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Prepared By: Approved By: Revision no. 05 dated 01.04.2019 Page 1 of 57 Deepak Nitrite Limited On Site Emergency Plan (Disaster Management Plan) REVISION NO. 06 EFFECTIVE DATE: 01.04.2019 Deepak Nitrite Limited Factory: Roha Division, Plot Nos. 1-7, 26-31, MIDC, Dhatav, Roha-402116 Dist. Raigad 402 116, Maharashtra, India Tel.: +91-2194-263 550/750, 264777/78/79. Fax: +91-2194-263 863 Website: www.deepaknitrite.com Corporate office: Deepak Nitrite Ltd. Aaditya-1, corporate office, Chhani road, Baroda, Gujarat-390024, Phone: 0265-2765200 Website: www.deepaknitrite.com

Transcript of Deepak Nitrite Limitedenvironmentclearance.nic.in/writereaddata/online/... · Deepak Nitrite...

Page 1: Deepak Nitrite Limitedenvironmentclearance.nic.in/writereaddata/online/... · Deepak Nitrite Limited Roha Division On Site Emergency Plan (Disaster Management Plan) Effective Date

Prepared By: Approved By:

Revision no. 05 dated 01.04.2019 Page 1 of 57

Deepak Nitrite Limited

On Site Emergency Plan (Disaster Management Plan)

REVISION NO. 06

EFFECTIVE DATE: 01.04.2019

Deepak Nitrite Limited Factory: Roha Division, Plot Nos. 1-7, 26-31, MIDC, Dhatav, Roha-402116

Dist. Raigad 402 116, Maharashtra, India

Tel.: +91-2194-263 550/750, 264777/78/79. Fax: +91-2194-263 863

Website: www.deepaknitrite.com

Corporate office: Deepak Nitrite Ltd. Aaditya-1, corporate office, Chhani road, Baroda,

Gujarat-390024, Phone: 0265-2765200

Website: www.deepaknitrite.com

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Deepak Nitrite Limited Roha Division

On Site Emergency Plan (Disaster Management Plan)

Effective Date : 01.04.2019

SR. NO. COPY HOLDER LOCATION COPY NO.

1. Dy. Director of Industrial Safety and Health DISH Office

2. GM-Manufacturing Roha

3. General Manager – HSE (Corporate) Nadesari

4. Emergency Control Center Security Office

5 Sr.Manager-Technical Roha

6 Sr,Manager-HR Roha

7 Sr.Manager-QA/QC Roha

8 Sr.Manager-Engineering Roha

9 Manager-Material Roha

10 Dy.Manager-SHE Roha

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Deepak Nitrite Limited Roha Division

On Site Emergency Plan (Disaster Management Plan)

Effective Date : 01.04.2019

CONTENTS

SECTION DESCRIPTION PAGE NO.

1. Introduction 4

2. Emergency Preparedness and Response Organisation 11

3. Emergency Mutual Aid 21

4. Preliminary Hazard Analysis 22

5. Identification of Site 24

6. Hazardous Chemicals 27

7. Likely Dangers to The Plant 29

8. Details of Safety Systems 38

9. Communication Facilities 40

10. Fire Fighting Resources 42

11. Medical Facilities 45

12 Post Emergency System 47

13 List of Fire Fightingcum Spill Control Team and First Aid cum

Rescue Team 49

14 Site plan

15 Fire Hydrant System

16 Material Safety Data Sheets

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On Site Emergency Plan (Disaster Management Plan)

Effective Date : 01.04.2019

SECTION - 1

1.1. OBJECTIVE

To provide employees, contractors, visitors with adequate information to follow in

respect of an emergency situation under control action plan.

1.2 POLICY

It is the policy of DEEPAK NITRITE, Roha sites to:

Health, Safety, Environment and Quality Policy:

Employee Health, Safety, Environmental protection and Quality are core business

values at Deepak Nitrite Ltd.

We strive towards excellence and align our growth path to make tomorrow safer,

cleaner, greener and more sustainable.

We aim to delight our customers and other stakeholders by providing dependable

services, products and innovative solutions.

We are committed to:

▪ Maintain our operations and workplace free from incidents and significant risk

to the health and safety of our stake holders.

▪ Adopt global principles of Sustainable development, Responsible Care® and

Management system standards.

▪ Inculcate process approach, evidence based decision making and Plan-Do-

Check Act cycle for continual improvement.

▪ Proactive compliance with all applicable statutory, regulatory and other

requirements.

▪ Strengthen Process Safety Management in existing and new manufacturing

operations.

▪ Conserve natural resources and protect environment through pollution

prevention.

▪ Recognize and respond to community concerns proactively.

▪ Work with key stakeholders to minimize risk level throughout our product life

cycle.

▪ Share and seek best practices, both inside and outside the organization.

Chief Executive Officer & Executive Director

April 11, 2016

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Deepak Nitrite Limited Roha Division

On Site Emergency Plan (Disaster Management Plan)

Effective Date : 01.04.2019

PERSONAL PROTECTIVE EQUIPMENT POLICY:

Use of PPE’s are prime concerns of management in manufacturing activities which

helps in maintaining Safety and Health standards at DNL

To express this concern, DNL has defined the PPE policy as follows,

We will remain committed to,

1. Insist on use of safety helmets, safety glasses and safety shoes by every

employee as specified minimum PPE standard irrespective of the job being

undertaken.

2. Insist on use of proper gloves by the workmen while handling any chemical

directly or indirectly.

3. Educate to select right type of PPE for the Job (both in terms of type and

MOC.)

4. Provide proper PPE in addition to minimum specified as per the job and ensure

that it is comfortable under working conditions.

5. Train workers adequately in use and maintenance of PPE.

6. Insist use of PPE in unspecified areas in accordance with instructions of the

superior.

7. Ensure that PPE will be stored in a clean and fully in operational condition.

8. Define the areas to store PPE properly where the equipments will not become

damaged or contaminated with dust or chemicals.

9. Define procedures for decontamination and its frequency while using reusable

PPE.

10. Keep a track of life of PPE based on manufacturer’s specification, actual shop

floor experience or any information from networking with other companies.

Sd/-

Date 1st July, 2010 Chief Executive Officer

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On Site Emergency Plan (Disaster Management Plan)

Effective Date : 01.04.2019

1.3 LEGAL REQUIREMENTS:

It is statutory requirement as per following acts and rules:

• Factories Act sec.41b,4

• Maharashtra Factories Rules 73Q and

• 13 (1) of Manufacture, Storage and Import of Hazardous Chemicals Rules 1989 for

the site to development of ‘On Site Emergency Plan’.

1.4 SCOPE

This emergency plan is applicable to any emergency arising at sites and affecting the

employees, the contractors, the visitors, the neighborhood, the business and environment.

1.5 SITE PROFILE

Site : Deepak Nitrite Ltd, Roha Division

Plot No.-1 to 7, 26 To 31, MIDC Area,

Roha- Raigad.

Telephone : 02194, 263550, 263750.

Fax No. : 02194, 263863.

Unit Head : Mr. Sunil Desai,

GM.-Manufacturing

Address: Trimurti Complex,

MIDC Area, Roha- Raigad.

Mobile : 9881490489

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Deepak Nitrite Limited Roha Division

On Site Emergency Plan (Disaster Management Plan)

Effective Date : 01.04.2019

Site’s Profile:

Deepak Nitrite Ltd, Roha factory is a primary manufacturing site. It is located 120 kms to

South of Mumbai. Manufacturing of Dyes Intermediate, Agrochemical and Pharma

Intermediate at the site.

The site is not classified as ‘Major Accident Hazard’ category.

The site operates in three shifts.

The total manpower strength is 213.

General Shift: 54 Nos

First Shift : 45 Nos

Second Shift: 40 Nos

Third Shift : 35 Nos

1.6 DEFINITION OF A MAJOR EMERGENCY

A major emergency can be defined as an incident which:

➢ Is beyond the control of responsible persons at the scene, or

➢ Requires the assistance of external emergency services or

➢ Has the potential to cause prolonged shutdown of production facilities or

➢ Could cause annoyance to or complaints from our neighbors.

1.7 TYPES OF EMERGENCIES:

➢ Fire / Explosion / Toxic Gas Release / Spillage.

