Emulsion Breaker 210 Product Sheet

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    Manufactured by :

    Information Technology Solutions

    PRODUCT DESCRIPTION

    Chemiphase are proud to launch our latest

    development in biodiesel technology, ademulsifier specifically designed to be used with

    biodiesel production to remove excess water

    content in biodiesel. Emulsion Breaker 210 can

    also be used in vegetable oils to remove water.

    Emulsion Breaker 2010 has been developed for

    the Biodiesel Water Washing Process. This

    product will knock out stubborn emulsions

    and "rag layers" rapidly. To achieve the best

    results with this product we recommend heating

    both the biodiesel and water above 55 deg C

    before adding the product, please ensure the

    EB 2010 is well mixed in the biodiesel.

    Emulsion Breaker 210 is designed to aid removal

    of wash water from bio diesel production.

    Emulsion Breaker is to be used when water

    washing takes place.

    PACK SIZES

    AVAILABLE

    20 LITRES

    200 LITRES

    1000 LITRES

    10,000 LITRES

    20,000 LITRES

    TECHNICAL

    SUPPORT

    Chemiphase wi l l

    of fer on- s i te

    technical support

    dur ing al l s tages of

    product ion.

    Technical supportincludes on-s i te

    test ing and resul ts .

    PRODUCT SAFETY

    All Chemiphase

    products are

    thoroughly

    researched and

    tested. All products

    are also COSHH

    registered and

    come complete with

    delivery.

    For more information

    on any of our

    products or services

    please visit us on the

    Web at:

    www.chemiphase.co.uk

    Phone :(08456) 432900

    Email :[email protected]

    Biodiesel Additive to Remove Water&Break Emulsions from Biodiesel

    Emulsion Breaker 210

    Emulsion Breaker 210 will speed up th

    splitting of the oil and water separatio

    producing two distinct layers.

    Typical dilution rate is 2-4 Litres per 1000 litr

    of water added, but this dependant upo

    the quality of the raw oil initially used. Onc

    mixed well, turn off the mixing equipme

    then leave to stand to ensure the f

    separation occurs prior to running the wat

    layer off the bottom of the tank.

    For more information on this product plea

    contact us directly on (08456) 432900 an

    we would be more than happy to help.

    http://www.chemiphase.co.uk/http://www.chemiphase.co.uk/http://www.chemiphase.co.uk/
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    PRODUCT RANGE :

    BIODIESEL ADDITIVES

    ALLKLEAR 400

    Biodiesel antioxidant to control

    oxidation levels in biodieselwhich can cause degradation

    and damage to tank storage.

    BIO-CONTROL 41

    Biodiesel biocide to control

    micro-biological growth in

    biodiesel.

    BIOBOOST 1000

    Biodiesel cetane enhancing

    product which increase

    performance and efficiency.

    PH CORRECT

    pH correction agent to control

    the pH of the biodiesel after

    the reaction stage.

    COLDFLOW 402Pour point additive designed

    for heavy oils like PME. SME,

    Tallow.

    CITRACLEAN

    Excellent cleaning detergent

    for areas where oil staining

    and greasy floors are a

    problem.

    Emulsion Breaker 210

    Emulsion Breaker 210 - Application

    Once the biodiesel reaction has been completed, remove the Glycerine layer prior to

    washing stage. Proceed to wash the biodiesel, with Emulsion Breaker 210 added to the warm

    water. We suggest the water is first heated to approximately 40 degrees C. The correct level

    of Emulsion Breaker 210 is then added to the warm water. This should be then mixed well to

    ensure all of the Emulsion Breaker 210 has dispersed correctly. This aqueous mixture should

    then be added to the bio diesel to remove the contaminants contained in the oil. Emulsion

    Breaker 210 will rapidly bring about the oil/water splitting process.

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    Potassium (ppm)

    0 hr hr 1 hrs

    Control 35 29.5 19.3

    409 15.5 6.5

    CC 16.5 6.5

    CC/N9 14.6 5.4

    417 16.7 9.6

    650 14.6 9.3

    evision date: March 2011

    CHEMIPHASE LTD

    SAFETY DATA SHEET

    EMULSION BREAKER 210

    Emulsion Breaker 210 Test Methods :Pour PointASTM

    D5950 (Deg C)

    CFPPASTM D6371

    (Deg C)

    PACK S IZES

    AVAILABLE

    20 LITRES

    200 LITRES

    1000 LITRES

    10,000 Tanker

    20,000 Tanker

    TECHNI CAL SUPPORT

    Ch emiph ase wi l l

    o f fer on- s i te

    technical suppor t

    du r in g a l l s tages o f

    product ion .

    Technical suppor t

    in c lu des on s i te

    test ing.

