Double bonds or not
description
Transcript of Double bonds or not
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Double bonds or not
• A saturated fat has no C=C double bonds (alkene functional groups) and is usually a solid fat like margarine or animal fat.
• An unsaturated fat has C=C double bonds and is usually an oil like vegetable oil.
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Example question
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Mark scheme
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Making margarine
• To make margarine we have to saturate vegetable oil by bubbling hydrogen gas through the oil.
• This process is called hydrogenation
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Is a fat or oil saturated or not?
• We can test for this by adding bromine water.
• If there are double bonds present the bromine water changes from orange/brown to colourless.
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Example question
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Mark scheme
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Hydrolysis
• When an ester is hydrolysed it goes back to an acid and alcohol
• We can hydrolyse by adding acid or alkali (NaOH).
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Example question
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Mark scheme
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Energy changes in chemistry
C7.2
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Quiz
• When a chemical reaction takes place heat may be given out or taken in.
1. Can you remember the word we use when heat is given out?
2. Can you remember the word we use when heat is taken in?
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What do I need to know?
1. Recall and use the terms ENDOTHERMIC and EXOTHERMIC
2. Describe examples of ENDOTHERMIC and EXOTHERMIC reactions.
3. Use simple energy level diagrams to represent ENDOTHERMIC and EXOTHERMIC reactions.
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Change in energy
• Chemical reactants have a certain amount of chemical energy stored within them.
• When the reaction has taken place they have either more or less energy stored within them than before.
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Definitions
When heat is given out (exothermic) then the products have less energy than they did before. They have lost it to the surroundings.
When heat is taken in (endothermic) then the products have more energy than they had before. They have taken it from the surroundings.
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Energy level diagrams
Which diagram do you think is endothermic and which is exothermic?
Heat taken inHeat given out
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Energy level diagrams
Endothermic Exothermic
Heat taken in Heat given out
Energy level of products is higher than reactants so heat taken in.
Energy level of products is lower than reactants so heat given out.
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Example question
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Mark scheme
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Bond enthalpies
C7.2
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Quick quiz1. Reactions where the products are at a lower energy than
the reactants are endothermic (TRUE/FALSE)2. Activation energy is the amount of energy given out when a
reaction takes place (TRUE/FALSE)3. A reaction which is exothermic transfers heat energy to the
surroundings (TRUE/FALSE)4. How can we tell if a reaction is exothermic or endothermic?5. Sketch the energy profile for an endothermic reaction.6. When methane (CH4) burns in oxygen (O2) bonds between
which atoms need to be broken?
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Answers1. Reactions where the products are at
a lower energy than the reactants are endothermic (TRUE/FALSE)
2. Activation energy is the amount of energy given out when a reaction takes place (TRUE/FALSE)
3. A reaction which is exothermic transfers heat energy to the surroundings (TRUE/FALSE)
4. How can we tell if a reaction is exothermic or endothermic?
5. Sketch the energy profile for an endothermic reaction.
6. When methane (CH4) burns in oxygen (O2) bonds between which atoms need to be broken?
FALSE
FALSE
TRUE
Measure the temperature change
C—H bonds and O=O bonds
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What do I need to know?
1. Recall that energy is needed to break chemical bonds and energy is given out when chemical bonds form2. Identify which bonds are broken and which are made when a chemical reaction takes place.3. Use data on the energy needed to break covalent bonds to estimate the overall energy change for a reaction.
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Activation energy revisited
• What is the activation energy of a reaction?• The energy needed to start a reaction.• BUT what is that energy used for and why
does the reaction need it if energy is given out overall?
• The activation energy is used to break bonds so that the reaction can take place.
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Burning methane
Consider the example of burning methane gas.
CH4 + 2O2 CO2 + 2H2O
This reaction is highly exothermic, it is the reaction that gives us the Bunsen flame. However mixing air (oxygen) with methane is not enough. I need to add energy (a flame).
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What happens when the reaction gets the activation energy?
Bond Forming
BondBreaking
Progress of reaction
Ener
gy in
che
mic
als
OO
OO
H
CH
HH
O OOO
C H H H H
O C OO
OH H
H H
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Using bond enthalpies
By using the energy that it takes to break/make a particular bond we can work out the overall enthalpy/energy change for the reaction.