➢ Operational / process Emergency

➢ Act of nature: Cyclone/ Earthquake/ Flood

➢ External Factor: War/ Sabotage

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Deepak Nitrite Limited Roha Division

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Effective Date : 01.04.2019

1.8 ON SITE EMERGENCY

Any of the following situations occurring in the factory is considered as an On Site

Emergency.

1.8.1 SPILLAGE

The spillage of corrosive or toxic chemicals and the flammable or halogenated

solvents. The scale of emergency will depend on the quantity of the spillage and

the properties of the chemical.

1.8.2 MAJOR RELEASE OF VAPOURS/ TOXIC GAS

A. VAPOURS

The leakage of gas or low boiling liquid from tank, drum, pipe or equipment can

result in a vapor cloud. If the material is flammable then there is danger that the

leak or cloud is ignited by the nearest source of ignition.

B. TOXIC GAS

Emergency arising out of leakage of toxic gas from Hazardous material. In case of

leakage of toxic gas, the seriousness of emergency will depend on the wind

direction and magnitude of leakage.

1.8.3 MAJOR FIRE OR EXPLOSION

Since the site uses the large quantities of the flammable solvents, fire is a major

risk for the site. Explosion can take due to run away reactions, hydrogenation,

cylinders or solvent drum getting overheated, incompatible material coming in

contact with each other and reacting.

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Effective Date : 01.04.2019

1.8.4 OPERATIONAL / PROCESS EMERGENCY

Plant Activity Hazards Control / Process safety Interlocks

TFMAP

Transfer of 3-ABTF Spillage and

chemicals exposure

• Transfer 3-ABTF through mass

flow meter.

Addition of Sod.

Nitrite solution

Exothermal

reaction & NOX

generation

• If temperature increases, Sod.

Nitrite solution addition will be

stopped. (R601, R602 & R603)

Addition of diazo mass

& 30 % caustic lye

solution

Exothermal

reaction and

decomposition of

diazo-mass.

• If temperature increases, diazo

mass & 30 % caustic lye solution

addition will be stopped. (R607,

R608, R610)

Effluence of pH during

Diazo coupling

reaction

Quality & yield

issue

• If pH decreases, addition of

diazo mass will be stopped.

• If pH increases, addition of

caustic lye solution will be

stopped.

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Plant Activity Hazards Control / Process safety Interlocks

Hydrogenation

Plant (HP) If cooling tower

pump CTP- 701A/B

/ CTP- 702A/B is

stopped.

Reaction

temperature will

increase may cause

explosion.

• Hydrogen addition will be

stopped.

If scrubber pumps P-

701B / P- 702B is

stopped.

Hydrogen liberate

in atmosphere may

cause fire.

• Hydrogen addition will be

stopped.

If- R-701 & R-702

agitator is off.

Loss of hydrogen

and reaction will

not complete.

• Hydrogen addition will be

stopped.

If temp & pressure

increases beyond the

maximum define

limit of 130° C temp

and11 kg/cm2

pressure.

Explosion with fire

• Hydrogen addition will get stop

• Safety alarm will get on.

• 100% cooling to reactor R-701 /

R-702 will get started from DCS

automatically.

Hydrogen leakage May cause fire

• During hydrogen leakage if

hydrogen content in atmosphere

is more than 20ppm, then Safety

alarm will get on.

• Hydrogen addition will get stop.

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Effective Date : 01.04.2019

Plant Activity Hazards Control / Process safety

Interlocks

Continuous

Nitration

If temperature goes above

than set point due to –

*If R1, R2, F-1

temperature goes above

given set point.

*If R1 & R2 tripped / stop

*If raw material flow rate

varies above given by pass

time

*If blower off

Runway reaction Nitration will get tripped.

Column If vacuum dropped in

column

Temperature & pressure

will increase may

causes release of

organic Vapour with

high velocity or may

cause explosion

(4-NOX column).

• All process is controlled

by DCS and provision of

alarm system is in place.

• Stopped steam.

• Column feed stopped.

Q.C. Lab. Hydrogen leakage in Lab.

during analysis.

Analysis will hold. If

concentration of

hydrogen is more may

cause fire.

• Instrument shows leak

detect information.

• Alarm system is in place.

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Effective Date : 01.04.2019

1.9 NATURAL CALAMITIES

1.9.1 FLOODING

Flooding is indicated by the covering of road/path/route with accumulation of

water. Water also starts entering in the plant/ department.

1.9.2 CYCLONE

Cyclone is indicated by high speed of wind, spread of dusting all over and

there may be chance of rain. Due to cyclone there may be chance of collapse

of buildings, electric poles and trees.

1.9.3 EARTH QUAKE

Earthquake is indicated by vibration to earth, collapse of buildings and tress.

There may be chance of major environmental damage, personal injury and

property damage.

1.10 EMERGENCIES POSSIBLE IN PLANTS.

• FIRE : Cumene Nitration plant, Continuous Nitration Plant, Solvent tank

farm, Furnace Oil storage tanks, CF 1950 plant, DEMAP,

Distillation Column, Pilot Plant.

• FIRE AND EXPLOSION: Solvent storage tank, Pilot Plant, Hydrogenation Plant.

• EXPLOSION HAZARD : Boilers, Hydrogenation Plant ,Pressure

Vessel, Thermopac

• MAJOR LEAKAGE OF LIQUIFIED GASES: Ammonia.

• MAJOR LEAKAGE OF HAZARDOUS LIQUID : Nitric Acid, Sulphuric Acid,

Cumene, Ammonia, D.M.S., M-Cresol, H2O2, Xylene etc

.

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1.11 OFF SITE EMERGENCY

Any major fire at Site, especially in the solvent yard located near north side boundary

wall can lead to an ‘Off Site Emergency’. Any other event at site leading to an Off Site

Emergency will be extremely rare

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Effective Date : 01.04.2019

SECTION - 2

EMERGENCY PREPAREDNESS AND RESPONSE ORGANISATION

2.1 SITE EMERGENCY KEY PERSONNEL

Key Personnel Responsible & It’s Alternative

• Site Main Controller GM-Manufacturing / Sr.Manager-Technical and after general

shift QC Executive.

• Incident Controller HOD / Section Head/ Shift Executive

• Communication Incharge HR Head / Dy Manager-Admin

• Engineering Team Manager Engineering Services, Available Electrical, Instrument

& Maintenance Technician

• Fire Fighting cum Spill

Control Team Trained persons from the available Manpower

• First Aid Cum Rescue Team Trained persons from the available Manpower

• Advisory Team Sr.Manager-Technical, Sr.Manager-QC, SHE-Head and

Dy.Manager-Production

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Effective Date : 01.04.2019

2.2 EMERGENCY ORGANISATION

2.2.1 SITE MAIN CONTROLLER

GENERAL MANAGER (MFG) :

(In his absence) : Sr.Manager Tec Services

Dy.Manager Production /

QC Executive.

(Period 17.30 Hrs to 09.00 Hrs)

2.2.2 INCIDENT CONTROLLER : HOD / Section Head / Sr.Executive /

Shift Executive

1. COMMUNICATION INCHARGE :

Sr. Manager (HR/ADMN.) : ----

(In his absence) : Dy.Manager (Admin)

2.2.4 ADVISORY TEAM

:

Dy.Manager – PRODUCTION, Sr.Manager - TECH.SERVICES, SHE-Head.

Sr.Manager – ENGINEERING, Q.C- Sr.Manager

2.2.5 ENGINEERING TEAM

Manager Engineering, available all Maintenance, Electrical, Utility and

Instrumentation staff.

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2.3 KEY PERSONNEL & THEIR RESPONSIBILITIES

Anyone noticing emergency situation like fire, explosion, toxic gas leakage and

chemical spillage due to catastrophic failure of reactor / tank/ receiver etc. Must

• Press the nearest Emergency switch and sound the emergency siren.

(Siren sound three times at 12 Second frequency intervals). Preferably within the

affected area. The affected area indication shall appear at Emergency Siren Panel

located at reception.

• Inform Security Officer; tell – NAME, TYPE OF INCIDENT, HELP NEEDED

and order Security Officer / Guard to inform all KEY persons. (USE

TELEPHONE NO. 119 and 160 )

• Seek help from the persons working nearby.

• Try to control the incident at its initial stage with available means / sources

quickly.

• Inform to Shift Executive about the incident.

2.3.1 RESPONSIBILITY OF SITE MAIN CONTROLLER

As soon as he is aware of the emergency:

• He will proceed to the Emergency Control Centre.

