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RMP 2004 Status and Trends Program. CCSF Sediment Trace Metals analyses. Contract #4981 2 3 4 5 6 7 8 9 10 11 12 13 14 15 17 18 19 20 21 22 23 24 25 26 27
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1 498 RMP 04S - 77 BC11 SedChem 7/30/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw2 498 RMP 04S - 170 SB020S SedChem 8/2/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw3 498 RMP 04S - 85 BD31 SedChem 7/29/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw4 498 RMP 04S - 207 SPB017S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw5 498 RMP 04S - 222 SPB019S SedChem 7/29/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw6 498 RMP 04S - 200 SPB016S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw7 498 RMP 04S - 162 SB019S SedChem 8/2/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw8 498 RMP 04S - 192 SPB015S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw9 498 RMP 04S - 185 SPB002S SedChem 7/29/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw10 498 RMP 04S - 61 BA10 SedChem 8/3/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw11 498 RMP 04S - 69 BA41 SedChem 8/2/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw12 498 RMP 04S - 177 SPB001S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw13 498 RMP 04S - 342 SU019S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw14 498 RMP 04S - 215 SPB018S SedChem 7/28/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw15 498 RMP 04S - 312 SU015S SedChem 7/27/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw16 498 RMP 04S - 31 LSB017S SedChem 8/3/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw17 498 RMP 04S - 305 SU002S SedChem 7/27/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw18 498 RMP 04S - 260 CB016S SedChem 7/30/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw19 498 RMP 04S - 24 LSB016S SedChem 8/3/2004 Integrated 1 04RMPS&T CCSF Sediment WholeSediment TE dw
Cristina Grosso, John Ross, Don Yee, Sarah Lowe
Amy Franz, Pedrag Stevanovic, Jennifer Hunt
• Upload RMP analytical results from laboratories into the relational database
format and continue to QA/QC these data
• Completed phase I of getting the labs to submit data in new standardized reporting formats.
2005: RMP Data Management
Sediment
Site Code Cruise # Qual Result MDL Unit Qual Result MDL Unit Qual Result MDL Unit
BD15 2000-02 0.200 0.020 mg/kg 0.411 0.090 mg/kg b 57.848 0.090 mg/kgBD22 2000-02 0.194 0.020 mg/kg 0.285 0.090 mg/kg b 52.760 0.090 mg/kgBD41 2000-02 0.041 0.020 mg/kg 0.184 0.090 mg/kg b 16.546 0.090 mg/kgBD15 2000-07 0.195 0.020 mg/kg 0.363 0.100 mg/kg 49.194 0.100 mg/kgBD22 2000-07 0.190 0.020 mg/kg 0.331 0.090 mg/kg 52.325 0.090 mg/kgBD31 2000-07 0.182 0.020 mg/kg 0.423 0.090 mg/kg 54.733 0.090 mg/kgBD41 2000-07 0.081 0.020 mg/kg 0.175 0.100 mg/kg 23.710 0.100 mg/kgBD15 2001-02 ND 0.147 mg/kg 0.333 0.074 mg/kg b 54.081 0.074 mg/kgBD22 2001-02 ND 0.173 mg/kg 0.225 0.087 mg/kg b 51.361 0.087 mg/kgBD41 2001-02 ND 0.080 mg/kg 0.069 0.040 mg/kg b 16.696 0.040 mg/kgBD15 2001-08 0.204 0.010 mg/kg 0.220 0.070 mg/kg 58.920 0.070 mg/kgBD22 2001-08 0.176 0.010 mg/kg 0.240 0.070 mg/kg 53.100 0.070 mg/kgBD31 2001-08 0.189 0.020 mg/kg 0.220 0.080 mg/kg 56.730 0.080 mg/kgBD41 2001-08 0.055 0.010 mg/kg 0.130 0.060 mg/kg 24.570 0.060 mg/kgBD31 2002-07 ND 0.090 mg/kg 0.340 0.090 mg/kg 50.920 0.090 mg/kgSPB001S 2002-07 0.180 0.090 mg/kg 0.270 0.090 mg/kg 42.100 0.090 mg/kgSPB002S 2002-07 0.090 0.090 mg/kg 0.300 0.090 mg/kg 45.970 0.090 mg/kgSPB003S 2002-07 0.160 0.100 mg/kg 0.250 0.100 mg/kg 53.660 0.100 mg/kgSPB004S 2002-07 0.210 0.100 mg/kg 0.380 0.100 mg/kg 49.160 0.100 mg/kgSPB005S 2002-07 ND 0.080 mg/kg 0.300 0.080 mg/kg 41.230 0.080 mg/kgSPB006S 2002-07 0.110 0.090 mg/kg 0.270 0.090 mg/kg 34.990 0.090 mg/kgSPB007S 2002-07 0.140 0.090 mg/kg 0.290 0.090 mg/kg 52.980 0.090 mg/kgSPB008S 2002-07 0.110 0.090 mg/kg 0.350 0.090 mg/kg 55.520 0.090 mg/kg
Ag Cd Cu
Maintain public access of RMP data
through our Web Query Tool
2006: Data Management
Upload RMP analytical results from laboratories into the SWAMP comparable relational database and continue to QA/QC these data;
Redesign the web-based data access tool to interface with the new relational database format.
