Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit … · 2020. 4. 8. · Note 4: See...
Transcript of Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit … · 2020. 4. 8. · Note 4: See...
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Report Title Air Emissions Compliance Monitoring Emissions Report
Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,
Park, Ennis Road, Limerick V94 NT63.
Stack Emissions Testing Report Commissioned by Environmental Efficiency
Facility Name Barclay Chemicals Manufacturing Limited
Contact Person Tiernan Keane
EPA Licence Number P0522-01
Licence Holder Barclay Chemicals Manufacturing Limited
Stack Reference Number A3-6
Dates of the Monitoring Campaign 05-09-2019
Job Reference Number BACHTL7050919
Report Written By Mr. Gregory Dempsey
Report Approved by Mark McGarry
Stack Testing Team Mr. Gregory Dempsey
Report Date 18-10-2019
Report Type Test Report Compliance Monitoring
Version 1
Signature of Approver Operations Manager
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Contents
1.0 Executive Summary ................................................................................................................................................................................ 3 1.1 Overall aim of the monitoring campaign ................................................................................................................................................ 3 1.2 Summary of substances to be monitored at each emission point .......................................................................................................... 3 1.3 Special Requirements ............................................................................................................................................................................. 3 1.4 Summary of Results ................................................................................................................................................................................ 4 Emission Point Number: A3-6 ...................................................................................................................................................................... 4 1.5 Operating Information ........................................................................................................................................................................... 5 1.6 Monitoring Deviations ............................................................................................................................................................................ 5 1.7 Reference Documents ............................................................................................................................................................................ 5 1.8 Revision History ...................................................................................................................................................................................... 5 Part 2: Supporting Information ........................................................................................................................................................................ 6 Appendix I ......................................................................................................................................................................................................... 7 1.1 Monitoring Personnel ............................................................................................................................................................................. 7 1.2 Equipment Inventory .............................................................................................................................................................................. 8 Appendix II ........................................................................................................................................................................................................ 9 2.1 Stack Emission Point Reference: A3-6 .................................................................................................................................................... 9 2.1.1 Suitability of Sample Location: .......................................................................................................................................................... 9 2.1.2 Stack Diagram ................................................................................................................................................................................. 10 2.1.3 Stack Raw Data ............................................................................................................................................................................... 11 Appendix III: Certificates and Process Detail Form ........................................................................................................................................ 20
Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited INAB accreditation. This test report shall not be reproduced, without the written approval of Air Scientific Limited.
All sampling and reporting is completed in accordance with Environmental Protection Agency Air Guidance Note 2 requirements.
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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1.0 Executive Summary
1.1 Overall aim of the monitoring campaign
The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values as specified
in the site licence.
1.2 Summary of substances to be monitored at each emission point
Stack Name: A3-6
Individual Gaseous Organic Compounds
Volumetric Flow Rate (Ref)
1.3 Special Requirements
There were no special requirements
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1.4 Summary of Results
Emission Point Number: A3-6
Parameter Method Units Result MU +/- Limit O2 Ref.
(%)
Moisture
Ref. (%) Compliant Blanks Date Time on Time off
Accreditation
Sampling Analysis
Speciated Organics Class I EN 13649 mg.m-3 >2.0 - <2.6 0.08 – 0.1 20 Note 3 N/a N/a N/a 0.44 05/09/2019 11:10 11:40 Yes Yes Note 4
Speciated Organics Class I EN 13649 kg.hr-1 >0.00028 - <
0.00037 0.00011 – 0.00014
0.1 N/a N/a Yes 0.0003 05/09/2019 11:10 11:40 Yes Yes Note 4
Volumetric Flow Rate (Ref) EN 16911 m3.h-1 140 53 N/a N/a N/a Yes N/a 05/09/2019 11:20 11:30 Yes N/a
Note 1: All results are normalised to standard temperature and pressure (0OC and 101.3kPa)
Note 2: All results are reported in the format as defined by the EPA in guidance note AG2:2018.
Note 3: Limit applied if mass threshold exceeded;
Note 4: See certificate of analysis for accredited parameters.
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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1.5 Operating Information
Please reference Process Details as per Appendix III attached.
