Differential Distillation
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Transcript of Differential Distillation
% vol. wt. ac. Wt. density v1 v2 m1 m2
10 48.64 26.82 1.0728 2.5 22.5 1.9775 22.5
20 48.33 26.51 1.0604 5 20 3.955 20
30 47.9 26.08 1.0432 7.5 17.5 5.9325 17.5
40 47.42 25.6 1.024 10 15 7.91 15
50 46.99 25.17 1.0068 12.5 12.5 9.8875 12.5
60 46.52 24.7 0.988 15 10 11.865 10
70 45.85 24.03 0.9612 17.5 7.5 13.8425 7.5
80 45.2 23.38 0.9352 20 5 15.82 5
90 44.3 22.48 0.8992 22.5 2.5 17.7975 2.5
100 43.51 21.69 0.8676 25 0 19.775 0
initial final weight ac. Weight density mol fr mass fr. meth.
1 79 81.7 45.06 23.24 0.9296 0.7 0.81 18.8244
81.7 82.5 45.23 23.41 0.9364 0.66 0.79 18.4939
3 82.5 82.8 45.32 23.5 0.94 0.65 0.78 18.33
82.8 84.4 45.53 23.71 0.9484 0.61 0.73 17.3083
5 84.4 85.7 45.8 23.98 0.9592 0.55 0.7 16.786
85.7 87.2 46.1 24.28 0.9712 0.51 0.67 16.2676
7 87.2 89 46.43 24.61 0.9844 0.45 0.61 15.0121
89 90.2 46.8 24.98 0.9992 0.38 0.57 14.2386
9 90.2 93.9 47.34 25.52 1.0208 0.29 0.44 11.2288
10 93.9 96.2 47.9 26.08 1.0432 0.19 0.345 8.9976
0.8
0.85
0.9
0.95
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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
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mass fr.
mass fr.
Mass fr. meth mol water mol mol fr.
0.080788 0.061797 1.25 0.047109
0.165101 0.123594 1.111111 0.1001
0.253174 0.185391 0.972222 0.160149 initial mol initial mol.
0.345264 0.247188 0.833333 0.228767 meth. water F B
0.441653 0.308984 0.694444 0.307929 5.500096 18.14662 23.64672 13.9087
0.542648 0.370781 0.555556 0.400266
0.648588 0.432578 0.416667 0.509368
0.759846 0.494375 0.277778 0.640255
0.876832 0.556172 0.138889 0.800177
1 0.617969 0 1
In liq liq
water meth mol wtr mol. mth. Mol wtr mol. x y 1/y-x
4.4156 0.588263 0.245311 4.911834 17.90131 0.215307 0.705712 2.039134
4.9161 0.577934 0.273117 4.333899 17.6282 0.197335 0.679083 2.075775
5.17 0.572813 0.287222 3.761087 17.34097 0.178233 0.666034 2.050016
6.4017 0.540884 0.35565 3.220203 16.98532 0.159372 0.603306 2.25259
7.194 0.524563 0.399667 2.69564 16.58566 0.139806 0.567568 2.337751
8.0124 0.508363 0.445133 2.187278 16.14052 0.119342 0.533156 2.416542
9.5979 0.469128 0.533217 1.718149 15.60731 0.099169 0.468031 2.711044
10.7414 0.444956 0.596744 1.273193 15.01056 0.078188 0.427144 2.86569
14.2912 0.3509 0.793956 0.922293 14.21661 0.060922 0.306502 4.072001
17.0824 0.281175 0.949022 0.641118 13.26759 0.046095 0.228561 5.480468
0.2326 0
1 1.1
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0 0.05 0.1 0.15 0.2 0.25
1.05
1.1
mol fr. vs. density
0.8
0.85
0.9
0.95
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1.05
0 0.2 0.4 0.6 0.8 1 1.2
De
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mol fr.
Ds
9.738017
0.25
Series1
Series1