Evonik TEGO RC Silicones · TEGO A18 are modified version of 2-Hydroxy-2-methyl-phenyl-1-propanone...
Transcript of Evonik TEGO RC Silicones · TEGO A18 are modified version of 2-Hydroxy-2-methyl-phenyl-1-propanone...
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TEGO® RC Silicones
TEGO® RC Silicones – Introduction
November 2018
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Pressure
Sensitive
Adhesive
Label
Substrate
Silicone
TEGO® RC Silicones – Introduction
Construction of a Label Laminate
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Europa 27%
North America27%
Asia Pacific39%
South America4%
Afric & Middle East 3%
World market release liner : 50.0 billion m²
(paper + film in 2017) ~ 50 000 tons of silicone @ 1g/m²
Source: AWA Assoc. BV
TEGO® RC Silicones – Introduction
Global market
Share Filmic Liners 19 %
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Labelstock
• diaper tapes,
sanitary napkins
Personal Hygiene
• standard label products,
clear-on-clear labels,
thermal labels, linerless
labels
Building & Insulation
• membranes, foams,
• floor covering,
• sound deadening,
• bitumen
Others
• thermal transfer printing,
over laminating,
protective films, process
liners, ceramic capacitor
Tapes
TEGO® RC Silicones – Introduction
• industry, electronics,
security, insulation,
carpet, envelopes, office
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49%
14%
11%
8%5%
3%2%
8% Labels
Tapes
Industrial
Hygiene
Graphic Arts
Medical
Envelopes
Food bakery& other
TEGO® RC Silicones – Introduction
Source: AWA Assoc. BV
Global market
Source: AWA Assoc. BV
Global market
Applications
World market release liner : 50.0 billion m²
(paper + film in 2017) ~ 50 000 tons of silicone @ 1g/m²
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When thermal silicones have to give up ...
TEGO® RC Silicones will provide a solution
for you!
• Use of heat-sensitive films
PE, PP, PET, PVC
• Absolute paper lay flat
coated craft paper like CCK, PEK
• Cost reduction
down gauging films and papers
• Environmentally friendly production
low energy consuming, no solvents
TEGO® RC Silicones – Introduction
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TEGO® RC Products make it possible to
reduce your waste:
• Linerless Labels
• Linerless Thermal Print
• Curing on Recycled Substrates
• 100 % Recyclable Liners
• Bio-Films such as PLA
• Thin BoPP Liners
• Partnerships with Linerless Innovators:
• ETI Converting Equipment
• Ravenwood Packaging
• Catch Point Labels
TEGO® RC Silicones – Introduction
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• Compact construction, easy
retrofitting
• Approx. 1.3 m in web direction,
less floor space
• Low equipment investment
• Extremely short start-up times
(< 5 min.)
• Less silicone waste, less rejects
of substrate
TEGO® RC Silicones – Introduction
Easy to Handle Machinery
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Our technology support
• Introduce you to release liner basics and testing
• Support in choosing the best suitable UV equipment
• Assistance during commissioning and ramp-up
• Optimizing coater settings and UV curing
• Partnership to develop new applications
• Development of suitable silicone formulation
• Use of our pilot lines to test different substrate types
• Examination of silicone-adhesive interaction
• Recommendations for improved adhesive formulation
• Global Tech. Service network for local support
• Confidentiality
TEGO® RC Silicones – Introduction
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Evonik: Pioneer and leading supplier for UV Silicones since 1985
Emulsions
Solvent-based Thermal Systems
Si-OH + HO-Si
Solvent-lessThermal Systems
Si-H + H2C=CH-Si
UV Cationic Curing
Epoxy Silicones
Silicone Acrylates
EB / UV Free Radical Curing
4th Generation
1950 1960 1970 1980 1990 2000 2010
TEGO® 1400er Series
True 1C Systems
TEGO® RC Silicones – Silicone Types
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Days up to weeks
NonePhotoinitiator Poisoning
Free Radical Curing
Necessary
No restrictions
None
None
Serval months
Cationic Curing
Not necessary
Yes
Restrictions
Yes
Yes
Post Curing
Nitrogen Inerting
Substrate
Moisture Inhibition
Bath Life
TEGO® RC Silicones – Silicone Types
UV Curing: Cationic or Radical?
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Formulations containing
RC 702, RC 922, RC 902, up to 200 m/min.
RC 800, RC 1002
RC 715, RC 1772 up to 300 m/min.
RC 711, RC 722 pure up to 400 m/min.
