CRUDE ASSAY REPORT - Reliance · PDF fileCRUDE ASSAY REPORT JOB NUMBER: 5818/14 SAMPLE NO: C...
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RELIANCE INDUSTRIES LIMITED 26.05.2014 ORIGINAL CRUDE ASSAY REPORT JOB NUMBER: 5818/14 SAMPLE NO: C 20717 REPORT NO: LB 15630 C ( Revision 1 ) ASSAY CONDUCTED FOR : PREPARED AND CHECKED BY: GERARD CHIN SAMPLE DESCRIPTION: RELIANCE CONDENSATE DATE REPORTED: 21.05.2014 DATE REVISED:
Transcript of CRUDE ASSAY REPORT - Reliance · PDF fileCRUDE ASSAY REPORT JOB NUMBER: 5818/14 SAMPLE NO: C...
RELIANCE INDUSTRIES LIMITED
26.05.2014
ORIGINAL
CRUDE ASSAY REPORT
JOB NUMBER: 5818/14
SAMPLE NO: C 20717
REPORT NO: LB 15630 C ( Revision 1 )
ASSAY CONDUCTED FOR :
PREPARED AND CHECKED BY: GERARD CHIN
SAMPLE DESCRIPTION: RELIANCE CONDENSATE
DATE REPORTED: 21.05.2014
DATE REVISED:
26/05/2014 ( Revision 1 ) 1 Reliance Condensate Assay Report
-50.0
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0 10 20 30 40 50 60 70 80 90 100
TE
MP
ER
AT
UR
E (
°C
)
CUMMULATIVE WEIGHT %
TBP & SIMULATED DIST. GRAPH
TRUE BOILING POINT CURVE
SIMULATED DISTILLATION CURVE
SUMMARY OF PRODUCT CUT POINTS AND YIELDS
YIELD ON YIELD ON
CRUDE ( vol. % ) CRUDE ( wt. % )
LPG 9.26 7.82
C5 - 140 Naphtha 83.47 84.09
C5 - 149 Naphtha 85.29 86.07
140 - 155 Naphtha / Kerosene 2.75 2.98
155 - 185 Naphtha / Kerosene 2.70 3.01
149 - 200 Naphtha / Kerosene 4.63 5.15
185 - 200 Kerosene 1.00 1.14
200 + Kerosene Residue 0.82 0.96
CUT POINT ( °C ) PRODUCT
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CUT CUT POINT DENSITY
NUMBER AET METHOD USED WEIGHT WEIGHT % VOLUME at 15 °C
°C gram CUT CUM ml CUT CUM g/cm3
1 LPG ASTM D 2892 860.8 7.82 7.82 1464.1 9.26 9.26 0.5879
2 70 ASTM D 2892 3798.4 34.49 42.31 5756.8 36.43 45.69 0.6598
3 90 ASTM D 2892 944.7 8.58 50.89 1315.0 8.32 54.01 0.7184
4 140 ASTM D 2892 4517.2 41.02 91.90 6119.2 38.72 92.73 0.7382
5 149 ASTM D 2892 218.1 1.98 93.89 287.4 1.82 94.55 0.7589
6 155 ASTM D 2892 110.5 1.00 94.89 145.2 0.93 95.47 0.7611
7 175 ASTM D 2892 216.1 1.96 96.85 278.3 1.77 97.24 0.7764
8 185 ASTM D 2892 115.0 1.04 97.90 146.2 0.93 98.18 0.7866
9 200 ASTM D 2892 126.0 1.14 99.04 157.6 1.00 99.18 0.7996
10 200 + ASTM D 2892 105.4 0.96 100.00 128.6 0.82 100.00 0.8193
WEIGHT OF SAMPLE ( g ) 11012.5
DENSITY @ 15°C OF CHARGE ( g/cm3 ) 0.7017
VOLUME OF CHARGE @ 15°C ( ml ) 15694.0
TRUE BOILING POINT DATA
YIELD % ON CRUDE
VOLUME %