Sum (bonds broken) – Sum (bonds made) = Energy change
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BIN MIX
Breaking bonds is ENDOTHERMIC energy is TAKEN IN when bonds are broken
Making bonds is EXOTHERMIC energy is GIVEN OUT when bonds are made.
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Bond enthalpiesBond Bond enthalpy (kJ) Bond Bond enthalpy (kJ)
C—H 435 Cl—Cl 243
C—C 348 C—Cl 346
H—H 436 H—Cl 452
H—O 463 O=O 498
C=O 804
C=C 614
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Can you work out the energy change for this reaction?
CH4 + Cl2 CH3Cl + HCl
Tip: Draw the reactants and products and work out the bonds you are breaking and the ones you are making.
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The answer is -120 kJ
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Example question part 1
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Question part 2
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Question part 3
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Mark scheme
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Challenge question
• The true value for the energy change is often slightly different from the value calculated using bond enthalpies.
• Why do you think this is?
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Example question
The calculated value is 120 kJ
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Mark scheme
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Definitions
Write each of these phrases in your book with a definition in your own words:
• Exothermic reaction• Endothermic reaction• Activation energy• Catalyst• Bond energy/enthalpy
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How did you do?Exothermic reactionA reaction which gives energy out to the surroundings.Endothermic reactionA reaction which takes in energy from the surroundings.Activation energyThe energy required to start a reaction by breaking bonds in the reactantsCatalystA substance that increases the rate of a reaction by providing an alternative pathway with lower activation energy. It is not used up in the process of the reactionBond energy/enthalpyThe energy required to break a certain type of bond. The negative value is the energy given out when that bond is made.
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Popular exam question
1. Explain why a reaction is either exothermic or endothermic?
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Popular exam question
1. Explain why a reaction is either exothermic or endothermic?
① In a chemical reactions some bonds are broken and some bonds are made.
② Breaking bonds takes in energy.③ Making bonds gives out energy.④ If the energy given out making bonds is higher than the
energy needed to break them the reaction is exothermic.⑤ If the energy needed to break bonds is higher than the
energy given out making them the reaction is endothermic.
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Chemical Equilibria
C7.3 Reversible Reactions & Dynamic Equilibria
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What do I need to know?
1. State that some chemical reactions are reversible
2. Describe how reversible reactions reach a state of equilibrium
3. Explain this using dynamic equilibrium model.
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Reversible or not reversible
Until now, we were careful to say that most chemical reactions were not reversible –
They could not go back to the reactants once the products are formed.
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Example
In the case of the vast majority of chemical reactions this is true, the reaction of methane and oxygen for example:
CH4(g) + O2(g) CO2(g) + 2H2O(l)
It is almost impossible to return the carbon dioxide and water to the original methane and oxygen.
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Reversible
• Some chemical reactions, however, will go backwards and forwards depending on the conditions.
• CoCl2·6H2O(s) CoCl2(s) + 6H2O(l) pink blue
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How do we write them down?
• This is the symbol for used for reversible reactions.
CoCl2·6H2O(s) CoCl2(s) + 6H2O(l)
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What is equilibrium?
• Reversible reactions reach a balance point, where the amount of reactants and the amount of products formed remains constant.
• This is called a position of equilibrium.
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Dynamic Equilibrium.
• In dynamic equilibrium the forward and backwards reactions continue at equal rates so the concentrations of reactants and products do not change.
• On a molecular scale there is continuous change.
• On the macroscopic scale nothing appears to be happening. The system needs to be closed – isolated from the outside world.
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Example question
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Mark scheme
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Dynamic Equilibria
C7.3 Controlling equilibria
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What do I need to know?
1. Recall that reversible reactions reach a state of dynamic equilibrium.2. Describe how dynamic equilibria can be affected by adding or removing products and reactants. 3. Explain the difference between a “strong” and “weak” acid in terms of equilibria
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Position of the equilibrium
• Equilibrium can “lie” to the left or right.• This is “in favour of products” or “in favour of
reactants”• Meaning that once equilibrium has been
reached there could be more products or more reactants in the reaction vessel.
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Le Chatelier’s principle
• If you remove product as it is made then equilibrium will move to the right to counteract the change
• If you add more reactant then equilibrium will move to the right to counteract the change.
• In industry we recycle reactants back in and remove product as it is made to push the equilibrium in favour of more product.
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Complete
When a system is at__________ to make more product you can_________ product or add more __________ for example by recycling them back in.