Free radical curing
RC Silicone with
2 % A18
Substrate and humidity influence cure speed
between 50 and 300 m/min.
Cationic Curing
RC Silicone with
2 % PC 1467
TEGO® RC Silicones – Silicone Types
Cure Speed with one 120 W/cm UV Lamp
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• FDA Food Contact Notification
FCN 041 for RC 711, RC 715, RC 726, PC 750
FCN 369 for RC 902 (in combination with A12)
• FDA Regulations 21 C.F.R. 175.105 ("Adhesives") and
C.F.R. 175.125 ("Pressure sensitive adhesives")
for release coatings up to 0.9 g/m² for film and up to 1.2 g/m² for paper based
on RC 706, RC 711, RC 715, RC 726 (FCN 41) and RC 902 (FCN 369) with
2 % A18
• Certificate of conformity by ISEGA
for § 31 Food, Consumer Goods and Feedstuffs Code (LFGB)
for free radical curing Silicones
Please contact us for more details.
TEGO® RC Silicones – Silicone Types
Food Contact Status
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• Addition of min. 30 % RC 711
or 15 – 30 % RC 722 (free
radical curing)
• Special anchorage additive
• In-line corona treatment
High in-line corona treatment is important
Primary: Oxidation and ionization of the surface
= good chemical anchorage
Secondary: Increase of the surface tension
= good wetting
Silicone
Substrate
TEGO® RC Silicones – Silicone Types
Silicone Anchorage to the substrate
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easy release
values
controlled
release values
tight release
values> 500 cN/inch
high release
values200 - 500 cN/inch
premium release
values
30 - 200 cN/inch
10 - 30 cN/inch
< 10 cN/inch
TEGO® RC Silicones – Silicone Types
Release Level Characterisation
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tight release
controlled to tight release for
“differential“ release values
controlled release
easy to controlled release
Addition of 30 % TEGO® RC 711 for proper anchorage (or 15 - 30 % TEGO® RC 722)
TEGO® RC 711
TEGO® RC 722
TEGO® RC 800
TEGO® RC 715
TEGO® RC 902
TEGO® RC 922 premium release
TEGO® RC Silicones – Silicone Acrylates
Free Radical Curing silicones
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TEGO® RC 1002 easy release with RPS effect
•Reduced penetration silicone (RPS) for open papers
matte surface and low CoF additive
• For special matte appearance of silicone surface
• Reduced Coefficient of Friction (CoF)
TEGO® RC 702 easy release
TEGO® RC Silicones – Silicone Acrylates
TEGO® RC 1772
Easy to use one component systems
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• No shrinkage of paper
• No re-moisturization
• Excellent lay-flat behaviour
• No loss of paper strengths with UV
• No photoinitiator poisoning
• All paper types possible
• Growing interest in alternative
inexpensive papers
TEGO® RC Silicones – Silicone Acrylates
Advantages on Paper Substrates
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• Film siliconising shows
strongest growth
• Lower film gauges
• Siliconizing of thermo-sensitive
substrates possible
• No limitations with
choice of filmic substrates
TEGO® RC Silicones – Silicone Acrylates
Advantages on Plastic Film Substrates
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• Multiple curable centres
• Fast and effective curing
• Hydrolytic stable SiC bonds
• High local acrylate concentration
• Easy release properties
• Good aging properties
Si O
CH3
CH3
RO Si O
CH3
CH3
Si
CH3
CH3
R O
O O
nm m
TEGO® RC Silicones – Silicone Acrylates
Example of a Silicone Acrylate
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Propagation P-C-C· + C=C P-C-C-C-C·
e. g.Termination P-C-C· + ·C-C-P P-C-C-C-C-P
InitiationP· + C=C P-C-C·
PI P· + I·
h
PI = Photoinitiator
TEGO® RC Silicones – Silicone Acrylates
Radical Polymerisation
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TEGO® Photoinitiator A18
TEGO A18 are modified version of 2-Hydroxy-2-methyl-phenyl-1-propanone
(HMPP) with
• improved silicone solubility
• highest reactivity in free radical curing silicones
• no odour during UV curing, less VOC
HMPP
OHCC
CH3
CH3
O
C
O
OHC
CH3
CH3
+UV
R R
TEGO® RC Silicones – Silicone Acrylates
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Standard UV lamps are good for TEGO® Photoinitiator A18
0,0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
220 230 240 250 260 270 280 290 300 310
Wavelength in nm
Ab
so
rbti
on
Spectrum
Hg Arc Lamp
TEGO® RC Silicones – Silicone Acrylates
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N2 0,4%Backing 41,4%
Silicone 8,1%HotMelt 19,9%
Face 30,2%• Nitrogen from a rental liquid gas tank
and evaporator is cost effective
available.