    DISCLAIMER :The information and all

    further technical advice

    are based on our presen

    knowledge and

    experience. However,

    they imply no liability or

    other legal responsibility

    on our part, including wi

    regards to existing third

    party intellectual proper

    rights, especially patent

    rights. In particular, no

    warranty, whether

    express or implied of

    guarantee of product

    properties is intended or

    implied. We reserve the

    right to make any

    changes according to

    technological progress o

    further developments. Thcustomer is not released

    from the obligation toconduct careful

    inspection and testing o

    incoming goods.

    Performance of theproduct described herei

    should be verified by

    testing, which should be

    carried out by qualified

    experts in the sole

    responsibility of the

    customer.

    Conclusion

    From the range of results you can see a clear drop in the potassium levels of the biodiesel

    samples tested. This indicates that due to the potassium being insoluble in the oil it has

    remained with the water and if the potassium levels have dropped off the water content has

    greatly been reduced. A clear indicator of the Emulsion Breaker range break tight emulsions

    found in this sample of biodiesel. The range of additives used are the major constituents of the

    Emulsion Breaker210. The results show a very quick reduction in water content and a greatly

    reduced water content in comparison with the control sample taken. The control sample

    contains no additives at all.

    Test Results from a Current Customer using

    Emulsion Breaker 210

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    1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY UNDERTAKING

    RODUCT NAME: EMULSION BREAKER 210

    RODUCT Description: Concentrated Oil Based Demulsifier -NEW FORMULATION MARCH 2005

    APPLICATION BIO DIESEL PRODUCTION

    UPPLIER Chemiphase LtdPO Box 168OrmskirkL40 6ZXTel: 00 44 1744 886622Fax: 00 44 1744 886633

    MERGENCY TELEPHONE (24 HR) 00 44 (0) 1744 886622

    2. COMPOSIITON INFORMATION ON INGREDIENTS

    AME EC No CAS No CONTENT CLASSIFICATION

    -BUTOXYETHANOL 203-905-0 111-76-2 8-15% XnR20/21/22 Xi,R36/38YLENE 215-535-7 1330-20-7 15-22% R10 Xn, R10/R20/21 Xi,

    R38 & S16

    he Full Text for all R- Phrases are displayed in Section 16

    3. HAZARDS IDENTIFICATION

    armful by inhalation, in contact with skin and if swallowed. Irritating to eyes and skin.

    LASSIFICATION Xn; R20/21/22. Xi;R36/38

    4. FIRST AID MEASURES

    ENERAL INFORMATION

    Move the exposed person to fresh air at once. Get medical attention if any discomfort continues.NHALATION

    Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Keep the affected person warm and at rest. Get pmedical attention.NGESTIONEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Remove victim immediately from source of exposure. Rinse mouth thoroughly. Proet affected person to drink large volumes of water to dilute the swallowed chemical. DO NOT induce vomiting. Get medical attention immediately.KIN CONTACTemove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothoaked through and wash as above. Get medical attention immediately.YE CONTACT

    Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eyelids. Continue to rinse east 15 minutes and get medical attention.

    5. FIRE FIGHTING MEASURES

    XTINGUISHING MEDIAse: Powder, Carbon dioxide (CO2). Water spray. FoamPECIAL FIRE FIGHTING PROCEDURESvoid water in straight hose stream; will scatter and spread fire. Use water to keep fire exposed containers cool and disperse vapours. Keep run-off water ewers and water sources. Dike for water control.PECIFIC HAZARDSy heating and fire, irritating vapours/gases may be formed.ROTECTIVE MEASURES IN FIRE

    Wear personal protective equipment. Wear self-contained breathing apparatus.

    6. ACCIDENTAL RELEASE MEASURES

    ERSONAL PRECAUTIONSWear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with skin and eyes. Provide adequate ventilation.NVIRONMENTAL PRECAUTIONS

    o not discharge into drains, watercourses or onto the ground.

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    PILL CLEAN UP METHODStop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected spillage must be properly la

    with correct contents and hazard symbol. Do not contaminate water sources or sewer.

    7. HANDLING AND STORAGE

    sage precautionsvoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level.TORAGE PRECAUTIONStore in tightly closed original container in a cool dry well-ventilated place. Use container made of : Stainless steel. Suitable plastic material. Do NOontainer made of: Carbon steel.

    8. EXPOSURE CONTROL/PERSONAL PROTECTION

    Name Std LT - ppm LT mg/m3 ST - ppm ST mg/m3

    YLENE OES 50 ppm (Sk) 220 mg/m3 (Sk) 100 ppm(Sk) 441 mg/m3(Sk)

    -BUTOXYETHANOL OES 25 PPM(Sk) 50 ppm(Sk)

    NGREDIENT COMMENTSOES = Occupational Exposure Standard. 2 Butoxyethanol (EGMBE) has a Biological Monitoring Guidance Value. See UK HSE EH40 Table 3

    ROTECTIVE EQUIPMENToggles and Gloves

    NGINEERING MEASURESrovide adequate general and local exhaust ventilation

    ESPIRATORY EQUIPMENT

    o specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination eWear respiratory protection with combination filter (dust and gas filter).

