Crystal Intro
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Transcript of Crystal Intro
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 1/13
Crystallography
Gypsum Monoclinic
Dolomite Triclinic
Emerald Hexagonal
AndalusiteOrthorhombic
Garnet Isometric
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 2/13
Symmetry Symbols Reflection (m)! produced by a mirror
plane that passes through a crystalstructure so the pattern on one side is amirror image o" the pattern on the other#
$symmetry o%er a plane&
' Ho( many mirror planes
do these crystals ha%e)
*oth ha%e +,
So notation is +m
7/24/2019 Crystal Intro
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Rotation (A)! rotational symmetry in%ol%esrepeating a moti" by a set o" uni"orm rotationsaround an axis# $symmetry about an axis& ' -epeating the pattern e%ery ./01 o" rotation means +!
"old symmetry#
' E%ery 201 3 2!"old symmetry
' Denoted as 4Ax
(here x3x "old rotational symmetry
Orthorhombic! + axes o" /!"old symmetry5 so
notation is +A/
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 4/13
More rotation
examples
(((#tulane#edu67sanelson
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 5/13
In%ersion $i&! also 8no(n as centersymmetry# Any line dra(n through the
origin (ill "ind identical "eaturese9uidistant "rom the origin on the oppositeside#
*oth o" these crystals ha%e center symmetry $i&
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 6/13
-otoin%ersion $:x& ! in%ol%es a rotation andin%ersion to repeat a pattern
' Denoted as 4:x (here x3x "old rotationalsymmetry
' ;ote :. 3 i and :/ 3 m
im +:+
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 7/13
The +/ crystal classes represent the +/possible combinations o" symmetryoperations#
Each crystal class (ill ha%e crystal "acesthat uni9uely de"ine the symmetry o" theclass#
These "aces5 or groups o" "aces are calledcrystal "orms#
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 8/13
;ote that the +/ crystal classes aredi%ided into 2 crystal systems#
The Triclinic System has only .!"old or .!"old rotoin%ersion axes#
The Monoclinic System has only mirrorplane$s& or a single /!"old axis#
The Orthorhombic System has only t(o"old axes or a /!"old axis and / mirrorplanes#
The Tetragonal System has either asingle <!"old or <!"old rotoin%ersion axis#
The Hexagonal System has no <!"oldaxes5 but has at least . 2!"old or +!"oldaxis#
The Isometric System has either < +!"oldaxes or < +!"old rotoin%ersion axes#
7/24/2019 Crystal Intro
http://slidepdf.com/reader/full/crystal-intro 10/13
Symmetry Operation Symmetry Symbol Hermann!Mauguin Symbol
Mirror m m
-otation A.5A/5A+5A<5A2 .5/5+5<52 Axis
-otoin%ersion :.3i5 :/5:+5:<5:2 .5/5+5<52
Axis
!! ! ! !