: 7.0 Dilution Factor: 1.00


99-09-2——————3-NitroaniIine_________83-32-9——————Acenaphthene__________51-23-5——————2,4-Dinitrcphenol______100-02-7—————4-Nitrophenol_____________132-64-9—————Dibenzofuran___________121-14-2—————2,4-Dinitro toluene______84-66-2——————Diethylphthalate________7005-72-3—————4-Chlorophenyl-phenylether_86-73-7——————Fluorane______________100-10-5—————4-Nitroaniline_________534-52-1—————4,S-Dinitro-2-Methylphenol_

1600 JU330 )U1600 |U1600 |U330 ]U330 |U330 |U320 (U320 |U

1600 |U1600 [U

86-30-6——————N-Nitrosodiphenylamine (1)__| 330 |U101-55-3—————4-Bromophenyl-phenylether__| 320 {U

ILJ

f i | 84-74-2——————Di-n-3utylphthalate 330 j'u

IU

Q-T Q<;_E;_____Q C /* 1 Q85-01-8 --——

84-74-2 ————206-44-0 — —129-00-0 ———an ca_~i91-94-1 ————56-55-3 ———O O rt-1 Q218-01-9 ———m— fit — ~7__ __ .117-84-0 ———205-99-2 ———207-08-9 ———50-32-8 ———193-39-5 ———53-70-3 ———191-24-2 ———

—— Pentachlorophenol—— Phenanthrene

—— Di-n-Butylphthalate—— Fluoranthene—— Pyrene—— Butylbenzylphthalate—— 3 , 3 ' -Dichlorobenzidine—— Benzo (a) Anthracene—— Chrysene—— bis ( 2-Ethylhexyl ) Phthalate __—— Di-n-Octyl Phthalate—— Benzo ( b ) Fluoranthene—— Benzo ( k ) Fluoranthene- —— Benzo ( a ) Pyrene—— Indeno ( 1 . 2 , 3-cd ) Pyrene—— D ibenzf a, h) Anthracene—— Benzo ( a , h , i ) Perylene

1600330Ww *U

Ww%/

330330330f f f\560330•5-30WWW

330•5-SCJOwv•9-30WWW

w-7"5-3flWWW

330O-3C(

330

iuIU|Uiu|ulu|uI_


FORM I SV-2 H R 3 0 9 3 i 3 1/87 Rev.

n

IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

TENTATIVELY IDENTIFIED COMPOUNDS | || SBLK2 |

Lab Name: NYTSST ENV INC________ Contract: 68-W8-0049 )___________|

Lab Code: NYTSST Case No.: 14442 SAS No.: _____ SDG No.: CDE56

Matrix: (soil/water) SOIL Lab Sample ID: SBLK2_____



% Moisture: not dec. __ dec. ___ Date Extracted: 07/13/90


GPC Cleanup: (Y/N) N_ pH: 7.0 Dilution Factor: 1.00__


1| CAS NUMBER

1 1.1

COMPOUND NAME

i UNKNOWN

1RT |

a—— .«..|-13.47 |

1

I 1EST. CONC. ) Q

1 i1 s 1

170 |J1 1

FORM I SV-TIC 1/87 Rev.A-R3093II*

000347

IB EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

I) CDE63MS |

Lab Name: NYTEST ENV INC _________ Contract: 63-U8-3349

Qn

Lab Code: NYTEST Cass No.: 14442 SAS No.: ______ SDG No.: CDE56


Sample wt/vol: 33.3 (g/mL) J __ Lab File ID: S1349

Level: (low/med) LOU Data Received: 37/11/93

% Moistura: not dec. _29 dec. ___ Date Extracted: 37/13/93

Extraction: (.SepF/Cont/Sonc) SONC Data Analyzed: 38/32/93n

•i GPC Cleanup: (Y/N) _N_ pH: 7.5 Dilution Factor: 1.33


f i

,

108-95-2 ~—111-44-4 ———95-57-3 ——— -541-73-1 — —136-46-7 — —133-51-6 ———

95-48-7 ————'5QdT*5Q -3O Q

136-44-5 — —621-54-7 -——67-72-1 ————ao oc n7O C 3 -1

OO *7C C

135-67-9 ———65-35-3 ———111-91-1 ———123 33 2123-82-1 ———91-23-3 — ——136-47-8 ———87-63-3 — ——59-53-7 ————91-57-6 ———77-47-4 ———88-36-2 ———qc QC . A _ .

