DRIVING MOBILITYMerck Intelligent Concept Car (MICC) and our Automotive Platform

DRIVING MOBILITYMerck Intelligent Concept Car (MICC) and our Automotive Platform

The connected carMore than 50% of the world population will be “digital natives” in 10 years. Digitally connected self-driving cars will be the next big thing.

Autonomous drivingFocus on quality time: people will be continuously online – working, surfing, playing and shopping.

Car sharingEmphasis on usership rather than ownership; the car will lose its function as a status symbol.

Seamless transitionNo more waiting times! Digital connectivity helps manage traffic flow and thus easy and convenient door-to-door mobility.

UrbanizationThis phenomenon will fundamentally change individual mobility. It is estimated that 6.5 billion people will live in cities in 2050.

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01 Liquid crystals for displays (p. 12)

02 Display materials for free-form displays (p. 13)

03 OLED materials for displays (p. 14)

04 OLED materials for interior and exterior lighting (p. 15)

05 Liquid crystals for smart antennas (p. 16)

06 Liquid crystals for smart lighting (p. 17)

07 Liquid crystal window technology for sunroof shading (p. 24)

08 Integrated circuit materials for sensors and other semiconductors (p. 25)

09 Packaging solutions for semiconductors (p. 26)

10 Effect pigments for exterior coatings (p. 27)

11 Effect pigments for interior applications (p. 28)

12 3D laser direct structuring for light-colored powder-coated and plastic components (p. 29)

13 Laser pigments for simplified laser marking (p. 30)

14 Security solutions for anti-counterfeiting (p. 31)

15 Conductive pigments for primer applications (p. 32)

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Merck Intelligent Concept Car (MICC)

INNOVATION DRIVES US

16 Polysilazanes and anti-scratch additives for surface protection (p. 33)

17 Optical coating materials for automotive imaging and lighting applications (p. 34)

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18 Organic photovoltaic for automotive applications (p. 35)

19 LED color converter for intelligent color rendering (p. 36)

20 Structuring and packaging materials for LED applications (p. 37)

It was a motorized three-wheeler that really got the history of the auto-mobile rolling – in Mannheim, Germany, in August 1888. And it was with a telegram that read: “Drive to Pforzheim successful – we have arrived at Grandma’s.”

The recipient was Carl Benz, inventor of the three-wheeled motor car, and the telegram was sent by his wife Bertha. Bertha Benz had secretly driven off early in the morning without her husband’s knowledge in a three-wheeled Benz Patent Motor Car No. 3. She drove more than 100 kilometers to Pforzheim, where her mother lived. On board were their 13- and 15-year-old sons, who sometimes had to get out and push the vehicle up steep inclines.

The slow-moving, snuffling motor car successfully completed the adventure, providing exactly the demonstration of reliability that Bertha Benz had intended. Her first long-distance drive in automotive history persuaded hesitant customers of this radical new – and completely horseless – form of mobility on the roads.

Roughly 130 years later, Germany’s automotive industry is a world leader. We have, however, arrived at an epoch of transition in which this industry must reinvent itself – almost as in the pioneering days of Bertha Benz.

But what does a chemical company like Merck have to do with mobility? The answer is: surprisingly a great deal! Merck has long been supplying the automo-tive industry with a wide array of high-tech products.

We are driven by curiosity! We search for new ideas that, in turn, will open up completely new technical possibilities. Our research efforts are considerable, and this combination of curiosity and scientific research has always been a decisive driver behind the success of Merck. The history of liquid crystals used in displays, whose development we have pushed from the start, is just one example.

Our Merck Intelligent Concept Car (MICC) demonstrates what our Performance Materials can do as well as the ideas we are working on together with our part-ners. It vividly shows which materials from Merck could be used in a car of the future, in which places, and what functions they offer.

With all of the euphoria about these fascinating visions of the future, however, one thing should be borne in mind: It is enormously time-consuming to develop new high-tech materials that have to maintain their intelligent function in a car over many years. More than anything, those of us on the chemical side need to have a great deal of stamina. This is why it is important for us to work together closely with our customers and partners. Developing materials of this kind would not be possible without intensive sharing of information and contacts.

With this, I hope you see this brochure as a basis for inspiration.

Best Regards,

Walter Galinat, Member of the Executive Board of Merck and CEO Performance Materials

The future of mobility

WHAT DRIVES US?

