Evaporative Waste Gas Colling

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    Utilization of vaporation

    Waste as ooling Systems

    to ounteract Rising

    nergy osts

    THIS ARTICLE IS AVAILABLEONLINE ATAIST.ORC FOR 30 DAYS FOLLOWINC PUBLICATION

    T

    oday's primary sources of energy are oil, coal,

    natural gas and nuclear. Fossil fuels like oil, natural

    gas and coal represent almost 8.5 of the energy con-

    sumption in the world. Renewable energy like hydro,

    In conventional waste gas cooling plants,

    the absorbed heat is emitted unused into

    the atmosphere. This steam can be used for

    various applications, such as steel degassing

    or heat and power generation. Integrating

    evaporation cooling plants into steel works

    reduces costs and preserves natural resources.

    wind, solar, biomass and nuclear energy account for the

    remainder.

    As we know, we depend on - and will continue to

    depend on for many years to come - fossil fuels as

    energy sources to produce electricity, transportation

    and industrial applications. We also know that fossil

    fuels will increase in cost with time, not because of

    depletion but due to increased production costs, and

    we know that fossil fuels produce emissions that could

    harm the environment.

    In view of the increasing production costs of these

    fuels and the increasing global primary energy demand,

    it ca.n be assumed that the cost of energy will strongly

    increase in the future. Moreover, most of the industrial

    countries have issued stricter environmental require-

    ments in order to reduce the adverse impact on the

    earth's climate thereby.

    This development entails an increasing cost pressure

    that will increase even further in the future, particularly

    for companies in energy-intensive sectors where energy

    costs represent a significant part of the produdion costs.

    Therefore, the use of energy-efficient and environ-

    mentally friendly technologies is already

    highly important for economic success

    and long-term competitiveness.

    Author

    Oschatz is an innovative, family-owned company that

    operates globally in the fields of plant construction,

    energy recovery and environmental technology. With

    more than 160 years of experience, 1,200 employees, six

    subsidiaries, as well as representative offices all over the

    world, Oschatz is a market leader in the product areas

    of iron and steel metallurgy, non-ferrous metallurgy,

    environmental and chemical technologies.

    Iron and steel metallurgy has had a high priority for

    Oschatz for many years. In order to relieve the effects on

    the environment and to recover the heat energy in waste

    gases, Oschatz has developed solutions for cooling the

    hot, highly dust-loaded and CO-containing waste gases

    from production plants. Each plant concept is based on

    customer and process-specific requirements to ensure

    the highest degree of availability, operational safety and

    profitability for the customer.

    It is the purpose of this paper to show the benefits o

    energy recovery from waste gases of furnaces using the

    proven concept of steam generation on an evaporating

    cooling system. Lower operating costs and a reduction

    of harmful emissions to the environment are the advan-

    tages of operating a more energy-efficient system.

    Cooling Plants for Basic Oxygen Furnace

    (BOF) Waste Gases

    The first LD (BOF) steel works in the world came

    onstream in Linz and Donawitz in 1952 and 1953

    respectively. Since then, the process has steadily been

    developed and further improved. Today, the greatest

    part of the world's crude steel production is rroduced

    according to the LD (Linz-Donawitz) process.

    Along the LD process, the converter is filled with

    fluid crude steel and a cooling fluid (scrap metal o

    iron sponge). Afterward, pure oxygen is blown through

    a water-cooled oxygen lance onto the iron melt. During

    this blowing process, the carbon concentration of the

    crude steel is reduced from approximately 4-4.5 down

    to less than 0.1 . Within this process, primary gas i

    produced that consists of 85-95 vol.

    of CO and 15-5

    vol. of CO2 during the main decarburization period.

    In practice, for the design of waste gas cooling plants,

    it is calculated with a primary gas analysis of 90 vol.