• Will assess the magnitude of the situation, in consultation with the Incident

Controller and advice to take all plants in safe mode and evacuate the people

from their department/section and assemble at the safe assembly point.

• Ensure that outside emergency services are called (Fire Brigade, Police,

Doctors, etc.)

• Ensure that key personnel are called.

• Exercise the dire operational control of those parts of the works, outside the

affected area.

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• Maintain review of possible developments and assess these to determine the

most probable course of events.

• Ensure that the emergency is intimated to the District Emergency Authorities if

required.

• Ensure that evidences are preserved.

• Control rehabilitation of affected areas on cessation of an emergency.

• Determine what investigations and reporting should be carried out, and by

whom, to determine the cause and (if appropriate) prevention of recurrence.

• Give instruction to Security Guard to raise All Clear siren after emergency

over in consultation with Incident Controller and confirmation of head count.

• Issue authorized statements to news media in consultation with Head Office.

• From 17.30 Hrs to 9.00 Hrs ,QC Shift Executive acts as a Site Main Controller

till he is arriving

2.3.2 RESPONSIBILITY OF INCIDENT CONTROLLER

On being informed about an emergency, proceed to the scene.

• Take charge of the situation.

• Assess the scale and the potential.

• Direct all operations within the affected area with the following priorities:

• Secure the safety of personnel.

• Minimize damage to plant, property, material and environment.

• Provide the advice and information to fire fighting Team.

• Assess the need for the external help in consultation with Fire fighting Team

and inform Site Main Controller for the same.

• On arrival of external fire fighting Team, give charge to them and provide

information / assistance as and when required.

• Ensure that the affected area is searched for casualties.

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• Ensure that all non-essential workmen in the affected area are evacuated to

the appropriate assembly points.

• In the event of failure of internal telephones, set up a communication point

and depute runners as appropriate for communication with the Emergency

Control Room.

• In consultation with Site Main Controller

• Direct the shutting down and evacuation of plant and areas.

• Ensure that outside emergency services and key personnel are called in.

• Report on all significant developments to the communication officer/ Site

Main Controller.

Preserve evidences that could facilitate any subsequent enquiry into the

clauses and circumstances of the emergency.

2.3.3 RESPONSIBILITY OF COMMUNICATION INCHARGE

On hearing the Emergency Siren, proceed to the Emergency Control Centre.

• Take charge of telephone system and report to the Site Main Controller.

• Establish contact with Incident Controller.

• Keep log of the incidents.

• If required communicate the incident to the government authorities as per

the instruction from Site Main Controller.

• Communicate about the incident to victim’s relatives & make necessary

arrangement to bring them.

• If outside help is required, contact to concerned offices or facilities as per

the direction of Site Main Controller.

• If Off Site Emergency is declared by the Site Main Controller, inform to the

Local Crisis Group, neighboring industries as well as near by villages, Gram

Panchayat according to the instruction of Site Main Controller.

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• The message should be prepared & same must be distributed to the team

member so that there is no discrepancy in the message going outside.

• The report of the communication to be prepared by the team leader & it will

submit to the Site Main Controller.

2.3.4 RESPONSIBILITY OF QC EXECUTIVE

• He will act as a Site Main Controller. (Period from 17.30 Hrs-9.00 Hrs)

2.3.5 RESPONSIBILITY OF ENGINEERING TEAM

On hearing the Emergency Siren, before leaving the work place, they will stop

the work safely and inform concerned Incharge of particular department where

the work is being carried out. .

Engineering Team will:

• Report to Assembly Point near main gate.

• Find out emergency location. Approach emergency site immediately.

• Report to Incident Controller.

• Take quick action as per the instructions from Incident Controller

• Sr.Executive/Executive and the shift electrician will report to the scene of

incident and close down the services, electric supply as requested by

Incident Controller.

2.3.6 RESPONSIBILITY OF FIRE FIGHTING CUM SPILL CONTROL

TEAM.

On hearing the Emergency Siren, before leaving the work place inform to

concerned shift executive & give the charge of activity then leave the place.

Fire fighting Team will:

• Report to Assembly Point near main gate.

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• As per instruction from Site Main Controller one of the team member will go

to fire pump location and take the following action:

a. Check the pressure of hydrant system.

b. Check the Main / Diesel Engine pump is ON.

c. Check the water level of firewater tank.

d. Starts make up of water to the tank by starting MIDC water tank pump.

• If any abnormality is observed, it should be reported to the Site Main

Controller

• Find out emergency location. Approach emergency site immediately.

• Report to Incident Controller.

• Take quick action as per the instructions from Incident Controller.

• Bring emergency under control as early as possible.

• Keep all fire fighting equipments in order after emergency is over.

• Do not leave process / equipment in UNSAFE CONDITION.

• Do not leave emergency site unless ALL CLEAR siren is blown.

• Do not use improper fire extinguisher.

• For minor spills, clean the spill using absorbent material and put the

Contaminated material in the drums & mark it as a hazardous waste.

• For major spills, report immediately to the concerned Executive,

Department Head, ETP Operator and SHE dept.

• Try to contain the spill material in the Collection Pit by providing bunds at

outlet of the Collection Pit. Before entering the spill area recommended

PPEs to be used.

• Warn other employees about the spill.

• Eliminate combustible material or other source of ignition.

• Incident Controller of the affected area shall initiate evacuation [of

employees] if applicable. Do not be panicky.

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2.3.7 RESPONSIBILITY OF FIRST AID CUM RESCUE TEAM

On hearing the Emergency Siren, before leaving the work place inform to

concerned shift executive & give the charge of activity then leave the place.

First Aid Team will:

• Report to Assembly Point near main gate.

• Keep available first aid box & stretcher ready to carry injured person.

• Approach emergency site quickly with BA set and First Aid box.

• Follow instructions of Incident Controller.

• Render first aid to the injured person, hospitalize, if required.

• Accompany him to hospital and assist doctor / nurse.

• Do not be panicky.

2.3.8 RESPONSIBILITY OF ADVISORY TEAM

• On hearing the Emergency Siren report to Site Main Controller.

• On demand of Site Main Controller provide necessary help such as the

technical information, MSDS, dispersion calculations, outside help etc.

• Work as per the Site Main Controller instruction.

2.3.9 RESPONSIBILITY OF SHE TEAM: (SHE-Head /Executive-SHE)

• To assess the scale of incident (Both for internal and External services.)

• To initiate the emergency procedure to secure the safety of employees,

minimize damage to the plant and property.

• To direct rescue and Fire Fighting operators until ( if necessary ) the Fire

Brigade arrives.

2.3.10 RESPONSIBILITY OF STORES INCHARGES / SR. EXECUTIVE /

EXECUTIVE:-

• Arrange for suitable extra protective equipment’s if required for store and

plants.

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• Arrange for particular Personal Protective Equipment from Mutual Aid

Response Group if required.

• Sr.Executive Stores will take head count at Assembly Point near gate

No.02 and report to Main Gate Security Officer. (Inter com 119/160).

• Brief about the incident to Assembly Point people.

2.3.11 RESPONSIBILITY OF HR & ADMIN OFFICER:

• Take head count at Assembly Point near main gate and report to Main gate

Security Officer. (Inter com 119/160)

• Brief about the incident to Assembly Point people.

• Act as Communication Incharge in absence of HR Head and Dy. Mgr.

Admin.

2.3.12 RESPONSIBILTY OF MEDICAL PERSONNEL:

• Keep ambulance (Emergency Vehicle) ready to proceed to the sense of

emergency at short notice.

• Send ambulance (Emergency Vehicle) with first Aiders to the side to render

immediate medical help.

• Arrange for the treatment of casualties at the medical center.

• Call for First Aiders from unaffected plants.

• Alert neighboring hospitals for receiving casualties and nature of treatment

required.

• Arrange for extra ambulance from neighboring Factories, Hospitals, and

Municipalities etc.

• Send Casualties to Hospitals accompanied by First Aiders.

• Prepare documentation.

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2.3.13 RESPONSIBILITY OF SECURITY OFFICER/ SECURITY GUARD

On hearing the Emergency Siren

• Follow instructions of Site Main Controller.

• Do not allow any vehicle to come inside the factory except emergency

vehicle.

• Do not allow visitors to move around.

• Keep gate closed.

• Assist in controlling contractors, vehicle movement and mob.