• Quality 4.6 or 5.0 (< 10 ppm O2).
• Nitrogen costs less than 1 % of a
label stock.
reactive
radical
unreactive
radical
P C
H
H
C
H
H
O2+ P C
H
H
C
H
H
O O
TEGO® RC Silicones – Silicone Acrylates
Oxygen Inhibition
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Barrier Nozzle
laminar flow for the replacement
of the boundary layer
Gap s = 0.8 mm
a 3s
Labyrinth
TEGO® RC Silicones – Silicone Acrylates
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• No post-curing perfect for in-line coating
• Rapid curing one 120 W/cm lamp for
200 m/min.
• Cure speed independent of substrate
and silicone coat weight
• Less misting even at higher line speeds
TEGO® RC Silicones – Silicone Acrylates
Advantages of Free Radical UV Curing
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Production start up with RC 902 / RC 711 / 70 : 30
• Very long pot life
• Easy cleaning procedure
• No gelation on coater
• Short runs with little waste of
substrate and silicone
• Very consistent release values
• Wide range of release values
TEGO® RC Silicones – Silicone Acrylates
Advantages of Free Radical UV Curing
0
20
40
60
80
100
120
10 11 12 13 14 15 16 17 18 19 20 25 30
Fre
qu
en
cy
Release force g/25mm
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Long Time Release Stability RC 902 / RC 711 / 70 : 30
TEGO® RC Silicones – Silicone Acrylates
0
5
10
15
20
25
30
0 50 100 150 200Ageing at 40°C [d]
HotMelt, permanent
HotMelt, permanent
Waterbased acrylic, permanent
Waterbased acrylic, permanent
Waterbased acrylic, removable
[cN
/in
] F
inat
10/
40
°C
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Aluminium & Foils
Foams
Non-Woven & Textiles
Office papers
Printed Surfaces
PVC
Recycled Materials
Renewable Films
Thermal Papers
Thinnest Films
Silicone coatings with special properties by adding:
Matting agents
Colours / pigments / dyes
Anchorage additives
Diluents
TEGO® RC Silicones – Silicone Acrylates
Possibilities for New Developments
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TEGO® RC Silicones – Epoxy Silicones
photo catalyst
for tight release
for easy release applications
Note: All silicones contain ITX, TEGO® RC 1403 is not available in the USA and Canada.
TEGO® PC 1467
TEGO® RC 1412
TEGO® RC 1403
TEGO® RC 1401 for premium release applications
Range of products cationic curing silicones
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Easy Release Silicone TEGO® RC 1403 and RC 1401
• Easy to handle and use
• Fast curing at 1 to 2 %
addition of PC 1467
• Inerting not required
• Sensitized silicone for very
fast curing
• Stable and low release with
most PSA´s
• Low extractables
xm
n
Me3SiO Si
Me
O Si
Me
O Si
Me
R
O
Me
R
O SiMe3
OH
TEGO® RC Silicones – Epoxy Silicones
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BlueStar
Evonik TEGO® PC 1467
Momentive
B
F F
F
FF4
-
I+
I (CH2)n(CH2)n CH3CH3
SbF6-
n = 11
TEGO® RC Silicones – Epoxy Silicones
Photocatalysts for cationic curing silicones
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TEGO® RC Silicones – Epoxy Silicones
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Si OH
+
+ n
Si O
HO O O O O O O
Si Si Si
Si Si SiSi
+
Si O Si OH
++ H
+
Protonation
Polymerisation
Network
not inhibited by oxygen
TEGO® RC Silicones – Epoxy Silicones
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Production
parameters
• High UV dose
• D-Bulbs
• Lower line speed
• 40 – 50 %rel. humidity
• High SiCtwt
• No additives in filmic
substrates such as slip
additives, colours,
stabilizers
• No alkaline or coated
papers
Silicone
formulation
Choice of
Substrate
• Standard concentration of photo-
catalyst PC 1467 is 1 – 2 %
• A higher concentration of photo-
catalyst PC 1467 can help to
improve the curing
TEGO® RC Silicones – Epoxy Silicones
How to Enhance the Degree of Cure
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Example
• 250 m/min. line speed
• UV Unit to rewind 4.5 m
1.1 sec. cure time
TEGO® RC Silicones – Epoxy Silicones
Limited Cure Time Available
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• Varying release values
- liner: high release
- laminate: low release
• Rub off (may disappear after post curing)
• Silicone transfer to back side
• Silicone transfer to adhesive, thus lower tack
A low degree of cure during production may disappear after
24 hrs of storage. Thus subsequent adhesion test is not suit-
able for quality control.
