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33 North Dearborn StreetChicago, Illinois 60602Tel. 312/578-9243, Fax: 312/578-9345

SITE ASSESSMENT REPORTFOR

TEXACO REFINERYLAWRENCEVILLE, LAWRENCE COUNTY, ILLINOIS

TDD No.: S05-9610-008PAN: 6C0801SIXX

JANUARY 17, 1997

Prepared for:UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Emergency Response Branch77 West Jackson Boulevard

Chicago, Illinois 60604

Prepared by

Reviewed by:

Approved by:

ART Assistant Program Manager

L-Thomas Kouris, STAJtT Prograbi Manager

Date

Date:

: / . / ? -#

Date:

Table of Contents

Section Page1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-12 Site Background . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1

2.1 Site Description . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-12.2 Site History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1

3 Site Assessment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-14 Analytical Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-15 Discussion of Potential Threats . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-16 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-1

Appendix Page

A Site Photographs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-l

B Analytical Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . B-lC RCMS Cost Projection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-l

List of Figures

Figure Page2-1 Site Location Map . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-33-1 Sample Location Map . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3

111

List of Tables

Table Page4-1 Analytical Sample Results Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-2

IV

1. Introduction

The United States Environmental Protection Agency (U.S. EPA) tasked the Ecology andEnvironment, Inc. (E & E), Superfund Technical Assessment and Response Team (START) toperform a site assessment at the Texaco Refinery (Texaco) site in Lawrenceville, Illinois. START

was requested under Technical Direction Document (TDD) S05-9610-008 to obtain and reviewbackground information; conduct a site visit; document site conditions with written and visual

documentation; make recommendations to U.S. EPA based on site assessment data collected;

determine site characteristics; determine pollutant dispersal pathways; develop a health and safetyplan; conduct sampling activities; schedule/provide for analytical support; perform air monitoring;and perform analytical data validation. All site activities were coordinated under the authority of theU.S. EPA On-Scene Coordinator (OSC) Steve Faryan.

1-1

2. Site Background

2.1 Site DescriptionThe Texaco site is located at 1 Havoline Street, Lawrenceville, Lawrence County, Illinois

(N 38°42'30.0" latitude and W 87°41'30.0" longitude). The 952-acre site is situated in a light

industrial and residential area and consists of the refinery, a landfarm, and Indian Acres (Figure 2-1).The 30-acre Indian Acres portion of the facility consists of several lagoons and is owned by IndianRefining Company. The landfarm area of the site consists of petroleum products treated bybiodegradation and is also owned by Indian Refining Company. The refinery portion of the site isowned by American Western Refining L.P. (American Western). The Embarrass River is locatedapproximately 2,000 feet east of the site and wetlands border the site to the south. Residential areasare located to the north, west, and south; and the site is fenced. The site operated as an oil refineryfrom approximately 1907 to 1985. The site is inactive, but not abandoned. Approximately 30employees currently maintain the facility.

2.2 Site HistoryThe Texaco site operated as an oil refinery from approximately 1907 to 1985 and had several

owners from 1907 to present.From 1907 to the early 1930s, the site was owned and operated by the Indian Asphalt

Company/Central Refining Company. From the early 1930s to 1985, the site was owned andoperated by The Texas Company, later renamed Texaco, Inc. In 1985, operations were suspendedand the site was internally transferred to Texaco Refining Marketing, Inc. (TRMI). In 1986, TRMItransferred the refinery to Indian Refining Company, a subsidiary of Texaco, Inc. In 1988, TRMIsold Indian Refining Company to Oil Producers, Inc. In 1989, Indian Refining Company stock wentto Castle Energy Corporation in a litigation settlement. Indian Acres and the landfarm remained partof Indian Refining Company, and the refinery portion went to Indian Refining Ltd., Partnership

2-1

(IRLP), a subsidiary of Castle Energy Corporation. In 1995, IRLP sold the refinery to AmericanWestern. Both Indian Refining Company and American Western are owned by Gadgil WesternCorporation of Dubai, Saudi Arabia. Gadgil Western Corporation is attempting to sell the refinery.

In 1986, the Illinois Environmental Protection Agency (IEPA) observed throughout the facility atotal of 33 potential Solid Waste Management Units, which consisted of landfarms, asbestos disposalareas, tank farm areas, and lagoons/impoundments. Numerous spills of petroleum product have beendocumented at the site from 1992 to 1995.

On July 16 and 17, 1996, the IEPA Site Assessment Unit collected soil and groundwater samplesfrom properties bordering the site. Three of the soil samples were collected in the residential areaimmediately north of Indian Acres. These samples were characterized by pH levels below 2, andcontained elevated levels of polynuclear aromatic hydrocarbons (PAHs). Upon receiving this data,IEPA informed U.S. EPA of the results, and U.S. EPA conducted a site assessment.

2-2

Refinery

Quadrangle Location

ecology and environment, inc.Technical Assistance Team

Region V33 N. Deirboro &., Chk^o, niinoii 60602

TITLESite Location Map

Texaco RefineryCITY

LawrencevilleSTATE

IllinoisSOURCE USGS Lawrencevfllef IL Quadrangle,

7.5 minute series

nOUREl

2-1SCALE

1:24000PAN

6C0801SIXXDATE 1965REVISED NA

2-3

3. Site Assessment

The site assessment occurred on October 16 and 17, 1996. On October 16, IEPA representativesCarol Fuller and Mark Densmore, START members Lisa Graczyk and Damon Sinars, and OSC SteveFaryan began the site assessment by performing a reconnaissance in the residential neighborhoodimmediately adjacent to the north side of Indian Acres. IEPA pointed out areas in the neighborhoodwhere a hard, black, asphalt-like substance appeared to be coming up out of the ground. These areaswere located in the yards and gardens of residents living adjacent to the Indian Acres fenceline, andalso approximately 100 yards north of the Indian Acres fenceline at 1606 4th Street. Air monitoringrevealed no organic vapors above background with the photoionization detector (PID).

START collected three soil/waste samples following the reconnaissance. All three samples,

RS-01, RS-02, and RS-03, resembled a hardened, black, asphalt-like material. Sample RS-01 wascollected from a material coming up out of the yard at 1606 4th Street (Figure 3-1). Sample RS-02was collected on City of Lawrenceville property, south of the wastewater treatment plant, andapproximately 20 feet north of the Indian Acres fenceline. Sample RS-03 was collected from asubstance coming from the ground, adjacent to Indian Acres fenceline, on residential property,approximately 200 feet west of the 302 Hickory Street house. A pH measurement was taken of soil

Sample RS-01 by mixing the soil with distilled water and then measuring the pH of the water with pHpaper. RS-01 had a pH measurement of 1.

On October 17, 1996, IEPA, START, U.S. EPA OSC, and Joe Malek, an U.S. EPA criminalinvestigator, met with refinery personnel. Joe Finch, Environmental Specialist, American Western;and John Braithwaite, Environmental Compliance Manager, American Western; showed IEPA,START, and U.S. EPA, the Indian Acres area. Indian Acres consists of several lagoons which havea hard crusty layer on top. Air monitoring throughout Indian Acres revealed no readings abovebackground of organic vapors on the PID. START collected Sample IR-1 approximately 20 feet

south of the residence at 3rd and Hickory Streets (302 Hickory Street). Sample IR-2 was collected

3-1

immediately south of the Indian Acres fenceline, and immediately south of where Sample RS-03 wascollected. Sample IR-3 was collected from what appeared to be a small lagoon which had hardened.Sample IR-4 was collected from a brown and black sediment in a large lagoon located just west of theentrance gate to Indian Acres. This lagoon contained approximately 3 feet of water over its sedimentand Sample IR-4 was collected by inserting a 5-foot PVC pipe into the sediment and then depositingthe sediment into the sample jar. The lagoon water was tested with pH paper and found to have a pHof 4. Sample IR-5 was collected approximately 5 feet south of the Indian Acres fenceline and southof where sample RS-02 was collected. Samples IR-1, IR-2, IR-3, and IR-5 resembled the black,hard, asphalt-like material collected in the neighborhood north of Indian Acres.

Samples IR-6 and IR-7 were collected approximately 20 feet south of Indian Acres in sewertrenches. While city contractors were installing a new sewer line, a black tar-like substance wasobserved in the ground. START collected samples in each of two openings which contained the tar-like material. IR-6 was collected in an east opening of the sewer trench and IR-7 in a west opening.

All samples, except IR-4, were collected at a depth of 0 to 6 inches. Sampling equipment,stainless steel trowels and bulb planters, were decontaminated prior to sampling with analconox/distilled water solution wash, followed by a distilled water rinse.

Following the sampling of Indian Acres, a tour of the landfarm was given by refinery personnel

and photographs were taken. An attorney for Indian Refining and American Western would not grantthe U.S. EPA access to the refinery property for sampling, but allowed U.S. EPA to tour the

refinery. A tour of the refinery was given by Finch and Braithwaite of American Western andphotographs of the refinery were taken.

Appendix A contains photographs of sample locations, Indian Acres, the landfarm, and therefinery.

3-2

4. Analytical Results

All samples were analyzed for pH, semivolatile organics compounds (SVOCs), volatile organiccompounds (VOCs), metals, and polychlorinated biphenyls (PCBs). Sample RS-02 was also analyzedfor pesticides. All samples were analyzed using U.S. EPA SW846 methodology. Quality AssuranceLevel II, as stated in the Office of Solid Waste and Emergency Response (OSWER)Directive 9360.4-01, April 1990, was requested. The samples were shipped Federal Express to thelaboratory, Ecology and Environment, Inc., Analytical Services Center, Lancaster, New York. The

samples were analyzed under analytical TDD S05-9610-806.Samples RS-01, RS-02, IR-1, and IR-2 had a pH of less than 2 units, and are therefore

considered a corrosive waste by 40 Code of Federal Regulations 261.22. A corrosive waste isdefined as a substance with a pH less than or equal to 2 or greater or equal to 12.5. Low levels of

VOCs and metals were detected in the samples (Table 4-1). PAHs (phenanthrene, pyrene, chrysene,and benzo(a)pyrene) were detected in the samples at moderate levels. Specifically, Sample RS-01contained the highest levels of PAHs at the following levels: 52 parts per million (ppm)phenanthrene, 190 ppm pyrene, 630 ppm chrysene, and 240 ppm benzo(a)pyrene. PCBs andpesticides were not detected in the samples. Analytical data is presented in Appendix B.

3-1

Appendix A

Site Photographs

A-l

5. Discussion of Potential Threats

Section 300.415, paragraph (b)(2) of the National Contingency Plan (NCP) lists factors to beconsidered when determining the appropriateness of a potential removal action at a site. Specifically,the following is a discussion of the applicable conditions which exist at the Texaco site:

• Actual or potential exposure to nearby human populations, animals, or the food chainfrom hazardous substances or pollutants or contaminants. Samples of a black, asphalt-likesubstance were collected from the surface soils of residential properties, which revealed thematerial to be corrosive, pH results as low as 1.3, and to contain low levels of VOCs andmetals, and moderate levels of PAHs. Corrosive materials are generally skin and eye irritantsand can cause burns. Some acids are toxic by inhalation and ingestion. Chrysene andbenzo(a)pyrene have shown to cause cancer in rats which had these compounds applied totheir skin. Phenanthrene and pyrene are questionable carcinogens. Chrysene,benzo(a)pyrene, phenanthrene, and pyrene all have reported human mutation data.

• High levels of hazardous substances or pollutants or contaminants in soils largely at ornear the surface that may migrate. All samples collected were at the soil surface and thesewere found to have hazardous properties. Heavy rains may cause migration of thesesubstances into surfacewater and groundwater. Winds can cause dust particulates containingthe hazardous constituents to migrate.

Weather conditions that may cause hazardous substances or pollutants or contaminantsto migrate or be released. Major flooding has occurred in the neighborhood immediatelynorth of Indian Acres on two occasions in the past 10 years, causing houses to becomeflooded. Flooding may potentially cause migration of these corrosive substances and PAHsinto peoples homes, surrounding soils, and groundwater. In addition, winds can cause dustparticulates containing the hazardous constituents to migrate.

5-1

6. Conclusion

The contaminants detected during this site assessment in surface soils have the potential to affecthuman health and the environment. In addition, the quantity of hazardous material in the ground isunknown. Further investigation to determine an approximate volume of this material is warranted.This may be accomplished using a drill rig, in conjunction with an appropriate extent ofcontamination sampling study.

A removal cost estimate was generated for this site using Removal Cost Management System(RCMS) Cost Projection, version 4.2. The total cost for the removal of 180 cubic yards ofcontaminated soil from the residential area north of Indian Acres is estimated at $52,000. It shouldbe noted that the actual volume of soil to excavate is unknown. The detailed RCMS cost projectionreport can be found in Appendix C.

6-1

UJ

Hickory Street

gCO

•5

f —— IA RS-01

RS-03A

AIR-2

^

V)

£

i — i

IA

R-l

Ol ^^-^1RS-02 A

I AIR-5

^^.IR-3

Wastewatertreatment plantarea

Indian Acres

^|jfe|

T

IR-4

IR ? Entrance gate ^-f^" I IR-6 ^ o^n <' A j l - - - - - - - - - - - - - - _ - _ _ - _ . _ - . _ ^ . _ _

Open sewer trench

Legend

Lagoon areas 0^2)Fence — —Sample location ANew sewer line - - - -

>ewer trench

|1] ecology and environment, inc.\T Superfund Technical Assessment and Response Team

Ty Region VJ 33 N. Dearborn

>^ Chicago, IL 60602TITLE

Sample Location MapSITE

Texaco RefineryCITY - .,, STATELawrenceville IL

FIGURE *

3-1SCALE

Not To ScalePAN

6C0701SIXX

Table 4-1

Analytical Results SummaryTexaco Refinery

October 16 and 17, 1996

Parameter

PH

Volatile Organics 0»g/Kg)

Methylene chloride

Acetone

Carbon disulfide

2-Butanone

1,1,1 -Trichloroethane

Benzene

4-Methyl-2-Pentanone

2-Hexanone

Toluene

Ethyl benzene

Xylene (total)

Semi-volatile Organics(pg/Kg)

2-Methyl-naphthalene

Phenanthrene

Pyrene

Chrysene

Benzo(a)Pyrene

Sample Designation

RS-01

1.3

RS-02

1.8

RS-03

3.0

IR-1

1.6

IR-2

1.8

IR-3

6.8

43BJ

830

6J

310

ND

19

76

61J

13

ND

ND

10J

1.800E

ND

500E

ND

5.700E

190

590E

150

57

470E

14B

410E

ND

120

11

59

40

99

4J

ND

17

ND

5.000E

ND

1,500

ND

200

580

2.400E

180

110

860

ND

52.000J

190.000J

630.000J

240.000J

ND

36.000J

ND

ND

84.000J

ND

ND

ND

48.000J

ND

ND

45.000J

ND

160,000

ND

49BJ

5.100E

9J

1.700E

ND

47

940

3.300E

130

71

790

ND

39,0001

ND

ND

ND

26BJ

360

ND

120

ND

ND

21J

61

ND

ND

ND

ND

ND

ND

ND

ND

IR-4

6.6

3J

9J

ND

ND

ND

ND

ND

ND

ND

ND

ND

IR-5

3.3

IR-6

7.3

IR-7

4.5

22BJ

120

ND

88

ND

ND

30

110

ND

ND

ND

ND

22

2J

ND

ND

45

ND

ND

42

28

210

2J

650E

ND

180

ND

29

22J

67

28

21

230

ND

ND

ND

14.000J

ND

ND

ND

ND

540.000J

ND

170.000J

36.000J

ND

ND

ND

ND

ND

ND

ND

ND

Table 4-1

Analytical Results SummaryTexaco Refinery

October 16 and 17, 19%

Parameter

Metals (mg/Kg)

Arsenic

Barium

Cadmium

Chromium

Lead

Mercury

Selenium

Silver

Sample Designation

RS-01 RS-02 RS-03 IR-1 1R-2 IR-3 IR-4

ND

4.4B1*

1.0

1.5

202*

ND

ND

ND

8.1*

35.5*

ND

3.3

171*

ND

ND

ND

4.8*

44.0*

0.08B1

4.9

148*

0.03NB1

ND

ND

2.9*

26.8*B'

ND

2.9

64.1*

ND

ND

ND

1.1*B'

12.3*B'

0.30B'

1.8

48.4*

ND

ND

ND

10.4*

113*

ND

6.7

28.6*

ND

1.0

ND

4.8*

38.2*

ND

5.6

244*

0.31N

ND

ND

IR-5 IR-6 IR-7

2.3*

59.6*

ND

2.2

47.7*

ND

0.68

ND

ND

ND

0.72

ND

7.8*

0.05N

ND

ND

8.8*

127*

ND

LIB1

17.0*

ND

ND

ND

Key,ND = Compound was not detected.E = Compound concentration exceeds calibration standard concentrations.J = Concentration is estimated.B = Compound was detected in blank.B' = Value is less than the contract required detection limit but greater than or equal to the instrument detection limit.* = Duplicate analysis not within control limits.N = Spiked sample recovery not within control limits.