91-58-7 —— —88-74-4 — — —131-11-3 — —238-96-8 — —636-23-2 ———

—— -Phenol——— b is (2-Cnlcroethyl) Ether——— 2-Chlorophanoi——— 1,3-0 ichlo rob en zane

——— Benzyl Alcohol——— 1,2-Dichlorobenzene——— 2-Methylphenol——— bis (2— Chlo roisopropyl) Ether _——— 4-Methylohenol——— N-Nitroso-Oi-n-P ropy lamina __——— Hexachlo roe thane——— Nitrobenzene——— Isophorone——— 2-Nitrophenol——— 2 . 4-Oimethylphenol——— Banzoic Acid——— bis (2-Chloroethoxy) Methane __——— 2,4-Oichloropnenol——— 1, 2, 4-Tr ichlo robenzene——— Naphthalene——— 4-Chloroaniline——— Hexachlorobutadiene——— 4-Chloro-3-Methylphenol——— 2-Methvlnaohthalene——— Hexachlo rocyclopentadiene ___——— 2.4.6-Trichlorophenol• ——— 2 . 4 . 5-Trichlorophenol——— 2-Chloronaphthalene

——— Dimethyl Phthalate——— Acenaoh thy lane——— 2. 6-Oinitro toluene

4634634634634534634634634634634634634634634534632333463463453463463463463463463463

2333463

2333463463463

1lu|ulu|u|u|u|u|u|uiulu|ulululu|u|u|ulu|u|ulululululu|u|u|ululululu!


5 000356

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____________

I| CDE63MS |

Lab Name: NYTEST ENV INC__________ Contract: 68-U8-0049 I_______________

Lab Code: NYTEST Casa No.: 14442 SAS No.: ______ SOG No.: CDE56,


Sample wt/vol: 33.3 (g/mL) J__ Lab File ID: S1349

Level: (low/med) LOU1 Date Recaived: 37/11/93»



GPC Cleanup: (Y/N) N_ pK: 7.5 Dilution Factor: 1.33


99-39-2—83-32-9 ——51-23-5 —133-82-7—132-64-9-121-14-2—O A f l~ O

7335-72-3-86-73-7 ——133-13-6—CO <l_e'?_1

86-33-6 ——131-55-3-118-74-1—fl7 — p<? e:

85-31-8 ——123-12-7-ft A - 7 A ... "* —

*?fl£ .Id Oi

129-33-3—85-53-7 ——91-94-1 ——56-55-3 ——»•> •* o rt "t rt

117-81-7-117-84-3—235-99-2-237-38-9—Cffl -50 Q

193-39-5—53-73-3 —191-24-2-

————— 3— Nitroaniline————— Acanaph thane————— 2, 4-Qinit.-cohanol————— 4-Nitroohanol————— Oibanzofuran————— 2. 4-Oinit.-c toluene

————— 4-Chlorochanyl-phenylether————— Fluor ane————— 4-Nitroaniiine————— 4 , 6-Oini trc-2-Methy Iphenol————— N-Nitrosodiphenylamine (1) __————— 4-3romophenyl-pheny lather————— Hexachlo rcbenzene————— Pentachloropnenol————— Phenanthrene————— Anthracene————— Di-n-Butylontnalate————— Fluoranthene————— Pyrane———— Butylbenzvlphthalata————— 3 , 3 ' -Oichlorobenzidine————— Benzo (a) Anthracene————— Chrvsene————— bis (2-E thy Ihexyl) Phthalate __————— Di-n-Octyl Phthalate————— Benzo(b) Fluoranthene————— Benzo (k) Fluoranthene————— Benzo (a) Pyrene————— Indeno ( 1. 2. 3-cd) Pyrene———— Oibenz(a , h) Anthracene————— Benzo (q,h,i)Perylene

