Design, Preparation, And Application of Ordered Porous Polymer
Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de...
Transcript of Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de...
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Challenge the future
DelftUniversity ofTechnology
Dynamics of polymers in porous media
Prof. Dr. P.L.J. (Pacelli) ZithaE-mail: [email protected]
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DEPARTMENT OF GEOSCIENCES AND
ENGINEERING
Faculty of Civil Engineering and Goesciences
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Course content
The course gives a introduction to polymer dynamics with emphasis on their use of polymers and gels for:
• water control during oil and gas production
• in-depth diversion for water flooding
• mobility control polymer flooding, alkali-surfactant-polymer (ASP)
The course starts with a brief overview of the above applications of polymers and gels for improving oil and gas recovery. Next it reviews the basics about polymer physics. Water control as this enables to illustrate the main advantages and issues when using polymers and gels in porous media: emplacement of the chemicals, permeability reduction concepts, etc. Operational aspects will also be briefly discussed.
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Scope of the Course
The course is organized in three parts: (a) physics of liquid polymers, (b) polymer transport in porous media and (c) the effect polymer adsorption and gel retention on multiphase flow. The lectures on the physics of liquid polymers will focus on dynamic and static properties of dilute and semi-dilute polymer solutions. Polymers under deformation flows will be considered as an introduction to flow through porous media. Special efforts will be devoted to the behavior of polymers near surfaces. Whenever possible, the discussions will stress scaling laws approach. Concerning flow through porous media, we shall consider mostly rheology and polymer adsorption and shall discuss some of the most recent developments including contributions of our group. Microscopic aspects will focus on local dynamic adsorption and flow reduction. Simple statistical theories for up-scaling these properties will be briefly outlined. The numerical treatment of the macroscopic equations will be discussed. Finally the modification of the relative permeability for oil and water will be analyzed.
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INTRODUCTION
Lecture 1
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Primary Oil Recovery
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Fracturing
Impermeable
Barrier
Natural
or Created
Fractures
Viscous
Fingering
Permeability
Contrast
Water production during oil
recovery
(Courtesy of Halliburton)
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Polymer & polymers gels
X-linked polymer/gels block water thieve zones
(WELGEL project 1997-1999)
OIL, WATERWATER
Oil, low k
Water, low k
Water Flooding
(designer water)
Oil
Polymer Flooding
(Alkali-Surfactant Polymer)
Secondary
Tertiary Oil
WATER FLOODING
Recovery Factor (RF)
Less than 25% OIIP
POLYMER FLOODING
Increase in RF
5-10% OIIP
(15-30% OIIP)
(Lake, 2010;
Green and Willhite, 1998)
• Mobility control: better sweep
• DPR effect: higher oil
productivity
• Full blocking: water control,
higher oil productivity
(Seright, 1990; Zaitoun, 1995)
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Introduction
• Polymers used for mobilitycontrol and better sweepefficiency.
• Commercial polymer EORprojects worldwide (see map*)rapidly expanding.
• Successfully applied examples:Angola (Dhalia Field), China(Daqing Field), India (MangalaField), Oman (Marmul Field),Suriname (Tambaredjo), …
• Polymer injectivity essential forextending the applicationenvelop to heavy oil reservoirs.
* Ref: http://www.snf-group.com/IMG/pdf/Oil_EOR-FLOPAAM-Desert.pdf
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Polymer flow in porous media
• Polymer rheology
• Effect concentration above C*
• Effect of shear rates
• Polymer retention (adsorption
dominant)
C<C* C=C* C>C*
VIS
CO
SIT
Y
SHEAR RATERADIUS AROUND WELL(Rubinstein, 2010;Macosko, 1994, Sorbie, 1991, McLeish, 2008)
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Polymer retention in porous media
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Cross-linked polymer gels
fill/block the pores
Sand grains
Gelled water
Cross-linked polymer
Oil blob isolated by gel
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References
• Introduction to Physical Polymer Science, 2nd Edition, Lesley H.
Sperling, Wiley Interscience (1992) ISBN 0-471-53035-2
• Principles of Polymer Chemistry, P.J. Flory (1953) Cornell
University Press, Inc., New York.
• The Physics of Polymers, Gert Strobl (1996) Springer-Verlag,
New York.
• Figures were reproduced from Polymer Physics, (1996) Ulf
Gedde, Chapman & Hall, New York.
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POLYMERS: BASIC PROPERTIES, PHYSICS.
Lecture 1
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Polymer StructureProperty Behavior
• chain thermodynamics
• chain dimensions
• chain environment
• chain topography
• mechanical behavior
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Gaussian Chains
• Random Chain Conformation
• End-to-End Distance
• Radius of Gyration
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r nl2 2
Mean Square End to End Distance
sr
2
2
6
Mean Square Radius of Gyration
Polymer Chain Size
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Effect of Solvent quality
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Kc
R M M
rA c
W W
1 1 16
3 6 222
2
2
2
2sin
where:K - contrast factorc - concentration of scattering speciesR - Rayleigh ratio (reduced intensity)r - distance from scattering center to detector.I0 - incident wave intensityA2 - 2nd virial coefficient
Measure of Chain Properties
Scattering Function
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Determinenation of Chain
Generation of a Zimm Plot
lim
0 2
12
Kc
R MA c
W
lim sinc
W W
Kc
R M M
r 0
2
2
2
21 1 16
3 6 2
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Chain Dimensions
Zimm Plot
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WriteThesis
100
101
102
10-3
10-2
10-1
Shear Rate, (s-1)
Vis
co
sit
y,
p
(Pa.s
)
S
s 5 g/L
pH 5.8
o Experiments
-- Model
5000 ppm
4000 ppm
3000 ppm
2000 ppm
1000 ppm
500 ppm
250 ppm
Brine
Bulk polymer rheology
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22
0'1 CkCwr
Ck
Crsp
2
00 '
1
CrC 1lim 00
Effect of Concentration on
Viscosity
Relative viscosity:
Reduced Specific Viscosity:
Intrinsic Viscosity:
wg MR3
0 Relation to Molecu;ar Weight:
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51.66 10GR cm 0 1 2 3 4 5 6
x 10-3
0
1000
2000
3000
4000
5000
6000
7000
8000
Concentration, cp (g/cc)
s
p/c
p,
(cc/g
)
Ss 20 g/L
pH 5.8
o Experiments
-- Linear Fit
[mu] 1542
kH 0.25
*
pc
0[ ] lim
p
p b
cp bc
1/3[ ] w
G
MR
/cc g
[ ]
Dilute
Regime
Semi Dilute
Regime
(Chauveteau, 1989; Sorbie, 1991 ; Lake, 1989; Ait Kadi.et.al, 1987)
Intrinsic viscosity, radius of gyration
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Summary
• Chain bond rotational potential energies dictate properties
• Chain dimensions can be calculated statistically or by vector
analysis
• Zimm Plots from scattering measurements give dimensions Mw
and Rg separately, along with A2
• Characteristic dimensions defined by structure and environment
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Linear flexible polymers
Polymer
Monomer
Dilute Regime Semi Dilute Regime
Dilute
Regime
Semi Dilute
Regime
(Zitha, 1995, Macosko, 1994)
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Complex fluids
(Complex fluids: Spread the word about nanofluids. Manoj K. Chaudhury
Nature 423, 131-132(8 May 2003)
(Complex fluids: Spread the word about nanofluids. Manoj K. Chaudhury
Nature 423, 131-132(8 May 2003)
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Complex fluids
(http://www.physics.fudan.edu.cn/tps/people/jphuang/viewclass4_2.asp)
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Complex fluids
(http://www.physics.fudan.edu.cn/tps/people/jphuang/viewclass4_2.asp)
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Complex fluids
(http://www.cims.nyu.edu/cmcl/ComplexFluids/ComplexFluids.html)
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Stick-beads network model
(http://www.cims.nyu.edu/cmcl/ComplexFluids/ComplexFluids.html)
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Complex fluids
(Extraction of physically realistic pore network properties from
three-dimensional synchrotron X-ray microtomography images
of unconsolidated porous media systems
R.I. Al-Raoush , C.S. Willson.