Source: Ecology and Environment, Inc., Analytical Services Center, Lancaster, New York, Analytical TDD S05-9610-806.

FIELD PHOTOGRAPHY LOG SHEET

SITE NAME; Texaco Refinery PAGE 1 OF 13U.S. EPA ID; A567 TDD; S05-9610-008 PAN; 6C0801SIXX

DATE: 10-16-96

TIME: 1550

DIRECTION OFPHOTOGRAPH:Down__________

WEATHERCONDITIONS:1 ny,________

50 - 60°F_____

PHOTOGRAPHED BY:Lisa Graczyk

SAMPLE ID(if applicable):RS-01_________

DESCRIPTION: Close-up of Sample RS-01 location.

j.'E: 10-16-96

TIME: 1550

DIRECTION OFPHOTOGRAPH:East_________

WEATHERCONDITIONS:sunny,________

50 - 60°F_____


SAMPLE ID(if applicable):RS-01_______

DESCRIPTION: Location of Sample RS-01. Edge of trailer home can be seen at^ n -v- ~I c^ •£ +~ r^-F r^ V) r^ f- r-, r~\ -y "pi Vl


SITE NAME; Texaco Refinery PAGE 2 OF 13U.S. EPA ID; A567 TDD; S05-9610-008 PAN; SCO8 01SIXX

DATE: 10-16-96

TIME: 1625

DIRECTION OFPHOTOGRAPH:South________

WEATHEREDITIONS:

fennny,________

50 - 60°F______



DESCRIPTION: Location of Sample RS-02. Bulb planter in center of photographmarks the exact location of Sample RS-02._______________________________

DATE: 10-16-96

TIME: 1625

DIRECTION OFPHOTOGRAPH:Down____________

WEATHERCONDITIONS:sunny,____________

50 - 60°F______




SITE NAME: Texaco Refinery PAGE 3 OF 13U.S. EPA ID; A567 TDD; S05-9610-008

DATE: 10-16-96

TIME: 1640


WEATHERCONDITIONS:sunny,_______

50 - 60°F______


SAMPLE ID(if applicable):RS-03

DESCRIPTION: Location of Sample RS-03

DATE: 10-16-96

"""ME: 1640

DIRECTION OFPHOTOGRAPH:South_________

WEATHERCONDITIONS:sunny,___________

50 - 60°F______



DESCRIPTION: Location of Sample RS-03

FIELD PHOTOGRAPHY LOG SHEETL


DATE: 10-16-96

TIME: 1640

DIRECTION OFPHOTOGRAPH:East_________


50 - 60°F_____

P^TOGRAPHED BY:Lisa Graczyk

SAMPLE ID(if applicable):RS-03

DESCRIPTION: Area of Sample RS-03 location.

DATE: 10-17-96

". 'E: 0955

DIRECTION OFPHOTOGRAPH:North________

WEATHERCONDITIONS:sunny,_________

50 - 60°F_____


SAMPLE ID(if applicable):IR-1_________

DESCRIPTION: Close-up of Sample IR-1



DATE: 10-17-96

TIME: 0955____


WEATHERCONDITIONS:g- "ny,________

50 - 60°F_______


SAMPLE ID(if applicable):

DESCRIPTION: Location of Sample IR-1

J5ATE: 10-17-96

TIME: 0955

DIRECTION OFPHOTOGRAPH:North_________

WEATHERCONDITIONS:sunny,__________

50 - 60°F________


SAMPLE ID(if applicable):



SITE NAME: Texaco Refinery PAGE 6 OF 13U.S. EPA ID; A567 TDD; S05-9610-008 PAN; 6C0801SIXX

DATE: 10-17-96

TIME: 1010

DIRECTION OFPHOTOGRAPH:North___________

WEATHERCONDITIONS:sunny,____________

50 - 60°F______

^.OTOGRAPHED BY:Lisa Graczyk

SAMPLE ID(if applicable):IR-3__________

DESCRIPTION: Close-up of Sample IR-3

DATE: 10-17-96

'ME: 1010

DIRECTION OFPHOTOGRAPH:North_________

WEATHERCONDITIONS:sunny,__________

50 - 60°F_______





SITE NAME; Texaco Refinery PAGE 7 OF 13U.S. EPA ID; A567 TDD; S05-9610-008 PAN: 6C0801SIXX

DATE: 10-17-96

TIME: 1030

DIRECTION OFPHOTOGRAPH:

sunny ,

50 - 60°F


SAMPLE ID(if applicable) :IR-3 ___

DESCRIPTION: Close-up of location of Sample IR-3 on Indian Acres

DATE: 10-17-96

TIME: 1030

DIRECTION OFPHOTOGRAPH :

WEATHERCONDITIONS :sunny, ________

50 - 60°F _____

PHOTOGRAPHED BYLisa Graczyk

SAMPLE ID(if applicable)IR-3


SITE NAME; Texaco Refinery PAGE 8 OF 13U.S. EPA ID: A567 TDD: S05-9610-008 PAN; 6C0801SIXX

DATE: 10-17-96

TIME: 1035

V? - ';/ /? j " iV /

DIRECTION OFPHOTOGRAPH:unknown______

WEATHERCONDITIONS:nny,________

50 - 60°F_____


SAMPLE ID(if applicable):NA

DESCRIPTION: Indian Acres property.

DATE: 10-17-96

TIME: 1035____

DIRECTION OFPHOTOGRAPH:unknown______


50 - 60°F_____


SAMPLE ID(if applicable):NA____________


SITE NAME; Texaco Refinery PAGE 9 OF 13U.S. EPA ID: A567 TDD; S05-9610-008 PAN; 6C0801SIXX

DATE: 10-17-96

TIME: 1035

DIRECTION OFPHOTOGRAPH :unknown

WEATHERCONDITIONS :

50 - 60°F

PHOTOGRAPHED BY:Lisa Graczvk

SAMPLE ID(if applicable) :NA ____________


10-17-96

TIME: 1035

DIRECTION OFPHOTOGRAPH:unknown_____________

WEATHERCONDITIONS:sunny,_______________

50 - 60°F______

PHOTOGRAPHED BY;Lisa Graczyk





DATE: 10-17-96

TIME: 1045

DIRECTION OFPHOTOGRAPH:Southwest_____

WEATHERCONDITIONS:any,________

50 - 60°F_____


SAMPLE ID(if applicable):IR-4

DESCRIPTION: Lagoon where Sample IR-4 was collected.

^TE: 10-17-96

TIME: 1055____

DIRECTION OFPHOTOGRAPH:Southwest_____


50 - 60°F_____



DESCRIPTION: Location of Sample IR-4. PVC pipe sticking out of lagoon incenter of photograph marks exact location of Sample IR-4._________________


SITE NAME; Texaco Refinery PAGE 11 OF 13U.S. EPA ID; A567 TDD: S05-9610-008 PAN; 6C0801SIXX

DATE: 10-17-96

TIME: 1103


WEATHERt^_ JDITIONS:sunny,________

50 - 60°F_____


SAMPLE ID(if applicable):IR-5 _____

DESCRIPTION: Location of Sample IR-5.

DATE: 10-17-96

TIME: 1110

DIRECTION OFPHOTOGRAPH:East_____________

WEATHERCONDITIONS:sunny,___________

50 - 60°F_________




SITE NAME; Texaco Refinery PAGE 12 OF 13U.S. EPA ID; A567

DATE: 10-17-96

TIME: 1117

DIRECTION OFPHOTOGRAPH :Southeast

WEATHER-"•"NDITIONS:

50 - 60°F

TDD: S05-9610-008 PAN; 6C0801SIXX


SAMPLE ID(if applicable) :IR-6 ______


DATE: 10-17-96

TIME: 1138



50 - 60°F______




SITE NAME: Texaco Refinery PAGE 13 OF 13U.S. EPA ID; A567 TDD; S05-9610-008 PAN; 6C0801SIXX

DATE: 10-17-96

TIME: 1200

DIRECTION OFPHOTOGRAPH:Southeast_____

WEATHER'"TODITIONS:v ..nny,________

50 - 60°F_____



DESCRIPTION: Landfarm area

Appendix B

Analytical Data

B-l



DATE:

TO:

FROM:

THROUGH:

SUBJECT:

REFERENCE:

M E M O R A N D U M

November 19, 1996

Lisa Graczyk, START Project Manager, E & E, Chicago,Illinois

David Hendren, START Analytical Services Manager,E & E, Chicago, Illinois

Mary Jane Ripp, Assistant START Program Manager,E & E, Chicago, Illinois

Organic Data Quality Review for Volatile OrganicCompounds, Texaco Refinery, Lawrenceville, LawrenceCounty, Illinois

Project TDD S05-9610-017Project PAN 6C0801SIXX

Analytical TDD S05-9610-806Analytical PAN 6CAF01TA

The data quality assurance (QA) review of ten soil/sludge samplescollected from the Texaco Refinery site is complete. The sampleswere collected on October 16 and 17, 1996, by the SuperfundTechnical Assessment and Response Team (START) contractor,Ecology and Environment, Inc. (E & E). The samples weresubmitted to Ecology and Environment, Inc., Analytical ServicesCenter, Lancaster, New York. The laboratory analyses wereperformed according to the United States Environmental ProtectionAgency (U.S. EPA) Solid Waste 846 Method 8240/8260.

Sample Identification

STARTIdentification No.

RS-01RS-02RS-03IR-1IR-2IR-3IR-4IR-5IR-6IR-7

LaboratoryIdentification No

EE-96-EE-96EE-96-EE-96EE-96EE-96EE-96EE-96-EE-96EE-96

54598545995460054601546025460354604546055460654607

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806VGAPage 2

Data Qualifications:

I. Sample Holding Time: Acceptable

The samples were collected on October 16 and 17, 1996, andanalyzed on October 28, 1996. This is within the 14-dayholding time limit.

II. Gas Chromatography/Mass Spectrometry (GC/MS) Tuning:Acceptable

GC/MS tuning to meet ion abundance criteria usingbromofluorobenzene (BFB) were acceptable and samples wereanalyzed within 12 hours of BFB tuning.

III. Calibrations:

• Initial Calibration: Acceptable

A five-point initial calibration was performed prior toanalysis. All average response factors were greater than0.05. The percent relative standard deviations (%RSDs)between response factors were less than 30% for alldetected target compounds.

* Continuing Calibration: Acceptable

The percent differences of the response factors were lessthan 25%, as required for detected target compounds.

IV. Blank: Acceptable

A method blank was analyzed with the samples. No targetcompounds or contaminants were detected in the blank.

V. Internal Standards: Acceptable

The areas of the internal standards in the samples wereoutside the range of -50% to +100% of the associatedcalibration check standard. Because the surrogaterecoveries were found to be acceptable, qualification wasnot judged to be necessary. The retention times of theinternal standards were within the 30-second control limit.

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806VGAPage 3

VI. Compound Identification: Acceptable

The mass spectrum and retention time of the detectedcompound matched those of the standards.

VII. Additional QC Checks: Acceptable

The recoveries of the surrogates used in the samples andblank were within laboratory-established guidelines, exceptfor one surrogate in three samples. The failure of one ofthe three surrogates used is allowed for this method.

VIII. Overall Assessment of Data for Use: Acceptable

The overall usefulness of the data is based on criteria forQA Level II as outlined in the Office of Solid Waste andEmergency Response (OSWER) Directive 9360.4-01 (April1990), Data Validation Procedures, Section 5.0, VOAs ByGC/MS analysis. Based upon the information provided, thedata are acceptable for use.

1AVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

Lab Name: E & E INC.

Lab Code: EANDE Case No.: 269

Matrix: (soil/water) SOIL

Sample wt/vol: 5.1 (g/mL) G

Level: (low/med) LOW

% Moisture: not dec. 32

Contract:

SAS No.:

IR-1

GC Column: DB-624

Soil Extract Volume:

I CAS NO.

ID: 0.530 (mm)

(uL)

COMPOUND

SDG No.: 54598

Lab Sample ID: 54601

Lab File ID: F6541

Date Received: 10/22/96

Date Analyzed: 10/28/96

Dilution Factor: 1.0

Soil Aliquot Volume:

CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG Q

(uL)

74-87-3-----74-83-9-----75-01-4-----75-00-3-----75-09-2-----67-64-1-----75-15-0-----75-35-4-----75-34-3-----67-66-3-----i n i n c. oo Q Q *3 *371-55-6-----56-23-5-----75-27-4-----•7Q Q -7 C

10061-01-5--79-01-6-----124-48-1----79-00-5-----71-43-2-----10061 02 6--75-25-2-----108-10-1----.D :? X - /O-D----127-18-4----79-34-5-----1 n Q Q Q "3

108 90 7100-41-4----100-42-5----1330-20-7---

- - - -Chloromethane- - - -Bromomethane----Vinyl Chloride- - - - Chloroethane----Methylene Chloride

i-i. — C L.W11C

----Carbon Disulfide- - - - 1 , 1 -Dichloroethene- - - -1, 1-Dichloroe thane----Chloroform--- -1 , 2-Dichloroethane- - - -2-Butanone----1,1, 1 -Trichloroethane----Carbon Tetrachloride- - - -Bromodichloromethane- - - - 1 , 2 -Dichloropropane- - - -cis-l , 3-Dichloropropene- - - -Trichloroethene- - - -Dibromochlorome thane----1,1, 2 -Trichloroethane

i-j v_> i. i £j v_. xi.\_.

--- - trans-1, 3 -Dichloropropene- - - -Bromoform- - --4-Methyl-2-Pentanone- - - - 2 - Hexanone- - - -Tetrachloroethene----1,1,2, 2 -Tetrachloroethane----Toluene- - - -Chlorobenzene- - - -Ethylbenzene- - --Styrene----Xylene (total)

1414141414

57001414141414

15001414141414141414851414

3301300141469144614

360

UUUUUEUUUUUEUUUUUUUU

UUEEUU

U

UE

FORM I VOA 3/90

25

IEVOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract:

SAS No.:

IR-1

LOW

32

ID: 0.530 (mm)

(UL)

SDG No.: 54598


Lab File ID: F6541




Soil Aliquot Volume: (uL)

Number TICs found: 12CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

CAS NUMBER

1 .2. 107-87-93 .4 .5.6.7 .8.9.

10.11 .12. 1120-21-4

COMPOUND NAME

Pentanone isomer2-PentanoneHexanone isomerHeptanone isomerNonane isomerHeptanone isomerDecane isomerUnknown hydrocarbonTrimethylbenzene isomerOctanone isomerPropylbenzene isomerUndecane

RT

10.3311.6614.3317.5018.5119.7120.0021.9922.4723 . 0923.3824 .68

EST. CONC.

370370180120330330190590300270230540

Q

JJNJJJJJJJJJJN

FORM I VOA-TIC 3/90

26


EPA SAMPLE NO.







GC Column: DB-624 ID: 0.530 (mm)

Soil Extract Volume: (uL)

Contract:

SAS No.:

IR-1RE

CAS NO. COMPOUND

SDG No.: 54598

Lab Sample ID: 54601RE

Lab File ID: F6570





CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

74-87-3------74-83-9------75-01-4------75-00-3------75-09-2------67-64-1------75-15-0------75-35-4------75-34-3------67-66-3------107-06-2-----*"? Q Q T "3

71-55-6------56-23-5------75-27-4------"~J Q Q ""7 C

10061-01-5---H Q n i a124-48-1-----79-00-5------71-43-2------10061-02-6---75-25-2------108-10-1-----591-78-6-----"1 ?7 - 1 ft 479-34-5-------i n Q Q Q "3

108-90-7-----100-41-4-----100-42-5-----1330-20-7----

- - -Chloromethane- - -Bromomethane---Vinyl Chloride- - - Chloroethane---Methylene Chloride

f^\^ \-f L> 11 >

---Carbon Disulfide---1, 1-Dichloroethene- - - 1 , 1 -Dichloroethane- - -Chloroform- - - 1 , 2 -Dichloroethane- - -2-Butanone---1,1, 1-Trichloroethane- - - Carbon Tet rachlor ide- - -Bromodichloromethane- - - 1 , 2 -Dichloropropane- - -cis-l , 3 -Dichloropropene- - -Trichloroethene- - -Dibromochloromethane---1,1,2 -Trichloroethane

DGrizsiiS---trans-l, 3 -Dichloropropene- - -Bromof orm- - - 4 -Methyl - 2 - Pentanone- --2-Hexanone- - -Tetrachloroethene---1,1,2, 2 -Tetrachloroethane- - -Toluene- - -Chlorobenzene- - -Ethylbenzene- - -Styrene---Xylene (total)

9292929276

50009292929292

15009292929292929292

2009292

5802400

929218092

11092

860

UUUUBJEUUUUU

UUUUUUUU

UU

EUU

U

U

FORM I VOA 3/90

52


EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract:

SAS No.:

IR-1RE

LOW

32

ID: 0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6570






CAS

1.2 .3 .4 .5 .6.7.8.9.