233345323332233453453453453453

233323334534504532333450463

2333460453463933453453513453463463463453463463

1|u|uIUlu|U|ulu|ulu|uiu|ulu|ulululu1luiululululu1lululululululu1

1111

111111111111111111111111111(1) - Cannot be separated from Diphenylamine

FORMisv-2 A R 30 93J6 1/87Rev-ODOSS7

13 EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET ____________

I| CDE63MSD |

Lab Name: NYTEST ENV INC_________ Contract: 68-W8-0349 I __

Lab Code: NYTEST_ Case No.: 14442 SAS No.: ______ SOG No.: CDE56



Level: (low/med) LQUJ__ Data Recsived: 07/11/90



GPC Cleanup: (Y/N) J__ pH: 7.5 Dilution Factor: 1.33___

i:

Ly


108-95-2 ——111-44-4 ———r) e- c- -7 n

541-73-1 ———106-46-7 ———100-51-6 — —95-53-1 ————95-43-7 ————39638-32-9—106-44-5 ———621-64-7 ——67-72-1 ———QP ne *i ___

70 ,.ec> 1 _„ .... ,

88-75-5 ———135-67-9 ———65-85-3 ———111-91-1 ———•1 O rt O *5 "

123-82-1 ———91-23-3 — ——136-47-8 ———p -r £Tp i

59-53-7 ———Q-t e -r f?

7 7 .. fl 7 _, /T _ -. i „ ,00 rtf? *-| M

95-95-4 —— —91-58-7 ———88-74-4 ————131-11-3 ———O t\ Q Q C p

636-23-2 ——

——— Phenol——— bis (2-Chioroe thy 1) Ether——— 2-Chlorochenol——— 1, 3-D ichlo robenzene——— 1, 4-Oichlorobanzene——— Benzyl Alcohol——— 1,2-Oichlo robenzene——— 2-Methylohenol——— bis (2-Chloroisopropyl) Ether _——— 4-iHethylphenol——— N— Nitroso— Oi— n— P ropy lamina——— Hexachlo roe thane——— Nitrobenzene——— Isoohorone——— 2-Nitrophenol——— 2 , 4-Dime thy Iphenol——— Benzoic Acid——— bis (2-Chloroethoxy) Me thane __——— 2, 4— Oichlorophenol——— 1 , 2 , 4-Trichlorobenzane——— Naphthalene——— 4-Chloroaniline——— Hexachlo robutadiena——— 4-Chloro— 3— Methylphenol——— 2-Methylnaphthalene——— Hexachlo rocyclopentadiene ___——— 2 , 4 , 6-Tr ichlo rophenol——— 2,4 ,5-Tr ichlo rophenol— —— 2-Chloronaphthalene——— 2-Nitroaniline——— Dimethyl Phthalate——— Acenaphthylene——— 2, 6-Oinitro toluene

460463463463.4634634634604604604634634604604604602333463450460463460460463460460463

2333460

2333463460460

1|ululu)u)u)ulu)ulululululululu|u|u|u|u|ulululu|ulu|ulu|ulululululu1 !


AR3093I7000363

n

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _____________

I| CDES3MSD |

Lab Name: NYTEST ENV INC__________ Contract: 63-U3-3049 |_____________

Lab Code: NYTEST Casa No.: 14442 SAS No.: ______ SDG No.: CDE56

Matrix: (soil/watar) SOIL Lab Sample ID: 5255036__

Sample wt/vol: 33.3 (g/mL) J__ Lab File ID: B1353

Level: (low/med) LOU Data Received: 07/11/93



GPC Cleanup: (Y/N) N_ pH: 7.5 Dilution Factor: 1.30___


99-09-2———————3—Nitrcaniline__________33—32—9———————Ac anaph thene____________51-28-5———————2,4-Oinitrophenol_______100-02-7—————4-Nitrophenol____._______132-64-9——————Qibanzofuran____________121-14-2——————2,4-Oinitro toluene_______84-66-2———————Oiathylphthalate__________7035-72-3—————4-Chlorophenyl-phenylether_36-73-7———————Fluor ene_______________130-10-6——————4-Nitroaniline__________534-52-1——————4,6-Dinitro-2-Methylphenol_86-33-6———————N-Nitrosodiphenylamina (1)_131-55-3——————4-8romcphenyl-phenylether_118-74-1——————Hexachlo robenzene_______87-86-5———————Pen tachlo rophenol_______85-31-8———————Phenanthrene____________123-12-7—————Anthracene_____________84-74-2———————Di-n-Butylphthalate______

