)~noto Corror:, t iol,

350~ W. .GI"nlld J{iver 1\ ve.

Ifowcll, MI 48843

(517) 546-8330

I. PRODUCT IDENTIFICATION 1069 1071, 1079, 1084.LVV-' '... .1 .

PRODUCT NAME: Professional Drain Opellar

CHEMICAL NAME: Sulfuric Acid Mixture:Gr.I(les; Commercial (93.19)

DESCRIPTION: RTECS NO.N/A

Drain Cleaner Contact a physician, or the .PoisonControl Center immediately.

Rooto Corporation3505 w. Grand River AveI~owell, MI 48843

II, PHYSICAL PROPERTIES AND EXPLOSION DATA

: Not appl~able

Physical State: liquid OdorThreshold: NodataBoiling Point: 93.19%: 27 6° C (529 ° F)

Melting/Freezing Point: 93.19%-29.5° C (-21.1° F)Vapor Pressure at 400 C (102° F) : 93.19%: 0.0016

mmHgSpecific Gravity at 15 ° C (60° F): 93.19%: 1.8354

Vapor Density:No data,not volatile at normal temperaturesBulk Denslty.Not applicable (see specific gravity).Evaporation Rate: Not applicableSolubility: Miscible in all proportions in water. Also solublein alcohol.% Volatile byVolume: 0% at room temperature.pH: 0.3 (1N solution at 25 o C/78 o F)

DATA

§.Ql;..Nodala .13~t~.Ql~I!f!:ling; Nodala~Millvil~loslfttl.9.-0ischarge: Nodala

TOXICOLOGICAL AND HEAL THRecommended Exposure limit: ACGII~ TLV-TWA(1987-88):

1 mg/mJOSHA PEL (1989): 1 mg/mJ

Toxicological Data: LD50 (oral, rat) = 2140 mg/kgLC5o (inhalation, rat) = 510 mg/mJ for 2 hrs.

Carcinogenicity Data: This product is not classified by NTP(National Toxicology Program), not regulated as carcinogenic byOSHA (Occupational Safety and health Administration), and has

Stability: UnderNormalConditions: StableUnder Fire Conditions: Decomposes to SOxHazardous Polymerization: Will not occur

Conditions toAvoid: Temperatures which may have a negativeeffect on the materials of construction used in equipment.Materials to Avoid : Contactwith organic materials (such aschlorates, carbides, fulminates and picrates) Maycausefire and.explosions. Contact with metals may produce flammable

hydrogen gas.Hazardous Decompos~ionofCombustionProducts: Toxicgases and vapors (e.g sutfurdioxide, sulruricacid vapors andsulfurtrioxlde) maybe released when sulruricacid decomposes.

VI. PRODUCT IDENTIFICATION

..fygienists).Effects: No information is available and no adverse

effects are anticipated. Mutagenicity Data: Noand no adverse mutagenic effects are

Teratogenicity Data: No information is available and

anticipated. Synergistic: None known.

of exposure when: l)JnMl~ Mists and vapors may

.May cause

resistance, transient cough and.Severe overexposure may result In lung

pulmonary edema which can be falal. Prolonged or: resull in impaired lung funclion and

erosion of leeth. 2) In contact wIth theConcenlrated solution may cause pain and severe burns to

Prolonged and repealedredness, pain and

H.AZARDSUM~Y(29CFR 1910.12QO)Physk;aIHazards: Oxidizer; Water-reactiveHeallhHazards: COlTOsiveProduct Synonyms: Oil ofVitrkJI, SulphuricAcidChemical Family: Inorganicacid Molecular Formula: H~SO 4WHMIS Classification: Class E -Corrosive, Class dlA -

Very ToxicProductUse:Used in manufacture of drain care products.

