Dry HCl Gas Handling

7/23/2019 Dry HCl Gas Handling

http://slidepdf.com/reader/full/dry-hcl-gas-handling 1/5

Signal word :

DANGER

Hazard statements -

CONTAINS GAS UNDER PRESSURE;

MAY EXPLODE IF HEATED

CAUSES SEVERE SKIN BURNS AND EYE DAMAGE

TOXIC IF INHALEDCORROSIVE TO THE RESPIRATORY TRACT

Do not handl !nt"l all #a$t% &'(a!t"on# ha) *n 'ad and !nd'#tood

A)o"d *'ath"n+ +a#

Do not +t "n %#, on #-"n, o' on (loth"n+.

U# and #to' onl% o!tdoo'# o' "n a /ll0)nt"latd &la(.

1a' &'ot(t") +lo)#, &'ot(t") (loth"n+, % &'ot(t"on, '#&"'ato'% &'ot(t"on, and2o' $a(

&'ot(t"on

Sto' lo(-d !&

D"#&o# o$ (ontnt#2(onta"n' D"#&o# "n a #a$ 3ann' "n a((o'dan( /"th lo(al2nat"onal'+!lat"on#

U# a *a(- $lo/ &')nt") d)"( "n th &"&"n+.

U# onl% /"th 4!"&3nt o$ (o3&at"*l 3at'"al# o$ (on#t'!(t"on and 'atd $o' (%l"nd' &'##!'.

Do not o&n )al) !nt"l (onn(td to 4!"&3nt &'&a'd $o' !#.

1hn 't!'n"n+ (%l"nd', "n#tall la- t"+ht )al) o!tlt (a& o' &l!+.

Clo# )al) a$t' a(h !# and /hn 3&t%.

P'ot(t $'o3 #!nl"+ht /hn a3*"nt t3&'at!' 5(d# 678C 9:768F.

F"'#t0a"d 3a#!'# a$t' "nhalat"on < I33d"atl% '3o) to $'#h a"'. I$ not *'ath"n+, +") a't"$"("al

'#&"'at"on. I$ *'ath"n+ "# d"$$"(!lt, 4!al"$"d &'#onnl 3a% +") o5%+n. Call a &h%#"("an.

1ARNING< To a)o"d &o##"*l (h3"(al *!'n#, th '#(!' #ho!ld a)o"d *'ath"n+ an% 5hald a"'

$'o3 th )"(t"3.

F"'#t0a"d 3a#!'# a$t' #-"n (onta(t < In (a# o$ (onta(t, "33d"atl% $l!#h a$$(td a'a# /"th

&lnt% o$ /at' $o' at la#t :6 3"n!t# /h"l '3o)"n+ (onta3"natd (loth"n+ and #ho#.

Call a &h%#"("an.

1a#h (loth"n+ *$o' '!#. D"#(a'd (onta3"natd #ho#.

F"'#t0a"d 3a#!'# a$t' % (onta(t < I33d"atl% $l!#h %# tho'o!+hl% /"th /at' $o' at la#t :6

3"n!t#. Hold th %l"d# o&n and a/a% $'o3 th %*all# to n#!' that all #!'$a(# a' $l!#hd

tho'o!+hl%.

Conta(t an o&hthal3olo+"#t "33d"atl%.F"'#t0a"d 3a#!'# a$t' "n+#t"on < In+#t"on "# not (on#"d'd a &otnt"al 'o!t o$ 5&o#!'.

Storage conditions <

:. Sto' "n a (ool, /ll0)nt"latd &la(. Sto' and !# /"th ad4!at )nt"lat"on. Sto' onl% /h'

t3&'at!' /"ll not 5(d :768F 9678C.

7. F"'3l% #(!' (onta"n'# !&'"+ht to -& th3 $'o3 $all"n+ o' *"n+ -no(-d o)'. In#tall )al)

&'ot(t"on (a&, "$ &'o)"dd, $"'3l% "n &la( *% hand. Sto' $!ll and 3&t% (onta"n'# #&a'atl%.

=. U# a $"'#t0"n, $"'#t0o!t "n)nto'% #%#t3 to &')nt #to'"n+ $!ll (onta"n'# $o' lon+ &'"od#.