• Direct the First Aiders to Occupational Health Centre or to the site of

incident.

• Ensure that the traffic movement within the factory is controlled.

• Render all possible help for controlling overall situation.

• Do not leave the site unless asked to do so.

• Stop the movement of unauthorized persons in factory.

• Provide transport arrangements within/ outside the factory for quick

movement of casualties and key personnel.

• Ensure that alternative transport is available when emergency vehicle

leaves the factory site.

• Ensure accounting of the site.

• Raise All Clear siren as per instruction by Site Main Controller.

2.3.14 RESPONSIBILITY OF TELEPHONE OPERATOR

• Help to Site Main Controller or Communication Incharge for

Communication.

• Check the head count by calling to all plants and unevaluated area.

• In absence of Telephone Operator, Security Officer will do the above

activity.

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2.3.15 RESPONSIBILITY OF ALL OTHER EMPLOYEES

• Gather at Safe Assembly Point.

• Be alert and be available if required.

• Wait for further instructions.

• Approach Assembling Points route as taking note of wind direction.

• Help in taking roll call.

• After hearing ALL CLEAR, go back to the departments.

• Start the work again after setting instruction from Shift Executive.

• Do not be panicky. Do not run.

• Do not approach emergency site unless asked for.

• Do not engage telephone except for emergency purpose. Keep lines free.

2.3.16 GENERAL INTRUCTIONS

• Cancel all work permits.

• Take note of wind direction.

• On hearing disaster siren evacuates as per evacuation route without

running and panicky and assembles at assembly points.

• Do not use telephone except for emergency purpose.

• Do not start work at height, vessel entry, and hot work unless permit

conditions are verified?

• Do not allow unauthorized person to approach emergency site.

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SECTION - 3

EMERGENCY MUTUAL AID

3.1 MUTUAL AID RESPONSE GROUP

SR

NO. NAME OF COMPANY CONTACT PERSON PHONE NO. FACILITY

1 Excel Ind. Limited Mr. S. Phase 263701 - 08 Ambulance

2 Sudarshan Chem.

Industries Limited.

Mr.B.N.Kadam 263531 – 35 Ambulance

3 MIDC Fire

Station,Dhatav

Mr. Gharat 101/ 263600 Fire Tender

3.2 TYPE OF ACCIDENT

a) Chemical spillage due to catastrophic failure of reactor / tank /

Receiver, etc.

b) Toxic gas leakage c) Fire

d) Explosion

e) Fall of structure / building

3.2 CO-ORDINATION BETWEEN THE ORGANISATION

Towards fulfillment of Mutual Aid, the companies in the area have formed Mutual

Aid Response Group. Mutual Aid Response Group meets every month and details are

under development.

The following emergency facilities are available.

1. Ambulance service.

2. Occupational Health Center Services.

3. Para Medical staff.

4. Technical staff to assist in Emergency.

5. Neutralizing compounds.

6. First-aid equipment, Safety equipment, Self breathing apparatus

7. Fire tenders /Fire extinguishers / fire extinguishing media

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SECTION - 4

PRELIMINARY HAZARD ANALYSIS

4.1 TYPES OF ACCIDENTS

The Causes for accidents could be as follows:

• Natural : Storm, Wind, Flood, Earthquake ,Lightening

• Deliberate : Sabotage, Civil Commotion

• Unsafe Acts

and

Situations

:

Corrosion, Equipment failure, Design deficiency

, Abnormalities in operation or maintenance,

Fire / Emergency in neighborhood

When an emergency becomes uncontrollable and leads to damage to life and property

in the industry and its neighborhood, it may be defined as a disaster.

4.2 SYSTEM ELEMENTS OR EVENTS THAT CAN LEAD TO A MAJOR

HAZARD

At the Site Disaster could be of the following type,

• Fire / Explosion

• Large Spillage of hazardous chemicals.

• Release of flammable or gas resulting in fire, explosion, or gas cloud, and other

forms of air pollution, thermal radiation and smoke.

• Toxic gas release from neighboring factory.

• Overturning of road tanker containing flammable / toxic materials

• Failure of piping containing flammable / toxic materials

• Fall of structure or building.

• Release of high velocity fragments of ruptured equipments due to overpressure

conditions.

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4.3 HAZARDS

By virtue of the hazardous chemicals stored and handled at site the site operations

have potential for fire, explosion and health hazard. Solvent storage and handling are

considered as an area for hazards at site.

4.4 SAFETY RELEVANT COMPONENTS

Pressure : PG , SRVs ,Interlocks & Alarm

Fire : Fire Hydrant System, Fire Extinguishers

Spill : LI , Dyke , Interlocks, Spare Capacity , Pumping Arrangement

, ETP

Dyke wall of storage tank should be kept closed and locked.

During monsoon check water quality then discharge to ETP.

Gas release : Hydrogen Gas Leak Detectors, SCBA.

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SECTION - 5

IDENTIFICATION OF SITE

5.1 SITE ACTIVITY:

5.1.1. MANUFACTURING OF FOLLOWING PRODUCTS.

LIST OF PRODUCTS

Sr.No. Name of Product Maximum Qty Hazards

01 Para Cumidine or 3 Amino

Benzotri Fluoride (3ABTF) 200 MT/M Corrosive & Harmful

02 Ortho Anisidine or Tri Methyl

Hydro Quinine 50 MT/M

Poison & Environmentally

Hazardous

03

2:4 Xylidine & 2:6 Xylidine or 2,3 Xylidine and 3,4 Xylidine or

2,5 Xylidine and 2,3 Xylenol or

2,4 and 2,5 Xylenol

250MT/M Poison

04 Diphenyl Amine Derivatives 50 MT/M. Poison

05

Crystalline Diethyl Meta Amino

Phenol

(Cryst. DEMAP ) Or

Di-Butyl Para Phenyl Di-Amine or

3 NAP ( 3 Nitro Aceto phenone)

3AAP ( 3 Amino Acetophenone)

3HAP (3Hydroxy Acetophenone)

40MT/M

Poison

06 TFMAP ( Trifluoromethyl)

acetophenon ) 80 MT/M Poison

07

2 MePPDA (2-Methyl p

Phenylene Diamine sulphate or

1,3 CHD (1,3 Cyclohexanedione)

60 MT/M Poison

08 Pilot Plant product (Synthetic

organic chemicals) 10 MT/M Poison

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5.1.2. MANUFACTURING PROCESS ARE

▪ Nitration

▪ Hydrogenation

▪ Ammonolysis

▪ Condensation

▪ Oxidation

▪ Dehydration

▪ Distillation

5.2 LOCATION OF HAZARDOUS CHEMICALS

Shown in plant lay out. Please refer Annexture No.

5.3 INVENTORY OF THE CHEMICALS (RAW MATERIALS) AND MSDS.

Sr.No Tank No. Name of Material Capacity

1 B-501A Ortho Xylene/ Meta Xylene 15 MT

2 B-6 98% Sulphuric Acid 40 MT

3 B-7 98% Nitric Acid 40 MT

4 UG/ST Toluene 22 MT

5 UG/ST Methanol 22 MT

6 ST-202 DMS 20 MT

7 901C Cumene 75 MT

8 Bags Soda Ash 07 MT

9 Cylinders Hydrogen Gas 5000m3

10 Carboys Hydrogen Peroxide 07 MT

11 Drums TMP 15 MT

12 Drums MEK 10 MT

13 Bags Para Nitro Aniline 10 MT

15 ST-01 & 02 Furnace Oil 45 MT

16 Drums Diesel 2.3 MT

17 ST-201 Caustic Soda Lye 10 MT

18 ST-600 & Drums M-Cresol 32 MT

19 Drums Iso Propyl Alcohol 3.5 MT

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Sr.No Tank No. Name of Material Capacity

20 ST-608 HCL (30%) 10 MT

21 Drums Ethyl Acetate 1.0 MT

22 Drums Liquor Ammonia 5.0 MT

23 Cylinder Ammonia Gas 0.06MT

24 Bags Azodye 30 MT

25 Tank Trichloro Benzene 25 MT

26 Carboys Raney Nickel (catalyst) 0.07 MT

5.4 OCCUPATIONAL HEALTH CENTER (First Aid Center)

We have full fledged Occupational Health Centre equipped with three bed

facility, Medical Oxygen Cylinder, Decontamination system, round the clock

male nurse.

