ECE-Elec 3 Lec1 Basic Physics of Semiconductors With Exercise

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    ECE-Elec 3 Lecture 1

    ECE ELEC3-UST ECE 2013 1

    Erika Escandor, ECE

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    Outline

    2

    Introduction

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    Introduction

    ELECTRONICS vs MICROELECTRONICS

    ELECTRONIC MICROELECTRONICS

    Began about a century ago

    Vacuum Tubes

    Transistors (1940s)

    Not until 1960s

    Integrated Circuits (ICs)

    Microchips

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    Introduction

    Imagine:

    A microprocessor containing about 100

    million transistors in a chip area of approximately3 cm x 3 cm.

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    uppose s were no nven e :Build the processor using 100 million

    discrete transistors.

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    Introduction

    Using 100 million discrete

    transistors:

    If each device occupies a volume of3 mm x

    3 mm x 3 mm

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    n mum vo ume wou e m xPlus wires to connect the transistors thus

    volume would increase substantially

    this will be extremely SLOW since signals

    would need to travel on long wires

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    Introduction

    Using 100 million discrete

    transistors:

    If each discrete transistor costs Php2.00,

    the processor would be worth Php200

    6

    If each discrete transistor would weigh 1 g

    each, the processor would weight up to 100

    tons

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    Integrated Circuit (IC)

    IC consists of interconnected electronic

    components in a single piece (chip) of

    semiconductor material

    In 1958, ack S. Kilb (Texas

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    Instruments) showed that it was possibleto fabricate a simple IC in Germanium

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    Integrated Circuit (IC)

    In 1959, Robert Noyce (Fairchild

    Semiconductor) demonstrated an IC

    made in Silicon using SiO2 as the

    insulator and Al for the metallic

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    interconnects

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    Integrated Circuit (IC)

    An IC that performs very complex tasks

    Can be built by connecting a large number

    of components, each performing simple

    operations

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    Integrated Circuit (IC)

    The degree of integration has increased

    at an exponential pace over the past ~40

    years

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    Moores Law

    Number o transistors on

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    ICs doubles approximatelyevery two years

    Named after Intel co-

    founder Gordon E.

    Moore

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    Outline

    12

    Basic Semiconductor P!sics

    Semiconductors

    Intrinsic Silicon

    "o#ing

    Carrier Concentrations

    $rans#ort o% Carriers Carrier "ri%t and "i%%usionECE ELEC3-UST ECE 2013

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    Semiconductor

    Material which has electrical

    conductivity between that of a metal and

    an insulator

    Remember:

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    Low resistivity = conductor

    High resistivity = insulator

    Intermediate resistivity = semiconductor

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    Semiconductor

    Generally crystalline in structure for

    IC devices

    In recent years, however, non-crystalline

    semiconductors have become

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    commerc a y very mportant

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    polycrystalline amorphous crystalline

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    Structure o% Solid

    Crystalline

    Solid material whose constituent atoms,

    molecules, or ions are arranged in an

    ordered pattern extending in all three

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    spat a mens ons Amorphous

    Non-crystalline solid is a solid that lacksthe long-range order characteristic of a

    crystal

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    Structure o% Solid

    Polycrystalline

    Solids that are composed of many

    crystallites of varying size and orientation

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    Semiconductor

    Has the ability to change conductivity

    by addition of impurities calledDoping

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    &alence e-

    Remember:

    -

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    electronics, since this is where we can get

    free electrons electrons that get

    dislodged from their orbit, capable ofcarrying a charge through a conductor.

    NOTE: The farther the electron is from

    the nucleus, the easier it is to set it free.ELE 311-UST ECE 2013

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    &alence e-

    Neon

    Complete outermost shell

    No tendency for chemical reaction

    Sodium

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    One (1) valence electron

    Donor of electrons

    Chloride Seven (7) valence electrons

    Acceptor of electronsELE 311-UST ECE 2013

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    Semiconductor

    Atoms having approximately four (4)

    valence electrons fall somewhere

    between inert gases and highly volatile

    elements

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    Group IV in periodic table Ex.Silicon,Germanium

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    Periodic $a'le o% Elements

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    Silicon

    Atomic density:5 x 1022atoms/cm3

    Si has four valence electrons

    Thus requiring another four to complete its

    outermost shell

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    It can form covalent bonds with four of itsnearest neighbors.