OTHER PRECAUTIONS FOR HAN!IN"# STORA"E# AN USE:

:.1hn handl"n+ &'od!(t !nd' &'##!', !# &"&"n+ and 4!"&3nt ad4!atl% d#"+nd to

/"th#tand th &'##!'# to * n(o!nt'd. N)' /o'- on a &'##!'">d #%#t3.

7. U# a *a(- $lo/ &')nt") d)"( "n th &"&"n+.

=. Ga## (an (a!# 'a&"d #!$$o(at"on *(a!# o$ o5%+n d$"("n(%; #to' and !# /"th ad4!at

)nt"lat"on.

?. I$ a la- o((!'#, (lo# th (onta"n' )al) and *lo/ do/n th #%#t3 "n a #a$ andn)"'on3ntall% (o''(t 3ann' "n (o3&l"an( /"th all "nt'nat"onal, $d'al2nat"onal,

#tat2&'o)"n("al, and lo(al la/#; thn '&a"' th la-.

6.N)' &la( a (onta"n' /h' "t 3a% *(o3 &a't o$ an l(t'"(al ("'(!"t.

Preca$tions %or sa%e &andling

:. 1a' lath' #a$t% +lo)# and #a$t% #ho# /hn handl"n+ (%l"nd'#.

7. P'ot(t (%l"nd'# $'o3 &h%#"(al da3a+; do not d'a+, 'oll, #l"d o' d'o&.=. 1h"l 3o)"n+ (%l"nd', al/a%# -& "n &la( '3o)a*l )al) (o)'. N)' att3&t to l"$t a

(%l"nd' *% "t# (a&; th (a& "# "ntndd #oll% to &'ot(t th )al).

?. 1hn 3o)"n+ (%l"nd'#, )n $o' #ho't d"#tan(#, !# a (a't 9t'oll%, hand t'!(-, t(. d#"+nd to

t'an#&o't (%l"nd'#.

6.N)' "n#'t an o*@(t 9.+., /'n(h, #('/d'")', &'% *a' "nto (a& o&n"n+#; do"n+ #o 3a%

da3a+ th )al) and (a!# a la-.

. U# an ad@!#ta*l #t'a& /'n(h to '3o) o)'0t"+ht o' '!#td (a&#.

. Slo/l% o&n th )al).

. I$ th )al) "# ha'd to o&n, d"#(ont"n! !# and (onta(t %o!' #!&&l"'.

. Clo# th (onta"n' )al) a$t' a(h !#; -& (lo#d )n /hn 3&t%.

:. N)' a&&l% $la3 o' lo(al">d hat d"'(tl% to an% &a't o$ th (onta"n'.

::. H"+h t3&'at!'# 3a% da3a+ th (onta"n' and (o!ld (a!# th &'##!' 'l"$ d)"( to $a"l

&'3at!'l%, )nt"n+ th (onta"n' (ontnt#

A''ro'riate engineering controls : U# a (o''o#"on0'#"#tant lo(al 5ha!#t )nt"lat"on #%#t3 /"th

#!$$"("nt a"' $lo/ )lo("t% to 3a"nta"n (on(nt'at"on *lo/ all a&&l"(a*l 5&o#!' l"3"t# "n th

/o'-'# *'ath"n+ >on. A (ano&%0t%&, $o'(d0d'a$t $!3 hood "# &'$''d.

Hand 'rotection : No&'n '!**' 9HNBR.

E(e 'rotection < P'o)"d 'ad"l% a((##"*l % /a#h #tat"on# and #a$t% #ho/'#. 1a' #a$t%

+la### /hn handl"n+ (%l"nd'#; )a&o'0&'oo$ +o++l# and a $a( #h"ld d!'"n+ (%l"nd' (han+o!to' /hn)' (onta(t /"th &'od!(t "# &o##"*l.

S)in and *od( 'rotection < 1a' 3tata'#al #ho# and /o'- +lo)# $o' (%l"nd' handl"n+, and

&'ot(t") (loth"n+ /h' ndd. 1a' a&&'o&'"at (h3"(al +lo)# 9.+. no&'n, n"t'"l, t(.

d!'"n+ (%l"nd' (han+o!t o' /h')' (onta(t /"th &'od!(t "# &o##"*l.