5.5 EMERGENCY CONTROL CENTER:

For the purpose of handling emergency, the following Emergency

Control Center has been identified.

• Emergency Control Room near main gate. (Intercom No.104)

All communications to and from will originate at this control center.

The Emergency Control Center will have the following:-

a) A copy of ON-SITE EMERGENCY PLAN.

b) List of important telephone numbers such as Police, Fire Brigade,

Hospitals, and other outside Emergency Services, etc.

c) List of key Personnel with addresses and telephone numbers.

d ) List of Fire and First Aid Cum Rescue Squad Members

e) Plant layout-indicating storage of hazardous materials

f) Fire Extinguisher etc.

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g) Fire Fighting System (layout of Fire Hydrants), List of Personal

Protective Equipment.

h) Material Safety Data Sheets - M.S.D.S.

i) List of employees with address, telephone numbers, blood groups etc.

j) Torches.

5.6 ASSEMBLY POINT:

Assembly Point– I : Near Main Gate

Assembly Point– II : Near Gate No.02.

Deepak Nitrite Limited Roha Division

On Site Emergency Plan (Disaster Management Plan)

Effective Date : 01.04.2019

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SECTION - 6

HAZARDOUS CHEMICALS

6.1 TITIES AND TOXICOLOGICAL DATA

In the manufacturing operations various flammable / Toxic / Corrosive Material, compressed

gases are utilized. Also the stock of combustible materials is maintained. These items have

potential to lead to accidents involving fire / explosion. The description of hazardous

chemicals handled at the plant site are listed in the following table.

TABLE 1: CHEMICALS HANDLED AT SITE

• Petroleum Class ‘A’ Chemicals :

Sr.

No NAME of Material

NFPA

HAZARD TOXICITY

INDEX LD 50 LC 50 TLV STEL Flash

Pt.[CC]

Nh Nf Nr Mg/kg

Oral –rat Mg/m3 PPM PPM 0C

1 Toluene 2 3 0 3400 100 150 4.5

2 Methanol 1 3 0 5628 200 250 12.2

3 MEK 1 3 0 2737 23500 200 300 -9

4 Isopropyl Alcohol 2 3 0 980 -- 11.6

5 Ethyl Acetate 1 3 0 1400 -- -4.4

• Petroleum Class ‘B’ Chemicals:

Sr.

No NAME of Material

NFPA

HAZARD TOXICITY

INDEX LD 50 LC 50 TLV STEL Flash

Pt.[CC]

Nh Nf N r Mg/kg

Oral –rat Mg/m3 PPM PPM 0C

1 Ortho Xylene 2 3 0 4300 100 150 36

2 Cumene 2 3 0 1400 75 36

3 Meta Xylene 2 3 0 5000 100 150 29.4

4 Diesel - - - - - - - -

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• Petroleum Class ‘C’ Chemicals:

• Corrosive , Oxidizing and Other Hazardous Chemicals

Sr. No. NAME of Material

NFPA HAZARD TOXICITY

INDEX LD 50 LC 50 TLV STEL Flash

Pt.[CC]

Nh Nf N r Mg/kg

Oral –rat Mg/m3 PPM PPM 0C

1 98% Sulphuric Acid 3 0 2 2140 -- -- 1 NA

2 98% Nitric Acid 3 0 -- -- 67 2 4 NA

3 Soda Ash 3 0 1 -- -- -- -- NA

4 Hydrogen Gas 0 4 0 -- -- -- -- NA

5 Hydrogen Peroxide 3 0 1 -- -- 1 -- NA

6 TMP -- -- -- -- -- --

7 Para Nitro Aniline -- -- -- -- -- -- -- --

8 Caustic Soda Lye 3 0 1 -- -- 2 -- --

9 HCL 30% -- -- -- -- -- 7 -- --

10 Liquor Ammonia -- -- -- 350 -- 25 35 --

11 Ammonia Gas -- -- -- -- -- 25 35 --

12 Chloro Benzene -- -- -- -- -- 75 -- --

13 Trichloro Benzene -- -- -- -- -- -- -- 105

14 Raney Nickel -- -- -- -- -- -- --

15 Coal -- -- --

National Fire Protection Association (NFPA)

HAZARD INDEX: N h - Health, N f - Highly flammable, N r-Reactivity

Sr. No. NAME of Material

NFPA HAZARD TOXICITY

INDEX LD 50 LC 50 TLV STEL Flash

Pt.[CC]

Nh Nf N r Mg/kg

Oral –rat Mg/m3 PPM PPM 0C

1 DMS 4 2 1 106.4 45 83

2 Furnace Oil 1 2 0 -- -- 78

3 M-Cresol 3 1 0 86

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Section - 7

LIKELY DANGERS TO THE PLANT 7.1 IDENTIFICATION OF HAZARDOUS/ FLAMMABLE AREAS

HAZARD AREA PROBABLE CAUSE OF THE ACCIDENT

Explosion

Hydrogenation / Boilers / Transformers

/Thermopac/Laboratory (due to Hydrogen)

Malfunctioning of the Safety Valve/

formation of flammable mixture, rupture of

line.

Flammable / Petroleum product storage

tank / drum storage shed

External fire causing pressure built up in

the tanks / barrels

Fire

H.S.D. / FO Storage Area. Flammable vapour / air mixture and source

of ignition.

Flammable /Petroleum product storage

tank / drum storage shed/ DG / Boiler

Formation on pool in the dyke wall and

source of ignition.

External fire → Built up of internal

pressure → Failure of the top cover of

tank.

Spillage Acid / alkali storage area/ manufacturing

area

Spillage of acid / alkali due to rupture of

the pipe line, collapse of the storage tank

7.2 STRESS AND STRAIN DURING NORMAL OPERATION

Following accidents events are considered for consequence analysis.

Case1: Continuous release of Hydrogen gas from truck or Hydrogen Generation

Plant due to failure of piping / valve.

Case 2 : Overflow of flammable / corrosive liquid.

Case 3 : Spill by transfer hose / pipeline failure.

Case 4 : Gasket failure, pipe line rupture.

Case 5 : Catastrophic failure of reactor / storage tank.

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7.3 CREDIBLE SCENARIO

7.3.1 PROCESS : NITRATION

PLANT : CONTINUOUS NITRATION

SAFETY AND EMERGENCY PROCEDURES:

Case Dos

Power Failure during the Reaction

• DG of 500 & 750 KVA takes care

during the power failure.

1. DCS has power back up for at least half an hour.

2. Ensure the DG power supply is ON.(DG auto starts

within 05 min. after power failure)

3. If it is not ON, immediately contact Engg. Dept. to start

the DG.

8 4. After getting power supply check all process

9 parameter are within limit and process is going

10 on safely.

MSEDCL Power failure for a prolonged

time due to breakdown

(MSEDCL H.T.Power Supply:22 KV)

• DG of 500 & 750 KVA takes care

during the power failure

• Coverage:All Equipments

1. DCS has power back up for atleast half an hour.

2. Ensure the DG power supply is ON.(DG auto starts

within 05 min. after power failure)

3. If it is not ON, immediately contact Engg. Dept. to start

the DG.

4. After getting power supply check all process parameter

are within limit and process is going on safely.

5. Ensure continuous D.G.power supply till MSEDCL

power is available.

Reaction temperature exceeds the limit

during the reaction

1. Process will stop automatically through DCS.

2. Monitor the required parameters.

3. Check utility parameters.

Leakages observed to the Reactor 1. Stop Reaction.

2. Do displacement by spent acid.

3. Do the Rectification activities.

4. Avoid spark generation activities.

Run Away Reaction 1. Process will stop automatically through DCS.

2. Inform to superior immediately.

3. Dump the total process mass in B-8 tank.

4. Check utility parameters.

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Case Dos

Fire 1. Stop total process activity.

2. Inform to superior immediately.

3. If small fire try to extinguish by fire extinguisher.

4. Isolate the power supply.

5. Act as per on site emergency plan.

Spillage 1. Inform to superior immediately.

2. Wear appropriate Personal Protective Equipments.

3. Contain the spilled material by using sand or inert

material.

4. Prevent material entering in the storm water gutter.

5. Use non-sparking tool.

6. Collect spilled material in drums or tank.

7. Decontaminate affected area with plenty of water.

8. Report ETP Operator and SHE Dept.

9. Transfer contaminated water to ETP after checking of

quality.

