English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB...

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English Heritage English Heritage The Effect of Air Tightness on RH Control David Thickett David Thickett Collections Conservation Team Collections Conservation Team

Transcript of English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB...

Page 1: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

The Effect of Air Tightness on RH Control

David Thickett David Thickett Collections Conservation TeamCollections Conservation Team

Page 2: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage AER Measurements

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desktop

medium <1m

high >1m

historic

print frames

MC frames

stewart boxes

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1.2ai

r ex

chan

ge r

ate

/day

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English HeritageEnglish Heritage RH measurement

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1991 THGs + 5%1994 squirrel+ 3%1996 Shinea + 3%2000 Vaisala humicap + 2%

2006 Rotronic hygroclip + 1%

1 pt3 ptdata failure

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English HeritageEnglish Heritage Thomsen (1977)

NMBt 4

2/1 =

t ½ is the hygrometric half life (days)M is the loading of silica gel in the box (0.1kg/m3)B is the specific moisture reservoir of silica gel (8 g/kg/%)N is air exchange rate (0.35 and 0.65 /day)

Thermal Equilibrium between enclosure and roomPerfect and rapid mixing in enclosure

Page 5: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Weintraub and Tetrault (2003)

DNCMFBt

eq

HRH =

tRH is time to reach a specifed RH (days)F is targeted range of RH fluctuation (irrelevant for this application but taken to be16 %)BH is specific moisture reservoir corrected for hysteresis (this effect is negligible for regular silica gel below 30% RHCeq is equilibrium concentration of water vapour (calculated g/m3)D is decimal difference between external RH and chamber (0.59)

Perfect and rapid mixing in enclosure

Page 6: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

Page 7: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Dryer than Room

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English HeritageEnglish Heritage

Stewart Boxes for Archaeological Metals

01020304050607080

18/01/200500:00

09/03/200500:00

28/04/200500:00

17/06/200500:00

date

RH (%

)

room model box

Thickett &Thickett & OdlyhaOdlyha, , Conservation Arch Materials, 2007Conservation Arch Materials, 2007

Page 9: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Porchester

Page 10: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

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17-Feb-0509-M

ar-0529-M

ar-0518-Apr-0508-M

ay-0528-M

ay-0517-Jun-0507-Jul-0527-Jul-0516-Aug-0505-Sep-0525-Sep-05

RHmodel

tt½½ = 4MB/n = 4MB/n M = 10kg/m3, B = 8, tM = 10kg/m3, B = 8, t½½ = 187days= 187days

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English HeritageEnglish Heritage

0102030405060708090

100

0 50 100 150 200 250 300 350

time (days)

RH

(%)

Thickett & Thickett & LuxfordLuxford, , Metal 07, 2007Metal 07, 2007

Page 12: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Wetter than Room

Page 13: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Down House, London

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19/11/200600:00

29/11/200600:00

09/12/200600:00

19/12/200600:00

29/12/200600:00

08/01/200700:00

Time (days)

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Page 14: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Above and Below Room

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English HeritageEnglish Heritage

Werner Collection, Rangers House London

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0.4 0.6 0.6 0.8 0.8 1 1.6 2.4 2.6 2.6 4.5

Thickett et al, Thickett et al, Conservator, 2005Conservator, 2005

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English HeritageEnglish Heritage

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Page 17: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Mechanical Conditioning

DehumidifiersDehumidifiersHumidifiersHumidifiersMixedMixedFlow Through, Hahn RK2, Flow Through, Hahn RK2, RecirculationRecirculation, , MiniclimaMiniclima

Page 18: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

Dehumidifier PerformanceBronzes, 42%

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<20 21-25 26-30 31-35 36-40 40-42 >42

20.4610.46.524.093.71

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20.46

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6.52

4.09

3.71

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English HeritageEnglish Heritage Dehumidifier Specification

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time (days)

wat

er v

apou

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English HeritageEnglish Heritage

y = -0.31x + 8.6582

7.27.47.67.8

88.28.48.68.8

0 1 2 3

days

ln [

CO

2 pp

m]

00.20.40.60.811.21.41.61.82

Inst

anta

neou

s A

ER(d

ay-1

)

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English HeritageEnglish Heritage

Dehumidifier PerformanceBones, 70%

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<40 40-50 50-60 60-70 70-80 80-90

room yearroom0.520.640.83

Page 22: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

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English HeritageEnglish Heritage Kenilworth Environment

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date

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Page 24: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Conditioning Performance

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Page 25: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Tapestry Case RH

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Page 26: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

Page 27: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Tapestry Case RH

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date

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Page 28: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

Page 29: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Conditioning Failure

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room

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English HeritageEnglish Heritage

Page 31: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

0%10%20%30%40%50%60%70%80%90%

100%

0 1 2 3 4 5 6 7

air exchange rate (/day)

prop

ortio

n [m

etha

noic

aci

d]

Page 32: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage

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English HeritageEnglish Heritage Ethanoic acid

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pb)

julydecember

Page 34: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Conclusions

Modelling internal Modelling internal RHs RHs fairly well, well enoughfairly well, well enoughTemperature effectsTemperature effectsWoodWood

Predict performance of casesPredict performance of casesSpecify AER required, cost implicationsSpecify AER required, cost implicationsMethanoic acid, equation works wellMethanoic acid, equation works wellEthanoic (sealed MDF), apparent ‘threshold’ Ethanoic (sealed MDF), apparent ‘threshold’ ~0.5day~0.5day--11

Page 35: English Heritage The Effect of Air Tightness on RH Control · English Heritage Thomsen (1977) N MB t 4 1/ 2 = t ½ is the hygrometric half life (days) M is the loading of silica gel

English HeritageEnglish Heritage Acknowledgements

Philip Fletcher, British MuseumPhilip Fletcher, British MuseumAndrew Andrew CalverCalver, Museum of London, Museum of LondonSarah Sarah LambarthLambarth, ICON/HLF, ICON/HLFUniversity of StrathclydeUniversity of Strathclyde