Drill: Draw & name 5 isomers of C 5 H 8. Review Drill & Test.
-
Upload
austen-chase -
Category
Documents
-
view
223 -
download
0
Transcript of Drill: Draw & name 5 isomers of C 5 H 8. Review Drill & Test.
Drill: Draw & name 5 isomers
of C5H8
Review Drill &
Test
Functional Groups
Draw & Name Isomers of:
C4H6
Functional Groups•Chemically active part of an organic
compound
Functional Groups•Anything other than
singularly bonded carbon & hydrogen in an organic compound
Functional Groups•The name of any
organic compound ends with the suffix for the
most important functional group
Terminology•R- represents the part
of the organic compound you are
not referring to
Terminology•R-OH
•-OH is the functional group
•R- anything else
Alkene
C=C
Alkyne
C=C
Halides R-X
•X = F, Cl, Br, or I
•haloalkane
•alkylhalide
Halides Cl
•2-chlorobutane
•2-butylchloride
Ethers R1-O-R2
•alkylalkylether
•alkoxyalkane
Ethers CH3CH2-O-CH3
•Methylethylether
•methoxyethane
Hydroxyl Group
C OH
Alcohols R-OH
•hydroxyalkane
•alkanol
Alcohols
CH3-CH2-OH
•hydroxyethane
•ethanol
Carbonyl Group
C=O
Ketones O
R-C-R
•Oxy or ketoalkane
•alkanone
Ketones O
•3-pentanone
•3-oxypentane
Aldehyde O
R-C-H
•alkanal
•alkanaldehyde
Aldehydes O
•hexanal
•hexanaldehyde
H
Name the following:
OH Cl
CH CH
H3C CH2 CH3
Name the following:
OH Cl
CH CH
H3C CH2 CH3
4-chloro-2-pentanol
OH Cl
CH CH
H3C CH2 CH3
Drill: Name the following: OH O
Carboxyl Group
C=OHO
Carboxylic Acid O
R-C-OH
•Alkanoic Acid
Carboxylic Acid O
CH3-CH2-C-OH
•Propanoic Acid
Drill: Draw & name 5 isomers of:
OH OH
Functional Isomers:•Isomers with different functional groups:
•The suffix changes
Propanone
Propanaldehyde
O
O
H
Positional Isomers:•Isomer’s functional group in a new location
•The # before the main chain name changes
2-propanol
1-propanol
OH
OH
Name the following: CH3-CH2-CH2-OH
CH3-CH2-O- CH2-CH3
O
CH3-CH2-C-CH2-CH3
Name the following: O O
C C
H3C CH OH
OH
Name the following: O O
C C
H3C CH OH
OH
2-hydroxy-3-ketobutanoic acid
O O
C C
H3C CH OH
OH
Name the following: O
CH3-CH2-CH2-C-OH
O
CH3-CH2-C-H
Carboxyl Derivatives
C=OO
Esters O
R1-C-O-R2
•Alkylalkanoate
Esters O
CH3-CH2-CH2-C-O-CH3
methylbutanoate
Anhydrides O O
R1-C-O-C-R2
•Alkanoicalkanoic anhydride
O
O
O
Butanoicpropanoic anhydride
Draw the following:• 2-hydroxypentanal
• Methylpropylether
• Trichloroethanoic acid
• Ethylbutanoate
• Aceticformic anhydride
Drill: Draw & Name 5 isomers of:
C3H6O2
Name, then & Draw & name a Functional Isomer of:
O
OHC
CC
CC
C OH
C
O
OHC
CC
CC
C OH
C
3-hydroxy-5-methylhexanoic acid
O
OHC
CC
CC
C OH
C
2,3-dihydroxy-5-methylhexanal(dehyde)
O
HC
CC
CC
C OH
C
OH
1,3-dihydroxy-5-methyl-2-hexanone
O
OHC
CC
CC
C OH
C
Name & Draw 1 Positional Isomer of:
O
OHC
CC
CC
C OH
C
O
OHC
CC
CC
C
OH
C
2-hydroxy-5-methylhexanoic acid
Name & Draw 1 Structural Isomer of:
O
OHC
CC
CC
C OH
C
3-hydroxyheptanoic acid
O
OHC
CC
C
CC OH