10.11.12 .

NUMBER

107-87-9111-65-9

110-12-3

111-13-7

1120-21-4

COMPOUND NAME

2 -PentanoneOctaneHeptanone isomerNonane isomerHeptanone isomerDecane isomerOctanone isomerUnknown hydrocarbonTrimethylbenzene isomerOctanone isomerPropylbenzene isomerUndecane

RT

11.6714.6017.5018.5119.7120.0021. 1021.9822.4823 .0823 .3824 .68

EST . CONC .

280530510

1200150060049023001300120010001400

Q

JNJNJJJNJJJJJNJJN

FORM I VOA-TIC- 3/l°3


EPA SAMPLE NO.









Contract

SAS No.

IR-2

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6542






74-87-3---------Chloromethane__________74-83-9---------Bromomethane___________75-Ol-4---------Vinyl Chloride75-00-3--------- Chloroethane ______75-09-2---------Methylene Chloride67-64-1---------Acetone _________75-15-0---------Carbon Disulfide ~75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform __________107-06-2--------1,2-Dichloroethane78-93-3--------- 2 -Butanone___________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------l,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6---------Trichloroethene_________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane____71-43-2-------- -Benzene_____10061-02-6------trans-1,3-Dichloropropene75-25-2-------- -Bromof orm_______________108-10-1--------4-Met hyl-2 -Pentanone____591-78-6--------2- Hexanone ___________127-l8-4--------Tetrachloroethene ~79-34-5---------1,1,2,2-Tetrachloroethane108-88-3--------Toluene_________________108-90-7--------Chlorobenzene___________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

1212121212

100009

12121212

32001212121212121212471212

12003700

1212130126912710

UUUUUEJUUUUEUUUUUUUU

UUEEUU

U

UE

FORM I VOA 3/90

SO


EPA SAMPLE NO.

ILab Name: E & E INC.



Sample wt/vol : 5.0 (g/tnL) G

Level: (low/mad) LOW

% Moisture: not dec.

GC Column: DB-624


Contract:

SAS No.:

IR-2

19

ID: 0.530 (mm)

(UL)

SDG No.: 54598


Lab File ID: F6542





dumber TICs found: 11CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

CAS

1.2 .3 .4 .5 .6 .7 .8.9.

10 .11.

NUMBER

79-20-9107-87-9

589-38-8

110-43-0

1120-21-4

COMPOUND

Methyl acetate2-PentanoneHexanone isomer3 -HexanoneHeptanone isomer2-HeptanoneOctanone isomerTrimethylbenzeneOctanone isomer

NAME

isomer

Propylbenzene isomerUndecane

RT

3.7611.6714 .3315.6218.5419.7121.9822 .4823.0923 .3824 .68

EST . CONC .

50130250170460580880670410550490

Q

JNJNJJNJJNJJJJJN

FORM I VGA-TIC 3/90

Z 81


EPA SAMPLE NO.







,GC Column: DB-624 ID: 0.530 (mm)

'Soil Extract Volume: (uL)

Contract:

SAS No.:

IR-2RE

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6571






74-87-3---------Chloromethane__________74-83-9---------Bromomethane___________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_______75-09-2---------Methylene Chloride67-64-l---------Acetone _________75-15-0---------Carbon Disulfide75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform_________107-06-2--------1,2-Dichloroethane78-93-3---------?- But anone____________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------1,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6-------- -Tr ichloroethene ______________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2---------Benzene _____________10061-02-6------t rans-1,3-Dichloropropene_75-25-2-------- -Bromof orm_______________~108-10-1--------4-Methyl-2 -Pentanone____591-78-6--------2- Hexanone ______________127-18-4--------Tetrachloroethene79-34-5---------l,l,2,2-Tetrachloroethane108-88-3--------Toluene________________108-90-7--------Chlorobenzene__________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

6262626249

51006262626262

17006262626262626262426262940

33006262120627162790

UUUUBJEUUUUUEUUUUUUUUJUU

EUU

U

U

(uL)

FORM I VGA 3/90

107


EPA SAMPLE NO.


I Lab Code: EANDE Case No.: 269


'sample wt/vol: 1.0 (g/mL) G

Level: (low/med)

% Moisture: not dec

• GC Column: DB-624

I Soil Extract Volume

Contract:

SAS No.:

IR-2RE

LOW

19

ID: 0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6571






CAS

1.2.3 .4 .5.6.7 .8 .9.

10.11.

NUMBER

79-20-9107-87-9

111-65-9

110-43-0

1120-21-4

COMPOUND NAME

Methyl Acetate2-PentanoneHexanone isomerOctaneHeptanone isomer2-HeptanoneOctanone isomerTrimethylbenzene isomerOctanone isomerPropylbenzene isomerUndecane

RT

3.7511.6614.3314.5918.5319.7221.9722.4723.0823.3924.68

EST . CONC .

180400480460990

120020001300100012001100

Q

JNJNJJNJJNJJJJJN

FORM I VOA-TIC


EPA SAMPLE NO.






|% Moisture: not dec. 17



Contract

SAS No.

IR-3

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6543






74-87-3---------Chloromethane___________74-83-9-------- -Bromomethane___________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_______75-09-2---------Methylene Chloride67-64-l---------Acetone _________75-15-0---------Carbon Disulfide75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform __________107-06-2--------1,2-Dichloroethane7S-93-3---------2- But anone __________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane______78-87-5---------l,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6-------- -Trichloroethene________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2---------Benzene ___________10061-02-6------t rans-1,3-Dichloropropene_75-25-2---------Bromoform_______________108-10-1--------4-Methyl-2 -Pentanone_____591-78-6--------2- Hexanone ___________127-18-4--------Tetrachloroethene79-34-5---------1,!,2,2-Tetrachloroethane10 8-88-3--------Toluene________________108-90-7--------Chlorobenzene___________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

121212121257012121212122001212121212121212121212661701212212121212

UUUUUEUUUUU

UUUUUUUUUUU

UUJUUUU

FORM I VOA


EPA SAMPLE NO.







GC Column: DB-624 ID:


Contract

SAS No.

IR-3

0.530 (mm)

(uL)

Number TICs found: 10

SDG No.: 54598


Lab File ID: F6543






(uL)

CAS

1.2 .3 .4 .5.6.7 .8 .9.

10 .

NUMBER

79-20-9107-87-9

589-38-8

106-35-4110-43-0

111-13-7

COMPOUND NAME

Methyl acetate2-PentanoneHexanone isomer3 -HexanoneHeptanone isomer3-Heptanone2 -HeptanoneDimethylcyclopentanone isomeOctanone isomer2-Octanone

RT

3.7611.6614.1715.6118.5519.4419.7120.6421.9523 .07

EST . CONC .

25622934252987306955

Q

JNJNJJNJJNJNJJJN

FORM I VOA-TIC 3/90

135


EPA SAMPLE NO.

I







Contract:

SAS No.:

IR-3RE

iGC Column: DB-624

^Soil Extract Volume:

CAS NO.

ID: 0.530 (ram)

(uL)

COMPOUND

SDG No.: 54598


Lab File ID: F6567






74-87-3-----74-83-9-----75-01-4-----75-00-3-----75-09-2-----67-64-1-----75-15-0-----75-35-4-----75-34-3-----67-66-3-----107-06-2----78-93-3-----71-55-6-----56-23-5-----7R 07 4 _/ _j £* i iTO Q 1 C

10061-01-5--79-01-6-----124-48-1----79-00-5-----71-43-2-----10061-02-6--75 25 2f ~J £* *J £*

108-10-1----C Q -1 -70 /-

127-18-4----79-34-5-----i n Q Q Q "jIn o Q n ^100-41-4----100-42-5----1330-20-7---

- - - -Chlorome thane- - - -Brotnome thane----Vinyl Chloride- - - -Chloroethane- ---Methylene Chloride

f^\^v** \*-**JHi*^

----Carbon Disulfide- - - -1 , 1-Dichloroethene- - - - 1 , 1 -Dichloroethane----Chloroform----1,2 -Dichloroethane- - - -l"!-Butanone- - - - 1 , 1 , 1 -Trichloroethane----Carbon Tetrachloride- - - -Bromodichloromethane- - - - 1 , 2 -Dichloropropane----cis-1,3 -Dichloropropene- - - -Trichloroethene- - - -Dibromochloromethane----1,1, 2 -Trichloroethane

-- --trans-1 , 3 -Dichloropropene----Bromoform- - - - 4 -Methyl - 2 - Pentanone- - - - 2 -Hexanone- - - -Tetrachloroethene----1,1,2,2 -Tetrachloroethane----Toluene- - - -Chlorobenzene- - - -Ethylbenzene- - - -Styrene----Xylene (total)

303030302636030303030301203030303030303030303030216130303030303030

UUUUBJ

UUUUU

UUUUUUUUUUUJUUUUUUU

FORM I VOA 3/90

155


EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract:

SAS No.:

IR-3RE

LOW

17

ID: 0.530 (mm)

(UL)

SDG No.: 54598


Lab File ID: F6567






(uL)

CAS NUMBER

1. 107-87-92.3 .4. 110-43-05 .6 .7.8.9.

10.

COMPOUND NAME

2-PentanoneHexanal isomerUnknown oxygenated hydrocarb2-HeptanoneUnknown hydrocarbonOctanone isomerDimethyl cyclohexanone isomeUnknown oxygenated hydrocarbUnknown oxygenated hydrocarbUnknown hydrocarbon

RT

11.6616 .1017.9619.7119.9321.9522.1723.0223 .2823 .98

EST . CONC .

40171728342818292421

Q

JNJJJNJJJJJJ

FORM I VOA-TIC 3/90

" 156


EPA SAMPLE NO.









Contract

SAS No.

IR-4

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6544






74-87-3---------Chloromethane__________74-83-9---------Bromomethane___________75-01-4---------Vinyl Chloride75-00-3--------- Chloroethane ______75-09-2---------Methylene Chloride67-64-1---------Acetone _________75-15-0---------Carbon Disulfide ~75-35-4---------1, 1 -Dichloroethene_________75-34-3---------1,1-Dichloroethane______67-66-3--------- Chloroform _____________107-06-2--------l,2-Dichloroethane7S-93-3---------2- But anone _____________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------1,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6-------- -Trichloroethene________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2-------- - Benzene____^_________10061-02-6------t rans-1,3-Dichloropropene75-25-2-------- -Bromof orm______________~108-10-1--------4-Methyl-2 -Pentanone____591-78-6--------2- Hexanone __________127-18-4--------Tetrachloroethene79-34-5---------l,l,2,2-Tetrachloroethane108-88-3--------Toluene_______________~_108-90-7--------Chlorobenzene___________100-41-4--------Ethylbenzene___________100-42-5------- - S tyrene ____________________1330-20-7-------Xylene '(total)

1717171739

1717171717171717171717171717171717171717171717171717

UUUUJJUUUUUUUUUUUUUUUUUUUUUUUUUU

(uL)

FORM I VOA 3/90175


EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract:

SAS No.:

IR-4

LOW

43

ID: 0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6544





CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/KG

" CAS NUMBER COMPOUND NAME RT EST . CONC . Q

FORM I VOA-TIC 3/90

176


EPA SAMPLE NO.


,ab Code: EANDE Case No.: 269




'% Moisture: not dec. 11

Contract:

SAS No.:

IR-5

iGC Column: DB-624o'Soil Extract Volume

CAS NO.

ID: 0.530 (mm)

(uL)

COMPOUND

SDG No.: 54598


Lab File ID: F6545






74-87-3---------Chloromethane__________74-83-9-------- -Bromomethane___________75-01-4---------Vinyl Chloride75-00-3--------- Chloroethane__________75-09-2---------Methylene Chloride67-64-1---------Acetone75-15-0---------Carbon Disulfide75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform107-06-2--------1,2-Dichloroethane78-93-3---------?-But anone71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------1,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6-------- -Tr ichloroethene __________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2--------- Benzene____^ _____________10061-02-6------trans-1,3-Dichloropropene75-25-2-------- - Br omo f orm_______________108-lO-l--------4-Methyl-2-Pentanone____591-78-6--------2- Hexanone ______________127-18-4--------Tetrachloroethene79-34-5---------l,l,2,2-Tetrachloroethane108-88-3--------Toluene_______________'_108-90-7--------Chlorobenzene__________100-41-4--------EthyIbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

111111111127011111111118811111111111111111111113011011111111111111

UUUUUEUUUUU

UUUUUUUUUUU

UUUUUUU

FORM I VOA 3/90182


EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract:

SAS No.:

IR-5

LOW

11

ID: 0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6545






(uL)

' CAS

1 .2.3 .4 .5.6 .7.8.9.

10 .

NUMBER

107-87-9589-38-8

110-43-0

111-13-7

COMPOUND NAME

2-Pentanone3-HexanoneHexanal isomerMethylcyclopentanone isomer2-HeptanoneDimethylcyclopentanone isomeDimethylcyclopentanone isomeOctanone isomer2 -OctanoneTrimethylcyclohexanone isome

RT

11.6515.6316.1118.4019.7220.0320.6621.9723 .0924.58

EST . CONC .

28212622664826862719

Q

JNJNJJJNJJJCTNJ

FORM I VGA-TIC 3/90

183


EPA SAMPLE NO.




(Sample wt/vol : 2.0 (g/mL) G


1% Moisture: not dec. 11

pC Column: DB-624 ID: 0.530 (mm)

lO^-i

Contract:

SAS No.:

IR-5RE

'Soil Extract Volume:

CAS NO.

(uL)

COMPOUND

SDG No.: 54598


Lab File ID: F6568






74-87-3---------Chloromethane__________74-83-9---------Bromomethane_____________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_______75-09-2---------Methylene Chloride67-64-1---------Acetone _________75-15-0---------Carbon Disulfide75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform__________107-06-2--------1,2-Dichloroethane78-93-3---------2-Butanone___________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------1,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6--------- Trichloroethene______________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane____71-43-2---------Benzene ______________10061-02-6------trans-1,3-Dichloropropene_75-25-2---------Bromoform______________108-10-1--------4-Methyl-2 -Pentanone____591-78-6--------2- Hexanone _______________

79-34-5---------l,l,2,2-Tetrachloroethane108-88-3------- -Toluene________________~108-90-7--------Chlorobenzene__________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

28282828221202828282828422828282828282828282828114528282828282828

UUUUBJ

UUUUU

UUUUUUUUUUUJUUUUUUU

FORM I VOA 3/90

20;


EPA SAMPLE NO.







GC Column: DB-624


Contract:

SAS No.:

IR-5RE

ID: 0.530 (mm)

(UL)

Number TICs found:

SDG No.: 54598


Lab File ID: F6568






(uL)

' CAS NUMBER

1. 107-87-92 .3 .4 .5.6 .

COMPOUND NAME

2-PentanoneHeptanone isomerUnknown oxygenated hydrocarbOctanone isomerUnknown ketoneUnknown oxygenated hydrocarb

RT

11.6719.7019.9321.9623 .0923 .29

EST . CONC .

152821272321

Q

JNJJJJJ

FORM I VOA-TIC 3/90£03


EPA SAMPLE NO.




jsample wt/vol: 5.2 (g/mL) G


J% Moisture: not dec. 18

jGC Column: DB-624 ID: 0.530 (mm)

Contract:

SAS No.:

IR-6


I CAS NO.

(uL)

COMPOUND

SDG No.: 54598


Lab File ID: F6546






74-87-3---------Chloromethane___________74-83-9---------Bromomethane75-01-4---------Vinyl Chloride75-00-3---------Chloroethane75-09-2---------Methylene Chloride67-64-l---------Acetone ________75-15-0---------Carbon Disulfide ~75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3--------- Chloroform _______________107-06-2--------1,2-Dichloroethane78-93-3---------?-Butanone_____________71-55-6---------1,!,1-Trichloroethane ~56-23-5---------Carbon Tetrachloride_____75-27-4---------Bromodichloromethane____78-87-5---------l,2-Dichloropropane_____l006l-Ol-5------cis-l,3-Dichloropropene__79-01-6-------- -Trichloroethene__________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2--------- Benzene____^ __________10061-02-6------t rans-1,3-Dichloropropene_75-25-2---------Bromoform______________108-10-l--------4-Methyl-2-Pentanone____591-78-6--------2- Hexanone ___________127-18-4--------Tetrachloroethene79-34-5---------l,l,2,2-Tetrachloroethane108-88-3-------- Toluene_______________~108-90-7--------Chlorobenzene___________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

1212121212222121212121212121212121212124512121212121242122812340

UUUUU

JUUUUUUUUUUUUU

UUUUUU

U

UE

FORM I VOA 3/90

218


EPA SAMPLE NO.







