Draft Environmental Impact Assessment Report & Environment ...

Draft Environmental Impact

Assessment Report &

Environment Management Plan

of

Urmit Chemicals Pvt. Ltd.

Survey No. 1384, Village: Rajpur, Tal: Kadi,

Dist.: Mehsana, Gujarat

Proposed Project for Manufacturing of

Dyes & Dye Intermediates– 400 MTPM

Project Activity: 5(f), Category: A

[ToR Letter No. F. No. J-11011/418/2018-IA-II(I)]

[Study Period: January, 2019 to March, 2019]

Prepared by

San Envirotech Pvt. Ltd.

(NABET Accreditation No. NABET/EIA/1619/RA0084; Valid till 23.12.2019)

424, Medicine Market, Paldi Cross Road, Ahmedabad-380006, Gujarat

Email: [email protected]

(June, 2019)

mailto:[email protected]

Declaration. by experts contributing to the EIA of. Urmit Chemicals

Private Limited

I, hereby, certify that I was a part of the EIA team in the following capacity

that developed the above EIA.

EIA Coordinator:

Name:

Signature & Date:

Period of involvement

Contact Information :

Dr. Mahendra Sadaria

Dember 2018 to date

079-26583077

Functional Area Experts I '

Functional Areas

Air Pollution Monitoring & Control (AP)

Air Quality Modeling and Prediction (AQ)

Water Pollution

(WP)

Solid and Hazardous Waste Management

(SHW)

Name of the Expert


Diti Patel



~nvolvement (Period and Task)

Planning of meteorological AAQM baseline monitoring, site visit/ survey, select monitoring locations, data verification & approval, interpretation of baseline condition of air environment. Evaluation of results of Ambient Air Quality Monitoring (AAQM). Contribution in EIA documentation. Meteorology file generation, quality model (ISCST-3) run us.: meteorology data, identifying source & receptor. Prediction of GLC & plotting isopleths. Study of GLCs obtained & calculating cumulative concentration of pollutants. Contribution in EIA documentation. Site visit, selection of sampling locations, review & interpret baseline water quality, water balance calculation for the project, prediction of impacts & proposed mitigation measures, contribution in EIA documentation. Identified source of generation of Hazardous waste & disposal methods, studying adequacy of mitigation measures for management of hazardous waste.

Signature & date

&d2

study area, assessment of the possible chances to socio-economic issues arising out of the proposed

classification and determine LULC of the area, prediction of impact on land use pattern, Suggest

suggestion of mitigation measures

modeling, finalization of RA, contribution in EIA documentation.

levels, source & its compliance with its, contribution in

D lar tion 9 guthorized person

I, Dr. Mahendra Sadaria, hereby confirm that the above mentioned experts

prepared the EIA of Urmit Chemicals Pvt. Ltd. at Survey IVo. 1384, Village:

Rajpur, Tal: Kadi, Dist: Mehsana, Gujarat I also confirm that, the consultant

organization shall be fully acco~~ntable for any misleading information

mentioned in this statement.

Signature:

Name: Dr. Mahendra Sadaria

~ e s i ~ n a t i o n : Director, Technical

Name of the EIA Consultant organization an Envirotech Pvt. Ltd.

NABET Certificate No. and date NABET/EIA/l619/RA0084, Valid ti l l 23.12.2019

San Envirotech Pvt. Ltd., Ahmedabad

Draft EIA Report of Urmit Chemicals Pvt. Ltd. I

Contents Particulars Page No.

Index I

List of Tables X

List of Figures XII

List of Annexures XII

Index Chapter 1 Introduction Page No.

1.1 Preface 1-1

1.2 Purpose of the Report 1-1

1.3 Identification of Project & Project Proponent 1-2

1.4 Importance of the project 1-3

1.5 Brief description of project 1-3

1.6 Applicable environmental regulatory framework 1-6

1.7 Scope of the study 1-6

1.8 Compliance to Terms of Reference 1-7

1.9 Objective of EIA 1-19

1.10 Methodology for EIA 1-19

1.11 List of Industries surrounding project site 1-21

1.12 Structure of report 1-21

Chapter 2 Project Description

2.1 Introduction 2-1

2.2 Location of the Project 2-1

2.3 Size or magnitude of operation 2-4

2.3.1 Land breakup & project site layout 2-4

2.3.2 Project Magnitude 2-5

2.4 Infrastructure Facilities 2-8

2.5 Description of manufacturing process 2-9

2.6 Project Components 2-9

2.7 Input Requirements 2-9

2.8 Generation of pollutants 2-23

2.8.1 Wastewater generation 2-23

2.8.2 Gaseous emission 2-23

2.8.3 Hazardous/ solid waste generation 2-25


Draft EIA Report of Urmit Chemicals Pvt. Ltd. II

2.8.4 Noise Generation 2-26

2.9 Pollution control strategy 2-26

2.9.1 Effluent management 2-26

2.9.2 Air pollution control measures(APCM) 2-31

2.9.3 Hazardous/solid waste management 2-31

2.9.4 Noise pollution control measures 2-32

2.10 Rain water harvesting 2-32

2.11 Green Belt Development 2-33

2.12 Occupational health & safety 2-33

Chapter 3 Description of Environment

3.1 General 3-1

3.2 Study area 3-1

3.3 Study Period 3-2

3.4 Source of environmental data generation 3-2

3.5 Methodology 3-3

3.6 Land Environment 3-3

3.6.1 Land use pattern of the Study Area 3-3

3.6.2 Objective of Land Use Studies 3-5

3.6.3 Topography and Drainage 3-5

3.6.4 Seismicity of the area 3-5

3.7 Meteorology 3-5

3.7.1 Site specific micro-meteorological data 3-5

3.7.2 Wind Rose 3-6

3.8 Ambient air quality 3-7

3.8.1 Introduction 3-7

3.8.2 Design of Network for Ambient Air Quality

Monitoring Stations

3-7

3.8.3 Reconnaissance 3-7

3.8.4 Parameters, Frequency and monitoring

Methodology

3-8

3.8.5 Interpretation of result 3-9

3.9 Water Environment 3-10

3.9.1 Hydrogeology of study area 3-10

3.9.2 Groundwater Resources 3-12

3.10 Water quality 3-13


Draft EIA Report of Urmit Chemicals Pvt. Ltd. III

3.10.1 Introduction 3-13

3.10.2 Sampling Frequency, Techniques & Methodology 3-13

3.10.3 Surface Water Quality (Primary data) 3-14

3.10.4 Ground Water Quality 3-14

3.10.5 Interpretation 3-14

3.10.6 Conclusion 3-15

3.11 Noise Environment 3-16

3.11.1 Instrument used for Sampling and Monitoring 3-16

3.11.2 Noise Quality Monitoring Locations 3-16

3.11.3 Ambient Noise Standards 3-16

3.11.4 Results 3-17


3.12 Soil Environment 3-17

3.12.1 Soil sampling locations 3-17

3.12.2 Methodology 3-18

3.12.3 Corollaries 3-19


3.13 Biological Environment 3-20

3.13.1 Period of the study 3-20

3.13.2 Study methodology 3-20

3.13.3 Floral species in the study area 3-21

3.13.4 Fauna in the study area 3-21

3.14 Socio Economic Environment 3-21

3.14.1 Objective of the study 3-22

3.14.2 Land use pattern and infrastructure 3-22

3.14.3 Demographic and Socio-Economic Environment 3-22

3.14.4 Living Standard and Infrastructure 3-23

Chapter 4 Anticipated Environmental Impacts &

Mitigation Measures

4.1 General 4-1

4.2 Identification of Impact 4-2

4.2.1 Identification of Impacting Activities 4-2

4.2.2 Identification of Environment Attributes 4-3

4.3 Impact on Topography 4-3

4.4 Impact on Air Environment 4-3

4.4.1 Air Pollution Dispersion modeling of stack 4-4


Draft EIA Report of Urmit Chemicals Pvt. Ltd. IV

4.4.2 Micrometeorology 4-5

4.4.3 Input data 4-6

4.4.4 Receptor Network 4-6

4.4.5 Output of Model (24-hourly GLCs) 4-7

4.4.6 Incremental & cumulative concentration of

pollutants

4-7


4.5 Impact on Water Environment 4-7

4.6 Impact on Noise Environment 4-9

4.7 Impact on Land Environment 4-10

4.8 Impact on Biological Environment 4-11

4.9 Impact on Socio-Economic Environment 4-12

4.10 Impact on Occupational Health & Safety 4-13

4.11 Impact on Existing Traffic System 4-14

Chapter 5 Analysis of Alternatives

5.1 Prologue 5-1

5.2 Site Alternative 5-1

5.3 Process Alternative 5-1

Chapter 6 Environmental Monitoring Program

6.1 Prelude 6-1

6.2 Environment Monitoring Program 6-1

6.3 Objective of Monitoring Plan 6-1

6.4 Schedule for Environment Monitoring 6-2

6.5 Ambient Air Quality Monitoring 6-2

6.6 Water Environment Monitoring 6-3

6.7 Noise Environment Monitoring 6-3

Chapter 7 Additional Studies

(A) HAZARD ANALYSIS & RISK ASSESSMENT 7-1


7.2 Risk Assessment- Identification of Hazards 7-1

7.3 Hazardous Materials Storage 7-3

7.4 Risk Screening Approach 7-4

7.4.1 Acute Exposure Guideline Levels (AEGLs) 7-8

7.4.2 Emergency Response Planning Guidelines (ERPGs) 7-9

7.5 QRA Approach 7-10

7.6 Thermal Hazards 7-10


Draft EIA Report of Urmit Chemicals Pvt. Ltd. V

7.7 Damage due to explosion 7-12

7.8 Toxic release 7-12

7.9 Acid/Alkali Hazards 7-13

7.10 Likely Failure Scenarios 7-14

7.11 Quantitative Risk Assessment & Consequence

Analysis

7-14

7.11.1 Preamble 7-14

7.11.2 Weather Effect 7-14

7.12 Incidents Impacts 7-15

7.13 Consequential Impacts 7-18

7.13.1 Thermal and Explosion Hazards 7-19

7.13.2 Toxic Hazards 7-19

7.13.3 Other Hazards 7-19

7.13.4 Other toxic Hazards 7-19

7.14 Occupational Health 7-19

7.15 Conclusion & Recommendations 7-21

Material Handling and Safety Measures 7-23

7.16 Action plan for handling & safety system of

chemical

7-23

7.16.1 Safety measures for transportation and unloading

of hazardous chemicals

7-23

7.16.2 Safety measures for storage/handling of hazardous

chemicals

7-23

7.16.3 Safety measures for process units 7-23

7.16.4 Safety measures for preventive maintenance 7-24

7.16.5 Safety measures to prevent spillage/leakage of

toxic chemicals

7-25

7.17 Arrangements for ensuring health & safety of

workers engaged in handling of toxic materials

7-25

7.18 Disaster management plan (DMP) 7-27

7.18.1 Definitions 7-27

7.18.2 Objective of the Disaster Management Plan 7-28

7.19 Onsite Emergency Plan 7-29

7.19.1 Incident controller 7-29

7.19.1.1 Duties of Incident controller 7-29

7.19.2 Site main controller 7-30

7.19.2.1 Duties of site main controller 7-30

7.19.3 Other key personnel 7-31


Draft EIA Report of Urmit Chemicals Pvt. Ltd. VI

7.19.3.1 Emergency response team 7-31

7.19.3.2 Emergency personnel’s responsibilities outside

normal working hours of the factory

7-31

7.19.3.3 Assembly points 7-31

7.19.4 Emergency control centre 7-32

7.19.4.1 Role of emergency control centre 7-32

7.19.5 Fire & Toxicity control arrangements 7-32

7.19.6 Medical arrangements 7-33

7.19.7 Transport & evacuation, mutual aid arrangements 7-33

7.20 Communication system 7-33

7.20.1 Declaring the emergency 7-33

7.20.1.1 Type of sirens 7-33

7.20.1.2 Location of siren 7-34

7.20.1.3 Raising alarm 7-34

7.20.2 Internal communication 7-35

7.20.2.1 Availability of key personnel outside normal

working hours

7-35

7.20.3 Communication to the authorities 7-35

7.21 Pre emergency activities 7-36

7.22 Post-emergency activities 7-36

7.22.1 Evacuation and transportation 7-36

7.22.2 Safe close down 7-37

7.22.3 Use of mutual aid 7-37

7.22.4 Use of external authorities 7-37

7.22.5 Medical treatment 7-37

7.22.6 Accounting for personnel 7-37

7.22.7 Access to records 7-37

7.22.8 Public relations 7-37

7.22.9 Rehabilitation 7-37

7.23 Causes of emergency 7-38

7.23.1 Risk 7-38

7.23.1.1 Nature 7-38

7.23.1.2 Various emergency actions 7-38

7.23.1.3 Response time-minutes 7-39

7.24 Off-site emergency plan 7-39

7.24.1 Need of the site emergency plan 7-39


Draft EIA Report of Urmit Chemicals Pvt. Ltd. VII

7.24.2 Structure of the off-site emergency plan 7-40

7.24.3 Role of the factory management 7-40

7.24.4 Role of emergency co-ordination office (ECO) 7-40

7.24.5 Role of local authority 7-40

7.24.6 Role of fire authorities 7-40

7.24.7 Role of the police and evacuation authorities 7-40

7.24.8 Role of health authorities 7-41

7.24.9 Role of mutual aid agencies 7-41

7.24.10 Role of factory inspectorate 7-41

7.25 Mock drills and records 7-41

7.25.1 Need of rehearsal & training 7-41

7.25.2 Some check points 7-41

7.25.3 Records and updating the plan 7-41

B. Social Impact Assessment 7-42

Chapter 8 Project Benefits


8.2 Improvement in Physical Infrastructure 8-1

8.3 Improvement in Social Infrastructure 8-1

8.4 Employment Potential 8-2

8.5 Other Tangible Benefits 8-2

Chapter 9 Environmental Cost Benefit Analysis 9-1

Chapter 10 Environment Management Plan


10.2 Environmental Management During Construction

Phase

10-1

10.2.1 Air and Noise Environment 10-2

10.2.2 Water Environment 10-2

10.2.3 Socio-Economic Environment 10-2

10.2.4 Health and Safety 10-2

10.3 Environmental Management during the Operational

Phase

10-3

10.3.1 Air Pollution Management 10-3

10.3.1.1 Source of Air Pollution and Control Measures 10-3

10.3.1.2 Measures for Solvent Recovery 10-4

10.3.1.3 Odour Control Plan 10-4



Draft EIA Report of Urmit Chemicals Pvt. Ltd. VIII

10.3.3 Hazardous/Solid waste management 10-6

10.3.4 Noise Control 10-6

10.3.5 Green Belt Development 10-7

10.3.6 Occupational Health & Safety Plan 10-9

10.3.7 Details of the separate isolated storage area 10-11

10.4 Post -Project Environmental Monitoring 10-11

10.4.1 Details of Work Place Air Quality Monitoring Plan 10-13

10.5 Environment Management Budget Allocation 10-13

10.6 Environmental Management Cell 10-13

10.6.1 Hierarchical Structure of Environmental

Management Cell

10-14

10.6.2 Environment Policy 10-14

10.6.3 Reporting System of Non-Compliances/Violations

of Environmental Norms

10-15

10.6.4 Framework for Continual Improvement of

Environmental Performance of Organization

10-16

10.7 Resource Conservation and Cleaner Production 10-16

10.8 Energy conservation programme 10-16

10.9 Socio Economic Activities 10-17

Chapter 11 Summary & Conclusion

11.1 Project Description 11-1

11.1.1 General Introduction 11-1

11.1.2 Brief project description 11-1

11.1.3 Investment of the Project 11-2

11.1.4 List of Products 11-2

11.2 Description of Environment 11-4

11.2.1 Baseline Environmental Study 11-4

11.2.2 Air Environment 11-4


11.2.4 Noise Environment 11-7

11.2.5 Soil Quality 11-7

11.2.6 Biological Environment 11-8

11.2.7 Socio-Economic Environment 11-8

11.3 Anticipated Environmental Impacts and Mitigation

Measures

11-8

11.3.1 Summary of Impacts on Air Environment 11-8

11.3.2 Summary of Impacts on Water Environment 11-9


Draft EIA Report of Urmit Chemicals Pvt. Ltd. IX

11.3.3 Impacts on Noise quality & Mitigation measures 11-10

11.3.4 Summary of Impacts on Land Environment 11-10

11.3.5 Summary of Impact on Socio Economy 11-10

11.3.6 Summary on Impact on Ecology 11-11

11.4 Environment Monitoring Programme 11-11

11.5 Additional Studies 11-12

11.5.1 Risk Assessment 11-12

11.6 Project Benefits 11-12

11.7 Environmental Management Plan 11-12

11.8 Conclusion 11-13

Chapter-12 Disclosure of Consultant engaged

12.1 Preface 12-1

12.2 Details of EIA Consultant Organization 12-1


Draft EIA Report of Urmit Chemicals Pvt. Ltd. X

List of Tables

Table No.

Name Page No.

1.1 Salient features of the project 1-3

1.2 Product details 1-4

2.1 Boundary coordinates of the site 2-3

2.2 Land breakup 2-4

2.3 List of products with its capacity 2-5

2.4 List of equipment and machineries 2-8

2.5 Raw Materials Requirement, Source & Transportation 2-9

2.6 Breakup of water consumption & w/w generation 2-21

2.7 Details of fuel consumption 2-23

2.8 Details of stacks 2-24

2.9 Estimated Emission quality of stack 2-24

2.10 Details of solid/Hazardous waste 2-25

2.11 Details of Effluent Treatment Plant (ETP) 2-29

2.12 Characteristics of untreated and treated effluent of

Process W/w

2-30

3.1 Environmental setting of the study area 3-2

3.2 Land use statistics work out based on satellite imaginary 3-4

3.3 Monitoring Methodology of Meteorological Data 3-6

3.4 Meteorological Data for the Monitoring Period 3-6

3.5 Methodology of Ambient Air Monitoring 3-8

3.6 Monitored Parameters and Frequency of Sampling 3-8

3.7 Sampling locations with source & date of sampling 3-14

3.8 Monitoring Methodology of Noise 3-16

3.9 Location of soil sampling 3-18

3.10 Methodology of Soil Sample analysis 3-18

3.11 Ambient Air Quality Monitoring Locations 3-25

3.12 Ambient Air Quality Status 3-26

3.13 Ambient Air Quality Status (PM10) 3-27

3.14 Ambient Air Quality Status (PM2.5) 3-28

3.15 Ambient Air Quality Status (SO2) 3-29

3.16 Ambient Air Quality Status (NOx) 3-30

3.17 Ambient Air Quality Status (CO, HC (Methane & non-

Methane), VOC, HCl)

3-31


Draft EIA Report of Urmit Chemicals Pvt. Ltd. XI

3.18 National Ambient Air Quality Standards 3-32

3.19 Results of Groundwater Quality in the Study Area 3-33

3.20 Results of Surface water Quality in the Study Area 3-34

3.21 Indian Standard Specification for Drinking Water 3-35

3.22 Ambient Noise Levels in the Study Area 3-36

3.23 Ambient Air Quality Standards with respect to Noise 3-36

3.24 Soil Analysis of Study area 3-37

3.25 Floral Diversity 3-38

3.26 Faunal Diversity 3-42

3.27 Traffic Survey 3-44

3.28 Land Use Pattern 3-45

3.29 Summary of Socio-Economic Status of Study area

(Demography)

3-46

3.30 Summary of Socio-Economic Status of Study area

(Amenities)

3-48

4.1 Input data for air quality modeling 4-15

4.2 Cumulative Concentrations at various locations 4-16

4.3 The 24-hourly average GLC Concentration Values for SPM 4-17

4.4 The 24-hourly average GLC Concentration Values for SO2 4-18

4.5 The 24-hourly average GLC Concentration Values for NOx 4-19

4.6 The 24-hourly average GLC Concentration Values for HCl 4-20

6.1 Environment Monitoring Plan 6-4

7.1 Bulk storage of Hazardous Chemicals 7-4

7.2 Properties of Hazard- Raw Materials (stored in bulk) 7-5

7.3 Hazard Analysis- Raw materials (stored in bulk) 7-7

7.4 Risk Classification 7-10

7.5 Effects due to Incident Radiation intensity 7-11

7.6 Thermal Radiation Impact to human 7-11

7.7 Tolerable Intensities for various objects 7-11

7.8 Damage due to overpressure 7-12

7.9 Different failure scenarios 7-14

7.10 Hazards scenario impact 7-18

7.11 Detailed expenditure break-up for CER activities 7-44

10.1 Environment Monitoring Plan 10-12

10.2 Budget Allocation for Environment Management 10-13

10.3 Budgetary provisions for the social upliftment 10-18


Draft EIA Report of Urmit Chemicals Pvt. Ltd. XII

List of Figures

Figure

No.

Name Page

No.

2.1 Location of the project site 2-2

2.2 Google map of 10 km radius 2-3

2.3 Image showing location of the with its coordinates 2-3

2.4 Plant layout 2-5

2.5 Water Balance Diagram 2-22

2.6 Flow diagram of “ETP-1” for process effluent 2-28

2.7 Flow diagram of “ETP-2” for Utilities + Washing 2-29

3.1 Land use map 3-4

3.2 Graphical representation of ambient air quality 3-26

3.3 Graphical representation for PM10 3-27

3.4 Graphical representation for PM2.5 3-28

3.5 Graphical representation for SO2 3-29

3.6 Graphical representation for NOx 3-30

3.7 Location of AAQM station 3-53

3.8 Wind Rose Diagram 3-54

3.9 Water sampling Locations 3-55

3.10 Noise monitoring Locations 3-56

3.11 Soil Sampling Locations 3-57

3.12 Topo sheet of location with site location map of 10 km

radius (1:50,000 scale)

3-58

4.1 Isopleths for Ground Level Concentration for SPM 4-21

4.2 Isopleths for Ground Level Concentration for SO2 4-22

4.3 Isopleths for Ground Level Concentration for NOx 4-23

4.4 Isopleths for Ground Level Concentration for HCl 4-24

7.1 Sulphuric acid spillage and evaporating toxic pool 7-15

7.2 Oleum Spillage SO3- Release 7-16

7.3 Toxic impact Zone Chlorine (Stability Class D) 7-16

7.4 Toxic Impact Zone Chlorine (stability class F) 7-17

7.5 Toxic Impact Zone Acetic Acid 7-17

7.6 Aniline Tank Leakage Toxic Impact 7-17

7.7 Hydrochloric Acid Tank Leakage Toxic Impact 7-18

10.1 Environment Management Cell 10-14


Draft EIA Report of Urmit Chemicals Pvt. Ltd. XIII

List of Annexures

Sr. No. Annexures Page no.

I. NABET-QCI Certificate A–1

II. Manufacturing process, Chemical reaction & Mass Balance of

all products

A–2

III. Photographs of the site A–93

IV. Land Documents A–94

V. Membership certificate for disposal of effluent at Common

Spray Drying Facility

A-106

VI. Material Safety Data Sheet of Chemicals A-107

VII. Undertaking from Consultant A–173

VIII. Undertaking from Project Proponent A–174

IX. Copy of Terms of Reference (TOR) A–175

X. Submitted Form-1 along with all Annexures/Attachments A–183


Draft EIA Report of Urmit Chemicals Pvt. Ltd. 1-1

Chapter-1

Introduction

1.1 PREFACE

An Environmental Impact Assessment (EIA) is an assessment of the

possible impacts that a proposed project may have on the environment -

consisting of the environmental, social and economic aspects. It is an

assessment and management tool that evaluates the possible impacts,

positive or negative, that a proposed project may have on the

environment. EIA systematically examines both beneficial and adverse

consequences of the project and ensures that these effects are taken into

account during project design. The purpose of the assessment is to

ensure that decision makers consider the ensuing environmental impacts

when deciding to proceed with a project. In India, Ministry of

Environment and Forests has defined elaborated “Environmental

Clearance (EC)” framework along with requirements for preparing

Environmental Impact Assessment (EIA) under the Environmental

(Protection) Act, 1986 (Environmental Impact Assessment Notification,

2006) for establishing/expanding and industry/development projects.

1.2 PURPOSE OF THE REPORT

Industrialization and infrastructure development have increased economic

growth and improved living standards of people in India. However,

development has led to rapid consumption of natural resources and

increased emissions of waste. To control the pollutions from industrial

activity, government has framed regulations which are governed by

Ministry of Environment, Forest & Climate Change in India. Environment

Impact analysis is mandatory as per the Environment Impact Assessment

(EIA) Notification issued by Ministry of Environment, Forest & Climate

Change (MoEF&CC), New Delhi dated 14th September, 2006 and its

subsequent amendment; for setting up a new projects or activities, or

expansion or modernization of existing projects or activities based on

their potential environmental impacts as indicated in the Schedule to the

notification, being undertaken in any part of India, unless prior

environmental clearance has been accorded.



Proposed activity of M/s. Urmit Chemicals Pvt. Ltd. falls under the

schedule of 5(f) - Synthetic Organic Chemicals Industry (dyes & dye

intermediates; bulk drugs and intermediates excluding drug formulations;

synthetic rubbers; basic organic chemicals, other synthetic organic

chemicals and chemical intermediates) and categorized under Category

“A”. Therefore, unit requires prior Environmental Clearance for proposed

project.

EIA Consultant

In view of the above, legal aspect and monitoring work has been carried

out for all the environmental attributes by M/s. San Envirotech Pvt.

Ltd. (SEPL), Ahmedabad. SEPL is accredited as Category-A organization

under the QCI-NABET Scheme for accreditation of EIA consultant

Organizations: Version 3 for preparing EIA-EMP reports in 10 sectors.

Draft Environment Impact Assessment (EIA) and Environmental

Management Plan (EMP) have been prepared after obtaining Terms of

References (TORs) from MoEF&CC, New Delhi. The public hearing will be

conducted by SPCB based on draft EIA/EMP submitted by project

proponent. Final EIA/EMP report will be prepared incorporating to

comments of Public hearing and compliance of the Terms of References.

1.3 IDENTIFICATION OF PROJECT & PROJECT PROPONENT

Urmit Chemicals Pvt. Ltd. Proposes to set up Dyes and dye

intermediates manufacturing unit at Kadi Taluka of Mehsana District.

Required facilities like infrastructure, communication, medical facilities,

fuel, water, power, unskilled & skilled manpower, raw materials, road

network etc. are readily available, therefore, no other optional site or

area was considered. There is no Rehabilitation and Resettlement

involved. Nearest city Mehsana is about 26 km away from the site, which

is having connectivity with other parts of the country by road, rail & air.

PROJECT PROPONENT

Project is promoted by young entrepreneur Mr. Ameet Patel, Bachelor

of Chemical Engineering & Mr. Krunal Patel, Bachelor of Chemical

Engineering. Both the key promoters have more than 10 years‟ of

experience in the same line.



1.4 IMPORTANCE OF THE PROJECT

The global dyes and dyes intermediate market is projected to reach USD

42.00 billion by 2021, at a CAGR of 5.0% from 2016 to 2021. The growth

of the market is primarily due to increasing population, coupled with

growing demand for dyes & pigments from various applications, such as

textile, paints & coatings, and plastics, among others. This has prompted

Urmit Chemicals to start manufacturing of dye intermediates, dyes

production of 400 MTPM.

1.5 BRIEF DESCRIPTION OF PROJECT

Salient features of the project and list of products are given in Table 1.1

and Table 1.2, respectively.

Table 1.1 Salient Features of the Project

Proposed production capacity 400 MTPM

Proposed project cost Rs. 8.0 Crores

Manpower requirement About 100 persons

Location

Survey No. 1384

Village Rajpur

Tehsil Kadi

District Mehsana

State Gujarat

Area 35662 m2

Coordinates Latitude: 23°20'48.44"N

Longitude: 72°24'26.99"E

Altitude 79 m above MSL

Topography Plain

Survey of India Toposheet No. F43A7

Seismic Zone Seismic Zone-III

Nearest

Town Kadi about 8.20 km

City Mehsana about 26 km

Railway Station Julasan, about 7.0 km,

Kadi, about 11.0 km

Highway SH41 (Ahmedabad-Mehsana),

about 1.0 km

Air Port Ahmedabad about 38.0 km

Reserve Forests/National

Park/Wildlife Sanctuary

None within 10 km radius

Note: Aerial distances are mentioned in above table.



Table 1.2 Product details

Sr.

No.

Name of Products Quantity

(MTPM)

(A) Dyes Intermediates

1. Chloranil 150

2. Ortho Amino Phenol (OAP)

3. Para Amino Phenol (PAP)

4. Meta Amino Phenol (MAP)

5. Ortho Amino Phenol Sulphonic Acid (OAPSA)

6. Metanilic Acid

7. 6 Chloro Metanilic Acid

8. 4-Chloro 2-Amino Phenol (4 CAP)

9. 4-Chloro-2-Amino Phenol-5-Sulphonic Acid

(4 CAPSA)

10. 4 Nitro 2 Amino Phenol (4 NAP)


12. 6 Nitro 2 Amino Phenol 4 Sulphonic Acid

(6 NAPSA)


(4 NAPSA)


(6 CAPSA)

15. 2 Pyridone

16. 1:3 Phenyl Methyl 5 Pyrazolone (PMP)

17. 1:4 Sulpho Phenyl 3 Methyl 5 Pyrazolone

(1:4 SPMP)

18. 2:5 Dichloro 4 Sulpho Phenyl 3 Methyl 5 Pyrazolone

(2:5 DCSPMP)

19. 2 Chloro 5 Sulphophenyl 3 Methyl 5 Pyrazolone

(2:5 CSMP)

20. 1,3 Sulpho Phenyl 3 Methyl 5 Pyrazolone

(1:3 SPMP)

21. 2 Chloro Phenyl Methyl 5 Pyrazolone (2 CPMP)

22. Para Toluene Phenyl Methyl 5 Pyrazolone (PTPMP)

(B) Dyes

Acid Dyes 100

1. Acid Yellow 79

2. Acid Yellow 151

3. Acid Yellow 49

4. Acid Yellow 99

5. Acid Yellow 194

6. Acid Yellow 220

7. Acid Yellow 232

8. Acid Brown 75



Sr.

No.


(MTPM)

9. Acid Brown 165

10. Acid Brown 161

11. Acid Brown 282

12. Acid Brown 432

13. Acid Brown 425

14. Acid Brown 434

15. Acid Green 16

16. Acid Blue 9

17. Acid Blue 15

18. Acid Blue 7

19. Acid Blue 113

20. Acid Blue 193

21. Acid Red 315

22. Acid Black 107

Direct Dyes

23. Direct Black 80

24. Direct Yellow 11

25. Direct Brown 44

26. Direct Blue 71

27. Direct Orange 118

28. Direct Red 239

29. Direct Red 254

30. Direct Violet 35

31. Direct Red 81

32. Direct Violet 9


34. Direct Black 19

Reactive Dyes

35. Reactive Blue 198




Basic Dyes Solid 50

39. Basic Brown 1

40. Basic Yellow 2

41. Basic Violet 1

42. Basic Green 4

43. Basic Green 1

44. Basic Blue 26

Basic Dyes Liquid 100

45. Basic Yellow 2



Sr.

No.


(MTPM)

46. Basic Violet 1

47. Basic Green 4

48. Basic Green 1

49. Basic Blue 26

Total 400

1.6 APPLICABLE ENVIRONMENTAL REGULATORY FRAMEWORK

The proposed project will abide and function under the purview of the

following Rules, Acts & Regulations which are formulated by the Govt. of

India to protect the environment and development in a sustainable way.

The Water (Prevention & Control of Pollution) Act, 1974

The Air (Prevention & Control of Pollution) Act, 1981

The Environmental (Protection) Act, 1986

Environmental Impact Assessment Notification dated 14th September

2006 and subsequent amendments

The Hazardous & Other Waste (Management and Transboundary

Movement) Rules, 2016

Noise Pollution (Regulation and Control) Rules, 2000 and its

amendments

The Public Liability Insurance Act, 1991

1.7 SCOPE OF THE STUDY

The scope of the EIA study is based on the guideline provided by

MoEF&CC. The scope of the study broadly includes:

Field sampling of environmental attributes at various representative

locations in the study area to establish the baseline status;

Collect & compile secondary data including socio-economic data;

Identification, assessment and evaluation of the beneficial and

adverse impacts on surrounding environment due to proposed

project activities considering the existing baseline status along with

compilation of other information.

Analysis of project proposal and data analysis.

Assessment of pollution potential due to proposed project.

Predict the incremental levels of pollutants in the study area due to

the proposed project;



Evaluate the predicted impacts on the various environmental

attributes by using scientifically developed and widely accepted

models.

Identification and assessment of risks associated with the proposed

project and their appropriate management through proper Risk

Assessment (RA) and Disaster Management Plan (DMP).

Prepare an Environmental Management Plan (EMP) to mitigate the

predicted impacts; and

Identify critical environmental attributes required to be monitored

during the project execution and to suggest post project monitoring.

The scope also includes all the conditions outlined in the TOR issued by

MoEF&CC and the compliance to the TOR is given below.

1.8 COMPLIANCE TO TERMS OF REFERENCE

MoEF&CC has prescribed the Standard Terms of Reference (TOR) -

IA-J-11011/418/2018-IA-II(I) dated 04/02/2019 for undertaking

detailed EIA study for the purpose of obtaining Environmental Clearance

in accordance with the provisions of the EIA Notification, 2006.

Compliance of TORs is as below:

Sr.

No.

Condition Compliance

A. Specific TOR

i Public consultation for obtaining

prior environmental clearance is

prescribed.

GPCB will conduct Public Hearing as

per the provision of the EIA

Notification, 2006 based on our

request. Minutes of PH will be

incorporated in final EIA report

along with Time Bound Action Plan

and Budgetary provision.

5(f) Standard Terms of Reference for Conducting Environment Impact

Assessment Study for Synthetic Organic Chemicals Industry (Dyes &

Dye Intermediates; Bulk Drugs and Intermediates Excluding Drug

Formulations; Synthetic Rubbers; Basic Organic Chemicals, Other

Synthetic Organic Chemicals and Chemical Intermediates) and

Information to be Included in EIA/EMP Report

A Standard Terms of Reference

1. Executive Summary Enclosed as Chapter-11.

2. Introduction

i. Details of the EIA Consultant

including NABET accreditation.

Details of EIA consultant is given in

Chapter-12 „Disclosure of



Consultant engaged‟.

NABET accreditation certificate is

enclosed as Annexure-I.

ii. Information about the project

proponent.

It is described in Chapter-1, Section

1.3 (Page no. 1-2).

iii. Importance and benefits of the

project.

Importance of the project is

described in Chapter-1, Section 1.4

(Page no. 1-3).

Benefits of the project are described

in Chapter-8 of EIA report.

3. Project Description

i. Cost of project and time of

completion.


2.1 (Paragraph 2; Page no. 2-1).

ii. Products with capacities for the

proposed project.


2.3.2 (Page no. 2-5).

iii. If expansion project, details of

existing products with capacities

and whether adequate land is

available for expansion, reference

of earlier EC if any.

Not applicable

(New project proposal).

iv. List of raw materials required and

their source along with mode of

transportation.

List of raw materials required and

their source along with mode of

transportation is given in Chapter-

2, Section 2.7a, Table 2.5 (Page no.

2-9).

v. Other chemicals and materials

required with quantities and

storage capacities.

List of raw materials required with

quantities are given in Chapter-2,

Section 2.7(a), (Page no. 2-9).

Storage capacity of materials is

mentioned in Chapter 7, Table 7.1

(Page no. 7-4).

vi. Details of Emission, effluents,

hazardous waste generation and

their management.

Details of pollution generation are

given in Chapter-2, Section 2.8

(Page no. 2-23) & their

management is given in Section 2.9

(Page no. 2-26).

vii. Requirement of water, power, with

source of supply, status of

approval, water balance diagram,

man-power requirement (regular

and contract).


2.7b (Page no. 2-21), 2.8c (Page

no. 2-22), 2.8d & 2.8e (Page no. 2-

23).

viii. Process description along with

major equipments and

machineries, process flow sheet

(quantities) from raw material to

products to be provided.

It is enclosed as Annexure-II.



ix. Hazard identification and details of

proposed safety systems.

Hazard identification is described in

Chapter-7, Section 7.2 (Page no. 7-

1); risk screening approach is

covered in Section 7.4 (Page no. 7-

4); details of proposed safety

system are covered in Section 7.16

(Page no. 7-23).

x. Expansion/modernization proposals:

a. Copy of all the Environmental

Clearance(s) including

Amendments thereto obtained for

the project from MOEF/SEIAA shall

be attached as an Annexure. A

certified copy of the latest

Monitoring Report of the Regional

Office of the Ministry of

Environment and Forests as per

circular dated 30th May, 2012 on

the status of compliance of

conditions stipulated in all the

existing environmental clearances

including Amendments shall be

provided. In addition, status of

compliance of Consent to Operate

for the ongoing/ existing operation

of the project from SPCB shall be

attached with the EIA-EMP report.

Not applicable


b. In case the existing project has

not obtained environmental

clearance, reasons for not taking

EC under the provisions of the EIA

Notification 1994 and/or EIA

Notification 2006 shall be

provided. Copies of Consent to

Establish/No Objection Certificate

and (Consent to Operate (in case

of units operating prior to EIA

Notification, 2006, CTE and CTO of

FY 2005-2006) obtained from the

SPCB shall be submitted. Further,

compliance report to the

conditions of consents from the

SPCB shall be submitted.

Not applicable


4. Site Details:

i. Location of the project site

covering village, Taluka/Tehsil,

District and State, Justification for

Location of the project site covering

Village, Taluka/Tehsil, District and

State is provided in Chapter 1,



selecting the site, whether other

sites were considered.

Table 1.1 (Page no. 1-3); also

shown in Figure 2.1 to 2.3 (Page

no. 2-2 to 2-3).

Justification for selecting the site is

covered in Chapter 5, Section 5.2

(Page no. 5-1).

ii. A toposheet of the study area of

radius of 10km and site location

on 1:50,000/1:25,000 scale on an

A3/A2 sheet. (Including all eco-

sensitive areas and

environmentally sensitive places).

Included in Chapter 3, Figure 3.12

(Page no. 3-58).

iii. Details w.r.t. option analysis for

selection of site.

Justification for site selection is

covered Chapter 5, Section 5.2

(Page no. 5-1).

iv. Co-ordinates (lat-long) of all four

corners of the site.

Included in Chapter 2, Table 2.1

(Page no. 2-3).

v. Google map-Earth downloaded of

the project site.

Included in Chapter 2, as Figure 2.2

and Figure 2.3 (Page no. 2-3).

vi. Layout maps indicating existing

unit as well as proposed unit

indicating storage area, plant area,

greenbelt area, utilities etc. If

located within an Industrial area/

Estate/Complex, layout of

Industrial Area indicating location

of unit within the Industrial area/

Estate.

Included in Chapter 2, Figure 2.4

(Page no. 2-5).

vii. Photographs of the proposed and

existing (if applicable) plant site. If

existing, show photographs of

plantation/greenbelt, in particular.

Attached as Annexure-III.

viii. Land use break-up of total land of

the project site (identified and

acquired), government/private -

agricultural, forest, wasteland,

water bodies, settlements, etc.

shall be included. (Not required for

industrial area).

Land use breakup is included in

Chapter 3, Table 3.2 (Page 3-4).

ix. A list of major industries with

name and type within study area

(10km radius) shall be

Incorporated. Land use details of

the study area.

A list of major industries with name

and type within study area is

provided in Chapter 1, Section 1.11

(Page no. 1-21).

Land use details of the study area

are included in Chapter 3, Section

3.6 (Page no. 3-3).



x. Geological features and Geo-

hydrological status of the study

area shall be included.

Geological features and Geo-

hydrological status of the study

area is included in Chapter 3,

Section 3.9 (Page no. 3-10).

xi. Details of Drainage of the project

up to 5 km radius of study area. If

the site is within 1 km radius of

any major river, peak and lean

season river discharge as well as

flood. Occurrence frequency based

on peak rainfall data of the past 30

years. Details of Flood Level of the

project site and maximum Flood

Level of the river shall also be

provided. (mega green field

projects)

There is no river & flood hazard

zone within 1 km radius from the

project site.

xii. Status of acquisition of land. If

acquisition is not complete, stage

of the acquisition process and

expected time of complete

possession of the land.

Land document are attached as

Annexure-IV.

xiii. R&R details in respect of land in

line with state Government policy.

No, R&R is involved.

5. Forest and wildlife related issues (if applicable):

i. Permission and approval for the

use of forest land (forestry

clearance), if any, and

recommendations of the State

Forest Department. (if applicable)

Not applicable.

(Project does not involve forest

land; and

Site is not located within 10 km of

the National Parks, Sanctuaries,

Biosphere reserves, Migratory

Corridors of Wild Animals)

ii. Land use map based on High

resolution satellite imagery (GPS)

of the proposed site delineating

the forestland (in case of projects

involving forest land more than 40

ha).

iii. Status of Application submitted for

obtaining the Stage I forestry

clearance along with latest status

shall be submitted.

iv. The projects to be located within

10 km of the National Parks,

Sanctuaries, Biosphere Reserves,

Migratory Corridors of Wild

Animals, the project proponent

shall submit the map duly

authenticated by Chief Wildlife

Warden showing these features



vis-à-vis the project location and

the recommendations or

comments of the Chief Wildlife

Warden-thereon.

v. Wildlife Conservation Plan duly

authenticated by the Chief Wildlife

Warden of the State Government

for conservation of Schedule I

fauna, if any exists in the study

area.

Not applicable.

No endangered floral or faunal

species has been recorded within

the study area.

vi. Copy of application submitted for

clearance under the Wildlife

(Protection) Act, 1972, to the

Standing Committee of the

National Board for Wildlife.

6. Environmental Status

i. Determination of atmospheric

inversion level at the project site

and site-specific micro-

meteorological data using

temperature, relative humidity,

hourly wind speed and direction

and rainfall.

Briefly covered in Chapter 3,

Section 3.7 (Page 3-5).

ii. AAQ data (except monsoon) at 8

locations for PM10, PM2.5, SO2, NOX,

CO and other parameters relevant

to the project shall be collected.

The monitoring stations shall be

based CPCB guidelines and take

into account the pre-dominant

wind direction, population zone

and sensitive receptors including

reserved forests.

AAQ data at 8 locations are

tabulated in Table 3.12 to 3.17 on

Page no. 3-26 to 3-31.

Air monitoring stations are shown

Figure 3.7, Page no. 3-53.

iii. Raw data of all AAQ measurement

for 12 weeks of all stations as per frequency given in the NAAQM

Notification of Nov. 2009 along with - min., max., average and 98% values for each of the AAQ

parameters from data of all AAQ stations should be provided as an

annexure to the EIA Report.

Briefly covered in Chapter 3, Table

3.13 to 3.17 (Page 3-27 to 3-31).

iv. Surface water quality of nearby

River (100m upstream and

downstream of discharge point)

and other surface drains at eight

locations as per CPCB/MoEF&CC

guidelines.

Unit will not discharge in surface

water.

Results of surface water monitoring

at eight locations are covered in

Chapter 3, Table 3.20 (Page no. 3-

34).



v. Whether the site falls near to

polluted stretch of river identified

by the CPCB/MoEF&CC, if yes give

details.

No, the site doesn‟t falls near to

polluted stretch of the river

identified by CPCB/MoEF&CC.

vi. Ground water monitoring at

minimum at 8 locations shall be

included.


3.19 (Page no. 3-33).

vii. Noise levels monitoring at 8

locations within the study area.


3.22 (Page no. 3-36).

viii. Soil Characteristic as per CPCB

guidelines.


3.24 (Page no. 3-37).

ix. Traffic study of the area, type of

vehicles, frequency of vehicles for

transportation of materials,

additional traffic due to proposed

project, parking arrangement etc.


3.27 (Page no. 3-44).

x. Detailed description of flora and

fauna (terrestrial and aquatic)

existing in the study area shall be

given with special reference to

rare, endemic and endangered

species. If Schedule-I fauna are

found within the study area, a

Wildlife Conservation Plan shall be

prepared and furnished.


3.25 (Page no. 3-38) & 3.26 (Page

no. 3-42).

No endangered floral or faunal

species has been recorded within

the study area.

xi. Socio-economic status of the study

area.

Briefly covered in Chapter 3,

Section 3.14 (Page no. 3-21); and

Table 3.29 (Page no. 3-46) & 3.30

(Page no. 3-48).

7. Impact and Environment Management Plan

i. Assessment of ground level

concentration of pollutants from

the stack emission based on site-

specific meteorological features. In

case the project is located on a

hilly terrain, the AQIP Modeling

shall be done using inputs of the

specific terrain characteristics for

determining the potential impacts

of the project on the AAQ.

Cumulative impact of all sources of

emissions (including

transportation) on the AAQ of the

area shall be assessed. Details of

the model used and the input data

used for modeling shall also be

provided. The air quality contours

Assessment of ground level

concentration of pollutant from the

stack emission superimposed on

geographical area map based on

the site specific meteorological

features is covered in Chapter 4,

Figure 4.1 to 4.4 (Page no. 4-21 to

4-24).

The modeling approach is briefly

covered in Chapter 4, Section 4.4.1

(Page no. 4-4).

Input parameters used for modeling

are provided in Table 4.1 (Page no.

4-15), additional inputs - maximum

50 (24-hr) average concentration

values for SPM, SO2, NOx, HCl are

given in Table 4.3 to 4.6 (Page no.



shall be plotted on a location map

showing the location of project

site, habitation nearby, sensitive

receptors, if any.

4-17 to 4-20).

Cumulative impact of all sources of

emissions on AAQ of the area is

given in Table 4.2 (Page no. 4-16).

ii. Water Quality modeling -in case of

discharge in water body

Not applicable, as Unit will not

discharge in water body.

iii. Impact of the transport of the raw

materials and end products on the

surrounding environment shall be

assessed and provided. In this

regard, options for transport of

raw materials and finished

products and wastes (large

quantities) by rail or rail-cum road

transport or conveyor-cum-rail

transport shall be examined.

Traffic study is provided in Chapter

3, Table 3.27 (Page no. 3-44). The

impact of the transport of raw

material and the end products on

the surrounding environment will be

insignificant, so rail or rail-cum road

transport of conveyor-cum- rail

transport is not required at this

point.

iv. A note on treatment of wastewater

from different plant operations,

extent recycled and reused for

different purposes shall be

included. Complete scheme of

effluent treatment. Characteristics

of untreated and treated effluent

to meet the prescribed standards

of discharge under E(P) Rules.

Treatment of wastewater from

different plant operations, extent

recycled and reuse for different

purposes is briefly described in

Chapter 2, Section 2.9.1 (Page no.

2-26).

ETP units are given in Table 2.11

(Page no. 2-29 & 2-30) and ETP

flow diagram is given in Figure 2.6

(Page no. 2-28) & Figure 2.7 (Page

no. 2-29).

Characteristic of untreated and

treated effluent is given in Table

2.12 (Page no. 2-30).

v. Details of stack emission and

action plan for control of emissions

to meet standards.

Details of stack emission are

covered in Chapter 2, Section 2.8.2

(Page no. 2-23), Table 2.8 (Page

no. 2-24) & action plan for control

of emissions to meet standards re

given in Section 2.9.2 (Page no. 2-

31).

vi. Measures for fugitive emission

control.

Measures for fugitive emission

control are covered in Chapter 2,

Section 2.9.2 (Page no. 2-31).

vii. Details of hazardous waste

generation and their storage,

utilization and management.

Copies of MOU regarding utilization

of solid and hazardous waste in

cement plant shall also be

included. EMP shall include the

Details of hazardous waste

generation and their management

are covered in Chapter 2, Section

2.8.3 & Table 2.10 (Page no. 2-25)

& 2.9.3 (Page no. 2-31).

Concepts of resource & energy

conservation and cleaner production



concept of waste-minimization,

recycle/reuse/recover techniques,

Energy conservation, and natural

resource conservation.

are covered in Chapter 10, Section

10.7 & 10.8 (Page no. 10-16).

viii. Proper utilization of fly ash shall be

ensured as per Fly Ash

Notification, 2009. A detailed plan

of action shall be provided.

A detailed plan of fly ash

management is covered in Chapter

10, Section 10.3.3 (Page no. 10-6).

ix. Action plan for the green belt

development plan in 33% area i.e.

land with not less than 1,500 trees

per ha. Giving details of species,

width of plantation; planning

schedule etc. shall be included.

The green belt shall be around the

project boundary and a scheme for

greening of the roads used for the

project shall also be incorporated.

Layout plan earmarking space for

development of green belt is

provided in Chapter 2, Figure 2.4

(Page no. 2-5).

Greenbelt Development Plan is

provided in Chapter 10, Section

10.3.5 (Page no. 10-7).

x. Action plan for rainwater

harvesting measures at plant site

shall be submitted to harvest

rainwater from the roof tops and

storm water drains to recharge the

ground water and also to use for

the various activities at the project

site to conserve fresh water and

reduce the water requirement

from other sources.

Action plan for rainwater harvesting

is provided in Chapter 2, Section

2.10 (Page no. 2-32).

xi. Total capital cost and recurring

cost/annum for environmental

pollution control measures shall be

included.

Total capital cost and recurring cost/annum for environmental

pollution control measures is included in Chapter 10, Section 10.5 (Page no. 10-13).

xii. Action plan for post-project

environmental monitoring shall be

submitted.

Action plan for post-project

environmental monitoring is included in Chapter 10, Section

10.4 (Page no. 10-11).

xiii. Onsite and Offsite Disaster

(natural and Man-made)

Preparedness and Emergency

Management Plan including Risk

Assessment and damage control.

Disaster management plan should

be linked with District Disaster

Management Plan.

Onsite and Offsite Disaster (natural

and man-made) Preparedness and

Emergency Management Plan are

included in Chapter 7, Section 7.19

(Page no. 7-29) & Section 7.24

(Page no. 7-39).

8. Occupational health:

i. Plan and fund allocation to ensure

the occupational health & safety of

Occupational health & safety plan is

given in Chapter 10, Section 10.3.6



all contract and casual workers. (Page no. 10-9); and Chapter 7,


Fund allocation is mentioned in

Chapter 10, Section 10.5 (Page no.

10-13).

ii. Details of exposure specific health

status evaluation of worker. If the

workers‟ health is being evaluated

by pre designed format, chest x

rays, Audiometry, Spirometry,

Vision testing (Far & Near vision,

color vision and any other ocular

defect) ECG, during pre-placement

and periodical examinations give

the details of the same. Details

regarding last month analyzed

data of above mentioned

parameters as per age, sex,

duration of exposure and

department wise.

Occupational health & safety

programme is covered in Chapter 7,

Section 7.14 (Page no. 7-19); and

Chapter 10, Section 10.3.6 (Page

no. 10-9).

iii. Details of existing Occupational &

Safety Hazards. What are the

exposure levels of hazards and

whether they are within

Permissible Exposure Level (PEL)?

If these are not within PEL, what

measures the company has

adopted to keep them within PEL

so that health of the workers can

be preserved.

No existing Occupational & Safety

Hazards (as this is a new project

proposal).

Hazard analysis of materials is

provided in Chapter 7, Table 7.2

(Page no. 7-5). Properties of

Hazardous materials are given in

Table 7.3 (Page no. 7-7).

Acute Exposure Guideline Levels

(AEGLS) provided in Section 7.4.1

(Page no. 7-8); Emergency

Response Planning Guidelines

(ERPGs) provided in Section 7.4.2

(Page no. 7-9); Immediately

dangerous to life or health air

concentration values (IDLH values)

provided in Section 7.8 (Page no. 7-

12).

iv. Annual report of health status of

workers with special reference to

Occupational Health and Safety.

Not applicable

(new project proposal).

9. Corporate Environment Policy

i. Does the company have a well laid

down Environment Policy approved

by its Board of Directors? If so, it

may be detailed in the EIA report.

Environment Policy approved

provided in Chapter 10, section-

10.6.2 (Page no. 10-14).

Additionally, company will set up a

separate Environment Management



Cell and the objectives and duties

of it are discussed in Chapter 10,


ii. Does the Environment Policy

prescribe for standard operating

process/procedures to bring into

focus any infringement/deviation /

violation of the environmental or

forest norms/conditions? If so, it

may be detailed in the EIA.

Yes, It is discussed in Chapter 10,


iii. What is the hierarchical system or

Administrative order of the

company to deal with the

environmental issues and for

ensuring compliance with the

environmental clearance

conditions? Details of this system

may be given.

It is discussed in Chapter 10,


iv. Does the company have system of

reporting of non-compliances /

violations of environmental norms

to the Board of Directors of the

company and/or shareholders or

stakeholders at large? This

reporting mechanism shall be

detailed in the EIA report.

Yes, It is discussed in Chapter 10,


10. Details regarding infrastructure

facilities such as sanitation, fuel,

restroom etc. to be provided to the

labor force during construction as

well as to the casual workers

including truck drivers during

operation phase.

It is discussed in Chapter 10,


11. Enterprise Social Commitment (ESC)

i. Adequate funds (at least 2.5 % of

the project cost) shall be

earmarked towards the Enterprise

Social Commitment based on

Public Hearing issues and item-

wise details along with time bound

action plan shall be included.

Socio-economic development

activities need to be elaborated

upon.

Industry proposes to allocate Rs.

16.0 Lakhs; 2.0% of project cost

towards Corporate Social

Responsibility. Detailed CER

activities with budgetary provision

are given in Chapter-7, Part (B),

Page no. 7-42.

It is also given in Section 10.9 &

Table 10.3, Page no. 10-17 to 10-

18.

12. Any litigation pending against the

project and/or any direction/order

passed by any Court of Law

No pending litigation against the

project and/or any direction/order

passed by any Court of Law against



against the project, if so, details

thereof shall also be included. Has

the unit received any notice under

the Section 5 of Environment

(Protection) Act, 1986 or relevant

Sections of Air and Water Acts? If

so, details thereof and compliance/

ATR to the notice(s) and present

status of the case.

the project.

13. A tabular chart with index for point

wise compliance of above TORs.

Done

B Specific Terms of Reference

1 Details on solvent to be used,

measures for solvent recovery and

for emission control.

There will be no use of any solvent.

2 Details of process emission from

the unit and its arrangement to

control.

It is briefly described in Chapter 2,

Table 2.8.2 (Page no. 2-23) & 2.9.2

(Page no. 2-31).

3 Ambient air quality data should

include VOC, other-process-

specific pollutants* like NH3*,

chlorine*, HCl*, HBr*, H2S*, HF*,

etc. (*-as applicable)

Ambient air quality data includes

VOCs, HC, CO & process-specific

pollutant - HCl are included in Table

3.17 (Page no. 3-31).

4 Work zone monitoring

arrangements for hazardous

chemicals.

It is described in Chapter 10, Table

10.1 (Page no. 10-12).

5 Detailed effluent treatment

scheme including segregation of

effluent streams for units adopting

„Zero‟ Liquid Discharge.

It is described in Chapter 2, Section

2.9.1 (Page no. 2-26).

6 Action plan for odour control to be

submitted.

It is described in Chapter 10,

Section 10.3.1.3 (Page no. 10-4).

7 A copy of the Memorandum of

Understanding signed with cement

manufactures indicating clearly

that they co-process organic solid

/Hazardous waste in TSDF if any.

Unit will consider obtaining such

Memorandum of Understanding

signed with cement manufacturers

after commissioning of plant.

8 Authorization/Membership for the

disposal of liquid effluent in CETP

and solid/hazardous waste in

TSDF, if any.

Unit will send treated effluent at

Chhatral Environment Management

System Pvt. Ltd. for spray drying.

Membership certificate is attached

as Annexure-V.

Unit will obtain membership of

TSDF before establishment.

9 Action plan for utilization of MEE/

dryers salts.

No generation of such salts.



10 Material Safety Data Sheet for all

the Chemicals are being used/will

be used.

Attached as Annexure-VI.

11 Authorization/Membership for the

disposal of solid/hazardous waste

in TSDF.

Unit will obtain membership of

TSDF before establishment.

12 Details of incinerator if to be

installed.

Not applicable

13 Risk assessment for storage and

handling of hazardous chemicals/

solvents. Action plan for handling

& safety system to be

incorporated.

Risk assessment for storage and

handling of hazardous chemicals is

covered in Chapter 7, Section 7.3

(Page no. 7-3), Section 7.4 (Page

no. 7-4). Hazard analysis of

materials is provided in Table 7.2

(Page no. 7-5) & Table 7.3 (Page

no. 7-7). Acute Exposure Guideline

Levels (AEGLS) provided in Section

7.4.1 (Page no. 7-8); Emergency

Response Planning Guidelines

(ERPGs) provided in Section 7.4.2

(Page no. 7-9); Immediately

dangerous to life or health air

concentration values (IDLH values)

provided in Section 7.8 (Page no. 7-

12). Quantitative risk assessment &

consequence analysis is covered in

Chapter-7, Section 7.11 (Page no.

7-14). Action plan for handling &

safety system is covered in Section

7.16 - 7.17 (Page no. 7-23 to 7-

25).

14 Arrangements for ensuring health

and safety of workers engaged in

handling of toxic materials.

It is briefly covered in Section 7.17

(Page no. 7-25).

1.9 OBJECTIVE OF EIA

The objectives of the present EIA study are to identify potential source of

pollution, assess the impacts on various environmental components due

to the proposed project activity, and recommend appropriate

environmental management system and environment management plan

for the unit to ensure that the adverse impacts, if any, will be minimized.

1.10 METHODOLOGY FOR EIA

Considering the nature and magnitude of the project, surrounding area

and various guidelines available, an area of 10-km radius from the center



of proposed plant site was considered for the purpose of environmental

impact assessment study. The methodology is briefly reported below,

Baseline data collection:

The baseline data for the impact zone have been generated for the

following environmental parameters.

Ambient Air Quality

Micrometeorology

Noise Level

Surface &Ground Water Quality

Soil Quality

Ecology &Biodiversity

Land use pattern

Socio-Economics

The baseline status of the above environmental parameters has been

worked out based on the rapid monitoring/analysis carried out during the

study period of January, 2019 to March, 2019 supplemented by data

collected from various Govt. Dept., census publications etc. The data is

collected and analyzed as per the standard methods for establishing the

baseline data and so determine the impact of proposed activity on the

same.

Evaluation of Impact from Project Activities

The Environmental Impact resulting from the various project activities,

have been identified, predicted and evaluated based on the study of

manufacturing process and other project related activities as well as

correlating the same with existing baseline status.

Preparation of Environmental Management Plan

Environmental Management Plan has been prepared covering pollution

prevention measures at source in terms of air and water pollution control

measures, solid waste/hazardous waste management, safety

management, greenbelt development, environmental surveillance and

environmental surveillance and environmental management team.

Finally, the detailed assessment of the resultant environmental impacts

have been made based on the impacts identification and evaluated from

the activities over the baseline status of various environmental



components to reduce the pollution and to delineate a comprehensive

environment management plan along with recommendations and

suggestions to improve environment management system.

1.11 LIST OF INDUSTRIES SURROUNDING PROJECT SITE

List of industries in the study area are shown below.

Name of Industries Activities

Torrent Pharma Pvt. Ltd. Pharmaceutical Industry

Jainson Cables India Pvt. Ltd. Cable Manufacturer

Sachin Industries Pvt. Ltd. Glass Lined Reactors Manufacturer

Ratnamani Healthcare Pharmaceutical Industry

Ratnamani Metals & Tube Pvt.

Ltd.

Metal Tubes Manufacturer

TLT Engineering Pvt. Ltd. Engineering Unit

Apollo Imfratech Pvt. Ltd. Concrete Manufacturer

Venu Proteins Ltd. Gram Flour Manufacturer

Sundek India Ltd. Laminates Manufacturer

Milton Industries Ltd. Laminates & Artificial Leather

Manufacturer

Ambuja Intermediates Ltd. Pigments, Intermediates, Specialty

Chemicals, & Dyestuffs Manufacturer

Ambuja Solvex Pvt. Ltd. Castor Oil Manufacturer

Ratnadeep Metal Tube Ltd. Metal Tube Manufacturer

Paras Bhavani Steel Pvt. Ltd. Stainless Steel Pipes & Tubes

Manufacturer

Nebula Pharma Pvt. Ltd. Pharmaceutical Industry

Karan Paper Ltd. Paper Mill

Asahi Songwon Ltd. Pigments Manufacturer

Vikram Thermo (India) Ltd. Pharmaceutical Industry

Asian Tubes Ltd. Metal Tubes Manufacturer

R K Paper Mill Paper Mill

1.12 STRUCTURE OF REPORT

The report consists of twelve chapters and the content is briefly described

in this section.

Chapter 1: Introduction

The chapter gives brief outline of the project and its proponent, brief

description nature, size and location of the project, purpose of the EIA

study including the scope of the study, TORs compliance etc. and work

to be covered under each Environmental component.



Chapter 2: Project Description

This chapter includes project details and Infrastructure facilities

including all industrial & environmental aspects of the unit as well as

manufacturing process details. It also gives information about utilities,

raw material, water & wastewater quantitative details, stack details,

hazardous waste generation, storage & disposal facility.

Chapter 3: Description of the Environment

This chapter covers data of existing condition of Valued Environmental

Components like air, water, noise, soil, biological environment and

socio-economic aspects, basic amenities land use pattern. It also gives

details of study area, period of study, component of environment & its

methodology. Various sections of the chapter discuss the existing land

use and drainage pattern, climate and meteorological parameters.

Both primary and secondary data collected for the study are depicted

in this chapter.

Chapter 4: Anticipated Environmental Impacts and Mitigation

Measures

This chapter describes the overall impacts of the project activities on

various environmental components. It predicts the overall impact of

the project activities on different components of the environment viz.

Air, Water, Land, Noise, Biological and Socio-Economic and its

mitigation measures.

Chapter 5: Analysis of Alternatives

This chapter gives details of analysis of alternatives in terms of

technology & site.

Chapter 6: Environmental Monitoring Programme

This chapter describes technical aspects of monitoring (including

measurement methodologies, frequency, location and data analysis,

reporting schedules, emergency procedures, detailed budget and

procurement schedules.

Chapter 7: Additional Studies

This chapter describes Risk assessment and on-site, off-site

emergency plan and occupational health & safety programme.



Chapter 8: Project Benefits

This chapter focuses on benefits of project on improvement in physical

infrastructure, social infrastructure & other tangible benefits.

Chapter 9: Environmental Cost Benefit Analysis

Chapter 10: Environmental Management Plan

This chapter describes Environment Management Plan (EMP) to be

adopted for mitigation of anticipated adverse impacts if any and to

ensure acceptable impacts.

Chapter 11: Summary & Conclusion

It gives brief of the EIA Report and chapters there in. It also describes

about overall justification for implementation of the project and

explanation on various mitigation measures.

Chapter 12: Disclosure of Consultants engaged

This chapter describes the name of the consultant engaged with their

brief nature of consultancy activities.



Chapter 2

Project Description

2.1 INTRODUCTION

M/s. Urmit Chemicals Pvt. Ltd. is a Greenfield project proposed to be

located at Survey No. 1384, Village: Rajpur, Tal: Kadi, Dist: Mehsana for

manufacturing of various Dyes and Dye Intermediates namely Dyes

Intermediates - 150 MTPM, Acid Dyes, Direct dyes and Reactive Dyes -

100 MTPM, Basic Dyes - 50 MTPM, Basic Dyes liquid - 100 MTPM.

Cumulative production of above products will be tuned around 400 MTPM.

Production details are summarized in Table 2.3.

Total cost of proposed project is Rs. 8.0. Crores. Out of which, Rs. 3.15

Crores will be earmarked to development of EMS as capital investment

and around Rs. 4.017 Crores will be recurring cost per annum. Time of

project completion will be about 1.5 – 2.0 years after accordance of the

EC.

As per the EIA Notification, 2006, proposed activities falls under the

Project or Activity - 5(f) - Synthetic organic chemicals industry (dyes &

dye intermediates; bulk drugs and intermediates excluding drug

formulations; synthetic rubbers; basic organic chemicals, other synthetic

organic chemicals and chemical intermediates) and categorized under

“A”.

Based on the type of project, following are the expected aspects:

Air Emission,

Waste water generation,

Noise generation,

Hazardous waste generation, and

Occupational health, hazards & safety risk.

2.2 LOCATION OF THE PROJECT

The project site is located at Survey No. 1384, Village: Rajpur, Tal: Kadi,

Dist.: Mehsana, Gujarat. Location of the project, Google map of 10 km

radius and boundary coordinates of the site are shown in Figure 2.1,

Figure 2.2, and Figure 2.3, respectively. The project site is

approachable by Road via Ahmedabad-Mehsana State Highway – SH-41



at an aerial distance of 1.0 Km. Nearest Railway Station and Airport are

Kadi Railway Station at about 11.0 km and Sardar Vallabhbhai Patel

International Airport, Ahmedabad at about 38.0 km, respectively.

Figure 2.1 Location of the project site



Figure 2.2 Google map of 10 km radius

Figure 2.3 Image showing location of the with its coordinates

Table 2.1 Boundary coordinates of the site

A 23°20'49.65"N 72°24'25.32"E

B 23°20'48.15"N 72°24'24.92"E

C 23°20'47.22"N 72°24'28.97"E

D 23°20'48.68"N 72°24'29.44"E



2.3 SIZE OR MAGNITUDE OF OPERATION

2.3.1 Land Breakup & Project Site Layout

Land area for the project is 5662 m2. Greenbelt will be developed in 1870

m2 which is tune around 33% of the project area. The detailed proposed

land break up is given below in Table 2.2, whereas the site layout map is

given in the Figure 2.4.

Table 2.2: Land breakup

Sr. No. Particulars Area (m2)

1 Admin + Lab 150

2 Parking 100

3 Raw Material Storage 300

4 Chlorine Storage 75

5 Liq. Raw material storage 75

6 Finished Good Storage 250

7 Dyes Intermediates 500

8 Dyes Plant 500

9 ETP 175

10 Fuel Storage 300

11 Utility area 275

12 Green Belt Area 1870

13 Road Area 1092

Total 5662



Figure 2.4 Plant Layout

2.3.2 Project Magnitude

The design capacity of the multi-purpose plant of Dyes Intermediates will

be 150 MTPM and 250 MTPM of different type of dyes. Urmit Chemicals

Pvt. Ltd. proposes to manufacture several products simultaneously based

on the market demand. Complete list of products proposed to be

manufactured is provided in Table 2.3.

Table 2.3: List of products with its capacity

Sr. No.

Name of Products Quantity (MTPM)


1. Chloranil 150





6. Metanilic Acid






Sr. No.


(4 CAPSA)



12. 6 Nitro 2 Amino Phenol 4 Sulphonic Acid (6 NAPSA)


(4 NAPSA)

14. 6-Chloro-2-Amino Phenol-5-Sulphonic Acid (6 CAPSA)

15. 2 Pyridone



(1:4 SPMP)

18. 2:5 Dichloro 4 Sulpho Phenyl 3 Methyl 5 Pyrazolone (2:5 DCSPMP)


(2:5 CSMP)

20. 1,3 Sulpho Phenyl 3 Methyl 5 Pyrazolone (1:3 SPMP)



(B) Dyes

Acid Dyes 100

1. Acid Yellow 79

2. Acid Yellow 151

3. Acid Yellow 49

4. Acid Yellow 99

5. Acid Yellow 194

6. Acid Yellow 220

7. Acid Yellow 232

8. Acid Brown 75

9. Acid Brown 165

10. Acid Brown 161

11. Acid Brown 282

12. Acid Brown 432

13. Acid Brown 425

14. Acid Brown 434

15. Acid Green 16

16. Acid Blue 9

17. Acid Blue 15



Sr. No.


18. Acid Blue 7

19. Acid Blue 113

20. Acid Blue 193

21. Acid Red 315

22. Acid Black 107

Direct Dyes

23. Direct Black 80


25. Direct Brown 44

26. Direct Blue 71


28. Direct Red 239

29. Direct Red 254


31. Direct Red 81

32. Direct Violet 9


34. Direct Black 19

Reactive Dyes





Basic Dyes Solid 50

39. Basic Brown 1

40. Basic Yellow 2

41. Basic Violet 1

42. Basic Green 4

43. Basic Green 1

44. Basic Blue 26


45. Basic Yellow 2

46. Basic Violet 1

47. Basic Green 4

48. Basic Green 1

49. Basic Blue 26

Total 400



2.4 INFRASTRUCTURE FACILITIES

The list of proposed plant equipment/machineries/utilities is given below

in Table 2.4.

Table 2.4: List of equipment and machineries

S. No.

Name of Equipment Capacity Number

1 MS Glass Lined Reactor 5 KL 7

2 MSRL Reactor 10 KL 10

3 SS/MS/CI Reactor 5 KL 10

4 MS Rubber Lined Reactor 75 KL 2

50 KL 3

20 KL 3

10 KL 3

5 Agitated Notch Filter 5 KL 2

6 Notch Filter 3 KL 2

7 Filter Press 48” x 48” 4

8 Centrifuge Filter 48” 3

9 Glass Column Scrubber -- 2

10 Alkali Scrubber -- 2

11 Vacuum Trey Dryer 200 Trey 1

12 Trey Dryer 600 Trey 1

13 Spin Flash Dryer 500 Liter/hr. 1

14 Spray Dryer 1000 Liter/hr. 1

15 HDPE Tank 10 KL 3

20 KL 2

40 KL 2

16 MS Tank 20 KL 3

50 KL 2

17 MS Blender 10 MT 2

5 MT 2

18 Ball Mill 0.5 MT 1

1 MT 1

2 MT 2

19 Ice Crusher -- 3

20 Pulverizer -- 3

List of Utilities

1 Boiler 1 T/hr. 1

2 T/hr 1

2 Hot Air Generator (HAG) 5 Lakhs Kcal/hr. 1

10 Lakhs Kcal/hr. 1

3 Thermic Fluid Heater

(TFH)

25 Lakhs Kcal/hr. 1

4 Cooling Tower 200 TR 1



5 Chilling Plant 200 TR 1

6 D.G. set 500 KVA 1

7 RO 25 m³/hr. 1

2.5 DESCRIPTION OF MANUFACTURING PROCESS

The company will use the Best Available Process Technology (BAT) for the

production. The manufacturing process of the product, chemical reactions

& mass balance of each products are given in Annexure-II.

2.6 PROJECT COMPONENTS

Components of the project include all facilities required for the operation,

which is summarized below:

a) Input Requirement: Raw materials, Water, Fuel, Power, Manpower

b) Utility requirement: Boilers, HAG, TFH, Cooling tower, Spray Dryer,

Scrubber, D.G. Set.

c) Treatment Facilities:

Water treatment facilities: ETP and RO

Air Pollution Control Facilities: Cyclone & bag filter for flue gas

stack, Water Scrubber, alkali scrubber for process stack.

Hazardous waste disposal facilities: Haz. waste storage facility

d) Other: Greenbelt and rain water harvesting

2.7 INPUT REQUIREMENTS

a) Raw material requirement:

The details of the raw material requirement with availability and mode of

transport are given in Table 2.5 below. The raw materials will be stored/

inventory will be maintained as per market requirement of the products

and production schedule.

Table 2.5 Raw material requirement, source & transportation

Sr.

No.

Product name Raw Material

Name

Quantity

MT/MT

Availability Transportation

Dyes Intermediates

1 Chloranil HCl 30% 1.000 Indigenous Road

Hydro Quinone 0.450 Indigenous Road

Chlorine Gas 1.136 Indigenous Road

2 OAP

(Ortho Amino

Phenol)

ONCB 1.480 Indigenous Road

Caustic Lye 0.850 Indigenous Road

H2 Gas 0.060 Indigenous Road

Catalyst 0.004 Indigenous Road

HCl 0.040 Indigenous Road



Sr.

No.


Name

Quantity

MT/MT


3 PAP

(Para Amino

Phenol)

PNCB 1.480 Indigenous Road




4 MAP (Meta

Amino Phenol)

Metanilic Acid 1.590 Indigenous Road

NaOH 0.750 Indigenous Road

5

Ortho Amino

Phenol Sulphonic

Acid (OAPSA)

OAP 0.580 Indigenous Road

H2SO4 0.520 Indigenous Road

Oleum 23% 0.425 Indigenous Road

6 Metanilic Acid Nitro benzene 0.720 Indigenous Road

Oleum (25%) 0.425 Indigenous Road


HCl (30%) 0.100 Indigenous Road

Iron Powder 0.125 Indigenous Road

7 6 Chloro

Metanilic Acid

ONCB 0.920 Indigenous Road


Oleum 0.425 Indigenous Road



8 4-Chloro 2-

Amino Phenol

(4 CAP)

2:5 DCNB 1.350 Indigenous Road

Caustic 0.300 Indigenous Road

Iron powder 0.125 Indigenous Road


9 4 Chloro-2-

Amino Phenol 5-

Sulphonic Acid (4

CAPSA)

4 CAP 0.650 Indigenous Road

Sulphuric Acid 0.520 Indigenous Road


10 4 NAP NaSH 0.515 Indigenous Road

Lime 0.220 Indigenous Road

2:4 DNCB 1.400 Indigenous Road

NaOH 0.300 Indigenous Road

11 5 NAP OAP 0.725 Indigenous Road

Acetic Anhydride 0.675 Indigenous Road

HNO3 0.450 Indigenous Road



12 6 NAPSA OAP 0.470 Indigenous Road




13 4 NAPSA Lime 0.220 Indigenous Road

NaSH 0.515 Indigenous Road

4 Nitro Chloro

Benzene

0.700 Indigenous Road






Sr.

No.