Journal of Hydrology
Volume 300, Issues 1–4, 10 January 2005, Pages 44–64
)
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Complex fluids
(http://www.porexpert.com/Help/index.html?capillary_bundle_mo
del.htm)
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Complex fluids
(http://www.cims.nyu.edu/cmcl/ComplexFluids/ComplexFluids.html)
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Modeling of Complex Fluids
(http://www.cims.nyu.edu/cmcl/ComplexFluids/ComplexFluids.html)
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EXAMPLE: PAPER SPE 165195 (2013)
Lecture 1
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Problem statement
• Past polymer retention studies:
• Polymer concentrations lower than 1500 ppm.
• Filtered polymer solutions
• Scope of this study
• Polymer injectivity for unfiltered polymer at concentrations
higher than 1500 ppm ?
• Will unfiltered polymer solutions cause mechanical entrapment
under current experimental conditions ?
• Will there be any retention of the polymer at the inlet face of
porous medium ?
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(Denys, 2003)
Polymer retention in porous media
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• Overall objective: shed light into the interrelation
between polymer rheology and retention in porous
media and well injectivity and increase value of
polymer flooding.
• Specific objectives:
Model and interpret the rheology of HPAM solutions.
Quantification and modeling of the injectivity and transport
properties of polymer solutions in porous media.
Model validation and study the effect of physical and
numerical parameters on injectivity.
Objectives
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Modeling: governing equations
Transport Equation for Polymer in Porous Media
2
2
(1 )p p p p
f p s s
c c cv D vc A
x x t t
Boundary Conditions ,
0
( 0, )p
p p init
x
cvc x t vc D
x
( , ) 0pc
x L tx
( , 0) 0pc x t
( , 0) 0p x t
Initial Conditions
Darcy Law
kA Pq
x
(Zitha, 2001, Sorbie 1991)
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Model: polymer rheology
Bulk Polymer Viscosity(Flory-Huggins)
2 3
1 2 31 b
p b p p p sa c a c a c S
Apparent Viscosity inPorous Media
( , )( )
( , )
p p eq
p
p p ref
cSF c
c
,
,
, ,
(1 )
1
p sh
p app
p sh rel
, ( , )p sh p p refc SF
Polymer VelocityEnhancement
1pf
4
1 d
p Hr
Shear Rate in Porous Media
13 1
4
v
v
m
mv
eq
v
m uC
m k
(Sorbie, 1991; Stavland, 2010; Chauveteau, 1984)
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PermeabilityReduction Model
( , )( , ) 1
p
k
x tR x t
4
1 H
pr
Mobility Reduction
Polymer Injectivity
0
p
m
b
PR
P
0
bp
p
PI
P
Model: polymer adsorption
Polymer AdsorptionEquilibrium
1
p e
p
e p
c k
k c
(Zitha, 2001, Chauveteau 1984)
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Numerical solution
• finite difference method: Nx grid-blocks
• upwind approximation for advection term
• central difference approximation for dispersion
• implicit ‘Euler backward’ method for time
![Page 45: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/45.jpg)
45
WriteThesis
100
101
102
10-3
10-2
10-1
Shear Rate, (s-1)
Vis
co
sit
y,
p
(Pa.s
)
S
s 5 g/L
pH 5.8
o Experiments
-- Model
5000 ppm
4000 ppm
3000 ppm
2000 ppm
1000 ppm
500 ppm
250 ppm
Brine
Bulk polymer rheology
a1 126.60
a2 15545.18
a3 14105109.79
Flory-
Huggins
Parameters
1
2 2
,0( ) 1vm
p b p b
![Page 46: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/46.jpg)
46
51.66 10GR cm
0 1 2 3 4 5 6
x 10-3
0
1000
2000
3000
4000
5000
6000
7000
8000
Concentration, cp (g/cc)
s
p/c
p,
(cc/g
)S
s 20 g/L
pH 5.8
o Experiments
-- Linear Fit
[mu] 1542
kH 0.25
*
pc
0[ ] lim
p
p b
cp bc
1/3[ ] w
G
MR
/cc g
[ ]
Dilute
Regime
Semi Dilute
Regime
(Chauveteau, 1989; Sorbie, 1991 ; Lake, 1989; Ait Kadi.et.al, 1987)
Intrinsic viscosity, radius of gyration
![Page 47: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/47.jpg)
47
Experimental setup
![Page 48: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/48.jpg)
48
125 250 500 1000 2000 3000 5000
5.0
10.0
20.0
Overview of experiments
Porous material: Bentheim sandstone
Polymer: HPAM (AN 905 Lot E 2686, SNF-Floerger)
Brine: Sodium Chloride (NaCl); Potassium Iodide KI (Tracer)
Experiments: 9 single-phase core-floods: 7 polymer concentrations 3
salinities
Accuracy: salinities and polymer concetrations±0.1 g/L; pH = 5.8±0.1
![Page 49: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/49.jpg)
49
p
s
c 250 (ppm)
S 20 ± 0.1 (g / L)
pH 5.8 ± 0.1
k 2.314 ± 0.11 (Darcy)
0.21 ± 0.01
q 1 ± 0.02 (cc / min)
0 2 4 6 8 10
1
1.2
1.4
1.6
1.8
2
PV
Mo
bil
ity R
ed
ucti
on
, R
m
Experiments
Model
0
p
m
b
PR
P
0 2 4 6 8 100
0.2
0.4
0.6
0.8
1
PV
Po
lym
er
Inje
cti
vit
y,
I p
Experiments
Model
0
bp
p
PI
P
ModelImprovement
0 2 4 6 8 100
2
4
6
8
10
12
14
16
18
20
PV
Pre
ssu
re D
rop
,
Pp (
mB
ar)
Experiments
Model
Exp.Error ± 1.2 mBar
WriteThesis
B P
P
P B
Base case: pressure drops
![Page 50: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/50.jpg)
50
WriteThesis
ModelImprovement
0 1 2 3 4 5 6
x 10-3
1
1.5
2
2.5
3
3.5
Concentration, cp (g/cc)
Reta
rdati
on
Facto
r, R
0 2 4 6 8 100
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
PV
C/C
o
Tracer Experiments
Polymer Experiments
Tracer Model
Polymer Model
Exp.Error ± 0.05
R
0 1 2 3 4 5 6
x 10-3
0
0.5
1
1.5
2
2.5
3x 10
-3
Concentration, cp (g/cc)
d
p/d
cp,
(cm
)
Experiments
Curve Fitting
0 1 2 3 4 5 6
x 10-3
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
2
2.2x 10
-4
Concentration, cp (g/cc)
Ad
so
rpti
on
,
p,
(g/g
)
sS 20 ± 0.1 (g / L)
pH 5.8 ± 0.1
q 1 ± 0.02 (cc / min)
ek
-6 2
2014.5 (cc / g)
Γ 1.46 × 10 (g / cm )
0
s
c 250 (ppm)
S 20 ± 0.1 (g / L)
pH 5.8 ± 0.1
sS 20 ± 0.1 (g / L)
pH 5.8 ± 0.1
q 1 ± 0.02 (cc / min)
ek
-6 2
2014.5 (cc / g)
Γ 1.46 × 10 (g / cm )
sS 20 ± 0.1 (g / L)
pH 5.8 ± 0.1
q 1 ± 0.02 (cc / min)
1
p e
p
e p
c k
k c
Base case: effluents
![Page 51: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/51.jpg)
51
0 5 10 150
5
10
15
20
25
30
35
PV
Pre
ssu
re D
rop
,
Pp (
mB
ar)
20 g/L
10 g/L
5 g/L
pc 500 (ppm)
pH 5.8 ± 0.1
k 2 ± 0.1 (Darcy)
q 1 ± 0.02 (cc / min)
k 2 ± 0.1 Darcy
Exp.Error ± 1.2 mBar
Effect of salinity
![Page 52: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/52.jpg)
52
0 1 2 3 4 5 6 7 8 9 100
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
PV
C/C
o
Tracer Experiments
Polymer Experiments
Tracer Model
Polymer Model
125 ppm
0 1 2 3 4 5 6 7 8 9 100
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
PV
C/C
o
Tracer Experiments
Polymer Experiments
Tracer Model
