Dr. Xu Shisen - iea.blob.core.windows.net
Transcript of Dr. Xu Shisen - iea.blob.core.windows.net
GreenGen and CO2 Capture Demonstration Projects
Dr. Xu Shisen
China Huaneng Group Clean Energy Research Institute
石油,燃气,煤,石
油焦
燃烧后PC
燃烧前PCDC
纯氧燃烧Oxyful
电力,热,
蒸汽空气
分离烟气
脱碳烟气
煤气
电力,
热,蒸汽
空气
H2
分离
燃料
CO2+H2O
空分空气
氧气 N2
电力,热,
蒸汽
CO2+H2O
锅炉
气化炉气化 重整 燃机,燃
料电池
纯氧燃
烧系统
CO2+H2O
压缩,脱水和输
送
封存测量和
监控驱油
驱煤层气
老油气田
盐田
生物固定
食品工业
化工用品
海洋
燃烧后捕碳技术适合传统燃煤电厂 燃烧前捕碳技术适合IGCC电厂
富氧燃烧技术适合传统燃煤电厂
How to capture CO2from power plant
Main CCS Demo. Projects from CHNG
www.chng.com.cn
3000 t/a Post-Combustion Capture CO2 and Refining
Utilization Project of China Huaneng Group
The First
Project in
China
120,000t/a Post-Combustion Capture CO2 and Refining
Utilization Project of China Huaneng Group
The Biggest
Project in
the world
Near Zero Emission Project for Coal
Fired Power Plant--- GreenGenNZEC plant
GreenGen Project
绿色煤电项目
GreenGen Ltd., Co.
Under the support of NDRC,MOST and other ministries and commissions, CHNG united other 8 energy enterprises founded the GreenGen Ltd., Co. China .
China Huaneng Group
China Datang Group
China Huadian Corporation
China Guodian Corporation
China Power Investment Corporation
Shenhua Group
State Development & Investment Co.
China Coal Group
Peabody
The founder agreement signing ceremony of GreenGen Ltd.
Energy enterprises support environment-friendly ,high
efficiency ,Independent innovation
Objective of GreenGen
• To research/develop and demonstrate (RD&D) the integrated coal gasification, hydrogen production, hydrogen power generation and CO2 sequestration system
• To achieve high coal-based generation efficiency and zero emission of all pollutant and CO2
• To master the core technologies and system integration technology form GreenGen technology with Chinese property right
• To conduct commercial demonstration atacceptable price and realize sustainable development of coal-based generation
IGCC plant
R&D for Key technologies ;
Improve IGCC technology
GreenGen demo-
engineering
Stage I Stage II Stage III
2000 t/d Gasification
250 MW IGCC
polygeneration (Power-
Heat-Syngas)
Build the GreenGen
Labaratory
Improve the IGCC polygeneration(Power-Heat-Syngas) technology
Economic and technical compare between 3500 t/d and 2×2000 t/dgasifers
H2 production
CCS
Fuel cell power generation technology
Preliminary work of the GreenGendemonstration
Build a 400MW GreenGen
demo-Engineering, including
H2 production, FC power
generation, H2 turbine
combined cycle generation and
CCS
Operate the GreenGen plant
Prove the GreenGen
economic viability
Prepare and extend for
commercial system
IGCC plant
R&D for Key technologies ;
Improve IGCC technology
GreenGen demo-
engineering
Stage I Stage II Stage III
2000 t/d Gasification
250 MW IGCC
polygeneration (Power-
Heat-Syngas)
Build the GreenGen
Labaratory
Improve the IGCC polygeneration(Power-Heat-Syngas) technology
Economic and technical compare between 3500 t/d and 2×2000 t/dgasifers
H2 production
CCS
Fuel cell power generation technology
Preliminary work of the GreenGendemonstration
IGCC plant IGCC plant
R&D for Key technologies ;
Improve IGCC technology
R&D for Key technologies ;
Improve IGCC technology
GreenGen demo-
engineering
GreenGen demo-
engineering
Stage I Stage II Stage III
2000 t/d Gasification
250 MW IGCC
polygeneration (Power-
Heat-Syngas)
Build the GreenGen
Labaratory
Improve the IGCC polygeneration(Power-Heat-Syngas) technology
Economic and technical compare between 3500 t/d and 2×2000 t/dgasifers
H2 production
CCS
Fuel cell power generation technology
Preliminary work of the GreenGendemonstration
Build a 400MW GreenGen