    Josip Kasalo, Oschatz GmbH. Essen. Germany ([email protected])

    48 .. Iron .Steel Technology

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    CO and 10 vol. CO2 and a primary gas temperature

    of about 1,700C.

    Because of the high temperatures and the highly dust-

    loaded primary gases, dust removal without cooling is

    not possible. Therefore, the primary gas is led through

    a waste gas cooling plant downstream the converter and

    is cooled to about 1,000-800C.

    An additional cooling of the waste gas can be achieved

    only by screen walls and/or convection cooling parts. By

    means of these cooling parts that are installed in an

    additional section of the cooling) stack, it is possible

    to reduce the waste gas temperature lower than 600C.

    After the cooling, the waste gas reaches the dedusting

    system, where it is processed further, depending on the

    chosen dust removal technology.

    For the waste gas cooling plants, also called cooling

    stacks, there are three different cooling systems:

    .Evaporation cooling.

    .

    Pressurized water cooling closed circuit).

    .

    Water cooling in an open circuit.

    The last mentioned cooling technology is only rarely

    implemented at new plants.

    In addition to the above-mentioned distinction of

    the cooling system, there is another differentiation

    between the converter cooling stacks, depending on the

    combustion factor. Because of the high CO content in

    the primary gas, it is possible, on the one hand, to com-

    pletely burn the gas over-stoichiometric/stoichiometric

    combustion, n 2 1.0) or, on the other hand, to cool

    down the partly combusted gas under deficiency of air

    under-stoichiometric combustion, n < 1.0), to remove

    the dust and to store it in a gas holder.

    In modern steel

    works, usually the

    under-stoichiometric igure

    operation mode is

    chosen with an intend-

    ed combustion factor

    of n < 0.1. Only then

    can the converter gas

    be recovered with the

    highest possible CO

    rate and be used for

    other processes.

    Another advantage

    of the very low com-

    bustion factor is the

    lower amount of waste

    gas in comparison to

    the higher combustion

    factor. By this means,

    the dimensions of the

    cooling stack, of the

    attendant facilities and

    of the dedusting sys-

    tem are reduced. This

    has a positive effect

    on the investment and

    operating costs. In Converter cooling stack. A

    addition, the lifetime and E = deflection bend.

    of the individual parts

    of the cooling stack is significantly extended due to the

    minor thermal load.

    Objective

    In this paper, two boiler systems

    -

    one based on evapo-

    ration cooling and the other based on pressurized water

    cooling, for the cooling of waste gases downstream from

    the LD converter - are described. In addition, for each

    plant, the energy supply and the consumption of feed

    water and - for the plant based on evaporation cooling

    -

    the credits for steam are determined and described.

    This data is later used as a basis for a rough calculation

    of profitability.

    The objective is to show that waste gas cooling plants

    based on evaporation cooling have further significant

    advantages, in addition to energy recovery in the form

    of industrially usable steam. Compared to cooling plants

    based on water cooling, they are more profitable and

    environmentally friendly.

    Cooling plants based on the open circuit see Figure

    7) were not taken into consideration in this report. This

    technology is not state of the art anymore, and therefore

    outdated due to the corrosion problems on the water

    and gas side, as well as its reinforced disposition to a

    water-side staining.

    Waste Gas Cooling Sjrstems - Cooling stacks, whether

    with evaporation cooling or pressurized water cooling,

    consist of basically the same components. Generally,

    these are the skirt, the hood, the stationary stack and the

    deflection bend Figure 1). Since the local conditions

    and the available space in the steel works have to be taken

    into account, other arrangements are possible as well.

    LDconverter BOF), B

    skirt, C

    hood, D = stationary stack

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    Figure

    Tube-to-tube construction.

    In contrast to the doublejacket cooling implemented

    in the past, these components consist mainly of a tube-

    to-tube or a tube-web-tube construction (Figures 2 and

    3) connected to a circular or square tube wall (also

    known as a panel wall or membrane wall) through

    which the cooling medium flows. Round cooling stacks

    have an advantage over square cooling stacks, as they are

    more stable and therefore safer in case of gas-side explo-

    sions. In addition, this form is less prone to sticking of

    slag and other deposits.