To return to reactants you ______ product or remove_________.
[equilibrium, add, reactant, remove, product]
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Strong and weak acids
A strong acid is one which is FULLY IONISED in water. It will have a high hydrogen ion concentration
HCl H+ + Cl-
A weak acid is one which is NOT fully ionised and is in equilibrium. It has a low hydrogen ion concentration
CH3COOH CH3COO- + H+
Caution – weak and strong are not the same as concentration.
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Mark scheme
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Example question
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Mark scheme
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Practicing definitions
Write each of these phrases in your book with a definition in your own words:
• Reversible reaction• Dynamic equilibrium• Position of equilibrium• Strong acid• Weak acid
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How did you do?Reversible reactionA reaction that can proceed in the forward or reverse directions (represented by two arrows in an equation).Dynamic equilibriumThe point where the rate of the forward reaction = rate of the reverse reaction.Position of equilibriumThe point where there is no further change in the concentration of either reactants or products. The position can lie to the left (favouring reactants) or right (favouring products).Strong acidAn acid that is completely dissociated in waterWeak acidAn acid that is only partly dissociated in water because the reaction is in dynamic equilibrium and favours the reactants (LHS).
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Popular exam question
1. Ethanoic acid (CH3COOH) is a weak acid but hydrochloric acid is a strong acid. Use ideas about ion formation and dynamic equilibrium to explain this difference.
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Popular exam questionEthanoic acid (CH3COOH) is a weak acid but hydrochloric acid is a strong acid. Use ideas about ion formation and dynamic equilibrium to explain this difference.
① Hydrochloric acid ionises completely② So hydrogen ion concentration is high③ Ethanoic acid only partly dissociates because the reaction
is reversible④ Equilibrium is mainly to the left⑤ So hydrogen ion concentration is low.
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Analysis
C7.4 – Analytical Procedures
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What do I need to know?
1. Recall the difference between qualitative and quantitative methods of analysis.
2. Describe how analysis must be carried out on a sample that represents the bulk of the material under test
3. Explain why we need standard procedures for the collection, storage and preparation of samples for analysis
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Qualitative vs. Quantitative
• A qualitative test is usually very quick. It can give vital information without needing to wait too long for it.
• A quantitative test gives precise values, for example for a concentration in Moldm-3
• Examples of qualitative tests include universal indicator, silver nitrate for halide ions and bromine water for unsaturation.
• Examples of quantitative tests include titration, chromatography and spectroscopy.
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Which sample should I test?
• It is important that the sample represents the bulk of the material under test.
• You may chose to test more than one sample from a range of points to ensure that you have results which represent the whole.
• For example is it well mixed? Are their pockets of higher concentration/different composition?
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Chemical industry
• Analysis of samples is crucial to the chemical industry to ensure the quality of the chemicals they are manufacturing. Some are analysed numerous times a day or even within an hour.
• To maintain consistency it is essential that we use standard procedures to:o collect the sampleo store the sampleo prepare the sample for analysiso analyse the sample.
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Chromatography
C7.4 – paper chromatography
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Chromatography
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Solvents
1. The mobile phase is the solvent – the part that moves
2. In paper chromatography it is water or ethanol
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Paper/column
1. The stationary phase is the paper in paper chromatography or the column in gas chromatography.
2. In thin layer chromatography it is silica gel on a glass plate
3. The stationary phase does not move.
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How does the technique work?
In chromatography, substances are separated by movement of a mobile phase through a stationary phase.
Each component in a mixture will prefer either the mobile phase OR the stationary phase.
The component will be in dynamic equilibrium between the stationary phase and the mobile phase.
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Substance A
• This is substance A
• Substance A prefers the stationary phase and doesn’t move far up the paper/column.
• The equilibrium lies in favour of the stationary phase.
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Substance B
• This is substance B
• Substance B prefers the mobile phase and moves a long way up the paper/column
• The equilibrium lies in favour of the mobile phase
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Using a reference
• In chromatography we can sometimes use a known substance to measure other substances against.
• This will travel a known distance compared to the solvent and is known as a standard reference.
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Advantages of TLC
TLC has a number of advantages over paper chromatography.
It is a more uniform surface chromotograms are neater and easier to interpret
Solvent can be used which is useful if a substance is insoluble in water.