Polymer Model
500 ppm
0 1 2 3 4 5 6 7 8 9 100
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
PV
C/C
o
Tracer Experiments
Polymer Experiments
Tracer Model
Polymer Model
1000 ppm
0 1 2 3 4 5 6 7 8 9 100
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
PV
C/C
o
Tracer Experiments
Polymer Experiments
Tracer Model
Polymer Model
2000 ppm
0 1 2 3 4 5 6 7 8 9 100
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
PV
C/C
o
Tracer Experiments
Polymer Experiments
Tracer Model
Polymer Model
3000 ppm
0 1 2 3 4 5 6 7 8 9 100
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
PV
C/C
o
Tracer Experiments
Polymer Experiments
Tracer Model
Polymer Model
5000 ppm
Effect of Concentration: adsorption
![Page 53: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/53.jpg)
53
0 5 10 150
5
10
15
20
25
PV
Mo
bil
ity R
ed
ucti
on
, R
m
125 ppm
250 ppm
500 ppm
1000 ppm
2000 ppm
3000 ppm
5000 ppm
Model
0 5 10 150
0.2
0.4
0.6
0.8
1
PV
Po
lym
er
Inje
cti
vit
y,
I p
125 ppm
250 ppm
500 ppm
1000 ppm
2000 ppm
3000 ppm
5000 ppm
Model
0 5 10 150
50
100
150
200
250
300
350
PV
Pre
ssu
re D
rop
,
Pp (
mB
ar)
125 ppm
250 ppm
500 ppm
1000 ppm
2000 ppm
3000 ppm
5000 ppm
Model
Exp.Error ± 1.2 mBar
Cp
[ppm]
Adsorption (g/g)
Permeability Reduction (Rk)
1252505001000200030005000
3.67E-55.60E-58.73E-51.13E-41.326E-41.583E-41.664E-4
1.021.041.061.081.101.111.12
pc
pH 5.8 ± 0.1
q 1 ± 0.02 (cc / min)
k 2 ± 0.1 Darcy
ok
d
kR
k
Effect of Concentration on injectivity
![Page 54: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/54.jpg)
54
1D POLYMER FLOW. ANALYTICAL SOLUTIONS
Lecture 2
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55
1D linear flow
• Basic assumptions Homogeneous and isotropic porous media Incompressible, non-inertial and isothermal flow Darcy’s flow equation
• Feature laboratory core-flood experiments
Polymer
2 3
...
Fraction Collector
k, f, As
Layer
adsorptionFree
polymer
coil
Grains of sand
or silicon carbide
![Page 56: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/56.jpg)
56
Governing equations
tssxxt ACDCuC ff 12
dat C
Pu x
Mass conservation:
Adsorption kinetics:
Darcy’s equation:
![Page 57: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/57.jpg)
57
Boundary conditions
00, txC
0
00,
xx
CDuCtxuC f
0, xx txC
OI PtLxPtPtxP ,;,0
Polymer
![Page 58: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/58.jpg)
58
Special case: no dispersion and
instantaneous adsorption
0 CvCF xtR
CC eee 1
‘Langmuir’ isotherm:
fff uvAF essR
;11 1
Retardation factor, intersticial velocity:
Transport equation:
![Page 59: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/59.jpg)
59
Solution to special case
0),0(;0)0,( tCxC
With front trajectory:
txxHCtxC f 0,
Solution:
Boundary conditions:
SLVVFQttx PPRf f ;
![Page 60: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/60.jpg)
60
Solutions graphs
txC ,
x
0C
tx f
r
x
0r
tx f
22
001 CkCCr
kR
x
0kR
tx f
41 pk rR Effect of polymerpropagation relativeviscosity and permeabiltyreduction.
![Page 61: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/61.jpg)
61
Pressure drop
x
rkww dxRkutxPtP0
,,0
General expression:
:txx f LxRPtP rkw /0
Behind the front:
txx f xxRPtP frkw /11 00
After the front:
![Page 62: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/62.jpg)
62
Pressure drop graphs
tP
PVQtPV /
wP
pP
First polymerentry in PM
PolymerBreakthrouh
![Page 63: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/63.jpg)
63
Steady-state flow in parallel cores
l2
POLYMER
OIL
WATER
L-l1
L-l2
l1
u2
u1
q2
q1
Q
s2
s1
![Page 64: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/64.jpg)
64
Basic pressure drop equations
2,1,)()(
ipppi
lLi
li ii
2,1,)(
isk
qlp
ip
i
iip
iili
20
1,
)()(
iif
iifw
sk
qlLp
ii
iiiilL i
![Page 65: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/65.jpg)
65
Pressure equations
11
111
11
1111
)(
sk
qlL
sk
qlp
w
w
p
p
2
2
2
222
22
222
2
)(
sk
qlL
sk
qlp
o
p
p
2,1,)( 11 idt
dxLsls
dt
dq i
iiii ff
powik
i
ii
,,;2,1,)(
)()(
![Page 66: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/66.jpg)
66
First equation for the penetration
depths
( ) (2)
( ) 1
( ) (1)
2
, 1,2; , , , ;i
i wwwi
w
F i w o p F
f
f
dt
dxxF
k
Lp wpw
w1
1)1(
1
211
1 ]1)1[( f
dt
dxFxFF
k
Lp wowowpw
w2)2(
2)2()2(
2
222
2 ])[( f
(1) (2) (2) (2)1 21 2[( 1) 1] [( ) ] 0ww wp wp wo wo
dx dxF F x F F x F
dt dt
![Page 67: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/67.jpg)
67
Second equation for the penetration
depths
t
LxsxsQdt0 222111 )(' ff
t
ss xrrxrrdttq0 1
)2()2(1
)1()1(')'( ff
S
srr
SL
tQtq ii
sii
)()(
,,)(
)(f
f
ff
t
ss xrrxrrdttq0 1
)1()1(1
)1()1()1)(2(')'( ff
1 2 1 2; 2S s s f f f
![Page 68: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/68.jpg)
68
1D radial flow of polymer
• Basic assumptions Homogeneous and isotropic porous media Incompressible, non-inertial and isothermal flow Darcy’s flow equation
• Feature polymer injection in the field
Layer
adsorptionFree
polymer
coil
Grains of sand
or silicon carbide
WATER
![Page 69: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/69.jpg)
69
Governing equations
tssrt ACuC ff 1
dat C
Pu r
Mass conservation:
Adsorption kinetics:
Darcy’s law
0 rur
![Page 70: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/70.jpg)
70
Boundary conditions
wrrrC ,00,
eewfw PtrPtPtrP ,;,
0;,0 0 tCtC
wrrr ;00,
![Page 71: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/71.jpg)
71
Integration of first equation
hQurconstruwrrw 2.
hrQru 2
PhrQ
C
AChrQC
r
dat
tssrt
ff
2
12
![Page 72: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/72.jpg)
72
Instantaneous adsorption
CC
ChrQCF
eee
rtR
f
1
02
trC ,
r
0C
trfwr
rtrHCtrC f 0,
2/12 hQtrtr wf f
Solution:
![Page 73: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/73.jpg)
73
Relative viscosity and
permeability rduction
r
x
0r
trf
22
001 CkCCr kR
x
0kR
trf
41
pk rR
![Page 74: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/74.jpg)
74
Pressure drop
e
w
r
rrkwwew drrRhkQtrPtrPtP 12,,
wewww rrLnhkQP 2
wewfrkw rrLnrrLnRPtP 11
![Page 75: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/75.jpg)
75
Pressure drop graphs
tP
t
wP
First polymerentry in PM
![Page 76: Dynamics of polymers in porous mediagrigori.impa.br/site/arquivos/IPO/Polymer course at Juiz de Fora.pdf · (b) polymer transport in porous media and (c) the effect polymer adsorption](https://reader033.fdocuments.in/reader033/viewer/2022060208/5f0412967e708231d40c2ef1/html5/thumbnails/76.jpg)
76
Polymer injection into a two-layer
reservoir
Penetration radii: r1 and r2 respectively
Pose: =Re/Rw, x1=r1/Rw and x2=r2/Rw.