.GC Column: DB-624 ID:

Contract:

SAS No.:

IR-6

JSoil Extract Volume

I Number TICs found:

0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6546





11CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

(uL)

CAS NUMBER

1. 108-87-22.3. 1678-91-74 .5 .6 .7.8.9.

10.11.

COMPOUND NAME

Cyclohexane, methyl -Octane isomerCyclohexane, ethyl -Trimethylcyclohexane isomerNonane isomerDecane isomerDecane isomerUnknown hydrocarbonTrimethylbenzene isomerUndecane isomerDecalin isomer

RT

11.1013 .1515.8516.0217.4420.0120.7121.5622.4822.7523 .74

EST. CONC.

190160866763576468706270

Q

JNJJNJJJJJJJJ

FORM I VGA-TIC 3/90

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET




pample wt/vol: 2.0 (g/mL) G


1% Moisture: not dec. 18


•Soil Extract Volume: (uL)

Contract •.

SAS No.:

IR-6RE

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6572






74-87-3---------Chloromethane__________74-83-9-------- -Bromomethane_________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_______75-09-2---------Methylene Chloride67-64-1---------Acetone75-15-0---------Carbon Disulfide75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform__________107-06-2--------1,2-Dichloroethane7S-93-3---------2- But anone____________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------l,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6-------- -Tr ichloroethene __________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2---------Benzene ____________10061-02-6------t rans-1,3-Dichloropropene_75-25-2---------Bromoform______________108-10-1--------4-Methyl-2 -Pentanone____591-78-6--------2- Hexanone _____________127-18-4--------Tetrachloroethene ~79-34-5---------1,!,2,2-Tetrachloroethane108-88-3------- -Toluene_______________~_108-90-7--------Chlorobenzene__________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

30303030222930303030303030303030303030303430303030303025301630210

UUUUBJJUUUUUUUUUUU .UUU

UUUUUUJUJU

(uL)

FORM I VOA 3/90244


EPA SAMPLE NO.



Matrix: (soil/water) SOILIjsample wt/vol:

Level: (low/med)

j% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract:

SAS No.:

IR-6RE

2.0 (g/mL) G

LOW

18

ID: 0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6572






(uL)

CAS NUMBER

1. 108-87-22 .3. 1678-91-74 .5 .6 .7 .8 .9.

10 .11.

COMPOUND NAME

Cyclohexane, methyl -Dimethylcyclohexane isomerCyclohexane, ethyl -Trimethylcyclohexane isomerDecane isomerUnknown hydrocarbonPropylbenzene isomerTrimethylbenzene isomerUndecane isomerDecalin isomerButylbenzene isomer

RT

11.1013.5315.8716.0220.7221.5621.9922.4922.7623.7424.68

EST. CONC.

25018019014013015010016013016099

QJNJJNJJJJJJJJ

FORM I VOA-TIC 3/


EPA SAMPLE NO.







,GC Column: DB-624 ID: 0.530 (mm)I

'soil Extract Volume: (uL)

Contract:

SAS No.:

IR-7

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6547






74-87-3---------Chloromethane___________74-83-9---------Bromomethane75-01-4---------Vinyl Chloride75-00-3--------- Chloroethane______75-09-2---------Methylene Chloride67-64-1---------Acetone75-15-0---------Carbon Disulfide75-35-4---------1,l-Dichloroethene______75-34-3---------1,!-Dichloroethane______67-66-3--------- Chloroform_____________107-06-2--------1,2-Dichloroethane7S-93-3---------2- But anone______________71-55-6---------1,1,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------l,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6-------- -Tr ichloroethene __________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane____71-43-2-------- -Benzene______,___________10061-02-6------t rans-1,3-Dichloropropene75-25-2-------- -Bromof orm________________'_108-10-1--------4-Me thyl-2- Pentanone____591-78-6--------2- Hexanone ______________127-l8-4--------Tetrachloroethene79-34-5---------1,1,2,2-Tetrachloroethane108-88-3--------Toluene_______________~108-90-7--------Chlorobenzene__________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

1212121221112121212121212121212121212122912121212121228122112

230

UUUUJJUUUUUUUUUUUUUU

UUUUUU

U

U

FORM I VGA 3/


EPA SAMPLE NO.






% Moisture: not dec.

GC Column: DB-624


Contract:

SAS No.:

IR-7

18

ID: 0.530 (mm)

(uL)


SDG No.: 54598


Lab File ID: F6547






(uL)

CAS NUMBER

1. 108-87-22. 1678-91-73 .4 .5.6 .7 .8 .9 .

10 .

COMPOUND NAME

Cyclohexane, methyl -Cyclohexane, ethyl -Trimethylcyclohexane isomerPropylcyclohexane isomerDecane isomerDecane isomerDecane isomerUndecane isomerUndecane isomerDecalin isomer

RT

11.0915.8516 .0118 .7019.7320.0020.7322 .7523 .2123 .74

EST . CONC .

22012011067679299

100100110

Q

JNJNJJJJJJJJ

FORM I VOA-TIC 3/90 26


EPA SAMPLE NO.




pample wt/vol: 2.1 (g/mL) G


fs Moisture: not dec. 18


Boil Extract Volume: (uL)

Contract:

SAS No.:

IR-7RE

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6573






74-87-3---------Chloromethane__________74-83-9-------- -Bromomethane________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_________75-09-2---------Methylene Chloride67-64-1---------Acetone75-15-0---------Carbon Disulfide75-35-4---------1,1-Dichloroethene______75-34-3---------1,!-Dichloroethane______67-66-3---------Chloroform ___________107-06-2--------1,2-Dichloroethane78-93-3--------- 2 -Butanone ______________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------1,2-Dichloropropane_____l0061-Ol-5------cis-l,3-Dichloropropene__79-01-6-------- -Trichloroethene___________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2---------Benzene ____________10061-02-6------t rans-1,3-Dichloropropene75-25-2-------- - Bromof orm______________~108-10-1--------4-Methyl-2 -Pentanone____591-78-6--------2- Hexanone _______________127-18-4--------Tetrachloroethene79-34-5---------l,l,2,2-Tetrachloroethane108-88-3-------- Toluene________________~_108-90-7--------Chlorobenzene__________100-41-4--------EthyIbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

2929292928

650292929292918029292929292929295

2929226729298

2929297

UUUUBJEUUUUU

UUUUUUUUJUUJUUJUUUJ

FORM I VOA 3/90

293


EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract

SAS No.

IR-7RE

LOW

18

ID: 0.530 (mm)

(UL)


SDG No.: 54598


Lab File ID: F6573 .






(uL)

CAS NUMBER

1. 75-28-52. 78-78-43 .4 .5.6 .7.8.9.

10. 1120-21-4

COMPOUND NAME

IsobutaneButane, 2 -methyl -Butanal isomerPentanone isomerPentanal isomerHexanal isomerUnknown hydrocarbonUnknown hydrocarbonOctanal isomerUndecane

RT

0.941.706.82

11.6611.7916.1018.5022 .0023.2824 . 67

EST . CONC .

48754941625739483946

QJNJNJJJJJJJJN

FORM I VOA-TIC 3/90

294


EPA SAMPLE NO.









Contract:

SAS No.:

RS-01

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6536






74-87-3---------Chloromet hane___________74-83-9-------- -Bromomethane___________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_______75-09-2---------Methylene Chloride67-64-1---------Acetone _________75-15-0---------Carbon Disulfide ~75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform__________107-06-2--------1,2-Dichloroethane78-93-3---------II - But anone _____________71-55-6---------1,1,1-Trichloroethane56-23-5---------Carbon Tetrachloride_____75-27-4---------Bromodichloromethane____78-87-5---------l,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6---------Trichloroethene_________124-48-1--------Dibromochloromethane79-00-5---------1,1,2-Trichloroethane_____71-43-2---------Benzene______________10061-02-6------trans-1,3-Dichloropropene_75-25-2---------Bromoform_____________108-10-l--------4-Methyl-2-Pentanone____591-78-6--------2- Hexanone __________127-18-4--------Tetrachloroethene ~79-34-5---------1,!,2,2-Tetrachloroethane108-88-3--------Toluene________________108-90-7-------- Chlorobenzene____________100-41-4--------Ethylbenzene___________100-42-5--------Styrene____1330-20-7-------Xylene (total)

1313131313

20006

1313131397013131313131313131913137651013131313131313

UUUUUEJUUUUEUUUUUUUU

UU

EUU

UUUU

(uL)

FORM I VOA 3/90


EPA SAMPLE NO.







GC Column: DB-624 ID:

Contract:

SAS No.:

RS-01


I Number TICs found:

0.530 (mm)

(uL)

10

SDG No.: 54598


Lab File ID: F6536






(uL)

CAS

1 .2 .3 .4 .5.6 .7 .8 .9.

10 .

NUMBER

75-07-0107-87-996-22-0

108-94-1

1120-21-4

COMPOUND NAME

Acetaldehyde2-Pentanone3-PentanoneHexanal isomerMethylcyclopentanone isomerHeptanone isomerCyclohexanoneUnknown ketoneOctanone isomerUndecane

RT

1.2311.6812.0116.1118.3819.7320.0621.9923 .1024 .68

EST . CONC .

151301955692001209087260

QJNJNJNJJJJNJJJN

FORM I VOA-TIC 3/90

31S


EPA SAMPLE NO.









Contract:

SAS No.:

RS-01RE

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6569






74-87-3----74-83-9----75-01-4----75-00-3----75-09-2----67-64-1----75-15-0----75-35-4----75-34-3----67-66-3----107-06-2---78-93-3----71-55-6----56-23-5----75-27-4----n Q Q ~i c10061-01-5-79-01-6----1 94 AR TJ- i 1. i Q -L.

79-00-5----71 43 210061-02-6-75-25-2----108-10-1---C Q ~\ rj Q C.

127-18-4---79-34-5-----i r\ Q Q o o

108-90-7---100-41-4---100-42-5---13 30-20- 7--

- - - - -Chloromethane- - - - -Bromomethane-----Vinyl Chloride- - - - -Chloroethane- - - - -Methylene Chloride

f^.\^ *** ^ ^ ^-----Carbon Disulfide- - - - -1 , 1-Dichloroethene- - - - - 1 , 1 -Dichloroethane----- Chloroform- - - - - 1 , 2 -Dichloroethane- - - - -2-Butanone-----1,1, 1-Trichloroethane-----Carbon Tetrachloride- - - - -Bromodichloromethane----- 1 , 2 -Dichloropropane-----cis-1, 3-Dichloropropene- - - - -Trichloroethene- - - - -Dibromochloromethane-----1,1, 2 -Trichloroethane

- - - - - trans-1 , 3 -Dichloropropene- - - - -Bromof orm----- 4 - Methyl - 2 - Pent anone----- 2 - Hexanone- - - - -Tetrachloroethene-----1,1,2, 2 -Tetrachloroethane--- - -Toluene----- Chlorobenzene- - - - -Ethylbenzene- - -- -Styrene-----Xylene (total)

636363634383063636363633106363636363636363636363636163636363636363

UUUUBJ

UUUUU

UUUUUUUUUUUUJUUUUUUU

(uL)

FORM I VGA 3/9.340


EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Soil Extract Volume

Contract:

SAS No.:

RS-01RE

LOW

21

ID: 0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6569





Number TICs found:CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

(uL)

CAS NUMBER

1. 107-87-92.

COMPOUND NAME

2-PentanoneUnknown oxygenated hydrocarb

RT

11.6623.30

EST . CONC .

4834

Q

JNJ

FORM I VOA-TIC 041


EPA SAMPLE NO.









Contract:

SAS No.:

RS-02

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6539






(uL)

74-87-3----74-83-9----75-01-4----75-00-3----75 09 7 -1 _ > \J -s £*

67-64-1----75-15-0----75-35-4----75-34-3----67-66-3----107-06-2---78-93-3----71-55-6----56-23-5----7R 97 4 - - -78-87-5----10061-01-5-n Q n i c.194 4R 1J_ 4-i L i O J_

79-00-5----71-43-2----10061-02-6-75 25 2108-10-1---cr n -\ -i Q (•

197 1 R A

79-34-5----i n Q Q Q ii n Q on *~7100-41-4---100-42-5---1330-20-7--

- - - - -Chloromethane- - - - -Bromome thane-----Vinyl Chloride- - - - - Chloroethane-----Methylene Chloride

t W w L» *-* A i. "*_-

-----Carbon Disulfide-----1, 1-Dichloroethene- - - - - 1 , 1 -Dichloroethane-----Chloroform- - - - - 1 , 2 -Dichloroethane- - - - -2-Butanone-----1,1, 1-Trichloroethane-----Carbon Tetrachloride- - - - -Bromodichloromethane-----1,2 -Dichloropropane- - - - -cis-1, 3 -Dichloropropene- - - - -Trichloroethene- - - - -Dibromochloromethane-----1,1, 2 -Trichloroethane

T5 ^ vi f* ^ *-» *-\

- - - - -trans-1 , 3 -Dichloropropene- - - - -Bromof orm- -- - -4 -Methyl -2 -Pentanone----- 2 -Hexanone-----Tetrachloroethene-----1,1,2, 2 -Tetrachloroethane- - - - -Toluene- - - - -Chlorobenzene- - - - -Ethylbenzene- - - - -Styrene-----Xylene (total)

1414141410

180014141414145001414141414141414

57001414

19'05901414150145714

470

UUUUJEUUUUUEUUUUUUUUEUU

EUU

U

UE

FORM I VGA

351

3/90


EPA SAMPLE NO.


)Lab Code: EANDE Case No.: 269





GC Column: DB-624

jSoil Extract Volume:

Contract:

SAS No.:

RS-03RE

ID: 0.530 (mm)

(uL)

SDG NO.: 54598

Lab Sample ID: 5460ORE

Lab File ID: F6564




Soil Aliquot Volume-.


(uL)

CAS NUMBER

1.2 .3 .4 .5.6 .7.8 .9.

10 .

COMPOUND NAME

Pentanone isomerHexanal isomerHeptanone isomerDimethylcyclopentanone isomeOctanone isomerTrimethylbenzene isomerOctanone isomerPropylbenzene isomerTrimethylcyclohexanone isomeUndecane isomer

RT

11.7016.1219.7520.7121.9922.4923 .1123 .4124 .5924 .70

EST . CONC .

1586456215049641006569

Q

JJJJJJJJJJ

;r

FORM I VOA-TIC404

3/90



DATE:

TO:

FROM:

THROUGH:

SUBJECT:

REFERENCE:

M E M O R A N D U M

November 19, 1996




Data Quality Review for Pesticides andPolychlorinated Biphenyls (PCBs), Texaco Refinery,Lawrenceville, Illinois



The data quality assurance (QA) review of ten soil/sludge samplescollected from the Texaco Refinery site is complete. The sampleswere collected on October 16 and 17, 1996, by the SuperfundTechnical Assessment and Response Team (START) contractor,Ecology and Environment, Inc. (E & E). The samples weresubmitted to Ecology and Environment, Inc., Analytical ServicesCenter, Lancaster, New York. The laboratory analyses wereperformed according to the United States Environmental ProtectionAgency (U.S. EPA) Solid Waste 846 Method 8080. (Only sampleRS-02 was analyzed for pesticides.)




LaboratoryIdentification No.

EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-

54598545995460054601546025460354604546055460654607

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806Pesticides/PCBsPage 2



The samples were collected on October 16 and 17, 1996,extracted on October 25, 1996, and analyzed on November 2,1996. Sample RS-02 was extracted for pesticides and PCBson October 28, 1996, and analyzed on November 6, 1996.This is within the 14-day holding time limit, fromcollection to extraction, and 40-day limit from extractionto analysis.

II. Instrument Performance: Acceptable

The chromatographic resolution was adequate in the standardand sample chromatograms. Surrogate retention times wereconsistent in the samples and standards.

III. Calibrations:


Initial calibrations for pesticides and PCBs demonstratedcorrelation coefficients exceeding 0.995.

• Continuing Calibration: Acceptable

The percent differences of the response factors for bothpesticides and PCBs were acceptable.


A method blank was analyzed with the sample. No targetcompounds or contaminants were detected in the blank.