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Past Paper Questions
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Past paper question
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Mark scheme
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Describing how chromatography works – exam definition
• stationary phase is paper and mobile phase is solvent / mobile phase moves up through stationary phase (1)
• for each compound there is a dynamic equilibrium between the two phases (1)
• how far each compound moves depends on its distribution between the two phases (1)
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Using an Rf value
• In order to be more precise we can use measurements on the TLC plate to compare the distance travelled by our substance (the solute) with the distance travelled by the solvent.
• The Rf value is constant for a particular compound.
• The distance travelled however could be different on different chromatograms.
• The Rf value is always less than 1.
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Rf value
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Example questionThis question relates to the chromatogram shown in the earlier question. Refer back…
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Mark scheme
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Example question
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Past paper question
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Mark scheme
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Gas-liquid chromatography
C7.4 GLC
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What do I need to know?
1. recall in outline the procedure for separating a mixture by gas chromatography (gc);
2. understand the term retention time as applied to gc;
3. interpret print-outs from gc analyses.
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Gas chromatography
• The mobile phase is an unreactive gas known as the carrier gas this is usually nitrogen
• The stationary phase is held inside a long column and is lots of pieces of inert solid coated in high bp liquid.
• The column is coiled in an oven
• The sample to be analysed is injected into the carrier gas stream at the start of the column.
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GC
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GC analysis• Each component of the sample mixture has a different
affinity for the stationary phase compared with the mobile phase
• Therefore each component travels through the column in a different time.
• Compounds favouring the mobile phase (usually more volatile) emerge first.
• A detector monitors the compounds coming out of the column and a recorder plots the signal as a chromatogram
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GLC Chromatograph
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Interpretation
• The time in the column is called the retention time
• Retention times are characteristic so can identify a compound
• Area under peak or relative heights can be used to work out relative amounts of substances
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The key points – revise this!
• the mobile phase carries the sample (1) • components are differently attracted to the
stationary and mobile phases (1) • the components that are more strongly attracted
to the stationary phase move more slowly (1) • the amount of each component in the stationary
phase and in the mobile phase is determined by a dynamic equilibrium (1)
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Past paper question
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Mark scheme
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Titration
C7.4
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What do I need to know?
1. Calculate the concentration of a given volume of solution given the mass of solvent;
2. Calculate the mass of solute in a given volume of solution with a specified concentration;
3. Use the balanced equation and relative formula-masses to interpret the results of a titration;
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Concentration• We can measure the concentration of solution in grams/litre. This
is the same as g/dm3
• 1dm3 = 1000cm3
• If I want to make a solution of 17 g/dm3 how much will I dissolve in 1dm3.
• 17 g
• If I want to make a solution of 17g/dm3 but I only want to make 100cm3 of it how much will I dissolve?
• 1.7g
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Making standard solutions
• For a solution of 17g/dm3
• First I will measure 17g of solid on an electronic balance
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Making standard solutions
• Now I must dissolve it in a known 1dm3 of water.
• I transfer it to a volumetric flask and fill up with distilled water to about half the flask.
• I then swirl to dissolve• Top up with a dropping pipette so that
the meniscus is on the line.
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How much to dissolve?
• Worked example:
• I want to make 250cm3 of a solution of 100g/dm3.
• How much solid do I transfer to my 250cm3 volumetric flask?
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How much to dissolve?
Worked example:I want to make 250cm3 of a solution of 100g/dm3.
1. Work out the ratio of 250cm3 to 1000cm3
250/1000 = 0.25
2. I therefore need 0.25 of 100g in 250cm3 which is 0.25x100=25g
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General rule
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Practie - how much to dissolve?
• I want to make 250cm3 of a solution of 63.5g/dm3.
• How much solid do I transfer to my 250cm3 volumetric flask?
• 250/1000 x 63.5 = 15.9 g
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Practice - how much to dissolve?
• I want to make 100cm3 of a solution of 63.5g/dm3.
• How much solid do I transfer to my 100cm3 volumetric flask?
• 100/1000 x 63.5 = 6.35 g
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Concentration from mass and volume
We need to rearrange this:
To give
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What is the concentration of?
1. 12g dissolved in 50cm3
2. 50g dissolved in 100cm3
3. 47g dissolved in 1000cm3
4. 200g dissolved in 250cm3
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What is the concentration of?