)ln(2
1)1(
1
11 x
h
qpp
p
w
11 1(1)
1
ln( / )2
e
w
qp p x
h
q1 is the flow rate, and p(1)=k1p/1p and w(1)=k1w/1w
the mobilities of polymer and water respectively. The pressure drop over the reservoir: p1(t)=pw -pe
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77
Semi-steady state flow, Pressure
drawdown, Productivity Index
Fwp(1) = w
(1)/ p(1) is the water-to-polymer mobility ratio
)]/ln()ln()1[(2
)( 11)1(
)1(1
11 xxF
h
qtp wp
w
dt
dxxRhq w
11
2111 2 f
)1(
21
1
w
wRC
f
dt
dxxFxCtp wp
11
)1(111 )]ln()ln()1[()(
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78
Polymer/gelant placement in a two-
layer reservoir
Fwp(1) = w
(1)/ p(1) is the water-to-polymer mobility ratio
dt
dxFxFFxCtp wowowp
2)2(2
)2()2(222 )]ln()ln()[()(
)2(2
22
wwRC
f
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79
Polymer/gelant placement in a two-
layer reservoir
Fww = w(1)/ w
(2) is the mobility between the two layers
(1) (2) (2) (2)1 21 1 2 21 ln( ) ln( ) ln( ) ln( )ww wp wp wo wo
dx dxF x F x x F F x F
dt dt
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80
Polymer/gelant placement in a two-
layer reservoir
Q(t) = the total flow rate
])1()1([')'(0
2
222
2
111
2
t
w xhxhRdttQ ff
( ) ( )
1 22
( )( ) , , 2i ii i
h
w
hQ tq t r r
R H Hf
ff f f
f
(1) (1) 2 (1) (1) 2
1 20
( ') ' ( 1) (2 )(1 )( 1)t
h hq t dt r r x r r xf f
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81
Semi-steady state flow, Pressure
drawdown, Productivity Index
Q(t) = the total flow rate
])1()1([')'(0
2
222
2
111
2
t
w xhxhRdttQ ff
( ) ( )
1 22
( )( ) , , 2i ii i
h
w
hQ tq t r r
R H Hf
ff f f
f
(1) (1) 2 (1) (1) 2
1 20
( ') ' ( 1) (2 )(1 )( 1)t
h hq t dt r r x r r xf f
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82
Polymer/gelant placement in a two-
layer reservoir
2 (1)
1 2 1 1
2 (2) (2)
2 2
, { [( 1) ln( ) ] }
{ [( ) ln( ) ] }
ww wp wp wp
wp wo op op
x x F x F x
x F F x
ln2
1)1(
wp
wp
F
ln2
)2()2()2(
wowowp
op FFF
(1) (1) 2 (1) (1) 2
1 2( 1) (2 )(1 )( 1)h hqt r r x r r xf f
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83
Semi-steady state flow, Pressure
drawdown, Productivity Index
0)}ln()ln(])({[
)}ln()ln(]1)({[
22)2(
2)2(
2)2(
1111)1(
uxFxFuF
uxxuFF
wowowp
wpww
211
111
21
42
1
wRh
qux
dt
dx
f
222
222
22
42
1
wRh
qux
dt
dx
f
2
)2()2(
1
)1()1()1)(2( urrurrq hh ff
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84
Semi-steady state flow, Pressure
drawdown, Productivity Index
tuxxk
ik
ik
i 11
0
)}ln()ln(])({[
)}ln()ln(]1)({[
21)2(
2)2(
2)2(
1111)1(
kkwo
kwo
kwp
kkkkwpww
uxFxFuF
uxxuFF
])1)(2([222
)2()2(11
)1()1( kkh
kkh uxrruxrrq ff
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85
Polymer/gelant placement in a two-
layer reservoir
TABLE I: COMPUTATION SCHEME
STEP TIME x1 x2 u1 u2
0 0 x10=0 x2
0=0 u10 u2
0
1 t x11= t u1
0 x21= t u2
0 u11 u2
1
2 2t x12=x1
1 t u11 x2
2=x21 t u2
1 u12 u2
2
k k t x1k=x1
k-1 t u1k-1 x2
k=x2k-1 t u2
k-1 u1k u2
k
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86
APPLICATIONS: WATER CONTROL USING
POLYMERS OR GELS. POLYMER
FLOODING
Lecture 3
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87
Course contents
The Causes of Excessive Water ProductionWell Related Causes Mechanisms Reservoir Related MechanismsExercise 3: Prediction of Water Cut from a Model Reservoir
Identification the Water Production Mechanism in the Field Data Gathering and Analysis Role of the Information about the GeologyMultiple-Scenario Diagnosis of Water sourceExercise 4: Identify the Water Production Mechanism for a Given Case
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88
A oil or gas well is producing at a
very high water cut!
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89
Fracturing
Impermeable
Barrier
Natural
or Created
Fractures
Viscous
Fingering
Permeability
Contrast
Water production during oil
recovery
(Courtesy of Halliburton)
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90
LOW kOIL or GAS
HIGH k WATER
Oil or Gas WATER CUT = 14.3 %Water
Higher oil rates during primary
secondary recovery
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91
After sometime water cut increases
rapidly and oil cut decreases
LOW kOIL or GAS
HIGH k WATER
WATER CUT = 80 %Oil or Gas Water
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92
The water cycle: opportunities and
challenges
27%
29%15%
29%
Shell Water Usage Options (1999)
Discharge to Sea
Re-injection for pressuremaintenance
Discharge to sweet water
Re-injection for disposal
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93
Statistics of Water Production
• 70% production from mature fields (over 30 years production)
• Ratio of water to total production (water-cut) > 75% on
average (> 3 bbl/d water for 1 bbl/d oil)
• Average water cost $0.67/bbl ($0.17 to $2.50/bbl in U.S.)
• Cost component: lifting, pumping, separation, de-oiling,
filtering, and re-injecting
• Environmental aspects, disposing off the water
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94
Produced Water Management
• Reduction of water
production (WATER SHUTOFF)
• Cement squeeze
• Mechanical methods (zone
isolation)
• Chemical water shutoff
(CWSO)
• Produced water
separation and re-injection
• Downhole dehydration and
produced water re-injection
• Surface separation and
produced water re-
reinjection (PWRI)
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95
Surface treatment of oily water
•Plate separation
•Hydrocyclone
separation
•Gas flotation
•Oil coalescence
•Centrifugation
•Membrane filtration
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96
Downhole separation and water
reinjection
• Separating water down-
hole reduces the cost of
lifting the excess water.
• Typical down-hole
separators are 50% efficient
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97
Down-hole separation system
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98
Produced Water Re-Injection
• Oil-water mixture exiting from a two-
dimensional micro-model
• Factors affecting separation efficiency and
re-injection
• Fluid production rates
• Droplet size distribution of the
dispersed phases
• the gas/liquid/oil ratios
• Phase densities and viscosities
• Interfacial tension
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99
Re-injection of produced water
• Matrix injection Injection pressure is below fracturing pressure
• Fractured injectionInjection pressure is above fracturing pressure
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100
Advantages of Reducing Water
Production
• Reduction of oil pumping costs (average cost
$0.67/bbl - $0.17 to $2.50/bbl in U.S.)