Res'irator( 'rotection :

U# an a"'0#!&&l"d o' a"'0&!'"$%"n+ (a't'"d+ "$ th a(t"on l)l 96 PPM "# 5(dd.

I$ (a't'"d+ t%& '#&"'ato'# a' !#d 9!& to 6 PPM, th (a't'"d+ 3!#t * a&&'o&'"at $o' th

(h3"(al 5&o#!' 9.+., an o'+an"( )a&o' (a't'"d+2a("d +a# (at'"d+.Fo' 3'+n("# o' "n#tan(# 96 PPM /"th !n-no/n 5&o#!' l)l#, !# a #l$0(onta"nd

*'ath"n+ a&&a'at!# 9SCBA /"th $!ll $a( &"(, hood.



S'ill +lea)age Proced$res:

:. P'#on# not /a'"n+ &'ot(") 4!"&3nt# and (loth"n+ #ho!ld * '#t'"(td $'o3 a'a# o$ la-#

!nt"ll a''#t#t"n+ and (lan!& ha# *n (o3&ltd.

7. )nt"lat a'a o$ la- to d"#&'# th +a#.=. Sto& $lo/ o$ +a#. I$ #o!'( o$ la- "# a (%l"nd' and la- (annot * #to&&d "n&la(, '3o) th

la-a+ (%l"nd' to a #a$ &la( "n th o&n a"', and '&a"' th la- o' allo/ th (%l"nd' to 3&t%.

Th a*o) o&'at"on# #ho!ld * don /"th &'o&' &'ot(t"on onl% a# l"#td *lo/



o,s:

:. Do not handl !nt"l all #a$t% &'(a!t"on# ha) *n 'ad and !nd'#tood

7. U# and #to' onl% o!tdoo'# o' "n a /ll0)nt"latd &la(

=. 1a' &'ot(t") n"t'"l +lo)#, )a&o'0&'oo$ +o++l# and a $a( #h"ld d!'"n+ (%l"nd'

(han+o!t

?. Sto' al/a%# "n )'t"(al &o#"t"on and lo(-d /"th )al) &'ot(t"on (a&6. Do not o&n )al) !nt"l (onn(td to 4!"&3nt &'&a'd $o' !#.

. Clo# )al) a$t' a(h !# and /hn 3&t%.

. Sto' $!ll and 3&t% (onta"n'# #&a'atl%.

. U# a $"'#t0"n, $"'#t0o!t "n)nto'% #%#t3 to &')nt #to'"n+ $!ll (onta"n'# $o' lon+ &'"od#.

. 1a' lath' #a$t% +lo)# and #a$t% #ho# /hn handl"n+ (%l"nd'#.

:. P'ot(t (%l"nd'# $'o3 &h%#"(al da3a+.

::. 1h"l 3o)"n+ (%l"nd', al/a%# -& "n &la( '3o)a*l )al) (o)'. N)' att3&t to l"$t a

(%l"nd' *% "t# (a&; th (a& "# "ntndd #oll% to &'ot(t th )al).

:7. 1hn 3o)"n+ (%l"nd'#, )n $o' #ho't d"#tan(#, !# a (a't 9t'oll%, hand t'!(-, t(.

d#"+nd to t'an#&o't (%l"nd'#.

:=. U# an ad@!#ta*l #t'a& /'n(h to '3o) o)'0t"+ht o' '!#td (a&#.:?. Slo/l% o&n th )al).

:6. I$ th )al) "# ha'd to o&n, d"#(ont"n! !# and (onta(t %o!' #!&'"o'.

:. Clo# th (onta"n' )al) a$t' a(h !#; -& (lo#d )n /hn 3&t%.

:. P'ot(t $'o3 #!nl"+ht /hn a3*"nt t3&'at!' 5(d# 678C .

on,t s:

:. A)o"d *'ath"n+ +a#

7. Do not +t "n %#, on #-"n, o' on (loth"n+

=. N)' "n#'t an o*@(t 9.+., /'n(h, #('/d'")', &'% *a' "nto (a& o&n"n+#; do"n+ #o 3a%

da3a+ th )al) and (a!# a la-.