1.6 Monitoring Deviations
Stack Name: A3-6
Parameter Deviation
Individual Gaseous Organic Compounds None
Volumetric Flow Rate (Ref) EN 16911 - in accordance with MID 16911-1
1.7 Reference Documents
Risk Assessment (RA) SOP 1011
Site Review (SR) SOP 1015
Site Specific Protocol (SSP) SOP 1015
1.8 Revision History
Revision Number Changes to the report
1 Original version of the report
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Part 2: Supporting Information
Report Title Air Emissions Compliance Monitoring Emissions Report
Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,
Park, Ennis Road, Limerick V94 NT63.
Stack Emissions Testing Report Commissioned by Environmental Efficiency
Facility Name Barclay Chemicals Manufacturing Limited
Contact Person Tiernan Keane
EPA Licence Number P0522-01
Licence Holder Barclay Chemicals Manufacturing Limited
Stack Reference Number A3-6
Dates of the Monitoring Campaign 05-09-2019
Job Reference Number BACHTL7050919
Report Written By Mr. Gregory Dempsey
Report Approved by Mark McGarry
Stack Testing Team Mr. Gregory Dempsey
Report Date 18-10-2019
Report Type Test Report Compliance Monitoring
Version 1
Signature of Approver Operations Manager
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Appendix I
1.1 Monitoring Personnel
Team Leader Name Gregory Dempsey
System approval ASL Team Leader Approved
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1.2 Equipment Inventory
ID Item of Equipment Used ID Item of Equipment Used ID Item of Equipment Used
ASLLK12EQ500 Pump ASLLK12EQ525 Horiba (PG-250) X ASLLK13EQ501 Vernier Calipers
ASLLK12EQ532 Pump ASLLK14EQ501 Horiba-PG 350 ASLLK14EQ503 Vernier Calipers
ASLLK12EQ533 Pump ASLLK14EQ512 Horiba PG250Y ASLLK14EQ507 Vernier Calipers
ASLLK12EQ534 Pump ASLLK16EQ508 Horiba- PG250z ASLLK17EQ533 Vernier Calipers
ASLLK12EQ535 Pump ASLLK17EQ515 Horiba 350 ASLLK18EQ506 Vernier Calipers
ASLLK12EQ536 Pump
ASLLK12EQ537 Pump
ASLLK12EQ538 Pump ASLLK12EQ526 Chiller ASLLK13EQ503 1kg weight
ASLLK12EQ540 Pump ASLLK14EQ513 Chiller ASLLK13EQ508 500g Hafner weight
ASLLK12EQ541 Pump ASLLK16EQ509 Chiller ASLLK13EQ509 500g Hafner weight
ASLLK12EQ542 Pump ASLLK18EQ505 Chiller ASLLK14EQ515 500g Weight
ASLLK12EQ543 Pump ASLLK15EQ511 1kg Weight
ASLLK13EQ513 Pump ASLLK15EQ512 1kg weight
ASLLK13EQ514 Pump ASLLK16EQ501 Velocity Meter ASLLK16EQ511 1kg weight
ASLLK16EQ518 Pump ASLLK17EQ508 Velocity Meter ASLLK16EQ512 500g weight
ASLLK16EQ519 Pump ASLLK17EQ514 Velocity Meter ASLLK17EQ529 500g weight
ASLLK17EQ509 Pump ASLLK18EQ504 Velocity Meter ASLLK17EQ530 1kg weight
ASLLK17EQ510 Pump ASLLK19EQ502 Velocity Meter
ASLLK17EQ522 Pump ASLLK13EQ504 G4
ASLLK17EQ523 Pump ASLLK13EQ515 G4
ASLLK17EQ524 Pump ASLLK14EQ500 FID ASLLK15EQ501 G4
ASLLK17EQ525 Pump ASLLK16EQ502 FID ASLLK17EQ534 ST5
ASLLK17EQ526 Pump ASLLK17EQ517 FID ASLLK18EQ503 ST5
ASLLK18EQ517 Pump ASLLK19EQ508 FID ASLLK18EQ513 ST5
ASLLK18EQ518 Pump ASLLK17EQ535 Signal Cutter ASLLK19EQ509 ST5
ASLLK13EQ512 PCDD thermometer ASLLK14EQ510 Digital Protractor
ASLLK15EQ506 MF Meter ASLLK14EQ511 Digital Protractor
ASLLK17EQ501 MF Meter ASLLK16EQ510 Measuring Tape ASLLK15EQ505 Digital Protractor
ASLLK17EQ542 MF Meter ASLLK16EQ513 Measuring Tape ASLLK16EQ507 Digital Protractor
ASLLK18EQ511 MF Meter ASLLK16EQ514 Measuring Tape ASLLK17EQ528 Digital Protractor
ASLLK18EQ512 MF Meter ASLLK17EQ527 Measuring Tape ASLLK18EQ507 Digital Protractor