Name

Quantity

MT/MT


14 6 CAPSA 2 Chloro Phenol 0.580 Imported/

Indigenous

Road/

Sea






15 2 Pyridone Mono Ethyl Amine 0.400 Indigenous Road

Methyl Cyno

Acetate


Methyl Aceto

Acetate Ester



16 1:3 Phenyl

Methyl 5

Pyrazolone (PMP)

Aniline 0.435 Indigenous Road


NaNO2 0.330 Indigenous Road

Sodium Bi

Sulphite


Soda Ash 1.550 Indigenous Road

Methyl Aceto

acetate ester


17 1,4 Sulpho

Phenyl-3-Methyl-

5-Pyrazolone

(1:4 SPMP)

Sulfanlic Acid 0.536 Indigenous Road



SBS 0.804 Indigenous Road


Methyl Aceto

Acetate Ester


18 2,5 Dichloro 4

Sulfo Phenyl 3

Methyl 5

Pyrazolone

(DCSPMP)

2,5 Dichlror

Aniline






Caustic Soda Lye 0.714 Indigenous Road

Methyl Aceto

Acetate Ester


19 2 Chloro 5

Sulphophenyl 3

Methyl 5

Pyrazolone

6 Chloro Metanilic

Acid






Caustic Soda Lye 0.450 Indigenous Road

Methyl Aceto

Acetate Ester


20 1, 3 Sulpho

Phenyl 3 Methyl

5 Pyrazolone

Metanilic Acid 0.536 Indigenous Road





Sr.

No.


Name

Quantity

MT/MT


(1:3 SPMP) SBS 0.800 Indigenous Road


Methyl Aceto

Acetate Ester


21 2 Chloro Phenyl

3 Methyl 5

Pyrazolone

Ortho Chloro

Aniline



Sodium nitrite 0.275 Indigenous Road

Sodium Bi

Sulphite



Methyl

Acetoacetic Ester


22 Para Toluene

Phenyl Methyl 5

Pyrazolone

Para Toludine 0.415 Indigenous Road



Sodium Bi

Sulphite



Methyl

Acetoacetic Ester


Acid Dyes

1 Acid Yellow 79 DAP Ester 0.400 Indigenous Road


Soda ash 0.250 Indigenous Road

5-Amino-3-

methyl-1-(3-

sulfophenyl)

pyrazole


Caustic flakes 0.060 Indigenous Road

Common Salt 0.650 Indigenous Road

2 Acid Yellow 151 OPSAmide 0.500 Indigenous Road

Hydrochloric Acid 0.112 Indigenous Road

Sodium Nitrite 0.184 Indigenous Road

Aceto Acetanilide 0.483 Indigenous Road



Cobalt Sulphate 0.415 Indigenous Road


3 Acid Yellow 49 2, 5 Dichloro

Sulfanilic Acid




5-Amino PMP 0.400 Indigenous Road


4 Acid Yellow 99 4 NAPSA 0.285 Indigenous Road


Nitrite 0.085 Indigenous Road

Acetoacetinilide 0.222 Indigenous Road



Sr.

No.


Name

Quantity

MT/MT


Caustic Flakes 0.052 Indigenous Road


Salicylic Acid 0.185 Indigenous Road

BCS 0.380 Indigenous Road



5 Acid Yellow 194 4-NAPSA diazo 0.550 Indigenous Road



Acetoacetanilide 0.435 Imported/

Indigenous

Road/

Sea


Cobalt Sulphate,

20%


6 Acid Yellow 220 Anthranilic OAPSA 0.500 Indigenous Road



OCl Aceto

acetanilide




Cobalt Sulfate 0.230 Indigenous Road


7 Acid Yellow 232 5 Sulfo

Anthranilic Acid


Hydrochloric Acid 0.125 Indigenous Road


1-Phenyl 3 Methyl

5 Pyrozolone




Basic Chromium

Sulfate



8

Acid Brown 75 Picramic acid 0.192 Indigenous Road

Hydrochloric acid 0.675 Indigenous Road


Caustic lye 0.090 Indigenous Road

Resorcinol 0.096 Indigenous Road

H-Acid 0.278 Indigenous Road



PNA 0.113 Indigenous Road

9 Acid Brown 165 Picramic acid 0.192 Indigenous Road

Hydrochloric acid 0.675 Indigenous Road






Sr.

No.


Name

Quantity

MT/MT


H-Acid 0.278 Indigenous Road


PNA 0.113 Indigenous Road

Ferrous Sulphate 0.260 Indigenous Road

10 Acid Brown 161 Anthranilic acid 0.190 Indigenous Road

Sulphuric acid 0.190 Indigenous Road

Formaldehyde 0.080 Indigenous Road




Aniline 2,4 SO3H 0.190 Indigenous Road





B.C.S 0.200 Indigenous Road

11 Acid Brown 282 6-Nitro 0.200 Indigenous Road

Beta Napthol 0.100 Indigenous Road



B.C.S. 0.180 Indigenous Road

4NAP 0.175 Indigenous Road



PMP 0.200 Indigenous Road

12 Acid Brown - 432 Anthranilic Acid 0.180 Indigenous Road





Laurent Acid 0.300 Indigenous Road


Chromium

Fluoride

0.160 Imported/

Indigenous

Road/

Sea

Liquid Ammonia 0.300 Indigenous Road


13 Acid Brown 425 Anthranilic acid 0.149 Indigenous Road





O.T. 5 SA. 0.220 Indigenous Road


B.C.S. 0.320 Indigenous Road


14 Acid Brown - 434 Sodium Picramate 0.267 Indigenous Road



Sr.

No.


Name

Quantity

MT/MT





1,6 cleave acid 0.205 Indigenous Road



Ferrous Sulphate 0.260 Indigenous Road

15 Acid Green 16 Di Methyl Aniline 0.600 Indigenous Road

Formaldehyde 0.220 Indigenous Road

Sulphanilic Acid 0.010 Indigenous Road


MnO2 0.400 Indigenous Road

Napthaline 0.400 Indigenous Road



Napthalene

Disulphonic Acid


Sodium

dichromate


Oxalic Acid 0.160 Indigenous Road

16 Acid Blue 9 Ethyl Benzyl

Aniline Sulphonic

Acid


Ortho

Benzaldehyde

Sulphonic Acid





MNO2 0.150 Indigenous Road

Acetic Acid 0.300 Indigenous Road


17 Acid Blue 15 Ethyl Benzyl

Aniline Sulphonic

Acid


Di Ethyl meta

Toludine

0.210 Imported/

Indigenous

Road/

Sea






18 Acid Blue 7 Benzaldehyde

Disulfonic Acid


Ethyl benzyl

aniline







Sr.

No.


Name

Quantity

MT/MT






19 Acid Blue 113 Metanillic Acid 0.300 Indigenous Road



Alpha Napthyl

Amine





Phenyl Peri Acid 0.490 Indigenous Road


Sodium Acetate 0.300 Indigenous Road

20 Acid Blue 193 B Napthol 0.350 Indigenous Road


1,2,4 Diazo 0.690 Indigenous Road



21 Acid Red 315 4 NAPSA 0.225 Indigenous Road



PMP 0.320 Indigenous Road




5 NAP 0.138 Indigenous Road

22 Acid Black 107 6 Nitro 0.480 Indigenous Road

Beta Naphthol 0.120 Indigenous Road



Chromuim

Formate


Sodium Picramate 0.200 Indigenous Road



Beta Napthol 0.245 Indigenous Road

Direct Dyes

23 Direct Black 80 P-amino

acetanilide




Gamma Acid 0.430 Indigenous Road


Caustic soda 0.215 Indigenous Road

Mixed Cleves acid 0.195 Indigenous Road



Sr.

No.


Name

Quantity

MT/MT


24 Direct Yellow 11 PNTOSA 0.600 Indigenous Road


Spent H2SO4

(70%)


25 Direct Brown 44 MPD 0.405 Indigenous Road



Sulphanilic Acid 0.300 Indigenous Road

CS Lye 0.220 Indigenous Road

26 Direct Blue 71 C-Acid 0.165 Indigenous Road



Alpha Napthyl

Amine


Caustic Flake 0.080 Indigenous Road

Mix Cleave Acid 0.330 Indigenous Road

J acid 0.250 Indigenous Road


27 Direct Orange

118

O-Toludine 5

Sulphonic Acid




Sodium bi-

carbonate


J-Acid Urea 0.350 Indigenous Road


28 Direct Red 239 Browner's acid 0.250 Indigenous Road




J-Acid Urea 0.292 Indigenous Road

Sodium Bi

Carbonate


29 Direct Red 254 PAABSA 0.400 Indigenous Road




J-Acid 0.350 Indigenous Road

Caustic soda lye 0.150 Indigenous Road

30 Direct Violet 35 C-Acid 0.330 Indigenous Road



p-Cresidine 0.150 Indigenous Road


n-Phenyl J-Acid 0.327 Indigenous Road

Caustic lye, 48% 0.300 Indigenous Road

31 Direct Red 81 PAABSA 0.350 Indigenous Road



Sr.

No.


Name

Quantity

MT/MT




Na2CO3 0.100 Indigenous Road

Benzyl Chloride 0.150 Indigenous Road

Sodium Acetate 0.160 Indigenous Road

J acid 0.280 Indigenous Road

32 Direct Violet 9 Sulphanilic acid 0.180 Indigenous Road



p-Cresidine 0.150 Indigenous Road


n-Phenyl J-Acid 0.327 Indigenous Road


33 Direct Yellow 99 DNSDA 0.550 Indigenous Road

Para Anisidine 0.245 Imported/

Indigenous

Road/

Sea



Salt 0.500 Indigenous Road

34 Direct Black 19 PNA 0.210 Indigenous Road



H acid 0.245 Indigenous Road



MPD 0.155 Indigenous Road

SD-40 0.020 Indigenous Road

Reactive Dyes

35 Reactive Blue

198

Cyanuric Chloride 0.220 Imported/

Indigenous

Road/

Sea


Tamol 0.010 Indigenous Road

Aniline 2:4 DSA 0.320 Indigenous Road

Soda Bi Carb 0.120 Indigenous Road

Blue HEGN-Base 0.400 Indigenous Road


Dicamol 0.045 Indigenous Road

36 Reactive Blue

187

Ethylene Diamine 0.250 Indigenous Road

PNCBOSA 0.230 Indigenous Road


Sodium Sulphite 0.085 Indigenous Road

Chloronail 0.175 Indigenous Road

Sodium

bicarbonate




Ammonium 0.150 Indigenous Road



Sr.

No.


Name

Quantity

MT/MT


persulphate

Cyanuric Chloride 0.200 Indigenous Road/

Aniline 2,5

disulphuric acid


Nicotinic acid 0.250 Indigenous Road


Dedusting Oil 0.025 Indigenous Road

37 Reactive blue

220

Sulpho OAVS 0.650 Indigenous Road




Sulphamic acid 0.004 Indigenous Road


4-Sulpho

Hydrazone

0.450 Imported/

Indigenous

Road/

Sea

Copper sulphate 0.350 Indigenous Road

Soda Bi

Carbonate



SD-40 0.030 Indigenous Road

38 Reactive Blue

221

6-Acetyl OAPSA 0.250 Indigenous Road




Sulphamic acid 0.002 Indigenous Road

Sodium acetate 0.120 Indigenous Road


4-Sulpho

Hydrazone

0.350 Imported/

Indigenous

Road/

Sea

Copper Sulphate 0.250 Indigenous Road

CS Flakes 0.350 Indigenous Road

Salt 0.120 Indigenous Road

Cyanuric Chloride 0.150 Indigenous Road

Tamol 0.020 Indigenous Road

N-Ethyl MBE 0.220 Imported/

Indigenous

Road/

Sea

Soda Bi Carb 0.130 Indigenous Road


Basic Dyes

39 Basic Brown 1 MPD 0.215 Indigenous Road



MPD 0.430 Indigenous Road


40 Basic Yellow 2 Di Methyl Aniline 0.833 Indigenous Road

Formaline 0.313 Imported/

Indigenous

Road/

Sea




Sr.

No.


Name

Quantity

MT/MT


T G Urea 1.030 Indigenous Road

Sulphur 0.110 Indigenous Road

41 Basic Violet 1

Crystal

Di Methyl Aniline 0.670 Imported/

Indigenous

Road/

Sea

Para

Formaldehyde


Mono Ethyl

Aniline

0.330 Imported/

Indigenous

Road/

Sea


Caustic Soda 1.000 Indigenous Road


42 Basic Green 4

Crystal

Di Methyl Aniline 0.800 Indigenous Road

Benzaldehyde 0.360 Indigenous Road




Ethyl Cellulose 0.080 Indigenous Road


Oxalic Acid 0.600 Indigenous Road

43 Basic Green 1

Crystal

Di Ethylaniline 1.000 Indigenous Road






44 Basic Blue 26

Crystal

Di Methyl Aniline 0.450 Imported/

Indigenous

Road/

Sea

Para

Formaldehyde


Phenyl Alpha

naphthalamine





45 Basic Yellow 2

Liquid


Formaline 0.100 Imported/

Indigenous

Road/

Sea



Glycerin 0.033 Imported/

Indigenous

Road/

Sea

T G Urea 0.335 Indigenous Road

Sulphur 0.035 Indigenous Road

46 Basic Violet 1

Liquid


Para

Formaldehyde


Mono Ethyl

Aniline






Sr.

No.


Name

Quantity

MT/MT


47 Basic Green 4

Liquid






Ethyl Cellulose 0.030 Indigenous Road

48 Basic Green 1

Liquid

Di Ethylaniline 0.330 Indigenous Road


Urea 0.040 Indigenous Road



49 Basic Blue 26

Liquid


Para

Formaldehyde

0.040 Imported/

Indigenous

Road/

Sea

Phenyl Alpha

naphthalamine




b) Water requirement:

Total water requirement (Industrial + Domestic + Greenbelt) will be 178

KLD; out of which 103 KLD will be fresh water requirement and 75 KLD

will be recycle/treated water. Unit will satisfy its fresh water demand from

Bore well. Major water demand will be industrial – mainly process (45

KLD), Scrubber (14 KLD), Washing (25 KLD), Cooling (45 KLD) and Boiler

(30 KLD). Detailed break-up of each water consumption and water

balance diagram is given in Table 2.6 and Figure 2.5, respectively

Table 2.6 Breakup of water consumption & w/w generation

Sr. No.

Source Water Consumption

(KL/day)

Wastewater generation

(KL/day)

1. Domestic 9 7.5

2. Green Belt 10 --

3. Industrial

A Process 45 80

B Scrubber 14 2

C Washing 25 25

D Boiler 30 3

E Cooling 45 15

Total Industrial 159 125

Total (1 +2 + 3) 178 132.5

Less recycle 75 --

Actual fresh water

consumption

103 --



Figure 2.5 Water Balance Diagram

c) Power:

Total power requirement of the unit will be 500 kVA, which will be

sourced from Uttar Gujarat Vij Company Limited (UGVCL). Unit will also

install stand by D.G. Set (500 kVA) for supply of electricity during the

time of power supply fails.

Total Water Consumption 178 KLD (Fresh Water 103 KLD + Recycle 75 KLD)

Domestic

9.0

Process

59

Washing

15*+10=25

Utilities

75

Greenbelt 10

Soak pit 7.5

Dyes Int.

29.0

ETP-1 48.0

ETP-2 32.0 + 2.0 + 25.0 +3.0 + 15.0 = 77.0

3.0

Boiler

30

Cooling

45

15.0 48.0

0

20 H2SO4

25.0

Scrubber

14.0

Total volume

86.0

Spent Acid 30.0

Drying Loss

4.0

23 HCl

Water from RM-14

SBS +HCl

12.0

2.0

RO

77.0 Reject

17

Permeate water 60.0

Acetic Acid

4.0

Water from RM-19

Dyes 16.0

Ice-30

Drying Loss by SD 15

32.0

Total volume 65.0

UF 30.0

Water reuse 15*

Drying Loss by TD 3.0

* Common Spray Dryer facility operated by Chhatral Environment

Management system Pvt. Ltd.

48 + 17 = 65

to Common Spray Dryer*



d) Fuel:

36 TPD Low Sulfur Coal will be required to be used in Boiler, Hot Air

Generator (HAG) and Thermic Fluid Heater (TFH). Diesel will be used as

fuel in stand by D.G. set at the rate of 100 lit/hr. Details of fuel

consumption in each utility are given below in Table 2.7.

Table 2.7 Details of fuel consumption

Sr.

No.

Utility Capacity Fuel

Type

Consumption

Rate

1 Boiler-1 1 TPH

Coal

4 TPD

2 Boiler-2 2 TPH 8 TPD

3 HAG-1 5 lakhs Kcal/hr. 3 TPD

4 HAG-2 10 lakhs Kcal/hr. 6 TPD

5 TFH 25 lakhs Kcal/hr. 15 TPD

6 D.G. set 500 kVA Diesel 100 lit/hr.

e) Manpower:

Total manpower requirements will be 100, which include manpower at all

levels.

2.8 GENERATION OF POLLUTANTS

The sources of generation of pollutants are given below;

2.8.1 Wastewater Generation

Total wastewater generation will be 132.5 KLD, of which 7.5 KLD will be

domestic wastewater and the rest (125 KLD) will be industrial effluent.

The main source of the industrial wastewater generation will be from

process (80 KLD), Scrubber (2 KLD), Washing (25 KLD) and utilities

(Boiler & cooling - 18 KLD). The details of wastewater generation are

mentioned in Table 2.5. Water balance diagram is given in Figure 2.5.

2.8.2 Gaseous Emission

Flue gas emission will be from stack attached with Boilers, Thermic Fluid

Heater and Hot Air Generators where Coal will be used as a fuel; and

standby D.G. Set. Most probable pollutants will be SPM, SO2 and NOx.

Process emission will be from the reaction vessels of Multipurpose Plant –

2 sets, Reaction Vessels of Chloranil and one vent of Spray Dryer.

Corresponding pollutants will be SO2, HCl and PM.

The details of the flue gas stacks & process gas stacks and emission

quality of Stacks are given in Table 2.8 and Table 2.9, respectively.



Table 2.8 Details of stacks

Sr.

No.

Stack attached to Stack

Height

(m)

Fuel

&

consumption

APC measure Pollutants

Flue gas Stack-Proposed

1 Steam Boiler

(1 TPH)

21 Coal – 4 TPD Cyclone

followed by

bagfilter

PM<150 mg/Nm3

SO2<100 ppm

NOx<50 ppm

2 Steam Boiler

(2 TPH)


followed by

bagfilter

3 Hot Air Generator

(5 Lakhs Kcal/hr.)


followed by

bagfilter

4 Hot Air Generator

(10 Lakhs Kcal/hr.)


followed by

bagfilter


(25 Lakhs Kcal/hr.)


followed by

bagfilter

6 D G Set (Stand By)

(500 kVA)

11 Diesel – 100

Liter/hr.

--

Process gas Stack-Proposed

1 Spray Dryer

(20 Kl/day)

15 -- Cyclone +

Scrubber +

Submerged

type gas

bubbling tank

PM<45 mg/Nm3

2 Reaction Vessels of

Multipurpose Plant –

2 sets

21 -- Alkali Scubber SO2<40 mg/Nm3

3 Reaction Vessel of

Chloranil

11 -- Water Scubber HCl<20 mg/Nm3

Table 2.9 Estimated Emission quality of stack

Sr.

No.


Height

(m)

Temp.

(0C)

Velocity

(m/s)

Dia.

(m)

Concentration

(mg/Nm3)

SPM SO2 NOx

1 Steam Boiler 21 180 6.5 0.375 75 40 25

2 Steam Boiler 21 180 6.5 0.450 75 40 25

3 Hot Air Generator 21 190 7.5 0.375 80 40 30

4 Hot Air Generator 30 190 7.5 0.450 80 40 30

5 Thermic Fluid Heater 30 200 7.5 0.500 80 40 30

6 DG Set (Stand by) 11 210 15.0 0.300 60 40 40

7 Spray Dryer 15 55 5.5 0.450 PM = 35 mg/Nm3


Multipurpose Plant

11 50 5.0 0.225 SO2 = 30 mg/Nm3


Chloranil

11 50 5.0 0.225 HCl = 15 mg/Nm3

Sources of fugitive emission:

In proposed activities, there will be chances of generation of acid fumes

from material handling area, process area, storage area etc. There will be

also changes of generation of PM (Dust) from packing/finishing area.



2.8.3 Hazardous/Solid waste generation

Main source of hazardous waste will be wastewater treatment, generating

ETP sludge (150 MTPM). Hazardous waste from process will be HCl (20-

22%) (52 MTPM), Spent Sulphuric acid (780 MTPM), Calcium Thio

Sulphite (78 MTPM), Acetic Acid (104 MTPM), Sodium Bisulphite (260

MTPM), Iron sludge (52 MTPM) and Spent catalyst (0.5 MTPM). Discarded

containers (10000 Nos./month), liners (1.0 MTPM) and used lubricating

oil (0.5 Kl/yr). Fly ash generation will be around 5.0 MT/day.

The details of solid/hazardous waste generation with its category and

quantity are given in Table 2.10.

Table 2.10 Details of Solid/Hazardous waste

Sr.

No.

Type of Waste Category Quantity Disposal method

Hazardous waste

1 ETP Waste 35.3 150

MT/month

Collection, Storage &

disposal at TSDF site approved by GPCB.

2 HCl

(20-22%)

26.3 52

MT/month

Collection, Storage and sell to actual users under Haz.

Waste rule.

3 Spent Sulphuric

acid (H2SO4)

26.3 780

MT/month

Collection, Storage, Reuse with in the process or sold

to actual users.

4 Iron Sludge 26.1 52

MT/month

Collection, Storage,

Transportation, sell to cement manufacturer or

disposed at TSDF site.

5 Calcium Thio

Sulphite

-- 78

MT/month

Collection, Storage, Transportation, sell to actual users under Haz.

Waste rule.

6 Acetic Acid 26.3 104

MT/month

Collection, Storage, Reuse within the process or sold

to actual users under Haz. Waste rule.

7 Sodium

Bisulphite

26.3 260

MT/month

Collection, Storage, Reuse

within the process or sold

to actual users under Haz.

Waste rule.

8 Used Lubricating

Oil

5.1 0.5 Kl/year Collection, Storage & use within premises as

lubricant/sell to registered recycler.

9 Discarded containers/

barrels/

33.1 Barrels-10000

nos./month

Collection, Storage and reuse for packing of

products or disposal by



liners Liner-1.0 MT/month

selling to approved recycler.

10 Spent catalyst 28.2 0.5

MT/month

Collection, Storage & return back to supplier for

regeneration.

Solid Waste

1 Fly ash -- 5.0

MT/day

Collection, Storage, Sells to

brick manufacturers and/or also supplied for land

leveling, conditioning & road construction.

2.8.4 Noise generation

Main source of noise generation will be Boiler, Thermic Fluid Heater, Hot

Air Generator, D.G. set, process plant, vehicular transportation & other

machineries.

2.9 POLLUTION CONTROL STRATEGY

The unit is equally conscious about the pollution control strategy. The

details of pollution control strategy for various parameters are given here

under,

2.9.1 Effluent Management

Source of the industrial wastewater generation will be from process,

washing & utilities. Total quantity of industrial effluent generation will be

125.0 KLD. Wastewater generated from the industrial activities will be

segregated into two streams for treatment –

a) Concentrated stream from Dye Intermediates plant

b) Dilute stream from Dyes plant, scrubber, washing and utilities

Process effluent from Dye Intermediates plant (48 KLD) will be treated in

“ETP-1”. Then it will be sent to Common Spray Drying facility for

evaporation at Chhatral Environment Management System Pvt. Ltd.

Wastewater from Dyes plant, Scrubber, Washing and utilities (cooling &

boiler) (77 KLD) will be treated in “ETP-2”. After treatment, it will be

passed through RO. RO permeate (60 KLD) will be reused; RO reject (17

KLD) will be Spray Dried along with effluent of ETP-1 (48 KLD) in

common evaporation facility at Chhatral Environment Management

System Pvt. Ltd.

Domestic wastewater of 7.5 KLD will be discharged into soak pit.



Unit will built 2 separate ETPs for treatment of effluent generated from

proposed project. ETP1 (for concentrated effluent) – 50 m3/day and ETP2

(for dilute effluent) – 80 m3/day will be installed.

Effluent treatment scheme:

Flow diagram of ETP-1 and ETP-2 are given as Figure 2.6 and 2.7,

respectively. Design details of ETP and characteristics of wastewater are

given in Table 2.11 and Table 2.12 respectively.

Process wastewater (ETP-1): Effluent from industrial wastewater will

be passed through equalization tanks. In equalization tank, effluent will

be equalized and neutralized using alkali (Hydrated Lime). Then effluent

be passed through flash mixer provided with alum/poly dosing for

coagulation and then to flocculation tank to enhance the formation of

flocs. The effluent will then be led to filter press to remove solids. The

effluent from filter press will then be led for tertiary treatment and then

evaporated at Common Spray Drying facility at Chhatral Environment

Management System Pvt. Ltd. Sludge from sludge drying bed will be

packed in HDPE bags and sent to TSDF site for land filling.

Washing & Utilities wastewater (ETP-2): Effluent from scrubber,

washing and utilities will be collected into Equalization/Neutralization

Tank. In equalization tank, effluent will be equalized and neutralized.

Then effluent is passed through primary settling tank led to clarifier to

remove solids. The effluent from primary settling tank will then send for

tertiary treatment and then pass through RO system to recover

usable/recyclable water and reject of RO will be evaporated into Common

Spray Dryer at Chhatral Environment Management System Pvt. Ltd.



Figure 2.6 Flow Diagram of “ETP-1” for Process effluent

Sr. No. Name of Unit

1. Equalization/Neutralization Tank

2. Flash Mixer

3. Flocculator

4. Lime Dosing Tank

5. Alum Dosing Tank

6. Poly Floc Dosing Tank

7. Filter Press

8. Intermediate Holding Tank

9. Pressure Sand Filter

10. Holding Sump

11. Sludge storage area



Figure 2.7: Flow Diagram of “ETP-2” for Utilities + Washing

Sr. No. Name of Unit

1. Equalization Tank

2. Neutralization tank

3. Primary Settling tank

4. Lime Dosing Tank

5. Intermediate Holding Tank

6. Pressure Sand Filter

7. RO

8. Sludge sump

9. Filter press

Table 2.11 Details of Effluent Treatment Plant (ETP)

Details of “ETP-1” for Process effluent; Design Capacity-50 KLD

Sr.

No.

Name of Unit Dimension

(m)

No. of

Unit

Capacity

(m3)

1. Equalization/ Neutralization Tank

3.5 x 3.5 x 4.0 (3.5 WD)

2 43 each

2. Flash Mixer 2.0 x 2.0 x 2.5 (2.0 WD)

1 8

3. Flocculator 2.0 x 2.0 x 2.5

(2.0 WD)

1 8

4. Lime Dosing Tank HDPE Tank 1 2

5. Alum Dosing Tank HDPE Tank 1 1

6. Poly Floc Dosing Tank HDPE Tank 1 0.5

7. Filter press 36” x 36 Plats 2 -

8. Intermediates Holding

Tank

3.5 x 3.5 x 4.0

(3.5 WD)

1 43

9. Pressure Sand Filter Standard supply 1 5 m³/hr.

10. Holding sump 4.5 x 4.5 x 4 (3.5 WD)

1 70



Details of “ETP-2” for Utilities + washing; Design Capacity-80 KLD

Sr.

No.

Name of Unit Dimension

(m)

No. of

Unit

Capacity

(m3)

1. Equalization Tank 6.0 x 6.0 x 3.5 1 100

2. Neutralization tank 3.5 x 3.5 x 4.0

(3.5 WD)

1 43

3. Primary Settling tank 4.5 x 4.5 x 2.5 1 20.25

4. Lime Dosing Tank HDPE Tank 1 5

5. Intermediates Holding

Tank

5.0 x 5.0 x 4.0 1 100

6. Pressure Sand Filter Standard supply 1 5 m³/hr.

7. Holding Sump 4.0 x 4.0 x 3.5 1 56

8. Sludge sump Common for both ETP

9. Filter press Common for both ETP

10. RO Standard supply 1 5 m³/hr.

Table 2.12

Characteristic of untreated and treated effluent of Process W/w

Stream-1 (Process)

Parameters Unit Process After

Treatment

Equalize

(Stream-1

& Stream-2)

pH pH Unit 2.0-2.5 7.0-7.5 7.0-7.5

TSS mg/L 800-1000 75-100 150-175

TDS mg/L 22550-25000 22550-25000 22550-25000

BOD mg/L 4000-4500 3500-4000 3000-3500

COD mg/L 15000-20000 12000-15000 10000-12000

Phenol mg/L 25 20 65

Stream-2 (Washing & Utilities)

Parameters Unit Equalize After

Treatment

RO

Permeate

RO

Reject

pH pH Unit 6.7-7.3 7.5 7.5 7.3

TSS mg/L 250-300 75 5 320

TDS mg/L 2870-3645 5025 175 22150

BOD mg/L 255-330 300 5 1350

COD mg/L 990-1065 860 15 3850



2.9.2 Air Pollution Control Measures (APCM)

Flue Gas and Process Emission Control

There will be six flue gas stacks and three process gas stacks which are

the main emission source from the plant under the Air Pollution Control

Act, 1981. All the flue gas stacks except stack of D.G. Set will be

equipped with Cyclone & bag filter as APCM.

Spray Dryer will be equipped with Cyclone + Scrubber + Submerged type

gas bubbling tank. Alkali scrubbers will be provided on process gas stack

attached to reaction vessels of Multipurpose Plant and water scrubber will

be provided on process gas stack attached to Reaction vessel of Chloranil.

The details of the flue gas stacks & process gas stacks and emission

quality of Stacks are given in Table 2.8 and Table 2.9, respectively.

Fugitive Emission Control

To control fugitive emission, following steps will be implemented:

Adequate scrubbing system to absorb process gas.

Entire process will be carried out in closed reactors.

Pneumatically transfer of liquid raw material in rector.

Raw material will be stored in the covered structure.

Regular maintenance of valves, pipes etc.

PPEs will be provided to the workers.

Frequent work area monitoring will be done to ensure fugitive

emissions level.

Greenbelt will be developed around the plant to arrest the fugitive

emission.

2.9.3 Hazardous/Solid Waste Management

Entire quantity of hazardous waste will be handled & disposed as per

Hazardous & Other waste (Management & Transboundary Movement)

Rules, 2016. ETP sludge will be disposed of at approved TSDF site. Iron

sludge will be sold to cement manufacturer or disposed at TSDF site. HCl,

Calcium Thio Sulphite will be sold to actual users under Haz. Waste rule,

Spent Sulphuric acid (H2SO4), Acetic Acid, Sodium Bisulphite will be

reused within the process or sold to actual users. Spent catalyst will be

sent for regeneration to the suppliers. Discarded containers/liners will be

disposed of by selling to registered recyclers; used lubricating oil will be



disposed by selling to registered recyclers. The unit will provide isolated

area with impervious flooring & roof cover for the storage of hazardous

waste. Details of hazardous waste disposal are given in Table 2.10.

Fly Ash management

Fly ash generation will be around 5.0 MT/day. Fly ash will be sold to brick

manufacturer working in 25 km radius from project site and also supplied

to the companies for land leveling, conditioning & road construction, etc.

Methodology of Decontamination of Discarded Containers

As per the HAZ Rules, contaminated containers will be decontaminated in

plant and log book will be maintained for generation and disposals.

Separate area for decontamination of containers will kept. Contaminated

water will be treated with effluent in ETP-1.

2.9.4 Noise Pollution Control Measures

The main noise generating sources in the plant are operation of boiler,

HAG, TFH and D.G. set, material handling, and process plant among

other machineries. All these sources will generate continuous noise.

However, the noise transmitted outside the plant boundary will be low

because most of the noise generating equipment will be in closed

structures provided with acoustic enclosure. Equipment will be statically

and dynamically balanced. Ear muff, ear plug will be provided to all

workers working at noisy area. Additionally, extensive oiling, lubrication,

periodic monitoring and regular maintenance will be carried out for the

machineries and equipment to reduce noise generation. Moreover,

adequate greenbelt will be developed within premises and around the

periphery to prevent the noise pollution. By taking measures as

mentioned, it is anticipated that noise levels in the plant will be

maintained below the permissible limit.

2.10 RAIN WATER HARVESTING

The rain water from the building roofs will be directed through the

drainage to the covered storm water drainage line. All drainage system

will be concreted lined and located along the roads up to rain water

harvesting pit. Roof top rain water will be collected in tanks and reused

after filtration as per requirements.



2.11 GREENBELT DEVELOPMENT

Total land area is 5662 m2. The unit has already developed greenbelt

along the plan periphery, and is committed to maintain adequate

greenbelt in area of around 1870 m2 (33% of the total project area).

Additionally, the unit also has plans to develop the greenbelt in areas

available outside the plant premises if necessary.

2.12 OCCUPATIONAL HEALTH & SAFETY

Urmit Chemicals is concerned with the health, safety and environment

protection. The company will formulate and develop an „Occupational

Health & Safety Policy‟ to ensure good health and safety of its employees.

Following key safety measures shall be a part of the Health & Safety

policy of the company and shall be followed after the project

implementation:

Safety Training shall be provided to the employees.

Safety Sirens with Alarm System in case of emergency shall be

provided.

Fire Hydrant System shall be installed.

Fire Extinguishers shall be provided.

Mock drills shall be periodically conducted and factors like response

time shall be evaluated.

First Aid Facility and training shall be provided.

Personnel protective Equipment shall be provided to the employees.

Health check-ups shall be organized at regular intervals.

Safety/Health records and MSDS shall be maintained.



Chapter-3

Description of Environment

3.1 GENERAL

To assess environmental impacts from proposed project at a specific

location, it is essential to monitor the existing environmental quality

prevailing in the surrounding area prior to implementation of the project.

The environmental status within the impact zone could be used for

identification of significant environmental issues to be addressed in the

impact assessment study. Baseline data generation forms a part of the

Environmental Impact Assessment (EIA) study and helps to evaluate the

predicted impacts on the various environmental attributes in the study

area by using scientifically developed and widely accepted impact

assessment methodologies. This section contains the description of

baseline studies of 10 km radius surrounding the project site. The

baseline study was carried out to understand following environmental

parameters.

Land Environment

Meteorology

Air Environment

Water Environment

Soil Environment

Noise Environment

Biological Environment

Socio-economic Environment

The data collected has been used to understand the existing environment

scenario around the project site against which the potential impacts of

the proposed project can be assessed.

3.2 STUDY AREA

The unit proposed to be located at Survey No. 1384, Village: Rajpur, Tal:

Kadi, Dist: Mehsana, An area of 10 km radius from the boundary of the

project site is considered as study area for the EIA study as per the TOR

issued by MoEF&CC.



Table 3.1 Environmental setting of the study area

Features Details

Location Vill: Rajpur, Tehsil: Kadi, Dist: Mehsana

Coordinates of the site Latitude: 23°20'48.44"N


Altitude 79 m above MSL

Topography Plain

Survey of India

Toposheet No.

F43A7

Seismic Zone Seismic Zone-III

Nearest

Human habitation Chandarda, about 1.45 km

Rajpur, about 1.58 km



Railway Station Julasan, about 7.0 km, Kadi, about 11.0 km

Highway SH41 (Ahmedabad-Mehsana), about 1.0 km

Air Port Ahmedabad about 38.0 km

Water body Pond of Chandarda village, about 1.45 km

Reserve Forests/National Park/Wildlife Sanctuary

None within 10 km radius

Note: Aerial distances are mentioned in above table

3.3 STUDY PERIOD

Baseline environmental quality represents the background scenario of

various environmental components. As part of EIA study, baseline

environmental monitoring was done over a radial distance of 10 km

around the project site during the period of January, 2019 to March,

2019.

3.4 SOURCE OF ENVIRONMENTAL DATA GENERATION

Baseline information on micrometeorology, ambient air quality, water

quality, noise level, soil quality and ecology (flora-fauna) are generated

by M/s. San Envirotech Pvt. Ltd., Ahmedabad. Apart from these,

secondary data have been collected from census book, revenue records,

soil survey and forest department, meteorological department etc. The

generation of primary as well as collection of secondary data &

information from the site and surrounding was carried out during the

period of January, 2019 to March, 2019.



3.5 METHODOLOGY

The process & methodology adopted for various environmental attributes

in the study is as follows:

To assess the Air environment in the study area, monitoring of the Air

quality was done by setting up reconnaissance. The samples were

collected by installation of combined sampler (with gaseous

attachment) at different locations for monitoring of primary air

pollutants to work out the existing status of air quality.

Ground water samples & surface water samples were analyzed for the

parameters necessary to determine water quality (based on IS:

10500-2012 criteria) and those which are relevant from the point of

view of environmental impacts of the project site.

Soil samples were collected using an Auger and analyzed for relevant

physico-chemical characteristics in order to assess the impact on soil.

The noise level monitoring was done at various locations at different

intervals of time with the help of sound level meter.

Socio-economic data was collected from field studies and secondary

sources like Census of India 2011, Revenue record, etc.

3.6 LAND ENVIRONMENT

Land Cover is the physical material at the surface of the earth (includes

grass, trees, bare ground, water etc.); whereas Land use is the human

use of land. Studies on land use aspects of eco-system play an important

role in identifying susceptible issues and to take appropriate action to

uphold ecological equilibrium in the region. Main objective is to provide a

baseline status of the study area so that temporal changes due to the

proposed activities on the surroundings can be assessed in future.

3.6.1 Land use pattern of the Study Area

The study area of 10-km around the project site is considered in the land

use pattern study. The term land-use indicates the way in which the land

is utilized for different purposes. The land-use distribution of the study

area is given in Table 3.2. Land-use map is given in Figure 3.1.



Figure 3.1 Land use Map

Table 3.2 Land use statistics work out based on satellite imaginary

Level 1 Level 2 Area (Sq. km.) Area (%)

Agricultural Agricultural land 254.58 80.84

Built-up

land

Industrial & Commercial 17.09 5.51

Public utilities & Facility 0.61 0.18

Rural 11.61 3.55

Transportation 4.78 1.54

Urban 5.16 1.7

Waste land Scrub land 16.45 5.28

Water body Canal 2.52 0.8

Lake/Ponds 1.01 0.33

Reservoirs/Tanks 0.91 0.26

Total 314.72 100



3.6.2 Objective of Land Use Studies

The objectives of land use studies are (i) to develop land use & land cover

map using land coordinates of the project area, (ii) to identify and mark

important basic features according primary and secondary data, and (iii)

to suggest measures for conservation and sustainable use of land.

3.6.3 Topography and Drainage

The site area is plain with little undulating at few places. Agriculture and

allied activities are most predominant in this area. Fallow land and barren

lands were less observed near project site. There was no Eco Fragile Zone

or Natural Forest near project site in study area. Toposheet of location

with site location map of 10 km radius at 1:50,000 scale is shown in

Figure 3.12.

3.6.4 Seismicity of the area

The project site falls under seismic zone III. The Seismic Zone Map of

Gujarat is given below.

3.7 METEOROLOGY

Meteorology is the key to understand the air quality. Wind fluctuations

over a very wide range of time, accomplish dispersion and strongly

influence other processes associated with them. The micrometeorological

conditions at the project site will be regulating the transport and diffusion

of air pollutants released into the atmosphere.

3.7.1 Site specific micro-meteorological data

The data on surface meteorological parameters in the study area were

collected from January, 2019 to March, 2019 by setting up portable



weather monitoring station placed at project site. The sensor of the

equipment was kept at sufficient height (about 10 m) from ground level

with free exposure to the atmosphere. The monitoring methodology is

given in Table 3.3 & data collected are presented in Table 3.4.

The following parameters were recorded at hourly intervals during

monitoring period:

• Wind speed & Wind direction

• Temperature

• Relative humidity

• Rainfall

Table 3.3: Monitoring Methodology of Meteorological Data

Sr.

No.

Sampling

Parameters

Sample Collection Total

Sampling

Period

Sampling

Frequency

Methodology

Sampling

Equipment

Sensitivity/

Detection

Limit

1 Wind Speed Anemometer

cup counter

(0 to 65 m/s)

0.25 m/s January,

2019 to

March,

2019.

Hourly As per

manufacturer‟s

manual,

Instruments

are

Calibrated

2 Wind

Direction

Wind vane

(0° to 359°)

10

3 Temperature Thermometer

(-40° to 60°)

0.10C

4 Humidity Hygrometer 3%

5 Rainfall Rain gauge 0.5 mm

6 Cloud Cover -- -- 4 Hourly Visual

Inspection by

the observer

Table 3.4: Meteorological Data for the Monitoring Period

(January, 2019 to March, 2019)

Month Wind

speed

(km/hr.)

Pre

dominant

wind

direction

Temp. (0C) Relative

Humidity

(%)

Rain fall (mm)

Max Min Max Min Max Min 24 hrs.

highest

No. of

rainy days

Jan,19 21.0 0.0 ENE 33.0 12.0 83.0 17.0 No rainfall during

the study period Feb,19 15.0 0.0 ENE 35.0 13.0 70.0 8.0

March,19 32.0 0.0 NE 41.0 14.0 86.0 9.0

3.7.2 Wind Rose

Wind rose is the diagrammatic representation of wind speed in a specified

direction with its arms representing sixteen directions, each arms give a

clear frequency distribution of wind speed in a particular direction for a

given period of time. It is one of the most important meteorological

parameters and governs dispersion, diffusion & transportation of



pollutants. The % frequencies of wind in 16 directions have been

computed from the recorded data during the study period for 24-hourly

intervals to plot wind rose. The predominant wind directions –ENE, NNE,

NE, NW, NNW; implying that winds come from these directions for most

of the time during the period. The wind speed class 1-5 kmph occurred

for 3.61%, 6-10 kmph about 26.72%, 11-15 kmph 43.33% and above 15

kmph and below 40 kmph occurred for 12.78% of the study period. Calm

wind during this period is 13.56%. Wind rose diagram is shown as Figure

3.8.

3.8 AMBIENT AIR QUALITY

3.8.1 Introduction

To quantify the impact of the proposed project on the ambient air quality,

it is necessary to evaluate the existing ambient air quality of the area.

The ambient air quality monitoring with respect to the study area of 10

km radius around the project site was done for the baseline information.

3.8.2 Design Network for Ambient Air Quality Monitoring Stations

The baseline status of the ambient air quality has been assessed through

a scientifically designed ambient air quality monitoring network. The

design of monitoring network is based on the following considerations:

Topography/Terrain of the study area

Populated areas within the region

Prediction of maximum concentrations and distances of their likely

occurrence under prevailing meteorological conditions

Representation of regional background

Representatives of likely impact areas

Ambient Air Quality Monitoring (AAQM) stations were placed at eight

locations with due consideration to the above mentioned points.

3.8.3 Reconnaissance

Reconnaissance was undertaken to establish the baseline status of air

environment in the study region. The prime objective of the NAAQ

survey, within 10 km radial study area around the proposed project, was

to establish the existing ambient air quality levels. The monitoring

locations (relative directions and distances) are given in Table 3.11 &

shown in Figure 3.7 and results are given in Table 3.12 to 3.17.



3.8.4 Parameters, Frequency and monitoring Methodology

The existing ambient air quality, in terms of Particulate Matter-10 (PM10),

Particulate Matter-2.5 (PM2.5), Sulphur Dioxide (SO2), Oxides of Nitrogen

(NOx), Carbon Monoxide (CO) and Hydrocarbons (HC) has been

measured. It was ensured that, the equipment was placed at open space

free from any obstacles at a height of at least 3 to 4 m above the ground

level at each monitoring station to avoid the effects of wind-blown ground

dust. Monitoring has been carried out as per the latest CPCB and

MoEF&CC guidelines and notifications. Details of methodology are given

in Table 3.5.

Table 3.5 Methodology of Ambient Air Monitoring

Sampling Parameters

Instrument used Analytical equipment

Detection Limit

Test method

PM10 Combined Sampler (GTI-241)

Electronic Balance 1 μg/m3 Gravimetric IS: 5182 (Part 23) 2006

PM2.5 Combined Sampler

(GTI-241)

Electronic Balance 1 μg/m3 Gravimetric CPCB

Guidelines for Ambient Air Monitoring

SO2 Gaseous flow attachment with

Combined sampler

Spectro Photometer 2.5 μg/m3

Colorimetric IS: 5182: (Part II) 2001

NOx Gaseous flow attachment with

combined sampler

Spectro Photometer 6.0 μg/m3

Colorimetric IS: 5182: (Part VI) 2006

CO Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography

HC Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography

VOC Bladder & Pump Gas Chromatograph

1 ppm Gas Chromatography

HCl Gaseous flow

attachment with Combined sampler

Titrimetric 1 μg/m3 Titrimetric

The duration of sampling of PM2.5, PM10, SO2 & NOx was 24-hourly

continuous sampling per day and CO and Hydro Carbons (HC), VOC, HCl

were sampled for 8-hours duration. The monitoring was done for twice a

week for three months. Parameters and frequency of sampling is given in

Table 3.6.

Table 3.6 Monitored Parameters and Frequency of Sampling

Parameters Sampling frequency

Fine Particulate Matter (PM2.5) 24 hourly sample twice a week for three

months

Respirable Particulate Matter (PM10) 24 hourly sample twice a week for three months

Sulphur dioxide (SO2) 24 hourly sample twice a week for three

months



Oxides of Nitrogen (NOx) 24 hourly sample twice a week for three

months

Carbon Monoxide (CO) 8 hourly sampling

Hydro Carbon (HC) 8 hourly sampling

Volatile Organic Compounds (VOCs) 8 hourly sampling

HCl 8 hourly sampling

3.8.5 Interpretation of result

The existing baseline levels with respect to PM10, PM2.5, SO2, NOX, CO and

HC are tabulated in Tables 3.12 to 3.17 & chart is given as Figure 3.2

to 3.6.

Particulate Matter (PM10)

An average and 98th percentile value of 24-hourly PM10 values at all the

locations are found from 64.5 – 70.3 g/m3 and 70.8 – 79.1 g/m3. The

results were found well within the National Ambient Air Quality Standards

(NAAQS-CPCB) of 100 g/m3.

Particulate Matter (PM2.5)

An average and 98th percentile value of 24-hourly PM2.5 values at all the

locations ranges from 37.4 – 40.1 g/m3 and 41.8 – 48.1 g/m3. The

values are well within National Ambient Air Quality Standards (NAAQS-

CPCB) of 60 g/m3.

Sulphur Dioxide (SO2)

An average and 98th percentile value of 24-hourly SO2 value of arithmetic

mean at all the locations ranged from 17.5 – 19.4 g/m3 and 22.8 – 26.4

g/m3 respectively, which are well below National Ambient Air Quality

Standards (NAAQS-CPCB) of 80 g/m3.

Oxides of Nitrogen (NOx)

An average and 98th percentile value of 24 hourly NOx value of arithmetic

mean at all the locations ranged from 21.0 – 23.2 g/m3 and 26.2 - 31.2

g/m3 respectively, which are well below the National Ambient Air Quality


Carbon Monoxide (CO)

Minimum & Maximum value of CO at all the locations ranged from 1046 –

1364 g/m3.



Hydro Carbon (HC)

Minimum & Maximum value of Methane HC at all the locations ranged

from 21.4 – 42.4 g/m3 and non-methane HC at all the locations ranged

from 1110 – 1283 g/m3.

Volatile Organic Compounds (VOCs)

Minimum & Maximum value of VOC at all the locations ranged from 0.16

g/m3 – BDL.

Hydrochloric acid (HCl)

HCl found below detectable limit at all the locations.

3.9 WATER ENVIRONMENT

3.9.1 Hydrogeology of study area

Precambrian hard rocks, semi-consolidated Mesozoic and tertiary

formations and unconsolidated quaternary alluvial deposits form multi-

layer aquifer system in the district. Groundwater occurs both under

phreatic and confined conditions, however its development is restricted

depending upon the aquifer geometry and yield characteristic of

individual aquifer and/or ground water quality of the formation water.

Occurrence of groundwater can be divided in two groups. Hydrogeological

Map of the district is presented in figure below.

a) Ground water in fissured formation (Hard rock): The north-

eastern part of the district mainly in Satlasna taluka is occupied by meta

sediments. The occurrence and movement of ground water is governed

by secondary porosity i.e. thickness and extent of weathering and size &

interconnections of fractures/joints. These formations generally don‟t

form good aquifer system. The depth of dug wells range from 15-30 mbgl

and of bore wells from 100-120 mbgl. Depth to water level in the dug

wells varies from 5 -14 mbgl and in bore wells from 15 to 60 mbgl. The

yield of wells range from 30-120 m3/day with an average of 75 m3/day.

b) Groundwater in porous formations (Sedimentaries): Major part

of the district is underlain by post Miocene alluvium and older

sedimentary formations. These sediments are mainly consisted by Coarse

sand, gravel, kankar, silt, clay and clay stones. Groundwater occurs both

under phreatic and confined conditions in erinaceous horizons within



sedimentaries. The occurrence and movement of groundwater is mainly

controlled by inter granular pore spaces.

Two major aquifer units have been identified the upper unit is mostly

phreatic but becomes semi confined to confined in some parts. It is

designated as aquifer A and consists of relatively coarse grained

sediments. The lower unit comprising a few hundred meters of alternating

sand and clay beds form confines aquifer system. It is subdivided into B,

C D and E in post Miocene sediments and aquifer F and G in the Miocene

sediments. Himmatnagar sandstone (Cretaceous) forms local aquifer in

the north eastern part and has been designated as aquifer H. The post

Miocene aquifers are generally coarse to fine grained sand with occasional

gravel beds. The Miocene aquifers are mainly fine to medium grained

sand, sandstone inter bedded with clay, clay stone and siltstone.

Himmatnagar sandstone is generally coarse grained and friable.

Aquifer parameters:

(i) Unconfined Aquifers:

Aquifer A: Specific capacity of phreatic aquifer in the district ranges from

31 m3/hr/m to less than 1 m3/hr/m and transmissivity from 30 m2/day to

1000m2/day.

(ii) Confined Aquifers:

Aquifer B: Specific capacity ranges from 1.8 m3/hr/m to 49 m3/hr hr/m.

Transmissivity ranges between 47 and 3400 m2/day, however it is mostly

between 200-600 m2/day. Storativity ranges from 0.6 - 12.3 x 10-4.

Aquifer C: Specific capacity calculated for wells at Saola and Charasan

ranges from 21.3 and 2.8 m2/day/m respectively. Transmissivity was

94m2/day at Charasan EW.

Aquifer D: Specific capacity calculated for EW at Dhinoj was found to be

1.3 m3/hr/day, the transmissivity being 69 m2/day.

Aquifer E: No pumping test carried in this aquifer.

Aquifer F & G: Specific capacity calculated for wells at Charasan and

Pilwai was 1.1 m3/hr/m and 1.7m3/hr/m respectively. Transmissivity was

59 m2/day and 70 m2/day.



Hydrogeological Map of Mehsana District

3.9.2 Ground Water Resources

Ground water from the confined aquifer system is under exploitation in a

major way for various uses in the district. Tube wells range in depth from

120 to 300 m and have copious yield. The piezometric surface of confined

aquifer ranges from less than 60 mbgl to more than 150 m bgl. However,

in major part, it is more than 90 m bgl. Because of excessive ground

water development, consistent decline of piezometric surface is observed

in the district.

Eight talukas in the district are categorized as over exploited and one as

critical. Project site is located in Kadi Taluka, categorized as Over

exploited. Various rainwater harvesting schemes depending on the

suitable hydrogeological conditions have been constructed in the district

viz. Check dams, Recharge tube wells, deepening the of the village ponds

etc. and have shown good impact on the groundwater scenario.

*The above mentioned data has been sourced from District Groundwater

Brochure Mahesana District Gujarat, Compiled By A. K. Sinha Assistant

Hydrogeologist (Central Ground Water Board, West Central Region,

Ahmedabad)



3.10 WATER QUALITY

3.10.1 Introduction

Water quality assessment is one of the essential components of EIA

study. Such assessment helps in evaluating the existing health of water

body and suggesting appropriate mitigation measures to minimize the

potential impact from development projects. The water quality at the site

and other locations within the 10-km impact zone was monitored during

the study period. The purpose of the study is to:

Assess the water quality characteristics for critical parameters;

Evaluate the impact on agricultural productivity, habitat conditions

recreational resources and aesthetics in the vicinity; and

Predict the likely impacts on water quality due to the project and

related activities.

Reconnaissance survey was undertaken and monitoring locations were

finalized based on:

Location of residential areas representing different activities/likely

impact areas; and

Likely areas, which can represent baseline conditions.

3.10.2 Sampling Frequency, Techniques & Methodology

Eight surface water and Eight groundwater samples were collected during

the study period. Ground water samples were collected from the existing

bore wells, while surface water was collected from ponds by surface

water sampler. These samples were taken as grab samples. Necessary

precautions were taken for preservation of samples. Sampling locations

with source & date of sampling is given in Table 3.7.

The samples collection procedure was adopted from „Standard Methods‟

for the examination of Water and Wastewater published by American

Public Health Association (APHA) and IS 10500-2012. The samples were

analyzed for Physico-chemical parameters to assess the existing water

quality of the area (based on IS: 10500-2012 & APHA/AWWA, 23rd

edition). The water sampling locations marked within the study area and

the result of the analysis (ground water and surface water) is presented

in the Figure 3.9 & Table 3.19 & 3.20 respectively.



Table 3.7 Sampling locations with source & date of sampling

Ground Water Sampling Locations

Sample Code

Location Date of Sampling

Taluka District

GW1 Nr. Project site 16.01.2019 Kadi Mehsana

GW2 Laxmipura 16.01.2019 Kadi Mehsana

GW3 Chandarda 16.01.2019 Kadi Mehsana

GW4 Mathasur 17.01.2019 Kadi Mehsana

GW5 Rajpur 17.01.2019 Kadi Mehsana

GW6 Irana 16.01.2019 Kadi Mehsana

GW7 Untva 16.01.2019 Kadi Mehsana

GW8 Bileshvarpura 17.01.2019 Kadi Mehsana

Surface Water Sampling Locations

Sample

Code

Location Date of

Sampling

SW1 Chandarda Pond 16.01.2019

SW2 Mathasur Pond 16.01.2019

SW3 Kaiyal Pond 17.01.2019

SW4 Aldesan Pond 17.01.2019

SW5 Kadi Pond 16.01.2019

SW6 Chhatral Pond 16.01.2019

SW7 Budasan Pond 17.01.2019

SW8 Narmada Canal 16.01.2019

3.10.3 Surface Water Quality (Primary data)

Surface water samples were collected from ponds/lakes of Chandarda

Pond, Mathasur Pond, Kaiyal Pond, Aldesan Pond, Kadi Pond, Chhatral

Pond, Budasan Pond and Narmada Canal. Analysis of the same is given in

Table 3.20. The results have been compared with the drinking water

quality standards specified in IS: 10500-2012. It was observed that all

the physico-chemical parameters and heavy metals from surface water

samples except turbidity are below stipulated drinking water standards

and are suitable for domestic purposes.

3.10.4 Ground Water Quality

The results of the ground water quality monitored during the study period

are given in Table 3.19.

3.10.5 Interpretation

The samples were taken as grab samples and analyzed for various

parameters of ground water. Sampling location is shown in Figure 3.9.



Color: All the samples were found color less meeting desirable norms.

pH: All the samples meet the desirable standards (pH ranges from 7.3 -

7.9).

Total Dissolved Solids (TDS): TDS in samples ranges from 1130 mg/L

(Rajpur) to 1471 mg/L (Bileshvarpura), all the Samples meet the

permissible limit of 2000 mg/L.

Calcium: Calcium contents in the water ranges from 47 mg/L (Mathasur)

to 95 mg/L (Bileshvarpura), all the samples meet the permissible limit of

200 mg/L, (Permissible Limit in the Absence of Alternate Source).

Magnesium: Magnesium content in the water ranges from 35 mg/L

(Chandarda) to 47 mg/L (Nr. Project Site). All the samples meet the

permissible limit of 100 mg/L (Permissible Limit in the Absence of

Alternate Source).

Sulfate: Sulfate content in the water ranges from 84 mg/L (Irana) to 128

mg/L (Bileshvarpura). All the samples meet the permissible limit of 400

mg/L (Permissible Limit in the Absence of Alternate Source).

Fluoride: Fluoride content in the water ranges from 0.65 mg/L (Nr.

Project Site) to 0.75 mg/L (Irana). All the samples meet the permissible

limit of 1.5 mg/L (Permissible Limit in the Absence of Alternate Source).

Total Alkalinity: Total alkalinity in the water samples ranges from 315

mg/L (Nr. Project Site) to 353 mg/L (Laxmipura). All the samples are

within the permissible limit of 600 mg/L (Permissible Limit in the Absence

of Alternate Source).

Other Parameters: Potassium (ranges from 55 mg/L to 74 mg/L),

Sodium (ranges from 346 mg/L to 446 mg/L) and Chloride (ranges from

518 mg/L to 661 mg/L). All the samples meet permissible limit in the

absence of alternate source.

Heavy metals like cadmium, copper, lead, chromium, iron and zinc are

well below the limit in all samples.

3.10.6 Conclusion

The results have been compared with the drinking water quality

standards specified in IS: 10500-2012 & all parameters meet the

permissible limit set by the (BIS). All the samples meet permissible limit



in the absence of alternate source. Indian Standard specification for

drinking water is given in Table 3.21.

3.11 NOISE ENVIRONMENT

Noise can be defined as an unwanted sound. The definition of noise as

unwanted sound implies that it has an adverse effect on human beings

and their environment. The noise level variation can be temporal, spatial.

It interferes with speech and hearing and is intense enough to damage

hearing or is otherwise annoying. Noise can also disturb natural wildlife

and ecological system. It is therefore, necessary to measure both the

quality as well as the quantity of noise in and around the proposed site.

3.11.1 Instrument used for Sampling and Monitoring

The intensity of sound energy in the environment is measured in a

logarithmic scale and is expressed in a decibel, dB(A) scale. Sound Level

Meter (SLM) is used for the collection of data related to noise at an

interval of one hour. The day noise levels have been monitored during

6:00 am to 10:00 pm and night noise levels during 10:00 pm to 6:00 am

at all the nine locations. Noise levels recorded at each station are

computed for equivalent noise levels. Noise monitoring methodology is

given in below Table 3.8.

Table 3.8 Monitoring Methodology of Noise

Environment

Component

Sampling

Location

Test method Instrument

used

Make

Ambient Noise level

09 Locations

As per manufacturers Manual

Sound Level Meter

Mextech-SL-4012

3.11.2 Noise Quality Monitoring Locations

The noise survey was conducted to assess the background noise levels in

different zones. Noise level measurements have been made at 9 locations

within the study area using Sound Level Meter. Based on the Gazettes

Notification (S.O. 123(E)) of MoEF dated February 14, 2000 on ambient

air quality standards, 9 monitoring locations were selected. The noise

monitoring locations & its results are given in Figure 3.10 & Table 3.22

respectively.

3.11.3 Ambient Noise Standards

Ministry of Environment & Forests (MoEF&CC) has notified the noise

standards vide Gazette Notification dated February 14, 2000 for different



zones viz. industrial, commercial, and residential and silence zones under

the Environment Protection Act (1986). These standards are given in

Table 3.23.

3.11.4 Results

The noise levels of various locations are given in Table 3.22. The

monitored noise level in the day time Leq (Ld) varies from 51.4 to 54.5

dB(A) and the night time Leq (Ln) varies from 40.0 to 43.3 dB(A) within

the study area. Higher noise value of 54.5 dB(A) was recorded during day

time at Primary School of Rajpur & lower noise value of 40.0 dB(A) was

recorded during night time at village Irana.

3.11.5 Conclusion

Based on the observations made during the studies, it is concluded that;

the noise levels recorded at various locations in the study area show

considerable fluctuations because of changes in traffic movement,

commercial and other domestic activities in the study area. Overall the

ambient noise level in the monitored locations was found to be within the

permissible limits stipulated for residential, industrial areas, silence and

commercial zone.

3.12 SOIL ENVIRONMENT

Soils may be defined as a thin layer of earth‟s crust that serves as a

natural medium for the growth of plants. It is the unconsolidated mineral

matter that has been subjected to and influenced by genetic and

environmental factors. Soils serve as a reservoir of nutrients for plants

and crops and also provide mechanical anchorage and favorable tilth.

The objective of the soil sampling is:

To determine the baseline soil characteristics;

To monitor the impact on soil in long run.

3.12.1 Soil sampling locations

Soil quality of the study area is one of the important components for

environment impact assessment. The composite soil samples were

collected from the study area from eight locations (Nr. Project site,

Laxmipura, Chandarda, Mathasur, Rajpur, Irana, Untva and

Bileshvarpura) and were analyzed for different parameters. The location



of the monitoring is given below in Table 3.9. Results are given in Table

3.24 and depicted in Figure 3.11.

Table 3.9 Location of soil sampling

Sample

Code

Locations Date of

sampling

Tehsil District

S1 Project site 16.01.2019 Kadi Mehsana

S2 Laxmipura 16.01.2019 Kadi Mehsana

S3 Chandarda 17.01.2019 Kadi Mehsana

S4 Mathasur 16.01.2019 Kadi Mehsana

S5 Rajpur 17.01.2019 Kadi Mehsana

S6 Irana 16.01.2019 Kadi Mehsana

S7 Untva 17.01.2019 Kadi Mehsana

S8 Bileshvarpura 17.01.2019 Kadi Mehsana

3.12.2 Methodology

To understand the soil quality of the study area, analysis of all eight

locations including the project site was conducted by making suspension

of soil sample. The samples were examined for various physical and

chemical characteristics in order to assess the impact on soil. Analysis

was done by using following methodology.

Table 3.10 Methodology of Soil Sample analysis

Sampling

Parameters

Sample

collection

Analytical

Equipment

Methodology Remarks

Porosity

Manual

sample

Collection in

polyethylene

bags using

an Auger

- IS: 2720 Part 7 Trial pit

method

for topsoil

sample

collection;

disturbed

samples

Water holding

capacity

- -

Permeability - IS: 2720 Part 17

Moisture

content

Electronic Balance IS: 2720 Part 2

Texture - IS: 2720 Part 4

Particle size

Distribution

Glass wares

IS: 2720 Part 4

5% Leachate

to

be made and

analyzed as

per

APHA,

“Standard

Methods”

All method

numbers are

as

per APHA

“Standard

Methods”

(23rd edition)

Cation

Exchange

Capacity

Centrifuge IS: 2720 Part 24

(1976)

SAR F. Photometer

(Na, K)

Titration (Ca & Mg)

Calculation

pH pH Meter 4500 H+B

Electrical

Conductivity

Conductivity Meter As per IS 14767

-2000

Calcium Glass wares 3500 Ca B

Magnesium Glass wares 3500 Mg B

Sodium Flame Photometer 3500 Na B

Potassium Flame Photometer 3500 K B



3.12.3 Corollaries

Physical Parameters

Particle Size: A Particle size of the different constituents (clay, silt, sand

and gravel) controls the porosity and water holding characteristic of the

soil. Clay (size<0.002 mm) amount in the soil samples ranges from 16 %

to 26%; Silt (size 0.002 to 0.075 mm) in the soil samples is 25% to 35%

and Sand (size 0.075 to 0.475 mm) in the soil samples is 23% to 29%,

while Gravel (size>4.75 mm) in the soil samples is 20% to 26%. Analysis

shows that the soil has moderate water holding capacity.

Porosity: Porosity is a measure of space in between soil particles caused

by structural conditions and determined under identical conditions.

Porosity of soil samples of the study area ranges from 39.3% to 41.7%.

Water Holding Capacity (WHC): Water Holding Capacity (WHC) of soil

samples of the study area ranges from 39.5% to 47.8%.

Bulk Density: Bulk Density of soils in the study area is found to be in the

range from 1.44 to 1.5 g/cm3.

Chemical Parameters

pH: pH of soils in the study area is found to be in the range of 7.5 to 8.

Chloride: Chloride content in soils of the study area is found to be in the

range of 239 to 440 mg/kg.

Soluble Calcium: The soluble calcium as CaCO3 in soil samples is found

to be in the range of 164 to 248 mg/kg.

Magnesium: Magnesium content in soil samples of the study area ranges

from 103 to 135 mg/kg.

Total Phosphorus: Available Phosphorus content in soil samples of the

study area ranges from 13 to 66 mg/kg.

Total Nitrogen: Available nitrogen content in soil samples of the study

area is found to be in the range from 100 to 154 mg/kg.

Potassium: Potassium content in soil samples of the study area is found

to be in the range from 135 to 263 mg/kg.

Sodium: Sodium content in soil samples of the study area is found to be

in the range from 271 to 383 mg/kg.

Total Organic Matter (TOM): Total organic matter content in soil

samples of the study area is found to be in the range of 1.7 to 2.4 mg/kg.



3.12.4 Conclusion

In the study area, pH value ranging from 7.5 to 8 which shows that the

soil is slightly alkaline in nature. Organic Matter ranges from 1.7 to 2.4

mg/kg in the soil samples. Soil of the study area is known to be good for

cultivation. Generally, soils with low bulk density have favorable physical

conditions (porosity and permeability) whereas those with high bulk

density exhibit poor physical conditions for agriculture crops.

3.13 BIOLOGICAL ENVIRONMENT

An ecological study of the ecosystem is essential to understand the

impact of industrialization and urbanization on existing flora and fauna of

the study area. The biological study was undertaken as a part of the EIA

study to:

Understand the present status of ecosystem prevailing in the study

area.

Compare it with past condition with the help of available data.

Predict changes in the biological environment as a result of present

activities and to suggest measures for maintaining its health.

The survey was conducted to study the flora & fauna in 10 km radius.

Some of the information was gathered from the local habitants. All the

collected data were classified to interpret the impact of pollution on the

flora and fauna of the region.

3.13.1 Period of the study

The baseline study, for the assessment of the floral and faunal

biodiversity of the terrestrial environment, within 10 km radius from the

site was conducted during January, 2019 to March, 2019.

3.13.2 Study methodology

Survey methodology was based on the flora and fauna species

identification in person, recently recorded and found in the region by the

localities. Sampling of grass species was carried out by quadrat sampling

method to examine the species distribution and its frequency in the

region.

Quadrate Sampling Method:

A quadrat (or plot-based) survey is a quantitative examination of species

distribution & abundance. Quadrats are more likely to detect



inconspicuous species because a smaller area is sampled in a

concentrated search. The survey was carried out for the vegetation

ground cover found in the road edges by 1 m2 quadrat and study on the

edge effect due to rapid industrialization and urbanization.

3.13.3 Floral species in the study area

Flora is basically the plant life that is present in a particular region or

habitat at a particular time. List of flora found in the study area is

tabulated in Table 3.25.

3.13.4 Fauna in the study area

Fauna is the animal life that is present in a particular region or habitat at

a particular time. Irrespective of its unfriendly terrain, Gujarat gives

shelter to a variety of animals and birds. They live in smaller herds and

thrive mainly on wild grasses and various types of shrubs. Faunal

biodiversity with their scientific names and common names is presented

in Table 3.26.

3.14 SOCIO-ECONOMIC ENVIRONMENT

An essential part of environmental study is socio-economic environment

incorporating various facts related to socio-economic conditions in the

area, which deals with the total environment. Socio economic study

includes demographic structure of the area, provision of basic amenities

viz., housing, education, health and medical services, occupation, water

supply, sanitation, communication, transportation as well as feature of

aesthetic significance such as temples, historical monuments etc. at the

baseline level. This would help in visualizing and predicting the possible

impact depending upon the nature and magnitude of the project. Socio-

economic study of an area provides a good opportunity to assess the

socioeconomic conditions of an area. This study will possibly make a

change in living and social standards of the particular area benefitted due

to the project. The gross economic production of the area will be

increased substantially due to the existence of this project. It can

undoubtedly be said that this plant will provide direct and indirect

employment and improve the infrastructural facilities and standards of

living of the area.



3.14.1 Objective of the study

The objectives of this socio-economic report consist of:

To conduct socio-economic assessment study in lease Area

To help in providing better living standards.

To know the current socio-economic situation in the region to cover

the sub sectors of education, health, sanitation, water and food

security.

To provide employment opportunities.

3.14.2 Land use pattern and infrastructure

The land use pattern indicates the manner in which different parts of land

in an area is being utilized or non-utilized. It is an important indicator of

environmental health; human activity and a degree of inter play between

these two. Even though the soil quality, water availability and climate

have strong influence on agriculture and vegetation, the human activity

may alter the natural environment to a large extent to suit human needs.

Unnatural land use often triggers rapid environmental deterioration and

disturbs ecological balance. In census records, major land use

classifications are; Forests, Culturable land, Culturable wasteland and

area not available for cultivation. Culturable land is further classified as:

irrigated and un-irrigated. Area not available for cultivation includes lands

put to non-agriculture uses as well as barren and uncultivable lands.

The main land use in area is for dwellings, infrastructure and related

activities. However, the land use pattern for rural areas is discussed

below. The information is preliminary based on 2011 Census as depicting

in Table 3.28. Total land area is 26340.25 ha, out of that Irrigated area

is 13163.1 ha and it constitutes 49.97%. 7848.3 ha are un-irrigated by

source and it constitutes 29.79% of total land area. The study area

consist of Cultivable wasteland is 1086.8 ha (4.12%). Area not available

for cultivation is 690.1 ha & it constitute 2.62%.

3.14.3 Demographic and Socio-Economic Environment

The demographic and Socio-economic details of the study area are

discussed below. These are primarily based on census data of 2011. Data

on number of households, population as well as literacy and employment

pattern in the study area have been presented in Table 3.29. The



employment pattern in the area is indicator of number of persons

employed in various sectors. It also indicates the various categories of

employment flourishing in the area. The Study area in 10 km radius has

43 villages including project site.

The total no. of household in the villages are 24817 and the total

population is 119449 (52.05% men & 47.95% women). 71.50% of are

literate while literacy rate among women & men is 64.10% & 78.31%

respectively. 53.21% of male population is part of main worker, while

only 10.42% of female population is a part of main workers. 2.90% of

male workers are marginal workers, while 6.65% of female workers are

engaged in such type of activities. 44.76% of male population and

84.27% of female population are non-workers.

3.14.4 Living Standard and Infrastructure

In India it is not possible to setup a primary standard of living because of

wide variations in terms of income, economic conditions, social custom,

employment opportunity, pattern of spending, etc. However, availability

of amenities like education, medical, water supply, communication, road

network, electricity, etc. significantly reflects the level of development of

the area. Information on available amenities in the study area has been

extracted from census record of 2011. Total numbers of village in study

area are 43. On the basis of data presented in the Table 3.30, the status

of available amenities is discussed in following sub-sections:

Educational Facilities

As per 2011 census, there are primary school in all 43 villages, 1 Pre-

primary school, 11 Secondary schools, 6 Senior Secondary schools in

study area of 10 km.

Medical Facilities

43 villages in the study area have 4 Primary Health Centre, 9 Primary

Health Sub Centre, 1 Maternity and Child Welfare Centre, 2 Veterinary

hospital, 1 Dispensary, 1 Family Welfare Centre in study area of 10 km.

Drinking Water Supply

All the 43 villages in the study area have two or more sources of drinking

water. Most of the villages in study area have tube well water supply in

addition to Tap water (almost all). Moreover all villages have facility of



well water and some villages have hand pump, river and tank water, tube

well or other facilities for water.

Communication and Transport

The main mode of public transport available in the study area is by bus

service. Five villages have approach to railway station as western railway

meter gauge line is passing through nearby. Majority of villages in the

study area is connected with pucca road.

Post and Telegraph

As per 2011 census record out of 43 villages in study area, almost all the

villages have post office facility at doorstep & phone facility.

Power Supply

As per 2011 census record almost all the villages are getting power

supply for all purposes.



Table 3.11: Ambient Air Quality Monitoring Locations

(Monitoring Period: January, 2019 to March, 2019)

Sr.

No.

Sampling

Location

Direction w.r.

to center of

Industry

Distance

in km

Coordinates Type of

Area

1 Project site

(A1)

-- -- 23°20'48.44"N

72°24'26.99"E

Industrial

2 Laxmipura (A2) NNW(UW) 2.10 23°21'55.68"N

72°24'9.84"E

Residential

3 Chandarda

(A3)

ENE(UW) 1.45 23°20'53.07"N

72°25'18.56"E

Residential

4 Mathasur (A4) NW(UW) 5.50 23°22'59.49"N

72°22'8.52"E

Residential

5 Rajpur (A5) S(UW) 1.70 23°19'52.44"N

72°24'26.23"E

Residential

6 Irana (A6) SSW(DW) 4.50 23°18'35.44"N

72°23'21.06"E

Residential

7 Untva (A7) WSW(DW) 4.90 23°19'28.83"N

72°21'55.45"E

Residential

8 Bileshvarpura

(A8)

SSE(UW) 6.35 23°17'51.88"N

72°26'24.01"E

Residential



Table 3.12: Ambient Air Quality Status


Sr.

No.