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KEY FACTS MERCK Merck is the oldest pharmaceutical and chemical company in the world. It is made up of three business sectors: Healthcare, Life Science and Performance Materials, each of which is driven by pioneering spirit, vision and determination.

1668Founded

66Countries

50,000Employees

€1.98 bnInvested in R&D

in 2016

€15 bnSales in 2016

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Performance Materials develops innovative high-tech chemicals for sophisticated applications. These include liquid crystals for displays, OLED materials for displays and lighting, effect pigments for coatings and cosmetic products, specialty chemicals for the semi conductor industry and functional materials for solar panels.

Performance Materials has many ingenious materials and technologies for the auto motive industry. We have established the Automotive Platform to consolidate our activities for the automotive industry under one umbrella.

Addressing the needs of the automotive industry in a coordinated approach and providing it with a clear contact and go-to point will expand our network, establish our brand as well as accelerate and advance our business.

What sets us apart?• Key player for innovative thinking with

essential and necessary structural distance to the automotive industry

• Competent partner for enabling breakthrough innovations at the beginning of the value chain

• Reliable and certified supplier of products in serial development projects

PERFORMANCEMATERIALS

We are a material and solution provider for the automotive industry.

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CHANGEDRIVES USCars are speeding ahead towards a digital future. What was science fiction yesterday is reality today. And it’s clear that there will be a lot of Merck inside the car of tomorrow.

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On a winter’s day in 1895, Walter Arnold floors the ac-celerator of his motor car and rattles through the English vil-lage of Paddock Wood. Arnold has to pay a price for his thrill for speed; he is the first driver in the world to get a speeding ticket. He had clocked up a whole 13 kilometers per hour on his speedometer, although only about three kilometers per hour were allowed.

Although legally and technically speaking, maximum speed limits have increased exponentially since the pioneering days of the automobile, in our present-day megacities it’s scarcely possible to move faster today than it was then. Bumper-to-bumper traffic congestion is a daily occurrence on our roads. Fine dust pollution causes breathing problems, and the automobile has long been proclaimed a climate killer. But a lot is happening. ‟Urbanization, electrically powered vehicles and digitalization will fundamentally change individual mobility,” says Harry Wagner, Professor for Auto-motive and Mobility Management at the Technical University of In-golstadt in Germany. Increasingly stringent global environmental regulations make it clear that the future lies in new drive tech-nologies. However, it will most likely be decades before electric vehicles dominate the roads, for instance.

Rolling computers

Digital change is happening at a much faster pace. Today’s cars are already rolling computers. In the future, they will even com-

municate with other vehicles and traffic control systems to a far greater extent. Experts agree that autonomous driving will be the next big thing. Digital connec-tivity makes it possible to smartly manage the traffic flow, possibly even without traffic lights. And this is likely to increase safety – owing to fewer accidents. But what do people do in self-driving cars? They’ll be online – work-ing, phoning, surfing, playing and shopping. An enormous flood of data on four wheels, which can be used to make money. And that’s probably the main reason why Internet companies are sudden-ly interested in the car-making business. Carmakers, on the other hand, will develop into mo-bility providers. ‟The emotional significance of owning a car will decrease; car sharing is on the advance. Apps will increasing-ly steer how we use intermod-al travel – combining different modes of transport – to get from A to B quickly and efficiently,” forecasts Wagner.

Innovative materials and technologies

Nobody knows exactly what the car of the future will look like. That makes it all the more ex-citing – for Merck as well. ‟Our Performance Materials business sector is developing many inno-vative materials and technologies with which we can help shape the future of the automobile,” says Nadine Langguth. She heads Merck’s Automotive Platform, which focuses on the innovation fields of automobility. With the ‟Displaying Futures” initiative, among other things, the company

seeks direct exchange with manu-facturers, suppliers and experts from various relevant disciplines. ‟We want to identify and under-stand the diversity of trends and requirements at an early stage in order to even better leverage our opportunities going forward as a development partner and mate-rials supplier,” states Langguth. Merck has long been supplying the automotive industry with a wide range of products. These in-clude effect pigments for coating applications, liquid crystal mix-tures for displays and semicon-ductor materials for microchips.