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    Electron Pro#erties o% Silicon

    Silicon is a semiconductor material

    Pure Si has a relatively high electrical

    resistivity at room temperature

    There are 2 t es o mobile char e-

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    carriers in Si:Conduction electrons- negatively charged

    Holes- positively charged

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    Electron Emission

    Electrons on the outermost shell were

    given enough additional energy to

    escape

    Methods o Electron Emission

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    Thermionic

    Photoelectric

    Field Emission / Cold Cathode / Antoelectronic

    Secondary Emission

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    Electron Emission %or Silicon

    The concentration (#/cm3) of conduction

    electrons & holes in a semiconductorcan be modulated in several ways:

    B

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    (dopants)

    By applying an electric field

    By changing the temperatureBy irradiation

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    Silicon "uring $ermal Emission

    When temperature goes up:

    Electrons gain thermal energy

    Thus can break away from the covalent

    bond and act as free charge carrier

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    Free electrons now exist in theconductionband

    Until they fall into another incomplete

    bond

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    Electron-ole Pair eneration

    When a conduction electron is thermally

    generated, a void or hole is also

    generated

    A hole is associated with a ositive

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    charge, and is free to move about the Sicrystal as well

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    Bandga# Energ!

    Denoted byEg

    Amount of energy needed to remove anelectron from a covalent bond

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    ,g= .

    Unit eV (electron volt) - represents the

    energy necessary to move one electron

    across a potential difference of 1 V1 eV = 1.6 x 10-19J

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    "ensit! or Concentration o% Electrons

    Number of electrons per unit volume

    Denoted byni

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    ere = . x

    -

    = Boltzmann constant

    T= absolute temperature

    Eg= bandgap energy

    B= coefficient related to a specific

    semiconductor material

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    "ensit! or Concentration o% Electrons

    Semiconductor Constants

    MATERIAL Eg (eV) B (cm-3 K-3/2)

    Silicon (Si) 1.1 5.23 x 1015

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    a um rsen e

    (GaAs)

    . . x

    Germanium (Ge) 0.66 1.66 x 1015

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    E*am#le +1

    Determine the density of electrons in

    Silicon at T = 300K (room temperature)

    and T = 600 K.

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    ,

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    Intrinsic and E*trinsic Semiconductors

    Intrinsic Semiconductor

    Pure Silicon -> has very high resistance

    Mass-Action Law

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    Where: n electron density

    = ni

    p hole density

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    Intrinsic and E*trinsic Semiconductors

    Extrinsic Semiconductor

    Resistivity of Silicon can be modified by

    replacing some of the atoms in the crystal

    with atoms of another material

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    "o#ing

    Addition of impurities to intrinsic

    semiconductor (ex. Silicon)

    Silicon can be doped with other

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    properties

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    "o#ing (, $!#e)

    For example, if Si is doped with

    phosphorus (P)P atom contains five (5) valence electrons

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    electron, so that the Si crystal has moreelectrons than holes

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    "o#ing (, $!#e)

    If a certain number of Phosphorus atoms

    are uniformly introduced in a Siliconcrystal

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    equivalent to the number of P atoms

    Phosphorus is adonor dopant

    Silicon crystal becomes an ExtrinsicSemiconductorknown asn type

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    "ensit! %or "o#ed Material

    Under thermal equilibrium conditions,

    the product of the conduction-electron

    density and the hole density isALWAYS

    e ual o he uare o n

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    Where:n electron density in extrinsic semiconductor

    p hole density in extrinsic semiconductor

    ni density in intrinsic semiconductor

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    E*am#le +

    A crystalline Silicon is doped uniformly

    with Phosphorus atoms. The doping

    density is 1016 atoms/cm3. Determine the

    electron and hole densities at room

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    temperature.

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    Carriers in an ,-t!#e Semiconductor

    Electron majority carrier

    Hole minority carrier

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    "o#ing (P $!#e)

    For example, if Si is doped with Boron

    (B)

    B atom contains three (3) valence electrons

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    ,

    the Si crystal has more holes thanelectrons

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    "o#ing (P $!#e)

    If a certain number of Boron atoms are

    uniformly introduced in a Silicon crystal

    The density of holes will be equivalent to

    the number o B atoms

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    Boron is anacceptor dopant

    Silicon crystal becomes an Extrinsic

    Semiconductorknown asp type

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    Carriers in an P-t!#e Semiconductor

    Hole majority carrier

    Electron minority carrier

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    " C i

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    "o#ant Com#ensation

    An n-type semiconductor can be

    converted into p-type material by

    counter-doping it with acceptors such

    that N > N

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    " C i

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    "o#ant Com#ensation

    A compensated semiconductor material

    has both acceptors and donors

    P-type material

    N-type material

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    A> DD> A

    S % C C i

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    Summar! o% Carge Carriers

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    $ % C i

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    $rans#ort o% Carriers

    Movement of charge in semiconductors

    DriftDiffusion

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    & l it

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    &elocit!

    Acceleration due to the field and the

    collision with the crystal counteract

    leading to a constant velocity for the

    carriers

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    Average velocity (v) is proportional to

    theElectric field(E):

    &elocit!

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    &elocit!

    where: -mobility, cm2/(Vs)

    Electron Velocit

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    Hole Velocity

    &elocit!

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    &elocit!

    For Silicon:

    n

    = 1350 cm2/ V s

    p= 480 cm2/ V s

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    E*am#le +3

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    E*am#le +3

    A uniform piece of n-type Silicon that is

    1 m long senses a voltage of 1 V.