Sampling

Location

PM10 PM2.5 SO2 NOx

Average (Min-Max)

1 Project site (A1) 67.3

(58.1-79.3)

37.5

(31.8-43.9)

18.1

(13.0-26.5)

23.2

(17.5-32.3)

2 Laxmipura (A2) 64.6

(58.1-74.3)

38.2

(34.8-44.6)

17.5

(13.7-23.8)

21.5

(16.4-26.7)

3 Chandarda (A3) 70.3

(58.3-79.6)

39.5

(32.1-45.1)

18.7

(14.4-26.6)

21.0

(16.6-28.3)

4 Mathasur (A4) 67.6

(62.7-72.7)

39.1

(32.8-47.1)

19.1

(13.8-23.5)

22.4

(16.5-27.5)

5 Rajpur (A5) 66.8

(61.7-71.5)

37.4

(33.3-42.6)

17.9

(13.7-23.4)

21.6

(17.2-27.6)

6 Irana (A6) 64.5

(55.4-71.4)

38.8

(33.7-45.5)

18.3

(12.9-24.1)

22.0

(17.1-27.9)

7 Untva (A7) 67.8

(60.5-72.9)

40.1(35.0-

48.4)

17.9

(13.9-25.3)

21.4

(16.6-26.9)

8 Bileshvarpura (A8) 65.9

(55.5-76.6)

39.8

(32.8-46.2)

19.4

(14.0-25.8)

22.9

(17.4-28.7)

Figure 3.2 Graphical representation of Ambient Air Quality

67.364.6

70.367.6 66.8 64.5

67.8 65.9

37.5 38.2 39.5 39.1 37.4 38.8 40.1 39.8

18.1 17.5 18.7 19.1 17.9 18.3 17.9 19.423.2 21.5 21.0 22.4 21.6 22.0 21.4 22.9

0.0

20.0

40.0

60.0

80.0

100.0

Co

nce

ntr

ati

on

in

mic

rog

ram

/m3

Location

Ambient Air Quality status

PM10

PM2.5

SO2

NOx



Table 3.13: Ambient Air Quality Status (PM10)


Average-24 Hours Unit-g/m3

Station Name Max Min 98th

Percentile

75th

Percentile

50th

Percentile

25th

Percentile

Avg SD

Project site(A1) 79.3 58.1 78.2 69.7 66.9 64.6 67.3 4.9

Laxmipura (A2) 74.3 58.1 73.0 66.1 64.4 62.7 64.6 3.8

Chandarda(A3) 79.6 58.3 79.1 75.2 71.3 66.1 70.3 6.2

Mathasur(A4) 72.7 62.7 72.6 71.0 68.2 64.8 67.6 3.5

Rajpur(A5) 71.5 61.7 71.5 69.2 67.0 63.8 66.8 3.1

Irana(A6) 71.4 55.4 70.8 67.4 65.5 61.7 64.5 4.0

Untva(A7) 72.9 60.5 72.6 70.7 67.8 65.6 67.8 3.3

Bileshvarpura(A8) 76.6 55.5 75.1 70.1 66.3 62.6 65.9 5.5

Figure 3.3 Graphical representations for PM10

67.3 64.670.3 67.6 66.8 64.5 67.8 65.9

0.0

20.0

40.0

60.0

80.0

100.0

Co

nce

ntr

ati

on

in m

icro

gra

m/m

3

Graphical representation for PM2.5Avr. Result CPCB Limit



Table 3.14: Ambient Air Quality Status (PM2.5)




Percentile

75th

Percentile

50th

Percentile

25th

percentile

Avg. SD

Project site(A1) 43.9 31.8 42.8 39.3 37.5 36.2 37.5 2.8

Laxmipura (A2) 44.6 34.8 43.5 39.9 37.6 36.2 38.2 2.6

Chandarda(A3) 45.1 32.1 44.3 41.8 39.9 37.8 39.5 3.1

Mathasur(A4) 47.1 32.8 45.6 40.5 38.5 37.4 39.1 3.1

Rajpur(A5) 42.6 33.3 41.8 38.9 37.4 36.3 37.4 2.3

Irana(A6) 45.5 33.7 44.6 41.1 38.9 36.2 38.8 3.1

Untva(A7) 48.4 35.0 48.1 42.1 39.3 37.7 40.1 3.6

Bileshvarpura(A8) 46.2 32.8 45.9 41.8 40.1 37.7 39.8 3.4

Figure 3.4 Graphical representation for PM2.5

37.5 38.2 39.5 39.1 37.4 38.8 40.1 39.8

0.0

20.0

40.0

60.0

Co

nce

ntr

ati

on

in m

icro

gra

m/m

3

Graphical representation for PM2.5Avr. Result CPCB Limit



Table 3.15: Ambient Air Quality Status (SO2)




Percentile

75th

Percentile

50th

Percentile

25th

percentile

Avg. SD

Project site(A1) 26.5 13.0 26.4 20.0 17.4 15.4 18.1 3.7

Laxmipura (A2) 23.8 13.7 22.8 18.8 17.3 15.9 17.5 2.4

Chandarda(A3) 26.6 14.4 25.0 20.5 18.1 16.5 18.7 2.9

Mathasur(A4) 23.5 13.8 23.4 20.5 19.0 17.7 19.1 2.5

Rajpur(A5) 23.4 13.7 22.8 19.7 18.1 16.2 17.9 2.5

Irana(A6) 24.1 12.9 23.8 20.8 18.1 15.6 18.3 3.1

Untva(A7) 25.3 13.9 24.4 19.5 17.3 15.6 17.9 3.0

Bileshvarpura(A8) 25.8 14.0 25.1 21.3 19.8 16.8 19.4 3.3

Figure 3.5 Graphical representations for SO2

18.1 17.5 18.7 19.1 17.9 18.3 17.9 19.4

0.0

20.0

40.0

60.0

80.0

Co

nce

ntr

atio

n in

mic

rogr

am/m

3

Graphical representation for SO2Avr. Result CPCB Limit



Table 3.16: Ambient Air Quality Status (NOx)

(Monitoring Period: January-19 to March-19)



Percentile

75th

Percentile

50th

Percentile

25th

percentile

Avg. SD

Project site(A1) 32.3 17.5 31.2 25.6 22.4 20.9 23.2 3.8

Laxmipura (A2) 26.7 16.4 26.7 23.0 21.3 19.6 21.5 2.6

Chandarda(A3) 28.3 16.6 26.6 22.9 21.8 20.4 21.0 2.8

Mathasur(A4) 27.5 16.5 26.8 24.5 22.4 20.4 22.4 2.9

Rajpur(A5) 27.6 17.2 26.9 23.6 22.7 19.5 21.6 2.9

Irana(A6) 27.9 17.1 27.6 24.6 22.2 19.3 22.0 3.3

Untva(A7) 26.9 16.6 26.2 23.2 21.3 19.6 21.4 2.5

Bileshvarpura(A8) 28.7 17.4 28.6 25.2 23.4 20.0 22.9 3.3

Figure 3.6 Graphical representations for NOx

23.2 21.5 21.0 22.4 21.6 22.0 21.4 22.9

0.0

20.0

40.0

60.0

80.0

Co

nce

ntr

ati

on

in m

icro

gra

m/m

3

Graphical representation for NOXAvr. Result CPCB Limit



Table 3.17: Ambient Air Quality Status

(CO, HC (Methane & Non-Methane), VOC, HCl)


Station Name CO

(g/m3)

Hydro Carbon

(g/m3)

VOC

(g/m3)

HCl

(g/m3)

Methane Non-

Methane

Benzene Toluene Xylene

Project site(A1) 1296 27.9 1143 0.38 BDL BDL BDL

Laxmipura (A2) 1227 30.4 1197 0.32 BDL 0.21 BDL

Chandarda(A3) 1342 40.8 1283 0.43 0.26 0.15 BDL

Mathasur(A4) 1098 24.1 1110 0.21 BDL BDL BDL

Rajpur(A5) 1136 35.1 1205 0.36 BDL BDL BDL

Irana(A6) 1046 21.4 1208 0.16 BDL BDL BDL

Untva(A7) 1249 26.9 1235 0.34 BDL BDL BDL

Bileshvarpura(A8) 1364 42.4 1236 0.28 0.19 0.23 BDL



Table 3.18: National Ambient Air Quality Standards

(EP, 7th amendment rules-2009)

Pollutants Time-weighted average

Concentration in ambient air

Industrial, Residential, Rural and

others area

Ecologically Sensitive area (Notified by

Central Government)

Method of Measurement

Sulphur Dioxide (SO2), µg/m3

Annual Average*

50 20 Improved west and Gaeke method

Ultraviolet fluorescence

24 hours** 80 80

Oxides of Nitrogen as (NO2), µg/m3

Annual Average*

40 30 Modified Jacob &Hochheiser

(Na-Arsenate) Chemiluminescence

24 hours** 80 80

Particulate Matter (Size less than 10 µm or PM10, µg/m3

Annual Average*

60 60 Gravimetric TOEM Beta attenuation 24 hours** 100 100

Particulate Matter (Size less than 2.5 µm or PM2.5, µg/m3

Annual Average*

40 40 Gravimetric TOEM Beta attenuation 24 hours** 60 60

Ozone (O3) µg/m3

8 hours ** 100 100 UV photometric Chemiluminescence Chemical Method

1hours** 180 180

Lead (Pb) µg/m3

Annual Average*

0.50 0.50 AAS/ICP method after sampling on EPM 2000 or equivalent filter paper

ED-XRF using Teflon

filter

24 hours** 1.0 1.0

Carbon Monoxide

(CO) mg/m3

8 hours** 02 02 Non Dispersive Infra

Red (NDIR) spectroscopy

1 hour** 04 04

Ammonia (NH3) µg/m3

Annual Average*

100 100 Chemiluminescence Indophenol Blue

Method 24 hours** 400 400

Benzene (C6H6) µg/m3

Annual* 05 05 Gas chromatography based continuous analyzer

Adsorption and desorption followed

by GC analysis

Benzo(a) Pyrine

(BaP)-particulate phase only, ng/m3

Annual* 01 01 Solvent extraction

followed by HPLC/GC analysis

Arsenic (As), ng/m3

Annual* 06 06 AAS/ICP method after sampling on EPM 2000 or equivalent

filter paper

Nickel (Ni) ng/m3

Annual* 20 20 AAS/ICP method after sampling on EPM

2000 or equivalent filter paper

* Annual Arithmetic mean of minimum 104 measurements in a year taken twice a week 24 hourly at uniform interval.

** 24 hourly/8 hourly or 01 hourly values, as applicable, shall be complied with 98% of the time in a year. 2% of the time, they may exceed the limits but not two consecutive days of monitoring.



Table 3.19: Results of Groundwater Quality in the Study Area

(Date of Sampling: 16 to 17, January, 2019)

Sr.

No

Parameters Unit Result

Nr. Project

site (GW1)

Laxmipura

(GW2)

Chandarda

(GW3)

Mathasur

(GW4)

Rajpur

(GW5)

Irana

(GW6)

Untva

(GW7)

Bileshvarpura

(GW8)

1 pH pH Unit 7.5 7.3 7.8 7.9 7.4 7.7 7.8 7.4

2 Color Co-Pt

Units

Color

less

Color

less

Color

less

Color

less

Color

less

Color

less

Color

less

Color

less

3 Turbidity NTU 1895 1930 1905 1950 1635 1815 2130 2125

Conductivity μmoh/cm 6.5 7.7 6.3 4.7 6.2 6.2 6.4 6.1

4 Total Hardness mg/L 1310 1336 1325 1349 1130 1260 1471 1466

5 Alkalinity mg/L 383 403 344 294 314 373 351 402

6 COD mg/L 315 353 321 335 317 316 339 327

7 Chlorides mg/L 405 357 389 435 353 346 446 424

8 Sulphate mg/L 57 62 59 58 60 74 55 63

9 TDS mg/L 76 92 80 47 63 85 81 95

10 Sodium mg/L 47 42 35 43 38 39 36 40

11 Potassium mg/L 618 585 624 610 518 562 661 637

12 Calcium mg/L 98 95 100 113 89 84 127 128

13 Magnesium mg/L 0.65 0.71 0.72 0.68 0.65 0.75 0.70 0.74

14 Nitrate mg/L 16 17 17 21 21 20 19 18

15 Fluoride mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001

16 Phenol as

C6H5OH

mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001

17 Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

18 Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

19 Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

20 Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

21 Manganese as

Mn

mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

22 Iron as Fe mg/L 0.24 0.20 0.22 0.22 0.19 0.34 0.27 0.22

23 Total Chromium mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

24 Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

25 Nickle as Ni mg/L 65.7 61.5 66.7 71.8 66.1 61.6 69.6 65.5



Table 3.20: Results of Surface water Quality in the Study Area


Parameters Unit CONCENTRATION

Chandarda Pond

(SW1)

Mathasur Pond

(SW2)

Kaiyal Pond

(SW3)

Aldesan Pond

(SW4)

Kadi Pond

(SW5)

Chhatral Pond

(SW6)

Budasan Pond

(SW7)

Narmada Canal (SW8)

pH pH Unit 7.35 7.62 7.81 7.29 7.43 7.46 7.52 7.63

Conductivity Micro mhos/cm 595 565 760 655 715 690 885 475

Turbidity NTU 15 16 18 10 14 12 16 20

TDS mg/L 418 392 523 452 493 472 610 332

DO mg/L 5.9 6.2 6.5 5.4 4.9 5.1 5.8 5.5

Total Hardness as

CaCO3

mg/L 166 134 213 174 176 183 245 123

Total Alkalinity mg/L 232 245 272 260 259 285 292 235

Sodium as Na+ mg/L 128 135 156 145 163 153 165 118

Potassium K+ mg/L 28 32 27 22 18 26 39 16

Calcium Ca+2 mg/L 30 24 36 30 36 32 42 26

Magnesium Mg+2 mg/L 22 18 30 24 21 25 34 14

Chlorides as Cl- mg/L 16 145 210 182 192 198 245 104

Sulfates as SO4-2 mg/L 32 24 46 29 36 24 49 28

Nitrates as NO3-3 mg/L 10.2 9.5 6.7 7.2 7.8 6.5 6.9 7.3

Phenol as CH3OH mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001

Cyanide as CN- mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001

Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Manganese as Mn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Iron as Fe mg/L 0.26 0.25 0.21 0.29 0.18 0.13 0.15 0.17

Total Chromium mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Total Coliform MPN/ml 92 86 74 70 52 68 52 60



Table 3.21: Indian Standard Specification for Drinking Water

Sr. No.

Parameters Desirable Limit

Permissible Limit in the

Absence of Alternate

Source

I Essential Characteristics

1. Colour, Hazen Units, Max. 5 25

2. Odour Unobjectionable -

3. Taste Agreeable -

4. Turbidity, NTU, Max. 5 10

5. pH 6.5-8.5 No Relaxation

6. Total Hardness (as CaCO3) mg/l, Max. 300 600

7. Iron (as Fe) mg/l, Max. 0.3 1.0

8. Chlorides (as Cl) mg/l, Max. 250 1000

9. Residual Free Chlorine, mg/l, Min. 0.20* -

II Desirable Characteristics

10. Dissolved Solids, mg/l, Max. 500 2000

11. Alkalinity (as CaCO3), mg/l, Max. 200 600

12. Sulphate (as SO4) mg/l, Max. 200 400

13. Nitrate (as NO3) 45 100

14. Fluoride (as F) mg/l, Max. 1.0 1.5

15. Calcium (as Ca) mg/l, Max. 75 200

16. Magnesium (as Mg) mg/l, Max. 30 100

17. Copper (as Cu) mg/l, Max. 0.05 1.5

18. Manganese (as Mn) mg/l, Max. 0.1 0.3

19. Mercury (as Hg) mg/l, Max. 0.001 No Relaxation

20. Cadmium (as Cd) mg/l, Max. 0.01 No Relaxation

21. Selenium (as Se) mg/l, Max. 0.01 No Relaxation

22. Arsenic (As As) mg/l, Max. 0.05 No Relaxation

23. Cyanide (as CN) mg/l, Max. 0.05 No Relaxation

24. Lead (as Pb) mg/l, Max. 0.05 No Relaxation

25. Zinc (as Zn) mg/l, Max. 5 15

26. Aluminium (as Al) mg/l, Max. 0.03 0.2

27. Boron (as B) mg/l, Max. 1 5

28. Chromium (as Cr) mg/l, Max. 0.05 No Relaxation

29. Phenolic Compounds (as C6H5OH) mg/l,

Max.

0.001 0.002

30. Anionic Detergents (as MBAS) mg/l, Max. mg/l, Max.

0.2 1.0

31. Mineral Oil mg/l, Max. 0.01 0.03

32. Pesticides Absent 0.001

33. Radioactive Materials a. Alpha Emitters, Bq/I, Max.

b. Beta Emitters, Pci/I, Max

-

-

0.1

0.037

Note: * Applicable only when water is chlorinated

Source: IS: 10500, 2012



Table 3.22: Ambient Noise Levels in the Study Area

(Date of Monitoring: 16 to 17, January, 2019)

Sr.

No.

Locations Ld/Ln Noise Level

dB(A)

1 Project site(N1) Ld 52.8

Ln 43.3

2 100 m West from the site (N2) Ld 54.0

Ln 42.1

3 250 m South from the site (N3) Ld 51.4

Ln 40.6

4 500 m North from the site (N4) Ld 50.9

Ln 41.3

5 1000 m East from the site (N5) Ld 51.7

Ln 40.4

6 Primary School Rajpur (N6) Ld 54.5

Ln 40.7

7 Village Irana (N7) Ld 54.0

Ln 40.0

8 Village Laxmipura (N8) Ld 52.9

Ln 41.0

9 Village Chandarda (N9) Ld 53.8

Ln 40.6

Table 3.23

Ambient Air Quality Standards with respect to Noise

Zone Limits Leq, dB(A)

Day Time Night Time

Industrial 75 70

Commercial 65 55

Residential 55 45

Silence 50 40



Table 3.24: Soil Analysis of Study area


S.

No.

Parameters Unit Project

site

(S1)

Laxmipura

(S2)

Chandarda

(S3)

Mathasur

(S4)

Rajpur

(S5)

Irana

((S6)

Untva

(S7)

Bileshvarpura

(S8)

1. pH (5%) Solution -- 7.8 7.5 7.7 8.1 7.7 8.7 7.9 7.5

2. Moisture % 5.2 7.1 6.6 8.2 5.9 6.3 7.1 5.9

3. Loss of Ignition % 10.4 10.8 8 8.9 10.8 11.4 10.8 8.5

4. Particle Size

Clay (<0.002 mm) % 21 26 16 18 24 25 23 25

Silt (0.002 to 0.075 mm) % 28 25 35 32 33 26 30 28

Sand (0.075 - 0.475 mm) % 29 23 24 27 23 23 26 24

gravel (size > 4.75 mm) % 22 26 25 23 20 26 21 23

5. Water Holding Capacity % 39.5 43.7 47.8 44.7 48.9 43.7 46.8 46.8

6. Permeability cm/hr. 3.00 3.25 3.24 3.12 3.20 3.18 3.25 3.16

7. Bulk Density g/cm3 1.44 1.49 1.5 1.48 1.5 1.47 1.49 1.46

8. Porosity % 41.7 39.6 39.3 40.0 39.3 40.5 39.7 40.9

9. Sodium Absorption Ratio Meq/100

gm

4.17 4.77 3.49 3.90 5.04 3.95 4.39 4.19

10. Sodium mg/kg 590 750 492 432 430 370 610 546

11. Potassium mg/kg 220 195 240 218 246 224 194 178

12. Calcium mg/kg 375 486 270 334 518 392 346 456

13. Magnesium mg/kg 160 95 165 192 180 285 218 192

14. Chlorides mg/kg 1010 970 1130 1049 846 996 1093 1120

15. Sulphates mg/kg 152 192 145 175 123 148 186 213

16. Organic Matter mg/kg 1.4 1.5 1.4 1.4 1.4 1.5 1.6 1.4

17. Total Nitrogen mg/kg 121 110 104 134 125 127 113 123

18. Total Phosphorus mg/kg 56 73 70 50 55 39 62 45

19. Iron mg/kg 1.46 1.41 1.24 1.49 1.44 1.65 1.75 1.33

20. Cation Exchange Capacity mg/100

gm

6.34 6.98 5.48 5.71 6.59 6.52 6.7 6.71



Table 3.25

Floral Diversity

(i) Trees

Scientific Name Vernacular Name Family

Acacia Chundra Khair Fabaceae

Acacia Nilotica Bawal Fabaceae

Acacia Senegal Goradiobaval Fabaceae

Acacia Tortilis Israeli Bawal Fabaceae

Ailanthus Excelsa Aurdso Simaroubiaceae

AlangiumSalvifolium Ankol Alangiaceae

AlbiziaLebbeck Siras Fabaceae

AnnonaAquamosa Sitafal Annonaceae

Annona Reticulate Ramphal Annonaceae

AzadirachtaIndica Neem Meliaceae

Borassusflabellifer Tad Arecaceae

ButeaMonosperma Palas Fabaceae

ButeaMonosperma Khakharo Papilionaceae

Carica Papaya Papaya Caricaceae

Cassia Fistula Amaltas Fabaceae

Cassia Fistula Garmalo Caesalpiniaceae

CasuarinaEquisetifolia Sharu Casuarinaceae

Citrus Limon Limbu Rutaceae

CordiaDichotoma Gunda Ehretiaceae

Cordiamyxa Pidar Boraginaceae

Dalbergiasissoo Shisham Papilionoideae

DelonixRegia Gaulmor Caesalpiniaceae

Delonixelata Gulmohar Caesalpiniaceae

DendrocalamusStrictus Bans Poaceae

Derris Indica Karanj Papilionaceae

Emblicaofficinalis Amla Euphorbiaceae

Eucalyptus Tereticornis Nilgiri Myrtaceae

FicusBengalesis Vad Moraceae

FicusMicrocarpa Banyan Moraceae

FicusReligiosa Piplo Moraceae

LimoniaAcidissima Kotha Rutaceae

MadhukaIndica Mahudo Sapotaceae

MangiferaIndica Ambo Anacardiaceae

ManilkaraHexandra Rayan Sapotaceae

ManilkaraZapota Chikoo Sapotaceae

MoringaOleifera Sargvo Moringaceae

Pithecellobiumdulce Gorasamli Fabaceae



PolylathiaLongifolia Asopalav Annonaceae

Pongamiapinnata Karanj Fabaceae

ProsopisJuliflora VilayatiBawal Fabaceae

Prosopiscineraria Khyigdo Mimosaceae

Syzygiumcumini Jamun Myrtaceae

TamarindusIndica Amli Fabaceae

Tectonagrandis Sag Verbenaceae

TerminaliaCatappa Almond Combretaceae

TerminaliaCatappa Badam Combretaceae

ThespesiaPopulnea Piplo Malvaceae

ZiziphusMauritiana Bor Rhamnaceae

ZizyphusGlabrata Bor Rhamnaceae

(ii) Shrubs


AbelomoschusEsculentus Bhindi Malvaceae

Acacia Catechu Khair Mimosoideae

Acacia Jacquemontii Baonli Mimosaceae

Adhatodavasica Adusa Acanthaceae

Annonasquamosa Sitafal Annonaceae

BalanitesAegyptiaca Ingorio Balanitaceae

Caesalpinia Crista Kachka Caesalpiniaceae

CalotropisGigantea Akado Asclepiadaceae

CalotroPisprocera Aak Asclepiadaceae

CapparisCarandas Karaunda Apocynaceae

Capparis Decidua Kerdo Capparaceae

CapparisSepiaria Kanthar Capparaceae


Cassia Auriculata Aval Caesalpiniaceae

Cassia Occidentalis Sundro Caesalpiniaceae

Cassia Tora Tarota Ceasalpinoideae

DaturaMetel Daturo Solanaceae

DaturaStramonium Daturo Solanaceae

Euphorbia Neriifolia Thor Euphorbiaceae

GossypiumHerbaceum Kapas Malvaceae

Hibiscus Rosa Jasund Malvaceae

JatrophaCurcas Ratanjot Euphorbiaceae

Lantana Camara Ganthai Verbenaceae

LawsoniaInermis Hina Lythraceae

LawsoniaInermis Mendhi Lythraceae

MaytenusEmarginata Vico Celastraceae



Murraya Exotica Madhukamini Rutaceae

Musa Paradisiaca Kela Musaceae

Nariumindicum Karne Apocynaceae

NeriumIndicum Lalkaren Apocynaceae

Ocimum Sanctum Tulsi Lamiaceae

PunicaGranatum Dadam Punicaceae

RicinusCommunis Devalo Euphorbiaceae

Ricinuscommunis Arandi Euphorbiaceae

Rosa Chinensis Rose Rosaceae

SesbaniaGrandiflora Agati Fabaceae

SolanumIncanum Ringan Solanaceae

ZizyphusMauritiana Bordi Rhamnaceae

ZizyphusNummularia Chanibor Rhamnaceae

(iii) Herbs


Abutilon Indicum Khapat Malvaceae

AdhatoDavasica Adusa Acanthaceae

Aloe Barbadensis Kunvarpato Liliaceae

AmaranthusViridis Amaranth Amaranthaceae

Annonasquamosa Sitafal Annonaceae

BiophytumReinwardii Lajwanti Oxalidaceae

BlumeaEriantha Kalhar Asteraceae

BoerhaviaDiffusa Satodi Nyctaginaceae

Brassica Oleraceae Gobi Brassicaceae

Brassica Oleraceae Cabbage Brassicaceae

CajanusCajan Tuvar Papilionaceae


CressaCretica Rudanti Convolvulaceae

Croton Bonplandianum Tulsi Euphorbiaceae

CuminumCuminum Jiru Apiaceae

Daturametel Datura Solanaceae

EchinopsEchinatus Shuliyo Asteraceae

EichhorniaCrassipes Kanphutti Pontederiaceae

Euphorbia Hirta Asthma Weed Euphorbiaceae

FoeniculumVulgare Variali Apiaceae

HygrophilaAuriculata Akaro Acanthaceae

Jatrophagossypifolia Ratanjyot Euphorbiaceae

LagasceaMollis Silk Leaf Asteraceae

Lantana Camara Raimunia Verbenaceae



LeucasAspera Kubi Lamiaceae

LyxopersiconLycopersicum Tamata Solanaceae

Medicago Sativa Lachko Papilionaceae

Nariumindicum Karne Apocynaceae

NymphaeaPubescens Kamal Nymphaeaceae

NymphoidesIndicum Kumudini Gentianaceae

Ocimum Sanctum Tulsi Lamiaceae

Oryza Sativa Chokha Poaceae

Pedalium Murex Gokhru Pedaliacae

Punicagranatum Dadam Puniacaceae

SolanumIndicum Ringni Solanaceae

SolanumNigrum Piludi Solanaceae

SolanumSurattense Bhoringni Solanaceae

Sorghum Bicolor Jowar Poaceae

TaraxacumOfficianale Dandelion Asteraceae

TehrosiaPurpurea Sarpankho Papilionaceae

TridaxProcumbens Bhangro Asteraceae

Xanthium Indicum Clotbur Asteraceae

Xanthium Strumarium Clotbur Asteraceae

Zea Mays Makai Poaceae



Table 3.26

Faunal Diversity

(A) Terrestrial & Aquatic Birds in the Study Area

Scientific Name Common Name

AcridotheresTristis Indian Myna

AlcedoAtthis Kingfisher

AnasPoecilorhyncha Duck

ApusApus Common Swift

ArdeolaGrayii Indian Heron

AtheneBrama Spotted Owlet

Bubulcus Ibis Cattle Egret

CentropusSinensis Greater Coucal

CeryleRudis Kingfisher

CetntropusSinensis Coucal

Columba Livia Rock Pigeon

CorvusCorax Common Raven

CorvusSplendens House Crow

EgrettaGarzetta Egret

ElanusCaeruleus Kite

EremoptrixGrisea Sparrow-Lark

EudynamysScolopacea Asian Koel

Halcyon Smyrnensis White Kingfisher

HimantopusHimantopus Black-Winged Stilt

MeropsPersicus Bee-Eater

MotacillaMaderaspatensis White Wagtail

MycteriaLeucocephala Painted Stork

Passer Domesticus Sparrow

PavoCristatus Peafowl

PhalacrocoraxFuscicollis Cormorant

PseudibisPapillosa Black Ibis

PsittaculaKrameri Parakeet

PycnonotusCafer Bulbul

SaxicoloidesFulicata Indian Robin

SpilopeliaSenegalensis Dove

StreptopeLiachinensis Spotted Dove

StreptopeliaDecaocto Eurasian Collared Dove

TurdoidesCaudatus Babbler

TurdoidesStriatus Jungle Babbler

VanellusIndicus Lapwing



(B) Mammals and Reptiles in the Study Area

Scientific Name Common Name

BoselaphusTragocamelus Nilgai

BungarusCaeruleus Common Krait

CalotesVersicolor Common Garden Lizard

CalotesVersicolor Garden Lizard

Canis Lupus Familiaris Indian Pariah Dog

DaboiaRusselii Russell‟s Viper

FunambulusPennantii Palm Squirrel

HemidactylusFlaviviridis Gecko

HerpestesEdwardsii Mongoose

LepusNigricollis Indian Hare

MusBooduga Field Mouse

NajaNaja Cobra

Presbytis Entellus Monkey

Ptyas Mucosa Dhaman

PtyasMucosus Common Rat Snake

RattusRattus Rat

Semnopithecus Entellus Langur

TateraIndica Indian Rat

XenochrophisPiscator Checkered Keelback



Table 3.27

Traffic Survey TRAFFIC SURVEY SHEET

Location of Industry is on Rajpur to Kherpur village Road, which finally opens

on State Highway 41 (SH-41)

Location State Highway 41 (SH-41)

TIME 09.00 to 10.00 DATE 16/01/2019

Total PCU calculation Total PCU/hr

BUSES*/truck 96 PCU x 3 288

CARS/VANS 342 PCU x 1 342

MOTORCYCLES / BICYCLES 472 PCU x 0.5 236

Total 866

TIME 18.00 to 19.00 DATE 16/01/2019

Total PCU calculation Total PCU/hr

BUSES* 90 PCU x 3 270

CARS/VANS 328 PCU x 1 328

MOTORCYCLES / BICYCLES 524 PCU x0.5 262

Total 860

Note: *Mini-bus, Chartered Bus, School Bus, have been collectively

classified as Buses.

The road from Ahmedabad to Mehsana SH (41) is four track lanes with

divider, all types of vehicles move on the road.

Capacity of road as per IRC = 2000 PCU‟s/hr.

Total Volume during Peak Hours = 852

Existing Volume/Capacity ratio = 866/2000= 0.433

The level of service is “C” that is Good

LEVEL OF SERVICE

Sr.

No.

Existing Volume/

Capacity Ratio

Level of Services

1. 0.0 to 0.2 “A” (Excellent)

2. 0.2 to 0.4 “B” (Very Good)

3. 0.4 to 0.6 “C” (Good)

4. 0.6 to 0.8 “D” (Fair)

5. 0.8 to 1.0 “E” (Poor)



Table 3.28 Land Use Pattern

Name of

Village

Total Area

of the

Village (ha)

Irrigated

by source

(ha)

Un-

irrigated

(ha)

Cultivable

waste

(ha)

Area not

available for

cultivation (ha)

Dholasan 384.52 400 157.3 0 3

Alampur 155.32 50 80.9 8.5 0

Bhatasan 494.04 260 70 119.2 0

Mokasan 468.2 218.2 0 167 1

Jasalpur 744.6 443.6 228 0 1.4

Visalpur 124.1 50.4 43.4 12.5 0.9

Mathasur 771.6 400 282.9 0 2.6

Aldesan 626.9 450 138.2 1.3 0

Kundal 634.7 395 95 0 26.3

Tundali 601.15 195.4 342.2 0 49.9

Mandali 347.33 210.2 277.7 0 38

Ganeshpura 344.48 0 0 0 0

Kaiyal 1100.93 500 512.9 0 3

Navi Sedhavi 499.5 400 39.5 0 51.4

Tankiya 223.92 62.4 144.1 0 4.2

Hadvi 318.45 200 54.6 0 18.6

Anandpura 316.09 152.2 87.1 42 0.4

Nandasan 1618.62 1276 117.6 0 3

Kherpur 453.72 375 38.3 0 0

Lakshmipura 0 200 24.9 0 2.8

Chandarda 289.49 150 51.5 8 0

Sarsav 886.94 715 89.6 8.6 0

Untva 880.73 478.4 285.1 15.1 5.3

Dangarva 1800.66 350.4 1223.7 0 2.4

Ghumasan 908.75 400 262.5 0 5.4

Chadasna 437.1 249.2 46.6 0.6 30

Irana 906.14 450.3 301.6 25.1 4.2

Indrad 1063.52 250 310.5 30 81

Budasan 662.23 261 37.9 50.8 3.6

Karannagar 1578.52 505.7 728 1.8 90

Ankhol 146.86 23.1 0 0 4.9

Bileshvarpura 245.85 120 4.2 97.5 0.9

Rajpur 181.74 51 0 0 1

Karjisan 567.28 92.3 0 350 10

Jhulasan 915.46 9.9 765.9 59.4 16

Ambavpura 250.62 168.4 0 5 20.2

Dhanali 453.76 350 61 8.8 0

Vadu 324.61 180 90 0 35.4

Achrasan 470.1 200 164.6 0 1.9

Manipur 672 441 47.4 69.6 69.6

Juni Sedhavi 454.4 300 75.6 0 34.7

Vadavsvami 333 120 168 0 27

Pansar 1682.32 1059 400 6 40.1



Table: 3.29 Summary of Socio-economic status of Study area (Demography)

Name of the

Village/

Town/

Ward

No. of

Occupied

Residential

House

Total Population

(Including

institutional and

houseless

population)

Literates Total main

Workers

Marginal

Workers Cultivators

Agricultural

Labourer Non-Worker

P M F M F M F M F M F M F M F

Dholasan 252 1231 647 584 474 347 377 64 21 5 61 2 241 57 265 504

Alampur 194 1059 538 521 407 333 278 19 25 10 148 4 33 7 235 492

Bhatasan 454 2206 1130 1076 880 627 641 85 8 1 174 13 316 54 481 990

Mokasan 365 1600 816 784 655 499 458 232 7 1 169 4 107 124 351 551

Jasalpur 562 2411 1228 1183 970 692 699 366 1 7 153 120 338 218 528 810

Visalpur 247 1215 640 575 488 308 381 330 2 20 108 10 151 166 257 225

Mathasur 578 2766 1409 1357 1169 884 693 53 92 131 109 9 241 8 624 1173

Aldesan 504 2423 1233 1190 925 666 686 116 32 130 114 2 437 92 515 944

Kundal 262 1323 683 640 525 440 345 18 20 123 47 0 105 2 318 499

Tundali 529 2743 1438 1305 1153 1021 793 38 21 14 225 4 377 18 624 1253

Mandali 208 1090 533 557 399 292 321 30 1 0 96 1 198 22 211 527

Ganeshpura 345 1504 768 736 595 447 416 135 33 7 186 40 48 45 319 594

Kaiyal 894 4352 2396 1956 1837 1173 1483 249 59 296 366 54 505 139 854 1411

Navi Sedhavi 382 1929 1023 906 805 598 583 353 1 1 204 3 149 136 439 552

Tankiya 259 1342 692 650 507 362 344 6 16 7 83 2 107 2 854 1411

Hadvi 160 780 415 365 321 244 216 11 7 1 62 0 80 5 192 353

Anandpura 255 1180 610 570 524 413 336 52 14 76 107 8 48 12 260 442

Nandasan 2605 13440 6972 6468 5393 4483 3297 411 268 116 559 54 696 168 3407 5941

Kherpur 351 1704 862 842 700 581 485 37 24 13 156 12 43 3 353 792

Lakshmipura 358 1658 855 803 734 644 491 196 8 6 166 3 20 11 358 605

Chandarda 419 2210 1146 1064 847 579 611 189 16 66 204 17 185 61 519 809

Sarsav 509 2486 1312 1174 1020 710 683 44 28 419 224 7 280 28 601 711

Untva 428 2065 1081 984 840 647 543 106 16 51 98 2 257 85 522 827

Dangarva 1129 5355 2797 2558 2244 1720 1485 347 66 11 341 98 492 180 1246 2200



Ghumasan 951 4631 2408 2223 2002 1739 1306 242 39 10 334 6 262 14 1063 1971

Chadasna 329 1508 747 761 585 472 415 96 10 26 160 21 125 41 322 639

Irana 717 3562 1863 1699 1379 961 1003 98 81 164 223 3 319 39 779 1437

Indrad 1006 4938 2665 2273 2086 1354 1270 125 175 449 323 7 235 83 1220 1699

Budasan 762 3249 1730 1519 1338 915 979 202 36 35 118 25 167 19 715 1282

Karannagar 1436 6794 3489 3305 2779 2156 1802 198 167 379 419 6 387 42 1520 2728

Ankhol 389 1891 1020 871 799 521 581 16 36 16 25 0 179 7 403 839

Bileshvarpura 422 2071 1113 958 858 593 559 102 23 37 65 19 72 11 531 819

Rajpur 275 1298 662 636 490 335 382 33 0 2 69 4 238 22 280 601

Karjisan 661 2971 1535 1436 1258 938 873 316 13 3 240 17 344 167 649 1117

Jhulasan 1073 5046 2605 2441 1967 1404 1292 165 140 197 246 11 225 49 1173 2079

Ambavpura 276 1309 682 627 531 445 398 51 2 0 145 1 110 29 282 576

Dhanali 534 2590 1328 1262 1055 811 745 181 20 8 255 126 303 46 563 1073

Vadu 569 2857 1459 1398 1140 838 746 105 50 293 308 7 256 74 663 1000

Achrasan 390 2079 1034 1045 762 554 560 33 30 358 185 3 51 20 444 654

Manipur 297 1312 687 625 552 403 412 36 7 87 107 3 186 13 268 502

Juni sedhavi 362 1647 859 788 678 512 449 106 67 30 62 0 80 5 343 652

Vadavsvami 245 1186 597 589 455 359 326 7 7 14 42 1 139 4 264 568

Pansar 1874 8438 4467 3971 3564 2693 2339 368 111 190 277 46 337 173 2017 3413



Table 3.30: Summary of Socio-economic status of Study area (Amenities)

Name of

Village

Educational

Facility

Medical Facility Drinking

Water

Facility

Communication

( Post or

Telegraph)

Transportation

Facility

(Bus etc.)

Approach to

Village

Nearest

town and

Distance

(Kms.)

Power

Supply

Dholasan PP(5-

10),P,S(5-

10),SS(5-10)

PHC(5-10),

PHS,MCW(5-10,FWC(5-

10),D(5-10),VH(5-10)

T,TW,TK, PH,PCO,SPO BS,RS PR,KR,FP Ambaliyasan EA

Alampur P,S(<5),SS

(<5)

PHC,PHS,MCW,VH,

FWC(<5)

T,TW,TK PO,PH,PCO,SPO BS,RS(5-10) SH(5-10),

PR,KR,FP

Kadi EA

Bhatasan P,S(5-10) PHC(5-10),PHS(5-10),

D(5-10),MCW(5-10),

VH(5-10),FWC(5-10)

T,TW PCO,PO,SPO BS PR,FP,KR Kadi EA

Mokasan PP(5-

10),P,S(<5),SS

(5-10),ASC(5-

10)

PHC(5-10),PHS(5-10),

D(5-10), VH(<5),

TBC(5-10), MCW(5-

10),FWC(5-10)

T,HP PO(<5),PH,PCO,

SPO(<50)

BS,RS(5-10) SH(,5),KR,

WBM(5-10),

PR, FP

Kadi EA

Jasalpur PP(5-10),P(2),

S, SS(5-10),

ASC(5-10)

PHC(5-10), PHS,

MCW(5-10), FWC(5-

10), D(5-10)),VH(5-10)

T,TW,TK PH,PCO,SPO,

PO(5-10)

BS,RS(5-10) PR,KR,FP,WB

M(5-10)

Kadi EA

Visalpur PP(5-10), P,

S(<5),SS(5-

10),ASC(5-10)

PHC(5-10),

PHS(<5),MCW(<5),TBC

(5-10),D(5-10),VH(5-

10),FWC(5-10)

T,TW,R/C PH, PCO(5-10),

SPO(<5),

PO(5-10)

BS,RS(5-10) SH(5-10),

PR,FP,KR,

WBM

Kadi EA

Mathasur P(3),SS,S D(5-10),VH(5-10),

PHC(5-10),

PHS(<5),MCW(<5),TBC

(S-10),FWC(5-10)

T,TW,R/C PH,PCO(5-10),

PO(5-10),

SPO(<5)

BS,RS(5-10) SH(5-

10),WBM,PR,

KR,FP

Kadi EA

Aldesan P,PP(5-10),

S(<5),SS(<5),

ASC(<5)

PHC(<5),PHS(<5),MCW

(<5),TBC(<5),FWC(<5)

, D(<5),VH(<5)

T,TW PH,PCO,PO(<5),

SPO(<5)

BS,RS(<5) PR,KR(<5),

FP,WBM(<5)

Kadi EA

Kundal PP(<5),P,

S(<5),

ASC(<5),

SS(<5)

PHS,PHC(<5),

MCW(<5), TBC(<5),

FWC(<5), D(<5),

VH(<5)

T,TW PH,PCO,SPO,

PO(<5)

BS,RS(<5) SH,WBM(<5),

PR,KR,FP

Kadi EA

Tundali PP(5-

10),P(3),S(5-

10),SS(5-10)

PHC(5-10), MCW(5-

10),D(5-10),VH(5-

10),FWC(5-10)

T,TW,TK PH,PCO,SPO BS,RS(5-10) PR,KR,FP,WB

M(5-10)

Ambaliyasan EA



Mandali P PHS(5-10) T,TW PH,PCO,SPO BS,RS(5-10) PR,KR,FP Becharaji EA

Ganeshpura PP(5-

10),P(2),S(5-

10),SS(5-10)

PHC(5-10),PHS(5-

10),MCW(5-10),

D(<5), VH(<5),

FWC(<5)

T,TW PH,PCO,SPO(5-

10),PO(5-10)

BS,RS(5-10) PR,KR,SH,FP Becharaji EA

Kaiyal P,S,SS(<5) PHC(5-10),PHS,

D(5-10)

T,TW,TK PH,PCO,SPO BS,RS SH(<5),PR,K

R,FP

Kadi EA

Navi Sedhavi P,PP(5-10),

S(5-10), SS(5-

10)

PHC(5-10),

PHS,MCW(5-10),

D(5-10),VH(5-10)

T,TW PO(<5),PH,PCO(5

-10),SPO(5-10)

BS PR,KR(5-10),

WBM(5-10),

FP

Ambaliyasan EA

Tankiya P PHC(<5),PHS(<5),MCW

(<5),D(<5),VH(<5)

T,TW,TK,

W

PH,PCO(<5),SPO(

<5),PO(<5)

BS,RS(<5) PR,KR,FP Kadi EA

Hadvi P,S(5-

10),SS(5-10)

PHC(5-10) T,TW PH,PCO,PO(5-

10),SPO(5-10)

BS,RS(5-10) SH(5-10),PR,

KR(5-10),FP

Mahesana EA

Anandpura P PHS(<5),PHC(<5),MCW

(<5),D(<5)

T,TW,TK PH,PCO(<5),SPO(

<5),PO(<5)

BS,RS(<5) PR,KR,

SH(<5), FP

Kadi EA

Nandasan P(7),S(2),SS PHC,PHS(2) T,TW,TK PH,PCO,SPO BS,RS(<5) PR,KR,FP,

SH(<5)

Kadi EA

Kherpur PP(5-10),P(2),

S(5-10),SS(5-

10),ASC(5-10)

PHC(5-10), PHS(5-10),

MCW(5-10),TBC(5-

10),D(5-10),FWC(S-10)

T,TW PO(5-

10),SPO(<5),PH,P

CO(5-10)

BS,RS(5-10) SH,PR,KR,WB

M(5-10),FP

Kadi EA

Lakshmipura P,S(5-10) PHC(<5),PHS(<5),MCW

(<5),FWC(<5)

T,TW PO(<5),SPO(<5),

PH,PCO(<5)

BS SH,PR,KR,FP Kadi EA

Chandarda P,SS(5-10) PHC(<5),PHS(<5),MCW

(<5),FWC(<5),

D(<5),VH(<5)


PH,PCO

BS,RS(5-10) SH,PR,KR,FP Kadi EA

Sarsav PP(<S),P,

S(<5),SS(<5),

ASC(<5)

PHC(5-10),

PHS(5-10),MCW(5-10),

TBC(5-10), FWC(5-10),

D(5-10), VH(5-10)

T,TW,TK PO(5-10),

SPO,PH,PCO

BS,RS(5-10) SH,KR,PR,WB

M(5-10),FP

Kadi EA

Untva PP(<5)P,S(5-

10),SS(5-10),

ASC(<5)

PHC(<5),PHS,VH(5-

10),D(<5),MCW(<5),

TBC(<5),FWC(<5)

T,W,TW,T

K

PO(5-

10),SPO,PH,PCO

BS,RS(5-10) SH,KR,PR,WB

M(<5),FP

Kadi EA

Dangarva P(3),SS,S PHC,PHS,D(5-10) T,TW,TK PO,PH,PCO BS,RS SH(5-

10),KR,PR,FP

Kadi EA

Ghumasan PP(5-

10),P(2),S,

SS(<5)

PHC(5-

10),PHS,MCW(5-10)

T,TW SPO,PH,PCO BS,RS SH(<5),KR,

PR, WBM(6-

10),FP

Kalol EA



Chadasna P,S(5-

10),SS(5-10)

PHC(5-10),PHS(<5),

MCW(5-10),VH(5-

10),FWC(5-10)


PH,PCO(<5)

BS,RS(<5) SH,PR,KR,FP Kalol EA

Irana PP(5-

10),P,S(5-10),

SS(S-10),

ASC(5-10)

PHC(5-10),PHS(5-

10),MCW(5-10),TBC(5-

10),TBC(5-10),FWC(5-

10),D(5-10),VH(5-10)

T,W,TW,T

K

PO(<5),SPO(<5),

PH,PCO

BS,RS(5-10) SH,KR,PR,FP,

WBM(5-10)

Kadi EA

Indrad PP(5-

10),P,S,SS(5-

10),ASC(5-10)

PHC(5-10),PHS,

MCW(5-10),TBC(5-10),

D(5-10), VH(5-10),

FWC(5-10)

T,TW PO(5-

10),SPO,PH,PCO


WBM(5-10)

Kadi EA

Budasan PP(5-

10),P,S(5-10),

SS(5-10),

ASC(5-10)

PHC(<5),PHS(5-

10),MCW(5-10),

TBC(5-10), FWC(5-10),

D(5-10), VH(5-10)

T,TW PO(5-

10),SPO,PH,PCO


WBM(5-10)

Kadi EA

Karannagar PP(5-

10),P(3),SS(2),

ASC(5-10)

PHC(5-

10),PHS,VH,D(5-

10),MCW(5-10),TBC(5-

10), FWC(5-10)

T,W,TW,T

K

PO(5-

10),SPO,PH,PCO

BS,RS SH(5-

10),KR,PR,FP,

WBM(5-10)

Kadi EA

Ankhol PP(5-10),

P,S(5-10),

SS(<5),

ASC(5-10)

PHC(5-10), PHS(5-

10),MCW(5-10),

TBC(5-10),FWC(5-10),

D(5-10),VH(5-10)

T,TW PO(5-10),SPO(5-

10),PH,PCO

BS SH(<5),KR,

PR,FP,

WBM(5-10)

Kadi EA

Bileshvarpura PP(5-10), P,

S(5-10),

SS(<5),

ASC(5-10)

PHC(5-10), PHS,

MCW(5-10),TBC(5-

10),FWC(5-10), D(5-

10),VH(5-10)

T,TW PO(<5),SPO(5-

10),PH,PCO

BS,RS(<5) SH,PR,KR,FP,

WBM

Kalol EA

Rajpur PP(<5), P,

S(<5), SS(<5)

PHC(<5),PHS(<5),

MCW(<5),FWC(<5),

D(<5), VH(<5)

T,W,TW,H

P

PO(<5),SPO(<5),

PH,PCO

BS,RS(5-10) SH(<5),KR,P

R,FP

Kheralu EA

Karjisan P(2),S,SS(<5) PHC(5-10),PHS T,TW,TK SPO,PCO,PH BS,RS(5-10) SH(5-10),

KR,PR,FP

Kadi EA

Jhulasan P(2),S,SS(<5) HO T,W,TW,T

K

PO(5-10),

SPO,PH,PCO

BS,RS SH(5-10),

KR,PR,FP

Kalol EA

Ambavpura P PHC(5-10),PHS(5-

10),MCW(5-10),FWC(5-

10),VH(5-10),D(<5)


PH,PCO

BS,RS(<5) SH(<5),KR,

PR,FP

Kalol EA

Dhanali P,S(5-

10),SS(5-10)

PHC(5-10),PHS,D(5-

10),VH(5-10)

T,TW,TK SPO,PH,PCO BS,RS(5-10) SH(<5),KR,

PR,FP

Kadi EA



Vadu P,S(<5),

SS(<5)

PHC(5-10),PHS T,TW SPO,PH,PCO BS SH,PR,KR,FP Visnagar EA

Achrasan PP(5-

10),P,S(5-

10),SS(<5),

ASC(5-10)

PHC(5-10), PHS(5-10),

MCW(5-10), TBC(5-

10),FWC(5-10), D(5-

10),VH(5-10)

T,TW PO(5-

10),SPO(<5),PH,P

CO

BS,RS(<5) SH(<5),PR,

KR,FP,

WBM(5-10)

Kadi EA

Manipur PP(5-

10),P,S,SS(5-

10),ASC(5-10)

PHC(5-

10),PHS,MCW(5-

10),TBC(5-10),FWC(5-

10),D(5-10),VH(5-10)

T,TW,TK SPO,PH BS PR,KR,FP,WB

M(5-10)

Kadi EA

Juni sedhavi PP,P,S(5-10),

SS(5-10)

PHC(5-10), MCW(5-

10),TBC(5-10), FWC(5-

10),D(5-10), VH(5-10)

T,W,TW,T

K

PH,SPO,PCO(5-

10)

BS,RS PR,FP Ambaliyasan EA

Vadavsvami PP(5-10),P,

S(5-10),

SS(<5),

ASC(5-10)

PHC(<5),PHS(5-

10),MCW(<5),TBC(5-

10),D(<5),VH(5-

10),FWC(5-10)

T,TW,TK PO(5-10),SPO(5-

10)PH,PCO

BS,RS(5-10) SH(5-10),PR,

KR(5-10),

WBM,FP

Kalol EA

Pansar PP(5-10),

P(2),S,SS,

ASC(5-10)

PHC,PHS(2),MCW,TBC,

VH,FWC(5-10)

T,W,TW,T

K

PO,SPO(5-

10),PH,PCO

BS,RS SH(5-

10),KR,PR,

FP,WBM

Kalol EA



Abbreviations:

Educational PP - Preprimary School

P - Primary School S - Secondary School

SS - Senior Secondary School C - College

Medical Facility

MCW - Maternity & Child Welfare Centre PHC - Primary Health Centre

PHS - Primary Health Sub-Centre

CHC - Community Health Centre HO - Allopathic Hospital

D - Dispensary FWC - Family Welfare Centre

CWC - Child Welfare Centre HA - Ayurvedic Hospital

MHC - Mobile Health Clinic T.B - T.B Clinic

Drinking Water

T - Tap Water HP - Hand Pump

TW - Tube well Water W - Well Water

TK - Tank water

R/C - River/Canal

Post and Telegraph PO - Post Office

PH - Telephone Connection SPO - Sub Post Office

PCO - Public Call Office

Transportation BS - Bus

RS - Railway Station

Approach to Village SH - State Highway

PR - Pucca Road

KR - Kutccha Road WBM - Water bound macadam

FP - Foot path

Power Supply EA - Electricity for all Purposes



Figure 3.7

Location of AAQM station

Indicating AAQM stations



Figure 3.8

Wind Rose diagram



Figure 3.9

Water sampling Locations

Indicating Ground Water sampling location

Indicating Surface Water Sampling location



Figure 3.10

Noise monitoring locations

Indicating Noise Monitoring location



Figure 3.11

Soil Sampling Locations

Indicating locations of Soil sampling



Figure 3.12 Toposheet of location with site location map of 10 km

radius (1:50,000 scale)


Draft EIA report of Urmit Chemicals Pvt. Ltd. 4-1

Chapter-4

Anticipated Environmental Impacts &

Mitigation Measures

4.1 GENERAL

Environmental Impact can be defined as any change in environmental

conditions which may be adverse or beneficial; occurred due to action or

set of actions under consideration. It can be assessed by identifying the

sources of the impact and predicting the same. The identification of

environmental impacts has been made by co-relating the relationship

between project activity and environmental parameters. As a part of

present EIA study, anticipated environmental impacts associated with the

project activity of the unit have been identified. The project activities are

usually divided into two phases: Construction Phase and Operation Phase.

For evaluation of impacts due to proposed activities, baseline data has

been utilized. Changes in the environmental parameters & their impact in

terms of short term or long term, positive or negative, reversible &

irreversible are identified & predicted.

The next step is prediction of impacts, which is an important component

in environmental impact assessment process. Several techniques and

methodologies are in vogue for predicting the impacts due to proposed

industrial development on physical, chemical, biological and socio-

economic components of environment. Such predictions delineate

contribution in existing baseline condition for the proposed project. The

additional impacts due to proposed activities are analyzed by keeping in

mind the baseline status. This helps to assess the assimilative capacity of

the environment and in turn the gravity of the impacts. Based on the

identification & prediction of the nature of impact, it can be evaluated

qualitatively and quantitatively.

In this chapter, the effect due to construction & operational activity of the

proposed project is explained.



4.2 IDENTIFICATION OF IMPACT

This chapter deals with the assessment of project impacts on

environment. Mitigation measures are suggested to minimize the likely

negative impacts. The network method (Cause - effect) was adopted to

identify potential impact of the proposed activity. It includes stepwise

study of relationship between an activity and its environmental

parameters. This method involves in the “Road Map” type of approach to

the identification of second & third order effect. The basic idea is to

account for the project activity & identify the type of impact that could

initially occur followed by the identification of secondary and tertiary

impact.

The project will have impacts of varying magnitude on different

environmental components. These impacts could be categorized as -

Primary impacts, i.e. impacts which occur as a direct result of the

project activities.

Secondary and tertiary impacts, i.e. impacts that occur as a result

of primary impacts.

4.2.1 Identification of Impacting Activities

Various activities involved in the project are divided viz.:

A. Construction phase activities: impacts are immediate, in the vicinity

and sporadic

B. Operation phase activities: impacts are long term, in wide area and

continuous

The activities identified for the project under each phase are:

Construction phase

Excavation

Foundation & Civil work

Transportation of construction materials, equipments & machineries

Installation of equipments & machineries

Operation phase

Plant operation

Material storage & handling

Utilities and services

Green belt development



4.2.2 Identification of Environment Attributes

There are various types of impacts arise due to the proposed activities

which will be evaluated considering the following environment parameters

in construction and operational phase,

Impact on Topography

Impact on Air Environment

Impact on Water Environment

Impact on Noise Environment

Impact on Land Environment (Hazardous/solid waste generation)

Impact on Biological Environment

Impact on Socio-Economic Environment

Impact on Occupational Health & Safety

4.3 IMPACT ON TOPOGRAPHY

Unit will be situated at Survey No. 1384, Village: Rajpur, Tal: Kadi, Dist:

Mehsana, Gujarat. Proposed land is already converted from agriculture to

non-agriculture for industrial purpose. During the construction, excavated

soil will be restored to its original shape. Thus, the impact during the

construction is reversible, for short terms and insignificant. Construction

of plant & building will be carried out for proposed unit. During the

operational phase of the project, no major impact is envisaged on the

topography.

4.4 IMPACT ON AIR ENVIRONMENT

a. Construction Phase impact & mitigation measures

During construction phase, there will be chances of dust generation due

to the construction activities to be carried out as per the plant design. It

will be limited up to working area only and not likely to spread in wider

area. To mitigate the impact, regular sprinkling of the water will be done.

Vehicular traffic may lead to increased concentration pollutants through

exhaust gases, affecting the ambient air quality of surrounding areas;

vehicles only with PUC certificates will be allowed. However, this effect

remains localized near to the plant site and during the time of vehicular

movement only. Thus, overall impact is envisaged as short-term negative

& reversible in nature. Hence, looking to the overall facts described



above, it can be concluded that, the impacts on air due to the

construction & erection activities will be minimum or negligible.

b. Operational phase impact & mitigation measures

Long term impacts on the air quality are anticipated due to operational

activities. It depends on various factors like process technology,

operation & maintenance, raw material, fuel, air pollution control

measures. For the study of impact assessment for air environment, all

probable emissions are studied including fugitive emission. The sources

and expected emission level are described in below section.

Emission from the project

Flue gas emission will be from stack attached with boilers, Hot Air

Generator & Thermic Fluid Heater, where low sulfur coal will be used as

fuel; and standby D.G. Set in which Diesel will be used as fuel. Process

emission will be from the vents attached to Reaction Vessels of

Multipurpose Plant – 2 sets and Reaction Vessel of Chloranil. Additionally,

spray dryer is also considered as source of process emission. Main

pollutants from flue gas stack will be SPM, SO2 and NOx and PM, SO2 and

HCl are pollutants emit from process.

Mitigation measures

All the flue gas stacks except stack of D.G. Set will be equipped with

Cyclone & bag filter as APCM. Spray dryer will be equipped with Cyclone

+ Scrubber + Sub merged type gas bubbling tank. Alkali scrubbers will

be provided on process gas stack attached to reaction/ process vessels (2

sets) and water scrubber will be provided on process gas stack attached

to Reaction/ Process vessels (Chloranil) as APCM. The details of process

gas stacks with their APC measures & height are given in Table 2.8.

4.4.1 Air Pollution Dispersion Modeling of stack

Following sub-section give air dispersion modeling details for prediction of

changes in GLC of pollutants emitted from the above stacks.

Objective: The objective of dispersion modeling is to predict the ground

level concentration during the operation of the project and its impact on

ambient air quality of the area concentrations and compare with

applicable NAAQS.



Model used: The impact on air quality due to emissions from single

source or group of sources is evaluated by use of mathematical models.

The impacts of air pollutants were predicted using Gaussian air dispersion

model, which is selected on the basis of existence of multiple point

sources within the industrial complex and the plain terrain at the project

site. In order to predict the impact of air pollutants on ambient air

quality, ISCST3 model (Industrial Source Complex – Short Term

(ISCST3) dispersion model) of United State Environmental Protection

Agency (USEPA) was used by considering guidelines stipulated by CPCB

for air pollution dispersion modeling. The Gaussian model provides

estimates of pollutant concentrations at various receptor locations.

It is an hour-by-hour steady state Gaussian model which takes into

account the following:

Terrain adjustments

Stack-tip downwash

Gradual plume rise

Buoyancy-induced dispersion, and

Complex terrain treatment and consideration of partial reflection

Plume reflection off elevated terrain

Building down wash

Partial penetration of elevated inversions is accounted for Hourly

source emission rates, exit velocity and stack gas temperature

Only two stability conditions based on the meteorology aspects were used

to calculate the theoretical maximum ground level concentration is

comparing the actual data and data generated from mathematical

modeling, it highlights that the stability condition E & A-B were

predominant in the region.

Following are the assumptions made while using the model:

- No dry and wet depletion of pollutants

- Receptors are on flat terrain

The key emitted pollutants will be SPM, SO2, & NOx & HCl.

4.4.2 Micrometeorology

Hourly micrometeorological data collected during the study period

(January 2019 to March 2019) have been used for modeling. The



hourly wind speed, solar insolation & total cloudiness during day time and

wind speed & total cloudiness during night time were used to determine

the hourly atmospheric stability classes (defined by Pasquill and Gifford

as A to F, A being most unstable and F being most stable). The hourly

stability classes were determined based on the technique suggested by

Turner.

Turner’s system used for determining the stability classes is as follows:

- For day or night: If total cloud cover (TC) = 10/10 and ceiling

<7000 ft (2134 m), NR=0

- For night-time (defined as period from one hour before sunset to

one hour after sunrise):

a) If TC<4/10, use NR = -2

b) If TC>4/10, use NR = -1

- For daytime: determine isolation class number (IN)

a) If TC<5/10, use NR=IN

b) If TC>5/10, modify IN by the sum of the following applicable

criteria

If ceiling<7000 ft (2134 m), modification = -2

If ceiling>7000 ft but <16000 ft (4877 m), modification = -1

- If TC=10/10 and ceiling>7000 ft, modification = -1 and let modified

value of IN=NR, except for day-time NR cannot be <+1.

During the study period, stability calculated based on above-mentioned

Turner method gives average stability as A-B class during Day time and E

class during Night time.

4.4.3 Input data

Stack emissions data have been used for prediction of incremental GLC

values of SPM, SO2, NOx and HCl using one season meteorological data

during (January, 2019 to March, 2019). Input data includes

quantitative expected emission levels, temperature, and mixing height

from the stack. Input data is given in Table 4.1.

4.4.4 Receptor Network

Uniform polar grid and ambient air monitoring locations are considered as

discrete Cartesian receptor network for entire study area of 10 km radius.



4.4.5 Output of model (24-hourly GLCs)

The 24-hourly average Ground Level Concentration (GLC) values from

project have been computed for SPM, SO2, NOx & HCl considering

topographical features around the plant & applicable stability classes. The

maximum 50 (24-hr) average concentration values for SPM, SO2, NOx &

HCl are given in Table 4.3 to 4.6. Corresponding Isopleths for 24-hourly

predicted value is generated which is shown in Figure 4.1 to 4.4.

It may be noted from the computed result for the proposed scenario that,

the highest 24-hourly average GLCs value of SPM, SO2, NOx & HCl from

the proposed activity are 4.161 g/m3, 3.154 g/m3, 1.702 g/m3 and

0.099 g/m3, respectively. These GLCs are expected to occur at a

distance of 1.0 km from the source in E direction. With this marginal

contribution due to the proposal of the project, the levels of PM10, SO2,

NOx & HCl will remain well below the 24-hourly ambient air quality

standards for SO2 & NOx (80 g/m3), PM10 (100 g/m3), PM2.5 (60 g/m3)

prescribed by CPCB.

4.4.6 Incremental & cumulative concentration of pollutants

The maximum incremental GLCs due to project for SPM, SO2, NOx, HCl is

superimposed on the baseline concentrations recorded during the study

period to arrive at the likely resultant concentrations after

implementation of the proposed plant. The cumulative concentrations

(baseline + incremental) of the project is tabulated below at Table 4.2.

4.4.7 Conclusion

The modeling study proved that, the air emissions from the proposed

activities would not likely to cause any significant impact on the ambient

air quality of the study area. The ambient air quality around project site

will remain within the National Ambient Air Quality Standards (NAAQS)

prescribed for residential area.

4.5 IMPACT ON WATER ENVIRONMENT

The main sources of impact on water environment will be due to

withdrawal of fresh water from the ground during construction and

operation phase. These are discussed below.



a. Construction Phase impacts & mitigation measures

The water requirement for various purposes will be met from ground

water. During construction work, water requirement is estimated to be

about 10-15 KLD depending upon nature of construction work. In addition

to this, about 1-2 KLD fresh water will be required for domestic activities

of the construction staff which will also be met through the same source.

There will be no wastewater generation from the construction work.

Hence, it can be concluded that there will be no adverse impact during

construction phase.

b. Operational Phase impacts & mitigation measures

Total water requirement (Industrial + Domestic + Greenbelt) at Urmit

Chemicals will be 178 KLD; out of which 103 KLD will be fresh water

requirement & 75 KLD will be recycle/treated water. Unit will satisfy its

fresh water demand from groundwater source. Major water demand will

be industrial – mainly Process (45 KLD), Scrubber (14 KLD), Washing (25

KLD), Cooling (45 KLD) and Boiler (30 KLD).


domestic wastewater and the rest will be industrial wastewater. The main

source of the industrial wastewater generation will be from process (80

KLD), Scrubber (2 KLD), Washing (25 KLD) and utilities (Boiler & cooling

- 18 KLD). Comprehensive details are mentioned in Table 2.6; Water

balance diagram in Figure 2.5 in Chapter 2.

The wastewater generated will be segregated into two streams for

treatment. Process wastewater will be treated in “ETP-1”. Wastewater

from utilities (cooling & boiler), washing and scrubber will be treated in

“ETP-2”. Effluent from “ETP-1” will be sent to Common Spray Drying

facility at Chhatral Environment Management System Pvt. Ltd. for

evaporation. Effluent from “ETP-2” will be sent to RO and permeate will

be reused; RO reject will be sent to common Spray Drying facility.

Domestic wastewater will be discharged into soak pit.

c. Impact Assessment

As fresh water will be met from Bore well water supply, unit will balance

it by recharging ground water during the monsoon. Hence, insignificant

impact envisage on ground water. Industry will develop rain water



harvesting structures nearby project area. So, there will not be any major

impact on the water environment due to proposed activities.

Mitigation Measures:

Minimum use of water will be done for construction phase.

Maximum reuse of water from RO during operational phase.

Regular maintenance of rain water harvesting structures shall be

undertaken to have effective recharge.

4.6 IMPACT ON NOISE ENVIRONMENT

Any unwanted sound that creates disturbance in hearing is termed as

Noise. Hence, it is important to assess the present noise quality of the

area in order to predict the potential impact of future noise levels due to

the project.

a. Construction Phase Impact & mitigation measures

During the construction phase at Urmit Chemicals impacts on noise level

will occur due to the noise generation from new equipments/machineries

as well as some impact due to transportation. Mainly the impacts of

increased noise levels during construction are likely to occur due to

increase movement of trucks & other diesel-powered material handling

equipment. The impacts of noise during the construction would be

restricted to the site only and will be temporary. PPEs like ear muff/ear

plug will be provided to the workers. Regular maintenance & lubrication

of construction equipment & machineries will be undertaken to reduce the

noise generation. Thus, it is envisaged that the impacts on noise during

the construction phase would be insignificant after mitigation measure.

b. Operational Phase Impact & mitigation measures

During operation of Urmit Chemicals, noise levels will increase due to

manufacturing process activities. The noise anticipated from the project

will be confined only within plant boundary. Adequate greenbelt will be

developed for prevention of noise propagation outside plant premises.

Oiling/lubrication & preventive maintenance will be done to reduce noise

generation at source to the permissible limit. However, at places where

noise levels may exceed the limit, PPEs will be provided to workers.

Adequate noise control measures such as silencers, anti-vibration pad

etc. will be provided. All the equipment will be designed/ operated in such



a way that the noise level in work place shall not exceed 85 dB(A) as per

the OSHA Standard. During operation, the protective measures like PPEs

(ear muff, ear plug) will be provided & the exposure duration of

workers/other personnel to noise will be managed as per OSHA standard.

The results of baseline monitoring carried out in the region are presented

in Chapter-3. The results are below the standards prescribed for

Industrial environment. It can be concluded that, the impact on noise

environment will be long term but insignificant.

4.7 IMPACT ON LAND ENVIRONMENT

The main source of impact on land and soil environment results due to

construction activities and hazardous waste disposal.

a. Construction Phase Impact & mitigation measures

The construction activities like excavation, clearing, leveling & vehicular

movements will entail change in the landscape, which are expected to be

of short duration and insignificant. Unit will provide sanitation facilities for

the staff engaged in construction work which will prevent the impacts on

land. Thus, there will not be any issue of impacts on land during the

construction phase.

b. Operational Phase impact (Solid/Hazardous Waste)

During the operation phase, it is identified that the impacts on land would

occur due to the contamination by Solid/Hazardous wastes. The

hazardous wastes are the major source of impacts on land. Hazardous

waste generation from project must be considered to identify the

potential impacts. At Urmit Chemicals, entire quantity of the hazardous

wastes will be stored in the isolated hazardous waste storage area within

premises having impervious platform having RCC floor, leachate

collection system & roof cover and disposed as per the scientific method.

Main source of hazardous waste will be wastewater treatment, generating

ETP sludge (150 MTPM). Hazardous waste from process will be HCl (20-

22%) (52 MTPM), Spent Sulphuric acid (780 MTPM), Calcium Thio

Sulphite (78 MTPM), Acetic Acid (104 MTPM), Sodium Bisulphite (260

MTPM), Iron sludge (52 MTPM) and Spent catalyst (0.5 MTPM).

Discarded containers (10000 Nos./month) /liners (1.0 MTPM) and used

lubricating oil (0.5 KL/yr).



Mitigation Measures:






Spent Sulphuric acid (H2SO4), Acetic Acid, Sodium Bisulphite will be

reused within the process or sold to actual users. Spent catalyst will be

sent for regeneration to the suppliers. Discarded containers/liners will be

disposed of by selling to registered recyclers; used lubricating oil will be

disposed by selling to registered recyclers. The unit will provided isolated

area with impervious flooring & roof cover for the storage of hazardous

waste. No adverse impact on the land environment is likely to occur.

Hence, no significant negative impact is envisaged on the surrounding soil

quality.

4.8 IMPACT ON BIOLOGICAL ENVIRONMENT

a. Construction phase impact & mitigation measures

This is a Greenfield project; hence minor cutting of trees/shrubs will be

done to clean the area. However, it will be balanced by developing

greenbelt within premises and along the roads. Various trees, shrubs and

herbs are found in and around it, a list of which is given in baseline. None

of the plants are in the list of endangered plant species. Also, the trees

are identified for their sensitivity & pollution tolerance capacity. This

concept helps to plan the greenbelt of the area making it less polluted

and a pollution absorber. Thus, it is envisaged that there will not be any

adverse impacts on the ecology/biological environment in construction

phase.

b. Operational phase impact & mitigation measures

There are no protected areas like national park/wildlife sanctuary within

the 10 km radial of the project site, so there will not be any significant

impact on ecology. No endangered floral or faunal species has been

recorded within the study area. Further, unit will develop greenbelt to

enhance the biological feature of the site. Also, the trees are identified for

their sensitivity & pollution tolerance capacity.



Following is the list of trees which are helpful as pollution absorber and at

the same time pollution sensitive.

Family Name Botanical Name Common

Name

Sensitive Tolerant

Anacardiaceae Mangiferaindica Mango Cement dust, Coal dust, SO2

Dust collector

Anonaceae Polyalthialongifolia Asopalav SO2 Dust collector

Caesalpini-

aceae

Cassia fistula Garmalo Cement dust,

Poor Dust collector, SO2

N.A

Delonixregia Gulmohar SO2, Fly ash, Cement dust

N.A

Meliaceae Azadirachtaindica Neem Cement dust SO2

Mimosaceae Pithecellobiumdulce Gorasamli N.A Better Dust

collector, SO2

There will not be any discharge of effluent on land or any receiving body

from Urmit Chemicals, and entire quantity of hazardous waste will be

handled & disposed as per Hazardous & Other Waste (Management &

Transboundary Movement) Rules, 2016. Hence there will not be any

impact on aquatic ecology of the surrounding area. GLCs of air pollutants

will remain low and hence no significant impact on terrestrial ecology is

expected. Thus, there will not be any significant impact on ecological

environment.

4.9 IMPACT ON SOCIO-ECONOMIC ENVIRONMENT

a. Construction Phase Impacts & mitigation measures

During the peak construction phase, construction manpower including

construction workers will be employed. However, to the maximum extent

possible, construction workers will be employed from within the study

area. Since the construction phase of this project will be for short time

period, the socio-economic impact due to construction of this project is

going to be temporary. Around 25-30 workers will be employed in the

construction work. This will increase construction employment in the

study area. As the construction phase for the proposed project will be few

months, the impact would be temporary.

b. Operation Phase Impacts & mitigation measures

The proposed unit will be located in private land, so no displacement of

person is envisaged. Unit will provide employment opportunity to locally



available skilled and un-skilled labors at different level as per the

requirement, which in turn result into a positive impact on prevailing

socio-economic environment. For the proposed activities, 100 nos. of

workers will be employed. In addition, employment will be generated by

the secondary supporting activities e.g. transportation, communication,

daily utility services. Surrounding area has got good educational facilities

and most of employees will come from the surrounding area. Thus,

overall impacts on socio-economic environment are long term and

positive in nature.

4.10 IMPACT ON OCCUPATIONAL HEALTH & SAFETY

a. Construction Phase Impacts & mitigation measures

In the Construction phase, some effects on occupational health & safety

of the employees working in the site are envisaged. Major health issues

encountered will be physical hazards & accidental hazards. All plans and

construction schedule will be followed as per relevant laws approved by

competent authority, so as to minimize the occupational health hazards.

Mitigation Measures

Necessary PPEs like helmets, ear plug/ear muff, safety shoes,

goggles etc. will be provided to workers.

Incident/accident reporting system will be developed and all the

employees will be made aware for the same.

Periodic inspection & testing of equipments & machineries will be

done.

b. Operational Phase Impacts & mitigation measures

In operational phase, various effects on occupational health and safety of

the employees working in the plant are envisaged. Major health and

safety issues encountered will be physical hazards, respiratory hazards,

electrical hazards, noise, fire hazards associated while working within the

plant. Preventive safety measures shall be taken to minimize the risk of

accident with respect to chemical handling.

Mitigation Measures

Emergency preparedness plan should be implemented.

First aid/other emergency treatment should be provided.



Workers shall be well equipped with PPEs. Only authorized persons

will be allowed inside the plant.

A health monitoring program shall be in place to monitor the health

of the persons working on the site to ensure the health status of all

concerned.

Fire extinguishers will be installed at different locations.

Sign boards will be displayed at designated locations indicating

appropriate hazard warnings.

Good house-keeping will be ensured within the factory premises.

4.11 IMPACT ON EXITING TRAFFIC SYSTEM

The traffic load is to be increased due to proposed project for the

transportation of finished goods and raw materials. Calculation of

transport load is summarized below.

Production: 400 MT/month and 1450 MT/month of different type of

hazardous waste which need to transport outside of factory premises.

Considering 26 days = 1850/26 = 71 Ton/day

Considering 20 T truck load = 71/10 = 7.1 say 7 nos. of vehicles/d

Generally, trucks use for raw materials are used for movement of finished

products. However, we are considering same numbers of truck for raw

material transportation i.e. 7.0 x 2 = 14

Considering to and fro movement, number of trucks passing per day will

be 14 x 2 = 14 nos.

Equivalent PCUs = 3.5 x 28 = 98/day

As per Indian Road Congress, a 4 lane divided road has a carrying

capacity of 2000 PCUs per hr.

Additional traffic from our project will be estimated 98 PCU/day

[28 trucks (in & out) x 3.5] and 25 PCU/day from car and

motorcycle, which have insignificant impact on existing traffic

load.