Continue with developing a tool for Status & Trends laboratories to submit electronic data via the web;
Develop tools to increase the efficiency of data review; Upload select datasets from RMP Pilot & Special Studies (or other
studies) into the RMP SWAMP comparable relational database so that the data could be downloaded using the data access tool.
2005: RMP Website
2005: RMP Website – Program information
2005: RMP Website - Data Access
SITE_CODE CRUISE_TYPE SITE_NAME Lat in DD long in DD DatumBA10 WATER Coyote Creek 37.46868 -122.06320 NAD-83BA20 WATER South Bay 37.49315 -122.08792 NAD-83BA30 WATER Dumbarton Bridge 37.51375 -122.13462 NAD-83BA40 WATER Redwood Creek 37.55878 -122.20912 NAD-83BB15 WATER San Bruno Shoal 37.61477 -122.28205 NAD-83BB30 WATER Oyster Point 37.66910 -122.32862 NAD-83BB70 WATER Alameda 37.74225 -122.32207 NAD-83BC10 WATER Yerba Buena Island 37.82158 -122.34950 NAD-83BC20 WATER Golden Gate 37.86350 -122.67333 NAD-83BC30 WATER Richardson Bay 37.86210 -122.47868 NAD-83BC41 WATER Point Isabel 37.88690 -122.34272 NAD-83BC60 WATER Red Rock 37.91765 -122.43573 NAD-83BD15 WATER Petaluma River 38.11148 -122.48655 NAD-83BD20 WATER San Pablo Bay 38.04823 -122.42185 NAD-83BD30 WATER Pinole Point 38.02423 -122.36262 NAD-83BD40 WATER Davis Point 38.05072 -122.27768 NAD-83BD50 WATER Napa River 38.09672 -122.26068 NAD-83BF10 WATER Pacheco Creek 38.05110 -122.09898 NAD-83BF20 WATER Grizzly Bay 38.11588 -122.03952 NAD-83BF40 WATER Honker Bay 38.06702 -121.93437 NAD-83BG20 WATER Sacramento River 38.05978 -121.81020 NAD-83BG30 WATER San Joaquin River 38.02062 -121.80522 NAD-83BW10 WATER Standish Dam 37.45167 -121.92150 NAD-83BW15 WATER Guadalupe River 37.42600 -121.98000 NAD-83C-1-3 WATER Sunnyvale 37.43425 -122.01010 NAD-83C-3-0 WATER San Jose 37.46023 -121.97560 NAD-83
Download data
Get maps
Get site locations
2006: RMP Website - Plans
Website maintenance and updates in 2006
2005: Status and Trends Monitoring
Successful sampling season
Contracts came in on budget
W=4S=8
W=6S=8
W=4S=8
W=10S=8
W=4S=8
Rivers
SuisunSan PabloBay
CentralBay
SouthBay
Lower SouthBay
Number of SAMPLES
Water: 31 totalSediment:47 total
= Historical fixed stationW=4S=8
W=6S=8
W=4S=8
W=10S=8
W=4S=8
Rivers
SuisunSan PabloBay
CentralBay
SouthBay
Lower SouthBay
Number of SAMPLES
Water: 31 totalSediment:47 total
W=4S=8
W=5S=8
W=4S=8
W=9S=8
W=4S=8
Rivers
SuisunSan PabloBay
CentralBay
SouthBay
Lower SouthBay
Rivers
SuisunSan PabloBay
CentralBay
SouthBay
Lower SouthBay
Number of SAMPLES
Water: 31 totalSediment:47 total
= Historical fixed station = Historical fixed station
2005: Status and Trends Monitoring
WATER SAMPLING
July 2005
31 sites (5 historic RMP)Backup site
Target site
2005: Status and Trends Monitoring
SEDIMENT SAMPLING
July/August 2005
47 sites (7 historic RMP)
Sediment organics analyses by High Resolution Mass Spectrometer
Backup site
Target site
2005: Status and Trends Monitoring
BIVALVE BIOACCUMULATION SAMPLING
June - Sept 2005
11 sites (all historical RMP)
Deployed Mytilus (9 sites)
Trawled for Corbicula Analyzed for organics
(including PBDEs)
2006: Status and Trends Monitoring
Water, Sediment, and Bivalve Bioaccumulation sampling
(same effort as in 2005)
NewWATER Chemistry
Drop Dissolved Organic Contaminants in Water (this year)
WATER Toxicity
Scheduled Every 5-years
Estuary Tributaries
Suisun Creek
Napa River
Petaluma River
San Lorenzo Creek
Coyote Creek
Note: Site locations are not accurately placed on this map.