    After leaving the converter, the primary gas flows

    through the skirt. It is directly installed above the con-

    verter and is designed for an optimal collection of the

    primary gas. By means of lifting and lowering the skirt,

    the gap between the converter mouth and the cooling

    stack is minimized, so that the intrusion of infiltration

    air into the cooling stack is minimized and the adjust-

    ment of the planned combustion factor is made easier.

    The skirt is particularly important regarding the adjust-

    ment of the combustion factors A - 0.05-0.l.

    The outcome of the partial combustion of the prima-

    ry gas is waste gas. Afterward, it reaches the hood that is

    installed downstream of the skirt. At the waste gas cool-

    ing plants used today, the lance dome, sublance dome

    and the flux chutes are components of the hood and

    are mostly connected gastight with the hood through a

    flange connection.

    Due to its location and form, the hood is exposed to

    converter emissions and to a very high thermal load.

    This entails an abrasion so that the hood has to be

    repaired or replaced more frequently than the other

    components of the cooling stack.

    In order to keep the shutdown periods as short as

    possible in case of a repair, it therefore makes sense to

    separate the hood via valves from the rest of the cool-

    ing system. In that way, it is assured that the hood can

    quickly be removed and a replacement hood can be

    installed, although the other parts of the cooling stack

    are still connected to the cooling circulation.

    After the hood, the waste gas is first cooled in the

    stationary stack and afterward in the deflection bend.

    The deflection bend forms the end of the cooling stack

    before the waste gas enters the dedusting system for

    further processing.

    Although the components of both types of plants

    are very similar, there are significant differences upon

    closer inspection of the whole plant.

    50 . Iron Steel Technology

    Figure

    Tube-web-tube construction.

    Waste Gas Cooling System With Evaporation Cooling

    -

    Evaporation cooling applied to waste gas systems

    generates steam, which can be used for many industrial

    purposes, in contrast to the pressurized water cooling

    system, where the energy transferred to the cooling

    water is just wasted.

    It could be assumed, based on a rough calculation,

    that 75-80 kg of steam per ton of hot metal is generated

    in a plant with evaporation cooling, giving the following

    process conditions: C content on hot metal (or molten

    iron) > 4 , C content on raw steel (or molten steel)

    < 0.1 , combustion factor = 0.1 and waste gas outlet

    temperature = approximately 950C.

    Two different circuits form part of the evaporation

    cooling system: the low-pressure system (LP system) and

    the high-pressure system (HP system).

    In a typical waste gas cooling plant, the parts that

    are connected to the LP system are the skirt, the lance

    dome, the sublance dome and the flux chutes. The heat

    absorbed during the blowing period by the LP system is

    used (in addition to the steam from the HP system) for

    degassing of the demineralized water. Demineralized

    water is used as makeup water to compensate for losses

    and consumed steam.

    The other parts of the waste cooling plant, like the

    hood, the stationary stack and the deflection bend, are

    connected to the HP system (Figure 4).

    The circulation water, coming from the steam drum

    at the HP system and the feed water tank at the LP sys-

    tem, which flows through the components of the waste

    gas cooling plant, is mainly in boiling condition. It

    becomes partly evaporated due to the heat transferred

    during the waste gas cooling process.

    Afterward, the water/steam mixture of the HP system

    is led by the riser piping to the steam drum, where it is

    separated and the riser piping of the LP system supplies

    the water steam mixture to the feed water tank.

    The makeup water necessary for the replacement of

    the consumed steam is delivered by means of feed water

    pumps from the feed water tank to the steam drum, and

    subsequently forwarded by circulation pumps to the

    plant components.