2303 |U460 )U2330 |U2330 |U453 |U463 |U460 |U463 |U463 |U

2303 |U2333 |U463 ')U463 |U463 |U2303 )U450 )U463 )U

1533 |236-44-3——————Fluoranthene______________| 463 |U129-03-0——————Pyrene___________________) 460 |U

)UIU|U|UIIU|U|UU|ululu

______I_(1) - Cannot be separated from Diphanylamine

FORM I SV-2 3R3093 { 8 1/87 Rev-

85-53-7 ————91-94-1 ————56-55-3 ————218-01-9 ———117-81-7 — ——117-34-3 ———205-99-2 ———207-08-9 ———53-32-8 ————•i no -70 e ,. .

53-73-3 — ——191-24-2 ———

——— Butylbenzylphthalate——— 3.3' -Dichlorobenzidine——— Benzo (a) Anthracene—— Chrysene——— bis(2-Ethylhexyl)Pnthalate __——— Oi-n-Octyl Phthalate——— Benzo (b) Fluoranthene——— Benzo(k) Fluoranthene——— Benzo (a) Pyrene——— Indeno ( 1, 2, 3-cd) Pyrene——— Dibenz ( a, h) Anthracene——— Benzo(q,h,i)Perylene

463930460463650460'463463460460460463

000364

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____;__________

I I| PBLK31 |

Lab Name: NYTEST EJW INC___________ Contract: S8-U8-3049 |_____________|

Lab Code: NYTEST Case No.: 14442 SAS No.: _____ SOG No.: CDESS

Matrix: (soil/water) SOIL Lab Sample ID: PSLK01

Sample wt/vol: 33 (g/mL) j3__ Lab File ID: ________

Level: (low/med) LOU Data Received: _______

% Moisture: not dec. ___ dec. ___ Date Extracted: 37/13/93i...


' i GPC Cleanup: (Y/N) N_ pH: 7.3 Dilution Factor: J.______

n

L:

0n.


319-84-S — —319-85-7 ———319-86-3 -— —58-39-9 — — —76-44-3 ————309-03-2 ———1024-57-3 ——959-98-3 ———60-57-1 ————7O C C £*

72-20-3 ————33213-65-9 —72-54-8 ————1331-37-8 ——53-29-3 ————72-43-5 — ——53494-73-5—5103-71-9 ——5103-74-2 ——8001-35-2 ——12674-11-2 —11104-23-2 —11141-16-5 —53469-21-9 —12672-29-6—11397-69-1 —11096-82-5—

——— 3lpha-BHCu ,— .» _ O LJ f—

——— calta-SHC——— carnma-BHC (Lindane)'——— Heotachlor—— Aldrin——— Heotachlor epoxide—— Endosulfan I——— Oieldrin——— 4, 4 '-DDE——— Endrin——— Endosulfan II——— 4. 4 '-ODD——— Endosulfan sulfate

4. 4 '-DOT——— Methoxychlor——— Endrin ketone——— alpha— Chlo rdane——— aamma-Chlordane——— Toxaohene——— Aroclor-1316——— Arocior-1221——— Aroclor-1232——— Aroclor-1242——— Aroclor-1248——— Aroclor-1254——— Aroclor-1263