V. Compound Identification: Not Applicable

There were no PCBs or target pesticides detected in anysample.

VI. Additional QC Checks: Acceptable

The recoveries of the surrogates used in the samples couldnot be determined due to sample dilution.

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806Pesticides/PCBsPage 3

VII. Overall Assessment of Data for Use: Acceptable

The overall usefulness of the data is based on criteria forQA Level II as outlined in the Office of Solid Waste andEmergency Response (OSWER) Directive 9360.4-01 (April1990), Data Validation Procedures, Section 6.0,Pesticides/PCBs. Based upon the information provided, thedata are acceptable for use.

TEST CODE :SPCB 1

Ecology and Environment, Inc.Analytical Services Center

CLIENT : START - CHICAGORESULTS IN DRY WEIGHTTEST NAME : 8080 PCBSAMPLE ID LAB : EE-96-54598SAMPLE ID CLIENT: RS-01

JOB NUMBER : 9602.269ELAP ID : 10486

%SOLIDS : 79 %UNITS : MG/KGMATRIX : SOLID

PARAMETER RESULTS QNT. LIMIT

PCB-1242PCB-1254PCB-1221PCB-1232PCB-1248PCB-1260PCB-1016

NDNDNDNDNDNDND

0000000

.125

.125

.125

.125

.125

. 125

.125

QUALIFIERS: C = COMMENT ND = NOT DETECTEDJ = ESTIMATED VALUE B = ALSO PRESENT IN BLANKN = ANALYTE WAS NOT CONFIRMED BY ALTERNATE PROCEDURE

1100

TEST CODE :SP&PCB1


CLIENT : START - CHICAGORESULTS IN DRY WEIGHTTEST NAME : PESTICIDE-PCBSAMPLE ID LAB : EE-96-54599SAMPLE ID CLIENT: RS-02




Aldrinalpha-BHCbeta-BHCgamma -BHC (Lindane)delta-BHCChlordane4,4' -ODD4,4' -DDE4,4' -DOTDieldrinEndosulfan IEndosulfan IIEndosulfan sulfateEndrinEndrin aldehydeHeptachlorHeptachlor epoxideToxapheneMethoxychlorPCB-1016PCB-1221PCB-1232PCB-1242PCB-1248PCB-1254PCB-1260

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

111111433833383811842734343434343434

.7

.7

. 7

. 7

.7

.4

.4

.4

.4

.4

.4

.4

.4

.4

.7

. 7

ND = NOT DETECTEDB = ALSO PRESENT IN BLANK

QUALIFIERS: C = COMMENTJ = ESTIMATED VALUEX = EXCEEDS CALIBRATION LIMITN = ANALYTE WAS NOT CONFIRMED BY ALTERNATE PROCEDUREA = PHENOMENON OF METHODOLOGY WITH ACID PRESERVATION

TEST CODE :SPCB 1


CLIENT : START - CHICAGORESULTS IN DRY WEIGHTTEST NAME : 8080 PCBSAMPLE ID LAB : EE-96-54600SAMPLE ID CLIENT: RS-03

JOB NUMBER :9602.269ELAP ID : 10486




NDNDNDNDNDNDND

0,0 ,0,0,0.0,0,

.22

.22

.22

.22

.22

.22

.22


1105

TEST CODE :SPCB 1


CLIENT : START - CHICAGORESULTS IN DRY WEIGHTTEST NAME : 8080 PCBSAMPLE ID LAB : EE-96-54601SAMPLE ID CLIENT: IR-1





NDNDNDNDNDNDND

0.290.290.290.290.290.290.29


1110

TEST CODE :SPCB 1




PARAMETER


%SOLIDSUNITSMATRIX

RESULTS Q

NDNDNDNDNDNDND

: 81 %: MG/KG: SOLID

QNT. LIMIT

0.250.250.250.250.250.250.25


1117

TEST CODE :SPCB 1







NDNDNDNDNDNDND

0,0,0,0,0,0,0.

.24

.24

.24

.24

.24

.24

.24


TEST CODE :SPCB 1







NDNDNDNDNDNDND

0000000

.35

.35

.35

.35

.35

.35

.35


1129

TEST CODE :SPCB 1







NDNDNDNDNDNDND

0.220.220.220.220.220.220.22


TEST CODE :SPCB 1






PCB-PCB-PCB-PCB-PCB-PCB-PCB-

1242125412211232124812601016

NDNDNDNDNDNDND

0000000

.24

.24

.24

.24

.24

.24

.24


TEST CODE :SPCB 1




fcSOLIDS : 82 %UNITS : MG/KGMATRIX : SOLID



NDNDNDNDNDNDND

0000000

.24

.24

.24

.24

.24

.24

.24


1146



M E M O R A N D U M

DATE:

TO:

FROM:

THROUGH:

SUBJECT:

REFERENCE:

December 19, 1996




Data Quality Review for Polynuclear AromaticHydrocarbons (PAH), Texaco Refinery, Lawrenceville,Illinois



The data quality assurance (QA) review of one soil/sludge samplecollected from the Texaco Refinery site is complete. The samplewas collected on October 16, 1996, by the Superfund TechnicalAssessment and Response Team (START) contractor, Ecology andEnvironment, Inc. (E & E). The sample was submitted to Ecologyand Environment, Inc., Analytical Services Center, Lancaster, NewYork. The laboratory analysis was performed according to theUnited States Environmental Protection Agency (U.S. EPA) SolidWaste 846 Method 8310.



EE-96-54598


RS-01


I. Sample Holding Time: Qualified

The sample was collected on October 16, 1996, extracted onNovember 12, 1996, and analyzed on November 19, 1996. Thisexceeds the 14-day holding time limit, from collection toextraction. All results have been qualified as estimated.

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806PAHPage 2

II. Instrument Performance: Acceptable

The chromatographic resolution was adequate in the standardand sample chromatograms.

III. Calibrations:


The relative standard deviations for all target compoundsin the initial calibration were less than 20%.


The percent differences of the response factors for allreported PAHs were less than 15%.


A method blank was analyzed with the sample. No targetcompounds or contaminants were detected in the blank.

V. Compound Identification: Qualified

Confirmation analysis was not performed by the laboratory.Because of the possibility of chromatographic peak shiftsand the absence of secondary analysis, in the professionaljudgement of the reviewer, all identifications should bequalified as tentatively identified at estimatedconcentration.

VI. Additional QC Checks: Acceptable


VII. Overall Assessment of Data for Use: Qualified

The overall usefulness of the data is based on criteria forQA Level II as outlined in the Office of Solid Waste andEmergency Response (OSWER) Directive 9360.4-01 (April1990), Data Validation Procedures, Section 9.0, GenericData Validation Procedures. Based upon the informationprovided, the data are acceptable for use with the abovestated qualifications.

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806PAHPage 3

Data Qualifiers and Definitions:

NJ - Presumptive evidence of the presence of the materialat an estimated quantity.

TEST CODE :SPAHOA1


CLIENT : START - CHICAGORESULTS IN DRY WEIGHTTEST NAME : 8310 PAH/LCSAMPLE ID LAB : EE-96-54598SAMPLE ID CLIENT: RS-01


%SOLIDS : 79 %UNITS : UG/KGMATRIX : SOLID


NaphthaleneAcenaphthylene1 -methylnaphthalene2 -MethylnaphthaleneAcenaphtheneFluorenePhenanthreneAnthraceneFluoranthenePyreneBenzo (a) anthraceneChryseneBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo (a) pyreneDibenzo (a, h) anthraceneBenzo (ghi) peryleneIndeno { 1 , 2 , 3 - cd ) pyrene

NDNDNDNDND14000640001400001200000640000ND2400001200005800006300002000000100000ND

760000760000760000760000760000

J 76000J 76000

760001900001900007600076000760007600076000

X 190000J 190000

76000

ND = NOT DETECTEDB = ALSO PRESENT IN BLANK

QUALIFIERS: C = COMMENTJ = ESTIMATED VALUEX = EXCEEDS CALIBRATION LIMITN = ANALYTE WAS NOT CONFIRMED BY ALTERNATE PROCEDUREA = PHENOMENON OF METHODOLOGY WITH ACID PRESERVATION

13



DATE:

TO:

FROM:

THROUGH:

SUBJECT:

REFERENCE:

M E M O R A N D U M

November 19, 1996




Inorganic Data Quality Review for ResourceConservation and Recovery Act (RCRA) Metals,Refinery, Lawrenceville, Illinois

Texaco



The data quality assurance (QA) review of ten soil/sludge samplescollected from the Texaco Refinery site is complete. The sampleswere collected on October 16 and 17, 1996, by the SuperfundTechnical Assessment and Response Team (START) contractor,Ecology and Environment, Inc. (E & E). The samples weresubmitted to Ecology and Environment, Inc., Analytical ServicesCenter. The laboratory analyses were performed according to theUnited States Environmental Protection Agency (U.S. EPA) SolidWaste 846 Methods 6010 and 7000.





EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-EE-96-

54598545995460054601546025460354604546055460654607

recycled paper

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806RCRA MetalsPage 2



The samples were collected on October 16 and 17, 1996, andanalyzed on November 4, 1996. Analysis for mercury wasperformed on August 25, 1996. This is within the 6-month(28 days for mercury) holding time limit.

II. Calibration:


Recoveries for the initial calibration verification werewithin 90 to 110% (80 to 120% for mercury), as required.The correlation coefficient for mercury exceeded 0.995.


All analytes included in the continuing calibrationverification standard were within 90 to 110% (80 to 120%for mercury), as required.

III. Blanks: Acceptable

Calibration and preparation blanks were analyzed with eachanalytical batch. No target analytes were detected in theblanks.

IV. Overall Assessment of Data For Use: Acceptable

The overall usefulness of the data is based on criteria forQA Level II as outlined in the Office of Solid Waste andEmergency Response (OSWER) Directive 9360.4-01 (April 1990)Data Validation Procedures, Section 3.0, Metallic InorganicParameters. Based upon the information provided, the dataare acceptable for use.

START - CHICAGO

1INORGANIC ANALYSES DATA SHEET

Contract:

EPA SAMPLE NO.

Lab Name: ECOLOGY_AND_ENVIRONMENT_ _

Lab Code: EANDE Case No.:9602.269 SAS No.:

IR-1

SDG No.: IR-1

Matrix (soil/water): SOIL

Level (low/med): LOW

Solids:



_68.5

Concentration Units (ug/L or mg/kg dry weight): MG/KG

Color Before:

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAnt imonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

2.926.8

0.03

2.9

64.1

0.02

0.670.16

C

B

U

U

UU

Q

**

*

N

N

M

NRNRPPNRPNRPNRNRNRPNRNRCVNRNRPPNRNRNRNRNR

Clarity Before: __

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1413

START - CHICAGO


Contract:

EPA SAMPLE NO,

ab Name: ECOLOGY_AND_ENVIRONMENT_ _

ab Code: EANDE_ Case No.:9602.269 SAS No.:


IR-2

SDG No.: IR-1


Date Received: 10/22/96evel (low/med): LOW_

Solids: _81.0


Color Before:

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

1.112.3

0.30

1.8

48.4

0.02

0.570.14

C

BB

B

U

UU

Q

**

*

N

N

M


Clarity Before: __

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

141.4

START - CHICAGO

INORGANIC ANALYSES DATA SHEETEPA SAMPLE NO.

Lab Name: ECOLOGY AND ENVIRONMENT Contract:IR-3

,ab Code: EANDE Case No.:9602.269 SAS No.: SDG No.: IR-1



Matrix (soil/water): SOIL_

Level (low/med): LOW_

\ Solids: _83.0


Color Before:

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

10.4113

0.02

6.7

28.6

0.02

1.00.13

C

U

U

U

Q

**

*

N

N

M


Clarity Before: __

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1415

START - CHICAGO

INORGANIC ANALYSES DATA SHEETEPA SAMPLE NO,


Lab Code: EANDE Case No.=9602.269 SAS No.: SDG No.: IR-1





\ Solids: _56.7


Color Before:

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

4.838.2

0.03

5.6

244

0.31

0.780.19

C

U

UU

Q

**

*

N

N

M


Clarity Before: __

Clarity After: C_

Texture: G

Artifacts:

FORM I - IN ILM03.0

1416

START - CHICAGO

INORGANIC ANALYSES DATA SHEETEPA SAMPLE NO.


,ab Code: EANDE Case No.:9602.269 SAS No.: SDG No.: IR-1


i^evel (low/med) : LOW_

Solids: 89.2




Color Before:

Color After:

Comments:

GAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

2.359.6

0.02

2.2

47.7

0.02

0.680.12

C

U

u

U

Q

**

*

N

N

M


Clarity Before: _

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1417

START - CHICAGO


Contract:

EPA SAMPLE NO,

Lab Name: ECOLOGY_AND_ENVIRONMENT_


IR-6

SDG No.: IR-1





V Solids: _81.8


Color Before

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

0.560.06

0.72

0.07

7.8

0.05

0.560.13

C

UU

U

UU

Q

**

*

N

N

M


Clarity Before: _

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1418

START - CHICAGO


Contract:

EPA SAMPLE NO,



IR-7

SDG No.: IR-1


Level (low/med): LOW

Solids :



_81.9


Color Before

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

8.8127

0.02

1.1

17.0

0.02

0.560.13

C

U

B

U

UU

Q

**

*

N

N

M


Clarity Before: __

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1419

START - CHICAGO


Contract:

EPA SAMPLE NO.

Lab Name: ECOLOGY_AND_ENVIRONMENT_ _


RS-01

SDG No.: IR-1





fc Solids: _79.1


£olor Before

'olor After:IComments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

0.584.4

1.0

1.5

202

0.02

0.580.14

C

UB

U

UU

Q

**

*

N

N

M


Clarity Before: __

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1420

START - CHICAGO

EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

Lab Name: ECOLOGY_AND_ENVIRONMENT

Lab Code: EANDE

Contract:RS-02

Case No.:9602.269 SAS No.: SDG No.: IR-1


LJ<


Date Received: 10/22/96,evel (low/med) : LOW_

Solids: _73.8


Color Before

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

8.135.5

0.03

3.3

171

0.02

0.620.15

C

U

U

UU

Q

**

*

N

N

M


Clarity Before: _

Clarity After: C

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1421

START - CHICAGO


Contract:

EPA SAMPLE NO.



RS-03

SDG No.: IR-1





Solids: _92.9


Color Before:

Color After:

Comments:

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte


Concentration

4.844.0

0.08

4.9

148

0.03

0.500.12

C

B

B

UU

Q

**

*

N

N

M


Clarity Before: __

Clarity After: C_

Texture: G_

Artifacts:

FORM I - IN ILM03.0

1422



DATE:

TO:

FROM:

THROUGH:

SUBJECT:

REFERENCE:

M E M O R A N D U M

November 19, 1996




Organic Data Quality Review for SemivolatileOrganic Compounds, Texaco Refinery, Lawrenceville,Lawrence County, Illinois



The data quality assurance (QA) review of ten soil/sludge samplescollected from the Texaco Refinery site is complete. The sampleswere collected on October 16 and 17, 1996, by the SuperfundTechnical Assessment and Response Team (START) contractor,Ecology and Environment, Inc. (E & E). The samples weresubmitted to Ecology and Environment, Inc., Analytical ServicesCenter, Lancaster, New York. The laboratory analyses wereperformed according to the United States Environmental ProtectionAgency (U.S. EPA) Solid Waste 846 Method 8270.





E E - 9 6 -E E - 9 6 -E E - 9 6 -E E - 9 6 -EE-96-EE-96E E - 9 6 -EE-96E E - 9 6 -EE-96

54598545995460054601546025460354604546055460654607

rpryrled

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806SVGAPage 2



The samples were collected on October 16 and 17, 1996,extracted on October 28, 1996, and analyzed on October 29and 31, 1996. This is within the 14-day holding timelimit, from collection to extraction, and 40-day limit,from extraction to analysis.

II. Gas Chromatoqraphy/Mass Spectrometry (GC/MS) Tuning:Acceptable

GC/MS tuning to meet ion abundance criteria usingdecafluorotriphenylphosphine (DFTPP) were acceptable andsamples were analyzed within 12 hours of DFTPP tuning.

III. Calibrations:


A five-point initial calibration was performed prior toanalysis. All average response factors were greater than0.05. The percent relative standard deviations (%RSDs)between response factors were less than 30% for alldetected target compounds.


The percent differences of the response factors were lessthan 25%, as required for detected target compounds.


A method blank was analyzed with the samples. No targetcompounds or contaminants were detected in the blank.

V. Internal Standards: Qualified

The areas of two internal standards in the samples wereoutside the range of -50% to +100% of the associatedcalibration check standard. All associated targetcompounds have been flagged "J", as estimated. Theretention times of the internal standards were within the30-second control limit.