• Reduction of oil and water separation costs
• Reduction of equipment and platform space required
• Reduction of scaling, sand production, corrosion
problems and related costs
• Reduction of risk of adverse impact on the
environment
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101
Benefits of Reducing Produced
Water
• Increases oil and gas production rates by reducing
hydrostatic column in the well and reducing bottom-
hole pressure
• Improve reservoir sweep efficiency
• Reduces formation damage due to scaling sand
production
• Extends the economic life of the reservoir and
ultimate recovery
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102
Methods to reduce water cut
• Cement, sand plugs, calcium carbonate
• Packers, bridge plugs, mechanical patches
• Pattern flow control
• In fill drilling/well abandonment
• Horizontal wells
• Resins
• Foams, emulsions, particulates, precipitates, microorganisms
• Polymers and Polymer gels, Oil soluble chemicals
• Polymers flooding, Smart water flooding
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103
Pressures in a production system
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104
Well completion is critical
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105
Well completion critical
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106
Different pumping systems
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107
Different pumping systems
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108
Semi-steady state flow, Pressure
drawdown, Productivity Index
wfP P P Pressure draw down: [psi]
QPI
P
Productivity Index: [psi/d/psi]
141.2 ln e
w
PkhQ
rB
r
[stb/d]Flow rate:
Field Units
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109
Single phase
Liquid flow
Bubbly
flow
Slug
flow
Churn
flow
Annular
flowHomogeneous
flow
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110
Categories of water-cut problems
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111
Difficulty of water-cut problems
• Category A (Problems 1-3): easier to treat than the others in
the list. Therefore, one should look first for these types of
problems.
• Category D, (Problems 11-13): difficult, no easy, low-cost
solution. Gel treatments will almost never work for these
problems.
• Categories B and C (Problems 4-10): result from linear-flow
features (e.g. fractures, fracture-like structures, narrow
channels behind pipe, or vug pathways.
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112
Data gathering for water production
diagnostics
• Analysis of well production data like rates, GOR, watercut, THP,
THT, deposits, sampling.
• Analysis of BHP surveys, production logging, PI surveys, PVT
samples
• Monitoring mechanical well status (sand, corrosion, wax, scale)
• Well stimulation.
Lack of data is often a problem for diagnosing high water-cut problems. Proper well surveillance, well performance analysis
helps solve this problem.
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113
Reservoir Surveillance &
Performance
• GOR, BSW behaviour, movements of GOC,
OWC, displacement anomalies.
• Analysis of vertical and horizontal drainage
• Analysis of reservoir drive mechanism.
• Reservoir simulation model
• Reassessment of STOIIP, GIIP, reserves.
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114
Polymers for water control
POLYMERS
PAM/HPAM Zaitoun et al.
polymer adsorption (k reduction)
temperature limit 70 0C
sensitive to reservoir pH and salinity
little enviromental issues
CPAM
Burrafato et al.
Mota et al.
Zaitoun et al.
Zitha et al.
stronger polymer adsorption (k
reduction)
temperature limit 70 0C
sensitive to reservoir pH and salinity
little enviromental issues
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115
Polyacrylamide and hydrolyzed
polyacrylamide
.
yCH2 CH .
CO
.
NH2PAM
CH2 CH
C O
NH2
CH CH
C
OH
O
MN
2CH2 CH
C O
NH2
CH CH
C
OH
O
MN
2Degree of hydrolysis is = N/(N+M). High Mw polymers: N+M=105-107
Random monomer distribution
HPAM
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116
05.0 yx
x
CH2 CH .
CO
CH2 CH.
CO
O
CCH3 CH3
CH3
NH2
x y
PAtBA
.
yCH2 CH .
CO
.
NH2PAM
PAtBA and PAM
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117
Metal ion cross-linker
Oligomers
ColloidalPrecipitate
C
C
C
COOHH
H
H2
2
O COOH
COOH
Citrate
Chromium in water
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118
Cross-linking of polymer gels
Semi-dilute polymer(e.g. HPAM, PTBA), C >> C* Cross-linked gel
Cross-linker (e.g. Cr(III), PEI)
+
Cross-linked polymer gel
Cross-linker (e.g. Cr(III), PEI, etc.) Gelation times times can be minutes to days
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119
Viscosity diverges at gel point
• Polyethyleneimine (PEI) is an
Organic Crosslinker
• PEI was nnown to crosslink
Polyacrylamide Copolymers
• Recent Work Indicated that
Simple Polyacrylamides Can Be
Crosslinked with PEI
0
4
8
12
16
20
0 20 40 60 80 100 120
Time, minutesV
isco
sit
y,
Pa
.s
PAtBA
PAM
7 wt% Polymer
1 wt% PEI
120oC
15,000 ppm Na
20.7 Bars
17.03 1/s
pH = 10.0
(Al-Muntasheri et al., SPE 104071, 2006)
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Cross-linked polymer gels
Chemical References Features HPAM-Cr
3+ Sydansk et al.
Sright et al.
Lockhart et al.
etc.
weak and strong gels
temperature limit 70-90 0C
sensitive to reservoir pH and salinity
enviromental issues due to Cr3+
HPAM-Zr2+
(lactate)
Cui, Xia and Xu,
Moradi et al.
Bagassi et al.
weak and strong gels
temperature limit 70-90 0C
sensitive to salinity, reservoir
conditions
enviromental issues due to chromium
PAM-HMTA
(phenyl-acetate)
Moradi et al. encapsulates
temperature limit 120 0C
lower sensitive to salinity, reservoir
conditions
lesser enviromental issues but toxicity
PATBA-PEI
Hardy et al. strong gels
temperature limit 120-150 0C
low sensitive to lithology reservoir
conditions
lesser enviromental issues
Oil soluble gelants Plazanet et al.
Thompson and
Folgler
strong or weak gels ???
temperature limit ???
sensitivity to reservoir pH, salinity ???
enviromental issues ???
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Organically cross-linked polymer
gels
• t-butyacrylate/acrylamide (PTBA) copolymer-Polyethyleneimine
(PEI) (H2Zero)
• PAM and co- and terpolymers with HCHO, HMTA or
phenolic/hydroquinone crosslinkers (Phillips and Unocal
processes, Organoseal, Multigel)
• Crosslinked AMPS, NVP, acrylamide/acrylate co and terpolymers
(HE)
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Chemical placement is a major issue
• Placement methods
• Zone isolation (using packers, plugs, etc.)
• Dual fluid injection (oil compatible and
polymer)
• Bullhead treatments (poorly known reservoir
properties, deviated and horizontal wells, etc.)
• Difficulty with bullhead treatments: risk
of penetration in oil layers
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Options for chemical placement
Method References Features Zonal isolation
(Strong and weak
gels)
Seright et al. ok for clearly layered systems without
cross-flow
relies on detailed knowledge of
reservoir geology
impractical in many wells
Self-diversion or
diversion
Stavland et al.
Zaitoun et al.
Zitha et al.
combine adsorption and rheology
(bridging adsorption phenomenon)
relies on (strong) permeability contrast
probably inefficient if there is
crossflow
Diversion with a
viscous preflsuh
Stavland et al.
Vermolen et al.
experimental evidence is scarce
Self-selectivity
(selectivity of the
basis of saturation)
Stavland et al.
Zimmerman et al.
Zitha et al.
relies on saturation differences
low permeability contrast is not a
limitation
perhaps not efficient when cross-flow
is strong.
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Water control/shutoff mechanisms
Type References Features (Full ??) Blocking
(strong gels)
Willhite et al.
Seright et al.
Stavland et al.
Lockhart et al
how full is full?
gel/longevity of blocking
Disproportionate
permeability
reduction (weak
gels, polymers)
Schneider and
Owens
sometimes it works: we just don't
know exactly when!!!
Self-diversion or
diversion
(polymers, weak
and strong gels)
Stavland et al.
Zaitoun et al.
Zitha et al.
combine adsorption and rheology
(bridging adsorption phenomenon)
relies on (strong) permeability contrast
probably inefficient if there is
crossflow
Diversion with a
viscous preflsuh
(???)
Stavland et al.