Existing Traffic Scenario and Level of Services

There will not be any major increase in transportation activity due to

proposed project as compared to present carrying capacity, which is

covered in Table 3.27 of Chapter-3 of EIA report.



Table 4.1

Input data for air quality modeling

Sr.

No.


Height

(m)

Temp.

(0K)

Velocity

(m/s)

Dia.

(m)

Concentration

(g/s)

SPM SO2 NOx

1 Steam Boiler

(1 TPH)

21 453 6.5 0.375 0.054 0.029 0.018

2 Steam Boiler

(2 TPH)

21 453 6.5 0.450 0.077 0.041 0.026

3 Hot Air Generator

(5.0 lac Kcal/hr.)

21 463 7.5 0.375 0.066 0.033 0.025

4 Hot Air Generator

(10.0 lac Kcal/hr.)

30 463 7.5 0.450 0.095 0.048 0.036


(25 lac Kcal/hr.)

30 473 7.5 0.500 0.132 0.059 0.052

6 DG Set (Stand By)

(500 kVA)

11 483 15.0 0.300 0.064 0.042 0.042

7 Spray Dryer-1

(20 KL/day)

15 328 5.5 0.450 PM = 0.031 g/s


Multipurpose Plant –

2 sets

11 323 5.0 0.225 SO2 = 0.006 g/s


Chloranil

11 323 5.0 0.225 HCl = 0.003 g/s



Table 4.2

Cumulative Concentrations at various locations

Station Direction Dist.

(Km)

Baseline

Concentration

(g/m3)

Predicted GLC

(g/m3)

Cumulative

Concentration

(g/m3)

PM SO2 NOx PM SO2 NOx PM SO2 NOx

Project Site (A1) -- -- 67.3 18.1 23.2 0.4 0.4 0.1 67.7 18.5 23.3

Laxmipura (A2) NNW(UW) 2.10 64.6 17.5 21.5 0.4 0.4 0.1 65.0 17.9 21.6

Chandarda (A3) ENE(UW) 1.45 70.3 18.7 21.0 3.2 1.6 1.2 73.5 20.3 22.2

Mathasur (A4) NW(UW) 5.50 67.6 19.1 22.4 0.0 0.0 0.0 67.6 19.1 22.4

Rajpur (A5) S(UW) 1.70 66.8 17.9 21.6 2.4 1.6 0.8 69.2 19.5 22.4

Irana (A6) SSW(DW) 4.50 64.5 18.3 22.0 0.4 0.0 0.0 64.9 18.3 22.0

Untva (A7) WSW(DW) 4.90 67.8 17.9 21.4 0.4 0.4 0.2 68.2 18.3 21.6

Bileshvarpura (A8) SSE(UW) 6.35 65.9 19.4 22.9 0.0 0.0 0.0 65.9 19.4 22.9



Table 4.3 24-hourly average GLC Concentration Values for SPM

RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE

1 4.161 ( 1000.00, .00) GC 26 2.388 ( .00, -2000.00) GC

2 4.043 ( 1000.00, 1000.00) GC 27 2.341 ( 2000.00, -2000.00) GC

3 3.713 ( .00, -1000.00) GC 28 2.336 ( .00, -1000.00) GC

4 3.674 ( 1000.00, -1000.00) GC 29 2.313 ( 3000.00, .00) GC

5 3.344 ( 1000.00, .00) GC 30 2.312 ( 1000.00, -1000.00) GC

6 3.323 ( -1000.00, -1000.00) GC 31 2.295 ( 2000.00, .00) GC

7 3.321 ( -1000.00, -1000.00) GC 32 2.288 ( 2000.00, .00) GC

8 3.274 ( 1000.00, -1000.00) GC 33 2.251 ( -1000.00, -1000.00) GC

9 3.237 ( 2000.00, .00) GC 34 2.248 ( -2000.00, -2000.00) GC

10 3.227 ( .00, -1000.00) GC 35 2.226 ( 1000.00, .00) GC

11 2.951 ( 1000.00, .00) GC 36 2.149 ( 1000.00, -1000.00) GC

12 2.914 ( 2000.00, 2000.00) GC 37 2.124 ( -1000.00, .00) GC

13 2.913 ( 1000.00, 1000.00) GC 38 2.123 ( .00, -3000.00) GC

14 2.903 ( 1000.00, .00) GC 39 2.115 ( -2000.00, -2000.00) GC

15 2.895 ( .00, -1000.00) GC 40 2.066 ( 2000.00, .00) GC

16 2.787 ( 1000.00, -1000.00) GC 41 2.061 ( 1000.00, .00) GC

17 2.778 ( .00, -2000.00) GC 42 2.035 ( 1000.00, .00) GC

18 2.770 ( 1000.00, -1000.00) GC 43 2.030 ( -1000.00, -1000.00) GC

19 2.729 ( -1000.00, -1000.00) GC 44 2.024 ( 3000.00, 3000.00) GC

20 2.649 ( 1000.00, .00) GC 45 2.018 ( -1000.00, -1000.00) GC

21 2.644 ( -1000.00, -1000.00) GC 46 2.000 ( 1000.00, .00) GC

22 2.610 ( 1000.00, -1000.00) GC 47 1.964 ( -1000.00, -1000.00) GC

23 2.580 ( -1000.00, -1000.00) GC 48 1.954 ( 1000.00, -1000.00) GC

24 2.488 ( .00, -2000.00) GC 49 1.947 ( -1000.00, .00) GC

25 2.452 ( 1000.00, .00) GC 50 1.944 ( -1000.00, -1000.00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3



Table 4.4 24-hourly average GLC Concentration Values for SO2


1 3.154 ( 1000.00, .00) GC 26 1.693 ( .00, -2000.00) GC

2 3.031 ( 1000.00, 1000.00) GC 27 1.645 ( 1000.00, -1000.00) GC

3 2.671 ( .00, -1000.00) GC 28 1.636 ( .00, -2000.00) GC

4 2.647 ( 1000.00, -1000.00) GC 29 1.600 ( 1000.00, .00) GC

5 2.471 ( .00, -1000.00) GC 30 1.587 ( -1000.00, -1000.00) GC

6 2.451 ( 1000.00, .00) GC 31 1.585 ( 2000.00, .00) GC

7 2.424 ( -1000.00, -1000.00) GC 32 1.564 ( -1000.00, .00) GC

8 2.392 ( -1000.00, -1000.00) GC 33 1.561 ( 2000.00, .00) GC

9 2.306 ( 1000.00, -1000.00) GC 34 1.559 ( 2000.00, -2000.00) GC

10 2.255 ( 1000.00, .00) GC 35 1.554 ( 1000.00, .00) GC

11 2.224 ( .00, -1000.00) GC 36 1.525 ( 3000.00, .00) GC

12 2.210 ( 2000.00, .00) GC 37 1.508 ( 1000.00, -1000.00) GC

13 2.207 ( 1000.00, .00) GC 38 1.502 ( -2000.00, -2000.00) GC

14 2.096 ( 1000.00, 1000.00) GC 39 1.501 ( -1000.00, -1000.00) GC

15 1.977 ( 1000.00, -1000.00) GC 40 1.464 ( 1000.00, .00) GC

16 1.971 ( 2000.00, 2000.00) GC 41 1.444 ( 1000.00, .00) GC

17 1.968 ( 1000.00, .00) GC 42 1.423 ( -1000.00, -1000.00) GC

18 1.968 ( 1000.00, -1000.00) GC 43 1.420 ( .00, -3000.00) GC

19 1.968 ( -1000.00, -1000.00) GC 44 1.410 ( 1000.00, .00) GC

20 1.935 ( .00, -2000.00) GC 45 1.407 ( 2000.00, .00) GC

21 1.929 ( -1000.00, -1000.00) GC 46 1.403 ( -2000.00, -2000.00) GC

22 1.856 ( 1000.00, -1000.00) GC 47 1.399 ( -1000.00, -1000.00) GC

23 1.856 ( -1000.00, -1000.00) GC 48 1.396 ( .00, -1000.00) GC

24 1.771 ( 1000.00, .00) GC 49 1.394 ( 1000.00, .00) GC

25 1.764 ( .00, -1000.00) GC 50 1.391 ( 1000.00, -1000.00) GC




Table 4.5 24-hourly average GLC Concentration Values for NOx


1 1.702 ( 1000.00, .00) GC 26 0.942 ( .00, -1000.00) GC

2 1.610 ( 1000.00, 1000.00) GC 27 0.929 ( .00, -2000.00) GC

3 1.474 ( .00, -1000.00) GC 28 0.913 ( 1000.00, -1000.00) GC

4 1.454 ( 1000.00, -1000.00) GC 29 0.899 ( 2000.00, -2000.00) GC

5 1.339 ( 1000.00, .00) GC 30 0.889 ( 2000.00, .00) GC

6 1.323 ( -1000.00, -1000.00) GC 31 0.888 ( 2000.00, .00) GC

7 1.318 ( -1000.00, -1000.00) GC 32 0.887 ( 3000.00, .00) GC

8 1.314 ( .00, -1000.00) GC 33 0.883 ( 1000.00, .00) GC

9 1.281 ( 1000.00, -1000.00) GC 34 0.883 ( -1000.00, -1000.00) GC

10 1.259 ( 2000.00, .00) GC 35 0.865 ( -2000.00, -2000.00) GC

11 1.187 ( .00, -1000.00) GC 36 0.855 ( -1000.00, .00) GC

12 1.186 ( 1000.00, .00) GC 37 0.844 ( 1000.00, -1000.00) GC

13 1.164 ( 1000.00, .00) GC 38 0.817 ( .00, -3000.00) GC

14 1.150 ( 1000.00, 1000.00) GC 39 0.812 ( -2000.00, -2000.00) GC

15 1.122 ( 2000.00, 2000.00) GC 40 0.812 ( 1000.00, .00) GC

16 1.099 ( 1000.00, -1000.00) GC 41 0.812 ( 1000.00, .00) GC

17 1.093 ( 1000.00, -1000.00) GC 42 0.812 ( -1000.00, -1000.00) GC

18 1.085 ( .00, -2000.00) GC 43 0.798 ( 2000.00, .00) GC

19 1.084 ( -1000.00, -1000.00) GC 44 0.797 ( -1000.00, -1000.00) GC

20 1.060 ( 1000.00, .00) GC 45 0.790 ( 1000.00, .00) GC

21 1.049 ( -1000.00, -1000.00) GC 46 0.780 ( -1000.00, -1000.00) GC

22 1.029 ( 1000.00, -1000.00) GC 47 0.772 ( 3000.00, 3000.00) GC

23 1.024 ( -1000.00, -1000.00) GC 48 0.772 ( 1000.00, .00) GC

24 0.971 ( 1000.00, .00) GC 49 0.771 ( 1000.00, -1000.00) GC

25 0.964 ( .00, -2000.00) GC 50 0.768 ( -1000.00, -1000.00) GC




Table 4.6 24-hourly average GLC Concentration Values for HCl


1 0.099 ( 1000.00, .00) GC 26 0.043 ( 1000.00, .00) GC

2 0.094 ( .00, -1000.00) GC 27 0.043 ( .00, -2000.00) GC

3 0.087 ( 1000.00, 1000.00) GC 28 0.043 ( -1000.00, -1000.00) GC

4 0.079 ( .00, -1000.00) GC 29 0.042 ( 2000.00, .00) GC

5 0.076 ( 1000.00, .00) GC 30 0.042 ( 1000.00, .00) GC

6 0.075 ( .00, -1000.00) GC 31 0.041 ( .00, -1000.00) GC

7 0.071 ( 1000.00, .00) GC 32 0.040 ( 1000.00, .00) GC

8 0.066 ( 1000.00, -1000.00) GC 33 0.040 ( 1000.00, .00) GC

9 0.064 ( -1000.00, -1000.00) GC 34 0.039 ( 1000.00, -1000.00) GC

10 0.064 ( 1000.00, .00) GC 35 0.038 ( 1000.00, .00) GC

11 0.059 ( -1000.00, -1000.00) GC 36 0.038 ( 1000.00, .00) GC

12 0.055 ( 1000.00, .00) GC 37 0.037 ( -1000.00, -1000.00) GC

13 0.054 ( .00, -1000.00) GC 38 0.037 ( 1000.00, -1000.00) GC

14 0.053 ( 1000.00, 1000.00) GC 39 0.036 ( -1000.00, -1000.00) GC

15 0.051 ( 1000.00, -1000.00) GC 40 0.036 ( 1000.00, .00) GC

16 0.050 ( -1000.00, -1000.00) GC 41 0.036 ( 1000.00, -1000.00) GC

17 0.049 ( -1000.00, -1000.00) GC 42 0.036 ( 1000.00, 1000.00) GC

18 0.047 ( 1000.00, -1000.00) GC 43 0.036 ( 1000.00, -1000.00) GC

19 0.046 ( -1000.00, .00) GC 44 0.036 ( 2000.00, 2000.00) GC

20 0.046 ( 1000.00, -1000.00) GC 45 0.036 ( -1000.00, -1000.00) GC

21 0.045 ( -1000.00, -1000.00) GC 46 0.035 ( 1000.00, .00) GC

22 0.045 ( .00, -1000.00) GC 47 0.035 ( -1000.00, .00) GC

23 0.045 ( 1000.00, .00) GC 48 0.034 ( 1000.00, .00) GC

24 0.045 ( 1000.00, .00) GC 49 0.034 ( 1000.00, -1000.00) GC

25 0.044 ( 1000.00, -1000.00) GC 50 0.034 ( 1000.00, .00) GC




Figure 4.1: Isopleths for Ground Level Concentrations for SPM

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Figure 4.2: Isopleths for Ground Level Concentrations for SO2

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Figure 4.3: Isopleths for Ground Level Concentrations for NOx

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Figure 4.4: Isopleths for Ground Level Concentrations for HCl

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Chapter-5

Analysis of Alternatives

5.1 PROLOGUE

Alternative analysis is the process of analyzing the proposed locating for

suitability for basic necessities to operate the plant safely, this analysis

also covers the environmental aspect of pollution prevention and

improvement in quality of life nearby the project vicinity. The project

alternative is the course of action in pace of another, that would meet the

same purpose and need, but which would avoid or minimize negative

impacts and enhance project benefits. Such projects may result in

specific impacts which can be avoided or mitigated by adherence to

certain predetermined performance standards, guidelines or design

criteria. Alternative approaches may therefore be more effective in

integrating environmental and social concerns into the project planning

process.

5.2 SITE ALTERNATIVE

Urmit Chemicals Pvt. Ltd. is a Greenfield project, proposes to set up

Dyes and Dye Intermediates manufacturing unit at Survey No. 1384,

Village: Rajpur, Tal: Kadi, Dist: Mehsana, Gujarat. Total production

capacity of all products will be tune around 400 MT/month. The area of

the plot (5662 m2) is sufficient for proposed activities to be carried out.

Required facilities like infrastructure, communication, medical facilities,

fuel, water, power, unskilled & skilled manpower, raw materials, road

network etc. are readily available, too. There is no Rehabilitation and

Resettlement involved. Nearest city Mehsana is about 26 km away from

the site, which is having connectivity with other parts of the country by

road, rail & air. Therefore, no other site or area was considered.

5.3 PROCESS ALTERNATIVE

Production Technology

Urmit Chemicals will have a team of scientists engaged in R&D activities,

work on differentiated medicines for the future. Proposed technology of

production is result of R&D and no alteration is currently with the

proponent.



Wastewater Treatment Technology

The wastewater generated will be separated into two streams for

treatment. Process wastewater from intermediates plant will be treated in

“ETP-1”. Wastewater from dyes plant, Scrubber, Washing and utilities

(cooling & boiler) will be treated in “ETP-2”. Effluent from “ETP-1” will be

sent to Common Spray Dryer for evaporation at Chhatral Environment

Management System Pvt. Ltd. Effluent from “ETP-2” will be sent to RO

and RO permeate will be reused; RO reject will be Spray Dried along with

effluent of ETP-1. Domestic wastewater will be discharged into soak pit.

Thus proven, most feasible and best available technology will be used for

wastewater management and no other alternatives are with the

proponent.

Air Pollution Control Technology

Flue gas emission is due to the combustion of fuel Coal in boiler, Hot Air

Generator and Thermic Fluid Heater. Cyclone, bag filter will be installed

as APCM for each flue gas emission source. Process gas emission will be

from the stack attached to process reactors and vent of Spray Dryer. To

control the process emission, water and alkali scrubber will be provided.

Thus proven, most feasible and best available technology will be used for

Air Pollution Control and no other alternatives are currently with the

proponent.



Chapter-6

Environmental Monitoring Programme

6.1 PRELUDE

Environment monitoring is the sampling and analysis tool to know the

environment conditions at particular time. The record of environmental

monitoring is most important as the environmental changes are slow in

nature and impact appears after many years. Environmental Monitoring is

the technical heart of assessment of environmental and social impacts

arising due to implementation of the proposed project. An equally

essential element of this process is to develop measures to eliminate,

offset or reduce impacts to acceptable levels during implementation and

operation of projects. The integration of such measures into project

implementation and operation is supported by clearly defining the

environmental requirements within an Environmental Management Plan.

Urmit Chemicals Pvt. Ltd. proposed to manufacture dyes and dye

intermediates with production capacity of 400 MT/month. The

environmental monitoring programme is developed as below.

6.2 ENVIRONMENT MONITORING PROGRAM

The periodically monitoring of Environmental parameters like air, water,

noise, soil and performance of pollution control facilities and safety

measures in the plant are vital for proper Environmental management of

any industrial project. Therefore, the company shall create environmental

monitoring facilities by the environmental and safety department to

monitor air and water pollutants as per the guideline of GPCB & CPCB.

Moreover, air and water quality shall be monitored by outside agencies

authorized by GPCB at regular frequencies. This department shall also

carry out periodical checkup of fire and safety equipments.

6.3 OBJECTIVE OF MONITORING PLAN

The basic objective of implementing a monitoring plan on a regular basis

is as follows:

To know the pollution status within the plant and its vicinity.

Generate data for corrective action in respect of pollution.



Correlate the production operations with emission & control

mechanism.

Examine the performance of pollution control system.

Assess the Environmental impacts.

Remedial measures and environment management plant to reverse

the impacts.

6.4 SCHEDULE FOR ENVIRONMENT MONITORING

The environmental monitoring will be scheduled on regular interval to

assess the conditions. The record of these monitoring will be compared

with the baseline study to know the changes in environmental conditions.

The post-project environmental monitoring suggested herewith should be

as per the following guideline.

The highlights of the integrated environmental monitoring plan are:

The stack monitoring facilities like ladder, platform and porthole at all

the stacks will be maintained in good condition.

Regular monitoring of all gaseous emissions from stacks/vents.

The performance of air pollution control equipment evaluated based

on these monitoring results.

Water consumption will be recorded daily.

As far as possible, noise curbed at its source, with the help of

acoustic hoods and other such noise reducing equipment. Regular

noise level monitoring will be carried out.

Greenbelt will be properly maintained and new plantation

programmes will be undertaken frequently.

Continuous environmental awareness programmes will be carried out

for the employees and also in the surrounding villages.

6.5 AMBIENT AIR QUALITY MONITORING

Flue gas emission will be due to the combustion of fuel Coal in boiler,

HAG and THF. Cyclone, bag filter will be installed as APCM for each flue

gas stacks. Process gas emission will be from the stack attached with

process reactors and vents of spray dryer. To control the process

emission, water and alkali scrubber will be provided.

Scheme for monitoring ambient air quality, stack emissions and fugitive

emissions are proposed. The ambient air quality monitoring systems are



recommended for monitoring the ground level concentrations and fugitive

emissions around the plant. Unit should install three monitoring stations

around its battery limit (at 1200 as per guideline) for monitoring PM, SO2

and NOx. The combined data will provide overall characteristic and

emission from the industry. Besides this, stack emissions monitoring as

per SPCB guidelines shall be carried out. Proposed monitoring schemes

are mentioned in Table 6.1.

6.6 WATER ENVIRONMENT MONITORING


domestic wastewater and the rest will be industrial wastewater. The main

source of the industrial wastewater generation will be from process (80

KLD), Scrubber (2 KLD), Washing (25 KLD) and utilities (Boiler & cooling

- 18 KLD).

The wastewater generated will be separated into two streams for

treatment. Process wastewater from intermediates plant will be treated in

“ETP-1”. Then it will be sent Common Spray Dryer for evaporation at

Chhatral Environment Management system Pvt. Ltd. Effluent from dyes

plant, Scrubber, Washing and utilities (cooling & boiler) will be treated in

“ETP-2”. Treated effluent will be sent to RO and the RO permeate will be

reused; RO reject will be Spray Dried along with effluent of ETP-1.

Domestic wastewater will be discharged into soak pit. ETP sludge will be

disposed to approve TSDF site. Domestic effluent will be disposed to soak

pit. The detail of water usage and wastewater generation is provided

comprehensively in Chapter 2. Proposed monitoring schemes are

mentioned in Table 6.1.

6.7 NOISE ENVIRONMENT MONITORING

Main source of noise generation at Urmit Chemicals Pvt. Ltd. will be

boilers, HAG, THF, D.G. set, process plant, vehicular transportation &

other machineries. Monitoring of noise levels is essential to assess the

efficacy of maintenance schedules undertaken to reduce noise levels and

noise protection measures. A good quality digital sound pressure level

meter is essential for this purpose. Proposed monitoring schemes are

mentioned in Table 6.1.



Table: 6.1 Environment Monitoring Plan

Nature of

Analysis

Frequency of

analysis

Parameters No. of

samples

Method of

Monitoring

Wastewater analysis

Monthly by external agency

pH, TDS, SS, COD, BOD, Oil

& Grease, etc.

2-3 samples APHA-AWWA 23rd edition

Stack Monitoring


PM, SO2, NOX, HCl

All stacks Stack monitoring kit

Ambient Air Quality

Monitoring

Monthly for 24 hours or as per

the statutory conditions by

external agency

PM10, PM2.5, SO2, NOX, HCl

3-5 locations RDS, Fine particulate

sampler

Noise level Monthly as per the statutory conditions by

external agency

Noise level 6-8 locations (Nr. Main gate,

Nr. boiler, Nr. D.

G. Set, Process

area etc.)

Sound Level Meter

Work zone fugitive monitoring


RPM, acid mist 2-3 locations Personal sampler

Health

check-up of workers

As per the

statutory guideline

All workers ---

**Rs. 3.0 Lakhs per annum are allocated for Environment Monitoring.



Chapter-7

Additional Studies A. Hazard Analysis & Risk Assessment

7.1 INTRODUCTION

Industrial plants deal with materials, which are generally hazardous in

nature by virtue of their intrinsic chemical properties or their operating

temperatures or pressures or a combination of these. Fire, explosion,

toxic release or combinations of these are the hazards associated with

industrial plants using hazardous chemicals. More comprehensive,

systematic and sophisticated methods of Safety Engineering, such as,

Hazard Analysis and Quantitative Risk Assessment have now been

developed to improve upon the integrity, reliability and safety of

industrial plants. The primary emphasis in safety engineering is to reduce

risk to human life, property and environment. Some of the more

important methods used to achieve this are:

Quantitative Risk Analysis: Provides a relative measure of the

likelihood and severity of various possible hazardous events by

critically examining the plant process and design.

Work Safety Analysis: The technique discerns whether the plant

layout and operating procedures in practice have any inherent

infirmities.

Safety Audit: Takes a careful look at plant operating conditions, work

practices and work environments to detect unsafe conditions.

7.2 RISK ASSESSMENT-Identification of Hazards

M/s. Urmit Chemicals Pvt. Ltd. Is proposed unit proposed to produce

Dyes and Dye Intermediates at Survey No. 1384, Village: Rajpur, Tal:

Kadi, Dist: Mehsana, Gujarat Total production capacity of the proposed

products will be 400 MT/month. A three ‗levels‘ risk assessment approach

has been adopted. The risk assessment levels are generally consistent

with the practices encountered through various assignments for medium

and large chemical complexes. The brief outline of the three tier approach

is given below:



Level 1 – Risk Screening

This is top-down review of worst-case potential hazards/risks, aimed

primarily at identifying plant sites or areas within plant, which pose the

highest risk. Various screening factors considered include:

Inventory of hazardous materials;

Hazardous Materials properties;

Storage conditions (e.g. temperature and pressure);

Location sensitivity (distance to residential areas/populace).

The data/information is obtained from plant. The results provide a

relative indication of the extent of hazards and potential for risk

exposure.

Level 2 – Major Risk Survey (Semi - Quantitative)

The survey approach combines the site inspection with established risk

assessment techniques applied both qualitative as well quantitative

mode. The primary objective is to identify and select major risks at a

specific location in the plant considering possible soft spots/weak links

during operation/maintenance. Aspects covered in the risk usually

include:

Process Hazards;

Process Safety Management Systems;

Fire Protection and Emergency response equipment and programs.

Security Vulnerability;

Impact of hazards consequences (equipment damage, business

interruption, injury, fatalities);

Qualitative risk identification of scenarios involving hazardous

materials;

Risk reduction measures.

Selection of critical scenarios and their potential of damage provide

means of prioritising mitigative measures and allocate the resources to

the areas with highest risks.

Level 3 – Quantitative Risk Assessment (Deterministic)

This is the stage of assessment of risks associated with all credible

hazards (scenarios) with potential to cause an undesirable outcome such



as human injury, fatality or destruction of property. The four basic

elements include:

Hazards identification utilizing formal approach (Level 2, HAZOP etc.);

Frequency Analysis. Based on past safety data (incidents/accidents);

Identifying likely pathway of failures and quantifying the toxic material

release;

Hazards analysis to quantify the consequences of various hazards

scenarios (fire, explosion, BLEVE, toxic vapour release etc.). Establish

minimum value for damage (e.g. IDLH, over pressure, radiation flux)

to assess the impact on environment.

Risk Quantification: Quantitative techniques are used considering

effect/impact due to weather data, population data, and frequency of

occurrences and likely hood of ignition/toxic release. Data are

analyzed considering likely damage (in terms of injury/fatality,

property damage) each scenarios is likely to cause.

QRA provides a means to determine the relative significance of a number

of undesired events, allowing analyst and the team to focus their risk

reduction efforts where they will be beneficial most. The QRA for this

plant is based on Level 1 and Level 2. Table 2.2 in Chapter 2 gives the

list of products (and their monthly production capacity) to be

manufactured. Table below gives the bulk storages of hazardous

chemicals and their consumption.

7.3 HAZARDOUS MATERIALS STORAGE

The solid raw materials will be received in bags or drums and will be

stored in chemicals godowns. The products will be packed in bags or

drums and stored in product godowns as per market demand. The bulk

storages of liquid hazardous materials are given in the Table 7.1 below.

In addition unit will store fuels mainly Coal for boiler, HAG, TFH and

Diesel (in limited quantity) for D.G. Set (during power failure only). The

solid material powder or granules spillage can results in polluting small

area only. The damage to personnel can be through ingress- dermal (if

individual come in contact), oral (if individual food gets infected through

fugitive dust) or inhalation (fugitive dust). The main route is fugitive dust

which in covered area will move to short distance only. The risk is



through liquid products which are volatile material. The toxic vapours due

to spillage of such material can travel to some distance (as they are

stored in covered godowns) and cause damage.

Table 7.1: Bulk Storage of Hazardous Chemicals

Sr.

No.

Name of Chemical State

(Solid/

Liquid/Gas)

Stored

in

MOC Storage

(MT)

1 Sulphuric Acid Liquid Tank MSRL 15+20

2 Oleum Liquid Tank MS 25

3 Caustic Lye Liquid Tank MS 10+15

4 Aniline oil Liquid Drum MS 5

5 HCl Liquid Tank HDPE 10+10

6 Nitric Acid Liquid Tank HDPE 10

7 Acetic Acid Liquid Tank HDPE 5

8 Benzaldehyde Liquid Drum MS 5

9 Chlorine Gas Liquid/Gas Tuner MS 0.9 x 9

10 Acetic Anhydride Liquid Drum MS 5

7.4 RISK SCREENING APPROACH

Risk screening of Urmit Chemicals was undertaken through process study

and study of data/information provided by the unit. Data of major/bulk

storages of raw materials, intermediates and other chemicals were

collected. MSDS of hazardous chemicals were studied vis a vis their

inventories and mode of storage. The chemicals stored in bulk and

defined under MSIHC Rule will be considered for detailed analysis. None

of the products are covered under MSIHC Rules. Raw materials under

hazardous category as specified by MSIHC Rules, 1989 (including

subsequent amendments) are as below,



Table 7.2: Properties of Hazard – Raw materials (stored in Bulk)

Sr.

No.

Raw material Description Sr. No & Threshold Quantity

(in MT) as per MSHIC Rules

Chemicals Hazards Potential

Sch-1,

Part-II

Sch-2,

Part-I

Sch-3,

Part-I

1. Sulphuric acid

CAS No: 7664-93-9

UN No: 1830

Oleum

CAS No: 8014-95-7

UN No: 1831

Colorless thick oily liquid

with strong marked acid

taste.

591 --- --- Very hazardous in case of skin contact

(corrosive, irritant, permeator), of eye

contact (irritant, corrosive), of ingestion,

of inhalation.

2. Caustic Lye

CAS No.: 1310-73-2

UN No.: 1824

Clear colorless, odorless

liquid with strong alkaline

bitter taste, easily soluble

in cold water.

--- --- --- Very hazardous in case of skin contact


contact (irritant, corrosive), of ingestion.

Slightly hazardous in case of inhalation

(lung sensitizer).

3. Aniline

CAS No.: 62-53-3

UN No.: 1547

Colorless oily liquid with

aromatic amine like odor

and taste of burning,

soluble in water, methanol,

diethyl ether.

37 --- --- Hazardous in case of skin contact

(irritant, permeator), of eye contact

(irritant), of ingestion, of inhalation.

4. Hydrochloric Acid

CAS No: 7647-01-0

UN No: 1789

Colorless to light yellow

liquid with pungent strong

irritating odor, soluble in

water and diethyl ether





(lung sensitizer). Non-corrosive for lungs.

5. Nitric Acid

CAS No.: 7697-37-2

UN No.: 2031

Colorless to light yellow

colored liquid with strong

acrid, disagreeable and

choking odor, easily soluble

in water, soluble in diethyl

ether.





(lung sensitizer). Liquid or spray mist

may produce tissue damage particularly

on mucous membranes of eyes, mouth

and respiratory tract.

6. Benzaldehyde

CAS No.: 100-52-7

UN No.: 1990

Colorless liquid with

Slightly soluble in water.

Strong oxidizing agents,

strong reducing agents,

--- --- --- May cause eye irritation. Causes redness

and pain. May cause skin irritation.

Causes redness and pain. May be harmful

if absorbed through the skin. Contact



Stable under normal

temperatures and

pressures.

with the skin defats the skin. Substance

is readily absorbed through the skin.

Chronic exposure may cause

degenerative muscle and myocardium

changes. 7. Chlorine Gas

CAS No:7782-50-5 UN No:1017

Greenish yellow gas with a

pungent suffocating odor. Toxic by inhalation.

119 5

TQ-1: 10MT

TQ-2: 25 MT

108

TQ-1: 10MT

TQ-2: 25 MT

Non Combustible; May ignite other

combustible materials (wood, paper, oil,

etc.). Mixture with fuels may cause

explosion. Container may explode in heat

of fire. Chlorine reacts explosively with or

supports the burning of numerous

common materials. Ignites steel at 100°C

in the presence of soot, rust, carbon, or

other catalysts. Ignites dry steel wool at

50°C. Hydrogen and chlorine mixtures

(5-95%) are exploded by almost any

form of energy (heat, sunlight, sparks,

etc.). Health Hazards: Poisonous; may be

fatal if inhaled. Contact may cause burns

to skin and eyes. Bronchitis or chronic

lung conditions

8. Acetic Acid CAS No.: 64-19-7

UN No.: 2789

Clear colorless liquid with strong, pungent, vinegar-like

sour odor and taste.

2 --- --- Very hazardous in case of skin contact (irritant), of eye contact (irritant), of

ingestion, of inhalation. Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive). Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract.

9. Acetic anhydride CAS No.: 108-24-7

UN No.: 1715

Light colored liquid with strong odor and taste.

3 --- --- Extremely hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Very hazardous in

case of skin contact (corrosive). Hazardous in

case of skin contact (permeator). Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract.



Table 7.3: Hazards Analysis – Raw materials (stored in Bulk)

Name of Chemicals

Physical form

BP oC

FP oC

LEL %

UEL % TLV ppm

LD50 mg/Kg & LC50 mg/l

Vapour Density

Specific Gravity

Sulphuric acid Liquid 270 NA NA NA 1 mg/m3 LD50

: 2140

LC50

: 510

3.4 1.84

Oleum Liquid 45 NA NA NA 1 LD50: 2140 3.4 1.92

Caustic flakes Solid 1388 NA NA NA 2 NA NA 2.13

Caustic Lye Liquid 140 NA NA NA 2 mg/m3 NA 0.62 (Water)

1.53

Aniline Liquid 184.1 70 1.3 23 2 LD50: 250 3.22 1.0216

Hydrochloric acid Liquid 108.58 NA NA NA 5 LD50: 900

LC50: 3124

1.267 1.1-1.19

Nitric Acid Liquid 121 NA NA NA 2 LC50

: 244 2.5 1.408

Benzaldehyde Liquid 179 64.4-

73.9

1.40% 8.50% N.A. LC50

:1300 3.65 1.050

Chlorine Gas Gas/Liquid -34 NA NA NA 0.5 LD50: 293

LC50

: 0.15

2.45 1.467

Acetic Acid Liquid 118.1 39-43 4% 19.90% 100 (ppm)

LD50: 2306 LC50: 14000

mg/m

2.1 1.05

Acetic anhydride Liquid 139.5 49 NA NA NA LD50:1780

LC50

: 1000

3.52 1.08

Note:

TQ-I: Threshold quantity (for application of rules 4, 5,7 to 9 and 13 to 15)

TQ-II: Threshold quantity (for application of rules 10 to 12)

1. Oral Toxicity (OT) in LD50 (mg/kg)

2. Dermal Toxicity (DT) in LD50 (mg/kg)

3. Inhalation Toxicity in LC50 (mg/l) [4 hrs.]



Summary: None of the raw materials are listed in Schedule 2 and 3 of

MSIHC Rules. None of the raw materials are extremely toxic.

Sr.

No.

Toxicity Oral toxicity

LD50 (mg/kg)

Dermal

toxicity LD50 (mg/kg)

Inhalation

toxicity LC50 (mg/l)

1. Extremely toxic <5 <40 <0.5

2. Highly toxic >5-50 >40-200 <0.5-2.0

3. Toxic >50-200 >200-1000 >2-10

7.4.1 Acute Exposure Guideline Levels (AEGLs)

AEGLs estimate the concentrations at which most people - including

sensitive individuals such as old, sick, or very young people - will begin to

experience health effects if they are exposed to a hazardous chemical for

a specific length of time (duration). For a given exposure duration, a

chemical may have up to three AEGL values, each of which corresponds

to a specific tier of health effects. AEGLs of the materials are as below.

The 3 tiers are defined as follows:

AEGL-3 is ―the airborne concentration of a substance above which it is

predicted that the general population, including susceptible individuals,

could experience life-threatening adverse health effects or death.‖



could experience irreversible or other serious, long-lasting adverse

health effects or an impaired ability to escape.‖



could experience notable discomfort, irritation, or certain asymptomatic

no sensory effects.‖

AEGLs of the materials are as below.

10 min 30 min 60 min 4 hr 8 hr Unit

Sulphuric acid (7664-93-9)/ Oleum (8014-95-7)

AEGL 1 0.20 0.20 0.20 0.20 0.20 mg/m3

AEGL 2 8.7 8.7 8.7 8.7 8.7 mg/m3

AEGL 3 270 200 160 110 93 mg/m3

Caustic Lye(1310-73-2)

AEGL 1 100 100 100 NR NR ppm

AEGL 2 170 170 130 80 42 ppm

AEGL 3 300 300 270 170 ppm

Aniline (62-53-3)



7.4.2 Emergency Response Planning Guidelines (ERPGs)

ERPGs estimate the concentrations at which most people will begin to

experience health effects if they are exposed to a hazardous airborne

chemical for 1 hour. (Sensitive members of the public—such as old, sick,

or very young people—aren't covered by these guidelines and they may

experience adverse effects at concentrations below the ERPG values). The

3 tiers are defined as follows:

ERPG-3 is "the maximum airborne concentration below which it is

believed that nearly all individuals could be exposed for up to 1 hour

without experiencing or developing life-threatening health effects."



without experiencing or developing irreversible or other serious health

effects or symptoms which could impair an individual's ability to take

protective action."



AEGL 1 48 16 8.0 2.0 1.0 ppm

AEGL 2 72 24 12 3.0 1.5 ppm

AEGL 3 120 40 20 5.0 2.5 ppm

Hydrogen Chloride (7647-01-0)

AEGL 1 1.8 1.8 1.8 1.8 1.8 ppm

AEGL 2 100 43 22 11 11 ppm

AEGL 3 620 210 100 26 26 ppm

Nitric Acid (7697-37-2)

AEGL 1 0.16 0.16 0.16 0.16 0.16 ppm

AEGL 2 43 30 24 6.0 3.0 ppm

AEGL 3 170 120 92 23 11 ppm

Chlorine Gas(7782-50-5)

AEGL 1 0.50 0.50 0.50 0.50 0.50 ppm

AEGL 2 2.8 2.8 2.0 1.0 0.71 ppm

AEGL 3 50 28 20 10 7.1 ppm

Acetic Acid(64-19-7)

AEGL 1 NR NR NR NR NR ppm

AEGL 2 12.0 8.3 6.6 1.7 0.83 ppm

AEGL 3 NR NR NR NR NR ppm

NR = Not recommended due to insufficient data * indicates value is 10-49% of LEL. Safety consideration against

explosions must be taken into account. ** indicates value is 50-99% of LEL. Extreme safety consideration against explosions must be taken into account.



without experiencing other than mild transient health effects or

perceiving a clearly defined, objectionable odor."

7.5 QRA APPROACH

Identification of hazards and likely scenarios (based on Level-1 and

Level-2 activities) calls for detailed analysis of each scenario for potential

of damage, impact area (may vary with weather conditions/wind

direction) and safety system in place. Subsequently each incident is

classified according to relative risk classifications provided in Table 7.4.

Table 7.4: Risk Classification

Stage Description

High

(> 10-2/yr.)

A failure which could reasonably be expected to occur within the

expected life time of the plant.

Examples of high failure likelihood are process leaks or single

instrument or valve failures or a human error which could result in

releases of hazardous materials.

Moderate

(10-2 --10-4/yr.)

A failure or sequence of failures which has a low probability of

occurrence within the expected lifetime of the plant.

Examples of moderate likelihood are dual instrument or valve

failures, combination of instrument failures and human errors, or

single failures of small process lines or fittings.

Low

(<10-4)

A failure or series of failures which have a very low probability of

occurrence within the expected lifetime of plant.

Examples of ‗low‘ likelihood are multiple instruments or valve

failures or multiple human errors, or single spontaneous failures of

tanks or process vessels.

Minor Incidents Impact limited to the local area of the event with potent for ‗knock

– on- events‘

Serious Incident One that could cause:

Any serious injury or fatality on/off site;

Property damage of more than 50 Lakhs INR

Extensive Incident One that is five or more times worse than a serious incident.

Assigning a relative risk to each scenario provides a means of prioritising

associated risk mitigation measures and planned actions.

7.6 THERMAL HAZARDS

In order to understand the damages produced by various scenarios, it is

appropriate to understand the physiological/physical effects of thermal

radiation intensities. The thermal radiation due to tank fire usually results

in burn on the human body. Furthermore, inanimate objects like

equipment, piping, cables, etc. may also be affected and also need to be

evaluated for damages. Table 7.5, Table 7.6 and Table 7.7 (below),

respectively give tolerable intensities of various objects and desirable

escape time for thermal radiation.



Thermal hazards could be from fires or explosion. Fire releases energy

slowly while explosion release energy very rapidly (typically in micro

seconds). Explosion is rapid expansion of gases resulting in rapidly

moving shock wave. BLEVE (boiling liquid expanding vapour explosion)

occurs if a vessel containing a liquid at a temperature above its

atmospheric boiling point ruptures. The subsequent BLEVE is the

explosive vaporization of large fraction of its vapour contents; possibly

followed by combustion or explosion of the vaporized cloud if it is

combustible. Thermal hazards have been considered for various scenarios

including: Fire in inflammable chemicals storage tanks.

Table 7.5: Effects due to Incident Radiation Intensity

Incident Radiation

kW/m2

Damage Type

0.7 Equivalent to Solar Radiation

1.6 No discomfort on long duration

4.0 Sufficient to cause pain within 20 sec. Blistering of skin (first degree burn are likely).

9.5 Pain threshold reached after 8 sec. Second degree burn after 20 sec.

12.5 Minimum energy required for piloted ignition of wood,

melting of plastic tubing etc.

25 Minimum Energy required for piloted ignition of wood, melting, plastic tubing etc.

37.5 Sufficient to cause damage to process equipment.

62.0 Spontaneous ignition of wood.

Table 7.6: Thermal Radiation Impact to Human

Exposure

Duration

Radiation Energy

{1% lethality;

kW/m2}

Radiation Energy

for 2nd degree

burns; kW/m2

Radiation Energy

for 1st degree

burns; kW/m2

10 sec 21.2 16 12.5

30 9.3 7.0 4.0

Table 7.7: Tolerable Intensities for Various Objects

Sl. No.

Objects Tolerable Intensities

(kw/m2)

1 Drenched Tank 38

2 Special Buildings (No window, fire proof doors)

25

3 Normal Buildings 14

4 Vegetation 10-12

5 Escape Route 6 (up to 30 secs.)

6 Personnel in Emergencies 3 (up to 30 secs.)

7 Plastic Cables 2

8 Stationary Personnel 1.5



7.7 DAMAGE DUE TO EXPLOSION

The explosion of a dust or gas (either as a deflagration or detonation)

results in a reaction front moving outwards from the ignition source

preceded by a shock wave or pressure front. After the combustible

material is consumed the reaction front terminates but the pressure wave

continues its outward movement. Blast damage is based on the

determination of the peak overpressure resulting from the pressure wave

impacting on the object or structure. Damage estimates based on

overpressure are given in Table 7.8 below:

Table 7.8: Damage due to Overpressure

Sr. No.

Overpressure (psig/bar)

Damage

1. 0.04 Loud Noise/sonic boom glass failure

2. 0.15 Typical pressure for glass failure

3. 0.5 - 1 Large and small windows usually shattered

4. 0.7 Minor damage to house structure

5. 1 Partial demolition of houses, made uninhabitable

6. 2.3 Lower limit of serious structure damage

7. 5 - 7 Nearly complete destruction of houses

8. 9 Loaded train box wagons completely demolished

9. 10 Probable total destruction of houses

10. 200 Limits of crater lip

In case of Urmit Chemicals, explosion probability is remote.

7.8 TOXIC RELEASE

For toxic release the damage criteria considered is IDLH concentration (if

data are available). The immediately dangerous to life or health air

concentration values (IDLH values) developed by the National Institute

for Occupational Safety and Health (NIOSH) characterize these high-risk

exposure concentrations and conditions and are used as a component of

respirator selection criteria. IDLH values are established (1) to ensure

that the worker can escape from a given contaminated environment in

the event of failure of the respiratory protection equipment and (2) to

indicate a maximum level above which only a highly reliable breathing

apparatus, providing maximum worker protection, is permitted.



IDLH of all the materials stored in bulk are as below.

IDLH Value Unit

Sulfuric Acid/ Oleum 15 mg/m3

Sodium Hydroxide 10 mg/m3

Aniline 100 ppm

Hydrochloric acid 50 ppm

Nitric acid 25 ppm

Chlorine Gas 30 ppm

Acetic Acid 50 ppm

Acetic anhydride 200 ppm

7.9 ACID/ALKALI HAZARDS

Various hazards that can occur due to the acid and alkali incidents are

Skin irritation and corrosive effects after spillage

Spill pool evaporation of hydrochloric acid or Caustic lye storage

tanks catastrophic failure are limited only

Catastrophic failure giving rise to spill pool evaporation dispersion

up to LC50, IDLH and TLV level

Based on the outcome of the risk assessment, following recommendation

has been made to avoid any risk associated with the storage and use of

acids in the plant:

Full body protection will be provided to operator.

Caution note and emergency first aid will be displayed.

All employees will be trained for use of emergency first aid.

Safety shower and eye wash will be provided in storage tank area

and plant area.

Dyke wall will be provided to storage tank.

Tanker unloading procedure will be prepared.

SOP will be prepared for Hydrochloric acid, Nitric acid , and Sulfuric

acid handling.

Training programme will be conducted for safe handling and

emergency handling of Acids.

In Storage Tank Area, reaction with water generating fumes should

be displayed and avoided.

Suitable extinguishing media-Extinguish with dry powder/sand. DO

NOT USE WATER.



7.10 LIKELY FAILURE SCENARIOS

Few likely failure scenarios have been selected after critical appraisal of

raw materials and storage inventories. Failure scenarios selected are as

given in Table 7.9 below:

Table 7.9: Different Failure Scenarios

Raw materials Scenario Remark

Sulphuric acid Tank leakage Toxic/Corrosive

Oleum Tank leakage Toxic/Corrosive

Chlorine Gas Tuner Leakage Toxic gas

Aniline Oil Tank/Drum leakage Toxic

Hydrochloric acid Tank leakage Toxic

Acetic Acid Tank leakage Spillage

7.11 QUANTITATIVE RISK ASSESSMENT & CONSEQUENCE ANALYSIS

7.11.1 PREAMBLE

In the previous section we have carried out the hazards analysis of Urmit

Chemicals considering various aspects including bulk storages of

hazardous chemicals, plant process system, plant incidents/accidents

records, critical appraisal and discussion at site for soft spots in the plant

etc. Based on the hazards analysis few critical scenarios have been

selected for QRA and consequence analysis. QRA quantifies vulnerable

zones for a conceived incident with various levels of severity.

In consequence calculation, use is made of a number of calculation

models to estimate the physical effects of an accident (spill of hazardous

material) and to predict the damage (lethality, injury, material

destruction and other property damage). The risk assessment modelling

can be roughly divided into three groups:

Determination of source strength parameters;

Determination of consequential effects;

Determination of damage or damage distances (with specific severity

rates)

7.11.2 Weather Effect

The effect of ambient conditions on the impact of fire/heat radiation and

GLC of hazardous/toxic material can be beneficial as well as harmful. A



high wind (turbulence) can dilute the toxic material while stable

environment can extend the reach of IDLH or IT (inhalation LC50 rats for

products) concentration to long distance. Any inflammable gas/vapour

release in turbulent weather will soon dilute the hazardous gases below

LEL and thus prevent the disaster.

7.12 INCIDENTS IMPACTS

The identified failure scenarios (Table 7.9) have been analyzed (Using

ALOHA and EFFECT Modules) for the impact zones considering damage

due to thermal and toxic impacts. Each incident will have Impact on the

surrounding environment which in extreme case may cross plant

boundary. The impact zones for various scenarios are given in Table

7.10 and shown in Figure 7.1 to 7.7.

Figure 7.1: Sulphuric Acid Spillage and Evaporating Toxic Pool



Figure 7.2: Oleum Spillage-SO3 release

Figure 7.3: Toxic Impact Zone Chlorine (Stability Class D)



Figure 7.4: Toxic Impact Zone Chlorine (Stability Class F)

Figure 7.5: Toxic Impact Zone Acetic Acid

Figure 7.6: Aniline Tank leakage Toxic Impact



Figure 7.7: Hydrochloric Acid Tank leakage Toxic Impact

Table 7.10: Hazards Scenario Impact

Scenario Impact Zone (m)

Sulphuric acid

Tank leakage

Red: 410 meters --- (25 mg/m3 = AEGL-3 [60 min])

Orange: 2150 meters --- (4.4 mg/m3 = AEGL-2 [60 min])

Yellow: >10000 meters --- (0.1 mg/m3 = AEGL-1 [60 min])

Oleum

Tank leakage

Red: 3100 meters --- (160 mg/m3 = AEGL-3 [60 min])

Orange: 10000 meters --- (8.7 mg/m3 = AEGL-2 [60 min])

Chlorine Gas

leakage(SC-D)

Red: 500 meters --- (20 ppm = AEGL-3 [60 min])

Orange: 724 meters --- (10 ppm = IDLH)

Yellow: 1720 meters --- (2 ppm = AEGL-1 [60 min])

Chlorine Gas

leakage (SC-E)


Orange: 925 meters --- (10 ppm = IDLH)


Aniline Tank

leakage


Orange: 161 meters --- (12 ppm = AEGL-2 [60 min])


Hydrochloric

Acid Tank

leakage



Note: Threat zone was not drawn because effects of near-

field patchiness make dispersion predictions less reliable for

short distances.

Yellow: 105 meters --- (1.8 ppm = AEGL-1 [60 min])

Acetic Acid

Tank leakage

Red: Not Drawn--- (250 ppm = AEGL-3 [60 min])



7.13 CONSEQUENTIAL IMPACTS

The consequential impacts from each incident scenarios can be though

mainly toxic route. The damage can be on plant personnel (and

neighboring premises in case incident crosses boundary). The impact

zones for some of the hazards are shown in Figure 7.1 to 7.7.



7.13.1 Thermal and Explosion Hazards

Incidents involving thermal and explosion hazards are mainly due to fire

in tank farm. In case of Urmit, no explosive chemicals stored in premises

because no use of solvent or highly explosive chemicals.

7.13.2 Toxic Hazards

Toxic hazards are mainly due to chemicals/gas leakage/spillage and their

impact is limited to plant boundary and adjacent premises based on the

wind direction (Sulphuric acid ~410 meters; Oleum Tank leakage ~ 3100

m; Hydrochloric Acid Tank leakage ~ 13 m, Chlorine Gas leakage (SC-D

~ 500 m & (SC-E) ~ 700 m) However the consequences may go outside

the plant boundary if the incidents lead to domino effect, which is highly

unforeseeable.

7.13.3 Other Hazards

The other hazards in the plant include (but not limited to):

Other toxic hazards due to acids/other toxic spillages (mainly limited

to spillage area only).

Mechanical hazards due to machines/equipment.

Hazards due to individual soft spots like walking casually and noticing

a pit and falling or colliding/stumbling or slipping (not noticing a wet

place etc.).

7.13.4 Other Toxic Hazards

Acid spillage-its impact will be limited to spillage area. The spillage if

comes in contact with metal parts will produce hydrogen which is highly

flammable gas. Any person moving in area and getting splash will get the

injury. In addition the spillage will cause pollution problem. The spillage is

to be collected and neutralized for toxic contents before disposal.

7.14 OCCUPATIONAL HEALTH

In any eventuality, injured personnel will be immediately rushed to

hospital after giving first aid. All employees will be having regular medical

checkup as per norms. One dedicated on-site vehicle and local ambulance

service will be always (round the clock) accessible for meeting any

eventuality.



Treatment of workers affected by accidental spillage of chemicals

There is wide range of chemicals present in the Chemical plants. The safe

cleanup of a chemical spill requires some knowledge of the properties and

hazards posed by the chemical & any added dangers posed by the

location of the spill. Employees must notify their immediate supervisor of

injury by spillage of chemicals or exposure to hazardous materials. All

injuries must be reported. Supervisor is responsible for reporting any

injuries or occupational illnesses to the management.

Following steps will be immediate taken by the Supervisor.

Identify spillage/leakages of hazardous chemicals

Chemical Exposure to Skin:

Immediately flush with cool water for at least 15 minutes. If there are no

visible burns, remove the cloth from burning part of body. Seek medical

attention if exposure/spillages occur major possible problems.

Chemical Exposure to Skin – Serious:

Remove all contaminated clothing. Locate the nearest emergency shower

and soak for at least 15 minutes. Have someone contact the Hospital for

immediate medical attention.

Chemicals in Eyes:

Irrigate eyes for at least 15 minutes with tempered water from

emergency eyewash station. Remove contact lenses if there is. Notify the

management and immediate medical attention.

Acid Fumes:

Anyone overcome by fumes should be removed to fresh air. Never

attempt to enter a location where potentially dangerous fumes might

place you at risk. If someone is down, contact emergency personnel and

let them enter. Self-breathing apparatus is required for persons entering

the affected area. Seek medical attention for exposure as soon as

possible.

Chemical Spills:

The safe clean-up of an acid spill requires some knowledge of the

properties and hazards posed by the acid and any added dangers posed

by the location of the spill. If you believe a spill is beyond your capacity

to clean up, do not attempt to do so by your own, immediately contact to



nearest fire/emergency station. Spill kits with instructions, absorbents,

neutralizing agents if applicable, protective equipment, and sealable

waste buckets should be present in plant area.

Following Steps to be taken for ensuring health and safety of

workers engaged in handling of Hazardous materials

Identify chemicals to be used, amounts required, condition followed as

per the MSDS guideline.

Evaluate the hazards posed by the chemicals and the process

conditions. The evaluation should cover toxic, physical, reactive, as

well as any other potential hazards posed by the respective chemicals.

Select appropriate controls to minimize risk, including use of

engineering controls, administrative controls, and Personal Protective

Equipment (PPE) to protect workers from hazards. The controls must

ensure that OSHA‘s Permissible Exposure Limits (PELs) are not

exceeded.

Avoid Underestimation of Risk of handling and its reaction.

Before working with chemicals, know the facility‘s policies and

procedures for how to handle an accidental spill or fire. Emergency

telephone numbers should be posted in a prominent area. Know the

location of all safety equipment and the nearest fire alarm and

telephone.

Provide popper Ventilation in the plant/process area.

Corrosive chemicals that require vented storage should be stored in

vented cabinets instead of in a chemical hood.

Local exhaust ventilation devices should be appropriate to the

operations in the plant.

Chemicals should be separated and stored according to hazard

category and compatibility.

7.15 CONCLUSION & RECOMMENDATIONS

The hazard analysis and risk assessment of few possible selected incident

scenarios indicates that most incidents will be limited to plant battery

limits, and have impact on adjoining area in very unlikely scenarios only.

Toxic hazards are mainly due to chemicals leakage/spillage and their

impact is limited to plant boundary and adjacent premises based on the



wind direction. The direction of impact will be in down wind direction

(wind direction and speed varies with season).

Some of the recommendations for Tank farm storage system are as given

below:

Dyke wall will be provided to storage tanks.

SOP will be prepared for Hydrochloric acid, Nitric acid, and Sulfuric

acid handling.

Fixed foam system with adequate capacity.

Regular ‗Hazard Survey‘ ensures the detection of leakage in the plant.

In house ‗capability building‘ to attend hazardous scenarios is to be

taken up through mock drills.

Train staff in attending such scenarios.

Human Factors: Human factors role in safety cannot be ignored. Odd

hours working and over/long hours work can drain out individual. It

shows in lack of efficiency and also the lack of apt attention the modern

chemical complex demand. They are to be closely looked into and

avoided, as

a. If no accident has happened so far probability of incident/accident

occurring increases.

b. ‗No accident‘/good safety record develops complacency inertia/over

confidence in the team. This attitude gives rise to gaps/soft spots in

the system giving chances to incidents/accidents.

c. Safety requires novelty. Routine training practices get stale with no

positive results. Look for novel scheme of training/ safety practices to

build up fresh impetus in safety.



MATERIAL HANDLING AND SAFETY MEASURES

7.16 ACTION PLAN FOR HANDLING & SAFETY SYSTEM OF CHEMICAL

Hazardous chemicals will be stored and handle in dispensing room for

taking out sample from the container for quality check-up purpose or for

the partial use. This activity for Hazardous material handling will be

carried out by using all PPEs with proper ventilation & under supervision.

7.16.1 Safety Measures for Transportation and Unloading of Hazardous

Chemicals

Static earthing provision will be made for tanker unloading.

Drum handling trolleys will be used for transportation of drums up to

plant and internal handling from storage to process area.

Display Boards will be provided on all storage tanks which include the

name of the chemicals and its major hazardous characteristics.

Fire extinguishers will be provided as required.

First aid boxes will also be provided at different places wherever

required.

Water showering system will be provided to the hazardous chemicals

storage area.

Area will be declared as ―NO SMOKE ZONE‖.

7.16.2 Safety Measures for Storage/Handling of Hazardous Chemicals

All Hazardous chemicals will store separately and away from the strong

oxidant & kept it in well ventilated room. Adequate firefighting system

will be installed. Safety shower and eye washer will be installed near

storage area. Flame proof light fitting will be provided at storage area.

Sprinkler system will be installed near storage area. Safety permit system

will be followed for loading and unloading. Isolate storage will be provided

with wire fencing under lock and key. Caution note, hazardous

identification board will be provided. Only authorized person will be

permitted in storage area and register will be maintained. ―NO SMOKING‖

board will be displayed and Wind Indicator and siren will be provided.

7.16.3 Safety Measures for Process Units

Safety measures are the most important aspect of selection of process

technology to ensure safety in production unit. For the safety in

production area some important critical safety measures will be provided



within the process technology/equipment itself & will put continue efforts

for developing new technology/equipment. Company will ensure such

provision in the technology/equipment/machineries at time of purchase.

The details of the critical safety measures for process unit are as below;

any reaction upsets will be confined to the reaction vessel itself as

defined quantity of raw materials will be issued to the reaction vessel by

metering pumps/load cells. Process parameters control will be provided

as per SOP- Standard Operating Procedures. Materials will be transferred

by pumping through pipeline or by vacuum from drums. All reaction vents

will be connected to vapor condensers system. Hazardous materials will

be transferred by pipelines and in controlled manners. Trained person will

be engaged for handling of hazardous materials. Proper safety

precautions will be taken during handling of hazardous materials. All

liquid hazardous material with required quantity will be charge in reactor

by pump or by gravity. All the vessels will be examined periodically by a

recognized competent person. All the vessels and equipments will be well

earthed appropriately and well protected against Static Electricity.

Temperature indicators will be provided near all reactor and distillation

systems. Flame proof light fittings will be installed in the plant. All the

Plant Personnel will be provided with Personal Protection Equipments to

protect against any adverse health effect during operations, leakage,

spillages or splash. PPE like Helmets, Safety Shoes and Safety Glasses

will be provided to the employees.

7.16.4 Safety Measures for Preventive Maintenance

The safety measures in the form of the general Do's & Don'ts for safety in

process & other plant area are as below:

Do not work on equipments without permission from plant head and

maintenance head.

Make sure equipment is empty and flushed with nitrogen and air.

Keep proper and adequate fire extinguisher near work area.

Use proper PPE.

Do not allow any employment without pre-medical check-up or without

checking fitness.

Work in any equipment must be conducted in presence of supervisor.



Additional safety measures in form of the checklist covering Do's &

Don'ts of preventive maintenance, strengthening of HSE,

manufacturing utility staff for safety related measures will be updated

timely and will be made available to all concern department &

personnel.

7.16.5 Safety measures to prevent spillage/leakage of toxic chemicals

The preventive maintenance will be planned and carried out as per plan

to avoid the failure of valve, pipelines and other component of

transferring line. The spillage will be confined to the dyke area

underneath the vessel. The resultant splash of such chemicals will result

in exposure of toxic chemicals to employees. Decontamination facilities

(Safety shower and eye wash fountains) will be provided in the plant

area, which can be used to decontaminate the affected employees.

Suitable decontamination procedure will be used to decontaminate the

spilled or leaked material. The SOP for decontamination will be available

with all related department.

7.17 ARRANGEMENTS FOR ENSURING HEALTH AND SAFETY OF

WORKERS ENGAGED IN HANDLING OF TOXIC MATERIALS

The significance of Safety & Health in plant has been a vital issue in

achieving productivity and quality standard. Following are basic

fundamental principles properly underlie all the workers working in the

plant. Consideration of each should be encouraged before beginning work

as part of the culture of safety within the plant.

Plan ahead. Determine the potential hazards associated with

production.

Minimize exposure to chemicals. Do not allow toxic chemicals to

come in contact with skin. Provide proper ventilation devices to

prevent/minimize airborne.

Do not underestimate hazards or risks. Assume that any mixture

of chemicals will be more toxic than its most toxic component. Treat

all the chemicals as toxic substances.

Be prepared for accidents. Before beginning of any batch reaction,

know what specific steps to take which cause to accident if any



hazardous substance release accidently. Proper follow SOP- Standard

Operating procedure to take batch reaction.

Unit will assess is careful examination of what, at work, could cause harm

to workers, accidents and ill health. All risks in the workplace must be

identified and assessed for control measures to be put in place.

Follow the five steps of hazard identification will be taken by unit namely;

Identify the hazards

Decide who might be harmed and how

Evaluate the risks and decide on precaution

Record your findings and implement them

Review your assessment and update if necessary

Following Information workers should know regarding hazardous

chemicals

Unit shall ensure that the employee is adequately trained with regard to:

The contents of the hazardous chemical substances

Potential source exposure to chemicals

Measures taken by the employer to protect employees against any risk

from exposure

Precautions to be taken by an employee to protect himself against the

health risks associated exposure

Correct use, maintenance of safety equipment, facilities and

engineering controls

Importance of good housekeeping at the workplace & personal hygiene

Safe working procedures

Procedures to be followed in the event of spillages or leakages.



EMERGENCY MANAGEMENT PLAN (EMP)

Emergency Management Plan (EMP) for Urmit Chemicals is proposed here

to meet the extremely adverse situations caused by the various

hazardous accident scenarios. Mock drills are to be carried out in

association with district authorities. Any weak points observed during the

mock drills are to be strengthened.

7.18 DISASTER MANAGEMENT PLAN (DMP)

Disaster/Emergency Management Plan is essential for a chemical plant as

the processes adopted for manufacturing are classified under Factory Act

as Hazardous due to handling and storage of toxic/ hazardous materials.

Primarily, DMP is prepared to furnish details which may require at the

time of the emergency, to delegate responsibility, to estimate the

consequences in advance and to prepare ourselves to control any type of

emergency. The plan explains basic requirements as follows:

Definition,

Objectives,

Organization set up,

Communication System,

Action on site,

Link with Off-site Emergency Plan,

Training rehearsal and record aspect.

7.18.1 Definitions

Various definitions on different analogy used on On-site & Off-site

Emergency Plan are as follows:

Accident: An accident may be defined as ―an undesirable and unplanned

event with or without or major damage consequence of life and /or

property.

Major Accident: It is a sudden, unexpected, unplanned event resulting

from uncontrolled developments during an industrial activity, which

causes or has the potential to cause, death or hospitalization to a number

of people, damage to environment, evacuation of local population or any

combination of above effects.

Emergency: This can be defined as any situation, which presents a

threat to safety of person's or/and property. It may require outside help

also.



Major Emergency: Occurring at a work is one that may affect several

departments within and/or may cause serious injuries, loss of life,

extensive damage to properly or serious disruption outside the works. It

will require the use of outside resources to handle it effectively.

Disaster: Disaster is a sudden calamitous event, bringing great damage,

loss or destruction.

Hazards: Hazard may be defined as ―the potential of an accident‖.

Hazard exists in man and the system of materials and machines.

Chemical Hazards: It is a hazard due to chemical(s) (including its

storage, process, handling, etc.) and it is realized by fire, explosion,

toxicity, corrosively, radiation, etc.

Risk: Risk may be defined as the combination of consequence and

probability or likelihood of an accident being caused in a given man-

material – machine system.

On-Site Emergency plan: It deals with measures to prevent and control

emergencies within the factory and not affecting outside public or

environment.

Off-Site Emergency plan: It deals with measures to prevent and

control emergencies affecting public and the environment outside the

premises.

7.18.2 Objective of the Disaster Management Plan

The DMP document is prepared keeping in view and to confirm the

requirements of the provisions of The Factories Act, 1948, Guidelines

issued by the MoEFCC and MSIHC, 1989 amended in 2000, Schedule 11

under Environmental Protection Act, 1986.

Following are the main objectives of the plan to:

Defined and assess emergencies, including hazards and risk

Control and contain incidents.

Safeguard employees and people in vicinity.

Minimize damage to property and/or the environment.

Minimization of risk and impact of event accident.

Preparation of action plan to handle disasters and to contain damage.



Inform employees, the general public and the authority about the

hazards/risk assessed and to provide safeguard, and the role to be

played by them in the event of emergency.

Be ready for 'mutual aid' if need arises to help neighboring unit.

Inform authorities and mutual aid centres to come for help.

Effect rescue and treatment of casualties.

Effective rehabilitation of the affected persons and prevention of

damage to the property.

Secure the safe rehabilitation of affected areas and to restore

normalcy.

Provide authoritative information to the news media.

7.19 ONSITE EMERGENCY PLAN

7.19.1 Incident Controller

Incident Controller‘s role is to control the emergency at the incident site.

7.19.1.1 Duties of Incident Controller

Incident Controller will proceed to the place of emergency after hearing

siren/announcement. He will:

Assess the scale of emergency and decide if a major emergency exists

or is likely, accordingly activate emergency procedure.

Immediately give his feedback to Emergency Control Centre (ECC)

regarding emergency.

Direct all operations within the area with following priorities.

o Secure the safety of personnel

o Minimize damage to plant property and environment.

o Minimize loss of material.

Direct rescue and firefighting operations till the arrival of the outside

Fire Brigade, he will relinquish control to Sr. Officer of Fire Brigade.

Ensure that the affected area is searched for causalities.

Ensure that all non-essential workers in the affected area evacuate to

the appropriate assembly point.

Set up communication point to establish Radio/Telephone/Messenger

contact as with emergency control centre.

Pending arrival of works site controller, assume the duties of the post

in particular to:



o Direct the shutting down and evacuation of plant and areas likely to

be threatened by emergency.

o Ensure that the outside emergency services have been called in.

Ensure that the key personnel have been called in.

Report all significant development to the Site Main Controller.

Provide advice and information, as required to the Senior Officer of the

Fire Brigade.

Preserve evidence that would facilitate any subsequent inquiry into the

cause and circumstances of emergency.

Dy. Incident Controller will carry out above said duties in absence of

Incident Controller.

7.19.2 Site Main Controller

Site Main Controller will be overall in-charge of emergency organization

7.19.2.1 Duties of Site Main Controller:

Relieve the Incident Controller of responsibility of overall main control.

Co-ordinate ECC or if required, security for raising evacuation siren

and also all clear siren, in case emergency is over.

Declaration of major emergency ensures that outside emergency

services will be called and when required nearby firms will be

informed.

Ensure that key personnel will be called in.

Exercise direct operational control on parts of the works outside the

affected area.

Maintain a speculative continuous review of possible development and

assess these to determine most possible cause of events.

Direct the shutting down and evacuation of plants in consultation with

key personnel.

Ensure causalities are receiving adequate attention; arrange for

additional help if required. Ensure relatives are advised.

Ensure the accounting of personnel.

Control traffic movement within the work.

Arrange for a chronological record of the emergency to be maintained.

During prolonged emergency, arrange for the relief of the personnel

and provision of catering facilities.



Contact the local office to receive early notification of impending

changes in weather conditions, in case of prolonged emergency.

Issue authorized statements to the news media and informs H.O.

Ensure that proper consideration is given to the preservation of

evidence.

Control rehabilitation of affected areas after control of the emergency.

7.19.3 Other Key Personnel

The key personnel required for taking decision about further action for

shutting down the plant, evacuate the personnel, and carry out

emergency engineering works in consultation with Site Main Controller in

light of the information received. HOD‘s /Senior Managers/ Section Heads

will be responsible for safety, security, fire, gas and pollution control,

spillage control, communication system including telephone, wireless etc.

Also medical services, transport, engineering, production, technical

services, will form part of advising team.

7.19.3.1 Emergency Response Team

The role of Emergency Response Team members is to actually combat

the emergency at the site and control the emergency situation and carry

out rescue operations. All team members will be thoroughly trained to

deal with fires, explosions, chemical spills and atmospheric releases, first

aid. As per priority list during emergency, the activities will be carried

out as per emergency control plan.

7.19.3.2 Emergency Personnel’s Responsibilities Outside Normal

Working Hours of the Factory.

The duties of Shift In-charge & team members have been brought out

in emergency control plan. All team members after evacuating the area

shall report to ECC/ Incident Place. The non-essential workers shall be

evacuated from the plants if need arises and this will be determined with

the forcible rate with which incident may escalate. Non-essential workers

shall assemble at the earmarked/specified point of assembly.

7.19.3.3 Assembly Points

At the plant, at least 2 assembly points will be identified and marked

properly.



7.19.4 Emergency Control Centre

It will be headed by Site Main Controller, HOD – PD, HOD- P&A and it is

sited in Office of Site Main Controller in Admin Building & security

office (after office hours), which is readily accessible & with minimum

risk, equipped with telephone facilities and other announcements extra

communications facilities needed. It has enough means to receive and

transmit information and directions from site main controller to incident

controller and other areas. In emergency control centre due to its safer

location and advantage of easier accessibility, all necessary personnel

protective equipment‘s fire-fighting extinguishers will be stocked in

sufficient quantity.

7.19.4.1 Role of Emergency Control Centre

In case of mishap or accident like fire, toxic gas leakage, explosion in the

factory, The Emergency Control Centre will be Office of Head- Operations.

The plot plan indicating all the activities in the factory premises

including that of storage‘s utility services, production area,

administration, will be kept for ready reference, showing the location

of fire hydrant and fire-fighting aids.

Normal roll of employees, work permits, gate entries and documents

for head count, employees blood group, other information and

addresses will be available and the person, who will handle this

operation will HOD P & A.

Stationery required is available in the Control Centre (ECC) and HOD

(P & A) looks after it.

The requirement of personnel protective equipment and other

material, like torches, have been worked out and the quantity required

during emergency will be kept in the Control Room (ECC). The

responsible person for maintaining the said requirement/inventory will

be HOD-HSE.

7.19.5 Fire & Toxicity Control Arrangements

The plant will be well equipped with suitable numbers of fire-fighting and

personnel protective equipment. The staff will be trained regularly to

handle the various emergency situations.



7.19.6 Medical Arrangements

Availability of first aid facilities in sufficient quantity will be always

ensured. In case of emergency arrangements will be made to avail

outside medical help immediately. Emergency transport facility will be

available.

7.19.7 Transport & Evacuation, Mutual Aid Arrangements

Transport & Evacuation and Mutual Aid arrangements will be available in

the factory.

7.20 COMMUNICATION SYSTEM

7.20.1 Declaring the Emergency

In case of any emergency in the plant, speedy and effective

communication of the same to all concerned in least possible time is the

most important aspect of any emergency-handling plan. An early

communication increases the chances of control of emergency in the bud

stage. Blowing siren will be adopted as method of communication of

emergency, to all employees in the plant.

7.20.1.1 Type of Sirens

Three different types of sirens have been identified for communication of

emergency.

Alert Siren: Single Continuous Siren for One Minute. This indicates

that there is some accidental happening in the plant. All have to become

alert. Incident controller will be rush to the site of emergency. Plant area

people have to start safe shut down. Rescue team and other emergency

control teams have to reach at the site of emergency.

Siren for evacuation: wailing & waning siren for three minutes.

This siren indicates that emergency is of serious proportion and

everybody has to leave his work place. All people having their role in

emergency control have to assume their assigned role. All non-essential

workers have to proceed immediately to assembly area and wait for

further instruction.

All clear siren: Long continuous siren for two minutes. This is a sign

of return of normalcy. On hearing this siren everybody should go back to

his or her respective workplace.



7.20.1.2 Location of Siren

Siren will be located in centre of the pant for wide coverage of the whole

campus. Switch for siren will be provided at security gate. The switch at

Security gate should be operated only as a general rule. Emergency

manual call bell will be installed which will be used in case of total failure

of electricity. It is responsibility of HOD (HSE) to maintain the upkeep of

electric call bell and HOD-Security and administration to maintain manual

and Hand operated siren.

7.20.1.3 Raising Alarm

Any person noticing any emergency situation in the plant should

immediately call security gate with following information:

Identify oneself

State briefly the type of emergency i.e. whether fire, explosion, toxic

gas release etc.

Give the location of the incident

Estimated severity of the incident

Security personnel after ensuring genuineness of the call shall raise the

ALERT SIREN. At the same time he will also contact the incident

controller and ECC in order and inform about the incident. He will keep

the gate open and rush his two security personnel at the site of

emergency with appropriate PPEs. ECC will be located at the office of

Head-Operations on normal working hours and at Security gate after

normal working hours (during night). ECC shall be immediately manned

on hearing alert siren. If the authorized people to handle ECC are not

available, any senior most people out of the available person nearby shall

occupy ECC till authorized person comes. Incident controller, on hearing

alert siren or by any other way of information of the emergency, will

immediately reach at the site of incident and assess the situation. He will

immediately give his feed back to ECC. ECC shall direct security gate to

raise evacuation siren, if the need arise. SIREN FOR EVACUATION shall

be raised on instruction from Site Main Controller or any Manager of the

plant in the ECC. Security gate person will be authorized to raise ALL

CLEAR SIREN on instruction from Site Main Controller or ECC, after the



emergency is over. Incident controller shall assume the responsibility of

site main controller in his absence.

7.20.2 Internal Communication

It shall be responsibility of ECC to communicate to all employees in the

plant. They may take help of telephone operator for such communication.

However, telephone operator can directly communicate information about

emergency to all internal departments, if such message comes from

incident controller or site main controller. Telephone operator will

continue to operate the switchboard advising the callers that staffs are

not available and pass all calls connected with the incident to ECC.

7.20.2.1 Availability of Key Personnel outside Normal Working Hours

The details of key personnel availability after working hours will be made

available at Security Gate, ECC, telephone operator as well as production

units. Security personnel shall call required key personnel from their

residence in case emergency occurs outside normal working hours.

Availability of emergency vehicle/Ambulance will be ensured to fetch the

key personnel residing outside. It will be the responsibility of HOD (P & A)

to maintain it.