C
Name & Draw 1 Optical Isomer of:
O
OHC
CC
CC
C OH
C
To draw an optical isomer, draw the
mirror image of an assymetric compound
O
OHC
CC
CC
C OH
C
3-hydroxy-5-methylhexanoic acid
C
CCC
CC
HO
O OH
C
3-hydroxy-5-methylhexanoic acid
Draw:•2-phenylpropanoic acid
•3-hydroxy-2-iodopentanal
•2-cyclohexyl-3-octanone
•phenylbutanoate
Drill: Name:
CC
CC OH
OC
OCl
Drill: Draw the following:
•Butanoicpentanoic anhydride
Thiol R-SH
•Sulfhydrylalkane
•Mercaptoalkane
•Alkanethiol
SH
•3-sulfhydrylpentane
•3-mercaptopentane
•3-pentanethiol
Sulfide
R1-S-R2
•Alkylalkylsulfide
•Alkylalkylthioether
Sulfide S
•diethylsulfide
•diethylthioether
Disulfide
R1-S-S-R2
•Alkylalkyldisulfide
Disulfide
S-S
methylphenyldisulfide
C
Thioesters O
R1-C-S-R2
•Alkylthioalkanoate
Thioesters O
CH3-C-S-CH3
•Methylthioethanoate
Draw the Following:• Methylthiobutanoate
• Methylphenyl ether
• Diphenyl thioether
• 2-propanethiol
Name:
CC
CC
C
OH
O
SH
Cl
CC
CC
C
OH
O
SH
Cl
3-chloro-2-mercaptopentanoic acid
CC
CC
C
OH
O
SH
Cl
Drill: Name:
CC
CC
O
C
O
Amine Group
N:
Ammonia
:NH3
Ammonium
NH4+
Primary Amines
R-NH2
•Aminoalkane
•alkylamine
Primary Amines
CH3-NH2
•Aminomethane
•methylamine
Secondary Amines R2
R1-NH
Alkylalkylamine
CH3
CH3-CH2-NH
methylethylamine
Tertiary Amines R2
R1-N-R3
Alkylalkylalkylamine
CH2-CH3
CH3-N:
CH2-CH2-CH3
methylethylpropylamine
Quaternary Amines R2
R1-N-R3
R4
•Tetraalkylammonium
+
CH3
CH3-N-CH3
CH2-CH2-CH3
trimethylpropylammonium
+
CH3
CH3-N-H
CH2-CH2-CH3
dimethylpropylammonium
+
Amides O
R1-C-NH2
•Alkanoamide
O
C-C-C-C-C
NH2
•Pentanoamide
Nitrile R-C=N
•Cyanoalkane
•Alkanonitrile
Nitrile
CH3-C=N
•Cyanomethane
•Ethanonitrile
Name:
CC
CC
C
OH
O
OH
F
Name:
CC
CC
C
OH
O
OH
F
3-fluoro-4-hydroxypentanoic acid
CC
CC
C
OH
O
OH
F
Draw & name 10 isomers of:
C4H9NO
Draw the following:
•2-phenyl-1-propanol
•Butylethenyl ether
Draw the following:
•phenylthioacetate
•methylisopropylsulfide
•2-mercaptobutanal
Name:
CC
CS
C
C
O
Name:
CC
CS
C
C
O
propylthioacetate
CC
CS
C
C
O
Name:
SH O
OH
OH
Name:
SH O
OH
OH
3-hydroxy-5-mercapto-6-methyl-7-phenyloctanoic acid
SH O
OH
OH
Draw & name 10 isomers of:
C4H8SO2
Drill: Name
SH
OH
O
Name
C
NOH
N
H
OH
Name
C
NOH
N
H
OH
4-cyano-2-hydroxy-3-methylhexanoamide
C
NOH
N
H
OH
Drill: Name
Cl OHOH
O
Primary Amines
R-NH2
•Aminoalkane
•alkylamine
Secondary Amines R2
R1-NH
Alkylalkylamine
Tertiary Amines R2
R1-N-R3
Alkylalkylalkylamine
Quaternary Amines R2
R1-N-R3
R4
•Tetraalkylammonium
+
Amides O
R1-C-NH2
•Alkanoamide
Nitrile R-C=N
•Cyanoalkane
•Alkanonitrile
Name
C
NOH
NH2
O
Cyanate
R-O-C=N
•Alkylcyanate
Cyanate
O-C=N
•cyclohexylcyanate
Isocyanate
R-N=C=O
•Alkylisocyanate
Isocyanate
N=C=O
•1-pentylisocyanate
Thiocyanate
R-S-C=N
•Alkylthiocyanate
Thiocyanate
S-C=N
•2-propylthiocyanate
Isothiocyanate
R-N=C=S
•Alkylisothiocyanate
Isothiocyanate
CH3-N=C=S
•Methylisothiocyanate
Phosphates O
R-O-P-O-1
O-1
•Alkylphosphate