ASLLK19EQ500 MF Meter ASLLK18EQ508 Measuring Tape
ASLLK19EQ501 MF Meter
ASLLK12EQ522 Balance
ASLLK12EQ527 Heated Line ASLLK16EQ515 Thermocouple K type ASLLK12EQ544 Balance
ASLLK14EQ509 Heated Line ASLLK16EQ516 Thermocouple K type ASLLK15EQ509 Balance
ASLLK14EQ514 Heated Line ASLLK18EQ510 K type Thermocouple ASLLK15EQ510 Balance
ASLLK17EQ502 Heated Line ASLLK19EQ503 K type Thermocouple ASLLK17EQ537 Balance
ASLLK17EQ503 Heated Line ASLLK19EQ504 K type Thermocouple ASLLK17EQ538 Balance
ASLLK17EQ539 Heated Line ASLLK19EQ505 K type Thermocouple
ASLLK18EQ516 Heated Line
ASLLK17EQ519 Stopwatch
ASLLK12EQ518 S type Pitot Tube ASLLK17EQ520 Stopwatch
ASLLK12EQ520 L Type Pitot tube ASLLK17EQ521 Stopwatch
ASLLK13EQ506 S type Pitot Tube ASLLK18EQ509 Stopwatch
ASLLK14EQ506 Pitot + thermocouple
ASLLK16EQ506 S type Pitot Tube
ASLLK16EQ517 S type Pitot Tube Long
ASLLK17EQ507 1 m S type & K type
ASLLK17EQ536 S type Pitot Tube
ASLLK18EQ514 S type Pitot Tube
ASLLK18EQ515 S type Pitot Tube
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Appendix II
2.1 Stack Emission Point Reference: A3-6
2.1.1 Suitability of Sample Location:
General Information
Permanent/Temporary Permanent
Inside/ Outside Outside
Platform Details
Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements
Value Comment
Sufficient Working area to manipulate probe and measuring instruments
Yes -
Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -
Platform has vertical base boards (approx. 0.25 m high) No -
Platform has chains / self-closing gates at top of ladders No -
There are no obstructions present which hamper insertion of sampling equipment
Yes -
Safe Access Available Yes -
Easy Access Available Yes -
Sampling Location / Platform Improvement Recommendations
None
EN 15259 Homogeneity Test Requirements
1.
Select Option: 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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2.1.2 Stack Diagram
c.10m
Ports 1
c.2metres
Ground Level
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2.1.3 Stack Raw Data
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Title: Determination of Speciated Organic Compounds
Method: EN 13649
Client: Barclay
Test Date: 05/09/2019
Test Time: 11:10
Laboratory Used: CLS
Stack Reference: A3-6
Leak Check Results VOCs
Prior to test: 0 l/min
Post Test: 0 l/min
Sample Volume Flow Rate: 0.35 l/min
Standard Requirement: <5 %
Test Result: 0 %
Test Status Pass
Calibration Details VOCs
Pump Number: ASLLK12EQ536
Calibration Unit: ASLLK17EQ501
Calibration Unit Uncertainty: <2 %
Calibration Rate Before Test: 0.35 Nl/min
Calibration Rate After Test: 0.35 Nl/min
Maximum allowed flow 0.5 Nl/min
Average sample Volume: 0.35 Nl/min
Sample Test Time: 30 minutes
Pump Gas Temperature: 12 OC
Pump Sample Pressure: 101.2 kPa
Normalised Gas Volume: 0.01050 Nm3
Tube Details VOCs
Tube Type: 226-09
Tube Identification Number: 7899201682
Blank Identification Number: 7899201673
Main Adsorbent Layer 400 mg
Backup Adsorbent Layer 200 mg
Containment Material Glass
Breakthrough Occurred No
Tubes in Lab in <7 days Yes
Tubes >7 days were stored <4 Deg C
Tubes >7 days were stored Dark -
Transport Container Airtight Yes
Exposed to Sunlight No
Transport Temp <20 Deg C Yes
Field Blank <10% Analyte Value Yes
Field Blank <10% ELV Yes
Test Details
Adsorption Tube Temperature: 12 OC
Stack Flow Rates Uncertainty