    Determine the velocity of the electrons.

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    electrons to cross a 1 m long Silicon.

    Current Calculation

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    Current Calculation

    NOTE:

    q = 1.6 x 10-19 C [charge of hole and

    electron (negative for the electron)]

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    Current Calculation

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    Current Calculation

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    With velocity ofv m/s

    Total charge in v meters passed thecross section in 1 second

    Current Calculation

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    Current Calculation

    Current - equal to the total charge

    enclosed in v meters of the bars length

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    v W h represents volume

    n q charge density in coulombs

    negative sign is due to electrons carrying anegative charge

    Current "ensit!

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    Current "ensit!

    Current density - current passing

    through a unit cross section area

    2

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    In the presence of electrons and holes:

    E*am#le +.

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    E*am#le +.

    Consider an equal electron and hole

    drift currents, how should the carrier

    densities be chosen?

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    ,

    densities for Silicon?

    Conducti/it! and 0esisti/it!

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    Conducti/it! and 0esisti/it!

    Conductivity

    unit: mho/cm

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    Resistivity

    unit: ohm-cm

    &elocit! Saturation

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    &elocit! Saturation

    With this we assume that velocity rises

    linearly with electric fieldIf electric field is high enough, there is

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    no linear relationship between v and Eanymore

    Because the carriers collide with the

    crystal so frequently and the time between

    the collisions is so short that they cannot

    accelerate much

    &elocit! Saturation

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    &elocit! Saturation

    Velocity saturation seen in

    transistors

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    Where: 0 low-field mobility

    b proportionality factor

    &elocit! Saturation

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    &e oc t! Satu at o

    Thus we can say that:

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    E*am#le +

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    #

    A uniform piece of semiconductor 0.2

    m long sustains a voltage of 1 V. If the

    low-field mobility is equal to 1350 cm2/

    V s and the saturation velocit o the

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    carriers 107cm/s, determine the effectivemobility.

    E*am#le + (cont2)

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    # ( )

    Also, calculate the maximum allowable

    voltage such that the effective mobility is

    only 10% lower than 0.

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    condition.

    "i%%usion

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    Flow from a region of high

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    concentrat on to reg on o ow

    concentration

    Even in the absence of electric field, can

    carry electric current as long as non-

    uniformity is sustained

    "i%%usion

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    The more non-uniform the

    concentration, the larger the current

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    Where: n carrier concentration at a

    given point along the x axis

    dn/dx concentration gradientwith respect to x

    "i%%usion

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    If each carrier has charge equal toqand

    given a cross-section area ofA

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    Where: Dn - proportionality factor called

    thediffusion constant, cm2/s

    "i%%usion Constant

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    For intrinsic Silicon:

    For electrons:

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    For holes:

    Current "ensit! %or "i%%usion Carrier

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    In the presence of electrons and holes:

    Linear Concentration Pro%ile

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    Constant diffusion current

    Suppose the electron concentration is

    equal toNat x = 0 and falls linearly to

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    E*am#le +

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    A p-type bar of Silicon is subjected to

    electron injection from the left and hole

    injection from the right. Determine the

    total current lowin throu h the device

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    if the cross-section area is equal to 1 mx 1 m.

    ,on-Linear Concentration Pro%ile

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    Varying diffusion current

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    $otal Current 4lowing in a

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    Semiconductor

    Total current flowing in a semiconductor

    is thesum of drift current and diffusion

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    Einstein 0elation

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    and D are related as:

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    Summar! o% Carge $rans#ort

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    Mecanisms

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    0e%erences

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    Fundamentals of Microelectronics by

    Wiley and Razavi

    Microelectronics : circuit analysis and

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    5dditional E*ercise +1

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    The intrinsic carrier concentration of

    Germanium is expressed as

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    where Eg= 0.66 eV

    Calculate ni at 300K and 600K and

    compare the results with those obtained forSilicon.

    5dditional E*ercise +1

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    The intrinsic carrier concentration of

    Germanium is expressed as

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    where Eg= 0.66 eV

    Determine the electron and hole

    concentrations if Ge is doped with P at adensity of 5 x 1016cm-3

    5dditional E*ercise +

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    An n-type piece of silicon experiences an

    electric field equal to 0.1 V/m.

    Calculate the velocity of electrons and

    holes in this material.

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    What doping level is necessary to providea current density of 1 mA/m2 under these

    conditions? Assume the hole current is

    negligible.

    5dditional E*ercise +3

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    A n-type piece of silicon with a length of

    0.1 m and a cross section area of 0.05

    m x 0.05 m sustains a voltagedi erence o 1 V.

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    If the doping level is 1017 cm-3, calculatethe total current flowing through the device

    at T = 300 K.

    Calculate the total current flowing through

    the device at T = 400K. Assume that

    mobility does not change with temperature.