SHIPPING DESCRIPTION:U.S. (Un~[QQLTJ CA.NADA~rLQ,}

Shipping Name: RQ SulfuricAcid SulfuricAcidHazard Class: CorrooiveMaterial Shipping Class/DIvision:

Class8 (92)Produdl.D. No.: UN1830

Pad<ing Groop: III-lAZAROOUS INGREOII:.NTS OF I\AA TERIALS:Hazardooslngredienls % ACGIH

TLVSulfuricAcid 00.100 1 mq/mJ

OSHAPEL

1 mq/m'

r~~ ~~-:~ ~:~~~~~~~~~I~; '~~~~-Jlyillg arId cr(1ckillg of 1111} !;ki,l. 3) 1!1 ~~fI13~1 Willl 11,1: ~yQ!;:

1II\1T\edi(1le I'ain. SCVClfJ b\"I's all(I,JOrl1lilI1CI'1 cornealllam.lgl'wllicll may resull ill blill(lncss 4)II'g~~~~~; Sevcre h lIning ,1 '(I

pain iIllIle moulll. 1I110C11 alld 3bdl)lll~n. Vonliling. di(1nl,ea an.

pelforalion of Il1e esopIla!,'Js arId SIOIM(;I, lil1i,lg ITIayo,::cllr. !.!

QU!-ef.H~~!tlLJ;.((.1!.Qts:- COlrosivc ~ff~cl!; O11111~ skill ,\1,d eyc:;

may I>e del(1yed a"d drn,l,lUo m(1y oc(:;\lr witl,()lIt 1IIe 5l!ll~mi()l, r

onset or pain. Strict adllercnce 10 lilst ai(1 me"sllles f{J"owiny

any eXr()SUI e is esselllial

F"sINdPr000dureswlIon:Inllall)d Moveviclilr,ll)r,,)sllt1i1. (3iv(!;11Iifir:iat,espir "liofI0NI- Y if

breall,irlg lIasslopred GiveCf1'(li(,rlIh 11(}I';]lyr~f)sll~cil"tior!(;r'I~) if

11lele isl1obleatllirl~'I\N[)no"IJlso ()1,1;,ir, IIK~(li(;.11i1llrnllio,llrv1rvlr:[ )II\ r l:-

I.Y.Incol1lacl witll tlleskin.lllI~;I, ~;I{inwilll'llr\llill~IW.II(~1 ,(" illlirli,llllllI0120

1llirll1las. Slil'll1l1sllirl~'wllilt! ,rnIKJVirlgC("llrullirlillml clt,lllill\J II ir,ilmi(,,1

"e,si$ls. rcreillllusllirlg ( )!J(;lirl'111~(lic;II(I"{!'IIj()flIMMI:-IJII\ I [L Y l>o,luI

1,.lllsrOlI vi(;Ii1 'IUI'loss \III! , 1!(.I)'II'IIf!"'lmllItI~IIi,I!J I'()I k)(lis (:O"II}lole

U'III)SS lllISllirlg {'A'fllJO COlllil\lJI!(Jti\lIir\!J11 iI'I~I!O'11,ICOlllrlclwilhll,o eyos. 1""IIC(lim(!lyrItJ~;II{!y4!Swill,,\I1\llill~'wil(el It)( il

'llirlirl\lIIT\OI20'llilltJlo~ 11(,IIII!yl!lkl~(,I)t!II(ltIlirl('"'J.;IIi,I(' Ilk,ilmk),1r)o,si.;(s.,0"eillnll!;I,irtU ()I)I;lir",m(I~:;II;IIII!'llk)(,.IMM( I)il\! 1,1 y I)()II')I

llrulspoll vi<.:lilI1UI'lilllll~ , (~{'f)(1 \lIK!r1(lcIllh,.;llirl~1 Pf!li()(1 i5 (;(~ III ,1t~1

rllJsllirlgcrlnbc corllirllledtlul illg I, rnl!;p()11

Ingeslod: l'victil11is aloll a,It1"ol (;()'lvuisil,~I.lir]Se olll 1llollllIrn,dgiv4J 1/

2101 gl(1sS orwaler lo(Jilllll~ '1Iillc,irn 11sponlmloolls voi'"li,IUOC(;lIrS.lIaveviclir11Iem,ro'w(1'd .Nillll,oad (l()wlllo nvoid !JI emllirlg il' or voflli(lJ5.

rinse moutll alld ndlJ)irllster more w(1ler IMMEOIl\l [L Y con\acl

Iloc(11 pOiSOIl. con\lol cel1ler. Vo~l'ilir'U IMy need 10 !J,! indllced !Jul

sll()lIld !Je dlrecled !Jy ~ "hysk;I~" or a poison con\rol cen\(!r.