7.3.2 PROCESS : HYDROGENATION

PLANT : HYDROGENATION PLANT

SAFETY AND EMERGENCY PROCEDURES:

Case Dos

Power Failure during the Reaction

• DG of 500 & 750 KVA takes care

during the power failure.

1. 1.DCS has power back up for atleast half an hour.

2. Ensure the DG power supply is ON.(DG auto starts

within 05 min. after power failure)

3. If it is not ON, immediately contact Engg. Dept. to

start the DG.

4. 4. After getting power supply check all process

parameter are within limit and process is going on

safely.

MSEDCL Power failure for a prolonged

time due to breakdown

(MSEDCL H.T.Power Supply:22 KV)

• DG of 500 & 750 KVA takes care

during the power failure.

• Coverage:All Equipments

1. 1 DCS has power back up for atleast half an hour.

2. Ensure the DG power supply is ON.(DG auto starts

within 05 min. after power failure)

3. If it is not ON, immediately contact Engg. Dept. to

start the DG.

4. After getting power supply check all process

parameter are within limit and process is going on

safely.

5. 5. Ensure continuous D.G.power supply till MSEDCL

power is available.

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Case Dos

Reaction temperature or pressure exceeds

the limit during the reaction

1. Process will stop automatically through DCS.

2. Inform to superior immediately.

3. Monitor the required parameters.

4. Check utility parameters

5. Check cause of temperature or pressure rise.

Leakages observed to the Reactor 1. Stop Reaction.

2. Cool the reactor to Room Temp.

3. Keep under Nitrogen blanketing.

4. Inform to superior immediately.

5. Avoid spark generation activities.

6. Do the Rectification activities.

Run Away Reaction 1. Process will stop automatically through DCS.

2. Inform to superior immediately.

3. Act as per On Site Emergency Plan.

Fire 1. Stop Hydrogen passing.

2. Inform to superior immediately.

3. If small fire try to extinguish by fire extinguisher.

4. Isolate the power supply.

5. Act as per On Site Emergency Plan.

Spillage 1. Inform to superior immediately.

2. Wear appropriate Personal Protective Equipments.

3. Contain the spilled material by using sand or inert

material.

4. Prevent material entering in the storm water gutter.

6. Use non sparking tool.

7. Collect spilled material in drums or tank.

8. Decontaminate affected area with plenty of water.

9. Report ETP Operator and SHE Dept.

10. Transfer contaminated water to ETP after checking

quality.

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7.3.3 PROCESS: Condensation

PLANT: CF 1950

SAFETY AND EMERGENCY PROCEDURES:

Case Dos

Power Failure during the Reaction

• DG of 500 & 750 KVA takes care

during the power failure.

1. Ensure the DG power supply is ON.(DG auto starts

within 15 sec after power failure)

2. If it is not ON, immediately contact Engg. Dept. to

start the DG.

3. After getting power supply check all process

parameters are within limit and process is going on

safely.

MSEDCL Power failure for a prolonged

time due to breakdown

(MSEDCL H.T.Power Supply:22 KV)

• DG of 500 & 750 KVA takes care

during the power failure.

• Coverage:All Equipments

1. Ensure the DG power supply is ON.(DG auto starts

within 15 sec after power failure)

2. If it is not ON, immediately contact Engg. Dept. to start

the DG.

3. After getting power supply check all process

parameters are within limit and process is going on

safely.

4. Ensure continuous D.G.power supply till MSEDCL

power is available.

Reaction temperature exceeds the limit

during the reaction

1. Stop charging immediately.

2. Apply cooling.

3. Inform to superior immediately.

4. Monitor the required parameters.

5. Check utility parameters

6. Check cause of temperature.

Leakage observed to the Reactor 1. Stop Reaction

2. Cool the reactor to Room Temp. & make appropriate

arrangement to unload the reaction mass

3. Inform to superior immediately.

4. Use necessary PPEs

5. Avoid spark generation activities.

6. Do the Rectification activities.

Fire 1. Stop process immediately.

2. Inform to superior immediately.

3. If small fire try to extinguish by fire extinguisher.

4. Isolate the power supply.

5. Act as per On Site Emergency Plan.

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Case Dos

Spillage 1. Inform to superior immediately.

2. Wear appropriate Personal Protective Equipments.

3. Contain the spilled material by using sand or inert

material.

4. Prevent material entering in the storm water gutter.

5. Use non-sparking tool.

6. Collect spilled material in drums or tank.

7. Decontaminate affected area with plenty of water.

8. Report ETP Operator and SHE Dept.

9. Transfer contaminated water to ETP after checking of

quality.

7.3.4 PROCESS : OXIDATION

PLANT : CF-1950

SAFETY AND EMERGENCY PROCEDURES:

Case Dos

Power failure for short time.

• DG of 500 &750 KVA takes care

during the power failure.

1. Ensure the DG power supply is ON.(DG auto starts

within 15 sec after power failure)

2. If it is not ON, immediately contact Engg. Dept. to start

the DG.

3. After getting power supply check all process

parameters are within limit and process is going on

safely.

MSEDCL Power failure for a proponed

time due to breakdown.

(MSEDCL H.T.Power Supply:22 KV)

• DG of 500 & 750 KVA takes care

during the power failure.

• Coverage:All Equipments

1. Ensure the DG power supply is ON.(DG auto starts

within 15 sec after power failure)

2. If it is not ON, immediately contact Engg. Dept. to start

the DG.

3. After getting power supply check all process

parameters are within limit and process is going on

safely.

4. Ensure continuous D.G.power supply till MSEDCL

power is available.

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Case Dos

Reaction temperature exceeds the limit

during the reaction

1. Stop charging immediately.

2. Apply cooling.

3. Inform to superior immediately.

4. Monitor the required parameters.

5. Check utility parameters

6. Check cause of temperature exceeds.

Leakage observed to the Reactor 1. Stop Reaction

2. Inform to superior immediately.

3. Cool the reaction mass to Room Temp. & make

appropriate arrangement to unload the reaction mass.

4. Use necessary PPEs

5. Avoid spark generation activities.

6. Do the Rectification activities.

Run away reaction 1. Stop charging and agitation immediately.

2. Inform to superior immediately.

3. If possible apply cooling.

4. Act as per On Site Emergency Plan. Fire 1. Stop process immediately.

2. Inform to superior immediately.

3. If small fire try to extinguish by fire extinguisher.

4. Isolate the power supply.

5. Act as per On Site Emergency Plan. Spillage 1. Inform to superior immediately.

2. Wear appropriate Personal Protective Equipments.

3. Contain the spilled material by using sand or inert

material.

4. Prevent material entering in the storm water gutter.

5. Use non-sparking tool.

6. Collect spilled material in drums or tank.

7. Decontaminate affected area with plenty of water.

8. Report ETP Operator and SHE Dept.

9. Transfer contaminated water to ETP after checking of

quality.

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7.3.5 PROCESS : DISTILLATION

PLANT : DISTILLATION COLUMN

SAFETY AND EMERGENCY PROCEDURES:

Case Dos

Power failure for short time.

• DG of 500 & 750 KVA takes care

during the power failure

1. DCS has power back up for atleast half an hour.

2. Vacuum will lock automatically through DCS.

3. Ensure the DG power supply is ON.(DG auto starts

within 15 sec after power failure)

4. If it is not ON, immediately contact Engg. Dept. to

start the DG.

5. After getting power supply check all process parameter

are within limit and process is going on safely.

MSEDCL Power failure for a prolon-

ged time due to breakdown.

(MSEDCL H.T.Power Supply:22 KV)

• DG of 500 & 750 KVA takes care

during the power failure.

• Coverage:All Equipments

1. DCS has power back up for atleast half an hour.

2. Vacuum will lock automatically through DCS.

3. Ensure the DG power supply is ON.(DG auto starts

within 15 sec after power failure)

4. If it is not ON, immediately contact Engg. Dept. to

start the DG.

5. After getting power supply check all process

parameter are within limit and process is going on

safely.

6. Ensure continuous D.G.power supply till MSEDCL

power is available. Fire 1. Stop process immediately.

2. Inform to superior immediately.

3. If small fire try to extinguish by fire extinguisher.

4. Isolate the power supply.

5. Act as per On Site Emergency Plan. Spillage 1. Inform to superior immediately.

2. Wears appropriate Personal Protective Equipments.

3. Contain the spilled material by using sand or inert

material.

