DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.

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DC Polarography – Dropping Hg electrode (DM

Transcript of DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.

Page 1: DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.

DC Polarography – Dropping Hg electrode (DME)

Page 2: DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.

http://www.ceb.cam.ac.uk/data/images/groups/CREST/Teaching/hydro/fig1.gif

First analytically reproducible electrode, quantitiative metal ion and organic analysis

http://www.ceb.cam.ac.uk/data/images/groups/CREST/Teaching/hydro/fig1.gif
http://www.ceb.cam.ac.uk/data/images/groups/CREST/Teaching/hydro/fig1.gif
Page 3: DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.
Page 4: DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.

Prof. Jaraslov Heyrovsky, Charles Univ., Prague, Czech Republic,Nobel Prize in Chemistry 1959 for discovery of Polarography

Prof. Petr Zuman, Clarkson Univ.Heyrovsky’s PhD student and my advisor, “scientific grandpa” to some of you!

Page 5: DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.

Modern 3-electrode potentiostat

Voltage follower

Output, I vs. ETo computer

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Counter reference working

Counter

working

= I Rcell

I Ru

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Steady state I-E methods• dc polarogrpahy• rotating disk voltammetry• square wave voltammetry

Square wave input

Page 8: DC Polarography – Dropping Hg electrode (DME). hydro/fig1.gif First analytically reproducible.

Steady state voltammetry methods

IL

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Staircase input waveforms are used to approximate linear scans


1.3Evaluating Limits Analytically

1.3Evaluating Limits Analytically

Pulse Polarography and Voltammetry with an Automated ...psasir.upm.edu.my/.../Different~al_Pulse_Polarography_and_Voltam… · Differentz"al pulse polarography usz"ng an automated,

Pulse Polarography and Voltammetry with an Automated ...psasir.upm.edu.my/.../Different~al_Pulse_Polarography_and_Voltam… · Differentz"al pulse polarography usz"ng an automated,

Polarography - ETH Zanalytik.ethz.ch/praktika/phys_anal/POL/Anleitung_ENG.pdf · Polarography 1. Introduction ... Its only role is to act as a reference in measuring and controlling

Polarography - ETH Zanalytik.ethz.ch/praktika/phys_anal/POL/Anleitung_ENG.pdf · Polarography 1. Introduction ... Its only role is to act as a reference in measuring and controlling

The trends of polarography - nobelprize.org · TRENDS OF POLAROGRAPHY 567 is the most exact electrochemical law announced since Faraday’s laws in 1833. When corrected for spherical

The trends of polarography - nobelprize.org · TRENDS OF POLAROGRAPHY 567 is the most exact electrochemical law announced since Faraday’s laws in 1833. When corrected for spherical

Polarography - ETH Z

Polarography - ETH Z

Polarography of aluminium (III) in the presence of ...chempap.org/file_access.php?file=274a437.pdf · POLAROGRAPHY OF ALUMINIÜM(III) increases slowly. At 4 equivalents the autocatalytic

Polarography of aluminium (III) in the presence of ...chempap.org/file_access.php?file=274a437.pdf · POLAROGRAPHY OF ALUMINIÜM(III) increases slowly. At 4 equivalents the autocatalytic

GTF205 Voltammetry n Polarography 2014a

GTF205 Voltammetry n Polarography 2014a

Voltammetry and Polarography

Voltammetry and Polarography

Polarography - ZAHNER-Elektrik GmbH & CoKGzahner.de/pdf/polarography_00.pdf · Polarography - 4 - 1. The Main Menu `Polarography` comes up with the main menu shown below. The main

Polarography - ZAHNER-Elektrik GmbH & CoKGzahner.de/pdf/polarography_00.pdf · Polarography - 4 - 1. The Main Menu `Polarography` comes up with the main menu shown below. The main

Application of Oscillographic Polarography Pyrimidines fileapplication of alternating current oscillographic polarography in the photo chemistry of a number of pyrimidines [3—6].

Application of Oscillographic Polarography Pyrimidines fileapplication of alternating current oscillographic polarography in the photo chemistry of a number of pyrimidines [3—6].

Suppl Fig1 1012-10

Suppl Fig1 1012-10

Artisan Technology Group is your source for quality ... · Differential Pulse Voltammetry and Polarography Normal Pulse Voltammetry and Polarography Sampled Current Polarography Square

Artisan Technology Group is your source for quality ... · Differential Pulse Voltammetry and Polarography Normal Pulse Voltammetry and Polarography Sampled Current Polarography Square

Model of Reactant Adsorption in dc Polarography

Model of Reactant Adsorption in dc Polarography

krishnauniversity.ac.inkrishnauniversity.ac.in/Academics/Syllabus/PG Courses...lications of polarography Amperometric titrations Electro catalysis - Fuel cells-Theory of polarography

krishnauniversity.ac.inkrishnauniversity.ac.in/Academics/Syllabus/PG Courses...lications of polarography Amperometric titrations Electro catalysis - Fuel cells-Theory of polarography

COMPUTERIZED KALOUSEK POLAROGRAPHY · Kalousek polarography has rcLeived little attention in recent years [ 11, although Kinard et al. [ 2] outlined important analytical applications

COMPUTERIZED KALOUSEK POLAROGRAPHY · Kalousek polarography has rcLeived little attention in recent years [ 11, although Kinard et al. [ 2] outlined important analytical applications

POLAROGRAPHY - ZAHNER-Elektrik GmbH & CoKGzahner.de/pdf/m_polarography.pdf · `POLAROGRAPHY` comes up with the main menu shown below. The main menu roughly is divided into four sections.

POLAROGRAPHY - ZAHNER-Elektrik GmbH & CoKGzahner.de/pdf/m_polarography.pdf · `POLAROGRAPHY` comes up with the main menu shown below. The main menu roughly is divided into four sections.

Scholars Research Library · polarography, cyclic voltammetry, a.c. polarography and differential pulse polarography in the supporting electrolytes of the pH ranging from 2.0 to 12.0.

Scholars Research Library · polarography, cyclic voltammetry, a.c. polarography and differential pulse polarography in the supporting electrolytes of the pH ranging from 2.0 to 12.0.

Application of Oscillographic Polarography in ... fileapplication of alternating current oscillographic polarography in the inves tigation of the effects of UV irradiation on the deoxyribonucleic

Application of Oscillographic Polarography in ... fileapplication of alternating current oscillographic polarography in the inves tigation of the effects of UV irradiation on the deoxyribonucleic

Adsorption Effects in Polarography of Berberine

Adsorption Effects in Polarography of Berberine

Polarography of transition metal complexes€¦ · Since the polarography of the NO group is complicated by pH variations, it would seem promising to consider the polarography of

Polarography of transition metal complexes€¦ · Since the polarography of the NO group is complicated by pH variations, it would seem promising to consider the polarography of