Texaco RefineryProject TDD S05-9610-017Analytical TDD S05-9610-806SVOAPage 3

VI. Compound Identification: Acceptable

The mass spectrum and retention time of the detectedcompound matched those of the standards.

VII. Additional QC Checks: Not Applicable


VIII. Overall Assessment of Data for Use: Acceptable

The overall usefulness of the data is based on criteria forQA Level II as outlined in the Office of Solid Waste andEmergency Response (OSWER) Directive 9360.4-01 (April1990), Data Validation Procedures, section 4.0, BNAs ByGC/MS analysis. Based upon the information provided, thedata are acceptable for use, with the above-statedqualifications.

Data Qualifiers and Definitions:

J - The associated numerical value is an estimated quantitybecause the reported concentrations were less than requireddetection limits or quality control criteria were not met.

IBSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

Lab Name: E & E INC. Contract:

Lab Code: EANDE Case No.: 269 SAS No.:




% Moisture: 32 decanted: (Y/N) N

Concentrated Extract Volume: 1000 (uL)

Injection Volume: 2.0(uL)

GPC Cleanup: (Y/N) N pH: 1.6

CAS NO. COMPOUND

IR-1

SDG No.: 54598


Lab File ID: G5166


Date Extracted: 10/28/96




108-95-2--------Phenol _________________lll-44-4--------bis(2-Chloroethyl)Ether95-57-S---------2-Chlorophenol___________541-73-l--------l,3-Dichlorobenzene_______106-46-7--------1,4-Dichlorobenzene_______95-50-l---------l,2-Dichlorobenzene_______95-4S-7---------2 -Me thy lphenol_^^________________108-60-1--------2,2'-oxybis(1-Chloropropane]106-44-5--------4- Methylphenol_____ _621-64-7--------N-Nitroso-Di-n-Propylamine_67-72-1---------Hexachloroethane__________98-95-3---------Nitrobenzene_____________78-59-1---------I sophorone _______________________88-75-S---------2-Nitrophenol105-67-9--------2,4-Dimethylphenol111-91-1--------bis(2-Chloroethoxy)Methane_120-83-2--------2,4-Dichlorophenol_________120-82-l--------l,2,4-Trichlorobenzene____91-20-3---------Naphthalene______________106-47-8--------4-Chloroaniline37-68-3---------Hexachlorobutadlene_______59-50-7---------4-Chloro-3-Methylphenol91-57-6---------2-Methylnaphthalene______77-47-4---------Hexachlorocyclopentadiene ~88-06-2---------2,4,6-Trichlorophenol_____95-95-4 ---------2,4,5-Trichlorophenol_____91-58-7---------2-Chloronaphthalene_______88-74-4---------2-Nitroaniline___________131-11-3--------Dimethylphthalate_________208-96-8--------Acenaphthylene___________606-20-2--------2,6-Dinitrotoluene________99-09-2---------3-Nitroaniline____________83-32-9---------Acenaphthene ____________51-28-5---------2,4-Dinitrophenol100-02-7--------4-Nitrophenol____________

290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000290000710000290000710000290000290000290000710000290000710000710000

UUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUUU

FORM I SV-1 3/90408

1CSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.



Matrix: (soil/water) SOIL!|Sample wt/vol: 2.0 (g/mL) G


1% Moisture: 32 decanted: (Y/N) N




_ CAS NO. COMPOUND

IR-1

SDG No.: 54598


Lab File ID: G5166






132-64-9--------Dibenzofuran121-14-2--------2,4-Dinitrotoluene ~84-66-2---------Diethylphthalate7005-72-3-------4-Chloropheny1-phenylether86-73-7-------- -Fluorene ____________'_100-01-6--------4-Nitroaniline534-52-1--------4,6-Dinitro-2-methylphenol_86-30-6---------N-Nitrosodiphenylamine (1)"101-55-3--------4-Bromophenyl-phenylether_118-74-1--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8---------Carbazole ________84-74-2---------Di-n-Butylphthalate206-44-0--------Fluoranthene_____________1 2 9 - 0 0 - 0 - - - - - - - - P y r e n e _ _ _ _ _ _ _ _ _ _85-68-7---------Butylbenzylphthalate ~91-94-l---------3,3'-Dichlorobenzidine___56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene________________117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate_____~205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo (a) Pyrene____________193-39-5--------Indeno(1,2,3 -cd)Pyrene53-70-3---------Dibenz{a,h)Anthracene____191-24-2--------Benzo(g,h,i)Perylene_____

290000290000290000290000290000710000710000290000290000290000710000450002900002900002900002900002900002900002900002900001600002900002900002900QO290000290000290000290000290000

1) - Cannot be separated from Diphenylamine

UUUUUUUUUUUJUUUUUUUUJUUUUUUUU

FORM I SV-2 3/90

499

IFSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.










wumber TICs found: 20

IR-1

SDG No.: 54598


Lab File ID: G5166






CAS NUMBER

1.2 .3 .4 .5 .6 .7 .8 .9 .

10 .11.12 .13 .

„ 14 .15 .16 .17 .18 .19.20 .

COMPOUND NAME

UNKNOWN SILOXANESTRAIGHT -CHAIN ALKANEUNKNOWN HYDROCARBONSTRAIGHT -CHAIN ALKANEUNKNOWN PAHSTRAIGHT- CHAIN ALKANEUNKNOWN PAHSTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT- CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT- CHAIN ALKANESTRAIGHT -CHAIN ALKANEUNKNOWN HYDROCARBONSTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANE

RT

8.5822.9224.1524 .2525.0125.5426.4526.7727.9329.0630 .1331.1632 . 1533 .1034 .0234.5834 .9135.7836 .7437.81

EST. CONC.

23000079000670001200009800019000020000023000076000073000077000092000076000075000096000036000055000015000001400000170000

Q

JJJJJJJJJJJJJJJJJJJJ

FORM I SV-TIC 3/90500


EPA SAMPLE NO.




[Sample wt/vol: 2.0 (g/mL) G



•Concentrated Extract Volume: 1000 (uL)

'injection Volume: 2.0(uL)


CAS NO. COMPOUND

IR-2

SDG No.: 54598


Lab File ID: G5167






108-95-2--111-44-4--95-57-8---541-73-1--106-46-7--95-50-1---95-48-7---108-60-1--106-44-5--621-64-7--67-72-1---Q Q Q C T

78-59-1---on •-! r- cr

105-67-9--111-91-1--ion Q i o120-82-1--9i ?o - 1106-47-8--Q H d Q "3

59-50-7---Q T [- "-i c

77-47-4---Q Q (\ £• O

95-95-4---Q -1 [T Q "~J

88-74-4---131-11-3--208-96-8--6n a on o99 09 ?_y -/ w «/ ij83-32-9---51-28-5---i n o no T

_ _ _ _ _ -phenol------bis (2-Chloroethyl)Ether------2- Chlorophenol- - - - - - 1 , 3 -Dichlorobenzene------1,4 -Dichlorobenzene------ 1 , 2 -Dichlorobenzene- - - - - -2 -Methylphenol------2,2' -oxybis (1-Chloropropane)- - - - - -4 -Methylphenol- - - - - -N-Nitroso-Di-n-Propylamine- - - - - -Hexachloroethane----- -Nitrobenzene- - - - - - Isophorone----- -2-Nitrophenol------2, 4-Dimethylphenol----- -bis (2 -Chloroethoxy) Methane------2,4 -Dichlorophenol------1,2, 4 -Trichlorobenzene----- -Naphthalene----- -4 -Chloroaniline----- -Hexachlorobutadiene- - - - - -4 -Chloro-3 -Methylphenol------ 2 -Methylnaphthalene----- -Hexachlorocyclopentadiene------2,4, 6-Trichlorophenol------2,4, 5 -Trichlorophenol----- -2-Chloronaphthalene- - - - - -2 -Nitroaniline----- -Dimethylphthalate----- -Acenaphthylene------2, 6-Dinitrotoluene----- -3 -Nitroaniline----- -Acenaphthene------2, 4-Dinitrophenol----- -4-Nitrophenol

240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000590000240000590000240000240000240000590000240000590000590000


FORM I SV-1 3/90

527


EPA SAMPLE NO

Lab Name: E & E INC. • Contract:

JLab Code: EANDE Case No.: 269 SAS No.:








CAS NO. COMPOUND

IR-2

SDG No.: 54598


Lab File ID: G5167






132-64-9--------Dibenzofuran121-14-2--------2,4-Dinitrotoluene ~84-66-2---------Diethylphthalate7005-72-3-------4-Chlorophenyl-phenylether86-73-7---------Fluorene ____________~100-01-6--------4-Nitroaniline534-52-1--------4,6-Dinitro-2-methylphenol_86-30-6---------N-Nitrosodiphenylamine (1)101-55-3--------4-Bromophenyl-phenylether^118-74-1--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene_____________120-12-7--------Anthracene______________86-74-8---------Carbazole_________84-74-2---------Pi-n-Butylphthalate206-44-0--------Fluoranthene_____________129-00-0--------Pyrene ______________85-68-7---------Butylbenzylphthalate91-94-l---------3,3'-Dichlorobenzidine____56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene________________117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0------- -Di-n-Octyl Phthalate_____~_205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo(a)Pyrene___________193-39-5--------Indeno(l,2,3-cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene____191-24-2--------Benzo(g,h,i)Perylene_____

24000024000024000024000024000059000059000024000024000024000059000039000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000

.1) - Cannot be separated from Diphenylamine

FORM I SV-2 3/90

523



EPA SAMPLE NO,










IR-2

SDG No.: 54598


Lab File ID: G5167





.mber TICs found: 20CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

CAS NUMBER

1.2 .3 .4 .5.6 .7.8 .9.

10 .11.12 .13 .14 .15 .16 .17.18 .19 .20.

COMPOUND NAME

UNKNOWN PAHSTRAIGHT-CHAINUNKNOWNUNKNOWN PAHSTRAIGHT- CHAINUNKNOWNUNKNOWNSTRAIGHT -CHAINUNKNOWNSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT- CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINUNKNOWNSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAIN

ALKANE

ALKANE

ALKANE

ALKANEALKANEALKANEALKANEALKANEALKANE

ALKANEALKANEALKANEALKANE

RT

25.0125.5426.0626 .4526 .7627.1327. 5227. 9228.5729.0630.1231.1632.1433 .0934 .0134 .5834 . 9035 .7736.7440.52

EST. CONC.

9200011000018000095000140000790003300006700003300006300007200007100006600005100007200002500003400001300000220000370000

Q


FORM I SV-TIC


EPA SAMPLE NO.










CAS NO. COMPOUND

IR-3

SDG No.: 54598


Lab File ID: G5201






108-95-2--------Phenol________________lll-44-4--------bis(2-Chloroethyl)Ether95-57-S---------2-Chlorophenol____________54l-73-l--------l,3-Dichlorobenzene________106-46-7--------i,4-Dichlorobenzene________95-50-1---------1,2-Dichlorobenzene________9S-48-7---------2 -Methylphenol__________108-60-1--------2,2'-oxybis(1-Chloropropane)106-44-5--------4 -Methylphenol_____ _62l-64-7--------N-Nitroso-Di-n-Propylamine67-72-1---------Hexachloroethane__________98-95-3---------Nitrobenzene______________78-59-1---------I sophorone ________________88-75-5---------2-Nitrophenol105-67-9--------2,4-Dimethylphenol111-91-1--------bis(2-Chloroethoxy)Methane120-83-2--------2,4-Dichlorophenol_________!20-82-l--------i,2,4-Trichlorobenzene_____91-20-3-------- -Naphthalene_______________106-47-8--------4-Chloroaniline^87-68-3---------Hexachlorobutadiene________59-50-7---------4-Chloro-3-Methylphenol91-57-6---------2 -Methylnaphthalene______77-47-4---------Hexachlorocyclopentadiene88-06-2---------2,4, 6-Trichlorophenol________95-95-4---------2,4,5-Trichlorophenol______91-58-7---------2-Chloronaphthalene________88-74-4---------2-Nitroaniline____________131-11-3--------Dimethylphthalate_________208-96-8--------Acenaphthylene____________606-20-2--------2,6-Dinitrotoluene_________99-09-2---------3-Nitroaniline____________83-32-9---------Acenaphthene_____________51-28-5---------2>4-Dinitrophenol ~100-02-7--------4-Nitrophenol_____________

600006000060000600006000060000600006000060000600006000060000600006000060000600006000060000600006000060000600006000060000600001400006000014000060000600006000014000060000140000140000


556FORM I SV-1 3/90


EPA SAMPLE NO










CAS NO. COMPOUND

IR-3

SDG No.: 54598


Lab File ID: G5201






132-64-9--------Dibenzofuran___________121-14-2--------2,4-Dinitrotoluene ~84-66-2---------Diethylphthalate7005-72-3-------4-Chlorophenyl-phenylether86-73-7---------Fluorene ____________"100-01-6--------4-Nitroaniline534-52-1--------4,6-Dinitrp-2-methylphenol_86-30-6---------N-Nitrosodiphenylamine (1)_101-55-3--------4-Bromophenyl-phenylether_118-74-i--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8---------Carbazole _________84-74-2---------Di-n-Butylphthalate206-44-0--------Fluoranthene____________129-00-0-------- Pyrene___________________85-68-7---------Butylbenzylphthalate91-94-l---------3,3'-Dichlorobenzidine____56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene________________H7-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate_____~_205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo(a) Pyrene__________193-39-5--------Indeno(1,2,3 -cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene____191-24-2--------Benzo(g,h,i)Perylene_____

(1~5 = Cannot be separated from" Diphenylamine

6000060000600006000060000140000140000600006000060000140000600006000060000600006000060000600006000060000600006000060000600006000060000600006000060000

UUUUUUUUUUUUUUUUUUUUUUUUUUUUU

FORM I SV-2



EPA SAMPLE NO,

Lab Name: E & E INC. Contract

ab Code: EANDE Case No.: 269 SAS No.









IR-3

SDG No.: 54598


Lab File ID: G5201






CAS NUMBER

1 .2 .3 .4 .5 .6 .7 .8 .9.

10 .11.12 .13 .

' 14 .15 .16 .17.18.

COMPOUND NAME

UNKNOWNUNKNOWNUNKNOWNUNKNOWNSTRAIGHT- CHAINUNKNOWNSTRAIGHT-CHAINSTRAIGHT-CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINUNKNOWNSTRAIGHT -CHAINSTRAIGHT- CHAINSTRAIGHT -CHAINSTRAIGHT -CHAIN

ALKANE

ALKANEALKANEALKANEALKANEALKANEALKANEALKANE

ALKANEALKANEALKANEALKANE

RT

5.0126.3627.5928.4229.1029 .6729. 9731.0031.9932.5432.9433.2933 .8634 .4034 .7535.6336 .5737.62

EST. CONC.

29000210008600054000110000820001100003100002100002800001900001100002800002500002300009000017000081000

Q

JJJJJJJJJJJJJJJJJJ

FORM I SV-TIC558

3/90


EPA SAMPLE NO.









Contract:

SAS No.:

RS-03

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6540






74-87-3---------Chloromethane__________74-83-9-------- -Bromomethane___________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_______75-09-2---------Methylene Chloride67-64-1---------Acetone _________75-15-0---------Carbon Disulfide75-35-4---------1,1-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform_________107-06-2--------l,2-Dichloroethane7S-93-3---------2- Bu t anone ___________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------1,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6---------Trichloroethene________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2---------Benzene _______________10061-02-6------t rans-1,3-Dichloropropene_75-25-2-------- - Bromo f orm______________~_108-10-1--------4-Methyl- 2 -Pentanone____591-78-6--------2-Hexanone__________127-18-4--------Tetrachloroethene79-34-5---------l,l,2,2-Tetrachloroethane108-88-3--------Toluene________________'_108-90-7--------Chlorobenzene__________100-41-4--------Ethylbenzene___________lOO-42-5--------Styrene_______________1330-20-7-------Xylene (total)

11111111116401111111111120111111111111111159111140991111411111114

UUUUUEUUUUU

UUUUUUUU

UU

UUJUUU

(uL)

FORM I VGA 3/90

378


EPA SAMPLE NO.





Level: (low/med)

% Moisture: not dec

GC Column: DB-624

Contract:

SAS No.:

RS-02

'Soil Extract Volume

"umber TICs found:

LOW

26

ID: 0.530 (mm)

(uL)

SDG No.: 54598


Lab File ID: F6539





12CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

(uL)

CAS NUMBER

1 .2. 107-87-93 .4 .5 .6 .7 .8 .9.