IMMEOII\ TEL Y Ir al1s"ol I viclilJ) 10 rnl elMrgen('y f(I(;ilily.

Nole 10 Pllyslcian. Medical condilions Il1al 'T'(1y I>e agg'avated

!Jy Qxposure illclude tlsll"n;J. broncllitis. cmrllysema ;]Ild oIlIer

lung dise~ses °'Id clI,onic; nose. sinus or 111'0,11 cor'dilioI15. I" Il1e

I event or skifl or eye co'II",;I. , a"i(1 t1111111101 OII~111 Ill1!;llirlg is

essel1li~1

I~P(;OIII/'lmlll;lliuIIS 'i!;IIl!JilIllli'. :;1)(;lk,I' itl(li\;;II()'lle'yl'e or oqllipment

wllk:, willproville l»olocliol1 ~!J,litIS' 0'/01 ()X"U5Uro '0I1,is rroduc'.

COiIIJlliol'5OrU5e. t1de\ll',I(;yor rnl!Jil)()rni,I~lor olllercO/ltrolmeasuJes.

ml: I ;lctu;llf).xrOSules willdiclnl(1 tllenecd ro, 5pcciricrrotectived~\ " :()S at yOl"WOI krl;)('.e .

['IVilloorirlg Conlrols: l.(JC.llexll;lust vclllil;llkJI'rcIluit ed.

11.I).riratoryprotoctiun/\NIOSII/MSI t/\;lllrrOvedt1itpulifyitlgre~:! )irnlor e(llJipred willl flcj(1 ~1;ls/fuIT'e. dust. mist CRlt, idges ror

t;ol:...entl nlk)l1s up to 10 "lg/JI1'. /\,1 ilir.surpliod respirator ir concon.

t,nlil.l/IS are 11igheror Ul1kI10WlI.

Skil1l.'rotoctiol1: 11I1peIViolJS (ie I'corlono, I)VC)glov()s.ooverRIls.

I>ools t111d/or otllcr i'cilll esi~;I;I'III)lott:!(;live cloll,irlg.

EyoProtection:Sart1ly ~/m5Sf~5 or tiglllrillil1g cllcmical goggles.Otllor rf)rsonal rroloclivo r: rll'ip"'orlt WI,()r c \I,ore Is a

d;llltl()r or ~;rillirl~1 ()r !:;IJI,l!;I,i,,!I. ;,(:ilJ , (!sisl;,,11 i'prOl15 or sllils

SIIOl11d I)() WOII'. lrouser legs !;llolll(J I,u wOln outside (1101

tuckl)d irl) , ubber bo()ls Silloly sIIUW(11 s mId eyewt1sh roU'I-

t(lirlS 511OUhll)c ir,sl;llle<l irl :;1(,J o!J(1 (",(II,;lI'dlirlg rn ens.

tlrnldlirlgPlocodures ;lnd .::<\IJiplnorlt: Crul)or,sleelorslair,'esssteclIn,ltmims ;lrc sliilm),,) rOlllSe Ir)r i'(;ilJ COII(~OIIII ollons e<\linlloor grentertI,;",{):J'X, Ilowevel.lIll) e"I)(:I( ,rkm(!1 COlICelll,mk)I'sol'"'o m;llerirns

or COII!1I,II'~liollr;OIII)c vmyc;ol'll)k)x (:(I/II;I(11)lrxlucI5IJI'pli(!r ror

5pc(;iri<:I(!(;rl/ll/l1el'(I;,liull.;wllm, 11;1/'(llirl!15111111Iicncj(J nl511ol1gllls

'C$S lImn 77"/n.