Urbanization, electrically powered vehicles and digi talization will fundamentally change indi vi d ual mobility.”

Prof. Dr. Harry WagnerProfessor for Automotive &

Mobility Management, Technical University of Ingolstadt

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Organic light-emitting diodes are opening up completely new design options for automotive light-ing.”

Own concept car

With its ‟Intelligent Concept Car,” Merck is showcasing the materials it manufactures for applications in the car of the future. For example, liquid crystals make high-resolu-tion automotive displays with high thermal stability and an extremely long lifetime possible.

The broad color spectrum produc-es an exceptionally high image quality. OLED (organic light-emit-ting diode) materials are used both in displays and lighting, and offer new design possibilities with their extremely thin structure. OLED displays provide exceptionally high contrast, brilliant colors and razor-sharp images from every angle, and can even be transpar-ent. Free-form displays with liquid crystal or OLED technology can be

seamlessly incorporated into var-ious spaces such as dashboards, doors and seats. Very thin glass or even plastic can be used for them. The first prototypes for cars al-ready exist. The materials used to produce highly reliable and pow-erful microchips and sensors are important for self-driving cars, for example. Laser direct structuring is used to directly mount electron-ic circuits onto plastic components or powder-coated parts. However, Merck wants to set new standards not only in car interiors. Liquid crystal windows for switchable sunroofs in cars allow continuous-ly variable switching from dark to light and vice versa in just sec-onds. When built into sunroofs or dashboards, printable photovoltaic cells can help to power cars in an eco-friendly way.

Dr. Marc Lünnemann, Head of OLED at Osram

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Liquid crystal antennas have the potential to transform cars into fully net-worked mobile communications systems.”

Owain Parri, Marketing Manager,

Display Materials

The end of wireless dead zones

In a digitalized world, it is becom-ing increasingly important to have powerful Internet access also in cars. Smart satellite antennas with Merck expertise inside make this possible. Through a thin functional liquid crystal layer, the antenna beam can be steered electronical-ly in different directions instead of mechanical positioning to the satellite as with conventional technologies. Special software ensures reliable contact to the satellite – making wireless dead

Our Perfor- mance Mate-rials business sec-tor is developing many innovative materials and technologies with which we can help shape the future of the automo-bile.”

Nadine LangguthDirector – Automotive Platform

Performance Materials, Display Materials

zones a thing of the past. ‟Liquid crystal antennas have the poten-tial to transform cars into fully networked mobile communica-tions systems. And in view of the rapidly growing data volumes, we can score with our experience in this promising field of technology,” says Owain Parri, marketing man-ager within the Display Materials business unit. The technology has been developed together with the Technical University of Darmstadt. Kymeta, a U.S. start-up, is plan-ning to launch the first smart an-tenna in 2017 using liquid crystal mixtures specifically designed for this application.

Light sources: safe and trendy

Smart lighting for the car of the future is another promising field of research that Merck is focusing on. Headlights containing liquid crystals have a higher resolution, allowing them to adapt automati-cally to any imaginable situation. A high beam headlight would thus provide maximum illumination without blinding oncoming drivers or pedestrians. In addition, Merck is collaborating with Osram, a lighting manufacturer, to develop innovative automotive lighting technologies. ‟Organic light-emit-ting diodes are opening up com-pletely new design options for automotive lighting,” says Marc Lünnemann, Head of OLED at Osram. First series vehicles with ultraflat, glass-based OLED rear lights are now coming onto the market. Their light is extremely homogeneous and precise and offers automobile designers a variety of options for differentia-tion. ‟The next leap in innovation

will be flexible OLED lighting that can be applied to bendable panels and designed in virtually any shape,” says Lünnemann. The abundance of examples shows that the possibilities for the car of the future are developing at top speed – without any speeding tickets. And Merck is leading the race.

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Kapitel-Headline10

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As a material and solution provider for the automotive industry, we supply the materials and know-how it requires for the metamorphosis of mobility.

PIONEERING SPIRITDRIVES US

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01High-performance

LIQUID CRYSTALSfor displays

licristal®

“We are anticipating future needs through successful partnerships.”

Seung-Eun Lee Marketing & Sales

• Enable temperature-stable, outstandingly durable displays for all seasons• Established and new technologies proven at major

LCD panel suppliers• Available through a fully developed global supply chain• Allow innovative display designs

Use advanced liquid crystal technologies to enable high-resdisplays with wide color gamut and high dynamic range forsuperb picture quality and low power consumption.