To the Outside Emergency Services

Decision to call outside help to deal with emergency like fire brigade,

ambulance, police, etc., shall be taken by Site Main Controller. However,

in absence of Site Main Controller, if the incident controller realizes the

situation going out of control, he may ask for immediate help from

outside. ECC will be responsible for calling help from outside. A list of

emergency services available in the area with their telephone numbers

will be provided at ECC, at Security gate and with telephone operator.

Facilities such as phones, emergency vehicle, and security personnel will

be available to help calling outside emergency services and authorities.

7.20.3 Communication to the Authorities

The emergency will be immediately communicated to the government

officers and other authorities such as SPCB, police, district emergency

authority, Factory Inspectorate, hospital etc. by Emergency Control

Centre.



Communication to Neighboring Firms & the General Public

In case of emergency having its outside impact, public will be cautioned

regarding the same. Co-ordination of police will be sought for speedy

action. This is to be ensured by ECC.

7.21 Pre-emergency activities

Internal Safety survey with regard to identification of hazards, availability

of protective equipment‘s, checking for proper installation of safety

devices will be carried out periodically.

Periodic pressure testing of equipment

Periodic pressure testing of lines

Periodic safety/relief valve testing

Periodic fire hydrant system testing

Mock drill to check up level of confidence, extent of preparedness of

personnel to face emergency is being contemplated

Regular training is being imparted to all personnel to create awareness

Adequate safety equipment will be made available

Periodic check-up of emergency lights

Safer assembly points will be identified

Storage of adequate first aid treatment facilities

7.22 POST-EMERGENCY ACTIVITIES

Following post emergency actions will be carried out to study in detail and

preventive measures to be taken

Collection of records

Inquiries

Insurance claims

Preparation of reports comprising suggestion and modification

Rehabilitation of affected personnel

Normalization of plant

7.22.1 Evacuation and Transportation

In case of emergency, evacuation and transportation of non-essential

workers will be carried out immediately. The affected personnel will be

transported for medical aid.



7.22.2 Safe Close Down

During emergency plant shut down will be carried out if situation

warrants. This will be as per the instruction of site main controller under

guidance of incident controller.

7.22.3 Use of Mutual Aid

Mutual aid agreement with nearby industries will be ensures to provide

help to each other in the emergency,

7.22.4 Use of External Authorities

As and when necessary, statutory authorities, police, pollution control

personnel, medical aid/center, ambulance etc. will be contacted.

7.22.5 Medical Treatment

The affected personnel will be brought to safer place immediately to give

them first aid. Immediate medical attention will be sought.

7.22.6 Accounting for Personnel

Proper accounting for personnel will be laid down in all the shifts. The

number of persons present inside the plant premises, their duty etc. will

be available with the P & A. This record will be regularly updated and will

be made available.

7.22.7 Access to Records

The relatives of affected personnel will be informed. The details regarding

all employees will be made available to Administration building.

7.22.8 Public Relations

In case of emergency, Manager P & A will be available for official release

of information pertaining to the incident.

7.22.9 Rehabilitation

The affected area will be cleared from emergency activities only after

positive ascertaining of the system in all respects. The entry to affected

area will have to be restricted until statutory authorities visit and inspect

the spot of incident. Nothing should be disturbed from the area till their

clearance. The site main controller will be in charge of the activities to be

undertaken. The plan will cover emergencies, which can be brought under

control by the works with the help of emergency team/fire services. The

DISASTER CONTROL PLAN for gas leak and fire will be prepared for entire

factory.



7.23 CAUSES OF EMERGENCY

7.23.1 Risk

7.23.1.1 Nature

In the plant, the nature of dangerous events could be of the following:

Fire : Chemical/Electrical

Toxic Release : From chemicals

Leakages : Equipment, pipe lines, valves, etc.

Release of vapours like chlorine / bromine gas or hexane can result in

highly toxic environment or in fire or explosion.

Improper handling of products (raw materials/finished products)

Large spillage to ground floors resulting in pollution & fire.

Failures of Equipment / Instruments.

Release of safety valves or ruptures of vessels due to excessive

pressures.

7.23.1.2 Various Emergency Actions

a) Onsite

Safe shut down of the plant and utilities

Emergency control measures.

To attempt with the help of trained crew in firefighting to contain the

fire spread up/gas emission and limit within limited space.

To cut off source of oxygen by use of firefighting appliances/to cut off

source of gas emission.

Cut off fall sources of ignition like electrical gadgets.

To protect fire prone area from the fire.

To remove material which can catch fire to the extent possible from

fire prone area.

Evacuation of non-essential persons.

b) Medical Facilities/Treatment

The Plant will have a Health centre which is manned with trained male

nurse on continuous basis who can render medical first aid. Doctor

will visit two times a week for two hour each time. The Plant is

searching for a full time medical officer and will appoint as and when

available.



Depending on seriousness the injured person shall be shifted to any

other hospital.

Vehicle will be available round the clock for transportation. Ambulance

will be also made available in the campus on regular basis.

c) In the event of Fatal Accidents

The information shall be given to following authorities:

Inspector of Police

Inspector of Factories

Mamlatdar

Corporate Office

Regd. Office

Insurance the plant

Regional Officer, SPCB

d) Emergency Siren

Emergency siren shall be blown for announcing the emergency which

shall have different sound for identification/differentiation than the

normally used for commencement of factory working etc.

Location of Siren Above Plant

Type of Siren Industrial Siren

Position of siren switch Located at Main Gate

e) Seeking help from neighboring industries/sources for fire engine

f) Advise for vacation of other areas

Since the effect of fire/gas emission shall be contained within the area

of the plant advice of vacation of other areas is not necessary.

7.23.1.3 Response Time-Minutes

Hazard Fire Fighting Police Medical Services

Fire & Explosion

Immediate with whatever

facilities available with the plant

10 min.

10 minutes

External Help within 15 minutes

7.24 OFF-SITE EMERGENCY PLAN

7.24.1 Need of the Site Emergency Plan

Depending upon the wind direction and velocity of the effects of accident

in factory may spread to outside its premises. To avert major disaster it

is essential to seek guidance/assistance of statutory authorities, police

and health department. The movement of traffic may have to be

restricted. Required information will be given to the authority and

consultation will be sought for remedial measures.



A purpose of the off-site emergency plan is:

To provide the local/district authorities, police, fire, brigade, doctors,

surrounding industries and public the basic information of risk and

environmental impact assessment and appraise them of the

consequences and the protection/prevention measures and to seek

their help to communicate with public in case of major emergency.

To assist district authorities for preparing the off-site emergency plan

for district or particular area and to organize rehearsals from time to

time and initiate corrective actions on experience.

7.24.2 Structure of the Off-Site Emergency Plan

Available with concerned authorities.

7.24.3 Role of the Factory Management

The site main controller will provide a copy of action plan to the statutory

authorities in order to facilitate preparedness of district/area off-site

emergency plan.

7.24.4 Role of Emergency Co-ordination Office (ECO)

He will be a senior police or fire officer co-ordination with site main

controller. He will utilize emergency control centre.

7.24.5 Role of Local Authority

Preparation of Off Site Plan lies with local authorities. An emergency-

planning officer (EPO) works to obtain relevant information for preparing

basis for the plan and ensures that all those organization involved in

offsite emergency and to know their role and responsibilities.

7.24.6 Role of Fire Authorities

The fire authorities will take over the site responsibility from incident

controller after arrival. They will be familiarized with site of flammable

materials, water and foam applies points, fire-fighting equipment.

7.24.7 Role of the Police and Evacuation Authorities

Senior Police Officer designated, as emergency co-ordination officer shall

take over all control of an emergency. The duties include protection of

life, property and control of traffic movement. Their functions include

controlling standards, evacuating public and identifying dead and dealing

with casualties and informing relatives of dead or injured. There may be

separate authorities/agencies to carry out evacuation and transportation



work. Evacuation depends upon the nature of accident, in case of fire

only neighboring localities shall be alerted. Whole areas have to be

evacuated in case of toxic release.

7.24.8 Role of Health Authorities

After assessing the extent of effect caused to a person the health

authorities will treat them.

7.24.9 Role of Mutual Aid Agencies

Various types of mutual aid available from the surrounding factories and

other agencies will be utilized.

7.24.10 Role of Factory Inspectorate

In the event of an accident, the Factory Inspector will assist the District

Emergency Authority for information and helping in getting Neighbouring

Industries/mutual aid from surrounding factories. Factory Inspector may

wish to ensure that the affected areas are rehabilitated safely.

7.25 MOCK DRILLS AND RECORDS

7.25.1 Need of Rehearsal & Training

Regular training and rehearsal program of emergency procedures shall be

conducted with elaborate discussions and testing of action plan with mock

drill. If necessary, the co-operation/guidance of outside agencies will be

sought.

7.25.2 Some Check Points

The extent of realistic nature of incidents.

Availability of sufficient resources such as water, fire-fighting aids,

personnel.

Logical sequences of actions.

The involvement of key personnel in the preparation of plan.

Satisfactory co-operation with local emergency services and district or

regional emergency planning offices.

7.25.3 Records and Updating the Plan

All records of various on-site and off-site emergency plans of the factory

will be useful alone with those of the factors by which statutory

authorities draw a detailed plan for the whole area/district. The records of

the activity will be updated regularly.



B. SOCIAL IMPACT ASSESSMENT

M/s. Urmit Chemicals Pvt. Ltd. proposed to be located at Survey No.

1384, Village: Rajpur, Tal: Kadi, Dist: Mehsana, Gujarat. Total production

capacity of the unit will be 400 MT/month. Around 25-30 workers will be

employed in the construction work. During the operational phase, around

100 nos. of manpower will be employed. Total area of the project is 5662

m2.

Social Corporate Responsibilities

Corporate Environmental Responsibility (CER) refers to a company‘s

duties to withdraw from damaging natural environments. These efforts

can range from donating money to non-profits to implementing

environmentally-friendly policies in the workplace. The group's CSR

activities are rooted in the knowledge that businesses have a duty to

enable all living beings to get a fair share of the planet's resources.

Survey Methodology

The survey aims to document the living conditions, level of socio-

economic development of the region and the socio-economic profile of

people in the core and buffer zones of the study area. The village level

data were collected from Census.

Study of Village Profile

This study includes village level survey of Population, Economics, Land

use Pattern, Employment pattern, Healthcare Facilities, Amenities for

Livelihood.

Sources of Information

As per the scope of present study, the information on the sociological

aspects like demography, human settlements, social aspects like SC & ST

population, literacy levels and economic aspects like occupational

structure of workers has been gathered and complied from secondary

sources viz. the District Census Statistical Handbook, 2011 as these

documents being comprehensive and authentic.

Socio Economic Survey within study area:

The Study area in 10 km radius has 43 villages including project site. The

total no. of household in the villages are 24817 and the total population is

119449 (52.05% men & 47.95% women).



1) Educational facility

Literacy is an important indicator for understanding the socio-economic

development of any area. 72.70% of are literate while literacy rate

among men & women is 76.18% & 62.69%, respectively. 71.50% of are

literate while literacy rate among women & men is 64.10% & 78.31%

respectively. 53.21% of male population is part of main worker, while

only 10.42% of female population is a part of main workers. 2.90% of

male workers are marginal workers, while 6.65% of female workers are

engaged in such type of activities. 44.76% of male population and

84.27% of female population are non-workers. Many villages of the study

area have no proper education facility and literacy rate is very low

especially in women. As per 2011 census, there are primary schools

every village, 1 pre-primary school, 11 Secondary schools, 6 Senior

Secondary School and 3 college in all 43 villages. Keeping in view of the

industrialization around these villages and there is need of semi-skilled

and skilled labor for the industrial units. Unit will motivate educational

activities by awarding meritorious school students in SSC & HSC, science

lab - equipment & books in libraries for schools, and supports for sport &

cultural competitions in schools. Women bear larger losses in terms of

educational attainment, employment and wages. Thus, more focus will be

on Women Education considering the gap in literacy rate and employment

rate.

2) Health & Family welfare

43 villages in the study area have 4 Primary Health Centre, 9 Primary

Health Sub Centre, 1 Maternity and Child Welfare Centre, 2 Veterinary

hospital, 1 Dispensary, 1 Family Welfare Centre in study area of 10 km.

Unit will contribute in health checkup camps organized by different

agencies by providing man, medicine, and money.

3) Preservation of Environment and Sustainable Development

For Preservation of Environment, unit will promote tree plantation in

surrounding villages. Unit will promote uses of non-conventional source of

energy i.e. solar power. Additionally, unit will raise awareness and

promote rain water harvesting in nearby villages.



Details of expenditure for ESR activities:

Cost of the proposed project : Rs. 8.0 Crores

Expenditure earmarked towards ESR : Rs. 16.0 Lakhs

(2.0 % of the project cost)

Table 7.11: Detailed expenditure break-up for CER activities

Sr.

No.

Activities Years (Rs. in Lakhs) Total Budget

(Rs. in Lakhs) 1st 2nd 3rd 4th 5th

1 Educational activities 0.6 0.6 0.6 0.6 0.6 3.0

2 Drinking water and sanitation

facilities

0.8 0.8 0.8 0.8 0.8 4.0

3 Women Empowerment &

children Development

activities

0.6 0.6 0.6 0.6 0.6 3.0

4 Preservation of Environment,

rain water harvesting

& tree plantation

1.2 1.2 1.2 1.2 1.2 6.0

Total 3.2 3.2 3.2 3.2 3.2 16.0



Chapter-8

Project Benefits

8.1 INTRODUCTION

Project benefit focus on those points which will become beneficial to the

surrounding area or community in terms of infrastructural development,

social development, employment and other tangible benefits due to

project. Proposed project of Urmit Chemicals Pvt. Ltd. has a potential

for employment of skilled, semi-skilled and unskilled employees during

construction phase as well as operational phase.

8.2 IMPROVEMENT IN PHYSICAL INFRASTRUCTURE

Urmit Chemicals Pvt. Ltd. has proposed to manufacture dyes and dye

intermediates with quantity of 400 MT/month. The project will have

requirement of an infrastructure, so direct benefits of infrastructure

development is anticipated. The project proposes to employ local people

which will help to increase the income of local people & improve their

standard of living. The construction and commissioning phase will require

a substantial manpower and resources. Hence, with the growth in the

economic conditions, the project may lead to growth in the social stature

& improvement of the quality of life in the surrounding area. It will also

help in improvement in local amenities. Thus, the project will have

considerable indirect benefits to the public physical infrastructures.

8.3 IMPROVEMENT IN SOCIAL INFRASTRUCTURE

The company will conduct social welfare activities which include the

funding & contribution for public infrastructure/facilities development,

maintenance & improvement on basis of as & when required. Due to

proposed project activity at Urmit Chemicals Pvt. Ltd., social

infrastructure will improve by means of civilization, vocational training

and basic amenities.

Civilization: Due to the project, employment and other infrastructural

facilities will boost up income of surrounding people and improve quality

of life. This will indirectly boost up the civilization of the surrounding

people.



Vocational Training: Unit will provide vocational training opportunity to

the surrounding people and motivate the education activities that will

lead the change in life style of the surrounding, hence, improving social

infrastructure.

Basic Amenities: Unit will consider providing or improving education

facilities, healthcare, and drinking water facilities in the area, which will

help in uplifting the living standards of local communities.

8.4 EMPLOYMENT POTENTIAL

In the construction phase, direct and indirect manpower will be involved.

Thus temporary and permanent employment will be generated during

construction phase. The proposed manpower requirement during

construction will be 25-30 nos. During the operation phase, 100 nos. of

skilled and unskilled manpower will be required. Moreover, unit will

provide first priority to local workers for the employment. Further, the

indirect employment via increased transportation, ancillary units & local

economic activities will also add in the employment potential of the

project. Thus, the Urmit Chemicals will result in considerable benefits in

terms of employment.

8.5 OTHER TANGIBLE BENEFITS

In addition to mentioned above, the project will have many employment

& trade opportunities, which will eventually result in appreciable

economic benefits to the local people & businesses/contractors.

Indirectly, the project will help the Government by paying different taxes

from time to time, which is a part of revenue and thus, will help in

developing the area.



Chapter-9

Environmental Cost Benefit Analysis

As per EIA Notification 2006, this Chapter of the ‘Environmental Cost Benefit

Analysis’ is applicable only if it is recommended at the Scoping stage. As per

the standard ToR issued by MoEF&CC, New Delhi vide File No. IA-J-

11011/418/2018-IA-II(I) dated 4th February 2019, the Environmental

Cost Benefit Analysis is not applicable and hence has not been prepared.



Chapter-10

Environment Management Plan

10.1 INTRODUCTION

Assessment of environmental and social impacts arising due to

implementation of the project activities is the technical heart of EIA

process. An equally essential element of this process is to develop

measures to eliminate, offset or reduce impacts to acceptable levels

during implementation and operation of projects. The integration of such

measures into project implementation and operation is supported by

clearly defining the environmental requirements within an Environment

Management Plan (EMP).

The EMP of Urmit Chemicals Pvt. Ltd. has been formulated considering

all necessary mitigation measures to prevent/minimize/eliminate

environmental impacts associated with the proposed activities. Unit will

form an Environment Management Cell to keep a close watch on the

performance of the pollution control equipments, emissions from the

sources and the quality of surrounding environment in accordance with

the monitoring program.

OBJECTIVE OF ENVIRONMENT MANAGEMENT PLAN

The key objectives of the Environment Management Plan are,

To limit/reduce the degree, extent, magnitude or duration of adverse

impacts,

To treat all the pollutants i.e. liquid effluent, air emissions and

hazardous waste with adoption of adequate and efficient technology,

To reduce risk/hazards and design the disaster management plan,

To make budgetary provision and allocation of funds for environment

management system and for timely revision of budgetary provisions.

10.2 ENVIRONMENTAL MANAGEMENT DURING CONSTRUCTION PHASE

Construction phase results in temporary environmental pollution except

for the permanent change in local land use pattern & aesthetics in certain

cases. Such pollution is mainly due to site preparation, civil works,

transportation, storage & handling of construction materials, construction

worker’s sanitation etc. These are usually short-term impacts.



10.2.1 Air and Noise Environment

During construction work at Urmit Chemicals, air pollution is expected in

the form of increased suspended particulate matter concentration.

Installation work will generate noise and dust, but it will be within

working areas. To mitigate the adverse environment impact due to the

construction phase, following measures will be taken:

Regular sprinkling of the water will be carried out at least twice a day

along with the construction activities to reduce dust emissions,

Regular preventing maintenance of machinery and transportation

vehicles will be carried out to reduce vehicular emissions and noise

pollution,

Provision of silencer to modulate the noise generated by the machine,

if required, and

Provision of personal protective equipment such as earmuffs/earplugs

to workers working in noisy area.

10.2.2 Water Environment

During construction phase, water supply from bore well and/or tankers

and portable sanitation facilities will be provided. Rest room will be

provided for workers as well as truck drivers during operation phase.

Domestic wastewater will be discharged into soak pit.

10.2.3 Socio-Economic Environment

The proposed manpower requirement during construction will be 25-30

nos. Unit will give preference to local people through both direct and

indirect employment.

10.2.4 Health and Safety

Adequate rest area will be provided to the construction workers, casual

workers, and truck drivers. Unit will also supply potable water and

portable sanitation facilities for the construction workers, casual workers,

and truck drivers. The safety department will supervise the safe working

of the contractor and their employees. Work spots will be maintained

clean, provided with optimum lighting and enough ventilation to eliminate

dust/fumes.



10.3 ENVIRONMENTAL MANAGEMENT DURING THE OPERATIONAL

PHASE

EMP proposed for implementation is detailed under the following heads:

Air Pollution Management

Wastewater Management

Solid/Hazardous Waste Management

Noise Management

Greenbelt Development

Occupational Safety and Health

Implementation of EMP and monitoring programme

10.3.1 Air Pollution Management

10.3.1.1 Source of Air Pollution and Control Measures

Flue gas emission will be from stack attached with boilers, Hot Air

Generator & Thermic Fluid Heater, where low sulfur coal will be used as

fuel; and standby D.G. Set in which Diesel will be used as fuel. All the

flue gas stacks, except stack of D.G. Sets, will be equipped with cyclone

& bag filter as APCM. Process emission will be from the vents attached to

Reaction Vessels of Multipurpose Plant – 2 sets and Reaction Vessel of

Chloranil Additionally three spray dryers are also consider as also source

of process emission. Alkali scrubbers will be provided on process gas

stack attached to reaction/ process vessels (2 sets) and water scrubber

will be provided on process gas stack attached to Reaction/ Process

vessels (Chloranil) as APCM. Spray dryer will be equipped with Cyclone +

Scrubber + Sub merged type gas bubbling tank.

Furthermore, adequate stack height and facility for sampling such as

ladder and sampling point will be provided as per the GPCB guidelines.

The details of stacks with their APC measures are given in Table 2.8 of

Chapter-2.

Measures to control fugitive emission

The fugitive pollutants of PM & Acid mists are likely to emit from process

area. Unit will adopt following measures,

Adequate scrubbing system to absorb the process gas and

condensing systems,

Entire process will be carried out in closed reactors,



Pneumatically transfer of liquid raw material in rector,

Raw material will be stored in the covered structure,

Regular maintenance of valves, pipes, etc.,

Greenbelt will be developed around the plant to arrest the fugitive

emission.

PPEs will be provided to the workers, and

Frequent work area monitoring will be done to ensure fugitive

emissions level.

10.3.1.2 Measures for Solvent Recovery

There is no use of solvent for recover of product or crystallization of

products. Hence no need to recovery of solvent.

10.3.1.3 Odour Control Plan

All solid raw materials shall be charged directly to reactor through special

air lock hopper against slight negative pressure (in water column) so that

no odour is emitted to the environment. Solid charging nozzle in reactor

shall be projected inside so that it directly falls in to the solvent media,

thereby eliminating carrying over of solid to vapour nozzle. Powder

transfer system shall also be used wherever applicable to have zero loss

of powder into the atmosphere. All liquid raw material handled in drum

shall be cooled down before charging so as to minimize its vapour

pressure and control of odour. Alternatively vacuum lock could also be

used in day tank for transfer of liquid from drum (pumping under

vacuum). Proper Personal Protective Equipment (PPEs) will be provided to

the workers who are involved in handling odorous materials.


Unit will satisfy its fresh water requirement from Bore well water supply.

Total water requirement (Industrial + Domestic + Greenbelt) at Urmit

Chemicals will be 178 KLD; out of which 103 KLD will be fresh water

requirement & 75 KLD will be recycle/treated water. Unit will satisfy its

fresh water demand from groundwater source. Major water demand will

be industrial – mainly process (45 KLD), Scrubber (14), Washing (25

KLD) Cooling (45 KLD) and Boiler (30 KLD).


domestic wastewater and the rest (125 KLD) will be industrial



wastewater. The main source of the industrial wastewater generation will

be from process (80 KLD), Scrubber (2 KLD), Washing (25 KLD) and

utilities (Boiler & Cooling - 18 KLD). The wastewater generated will be

separated into two streams for treatment.

a) Concentrated stream from Dye Intermediates plant

b) Dilute stream from Dyes plant, scrubber, washing and utilities

Process effluent from Dye Intermediates plant (48 KLD) will be treated in

“ETP-1”. Then it will be sent to Common Spray Drying facility for

evaporation at Chhatral Environment Management System Pvt. Ltd.

Wastewater from Dyes plant, Scrubber, Washing and utilities (cooling &

boiler) (77 KLD) will be treated in “ETP-2”. After treatment, it will be

passed through RO. RO permeate (60 KLD) will be reused; RO reject (17

KLD) will be Spray Dried along with effluent of ETP-1 (48 KLD) in

common evaporation facility at Chhatral Environment Management

System Pvt. Ltd. Sewage of 7.5 KLD will be disposed to soak pit.

Flow diagram of ETP-1 and ETP-2 are given as Figure 2.6 and 2.7,

respectively in Chapter-2. Design details of ETP are given in Table 2.10.

Effluent treatment scheme:

Process wastewater (ETP-1): Effluent from industrial wastewater will

be passed through equalization tanks. In equalization tank, effluent will

be equalized and neutralized using alkali (Hydrated Lime). Then effluent

be passed through flash mixer provided with alum/poly dosing for

coagulation and then to flocculation tank to enhance the formation of

flocs. The effluent will then be led to filter press to remove solids. Effluent

from filter press will then be led for tertiary treatment and then

evaporated at Common Spray Drying facility.

Washing & Utilities wastewater (ETP-2): Effluent from scrubber,

washing and utilities will be collected into Equalization/Neutralization

Tank. In equalization tank, effluent will be equalized and neutralized.

Then effluent is passed through primary settling tank led to clarifier to

remove solids. The effluent from primary settling tank will then send for

tertiary treatment and then pass through RO system to recover

usable/recyclable water and reject of RO will be evaporated into common

Spray Drying facility.



10.3.3 Hazardous/Solid Waste Management


Hazardous & Other Waste (Management & Transboundary Movement)

Rules, 2016. ETP sludge (150 MTPM) will be disposed off at TSDF site.

Hazardous waste from process will be HCl (20-22%) (52 MTPM), Spent

Sulphuric acid (780 MTPM), Calcium Thio Sulphite (78 MTPM), Acetic Acid

(104 MTPM), Sodium Bisulphite (260 MTPM), Iron sludge (52 MTPM) and

Spent catalyst (0.5 MTPM). Discarded containers (10000 Nos./month)

/liners (1.0 MTPM) and used lubricating oil (0.5 KL/yr).

The unit will provide isolated area with impervious flooring & roof cover

for the storage of hazardous waste. Details of hazardous waste disposal

methods are given in Chapter 2 (Table 2.10).

Fly Ash management

Fly ash generation will be around 5.0 MT/day. Fly ash will be sold to brick

manufacturer working in 25 km radius from project site and also supplied

to the companies for land leveling, conditioning & road construction, etc.

Storage and Transportation of Solid/Hazardous Waste:

Proper Hazardous waste storage area with impervious flooring and

covered shed is provided for storage of solid/hazardous waste.

Entire quantity of the hazardous waste is stored in the isolated

hazardous waste storage area within premises having leachate

collection system and roof cover. The storage yard shall be properly

labeled for identification of wastes.

Hazardous waste shall not be stored for a period more than 90 days.

Records of the same shall be maintained and make them available for

inspection.

Properly packed & labeled waste shall be transported through

dedicated vehicle.

10.3.4 Noise Control

Urmit Chemicals proposes following measures to minimize the impact of

noise on the environment during the operational phase,

Noise suppression measures such as enclosures, buffers and/or

protective measures should be provided, if required (wherever noise

level is more than 90 dB (A)).



Extensive oiling, lubrication and preventive maintenance will be carried

out for the machineries and equipments to reduce noise generation.

Use of PPEs like ear plugs and ear muffs is made compulsory near the

high noise generating machines.

Moreover, the personnel shall be provided breaks in their working

hours, with the continuous exposure not increasing three hours.

The transportation contractor shall be informed to avoid unnecessary

speeding of the vehicles inside the premises.

Acoustic enclosure shall be provided for D.G. set and similar provisions

like noise attenuator wherever suitable/possible.

Areas with high noise levels will be identified and segregated where

possible and will include prominently displayed caution boards.

Adequate greenbelt will be developed within industrial premises and

around the periphery to prevent the noise pollution.

Periodic monitoring of noise levels as per post-project monitoring plan

shall be done on regular basis.

By taking measures as mentioned above, it is anticipated that noise

levels in the plant will be maintained below the permissible limit.

10.3.5 Green Belt Development

Tree plantation is one of the effective remedial measures to control the

air pollution and noise pollution. It also causes aesthetics improvement of

the area as well as sustains and supports the biosphere. Urmit Chemicals

proposes to do extensive plantation in 1870 m2. Overall greenbelt area

will be more than 33% of the total area of the project.

Design of Green Belt

As far as possible, following guidelines will be considered in greenbelt

development.

The spacing between the trees will be maintained as per SPCB

guideline i.e. 1 tree/4 sqm.

Spaces, so that the trees may grow vertically and slightly increase

the effective height of the greenbelt.

Planting of trees in each row will be in staggered orientation.



The short trees (< 10 m height) will be planted in the first two rows

(towards plant side) of the green belt. The tall trees (> 10 m height)

will be planted in the outer three rows (away from plant side).

Planting methodology

The plantation shall be done in pits. The pit shall be refilled with soil after

the planting. The sampling of healthy, nursery raised, seedlings in

polythene containers shall be transported in baskets. Planting shall be

done after first monsoon showers. The level of soil is about 10 cm above

of ground level. The soil around the plant shall be pressed to form a low

through. About 25 gm chemical fertilizers shall be added. Watering shall

be continued after plantation if any dry spells follows. Planted area shall

be inspected and mortality rate ensured for each species. The dead and

drying plant shall be replaced by fresh seedlings.

Selection of species for greenbelt

For the development of greenbelt, plants having simple big leaves and

native species are preferred to the plants. The plants are suitable for

greenbelt development based on gaseous exchange capacity of foliage

which is ascertained by the following characteristics:

The plant should be fast growing.

It should have thick canopy cover.

It should be perennial and evergreen.

It should have large leaf area index.

It should be indigenous.

It should be efficient in absorbing pollutants without significant effects

on plant growth.

The objectives of the industrial greenbelt are to improve the micro-

environment. The success depends on the type of land available and

selection of suitable tree species for pollution control. Selection of tree

species for industrial areas is influenced by the nature of industry. The

objective should be to ensure a green cover tolerating pollutant gases

and solid particulates present in the atmosphere. It is also advisable to

select suitable tree species and adopt simple techniques which require

minimum investment and care.



Floral species recommended for greenbelt

Azadirachtaindica (Neem), Albizialebbeck (Siris), Pongamiapinnata

(Karanj), Ficusreligiosa (Peepal) are suggested for the greenbelt

development with respect to this particular area. They are mostly

deciduous and evergreen tree types suitable to be grown in the area.

Survival rate of trees and post plantation care

Considering the availability of water and general survey of surrounding

area, the survival rate is expected to be around 70-75%. Moreover, the

wire net guards will be provided to protect the saplings. The same will be

properly manured and watered so that it can grow well.

Protection of plantation site:

Protection from grazing will be done by erecting tree guards around

planted sapling.

Though the tree suggested for plantation will require very less water,

however during the first year watering will be done twice in a day.

There after watering will be done twice in a week.

The manuring will be done when plantation take up. For this purpose,

cow dung will be dump in the pit. No other manuring will require for

plantation. Cow dung is easily available in the study area.

Damaged plants will be replaced with new plants.

Strict surveillance will be made to increase the survival rate of the

trees.

10.3.6 Occupational Health & Safety Plan

To maintain high standard in Health, Safety and Environment, necessary

key mitigation measures & action plan as EMP has been suggested as

described below.

Post-employment health check-up programs will be carried out on

annually and all records & documents related with employee health

check-up program will be maintained.

As per RA report, all risk control & prevention measures in the unit will

be implemented.

Necessary PPEs, safety equipments/materials to ensure healthy & safe

work conditions will be provided to employees.



All employees will be provided with required set of PPEs like ear plug,

ear muff etc. where noise levels in excess of 80 dB(A) are regularly

generated.

It is recommend that pre-employment health check-up programs shall

be carried out for every new employee and all records & documents

related with employee health check-up program shall be maintained

by the proponent.

Safety documents, procedures, guidelines along with MSDS shall be

provided to the associated/concerned personnel engaged in respective

operational activities.

Training programs & safety audit shall be done on regular basis to

prevent impacts of the operational activities on occupational health as

well as to improve workplace condition & safe work system.

The proponent shall ensure implementation of emergency

management plan with provision of fire-fighting equipment/facilities,

first aid & medical facilities, evacuation procedures etc.

Proponent shall also ensure proper implementation & functioning as

well as assess effectiveness of this safety & emergency system on

regular basis throughout the project operation phase.

Plans for Periodic Medical Checkup

Part time doctor is periodically visited the plant for health check-up of

each employee.

Pre-employment health check-up will be followed by periodical health

check-up with special attention to occupational health.

Medical records of each employee will be maintained in prescribed

format as per Factory Act.

The health check-up will be conducted as per the pre-designed format

which will include chest X-rays, Audiometry, Spirometry, Vision

Testing, ECG, Blood and urine test etc.

The work zone monitoring will be conducted on regular basis.

Monitoring of the Occupational Injury & It’s Impact on workers

The action plan will be prepared to monitor the injury to workers:

Each workplace will be evaluated for the existing work conditions.

Unsafe Act &unsafe Practices will be identified.



Unsafe equipment, unsafe areas, etc., will be identified.

Area will be checked for proper Ventilation and Illumination.

Air-borne concentration of toxic chemicals will be measured and

records will be kept.

Evaluation of training & on the job work.

Impact of the above mentioned unsafe conditions on workers will be

studied and remedial measures for the same will be adopted.

10.3.7 Details of the separate isolated storage area:

Unit will provide isolated storage area for solvent and corrosive

chemicals. Details of storage are given in Table 7.1 of Chapter-7 of EIA

report. All the raw materials are stored in isolated storage area and

containers are tightly closed.The following precautions shall be taken to

avoid foreseeable accident like spillage, fire and explosion hazards and to

minimize the effect of any such accident and to combat the emergency at

site level in case of emergency.

Various emergency spots in plant area will be identified and kept in

sharp and alert watch.

Protective equipment will be regularly checked and will be kept easily

accessible and easily workable during emergency.

Safety installations like available quantity of running water will be

regularly watched.

Fire bucket and hose reels will be provided to withstand the fire or

explosion conditions.

Various types of fire extinguishers such as (Foam type, water CO2

type, CO2 type) will be provided inside the factory premises.

Every pressure vessel will be provided with minimum one or more

pressure relief devices. The design of the valve is made in such a way

that the breakage of any part will not obstruct force discharge of the

liquid under pressure. Moreover, relief valves are tested and a periodic

schedule for their testing shall be maintained.

10.4 POST-PROJECT ENVIRONMENTAL MONITORING

The highlights of the integrated environmental monitoring plan are:

The stack monitoring facilities like ladder, platform and port-hole of all

the stacks maintained in good condition.



Regular monitoring of all gaseous emissions from stacks & fugitive

emissions in the process areas.

The performance of air pollution control equipment will be evaluated

based on these monitoring results.

Water consumption in the unit recorded daily.

Analysis of untreated and treated effluent will be carried out regularly.

Performance of effluent treatment plant units and RO will be evaluated

based on above analysis results.

As far as possible, noise curbed at its source, with the help of acoustic

hoods and other such noise reducing equipment. Regular noise level

monitoring carried out.

Greenbelt will be properly maintained and new plantation programmes

undertaken frequently.

Continued environmental awareness programmes carried out within

the employees and also in the surrounding villages.

Rain water harvesting ponds will be developed within the industrial

premises and encouraged in the surrounding villages too.

Table 10.1: Environment Monitoring Plan

Nature of Analysis

Frequency of analysis with its analyzer

Parameters No. of samples

Wastewater

analysis

Monthly by external

agency

pH, TDS, SS,

COD, BOD, Oil & Grease, etc.

3-4 samples

Stack Monitoring of each stack


PM, SO2, NOX, HCl

All stacks

Ambient Air

Quality Monitoring

Monthly for 24 hours or

as per the statutory conditions by external agency

PM10, PM2.5,

SO2, NOX, HCl

3-5 locations

Noise level Monthly as per the

statutory conditions by external agency


Nr. boiler, Nr. D.

G. Set, Process

area etc.)

Work zone

fugitive monitoring

Monthly by external

agency

RPM, acid mist 2-3 locations

Health check-up of workers

As per the statutory guideline

All workers



10.4.1 Details of Work Place Air Quality Monitoring Plan

Work zone monitoring will be carried out by independent competent third

party every month. Records will be kept in Form No. 37 as per Gujarat

Factories Rules. Location for samplings will be identified. Following

information will be incorporated in the format for maintaining records of

work zone monitoring:

Location/Operation monitored

Identified contaminant

Sampling instrument used

Number of Samples

Range of contaminant concentration as measured in sample

Average concentration

Reference method used for analysis

Number of workers exposed at the location being monitored

Signature of the person taking samples

10.5 ENVIRONMENT MANAGEMENT BUDGET ALLOCATION

Total capital cost and recurring cost/annum earmarked for environment

pollution control measures by Urmit Chemicals Pvt. Ltd. will be as under.

Table 10.2: Budget Allocation for Environment Management

Sr.

No.

Particulars Capital Cost

(Rs. in Lakhs)

Recurring Cost

per annum (Rs. in Lakh)

1 Air Pollution Control 150 15.0

2 Water Pollution Control 140 350

3 Noise Pollution Control 1.0 2.0

4 Solid/Hazardous Waste Management

10.0 25.0

5 Environment Monitoring

and Management

2.5 3.0

6 Occupational Health 1.5 5.0

7 Green Belt Development Plan

5.0 1.2

8 Rain Water Harvesting

System

5.0 0.5

Total 315 401.7

10.6 ENVIRONMENTAL MANAGEMENT CELL

Urmit Chemicals will set up separate Environment Management Cell. The

major duties & responsibilities of EMC will be as follows:



To implement the Environmental Management Plan,

To ensure regular operation &maintenance of pollution control devices,

To assure regulatory compliance with all relevant rules and

regulations,

To minimize environmental impacts by strict adherence to the EMP,

To initiate environmental monitoring as per approved schedule,

Review & interpretation of monitored results and corrective measures

in case monitored results are above the specified limit,

Maintain documentation of good environmental practices and

applicable environmental laws as ready reference,

Maintain environmental related records,

Coordination with regulatory agencies, external consultants and

monitoring laboratories, and

Maintaining log of public complaints and the action taken

10.6.1 Hierarchical Structure of Environmental Management Cell

The hierarchical structure of Urmit Chemicals is given below.

Figure 10.1: Environment Management Cell

10.6.2 ENVIRONMENT POLICY

Unit will develop Environment Policy. They commit themselves to:

Ensure continuous improvement in environmental performance of our

works through protective Environmental management system.

Comply with applicable legal and other requirements related to

environmental aspects.

EHS Head

ETP in-charge

General Manager

(Operation)

ETP

Chemist

Safety officer

ETP

Operator



Conserve the resources particularly water, power by fixing and

improving consumption norms.

Concept of cleaner production will be adopted.

Ensure involvement of all employees and contractors in effective

implementation of Environment Management System through

training and awareness.

Promote awareness among local surrounding community for

preservation and maintaining clean environment.

10.6.3 Reporting System of Non-Compliances/Violations of

Environmental Norms

Record keeping and reporting of performance is an important

management tool for ensuring sustainable operation of the unit. Records

are maintained for regulatory, monitoring and operational issues. Urmit

Chemicals Pvt. Ltd. will develop reporting systems of non-

compliances/violations of environmental norms to the Board of Directors.

The mechanism is summarized below:

1. Identify deviation/non-compliance/violation of environmental norms

as lay down in consent to operate and letter of Environmental

clearance. Record to communication/complain received from

plausible stake holder.

2. The EHS manager will identify deviation/non-compliance/violation

from failure to comply with statutory requirements.

3. Respond from EHS manager within reasonable time limit to concern

authorities with c/c mark to Technical head.

4. Technical head will take it in action and give necessary guideline to

comply this deviation/non-compliance/violation of environmental

norms. Parallel arrange budget for necessary action to comply the

condition.

5. Communication received from the EHS manager will be discussed in

technical management meeting.

6. Board discussion, Decision and Action

The chairperson will review the information available and take a

decision depending on the seriousness of the violation.



The decision will be taken to ensure the compliance of non-

compliance/violation of environmental norms and it’s safeguarded.

The decision will be taken by consensus and if no consensus is

arrived at, voting will be conducted.

Enlist measures that would undertake to ensure that deviations/

non-compliance/violations of Environmental norms and take care

not to occur same violation in future.

10.6.4 Framework for Continual Improvement of Environmental

Performance of Organization

10.7 RESOURCE CONSERVATION AND CLEANER PRODUCTION

Steps that are undertaken by the industry are given below:

RO permeate will be reused to reduce fresh water demand.

Housekeeping will be regularly maintained. Dedicated staff for the

purpose will be employed.

Solid wastes e.g. powders, spills, etc. in process and packaging are

to be separately collected and disposed of instead of allowing these

to effluent streams. This will reduce load to treatment and increase

the efficiency of treatment system.

Mechanical seals will be provided to the process vessels having

agitator for reduction of fugitive emissions and leakages.

Rain water harvesting system will be adopted to compensate the

fresh water withdrawal.

10.8 ENERGY CONSERVATION PROGRAMME

Energy conservation measures are often the easiest, quickest and

cheapest way to reduce costs and be environmentally pro-active. The

conservation efforts would consist of the following:

EMP

Implementation

Monitoring as

per EMP

requirement

Internal and

External Audits

Corrective and

Preventive Actions

Review and revision of EMP

based on Environmental

Performance Evaluation Improvement

Mitigation

measures



Ensure proper selection fuel-firing equipments - Burners, mechanical

stokers, etc.

Reduce radiation losses from boilers, furnaces and auxiliary equip-

meant by improved thermal insulation. This will also improve the

working conditions within the building and eliminate unnecessary

ventilation,

Schedule process operations to avoid fluctuations in boiler loads,

Keep the heat transfer surfaces clean by preventing excessive scale

formation,

Pressure vessels should be designed with a length to diameter ratio

of roughly three as they are the most economical,

Maximize the use of natural lighting through design,

CFLs or LED lights are used in administration building and plant

premises,

Constant monitoring of energy consumption and defining targets for

energy conservation,

Maximize the use of laptop computers over desktop computers as

Laptops use less energy than desktop and leave a smaller

environmental footprint at end of life,

Adjusting the settings and illumination levels to ensure minimum

energy used for desired comfort levels,

Recycling of water will be done, and

10.9 SOCIO-ECONOMIC ACTIVITIES

Enterprise Social Commitment (ESC) refers to voluntary actions

undertaken by company/organization to either improve the living

conditions (economically, socially, environmentally) of local communities

or to reduce the negative effects of the project. By definition, voluntary

actions are those that go beyond legal obligations, contracts, and license

agreements. Socio-economic development activities is a concept of

organization whereby organizations serve the interests of society by

taking responsibility for the impact of their activities on customers,

employees, shareholders, communities and the environment in all aspects

of their operations.



Following activities will be under taken as a part of CER:

A. Education

Awarding meritorious school students in SSC & HSC

Science Lab - Equipment & books in libraries for schools

Supports for sport & cultural competitions in schools

B. Health and family welfare

Malaria eradication camps (collection of blood sample & detection of

virus & free medicine distribution, blood donation camp)

Contribution towards primary health services depending on local

needs.

C. Preservation of Environment and Sustainable Development

Water harvesting systems in nearby villages.

Landscaping and greenbelt development around the project site.

Provide sanitation facilities to villagers.

D. Women Empowerment & children Development activities

Providing training and basic facility for self-sustainability of women.

Scholarship for education to children coming from Low Income

family.

Urmit Chemicals Pvt. Ltd. proposes to allocate Rs. 0.16 Crores (2.0% of

total project cost i.e. Rs. 8.0 Crores) towards the Enterprise Social

Commitment. Proposed activities are shown below, which may change

based on inputs from community during public hearing.

Table 10.3: Budgetary Provisions for the Social Upliftment

Sr.

No.

Activities Years (Rs. in Lakhs) Total Budget (Rs. in

Lakhs)

1st 2nd 3rd 4th 5th

1 Educational activities 0.6 0.6 0.6 0.6 0.6 3.0

2 Drinking water and

sanitation facilities

0.8 0.8 0.8 0.8 0.8 4.0

3 Women Empowerment & children Development activities

0.6 0.6 0.6 0.6 0.6 3.0

4 Preservation of

Environment, rain water harvesting

& tree plantation

1.2 1.2 1.2 1.2 1.2 6.0

Total 3.2 3.2 3.2 3.2 3.2 16.0



Chapter-11

Summary & Conclusion

11.1 PROJECT DESCRIPTION

11.1.1 General Introduction

M/s. Urmit Chemicals Pvt. Ltd is a green field project, proposes to set

up Dyes and Dye Intermediates manufacturing unit at Survey no. 1384,

Village: Rajpur, Tal: Kadi, Dist: Mehsana, Gujarat. Total production

capacity of all products will be tune around 400 MT/month.

Project activity falls under item 5(f) of the Schedule of EIA Notification,

2006 and its subsequent amendments.

11.1.2 Brief project description

Name of the Project M/s. Urmit Chemicals Pvt. Ltd.

Proposed production capacity 400 MTPM

Proposed project cost Rs. 8.0 Crores

Manpower requirement About 100 persons

Location

Survey No. 1384

Village Rajpur

Tehsil Kadi

District Mehsana

Coordinates Latitude: 23°20'48.44"N


Nearest

Human habitation Chandarda, about 1.45 km

Rajpur, about 1.58 km



Railway Station Julasan, about 7.0 km, Kadi, about 11.0

km

Highway SH41 (Ahmedabad-Mehsana), about 1.0

km

Air Port Ahmedabad, about 38.0 km

National Park/Wildlife Sanctuary None, within 10 km radius

Proposed

Power Requirement 500 kVA, Source: UGVCL (Uttar Gujarat

Vij Company Limited)

Water Requirement Total: 178 KLD;

Fresh water: 103 KLD; Recycle: 75 KLD

Source of raw water: Bore well



Wastewater Generation Industrial: 125 KLD Domestic: 7.5 KLD

Fuel Requirement Coal: 36 TPD Diesel for D.G. Set: 100 lit/hr.

Source of Air Emission Boiler (2 no.), Thermic fluid heater (1 no), Hot air generator (2 no.), D. G. set

(1 no.), process vent (2 no.), Spray Dyer (1 nos.).

Details of Haz. Waste ETP sludge, Calcium Thio Sulphite, Acetic

Acid, Iron Sludge, spent H2SO4, spent

catalyst, Used Oil, Discarded drums/

containers & Liners, HCl, Sodium bisulfite

11.1.3 Investment of the project

Estimated cost of the proposed project will be around Rs. 8.0 Crores.

Out of this, Rs. 3.15 Crores will be earmarked as capital investment for

EMS and Rs. 4.017 Crores will be recurring/operating cost per annum.

11.1.4 List of products

Product details with its capacity are given in table below.

Sr.

No.


(MTPM)


1. Chloranil 150





6. Metanilic Acid




(4 CAPSA)




(6 NAPSA)


(4 NAPSA)


(6 CAPSA)

15. 2 Pyridone



(1:4 SPMP)



Sr.

No.


(MTPM)

18. 2:5 Dichloro 4 Sulpho Phenyl 3 Methyl 5 Pyrazolone

(2:5 DCSPMP)


(2:5 CSMP)

20. 1,3 Sulpho Phenyl 3 Methyl 5 Pyrazolone

(1:3 SPMP)



(B) Dyes

Acid Dyes 100

1. Acid Yellow 79

2. Acid Yellow 151

3. Acid Yellow 49

4. Acid Yellow 99

5. Acid Yellow 194

6. Acid Yellow 220

7. Acid Yellow 232

8. Acid Brown 75

9. Acid Brown 165

10. Acid Brown 161

11. Acid Brown 282

12. Acid Brown 432

13. Acid Brown 425

14. Acid Brown 434

15. Acid Green 16

16. Acid Blue 9

17. Acid Blue 15

18. Acid Blue 7

19. Acid Blue 113

20. Acid Blue 193

21. Acid Red 315

22. Acid Black 107

Direct Dyes

23. Direct Black 80


25. Direct Brown 44

26. Direct Blue 71


28. Direct Red 239

29. Direct Red 254


31. Direct Red 81



Sr.

No.


(MTPM)

32. Direct Violet 9


34. Direct Black 19

Reactive Dyes





Basic Dyes Solid 50

39. Basic Brown 1

40. Basic Yellow 2

41. Basic Violet 1

42. Basic Green 4

43. Basic Green 1

44. Basic Blue 26


45. Basic Yellow 2

46. Basic Violet 1

47. Basic Green 4

48. Basic Green 1

49. Basic Blue 26

Total 400

11.2 DESCRIPTION OF ENVIRONMENT

11.2.1 Baseline Environmental Study

To predict the impact of the project on the surrounding environment, the

current baseline environmental status was studied by collecting the data

and carrying out monitoring during January, 2019 to March, 2019 in

the study area of 10 km radius from project site as per the TOR.

11.2.2 Air Environment

The ambient air quality monitoring was carried out at 8 AAQM locations,

to assess the existing sub-regional air quality status during the period of

January, 2019 to March, 2019.

Combined Sampler along with the analytical methods, prescribed by

CPCB was used for carrying out air quality monitoring. At all these

sampling locations; PM10, PM2.5, SO2 and NOx were monitored on 24-

hourly and HCl, CO, HC and VOCs were monitored on 8-hourly basis to

enable the comparison with ambient air quality standards prescribed by



the CPCB. The data on concentrations of various pollutants were

processed for different statistical parameters like arithmetic mean,

standard deviation, minimum and maximum concentration and various

percentile values. The results are summarized below:

Particulate Matter (PM10)

An average and 98th percentile value of 24-hourly PM10 values at all the

locations are found from 64.5 – 70.3 g/m3 and 70.8 – 79.1 g/m3. The

results were found well within the National Ambient Air Quality Standards

(NAAQS-CPCB) of 100 g/m3.

Particulate Matter (PM2.5)

An average and 98th percentile value of 24-hourly PM2.5 values at all the

locations ranges from 37.4 – 40.1 g/m3 and 41.8 – 48.1 g/m3. The

values are well within National Ambient Air Quality Standards (NAAQS-

CPCB) of 60 g/m3.

Sulphur Dioxide (SO2)

An average and 98th percentile value of 24-hourly SO2 value of arithmetic


g/m3 respectively, which are well below National Ambient Air Quality


Oxides of Nitrogen (NOx)

An average and 98th percentile value of 24 hourly NOx value of arithmetic


g/m3 respectively, which are well below the National Ambient Air Quality


Carbon Monoxide (CO)

Minimum & Maximum value of CO at all the locations ranged from 1046 –

1364 g/m3.

Hydro Carbon (HC)

Minimum & Maximum value of Methane HC at all the locations ranged

from 21.4 – 42.4 g/m3 and non-methane HC at all the locations ranged

from 1110 – 1283 g/m3.

Volatile Organic Compounds (VOCs)

Minimum & Maximum value of VOC at all the locations ranged from 0.16

g/m3 – BDL.



Hydrochloric acid (HCl)

HCl found below detectable limit at all the locations.

Conclusion:

The quality of ambient air in the study area is compared with AAQM

Standards prescribed by CPCB & found below the prescribed standards.


Eight surface water & eight ground water samples were collected during

the study period.

Surface Water Quality

Surface water samples were collected from ponds/lakes of Chandarda

Pond, Mathasur Pond, Kaiyal Pond, Aldesan Pond, Kadi Pond, Chhatral

Pond, Budasan Pond and Narmada Canal. Results of the same are given

in Chapter-3 of EIA report.

Conclusion:

It was observed that all the physico-chemical parameters and heavy

metals from surface water samples except turbidity are below stipulated

drinking water standards and are suitable for domestic purposes.

Ground Water Quality

Ground water samples have been collected Nr. Project site, Laxmipura,

Chandarda, Mathasur, Rajpur, Irana, Untva and Bileshvarpura villages.

The summary of the analysis is as below:

Color: All the samples were found color less meeting desirable norms.

pH: All the samples meet the desirable standards (pH ranges from 7.3 -

7.9).

Total Dissolved Solids (TDS): TDS in samples ranges from 1130 mg/L

(Rajpur) to 1471 mg/L (Bileshvarpura), all the Samples meet the

permissible limit of 2000 mg/L TDS.

Calcium: Calcium contents in the water ranges from 47 mg/L (Mathasur)

to 95 mg/L (Bileshvarpura), all the samples meet the permissible limit of

200 mg/L, (Permissible Limit in the Absence of Alternate Source).

Magnesium: Magnesium content in the water ranges from 35 mg/L

(Chandarda) to 47 mg/L (Nr. Project Site). All the samples meet the

permissible limit of 100 mg/L (Permissible Limit in the Absence of

Alternate Source).



Sulfate: Sulfate content in the water ranges from 84 mg/L (Irana) to 128

mg/L (Bileshvarpura). All the samples meet the permissible limit of 400

mg/L (Permissible Limit in the Absence of Alternate Source).

Fluoride: Fluoride content in the water ranges from 0.65 mg/L (Nr.

Project Site) to 0.75 mg/L (Irana). All the samples meet the permissible

limit of 1.5 mg/L (Permissible Limit in the Absence of Alternate Source).

Total Alkalinity: Total alkalinity in the water samples ranges from 315

mg/L (Nr. Project Site) to 353 mg/L (Laxmipura). All the samples are

within the permissible limit of 600 mg/L (Permissible Limit in the Absence

of Alternate Source).

Other Parameters: Potassium (ranges from 55 mg/L to 74 mg/L),

Sodium (ranges from 346 mg/L to 446 mg/L) and Chloride (ranges from

518 mg/L to 661 mg/L). All the samples meet permissible limit in the

absence of alternate source.

Heavy metals like cadmium, copper, lead, chromium, iron and zinc are

well below the limit in all samples.

Conclusion:

The results have been compared with the drinking water quality

standards specified in IS: 10500-2012 & all parameters meet the

permissible limit set by the authority (BIS).

11.2.4 Noise Environment

Noise monitoring has been conducted at nine locations in the study area.

The monitored noise level in the day time Leq (Ld) varies 51.4 to 54.5

dB(A) and the night time Leq (Ln) varies from 40.0 to 43.3 dB(A) within

the study area. Higher noise value of 54.5 dB(A) was recorded during day

time at Primary School of Rajpur & lower noise value of 40.0 dB(A) was

recorded during night time at village Irana.

11.2.5 Soil Quality

Soil samples were collected from 8 different locations and analyzed to

assess the soil quality prevailing in the study area. Physical

characteristics of soil have been delineated through specific parameters,

viz. particle size distribution (grain size analysis), porosity, water holding

capacity and permeability whereas data for chemical characterization of



soil, viz. pH, electrical conductivity, cation exchange capacity and sodium

absorption ratio have been analyzed.

11.2.6 Biological Environment

Baseline data for flora & fauna has been collected with its family. It was

found that, none of the species of conservation importance exists in the

study area and no endangered species found in the study area.

11.2.7 Socio-Economic Environment

Socio-economic study includes description of demography, available basic

amenities like housing, health care services, transportation, education

facilities. Information on the above said parameters has been collected to

define the socio-economic profile of the study area (10-km radius).

11.3 ANTICIPATED ENVIRONMENTAL IMPACTS AND MITIGATION

MEASURES

Impact identification has been carried out for various activities involved in

construction as well as operational phase of the project and prediction

has been done for significant impacts. The summary of anticipated

adverse environmental impacts due to proposed project and mitigation

measures is given below.

11.3.1 Summary of impacts on Air Environment:

(a) During construction phase & Mitigation measures

Main sources of impact during construction phase are due to movement

of vehicles & construction equipment at site, foundation works,

transportation of construction material etc. Water sprinkling in the vicinity

of the construction area will be done to control dust. PUC certified

vehicles will be used. Temporary barricades will be provided to reduce

spreading of particulates from construction area.

(b) During operation phase & Mitigation measures

Flue gas emission will be from stack attached with boilers, Thermic Fluid

Heater and Hot Air Generators, where Coal will be used as a fuel; and

standby D.G. Set (500 KVA). Most probable pollutants will be SPM, SO2

and NOx. Cyclone & bag filter will be installed as APCM.

Process emission will be from the reaction vessels of Multipurpose Plant,

Reaction Vessels of Chloranil and one vent of Spray Dryer. Corresponding

pollutants will be SO2, HCl and PM. To control the process emission, water



and alkali scrubber will be provided. Spray Dryer will be equipped with

Cyclone + Scrubber + Submerged type gas bubbling tank.

Prediction of impacts on air environment is quantified using ISCST3

model. Maximum Ground level concentrations of 24-hr average for SPM,

SO2, NOX & HCl are found 4.161 g/m3, 3.154 g/m3, 1.702 g/m3 and

0.099 g/m3, respectively. These GLCs are expected to occur at a

distance of 1.0 km from the source in E direction. The obtained GLCs are

well within the 24-hourly ambient air quality standards stipulated by

CPCB. Unit will provide adequate stack height for proper atmospheric

dispersion as per the norms.

11.3.2 Summary of impacts on Water Environment

(a) Impacts during construction phase & Mitigation measures:

Temporary impacts are likely to occur due to water consumption &

sewage generation. It will not be significant as water requirement would

be temporary during construction phase. Proper sanitation facilities with

adequate disposal system will be provided within the operational plant.

(b) Impacts during operation phase & Mitigation measures:

Fresh water requirement of the unit will be satisfied from bore well. Total

water requirement (Industrial + Domestic + Greenbelt) will be 178 KLD;

out of which 103 KLD will be fresh water requirement & 75 KLD will be

recycle/treated water (RO permeate).

Total industrial w/w generation will be 125 KLD. The wastewater

generated will be segregated into two streams for treatment. Process

effluent from Dye Intermediates plant (48 KLD) will be treated in “ETP-1”.

Then it will be sent to Common Spray Drying facility for evaporation at

Chhatral Environment Management System Pvt. Ltd. Wastewater from

Dyes plant, Scrubber, Washing and utilities (cooling & boiler) (77 KLD)

will be treated in “ETP-2”. After treatment, it will be passed through RO.

RO permeate (60 KLD) will be reused; RO reject (17 KLD) will be Spray

Dried along with effluent of ETP-1 (48 KLD) in common evaporation

facility. Domestic wastewater 7.5 KLD will be discharged into soak pit.



11.3.3 Impacts on Noise quality & Mitigation measures


During construction phase, major sources of noise are vehicle’s

movement & construction activities. High noise producing activities will be

restricted to daytime only. Well maintained equipments will be used to

prevent noise. Usage of PPE by workers will be made compulsory.


During the operation phase, the noise levels may increase due to the

operation of boilers, reactors, D.G. sets and other machineries. The

impact is found to be insignificant outside the premises. Unit will provide

necessary PPEs like earplugs or earmuffs to all workers where exposure is

85 dB(A) or more. Selection of any new plant equipment will be made

with specification of low noise levels.

11.3.4 Summary of Impacts on Land Environment


The construction activities like excavation, leveling & vehicular

movements will change the landscape, which are expected to be of short

duration & insignificant. Preliminary activities like proper storage of

construction materials & proper management will be done within the

project area. Therefore, impact will be negligible. Unit will provide

sanitation facilities for the staff engaged in construction work which will

prevent the impacts on land.


Hazardous wastes will have significant negative impacts if disposed

unsystematically. Unit has provided all required structural facilities like

separate hazardous waste storage room with RCC floor, leachate

collection system, and concrete floors within premises. Hence, no

significant negative impact is envisaged on the land environment.

11.3.5 Summary of impact on Socio Economy


As this is a Greenfield project, workers for the construction work will be

required. Local contractors to be employed for construction, so no other

issues like social conflict are envisaged.



Temporary employment generated during construction of project will

have beneficial impacts on economic environment.


Project will require about 100 persons for its operation, which result into

a positive impact on prevailing socio-economic environment. Project will

also have potential of indirect employment due to the increase

transportation activities, contractual works as well as opportunity of

trade. Thus, overall impacts on socio-economic environment are long

term and positive in nature.

11.3.6 Summary of impact on Ecology

There are no protected areas like National Park/Wildlife Sanctuary within

the 10 km radial periphery of the project site so there will not be any

significant impact on ecology.

11.4 ENVIRONMENT MONITORING PROGRAMME

The unit will have dedicated Environment Management Cell to monitor

and evaluate the environmental performance and to supervise the EMS.

Below Post-project monitoring programme will be followed.

Environment Monitoring Program

Nature of

Analysis

Frequency of

analysis

Parameters No. of samples

Wastewater

analysis

Monthly by external

agency

pH, TDS, SS,

COD, BOD, Oil &

Grease, etc.

2-3 samples

Stack Monitoring Monthly by external

agency

PM, SO2, NOX, HCl All stacks

Ambient Air

Quality

Monitoring

Monthly for 24 hours

or as per the

statutory conditions

by external agency

PM10, PM2.5, SO2,

NOX, HCl

3-5 locations

Noise level Monthly as per the

statutory conditions

by external agency


Nr. boiler, Nr. D.

G. Set, Process

area etc.)

Work zone

fugitive

monitoring

Monthly by external

agency

RPM, acid mist 2-3 locations

Health check-up

of workers

As per the statutory

guideline

All workers



11.5 ADDITIONAL STUDIES

11.5.1 Risk Assessment

Risk analysis and study have been carried out for identification of

accident hazards, selection of credible scenarios, Risk Mitigation

measures etc. All the hazardous chemicals will be stored and handled as

per MSDS guidelines. The detail study is prescribed in Chapter-7.

11.6 PROJECT BENEFITS

Proposed project has a potential for employment of skilled, semi-skilled &

unskilled employees. The direct employment potential is estimated as

100 persons and many others will be indirectly employed. Indirectly, the

proposed project will help the Government by paying different taxes from

time to time, which is a part of revenue and thus, will help in developing

the area. The company has allocated a budget of Rs. 16.0 Lakhs for CER

activities, which can lead to improve social infrastructure.

11.7 ENVIRONMENTAL MANAGEMENT PLAN

Management plan of impacts identified is detailed below:

Air Pollution Management

Cyclone & bag filter will be installed as APCM to control flue gas emission.

To control the process emission, water and alkali scrubber will be

provided. Spray dryer will be equipped with Cyclone + Scrubber + Sub

merged type gas bubbling tank. D.G. set is not the continuous source of

emission hence no appropriate stack height and SMF will also be provided

as per the guideline. To control the fugitive emission, following mitigation

measures will be adopted: • Regular maintenance of valves, pumps and other equipment will be

done to prevent leakages.

• Regular maintenance of air pollution control equipments.

• Mechanical seals will be provided to all the reactors.

• Regular periodic monitoring of work area to check the fugitive

emission.

Water Pollution Management

• Industrial wastewater will be treated in ETP followed by RO and send

to common spray drying facility.

• RO permeate will be reused within the premises.



• Unit will maintain the records for the total water consumption.

• Regular monitoring of working of ETP, RO.

• Rain water harvesting will be done.

Hazardous Waste Management






Spent Sulphuric acid, Acetic Acid, Sodium Bisulphite will be reused within

the process or sold to actual users. Spent catalyst will be sent for

regeneration to the suppliers. Discarded containers/liners will be disposed

of by selling to registered recyclers; used lubricating oil will be sold to

registered recyclers. Fly ash will be sold to brick manufacturers. The unit

will provide isolated area with impervious flooring & roof cover for the

storage of hazardous waste. There will not be any major impact on the

environment due to hazardous waste management.

Noise Pollution Management

• Extensive oiling, lubrication and regular maintenance will be carried

out for the machineries and equipments to reduce noise generation.

• PPEs will be provided to the workers working in high noise area.

• Acoustic enclosure will be provided to D.G. set.

• Greenbelt will be developed within industrial premises to prevent the

noise pollution.

• Periodic monitoring of noise levels will be done.

Green Belt Development

Total land area is 5662 m2. The unit will develop greenbelt in an area of

1870 m2. Overall greenbelt area will be more than 33% of the total area

of the project.

11.8 CONCLUSION

Based on the study it is concluded that-

There will be no major impact on water environment as – (1) Effluent

of Dye Intermediates plant will be treated in “ETP-1” and send to

Common Spray Drying facility for evaporation. (2) Effluent from Dyes



plant, Scrubber, Washing and utilities (cooling & boiler) will be treated

in “ETP-2” and then passed through RO. RO reject will be Spray Dried

along with effluent of ETP-1 in common evaporation facility.

RO permeate will be reused/recycled within plant premises. Thus,

reducing fresh water consumption.

Domestic effluent will be disposed to soak pit though septic tank.

Cyclone and bag filter will be used as pollution control equipments for

control of flue gas emission.

Water scrubber and Alkali scrubber will be installed as pollution control

equipments for process emission from the unit.

Spray Dryer will be equipped with Cyclone + Scrubber + Submerged

type gas bubbling tank.

Fugitive emission will be controlled by close material handling system

and proper storage of materials.

For noise control, unit will provide necessary PPEs like earplugs or

earmuffs to all workers and selection of any new plant equipment will

be made with specification of low noise levels.

Entire quantity of hazardous waste will be handled and disposed as per

Hazardous & Other Waste (Management & Transboundary Movement)

Rules, 2016.

Greenbelt will be developed in 33% of the total area.

Fire protection and safety measures will be provided.

Direct and indirect employment opportunities will have positive

impact.



Chapter-12

Disclosure of Consultant engaged

12.1 PREFACE

San Envirotech Pvt. Ltd. (SEPL) has been appointed by Urmit Chemicals

Pvt. Ltd. to carry out this Environmental Impact Assessment Study as

per the EIA notification, 2006 as amended till date. SEPL is accredited as

Category-A organization under the QCI-NABET Scheme for

accreditation of EIA consultant Organizations: Version 3 for preparing

EIA-EMP reports in 10 sectors (Certificate No. NABET/EIA/

1619/RA0084; Valid till 23.12.2019).

12.2 DETAILS OF EIA CONSULTANT ORGANIZATION

San Envirotech Pvt. Ltd. has started its work in 1990 to serve the

environment as a trustee of next generation with a small infrastructure

under the dynamic leadership of Dr. Mahendra Sadaria. SEPL has wide

spectrum of national and multinational clients covering the industries -

Bulk Drugs and Pharmaceuticals, Dyes and Dye Intermediates, Pesticides,

Fertilizers, Chemicals, Cement, Mining, and Infrastructure. During last

two decades, SEPL has been taking care of client’s unique problems and

concerns in order to develop cost effective strategies to meet their

regulatory obligations. SEPL focuses on strategic planning and

comprehensive solutions to address both short and long term needs of

the clients.

SEPL has in-house multi-disciplinary analytical testing laboratory that is

MoEF&CC approved under EP Act. SEPL is also a recognized schedule-II

Environmental Auditor appointed by Gujarat Pollution Control Board as

per the directives of the Honorable High Court of Gujarat. SEPL is also an

ISO 9001:2008, 14001:2008 and OHSAS 18001 certified company. SEPL

team consists of qualified & experienced personnel. Experts involved in

the preparation of this EIA/EMP report are given in EIA report as

‘declaration by experts’.

Annexure-I NABET-QCI Certificate

Annexure-II Manufacturing process, Chemical Reaction &

Mass Balance of all products

Urmit Chemicals Pvt. Ltd. A-2

Manufacturing Process, Chemical Reaction & Mass Balance of all products

(A) Dye Intermediates

1. Chloranil

Manufacturing Process:

Hydroquinone and HCl (30%) are charged in the reactor, Mixture is heated

up to 700C. Reaction mixture is cooled down to the 300C, and sent to

Agitated Notch filter, filtered mass is washed by water, mother liquor sent

ETP. Wet Cake is dried to obtain finished product.

Chemical Reaction:

+ Cl2 =========

Mass Balance:

INPUT KG OUTPUT KG

HCl 30% (SPENT) 1000

Hydro quinone 450 HCl Gas 370

Chlorin Gas 1136

Effluent 616

Water 250

Drying loss 850

Chloranil 1000

Total 2836 2836

Nutch Filter

Drying

Mass Balance of Chloranil

Chlorination




Take Ortho Nitro Chloro Benzene (ONCB), water, caustic flakes and heat

the mass to bring the pressure up to 3 atmospheres. ONCB gets converted

into Ortho Nitro Phenol (ONP). Remove the product by layer separation.

Take ONP in hydrogenator, remove oxygen through flushing of N2 gas and

after that pass H2 gas at temperature 800C and 8 to 10 kg pressure in

presence of Catalyst. ONP gets converted into Para Amino Phenol (PAP).

Distill out the product and wash and centrifuge for final packing and

dispatch.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

ONCB 1480

Caustic Lye 850

Water 2500

H2 Gas 60

Catalyst 4

Catalyst for reuse 4

HCl 40 Waste Water 5070

Water 2030

Drying loss 890

Ortho Amino Phenol 1000

Total 6964 6964

Drying &

packing

Mass Balance of OAP (Ortho Amino Phenol)

Hydrolysis

Hydrogenation

Precipitaion &

Filteration

Clarification




Take Para Nitro Chloro Benzene (PNCB), water, caustic flakes and heat the

mass to bring the pressure up to 3 atmospheres. PNCB gets converted into

Para Nitro Phenol (PNP). Remove the product by layer separation. Take

PNP in hydrogenator, remove oxygen through flushing of N2 gas and after

that pass H2 gas at temperature 800C and 8 to 10 kg pressure in presence

of Catalyst. PNP gets converted into Para Amino Phenol (PAP). Distill out

the product and wash and centrifuge for final packing and dispatch.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

PNCB 1480

Caustic Lye 850

Water 2500

H2 Gas 60

Catalyst 4

Catalyst 4

HCl 40 Waste Water 5020

Water 2030

Drying loss 940

Para Amino Phenol 1000

Total 6964 6964

Drying &

packing

Mass Balance of PAP (Para Amino Phenol)

Hydrolysis

Hydrogenation

Precicpitation &

Filteration

Clarification




Charge in vessel caustic lye/flakes, Metanilic acid Powder/Liquid and heat

up to 2500C to 2600C under string and after complete reaction, charge

water and make slurry of reaction mass and transfer to isolation vessel.

Take slurry in isolation vessel and isolate material with Ice and slowly add

Hydrochloric acid in it to isolate material, after complete isolation do

centrifuge and then transfer for Drying. Take Centrifuge wet cake for

Drying and pack Meta Amino Phenol. Generated waste water from

centrifuge will transfer to ETP for treatment.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

Metanilic Acid 1590

NaOH 750

Catalyst 4

Water 3000

Catalyst 4

Waste water 3390

Drying loss 950

Meta amino phenol 1000

Total 5344 5344

Fusion Reaction

Clarification

Precicpitation &

Filteration

Drying &

Packing

Mass Balance of MAP (Meta Amino Phenol)


5. Ortho Amino Phenol Sulphonic Acid


Sulphonation: Take H2SO4 - 98% then charge Oleum 23% and start

chilling get temperature 40 to 45⁰C then charge OAP between 40 to 45⁰C

with 6 hrs. After charging, start heating and maintain 4 hrs. with

temperature 90 to 95⁰C. Then check TLC with OAP and OAPSA and check

Acidity (Range 79 to 82%). If TLC is not OK then maintain temperature 90

to 95⁰C for 2 hrs. Transfer in dumping vessel.

Dumping: Take water and charge Ice in 2 hrs. Then charge Sulpho mass

slurry slowly addition with temperature 40 to 45⁰C. Maintain with free

string 2 hrs. Check filter loss (0.8% to 1%). After testing start nutch filter.

Suck the M/L start centrifuge. Start crushing and packing.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

OAP 580

H2SO4 520

Oleum 23% 425

Water 4200 Spent Acid(35-40%) 2125

Waste water 1750

Drying loss 850

OAPSA 1000

Total 5725 5725

Sulphonation

Filteration

Drying &

Packing

Mass Balance of Ortho Amino Phenol Sulphonic Acid (OAPSA)


6. Metanalic Acid


Sulfonation: Nitrobenzene is sulfonated with 65% oleum at various

temperatures to yield Nitrobenzene 2 Sulphonic Acid.

Drowning: SulphonicAcid mass is drowned in water and excess acid is

neutralized using lime stone and soda Ash to pH- 7.5-8.0.

Filtration: The nitro mass is filtered and washed to get gypsum as

byproduct and nitro solution.

Reduction: The nitrobenzene sulfonic acid is reduced using iron and

hydrochloric Acid to yield metanilic Acid.

Filtration: The reduction mass is filtered to remove the iron sludge.

Isolation: The reduction mass is isolated using diluting sulfuric acid to

yield Metanilic acid. This is then filtered, washed and dried.

Chemical Reaction:

Mass Balance:

Input KG Output KG

Nitro benzene 720

Oleum (25%) 425

H2SO4 520


HCl (30%) 100

Iron Powder 125 Iron Sludge 350

Water 2000

Waste water 1320

Drying loss 870

Metanilic Acid 1000

Total 5390 5390

Mass Balance of Metanilic Acid

Filtration

Drying

Filtration

Sulfonation

Reduction &

Clarification




Charge ONCB, Sulphuric acid and Oleum are added into reactor then it is

filtered. Then iron powder is added into vessel along with hydrochloric acid

and mass is clarified then it is filtered and waste water is sent into ETP.

Product is sent into dryer for drying.

Mass Balance:

Input KG Output KG

ONCB 920

H2SO4 520

Oleum 425


Iron Powder 125

HCl 100 Iron Sludge 350

Water 2000

Waste water 1525

Drying Loss 925

6 Chloro Metanilic Acid 1000Drying

Mass Balance of 6 Chloro Metanilic Acid

Sulfonation

Filtration

Reduction &

Clarification

Filtration


8. 4-Chloro 2-Amino Phenol


2, 5 Dichloro Nitro Benzene, Caustic soda flakes & Water is charged in the

reactor. Reaction mass is charged along with Soda ash, Iron powder, HCl,

Sodium Bicarbonate & Water in vessel after filtrate the reaction mass. HCl

is added to reduce the pH of mass up to 2.5. Lime and caustic soda is

added for the neutralization the mass. Iron sludge is separated from slurry

during filtration. Isolation, Centrifuging and Drying steps are carried out to

get the product.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

2:5 DCNB 1350

Caustic 300

Water 2000

Iron powder 125

HCl 100 Iron Sludge 350

Waste Water 1775

Drying Loss 750

4 CAP 1000

Total 3875 3875

Drying &

Packing

Nutch Filter

Mass balance of 4-Chloro 2-Amino Phenol (4 CAP)

Hydrolysis

Reduction &

Clarification




For manufacturing of 4-Chloro-2-Amino Phenol-5-Sulphonic Acid, the raw

material, 4-Chloro-2-Amino Phenol is subjected to Sulphonation reaction

by Sulphuric Acid and Oleum at desired reaction temperature. Sulphonated

mass is then drowned in salt solution. Then the mass is filtered in nutch

filter followed by centrifuge filter. Mother Liquor is collected in Mother

Liquor Storage Tank and the product in the form of filtrate is packed for

dispatch.