4. Prevent material entering in the storm water gutter.

5. Use non-sparking tool.

6. Collect spilled material in drums or tank.

7. Decontaminate affected area with plenty of water.

8. Report ETP Operator and SHE Dept.

9. Transfer contaminated water to ETP after checking of

quality.

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7.3.6 CYCLONE

SAFETY AND EMERGENCY PROCEDURES:

Case Dos

Cyclone 1. Inform to superior immediately.

2. Do not listen to or spread rumours-Follow the

instruction of superior only.

3. Take latest weather warnings from nearest Metrological

office.

4. Don’t stay under suspended shade.

5. Stay on open area.

6. Take all process operation in safe mode.

7. Switch off electrical supply if necessary.

8. Ensure safety of other plants and people.

9. Act as per On Site Emergency Plan.

10. Do not be Panicky.

7.3.7 FLOODING

SAFETY AND EMERGENCY PROCEDURES :

Case Dos

Flooding 1. Inform to superior immediately.

2. Take latest weather warnings from nearest

Metrological office.

3. Inform to Site Main Controller immediately.

4. Follow the instruction of Site Main Controller.

5. Take all process operation in safe mode.

6. Switch off electrical supply if necessary.

7. Ensure safety of other plants and people.

8. Don’t enter into the flood water.

9. Stay away from electric poles and fallen power lines.

10. Stay away from gutters or drains etc.

11. Keep Personal Protective Equipments available.

12. Act as per On Site Emergency Plan.

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7.3.8 EARTH QUAKE

SAFETY AND EMERGENCY PROCEDURES:

Case Dos

Earthquake 1. Inform to superior immediately.

2. Do not listen to or spread rumours-Follow the

instruction of superior only.

3. Take cover under a stand by desk or table.

4. Take latest weather warnings from nearest

Metrological office.

5. Don’t stay under suspended shade or material.

6. Stay on open area.

7. If possible take all process operation in safe mode.

8. Switch off electrical supply if necessary.

9. Do not be Panicky.

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SECTION - 8

DETAILS OF SAFETY SYSTEMS

8.1 HAZARD CONTROL PLAN

(In line with Emergency Control and hazard control planning, ensuring the necessary

technical and organizational precautions)

8.1.1 ALARM / SIREN

We have total 15 Nos Manual Call Points. In case of any emergency, Manual Call

Point is operated by first observer to declare an emergency.

Location of Manual Call Points are shown on Plot Plan.

Presently there is one siren installed in the factory premises.

CODIFICATION OF SIRENS

Sr. SIRENS INDICATES AUTHORITY

1. 30 Sec. Continuous Shift End Unit Head

2. Siren sound three times at 12

Second frequency interval Emergency Site Main Controller

3. 30 Sec. Continuous Emergency Controlled

(all clear) Site Main Controller

4. Siren sound three times at 12

Second frequency interval and 30

Second Continuous

Testing SHE Head

Presently there is one siren installed in the factory premises as marked on the site plan.

Note:

1. Emergency siren is to be sounded only if required.

2. After hearing emergency siren all plants processes have to bring safe mode

and make evacuation.

3. All employees in areas to proceed to safe assembly point.

4. No emergency organization member will leave the emergency spot unless `all

clear’ siren blown.

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8.1.3 TESTING OF ALARM

Every Friday at 11.00 Hrs wailing pitch and continuous siren will be sounded for

testing. Continuous siren will be sounded for shift purpose also. Emergency siren is

located at DEMAP Plant building as marked on the site plan.

On hearing alarm the Incident Controller will activate the action on disaster control

plan by giving proper instructions or predetermined signals.

8.1.4 SAFETY SYSTEM

We have hydrogen gas detector, flameproof electrical system, earthing and bonding,

lightening arrester, and flame arrester and scrubber system to prevent hazard.

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SECTION - 9

COMMUNICATION FACILITIES

PAS (Public Address System): NA

Intercom (system): Given below

9.2 IMPORTANT TELEPHONE NUMBERS : EMERGENCY SERVICES

SN Service Description Telephone no.

1. POLICE Superintend of police, Alibag 02141 – 222001( O)

- 222081(O)

- 222002 (R)

- 222086 (R )

Dep. Superintend of police, Roha 234933

Police Station, MIDC ---

2. INSPECTOR OF

FACTORIES

Inspector of factory, Mumbai

022- 27578587

3. FIRE BRIGADE MIDC

101 / 263600

4. HOSPITAL Dr.Mrs Wagale Hospital,Roha

Civil Hospital,Roha

Dr,Dhruv Hospital

235079

234656

263218

5. AMBULANCE Excel Industries

Sudarshan Chemical Ind.

263708

263531

6. SURGEON Civil Surgeon, Alibag 02141- 222017/222157

6. MIDC Roha 263825

7 MSEDCL (MSEB) MIDC Area 263618, 263634

8 MPCB SRO Office MPCB 022-27576034

9.3 HEAD OFFICE

Sr.

No. Name Designation

Phone Nos.

Office Mobile

Number

1. Mr.Umesh Asikar Occupier 0265-2840639/ 40

2. Mr. Saiprasad Jadhav V.P.Operations 0265-2840639/ 40

3. Mr.Nilesh Dave V.P.HR 0265-2765200

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9.4 KEY PERSONNEL OF THE FACTORY AND THEIR CONTACT NUMBERS

NAME Designation Intercom Mobile Number

Mr. Sunil Desai GM-Manufacturing 102 9881490489

Mr. G.A.Deshpande Chief Manager –EHS 115 9404263356

Mr. Shivanand Kalagi Site Head 127 9130024344

Mr. Nitin Dhangade Sr. Manager-HR 103 7875041717

Mr. K.S. Gogate Sr.Manager. – Engineering 110 9130024384

Mr. M.T.Singh Sr.Manager – QC/QA 117 9130024386

Mr. Sandesh Kapse Manager – Material 113 9503883047

Mr. S P.Tandel Manager - SHE 115 9130024385

Mr. Gaurav E. Patil Dy.Manager - SHE 147 8275411493

Mr. M.J.Patel Dy.Manager – Production 136 9130024392

Mr. A.P.Kolhe Dy.Manager – Production 129 9130024395

Mr. P.P.Kulkarni Dy.Manager – Production 132 9130024387

HOSPITALS

There is adequate arrangement with local hospitals for any medical emergency.

Sr.No. Name of Hospital Phone No. Bed Facility

1. DR. DHRUV HOSPITAL,

VARSE-ROHA 263218, 263228 15

2. DR. DEVENDRA JADHAV

(EYE SPECIALIST) 233435 10

3. JHADHAV NURSING HOME

DAMKHADI-ROHA 233232 12

4. BHAT NURSING HOME,

BHUVANESHWAR-ROHA 234672 10

5. WAGLE NURSING HOME

NEAR S.G.HOSPITAL 235073, 234090 10

6. DR. GUDSURKAR

(EYE SPECIALIST) 233051 Not Available

7. CIVIL HOSPITAL 234656 15

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SECTION - 10

FIRE FIGHTING RESOURCES

10.1 FIRE EXTINGUISHERS

Fire extinguishers for emergency, located at strategic positions at each process floor,

storage areas, security office etc. The same are easily accessible, marked properly,

and maintained regularly.

Sr.No. Type of Fire Extinguishers Qty in Nos

1 Dry Chemical Powder 83

2 Mechanical Foam 24

3 Chemical Foam 28

4 Carbon Dioxide 41

Total 176

10.2 FIRE HYDRANT SYSTEM :

➢ The detailed diagram showing the hydrant system is given in annexure.

➢ Fire Hydrant System designed as per guidelines by Tariff Advisory

Committee.

➢ Static water tank of 2 x 300 M3 = 600 cubic meters capacity

➢ There are 40 hydrant points with hose boxes with Nos. hoses.

➢ Fire hydrant pumps : Electric Driven - 171 M3/hour at 7 kg./cm2 - 1 No;

Jockey Pump –10.8 M3/hour at 7 kg./cm2 - 1 No. and Diesel Engine

Pump-171 M3/hour at 7 kg./cm2 - 1 No.

➢ 500 KVA DG System ensures that the hydrant pump is kept working.

➢ 02 Nos.Fire tenders are available at MIDC fire station.

