Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.

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Transcript of Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.

Page 1: Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.
Page 2: Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.
Page 3: Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.
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Crystal Field Theory

Page 6: Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.

Molecular Orbital Theory:Donor- Acceptor Interactions

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Molecular Orbital Theory: Full ML6

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Molecular Orbital Theory: Simplified

Page 9: Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.

Counting d-electron Configurations

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Counting d-electron Configurations

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How do we predict/explain transition metal structures?

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Colors and Spectroscopy of Transition Metal Complexes

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Sigma Interaction Strength

Spectrochemical Series:

I- < Br - < Cl- , F- < OH- < OH2 < NH3 < en < CN- < CO

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Pi Donor Ligands: Mainly oxides and halides

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Mn2+(aq) MnO4 -

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Pi Acceptor Ligands: CO, CN-, pyridine

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Pi Acceptor Ligands and spectroscopy: CO, CN-, pyridine

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Valence Bond Theory and Molecular Orbital Theory.

Valence Bond Theory and Molecular Orbital Theory.

Hybridization and Molecular Orbital (MO) Theory

Hybridization and Molecular Orbital (MO) Theory

Part 2.7: Orbital Diagrams 1. Orbital Diagrams Orbital Interactions Molecular Orbital Theory Orbital Energies MO Diagrams – HF, H 2 O, CO 2, C 2 H 4,

Part 2.7: Orbital Diagrams 1. Orbital Diagrams Orbital Interactions Molecular Orbital Theory Orbital Energies MO Diagrams – HF, H 2 O, CO 2, C 2 H 4,

Molecular Orbital Theory - OpenStax CNXcnx.org/.../molecular-orbital-theory-5.pdfMolecular orbitals are combinations of atomic orbital wave functions. Combining waves can lead to constructive

Molecular Orbital Theory - OpenStax CNXcnx.org/.../molecular-orbital-theory-5.pdfMolecular orbitals are combinations of atomic orbital wave functions. Combining waves can lead to constructive

Inorganic Chemistry Molecular orbital theory

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CHEMISTRY SYLLABUS (2016) - ngbu · Metal -Ligand Bonding Limitation of crystal field theory, molecular orbital theory, octahedral, ... complexes, -bonding and molecular orbital theory.

CHEMISTRY SYLLABUS (2016) - ngbu · Metal -Ligand Bonding Limitation of crystal field theory, molecular orbital theory, octahedral, ... complexes, -bonding and molecular orbital theory.

Molecular Orbital Theory

Molecular Orbital Theory

Bonding III Valence Bond Theory and Molecular Orbital Theory.

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Ab initio molecular orbital theory - UHkarin.fq.uh.cu/qct/Articulos_seminarios_evaluativos/Seminario_2/28... · Vol. 9, 1976 Molecular Orbital Theory Ab Initio Molecular Orbital Theory

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Polyatomic Molecular Orbital Theory

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Chapter 5 Molecular Orbital Theory

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MOLECULAR ORBITAL THEORY OF COORDINATION COMPOUNDS

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Molecular Orbital Theory - cnx.org · OpenStax-CNX module: m51059 3 Molecular orbital theory (MO theory) provides an explanation of chemical bonding that accounts for …

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Introduction to Molecular Orbital Theory

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Section 2 Simple Molecular Orbital Theory

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Molecular orbital calculations (on dinitrogen …CHAPTER ONE. Molecular Orbital Theory 1.1 Introduction 1.2 Molecular Orbital Theory for Closed Shell Molecules 1.3 Configuration Interaction

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Unconventional Approach to Orbital-Free Density … · Unconventional Approach to Orbital-Free Density Functional Theory Derived from a ... theory ·Orbital free density functional

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