Chemical Reaction:

++ H2S2O7

OH

H2SO4

NH2

Cl

OH

Cl

SO3H

NH2

Mass Balance:

INPUT KG OUTPUT KG

4 CAP 650

Sulphuric Acid 520

Oleum 425


Waste Water 825

Drying Loss 850

4 CAPSA 1000

Total 4095 4095

Mass balance of 4 Chloro-2-Amino Phenol 5-Sulphonic Acid (4 CAPSA)

Drying &

Packing

Sulphonation

Nutch Filter


10. 4 Nitro 2 Amino Phenol


Step-I: Preparation of Calcium Polysulfide

Calcium oxide along with water is charged into M.S. jacketed reactor-I and

heated up to 800 C. Sodium Hydro sulfides & Sulphur powder are added & entire

mass is known as Calcium Polysulfide.

Step-II: Preparation of Phenolate

Caustic soda lye and 2:4 Di Nitro Chloro Benzene is taken in the M.S. jacked

reactor-II & temperature is increase up to 700C. As entire process is being

exothermic, temperature of the reaction mass is automatically up to 85-90°C.

Sulphuric Acid is added for the neutralization of excess alkali. The neutralized

mass is known as phenolate.

Step-III: Hydrolysis of 2:4 DNCB

Reduction of sodium Di Nitro Phenolate is carried out by Calcium Poly sulfide

solution in brick lined reactor at 800C & this temperature is maintained for 10

hrs.

Step-IV: Isolation & Filtration

After completion of the reaction, common salt is added for the isolation &

mixture is cooled up to 300C. Entire mass is Filtered into Nutch and centrifuged.

Mass Balance:

INPUT KG OUTPUT KG

NaSH 515

Lime 220

Water 500

2:4 DNCB 1400

NaOH 300

Water 1000

Calcium Thio Sulphite 635

Waste Water 1500

Drying Loss 800

4 NAP 1000

Total 3935 3935

Drying &

Packing

Mass balance of 4 NAP

Hydrolysis

Reduction &

Clarification

Nutch Filter

Calcium

Polysulphide




OAP along with water is charged into M.S. jacketed reactor-I and Heated

up to 800C. And Acetic Anhydride is added into vessel. The nitric acid is

added. And further hydrolyzed by hydrogen gas. Then the wet product is

goes into nutch filter and waste water is sent into ETP. And product is sent

into spray dryer.

Mass Balance:

INPUT KG OUTPUT KG

OAP 725

Acetic Anhydride 675

Water 1500

HNO3 450

H2SO4 850

H2 Gas 80 Acetic Acid 800

Waste Water 1690

Drying Loss 790

5 NAP 1000

Total 4280 4280

Drying &

Packing

Mass balance of 5 NAP

Acetylation

Nitration

Hydrolysis

Nutch Filter




Sulphonation: Take 98% H2SO4 then charge 23% Oleum and start chilling

get temperature 20 to 30°C check TLC with OAP and OAPSA and check

Acidity (Range 79 to 82). If TLC is not OK then 2 hrs maintain temperature

100 to 105°C. Transfer in nitration vessel.

Nitration: Collect Sulpho mass and start chilling get temperature 15 to

20°C and 6 hrs. Then start WNA 68% with addition between temperatures

15 to 20°C 650 kg in 36 hrs. Maintain with free string 2 hrs then check

AR/BR (0.3% to 0.55% different). If AR/BR different more than 0.55%

charge WNA and again check AR/BR different. Transfer in dumping vessel.

Dumping: Charge Ice approximately 4500 kg in 2 hrs. Then charge Nitro

mass slurry. Slowly addition with temperature 5 to 10°C. Maintain with

free string 2 hrs. Check filter loss (1.5% to 2.5%).After testing start press

filter/nutch filter. Suck the M/L start centrifuge. Start crushing and

packing.

Mass Balance:

INPUT KG OUTPUT KG

OAP 470

Oleum (23%) 800

Water 1750

HNO3 270

H2SO4 550

Waste Water 2030

Drying Loss 810

6 NAPSA 1000

Total 3840 3840

Filteration

Drying &

Packing

Mass balance of 6 NAPSA

Sulphonation

Nitration




p-Nitro Chlorobenzene is Sulphonated with Oleum (23%) & Sulphuric acid

followed by nitration with Nitric acid to get 2-chloro-3,5-dinitro benzene

sulphonic acid. The above product is hydrolyzed in alkaline medium &

partially reduced by adding NaHS to get 4-NAPSA (Na salt). Filter it and

C/F. Dissolve the 4-NAPSA (Na salt) in Sulphuric Acid and clarify through

filter press & isolated by Sulphuric acid, filter and centrifuge to get pure 4-

NAPSA.

Mass Balance:

Input KG Output KG

Lime 220

NaSH 515

Water 800

4 Nitro Chloro Benzene 700

Oleum 800

HNO3 270

H2SO4 550

Calcium Thio Sulphide 635

Waste Water 1350

Drying Loss 870

4 NAPSA 1000

Total 3855 3855

Reduction &

Clarification

Nutch Filter

Drying &

Packing

Nitration

Mass balance of 4 NAPSA

Sulphonation

Calcium

Polysulfide


14. 6-Chloro-2-Amino Phenol-5-Sulphonic Acid (6 CAPSA)


2 Chloro Phenol along with Oleum is charged into reactor and Heated up to

800C. The nitric acid is added during nitration process. And then it goes

into reduction where iron powder is added along with HCl. Then the wet

product is goes for filtration and waste water is sent into ETP. And product

is sent into for drying.

Mass Balance:

INPUT KG OUTPUT KG

2 Chloro Phenol 580

Oleum 800

HNO3 270

H2SO4 550

Iron Powder 125 Iron Sludge 350

HCl 100

Water 1000

Waste Water 1175

Drying Loss 900

6 CAPSA 1000

Total 3425 3425

Drying &

Packing

Mass balance of 6 CAPSA

Sulphonation

Nitration

Reduction &

Clarification

Filteration


15. 2 Pyridone


In the reactor mono ethyl amine and Methyl Cyno Acetate is added for

condensation. Then mass is further condensate by Methyl Aceto Acetate

Ester. Mass is sent for hydrolysis where it is hydrolyzed by Sulphuric acid.

Then filter is sent into washing and filtration. Waste water is sent into ETP.

And then product is charged into dryer.

Mass Balance:

INPUT KG OUTPUT KG

Mono Ethyl Amine 400

Methyl Cyno Acetate 525

Methyl Aceto Acetate Ester 660

H2SO4 3600


Waste Water 1725

Drying Loss 910

2 pyridone 1000

Total 8635 8635

Filteration &

washing

Drying &

Packing

Mass balance of 2 Pyridone

Condensation

Condensation

Hydrolysis




Take water and Oleum in the vessel and then add slowly Aniline. Then

diazotize it with sodium nitrite at 00C. Pour diazo for neutral reduction into

solution of SBS and soda ash. Heat at 800C and carry out hydrolysis by

HCl. Then do formation of hydrazine with M.A.A Ester. Then isolation with

HCl. Then cool it down and filter out the material.

Mass Balance:

INPUT KG OUTPUT KG

Aniline 435

HCl 700

NaNO2 330

Ice 500

Water 500

Sodium Bi Sulphite 1160 SO2 Gas to Scrubber 700

Soda Ash 1550

HCl 4000

Methyl Aceto acetate

ester 525

Water 1800

Waste water 9050

Drying loss 750

PMP 1000

Total 11500 11500

Washing

Filtation &

Centrifuge

Drying &

Packing

Mass balance of 1:3 Phenyl Methyl 5 Pyrazolone (PMP)

Diazotization

Reduction

Hydrolysis

Condensation




Take water and Oleum in the vessel and then add slowly S. Acid. Then

diazotize it with sodium nitrite at 00C.Pour Diazo for neutral reduction into

solution of SBS and soda ash. Heat at 800C and carry out hydrolysis by



Mass Balance:

INPUT KG OUTPUT KG

Sulfanlic Acid 536

HCl 500

NaNO2 218

Ice 500

Water 500

SBS 804 SO2 Gas to scrubber 485Soda Ash 1035

HCl 2642


Water 860

Waste Water 5507

Drying Loss 950

1:4 SPMP 1000

Total 7942 7942

Filtation

Drying &

Packing

Mass Balance of 1,4 Sulpho Phenyl-3-Methyl-5-Pyrazolone (1:4 SPMP)

Diazotization

Reduction

Hydrolysis

Condensation

Washing




Take water and Oleum in the vessel and then add slowly 2.5 Dichloro

Aniline. Then diazotize it with sodium nitrite at 00C. Pour diazo for neutral

reduction into solution of SBS and soda ash. Heat at 800C and carry out

hydrolysis by HCl. Then do formation of hydrazine with M.A.A Ester. Then

cool it down and filter out the material.

Mass Balance:

INPUT KG OUTPUT KG

2,5 Dichlror Aniline 500

HCl 500

NaNO2 221

Ice 500

Water 500

SBS 696

Soda Ash 500 SO2 Gas 416Caustic Soda Lye 714

HCl 1107


Water 5739

Waste water 8950

Drying loss 950

2,5 DCSPMP 1000

Total 11316 11316

Filtration

Drying &

Packing

Mass Balance of 2,5 Dichloro 4 Sulfo Phenyl 3 Methyl 5 Pyrazolone(DCSPMP)

Diazotization

Reduction

Hydrolysis

Condensation

Washing


19. 2 Chloro 5 Sulphophenyl 3 Methyl 5 Pyrazolone (2:5 CSMP)


Take water and Oleum in the vessel and then add slowly 6 Chloro Metanilic

Acid. Then diazotize it with sodium nitrite at 00C. Pour diazo for neutral



isolation with HCl. Then cool it down and filter out the material.

Mass Balance:

INPUT KG OUTPUT KG

6 Chloro Metanilic Acid 750

HCl 600

NaNO2 265

Ice 500

Water 500

SBS 1150

Soda Ash 850 SO2 Gas 690

Caustic Soda Lye 450

HCl 1800


Water 1600

Waste water 6315

Drying loss 880

2,5 CSMP 1000

Total 8885 8885

Filtration

Drying &

Packing

Mass Balance of 2 Chloro 5 Sulphophenyl 3 Methyl 5 Pyrazolone

Washing

Diazotization

Reduction

Hydrolysis

Condensation




Take water and Oleum in the vessel and then add slowly Metanilic Acid.

Then diazotize it with sodium nitrite at 00C.Pour diazo for neutral reduction

into solution of SBS and soda ash. Heat at 800C and carry out hydrolysis by



Mass Balance:

INPUT KG OUTPUT KG

Metanilic Acid 536

HCl 600

NaNO2 217

Ice 500

Water 500

SBS 800 SO2 Gas 480

Soda Ash 1035

HCl 1540


Water 850

Waste water 4534

Drying loss 910

1,3 SPMP 1000

Total 6924 6924

Filtration

Drying &

Packing

Mass Balance of 1, 3 Sulpho Phenyl 3 Methyl 5 Pyrazolone (1:3 SPMP)

Diazotization

Reduction

Hydrolysis

Condensation

Washing


21. 2 Chloro Phenyl 3 Methyl 5 Pyrazolone (2 CPMP)


Take water and Oleum in the vessel and then add slowly Ortho Chloro

Aniline. Then diazotize it with sodium nitrite at 00C.Pour diazo for neutral



isolation with HCl Then cool it down and filter out the material.

Mass Balance:

INPUT KG OUTPUT KG

Ortho Chloro Aniline 500

HCl 600

Sodium nitrite 275

Ice 500

Water 500

Sodium Bi Sulphite 972 SO2 Gas 560Soda Ash 1311

HCl 2380

Methyl Acetoacetic Ester 410

Water 1352

Waste water 6400

Drying loss 840

2 CPMP 1000

Total 8800 8800

Filtation

Drying &

Packing

Mass Balance of 2 Chloro Phenyl 3 Methyl 5 Pyrazolone

Diazotization

Reduction

Hydrolysis

Condensation

Washing




Take water and Oleum in the vessel and then add slowly Para Toludine.

Then diazotize it with sodium nitrite at 00C.Pour diazo for neutral reduction

into solution of SBS and soda ash. Heat at 800C and carry out hydrolysis by



Mass Balance:

INPUT KG OUTPUT KG

Para Toludine 415

HCl 600

NaNO2 270

Ice 500

Water 500

Sodium Bi Sulphite 965 SO2 Gas to scrubber 570Soda Ash 1300

HCl 2350

Methyl Acetoacetic Ester 435

Water 1335

Waste water 6195

Drying loss 905

PTPMP 1000

Total 8670 8670

Filtation

Drying &

Packing

Mass Balance of Para Toluene Phenyl Methyl 5 Pyrazolone

Diazotization

Reduction

Hydrolysis

Condensation

Washing


(B) Dyes

1. Acid Yellow 79


Diazotization of DAP Ester in by Nitrosyl Sulphuric Acid, coupling with 5-

Amino-3-methyl-1-(3-sulfophenyl) Pyrazole, Filter the solution, collect wet

cake and dry in oven.

Mass Balance:

INPUT KG OUTPUT KG

DAP ESTER 400

H2SO4 540

Soda ash 250

Ice 1000

Water 1500

5-Amino-3- methyl-1-

(3-sulfophenyl)

pyrazole

390

Caustic flakes 60

Ice 1000

Common Salt 650 Wastewater 3900

Drying Loss 890

Acid Yellow 79 1000

Total 5790 5790

Drying &

packing

Diazotization

Coupling

Isolation &

Filteration

Mass Balance of Acid Yellow 79


2. Acid Yellow 151


Prepare Diazo of OAPSAAmide in vessel with sodium nitrite & HCl

(Hydrochloric Acid). After that charge Acetoacitanilide in the vessel for

coupling. Metallize the mass by adding cobalt sulphate & sodium

hydroxide. Now, reaction mass transferred for spray drying to got finished

product.

Mass Balance:

Input Kgs Reaction OutPut Kgs

OPSAmide 500

Hydrochloric Acid 112

Sodium Nitrite 184

Ice 1400

Water 1000

Aceto Acetanilide 483

Caustic Lye 125

Soda Ash 250

Ice 500

Water 1000

Cobalt Sulphate 415

Caustic Lye 85

Steam 800


Drying Loss 910

Acid Yellow 151 1000

Total 7504 7504

Isolation

&Filteration

Drying & packing

Mass Balance Acid Yellow 151

Coupling

Cobaltination

Diazotization


3. Acid Yellow 49


Prepare diazo of 2, 5 Dichlorosulphanilic acid in vessel with sodium

nitrite & HCl (Hydrochloric acid) & apply heating.

After cooling, charge 5, amino-3-methyl-1-phenyl Pyrozolone in the

vessel for coupling.

Now reaction mass transferred for filtration & after that wet cake is

dried to got Finished product.

Mass Balance:

INPUT KG OUTPUT KG

2, 5 Dichloro

Sulfanilic Acid 500

HCl 325

Sodium Nitrite 155

Water 1200

Ice 900

5-Amino PMP 400

HCl 475

Ice 600

Salt 125Water 800

Common Salt 650 Waste Water 4180

Drying Loss 950

Acid Yellow 49 1000

Total 6130 6130


Diazotization

Coupling

Isolation &

Filtration

Drying &

Packing


4. Acid Yellow 99


Diazotisation of 4-NAPSA, coupling with Acetoacetanilide, metallisation with

Basic Chromium Sulphate. Filter it and collect wet cake and dry it.

Mass Balance:

INPUT KG OUTPUT KG

4 NAPSA 285

HCl 110

Nitrite 85

Ice 1400

Water 1400

Acetoacetinilide 222

Caustic Flakes 52

Soda Ash 135

Ice 500

Water 1000

Salicylic Acid 185

BCS 380

Caustic Flakes 145

Steam 800


Drying Loss 1060

Acid Yellow 99 1000

Total 7249 7249


Diazotization

Coupling

Isolation &

Filtration

Drying &

Packing

Chromination


5. Acid Yellow 194


Prepare 4-NAPSA diazo with help of Hydrochloric acid and sodium nitrite in

presence of ice to maintain temp. Make clear solution of AAA with help of

caustic lye. 4-NAPSA diazo coupled with AAA in alkaline medium and then

metallization with cobalt sulphate at 80-900C for 3-4 hr. When test is OK.

Spray dry the above reaction mass.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

4-NAPSA diazo 550

HCl 430

sodium nitrite 165

Ice 1000

water 1500

Acetoacetanilide 435

Water 700

Ice 1000

Caustik Lye 100

Cobalt Sulphate, 20% 325

Water reuse 2605

Drying Loss 2600


Total 6205 6205

Standardization &

Packing

Reverse Osmosis


Preparation of 4-

NAPSA diazo

Coupling in

alkaline medium

Metallization

Spray Drying

OHSO3H

NH2

NO2

HCl + NaNO2OHSO3H

N=N-Cl

NO2

+ Aceto AcetanilideOH SO3H

NO2

N=NCH

C

O

NH Ph

C

O

CH3

+ Cobalt Sulphate CoSO4.7H2O

NO2

SO3HO

N=NCH

C

O

-Ph HN

C

CH3 O

Co

OSO3H

NO2

N=N HC C

C

O

- CH3

O

NHPh

Acid Yellow 194


6. Acid Yellow 220


Diazotization of Anthranilic OPSAMIDE and Sodium Nitrite, coupling with O-

Cl-Acetoacetanilide with Cobalt Sulphate. Clarify solution; filter and dry it.

Mass Balance:

Input Kgs Reaction OutPut Kgs

Anthranilic OAPSA 500

HCl 87

Nitrite 112

Ice 1600

Water 1000

O Cl Acetoacetinilide 350

Caustic Flakes 70

Soda Ash 240

Ice 500

Water 1000

Cobalt Sulfate 230

BCS 50

Steam 800

Water reuse 2339

Drying Loss 3200


Total 6539 6539

Spray Drying &

Packing

Reverse Osmosis

Mass Balance Acid Yellow 220

Diazotization

Coupler Solution

Cobaltination


7. Acid Yellow 232


Diazotisation of 5-sulfo anthranilic acid, coupling with 1-phenyl-3-methyl-5

pyrazolone, metallisation with Basic Chromium Sulphate. Chelating with

another monoazo dye produced from (Diazotisation of Anthranilic acid and

coupling with 1-phenyl-3-methyl-5-pyrazolone) Clarify solution, filter and

dry it.

Mass Balance:

INPUT KG OUTPUT KG

5 Sulfo Anthranilic Acid 233

Hydrochloric Acid 125

Sodium Nitrite 160

Ice 1000

Water 900

1-Phenyl 3 Methyl 5 Pyrozolone 410

Soda Ash 250

Ice 1000

Water 1000

Salicylic Acid 40

Basic Chromium Sulfate 400

Steam 800Sulphuric Acid 136

Water reuse 2554

Drying Loss 2900


Total 6454 6454

Spray Drying


Diazotization

Coupling

Chromination

Reverse Osmosis


8. Acid Brown 75


H-Acid Diazotized with HCl & Nitrite at 0ºC temp. Stir 1-1/2” hours.

Coupling with resorcinol in alkaline medium and stir. After 2 hours Na

picramate diazo coupling with first coupling in alkaline medium stir 2 hours

After 2 hours PNA Diazo coupled with second coupling at 6.5 pH, stir 6

hours then filter and dry it.

Chemical Reaction:

H-Acid Diazo

Diazo Coupling with Resourcinol

II Coupling with Na Picramate Diazo

PNA Diazo

III Coupling


Mass Balance:

INPUT KG OUTPUT KG

Picramic acid 192

Hydrochloric acid 250

Ice 500

water 1000

Sodium Nitrite 95

Caustic lye 50

Resorcinol 96

Ice 500

H-Acid 278

Soda ash 346


Ice 500

Water 800

Sodium nitrite 85

Ice 500

caustic lye 40

PNA 113

Ice 500

Water 750

Sodium nitrite 85


Common Salt 550 Effluent 5305

Drying Loss 1350

Acid Brown 75 1000

Total 7655 7655

Drying &

Packing

Final Coupling

Mass Balance of Acid Brown 75

Preparation of

Sodium

Picramate

diazo

1 st Coupling

Preparation of

H Acid diazo

2 nd Coupling

Preparation of

PNA diazo

Isolation &

Filtration


9. Acid Brown 165


H-Acid Diazotized with HCl, Nitrite & Ice at 5ºC temp. Stir for 1-½ hours.

After 1-1/2 hour coupling with Resorcinol in alkaline Medium stirrer 2 hours

Na picramate Diazo coupling with first coupling in alkaline medium stirrer.

2 hours After 2 hours PNA Diazo coupled with second coupling at 6.5 pH

stirrer 6 hours. After 6 hours heat at 80ºC. Above couple mass metalized

with Ferrous Sulphate’s solution at 5.5 pH. Stir for 3 hour after 3 hour,

filter and collect W/C & dry it.

Chemical Reaction:

H Acid Diazo

H Acid diazo Coupling with resorcinol

II Coupling with Na Picramatediazo

PNA Diazo


III Coupling

Above Dye Metalized with Ferrous Sulphate

Mass Balance:

INPUT KG OUTPUT KG

Picramic acid 192


Ice 500

water 800

Sodium Nitrite 95

Caustic lye 50

Resorcinol 96

Ice 500

H-Acid 278

Soda ash 346


Ice 500

Water 800

Sodium nitrite 85

Ice 500

caustic lye 40

PNA 113

Ice 500

Water 750

Sodium nitrite 85


Water 450

Steam 600

Ferrous Sulphate 260


Drying Loss 1360

Acid Brown 165 1000

Total 8765 8765

Final Coupling

Isolation &

Filtration

Drying &

Packing

Metalization


Preparation of

Sodium

Picramate diazo

1 st Coupling

Preparation of H

Acid diazo

2 nd Coupling

Preparation of

PNA diazo


10. Acid Brown 161


Anthranilic Acid diazotized with HCl, Nitrite at 0°C temp. Stir for 1 hour,

and then couple with Resorcinol in alkaline medium at 50°C temp. Stir for

2 hours, then make diazo of Aniline 2:4 SO2H with HCl, Nitrite & Ice at 50C

temp. Stir for 1 hour then coupled with first coupling in alkaline medium.

Stir for 4 hours, Heat at 80°C then metalized with copper sulphate solution

at 80°C in alkaline medium. Stir for 4 hours, filter and Dry it.

Chemical Reaction:

Anthranilic condensation with Formaldehyde & make Diazo

Anthranilic Acid Dizo Coupling with Resorcinol

Aniline 2:4 Disulphonic Acid Diazo

II Coupling


Above Mono azo Metallized with copper Sulphate at 85ºC temp at

alkaline medium

Mass Balance:

INPUT KG OUTPUT KG

Anthranilic acid 190

Sulphuric acid 190

Formaldehyde 80

Nitrite 100

Ice 1000

Water 800

Resorcinol 170

Caustic Flakes 200

Ice 1000

Water 600

Aniline 2,4 SO3H 190

HCl 180

Sodium Nitrite 90

Ice 800

Soda Ash 350

Water 800

Salicylic Acid 50

B.C.S 200

Steam 800

Water reuse 3890

Drying loss 2900

Acid Brown 161 1000

TOTAL 7790 7790

Spray Drying


Condensation

& Diazotization

Ist coupling

Diazotization of

Aniline 2,4

SO3H

Chromination

RO/UF

Coupling


11. Acid Brown 282


6 nitro solution with ice coupled with beta naphthol solution in alkaline

medium. Stir for 2 hours, after 2 hours chromination with salicylic acid &

BCS at 95° - 100°C. Stir for 16 hours. Filter collect w/c. 4 Nitro Amino

phenol diazotized with HCl, nitrite at 0°C temp and coupled with PMP clear

solution at 5.5 pH and stir for 8 hours. In orange base solution charge

black base w/c. Heat 90°C and take pH 5.5. Maintain for 4 hour at 90°C &

pH + 5.5. If test ok then isolated with salt, collect w/c. make slurry &

spray dryer it.

Chemical Reaction:


Mass Balance:

INPUT KG OUTPUT KG

Stage I

6-Nitro 200

Ice 500

Water 750

Beta Napthol 100

Water 750

Ice 500

Caustik Flakes 50

Salicylic Acid 65

B.C.S. 180Steam 600

Watse water 2575

1120

Stage II

4NAP 175

Water 1200

HCl 33

Nitrite 95

Ice 750

Water 950PMP 200

Caustik Flakes 50

Drying Loss 3573

Acid Brown 282 1000

Total 7148 7148

Diazotization

Ist Coupling

Addition of W/C

Spray Drying


6 Nitro Slurry

1st Coupling

Chromination

Filteration

W/C


12. Acid Brown 432


Anthranilic Diazotized with HCl, Nitrite & Ice at 00C temp. Stir for 1 - 1/2

hours, Resorcinol Coupling with this Diazo in alkaline medium at 50C temp.

Laurent Acid Diazotized with HCl, Nitrite & Ice, at 50C temp. stir for 2 hour,

After 2 hour, this Diazole coupling with first coupling at Neutral pH at 70C

temp stirrer - 6 hour, After 6 hours, heat at 900C temp metalized with

salicylic acid chromium fluoride. If crimination tests ok, then clarify/R/o/

Spray Dryer it.

Chemical Reaction:

1. Anthranilic Acid Diazo

2. Ist Coupling with Resorcinol

3. Laurent Acid Diazo

4. IInd Coupling


5. Above metalized with salicylic acid & chromium fluoride

Mass Balance:

Input Kg Output Kg

Anthranilic Acid 180

HCl 85

Nitrite 85

Ice 1200

Water 2200

Resorcinol 150

Soda Ash 330

Ice 1100

Laurent Acid 300

HCl 125

Nitrite 95

Ice 700

Salicylic Acid 160

Chromium Fluoride 160

Liquid Ammonia 300

Steam 800

Caustic Flakes 30

Water reuse 4020

Drying loss 2980

Acid Brown - 432 1000

Total 8000 8000

Spray Drying

Mass Balance of Acid Brown - 432

Anthranilic Acid

Diazo

Ist coupling

IInd Coupling

Chromination

RO/UF


13. Acid Brown 425


Anthranilic acid Diazotized with HCl Nitrite at 0°C temp with Ice Stirrer 1

hour, Resorcinol coupled with this Diazo in alkaline medium at 50°C Stirrer

2 hour, O.T. 5 SA Diazo with HCl Nitrite and Ice at 0°C temp. Stirrer 1-1/2

hour this Diazo coupled with first coupling in alkaline pH at 50°C temp

stirrer 6 hour. After 6 hour heat 90°C - 95°C and metalized with salicylic

acid and B.C.S at 5.5 pH maintain for 4 hour, After 4 hour test. If test is

ok, then clarify, filter and Dry it.

Chemical Reaction:


First Coupling with Resorcinol

2. II Coupling with Ortho Toludine 5, Sulphonic Acid


Mass Balance:

INPUT KG OUTPUT KG

Anthranilic acid 149

HCl 60

Nitrite 80

Ice 800

Water 1250

Resorcinol 117

Soda Ash 330

Ice 900

Water 500

O.T. 5 SA. 220

HCl 55

Nitrite 70

Ice 750

Water 1000

Salicylic Acid 105

B.C.S. 320

Steam 800

Caustic Flakes 35

Water reuse 3421

Drying loss 3120

Acid Brown 425 1000

TOTAL 7541 7541

Spray Drying

RO/UF

Mass balance of Acid Brown 425

Anthranilic Acid

Diazo

1st COUPLING

2nd COUPLING

Chromination

Clarification


14. Acid Brown 434


Sodium picramate Diazotized with HCl, Nitrite at 0ºC temp stirrer – 1.5

hour then couple with picramatediazo in alkaline medium 1.6 cleave acid

diazotized of, Nitrite & Ice at 00C temp this diazo coupled with first

coupling at 30C temp., stir for 6 hrs. heat at 80 temp. Metalized with

ferrous sulphate solution in natural medium stir for 4 hrs. If test ok then

isolated with common salt. Filter collect w/c, dry it.

Chemical Reaction:


2. Ist Coupling with Resorcinol

3. Laurent Acid Diazo

4. IInd Coupling


5. Above metalized with salicylic acid & chromium fluoride

Mass Balance:

INPUT KG OUTPUT KG

Sodium Picramate 267

HCl 300

Nitrite 70

Ice 600

Water 1000

Resorcinol 96

Ice 500

Water 400

1,6 cleave acid 205

HCl 345

Ice 500

Sodium Nitrite 60

Ice 400

Caustic Lye 135

Steam 600

Ferrous Sulphate 260

Common Salt 550

Waste Water 4298

Drying loss 990

Acid Brown 434 1000

Total 6288 6288

Spray Drying

Mass Balance of Acid Brown - 434

Sodium

picramate diazo

Coupler Vessel

Diazo of Mix

Cleave

Coupling

Metallisation

Isolation &

Filtration


15. Acid Green 16


• In M.S. Reactor Naphthalene and Sulphuric Acid is mixed for reaction.

Then add soda ash and filter it. Wet cake formed is Naphthalene

Disulfonic Acid will be used for further procedure and effluent goes to

ETP.

• Now in another M.S lead bonded jacketed Vessel take Dimethyl aniline,

formaldehyde and Sulphanilic acid. Add soda ash to this mass and filter

it. Effluent goes to ETP. Now mix this wet cake with previously prepared

wet cake of Naphthalene Disulfonic Acid, also add water and sulphuric

acid. Once this mass is oxidized using water, sodium dichromate, oxalic

acid, sulphuric acid and soda ash; it is salted with common salt and

filtered. Wet cake obtained now is dried in dryer, pulverized in ball mill

as per required standard and packed for sale.

Mass Balance:

INPUT KG OUTPUT KG

Di Methyl Aniline 600

Formaldehyde 220

Sulphanilic Acid 10

Soda Ash 250 Waste Water 1350

MnO2 400 DMA W/C 1630

Water 1500

Napthaline 400 Waste Water 1230

Sulphuric Acid 500 Napthaline di sulphonic Acid w/c 750

Oleum 450

Soda 630

Napthalene Disulphonic Acid 750

DMA W/C 1630

Sodium dichromate 110

Sulphuric Acid 550

Oxalic Acid 160

Soda 150

Water 1000


Drying Loss 1250

Acid Green 16 1000

Total 9960 9960

Mass Balance of Acid Green 16

Condensation

Oxidation &

Filteration

Sulphonation &

Filteration

Drying & packig

Condantation &

Oxidation

Isolation &

Filteration


16. Acid Blue 9


Ortho-Benzaldehyde sulfonic acid and Ethyl benzyl aniline sulfonic acid

(EBASA) condensation, oxidation with Manganese Oxide in presence of

Acetic acid, and then the product into the Sodium salt, filter and dry it.

Mass Balance:

INPUT KG OUTPUT KG

Ethyl Benzyl Aniline

Sulphonic Acid 750

Ortho Benzaldehyde

sulphonic Acid 275

H2SO4 300

Soda Ash 150

HCl 350Water 1000

MNO2 150

H2SO4 300

Soda Ash 250

HCl 400

Acetic Acid 300Water 1000


Drying Loss 1125

Acid Blue 9 1000

Total 6025 6025

Mass Balance of Acid Blue 9

Condensation

Oxidation

Isolation &

Filteration

Drying & packig


17. Acid Blue 15


Ethyl benzyl aniline sulfonic acid (EBASA) condensation, and then (a)

oxidation as dimer water molecules (hydrol), again with N,N-diethyl meta

toluidine condensation, oxidation with Manganese Oxide in presence of

H2SO4 and translated into sodium salt, filter and dry it.

Mass Balance:

INPUT KG OUTPUT KG

Ethyl Benzyl Aniline

Sulphonic Acid1090

Di Ethyl meta toludine 210

H2SO4 300

SODA ASH 150

HCl 350

WATER 1000

MNO2 150

H2SO4 300

Soda Ash 250

HCl 400

Acetic Acid 300

Water 1000


Drying Loss 1180

Acid Blue 15 1000

Total 6300 6300


Condensation

Oxidation

Isolation &

Filteration

Drying & packig


18. Acid Blue 7


Benzaldehyde -1,3-disulfonic acid and N-benzyl-N-ethyl Aniline (2 More)

condensation and oxidation with Manganese Dioxide in presence of acetic

acid, convert into sodium salt, Filter and dry it.

Mass Balance:

INPUT KG OUTPUT KG

Benzaldehyde Disulfonic Acid 330

Ethyl benzyl aniline 380

H2SO4 300

Soda Ash 150

HCl 350

Water 1100

MNO2 150

H2SO4 300

Soda Ash 250

HCl 400

Acetic Acid 300

Water 1000


Drying Loss 1080

Acid Blue 7 1000

Total 5810 5810

Drying & packig


Condensation

Oxidation

Isolation &

Filteration


19. Acid Blue 113


Metanilic acid is diazotized with HCl, Nitrite and Ice at 0°C temp. Stir for 1

hour. Alpha Naphthyl amine coupled with Metanilic acid in acidic medium.

Stir for 8 hours. After 8 hours ANA diazo with HCl & Nitrite at 18°C temp.

Stirrer for 3 hours and then coupled with phenyl peril acid. At neutral pH,

stir for 3 hours, then isolated & spray dryer it.

Mass Balance:

INPUT KG OUTPUT KG

Metanillic Acid 300

HCl 65

Sodium Nitrite 70

Ice 1000

Water 900

HCl 55

Alpha Napthyl Amine 240

Ice 500

Water 600

Nitrite 50

H2SO4 250

Caustic Flakes 200

Ice 1000

Phenyl peri Acid 490

Soda Ash 200

Sodium Acetate 300

Ice 500

Water 500

Common Salt 800 Waste water 5640

Drying Loss 1380

Acid Blue 113 1000

Total 8020 8020

Spray Drying


Diazotization

1st Coupling

IInd

Diazotization

IInd Coupling

Isolation &

Filtration


20. Acid Blue 193


Solution of 2-Naphthol

Take water and 2-Naphthol, Charge along with Caustic flakes. Stir for 3

hrs., check clear solution.

Preparation of 1,2,4-diazo solution

Add 1,2,4-diazo, ice and water, to make a slurry. Temp should be less than

100C. Stir for 1 hr at 100 C

Diazo coupling

Charge coupler solution to diazo slurry at 25-350C, Stir 2 hr at 25-350 C,

then Heat to 700 C.

Metal Complexation (Commination)

Add salicylic acid at 700C. Charge basic chromium Sulphate. Adjust pH 4.0-

4.5 by adding HCl. Heat to 95-1000C and maintain temperature for 5 hr.

Clarify in filter press. Adjust pH 7 by adding caustic flacks just before spray

drying.

Mass Balance:

INPUT KG OUTPUT KG

B Napthol 350

Caustic Lye 125

ICE 800

Water 1200

1,2,4 Diazo 690

Ice 500

Water 1000

Caustic Lye 120

Salicylic Acid 50

BCS 240

Steam 700

Water reuse 2075

Drying loss 2700

Acid Blue 193 1000

TOTAL 5775 5775


Preparation of B

Napthol

Solution

Diazotization

Spray Drying

RO

Coupling &

Chromination


21. Acid Red 315


Diazotisation of 4-NAPSA, coupling with 1-phenyl-3-methyl-5-pyrazolone,

metallisation with Basic Chromium Sulphate. Chelating with another

monoazo dye produced from (Diazotisation of 5-Nitro-2-aminophenol and

coupling with 1-phenyl-3-methyl-5- pyrazolone) Clarify solution, filter and

dry it.

Mass Balance:

INPUT KG OUTPUT KG

4 NAPSA 225

HCL 125

NITRITE 68

ICE 750

WATER 750

PMP 160

Ice 500

CAUSTIC FLAX 50

WATER 500

SALASYLIC ACID 40

BCS 350

CAUSTIC FLEX 50

STEAM 800

EFFLUENT 2588

WATE CAKE ORANGE 1780

5 NAP 138

HCL 125

NITRITE 68

ICE 750

WATER 750

PMP 160

Ice 500

CAUSTIC FLAX 50

WATER 700

EFFLUENT 1851

WATE CAKE RED 1390

WATE CAKE ORANGE 1780

WATE CAKE RED 1390

CAUSTIC FLAX 50

WATER 1000

Drying loss 3220

ACID RED 315 1000

Total 11829 11829

FILTER

Condensation

SPRAY DRYING

Mass Balance Acid Red 315

Diazotiazation

COUPLING

CHROMINATION

FILTER

Diazotiazation

COUPLING


NO2 OH

NH2

NO2

+ HCl+NaNO2+Ice

Dioazotization

NO2

N

OHNO2

N.Cl- +

OH

Picramic Acid(4:6 Dinitro-2-Aminophenol)

Beta Naphthol

Coupling

OH

N

NO2 OH

N

NO2

Monoazo

OH

NH2N

NO2

HO3S

OH

+

HO3S

NO2

OH

N N

OH

Chromination

Basic & Acidic 1:1

O

N N

O

Cr+3

1:1 Cr Complex of 6NDA

Beta Naphthol

+ Monoazo

NO2

N

NO2

N

O O

Cr

O O

N N SO3H

NO2Acid Black - 107

NO2 OH

NH2

NO2

+ HCl+NaNO2+Ice

Dioazotization

NO2

N

OHNO2

N.Cl- +

OH

Picramic Acid(4:6 Dinitro-2-Aminophenol)

Beta Naphthol

Coupling

OH

N

NO2 OH

N

NO2

Monoazo

OH

NH2N

NO2

HO3S

OH

+

HO3S

NO2

OH

N N

OH

Chromination

Basic & Acidic 1:1

O

N N

O

Cr+3

1:1 Cr Complex of 6NDA

Beta Naphthol

+ Monoazo

NO2

N

NO2

N

O O

Cr

O O

N N SO3H

NO2Acid Black - 107

22. Acid Black 107


6-nitro-1-diazo-2-naphthol-4-sulphonic acid coupling with Beta naphthol,

metallisation with Basic Chromium Sulphate. Chelating with another

monoazo dye produced from (Diazotisation of Sodium Picramate and

coupling with Beta Naphthol) Spray dry the resulting dyestuff solution.

Chemical Reaction:


Mass Balance:

INPUT KG OUTPUT KG

6 Nitro 480

Ice 500

Water 750

Beta Napthol 120

Ice 500

Caustic Flakes 50

Water 500

Salacylic Acid 45

Chromuim Formate 400

Caustic Flakes 50

Steam 800

EFFLUENT 2415

WATE CAKE Black 1780

Sodium Picramate 200

HCl 250

Nitrite 80

Ice 500

Water 750

Beta Napthol 245

Ice 500

Caustic Flakes 150

Water 700

EFFLUENT 1985

WATE CAKE Blue 1390

Wate Cake Black 1780

Wate Cake Blue 1390

Caustic Flekes 50

Water 1000

Dryign loss 3220

ACID Black 107 1000

Total 11790 11790

Mass Balance Acid Black 107

FILTER

Condensation

SPRAY DRYING

Diazotiazation

COUPLING

CHROMINATION

FILTER

Diazotiazation

COUPLING


(C) DIRECT DYES:

23. Direct Black 80


Para amino acetamide diazotized and couple with Gamma acid in alkaline

medium and deacylation with caustic soda at 95oC. Deacylation mass is

again tetrazotized and couple first with Mixed Cleves acid and then with

Gamma acid in an alkaline condition, Isolate with salt and pass though RO

and finally spry dry it.

Mass Balance:

INPUT KG OUTPUT KG

P- amino acetanilide 145

Sodium Nitrite 105

HCl 250

Ice 500

Water 750

Gamma Acid 430

Soda Ash 790

Water 750

Ice 500

Caustik soda 215

Steam 500

HCl 500

Sodium Nitrite 210

Ice 500

Mixed cleves acid 195

Water 400

Ice 500

Common Salt 550

Waste Water 5330

Drying Loss 1460

Direct Black 80 1000

Total 7790 7790

2nd Coupling

Isolation

Filtration

Drying & Packing

Diazotization of

1st Copling Mass

Mass Balance of Direct Black 80

Diazotization

1st Coupling

Hydrolysis




Take water in vessel and add caustic lye, then add PNTOSA slowly. After

complete charging check pH. Adjust pH 8.00 and temp to 55°C and

maintain for 1 hr. Then charge caustic for condensation. After complete

charging bring the temp to 66°C and maintain for 3 hr. Then add 50%

Sulphuric acid for reduction, at pH 2.0, maintain for 2 hr. Take

Nitrobenzene and Amine in vessel, then add above condensed mass slowly

and after complete charging, complete the reduction by adding extra

amine and check for separation. Then stop the stirrer and give 3.00 hr of

settling time. Take DEA + water in vessel and add above mass (Dye+ NB

+ Amine) slowly in vessel and stop when water level is reached. Complete

the reduction by adding extra DEA and adjust pH at 8.50. Stop the stirrer

for 7.00 hr. Recover dye from bottom and send for packing. The balanced

Nitrobenzene + Amine use in next batch.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

PNTOSA 600

caustic lye 215

Water 2500

Steam 1000

Spent H2SO4 (70%) 500

Common Salt 650

Wastewater 3005

Drying loss 1460

Direct Yellow 11 1000

Total 5465 5465

Drying &

Packing

Mass Balance of Direct Yellow 11

Condensation

Nutralization

Isolation &

Filtration


25. Direct Brown 44


Preparation of MPD Solution: Charge MPD in the MSRL vessel with

sodium nitrite. Add water and ice in it. It is coupled with hydrochloric acid

and ice to keep the temperature 0 to 5°C.

Preparation of Sulphanilic Diazo: Charge Sulphanilic acid and

Hydrochloric acid along with ice in the MSRL vessel with caustic lye. And

mass is coupled.

Coupling: Add Caustic lye in the in the mass and coupled.

Spray Drying: Send the total mass for the drying purpose.

Mass Balance:

INPUT KG OUTPUT KG

MPD 135

Water 1000

Sodium Nitrite 158

Ice 500

HCl 180

Ice 500

MPD 270

HCl 220

Sulphanilic Acid 300

Sodium Nitrite 100

Water 1250Ice 750

Ice 800

CS Lye 220

Water Reuse 2403

Drying loss 2980

Direct Brown 44 1000

Total 6383 6383

RO/UF

Spray Drying

Standardization

& Packing

Mass Balance of Direct Brown 44

Preparation of

MPD solution

1st Coupling

Preparation of

Sulphanilic

Diazo

Iind Coupling

Mixing


26. Direct Blue 71


C-Acid diazo solution: Prepare diazo of C-Acid with help of hydrochloric

acid (30%) and Sodium Nitrite solution in presence of ice.

α-Napthylamine solution: Prepare α-Napthyl amine clear solution by

heating with Hydrochloric acid (30%) and water. Clear pinkish solution is

obtained.

First coupling: Transfer α-Napthyl amine solution to C-Acid Diazo keeping

temp to 10°C under continuous stirring.

Mono azodiazo: Prepare diazo of first coupled mass with help of

Sodiumnitrite and ice. When diazo is ready add to Mix cleave acid clear

solution. When coupling is over, make diazo of aforesaid coupling mass

with help of Hydrochloric acid, ice and Sodium Nitrite.

J-Acid solution: Prepare J-Acid solution in water, ice and caustic lye.

Transfer diazo to J-Acid solution in alkali condition. Check the completion

of reaction.

Drying: Spray dry the reaction mass.

Chemical Reaction:

SO3H

NH2 SO3H

+ HCl + NaNO2

SO3H

SO3HN=N-Cl

NH2

SO3H

SO3HN

N

NH2

HCl + NaNO2

C-Acid C-Acid Diazonium Chloride Naphthylamine

Monoazo

SO3H

SO3HN

N

N=N-Cl

+ SO3H

NH2

N

N

SO3H

SO3H

N

N

SO3HNH2 Direct Blue 71

https://en.wiktionary.org/wiki/%CE%B1

https://en.wiktionary.org/wiki/%CE%B1


Mass Balance:

INPUT KG OUTPUT KG

C-Acid 165

HCl 300

Sodium Nitrite 155

Ice 500

Water 1000

Alpha Napthyl Amine 170

Caustik Flake 40

Ice 500

Sodium Nitrite 145

Ice 900

HCl 200

Mix Cleave Acid 330

Caustik Flake 40

Ice 500

Water 750

Sodium Nitrite 145

Ice 900

HCl 200

J acid 250

Caustic Lye 60

Water 800

Ice 600

Water Reuse 4270

Drying Loss 3380

Direct Blue 71 1000

Total 8650 8650

RO/UF

Spray Drying

Standardization

& Packing

Mass Balance of Direct Blue 71

Preparation of

C-Acid diazo

solution

1st Coupling

Diazotization of

1st Coupling

Mass

3rd Coupling

2nd Coupling

Diazotization of

2nd Coupling

Mass




Diazotization of p-Cresidine-o-Sulphonic acid: p-Cresidine-o-

Sulphonic acid is diazotized in presence of Hydrochloric acid and Sodium

Nitrite. Just before coupling make CR and SI –ve with sodium bicarbonate.

Coupler Solution: Take water and add J-Acid Urea and make uniform

solution. Add Sodium bi-carbonate. Receive above diazo mass in course of

45 min. Stir overnight. Heat up to 80°C & stir for 2 hr. Spray dry the above

reaction mass

Chemical Reaction:

Me NH2

OMeSO3H

+ HCl + NaNO2

Me N=N-Cl

OMeSO3H

P-Cresidine O-Sulphonic Acid P-Cresidine O-Sulphonic Diazonium Chloride

OH

SO3H

NH-C-NH

O OH

SO3H

+ NaHCO3

J Acid Urea

OH

SO3Na

NH-C-NH

O

OH

SO3Na

+ 2 Cl-N=NMe

SO3HOMe

J Acid Urea Disodium Salt

Me

N=N

OMe SO3H SO3H

OH

NH-C-NH

O

OH

SO3

N=N

OMe SO3H

Me

Direct Orange 118


Mass Balance:

INPUT KG OUTPUT KG

O - Toludine 5 Sulphonic Acid 250

HCl 375

Sodium Nitrite 95

Ice 800

Sodium bi-carbonate 50

Water 1200

Ice 700

J-Acid Urea 350


Dryng Loss 980

Direct Orange 118 1000

Total 4470 4470

Mass Balance of Direct Orange 118

Diazotization

Coupling

Standardization

& Packing

Isolation &

Filteration


28. Direct Red 239


Bronner’s Acid: Make clear solution of bronner’s Acid with caustic lye.

Add Sodium Nitrite in the solution and make reverse diazo in Hydrochlori

acid and ice to maintain diazo at temp 5-7°C.

Coupler solution: Prepare J-Acid Urea solution in water, stir to form good

slurry. Transfer diazo to coupler solution in alkali medium. When coupler is

over, stir over night.

Drying: Spray dry the above reaction mass.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

Browner's acid 250

Water 1500

Ice 750

caustic lye 100

Sodium Nitrite 95

HCl 550

J-Acid Urea 292

Water 1250

Ice 750

Sodium Bi Carbonate 250

Water Reuse 1927

Drying loss 2860

Direct Red 239 1000

Total 5787 5787

Mass Balance of Direct Red 239

Diazotization

Coupling

Spray Drying

Standardization

& Packing

R/O

NH2

SO3H

2 + NaNO2 + HCl

N=N-Cl

SO3H

2

Bronner's Acid

SO3H

N=N

OH

SO3H

NH-C-NH

O

OH

N=N

SO3H SO3H

Direct Red 239


29. Direct Red 254


PAABSA solution: Prepare solution of PAABSA by caustic lye. Stir and add

Sodium Nitrite in the solution and make reverse diazo in Hydrochloric acid

and ice. Just before coupling destroy excess nitrite by sulfamic acid.

Coupler solution: Prepare J-Acid solution with help of caustic soda lye.

Transfer the diazo to coupler solution in alkali medium. When coupling is

over, heat the coupling mass.

Drying: Spray dry the above reaction mass.

Chemical Reaction:

SO3H N=N NH2 + HCl + NaNO2

P-Aminoazo Benzene 4-Sulphonic Acid

SO3H N=N N=N-Cl

P-Aminoazo Benzene 4-Sulphonic Acid

+

SO3H

NH2

OH

J Acid

SO3H N=N N=N

OH

NH2

SO3H

Direct Red 254


Mass Balance:

INPUT KG OUTPUT KG

PAABSA 400

Sodium Nitrite 100

WATER 1250

Soda ash 300

Ice 1000

HCl 550

J-Acid 350

caustic soda lye 150

Water 1200

Ice 700

Water reuse 2020

Drying Loss 2980

Direct Red 254 1000

Total 6000 6000

Standardization

& Packing


Preparation of

PAABSA

Solution

Coupling

R/O

Spray Drying




C-Acid diazo: Prepare diazo of C-Acid in presence of Hydrochloric acid

(30%) Sodium Nitrite and ice.

P-Cresidine: Make solution of p-Cresidine in water. Then couple with C-

Acid diazo. Stir continuously. When coupling is over, make mono azodiazo

by adding Hydrochloric acid and Sodium nitrite solution in presence of ice.

Stir mono azo diazo for 4-5 hr. Then destroy excess sodium nitrite adding

sulfamilic acid. Final coupling will take place with n-Phenyl J-Acid solution

in alkaline condition. After completion of final coupling, heat to 70°C. Spray

Dry the above reaction mass.

Mass Balance:

INPUT KG OUTPUT KG

C-Acid 330

HCl 350

Sodium Nitrite 147

Water 800

Ice 500

p-Cresidine 150

Water 1000

Soda Ash 100

Ice 500

HCl 350

Sodium Nitrite 147

Ice 1100

n-Phenyl J-Acid 327

Water 750

Ice 500

Caustic lye, 48% 300

Water reuse 3251

Drying Loss 3100

Direct Violet 35 1000

Total 7351 7351

Spray Drying

Standardization

& Packing

Mass Balance of Direct Violet 35

Preparation of C-

Acid diazo

Preparation of p-

Cresidine

I st Coupling

Final Coupling

RO

Diazotization of

1st Coupling

Mass


31. Direct Red 81


Diazotization: PAABSA is charged to a M.S.R.L reaction vessel along with

water and ice to maintain temperature between 0 to 50C. Then

Hydrochloric Acid will be added followed by Sodium Nitrite powder

gradually till diazotization completed, which can be confirmed by starch

iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid

just before coupling. Keep temperature between 0 to 50C throughout the

diazotization reaction.

Preparation of coupling component: Charge J acid in the MSRL vessel

and make clear solution with caustic lye. Add ice with water the coupler

solution. Take water in which add sodium Acetate and benzyl chloride.

Coupling: Charge coupler solution to the diazotized PAABSA keeping the

temperature between 0 to 50C by adding of ice.

Isolation: Add salt for the Isolation of the product and then send the

product for further filtration following by tray drying.

Chemical Reaction:

SO3H N=N NH2 + HCl + NaNO2 N=NSO3H N=N Cl

4 4' p-Amino Azo Benzene Sulphonic Acid

OH

SO3H NH2

+ C-Cl

O

J Acid Benzoyl Chloride

OH

SO3H

NH-C

O + SO3H N=N N=N-Cl

Benzoylated J Acid

N=NSO3H N=N

OH

SO3H NH-C

O

Direct Red 81


Mass Balance:

INPUT KG OUTPUT KG

PAABSA 350

HCl 300

Water 1000

Ice 1000

Caustic lye 48% 260

Na2CO3 100

Benzyl Chloride 150

Sodium Acetate 160

J acid 280

Water 750

Ice 500


Drying loss 1380

Direct Red 81 1000

Total 5500 5500

Standardized &

Packing


Diazotization

Benzoylation of

J Acid

Isolation &

Filtration

Drying

Coupling


32. Direct Violet 9


Sulfanilic acid diazo: Prepare diazo of sulfanilic acid in presence of

Hydrochloric acid, Sodium Nitrite and ice.

p-Cresidine solution: Prepare solution of p-Cresidine in water. Couple

with Sulfanilic acid diazo. Stir continuously. When coupling is over make

monoazo diazo by adding Hydrochloric acid and Sodium Nitrite solution in

presence of ice. Stir monoazo diazo for 4-5 hr to consume sodium nitrite.

After that destroy excess nitrite by adding sulfamic acid. Final coupling will

take place with n-Phenyl J-Acid in alkaline medium. After completion of

coupling, heat to 70°C. Spray dry the above reaction mass.

Chemical Reaction:

SO3H NH2 + NaNO2 + HCl SO3H N=N-Cl + CH3

Me

NH2

OCH3(OMe)

P-Cresidine

Sulphanilic Acid

SO3H N=N

Me

NH2

OMe

Monoazo

HCl + NaNO2

N=NSO3H

Me

N=N Cl

OMe

Monoazo Diazo

+

Ph NH2 SO3H

OH N-Phenyl J Acid

SO3H N=N

Me

N=N

OMe SO3H

NH-Ph

OH

Direct Violet 9


Mass Balance:

INPUT KG OUTPUT KG

Sulphanilic acid 180

HCl 500

Sodium Nitrite 147

Ice 1300

Water 1000

p-Cresidine 150

Ice 500

Water 750

SodaAsh 75

HCl 500

Sodium Nitrite 147

Ice 500

n-Phenyl J-Acid 327

Caustic lye, 48% 148

Ice 1000

Water reuse 3244

Drying Loss 2980

Direct Violet 9 1000

Total 7224 7224

Standardization

& Packing

R/O

Mass Balance of Direct Violet 9

Prepare diazo

of sulfanilic acid

Preparation of

p-Cresidine

solution

Final Coupling

Spray drying

Prepare diazo

of 1st Coupling

Mass

1st Coupling




Condensation: DNSDA, Para anisidine and water is charged into vessel.

And caustic flakes are added to the vessel to maintain the pH 5.5-6.3.

Isolation: The mass is isolated by HCl and steam is injected into vessel.

Filtration: The mass is filtered and then sent to the drying.

Standardization: The spray dried powder is then charged to the Ball –

Mill and standardize be adding Glauber salt and anti – dusted by anti-

dusting oil.

Packing: The final product is then packed in HDPE bags/M.S. Drums/

Plastic Carboys/ Paper cartoon boxes.

Mass Balance:

INPUT KG OUTPUT KG

DNSDA 550

Para anisidine 245

Caustic lye 157

Water 2200

HCl 260

steam 750

Salt 500

Water 1000

Water reuse 1822

Drying Loss 2840

Product ReceivedDirect Yellow 99 1000

Total 5662 5662

Spray Drying

Standardization

& Packing

Mass Balance of Direct Yellow 99

Condensation

Isolation

R/O


34. Direct Black 19


Diazotization: Charge PNA along with HCl in the MSRL vessel. Add water

and ice in it.

Preparation of Gamma Acid Solution: Charge H Acid in the MSRL vessel

with HCl, water and soda ash.

Coupling: Above mass is coupled with MPD and ice. Keeping the

temperature 0 to 5oC by adding of ice and by adding water wet cake slurry

is generated at the end.

Spray Drying: Wet cake slurry is spray dried and product is generated.

Mass Balance:

INPUT KG OUTPUT KG

PNA 210

Water 750

HCl 540

Sodium Nitrite 180

Ice 1000

H acid 245

Water 700

Ice 500

Soda Ash 75

HCl 540

Sodium Nitrite 180

Ice 1000

MPD 155

Water 750

Ice 500

Soda Ash 110

Water reuse 3065

Drying Loss 3390

SD-40 20

Product ReceivedDirect Black 19 1000

Total 7455 7455

Spray Drying

Standardization

& Packing

Mass Balance of Direct Black 19

Diazotization

1st Coupling

Coupling

R/O

Diazotization of

1st Coupling

Mass


(D) Reactive Dyes

35. Reactive Blue 198:

Manufacturing process:

Cynuration: Cyanuric Chloride is charge into a clear solution of Aniline 2:4

Disulphonic Acid in Cold. Stir well to complete the cynuration.

Condensation: Cynurated mass is added in the slurry of Blue 198 base

and slowly heated to 50oC – 55oC maintaining pH: 7.0 and stir well to get

complete reaction.

Clarification: Final product dye solution is clarified to remove any

insoluble foreign particles in clarifier.

Spray Drying: Final product clarified dye solution is spray dried

Standardization: The spray dried powder is then charged to the Ball –

Mill and standardize be adding Glauber salt and anti – dusted by anti-

dusting oil.


Plastic Carboys / Paper cartoon boxes.

Chemical Reaction:


Mass Balance:

INPUT KG OUTPUT KG

Cyanuric Chloride 220

Soda ash 150

Tamol 10

Aniline 2:4 DSA 320

Soda Bi Carb 120

Water 800

Ice 1000

Blue HEGN-Base 400

HCl 120

Water 800

Dicamol 45 Solid waste 50

wastewater 1735

Drying loss 1200

Reactive Blue 198 1000

Total 3985 3985

Standardization &

Packing

Mass Balance of Reactive Blue 198

Cyanuration of Aniline

2:4 DSA

Condensation

Clarification

RO/UF

Spray Drying




First condensation: In the first stage of process P-nitro chloro Benzene

ortho sulfonic acid is added with ethylene diamine to give condensed

product and salt.

Second condensation: Reduced product is charged with sodium

carbonate and chloronil to form brown base condensed product along with

salt, liberating water.

Cyclization: In this stage brown base condensed product is reacted with

Oleum to produce cyclized product liberating sulphuric acid.

Cyanuration: Sodium salt of aniline 2,5 DSA is charged with cyanuric

chloride for cyanuration process to get cyanurated aniline 2,5 DSA.

Isolation: Mass is isolated by nicotinic acid. And then further clarified.

Spray Drying: The liquid will be transferred to the spray drying holding

tank and spray dry.


Plastic Carboys/Paper cartoon boxes.

Chemical Reaction:

1. 1st CONDENSATIONCl

NO2

SO3Na

+ NH2CH

2CH

2NH

2

NO2

SO3H

+

NHCH2CH2NH2

NaCl

2. REDUCTION

NO2

SO3H

NHCH2CH2NH2

+ Fe + HClNa

2CO

3

NH2

SO3

NHCH2CH2NH2

+ Fe2O

3 + NaCl + CO2 + H

2O


3. 2nd CONDENSATION

NH2

SO3

NHCH2CH2NH2

2+ NaHCO

3 +Cl Cl

ClCl

O

O

SO3Na

NH2CH2CH2NH

NH

NHO

O

Cl

Cl

SO3Na

NHCH2CH2NH2

+ NaCl + CO2 + H

2O

4. CYCLIZATION

SO3Na

NH2CH2CH2NH

NH

NHO

O

Cl

Cl

SO3Na

NHCH2CH2NH2

+ H2S

2O

7

SO3H

NH2CH2CH2NH O

O

Cl

Cl

NHCH2CH2NH2N

N

SO3H

5. DISSOLUTIONSO3H

SO3H

NH2

+ Na2CO

3

SO3Na

NH2

+

SO3Na

CO2 + H

2O

sodium salt of aniline 2:5 DSA

6. CYANURATION

SO3Na

NH2

SO3Na

+N

N

N

Cl

Cl Cl

N

N

N

Cl

Cl NH

SO3Na

SO3Na

+ NaCl

7. 3rd CONDENSATIONSO3Na

NH2

SO3Na

2 +

SO3H

NH2CH2CH2NH O

O

Cl

Cl

NHCH2CH2NH2N

N

SO3H

+ Na2CO

3

NH2CH2CH2NH O

O

Cl

Cl

NHCH2CH2NH2N

N

SO3Na

SO3Na

N

N

N

Cl NH

SO3Na

SO3Na

N

N

N

Cl NH

SO3Na

SO3Na

8. 4th CONDENSATION

NH2CH2CH2NH O

O

Cl

Cl

NHCH2CH2NH2N

N

SO3Na

SO3Na

N

N

N

NH

SO3Na

SO3Na

N

N

N

Cl NH

SO3Na

SO3Na

+N COOH

NH2CH2CH2NH O

O

Cl

Cl

NHCH2CH2NH2N

N

SO3Na

SO3Na

N

N

N

NH

SO3Na

SO3Na

N

N

N

NH

SO3NaNCOO

-

NCOO

-

SO3Na

reactive blue 187


Mass Balance:

INPUT KG OUTPUT KG

Etheylene Diamine 250

PNCBOSA 230

Water 1500

HCl 800

Ice 2100 Waste Water 2440

HCl 315

Sodium sulphite 85

Chloronail 175

Sodium bicarbonate 160

Water 800

Sulphuric Acid 650

Oleum 300

Ammonium persulphate 150

wash water 800 Waste Water 2100


Aniline 2,5 disulphuric acid 260

Nicotinic acid 250

Dicamol 55

Dedusting Oil 25 Drying loss 3565

REACTIVE BLUE 187 1000

Condensation

Reduction and

condensation

Cyclization

Filtration

Mass Balance of REACTIVE BLUE 187

Isolation

Clarification

Spray Drying

Standardization &

Packing

Isolation and filtration

Cyanuration




Diazotization: Sulfo OAVS is diazotized with HCl and sodium Nitrite at

0°C temperature and stirred well to complete diazo.

Coupling: Sulfo OAVS diazo is coupled with 4-Sulfo Hydrazone in alkaline

condition in presence of Copper sulfate to form the final dye is called

Reactive Blue BB.

Clarification: The final dye is clarified to remove un-reacted reactants or

foreign particles.

Spray Drying: Final product clarified dye solution is spray dried.

Standardization & Packing: The spray dried powder is then charged to

the Ball – Mill and standardize be adding Glauber salt and anti – dusted by

anti-dusting oil. The final product is then packed in HDPE bags/M.S.

Drums/Plastic Carboys/Paper cartoon boxes.

Chemical Reaction:


Mass Balance:

INPUT KG OUTPUT KG

Sulpho OAVS 650

HCl 175

Sodium Nitrite 65

CS Lye 80

Sulphamic acid 2

Soda Ash 125

Water 600

Ice 800

4-Sulpho Hydrazone 450

HCl 150

Sodium Nitrite 65

CS Lye 45

Sulphamic acid 2

Soda Ash 150

Water 800

Ice 600

Copper sulphate 350

Soda Bi Carbonate 195

Water 600

Dicamol 70 solid Waste 100

wastewater for reuse 4154

SD-40 30 Drying loss 750

Reactive blue 220 1000

TOTAL 6004 6004

Spray Drying

Standardization &

Packing

Mass balance of Reactive blue 220

Diazotization of

Supho OAVS

Coupling of 4 -

Sulpho Hydrazone

Coppering

Clarification

RO/UF




Diazotization: 6-Acetyl OAPSA charged to a MSRL reaction vessel along

with water and ice to maintain temperature between 0 to 5°C. Then

Hydrochloric Acid will be added followed by Sodium Nitrite powder

gradually till diazotization completed, which can be confirmed by starch

iodide paper. Any excess nitrite will be removed by adding Sulfamic Acid

just before coupling. Keep temperature between 0 to 5 °C throughout the

diazotization reaction.

Coupling: Coupling of above mass with 4-Sulpho hydrazone Acid the

diazotized 6-Acetyl OAPSA stir it keeping the temperature 0-5°C by adding

of ice.

Coppering: The above mass coppering with Copper Sulphate is done at

95°C temperature.

Isolation: Blue BRF base to be isolated with HCl to remove extra impurity

by isolation.

Cyanuration: Blue BRF Base is condensed with of Cyanuric Chloride in

neutral condition at 0°C temp.

Condensation: The Cyanurated product is further condensed with N-Ethyl

Meta Base Ester Eater at 50°C temperature in presence of slightly access

of Sodium Carbonate to get the final dye.

Clarification: Final product dye solution is clarified to remove any

insoluble foreign particles in clarifier. The standardized dye liquid will be

transferred to the spray drying holding tank and spray dry.

Spray Drying: Final product clarified dye solution is spray dried.

Standardization: The spray dried powder is then charged to the Ball Mill

and standardize be adding Glauber salt and anti–dusted by anti-dusting oil.


Plastic Carboys/ Paper cartoon boxes.


Chemical Reaction:


Mass Balance:

INPUT KG OUTPUT KG

6-Acetyl OAPSA 250

CS Lye 55

HCl 550

Sodium nitrite 70

Sulphamic acid 2

Sodium acetate 120

soda ash 65

Water 600

Ice 400

4-Sulpho Hydrazone 350

Soda ash 120

Ice 400

HCl 250

Water 600

Copper sulphate 250

CS Flakes 350

Hot water 400

Salt 120 wastewater 2430

Soda ash 150


Tamol 20

N-Ethyl MBE 220

Soda Bi Carb 130

Dicamol 55 Solid waste 95

Drying loss 2152

Reactive Blue 221 1000

Total 5677 5677

Mass Balance of REACTIVE BLUE 221

Condensation

Clarification

Spray Drying

Standardization &

Packing

Diazotization of

6-Acetyl OAPSA

Coupling of

4-Sulpho Hydrazone

Coppering

Isolation &

Filteration

Base Cyanuration


(E) BASIC DYES

39. Basic Brown 1


Diazotisation of MPD in presence of HCl and nitrite, and further coupling of

MPD with caustic Flakes, then Filter it and collect wet cake, and Dry it.

Mass Balance:

INPUT KG OUTPUT KG

MPD 215

HCl 750

Nitrite 300

Ice 1000

Water 1250

MPD 430

Caustic Flakes 50

Ice 500

Water 1000


Drying Loss 1190

Basic Brown 1 1000

Total 5945 5945

Isolation &

Filteration

Drying & packig

Mass Balance of Basic Brown 1

Diazotization

Coupling


40. Basic Yellow 2


Dimethyl Aniline and formaline are reacted in presence of H2SO4, to

prepare methane base. Methane base is reacted with T G Urea in presence

of Sulphur, filter the reaction mass and dry it.

Mass Balance:

INPUT KG OUTPUT KG


Formaline 313

Water 2500

H2SO4100

T G UREA 1030

SULPHUR 110


Drying Loss 1280

Basic Yellow 2 1000

Total 5336 5336

Filteration

Drying & packig

Clarification

Mass Balance of Basic Yellow 2

Condensation

Condensation


41. Basic Violet 1 Crystal


Para Formaldehyde, Mono Methyl Aniline, N, N-dimethylaniline and Acetic

Acid are reacted at reflux temp in presence of Catalyst for 12 hrs. Product

is isolated with cooling and filters at room temp. Wash with dilute HCl. Dry

and pulverized.

Mass Balance:

INPUT KG OUTPUT KG


Para Formaldehyde 110

Mono Ethyl Aniline 330

Catalyst 50

Oxygen 50

Acetic Acid 800

Water 1000

Caustic Soda 1000 Effluent 2640

HCl 330

Water 1000

Drying Loss 1700

Basic Violet 1 Crystal 1000

Total 5340 5340

Drying & packig

Mass Balance of Basic Violet 1 Crystal

Condensation

Clarification

Nutralization &

Filter

Paste Forming


42. Basic Green 4 Crystal


Benzaldehyde, N, N-dimethylaniline and Acetic Acid are reacted at reflux

temp in presence of Ethyl Cellulose and Catalystfor 12 hrs. Product is

isolated with cooling and filters at room temp. Wash with dilute HCl. Dry

and pulverized.

Mass Balance:

INPUT KG OUTPUT KG


Benzaldehyde 360

HCl 360

Acetic Acid 600

Catalyst 40

Ethyl Cellulose 80

Oxygen 160


Oxalic Acid 600

Water 1000

Drying Loss 2060

Basic Green 4 Crystal 1000

Total 4750 4750

Drying & packig

Mass Balance of Basic Green 4 Crystal

Condensation

Clarification

Nutralization &

Filter

Crystalization




Benzaldehyde, N, N-diethylaniline and Acetic Acid are reacted at reflux

temp in presence of Catalyst for 12 hrs. Product is isolated with cooling

and filters at room temp. Wash with dilute HCl. Dry and pulverized.

Mass Balance:

INPUT KG OUTPUT KG

Di Ethylaniline 1000

Benzaldehyde 330

Acetic Acid 1460

Catalyst 50

Oxygen 160


H2SO4 600

Water 1000

Drying Loss 1990

Basic Green 1 Crystal 1000

Total 5400 5400

Drying & packig

Mass Balance of Basic Green 1 Crystal

Condensation

Clarification

Nutralization &

Filter

Crystalization


44. Basic Blue 26 Crystal


Para Formaldehyde, Phenyl alpha Napthyl amine, N, N-dimethylaniline and

Acetic Acid are reacted at reflux temp in presence of Catalyst for 12 hrs.

Product is isolated with cooling and filters at room temp. Wash with dilute

H2SO4. Dry and pulverized.

Mass Balance:

INPUT KG OUTPUT KG



Phenyl Alpha naphthalamine 415

Acetic Acid 750

Catalyst 20

Oxygen 20


H2SO4 600

Water 1000

Drying Loss 2010

Basic Blue 26 Crystal 1000

Total 4330 4330

Drying & packig

Mass Balance of Basic Blue 26 Crystal

Condensation

Clarification

Nutralization &

Filter

Crystalization


(F) BASIC DYES LIQUID

45. Basic Yellow 2


Dimethyl Aniline and formaline are reacted in presence of H2SO4, to

prepare methane base. Methane base is reacted with T G Urea in presence

of Sulphur, Clarify the reaction mass and send for packing.

Mass Balance:

INPUT KG OUTPUT KG


Formaline 100

H2SO4 50

Acetic Acid 225

Glycerine 33

T G Urea 335

Sulphur 35

Sludge 48

Basic Yellow 2 Liquid 1000

Total 1048 1048

Clarification

Mass Balance of Basic Yellow 2 Liquid

Condensation

Condensation


46. Basic Violet 1


Para Formaldehyde, Mono Ethyl Aniline, N, N-dimethyl aniline and Acetic

Acid are reacted at reflux temp in presence of Catalyst for 12 hrs. Product

is clarified, and send for packing.

Mass Balance:

INPUT KG OUTPUT KG



Mono Ethyl Aniline 170

Catalyst 20

Oxygen 20

Acetic Acid 450

Sludge 40

Basic Violet 1 Liquid 1000

Total 1040 1040

Mass Balance of Basic Violet 1 Liquid

Condensation

Clarification


47. Basic Green 4


Benzaldehyde, N,N-dimethyl aniline and Acetic Acid are reacted at reflux

temp in presence of Ethyl Cellulose and Catalyst for 12 hrs. Product is

clarified and send for packing.

Mass Balance:

INPUT KG OUTPUT KG


Benzaldehyde 150

HCl 150

Acetic Acid 300

Catalyst 20

Ethyl Cellulose 30

Oxygen 70

Sludge 50

Basic Green 4 Liquid 1000

Total 1050 1050

Mass Balance of Basic Green 4 Liquid

Condensation

Clarification


48. Basic Green 1


Benzaldehyde, N,N-diethylaniline and Acetic Acid are reacted at reflux

temp in presence of Catalyst for 12 hrs. Product is clarified and send for

packing.

Mass Balance:

INPUT KG OUTPUT KG

Di Ethylaniline 330

Benzaldehyde 110

Urea 40

Acetic Acid 500

Catalyst 20

Oxygen 50

Sludge 50

Basic Green 1 Liquid 1000

Total 1050 1050

Mass Balance of Basic Green 1 Liquid

Condensation

Clarification


49. Basic Blue 26


Para Formaldehyde, Phenyl alpha Napthyl amine, N,N-dimethylaniline and

Acetic Acid are reacted at reflux temp in presence of Catalyst for 12 hrs.

Product is clarified and send for packing.

Mass Balance:

INPUT KG OUTPUT KG



Phenyl Alpha naphthalamine 265

Acetic Acid 550

Catalyst 20

Oxygen 20

Drying Loss 175

Basic Blue 26 Liquid 1000

Total 1175 1175

Mass Balance of Basic Blue 26 Liquid

Condensation

Clarification

Annexure-III Photographs of the Site

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Annexure-IV Land Documents

Annexure-V Membership Certificate for disposal of

effluent at Common Spray Drying Facility

Annexure-VI Material Safety Data Sheet of Chemicals

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Material Safety Data SheetSulfuric acid MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sulfuric acid

Catalog Codes: SLS2539, SLS1741, SLS3166, SLS2371,SLS3793

CAS#: 7664-93-9

RTECS: WS5600000

TSCA: TSCA 8(b) inventory: Sulfuric acid

CI#: Not applicable.

Synonym: Oil of Vitriol; Sulfuric Acid

Chemical Name: Hydrogen sulfate

Chemical Formula: H2-SO4

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sulfuric acid 7664-93-9 95 - 98

Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m2 hours [Rat]. 320 mg/m 2 hours [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth andrespiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratorytract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation ofthe eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening,or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspected forhuman.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTALTOXICITY: Not available. The substance may be toxic to kidneys, lungs, heart, cardiovascular system, upper respiratory tract,eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged

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contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spraymist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion:Products of combustion are not available since material is non-flammable. However, products of decompostion include fumesof oxides of sulfur. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generatecarbon dioxide gas. Reacts with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

Fire Hazards in Presence of Various Substances: Combustible materials

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards:Metal acetylides (Monocesium and Monorubidium), and carbides ignite with concentrated sulfuric acid. White Phosphorous +boiling Sulfuric acid or its vapor ignites on contact. May ignite other combustible materials. May cause fire when sulfuric acidis mixed with Cyclopentadiene, cyclopentanone oxime, nitroaryl amines, hexalithium disilicide, phorphorous (III) oxide, andoxidizing agents such as chlorates, halogens, permanganates.

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Special Remarks on Explosion Hazards:M i x t u r e s o f s u l f u r i c a c i d a n d a n y o f t h e f o l l o w i n g c a n e x p l o d e : p - n i t r o t o l u e n e , p e n t a s il v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride, carbides, nitro compounds, nitrates,carbides, phosphorous, iodides, picratres, fulminats, dienes, alcohols (when heated) Nitramide decomposes explosivelyon contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosivedecompositon.