    AND PROTECTIONse protective gloves. Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform aboureakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.

    YE PROTECTIONWear approved safety goggles.

    OTHER PROTECTIONWear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.

    YGIENE MEASURESO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap and water ecomes contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

    9. PHYSICAL AND CHEMICAL PROPERTIES

    APPEARANCE Liquid

    OLOUR Slightly hazy

    ODOUR: Slight Aromatic Boiling Point/ range(OC) 137-143

    MELTING POINT (Oc) Pour Point , -20 RELATIVE DENSITY OC

    Ph, VALUE,

    DILUTED SOLUTION 6.5-8.5, 5% in water VISCOSITY < 100 mPas @ 20oC

    LASH POINT (OC) 25 AUTOFlammability (OC) 480

    10. STABILITY AND REACTIVITY

    TABILITYtable under normal temperature conditions.

    ONDITIONS TO AVOIDvoid heat, flames and other sources of ignition

    MATERIAL TO AVOIDtrong oxidising substances. Strong acids

    AZARDOUS DECOMPOSITION PRODUCTS

    uring fire, toxic gases (CO, CO2) are formed.

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    11. TOXICOLOGICAL INFORMATION

    OXIC DOSE 1 LD50 >4000 mg/kg (oral rat)

    NHALATIONarmful by inhalation. In high concentrations, vapours are anaesthetic and may cause headache, fatigue, dizziness and central nervous system effects. Upp

    espiratory irritation. Vapours may cause headache, fatigue, dizziness and nausea.

    NGESTIONarmful if swallowed. Gastrointestinal symptoms, including upset stomach. May cause nausea, headache, dizziness and intoxication.

    KIN CONTACT

    armful in contact with skin. Irritating to skin.

    YE CONTACTrritating to eyes. Spray and vapour in the eyes may cause irritation and smarting.

    Other Health Effectso sensitising effects known.

    12. ECOLOGICAL INFORMATION

    COTOXICITYhe product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can havarmful or damaging effect on the environment.

    MOBILITYhe product is insoluble in water

    IOACCUMULATIONo data available

    EGRADABILITYhe product is expected to be biodegradable

    WATER HAZARD CLASSIFICATIONWGK 1

    13. DISPOSAL CONSIDERATIONS

    ENERAL INFORMATIONmpty containers should be taken for local recycling, recovery or waste disposal

    ISPOSAL METHODSecover and reclaim or recycle, if practical. Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authoequirements.

    WASTE CLASSor this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer has to lay down theurpose first. The catalogue number has to be given according to the local waste removal processes.

    14. TRANSPORT INFORMATION

    GENERAL ADR/RID UN no: 1307 ADR Class: 3

    Packing Group: III Classification code: F1

    Shipping name n/a

    Labelling: 3 Hazard ID no: 30IMDG/IMO UN no: 1307 Class: 3

    Packing Group: III EMS:F-E, S-D

    Marine Pollutant: NO Labelling: 3

    IATA/ICAO UN no: 1307 Class: 3

    Packing Group: III Packing Instructions; 309(p&CA):310(CAO)

    Marine Pollutant: NO Labelling: 3

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    15. REGULATORY INFORMATION

    ABELLING

    Harmful

    ONTAINS 2-BUTOXYETHANOL, Xylene

    ISK PHRASES R20/21/22 Harmful by inhalation, in contact with skin and if swallowed

    R10 FlammableR36/38 Irritating to eyes and skin

    AFETY PHRASES S36/37 Wear suitable protective clothing and gloves

    S16 Keep away from sources of ignitionNO SMOKINGS60 This material and its container must be disposed of as hazardous waste

    S23 Do not breathe vapour/spray

    S26 In case of contact with eyes, rinse immediately with plenty of water and see medical advice

    S51 Use only in well-ventilated areas

    S24/25 Avoid contact with skin and eyes

    K REGULATORY REFERENCESpproved Supply List

    TATUTORY INSTRUMENTShemicals (Hazard Information and Packaging) RegulationsPPROVED CODE OF PRACTICElassification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations.

    UIDANCE NOTESOccupational Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply.

    16. OTHER INFORMATION

    EVISION COMMENTSeneral revision

    SSUED BYES

    EVISION DATE MARCH 2008

    EVISED SDS GENERATED MARCH 2005

    ISK PHRASES IN FULL

    10 Flammable

    20/21 Harmful by inhalation and in contact with skin20/21/22 Harmful by inhalation, in contact with skin and if swallowed36/38 Irritating to eyes and skin38 Irritating to skin

    X

    DISCLAIMERThe information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. Theinformation given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release andis not be considered a warranty or quality specification. The information relates only to the specific material designated and may notbe valid for such material used in combination with any other materials or in any process unless specified in the text.