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Boiling Point Cum Yield Boiling Point Cum Yield
( °C ) ( Mass % ) ( °C ) ( Mass % )
IBP -20.6 0.5 51 90.3 51
1 -5.1 1 52 90.5 52
2 -4.2 2 53 91.3 53
3 -3.0 3 54 92.6 54
4 -2.0 4 55 93.0 55
5 -0.3 5 56 94.3 56
6 14.1 6 57 95.3 57
7 14.2 7 58 96.0 58
8 14.5 8 59 99.3 59
9 14.5 9 60 99.9 60
10 14.8 10 61 100.1 61
11 15.2 11 62 100.3 62
12 22.3 12 63 100.4 63
13 22.5 13 64 100.6 64
14 22.6 14 65 100.7 65
15 22.7 15 66 105.7 66
16 22.8 16 67 106.1 67
17 22.9 17 68 106.3 68
18 23.2 18 69 106.5 69
19 23.5 19 70 106.6 70
20 23.7 20 71 106.7 71
21 36.3 21 72 106.8 72
22 50.7 22 73 107.0 73
23 52.2 23 74 107.1 74
24 52.7 24 75 107.5 75
25 53.0 25 76 111.4 76
26 53.2 26 77 115.4 77
27 53.3 27 78 115.9 78
28 54.2 28 79 118.8 79
29 60.0 29 80 119.3 80
30 60.5 30 81 121.1 81
31 69.0 31 82 121.7 82
32 69.4 32 83 122.1 83
33 69.6 33 84 123.6 84
34 69.7 34 85 127.0 85
35 69.8 35 86 127.9 86
36 69.9 36 87 128.1 87
37 70.0 37 88 128.3 88
38 70.1 38 89 135.1 89
39 70.1 39 90 136.2 90
40 70.2 40 91 141.2 91
41 76.7 41 92 143.6 92
42 77.0 42 93 147.4 93
43 77.2 43 94 152.0 94
44 78.0 44 95 154.0 95
45 84.3 45 96 163.5 96
46 87.0 46 97 173.9 97
47 87.3 47 98 189.6 98
48 87.5 48 99 233.1 99
49 87.7 49 100 266.0 99.5
50 89.9 50
SIMULATED DISTILLATION DATA
No No
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NO. COMPOSITION METHOD
WT % ON FRACTION YIELD ( WT ON CRUDE )
1 METHANE GC 0.03 0.29
2 ETHANE GC 0.04 0.38
3 PROPANE GC 0.88 7.60
4 I-BUTANE GC 14.03 120.74
5 N-BUTANE GC 65.22 561.40
7 I-PENTANE GC 10.33 88.92
8 N-PENTANE GC 8.71 74.96
9 HEXANE+ GC 0.72 6.19
10 CARBON DIOXIDE GC 0.03 0.27
LIGHT HYDROCARBON ANALYSIS
RESULTS
LIQUIFIED PETROLEUM GAS
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NAPHTHA (C5 - 140) NAPHTHA (140 - 185)
( WT % ON FRACTION ) ( WT % ON FRACTION )
1 PARAFFINS DHA 60.890 65.802
2 OLEFINS DHA 0.000 0.000
3 NAPHTHENE DHA 33.307 15.916
4 AROMATIC DHA 5.094 9.092
5 HEAVIES DHA 0.000 0.000
6 UNKNOWNS DHA 0.709 9.191
7 TOTAL C3 DHA 0.000 0.000
8 TOTAL C4 DHA 0.065 0.000
9 TOTAL C5 DHA 5.695 0.000
10 TOTAL C6 DHA 25.318 0.007
11 TOTAL C7 DHA 40.792 0.107
12 TOTAL C8 DHA 21.906 0.153
13 TOTAL C9 DHA 3.619 19.878
14 TOTAL C10 DHA 1.657 62.207
15 TOTAL C11 DHA 0.238 8.225
16 TOTAL C11+ DHA 0.000 0.233
17 TOTAL HEAVIES DHA 0.000 0.000
18 TOTAL UNKNOWNS DHA 0.709 9.191
19 C3 PARAFFINS DHA 0.000 0.000