8.38.38.08.08.08.08.08.01616ISISISISISS3168083

1608080838380160160

1|uIUluluiuiu|u|u|u|u|u[u|u|ulu|uiu|uiu|u|uiu|uiulu|ulu1


8R3093I9 000484

10 EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ______________

I| CDE63MS

Lab Name: NYTEST ENV INC_________ Contract: 63-U3-0049 |____________


Matrix: (soil/water) SOIL Lab Sample ID: 525S03S

Sample wt/vol: 33 (g/mL) G___ Lab File ID: ________




GPC Cleanup: (Y/N) N_ p'H: 7.3 Dilution Factor: JL_____


*3 -i r\ "3 >i C

319-35-7 ————319-36-8 —— —58-89-9 — — —76-44-8 — — —309-30-2 ————1024-57-3 ———959-98-8 ————60-57-1 —————72-55-9 —————-70 ~>e\ o

33213-65-9 ——72-54-8 ————1331-07-8 ———50-29-3 ————72-43-5 ———53494-73-5 ——5133-71-9 ———5133-74-2 ———8331-35-2 ———12674-11-2 ——11134-28-2 ——11141-16-5 ——53469-21-9 ——12672-29-6 ——11097-69-1 ——| 11096-82-5 ——

—— aloha-BHC—— beta-BHC—— delta-BHC—— aatnma-BHC (Lindane)—— Heotachlor—— Aldrin—— Heotachlor eooxide—— Endosulfan I—— Oieldrin—— 4 , 4 ' -ODE—— Endrin—— Endosulfan II——— 4, 4 '-ODD—— Endosulfan sulfate—— 4. 4 '-DOT—— Methoxycnlor—— Endrin ketone—— alpha-Chic rdane—— qamma-Chlordane—— Toxaphene—— Aroclor-1016—— Aroclor-1221—— Aroclor-1232—— Aroclor-1242—— Aroclor-1248—— Aroclor-1254—— Aroclor-1263

.

111111111111111122222222222222

11322

113113223113113110113110220220

1|u|u)u|ulu|ulululu|ulululu|ulu|ulu|u|u|ulu|u|u|ululu|u1


SR309320 '000489

10 EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET _____________

I I| CDE60MSD |

Lab Name: NYTEST ENV INC__________ Contract: 68-W8-0049 I______________\

D

D

Lab Code: NYTEST Case .No.: 14442 SAS No.: ______ SDG No.: CDE5S

Matrix: (soil/water) SOI'. Lab Sample ID: 5256306__

Sample wt/vol: 33 (g/mL) G__ Lab File ID: _______

Level: (low/med) LCU Data Received: 37/11/93



. j GPC Cleanup: (Y/N) J__ pH: 7.3 Dilution Factor: J._______

i:DP

0

CONCENTRATION UNITS:CAS NO. CC.1POUND (ug/L or ug/Kg) UG./KG

319-84-6— ———319-35-7 —— —319-36-3 —— —53-89-9 —— —— -76-44-8 —— ——309-33-2 — ——1324-57-3 ———959-98-3 — — —60-57-1 ————72-55-9 — — —-72-23-3 —————33213—65—9 ——72-54-8 —————1331-37-8 ———53-29-3 —————72-43-5 —————53494-73-5 ——5133-71-9 ———5133-74-2 — —8031-35-2 ———12674-11-2 ——11134-28-2 ——11141-16-5 ——53469-21-9 ——12672-29-6 ——11097-69-1 ——| 11095-82-5 ——

—— sl^ha-BHC—— fceta-BHC—— dslta-BHC—— ca:Tma-BHC (Lindane)—— Kestacnlor—— Aldrin—— Hsotachlor eooxide—— Endosulfan I—— Dialdrin—— 4.4 '-DDE—— E.-drin—— Er.dosulfan II—— 4.4'-DOO—— Endosulfan sulfate—— 4. 4 '-DOT—— Methoxychlor—— Endrin ketone—— aiaha-Chlordane—— camma-Chlordane—— Toxaphene—— Aroclor-1316—— Aroclor-1221—— Aroclor-1232—— Aroclor-1242—— Aroclor-1248—— Aroclor-1254—— Aroclor-1253

.

1111111111111111222222"?"?222222

11322

113113223110110110113113223223

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^ In Reference to Case No(s):

Contract Laboratory ProgramREGIONAL/LABORATORY COMMUNICATION SYSTEM

Telephone Record Log

Date of Call: _____/7-//-9Q_______________> . V.