Section 6: Accidental Release Measures

Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentrationlevel above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducingagents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in ametallic or coated fiberboard drum using a strong polyethylene inner package.

Storage:Hygroscopic. Reacts. violently with water. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do notstore above 23°C (73.4°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:TWA: 1 STEL: 3 (mg/m3) [Australia] Inhalation TWA: 1 (mg/m3) from OSHA (PEL) [United States] Inhalation TWA: 1 STEL: 3(mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation TWA: 1 (mg/m3) from NIOSH [United States] Inhalation TWA: 1(mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

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Physical state and appearance: Liquid. (Thick oily liquid.)

Odor: Odorless, but has a choking odor when hot.

Taste: Marked acid taste. (Strong.)

Molecular Weight: 98.08 g/mole

Color: Colorless.

pH (1% soln/water): Acidic.

Boiling Point:270°C (518°F) - 340 deg. C Decomposes at 340 deg. C

Melting Point: -35°C (-31°F) to 10.36 deg. C (93% to 100% purity)

Critical Temperature: Not available.

Specific Gravity: 1.84 (Water = 1)

Vapor Pressure: Not available.

Vapor Density: 3.4 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility:Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Soluble in ethyl alcohol.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability:Conditions to Avoid: Incompatible materials, excess heat, combustible material materials, organic materials, exposure to moistair or water, oxidizers, amines, bases. Always add the acid to water, never the reverse.

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture.

Corrosivity:Extremely corrosive in presence of aluminum, of copper, of stainless steel(316). Highly corrosive in presence of stainlesssteel(304). Non-corrosive in presence of glass.

Special Remarks on Reactivity:Hygroscopic. Strong oxidizer. Reacts violently with water and alcohol especially when water is added to the product.Incompatible (can react explosively or dangerously) with the following: ACETIC ACID, ACRYLIC ACID, AMMONIUMHYDROXIDE, CRESOL, CUMENE, DICHLOROETHYL ETHER, ETHYLENE CYANOHYDRIN, ETHYLENEIMINE, NITRICACID, 2-NITROPROPANE, PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOLMONOMETHYL ETHER, ETHYL ACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHERACETATE, GLYOXAL, METHYL ETHYL KETONE, dehydrating agents, organic materials, moisture (water), Acetic anhydride,Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile+water, Alcohols + hydrogen peroxide, ally compounds such as Allyl alcohol, and Allyl Chloride, 2-Aminoethanol, Ammoniumhydroxide, Ammonium triperchromate, Aniline, Bromate + metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesiumacetylene carbide, Chlorates, Cyclopentanone oxime, chlorinates, Chlorates + metals, Chlorine trifluoride, Chlorosulfonicacid, 2-cyano-4-nitrobenzenediazonium hydrogen sulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-Dinitronaphthlene +

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sulfur, Diisobutylene, p-dimethylaminobenzaldehyde, 1,3-Diazidobenzene, Dimethylbenzylcarbinol + hydrogen peroxide,Epichlorohydrin, Ethyl alcohol + hydrogen peroxide, Ethylene diamine, Ethylene glycol and other glycols, , Ethylenimine,Fulminates, hydrogen peroxide, Hydrochloric acid, Hydrofluoric acid, Iodine heptafluoride, Indane + nitric acid, Iron, Isoprene,Lithium silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals (powdered), Nitromethane, Nitric acid + glycerides,p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate, Perchlorates, Perchloric acid, Permanganates + benzene, 1-Phenyl-2-methylpropyl alcohol + hydrogen peroxide, Phosphorus, Phosphorus isocyanate, Picrates, Potassium tert-butoxide,Potassium chlorate, Potassium Permanganate and other permanganates, halogens, amines, Potassium Permanganate +Potassium chloride, Potassium Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silverpermanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric acid, Vinyl acetate,Thalium (I) azidodithiocarbonate, Zinc chlorate, Zinc Iodide, azides, carbonates, cyanides, sulfides, sulfites, alkali hydrides,carboxylic acid anhydrides, nitriles, olefinic organics, aqueous acids, cyclopentadiene, cyano-alcohols, metal acetylides,Hydrogen gas is generated by the action of the acid on most metals (i.e. lead, copper, tin, zinc, aluminum, etc.). Concentratedsulfuric acid oxidizes, dehydrates, or sulfonates most organic compounds.

Special Remarks on Corrosivity:Non-corrosive to lead and mild steel, but dillute acid attacks most metals. Attacks many metals releasing hydrogen. Minorcorrosive effect on bronze. No corrosion data on brass or zinc.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2140 mg/kg [Rat.]. Acute toxicity of the vapor (LC50): 320 mg/m3 2 hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspectedfor human.) by ACGIH. May cause damage to the following organs: kidneys, lungs, heart, cardiovascular system, upperrespiratory tract, eyes, teeth.

Other Toxic Effects on Humans:Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,permeator), of eye contact (corrosive), of ingestion, .

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans:Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse reproductive effectsbased on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a dose of 20 mg/m3 for 7 hrs.(RTECS)Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses producing some maternaltoxicity

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis.Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May causepermanent damage to the digestive tract. Causes gastrointestial tract burns. May cause perforation of the stomach, GIbleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse(similar to acute inhalation). It mayalso cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucousmembranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratorytract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis,and pulmonary edema. Cause corrosive action on mucous membranes. May affect cardiovascular system (hypotension,depressed cardiac output, bradycardia). Circulatory collapse with clammy skin, weak and rapid pulse, shallow respiration, andscanty urine may follow. Circulatory shock is often the immediate cause of death. May also affect teeth(changes in teeth andsupporting structures - erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalationmay affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart(ischemic heart leisons), and respiratory system/lungs(pulmonary edema, lung damage), teeth (dental discoloration, erosion).Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.

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Section 12: Ecological Information

Ecotoxicity: Ecotoxicity in water (LC50): 49 mg/l 48 hours [bluegill/sunfish].

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:Sulfuric acid may be placed in sealed container or absorbed in vermiculite, dry sand, earth, or a similar material. It may alsobe diluted and neutralized. Be sure to consult with local or regional authorities (waste regulators) prior to any disposal. Wastemust be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Sulfuric acid UNNA: 1830 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sulfuric acid New York release reporting list: Sulfuric acid RhodeIsland RTK hazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid Minnesota: Sulfuric acid MassachusettsRTK: Sulfuric acid New Jersey: Sulfuric acid California Director's List of Hazardous Substances (8 CCR 339): Sulfuric acidTennessee RTK: Sulfuric acid TSCA 8(b) inventory: Sulfuric acid SARA 302/304/311/312 extremely hazardous substances:Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:Sulfuric acid: 1000 lbs. (453.6 kg)

Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):R35- Causes severe burns. S2- Keep out of the reach of children. S26- In case of contact with eyes, rinse immediately withplenty of water and seek medical advice. S30- Never add water to this product. S45- In case of accident or if you feel unwell,seek medical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

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Personal Protection:

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:

Protective Equipment:Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Face shield.

Section 16: Other Information

References:-Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec. -The Sigma-AldrichLibrary of Chemical Safety Data, Edition II. -Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., VanNostrand Reinold, 1987.

Other Special Considerations: Not available.

Created: 10/09/2005 11:58 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

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Material Safety Data SheetSulfuric acid, fuming, 20% MSDS


Product Name: Sulfuric acid, fuming, 20%

Catalog Codes: SLS1405

CAS#: 8014-95-7

RTECS: WS5605000

TSCA: TSCA 8(b) inventory: Sulfuric acid; Sulfur trioxide


Synonym: Oleum; Sulfuric Acid mixture with sulfurtrioxde; Fuming Sulfuric Acid

Chemical Name: Not applicable.

Chemical Formula: H2SO4 + 20% SO3









Composition:


Sulfuric acid 7664-93-9 76-82

Sulfur trioxide 7446-11-9 18-24

Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m2 hours [Rat]. 320 mg/m 2 hours [Mouse]. Sulfur trioxide LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightlyhazardous in case of inhalation (lung sensitizer). Liquid or spray mist may produce tissue damage particularly on mucousmembranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may producesevere irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure canresult in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterizedby itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC[Sulfuric acid, fuming]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL

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TOXICITY: Not available. The substance may be toxic to kidneys, lungs, heart, cardiovascular system, upper respiratory tract,eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolongedcontact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spraymist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.














Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat, of oxidizing materials.


Special Remarks on Fire Hazards:When heated to decomposition it emits highly toxic fumes. May ignite other combustible materials.

Special Remarks on Explosion Hazards:M i x t u r e s o f s u l f u r i c a c i d a n d a n y o f t h e f o l l o w i n g c a n e x p l o d e : p - n i t r o t o l u e n e , p e n t a s il v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,

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mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride. Nitramide decomposes explosivelyon contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosivedecompositon.





Precautions:Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from directsunlight or strong incandescent light. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.Avoid shock and friction. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medicaladvice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles suchas oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrodemetallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene inner package.

Storage:Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic; keep container tightly closed. Willreact with water or steam to produce heat and toxic fumes.





Exposure Limits:TWA: 1 (mg/m3) from NIOSH Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid. (Fuming oily liquid.)

Odor: sharp, penetrating, choking.

Taste: Not available.


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Color: Colorless to slight yellow/brown


Boiling Point: The lowest known value is 45°C (113°F) (Sulfur trioxide). Weighted average: 254.47°C (490°F)

Melting Point: May start to solidify at 16.8°C (62.2°F) based on data for: Sulfur trioxide. Weighted average: 11.29°C (52.3°F)

Critical Temperature: The lowest known value is 217.8°C (424°F) (Sulfur trioxide).


Vapor Pressure: Not available.

Vapor Density: The highest known value is 3.4 (Air = 1) (Sulfuric acid). Weighted average: 3.31 (Air = 1)






Solubility:Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Reacts violently with water.




Conditions of Instability: Moist air, water, excess heat, incompatible materials

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture. Theproduct may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxicgases or it may become self-reactive under conditions of shock or increase in temperature or pressure.

Corrosivity:Extremely corrosive in presence of copper. Highly corrosive in presence of steel, of aluminum, of stainless steel(304), ofstainless steel(316). Non-corrosive in presence of glass.

Special Remarks on Reactivity:Hygroscopic; keep container tightly closed. Will react with water or steam to produce heat and toxic fumes. Incompatiblewith ACETIC ACID, ACRYLIC ACID, AMMONIUM HYDROXIDE, CRESOL, CUMENE, D I C H L O R O E T H Y L E TH E R , E T H Y L E N E C Y A N O H Y D R I N , E T H Y L E N E I M I N E , N I T R I C A C I D , 2-NITROPROPANE,PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOL MONOMETHYL ETHER, ETHYLACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHER ACETATE, GLYOXAL, METHYLETHYL KETONE, dehydrating agents, organic materials, moisture, Acetic anhydride, Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile+water, Alcohols + hydrogenperoxide, Allyl alcohol, Allyl Chloride, 2-Aminoethanol, Ammonium hydroxide, Ammonium triperchromate, Aniline, Bromate+ metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesium acetylene carbide, Chlorates, Cyclopentanone oxime,chlorinates, Chlorated + metals, Chlorine trifluoride, Chlorosulfonic acid, 2-cyano-4-nitrobenzenediazonium hydrogensulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-Dinitronaphthlene + sulfur, Diisobutylene, p-dimethylaminobenzaldehyde,1,3-Diazidobenzene, Dimethylbenzylcarbinol + hydrogen peroxide, Epichlorohydrin, Ethyl alcohol + hydrogen peroxide,Ethylene diamine, Ethylene glycol, Ethylenimine, Fulminates, hydrogen peroxide, Hydrochloric acid, Hydrofluoric acid, Iodineheptafluoride, Indane + nitric acid, Iron, Isoprene, Lithium silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals(powdered), Nitromethane, Nitric acid + glycerides, p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate Perchlorates,Perchloric acid, Permanganates + benzene, 1-Phenyl-2-methylpropyl alcohol + hydrogen peroxide, Phosphorus, Phosphorusisocyanate, Picrates, Potassium tert-butoxide, Potassium chlorate, Potassium Permanganate, Potassium Permanganate +Potassium chloride, Potassium Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silver

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permanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric acid, Vinyl acetate,Thalium (I) azidodithiocarbonate, Zinc chlorate, Zinc Iodide.

Special Remarks on Corrosivity:Minor corrosive effect on bronze. No corrosion data for brass or zinc.




Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2140 mg/kg [Rat.]. (Sulfuric acid). Acute toxicity of the vapor (LC50): 347 1 hours [Rat]. (Sulfuric Acid, fuming)

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC [Sulfuric acid, fuming]. May cause damage to thefollowing organs: kidneys, lungs, heart, cardiovascular system, upper respiratory tract, eyes, teeth.


Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LCL [Guinea Pig]- Route: Inhalation; Dose 30 mg/m3/6H (Sulfur trioxide)

Special Remarks on Chronic Effects on Humans:Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse reproductive effectsbased on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a dose of 20 mg/m3 for 7 hrs.(RTECS)Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses producing some maternaltoxicity (Sulfuric acid)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis.Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May causepermanent damage to the digestive tract. Causes gastrointestial tract burns. May cause perforation of the stomach, GIbleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse(similar to acute inhalation). It mayalso cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucousmembranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratorytract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis,and pulmonary edema. Cause corrosive action on mucous membranes. May affect cardiovascular system (hypotension,depressed cardiac output, bradycardia). Circulatory collapse with clammy skin, weak and rapid pulse, shallow respiration, andscanty urine may follow. Circulatory shock is often the immediate cause of death. May also affect teeth(changes in teeth andsupporting structures - erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalationmay affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart(ischemic heart leisons), and respiratory system/lungs(pulmonary edema, lung damage), teeth (dental discoloration, erosion).Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.


Ecotoxicity: Not available.





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Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.



Identification: : Sulfuric acid, fuming (Sulfuric acid) UNNA: 1831 PG: I

Special Provisions for Transport: Poison inhalation hazard zone B (Sulfur trioxide)


Federal and State Regulations:Connecticut hazardous material survey.: Sulfur trioxide Illinois toxic substances disclosure to employee act: Sulfuric acidIllinois chemical safety act: Sulfur trioxide New York release reporting list: Sulfuric acid; Sulfur trioxide Rhode Island RTKhazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid; Sulfur trioxide Minnesota: Sulfuric acid MassachusettsRTK: Sulfuric acid; Sulfur trioxide Massachusetts spill list: Sulfur trioxide New Jersey: Sulfuric acid; Sulfur trioxide New Jerseyspill list: Sulfur trioxide New Jersey toxic catastrophe prevention act: Sulfur trioxide Louisiana RTK reporting list: Sulfur trioxideTSCA 8(b) inventory: Sulfuric acid; Sulfur trioxide SARA 302/304/311/312 extremely hazardous substances: Sulfuric acid;Sulfur trioxide SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:Sulfuric acid: 1000 lbs. (453.6 kg); Sulfur trioxide: 100 lbs. (45.36 kg);

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).


WHMIS (Canada):CLASS E: Corrosive liquid. CLASS F: Dangerously reactive material.

DSCL (EEC):R14- Reacts violently with water. R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plentyof water and seek medical advice. S30- Never add water to this product. S45- In case of accident or if you feel unwell, seekmedical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2



Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:



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References: Not available.


Created: 10/09/2005 11:59 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSodium hydroxide MSDS


Product Name: Sodium hydroxide

Catalog Codes: SLS3298, SLS1081, SLS2503, SLS3925,SLS1705

CAS#: 1310-73-2

RTECS: WB4900000

TSCA: TSCA 8(b) inventory: Sodium hydroxide

CI#: Not available.

Synonym: Caustic Soda

Chemical Name: Sodium Hydroxide

Chemical Formula: NaOH









Composition:


Sodium hydroxide 1310-73-2 100

Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,of inhalation. The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage orblindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal orrespiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation ischaracterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic tomucous membranes, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce targetorgans damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure canproduce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation orlung damage.

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Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.



Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or waistband.








Fire Hazards in Presence of Various Substances: metals

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat.

Fire Fighting Media and Instructions: Not available

Special Remarks on Fire Hazards:sodium hydroxide + zinc metal dust causes ignition of the latter. Under proper conditions of temperature, pressure and stateof division, it can ignite or react violently with acetaldehyde, ally alcohol, allyl chloride, benzene-1,4-diol, chlorine trifluoride,1,2 dichlorethylene, nitroethane, nitromethane, nitroparaffins, nitropropane, cinnamaldehyde, 2,2-dichloro-3,3-dimethylbutane.Sodium hydroxide in contact with water may generate enough heat to ignite adjacent combustible materials. Phosphorousboiled with NaOH yields mixed phosphines which may ignite spontanously in air. sodium hydroxide and cinnamaldehyde +heat may cause ignition. Reaction with certain metals releases flammable and explosive hydrogen gas.

Special Remarks on Explosion Hazards:Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonateprepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, under vacuumdistillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrofuran, which can contain peroxides, can

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cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat tocause an explosion.


Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue witha dilute solution of acetic acid.

Large Spill:Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration levelabove TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitablerespiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skinand eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic. Deliquescent.


Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.

Personal Protection:Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used toavoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handlingthis product.

Exposure Limits:STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/m3) from NIOSHConsult local authorities for acceptable exposure limits.


Physical state and appearance: Solid. (Deliquescent solid.)

Odor: Odorless.


Molecular Weight: 40 g/mole

Color: White.

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pH (1% soln/water): 13.5 [Basic.]

Boiling Point: 1388°C (2530.4°F)

Melting Point: 323°C (613.4°F)



Vapor Pressure: Not applicable.

Vapor Density: Not available.






Solubility: Easily soluble in cold water.




Conditions of Instability: Incompatible materials, moisture, moist air

Incompatibility with various substances:Highly reactive with metals. Reactive with oxidizing agents, reducing agents, acids, alkalis, moisture.

Corrosivity: Not available.

Special Remarks on Reactivity:Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must be usedfor this process. Sodium hydroxide solution and octanol + diborane during a work-up of a reaction mixture of oxime anddiborane in tetrahyrofuran is very exothermic, a mild explosion being noted on one occassion. Reactive with water, acids(mineral, non-oxidizing, e.g. hydrochloric, hydrofluoric acid, muriatic acid, phosphoric), acids (mineral, oxidizing e.g. chromicacid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic e.g. acetic acid, benzoic acid, formic acid, methanoic acid,oxalic acid), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, foraldehyde), carbamates (e.g. carbanolate, carbofuran),esters (e.g. butyl acetate, ethyl acetate, propyl formate), halogenated organics (dibromoethane, hexachlorobenzene, methylchloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (acetone, acetophenone, MEK, MIBK), acidchlorides, strong bases, strong oxidizing agents, strong reducing agents, flammable liquids, powdered metals and metals (i.ealuminum, tin, zinc, hafnium, raney nickel), metals (alkali and alkaline e.g. cesium, potassium, sodium), metal compounds(toxic e.g. berylium, lead acetate, nickel carbonyl, tetraethyl lead), mitrides (e.g. potassium nitride, sodium nitride), nitriles(e.g. acetonitrile, methyl cyanide), nitro compounds (organic e.g. nitrobenzene, nitromethane), acetic anhydride, chlorohydrin,chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrosulfuric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide,chloroethanol, chloroform-methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reactswith formaldehyde hydroxide to yield formic acid, and hydrogen.

Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture.




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Toxicity to Animals:LD50: Not available. LC50: Not available.

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: mucousmembranes, upper respiratory tract, skin, eyes.


Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Rabbit] - Route: Oral; Dose: 500 mg/kg

Special Remarks on Chronic Effects on Humans: May affect genetic material. Investigation as a mutagen (cytogeneticanalysis)

Special Remarks on other Toxic Effects on Humans:





Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.






Identification: : Sodium hydroxide, solid UNNA: 1823 PG: II



Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide NewYork release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide PennsylvaniaRTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxideLouisiana spill reporting: Sodium hydroxide California Director's List of Hazardous Substances: Sodium hydroxide TSCA 8(b)inventory: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6 kg)


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WHMIS (Canada): CLASS E: Corrosive solid.

DSCL (EEC):R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S37/39- Wear suitable gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical adviceimmediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

Personal Protection: j


Health: 3

Flammability: 0

Reactivity: 1

Specific hazard:

Protective Equipment:Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Splash goggles.




Created: 10/09/2005 06:32 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetAniline MSDS


Product Name: Aniline

Catalog Codes: SLA1735

CAS#: 62-53-3

RTECS: BW6650000

TSCA: TSCA 8(b) inventory: Aniline


Synonym: Aminobenzene; Benzenamine; Aminophen

Chemical Name: Aniline

Chemical Formula: C6H5NH2









Composition:


Aniline 62-53-3 100

Toxicological Data on Ingredients: Aniline: ORAL (LD50): Acute: 250 mg/kg [Rat.]. 464 mg/kg [Mouse]. DERMAL (LD50):Acute: 820 mg/kg [Rabbit.]. 1400 mg/kg [Rat].


Potential Acute Health Effects:Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Severe over-exposure can result in death.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified A3 (Proven for animal.) byACGIH. 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenicfor bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Thesubstance may be toxic to blood, kidneys, liver, bladder, spleen, cardiovascular system, central nervous system (CNS).Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a


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Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention. Finish by rinsing thoroughly with running water to avoid a possibleinfection.

Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.







Flammability of the Product: Combustible.

Auto-Ignition Temperature: 615°C (1139°F)

Flash Points: CLOSED CUP: 70°C (158°F).

Flammable Limits: LOWER: 1.3% UPPER: 23%

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).

Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.

Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards:Ignites on contact with sodium peroxide + water. Aniline ignites spontaneously in presence of red fuming nitric acid. Sodiumperoxide or potassium peroxide is spontaneouly flammable with aniline. When heated to decomposition it emits toxic fumes.

Special Remarks on Explosion Hazards:Spontaneously explosive reactions occur with benzenediazonium -2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosylperchlorate, red fuming nitric acid, peroxodisulfuric acid, and tetranitromethane. Addition of a drop of aniline to 1 gram ofdibenzoyl peroxide leads to mildly explosive decompostion after a short delay. Addition of aniline to nitromethane renders itsusceptible to initiation by a detonator. Anililne reacts with perchloric acid, and then formaldehyde to produce explosive andcombustible condensed resin.

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Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of acetic acid.

Large Spill:Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Neutralize theresidue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level above TLV.Check TLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals, acids, alkalis.

Storage:Air and light sensitive. Store in light-resistance container. Keep container in a cool, well-ventilated area. Keep container tightlyclosed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).



Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.


Exposure Limits:TWA: 7.6 (mg/m3) from ACGIH (TLV) [United States] SKIN TWA: 2 (ppm) from ACGIH (TLV) [United States] SKIN TWA: 2[Canada] TWA: 7.6 (mg/m3) [Canada] TWA: 5 (ppm) from OSHA (PEL) [United States] TWA: 19 (mg/m3) from OSHA (PEL)[United States] TWA: 1 (ppm) [United Kingdom (UK)] TWA: 4 (mg/m3) [United Kingdom (UK)]Consult local authorities foracceptable exposure limits.


Physical state and appearance: Liquid. (Oily liquid.)

Odor: Aromatic. Amine like.

Taste: Burning.


Color: Colorless.

pH (1% soln/water): Basic.

Boiling Point: 184.1°C (363.4°F)

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Melting Point: -6°C (21.2°F)

Critical Temperature: 425.6°C (798.1°F)


Vapor Pressure: 0.1 kPa (@ 20°C)



Odor Threshold: 2.4 ppm

Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 0.9


Dispersion Properties: See solubility in water, methanol, diethyl ether.

Solubility: Soluble in cold water, hot water, methanol, diethyl ether.




Conditions of Instability: Not available.

Incompatibility with various substances: Reactive with oxidizing agents, metals, acids, alkalis.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:Air and light sensitive. May darken on exposure to light or air. Incompatible with strong oxidizing agents , strong acids, bases,aluminum, fluorine, formaldehyde, iron, nitric acid, silver perchlorate, sodium peroxide, sulfuric acid, zinc, hydrogen peroxide,benzenediazonium-2-carboxylate, boron trichloride, tetranitromethane, trichloronitromethane, diisopropyl peroxydicarbonate,hexachloromelamine, peroxomonosulfuric acid, albumin, iron salts, perchloric acid, nitrobenzene, alkalis, potassiumperoxide, glycerine , fuming nitric acid, peroxydisulfuric acid, N-chloro compounds, N-bromides (e.g. n-bromosuccinimide),nitrosyl fluroide, toluene diisocyanate, performic acid. Formaldehyde + aniline reacts violently with 90% performic acid,acetic anhyride. Aniline + trichloronitromethane can produce a violent reaction. Aniline can react vigorously with oxidizingmaterials. Violent reactions can occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane,chlorosulfonic acid, peroxydisulfuric acid, FO3Cl, nitric acid + N2O4 + sulfuric acid, b-propiolactone, AgClO4.

Special Remarks on Corrosivity: Not available.




Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 250 mg/kg [Rat.]. Acute dermal toxicity (LD50): 820 mg/kg [Rabbit.]. Acute toxicity of the vapor (LC50): 175 7hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified A3 (Proven for animal.) by ACGIH. 3 (Not classifiable for human.) by IARC.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage tothe following organs: blood, kidneys, liver, bladder, spleen, cardiovascular system, central nervous system (CNS).

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

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Special Remarks on Chronic Effects on Humans:May affect genetic materials. May cause adverse reproductive effects. It may cause cancer. However, IARC has foundinadequate evidence in humans. Human: passes through the placenta.

Special Remarks on other Toxic Effects on Humans:










DOT Classification: CLASS 6.1: Poisonous material.

Identification: : Aniline UNNA: 1547 PG: II



Federal and State Regulations:California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,birth defects or other reproductive harm, which would require a warning under the statute: Aniline California prop. 65 (nosignificant risk level): Aniline: 0.1 mg/day (value) California prop. 65: This product contains the following ingredients forwhich the State of California has found to cause cancer which would require a warning under the statute: Aniline Connecticuthazardous material survey.: Aniline Illinois toxic substances disclosure to employee act: Aniline Illinois chemical safetyact: Aniline New York release reporting list: Aniline Rhode Island RTK hazardous substances: Aniline Pennsylvania RTK:Aniline Minnesota: Aniline Massachusetts RTK: Aniline Massachusetts spill list: Aniline New Jersey: Aniline New Jerseyspill list: Aniline Louisiana RTK reporting list: Aniline Louisiana spill reporting: Aniline California Director's List of HazardousSubstances: Aniline TSCA 8(b) inventory: Aniline TSCA 8(a) IUR: Aniline TSCA 8(d) H and S data reporting: Aniline: 10/4/92SARA 302/304/311/312 extremely hazardous substances: Aniline SARA 313 toxic chemical notification and release reporting:Aniline CERCLA: Hazardous substances.: Aniline: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-1A: Material causingimmediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC).

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DSCL (EEC):R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. R36/38- Irritating to eyes and skin. R40- Possible risksof irreversible effects. S2- Keep out of the reach of children. S28- After contact with skin, wash immediately with plenty ofwater. S36/37- Wear suitable protective clothing and gloves. S46- If swallowed, seek medical advice immediately and showthis container or label.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0

Personal Protection: h


Health: 3

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.


References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -Material safetydata sheet emitted by: la Commission de la SantÃ© et de la SÃ©curitÃ© du Travail du QuÃ©bec. -SAX, N.I. DangerousProperties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of Chemical SafetyData, Edition II. -Guide de la loi et du rÃ¨glement sur le transport des marchandises dangeureuses au canada. Centre deconformitÃ© internatinal LtÃ©e. 1986. Registery of Toxic Effects of Chemical Substances (RTECS) database, REPROTEXTdata base, Ariel Global View database.


Created: 10/11/2005 11:19 AM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetHydrochloric acid MSDS


Product Name: Hydrochloric acid

Catalog Codes: SLH1462, SLH3154

CAS#: Mixture.

RTECS: MW4025000

TSCA: TSCA 8(b) inventory: Hydrochloric acid


Synonym: Hydrochloric Acid; Muriatic Acid


Chemical Formula: Not applicable.









Composition:


Hydrogen chloride 7647-01-0 20-38

Water 7732-18-5 62-80

Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightlyhazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid or spray mist may produce tissue damageparticularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of thespray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath.Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skininflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable forhuman.) by IARC [Hydrochloric acid]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upperrespiratory tract, skin, eyes, Circulatory System, teeth. Repeated or prolonged exposure to the substance can produce target

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organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchialinfection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in oneor many human organs.







Ingestion:If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.








Fire Hazards in Presence of Various Substances: of metals

Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.


Special Remarks on Fire Hazards:Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reacts withhydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warmhydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid isused, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid producesspontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact withhydrochloric acid unless acid is dilute. Reacts with most metals to produce flammable Hydrodgen gas.

Special Remarks on Explosion Hazards:

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Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction:Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Aminoethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesiumcarbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithiumdisilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate,beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodiumhydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbontetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C.





Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organicmaterials, metals, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strongpolyethylene inner package.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.





Exposure Limits:CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3) from OSHA (PEL) [United States] CEIL: 5 from NIOSHCEIL: 7 (mg/m3) from NIOSH TWA: 1 STEL: 5 (ppm) [United Kingdom (UK)] TWA: 2 STEL: 8 (mg/m3) [United Kingdom(UK)]Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid.

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Odor: Pungent. Irritating (Strong.)


Molecular Weight: Not applicable.

Color: Colorless to light yellow.


Boiling Point:108.58 C @ 760 mm Hg (for 20.22% HCl in water) 83 C @ 760 mm Hg (for 31% HCl in water) 50.5 C (for 37% HCl in water)

Melting Point:-62.25°C (-80°F) (20.69% HCl in water) -46.2 C (31.24% HCl in water) -25.4 C (39.17% HCl in water)


Specific Gravity:1.1- 1.19 (Water = 1) 1.10 (20%and 22% HCl solutions) 1.12 (24% HCl solution) 1.15 (29.57% HCl solution) 1.16 (32% HClsolution) 1.19 (37% and 38%HCl solutions)

Vapor Pressure: 16 kPa (@ 20°C) average



Odor Threshold: 0.25 to 10 ppm



Dispersion Properties: See solubility in water, diethyl ether.

Solubility: Soluble in cold water, hot water, diethyl ether.




Conditions of Instability: Incompatible materials, water

Incompatibility with various substances:Highly reactive with metals. Reactive with oxidizing agents, organic materials, alkalis, water.

Corrosivity:Extremely corrosive in presence of aluminum, of copper, of stainless steel(304), of stainless steel(316). Non-corrosive inpresence of glass.

Special Remarks on Reactivity:Reacts with water especially when water is added to the product. Absorption of gaseous hydrogen chloride on mercuricsulfate becomes violent @ 125 deg. C. Sodium reacts very violently with gaseous hydrogen chloride. Calcium phosphideand hydrochloric acid undergo very energetic reaction. It reacts with oxidizers releasing chlorine gas. Incompatible with,alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides, phosphides, cyanides, carbonates. Reactswith most metals to produce flammable Hydrogen gas. Reacts violently (moderate reaction with heat of evolution) withwater especially when water is added to the product. Isolate hydrogen chloride from heat, direct sunlight, alkalies (reactsvigorously), organic materials, and oxidizers (especially nitric acid and chlorates), amines, metals, copper and alloys (e.g.brass), hydroxides, zinc (galvanized materials), lithium silicide (incandescence), sulfuric acid(increase in temperature andpressure) Hydrogen chloride gas is emitted when this product is in contact with sulfuric acid. Adsorption of Hydrochloric Acidonto silicon dioxide results in exothmeric reaction. Hydrogen chloride causes aldehydes and epoxides to violently polymerize.Hydrogen chloride or Hydrochloric Acid in contact with the folloiwng can cause explosion or ignition on contact or

Special Remarks on Corrosivity:

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Highly corrosive. Incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum,silver, and certain alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys.No corrosivity data on zinc, steel. Severe Corrosive effect on brass and bronze



Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.

Toxicity to Animals:Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity ofthe vapor (LC50): 3124 ppm, 1 hours [Rat].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric acid]. May cause damage to thefollowing organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (corrosive, irritant, permeator), of ingestion, . Hazardous in case of eye contact(corrosive), of inhalation (lung corrosive).

Special Remarks on Toxicity to Animals:Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M

Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fetoxicity). May affect genetic material.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severeeye irritation/conjuntivitis, burns, corneal necrosis. Inhalation: May be fatal if inhaled. Material is extremely destructive totissue of the mucous membranes and upper respiratory tract. Inhalation of hydrochloric acid fumes produces nose, throat,and larryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, hoarseness, laryngealspasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations. Inhalation of high concentrationscan result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, nasospetal perforation,glottal closure, occur, particularly if exposure is prolonged. May affect the liver. Ingestion: May be fatal if swallowed. Causesirritation and burning, ulceration, or perforation of the gastrointestinal tract and resultant peritonitis, gastric hemorrhage andinfection. Can also cause nausea, vomitting (with "coffee ground" emesis), diarrhea, thirst, difficulty swallowing, salivation,chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect behavior (excitement), thecardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary system (kidneys- renalfailure, nephritis). Acute exposure via inhalation or ingestion can also cause erosion of tooth enamel. Chronic Potential HealthEffects: dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also








Waste Disposal:

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Waste must be disposed of in accordance with federal, state and local environmental control regulations.



Identification: : Hydrochloric acid, solution UNNA: 1789 PG: II



Federal and State Regulations:Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloricacid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTKhazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid MassachusettsRTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid CaliforniaDirector's List of Hazardous Substances: Hydrochloric acid TSCA 8(b) inventory: Hydrochloric acid TSCA 4(a) proposed testrules: Hydrochloric acid SARA 302/304/311/312 extremely hazardous substances: Hydrochloric acid SARA 313 toxic chemicalnotification and release reporting: Hydrochloric acid CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):R34- Causes burns. R37- Irritating to respiratory system. S26- In case of contact with eyes, rinse immediately with plenty ofwater and seek medical advice. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the labelwhere possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 1



Health: 3

Flammability: 0

Reactivity: 1

Specific hazard:



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References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library ofChemical Safety Data, Edition II. -Guide de la loi et du règlement sur le transport des marchandises dangeureuses au canada.Centre de conformité internatinal Ltée. 1986.


Created: 10/09/2005 05:45 PM

Last Updated: 05/21/2013 12:00 PM


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Concentrated Nitric Acid, 98% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date: November 2017

Version: 1.0

November 2017 EN (English US) 1/10

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY Product Identifier Product Name: Concentrated Nitric Acid, 98% Synonyms: Hydrogen Nitrate, Aqua Fortis, White Fuming Nitric Acid Intended Use of the Product Not available Name, Address, and Telephone of the Responsible Party

Company El Dorado Chemical Company 4500 North West Ave. P.O. Box 231 El Dorado, AR 71731 T (870) 863-1400 - F (870)-863-1126

Emergency Telephone Number Emergency number : (870) 863-1400, (800) 424-9300 (CHEMTREC, 24 hours)

SECTION 2: HAZARDS IDENTIFICATION

Classification of the Substance or Mixture Classification (GHS-US) Ox. Liq. 3 H272 Met. Corr. 1 H290 Skin Corr. 1A H314 Eye Dam. 1 H318

Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) :

GHS03

GHS05

Signal Word (GHS-US) : Danger

Hazard Statements (GHS-US) : H272 - May intensify fire; oxidizer H290 - May be corrosive to metals H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage

Precautionary Statements (GHS-US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking. P220 - Keep/Store away from extremely high or low temperatures, ignition sources, combustible materials, incompatible materials. P221 - Take any precaution to avoid mixing with incompatible materials, ignition sources, combustible materials. P234 - Keep only in original container. P260 - Do not breathe vapors, mist, spray. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P280 - Wear protective gloves, protective clothing, eye protection, face protection, respiratory protection. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER or doctor/physician.

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Concentrated Nitric Acid, 98% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations


P321 - Specific treatment (see section 4). P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use appropriate media for extinction. P390 - Absorb spillage to prevent material damage. P405 - Store locked up. P406 - Store in corrosive resistant container with a resistant inner liner. P501 - Dispose of contents/container to local, regional, national, territorial, provincial, and international regulations.

Other Hazards Other Hazards Not Contributing to the Classification: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. May cause or intensify fire; oxidizer. When heated to decomposition, emits toxic fumes. Contact with metals may evolve flammable hydrogen gas.

Unknown Acute Toxicity (GHS-US) Not available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Mixture

Name Product identifier % (w/w) Classification (GHS-US)

Nitric acid (CAS No) 7697-37-2 97.5 - 100 Ox. Liq. 3, H272 Met. Corr. 1, H290 Skin Corr. 1A, H314 Eye Dam. 1, H318

Full text of H-phrases: see section 16

SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call for medical assistance.

Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Immediately call for medical assistance. Wash contaminated clothing before reuse.

Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call for medical assistance.

Ingestion: Rinse mouth. Do NOT induce vomiting. Immediately call for medical assistance.

Most Important Symptoms and Effects Both Acute and Delayed General: Causes severe skin burns and eye damage. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.

Skin Contact: Causes severe irritation which will progress to chemical burns.

Eye Contact: Causes serious eye damage.

Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms: May cause erosion of the teeth, or chronic bronchitis.

Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention.

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SECTION 5: FIREFIGHTING MEASURES

Extinguishing Media

Special Hazards Arising From the Substance or Mixture

Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Nitrogen oxides. Acrid vapors. Corrosive vapors. Other information: Do not allow run-off from fire fighting to enter drains or water courses. Contact with metals may evolve flammable hydrogen gas. Use water spray to disperse vapors. Reference to Other Sections Refer to section 9 for flammability properties.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures

General Measures: Do NOT breathe (vapors, mist, spray). Avoid all contact with skin, eyes, or clothing. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area.

Environmental Precautions

Prevent entry to sewers and public waters.

Methods and Material for Containment and Cleaning Up

For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Cautiously neutralize spilled liquid with crushed limestone, soda ash or lime. CAUTION : Neutralization can produce vigorous reaction, boiling and fumes. Use extreme caution in clean-up procedure. As an immediate precautionary measure, isolate spill or leak area in all directions. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Absorb spillage to prevent material damage. Cautiously neutralize spilled liquid with crushed limestone, soda ash or lime. CAUTION : Neutralization can produce vigorous reaction, boiling and fumes. Use extreme caution in clean-up procedure. Contact competent authorities after a spill.

Reference to Other Sections See section 8, Exposure Controls and Personal Protection.

SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: May be corrosive to metals. When heated to decomposition, emits toxic fumes. Corrosive vapors are released. Contact with metals may evolve flammable hydrogen gas. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do no eat, drink or smoke when using this product. Wash hands and forearms thoroughly after handling.

Suitable Extinguishing Media: Water spray, fog, carbon dioxide, foam, dry chemical. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.

Fire Hazard: May intensify fire; oxidizer. Will burn if exposed to heat, and in addition, will accelerate the burning of other combustibles, resulting in more rapid spread of fire. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. In contact with metals, emits flammable/explosive gas. May cause fire or explosion; strong oxidizer. Reactivity: Thermal decomposition generates : toxic/corrosive vapors. Can react explosively with reducing agents, metal powders, Hydrogen sulfide, nitrate, and organic materials. Contact with metals may evolve flammable hydrogen gas.

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Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof electrical, ventilating, and lighting equipment. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place. Keep/Store away from extremely high or low temperatures, direct sunlight, heat, ignition sources, combustible materials, incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Finely divided metals. Hydrogen sulfide. Reducing agents. Organic materials.

Specific End Use(s) Not available

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters

Nitric acid (7697-37-2)

Mexico OEL TWA (mg/m³) 5 mg/m³

Mexico OEL TWA (ppm) 2 ppm

Mexico OEL STEL (mg/m³) 10 mg/m³

Mexico OEL STEL (ppm) 4 ppm

USA ACGIH ACGIH TWA (ppm) 2 ppm

USA ACGIH ACGIH STEL (ppm) 4 ppm

USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³

USA OSHA OSHA PEL (TWA) (ppm) 2 ppm

USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³

USA NIOSH NIOSH REL (TWA) (ppm) 2 ppm

USA NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³

USA NIOSH NIOSH REL (STEL) (ppm) 4 ppm

USA IDLH US IDLH (ppm) 25 ppm

Alberta OEL STEL (mg/m³) 10 mg/m³

Alberta OEL STEL (ppm) 4 ppm

Alberta OEL TWA (mg/m³) 5.2 mg/m³

Alberta OEL TWA (ppm) 2 ppm

British Columbia OEL STEL (ppm) 4 ppm

British Columbia OEL TWA (ppm) 2 ppm

Manitoba OEL STEL (ppm) 4 ppm

Manitoba OEL TWA (ppm) 2 ppm

New Brunswick OEL STEL (mg/m³) 10 mg/m³

New Brunswick OEL STEL (ppm) 4 ppm

New Brunswick OEL TWA (mg/m³) 5.2 mg/m³

New Brunswick OEL TWA (ppm) 2 ppm

Newfoundland & Labrador OEL STEL (ppm) 4 ppm

Newfoundland & Labrador OEL TWA (ppm) 2 ppm

Nova Scotia OEL STEL (ppm) 4 ppm

Nova Scotia OEL TWA (ppm) 2 ppm

Nunavut OEL STEL (mg/m³) 10 mg/m³

Nunavut OEL STEL (ppm) 4 ppm

Nunavut OEL TWA (mg/m³) 5.2 mg/m³

Nunavut OEL TWA (ppm) 2 ppm

Northwest Territories OEL STEL (mg/m³) 10 mg/m³

Northwest Territories OEL STEL (ppm) 4 ppm

Northwest Territories OEL TWA (mg/m³) 5.2 mg/m³

Northwest Territories OEL TWA (ppm) 2 ppm

Ontario OEL STEL (ppm) 4 ppm

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Ontario OEL TWA (ppm) 2 ppm

Prince Edward Island OEL STEL (ppm) 4 ppm

Prince Edward Island OEL TWA (ppm) 2 ppm

Québec VECD (mg/m³) 10 mg/m³

Québec VECD (ppm) 4 ppm

Québec VEMP (mg/m³) 5.2 mg/m³

Québec VEMP (ppm) 2 ppm

Saskatchewan OEL STEL (ppm) 4 ppm

Saskatchewan OEL TWA (ppm) 2 ppm

Yukon OEL STEL (mg/m³) 10 mg/m³

Yukon OEL STEL (ppm) 4 ppm

Yukon OEL TWA (mg/m³) 5 mg/m³

Yukon OEL TWA (ppm) 2 ppm

Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use explosion-proof equipment. Ensure all national/local regulations are observed. Alarm detectors should be used when toxic gases may be released. Gas detectors should be used when flammable gases/vapors may be released.

Personal Protective Equipment: Gloves. Respiratory protection of the dependent type. Protective goggles. Protective clothing.

Materials for Protective Clothing: Chemically resistant materials and fabrics. Corrosion-proof clothing. Wear fire/flame resistant/retardant clothing.

Hand Protection: Wear chemically resistant protective gloves. Acid-resistant protective gloves.

Eye Protection: Chemical goggles or face shield.

Skin and Body Protection: Wear suitable protective clothing.

Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of vapor or mist are expected to exceed exposure limits.

Other Information: When using, do not eat, drink or smoke.

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties Physical State : Liquid

Appearance : Colorless,light brown

Odor : Acrid

Odor Threshold : Not available

pH : < 1

Relative Evaporation Rate (butylacetate=1) : > 1

Melting Point : Not available

Freezing Point : -41.1 °C (-42°F)

Boiling Point : 83.9 °C (183°F)

Flash Point : Not available

Auto-ignition Temperature : Not available

Decomposition Temperature : Not available

Flammability (solid, gas) : Not available

Lower Flammable Limit : Not available

Upper Flammable Limit : Not available

Vapor Pressure : 51 mm Hg @25°C (77°F)

Relative Vapor Density at 20 °C : >1

Relative Density : Not available

Specific Gravity : 1.51

Solubility : Miscible.

Viscosity : 1 cp @20°C (68°F)

Volatility : 100% Explosion Data – Sensitivity to Mechanical Impact : Not available

Explosion Data – Sensitivity to Static Discharge : Not available

SECTION 10: STABILITY AND REACTIVITY

Reactivity: Thermal decomposition generates : toxic/corrosive vapors. Can react explosively with reducing agents, metal powders, Hydrogen sulfide, nitrate, and organic materials. Contact with metals may evolve flammable hydrogen gas.

Chemical Stability: May intensify fire; oxidizer.

Possibility of Hazardous Reactions: Hazardous polymerization will not occur.

Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Overheating. Open flame. Incompatible materials. Adding water to acid should be avoided.

Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Metals. May be corrosive to metals. Reducing agents. Amines.

Hazardous Decomposition Products: Thermal decomposition generates : Corrosive vapors. Nitrogen oxides. Explosive hydrogen gas. Toxic vapors.

SECTION 11: TOXICOLOGICAL INFORMATION

Information on Toxicological Effects - Product

LD50 and LC50 Data: Not available

Skin Corrosion/Irritation: Causes severe skin burns and eye damage. pH: < 1

Serious Eye Damage/Irritation: Causes serious eye damage. pH: < 1

Respiratory or Skin Sensitization: Not classified

Germ Cell Mutagenicity: Not classified

Teratogenicity: Not available

Carcinogenicity: Not classified

Specific Target Organ Toxicity (Repeated Exposure): Not classified

Reproductive Toxicity: Not classified

Acute Toxicity: Not classified.

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Specific Target Organ Toxicity (Single Exposure): Not classified

Aspiration Hazard: Not classified

Symptoms/Injuries After Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.

Symptoms/Injuries After Skin Contact: Causes severe irritation which will progress to chemical burns.

Symptoms/Injuries After Eye Contact: Causes serious eye damage.

Symptoms/Injuries After Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms: May cause erosion of the teeth, or chronic bronchitis. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data:


LC50 Inhalation Rat (mg/l) 0.13 mg/l (Exposure time: 4 h)

LC50 Inhalation Rat (ppm) 67 ppm/4h

SECTION 12: ECOLOGICAL INFORMATION Toxicity Not classified

Persistence and Degradability

Concentrated Nitric Acid

Persistence and Degradability Not established.

Bioaccumulative Potential


Bioaccumulative Potential Not established.


Log Pow -2.3 (at 25 °C)

Mobility in Soil Not available

Other Adverse Effects

Other Information: Avoid release to the environment.

SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations.

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SECTION 14: TRANSPORT INFORMATION

14.1 In Accordance with DOT

Proper Shipping Name : NITRIC ACID other than red fuming, with more than 70% nitric acid

Hazard Class : 8

Identification Number : UN2031

Label Codes : 8,5.1

Packing Group : I

ERG Number : 157

14.2 In Accordance with IMDG

Proper Shipping Name : NITRIC ACID

Hazard Class : 8


Packing Group : I

Label Codes : 8,5.1

EmS-No. (Fire) : F-A

EmS-No. (Spillage) : S-Q

14.3 In Accordance with IATA


Packing Group : I


Hazard Class : 8

Label Codes : 8,5.1

ERG Code (IATA) : 8X

14.4 In Accordance with TDG


Packing Group : I

Hazard Class : 8


Label Codes : 8,5.1

SECTION 15: REGULATORY INFORMATION US Federal Regulations


Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings)

SARA Section 302 Threshold Planning Quantity (TPQ) 1000

SARA Section 313 - Emission Reporting 1.0 %

US State Regulations


U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute U.S. - California - SCAQMD - Toxic Air Contaminants With Proposed Risk Values U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)


SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard

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U.S. - Delaware - Accidental Release Prevention Regulations - Sufficient Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Threshold Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Toxic Endpoints U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs) U.S. - Idaho - Occupational Exposure Limits - TWAs U.S. - Illinois - Toxic Air Contaminants U.S. - Louisiana - Reportable Quantity List for Pollutants U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Right To Know List U.S. - Massachusetts - Toxics Use Reduction Act U.S. - Michigan - Occupational Exposure Limits - STELs U.S. - Michigan - Occupational Exposure Limits - TWAs U.S. - Michigan - Polluting Materials List U.S. - Michigan - Process Safety Management Highly Hazardous Chemicals U.S. - Minnesota - Chemicals of High Concern U.S. - Minnesota - Hazardous Substance List U.S. - Minnesota - Permissible Exposure Limits - STELs U.S. - Minnesota - Permissible Exposure Limits - TWAs U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances U.S. - New Jersey - Environmental Hazardous Substances List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Special Health Hazards Substances List U.S. - New Jersey - TCPA - Extraordinarily Hazardous Substances (EHS) U.S. - New York - Occupational Exposure Limits - TWAs U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances U.S. - North Carolina - Control of Toxic Air Pollutants U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour U.S. - Ohio - Accidental Release Prevention - Threshold Quantities U.S. - Ohio - Extremely Hazardous Substances - Threshold Quantities U.S. - Oregon - Permissible Exposure Limits - TWAs U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour U.S. - South Carolina - Toxic Air Pollutants - Maximum Allowable Concentrations U.S. - South Carolina - Toxic Air Pollutants - Pollutant Categories U.S. - Tennessee - Occupational Exposure Limits - STELs U.S. - Tennessee - Occupational Exposure Limits - TWAs U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term U.S. - Vermont - Permissible Exposure Limits - STELs U.S. - Vermont - Permissible Exposure Limits - TWAs U.S. - Washington - Permissible Exposure Limits - STELs U.S. - Washington - Permissible Exposure Limits - TWAs U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40 Feet

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U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75 Feet U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet U.S. - Wyoming - Process Safety Management - Highly Hazardous Chemicals

Canadian Regulations


Listed on the Canadian DSL (Domestic Substances List) inventory. Listed on the Canadian Ingredient Disclosure List

WHMIS Classification Class C - Oxidizing Material Class E - Corrosive Material

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.

SECTION 16: OTHER INFORMATION

Revision date : November 2017 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA

Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases:

------ Eye Dam. 1 Serious eye damage/eye irritation Category 1

------ Met. Corr. 1 Corrosive to metals Category 1

------ Ox. Liq. 3 Oxidizing liquids Category 3

------ Skin Corr. 1A Skin corrosion/irritation Category 1A

------ H272 May intensify fire; oxidizer

------ H290 May be corrosive to metals

------ H314 Causes severe skin burns and eye damage

------ H318 Causes serious eye damage

NFPA Health Hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given.

NFPA Fire Hazard : 0 - Materials that will not burn. NFPA Reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water. NFPA Specific Hazard : OX - This denotes an oxidizer, a chemical which can greatly

increase the rate of combustion/fire. Party Responsible for the Preparation of This Document El Dorado Chemical Company P.O. Box 231 El Dorado, AR 71731 (870) 863-1400 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.


WHMIS Classification Class E - Corrosive Material Class C - Oxidizing Material

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Material Safety Data SheetAcetic acid MSDS


Product Name: Acetic acid

Catalog Codes: SLA3784, SLA1438, SLA2101, SLA3604,SLA1258

CAS#: 64-19-7

RTECS: AF1225000

TSCA: TSCA 8(b) inventory: Acetic acid


Synonym: Acetic acid; glacial acetic acid

Chemical Name: Acetic Acid, Glacial

Chemical Formula: C2-H4-O2









Composition:


Acetic acid 64-19-7 100

Toxicological Data on Ingredients: Acetic acid: ORAL (LD50): Acute: 3310 mg/kg [Rat]. 4960 mg/kg [Mouse]. 3530 mg/kg[Rat]. DERMAL (LD50): Acute: 1060 mg/kg [Rabbit]. VAPOR (LC50): Acute: 5620 ppm 1 hours [Mouse].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skincontact (corrosive, permeator), of eye contact (corrosive). Liquid or spray mist may produce tissue damage particularly onmucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist mayproduce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of theeye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,occasionally, blistering.

Potential Chronic Health Effects:Hazardous in case of skin contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, mucousmembranes, skin, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated

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or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolongedexposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.










Flammability of the Product: Flammable.

Auto-Ignition Temperature: 463°C (865.4°F)

Flash Points: CLOSED CUP: 39°C (102.2°F). OPEN CUP: 43°C (109.4°F).

Flammable Limits: LOWER: 4% UPPER: 19.9%

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizingmaterials, of metals.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.

Fire Fighting Media and Instructions:Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.

Special Remarks on Fire Hazards:Reacts with metals to produces flammable hydrogen gas. It will ignite on contact with potassium-tert-butoxide. A mixture ofammonium nitrate and acetic acid ignites when warmed, especially if warmed.

Special Remarks on Explosion Hazards:

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Acetic acid vapors may form explosive mixtures with air. Reactions between acetic acid and the following materialsare potentially explosive: 5-azidotetrazole, bromine pentafluoride, chromium trioxide, hydrogen peroxide, potassiumpermanganate, sodium peroxide, and phorphorus trichloride. Dilute acetic acid and dilute hydrogen can undergo anexothermic reaction if heated, forming peracetic acid which is explosive at 110 degrees C. Reaction between chlorinetrifluoride and acetic acid is very violent, sometimes explosive.



Large Spill:Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. If theproduct is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is inits liquid form: Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Absorbwith an inert material and put the spilled material in an appropriate waste disposal. Do not touch spilled material. Use waterspray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistanceon disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at aconcentration level above TLV. Check TLV on the MSDS and with local authorities.


Precautions:\Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratoryequipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin andeyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis.

Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame).



Personal Protection:Splash goggles. Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves(impervious).


Exposure Limits:TWA: 10 STEL: 15 (ppm) [Australia] TWA: 25 STEL: 27 (mg/m3) [Australia] TWA: 10 STEL: 15 (ppm) from NIOSH TWA: 25STEL: 37 (mg/m3) from NIOSH TWA: 10 STEL: 15 (ppm) [Canada] TWA: 26 STEL: 39 (mg/m3) [Canada] TWA: 25 STEL: 37(mg/m3) TWA: 10 STEL: 15 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 10 (ppm) from OSHA (PEL) [United States]TWA: 25 (mg/m3) from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.


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Odor: Pungent, vinegar-like, sour (Strong.)

Taste: Vinegar, sour (Strong.)


Color: Colorless. Clear (Light.)

pH (1% soln/water): 2 [Acidic.]


Melting Point: 16.6°C (61.9°F)

Critical Temperature: 321.67°C (611°F)






Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -0.2


Dispersion Properties: See solubility in water, diethyl ether, acetone.

Solubility:Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible with Glycerol, alcohol, Benzene, CarbonTetrachloride. Practically insoluble in Carbon Disulfide.




Conditions of Instability: Heat, ignition sources, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, metals, acids, alkalis.

Corrosivity:Highly corrosive in presence of stainless steel(304). Slightly corrosive in presence of aluminum, of copper. Non-corrosive inpresence of stainless steel(316).

Special Remarks on Reactivity:Reacts violently with strong oxidizing agents, acetaldehyde, and acetic anhydride. Material can react with metals, strongbases, amines, carbonates, hydroxides, phosphates, many oxides,cyanides, sulfides, chromic acid, nitric acid, hydrogenperoxide, carbonates. ammonium nitrate, ammonium thiosulfate, chlorine trifluoride, chlorosulfonic acid, perchloric acid,permanganates, xylene, oleum, potassium hydroxide, sodium hydroxide, phosphorus isocyanate, ethylenediamine, ethyleneimine.

Special Remarks on Corrosivity: Moderate corrosive effect on bronze. No corrosion data on brass




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Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 3310 mg/kg [Rat]. Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 56201 hours [Mouse].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage tothe following organs: kidneys, mucous membranes, skin, teeth.

Other Toxic Effects on Humans:Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (irritant), of ingestion, .Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive).


Special Remarks on Chronic Effects on Humans: May affect genetic material and may cause reproductive effects based onanimal data. No human data found.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Extremely irritating and corrosive. Causes skin irritation (reddening and itching,inflammation). May cause blistering , tissue damage and burns. Eyes: Extremely irritating and corrosive. Causes eye irritation,lacrimation, redness, and pain. May cause burns, blurred vision, conjunctivitis, conjunctival and corneal destruction andpermanent injury. Inhalation: Causes severe respiratory tract irritation. Affects the sense organs (nose, ear, eye, taste),and blood. May cause chemical pneumonitis, bronchitis, and pulmonary edema. Severe exposure may result in lung tissuedamage and corrosion (ulceration) of the mucous membranes. Inhalation may also cause rhinitis, sneezing, coughing,oppressive feeling in the chest or chest pain, dyspnea, wheezing, tachypnea, cyanosis, salivation, nausea, giddiness,muscular weakness. Ingestion: Moderately toxic. Corrosive. Causes gastrointestinal tract irritation (burning and pain of themouth, throat, and abdomen, coughing, ulceration, bleeding, nausea, abdomial spasms, vomiting, hematemesis, diarrhea.May Also affect the liver (impaired liver function), behavior (convulsions, giddines, muscular weakness), and the urinarysystem - kidneys (Hematuria, Albuminuria, Nephrosis, acute renal failure, acute tubular necrosis). May also cause dyspneaor asphyxia. May also lead to shock, coma and death. Chronic Potential Health Effects: Chronic exposure via ingestion maycause blackening or erosion of the teeth and jaw necrosis, pharyngitis, and gastritis. It may also behavior (similar to acuteingestion), and metabolism (weight loss). Chronic exposure via inhalation may cause asthma and/or bronchitis with cough,phlegm, and/or shortness of breath . It may also affect the blood (decreased leukocyte count), and urinary system (kidneys).Repeated or prolonged skin contact may cause thickening, blackening, and cracking of the skin.


Ecotoxicity:Ecotoxicity in water (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours[Fish (bluegill sunfish)]. >100 ppm 96 hours [Daphnia].

BOD5 and COD: BOD-5: 0.34-0.88 g oxygen/g







DOT Classification:

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CLASS 3: Flammable liquid. Class 8: Corrosive material

Identification: : Acetic Acid, Glacial UNNA: 2789 PG: II



Federal and State Regulations:New York release reporting list: Acetic acid Rhode Island RTK hazardous substances: Acetic acid Pennsylvania RTK: Aceticacid Florida: Acetic acid Minnesota: Acetic acid Massachusetts RTK: Acetic acid New Jersey: Acetic acid California Director'sList of Hazardous Subtances (8 CCR 339): Acetic acid TSCA 8(b) inventory: Acetic acid CERCLA: Hazardous substances.:Acetic acid: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.

DSCL (EEC):R10- Flammable. R35- Causes severe burns. S23- Do not breathe gas/fumes/vapour/spray [***] S26- In case of contact witheyes, rinse immediately with plenty of water and seek medical advice. S45- In case of accident or if you feel unwell, seekmedical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 2

Reactivity: 0

Personal Protection: H


Health: 3

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves (impervious). Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Splash goggles.




Created: 10/09/2005 03:35 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

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no liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

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Material Safety Data SheetBenzaldehyde MSDS


Product Name: Benzaldehyde

Catalog Codes:

CAS#: 100-52-7

RTECS: CU4375000

TSCA: TSCA 8(b) inventory: Benzaldehyde

CI#: Not available.

Synonym:

Chemical Formula: C7H6O









Composition:


Benzaldehyde 100-52-7 100

Toxicological Data on Ingredients: Benzaldehyde: ORAL (LD50): Acute: 1300 mg/kg [Rat].


Potential Acute Health Effects:Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. Slightlyhazardous in case of skin contact (permeator).

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, the nervous system, mucous membranes.Repeated or prolonged exposure to the substance can produce target organs damage.


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. WARM water MUST be used. Get medical attention.

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Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.


Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.

Serious Inhalation: Not available.




Flammability of the Product: Combustible.


Flash Points: CLOSED CUP: 64.4°C (147.9°F). OPEN CUP: 73.9°C (165°F).

Flammable Limits: LOWER: 1.4%


Fire Hazards in Presence of Various Substances: Not available.


Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.


Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Finish cleaning byspreading water on the contaminated surface and allow to evacuate through the sanitary system.


Precautions:Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do notbreathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratoryequipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin andeyes.

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Storage:Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possiblesources of ignition (spark or flame).



Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.


Exposure Limits: Not available.



Odor: Not available.



Color: Not available.

pH (1% soln/water): Not available.

Boiling Point: 179°C (354.2°F)

Melting Point: -26°C (-14.8°F)









Dispersion Properties: Not available.

Solubility: Very slightly soluble in cold water.




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Incompatibility with various substances: Not available.


Special Remarks on Reactivity: Not available.




Routes of Entry: Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 1300 mg/kg [Rat].

Chronic Effects on Humans: Causes damage to the following organs: lungs, the nervous system, mucous membranes.

Other Toxic Effects on Humans:Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of inhalation. Slightly hazardous in case ofskin contact (permeator).


Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.





Toxicity of the Products of Biodegradation: The products of degradation are more toxic.



Waste Disposal:


DOT Classification: CLASS 3: Combustible liquid

Identification: : Not available. UNNA: UN1989 PG: Not available.



Federal and State Regulations:

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Pennsylvania RTK: Benzaldehyde Massachusetts RTK: Benzaldehyde TSCA 8(b) inventory: Benzaldehyde



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2A: Material causingother toxic effects (VERY TOXIC).

DSCL (EEC):R22- Harmful if swallowed. R36/38- Irritating to eyes and skin.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0

Personal Protection: h


Health: 2

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.




Created: 10/10/2005 08:14 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetChlorine Standard Solution MSDS


Product Name: Chlorine Standard Solution

Catalog Codes: SLC3214

CAS#: Mixture.

RTECS: Not applicable.

TSCA: TSCA 8(b) inventory: Potassium iodate; Water

CI#: Not available.

Synonym:


Chemical Formula: Not applicable.









Composition:


Potassium iodate 7758-05-6 0.01

Water 7732-18-5 100

Toxicological Data on Ingredients:


Potential Acute Health Effects:Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Non-corrosive for skin. Non-sensitizerfor skin. Non-permeator by skin. Non-irritant for lungs. Non-sensitizer for lungs. Non-corrosive to the eyes. Non-corrosive forlungs.

Potential Chronic Health Effects:Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs.CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.


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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention if irritation occurs.

Skin Contact:Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold watermay be used.

Serious Skin Contact: Not available.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention if symptoms appear.

Serious Inhalation: Not available.









Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.



Special Remarks on Explosion Hazards:Potentially explosive reaction with charcoal + ozone; metals; arsenic; carbon; phosphorus; sulfur; alkali metal hydrides;alkaline earth metal hydrides; antimony sulfide; arsenic sulfide; tin sulfide; metal cyanides; metal thiocyanates; maganesedioxide. (Potassium iodate)


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authorityrequirements.

Large Spill:Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading wateron the contaminated surface and allow to evacuate through the sanitary system.


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Precautions: No specific safety phrase has been found applicable for this product.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.


Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value.

Personal Protection: Safety glasses. Lab coat.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFOREhandling this product.

Exposure Limits: Not available.



Odor: Not available.


Molecular Weight: Not applicable.

Color: Clear Colorless.

pH (1% soln/water): Neutral.

Boiling Point: The lowest known value is 100°C (212°F) (Water).

Melting Point: Not available.


Specific Gravity: The only known value is 1 (Water = 1) (Water).

Vapor Pressure: The highest known value is 2.3 kPa (@ 20°C) (Water).

Vapor Density: The highest known value is 0.62 (Air = 1) (Water).






Solubility: Easily soluble in cold water, hot water.




Conditions of Instability: Incompatible materials

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Special Remarks on Reactivity:It can react vigorously with reducing materials. (Potassium iodate)




Routes of Entry: Absorbed through skin. Eye contact.

Toxicity to Animals:LD50: Not available. LC50: Not available.

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans:Slightly hazardous in case of skin contact (irritant), of ingestion, . Non-corrosive for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritant for lungs. Non-sensitizer for lungs. Non-corrosive to the eyes. Non-corrosive for lungs.

Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Mouse] - Route - Oral; Dose: 531 mg/kg LDL [Dog] - Route - Oral; Dose: 200 mg/kgLethal Dose/Conc 50% Kill: LD50 [Mouse] - Route - Intraperitoneal; Dose: 136 mg/kg (Potassium iodate)


Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May causerespiratory tract irritation. Ingestion: May cause gastrointestinal tract irritation. This solution contains Potassium Iodatewhich may affect behavior/Central Nervous system (excitement, convulsions), respiration. Chronic Potential Health Effects:Ingestion: Prolonged or repeated ingestion of Potassium Iodate may affect the liver and kidneys, metabolism (anorexia), andthe blood (anemia).





Toxicity of the Products of Biodegradation: Not available.





DOT Classification: Not a DOT controlled material (United States).

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Identification: Not applicable.

Special Provisions for Transport: Not applicable.


Federal and State Regulations: TSCA 8(b) inventory: Potassium iodate; Water

Other Regulations: Not available. or of its ingredients


WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):This product is not classified according to the EU regulations. Not applicable.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 0

Reactivity: 0

Personal Protection: a


Health: 1

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Not applicable. Lab coat. Not applicable. Safety glasses.




Created: 10/10/2005 12:58 AM

Last Updated: 05/21/2013 12:00 PM


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p. 1

2 3 1

He a lt h

Fire

Re a c t iv it y


3

2

0

Material Safety Data SheetAcetic anhydride MSDS


Product Name: Acetic anhydride

Catalog Codes: SLA1693

CAS#: 108-24-7

RTECS: AK1925000

TSCA: TSCA 8(b) inventory: Acetic anhydride

CI#: Not available.

Synonym:

Chemical Formula: (CH3CO)2)









Composition:


Acetic anhydride 108-24-7 100

Toxicological Data on Ingredients: Acetic anhydride: ORAL (LD50): Acute: 1780 mg/kg [Rat]. DERMAL (LD50): Acute: 4000mg/kg [Rabbit].


Potential Acute Health Effects:Extremely hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Very hazardous incase of skin contact (corrosive). Hazardous in case of skin contact (permeator). Liquid or spray mist may produce tissuedamage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalationof the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath.Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolongedexposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may producechronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tractirritation leading to frequent attacks of bronchial infection.

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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Getmedical attention immediately.







Flammability of the Product: Flammable.


Flash Points: CLOSED CUP: 49°C (120.2°F). OPEN CUP: 51°C (123.8°F).

Flammable Limits: LOWER: 2.7% UPPER: 10.3%


Fire Hazards in Presence of Various Substances: Flammable in presence of heat.


Fire Fighting Media and Instructions:Flammable liquid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Coolcontaining vessels with water jet in order to prevent pressure build-up, autoignition or explosion.


Special Remarks on Explosion Hazards: Not available.


Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

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Large Spill:Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorbwith DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material.Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Callfor assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on theMSDS and with local authorities.


Precautions:Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material.Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes.

Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame).





Exposure Limits:TWA: 5 TWA: 20 Consult local authorities for acceptable exposure limits.



Odor: Strong.

Taste: Strong.


Color: Light.

pH (1% soln/water): Not available.


Melting Point: -73.1 (-99.6°F)





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Dispersion Properties: Not available.

Solubility: Not available.






Corrosivity: Not available.

Special Remarks on Reactivity: Not available.




Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 1780 mg/kg [Rat]. Acute dermal toxicity (LD50): 4000 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 10004 hours [Rat].

Chronic Effects on Humans: Causes damage to the following organs: lungs, mucous membranes.

Other Toxic Effects on Humans:Extremely hazardous in case of skin contact (irritant), of ingestion, . Very hazardous in case of skin contact (corrosive).Hazardous in case of skin contact (permeator), of eye contact (corrosive), of inhalation (lung corrosive).



Special Remarks on other Toxic Effects on Humans: Not available.







A-170

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Waste Disposal:



Identification: : Acetic Anhydride UNNA: UN1715 PG: II



Federal and State Regulations:Pennsylvania RTK: Acetic anhydride Massachusetts RTK: Acetic anhydride TSCA 8(b) inventory: Acetic anhydride CERCLA:Hazardous substances.: Acetic anhydride



WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.

DSCL (EEC):R10- Flammable. R20/22- Harmful by inhalation and if swallowed. R34- Causes burns.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 2

Reactivity: 0



Health: 3

Flammability: 2

Reactivity: 1

Specific hazard:





Created: 10/10/2005 08:13 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

A-171

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no liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

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Annexure-VII Undertaking from Consultant

Annexure-VIII Undertaking from Project Proponent

Annexure-IX Copy of Terms of Reference (TOR)

No.IA-J-11011/418/2018-IA-II(I)

Goverment of India

Minister of Enviroment,Forest and Climate Change

Impact Assessment Division

***

Indira Paryavaran Bhavan,

Vayu Wing,3rd Floor,Aliganj,

Jor Bagh Road,New Delhi-110003

04 Feb 2019

To,

M/s URMIT CHEMICALS PVT. LTD.

102 Janpath Co-Op. Hou. Soc. Ltd. , Near Avkar Hall, Ghodasar, Ahmedabad,

Ahmedabad-380050

Gujarat

Tel.No.79-26583055; Email:[email protected]

Sir/Madam,

This has reference to the proposal submitted in the Ministry of Environment, Forest

and Climate Change to prescribe the Terms of Reference (TOR) for undertaking detailed EIA

study for the purpose of obtaining Environmental Clearance in accordance with the provisions of

the EIA Notification, 2006. For this purpose, the proponent had submitted online information in the

prescribed format (Form-1 ) along with a Pre-feasibility Report. The details of the proposal are

given below:

1. Proposal No.: IA/GJ/IND2/89506/2018

2. Name of the Proposal:

Proposed project for manufacturing of various

Dye intermediates and dyes by Urmit

Chemicals Pvt. Ltd.

3. Category of the Proposal: Industrial Projects - 2

4. Project/Activity applied for: 5(f) Synthetic organic chemicals industry (dyes

& dye intermediates; bulk

5. Date of submission for TOR: 24 Dec 2018

In this regard, under the provisions of the EIA Notification 2006 as amended, the Standard TOR

for the purpose of preparing environment impact assessment report and environment

management plan for obtaining prior environment clearance is prescribed with public consultation

as follows:

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STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FOR PROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE

5(f):STANDARD TERMS OF REFERENCE FOR CONDUCTINGENVIRONMENT IMPACT ASSESSMENT STUDY FOR SYNTHETICORGANIC CHEMICALS INDUSTRY (DYES & DYEINTERMEDIATES; BULK DRUGS AND INTERMEDIATESEXCLUDING DRUG FORMULATIONS; SYNTHETIC RUBBERS;BASIC ORGANIC CHEMICALS, OTHER SYNTHETIC ORGANICCHEMICALS AND CHEMICAL INTERMEDIATES) ANDINFORMATION TO BE INCLUDED IN EIA/EMP REPORT

A. STANDARD TERMS OF REFERENCE

1) Executive Summary

2) Introduction

i. Details of the EIA Consultant including NABET accreditation

ii. Information about the project proponent

iii. Importance and benefits of the project

3) Project Description

i. Cost of project and time of completion.

ii. Products with capacities for the proposed project.

iii. If expansion project, details of existing products with capacities and whether adequate landis available for expansion, reference of earlier EC if any.

iv. List of raw materials required and their source along with mode of transportation.

v. Other chemicals and materials required with quantities and storage capacities

vi. Details of Emission, effluents, hazardous waste generation and their management.

vii. Requirement of water, power, with source of supply, status of approval, water balance diagram,man-power requirement (regular and contract)

viii. Process description along with major equipments and machineries, process flow sheet(quantative) from raw material to products to be provided

ix. Hazard identification and details of proposed safety systems.

x. Expansion/modernization proposals:

c. Copy of all the Environmental Clearance(s) including Amendments thereto obtained forthe project from MOEF/SEIAA shall be attached as an Annexure. A certified copy of thelatest Monitoring Report of the Regional Office of the Ministry of Environment and Forestsas per circular dated 30th May, 2012 on the status of compliance of conditions stipulatedin all the existing environmental clearances including Amendments shall be provided. In

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STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FORPROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE

addition, status of compliance of Consent to Operate for the ongoing Iexisting operationof the project from SPCB shall be attached with the EIA-EMP report.

d. In case the existing project has not obtained environmental clearance, reasons for nottaking EC under the provisions of the EIA Notification 1994 and/or EIA Notification2006 shall be provided. Copies of Consent to Establish/No Objection Certificate andConsent to Operate (in case of units operating prior to EIA Notification 2006, CTE andCTO of FY 2005-2006) obtained from the SPCB shall be submitted. Further, compliancereport to the conditions of consents from the SPCB shall be submitted.

4) Site Details

i. Location of the project site covering village, Taluka/Tehsil, District and State, Justificationfor selecting the site, whether other sites were considered.

ii. A toposheet of the study area of radius of 10km and site location on 1:50,000/1:25,000 scaleon an A3/A2 sheet. (including all eco-sensitive areas and environmentally sensitive places)

iii. Details w.r.t. option analysis for selection of site

iv. Co-ordinates (lat-long) of all four corners of the site.

v. Google map-Earth downloaded of the project site.

vi. Layout maps indicating existing unit as well as proposed unit indicating storage area, plantarea, greenbelt area, utilities etc. If located within an Industrial area/Estate/Complex, layoutof Industrial Area indicating location of unit within the Industrial area/Estate.

vii. Photographs of the proposed and existing (if applicable) plant site. If existing, showphotographs of plantation/greenbelt, in particular.

viii. Landuse break-up of total land of the project site (identified and acquired), government/private - agricultural, forest, wasteland, water bodies, settlements, etc shall be included. (notrequired for industrial area)

ix. A list of major industries with name and type within study area (10km radius) shall beincorporated. Land use details of the study area

x. Geological features and Geo-hydrological status of the study area shall be included.

xi. Details of Drainage of the project upto 5km radius of study area. If the site is within 1 kmradius of any major river, peak and lean season river discharge as well as flood occurrencefrequency based on peak rainfall data of the past 30 years. Details of Flood Level of theproject site and maximum Flood Level of the river shall also be provided. (mega green fieldprojects)

xii. Status of acquisition of land. If acquisition is not complete, stage of the acquisition processand expected time of complete possession of the land.

xiii. R&R details in respect of land in line with state Government policy.