Phosphates O
-O-P-O-1
O-1
•Phenylphosphate
Diphosphates O O
R-O-P-O-P-O-1
O-1 O-1
•Alkyldiphosphate
Diphosphates O O
CH3-O-P-O-P-O-1
O-1 O-1
•Methyldiphosphate
Triphosphates O O O
R-O-P-O-P-O-P-O-1
O-1 O-1 O-1
•Alkyltriphosphate
Triphosphates O O O
-O-P-O-P-O-P-O-1
O-1 O-1 O-1
•2-butyltriphosphate
Phosphodiester O
CH3-CH2-O-P-O-CH3
O-1
•Methylethylphosphate
Carboxylic acidCarboxylic acid derivativeAldehydeKetoneAlcoholAmineThiol
Drill: Draw & Name 5 isomers of:
C3H7NO2
Drill: Name:
CO
OHNH2
OH
Br
Organic HW•Draw & Name 5
isomers of: C3H6SO
Drill:Draw & Name 5
Isomers of:
C4H7NO
Lab: Today Review: TomorrowTest : Wednesday
Name the following:
CO
NH2OH
NC
Name the following:
CO
NH2OH
NC
3-cyano-2-hydroxy-7-methyl-6-phenyloctanoamide
CO
NH2OH
NC
Drill: Name the following:
CO
OHNHSH
Cl
Name the following:
CO
OHNHSH
Cl
2-amino-3-chloro-4-mercapto-N,7-dimethyl-6-
phenylnonanoic acid
CO
OHNHSH
Cl
Test Tomorrowon
Functional Groups
Name the following:
O
OHF
Name the following:
O
OHF
3-fluoro-1-methoxy-4-methyl-2-cyclopropylhepta-5-yn-1-ol
O
OHF
Name the following:
OO
O
PO4-2 OH
Name the following:
OO
O
PO4-2 OH
21
4-methyl-3-phenyl-2-phosphopentanoic-2-
hydroxypropanoic anhydride
OO
O
PO4-2 OH
21
Draw:• 3-mercaptohexanoamide
• Methyl-2-hydroxythioacetate
• Para-iodophenylformic acid
• Phenylpropylamine
• 2-amino-3-ethyl-4-keto-N- methylhexanaldehyde
Draw & Name 10 isomers of:
C4H9SNO
Draw & Name 10 isomers of:
C4H9NO2
Name the following:
NH
P3O10-4
Name the following:
NH
P3O10-4
4-amino-6,7-dimethyl-N-phenyl-3-octyltriphosphate
NH
P3O10-4
Name the following:
O
SH O
H
Name the following:
O
SH O
H
3-mercapto-6,7-dimethyl-4-phenoxynonanal
O
SH O
H
Drill: Name:
OH
NH2 O
OH
NC
Name:
OH
NH2 O
OH
NC
3-amino-5-cyano-4-hydroxyhexanoic acid
OH
NH2 O
OH
NC
Name the following:
Br
O
O
NCS
Name the following:
Br
O
O
NCS
1
propyl-4-bromo-3-cyclobutyl-5-thiocyanatohexanoate
Br
O
O
NCS
1
Name the following:
O
OHCl
Name the following:
O
OHCl
3-chloro-2-cyclopropyl-4-methylpentanoic acid
O
OHCl
Drill: Name the following:
O
OF
O
Drill: Name the following:
O
OF
O1
2
Methyl-3-fluoro-2-keto-4-methylpentanoate
O
OF
O1
2
Name the following:
S
OOH
NC
Name the following:
S
OOH
NC
1
2
Ethyl-2-cyano-3-hydroxythiohexanoate
S
OOH
NC
1
2
Draw the Following:
•3-methyl-5-propyl-octanoamide
•Octylbutanoate
Draw the Following:
•Aceticpentanoic anhydride
•2-cyano-3-mercaptohexanoic acid
Drill Draw & name 5 isomers
of:
•C4H7NO
Draw:•Benzoic acid
Draw:•4-hydroxy-N-
methyl-benzoamide
Drill: Draw:4-hydroxy-2-
mercapto
pentanoic acid
Review
C=C
OR C O R
R N C O
R-SH
R-NH2
OR C OH
O
C
R R
R-OH
O O C CR O R
R C N
H:N R R
OR C NH2
OR C H
R O C N
R1-O-R2
R-I
R +R N R R
C=C
R +R NH R
R1-S-R2
OR C S R
R S C N
O -2
O P O R O
R:N R R
R-S-S-R
R N C S
Drill: Name:
OH
O
NH2
SH
Name the compounds on
the board
Draw the compounds on
the board
Draw & Name 10 isomers of
C4H7SNO
C4H7NO