... means
If the silicone is not sufficiently cured in the moment
of rewinding or in-line adhesive coating this can cause:
TEGO® RC Silicones – Epoxy Silicones
Post curing
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Filmic substrates
BOPP
CR 30 or CR 50 Innovia films (B)
2011 MFN Superfilm (TR)
PM, S1M and S2G Manulifilm (I)
MSO Trias Sentosa (ID)
30 MB 400 Exxon Mobil
Poli M514 Polinas (TR)
PET ®Hostaphan (Mitsubishi Polyester Film)
(3 % TEGO® RC1480 for anchorage recommend)®Hostaphan WDW 50 CSRE®Hostaphan SP36®Hostaphan WO 50 D027B®Hostaphan GN 36 4600®Hostaphan RN 30 23SB®Hostaphan RNK
Paper release liner
special alkaline free papers, e. g.
SAPPI Algro Sol C (37 – 80 g/m²)
Business Forms: with high coat weight
TEGO® RC Silicones – Epoxy Silicones
Epoxy silicones offer benefits with the right substrate
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Headquarters in Essen/Germany
Global sales ( ) and distribution network
Production facilities for RC Silicones ( )
RC Technical Service Centres ( )
TEGO® RC Silicones – Pilot Lines
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• Silicone coating/UV drying
• Adhesive inline coating
dispersion acrylics
hotmelts & UV hotmelts
• Inline/offline process
• Max. 500 mm working width
roll width 520 mm
outer Ø 600 mm
• Max. 100 m/min. line speed
• Production of release liners,
tapes and label laminates
TEGO® RC Silicones – Pilot Lines
RC Pilot Line Essen/Germany
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Lab coater Essen/Germany
• Equipped with a 5-roll coater, maximum web width of 150 mm
• Line speed can be varied to a maximum of up to 50 m/min
• IST inerted UV lamp 120 W/cm, adjustable in height
• Inline Corona treatment 1000 W over 150mm
• 3” core, maximum roll diameter of 400 mm, maximum weight of 25kg
TEGO® RC Silicones – Pilot Lines
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• Offset gravure coater
• Inerted ELTOSCH UV unit with
2 x160 W/cm UV lamps
• Web width 61 cm
• Substrate on 3 inch or 6 inch core
• Line speed 25 - 250 m/min.
TEGO® RC Silicones – Pilot Lines
Pilot Line for UV Siliconizing in Hopewell/USA
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• Gravure roll coater
• Inline corona treatment
• Web width 33 cm
• Substrate on 3” core
• Line speed max. 150 m/min.
TEGO® RC Silicones – Pilot Lines
Pilot Line for UV Siliconizing in Shanghai/China
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• Max. 580 mm working width
• Up to 150 m/min. line speed
• 80 W/cm arc UV lamps
• 570 mm length in web direction
• 560 mm height (opened)
• 50 m³/h nitrogen consumption at
100 m/min.
Asian Mobile UV Unit for Narrow Web Applications
TEGO® RC Silicones – Pilot Lines
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• Max. 700 mm working width
• 150 m/min. line speed and more
• Two 120 W/cm arc UV lamps
• 707 mm length in web direction
• Made by Germatec, Rio de Janeiro/ Brazil
Latin America Mobile UV Unit for Narrow Web Applications
TEGO® RC Silicones – Pilot Lines
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• 550 mm working width
• Up to 200 m/min. line speed
• 160 W/cm arc UV lamps
• 475 mm length in web direction
• 480 mm height (opened)
• 50 m³/h nitrogen consumption at 200 m/min.
• Made by Eltosch/Hönle/Germany
European Mobile UV Unit for Narrow Web Applications
TEGO® RC Silicones – Pilot Lines
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For more information please visit our website
www.evonik.com/tego-rc
TEGO® RC SiliconesTEGO® RC Silicones
Authors
Hardi Döhler
Dr. Winfried Hamann
Evonik Nutrition & Care GmbH
Goldschmidstraße 100
45147 Essen/Germany
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