Vermolen et al.
experimental evidence is scarce
k reduction in the
presence of water
(not a classic
DPR!)
Stavland et al.
Zimmerman et al.
Zitha et al.
how does it work at intermediate
oil/water saturations?
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Cross-linked polymer gels fill/block
the pores
Sand grains
Gelled water
Cross-linked polymer
Oil blob isolated by gel
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Water shuttoff cross-linked polymer
gels
• Water shutoff technology:
• Inject a limited amount of chemicals
(cement, polymers, polymer gels, etc.)
• Chemicals reduce water flow but not oil
flow
• Tow main issues:
• Placement of chemicals (porous media
flow)
• Water flow reduction mechanism
(relative permeability, full blocking)
GRAINS GEL
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Gels fill the pore and block flow
Gel has very low intrinsic permeability.
Grain
Pore
throat
2RP2(RP-eH)
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Matrix versus well high water-cut
Leakage behind the casing
Channeling through high permeability layers
Oil
Water
Water Oil
Water
Water
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Principle of a water-shutoff
treatment
• Injection of limited amount of
polymer solution or gelant
• Polymer adsorption, partial or
full blokking by gel
• Disproportionate permeability
reduction by the polymer or gel
LOW kOIL/GAS
HIGH k
SMALL DEPTH/NO GELIN OIL OR GAS LAYER
WATER
CHEMICAL
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Polymer and gelant penetrate all layers!
LOW kOIL or GAS
HIGH k
Problem: penetration in oil or gas layers
Bull head treatments: penetration of polymer or gelantinto oil layers must be minimized
WATER
Polymer/Gelant
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Bullhead water shutoff treatments
Polymer or Gel
LOW kOIL or GAS
HIGH k
Polymer or gel treatment: results in higher oil cuts.
WATER
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How to size the treatment?
LOW kOIL or GAS
HIGH k WATER
Wellbore
h2
h1
hs
Re
Rw
k1, f1,As(1)
k2, f2,As(2)
Shale
Layer 2
Layer 1
PolymerGelant
Production packer
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Penetration radius (single layer)
ttQShtr or )(1)( 1
2
1 fVolume conservation:
)(1 tr [ft]
1h [ft]f [-]
orS [ - ])(tQ [bbl/min]
Penetration radius
Reservoir height
Porosity Residual oil saturation
Injection rate t [hour]Time
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Penetration radius (single layer)
0
5
10
15
20
25
30
0 2 4 6 8 10 12 14
TIME (hour)
RA
DIU
S (
ft)
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Steady-state flow analysis
• Homogeneous and isotropic porous media
• Incompressible, non-inertial and isothermal
• Dispersion is negligible
• Instantaneous layer adsorption
• No desorption after bridging adsorption
• Steady state Darcy’s flow with RRF=RRF(t)
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Semi-steady state flow, Pressure
drawdown, Productivity Index
wfP P P Pressure draw down: [psi]
QPI
P
Productivity Index: [psi/d/psi]
141.2 ln e
w
PkhQ
rB
r
[stb/d]Flow rate:
Field Units
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Exercise 1,2 : Water Production
Economics
• Consider a two layer reservoir with consisting of two layers L1
and L2 separated by an impermeable shale layer with thickness
Ls. Geophysical and geological data show that the reservoir is
bound by two sealing faults at a distance d = 1850 m and has
an average width w = 810 meters.
• The (average) properties of L1 and L2 are:
• L1: k1 = 250 mD, f1 = 0.22, h1 =10 m, Swi = 0.28
• L2: k2 = 1580 mD, f2 = 0.23, h2 = 45 m, Swi = 0.32
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Exercise 1,2 : Water Production
Economics
• Static reservoir pressure and temperature are: P = 1230 psi
and = 160 0F.
• Properties of the fluids in the reservoir at reservoir conditions
(for both layers):
• Oil: o = 8.53 cP, o = 0.70 g/cm3, co =1.34 1/bar
• Water: w = 1.00 cP, w = 1.00 g/cm3, cw = 0.86 1/bar
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Exercise 1,2 : Water Production
Economics
• Two identical wells are drilled in the reservoir at a distance of
234 m. One of the wells (IW) is used as an injector and the
second well (PW) is used as a producer.
• Well radius: 7 inch
• FBHP: 890 psi
• Compute the production history
• Compute the NPV for two scenarios:
• No water-control treatment
• Water treatment
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Penetration radius (single layer)
Problem 1 : Consider the reservoir in the exercises 1,2. The high permeability layer totally watered out with Sor = 35%. We plan to carry out a gel treatment. A gelant with viscosity 10 cP gel time is 5 hours is used in this job.1) How much gelant is it needed to reach the target radius of 10 ft?2) At what rate must should the gelant bbe injected to reach the target radius of 10 ft at ½ of the gel time?3) Can this rate be sustained without fracturing the reservoir?
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Excess Water Production
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Flow-chart
Mahgoub, Mahmoud,
Abu El Ela, O&GJ,
105 (7), Feb 19, 2007
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Water-cut increases rapidly
Mahgoub, Mahmoud, Abu El Ela, O&GJ, 105 (7), Feb 19, 2007
Bridge plug
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Successful water-shutoff treatment:
general information
• A well in Kahraman-C41 field
• Field is in NW of Khalda concession, N part of Egypt’s western.
• Field discovery well, Kahraman-C2, was drilled in 1992.
• Field currently has 60 oil producers and 18 water-injectors
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Field location
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Successful water-shutoff treatment:
general information
• Kahraman-C mainly produces from Bahariya reservoirs,
laminated sandstone, two main horizons:
• Lower Bahariya (LBAH): main producing interval, good
quality sand, permeability up to 400 mD and porosity up to
24%, provides ~70% of the field’s total production.
• Upper Bahariya (UBAH): lower quality rock, thin sand
streaks inter-bedded with shale and carbonate barriers,
zone being developed with hydraulic fracturing (like most
other fields in the Khalda concession)
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Successful water-shutoff:
petrophysics, testing
• The Bahariya reservoirs lie at about -5,700 ft subsea.
• Well Kahraman-C41 drilled in February 2005 as part of the
integrated development plan of both the upper and lower Bahariya
West of Kahraman-C field.
• Petrophysical analysis: 41 ft [12.5 m] of good quality pay with f =
23% and Sw = 40% on average
• The LBAH as good as the producing LBAH that produces west of
Kahraman-C field. No repeat formation tester (RFT), however, at
almost the same drilling time, but RFT was run in offset Kahraman-
C46 well, 560-m away.
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Successful water-shutoff treatment:
lift testing
• The Kahraman-C46 RFT: pressure of 970 psi in the main producing sand, 1500 psi in the wet sand right below the main producing sand and 2600 psi in the wet sand further downhole.
• The initial LBAH intervals perforated in Kahraman-C41 were at 6,540-6,554 and 6,566-6,590. The test of the intervals with nitrogen lift produced all water at 960 b/d. The water had a 78,500-ppm chloride content, which is the same as in Bahariya water.
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Successful water-shutoff treatment:
diagnosis
• Review of the cement-bond log-variable density (CBL-VDL) log showed bad cement behind the casing with almost free pipe.This indicated that cross flow from the high-pressure wet sand into the low-pressure oil zone through the channels behind the casing may be causing the water problem.
• To remedy the problem, the operator performed a cement squeeze with 17.5 bbl of cement through the perforated intervals. After drilling out the cement and cleaning the hole, the operator re-perforated the LBAH intervals 6,540-6,554 and 6,566-6,580.
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Post-treatment testing
• The test of the well with nitrogen lift again produced 100%
water at 222 b/d. The water contained 79,900 ppm chlorides.
• A new CBL-VDL showed some cement improvement against the
LBAH compared to the original CBL-VDL that showed almost
free pipe.
• The offset well in the same reservoir, 560-m away, produced
oil with a low water cut, about 5%.