?. Do not d'a+, 'oll, #l"d o' d'o& th (%l"nd'#

S'ill and lea)age Proced$res:

:. P'#on# not /a'"n+ &'ot(") 4!"&3nt# and (loth"n+ #ho!ld * '#t'"(td $'o3 a'a# o$ la-#

!nt"ll a''#t#t"n+ and (lan!& ha# *n (o3&ltd.

7. )nt"lat a'a o$ la- to d"#&'# th +a#.

=. Sto& $lo/ o$ +a#. I$ #o!'( o$ la- "# a (%l"nd' and la- (annot * #to&&d "n&la(, '3o) thla-a+ (%l"nd', &la( "t "n (%l"nd' &"t and '&a"' th la- o' allo/ th (%l"nd' to 3&t%.

?. U# #&'"n-l' $o' /at' #&'a% to 'd!( )a&o'#. K& o!t o$ lo/ a'a#. Coll(t (onta3"natd

/at' and d"#&o# &'o&'l%.

Th a*o) o&'at"on# #ho!ld * don /"th &'o&' &'ot(t"on onl% a# l"#td *lo/

Hand 'rotection : No&'n2 n"t'"l '!**' +lo)#.

E(e 'rotection < 1a' #a$t% +la### /hn handl"n+ (%l"nd'#; )a&o'0&'oo$ +o++l# and a $a(

#h"ld d!'"n+ (%l"nd' (han+o!t o' /hn)' (onta(t /"th &'od!(t "# &o##"*l.

S)in and *od( 'rotection < 1a' a&&'o&'"at no&'n2 n"t'"l (h3"(al +lo)# !t o' /h')'

(onta(t /"th &'od!(t "# &o##"*l.

Res'irator( 'rotection : Fo' 3'+n("# o' "n#tan(# !# a #l$0(onta"nd *'ath"n+ a&&a'at!# 9SCBA /"th $!ll $a( &"(,

hood.



Eac$ation 'roced$re on s'illage o% PCl..

I$ th &ho#&ho'!# &nta(hlo'"d "# #&"lld ta- th $ollo/"n+ #t&#<

:. E)a(!at &'#on# not /a'"n+ th &'ot(t") 4!"&3nt $'o3 th a'a o$ #&"ll !nt"l (lan !& "#(o3&ltd

7. (oll(t &o/d'd 3at'"al "n th 3o#t (on)n"nt and #a$ 3ann', d&o#"t "n #ald (onta"n'#

$o' d"#&o#al.

=. o not $se water ot wet met&od

?. (o)' th #&"ll a'a /"th #od"!3 *"(a'*onat2d'% #and and (lan0!&

6. )nt"lat th /a#h a'a a$t' (lan0!&.

PPE,s

Hand 'rotection : No&'n2 N"t'"l '!**' +lo)#.

E(e 'rotection < 1a' #a$t% +la### /hn)' (onta(t /"th PCl6 "# &o##"*l.

S)in and *od( 'rotection < 1a' a&&'o&'"at no&'n2 n"t'"l (h3"(al +lo)# !t o' /h')'(onta(t /"th &'od!(t "# &o##"*l

Res'irator( 'rotection :

Fo' 3'+n("# o' "n#tan(# !# a #l$0(onta"nd *'ath"n+ a&&a'at!# 9SCBA /"th $!ll $a( &"(,

hood.

Handling 'roced$re d$ring Power Fail$re w&ile HCl gas Feeding:

:. Sto& "33d"atl% D'% HCl +a# $d"n+ to 'ato' *% (lo#"n+ #!&&l% )al) at 'ato'.

7. Clo# HCl +a# #!&&l% )al at C%l"nd'#.

=. 1a"t $o' &o/' '#!3 and n#!' th !t"l"t% 9CHB #!&&l% &'##!' "# :. K+2(37 9+.

?. A$t' &'##!' n#!'"n+, #ta't a+"tato' and thn #ta't th HCl $d"n+.

Emergenc( Eac$ation:

Lo+"n U#' Id

Pa##/o'd

In#tallat"on ad3"n &a##/o'd

Dry HCl Gas Handling

Documents

Transcript of Dry HCl Gas Handling