    More efficient waste gas cooling systems with evapo-

    ration cooling are designed with several components

    operated in natural circulation to reduce the power

    demand on the circulation pumps (Figure 5). This has

    the advantage that the quantity of circulation water,

    within the forced circulation circuit, is reduced thereby,

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    Figure

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    igure

    I

    I

    i

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    depending on the hood and stack design arrangement.

    The heat load of the waste gas transferred to the cool-

    ing water is then removed by a heat exchanger system.

    The circuit is then closed when the cooling water again

    reaches the expansion tank (Figure 6).

    Cost Comparison of Both Waste

    as

    ooling Plants

    Basic Data for Design

    -

    The same metallurgical bound-

    ary conditions are presumed to allow for a comparison

    of the operating costs of both plant designs, where

    investment costs, energy demand, demineralized water

    consumption and credit for the generated steam are

    taken into consideration. Tables 1-4 provide the data

    for plant design. The following symbols should be con-

    sidered for the tables:

    .

    All volumes in mn 3 or volumetric flowrates in

    mn3/hour, mn3/minute or mn3/second refer to

    the standard state according to DIN 1343.

    .

    All volumes in m3 or volumetric flowrates in m3

    I

    hour, m3/minute or m3/second refer to the

    operation conditions.

    .

    nco = combustion factor = LILa, related to the

    CO in the primary gas, where L = air quantity

    effectively drawn in mn3/hour and La = air quan-

    tity theoretically required to obtain a stoichio-

    metric combustion of the CO contained in the

    primary gas.

    .dc/dt .= decarburization rate in C/minute,

    related to the hot metal quantity per heat.

    .Ch = heat.

    Figure 8 shows a diagram of the thermal energy

    absorbed by the boiler, the combustion factor, as well as

    the decarburization rate during the blowing time.

    Energy Consumption - Considering the basic data cal-

    culated earlier, the energy consumption for both cool-

    ing systems is shown in Table 6.

    Considering the energy consumption of the plant

    with pressurized water cooling (Table 7), the feed water

    pumps are neglected because they are used solely for

    Table 4

    Table

    Technical Data for the Steelmaking Process

    Process

    LD converter (BOF)

    --

    ---~--

    Number of BOFs

    Hot metal quantity

    340 t/Ch

    -~

    ,.. ..

    --- - -

    Carbon content of hot metal

    4.50

    u-

    Carbon content of crude steel

    0.10

    ~-

    ------.

    Decarburization rate 4.50 - 0.10

    ~

    4.40

    16 minutes

    -----

    ---....

    Heat period (tap-to-tap time)

    44 minutes

    --

    -- -----

    Max. reacting oxygen quantity

    1,300 mn3/minute

    --

    --

    - -

    Table 2

    Technical Data for Primary Gas Waste Gas

    Temperature of primary gas 1,700 C

    Analysis of primary gas: CO

    CO2

    90 vol.

    10 vol.

    Combustion factor nca

    0.1

    Outlet temperature of waste gas

    850C

    --

    Table3

    Technical Data for the Water Steam System

    Operation pressure

    Waste gas cooling plant with evaporation cooling

    HP system 20-40 bar

    LP system 4-8 bar

    Waste gas cooling plant with pressurized water cooling

    14-1 8 bar

    ---

    A _--

    -- ---

    Cooling water temperature (pressurized water cooling)

    at boiler inlet 105 C

    at boiler outlet 150C

    ------------

    .- ------

    Calculated Values With Regard to the Gas Flow and Heat Flowrates

    Primary gas flowVp' 142.000

    --

    166,000

    -

    22.5 MWh/Ch i) 81.0 GJ/Ch

    Waste gas flow VA'

    --

    -,-- --- - ----

    ---

    bsorbed heat flow 1' (uncontrolled at nea ~ 1.0)

    120.0 MW

    Absorbed heat flow 2' (controlled at nea

    ~

    0.1)

    Max. decarburization rate

    98.0 MW

    --

    Note: The values

    0.372 C/minute

    and are based on a max. reacting oxygen flowrate of 1,300 mn3/hour.