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5) Forest and wildlife related issues (if applicable):

i. Permission and approval for the use of forest land (forestry clearance), if any, andrecommendations of the State Forest Department. (if applicable)

ii. Landuse map based on High resolution satellite imagery (GPS) of the proposed site delineatingthe forestland (in case of projects involving forest land more than 40 ha)

iii. Status of Application submitted for obtaining the stage I forestry clearance along with lateststatus shall be submitted.

iv. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere Reserves,Migratory Corridors of Wild Animals, the project proponent shall submit the map dulyauthenticated by Chief Wildlife Warden showing these features vis-à-vis the project locationand the recommendations or comments of the Chief Wildlife Warden-thereon.

v. Wildlife Conservation Plan duly authenticated by the Chief Wildlife Warden of the StateGovernment for conservation of Schedule I fauna, if any exists in the study area.

vi. Copy of application submitted for clearance under the Wildlife (Protection) Act, 1972, to theStanding Committee of the National Board for Wildlife.

6) Environmental Status

i. Determination of atmospheric inversion level at the project site and site-specific micro-meteorological data using temperature, relative humidity, hourly wind speed and directionand rainfall.

ii. AAQ data (except monsoon) at 8 locations for PM10, PM2.5, SO2, NOX, CO and otherparameters relevant to the project shall be collected. The monitoring stations shall be basedCPCB guidelines and take into account the pre-dominant wind direction, population zoneand sensitive receptors including reserved forests.

iii. Raw data of all AAQ measurement for 12 weeks of all stations as per frequency given in theNAQQM Notification of Nov. 2009 along with - min., max., average and 98% values foreach of the AAQ parameters from data of all AAQ stations should be provided as an annexureto the EIA Report.

iv. Surface water quality of nearby River (100m upstream and downstream of discharge point)and other surface drains at eight locations as per CPCB/MoEF&CC guidelines.

v. Whether the site falls near to polluted stretch of river identified by the CPCB/MoEF&CC, ifyes give details.

vi. Ground water monitoring at minimum at 8 locations shall be included.

vii. Noise levels monitoring at 8 locations within the study area.

viii. Soil Characteristic as per CPCB guidelines.

ix. Traffic study of the area, type of vehicles, frequency of vehicles for transportation of materials,additional traffic due to proposed project, parking arrangement etc.

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x. Detailed description of flora and fauna (terrestrial and aquatic) existing in the study areashall be given with special reference to rare, endemic and endangered species. If Schedule-I fauna are found within the study area, a Wildlife Conservation Plan shall be prepared andfurnished.

xi. Socio-economic status of the study area.

7) Impact and Environment Management Plan

i. Assessment of ground level concentration of pollutants from the stack emission based onsite-specific meteorological features. In case the project is located on a hilly terrain, theAQIP Modelling shall be done using inputs of the specific terrain characteristics fordetermining the potential impacts of the project on the AAQ. Cumulative impact of all sourcesof emissions (including transportation) on the AAQ of the area shall be assessed. Details ofthe model used and the input data used for modelling shall also be provided. The air qualitycontours shall be plotted on a location map showing the location of project site, habitationnearby, sensitive receptors, if any.

ii. Water Quality modelling - in case of discharge in water body

iii. Impact of the transport of the raw materials and end products on the surrounding environmenthall be assessed and provided. In this regard, options for transport of raw materials andfinished products and wastes (large quantities) by rail or rail-cum road transport or conveyor-cum-rail transport shall be examined.

iv. A note on treatment of wastewater from different plant operations, extent recycled and reusedfor different purposes shall be included. Complete scheme of effluent treatment. Characteristicsof untreated and treated effluent to meet the prescribed standards of discharge under E(P)Rules.

v. Details of stack emission and action plan for control of emissions to meet standards.

vi. Measures for fugitive emission control

vii. Details of hazardous waste generation and their storage, utilization and management. Copiesof MOU regarding utilization of solid and hazardous waste in cement plant shall also beincluded. EMP shall include the concept of waste-minimization, recycle/reuse/recovertechniques, Energy conservation, and natural resource conservation.

viii. Proper utilization of fly ash shall be ensured as per Fly Ash Notification, 2009. A detailedplan of action shall be provided.

ix. Action plan for the green belt development plan in 33 % area i.e. land with not less than1,500 trees per ha. Giving details of species, width of plantation, planning schedule etc. shallbe included. The green belt shall be around the project boundary and a scheme for greeningof the roads used for the project shall also be incorporated.

x. Action plan for rainwater harvesting measures at plant site shall be submitted to harvestrainwater from the roof tops and storm water drains to recharge the ground water and also to

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use for the various activities at the project site to conserve fresh water and reduce the waterrequirement from other sources.

xi. Total capital cost and recurring cost/annum for environmental pollution control measuresshall be included.

xii. Action plan for post-project environmental monitoring shall be submitted.

xiii. Onsite and Offsite Disaster (natural and Man-made) Preparedness and Emergency ManagementPlan including Risk Assessment and damage control. Disaster management plan should belinked with District Disaster Management Plan.

8) Occupational health

i. Plan and fund allocation to ensure the occupational health & safety of all contract and casualworkers

ii. Details of exposure specific health status evaluation of worker. If the workers' health is beingevaluated by pre designed format, chest x rays, Audiometry, Spirometry, Vision testing (Far& Near vision, colour vision and any other ocular defect) ECG, during pre placement andperiodical examinations give the details of the same. Details regarding last month analyzeddata of above mentioned parameters as per age, sex, duration of exposure and departmentwise.

iii. Details of existing Occupational & Safety Hazards. What are the exposure levels of hazardsand whether they are within Permissible Exposure level (PEL). If these are not within PEL,what measures the company has adopted to keep them within PEL so that health of the workerscan be preserved,

iv. Annual report of heath status of workers with special reference to Occupational Health andSafety.

9) Corporate Environment Policy

i. Does the company have a well laid down Environment Policy approved by its Board ofDirectors? If so, it may be detailed in the EIA report.

ii. Does the Environment Policy prescribe for standard operating process / procedures to bringinto focus any infringement / deviation / violation of the environmental or forest norms /conditions? If so, it may be detailed in the EIA.

iii. What is the hierarchical system or Administrative order of the company to deal with theenvironmental issues and for ensuring compliance with the environmental clearanceconditions? Details of this system may be given.

iv. Does the company have system of reporting of non compliances / violations of environmentalnorms to the Board of Directors of the company and / or shareholders or stakeholders atlarge? This reporting mechanism shall be detailed in the EIA report

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10) Details regarding infrastructure facilities such as sanitation, fuel, restroom etc. to be provided to thelabour force during construction as well as to the casual workers including truck drivers duringoperation phase.

11) Enterprise Social Commitment (ESC)

i. Adequate funds (at least 2.5 % of the project cost) shall be earmarked towards the EnterpriseSocial Commitment based on Public Hearing issues and item-wise details along with timebound action plan shall be included. Socio-economic development activities need to beelaborated upon.

12) Any litigation pending against the project and/or any direction/order passed by any Court of Lawagainst the project, if so, details thereof shall also be included. Has the unit received any noticeunder the Section 5 of Environment (Protection) Act, 1986 or relevant Sections of Air and WaterActs? If so, details thereof and compliance/ATR to the notice(s) and present status of the case.

13) 'A tabular chart with index for point wise compliance of above TOR.

B. SPECIFIC TERMS OF REFERENCEFOREIASTUDIES FOR SYNTHETICORGANIC CHEMICALS INDUSTRY (DYES & DYE INTERMEDIATES;BULK DRUGS AND INTERMEDIATES EXCLUDING DRUGFORMULATIONS; SYNTHETIC RUBBERS; BASIC ORGANICCHEMICALS, OTHER SYNTHETIC ORGANIC CHEMICALS ANDCHEMICAL INTERMEDIATES)

1. Detailsonsolvents to be used,measuresfor solventrecovery and for emissions control.

2. Details of process emissions from the proposed unit and its arrangement to control.

3. Ambient air quality data should include VOC, otherprocess-specificpollutants* like NH3*, chlorine*,HCl*, HBr*, H2S*, HF*,etc.,(*-asapplicable)

4. Work zone monitoring arrangements for hazardous chemicals.

5. Detailed effluent treatment scheme including ssegregation of effluent streams for units adopting'Zero' liquid discharge.

6. Action plan for odour control to be submitted.

7. A copy of the Memorandum of Understanding signed with cement manufacturers indicating clearlythat they co-process organic solid/hazardous waste generated.

8. Authorization/Membership for the disposal of liquid effluent in CETP and solid/hazardous waste inTSDF, if any.

9. Action plan for utilization of MEE/dryers salts.

10. Material Safety Data Sheet for all the Chemicals are being used/will be used.

11. Authorization/Membership for the disposal of solid/hazardous waste in TSDF.

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12. Details of incinerator if to be installed.

13. Risk assessment for storage and handling of hazardous chemicals/solvents. Action plan for handling& safety system to be incorporated.

14. Arrangements for ensuring health and safety of workers engaged in handling of toxic materials.

***

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Annexure-X Submitted Form-1 along with

all Annexures/Attachments

6/26/2019 Welcome to PARIVESH

environmentclearance.nic.in/onlinesearch.aspx 1/2

Environment Clearance Status Query Form

(Proposals received on or after 4th July 2014 )

* Status : STANDARD TOR GRAN Year : -All Years-

* Category : -All Category- State : -All State-

Enter text for Search :

IA/GJ/IND2/89506/2018 Type of project : -All Project Type-

SEARCH

List of the proposals as per above given/selected query (As on 26-06-2019)

Help : *Kindly click on image button to open the attached files ( e.g. Form1,PFR,TOR letter,Form1 for EC,EIA/EMP Report, Public hearing, EC letter, Additional information,Compliance Report,Monitoring Report etc.)

A-183

6/26/2019 Welcome to PARIVESH

environmentclearance.nic.in/onlinesearch.aspx 2/2

(writereaddata/Online/TOR/19560)

(writereaddata/Form-1A/TOR/0402201989OJBJ3I.pdf)

(writereaddata/Online/TOR/24_Dec_2018_160845153DC3MQV2

(auth/FORM_A_PDF.aspx?cat_id=IA/GJ/IND2/89506/2018&pid=

(writereaddata/Online/TOR/24_Dec_2018_16084516781BTGZSP

(writereaddata/Online/TOR/24_Dec_2018_16084517781BTGZSP

S.No Proposal Details Location Important Dates Category Company/Proponent Typeofproject

* Attached Files

1 ProposalNo

:IA/GJ/IND2/89506/2018

File No:

IA-J-11011/418/2018-IA-II(I)

ProposalName

:

Proposed project formanufacturing ofvarious Dyeintermediates anddyes by UrmitChemicals Pvt. Ltd.

State : Gujarat

District : Mahesana

Tehsil : Kadi

Date ofSubmissionfor TOR

:24Dec2018

ProposalAcceptedby MS on

:31Dec2018

Date ofTORGranted

:04Feb2019

IndustrialProjects -2

URMITCHEMICALS PVT.LTD.

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A-184

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6/26/2019 Report Part 1

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APPENDIX I(See Paragraph-6)

FORM 1

Note : If space provided against any parameter is inadequate, Kindly upload supporting document under'Additional Attachments if any' at the last part of the Form1. Please note that all such Annexures mustbe part of single pdf document.

(I) Basic InformationS.No. Item Details

Whether it is a violation case and applicationis being submitted under Notification No.S.O.804(E) dated 14.03.2017 ?

No

1.

Name of the Project/s Proposed project for manufacturing of various Dyeintermediates and dyes by Urmit Chemicals Pvt. Ltd.

Brief summary of project Annexure-Brief summary of projectProposal Number IA/GJ/IND2/89506/2018Project Cost (in lacs) 500

2.S. No. in the schedule 5(f) Synthetic organic chemicals industry (dyes & dye

intermediates; bulkProject Sector Industrial Projects - 2

3.Proposed capacity/area/length/tonnage to behandled/command area/lease area/numberor wells to be drilled

1) Dyes Intermediates: 150 MTPM 2) Acid Dyes, Direct dyesand Reactive Dyes: 100 MTPM 3) Basic Dyes: 50 MTPM 4)Basic Dyes liquid: 100 MTPM Total Production: 400 MTPM LandArea = 5662 m2 ha.

4. New/Expansion/Modernization New

5. Existing Capacity/Area etc. 00 ha.

6. Category of project i.e. 'A' or 'B' A

7. Does it attract the general condition? If yes,please specify No

8. Does it attract the specific condition? If yes,please specify No

9.Location of the project Survey No. 1384, Village: Rajpur, Tal: Kadi, Dist: Mahesana,

GujaratShape of the project land Block (Polygon)

Uploaded GPS file Annexure-GPS file Uploaded copy of survey of India Toposheet Annexure-Survey of india toposheetPlot/Survey/Khasra No. Survey No. 1384Town / Village RajpurState of the project Gujarat

Details of State of the project

S.no State Name District Name Tehsil Name

(1.) Gujarat Mahesana Kadi

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http://environmentclearance.nic.in/writereaddata/Online/TOR/24_Dec_2018_153703550SR8M0QKYProjectSummary.pdf

http://environmentclearance.nic.in/auth/Testmap1.aspx?type=ca&fname=24_Dec_2018_155002187RDYS37VGUrmitChemical.kml&proposalno=IA/GJ/IND2/89506/2018

http://environmentclearance.nic.in/download.aspx?files=writereaddata/Online/TOR/24_Dec_2018_155002187RDYS37VGUrmitChemical.kml

http://environmentclearance.nic.in/writereaddata/Online/TOR/24_Dec_2018_1537035038LJ1NKQ7Toposheet.pdf



10. Nearest railway station along with distancein kms Kadi Railway Station, 11 km

Nearest airport along with distance in kms Sardar Vallabhbhai Patel International Airport(Ahmedabad), 38 km

11. Nearest Town/City/District Headquartersalong with distance in kms Kadi , 10 km

12.Village Panchayats, Zila Parishad, MuncipalCorporation, Local body (Complete postaladdress with telephone nos. to be given)

District Collector Office Block No.3, MS Building, RajmahalRoad, Mehsana, Gujarat – 384001 Phone no. +91 2762222203

13. Name of the Applicant Amit

14. Registered Address Survey no. 1384, Village: Rajpur, Tal.: Kadi, Dist: Mehsana,Gujarat

15.

Address for correspondance:Name of the Company URMIT CHEMICALS PVT. LTD.Name of the Applicant AmitDesignation (Owner/ Partner/ CEO) DirectorPin code 380050E-mail [email protected] No. 79-26583055Fax No. 79-Copy of documents in support of thecompetence/authority of the person makingthis application to make application on behalfof the User Agency .

Annexure-Uploaded Copy of documents in support of thecompetence/authority

16. Details of Alternative Sites examined, if any.Location of these sites should be shown on atoposheet

No

17. Whether part of Interlinked projects? No

18. Whether separate application of Interlinkedproject has been submitted? N/A

19. If Yes, MoEF file number N/ADate of submission N/A

20. If No, Reason N/A

21. Whether the proposal involves Approval/ Clearance under: if yes, details of the same and theirstatus to be given(i) Whether the proposal involvesapproval/clearance under the Forest(Conservation) Act,1980?

No

(ii) Whether the proposal involvesapproval/clearance under the wildlife(Protection) Act,1972?

No

(iii) Whether the proposal involvesapproval/clearance under the C.R.Znotification, 2011?

No

22. Whether there is any GovernmentOrder/Policy relevant/relating to the site? No

23. Whether any Forest Land Involved? NoArea of Forest land Involved (hectares) N/A

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http://environmentclearance.nic.in/writereaddata/Online/TOR/24_Dec_2018_160629407SRE963YFAuthorityLetter.pdf



24. Whether there is any litigation pendingagainst the project and/or land in which theproject is proposed to be set up?

No

(a) Name of the Court N/A(b) Name of the Sub court N/A(c) Case No. N/A(d) Orders/directions of the court, if any andrelevance with the proposed project N/A

(II) Activity

1 Construction, operation or decommissioning of the Project involving actions, which will causephysical changes in the locality (topography, land use, changes in water bodies, etc.)

S.NoInformation/Checklist confirmation Yes/No

Details there of (with approximatequantities/rates, wherever possible) with

source of information data

1.1

Permanent or temporary change in land use,land cover or topography including increasein intensity of land use (with respect to localland use plan)

YesTemporary change in topography of land during theplant construction activities and it will be a temporaryeffect.

1.2 Clearance of existing land, vegetation andbuildings? Yes

Land is converted to “non-agriculture” use for industrialpurpose. The area is free from existing buildings&vegetation.

1.3 Creation of new land uses? No N.A.

1.4 Pre-construction investigations e.g. borehouses, soil testing? No Not required

1.5 Construction works? Yes Construction work will be done as per the requirement ofproposed project.

1.6 Demolition works? No Not required

1.7 Temporary sites used for construction worksor housing of construction workers? No Most of the workers are from nearby villages, so housing

for construction workers is not required.

1.8Above ground buildings, structures orearthworks including linear structures, cutand fill or excavations and fill or excavations

NoThere is no existing above ground buildings, structuresor earthworks. Proposed structures will be as per theplant design.

1.9 Underground works including mining ortunnelling? No Not required

1.10 Reclamation works? No Not required

1.11 Dredging? No Not required

1.12 Offshore structures? No Not required

1.13 Production and manufacturing processes? Yes Production and manufacturing process is as perAnnexure-I & II.

1.14 Facilities for storage of goods or materials? YesUnit will create storage facilities for raw materials,intermediates and products as per the MSIHC andexplosive rules.

1.15 Facilities for treatment or disposal of solidwaste or liquid effluents?

Yes Effluent from Dyes plant will be treated in ETP-1followed by RO, RO permeate will be reused again.

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Effluent from dye intermediate will be treated in ETP -2along with reject of RO and after that the entire effluentwill be spray dried in spray dryer. Detail of waterbalance is given in Annexure-III. Details of hazardouswaste are given in Annexure- IV.

1.16 Facilities for long term housing ofoperational workers? No Not required as Local workers are involved.

1.17 New road, rail or sea traffic duringconstruction or operation? No No new roads and railare envisioned.

1.18

New road, rail, air water borne or othertransport infrastructure including new oraltered routes and stations, ports, airportsetc?

No Not required

1.19Closure or diversion of existing transportroutes or infrastructure leading to changesin traffic movements?

No No closure or diversion of existing transport routes orinfrastructure required.

1.20 New or diverted transmission lines orpipelines? No Not required

1.21Impoundment, damming, culverting,realignment or other changes to thehydrology of watercourses or aquifers?

No No changes to the hydrology of watercourses will becaused.

1.22 Stream crossings? No N.A.

1.23 Abstraction or transfers of water fromground or surface waters? Yes Abstraction of water from ground source and necessary

water recharging mechanism will be adopted.

1.24 Changes in water bodies or the land surfaceaffecting drainage or run-off? No Unit will notdischarge wastewater on land, hence land

surface will not affected by proposed activities.

1.25 Transport of personnel or materials forconstruction, operation or decommissioning? Yes Employees and materials to and from the site will be

transported by road.

1.26 Long-term dismantling or decommissioningor restoration works? No N.A.

1.27Ongoing activity during decommissioningwhich could have an impact on theenvironment?

No N.A.

1.28 Influx of people to an area in eithertemporarily or permanently? Yes Temporarily during construction phase and permanent

during operation phase.

1.29 Introduction of alien species? No N.A.

1.30 Loss of native species or genetic diversity? No N.A.

1.31 Any other actions? No N.A.

2 Use of Natural resources for construction or operation of the Project (such as land, water, materialsor energy, especially any resources which are non-renewable or in short supply):


Details thereof (with approximatequantities/rates, wherever possible) with


2.1 Land especially undeveloped or agriculturalland (ha)

Yes Land is converted to “non-agriculture” use for industrialpurpose. The area is free from existing buildings&vegetation.

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2.2 Water (expected source & competing users)unit: KLD Yes

Water requirement for domestic, industrial and greenbeltis estimated to be about 178 KLD. Source of watersupply: Bore well.

2.3 Minerals (MT) No Not required

2.4 Construction material – stone, aggregates,sand / soil (expected source – MT) Yes Cement, Stone, Steel etc. will be used for construction

activities. Exact quantity of each is still not worked out.

2.5 Forests and timber (source – MT) No Timber usage will be limited to office furniture only.

2.6Energy including electricity and fuels(source, competing users) Unit: fuel(MT),energy (MW)

YesEnergy: 500 KVA Source: from UGVCL Fuel for boiler,HAG & TFH: Coal- 51TPD D.G. set– 500 kVA HSD–100ltr/hr

2.7 Any other natural resources (use appropriatestandard units) No N.A.

3Use, storage, transport, handling or production of substances or materials, which could be harmfulto human health or the environment or raise concerns about actual or perceived risks to humanhealth




3.1

Use of substances or materials, which arehazardous (as per MSIHC rules) to humanhealth or the environment (flora, fauna, andwater supplies

YesOleum, hydrochloric acid, sodium hydroxide, ammonia,acetic acidand other chemicals are considered as Haz.Chemicals and storage will be as per the MSIHC rules.

3.2Changes in occurrence of disease or affectdisease vectors (e.g. insect or water bornediseases)

No N.A.

3.3 Affect the welfare of people e.g. by changingliving conditions? No May improve the living standard positively through

employment by unit.

3.4Vulnerable groups of people who could beaffected by the project e.g. hospital patients,children, the elderly etc.

No N.A.

3.5 Any other causes No N.A.

4 Production of solid wastes during construction or operation or decommissioning (MT/month)




4.1 Spoil, overburden or mine wastes No N.A.

4.2 Municipal waste (domestic and orcommercial wastes) Yes

Domestic waste will be generated by the employees atsite.Itwill be disposed of through a septic tank and soakpit system.

4.3 Hazardous wastes (as per Hazardous WasteManagement Rules) Yes As per Annexure-IV

4.4 Other industrial process wastes Yes As per Annexure-IV

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4.5 Surplus product No N.A.

4.6 Sewage sludge or other sludge from effluenttreatment Yes

Domestic sewage will be disposed of through a septictank and soak pit system. Sludge from the effluenttreatment will be disposed to approve TSDF site.

4.7 Construction or demolition wastes No

Construction wastes will be inert in nature and will becollected and utilized by filling of low-lying areas withinthe unit. No demolition work will be carried out for theproposed unit.

4.8 Redundant machinery or equipment No N.A.

4.9 Contaminated soils or other materials No N.A.

4.10 Agricultural wastes No N.A.

4.11 Other solid wastes Yes Used Lube Oil, Discarded Drums/ containers & PlasticLiners.

5 Release of pollutants or any hazardous, toxic or noxious substances to air(Kg/hr)




5.1 Emissions from combustion of fossil fuelsfrom stationary or mobile sources Yes As per Annexure-V

5.2 Emissions from production processes Yes As per Annexure-V

5.3 Emissions from materials handling includingstorage or transport No There are no emissions during handling or storage.

5.4 Emissions from construction activitiesincluding plant and equipment Yes

There will be generation of particulate matter (PM) dueto construction activities. Proper sprinkling of water will

be done to reduce PM emissions.

5.5Dust or odours from handling of materialsincluding construction materials, sewage andwaste

Yes Sewage will be sent to soak pit & Water will be sprinkledto reduce dust emissions during construction.

5.6 Emissions from incineration of waste No N.A.

5.7 Emissions from burning of waste in open air(e.g. slash materials, construction debris) No N.A.

5.8 Emissions from any other sources No N.A.

6 Generation of Noise and Vibration, and Emissions of Light and Heat:




6.1 From operation of equipment e.g. engines,ventilation plant, crushers

Yes There will be generation of noise due to operation ofequipment. Adequate sound enclosures will be providedto all equipment and machineries generating high noise.

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Ear protecting devices will be provided to the workersworking in high noise areas.Greenbelt development willhelp to abate noise levels, too.

6.2 From industrial or similar processes Yes Noise will be generated from industrial process and itwill be below the statutory norms.

6.3 From construction or demolition Yes Noise Level at different sources is expected to be comingbelow acceptable limit.

6.4 From blasting or piling No N.A.

6.5 From construction or operational traffic Yes There will be momentary increase in the noise level dueto traffic during operational phase.

6.6 From lighting or cooling systems No N.A.

6.7 From any other sources No N.A.

7 Risks of contamination of land or water from releases of pollutants into the ground or into sewers,surface waters, groundwater, coastal waters or the sea:




7.1 From handling, storage, use or spillage ofhazardous materials Yes Dyke wall will be provided to collect any spillage of

hazardous material.

7.2From discharge of sewage or other effluentsto water or the land (expected mode andplace of discharge)

No

Domestic sewage will be disposed of through a septictank and soak pit system. Effluent from Dyes plant willbe treated in ETP-1 followed by RO, RO permeate will bereused again. Effluent from dye intermediate will betreated in ETP -2 along with reject of RO and after thatthe entire effluent will be spray dried in spray dryer.

7.3 By deposition of pollutants emitted to air intothe land or into water No No major impact is anticipated.

7.4 From any other sources No N.A.

7.5Is there a risk of long term build up ofpollutants in the environment from thesesources?

No N.A.

8 Risk of accidents during construction or operation of the Project, which could affect human healthor the environment




8.1From explosions, spillages, fires etc fromstorage, handling, use or production ofhazardous substances

Yes

During the construction work no hazardous substanceswill be used, handled and stored. Therefore, no risk ofaccidents is anticipated due to hazardous substances.During the operation of the Project, guidelines of factoryact shall be followed to minimize the risk of accidents.

8.2 From any other causes No N.A.

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8.3 Could the project be affected by naturaldisasters causing environmental damage(e.g. floods, earthquakes, landslides,cloudburst etc)?

Yes Project could be affected by natural disasters – floods,earthquakes. (Project area falls under Seismic Zone-III.)

9Factors which should be considered (such as consequential development) which could lead toenvironmental effects or the potential for cumulative impacts with other existing or plannedactivities in the locality

S.No Information/Checklist confirmation Yes/NoDetails thereof (with approximate

quantities/rates, wherever possible) withsource of information data

9.1

Lead to development of supporting utilities,ancillary development or developmentstimulated by the project which could haveimpact on the environment e.g.:

Supporting infrastructure (roads, powersupply,waste or waste water treatment,etc.)housing developmentextractive industriessupply industriesOther

No

The Project will provide employment to nearbyvillages.However, no new housing development plans,extractive industries, and creation of new supplyindustries are envisioned for the project.

9.2 Lead to after-use of the site, which couldhave an impact on the environment No N.A.

9.3 Set a precedent for later developments No N.A.

9.4Have cumulative effects due to proximity toother existing or planned projectswith similar effects

No N.A.

(III) Environmental Sensitivity

S.No Areas Name/Identity Aerial distance (within 15km.) Proposedproject location boundary

1

Areas protected under internationalconventions, national or local legislation for their ecological, landscape, cultural or otherrelated value

No There are no such areas within 15 km fromproposed project area.

2

Areas which are important or sensitive forecological reasons - Wetlands, watercoursesor other water bodies, coastal zone,biospheres, mountains, forests


3

Areas used by protected, important orsensitive species of flora or fauna forbreeding, nesting, foraging, resting, overwintering, migration


4 Inland, coastal, marine or undergroundwaters No There are no such areas within 15 km from

proposed project area.

5 State, National boundaries No There are no such areas within 15 km from

A-193



proposed project area.

6Routes or facilities used by the public foraccess to recreation or other tourist, pilgrimareas


7 Defence installations No There are no such areas within 15 km fromproposed project area.

8 Densely populated or built-up area Yes Kadi and Chhatral are the densely populated areaswithin 15 km radius of the project.

9Areas occupied by sensitive man-made landuses (hospitals, schools, places of worship,community facilities)

Yes Schools and hospitals are present within 15 kmradius of the project.

10Areas containing important, high quality or scarceresources.(ground water resources,surfaceresources,forestry,agriculture,fisheries,tourism,minerals)

No There are no such areas within 15 kmfrom proposed project area.

11Areas already subjected to pollution orenvironmental damage.(those where existinglegal environmental standards are exceeded)


12

Areas susceptible to natural hazard whichcould cause the project to presentenvironmental problems (earthquakes,subsidence, landslides, erosion, flooding orextreme or adverse climatic conditions)similar effects

Yes Area is susceptible to earthquakes (falls underSeismic Zone-III).

(IV) Proposed Terms of Reference for EIA studies

1 Uploaded Proposed TOR File Annexure-TOR file

2 Uploaded scanned copy of coveringletter Annexure-scanned copy of covering letter

3 Uploaded Pre-Feasibility report(PFR) Annexure-PFR

4 Uploaded additional attachments(onlysingle pdf file) Annexure-Additional attachments

(V) UndertakingI hereby give undertaking that the data and information given in the application and enclosures aretrue to be best of my knowledge and belief and I am aware that if any part of the data andinformation found to be false or misleading at any stage, the project will be rejected and clearancegiven, if any to the project will be revoked at our risk and cost.

V.(i)

Name of Applicant AmitDesignation DirectorName of Company (Applicant Nameshould not be given here) URMIT CHEMICALS PVT. LTD.

Address Survey no. 1384, Village: Rajpur, Tal.: Kadi, Dist: Mehsana,Gujarat

Print

A-194

http://environmentclearance.nic.in/writereaddata/Online/TOR/24_Dec_2018_1608451471ST3LEVLProposedToR.pdf

http://environmentclearance.nic.in/writereaddata/Online/TOR/24_Dec_2018_160845153DC3MQV2RCoveringLetter.pdf

http://environmentclearance.nic.in/writereaddata/Online/TOR/24_Dec_2018_16084516781BTGZSPPFR.pdf

http://environmentclearance.nic.in/writereaddata/Online/TOR/24_Dec_2018_16084517781BTGZSPAnnexure.pdf

Urmit Chemicals Pvt. Ltd. 1

Proposed TORs include

The standard terms of reference (page 181‐187) for the category 5(f), issued

by the Ministry of Environment Forest and Climate change shall be followed

for preparation of EIA report. Any additional study proposed by the EAC shall

also be completed.

Ref: Standard Terms of Reference (TOR) for EIA/EMP report for

projects/activities requiring environmental clearance under EIA notification,

2006, MoEFCC, GOI, and April 2015.

A-195


Annexure-I

List of Products

Sr. No

Name of Products

Total MTPM


1. CHLORANIL 150 2. OAP

3. PAP

4. MAP

5. OAPSA

6. Metanilic Acid


8. 4 CAP

9. 4 CAPSA

10. 4 NAP

11. 5 NAP (5 NITRO 2 AMINO PHENOL)

12. 6 NAPSA

13. 4 NAPSA

14. 6 CAPSA

15. 2 PYRIDONE


17. 1 : 4 Sulpho Phenyl 3 Methyl 5 Pyrazolone (1:4 SPMP)

18. 2:5 Dichloro 4 Sulpho Phenyl 3 Methyl

5 Pyrazolone (2:5 DCSPMP)

19. 2 Chloro 5 Sulphophenyl 3 Methyl 5

Pyrazolone (2, 5 C


21. 2 Chloro Phenyl Methyl 5 Pyrazolone

22. P.T. Phenyl Methyl 5 Pyrazolone

(B) Dyes

Acid Dyes 100

1. Acid Yellow 79

2. Acid Yellow 151

3. Acid Yellow 49

4. Acid Yellow 99

5. Acid Yellow 194

6. Acid Yellow 220

7. Acid Yellow 232

8. Acid Brown 75

9. Acid Brown 165

10. Acid Brown 161

11. Acid Brown 282

12. Acid Brown 432

13. Acid Brown 425

14. Acid Brown 432

A-196


Sr.

No

Name of Products

Total

MTPM

15. Acid Green 16

16. Acid Blue 9

17. Acid Blue 15

18. Acid Blue 7

19. Acid Blue 113

20. Acid Blue 193

21. Acid Red 315

22. Acid Black 107

Direct Dyes

23. Direct Black 80


25. Direct Brown 44

26. Direct Blue 71


28. Direct Red 239

29. Direct Red 254


31. Direct Red 81

32. Direct Violet 9


34. Direct Black 19

Reactive Dyes





Basic Dyes 50 39. Basic Brown 1

40. Basic Yellow 2





Basic Dyes Liquid 100 45. Basic Yellow 2

46. Basic Violet 1

47. Basic Green 4

48. Basic Green 1

49. Basic Blue 26

Total 400

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List of Raw Material

Sr. no

.

Product name Raw Material Name Quantity MT/MT

Dyes Intermediates

1

Chloranil HCl 30% (SPENT) 1.000

Hydro quinone 0.450

Chlorine Gas 1.136

2

OAP (Ortho Amino Phenol)

ONCB 1.480

Caustic Lye 0.850

H2 Gas 0.060

Catalyst 0.004

HCl 0.040

3

PAP (Para Amino Phenol)

PNCB 1.480

Caustic Lye 0.850

H2 Gas 0.060

Catalyst 0.004

HCl 0.040

4

MAP (Meta Amino Phenol)

Metanilic Acid 1.590

NaOH 0.750

Catalyst 0.004

5

Ortho Amino Phenol

Sulphonic Acid (OAPSA)

OAP 0.580

H2SO4 0.520

Oleum 23% 0.425

6

Metanilic Acid Nitro benzene 0.720

Oleum (25%) 0.425

H2SO4 0.520

HCl (30%) 0.100

Iron Powder 0.125

7

6 Chloro Metanilic Acid ONCB 0.920

H2SO4 0.520

Oleum 0.425

Iron Powder 0.125

HCl 0.100

8

4-Chloro 2-Amino Phenol (4 CAP)

2:5 DCNB 1.350

Caustic 0.300

Iron powder 0.125

HCl 0.100

9

4 Chloro-2-Amino Phenol 5-Sulphonic

Acid (4 CAPSA)

4 CAP 0.650

Sulphuric Acid 0.520

Oleum 0.425

10

4 NAP NaSH 0.515

Lime 0.220

2:4 DNCB 1.400

NaOH 0.300

11

5 NAP OAP 0.725

Acetic Anhydride 0.675

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HNO3 0.450

H2SO4 0.850

H2 Gas 0.080

12

6 NAPSA OAP 0.470

Oleum (23%) 0.800

HNO3 0.270

H2SO4 0.550

13

4 NAPSA Lime 0.220

NaSH 0.515

4 Nitro Chloro Benzene 0.700

Oleum 0.800

HNO3 0.270

H2SO4 0.550

14

6 CAPSA 2 Chloro Phenol 0.580

Oleum 0.800

HNO3 0.270

H2SO4 0.550

Iron Powder 0.125

HCl 0.100

15

2 Pyridone Mono Ethyl Amine 0.400

Methyl Cyno Acetate 0.525

Methyl Aceto Acetate Ester 0.660

H2SO4 3.600

16

1:3 Phenyl Methyl 5 Pyrazolone (PMP)

Aniline 0.435

HCl 4.700

NaNO2 0.330

Sodium Bi Sulphite 1.160

Soda Ash 1.550

Methyl Aceto acetate ester 0.525

17

1,4 Sulpho Phenyl-3-Methyl-5-Pyrazolone

(1:4 SPMP)

Sulfanlic Acid 0.536

HCl 3.142

NaNO2 0.218

SBS 0.804

Soda Ash 1.035


18

2,5 Dichloro 4 Sulfo Phenyl 3 Methyl 5

Pyrazolone (DCSPMP)

2,5 Dichlror Aniline 0.500

HCl 1.607

NaNO2 0.221

SBS 0.696

Soda Ash 0.500

Caustic Soda Lye 0.714


19

2 Chloro 5

Sulphophenyl 3 Methyl 5 Pyrazolone

6 Chloro Metanilic Acid 0.750

HCl 2.400

NaNO2 0.265

SBS 1.150

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Soda Ash 0.850



20

1, 3 Sulpho Phenyl 3 Methyl 5 Pyrazolone

(1:3 SPMP)


HCl 2.140

NaNO2 0.217

SBS 0.800

Soda Ash 1.035


21

2 Chloro Phenyl 3 Methyl 5 Pyrazolone

Ortho Chloro Aniline 0.500

HCl 2.980

Sodium nitrite 0.275


Soda Ash 1.311

Methyl Acetoacetic Ester 0.410

22

Para Toluene Phenyl Methyl 5 Pyrazolone

Para Toludine 0.415

HCl 2.950

NaNO2 0.270


Soda Ash 1.300


Acid Dyes

1

Acid Yellow 79 DAP ESTER 0.400

H2SO4 0.540

Soda ash 0.250

5-Amino-3- methyl-1-(3-

sulfophenyl) pyrazole

0.390

Caustic flakes 0.060

Common Salt 0.650

2

Acid Yellow 151 OPSAmide 0.500

Hydrochloric Acid 0.112

Sodium Nitrite 0.184

Aceto Acetanilide 0.483

Caustic Lye 0.210

Soda Ash 0.250

Cobalt Sulphate 0.415

Common Salt 0.650

3

Acid Yellow 49 2, 5 Dichloro Sulfanilic Acid 0.500

HCl 0.800


5-Amino PMP 0.400

Common Salt 0.775

4

Acid Yellow 99 4 NAPSA 0.285

HCl 0.110

Nitrite 0.085

Acetoacetinilide 0.222

Caustic Flakes 0.052

A-200


Soda Ash 0.135

Salicylic Acid 0.185

BCS 0.380


Common Salt 0.550

5

Acid Yellow 194 4-NAPSA diazo 0.550

HCl 0.430

sodium nitrite 0.165

Acetoacetanilide 0.435

Caustic Lye 0.100

Cobalt Sulphate, 20% 0.325

6

Acid Yellow 220 Anthranilic OAPSA 0.500

HCl 0.087

Nitrite 0.112

O Cl Acetoacetinilide 0.350


Soda Ash 0.240

Cobalt Sulfate 0.230

BCS 0.050

7

Acid Yellow 232 5 Sulfo Anthranilic Acid 0.233



1-Phenyl 3 Methyl 5

Pyrozolone

0.410

Soda Ash 0.250


Basic Chromium Sulfate 0.400


8

Acid Brown 75 Picramic acid 0.192

Hydrochloric acid 0.675


Caustic lye 0.090

Resorcinol 0.096

H-Acid 0.278

Soda ash 0.346


PNA 0.113

Common Salt 0.550

9




Caustic lye 0.090

Resorcinol 0.096

H-Acid 0.278

Soda ash 0.346

PNA 0.113

Ferrous Sulphate 0.260

A-201


Common Salt 0.550

10

Acid Brown 161 Anthranilic acid 0.190

Sulphuric acid 0.190

Formaldehyde 0.080

Nitrite 0.100

Resorcinol 0.170


Aniline 2,4 SO3H 0.190

HCl 0.180


Soda Ash 0.350


B.C.S 0.200

11

Acid Brown 282 6-Nitro 0.200

Beta Napthol 0.100

Caustik Flakes 0.100


B.C.S. 0.180

4NAP 0.175

HCl 0.033

Nitrite 0.095

PMP 0.200

12

Acid Brown - 432 Anthranilic Acid 0.180

HCl 0.210

Nitrite 0.180

Resorcinol 0.150

Soda Ash 0.330

Laurent Acid 0.300


Chromium Fluoride 0.160

Liquid Ammonia 0.300


13


HCl 0.115

Nitrite 0.150

Resorcinol 0.117

Soda Ash 0.330

O.T. 5 SA. 0.220


B.C.S. 0.320


14

Acid Brown - 434 Sodium Picramate 0.267

HCl 0.645

Nitrite 0.070

Resorcinol 0.096

1,6 cleave acid 0.205


A-202


Caustic Lye 0.135


Common Salt 0.550

15

Acid Green 16 Di Methyl Aniline 0.600

Formaldehyde 0.220

Sulphanilic Acid 0.010

Soda Ash 1.030

MnO2 0.400

Napthaline 0.400


Oleum 0.450

NapthaleneDisulphonic Acid 0.750

Sodium dichromate 0.110

Oxalic Acid 0.160

Common Salt 0.650

16

Acid Blue 9 Ethyl Benzyl Aniline Sulphonic Acid

0.750

Ortho Benzaldehyde sulphonic

Acid

0.275

H2SO4 0.600

Soda Ash 0.400

HCl 0.750

MNO2 0.150

Acetic Acid 0.300

Common Salt 0.800

17

Acid Blue 15 Ethyl Benzyl Aniline Sulphonic

Acid

1.090

Di Ethyl meta Toludine 0.210

H2SO4 0.600

SODA ASH 0.400

HCl 0.750

MNO2 0.150

Acetic Acid 0.300

Common Salt 0.800

18

Acid Blue 7 Benzaldehyde Disulfonic Acid 0.330

Ethyl benzyl aniline 0.380

H2SO4 0.600

Soda Ash 0.150

HCl 0.350

MNO2 0.150

Soda Ash 0.250

HCl 0.400

Acetic Acid 0.300

Common Salt 0.800

19 Acid Blue 113 Metanillic Acid 0.300

HCl 0.120


A-203


Alpha Napthyl Amine 0.240

Nitrite 0.050

H2SO4 0.250


Phenyl peri Acid 0.490

Soda Ash 0.200

Sodium Acetate 0.300

Common Salt 0.800

20 Acid Blue 193 B Napthol 0.350

Caustic Lye 0.245

1,2,4 Diazo 0.690


BCS 0.240

21 Acid Red 315 4 NAPSA 0.225

HCl 0.250

Nitrite 0.136

PMP 0.320


Salacylic Acid 0.040

BCS 0.350

5 NAP 0.138

22 Acid Black 107 6 Nitro 0.480

Beta Napthol 0.120



ChromuimFormate 0.400

Sodium Picramate 0.200

HCl 0.250

Nitrite 0.080

Beta Napthol 0.245

Direct Dyes

23 Direct Black 80 P- amino acetanilide 0.145


HCl 0.750

Gamma Acid 0.430

Soda Ash 0.790

Caustic soda 0.215

Mixed cleves acid 0.195

Common Salt 0.550

24 Direct Yellow 11 PNTOSA 0.600

Caustic lye 0.215

Spent H2SO4 (70%) 0.500

Common Salt 0.650

25 Direct Brown 44 MPD 0.405


HCl 0.400


A-204


CS Lye 0.220

26 Direct Blue 71 C-Acid 0.165

HCl 0.700



Caustic Flake 0.080

Mix Cleave Acid 0.330

J acid 0.250

Caustic Lye 0.060

27 Direct Orange 118 O - Toludine 5 Sulphonic Acid 0.250

HCl 0.375


Sodium bi-carbonate 0.050

J-Acid Urea 0.350

Common Salt 0.650

28 Direct Red 239 Browner's acid 0.250

caustic lye 0.100


HCl 0.550

J-Acid Urea 0.292

Sodium Bi Carbonate 0.250

29 Direct Red 254 PAABSA 0.400


Soda ash 0.300

HCl 0.550

J-Acid 0.350

caustic soda lye 0.150

30 Direct Violet 35 C-Acid 0.330

HCl 0.700


p-Cresidine 0.150

Soda Ash 0.100

n-Phenyl J-Acid 0.327

Caustic lye, 48% 0.300


HCl 0.300

Caustic lye 48% 0.260

Na2CO3 0.100

Benzyl Chloride 0.150


J acid 0.280

Common Salt 0.650

32 Direct Violet 9 Sulphanilic acid 0.180

HCl 1.000


p-Cresidine 0.150

SodaAsh 0.075

A-205




33 Direct Yellow 99 DNSDA 0.550

Para anisidine 0.245

Caustic lye 0.157

HCl 0.260

Salt 0.500

34 Direct Black 19 PNA 0.210

HCl 1.080


H acid 0.245

Soda Ash 0.185


MPD 0.155

SD-40 0.020

Reactive Dyes

35 Reactive Blue 198 Cyanuric Chloride 0.220

Soda ash 0.150

Tamol 0.010

Aniline 2:4 DSA 0.320

Soda Bi Carb 0.120

Blue HEGN-Base 0.400

HCl 0.120

Dicamol 0.045

36 REACTIVE BLUE 187 EtheyleneDiamine 0.250

PNCBOSA 0.230

HCl 0.800

HCl 0.315

Sodium sulphite 0.085

Chloronail 0.175

Sodium bicarbonate 0.160


Oleum 0.300

Ammonium persulphate 0.150

Cyanuric Chloride 0.200

Aniline 2,5 disulphuric acid 0.260

Nicotinic acid 0.250

Dicamol 0.055

Dedusting Oil 0.025

37 Reactive blue 220 Sulpho OAVS 0.650

HCl 0.325


CS Lye 0.125

Sulphamic acid 0.004

Soda Ash 0.275

4-Sulpho Hydrazone 0.450

Copper sulphate 0.350

A-206


Soda Bi Carbonate 0.195

Dicamol 0.070

SD-40 0.030

38 REACTIVE BLUE 221 6-Acetyl OAPSA 0.250

CS Lye 0.055

HCl 0.800



Sodium acetate 0.120

soda ash 0.335



CS Flakes 0.350

Salt 0.120


Tamol 0.020

N-Ethyl MBE 0.220

Soda Bi Carb 0.130

Dicamol 0.055

Basic Dyes

39

Basic Brown 1 MPD 0.215

HCl 0.750

Nitrite 0.300

MPD 0.430


Common Salt 0.450

40 Basic Yellow 2 Di Methyl Aniline 0.833

Formaline 0.313

H2SO4 0.100

T G UREA 1.030

SULPHUR 0.110

Common Salt 0.450

41 Basic Violet 1 Crystal Di Methyl Aniline 0.670

Para Formaldehyde 0.110

Mono Ethyl Aniline 0.330

Catalyst 0.050

Acetic Acid 0.800

Caustic Soda 1.000

HCl 0.330

42 Basic Green 4 Crystal Di Methyl Aniline 0.800

Benzaldehyde 0.360

HCl 0.360

Acetic Acid 0.600

Catalyst 0.040

Ethyl Cellulose 0.080

Caustic Soda 0.750

Oxalic Acid 0.600

A-207


43 Basic Green 1 Crystal Di Ethylaniline 1.000

Benzaldehyde 0.330

Acetic Acid 1.460

Catalyst 0.050

Caustic Soda 0.800

H2SO4 0.600

44 Basic Blue 26 Crystal Di Methyl Aniline 0.450


Phenyl Alpha naphthalamine 0.415

Acetic Acid 0.750

Catalyst 0.020

Caustic Soda 1.000

H2SO4 0.600

45 Basic Yellow 2 Liquid Di Methyl Aniline 0.270

Formaline 0.100

H2SO4 0.050

Acetic Acid 0.225

Glycerine 0.033

T G Urea 0.335

Sulphur 0.035

0.000

46 Basic Violet 1 Liquid Di Methyl Aniline 0.330



Catalyst 0.020

Acetic Acid 0.450

47 Basic Green 4 Liquid Di Methyl Aniline 0.330

Benzaldehyde 0.150

HCl 0.150

Acetic Acid 0.300

Catalyst 0.020


48 Basic Green 1 Liquid Di Ethylaniline 0.330

Benzaldehyde 0.110

Urea 0.040

Acetic Acid 0.500

Catalyst 0.020

49 Basic Blue 26 Liquid Di Methyl Aniline 0.240



Acetic Acid 0.500

Catalyst 0.020

A-208


Annexure-II

Manufacturing Process

Manufacturing process is given in Annexure-II of EIA Report. There is no

change in process description, mass balance and chemical reaction

submitted in Form-1

A-209


Annexure-III

Water Balance Diagram

OR

Total Water Consumption

178 KLD (Fresh Water 103 KLD +Recycle 75 KLD)

Domestic

9.0

Process

59

Washing

15*+10=25

Utilities

75

Greenbelt 10

Soak pit

7.5 Dyes Int.

29.0

ETP-2 48.0

ETP -1

32.0 + 2.0 + 25.0 +3.0 + 15.0 = 77

3.0

Boiler

30

Cooling

45

15 48.0

0

In-house Spray Dryer

65

20 H2SO4

25.0

Scrubber

14.0

Total volume

86.0

Spent Acid 30.0

Drying Loss 4.0

23 HCl

Water from RM-14

SBS +HCl

12.0

2.0

RO 77.0

Reject 17

Permeate water 60.0

Evp Salt 2.25

Acetic Acid 4.0

Water from

RM-19

Dyes 16.0

Ice-30

Drying

Loss by SD 15

32.0

Total volume 65.0

UF 30.0

Water reuse 15*

Drying Loss by TD 3.0

* Common MEE facility operated by Chhatral Environment Management

system Pvt. Ltd.

Common

MEE *

A-210


Water Consumption and waste water generation

Sr.

No.


Existing

(KL/day)

Waste Water

generation

(KL/day)

1. Domestic 9.0 7.5

2. Green Belt 10.0 --

3. Industrial

A Process 45 80

B Scrubber 14 2.0

C Washing 25 25

D Boiler 30 3.0

E Cooling 45 15


Total (1 +2 + 3) 178 132.5

Less recycle 75 --

Actual fresh water

consumption

103 --

A-211


Annexure IV

Details of Hazardous/Solid waste

Sr.

No.

Type of

Solid Waste

Schedule Quantity Disposal method

1 ETP Waste

Salt from

Spray Dryer

35.3 150.0

65.0

215.0

Collection, storage & disposal at

TSDF site approved by GPCB.

2 HCl

(20-22%)

26.3 52 MT/month

Collection, Storage and captive

consumption and/or sell to

actual user.

3 Spent

Sulphuric

acid (H2SO4)

26.3 780 MT/month

Collection, Storage, Reuse with

in the process or sold to actual

users.

4 Iron sludge 26.1 52

MT/month


Transportation, sell to cement

manufacturer or disposed at

TSDF site.

5 Calcium Thio

Sulphite

-- 78

MT/month


Transportation, sell to actual

users under Haz. Waste rule.


MT/month




7 Sodium

Bisulphite

26.3 260 MT/month




8 Used

Lubricating

Oil

5.1 0.5 Kl/year Collection, storage & use within

premises as lubricant/sell to

registered recycler.

9 Discarded

containers/

barrels/

liners

33.1 Barrels-10000

nos./month Liner-1.0 Mt/month

Collection, storage and reuse for

packing of products or disposal

by selling to approved recycler.

10 Spent

catalyst

28.2 0.5

MT/month

Collection, storage &return back

to supplier for regeneration.

A-212


Annexure-V

Source of Air Emissions

Flue gas Stack-Proposed

Sr.

No.

Stack attached

to

Stack

Height

in m

Fuel

Used

Fuel

consumption

rate

APC

measure

Pollutant

1 Steam Boiler

(1TPH)

21 Coal 4 TPD Cyclone

followed

by bag

filter

PM<150 mg/NM3

SO2<100 ppm

NOx<50 ppm

2 Steam Boiler

(2 TPH)


followed

by

bagfilter

3 Hot air

generator

(5.0 lac Kcal/hr)


followed

by

bagfilter

4 Hot air

generator

(10.0 lac

Kcal/hr)


followed

by

bagfilter

5 Hot air

generator

(25.0 lac

Kcal/hr)


followed

by

bagfilter

6 Thermic fluid

heater

(25 lac Kcal/hr.)


followed

by bag

filter

7 DG Set (Stand

By) (500 kVA)

11 HSD 100 Liter/Hr --

Process gas Stack-Proposed

8 spray dryer-1

(For Product

Recovery)

(20 KL/Day)

15 -- -- Cyclone

+

Scrubber

+ Sub

merged

type gas

bubbling

tank

PM<150 mg/NM3

9 Spray Dryer-2

(For Effluent)

(40 KL/Day)

21 -- -- PM<150 mg/NM3

10 Spray Dryer-3

(For Effluent)

(40 KL/Day)

PM<150 mg/NM3

11 Reaction Vessels

of Multipurpose

Plant – 2 sets

21 -- -- Alkaline

Scubber

SO2<40 mg/NM3

12 Reaction Vessel

of Chloranil

11 -- -- Water

Scubber

HCl<20 mg/NM3

A-213

A-214

Admin

Text Box

Annexure VI Land Possession Document


Pre Feasibility Report

of

URMIT CHEMICALS PVT.LTD.

Survey No. 1384,

Village:Rajpur, Tal: Kadi,

Dist: Mahesana, Gujarat

A-215


1. INTRODUCTION

M/s. Urmit Chemicals Pvt. Ltd. proposes to manufacture Dyes

intermediates and various dyes at Survey No. 1384, Village: Rajpur, Tal:

Kadi, Dist.: Mehsana-382705.

2. Cost of Project:

The estimated costof the project for the proposed new manufacturing

project is estimated around Rs. 5.0Crore. Out of this around Rs. 1.5

crores will be invested for pollution control measures.

3. Production Capacity

Production capacity is prescribe below:

List of Products

Sr. No

Name of Products

Total MTPM


1. CHLORANIL 150 2. OAP

3. PAP

4. MAP

5. OAPSA

6. Metanilic Acid


8. 4 CAP

9. 4 CAPSA

10. 4 NAP

11. 5 NAP (5 NITRO 2 AMINO PHENOL)

12. 6 NAPSA

13. 4 NAPSA

14. 6 CAPSA

15. 2 PYRIDONE

16. 1:3 PHENYL METHYL 5 PYRAZOLONE (PMP)

17. 1 : 4 Sulpho Phenyl 3 Methyl 5 Pyrazolone (1:4 SPMP)


19. 2 Chloro 5 Sulphophenyl 3 Methyl 5 Pyrazolone (2,

5 C


21. 2 Chloro Phenyl Methyl 5 Pyrazolone

22. P.T. Phenyl Methyl 5 Pyrazolone

(B) Dyes

Acid Dyes 100

1. Acid Yellow 79

A-216


Sr.

No

Name of Products

Total

MTPM

2. Acid Yellow 151

3. Acid Yellow 49

4. Acid Yellow 99

5. Acid Yellow 194

6. Acid Yellow 220

7. Acid Yellow 232

8. Acid Brown 75

9. Acid Brown 165

10. Acid Brown 161

11. Acid Brown 282

12. Acid Brown 432

13. Acid Brown 425

14. Acid Brown 432

15. Acid Green 16

16. Acid Blue 9

17. Acid Blue 15

18. Acid Blue 7

19. Acid Blue 113

20. Acid Blue 193

21. Acid Red 315

22. Acid Black 107

Direct Dyes

23. Direct Black 80


25. Direct Brown 44

26. Direct Blue 71


28. Direct Red 239

29. Direct Red 254


31. Direct Red 81

32. Direct Violet 9


34. Direct Black 19

Reactive Dyes





Basic Dyes 50 39. Basic Brown 1

40. Basic Yellow 2





A-217


Sr.

No

Name of Products

Total

MTPM

Basic Dyes Liquid 100 45. Basic Yellow 2

46. Basic Violet 1

47. Basic Green 4

48. Basic Green 1

49. Basic Blue 26

Total 400

List of Raw Material

Sr. no.

Product name Raw Material Name Quantity MT/MT

Dyes Intermediates

1

Chloranil HCl 30% (SPENT) 1.000

Hydro quinone 0.450

Chlorine Gas 1.136

2

OAP (Ortho Amino Phenol)

ONCB 1.480

Caustic Lye 0.850

H2 Gas 0.060

Catalyst 0.004

HCl 0.040

3

PAP (Para Amino Phenol)

PNCB 1.480

Caustic Lye 0.850

H2 Gas 0.060

Catalyst 0.004

HCl 0.040

4

MAP (Meta Amino

Phenol)


NaOH 0.750

Catalyst 0.004

5

Ortho Amino Phenol Sulphonic Acid

(OAPSA)

OAP 0.580

H2SO4 0.520

Oleum 23% 0.425

6

Metanilic Acid Nitro benzene 0.720

Oleum (25%) 0.425

H2SO4 0.520

HCl (30%) 0.100

Iron Powder 0.125

7

6 Chloro Metanilic Acid ONCB 0.920

H2SO4 0.520

Oleum 0.425

Iron Powder 0.125

HCl 0.100

8

4-Chloro 2-Amino

Phenol (4 CAP)

2:5 DCNB 1.350

Caustic 0.300

Iron powder 0.125

A-218


HCl 0.100

9

4 Chloro-2-Amino Phenol 5-Sulphonic

Acid (4 CAPSA)

4 CAP 0.650


Oleum 0.425

10

4 NAP NaSH 0.515

Lime 0.220

2:4 DNCB 1.400

NaOH 0.300

11

5 NAP OAP 0.725

Acetic Anhydride 0.675

HNO3 0.450

H2SO4 0.850

H2 Gas 0.080

12

6 NAPSA OAP 0.470

Oleum (23%) 0.800

HNO3 0.270

H2SO4 0.550

13

4 NAPSA Lime 0.220

NaSH 0.515

4 Nitro Chloro Benzene 0.700

Oleum 0.800

HNO3 0.270

H2SO4 0.550

14

6 CAPSA 2 Chloro Phenol 0.580

Oleum 0.800

HNO3 0.270

H2SO4 0.550

Iron Powder 0.125

HCl 0.100

15

2 Pyridone Mono Ethyl Amine 0.400

Methyl Cyno Acetate 0.525


H2SO4 3.600

16

1:3 Phenyl Methyl 5 Pyrazolone (PMP)

Aniline 0.435

HCl 4.700

NaNO2 0.330


Soda Ash 1.550

Methyl Aceto acetate ester 0.525

17

1,4 Sulpho Phenyl-3-Methyl-5-Pyrazolone

(1:4 SPMP)

Sulfanlic Acid 0.536

HCl 3.142

NaNO2 0.218

SBS 0.804

Soda Ash 1.035


18 2,5 Dichloro 4 Sulfo 2,5 Dichlror Aniline 0.500

A-219


Phenyl 3 Methyl 5

Pyrazolone (DCSPMP)

HCl 1.607

NaNO2 0.221

SBS 0.696

Soda Ash 0.500



19

2 Chloro 5

Sulphophenyl 3 Methyl 5 Pyrazolone

6 Chloro Metanilic Acid 0.750

HCl 2.400

NaNO2 0.265

SBS 1.150

Soda Ash 0.850



20

1, 3 Sulpho Phenyl 3 Methyl 5 Pyrazolone

(1:3 SPMP)


HCl 2.140

NaNO2 0.217

SBS 0.800

Soda Ash 1.035


21

2 Chloro Phenyl 3 Methyl 5 Pyrazolone

Ortho Chloro Aniline 0.500

HCl 2.980



Soda Ash 1.311


22

Para Toluene Phenyl Methyl 5 Pyrazolone

Para Toludine 0.415

HCl 2.950

NaNO2 0.270


Soda Ash 1.300


Acid Dyes

1

Acid Yellow 79 DAP ESTER 0.400

H2SO4 0.540

Soda ash 0.250

5-Amino-3- methyl-1-(3-

sulfophenyl) pyrazole

0.390

Caustic flakes 0.060

Common Salt 0.650

2

Acid Yellow 151 OPSAmide 0.500



Aceto Acetanilide 0.483

Caustic Lye 0.210

Soda Ash 0.250

Cobalt Sulphate 0.415

Common Salt 0.650

A-220


3

Acid Yellow 49 2, 5 Dichloro Sulfanilic Acid 0.500

HCl 0.800


5-Amino PMP 0.400

Common Salt 0.775

4

Acid Yellow 99 4 NAPSA 0.285

HCl 0.110

Nitrite 0.085

Acetoacetinilide 0.222


Soda Ash 0.135


BCS 0.380


Common Salt 0.550

5

Acid Yellow 194 4-NAPSA diazo 0.550

HCl 0.430

sodium nitrite 0.165

Acetoacetanilide 0.435

Caustic Lye 0.100

Cobalt Sulphate, 20% 0.325

6

Acid Yellow 220 Anthranilic OAPSA 0.500

HCl 0.087

Nitrite 0.112

O Cl Acetoacetinilide 0.350


Soda Ash 0.240

Cobalt Sulfate 0.230

BCS 0.050

7

Acid Yellow 232 5 Sulfo Anthranilic Acid 0.233



1-Phenyl 3 Methyl 5

Pyrozolone

0.410

Soda Ash 0.250


Basic Chromium Sulfate 0.400


8




Caustic lye 0.090

Resorcinol 0.096

H-Acid 0.278

Soda ash 0.346


PNA 0.113

A-221


Common Salt 0.550

9




Caustic lye 0.090

Resorcinol 0.096

H-Acid 0.278

Soda ash 0.346

PNA 0.113


Common Salt 0.550

10


Sulphuric acid 0.190

Formaldehyde 0.080

Nitrite 0.100

Resorcinol 0.170


Aniline 2,4 SO3H 0.190

HCl 0.180


Soda Ash 0.350


B.C.S 0.200

11

Acid Brown 282 6-Nitro 0.200

Beta Napthol 0.100

Caustik Flakes 0.100


B.C.S. 0.180

4NAP 0.175

HCl 0.033

Nitrite 0.095

PMP 0.200

12

Acid Brown - 432 Anthranilic Acid 0.180

HCl 0.210

Nitrite 0.180

Resorcinol 0.150

Soda Ash 0.330

Laurent Acid 0.300


Chromium Fluoride 0.160

Liquid Ammonia 0.300


13


HCl 0.115

Nitrite 0.150

Resorcinol 0.117

Soda Ash 0.330

A-222


O.T. 5 SA. 0.220


B.C.S. 0.320


14

Acid Brown - 434 Sodium Picramate 0.267

HCl 0.645

Nitrite 0.070

Resorcinol 0.096

1,6 cleave acid 0.205


Caustic Lye 0.135


Common Salt 0.550

15

Acid Green 16 Di Methyl Aniline 0.600

Formaldehyde 0.220


Soda Ash 1.030

MnO2 0.400

Napthaline 0.400


Oleum 0.450

NapthaleneDisulphonic Acid 0.750

Sodium dichromate 0.110

Oxalic Acid 0.160

Common Salt 0.650

16

Acid Blue 9 Ethyl Benzyl Aniline Sulphonic Acid

0.750

Ortho Benzaldehyde sulphonic

Acid

0.275

H2SO4 0.600

Soda Ash 0.400

HCl 0.750

MNO2 0.150

Acetic Acid 0.300

Common Salt 0.800

17

Acid Blue 15 Ethyl Benzyl Aniline Sulphonic

Acid

1.090

Di Ethyl meta Toludine 0.210

H2SO4 0.600

SODA ASH 0.400

HCl 0.750

MNO2 0.150

Acetic Acid 0.300

Common Salt 0.800

18

Acid Blue 7 Benzaldehyde Disulfonic Acid 0.330

Ethyl benzyl aniline 0.380

H2SO4 0.600

A-223


Soda Ash 0.150

HCl 0.350

MNO2 0.150

Soda Ash 0.250

HCl 0.400

Acetic Acid 0.300

Common Salt 0.800

19 Acid Blue 113 Metanillic Acid 0.300

HCl 0.120



Nitrite 0.050

H2SO4 0.250


Phenyl peri Acid 0.490

Soda Ash 0.200


Common Salt 0.800

20 Acid Blue 193 B Napthol 0.350

Caustic Lye 0.245

1,2,4 Diazo 0.690


BCS 0.240

21 Acid Red 315 4 NAPSA 0.225

HCl 0.250

Nitrite 0.136

PMP 0.320



BCS 0.350

5 NAP 0.138

22 Acid Black 107 6 Nitro 0.480

Beta Napthol 0.120



ChromuimFormate 0.400

Sodium Picramate 0.200

HCl 0.250

Nitrite 0.080

Beta Napthol 0.245

Direct Dyes

23 Direct Black 80 P- amino acetanilide 0.145


HCl 0.750

Gamma Acid 0.430

Soda Ash 0.790

Caustic soda 0.215

A-224


Mixed cleves acid 0.195

Common Salt 0.550

24 Direct Yellow 11 PNTOSA 0.600

Caustic lye 0.215

Spent H2SO4 (70%) 0.500

Common Salt 0.650

25 Direct Brown 44 MPD 0.405


HCl 0.400


CS Lye 0.220

26 Direct Blue 71 C-Acid 0.165

HCl 0.700



Caustic Flake 0.080

Mix Cleave Acid 0.330

J acid 0.250

Caustic Lye 0.060

27 Direct Orange 118 O - Toludine 5 Sulphonic Acid 0.250

HCl 0.375


Sodium bi-carbonate 0.050

J-Acid Urea 0.350

Common Salt 0.650

28 Direct Red 239 Browner's acid 0.250

caustic lye 0.100


HCl 0.550

J-Acid Urea 0.292

Sodium Bi Carbonate 0.250



Soda ash 0.300

HCl 0.550

J-Acid 0.350

caustic soda lye 0.150

30 Direct Violet 35 C-Acid 0.330

HCl 0.700


p-Cresidine 0.150

Soda Ash 0.100




HCl 0.300

Caustic lye 48% 0.260

A-225


Na2CO3 0.100

Benzyl Chloride 0.150


J acid 0.280

Common Salt 0.650

32 Direct Violet 9 Sulphanilic acid 0.180

HCl 1.000


p-Cresidine 0.150

SodaAsh 0.075



33 Direct Yellow 99 DNSDA 0.550

Para anisidine 0.245

Caustic lye 0.157

HCl 0.260

Salt 0.500

34 Direct Black 19 PNA 0.210

HCl 1.080


H acid 0.245

Soda Ash 0.185


MPD 0.155

SD-40 0.020

Reactive Dyes

35 Reactive Blue 198 Cyanuric Chloride 0.220

Soda ash 0.150

Tamol 0.010

Aniline 2:4 DSA 0.320

Soda Bi Carb 0.120

Blue HEGN-Base 0.400

HCl 0.120

Dicamol 0.045

36 REACTIVE BLUE 187 EtheyleneDiamine 0.250

PNCBOSA 0.230

HCl 0.800

HCl 0.315

Sodium sulphite 0.085

Chloronail 0.175

Sodium bicarbonate 0.160


Oleum 0.300

Ammonium persulphate 0.150


Aniline 2,5 disulphuric acid 0.260

Nicotinic acid 0.250

A-226


Dicamol 0.055

Dedusting Oil 0.025

37 Reactive blue 220 Sulpho OAVS 0.650

HCl 0.325


CS Lye 0.125


Soda Ash 0.275



Soda Bi Carbonate 0.195

Dicamol 0.070

SD-40 0.030

38 REACTIVE BLUE 221 6-Acetyl OAPSA 0.250

CS Lye 0.055

HCl 0.800



Sodium acetate 0.120

soda ash 0.335



CS Flakes 0.350

Salt 0.120


Tamol 0.020

N-Ethyl MBE 0.220

Soda Bi Carb 0.130

Dicamol 0.055

Basic Dyes

39

Basic Brown 1 MPD 0.215

HCl 0.750

Nitrite 0.300

MPD 0.430


Common Salt 0.450

40 Basic Yellow 2 Di Methyl Aniline 0.833

Formaline 0.313

H2SO4 0.100

T G UREA 1.030

SULPHUR 0.110

Common Salt 0.450

41 Basic Violet 1 Crystal Di Methyl Aniline 0.670



Catalyst 0.050

Acetic Acid 0.800

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Caustic Soda 1.000

HCl 0.330

42 Basic Green 4 Crystal Di Methyl Aniline 0.800

Benzaldehyde 0.360

HCl 0.360

Acetic Acid 0.600

Catalyst 0.040


Caustic Soda 0.750

Oxalic Acid 0.600

43 Basic Green 1 Crystal Di Ethylaniline 1.000

Benzaldehyde 0.330

Acetic Acid 1.460

Catalyst 0.050

Caustic Soda 0.800

H2SO4 0.600

44 Basic Blue 26 Crystal Di Methyl Aniline 0.450



Acetic Acid 0.750

Catalyst 0.020

Caustic Soda 1.000

H2SO4 0.600

45 Basic Yellow 2 Liquid Di Methyl Aniline 0.270

Formaline 0.100

H2SO4 0.050

Acetic Acid 0.225

Glycerine 0.033

T G Urea 0.335

Sulphur 0.035

46 Basic Violet 1 Liquid Di Methyl Aniline 0.330



Catalyst 0.020

Acetic Acid 0.450

47 Basic Green 4 Liquid Di Methyl Aniline 0.330

Benzaldehyde 0.150

HCl 0.150

Acetic Acid 0.300

Catalyst 0.020


48 Basic Green 1 Liquid Di Ethylaniline 0.330

Benzaldehyde 0.110

Urea 0.040

Acetic Acid 0.500

Catalyst 0.020

49 Basic Blue 26 Liquid Di Methyl Aniline 0.240

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Acetic Acid 0.500

Catalyst 0.020

4. ManufacturingProcess

Manufacturing process is given as Annexure – II in form-1.

5. Details of manpower

Total manpower requirement at all level of plant will be 100.

6. Water Consumption & Waste Water Generation

Sr.

No.


Existing

(KL/day)

Waste Water

generation

(KL/day)

1. Domestic 9.0 7.5

2. Green Belt 10.0 --

3. Industrial

A Process 45 80

B Scrubber 14 2.0

C Washing 25 25

D Boiler 30 3.0

E Cooling 45 15


Total (1 +2 + 3) 178 132.5

Less recycle 75 --

Actual fresh water

consumption

103 --

7. Source of Pollution

Details of Air Pollution

There will be 7flue gas stacks,which will the main emission source from the

plant under the Air Pollution Control Act, 1981. Cyclone followed by bag

filter will be provided on flue gas stack as APCM. Process emission will be

from spray dryers, process vent attach to reaction vessel of multipurpose

plant (2 Sets) and reaction vessel of Chloranil. Proper Stack height & APCM

will be provided in order to achieve norms prescribed by statutory

authority.The details of stacks are given below:

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Source of Air Emissions

Flue Gas Stack

Sr. No.

Stack attached to

Stack Height

in m

Fuel Used

Fuel consumption

rate

APC measure

Pollutant

1 Steam Boiler

(1 TPH)


followed by bag

filter

PM<150

mg/NM3 SO2<100 ppm

NOx<50 ppm

2 Steam Boiler (2 TPH)

21 Coal 8 TPD Cyclone followed by bag

filter

3 Hot air generator (5.0 lac

Kcal/hr)

21 Coal 3 TPD Cyclone followed by bag

filter

4 Hot air generator

(10.0 lac Kcal/hr)

30 Coal 6 TPD Cyclone followed

by bag filter

5 Hot air generator

(25.0 lac Kcal/hr)


by bag filter

6 Thermic fluid heater

(25 lac Kcal/hr.)


by bag filter

7 DG Set (Stand

By) (500 kVA)

11 HSD 100 Liter/Hr --

Process gas Stack

8 spray dryer-1

(For Product Recovery)

20 KL/Day

15 -- -- Cyclone

+ Scrubber

+ Sub merged type gas

bubbling tank

PM<150

mg/NM3

9 Spray Dryer-2

(For Effluent) (40 KL/Day)

21 -- -- PM<150

mg/NM3

10 Spray Dryer-3

(For Effluent) (40 KL/Day)

21 -- -- PM<150

mg/NM3


Multipurpose Plant – 2 sets

21 -- -- Alkaline Scubber

SO2<40 mg/NM3


Chloranil

11 -- -- Water Scubber

HCl<20 mg/NM3

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Source and disposal of waste water

Effluent from Dyes plant will be treated in ETP-1 followed by RO, RO

permeate will be reused again. Effluent from dye intermediate will be

treated in ETP -2 along with RO reject and after that the entire effluent will

be spray dried in spray dryer. Domestic sewage will be disposed of through

a septic tank and soak pit system. Hence, Unit will maintain “Zero Liquid

Discharge”

Source and disposal of Hazardous wastes

There will be Ten sources of Solid/hazardous waste generation. ETP Sludge

& salt from Spray Dryer will be disposed off to approve TSDF site. Iron

sludge will be sold to the cement plant or disposed off to approve TSDF site. HCl

will be reused within premises. Spent sulfuric Acid will be reused within process

and partly sold to actual users. Calcium Thio Sulphite, Acetic Acid, Sodium

Bisulphite will be sold to actual user. Used/ Spent oil will be sold to actual

users and Containers/Barrels&liners will be sold to registered recyclers. The

details of Solid/hazardous waste are given below:

Sr.

No.

Type of

Solid Waste

Schedule Quantity Disposal method

1 ETP Waste

Salt from

Spray Dryer

35.3 150.0

65.0

215.0

Collection, storage & disposal at

TSDF site approved by GPCB.

2 HCl

(20-22%)

26.3 52 MT/month

Collection, Storage and captive

use in the plant premises.

3 Spent

Sulphuric

acid (H2SO4)

26.3 780 MT/month



users.

4 Iron sludge 26.1 52 MT/month


Transportation, sell to cement

manufacturer or disposed at

TSDF site.

5 Calcium Thio

Sulphite

-- 78 MT/month


Transportation, sell to actual



MT/month




7 Sodium

Bisulphite

26.3 260

MT/month




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8 Used

Lubricating

Oil

5.1 0.5 Kl/year Collection, storage & use within

premises as lubricant/sell to

registered recycler.

9 Discarded

containers/

barrels/

liners

33.1 Barrels-

10000 nos./month Liner-1.0

Mt/month

Collection, storage and reuse for

packing of products or disposal

by selling to approved recycler.

10 Spent

catalyst

28.2 0.5 MT/month

Collection, storage &return back

to supplier for regeneration.

8. FUNDS FOR POLLUTION CONTROL MEASURES

The management is quite conscious of its responsibility for maintaining

clear environment adequate funds can be provided for the pollution control

measures as financing part of overall project.Necessary provision for

Environmental management system is in practice.

9. MONITORING FACILITIES

Air sampling will be done by outside agency and will be part of practice in

future projects.

10. CONCLUSION

On the basis of information presented in the pre-feasibility report on

pollution control measures and after its implementation, there will be no

discharge of effluent and air emission from the plant beyond the norms

specified by the Board as per the provisions of Air (Prevention and Control

of Pollution) Act, 1981 and Water (Prevention and Control of Pollution).

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