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• Open up flexible and free-form display design opportunities

• Suggest new uses for displays• Integrate seamlessly into dashboards, doors, seats, etc.

Integrate flexible and free-form car interior displays where ideally they need to provide a surface curvature in two directions. Can be integrated into existing glass-based production processes or plastic substrates during manufac-turing.

Flexible

DISPLAY MATERIALS

for free-form displays

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• Allow superb brightness and contrast • Appear very dark – there is no dark glowing

during night-time• Open up new design opportunities for trans-

parent and very thin displays

Create displays with high-contrast, brilliant colors and razor-sharp images that can be viewed comfortably from any angle.

High-contrast

OLED MATERIALSfor displays

“OLEDs give us a new degree of freedom in designing lighting and screens. A car dashboard may soon look like a spaceship control panel.”

Joachim KaiserResearch & Development

livilux®

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• Allow highly energy-efficient lighting elements

• Provide striking 3D effect and real area lighting due to very thin shapes with very low weight

• Enable transparent and mirror designs

Design exclusive interior and exterior OLED lighting and enjoy the new design freedom.

Energy-efficient

OLED MATERIALS

for interior and exterior lighting

livilux®

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• Use one-to-many advantage of satellite over LTE• Leverage future cost-effective satellite

communications systems• Help to avoid expensive software recalls• Reduce the privacy and software hacking issue

Equip the connected car with planar LC satellite antennas, and wireless dead zones become a thing of the past.

“When you’re driving through the countryside, you realize how much our routine tasks depend on uninterrupted data transmission.”

Carsten Fritzsch Research & Development

05Reconfigurable

LIQUID CRYSTALSfor smart antennas

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• Switch light on a pixel level to allow very flexible patterning to adapt car headlights to any imaginable situation

• Reduce costs and failure of mechanical solutions

Increase safety with fully adaptive LC-managed light for high-resolution headlights.

06Adaptive

LIQUID CRYSTALS

for smart lighting

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Merck Intelligent Concept Car (MICC)

VISION DRIVES US

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1. Download the “Merck Showcar AR” app from Google Play store/iTunes Store.

2. Open the file on your smartphone or tablet (i.e. iPhone 6, Samsung S6 or higher).

3. Follow the instructions on the screen (you need to print out the marker or use the one below).

4. Hold your device over the marker (full marker needs to be visible on the screen).

5. Experience MICC in augmented reality (AR) by moving your device and selecting different functionalities from the menu.

Experience our augmented reality Merck Intelligent Concept Car

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INTERACTION DRIVES US

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Our idea with the MICC is to create a car that is connected to the external world. As a mobile environment, MICC allows passengers to be brought from one place to the other safely and independently while using their time efficiently, for instance to interact with outside friends. With less concentration on performance, the car of the future addresses the need for usership rather than ownership.

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Watch the video and see how cleverly our performance materials

are integrated into the Merck Intelligent Concept Car

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<<< Look inside

“Our materials already provide functionality and aesthetics in many parts of today’s automobiles. Through digitization and con-nectivity, the car of the future will undergo a metamorphosis. With our specially devel-oped futuristic MICC, we dare to take a look into this very future.

The vehicle design incorporates our high-tech materials. It demonstrates what new directions such materials open up for the automotive industry. We want to develop these materials further, also in conjunction with partners from the auto branch.”

Walter Galinat

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• Are tested for tough environmental conditions (UV, temperature)

• Allow instant switching (<1s) • Demonstrate low haze• Operate on low voltage• Enable a variety of colors

Introduce Liquid Crystal Window (LCW) technology to sun-roofs and thus enhance the comfort of driver and passenger.

07Switchable

LIQUID CRYSTAL WINDOW (LCW) TECHNOLOGYfor sunroof shading

licrivision™

“We have created the ultimate window technology platform. It’s the perfect combination of aesthetics and function.”

Martin Zitto Business Development

• Enable reliable and powerful microchips and sensors for assisted and self-driving functionalities

• Deliver high processing performance for embedded high-tech gadgets

Employ innovative integrated circuit materials for next-generation microchips and sensors to support future automotive technologies.