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    Figure 8

    130

    120

    110

    ~ 100

    ~ 90

    ~ 80

    : 70

    .c

    ]

    60

    - 50

    ~ 40

    30

    20

    10

    0

    01'

    O2'

    0

    2 4

    A

    1,50

    1,40

    1,30

    1,20

    1,10 ~

    1,00

    ]

    0,90

    6

    0,80 ~

    ..

    ~

    r

    0,70 ~

    ~ 0.60 u

    0.50

    f

    0.50

    0.40 0,40

    0,30 0,30

    0,20

    J

    0,20

    0.10 0.10

    0,00 0.00

    17

    c

    c

    'E

    ~

    ge,

    B

    5 6 7 8 9 ro n ~ M ~ ~

    Blowl.. . period [ mln )

    Heat diagram, A. Absorbed thermal energy by boiler system at nco = 0.1; B.

    Decarburization rate (dc/dtJ; and C. Combustion factor.

    Table

    filling the plant and for compensating

    the eventual leakage losses.

    Cost Analysis - For the comparison o

    both plants under the economic point

    of view, the following average specific

    costs/ credits are taken as a basis:

    .

    Electrical energy

    cost

    .Steam credit

    . Demi-water (fully

    demineralized) costs

    O.08/kWh

    27.6/t

    6.9/t

    The one-time accruing investment

    costs, which have been only roughly

    estimated, are shown in Table 8.

    Generated Steam

    Generated steam quantity approx,

    Required steam for degassing

    - ~-- -

    n - - n

    36 tICh ~ 49 t/hour

    7,5 tICh ~ 10 t/hour

    Delivered steam quantity (to consumers)

    (the delivered steam quantity is related to the system boundaries: Inlet demi-water at feed water tank/steam

    accumulator outlet and a demi-water temperature of 200 C)

    28,5

    t/Ch

    ~ 39

    t/hour

    Required demi-water quantity

    --- -- -

    - ----

    - - -

    28.5 t/Ch ~ 39 t/hour

    Table

    Energy Consumption of Waste Gas Cooling for a Plant With Evaporation Cooling

    Volume flowrate

    Feed water pumps:

    For the design of the feed water pumps, it was consid-

    ered that the full delivery is achieved only during the blowing period of 16

    minutes and that, during the intermission of 28 minutes, only a minimum

    flow is returned to the feed water tank.

    Circulation pumps:

    a HP circulation pumps:

    Volume flowrate

    Power consumption of HP cire. pump

    Number of pumps

    Elect ric motor efficiency

    Energy consumption per heat

    Summary

    Plant component

    Feed water pump

    HP circulation pumps

    LP circulation pumps

    Total energy consumption

    155 m3/hour

    265 kW

    Number of pumps

    Power consumption of feed water pump

    ---

    Elect ric motor eff ic iency

    95

    Energy consumption per heat

    74 kWh/Ch

    1,900 m3/hour

    b LP circulation

    pumps:

    Volume flowrate

    400 m hour

    ---

    2 with 950 m3/hour/pump)

    Number of pumps

    Power consumption of LP cire. pump

    57kW

    60 kW

    ----

    95

    Elect ric motor eff ic iency

    Energy consumption per heat

    44 kWh/Ch

    x 124 kWh/Ch

    Energy demand

    74 kWh/Ch

    248 kWh/Ch

    44 kWh/Ch

    366 kWh/Ch

    54

    .