10 .11.12. 1120-21-4

COMPOUND NAME

Pentanone isomer2-PentanoneOctane isomerNonane isomerHeptanone isomerUnknown hydrocarbonUndecane isomerDecane isomerTrimethylbenzene isomerOctanone isomerPropylbenzene isomerUndecane

RT

10 .3511.6514 .5918.4919.7019.9920.7121.9822.4723 .0823 .3724 .67

EST . CONC .

68554576465031120805665110

Q

JJNJJJJJJJJJJN

FORM I VOA-TIC 3/TO2


EPA SAMPLE NO.







GC Column: DB-624


Contract:

SAS No.:

RS-03

ID: 0.530 (mm)

(uL)

Tumber TICs found: 11

SDG No.: 54598


Lab File ID: F6540






(uL)

CAS NUMBER

1. 107-87-92 .3 .4 .5 .6 .7.8.9.

10 .11. 1120-21-4

COMPOUND NAME

2-PentanoneHexanal isomerHeptanone isomerUnknown hydrocarbonDimethylcyclopentanone isomeOctanone isomerTrimethylbenzene isomerUnknown ketonePropylbenzene isomerTrimethylcyclohexanone isomeUndecane

RT

11.6816.1019.7219. 9820.6821.9822 .4723.0923 .3824 .5724.67

EST . CONC .

32325650311203943563748

Q

JNJJJJJJJJJJN

FORM I VOA-TIC


EPA SAMPLE NO.


JLab Code: EANDE Case No.: 269iMatrix: (soil/water) SOIL






Contract

SAS No.

RS-03RE

CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: F6564






74-87-3---------Chloromethane__________74-83-9---------Bromomethane___________75-01-4---------Vinyl Chloride75-00-3---------Chloroethane_______75-09-2---------Methylene Chloride67-64-1---------Acetone _________75-15-0---------Carbon Disulfide75-35-4---------1,!-Dichloroethene______75-34-3---------1,1-Dichloroethane______67-66-3---------Chloroform__________107-06-2--------1,2-Dichloroethane78-93-3---------2-Butanone___________71-55-6---------1,!,1-Trichloroethane56-23-5---------Carbon Tetrachloride____75-27-4---------Bromodichloromethane____78-87-5---------l,2-Dichloropropane_____10061-01-5------cis-l,3-Dichloropropene__79-01-6---------Trichloroethene________124-48-1--------Dibromochloromethane79-00-5---------1,!,2-Trichloroethane___71-43-2---------Benzene_________10061-02-6------trans-1,3-Dichloropropene75-25-2---------Bromoform______________~_108-10-l--------4-Methyl-2-Pentanone____591-78-6--------2-Hexanone__________127-18-4--------Tetrachloroethene79-34-5---------1,1,2,2-Tetrachloroethane108-88-3-------- Toluene_______________'_108-90-7--------Chlorobenzene__________100-41-4--------Ethylbenzene___________100-42-5--------Styrene________________1330-20-7-------Xylene (total)

1111111114

410111111111147111111111111111121111356011111111111117

UUUUBEUUUUU

UUUUUUUJUU

UUUUUU

(uL)

FORM I VGA 3/90

403


EPA SAMPLE NO.

Lab Name: E Sc E INC. Contract:

'Lab Code: EANDE Case No.: 269 SAS No.:








-— CAS NO. COMPOUND

RS-01

' SDG No.: 54598


Lab File ID: G5170





CONCENTRATION UNITS:(ug/L or ug/Kg) .UG/KG

108-95-2- -------Phenol_^____________________lll-44-4--------bis(2-Chloroethyl) Ether95-57-8---------2-Chlorophenol____________541-73-1--------1,3-Dichlorobenzene________106-46-7--------1,4-Dichlorobenzene________95-50-l---------l,2-Dichlorobenzene________95-4S-7---------2-Methylphenol_^_________108-60-l--------2,2'-oxybis(1-Chloropropane)106-44-5--------4 -Methylphenol_____ _621-64-7--------N-Nitroso-Di-n-Propylamine67-72-1---------Hexachloroethane__________98-95-3---------Nitrobenzene______________78-59-1---------Isophorone ________________88-75-5---------2-Nitrophenol105-67-9--------2,4-Dimethylphenol111-91-1--------bis(2-Chloroethoxy)Methane120-83-2--------2,4-Dichlorophenol_________120-82-l--------l,2,4-Trichlorobenzene_____91-20-3-------- -Naphthalene__________________106-47-8--------4-Chloroaniline_87-68-3---------Hexachlorobutadiene______59-50-7---------4-Chloro- 3-Methylphenol91-57-6---------2 -Methylnaphthalene_______77-47-4---------Hexachlorocyclopentadiene88-06-2---------2,4,6-Trichlorophenol______95-95-4---------2,4,5-Trichlorophenol______91-58-7---------2-Chloronaphthalene________88-74-4---------2-Nitroaniline____________131-11-3--------Dimethylphthalate_________208-96-8--------Acenaphthylene____________606-20-2--------2,6-Dinitrotoluene________99-09-2---------3-Nitroaniline____________83-32-9---------Acenaphthene____________51-28-5---------2,4-Dinitrophenol100-02-7--------4-Nitrophenol_____________

250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000250000610000250000610000250000250000250000610000250000610000610000

FORM I SV-1

UuUuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuuu

3/90

681



EPA SAMPLE NO.


Contract

SAS No.








CAS NO. COMPOUND

IR-4

SDG No.: 54598


Lab File ID: G5202






108-95-2--------Phenol ___________________111-44-4--------bis(2 -Chloroethyl)Ether9S-57-8---------2-Chlorophenol____________541-73-l--------l,3-Dichlorobenzene________106-46-7--------1,4-Dichlorobenzene________95-50-1---------1,2-Dichlorobenzene_______9S-48-7---------2 -Methylphenol___________108-60-1--------2,2'-oxybis(1-Chloropropane)106-44-5--------4 -Methylphenol_____ _621-64-7--------N-Nitroso-Di-n-Propylamine67-72-1---------Hexachloroethane__________98-95-3---------Nitrobenzene______________78-59-1---------I sophorone _______________88-75-5---------2-Nitrophenol105-67-9--------2,4-Dimethylphenol111-91-1--------bis(2-Chloroethoxy)Methane120-83-2--------2,4-Dichlorophenol_________120-82-l--------l,2,4-Trichlorobenzene_____91-20-3-------- -Naphthalene_________________106-47-8--------4-Chloroaniline87-68-3---------Kexachlorobutadiene________59-50-7---------4-Chloro-3-Methylphenol91-57-6---------2 -Methylnaphthalene______77-47-4---------Hexachlorocyclopentadiene88-06-2---------2,4,6-Trichlorophenol______95-95-4---------2,4,5-Trichlorophenol______91-58-7---------2-Chloronaphthalene_______88-74-4---------2-Nitroaniline___________131-11-3--------Dimethylphthalate_________208-96-8--------Acenaphthylene____________606-20-2--------2,6-Dinitrotoluene_________99-09-2---------3-Nitroaniline____________83-32-9---------Acenaphthene____________51-28-5---------2,4-Dinitrophenol100-02-7--------4-Nitrophenol_____________

870008700087000870008700087000870008700087000870008700087000870008700087000870008700087000870008700087000870008700087000870002100008700021000087000870008700021000087000210000210000


FORM I SV-1 3/90581


EPA SAMPLE NO,


,ab Code: EANDE Case No.: 269 SAS No.:


jSample wt/vol: 2.0 (g/mL) G



iConcentrated Extract Volume: 1000 (uL)


(Y/N) N pH: 6.6

COMPOUND

IR-4

SDG No.: 54598


Lab File ID: G5202





pPC Cleanup:

CAS NO.CONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

132-64-9------ - -Dibenzof uran __________121-14-2--------2,4-Dinitrotoluene ~84-66-2---------Diethylphthalate7005-72-3-------4-Chloropheny1-phenylether86-73-7--------- Fluorene ____________'_100-01-6--------4-Nitroaniline534-52-1--------4,6-Dinitro-2-methylphenol86-30-6---------N-Nitrosodiphenylamine (1) "101-55-3--------4-Bromophenyl-phenylether_118-74-i--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8---------Carbazole ____________84-74-2---------Pi-n-Butylphthalate206-44-0--------Fluoranthene_____________129-00-0-------- Pyrene_____________________85-68-7---------Butylbenzylphthalate91-94-l---------3,3'-Dichlorobenzidine____56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene_________________117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate_______~205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo(a)Pyrene__________193-39-5--------Indeno(1,2,3 -cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene____191-24-2--------Benzo(g,h,i)Perylene_____

~ Cannot be separated from Diphenylamine

8700087000870008700087000210000210000870008700087000210000870008700087000870008700087000870008700087000140008700087000870008700087000870008700087000

UUUUUUUUUUUUUUUUUUUUJUUUUUUUU

FORM I SV-2 3/90

532



EPA SAMPLE NO.

ILab Name: E & E INC. Contract

Lab Code: EANDE Case No.: 269 SAS No.


jsample wt/vol: 2.0 (g/mL) G


j% Moisture: 43 decanted: (Y/N) N

.Concentrated Extract Volume: 1000 (uL)


jGPC Cleanup: (Y/N) N . pH: 6.6

somber TICs found: 12

IR-4

SDG No.: 54598


Lab File ID: G5202






CAS NUMBER

1.2.3 .4 .5.6.7.8.9.

10 .11.12 .

COMPOUND NAME

STRAIGHT -CHAIN ALKANEUNKNOWNSTRAIGHT -CHAIN ALKANEUNKNOWNUNKNOWNSTRAIGHT- CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANEUNKNOWNSTRAIGHT -CHAIN ALKANEUNKNOWNSTRAIGHT -CHAIN ALKANE

RT

27.7528 .4428.8729.0729.2529.9530.9831.9632.7133 .8434 .3934 .72

EST. CONC.

330001900028000220001800026000760003900089000230000150000310000

Q

JJJJJJJJJJJJ



EPA SAMPLE NO.








'injection Volume: 2 . 0 (uL)

GPC Cleanup: (Y/N) N pH: 3 .3

CAS NO. COMPOUND

IR-5

SDG No.: 54598


Lab File ID: G5203






108-95-2--------Phenol________________lll-44-4--------bis(2-Chloroethyl)Ether95-S7-8---------2-Chlorophenol___________541-73-l--------l,3-Dichlorobenzene_______106-46-7--------1,4-Dichlorobenzene_______95-50-1---------1,2-Dichlorobenzene______95-4S-7---------2-Methylphenol_________108-60-1--------2,2'-oxybis(1-Chloropropane ]106-44-5--------4 -Methylphenol_____ ^621-64-7--------N-Nitroso-Di-n-Propylamine__67-72-1---------Hexachloroethane_________98-95-3---------Nitrobenzene_____________78-59-1---------Isophorone_____________88-75-5---------2-Nit rophenol105-67-9--------2,4-Dimethylphenol111-91-1--------bis(2-Chloroethoxy)Methane_120-83-2--------2,4-Dichlorophenol_________120-82-l--------l,2,4-Trichlorobenzene____91-20-3---------Naphthalene_____________106-47-8--------4-Chloroaniline87-68-3---------Hexachlorobutadlene_______59-50-7---------4-Chloro-3-Methylphenol91-57-6---------2-Methylnaphthalene_____77-47-4---------Hexachlorocyclopentadiene ~88-06-2---------2,4,6-Trichlorophenol_____95-95-4---------2,4,5-Trichlorophenol_____91-58-7---------2-Chloronaphthalene_______S8-74-4---------2-Nitroaniline___________131-11-3--------Dimethylphthalate_________208-96-8------- - Acenapht hylene__________606-20-2--------2,6-Dinitrotoluene________99-09-2---------3-Nitroaniline____________83-32-9---------Acenaphthene____________51-28-5---------2,4-Dinitrophenol100-02-7--------4-Nitrophenol_____________

560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000560000130000056000013000005600005600005600001300000560000

13000001300000


FORM I SV-1 -3/9



EPA SAMPLE NO.










dumber TICs found: 18

IR-5

SDG No.: 54598


Lab File ID: G5203






CAS NUMBER

1.2 .3 .4 .5.6 .7 .8 .9 .

10 .11.12 .13 .14 .15.16 .17.18 .

COMPOUND NAME

UNKNOWN PAHUNKNOWNUNKNOWN PAHSTRAIGHT -CHAIN ALKANEUNKNOWNUNKNOWNUNKNOWN PAHUNKNOWN PAHSTRAIGHT -CHAIN ALKANEUNKNOWNUNKNOWNBENZONAPHTHOTH I OPHENE ISOMERUNKNOWN PAHSTRAIGHT -CHAIN ALKANEUNKNOWNSTRAIGHT- CHAIN ALKANEUNKNOWN PAHUNKNOWN

RT

26.2827.4427.5927.7528 .1528 .2528.4728.7028.8729.4929.9430 .4430.7130. 9831.5531.9832.5033 .28

EST . CONC .

140000460000190000370000180000180000330000410000360000470000460000240000360000420000300000460000820000340000

Q

JJJJJJJJJJJJJJJJJJ



EPA SAMPLE NO,

1Lab Name: E & E INC. Contract









CAS NO. COMPOUND

IR-6

SDG No.: 54598


Lab File ID: G5204






132-64-9--------Dibenzofuran___________121-14-2--------2,4-Dinitrotoluene84-66-2---------Diethylphthalate7005-72-3-------4-Chlorophenyl-phenylether_86-73-7---------Fluorene100-01-6--------4-Nitroaniline ~~~534-52-1--------4,6-Dinitro-2-methylphenol_86-30-6---------N-Nitrosodiphenylamine (1)"101-55-3--------4-Bromophenyl-phenylether_118-74-1--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8---------Carbazole_________84-74-2---------Di-n-Butylphthalate206-44-0--------Fluoranthene_____________1 2 9 - 0 0 - 0 - - - - - - - - P y r e n e _ _ _ _ _ _ _ _ _85-68-7---------Butylbenzylphthalate91-94-l---------3,3'-Dichlorobenzidine____56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene________________117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate_____'_205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo(a)Pyrene___________193-39-5--------Indeno(1,2,3-cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene____191-24-2--------Benzo(g,h,i)Perylene_____

l"5 - Cannot be separated from Diphenylamine

24000024000024000024000024000059000059000024000024000024000059000036000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000

UUUUUUUUUUUJUUUUUUUUUUUUUUUUU

FORM I SV-26333/90



EPA SAMPLE NO




(Sample wt/vol : 2.0 (g/mL) G



|Concentrated Extract Volume: 1000 (uL)




IR-6

SDG No.: 54598


Lab File ID: G5204






CAS NUMBER

1.2. 90-12-03 .4 .5.6 .7 .8 .9 .

10 .11.12 .13 .

" 14 .15 .16 .17. 593-45-3

COMPOUND NAME

UNKNOWN HYDROCARBON1 -MethylnaphthaleneDIMETHYLNAPHTHALENE ISOMERDIMETHYLNAPHTHALENE ISOMERDIMETHYLNAPHTHALENE ISOMERBRANCHED -CHAIN ALKANEBRANCHED -CHAIN ALKANEBRANCHED -CHAIN ALKANESTRAIGHT -CHAIN ALKANEUNKNOWN PAHUNKNOWN HYDROCARBONUNKNOWN HYDROCARBONUNKNOWN HYDROCARBONSTRAIGHT- CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALAKNEOctadecane

RT

14 .3315.3016.7816.9717.2217.6620.5921.4223 .9924 .5926.2926.9627 .7528 .1530.9631. 9632 . 51

EST . CONC .

