Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the...

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Transcript of Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the...

Page 1: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.
Page 2: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Exit Slip

1. How are the lessons? – Too fast? long? slow? Boring?

2. How are you finding the pace of the course? Difficult? Easy? Challenging?

3. What do you wish we could do more of in class? Less of in class?

Page 3: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Cyclic compounds

• Draw the following compounds, then count the carbons and hydrogen of each and write out the molecular formula

1. propane & cyclopropane2. butane, butene & cyclobutane3. hexane, hexene, cyclohexane

Page 4: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Cyclic molecules

• When naming/drawing cyclic molecules the multiple bond is always on carbon 1… then the chains are after

Page 5: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Draw these

• 3-methylcyclohexene

• 2,3-dimethlycyclopentene

Page 6: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Sec. 9.4: Aromatics

Page 7: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Cyclic compound

• Draw cyclic molecule of C6H6

• Hint: it has 3 double bonds

Page 8: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Aromatics

• Benzene is a organic compound that puzzled scientist for a long time.

• Its chemical properties could not be explained by normal means– Based on percent composition and molar mass the

empirical formula is– Melting point 5.5 boiling point 80.1 and tests

shows that the molecule is non polar– No empirical evidence of double or triple

bonds in the molecule

6 6C H

C C

Page 9: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

– X-ray diffraction indicate that all carbon-carbon bonds are the same length

– Evidence from chemical reactions indicates that all carbons are identical and that each carbon is bonded to one hydrogen

• The first attempt at a theory was the following diagram

• But it does not follow octet rule that says that carbon forms four bonds with other atoms

Page 10: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

• Another theory is consistent with the four bonding carbon but still doesn’t explain some empirical evidence

Page 11: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

• August Kekule was the one who came up with an accepted theory for the chemical structure of benzene that followed all the accepted theory

• He proposed that the 18 electrons not involved in the bonding with the hydrogen are equally distributed around the carbon atoms. – So each carbon-carbon bond is equal length and identical in nature

This is the line structural diagramthat represents a benzene ring

Page 12: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

• Aromatics are compounds that contain a benzene ring. – Name was originally assigned to compounds that gave off a

odor.

• Examples

Page 13: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Naming Aromatics

• Simple aromatics are easy to name. They are treated as relatives of benzene.

• When this is the case, we name them the same as we do for cycloalkanes.– Number the carbons starting at a carbon containing a branch– Name the branches as before

Page 14: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

• 1,3 dimethyl benzene

• 2-4-diethyl,1-methyl benzene• Not• 4-6 diethyl 1-methyl benzene

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Page 15: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

• Draw 1-3 dipropyl benzene

• Draw 4-ethyl-1-2 dimethyl-benzene

Page 16: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

• More complex aromatics, those that have the benzene ring attached to a long chain of carbons, have the benzene ring as a branch of the chain.

• For this situation, name the hydrocarbon as before with the benzene ring named as a “phenyl” branch

• Example

nonane= parent chain

3,5 dimethyl-4-phenylnonane

Page 17: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Name the following

Page 18: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Summary of Hydrocarbons

Page 19: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Alkanes Alkenes Alkynes Aromatics-Single bonds

-Number the carbons so the number indicating the branch is small as possible -Branches are named with “yl” suffixes -Cycloalkanes

-Single bonds in a closed ring

-At least one double bond

-Number the carbons so the number indicating the double bond is small as possible -More than one double bond indicated by “diene”-Cycloalkenes

-Double bonds in a closed ring

-At least one triple bond

-Number the carbons so the number indicating the triple bond is small as possible -More than one triple bond indicated by “diyne”-Cycloalkynes

-triple bonds in a closed ring

-contains a benzene ring

-simple aromatics are named with branches of the benzene-more complex aromatics, the benzene is treated a “phenyl” branch

2 2n nC H

2n nC H

2n nC H

2 2n nC H 2 4n nC H

2 2n nC H 6 6C H

Page 20: Exit Slip 1.How are the lessons? – Too fast? long? slow? Boring? 2. 2. How are you finding the pace of the course? Difficult? Easy? Challenging? 3. What.

Homework

• Pg. 385 #3,5,7