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10.4 LIST OF PERSONEL PROTECTIVE EQUIPMENTS

Sr. NO. ITEM Sr No. ITEM

1 Safety Helmet 11 PVC Dust Mask

2 Safety Goggles 12 Cotton Dust Mask

3 Safety Shoes 13 Eye Wash Fountain

4 Rainy Shoes 14 On Line Respirator Hood

5 Gum Boots 15 Full Face Gas Mask

6 PVC Apron 16 Organic Vapour Mask

7 Leather Hand Gloves 17 Self Contained Breathing Apparatus

8 Rubber Hand Gloves 18 Half Line Gas/ Organic Vapour Mask

9 Electrical Hand Gloves 19 PVC Back Open Coat

15 Safety Belt

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10.5 LIST OF FIRE FIGHTING TEAM

LIST OF FIRE FIGHTING CUM SPILL CONTROL TEAM

1 MR.ANAND TEMKAR

2 MR.L.D.PATIL

3 MR.S.M.TALEGAONKAR

4 MR.MANOJ JUIKAR

5 MR.V.S.MARWADE

6 MR.BHARAT SALUNKE

7 MR.T.H.SHELKE

8 MR. S.N.GORIWALE

9 MR.M.C.JANGAM

10 MR.D.S.SHINDE

11 MR.SUNIL SALVI

12 MR.MAHESH MHASKAR

13 MR.M.D.KAPSE

14 MR.VINAY THAKUR

15 MR.S.N.BERDE

16 MR.P.M.PATIL

17 MR.B.V.PAWAR

18 MR.S.S.SHIGWAN

19 MR.SANJAY SANAP

20 MR.J.V.DHANAK

21 MR.VITTHAL BHOKTE

22 MR.R.S.SANAP

23 MR.NITIN JADHAV

24 MR.U.D.GHANEKAR

25 MR.H.M.TELANGE

Sr.No. Name of Fire Fighting Cum Spill Control Team

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Sr.No. Name of Fire Fighting Cum Spill Control Team

26 MR.S.R.VARPE

27 MR.KADAM MAHESH

28 MR.SANJAY KONDE

29 MR.V.G.PATIL

30 MR.K.K.ASWAR

31 MR.RAJU KONDE

32 MR.P.P.POTHPHODE

33 MR.R.V.GOLE

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SECTION - 11

MEDICAL FACILITIES

11.1 OCCUPATIONAL HEALTH CENTRE

We have full fledged Occupational Health Centre equipped with 03 male nurse round

the clock.

11.2 LIST OF RESCUE /FIRST AID TEAM

List of First Aider Cum Rescue Team

Sr.No. Name of First Aider Cum Rescue Team

1 Mr. A. N. Temkar

2 Mr. Anil Mohite

3 Mr. S. D. Khandekar

4 Mr. S. M. Malusare

5 Mr. R. N. More

6 Mr. N. V. Mhatre

7 Mr. Pundalik Mahadik

8 Mr. Sandip Jadhav

9 Mr. S. M. Kale

10 Mr. Sunil Salvi

11 Mr. Ashok N. Gaikar

12 Mr. Sachin Munde

13 Mr. M. M. Bhagat

14 Mr. Satish Deshmukh

15 Mr. K. R. Alatekar

16 Mr. R. L. Dandekar

17 Mr. A. E. Sanap

18 Mr. Mangesh Chalke

19 Mr. S. V. Narkhede

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20 Mr. C. D. Deshmukh

21 Mr. M. V. Lokhande

22 Mr. S.P.Tandel

23 Mr. V. K. Singh

24 Mr. G. B. Mane

25 Mr. G. K. Thakur

26 Mr. G. P. Dhondge

27 Mr. V. H. Thakur

28 Mr. Rajesh Deshmukh

29 Mr. Sharad G. Pawar

30 Miss. Karishma Vichare

11.3 COMPANY DOCTOR

A qualified doctor is appointed on part time basis.

Dr. Mrs. Minal Wagale (M.B.B.S.; A.F.I.H)

11.4 ANTODOTES

Antidotes e.g. Methylene Blue and Anti Snake Venum are available at Occupational

Health Center.

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SECTION - 12

POST EMERGENCY SYSTEM

After emergency, recovery operation will be carried out by Spill Control Team under

guidance Incident Controller and SHE Team.

Team will take round of all affected area affected during emergency.

Following checks will carried out during inspection:

1) Check out generation of hazardous waste due to fire or spillage.

2) Check for spills. In the event of a major disaster, the SHE Head following the leanup

should insure decontamination of equipment, buildings, and grounds of the plant and

surrounding areas and the replacement of emergency supplies at all designated

locations.

3) In case of spills or leakage of hazardous material/waste, cleanup should begin

immediately. If a container is leaking, material should be transferred to a second

clean, secure container and the damaged container discarded. For spills of hazardous

material/waste, appropriate absorbent material (cloth towels, vermiculite, sand, lime,

sodium bicarbonate, or hydro-choric acid) should be utilized to contain and or

neutralize the spill and the resulting material packaged, collected, and labeled for

disposal as hazardous waste, if necessary and send to authorized disposal party as

MWML. For transferring material make arrangement of Diesel pump.

4) Inform to ETP operator/HSE officer about the leakage.

5) Check out property damage.

6) Check out any injury during emergency.

7) Check out any off site damage.

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8) Make proper disposal of contaminated water by bunding to avoid entry of polluted

water in storm water.

9) Collected materials try to collect in drums or tank.

10) Make proper packing of any hazardous solid waste which is generated during

emergency.

11) SHE department will clean up or stabilize spills which are considered high hazard

12) Emergency resources are replenished and/or re-commissioned following an

emergency

13) Emergency team members are debriefed post incident.

14) Post-incident recording and reporting is completed and meets organizational

requirements.

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List of Fire Fighting Cum Spill Control Team and List of First Aider Cum Rescue

Team

Sr. No. Name of Fire Fighting Cum Spill

Control Team

Sr.

No.

Name of First Aider Cum Rescue

Team

1 MR ANAND TEMKAR 1 Mr. A. N. Temkar

2 MR.L.D.PATIL 2 Mr. Anil Mohite

3 MR.S.M.TALEGAONKAR 3 Mr. S. D. Khandekar

4 MR.MANOJ JUIKAR 4 Mr. S. M. Malusare

5 MR.V.S.MARWADE 5 Mr. R. N. More

6 MR.BHARAT SALUNKE 6 Mr. N. V. Mhatre

7 MR.T.H.SHELKE 7 Mr. Pundalik Mahadik

8 MR. S.N.GORIWALE 8 Mr. Sandip Jadhav

9 MR.M.C.JANGAM 9 Mr. S. M. Kale

10 MR.D.S.SHINDE 10 Mr. Sunil Salvi

11 MR.SUNIL SALVI 11 Mr. Ganesh Salunkhe

12 MR.MAHESH MHASKAR 12 Mr. Sachin Munde

13 MR.M.D.KAPSE 13 Mr. M. M. Bhagat

14 MR.VINAY THAKUR 14 Mr. Satish Deshmukh

15 MR.S.N.BERDE 15 Mr. K. R. Alatekar

16 MR.P.M.PATIL 16 Mr. R. L. Dandekar

17 MR.B.V.PAWAR 17 Mr. A. E. Sanap

18 MR.S.S.SHIGWAN 18 Mr. Mangesh Chalke

19 MR. DILIP DESHMUKH 19 Mr. S. V. Narkhede

20 MR.J.V.DHANAK 20 Mr. C. D. Deshmukh

21 MR.VITTHAL BHOKTE 21 Mr. M. V. Lokhande

22 MR.R.S.SANAP 22 Mr. S.P.Tandel

23 MR.NITIN JADHAV 23 Mr. J. B . Mhaske

24 MR.U.D.GHANEKAR 24 Mr. Rohit Bhoir

25 MR.H.M.TELANGE 25 Mr. Asif Shikalgar

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26 MR.S.R.VARPE 26 Mr. Indrajeet Gonjari

27 MR.KADAM MAHESH 27 Mr. G. B. Mane

28 MR.SANJAY KONDE 28 Mr. G. K. Thakur

29 MR.V.G.PATIL 29 Mr. G. P. Dhondge

30 MR.K.K.ASWAR 30 Mr. V. H. Thakur

31 MR. RAJU KONDE 31 Mr. Rajesh Deshmukh

32. MR.VAIBHAV SATVE. 32 Mr Prashant Pore

33. MR. M .S . HEMBRAM 33. Mr. Rouf Ali