Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3...

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Transcript of Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3...

Page 1: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.
Page 2: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.
Page 3: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Decomposition of Nitrogen Triiodide

2 NI3(s) N2(g) + 3 I2(g)

NI3 I2

N2

Page 4: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Exothermic ReactionReactants Products + Energy 10 energy = 8 energy + 2 energy

Reactants

Products

-H

Ene

rgy

Energy of reactants

Energy of products

Reaction Progress

Page 5: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Endothermic ReactionEnergy + Reactants Products

+H Endothermic

Reaction progress

Ene

rgy

Reactants

ProductsActivation Energy

Page 6: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Effect of Catalyst on Reaction Rate

reactants

products

Ene

rgy

activation energy for catalyzed reaction

Reaction Progress

No catalyst

Catalyst lowers the activation energy for the reaction.What is a catalyst? What does it do during a chemical reaction?

Page 7: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

An Energy Diagram

activationenergyEa

reactants

products

course of reaction

ener

gy

Animation by Raymond ChangAll rights reserved

Page 8: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Formation of a solid AgCl

AgNO3(aq) + KCl(aq) KNO3 (aq) + AgCl(s)

Page 9: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Single and Double Replacement Reactions

Double-replacement reaction

CaCO3 + 2 HCl CaCl2 + H2CO3

General form: AB + CD AD + CB

Single-replacement reaction

Mg + CuSO4 MgSO4 + Cu

General form: A + BC AC + B

Page 10: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Single displacement is a type of a reaction when a metal reacts with a compound containing a metal, where the single metal in the reaction is more reactive replaces the less reactive metal in the compound.

Single-replacement reaction

Mg + CuSO4 MgSO4 + Cu

General form: A + BC AC + B

Page 11: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

DOUBLE DISPLACEMENT REACTIONS: In a double displacement reaction (ionic reaction) the ions of two compounds exchange places in an aqueous solution to form two new compounds.

Double-replacement reaction

CaCO3 + 2 HCl CaCl2 + H2CO3

General form: AB + CD AD + CB

Page 12: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Double Replacement Reaction

Page 13: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Synthesis Reactions - when two compounds or elements combine to make one molecule or compound. A+ B --> AB 2 H2 + O2 -------> 2 H2O

Decomposition Reactions - a compound or molecule breaks down into simpler elements or compounds AB - -> A + B CO2 ------> C + O2

Page 14: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Important Chemical Reactions

Oxidation ReactionsReactant + Oxygen -------> Products

Oxidation reactions are fundamental to our existence

Definition: A chemical change involving oxygen

Oxidation reactions can occur more rapidly in the presence of humidity in the air, or in the presence of light

GALVINIZATION – coating iron materials with zinc to prevent the formation of rust.

Page 15: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Combustion Combustion – Form of oxidation that releases a large

amount of energy (HIGHLY EXOTHERMIC).

Three requirements for a combustion: Fuel – reacts with oxidizing agent to release energy Oxidizing agent – substance that causes a fuel to react

(usually oxygen) Ignition temperature – the required temperature needed to

combust the fuel

Three types of combustions: Rapid – Release a lot of energy in a short period of time Spontaneous – Fuel ignites without the need for outside

energy Slow – Occurs of long period of time

Page 16: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

A Combustion reaction usually looks like: Fuel + oxygen ------> CO2 + H2O + Energy

CH4 + O2 -------> CO2 + H2O

Page 17: Exothermic vs. Endothermic. Decomposition of Nitrogen Triiodide 2 NI 3 (s) N 2 (g) + 3 I 2 (g) NI 3 I2I2 N2N2.

Other important Chemical Reactions ...

Cellular Respiration Glucose + Oxygen -----> Carbon Dioxide + Water + Energy

Photosynthesis Light + Carbon Dioxide + Water-----> Oxygen + Glucose