Laboratory Name: ~/~) L JJ J J LJJ- J f n AfyJIO C.AIW TfilSlX, ,s(./-\ f yu. 7~\ i / <

Lab Contact:

Region: $R jJ JT J 3Regional Contact: CjT&£ljtCO sf\&&e ,_____________

(J ,Call Initiated By: ___ Laboratory ___ Region >( <;/LfQ uTVUJ-£cLYVbjl

In reference to data for the following sample number(s):

U uSummary of Questions/Issues Discussed:

o

Summary of Resolution:

______Signature ( Date

Distribution: (I) Lab Copy, (2) Region Copy, (3) SMO Copy 4/t , ,6 { 6 > ) O

In Reference to Case No(s):


Telephone Record Log

Date of Call: _______^ - I Q.-Q C>__________________

Laboratory Name: / /U jU Lj rf U- JdyyUTL LT &ijLj (L /VJ VT"£L^S"T)_—L/\~ fl n /7 ! ——— jLab Contact:

Region:Regional Contact:

———————dCall Initiated By: ___ Laboratory ___ Region _t_>__^J1 ^ __. ^ ^ . . ——

In reference to data for the following sample number(s): ^ I

Summary of Questions/Issues Discussed


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nytest environmental.tnc.' Case Narrative

Case: 14442SDG#: CDE56Log In: 5256Date: August 14, 1990

Volatile Fraction:

Surrogates: All samples pass surrogate QC requirements.

MS/MSD: All compounds pass percent surrogate recovery andpercent RPD requirements.

Method Blank: No target compounds were found in water or soilblanks.

Calibrations: All CCC and SPCC compounds pass QC requirements ininitial and continuing calibrations. Two compounds in initialcalibration, Benzene and Toluene-DS, are saturated at 200ppb.

D Therefore only four point calibration curve is used for water andsoil calibrations. Some compounds exceed 25%D in continuingcalibrations. Form 5A in the data package is divided inpages, but it is under one BFB. These forms list twomatrices i.e. soil and water. The computer generateddeliverable will appear as attached.

Internal Standard: All samples pass internal standard QCrequirements.

Q Samples: All samples were run as low level. No QC was performedon water sample, see telephone log.

Semivolatile Fraction:

Surrogates: All surrogate recoveries were within QC limits.

Matrix Spike/ Matrix Spike Duplicate: All RPDs and 20 of 22%recoveries were within QC limits.

Method Blanks: No targeted compounds were found in the MethodBlank. One unknown TIC was found at RT 13:47.

Calibrations: All CCC and .SPCC were within QC limits. All %Dwere within QC limits. Some compounds exceed 25%D in continuingcalibration.

Samples: No problems were encountered. All samples were run a

AR309326 000003

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nytest environmental*low level. No water samples analyzed see telephone log for7/11/90 & 7/12/90.

Feticides:

Surrogates: All within QC limits.

MS/MSD: One out of twelve spiking compound recoveries areoutside QC limits. All RPDs are within QC limits.

Blanks: No target compounds found.

Retention Times: All within QC limits.

Standards: In the HP5890 DB608 primary sequence of 7/27/90, the%D of endosulfan II is greater than 15% for INDA 02:56, 7/28/90.Since no samples were analyzed after the INDA that failed, noreanalysis of any samples were necessary: see telephone logPatricia Sheridan 8/9/90.

Samples: Aroclor 1248 was found in sample CPE 57.

VERBATIM;

I certify that this data package is in compliance with theterms and conditions of the contract, both technically and forcompleteness, for other than the conditions detailed above.Release of the data contained in this hardcopy data package andin the computer-readable data submitted on floppy diskette hasbeen authorized by the Laboratory Manager or his designee, asverified by the following signature.

Parag K. Shah, Ph.D.Organic Laboratory Manager

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f-m?Cls-1,3-Dichloropropen e in Trichloroethen e | un ga JS 4k* b O Je i a in 1.1.2-Trlchloroethan e...

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