    Iron & Steel Technology

    95

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    Table 7

    Circulation pumps:

    Volume flowrate

    2,400 m3 hour

    Energy Consumption of Waste Cas Cooling for a Plant With Pressurized Water Cooling Closed Circuit

    Air cooled heat exchanger:

    Airflow

    1,300 m3 second

    Power consumption of circulation pumps

    240 kW

    Number of pumps 2 (with 1,200

    m31

    hour per pump)

    Elec tr ic motor eff ic iency

    95

    Energy consumption per heat

    2 x 185 kWh/Ch

    Summary:

    Plant component Energy demand

    Circulation pumps

    370 kWh/Ch

    Air-cooled heat exchanger

    209 kWh/Ch

    Total energy consumption

    579 kWh/Ch

    Table 8

    Power consumption

    285 kW

    Energy consumption per heat

    209 kWh/Ch

    One-Time Accruing Investment Costs

    Waste gas cooling plant with evaporation cooling

    Design

    Waste gas cooling stack

    Steam drum

    Steam accumulator

    Feed water tank

    HP circulation pumps

    LP circulation pumps

    Feed water pumps

    Piping

    Valves

    Measuring and control equipment

    Waste gas cooling plant with pressurized water cooling

    Design

    Waste gas cooling stack

    Feed water tank

    Expansion tank

    Circulation pumps

    Feed water pumps

    Piping

    Valves

    Measuring and control equipment

    Air-cooled heat exchanger

    Note: The costs for transportation, as well as the costs for installation, are considered to be similar.

    Cost Comparison - Table 9 shows the cost comparison

    for each waste gas cooling plant. The credit entries are

    marked with a plus sign (+) and the costs with a minus

    sign (-). The cost breakdown comparison includes only

    the costs that are different between both plants, being

    the costs for direct capital investment, energy consump-

    tion, demineralized water consumption and steam

    utilization. The rest of the capital and operating costs,

    like indirect costs for the capital project, amortization,

    operating costs, maintenance, labor, etc., are considered

    equal and are not shown on the breakdown.

    General Consideration

    -

    The higher capital invest-

    ment cost of the evaporation cooling plant compared to

    the conventional pressurized cooling water plant is due

    to the additional costs for valves and components, the

    boiler s higher operating pressure, as well as the costs

    for additional plant components like the steam drum

    and steam accumulator. It is even higher if one consid-

    ers the cost of the air-cooled heat exchanger needed on

    the pressurized cooling water system.

    However, if one considers the advantages in operating

    costs, assuming that one could consume or sell the gen-

    erated steam, the selection of an evaporation cooling

    system is still economically recommended. It is not only

    the advantage of the steam generation and use capa-

    bilities of the system, but also the lower electric energy

    consumption due to the combined natural/forced cir-

    culation design.

    Even more, if one considers that both waste gas cool-

    ing systems could store a certain amount of CO gas and

    receive credit for it, one could add it to the benefits

    of the steam generation credit and conclude that the

    returns of the evaporation cooling system are higher

    than of the plant with pressurized water cooling (see

    Figure 9).

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    able

    ost omparison for Each Waste as ooling Plant

    Waste gas cooling plant with evaporation cooling

    ~ --~-

    Investment

    costs approx.

    15,800,000

    - -_.-

    --- --

    Energy consumption

    Demand per heat

    Specific costs

    Total costs

    366 kWh/Ch

    0.08/kWh

    - 29/Ch

    ---

    Demand demi-water

    Demand per heat

    Specificcosts

    Total costs

    28.5 t/Ch

    6.9/t

    -197/Ch

    - -~ -.-.

    Steam utilization

    Delivery per heat

    Specific costs

    Total credits/costs

    28.5 t/Ch

    27.6/t

    + 787/Ch

    --.~-- ---

    Credits/costs per heat

    + 561 /Ch

    ----

    --

    Annual credits/costs

    Heats per year

    Total credits/costs per year

    7,500 Ch/a

    4,207,000/a

    --~-~--- --- ~- -

    Waste gas cooling plant with pressurized water cooling

    -----

    -

    ---

    Investment costs approx.

    13,100,000

    --............