2700013000057000700001200005700082000140000470007600012000062000160000130000170000150000150000

Q

JJNJJJJJJJJJJJJJJJN

FORM I SV-TIC 3/90

1C EPA SAMPLE NOSEMIVOLATILE ORGANICS ANALYSIS DATA SHEET









|GPC Cleanup: (Y/N) N pH: 1.3

v CAS NO. COMPOUND

RS-01

SDG No.: 54598


Lab File ID: G5170






132-64-9--------Dibenzofuran121-14-2--------2,4-Dinitrotoluene ~84-66-2---------Diethylphthalate7005-72-3-------4-Chloropheny1-phenylether_8'6-73-7-------- -Fluorene _____________100-01-6--------4-Nitroaniline ~~534-52-1--------4,6-Dinitro-2-methylphenol_86-30-6---------N-Nitrosodiphenylamine (1)_101-55-3--------4-Bromophenyl-phenylether_118-74-1--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8---------Carbazole_________84-74-2---------pj-n-Butylphthalate206-44-0--------Fluoranthene_____________129-00-0-------- Pyrene ________85-68-7---------Butylbenzylphthalate ~91-94-l---------3,3'-Dichlorobenzidine___56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene ______^__117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0------- -Di-n-Octyl Phthalate_____'_205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo(a)Pyrene__________193-39-5--------Indeno(l,2>3-cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene____191-24-2--------Benzo(g,h,i)Perylene_____

25000025000025000025000025000061000061000025000025000025000061000052000

250000250000250000250000190000250000250000250000630000250000250000250000250000240000250000250000250000

Cannot be separatea from Diphenylamine

UUUUUUUUUUUJUUUUJUUU

UUUUJUUU

FORM I SV-2 3/90

682


EPA SAMPLE NO,






|% Moisture: 11 decanted: (Y/N) N


iInjection Volume: 2.0(uL)

IR-5

SDG No.: 54598


Lab File ID: G5203





iGPC Cleanup: (Y/N) N

CAS NO.

pH: 3.3

COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

132-64-9--------Dibenzofuran___________121-14-2--------2,4-Dinitrotoluene84-66-2---------Diethylphthalate7005-72-3-------4-Chlorophenyl-phenylether86-73-7---------Fluorene ____________"100-01-6--------4-Nitroaniline ~~~534-52-1--------4,6-Dinitro-2-methylphenol86-30-6-------- -N-Nitrosodiphenylamine (1)'_101-55-3--------4-Bromophenyl-phenylether_118-74-i--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8---------Carbazole __________84-74-2---------Di-n-Butylphthalate206-44-0--------Fluoranthene_____________129-00-0-------- Pyrene___________________85-68-7---------Butylbenzylphthalate91-94-l---------3,3'-Dichlorobenzidine____56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene________________117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate_____~205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo (a) Pyrene__________193-39-5--------Indeno(1,2,3-cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene____191-24-2--------Benzo(g,h,i)Perylene_____

Tl- Cannot be separated from Diphenylamine

560000560000560000560000560000130000013000005600005600005600001300000560000560000560000560000560000560000560000560000560000540000560000560000560000560000560000560000560000560000


FORM I SV-2



EPA SAMPLE NO.

Lab Name: E & E INC. ContractI

(Lab Code: EANDE Case No.: 269 SAS No.







(GPC Cleanup: (Y/N) N pH: 1.3Iv xtnber TICs found: 20

RS-01

SDG No.: 54598


Lab File ID: G5170






CAS NUMBER

1.2 .3 .4 .5 .6 .7 .8.9.

10 .11 .12.13 .14 .15.16 .17.18.19.20 .

COMPOUND NAME

STRAIGHT-CHAINUNKNOWN PAHUNKNOWNUNKNOWN PAHUNKNOWN PAHSTRAIGHT -CHAINUNKNOWNSTRAIGHT -CHAINUNKNOWN PAHUNKNOWN PAHSTRAIGHT -CHAINUNKNOWNUNKNOWNUNKNOWNUNKNOWNSTRAIGHT -CHAINUNKNOWNSTRAIGHT -CHAINSTRAIGHT -CHAINUNKNOWN PAH

ALKANE

ALKANE

ALKANE

ALKANE

ALKANE

ALKANEALKANE

RT

24.2625.0225.7726.1026.4726.7627.7827.9528.6028 . 9229.0729.6829.8530.1530.5131.1831.7832.1732.4832.84

EST . CONC .

680001800006500096000170000100000100000230000110000170000180000260000100000220000120000220000160000110000160000110000

Q


FORM I SV-TIC 3/90

683


EPA SAMPLE NO

Lab Name: E k E INC. Contract







IR-6

'Injection Volume: 2.0(uL)

|GPC Cleanup: (Y/N) N pH:

SDG No.: 54598


Lab File ID: G5204





7.3

CAS NO. COMPOUNDCONCENTRATION UNITS:(ug/L or ug/Kg) UG/KG

108-95-2-------- Phenol________________lll-44-4--------bis(2 -Chloroethyl)Ether95-57-S---------2-Chlorophenol____________541-73-l--------l,3-Dichlorobenzene________106-46-7--------1,4-Dichlorobenzene________95-50-1---------1,2-Dichlorobenzene________95-4S-7---------2-Methylphenol_________108-60-1--------2,2'-oxybis(1-Chloropropane)106-44-5--------4 -Methylphenol_____ _621-64-7--------N-Nitroso-Di-n-Propylamine67-72-1---------Hexachloroethane__________98-95-3---------Nitrobenzene______________78-59-1--------- I sophorone__^______________88-75-5---------2-Nitrophenol105-67-9--------2,4-Dimethylphenol111-91-1--------bis(2-Chloroethoxy)Methane ~120-83-2--------2,4-Dichlorophenol_________120-82-l--------l,2,4-Trichlorobenzene______91-20-3---------Naphthalene_______________106-47-8--------4-Chloroaniline87-68-3---------Hexachlorobutadiene________59-50-7---------4-Chloro-3-Methylphenol91-57-6--------- 2 -Methylnaphthalene__^^_______77-47-4---------Hexachlorocyclopentadiene88-06-2---------2,4,6-Trichlorophenol______95-95-4---------2,4,5-Trichlorophenol______91-58-7---------2-Chloronaphthalene_______88-74-4---------2-Nitroaniline____________131-11-3--------Dimethylphthalate_________208-96-8--------Acenaphthylene____________606-20-2--------2,6-Dinitrotoluene________99-09-2---------3-Nitroaniline____________83-32-9---------Acenaphthene__________51-28-5---------2,4-Dinitrophenol100-02-7--------4-Nitrophenol_____________

240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000240000170000240000240000590000240000590000240000240000240000590000240000590000590000

FORM I SV-1

UUUUUUUUUUUUUUUUUUUUUUJUUUUUUUUUUUU

3/90

632


EPA SAMPLE NO










CAS NO. COMPOUND

RS-03

SDG No.: 54598


Lab File ID: G5200






132-64-9--------Dibenzofuran___________121-14-2--------2,4-Dinitrotoluene84-66-2---------Diethylphthalate7005-72-3-------4-Chlorophenyl-phenylether_86-73-7---------Fluorene______________100-01-6--------4-Nitroaniline534-52-1--------4,6-Dinitro-2-methylphenol_86-30-6---------N-Nitrosodiphenylamine (1)101-55-3--------4-Bromophenyl-phenylether^118-74-1--------Hexachlorobenzene________87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8--------- Carbazole ___________84-74-2---------Di-n-Butylphthalate206-44-0--------Fluoranthene____________129-00-0--------Pyrene____________________85-68-7---------Butylbenzylphthalate91-94-l---------3,3'-Dichlorobenzidine___56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene________________117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate_____~205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8-------- - Benzo (a) Pyrene____________193-39-5--------Indeno(1,2,3-cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene_____191-24-2--------Benzo(g,h,i)Perylene_____

5300053000530005300053000130000130000530005300053000130000530005300053000530005300053000530005300053000480005300053000530005300053000530005300053000



FORM I SV-2 3/90


EPA SAMPLE NO.










CAS NO. COMPOUND

RS-02

SDG No.: 54598


Lab File ID: G5171

Date Received:. 10/22/96





FORM I SV-1

Q

108-95-2-111-44-4-95-57-8--541-73-1-106-46-7-95-50-1--95-48-7--108-60-1-106-44-5-621-64-7-67-72-1--98-95-3--78-59-1--Q Q n C C

105-67-9-111-91-1-ion Q *3 oion HO nQI on ">.106-47-8-87-68-3--59-50-7--91-57-6--77-47-4--Q Q r\ /- o

95-95-4--Q 1 CI Q —J

Q Q T /I /I

131-11-3-i n Q Q £ Q606-20-2-99-09-2--

51-28-5--100-02-7-

_ _ _ _ _ _ _ b i s (2-Chloroethyl) Ether-------2 -Chlorophenol

/ ^± UJ.^_'li-LWJ_ V— 'iJ*_ll AJ 1 — llt_

_ _ _ _ _ _ _ 1 ( 2 -Dichlorobenzene_ _ _ _ _ _ _ 2 -Methylphenol-------2,2' -oxybis ( 1-Chloropropane)_ _ _ _ _ _ -4 -Methylphenol_ _ _ _ _ _ -N-Nitroso-Di-n-Propylamine_ _ _ _ _ _ -Hexachloroethane_ _ _ _ _ _ -Nitrobenzene- - _ _ _ - _ isophorone------- 2 -Nitrophenol-------2,4 -Dimethylphenol_ _ _ _ _ _ _ b i s (2-Chloroethoxy) Methane-------2,4 -Dichlorophenol-------1,2,4 -Trichlorobenzene_ _ _ _ _ _ -Naphthalene-------4 -Chloroaniline---- - - -Hexachlorobutadiene_ _ _ _ _ _ _ 4 -Chloro-3 -Methylphenol------ -2 -Methylnaphthalene------ -Hexachlorocyclopentadiene_ - - - _ _ _ 2 , 4 , 6-Trichlorophenol-------2,4, 5 -Trichlorophenol------ -2- Chloronaphthalene------ -2-Nitroaniline_ _ _ _ _ _ -Dimethylphthalate_ _ _ _ _ _ -Acenaphthylene-------2, 6-Dinitrotoluene-------3 -Nitroaniline

M.k_- clld|JIlu I It: I Ic-------2, 4-Dinitrophenol-------4 -Nitrophenol

270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000270000650000270000650000270000270000270000650000270000650000650000


3/90

713


EPA SAMPLE NO.



Contract

SAS No.

RS-03







|GPC Cleanup: (Y/N) N pH: 3.0

x_ CAS NO. COMPOUND

SDG No.: 54598


Lab File ID: G5200






10 8-95-2--------Phenol __________________lll-44-4--------bis(2-Chloroethyl)Ether95-S7-8---------2-Chlorophenol____________541-73-l--------l,3-Dichlorobenzene________106-46-7--------1,4-Dichlorobenzene________95-50-l---------l,2-Dichlorobenzene________95-4S-7---------2 -Methylphenol___________108-60-l--------2,2'-oxybis(1-Chloropropane)106-44-5------ --4-Methylphenol_____ _621-64-7--------N-Nitroso-Di-n-Propylamine67-72-1---------Hexachloroethane__________98-95-3---------Nitrobenzene______________78-59-1---------I sophorone_^____________'88-75-5---------2-Nitrophenol105-67-9--------2,4-Dimethylphenol111-91-1--------bis(2-Chloroethoxy)Methane ~120-83-2--------2,4-Dichlorophenol_________120-82-l--------l,2,4-Trichlorobenzene_____91-20-3-------- -Naphthalene________________106-47-8--------4-Chloroaniline87-68-3---------Hexachlorobutadiene_______59-50-7---------4-Chloro-3-Methylphenol91-57-6---------2-Methylnaphthalene_______77-47-4---------Hexachlorocyclopentadiene88-06-2---------2,4,6-Trichlorophenol______95-95-4---------2,4,5-Trichlorophenol______91-58-7---------2-Chloronaphthalene_______88-74-4---------2-Nitroaniline____________131-11-3--------Dimethylphthalate_________208-96-8------- - Acenaphthylene________________606-20-2--------2,6-Dinitrotoluene_________99-09-2---------3-Nitroaniline____________83-32-9---------Acenaphthene______________51-28-5---------2,4-D ini trophenol100-02-7--------4-Nitrophenol_____________

530005300053000530005300053000530005300053000530005300053000530005300053000530005300053000530005300053000530005300053000530001300005300013000053000530005300013000053000130000130000


FORM I SV-1

I



EPA SAMPLE NO,




sample wt/vol: 2.0 (g/mL) G






TICs found: 20

RS-02

SDG No.: 54598


Lab File ID: G5171






CAS NUMBER

1 .2 .3 .4 .5 .6 .7 .8 .9 .

10.11.12.13 .14 .15 .16 .17 .18 .19 .20 .

COMPOUND NAME

UNKNOWN PAHSTRAIGHT -CHAINUNKNOWNUNKNOWN PAHSTRAIGHT -CHAINSTRAIGHT -CHAINUNKNOWNSTRAIGHT-CHAINBRANCHED -CHAINUNKNOWNUNKNOWN PAHSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT- CHAINSTRAIGHT -CHAINSTRAIGHT -CHAINSTRAIGHT- CHAIN

ALKANE

ALKANEALKANE

ALKANEALKANE

ALKANEALKANEALKANEALKANEALKANEALKANEALKANEALKANEALKANE

RT

25.0325.5526.0826 .4626.7727. 1427.5227. 9428.3528.5928. 9229.0730.1431 . 1732 . 1633 . 1234 .0434 . 9235.8036 .75

EST. CONC.

13000012000096000

2400002200001600003100008400002700002600001600008400008300009500009500006400008500007900001600000360000

Q




EPA SAMPLE NO.


Lab Code: EANDE

Contract:RS-02

Case No.: 269








CAS NO. COMPOUND

SAS No.: SDG No.: 54598


Lab File ID: G5171






132-64-9--------Dibenzofuran___________121-14-2--------2,4-Dinitrotoluene ~84-66-2---------Diethylphthalate7005-72-3-------4-Chlorophenyl-phenylether86-73-7--------- Fluorene ____________~_100-01-6--------4-Nitroaniline534-52-1--------4,6-Dinitro-2-methylphenol_86-30-6-------- -N-Nitrosodiphenylamine (1) ~_101-55-3--------4-Bromophenyl-phenylether^118-74-1--------Hexachlorobenzene_______87-86-5---------Pentachlorophenol________85-01-8---------Phenanthrene____________120-12-7--------Anthracene______________86-74-8---------Carbazole_______________84-74-2---------Di-n-Butylphthalate206-44-0--------Fluoranthene_____________129-00-0-------- Pyrene__________________85-68-7---------Butylbenzylphthalate91-94-l---------3,3'-Dichlorobenzidine____56-55-3---------Benzo(a)Anthracene_______218-01-9--------Chrysene________________117-81-7--------bis(2-Ethylhexyl)Phthalate117-84-0--------Di-n-Octyl Phthalate_____'_205-99-2--------Benzo(b)Fluoranthene_____207-08-9--------Benzo(k)Fluoranthene_____50-32-8---------Benzo(a)Pyrene__________193-39-5--------Indeno(1,2,3-cd)Pyrene53-70-3---------Dibenz(a,h)Anthracene____!9l-24-2--------Benzo(g,h,i)Perylene_____

27000027000027000027000027000065000065000027000027000027000065000036000

27000027000027000027000027000027000027000027000021000027000027000027000027000084000270000270000270000


UUUUUUUUUUUJUUUUUUUUJUUUUJUUU

FORM I SV-2 3/90714



EPA SAMPLE NO.


,Lab Code: EANDE Case No.: 269 SAS No.:

Matrix: (soil/water) SOILI

[Sample wt/vol: 2.0 (g/mL) G

Level: ( low/med) LOW

|% Moisture: 7 decanted: (Y/N) N


•Injection Volume: 2 . 0 ( u L )

RS-03

SDG No.: 54598


Lab File ID: G5200





iGPC Cleanup: (Y/N) N

lumber TICs found: 20

pH: 3.0


CAS NUMBER

1 .2 .3 .4 .5 .6 .7 .8 .9 .

10 .11 .12 .13 .

- 14 .15.16 .17 .18 .19.20.

COMPOUND NAME

UNKNOWNUNKNOWN SILOXANEUNKNOWN PAHUNKNOWN PAHUNKNOWN PAHSTRAIGHT -CHAIN ALKANEUNKNOWNSTRAIGHT -CHAIN ALKANEUNKNOWNSTRAIGHT-CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT-CHAIN ALKANESTRAIGHT- CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANESTRAIGHT -CHAIN ALKANEUNKNOWNUNKNOWN

RT

5.028.4324.5524.8226.2626.5927.3227.7528.3928 .8729 . 9430 . 9831. 9732. 9233.8434.7235.5936.5136.8137.75

EST . CONC .

1600053000-1700013000230001200012000011000066000930009200012000010000016000012000082000

400000120000160000310000

Q


FORM I SV-TIC 3/

Appendix C

RCMS Cost Projection

i1 C-l

Projection Name: Texaco RefineryProjection Type: Initial

Cost Summary

Date: 12/23/96

Prime Contractor: EQ5

Page:

ProjectionCONTRACTOR

Personnel CostEquipment CostOther Direct Cost

Total for Contractor

Contractor Contingency:20.00%

Including Contractor Contingency

Site Contingency:15.00%

Including Site Contingency

11493175417793

31040

Archive

00

0

Total

11493

1754

17793

31040

6208

37248

4656

GOVERNMENT

Personnel CostEquipment CostOther Direct Cost

Total for Goverment

Site Contingency: 15.00%

Including Site Contingency

66140

2028

8642

6614

0

2028

8642

1296

PROJECT TOTAL 51842

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