20 C4 PARAFFINS DHA 0.065 0.000
21 C5 PARAFFINS DHA 5.234 0.000
22 C6 PARAFFINS DHA 13.172 0.007
23 C7 PARAFFINS DHA 23.270 0.040
24 C8 PARAFFINS DHA 15.216 0.015
25 C9 PARAFFINS DHA 2.597 9.639
26 C10 PARAFFINS DHA 1.206 50.215
27 C11 PARAFFINS DHA 0.130 5.833
28 C12 PARAFFINS DHA 0.000 0.053
29 C13 PARAFFINS DHA 0.000 0.000
30 C14 PARAFFINS DHA 0.000 0.000
31 C5 OLEFINS DHA 0.000 0.000
32 C6 OLEFINS DHA 0.000 0.000
33 C7 OLEFINS DHA 0.000 0.000
34 C8 OLEFINS DHA 0.000 0.000
35 C9 OLEFINS DHA 0.000 0.000
36 C10 OLEFINS DHA 0.000 0.000
37 C11 OLEFINS DHA 0.000 0.000
38 C12 OLEFINS DHA 0.000 0.000
39 C13 OLEFINS DHA 0.000 0.000
40 C5 NAPHTHENE DHA 0.461 0.000
41 C6 NAPHTHENE DHA 11.038 0.000
42 C7 NAPHTHENE DHA 15.317 0.028
43 C8 NAPHTHENE DHA 5.549 0.037
44 C9 NAPHTHENE DHA 0.676 6.906
45 C10 NAPHTHENE DHA 0.208 6.805
46 C11 NAPHTHENE DHA 0.058 2.122
47 C12 NAPHTHENE DHA 0.000 0.018
48 POLYNAPHTHENE DHA 0.000 0.000
49 C6 AROMATIC DHA 1.109 0.000
50 C7 AROMATIC DHA 2.206 0.038
51 C8 AROMATIC DHA 1.140 0.101
52 C9 AROMATIC DHA 0.346 3.333
53 C10 AROMATIC DHA 0.244 5.187
54 C11 AROMATIC DHA 0.050 0.271
55 C12 AROMATIC DHA 0.000 0.162
56 UNKNOWNS DHA 0.709 9.191
DETAILED HYDROCARBON ANALYSIS
RESULTS
NO. COMPOSITION METHOD
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NO. TEST METHOD UNIT RESULTS
1 Density @ 15 °C ASTM D4052 g/cm3 0.7017
2 API Gravity Calculated degree 70.10
3 Basic Sediment & Water ASTM D4007 vol. % 0.00
4 Water Content ASTM D4928 vol. % 0.01
5 Reid Vapor Pressure @ 37.8°C ASTM D5191 kPa 63.7
6 Total Acid Number ASTM D664 mgKOH/g <0.05
7 Flash Point IP 170 °C < -10.0
8 Pour Point ASTM D5853 °C <-36
9 Colour Saybolt ASTM D156 - +26
10 Total Sulphur ASTM D4294 mg/kg 61
11 Salt Content ASTM D3230 lb/1000bbls 0.6
12 Nitrogen Content ASTM D4629 ppm wt < 1
13 Ash Content ASTM D482 wt % <0.001
14 Wax Content UOP 46 wt % < 5.0
15 MCRT - 100% Sample ASTM D4530 wt % < 0.01
16 Kinematic Viscosity @ 40°C ASTM D445 cSt $
17 Kinematic Viscosity @ 70°C ASTM D445 cSt $
18 Characterisation Factor UOP 375 - 11.93
19 Gross Calorific Value ASTM D240 MJ/kg 47.38
20 Asphaltenes IP 143 wt % <0.05
21 Mercury UOP 938 ppb wt 1
22 Metal
Sodium (Na) IP 470 ppm wt 34.1
Potassium (K) IP 470 ppm wt < 1
Copper (Cu) IP 470 ppm wt < 1
Lead (Pb) IP 470 ppb wt < 1
Iron (Fe ) IP 470 ppm wt 2.6
Nickel (Ni) IP 470 ppm wt < 1
Vanadium (V) IP 470 ppm wt < 1Arsenic (As) SGS In-House No. L/INH/121 ppb wt < 1