Storago To'"pori)turo: StrJlt:! OI)OVCrl(!f1lir,gruit,1 (Secti0112).Elovatedtemprnalllle5 willir,creas(! II)() (;(»rosion r(lte ()r rnost metals.

Storage l1.equiromenls : Sto' e pnck"ged ;I(.id itl a dl y. well velllilated

loc..,liol1 Rwayr, olncoml>lI5til)le5. oxidizers.I)i)ses. or melt1l1ic

p(JWders SloI ilge Irn Iks sllol/kl ()e rrolect(!d flomwaler ingress. be

w()1I vonlilnled. and 11mi,llmlled SIIUCtl" allyin 3 sare m,d relinble

cr)l1(lili<)11Ol"or rrecaulfons: KeerflWt1yrIollligniliol1 soulces. SuKulicacidwillaltack 50/11e fonns or rlnsli(;s arid coalil1gs 1\Iw~ys add acid towaler -

not wat()llo acid Ir kopl in l/rp()1 floors or ()uiklillg. floors should I>e

acid ploorwilll dl ;lir,!) 10 ;lret~ovolyt,IJIk

VII. ENVIRONMEN f/\l- r',{O I-E(~IIOI~ DATA--

VIII. ADDI1-IONf\L I NI:Or~MA1-ION AND

SOlJr~CES USED

1 fvl/\I~SUIEX fecltllk:;,,!UIII"!lii,. "S\lll\llk;/\(:i(r21::.IIVilo-111)S M;1rl\l.II."SI IlflII i(:/\(:id,tll(1 °"Jtlln". ErIVirorllnellt Conada,

r-el>J\I(lly.1~JlM.

1 110 illfoII11"liI)11COIII;lirl()d Iloleillllasl)110111)1 (!paled byl~OOTO GORP. !

alld is orloledonly ?S " glJide In IIIQ h,lll~lIill~1 oftllis specific malelialarn'has been p' opal ed 111 y()()d f ,111111,y technlC<llly kllowledgeable personnel.

II is not illlendedtobe ,,11.ilIClusive alld tIle 111i1nnerand conditions of use

~andll(lndlillg may irlvolve olllcI alld addilionnlconsiderations. No

wallalllyof",lykilIdis{livcIIOI iIIIIJliedal«Jr{OOTO GORP. will,lotbo

liable fol "'ly dal11(1ges.losse~. ilIjUI iosol collsequ.entialdamages wh!cll

may I esllll frolllthe use or rOfl()n(;f~ of f]lly 11Iformatloncontained herein.

Sleps lobo Inko11 ill tl10 OVUIII of ;1 srill ollunk: I ~t!III()VO .,lIitllliliull

5OUICeS. VolllilnleallJn Slul'()rl()(lllc(! 111;11< if 5nfIJ ludoso Oikowilll

"Iml 'llnlel if11 (S(1lld, e(1II1" {!1(: ) (;ull()(;1 illl(lcOIII,liIIU' S fol , C(;I;:lilll or

disfx)snltnvironmenl(11 Effects: 1I;11II'f\,llornlll,lli(; lir(1ill vmyhJWc(Jflr;olll, f1-

lions Maybe dmlgerousirill!lllolswnlol illl~k(!; fi3111oxicilyclilicmcollcel'lrallon"' 10 ITIgf\-: 7 :l.IIII~If\JIJ6I\15 -'- yl'lne:lO l~ml/511 i5 -0-

100"/ol'IOII(1lily.Oeacllv(1llng Chonlicals.lilllo.lillle:;lollf!. sodiu,11(~;111,l)fmlu(5od"ash), sodillI11bicmbomll(!, dilllln sodil"lllly(1Iuxillc,dilulo rnl\ln

rnnllOnk,.Wasle OisposaIMetl,ods. Oi~roseorwnslem.llel i<l1 m (1nnrr' oved

; wasle Ireat,TlenUdisposrn f,lCilily .in flCC<)1 ti"ncewitl\ ,)p,,'i(;.,IJIf)

regulalions 00 no1 disros(! of W(1SI(~ will\ norlnal ~lfll!Jage.