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Refine diagnosis
• Based on this information, the conclusion was that water cross flowed from the high-pressure wet sand to the low-pressure oil zone through the channels behind the casing after the initial perforation of the LBAH and during the first test. During that period, water had moved from the wet sand into the oil zone because of the high-pressure difference. This resulted in the 100% water cut during the second test after the cement squeeze job.
• The cement squeeze job appeared successful, as indicated by the drop in production between the two tests, 950 b/d in the first and 222 b/d in the second.
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Problem solved: diagnosis confirmed:
• The operator decided to complete the well and run an electric
submersible pump (FC-450) that could handle up to 500 b/d
and remove the water that had crossed flow into the oil zone.
This proved to be the right decision because a test 6 days later
produced 385 b/d of fluid with a 8% water cut or 354 bo/d.
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Well producing at low water cut
Mahgoub, Mahmoud, Abu El Ela, O&GJ, 105 (7), Feb 19, 2007
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POLYMER FLOODING. TWO-PHASE POLYMER-
OIL DISPLACEMENTS
Lecture 3
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Hydrolyzed Polyacrylamide in Porous Media
• Polymer rheology: Polymer solutions
are non-Newtonian fluids.
• Polymer adsorption and
permeability reduction: Adsorbed
polymer chains form a layer, which leads
to a steady-state permeability reduction.
• Inaccessible pore volume: This
causes the polymer molecules to
travel faster through the porous
medium than inert tracer molecules.
• Physical dispersion: This smears
the interface between polymer and
brine.
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Tambaredjo oilfield
• Field location: district of Saramacca, 45 kilometers west of the capital Paramaribo.
• Production is by primary recovery.
• The field has over 900 wells with a spacing of 200 meter.
• STOIIP (proven as per 2005) = 633 MMSTB.
• Ultimate recoverable reserves (proven as per 2005) = 65 MMSTB.
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Tambaredjo oilfield
• Production comes from shallow unconsolidated sands (T-sands of Paleocene age).
• The sands are fluvial estuarine to coastal marine of origin.
• Reservoir is charged by Canje source rock.
• Shale forms the seal at the top, while to the south sands pinch out up dip
providing stratigraphic traps for oil.
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Pilot Sector
• Reservoir properties (porosity, permeability
and water saturation) were determined from
multi-well petrophysical analysis.
• The model consists of 68, 54 and 16 cells in
respectively x, y and z direction, with a grid
size of 25 x 25 x 1 meter.
• The sector model is a relatively small part of
the overall reservoir model.
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Model_ control volume
• The net pay zone of the reservoir was delimited based on the permeability and oil
saturation of the layers.
• A control volume was defined for which the oil in place was calculated
Perm. (mD) So
layer 2 225 0,18
layer 3 825 0,26
layer 4 1387 0,38
layer 5 2447 0,40
layer 6 3529 0,42
layer 7 1380 0,35
layer 8 2532 0,46
layer 9 4070 0,50
layer 10 6117 0,53
layer 11 5203 0,48
layer 12 301 0,20
Dx=Dy 25 m
Dz 1 m
Top reservoir 288 m
#Cells x 15
#Cells y 9
#Cells z 9
Porosity 0.34
Area 0.84×105 m2
BRV 7.59×105 m3
PV 2.58×105 m3
STOIIP 9.77×105 stb
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Model_ reservoir fluids and rock-fluid properties
•The oil and water viscosity are respectively 240 cP
and 0.7 cP (at reservoir temperature of 36°C).
•PVT data for this area were scarce due to technical
difficulties in obtaining appropriate downhole
samples.
•The reservoir is water-wet.
0
0,2
0,4
0,6
0,8
1
0 0,2 0,4 0,6 0,8 1
kr
Sw
Water
Oil
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161
Model_ polymer flow modeling: polymer viscosity
•Based on the flow velocity of polymer in the reservoir, an in-situ shear rate of 7s-1
was estimated. This was asserted on the rheological measurement of the polymer
for describing the polymer solution viscosity during numerical modeling.
0
10
20
30
40
50
60
0 200 400 600 800 1000
Po
lym
er
vis
co
sity (
cP
)
Polymer concentration (ppm)
Polymer viscosity (in-situ)
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Model_ polymer flow modeling: polymer adsorption
•Adsorption of polymer was found to be 2×10-5 gram of polymer/gram of rock at a
polymer concentration of 1000 ppm.
•An adsorption isotherm was created by scaling data published by Zitha et al., 2002
for layer adsorption.
0,0E+00
5,0E-06
1,0E-05
1,5E-05
2,0E-05
2,5E-05
3,0E-05
0 500 1000 1500 2000
Ad
so
rptio
n le
ve
l (g
/g)
Polymer concentration (ppm)
Adsorption isotherm
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163
Model_ polymer flow modeling:
permeability reduction and inaccessible pore volume
Permeability reduction
•The permeability reduction (Rk) was modeled as a function of polymer
concentration.
•Rk varies between one and the residual resistance factor (RRF). Likely levels of RFF
between 2 and 5 are reported.
Inaccessible pore volume
•The irreducible water saturation is used as an estimate for this.
max1 1
ap
k ap
CR RRF
C
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Numerical details
•The numerical modeling and simulation was done using the Eclipse100 (2009.1)
software from Schlumberger.
•It includes the relevant polymer flooding mechanisms.
1w p a rw
r p w w z p w p
r w w peff k
V S C Tkd dV C P gD C Q C
dt B B dt B R
f
f
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Numerical details (2)
•The model aims to capture both the effects of polymer concentration and physical
dispersion on polymer viscosity.
•An arbitrary parameter is used for this, which describes the degree of mixing
between polymer solution and brine at the leading edge of the slug.
•This parameter varies between 0 and 1 respectively describing zero and complete
mixing between polymer solution and brine within a grid block.
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Results_ overview
1-D results
3-D results
• Forward simulation of primary recovery
• Polymer flooding simulations
• Fluid distribution
• Dispersion
• Production data
• Incremental oil recovery
• Sensitivity analysis
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1D polymer flooding
One dimensional analysis has been done for:
• Validating the numerical model
• Verifying the consistency of results
0
0,2
0,4
0,6
0,8
0 0,2 0,4 0,6 0,8 1
Sw
X
Saturation profiles for polymer flooding
0.1 PV
0.3 PV
0.5 PV
numerical
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Comparison between numerical and analytic results (2)
0
0,2
0,4
0,6
0,8
0 0,2 0,4 0,6 0,8 1
Sw
X
Saturation profile for water flooding (at 0.08 PV)
analytic
numerical
0
0,2
0,4
0,6
0,8
0 0,2 0,4 0,6 0,8 1
RF
PV
Oil recovery
polymerflooding
waterflooding
numerical
• The comparison shows a good to excellent match between both results, which validates the
use of the numerical model.
The numerical model can be used in the future for matching with experiments.
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Results 3-D
•The history match of primary recovery was done earlier by Staatsolie (Falla et al., 2010)
using the oil production as a constraint.
•We just did one forward simulation of primary recovery to confirm that the results are
consistent.
0,E+00
1,E+06
2,E+06
3,E+06
4,E+06
jul-90 apr-93 jan-96 okt-98 jul-01 apr-04 jan-07
Oil
pro
du
ctio
n (
stb
)
Time
History match total oil production
Simulated
Measured
0,E+00
1,E+06
2,E+06
jul-90 apr-93 jan-96 okt-98 jul-01 apr-04 jan-07
Wate
r pro
duction (
stb
)
Time
History match total water production
Simulated
Measured
Forward simulation of primary recovery
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Forward simulation of primary recovery (2)
• The match for oil production is very good. But the minor mismatch in the
production of water is believed to be due to uncertainties about the static model,
PVT data and reservoir drive mechanisms.