08High-tech

INTEGRATED CIRCUIT MATERIALS

for sensors and other semiconductors

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• Comply with ROHS and are fully lead-free• Allow high-temperature resistant components that

are reliable in the engine compartment • Facilitate a smaller, more integrated component

design that enhances performance

Apply high-end material technologies to eco-friendly, high-temperature, high-performance component packaging for powerful semiconductors.

09Eco-friendly

PACKAGING SOLUTIONSfor semiconductors

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• Are designed for high performance in outdoor applications

• Enliven coatings from subtle to living sparkle effects• Yield high chroma for strong and deep colors

Utilize the infinite styling potential of weather-stable effect pigments in car coatings to underscore the car body’s beauty; set your brand apart from the competition.

10Weather-resistant

eFFECT PIGMENTS

for exterior coatings

“First impressions count. Our effect pigments open up a world of styling options to grab attention.Design with effect pigments to generate value.”

Filip Roscam Design Director

Pigments & Functional Materials

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• Make colors more vibrant• Are applicable on a variety of materials such as

leather, textile and plastic• Can be used in various application techniques such

as powder, liquid and coil coating

Open a huge field of design and color possibilities to add value to car interiors.

11Powerful

EFFECT PIGMENTSfor interior applications

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• Omits the extra IC board – LDS integrates conductive pathways onto electronic components

• Goes beyond the classic flat 2D IC board – enjoy new design freedom in construction

• Facilitates last-minute changes in construction

Laser-write conductive pathways of 50-100 μm line width directly onto plastic or powder-coated compo-nents, thus creating 3D MIDs (mechatronic integrated devices). Special light-colored laser pigments allow electroless plating after laser treatment.

State-of-the-art

3D LASER DIRECT STRUCTURING (LDS)

for light-colored powder-coated and plastic components

“Laser direct structuring onto 3D carriers supports the general trend towards minia-turization of electronic components.”

Oliver Robert Piening Marketing & Sales

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• Enable permanent and high-resistant markings in nearly all polymers• Execute contact-free marking even of curved parts• Avoid surface damage to the powder coating• Profit from inline-marking process• Forgo cost for consumables (no ink)

Laser mark powder-coated and plastic components with functional or decorative markings: from basic text to photorealistic design to any kind of code. The addi-tives activate the matrix and allow economic, durable and fast marking – directly in the polymer, on any powder-coated metal or plastic surface and without any pretreatment required.

13Laser-sensitive

LASER PIGMENTSfor simplified laser marking of powdered-coated and plastic parts

“Thanks to quick-as-a-flash reaction to laser light, you can now laser mark thin-laser applications like films or powder-coated materials.”

Stefan Gutberlet, Marketing & Sales

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• Incorporate invisible IR taggants that can be detected only by special readers

• Address quality issues of intermediates or possible threats of imitations

Respond to supply chain challenges caused by globalization, and incorporate IR taggants into literally any kind of material. Be aware that product liability remains with the respective manufacturer.

Invisible

SECURITY SOLUTIONS

for anti-counterfeiting

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• Enable electrostatic application (ESTA) of plastic components• Create perfect light-colored coatings with exceptionally smooth

surfaces • Reduce the amount of costly base coat material needed

Match plastic parts with neighboring car body parts made of metal perfectly. Light or colorful car coatings in particular can unfold their full effect owing to the light masstone color of Iriotec® 7300-based conduc-tive primers.

Multifunctional

POLYSILAZANES AND ANTI-SCRATCH ADDITIVES

for ultimate protection of a multitude of surfaces

15Light-colored

CONDUCTIVE PIGMENTSfor electrically conductive primer applications

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• Preserve and protect interior and exterior car surfaces• Permit high-performance coatings for heat-enduring components • Keep the car coating pristine and scratch-protected for a long time• Are suitable for nearly all surfaces

Protect the beauty of auto surfaces against heat, corrosion, scratches, friction and dirt with Durazane™ – a real ceramic coating. With Tivida® anti-scratch particles, the glossy top coat of a car will be effectively and durably protected from any scratches.

Multifunctional

POLYSILAZANES AND ANTI-SCRATCH ADDITIVES

for ultimate protection of a multitude of surfaces

“Merck recently became the only manufacturer in the world of organic and inorganic polysilazanes – special-purpose polymers used in a wide spectrum of industries.”