Normalised Flow Rate: 140 m3.hr-1 38 %
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Speciated Organic Results
Class I ug/tube mg.Nm-3 kg.hr-1
Benzene 1 0.10 0.0000
Carbon Tetrachloride 14 1.33 0.0002
Chloroform 3 0.29 0.0000
Dichloromethane 4 0.38 0.0001
Tetrachloroethylene 3 0.29 0.0000
Trichloroethylene 3 0.29 0.0000
Concentration Uncertainty ELV
mg.Nm-3 mg.Nm-3 mg.Nm-3
Total Class I 2.67 0.10 20
Mass Emission Uncertainty Threshold
kg.Hr-1 kg.Hr-1 kg.Hr-1
Total Class I 0.0004 0.00014 0.1
Speciated Organic Results - Detected
Class I ug/tube mg.Nm-3 kg.hr-1
Benzene - - -
Carbon Tetrachloride 14 1.33 0.0002
Chloroform - - -
Dichloromethane 4 0.38 0.0001
Tetrachloroethylene 3 0.29 0.0000
Trichloroethylene - - -
Concentration Uncertainty ELV
mg.Nm-3 mg.Nm-3 mg.Nm-3
Total Class I 2.00 0.08 20
Mass Emission Uncertainty Threshold
kg.Hr-1 kg.Hr-1 kg.Hr-1
Total Class I 0.0003 0.00011 0.1
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Speciated Organic Results - Blanks
Class I ug/tube mg.Nm-3 kg.hr-1
Benzene 1 0.10 0.0000
Carbon Tetrachloride 14 1.33 0.0002
Chloroform 3 0.29 0.0000
Dichloromethane 4 0.38 0.0001
Tetrachloroethylene 3 0.29 0.0000
Trichloroethylene 3 0.29 0.0000
Concentration Uncertainty ELV
mg.Nm-3 mg.Nm-3 mg.Nm-3
Total Class I 0.44 0.02 20
Mass Emission Uncertainty Threshold
kg.Hr-1 kg.Hr-1 kg.Hr-1
Total Class I 0.0004 0.00014 -
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Uncertainty calculation A3-6 TA Luft Class 1
Measurement Equation
Limit value (ELV) 20 mg.m-3
Reference oxygen % by volume
Measured concentration 2.67 mg.m-3
(at reference conditions)
Measured Quantities Symbol Value Standard uncertainty Units Uncertainty as percentage Uncertainty at lv Requirement of std
Sampled Volume Gas Vm 0.0105 uVm 0.0001 m3
0.95 <=2%
Sampled gas Temperature Tm 285 uTm 2 k 2.00 <2.5 k
Sampled gas Pressure ρm 101.2 uρm 1 kPa 0.99 <=1%
Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%
Oxygen content O2,m uO2,m 0.1 % by volume #DIV/0! <=5%
Note - Sampled gas humidity, temperature and pressure are values at the gas meter
Leak L 0.5 % 0.50 <=2%
Intermediate calculations
Factor for std conds fs 0.96
uncertainty components symbol sensitivity coeff u (in units of fs)
ρm 0.009 0.009
Hm 0.010 0.010
Tm 0.003 0.007
ufs 0.015 1.57
Corrected volume V 0.01 uV 0.000 m3
1.86
Factor for O2 correction fc 1.00
uncertainty components symbol sensitivity coeff u
O2,m 0.05 0.005
Factor for O2 Correction ufc 1.00 0.005 0.48
Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %
Corrected Volume (standard conditions) V 0.01 m3
265.39 0.05 mg.m-3
1.86 %
Factor for O2 Correction fc 1.00 2.67 0.01 mg.m-3
0.48 %
Leak L 0.01 mg.m-3
1.00 0.01 mg.m-3
0.29 %
Combined uncertainty 0.05 mg.m-3
Expanded uncertainty as percentage of measured value 3.88 % measured of value expressed with a level of confidence of 95%
(Using a coverage factor k=2)
Expanded uncertainty in units of measurement 0.1035 mg.m-3
Expanded uncertainty as percentqge of limit value 0.52 % ELV
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Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Title: Determination of Stack Flow Rate
Method: EN 16911
Client: Barclay Chemicals
Stack Reference: A3-6
Stack details Value Units
Date of survey 05/09/2019
Time of survey 11:20
Type (Circular or Rectangular) Circular
Stack Diameter / Depth, D 0.15 Length (m) m
Stack Width, W m