• The oil is seemingly produced by a combination of several drive mechanisms,
including water influx, solution gas drive, rock compaction and oil expansion
0
0,2
0,4
0,6
0,8
1
jul-90 apr-93 jan-96 okt-98 jul-01 apr-04 jan-07
Fra
ction o
f oil
pro
duction
Time
Drive mechanisms during primary recovery
Oil expansion
Rock compaction
Solution gas drive
Water influx
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171
Polymer flooding simulations
• For the numerical simulations injection starts on the starting date of the pilot test,
12 September 2008.
• The polymer is injected at a concentration of 1000 ppm and at a fixed bottom-hole
pressure (BHP) of 800 psi.
• The polymer was only injected in the bottom part of the reservoir.
Polymer injection
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172
Polymer flooding simulations
• First the results of a base case polymer flood are presented.
• Then the sensitivity to the physical parameters is described.
• An overview of these cases is shown below.
Polymer injection
Base case
Case1 Case2 Case3 Case4
Adsorption Yes Yes No Yes Yes
RRF 2.00 2.00 1.00 3.00 2.00
IPV 0.28 0.28 0.28 0.28 0.10
Mixing parameter
0.33 0.66 0.33 0.33 0.33
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Fluid distribution_ cross sectional profile
Polymer injection
•Polymer concentration profile between injector and producer at 2008 (top-left), 2011 (top-right), 2013 (bottom-left) and 2015 (bottom-right). •Polymer breaks through in 2013 at 1M051
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Fluid distribution
• Areal distribution of polymer, at 2013 (top-left) and 2017 (top-right), together with areal distribution of oil at 2008 (bottom-left) and 2017 (bottom-right). • Polymer propagates in a front like manner.• At 1M10 breakthrough occurs in 2017 • There is only residual oil in the swept area.
Polymer
injection
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Dispersion
•In order to describe the effects of both
numerical and physical dispersion, we
zoom in on the polymer front.
•The absence of a sharp front is mainly
the effect of numerical dispersion
caused by the large grid blocks in the
model.
•The effect of physical dispersion is
relatively small.
•Numerical dispersion leads to lower
mobility control and earlier arrival of
polymer at the production wells.
0
200
400
600
800
1000
0,00 0,33 0,67 1,00Po
lym
er
co
nce
ntr
aio
n (
pp
m)
Distance between 1M101 and 1M051 (-)
Effect of dispersion on polymer front
mix=1/3
mix=2/3
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176
Production data
• Polymer breakthrough times as
expected.
• Well 1M051, first increase in water-
cut due to oil bank breakthrough.
The second jump corresponds to
polymer breakthrough.
• Well 1M10 shows similar behavior.
• 1M09 the oil production is highest,
since this well produces the largest
oil bank.
• Well 1N06 is shut-in at 2017,
because pressure was low to
produce at required bottom-hole
pressure
0
0,2
0,4
0,6
0,8
1
0
5
10
15
2008 2012 2016 2020 2024 2027
Wate
r C
ut
+ C
/Co
Oil
rate
(stb
/day)
Time
1M051Oil rate
WatercutC/Co
0
0,2
0,4
0,6
0,8
1
0
5
10
15
2008 2012 2016 2020 2024 2027
Wate
r C
ut
+ C
/Co
Oil
rate
(stb
/day)
Time
1M10
Oilrate
Watercut
0
0,2
0,4
0,6
0,8
1
0
5
10
15
2008 2012 2016 2020 2024 2027
Wate
r C
ut
+ C
/Co
Oil
rate
(stb
/day)
Time
1M09
Oil rate
WatercutC/Co
0
0,2
0,4
0,6
0,8
1
0
5
10
15
2008 2012 2016 2020 2024 2027
Wate
r C
ut
+ C
/Co
Oil
rate
(stb
/da
y)
Time
1N06OilrateWatercutC/Co
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Monitoring production data
• Breakthrough of polymer was measured within one year after start of injection.
• Clay tests were used for the measurement of polymer concentration at the
producers. However, it is mostly qualitative and cannot be used for accurate
estimates of polymer concentration.
• Only later this year, Staatsolie could get actual values of polymer concentration
using this test.
• The large difference in breakthrough time (measured and simulated) is due to
uncertainties in the reservoir and the polymer flow models.
Polymer injection
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Incremental oil recovery
• These recovery factors for PF, WF and NFA
are respectively 40%, 37% and 32%. The
incremental recovery is therefore respectively
8% and 3%.
• The displaced oil fraction describes the oil
recovery for the control volume only. This is
respectively 34%, 28% and 22%.
• There exists a discrepancy between them.
The recovery factor is higher than the displaced
oil, which means that the control volume does
not only contribute to the oil production.
0,00
0,05
0,10
0,15
0,20
0,25
0,30
0,35
0,40
0,45
jul-90 jul-94 jul-98 jul-02 jul-06 jul-10 jul-14 jul-18 jul-22 jul-26
Recovery
facto
r
Time
Incremental oil recovery
Polymerflooding
Water flooding
0,00
0,05
0,10
0,15
0,20
0,25
0,30
0,35
0,40
0,45
jul-90 jul-94 jul-98 jul-02 jul-06 jul-10 jul-14 jul-18 jul-22 jul-26
Dis
pla
ced o
il fr
action
Time
Incremental displaced oil
Polymerflooding
Water flooding
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Incremental oil (2)
• Until the start of both floods the displaced oil is half of the recovered oil, meaning that
the control volume only contributes to half of the total oil production.
• Considering the polymer flood
From 2008 till 2017 the oil recovery is 8%, while the displaced oil fraction is 10%.
If we consider the control volume only, then the oil recovery is roughly half of the
displaced oil.
From 2017 till 2030 the oil recovery is 3%, while the displaced oil fraction is 9%.
Therefore after 2017 even more oil will be swept out of the control volume rather
than produced, hence the pilot efficiency diminishes.
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Incremental oil (3)
• If the incremental oil cannot offset the
extra costs for polymer flooding, water
flooding could be an alternative to
polymer flooding.
• With polymer flooding there is some
potential for increase in the incremental
oil, since only part of the swept oil is
produced.
• An extra case with three additional
wells was simulated for this. Here the
overall recovery factor increased with
3%, while the incremental oil recovery
increased with 1%.
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181
Sensitivity analysis
• Considering the physics of polymer displacement, the breakthrough times are as
expected.
• The recovery factor on the other hand is only slightly affected by changes in
polymer adsorption and residual resistance factor.
Polymer injection
Polymer breakthrough
1M051 1M10 1M09 1N06 Recovery factor
Base case 2013 2017 - - 0.40
Case 1 (mixing parameter=0.66)
2011 2014 - - 0.40
Case 2 (No adsorption) 2010 2012 2021 - 0.42
Case 3 (RRF=3) 2016 2022 - - 0.39
Case 4 (IPV=0.1) 2014 2019 - - 0.40
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Summary
• The numerical model for simulating polymer flooding is robust.
• Numerical dispersion leads to lower mobility control and earlier arrival of polymer
at the production wells.
• The large difference in breakthrough time (measured and simulated) is due to
uncertainties in the reservoir and polymer flow models.
• Based on these simulations, water influx appears to be the main drive mechanism,
while the effect of solution gas drive increases with time.
• The incremental oil recovery is 8% compared to NFA, however to water flooding
this is only 3%. Since only part of the swept oil is produced, there is some potential
for increasing the incremental oil by adding producers to the pilot area.
• Large uncertainties in the physical parameters have a direct impact on the
breakthrough time of polymer. The overall recovery factor however, is only slightly
affected. To resolve this at least partly, a detailed experimental study is needed.
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Back-up_ effect of numerical dispersion in 1-D
0
0,2
0,4
0,6
0,8
0 0,2 0,4 0,6 0,8 1
Sw
X
Effect of numerical dispersion for polymer flooding
analytic
numerical
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Back-up_ drive mechanisms
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0 10 20 30 40 50
fraction o
f oil
pro
duction
Time (years)
fraction of oil produced by different mechanisms
oil expansion
solution gas drive
rock compaction
water influx
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185
Swamp boats
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186
Swamp Operations in the Tambaredjo Field
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Intervention at the wellhead
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Polymer injection data
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189
ADEK students examine polymer facilities
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Polymer mixing
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