    Energy consumption

    Demand per heat

    Specific costs

    Total costs

    579 kWh/Ch

    $0.08/kWh

    -$46/Ch

    -- -------

    ---

    Demand demi-water

    Demand per heat

    Specific costs

    Total costs

    - t/Ch

    - /t

    - /Ch

    ,_. ,-.-

    ---

    Steam utilization

    Delivery per heat

    Specific costs

    Total credits/costs

    - t/Ch

    - /t

    - /Ch

    - 46/Ch

    --

    ----

    Credits/costs per heat

    --

    - ----

    Annual credits/costs

    Heats

    per year

    Total credits/costs per year

    7,500 Ch/a

    - 345,000/a

    . _'_'T ----

    -- ---

    The differences between both plants in the cost/

    return development become especially evident when

    the plant is operated with a higher combustion factor.

    One must consider that, at a high combustion factor

    (nea;:: 1.0) the storage of CO gas is no longer feasible,

    and at a low combustion factor (nea > 0.4) the storage

    is seldom carried out due to the low calorific value. At

    these two scenarios, credit is not available.

    In Figure 10, for both waste gas cooling systems

    without CO storage, the progress of the cost/return-

    development is qualitatively shown.

    As a result of the missing credits for the CO storage,

    the pressurized cooling water system works primarily as

    a consumer; therefore, the permanent charges affect

    igure

    >-

    1

    dY1

    0

    Return development for a plant with CO storage (qualita-

    tively illustrated). A = plant with evaporation cooling; B =

    plant with pressurized cooling water; X = time; Y = return;

    dYl

    =

    Return development - pressurized water cooling;

    dY 2

    =

    Return development - evaporation cooling.

    56 .

    Iron IS Steel Technology

    the cost side negatively (Figure 10, curve B). At the

    plant with evaporation cooling, the steam credit leads to

    the fact that this type of plant is still economically rec-

    ommended, in spite of the missing credit for CO storage

    (Figure 10, curve A).

    It should be also considered that a desire for a higher

    combustion factor will mean an increase in the waste

    gas flowrate, and therefore the complete plant needs

    to have greater dimensions, resulting in higher capital

    investment costs. It could be assumed that the amortiza-

    tion time for a plant with steam-only utilization would

    be longer than for a plant with combined energy utili-

    zation, steam and CO storage. These factors should be

    taken into account during the project feasibility study.

    dY

    dZ

    x

    B

    Total cost/return development for a plant without CO-storage

    (qualitatively illustrated). A

    =

    Plant with evaporation cooling

    B

    =

    Plant with pressurized cooling water; X

    =

    Time; Y

    =

    Return; Z

    =

    Cost; dY

    =

    Return development - evaporatio

    cooling; dZ = Cost development - pressurizedwater cooling

    igure

    10

    >-

    t

    O.

    dY2

    -

    N

    .... X

  • 7/18/2019 Evaporative Waste Gas Colling

    10/10

    Evaporation Cooling Systems -

    Operational Safety and Environmental

    Protection

    In the previous section, it was shown that evapora-

    tion cooling plants have clear economic advantages

    compared with pressurized cooling water plants. In

    the following paragraphs, some other advantages are

    described briefly.

    Operational Safety - Water leakage from water-cooled

    elements entering the furnace is the main source of

    explosion hazard on any steelmaking plant. Therefore,

    one of the requirements

    for

    a safe steelmaking opera-

    tion is to avoid tube damages that would lead to water

    leakage.

    One important advantage of evaporation cooling is

    the reduction of the risk of water leakage due to tube

    damage. The cooling water inside the tube is under

    saturation pressure in boiling condition. Therefore, the

    cooling water flows through the cooling elements under

    a constant temperature. Consequently, there are no dif-

    ferential tensions and/or increased tension on the cool-

    ing element due to a sudden increase of waste gas heat

    load. Furthermore, due to the higher heat-transfer coef-

    ficient, the temperature gradient between the unheated

    and heated sides of the tubes would be less than in the

    pressurized cooling water system. In this case, the risk

    of thermal shock cracks is also reduced by the lower

    tube material temperature difference in the tube wall,

    whereby the lifetime of the cooling plant components

    is increased.