Average Stack Gas Temp., Ta 15.8 288.95 C
Average Static Pressure, P static 0.02 kPa
Average Barometric Pressure, Pb 101.2 kPa
Type of Pitot (S or L) S
Are Water Droplets Present ? No
Average Pitot Tube Calibration Coeff, Cp 0.81
No local negative flow Yes
Highly homogeneous flow stream/gas velocity Yes
Sample Port Size 25.4 mm
Initial Pitot Leak Check Pass Pa
Final Pitot Leak Check Pass Pa
Stagnation Check Pass Pa
Orientation of Duct
Pitot Tube Cp 0.998
Number of Lines Available 1
Number of Lines Used 1
Sampling Line A
Point Distance Pa Temp C Velocity Oxygen Swirl
1 0.05 5.1 15.8 2.3 20.9 2
2 0.1 5 15.8 2.3 29,9 1
3 - - - - - -
4 - - - - - -
5 - - - - - -
6 - - - - - -
7 - - - - - -
8 - - - - - -
9 - - - - - -
10 - - - - - -
Average 5.05 15.8 2.3 20.9 2
Min 5 15.8 2.3
Max 5.1 15.8 2.3
Sampling Line B
Point Distance Pa Temp C Velocity Oxygen Swirl
1 - - - - - -
2 - - - - - -
3 - - - - - -
4 - - - - - -
5 - - - - - -
6 - - - - - -
7 - - - - - -
8 - - - - - -
9 - - - - - -
10 - - - - - -
Average 0 0.0 0.0 0 0
Min 0 0 0.0
Max 0 0 0.0
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Average stack Gas Velocity 2.33 m/s
Lowest Differential Pressure 5.00 Pa
Lowest Gas Velocity 2.32 m/s
Highest Gas Velocity 2.34 m/s
Average Differential Pressure 5.05 Pa
Velocity Ratio of High to Low (3:1) 1.01
Average Angle of flow 1
Component Conc ppm
Conc Dry % v/v
Conc Wet % v/v
Molar Mass
Carbon Dioxide CO2 - 0.1 44.01
Oxygen O2 - 20.9 32
Nitrogen N2 - 79 28.1
Moisture (H2O) - - 0 18.02
Reference Conditions Units Numbers
Temperature K 273.13
Total Pressure kPa 101.3
Moisture % -
Oxygen (Dry) % -
General Stack Details
Stack details Units Value
Stack Diameter / Depth, D m 0.15
Stack Width, W m 0
Stack Area, A m2 0.02
Average Stack Gas Temp., Ta C 15.8 288.95 K
Average Static Pressure, P static kPa 0.02
Average Barometric Pressure, Pb kPa 101.2
Average Pitot Tube Calibration Coeff, Kpt 0.81
Calc box Area
Circular Duct Rectangular Duct
R = 0.075 Length (m) 0
R2 = 0.005625 Width (m) 0
Area = Pie*R2 0.02 Area 0
Stack Gas Composition & Molecular Weights
Component Molar Mass
M Density Kg/m3 p
Conc Dry % v/v
Dry Volume Fraction r
Carbon Dioxide CO2 44.01 1.96 0.1 0.001
Oxygen O2 32 1.43 20.9 0.209
Nitrogen N2 28.1 1.25 79 0.79
Moisture (H2O) 18.02 0.80
where p=M/22.41
pi = r x p
Dry Conc kg/m3 pi
Conc wet % v/v
Wet Volume Fraction r
Wet Conc kg/m3 pi
Carbon Dioxide CO2 0.00 0.10 0.00 0.00
Oxygen O2 0.30 20.90 0.21 0.30
Nitrogen N2 0.99 79.00 0.79 0.99
Moisture (H2O) - 0 0.00 0.00
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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Calculation of Stack Gas Densities
Determinant Units Result
Dry Density (STP), P STD kg/m3 1.291
Wet Density (STP), P STW kg/m3 1.291
Dry Density (Actual), P Actual kg/m3 1.219
Average wet Density (Actual), P Actual kg/m3 1.219
Where
P STD = sum of component concentrations, kg/m3 (excluding water vapour)
P STW = (P STD + pi of H2O) / ( 1 + (pi of H2O / 0.8036))
P actual = P STD x (T STP / (P STP)) x (Pa / Ta)
P actual W (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)
Calculation of Stack Gas Volumetric Flow rate, Q
Duct gas flow conditions Units Actual REF
Temperature K 288.95 273.13
Total Pressure kPa 101.2 101.3
Moisture % 0 -
Oxygen (Dry) % 20.9 -
Gas Volumetric Flow rate Units Result
Gas Volumetric Flow Rate (Actual) m3/hr 148