Remark :
1) $ - Sample evaporate at this temperature
PRELIMINARY ANALYSIS ON CRUDE
26/05/2014 ( Revision 1 ) 7 Reliance Condensate Assay Report
Tests Method Unit C5 - 70 70 - 90 90 - 140 140 - 149 149 - 155 155 - 185 175 - 185
Yield on Crude ASTM D2892 vol % 36.43 8.32 38.72 1.82 0.93 2.71 0.93
Yield on Crude ASTM D2892 wt % 34.49 8.58 41.02 1.98 1.00 3.01 1.04
Density ASTM D 4052 g/cm3 0.6598 0.7184 0.7382 0.7589 0.7611 0.7784 0.7866
API Gravity Calculated degree 82.93 65.41 60.13 54.88 54.34 50.21 48.32
Sulphur ASTM D 3120 ppm wt < 1 < 1 11
Sulphur ASTM D 4294 mg/kg 69 88
Sulphur ASTM D 4294 ppm wt 0.0178 0.0275
Nitrogen ASTM D 4629 wt % < 1 < 1 < 1 < 1 < 1 < 1 < 1
Total Acid Number ASTM D 664 mgKOH/g <0.05 <0.05 @ @
Smoke Point ASTM D 1322 mm 34.0 34.5 28.5 28.5
Flash Point ( Abel ) IP 170 °C 23.5 31.5 @ @
Flash Point ( PMCC ) ASTM D 93 °C
Freezing Point ASTM D 2386 °C <-65.0 <-65.0 -61.5 <-58.5
Aniline Point ASTM D 611 °C 57.35 61.00 58.65 @
Colour Saybolt ASTM D 156 - +30 +30 +30 +30 +30 +30 +30
Colour ASTM ASTM D 1500 -
Reseach Octane Number ASTM D 2699 - 68.5 65.5 54.0
Kinematic Viscosity @ - 20°C ASTM D 445 cSt 1.802 2.109 2.610 3.299
Reid Vapour Pressure ASTM D 5191 kPa 89.8 31.9 16.9
Cetane Index ASTM D 976 - 34.07 37.85 39.42 42.25
Ash Content ASTM D 482 wt % <0.001 <0.001 <0.001 <0.001
Mercaptan Sulphur UOP 163 ppm wt 9.4 13.5 @ @
- Paraffins DHA vol % 87.799 60.878 59.694 64.060 72.829 60.557 53.938
- Olefins DHA vol % 0.000 0.000 0.000 0.000 0.000 0.000 0.000
- Naphthenes DHA vol % 9.073 36.497 34.783 21.411 18.377 11.944 13.036
- Aromatics DHA vol % 1.670 2.608 4.756 10.149 7.010 18.092 22.663
- Total C14 + DHA vol % 0.000 0.000 0.000 0.000 0.000 0.000 0.000
- Unknowns DHA vol % 1.457 0.017 0.768 4.380 1.784 9.407 10.363
Naphathalene Content ASTM D 1840 vol % <0.01 <0.01 <0.01 <0.01
Mercury UOP 938 ppb wt 1 1 < 1 1 <1 <1 1
Distillation ASTM D 86
- Initial Boiling Point °C 36.8 73.8 96.7 133.5* 135.7* 144.0* 159.9*
- 5% °C 44.8 75.9 98.7 136.3* 143.9* 152.2* 168.0*
- 10% °C 45.9 76.6 99.4 137.3* 146.6* 153.4* 172.3*
- 20% °C 47.3 77.2 100.6 142.5* 150.8* 160.5* 176.5*
- 30% °C 48.7 77.8 101.7 143.8* 153.7* 164.7* 177.7*
- 40% °C 50.4 78.5 102.8 146.0* 154.7* 168.2* 178.6*
- 50% °C 52.3 79.4 104.3 148.2* 155.4* 171.0* 183.1*
- 60% °C 54.6 80.4 106.1 151.3* 156.0* 174.7* 185.9*
- 70% °C 57.4 81.8 108.5 154.1* 158.7* 177.5* 189.6*