San Mateo Creek
REVIEW
SEDIMENT INVESTIGATION
IN THE TRIBUTARIES
Nov & April (2004-2005)
Six Tributaries, two locations ea.,
two sampling events. Sediment Toxicity-two amphipods
(Hyalella (FW) + Eohaustorius (Est.)) Sediment chemistry at upstream sites
and toxic downstream sites (RMP analyte list + pyrethroids)
Water Toxicity Sampling (April only)
Five Tributaries
Ceriodaphnia, Americamysis, Menidia
Diazinon & Chlorpyrifos
2005 S&T: Episodic Toxicity Monitoring & PRISM
November Sampling (Nov. 1st – 4th)
April Sampling (Apr. 18th – 20th)
Sampled Tributaries
Suisun Creek
Napa River
Petaluma River
San Lorenzo Creek
Coyote Creek
Note: Site locations are not accurately placed on this map.
San Mateo Creek
November - 2004
Preliminary Results – Sediment Toxicity
Sampled Tributaries
Suisun Creek
Napa River
Petaluma River
San Lorenzo Creek
Coyote Creek
Note: Site locations are not accurately placed on this map.
San Mateo Creek
April - 2005
Preliminary Results – Sediment Chemistry
MIN MAX MIN MAX% Fines (<63 um) 15 67 24 100TOC (%) 0.5 2.7Bifenthrin 1.9 10.3 0 2.4Cyfluthrin 0 8.62 0 0Cypermethrin 0 4.17 0 0Esfenvalerate 0 0 0 0Lambda-cyhalothrin 0 0 0 0Permethrin 0 20.5 0 0
Nov Apr
NA
Preliminary Results – Sediment Chemistry
NBay SBayERM MIN MAX MIN MAX AVG AVG
% Fines (<63 um) 15 67 24 100 64 86TOC (%) 0.5 2.7 1.1 1.4Sum of DDTs (SFEI) 46.1 6.7 122.3 2.3 44.6 3.5 4.8Sum of Chlordanes (SFEI) 6 0 58.2 0 45.8 0.5 1.4Aldrin 0 0.5 0 0.6 0.8 0.9Dieldrin 8 0 6.7 0 3.58 0.3 0.5Endrin 0 0 0 0 0.3 1.4Sum of PBDEs (SFEI) 0 8 0 23 3 34Sum of PCBs (SFEI) 180 4 36 7 35 3 15
Nov Apr
NA
Preliminary Results – Sediment Chemistry
NBay SBayERM MIN MAX MIN MAX AVG AVG
% Fines (<63 um) 15 67 24 100 64 86Ag 3.7 0.2 0.7 0.2 0.3Al 36175 56700 33584 36543As 70 2.5 8.0 10.1 8.5Cd 9.6 0.1 0.4 0.2 0.2Cu 270 20 57 42 40Fe 9313 32695 39065 39174Hg 0.71 0.05 0.70 0.03 1.53 0.22 0.32Mn 364 1134 989 1323Ni 51.6 9 125 90 88Pb 218 18 63 17 24Se 0.1 0.7 0.3 0.3Zn 410 62 198 108 125
NA
NA
NA
NA
NA
NA
NA
NA
Nov Apr
NA
NA
NA
2006 Proposal: Episodic Toxicity Monitoring
Water Board priority to investigate the causes of the persistent sediment toxicity observed in the Estuary
Focus on locations which have been shown to be toxic and work to investigate the potential causes.
A workgroup will convene in the spring of 2006 to begin planning the detailed workplan
Sampling will occur in the wet season of next year (Nov 06 – Apr 07)
timing will allow for coordination with other RMP projects (EEPS).
• Sample Water and Sediment twice & archive sediments
• Test for toxicity and water/sediment quality
if toxic sediments
if really toxic sediments then add
Resample to investigate duration of toxicityPerform sediment chemistry (RMP list + pyrethroids)
Resample to perform sediment TIEs
2006 Proposal: Episodic Toxicity Monitoring
Focus on a couple tributaries known to be toxic