1. 12g dissolved in 50cm3
= 1000/50 x 12= 240g/dm3
2. 50g dissolved in 100cm3
=1000/100 x 50 = 500g/dm3
3. 47g dissolved in 1000cm3
= 1000/1000 x 47= 47g/dm3
4. 200g dissolved in 250cm3
1000/250 x 200= 800g/dm3
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Solutions from stock solutions
Stock solution•highest concentration
•use to make other solutions
Extract a portion of stock solution•as calculated
Dilute with distilled water•Making a known volume of a lower concentration
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Making solutions from stock solutions
If I have a solution containing 63g/dm3, how do I make up 250cm3 of a solution of concentration 6.3g/dm3?
To make 1dm3 of 6.3g/dm3 I would need 100cm3
To make 250cm3 of 6.3g/dm3 I would therefore need 25cm3 and make it up to 250cm3 with distilled water
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Working out masses
• We can use the useful relationship
• Where Mr is the molecular mass• eg Mr of NaOH is (23 + 16 + 1) = 40• This can help us to calculate an unknown mass
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Titration calculations
• In a titration we have added a known amount of one substance usually an acid (in the burette) to a known amount of another substance usually an alkali (in the conical flask).
• The amount added allows us to determine the concentration of the unknown.
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Titration equipment
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Using a table
• It can be helpful to sketch a table to keep track of information you know…
Value Acid Alkali
Volume (cm3)
Mass (g)
Concentration (g/dm3)
Molecular weight (Mr)
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Mark scheme
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Uncertainty
• Uncertainty is a quantification of the doubt about the measurement result.
• In a titration the uncertainty is the range of the results.
• If results are reliable then it will be within 0.2cm3
• NOTE THAT THIS IS RELIABLE NOT NECESSARILY ACCURATE
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C7.5 Green Chemistry
The Chemical Industry
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What do I need to know?
1. Recall and use the terms 'bulk' (made on a large scale) and 'fine' (made on a small scale) in terms of the chemical industry with examples;
2. Describe how new chemical products or processes are the result of an extensive programme of research and development;
3. Explain the need for strict regulations that control chemical processes, storage and transport.
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Bulk processes
• A bulk process manufactures large quantities of relatively simple chemicals often used as feedstocks (ingredients) for other processes.
• Examples include ammonia, sulfuric acid, sodium hydroxide and phosphoric acid.
• 40 million tonnes of H2SO4 are made in the US every year.
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Fine processes
• Fine processes manufacture smaller quantities of much more complex chemicals including pharmaceuticals, dyes and agrochemicals.
• Examples include drugs, food additives and fragrances
• 35 thousand tonnes of paracetamol are made in the US every year.
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Example question
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Research and Development
• All chemicals are produced following an extensive period of research and development.
• Chemicals made in the laboratory need to be “scaled up” to be manufactured on the plant.
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Research in the lab
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Examples of making a process viable
• Trying to find suitable conditions – compromise between rate and equilibrium
• Trying to find a suitable catalyst – increases rate and cost effective as not used up in the process.
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Catalysts
• Can you give a definition of a catalyst?• A substance which speeds up the rate of a
chemical reaction by providing an alternative reaction pathway.
• The catalyst is not used up in the process• Catalysts can control the substance formed eg
Ziegler Natta catalysts.
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Regulation of the chemical industry
• Governments have strict regulations to control chemical processes
• Storage and transport of chemicals requires licenses and strict protocol.
• Why?
• To protect people and the environment.
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Example question
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Process development
preparation of
feedstockssynthesis
separation of
products
handling of by-
products and wastes
monitoring of purity
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Example question – part 1
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Example question part - 2
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Example question – part 3
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Factors affecting the sustainability of a process
Sustainability
renewable feedstock
atom economy
type of waste and disposal
energy inputs and outputsenvironmental
impacthealth and safety risks
social and economic benefits
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Example question
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Atom economy
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Atom economy calculationFor example, what is the atom economy for making hydrogen by reacting coal with steam?
Write the balanced equation:
C(s) + 2H2O(g) → CO2(g) + 2H2(g)
Write out the Mr values underneath:
C(s) + 2H2O(g) → CO2(g) + 2H2(g)
12 2 × 18 44 2 × 2
Total mass of reactants 12 + 36 = 48gMass of desired product (H2) = 4g
% atom economy = 4⁄48 × 100 = 8.3%
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Exam
ple
ques
tion
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Example question – part 2
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Mark scheme