- 80% °C 60.6 83.7 112.0 154.9* 161.8* 178.5* 192.9*
- 90% °C 63.9 86.7 117.8 155.9* 166.0* 185.4* 198.8*
- 95% °C 65.6 89.1 122.6 160.7* 168.2* 190.8* 200.4*
- Final Boiling Point °C 71.8 102.1 140.3 171.0* 178.1* 204.2* 212.6*
- Recovery vol % 99.0 98.9 98.9
- Residue vol % 0.9 0.9 0.9
- Loss vol % 0.1 0.2 0.2
Remarks :
1) @ - Insufficient sample
2) * - Using ASTM D2887 ( Insufficient to test using ASTM D86 )
RESULTS
ANALYSIS FOR PRODUCT CUT
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Tests Method Unit 185 - 200 200 +
Yield on Crude ASTM D2892 vol % 1.00 0.82
Yield on Crude ASTM D2892 wt % 1.14 0.96
Density ASTM D 4052 g/cm3 0.7996 0.8193
API Gravity Calculated degree 45.38 41.12
Sulphur ASTM D 4294 wt % 0.0396 0.0675
Nitrogen ASTM D 4629 ppm wt < 1 198
Total Acid Number ASTM D 664 mgKOH/g @ 0.173
Smoke Point ASTM D 1322 mm 25.5
Flash Point ( Abel ) IP 170 °C @
Flash Point ( PMCC ) ASTM D 93 °C 80.5
Pour Point ASTM D97 °C +45
Freezing Point ASTM D 2386 °C -53.5
Aniline Point ASTM D 611 °C 60.85 101.95
Colour Saybolt ASTM D 156 - +30
Colour ASTM ASTM D 1500 - D8.0
Kinematic Viscosity @ - 20°C ASTM D 445 cSt 4.008
Kinematic Viscosity @ 40°C ASTM D 445 cSt 1.199
Kinematic Viscosity @ 50°C ASTM D 445 cSt 20.80
Kinematic Viscosity @ 75°C ASTM D 445 cSt 6.776
Kinematic Viscosity @ 100°C ASTM D 445 cSt 4.300
Cetane Index ASTM D 976 - 44.43
MCRT - 100% Sample ASTM D 4530 wt % 2.56
Mercaptan Sulphur UOP 163 ppm wt @
- Aromatics ASTM D 1319 vol % 12.3
- Olefins ## vol % 0.0
- Saturates ASTM D 1319 vol % 87.7
Ash Content ASTM D 482 wt % <0.001 <0.001
Naphthalene Content ASTM D 1840 vol % <0.01
Asphaltenes IP 143 wt % <0.05
Wax Content UOP 46 wt % 14.9
Nickel (Ni) ASTM D 5863 ppm wt 1.2
Vanadium (V) ASTM D 5863 ppm wt < 1
Distillation ASTM D 86
- Initial Boiling Point °C 169.1* 188.7*
- 5% °C 175.8* 204.1*
- 10% °C 180.4* 211.5*
- 20% °C 187.4* 220.0*
- 30% °C 191.9* 229.3*
- 40% °C 197.2* 235.6*
- 50% °C 199.5* 244.6*
- 60% °C 200.5* 251.8*
- 70% °C 204.2* 259.9*
- 80% °C 209.1* 266.4*
- 90% °C 216.2* 276.1*
- 95% °C 219.8* 284.1*
- Final Boiling Point °C 233.6* 291.0*
- Recovery vol %
- Residue vol %
- Loss vol %
Remark :
1) ## - Confirm by ASTM D1159
2) * - Using ASTM D2887 ( Insufficient to test using ASTM D86 )
3) @ - Insufficient sample
RESULTS
ANALYSIS FOR PRODUCT CUT
26/05/2014 ( Revision 1 ) 9 Reliance Condensate Assay Report