demo-Engineering, including
H2 production, FC power
generation, H2 turbine
combined cycle generation and
CCS
Operate the GreenGen plant
Prove the GreenGen
economic viability
Prepare and extend for
commercial system
Three Stages of the GreenGen Programe
The Flow Sheet of GreenGen
GreenGen Phase II
Ga
s
Pu
rifica
tion
Polygeneration
Chemical Raw
Material
Water
Clean gas
1.WGSCO2 Capture
8700 Nm3/h H2
1300Nm3/h N2
6100 Nm3/h
CO2
Fuel Cell
Hydrogen
turbine
2.Hydrogen
Hydrogen
ultra clean-up
Hydrogen
storage
3. transport supply
4.CO2
compress、
dry、transfer
CO2 stogage
In Geologic
formations
CO2
Enhance Oil
Recovery
5.CO2 sequestration
230kW
CO2 transfer coal
powder
10,000 Nm3/h
60,000-100,000t/a CO2 capture and
sequestration
2012 Start Operation
Air Air Separation Nitrogen
Oxygen
Coal
Water or
Steam
Ga
sific
atio
nM
ark
eta
ble
As
h a
nd
Sla
g
Water
Ga
s
Pu
rifica
tion
Su
lfur
Rec
ove
ryM
ark
eta
ble
Su
lfur
Syn
gas
Sh
ift
Air Ga
s T
urb
ine
Ste
am
Tu
rbin
e
Power
PowerFuel Cell
Cle
an
Ga
s
Ge
o-
Sto
rag
e
Co
al B
ed
s
EO
R
H2 &
CO
2
Se
para
tion
H2
Se
pa
ratio
n
H2
CO2R
ich
Hyd
rog
en
Phase III -- 400MW GreenGen Project
www.chng.com.cn
Under-construction of the 250MW IGCC
•Power: 265MW•Net eff. 41%•SO2 : <1.4mg/Nm3
•NOX: 52mg/Nm3•PM: <1mg/Nm3
•Start to operate in June 2011
• Gasifier: TPRI• GT: SIEMENS• ASU: Kai Kong• ST: Shanghai Electric• HRSG: Hang Guo
3000 t/a PCC Plant
燃煤电厂3000吨/年 CO2捕集系统
PCC Demonstration
3000t/a CO2 Capture Plant in Beijing
3000 t/a Capture in Huaneng Beijing Thermal Power Plant
• Input CO2 in FG:12%-15%
• Capacity:1800-3200Nm3/h (75%-135%) FG
• CO2 in Exhaust Gas: ~2%
• Captured CO2 : 99.7%~99.997%,350-600kg/h
• SO2 can’t find
• 3000t/a Food Grade CO2 Produced and Sold
3000t/a CO2 capture Pilot Plant
International report about the PCC project,
including SCIENCE and NATURE
120,000 t/a PCC from coal-fired
power plant in Shanghai
上海12万吨/年CO2捕集项目
120,000 t/a PCC project
Brief Information 简介
• Project:660 USC in Huaneng Shanghai Shidongkou
No.2 power plant
依托华能上海石洞口二厂66万超超临界机组
• Scale:capture from 70,000Nm3/h flue gas, recovery CO2
16.7t/h and 100,000t/a
从70,000Nm3/h烟气中捕集,每小时回收CO2 16.7t
• CO2: main food-grade, remain industrial-grade
CO2主要为食品级,部分工业级
• Cost: Less than 30$/t CO2
• Project Period: 2008.12~2009.12 , EPC by CHNG
项目工期: 2008.12~2009.12
Feasibility Study Based on 600MW Unit: consider full chain
of capture, transport, EOR and storage of CO2
进行600MW机组全流量CO2捕集、运输、EOR与封存的可研
Financial requirements and potential sourcing
资金需求及可能的经费来源
PDP towards realisation of full-scale CCUS demonstration
为实现全流量CCUS示范项目的初步设计
Environmental impact assessment
环境影响评估
Selection of preferred demonstration project location
筛选最优的一个工程实施地点
JCG meeting Shanghai 24
Towards Full Scale CCUS Demonstration
COACH
华能牵头开展基于250MW与400MW IGCC电站的系统研究与设计;
华能牵头进行气化接口及CO2捕集接口的研究
NZEC
华能牵头开展基于400MW电站的案例研究方案及燃烧前CO2捕集研究
CHNG-ENEL CCS项目
示范项目试验经验分享与交流
利用华能清能院技术针对华能铜川电厂开展100万吨级捕集预可行性研究
CERC
清洁煤技术联盟,华能清能院为中方牵头单位
International Cooperation
国际合作项目
CHNG-Duke Energy
签署合作备忘录
利用华能清能院技术,正在进行100万吨级全流量CO2捕集与封存
项目前期方案及可行性研究
CHNG-AEP
签署合作备忘录
利用华能清能院技术,正在进行100万吨级全流量CO2捕集与封存
项目前期方案及可行性研究
CERI-LLNL 美国劳伦斯利弗摩尔国家实验室
签署合作备忘录
在CCS、IGCC等专业领域结成合作伙伴,开展技术交流与合作
针对杜克能源项目,开展项目互相评估合作
International Cooperation
国际合作项目
CERI-SaskPower
委托华能清能院开展100万吨CO2捕集技术方案评估及初步可行性研
究
加方邀请清能院参与BD3机组大型示范项目工程阶段技术审查等
CERI-CSIRO
合作进行100kg/hCO2捕集移动测试平台设计与测试
进行中澳洁净煤工作组合作框架下的大规模CCUS项目范围研究及可
行性研究
CERI-EmberClear 美国宾西法尼亚IGCC项目
气化炉处理煤量: 2300t/d
清能院已完成全厂和气化岛的PDP设计
CERI-PowerSpan
合作参与该项目的技术评估及项目投标
International Cooperation
国际合作项目
It is very important for CCS to start to do
demonstration projects
International Cooperation is important for us
Thank you for your attention