Gas Volumetric Flow Rate (STP, Wet) m3/hr 140 Uncertainty
Gas Volumetric Flow rate (STP, Dry) m3/hr 140 53 m3/hr
Gas Volumetric Flow rate REF to Oxygen m3/hr - 38.0 %
Where
Actual = Va * A * 3600
STP Wet =Actual x (Ts / Ta) x (Pa / Ps)
STP , Dry = STP Wet / (100 - Water Vapour % ) / (100- Water Vapour Ref))
REF = STP Wet x (100 - Water Vapour % ) / (100- Water Vapour Ref)) x (20.9 - O2m)/ (20.9 -O2 Ref)
Sampling Plane Validation Criteria Value Units Requirement Compliance Method
Lowest Differential Pressure 5.00 Pa >5 Pa Pass EN 16911
Lowest Gas Velocity 2.32 m/s - - -
Highest Gas Velocity 2.34 m/s - - -
Ratio of Above 1.01 :1 <3:1 Pass EN 16911
Mean Velocity 2.33 m/s - - -
Angle of flow 0.75 degrees < 15 Pass EN 16911
No local negative flow Yes - - - -
Homogeneous flow Yes - - - -
Calculation of stack Gas Velocity, V
Velocity at Traverse Point, V = Kcp * Sqroot ((2 * DP ) / Density) 8.284796816
Where
Kpt = Pitot tube calibration coefficient 0.81
Compressibility correction factor, assumed at a constant 0.998 0.998
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
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V1.4 Oct-16
Enter data in orange cells only <---- Complete (Don’t Touch)
ConstantsGas constant 8.314 J/(K.mol)
3735 Pa
1 Pa
0.03 % of value
0.1 % of range between calibrations
0.17 % of range
0.9 Pa
Water vapour measurement 2 % relative
Pitot coefficient, K 0.81 1 °C CO content measurement 2 % relativeExpanded uncertainty (95%, k=2) 0.03 100 Pa CO2 content measurement 2 % relative
1.0 % O2 content measurement 2 % relative
Duct dimensions Circular RectangularDiameter 0.15 m a 0.0 m
Area 0.0 m2 b 0.0 m
Area 0.0 m2
All Pressures should be entered in Pascals, PaMeasurement Point Atmospheric Pressure, Pa Stack Pressure, Pa Static Pressure, Pa meas1, Pa Delta P, PaStack Temperature, CWater Vapour Content, %CO, ppm CO2, % N2, % O2, %
1 101200 101220 20 5.05 5.05 15.8 0 0 0.1 79.0 20.9
Mean 101200 101220 20.0 5.1 5.1 15.8 0.0 0.0 0.1 79.0 20.9
Mean density 1.216 kg/m3
Mean velocity 2.33 m/sec
Standard uncertainty of velocity 0.44 m/sec 19.0 % of value
Expanded uncertainty in velocity 0.89 m/sec 38.0 % of value
Circular duct Rectangular duct
Flow rate 140 m3/hour 140 m3/hour
Volume flow rate expanded uncertainty 53 m3/hour #DIV/0! m3/hour
Volume flow rate expanded uncertainty 38.0 % of value #DIV/0! % of value
28.85
dry molecular wt, g/mol
28.85
28.85
stack molecular wt, g/mol
28.85
Uncertainty in duct area measurement
Dry gas basis
Uncertainty in stack gas compositionUncertainty in Delta P transducer Enter uncertainties as (95%,k=2) where relevant
Uncertainty in temperature readout system
Uncertainty in atmospheric pressure transducer
Enter uncertainties as (95%,k=2) where relevant
Repeatability of Delta P transducer
Drift of Delta P transducer
Lack of fit of measurement system
Uncertainty calculation for Velocity and Volume Flow Rate Measurement by Pitot tube EN ISO 16911-1
Characteristics of pressure sensor used for Delta PEnter uncertainties as (95%,k=2) where relevant
Range of Delta P transducer
Resolution of Delta P transducer
Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1
20 of 20
Appendix III: Certificates and Process Detail Form
Test Certificate Date 20/09/2019
AIR SCIENTIFIC (LK)**NEW**
Unit 5 Caherdavin Business Centre
Caherdavin
Ennis Road
Limerick
V94 NT63
Client Order No. BACHTL7050919
WK19-7067Certificate No.