Ivo Zenz Marketing & Sales

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• Enable next generation driver assistance systems, for example through high-image-quality camera optics

• Improve optical component robustness, for example through hard overcoats for mirrors

• Improve the functionality of optical performance in all kinds of weather, for example through an anti-smudge coating

• Ensure optical functionality for cameras and headlights as well as long-term availability of identical parts

Rely on Patinal® materials for high-quality optical coatings. Choose from over 40 evaporation materials with proven batch-to-batch consistency, stable and reproducible processing and long-term, global availability.

17Reliable

OPTICAL COATING MATERIALS for automotive imaging and lighting applications

Patinal®

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• Downsize to smaller air conditioning and compen-sate creeping current by integrating aesthetic OPV power supply into sunroofs or dashboards

• Benefit from option for CO2 credits• Realize self-sufficient devices in car’s interior

Exploit natural and artificial light by integrating OPV in the car design and power management.

Eco-friendly

ORGANIC PHOTOVOLTAIC (OPV)

for automotive applications

lisicon®

“Printing OPV enables lightweight and flexible PV modules. You can attach them to any surface – also curved ones – like a second skin. First applications like the solar trees at the EXPO 2015 in Milan or the African Nation building in Addis Ababa are lighthouse projects. As a next step to mass adoption, we are targeting lightweight roof applications and façades with integrated organic photovoltaics.”

Hannah Bürckstümmer Strategic Marketing

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• Enables vivid color solutions for light spectrum engineering

• Tailors LED spectrum for nearly every brand color• Offers especially advanced solutions for human-

centric lighting by dynamically adjusting the color temperature as well as adopting the LED light spectrum to human’s natural circadian rhythm

Accomplish the perfect illumination with our color converting materials (phosphors). Differentiate vehicles through innovative interior LEDs.

19Cutting-edge

LED COLOR CONVERTER for intelligent color rendering

isiphor®

“isiphor® phosphors support the lighting revolution with vibrant colors and superior efficiency.”

Rose Yang Business Development

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• Incorporate highest reliable encapsulant for LED rear light and/or front light LED package applications, for example DRL

• Implement innovative photo resists that support the latest design style for ultra-power LEDs

• Integrate novel photo-patternable dielectric materials for future LED design trends, for example head-up displays for augmented driver assistance systems

Structure and package LED car applications that meet the highest reliability requirements in the industry. Our superior LED packaging materials are designed for harsh environmental conditions and high-power applications.

Superior

STRUCTURING AND PACKAGING MATERIALS

for LED applications

isiphor®

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Products are warranted to meet the specifications set forth on their label/packaging and/or certificate of analysis at the time of shipment or for the expressly stated duration. Merck provides information and advice on application technologies and relevant regulations based upon its current knowledge and opinion. MERCK MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE REGARDING OUR PRODUCTS, THEIR APPLICATION OR ANY INFORMATION PROVIDED IN CONNECTION THEREWITH. Merck shall not in any event be liable for incidental, consequential, indirect, exemplary or special damages of any kind resulting from any use or failure of the prod-ucts. The customer is responsible for and must independently determine the suitability of Merck´s products for its products, intended use and processes. The foregoing information and suggestions are also provided without warranty of non-infringe-ment as to intellectual property rights of third parties and shall not be construed as any inducement to infringe the rights of third parties. The customer shall be responsible for obtaining any applicable third party intellectual property licenses. All sales are subject to Merck’s complete Terms and Conditions of Sale. Prices are subject to change without notice. Merck reserves the right to discontinue products without prior notice.

Merck, the vibrant M, Durazane™, Effect Pigments®, Iriotec®, Isiphor®, Licristal®, Licrivision™, Lisicon®, Livilux®, Patinal®, Securalic® and Tivida® are trademarks of Merck KGaA, Darmstadt, Germany. All other trademarks pertain to their proprietors.

Smarter. Brighter. Faster.

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YOU DRIVE US

Our Automotive

Platform

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Displaying Futures initiative

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Automotive PlatformMerck KGaAPerformance MaterialsFrankfurter Str. 25064293 Darmstadt, Germany

Phone: +49 (0) 6151 / 72-0Fax: +49 (0) 6151 / 72-2000service@merckgroup.comwww.merck-performance-materials.com

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