    In the event of mechanical or thermal damage during

    operation, which causes a leak, the following physical

    effect takes place in the evaporation cooling system: due

    to the sudden expansion of the coolant and following

    evaporation in the leakage point, a blocking effect

    for

    the coolant occurs. The quantity ofleaking water, along

    with the resulting losses in such systems, is insignificant

    compared to pressurized cooling water systems.

    Additionally, the residual water in the system is at

    boiling point; hence it is evaporated immediately by

    the contact with the gas thermal load and/or furnace

    radiation. Leakage of important water quantities, and

    consequently risk of explosion and damage, is greatly

    reduced.

    These facts considerably reduce the causes for explo-

    sion incidents, increasing in that way the operation

    safety of the furnace.

    Another advantage is that it leaves sufficient time to

    the plant owner to establish a well-defined repair pro-

    gram. The main root causes of damage that normally

    leads to emergency shutdowns - such as damage to the

    tube and cooling elements leading to water leakages,

    due to thermal stress, lack of cooling, etc. - can be

    eliminated to a large extent.

    Environmental Protection

    - Today, besides economic

    efficiency and operational safety, industrial plants must

    also be evaluated with regard to their environmental

    impact and the sustainable use of energy.

    Evaporation cooling plants recover energy in the

    form of steam. Two examples are described here, show-

    ing the magnitude of the energy recovered, which is

    otherwise dissipated unused to the environment.

    In accordance with the calculated values shown in

    Table 5, the utilizable amount of steam generated has a

    thermal energy content of approximately 21.5 MWh/Ch

    - 28.5 t/ Ch of steam generated related to a demineral-

    ized water temperature of 20C).

    If we assume 7,500 heats/year and an annual power

    demand of approximately 14,500 kWh per year and

    household for the production of heat, this energy would

    suffice to supply about 11,100 private households dur-

    ing one year with heat.

    Additionally, this energy amount is enough to save

    approximately 14.5 x 106 m3 of natural gas Hi

    = 10.5

    kWh/m3) in a year, by which 32,250 t CO2 emission

    factor

    for

    natural gas

    0 2

    kg/kWh) would not be emitted

    into the atmosphere in a year.

    Following these two examples, it quickly becomes evi-

    dent that the potential of energy recovered as steam is

    significant and could make a positive impact: there will

    be less detrimental exhaust gas emitted into the atmo-

    sphere, and energy is saved.

    Summary

    Based on an LD converter BOF) operation with a hot

    metal capacity of 340 t/Ch and using average unit costs,

    it has been shown that waste gas cooling plants with

    evaporation cooling are more economically feasible

    to operate due to the return received from the steam

    generation and use, in addition to the CO storage

    possibility, than comparable pressurized cooling water

    plants. Another advantage is the fact that, due to the

    heat recovery capabilities as industrially usable steam,

    less fossil fuel is consumed and less CO2 is emitted into

    the atmosphere.

    The use of energy-efficient and environmentally

    friendly technologies is proven to be highly important

    for the competitiveness of companies in energy-inten-

    sive sectors. Only those who efficiently protect natural

    resources, the environment and our communities will

    have sustainable success within the global competition.

    Reference

    1. http://www.stahl-online.de/wirtschafcund_politik/stahU

    zahlen/start.asp,Jan. 20, 2009. ..

    Thispaper was presented at AISTech 2010 - The Iron Steel Technology Conference and Exposition

    Pittsburgh

    Po.,

    andpublishedin the ConferenceProceedings

    Did you find this article to be of significant relevance to the advancement of steel technology?

    Ifso, please consider nominating it for the AISTHunt-KellyOutstanding Paper Award at AIST.org/huntkelly.

    November 2010

    7