Issue No. 1
Contact 12/09/2019Date ReceivedGregory Dempsey
Description 2 Tubes for VOCs Technique GC-FID
Sample No. 1068078 A3-6 VOC Method
O8(U)<1 µgBenzene
G8(N)14 ugCarbon tetrachloride
G8(N)<3 µgChloroform
O8(U)4 µgDichloromethane
O8(U)3 µgTetrachloroethylene
O8(U)<3 µgTrichloroethylene
Sample No. 1068079 Blank VOC Method
O8(U)<1 µgBenzene
G8(N)<3 ugCarbon tetrachloride
G8(N)<3 µgChloroform
O8(U)<3 µgDichloromethane
O8(U)<2 µgTetrachloroethylene
O8(U)<3 µgTrichloroethylene
RPS Environmental Management Ltd trading as RPS laboratories. Unit 12. Waters Edge Business Park. Modwen
Road. Salford. M5 3EZ
Page 1 of 2
Date 20/09/2019Test Certificate
WK19-7067Certificate No.
1Issue No.
Client AIR SCIENTIFIC (LK)**NEW**
Approved By Date
Jun Huan ZhaoTested By 13/09/2019Date
Joanne Dewhurst
Operational
For and on authority of RPS Laboratories Ltd.
Method Symbols (U) Analysis is UKAS Accredited
(N) Analysis is not UKAS Accredited
Concentration values (mg/m3 and ppm) are not covered by the scope of UKAS accreditation.
Results stated as ml are refering to the sample volume.
Analysis carried out on samples 'as received'
This document may not be reproduced other than in full, except with the written approval of the issuing laboratory.
RPS Laboratories terms and conditions apply - a copy is available on request.
Tammy Illingworth 19/09/2019
20/09/2019
RPS Environmental Management Ltd trading as RPS laboratories. Unit 12. Waters Edge Business Park. Modwen
Road. Salford. M5 3EZ
Page 2 of 2
Process Details Form
Process Details Form
Licensee Barclay Chemicals Contractor Air Scientific
Reg. Number P0522-01
Site Contact Elizabeth Monaghan Contractor’s Contact Mark McGarry
Role EHS Team Lead Role Operation manager
Signature Signature
Emission Point as per License
N/A N/A A3-6
Type of process
O Rotogravure printing O Rotogravure printing O Rotogravure printing
O Cement plant O Cement plant O Cement plant
O Electrical generation O Electrical generation O Electrical generation
O Steam boiler O Steam boiler O Steam boiler
O Other: O Other: x Other: process scrubber
Load of Process (Rotogravure printing: the solvent type and content of the ink, the ink delivery rate, the press temperature, the status of abatement plant, printing rate (m/s), etc.; Cement plant: Clinker source and loading rate, fuel source and load rate; Power plant: Electrical generation (MW) and fuel; Cement, chemical or pharmaceutical plants: Rate of material processed (tons/ hour); General manufacturing processes: Rate of items processed per hour; Steam boilers: Percentage with regards maximum capacity where appropriate )
N/A N/A 2,500 kg of MIPA per hour based on 8.5 hour day approx. 5 batches per day
Abatement system
O Bag filter O Bag filter O Bag filter O Electrostatic precipitator O Electrostatic precipitator O Electrostatic precipitator
O Cyclone O Cyclone O Cyclone
O Thermal oxidiser O Thermal oxidiser O Thermal oxidiser
O Active carbon bed O Active carbon bed O Active carbon bed
O NSCR O NSCR O NSCR
O SCR O SCR O SCR
O Dry scrubber O Dry scrubber O Dry scrubber
O Wet scrubber O Wet scrubber X Wet scrubber
O Lime injection O Lime injection O Lime injection
O Biofilter O Biofilter O Biofilter
O None O None O None
O Other:
O Other:
O Other:
Process Details Form
List of solvents used per process (to be added to the solvent suite)
Emission point as per Licence
A1-1 A1-2 A3-6
N/A N/A Client to inform Environmental Efficiency once monitoring complete