CpRuIIPF6/Quinaldic Acid-Catalyzed Chemoselective Allyl Ether Cleavage. A Simple and Practical...

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2004 Deprotection O 0345 CpRu II PF 6 /Quinaldic Acid-Catalyzed Chemoselective Allyl Ether Cleavage. A Simple and Practical Method for Hydroxyl Deprotection. — CpRu II PF6/quinaldic acid is found to be a new and efficient catalytic system for the cleavage of a wide variety of allyl ethers. Under these conditions multifunctional compounds including peptides and nucleosides undergo allyl ether cleavage with excellent chemoselectivity. — (TANAKA, S.; SABURI, H.; ISHIBASHI, Y.; KITAMURA*, M.; Org. Lett. 6 (2004) 11, 1873-1875; Res. Cent. Mater. Sci., Nagoya Univ., Chikusa, Nagoya 464, Japan; Eng.) — Jannicke 40- 064

Transcript of CpRuIIPF6/Quinaldic Acid-Catalyzed Chemoselective Allyl Ether Cleavage. A Simple and Practical...

Page 1: CpRuIIPF6/Quinaldic Acid-Catalyzed Chemoselective Allyl Ether Cleavage. A Simple and Practical Method for Hydroxyl Deprotection.

2004

DeprotectionO 0345 CpRuIIPF6/Quinaldic Acid-Catalyzed Chemoselective Allyl Ether Cleavage. A

Simple and Practical Method for Hydroxyl Deprotection. — CpRuIIPF6/quinaldic acid is found to be a new and efficient catalytic system for the cleavage of a wide variety of allyl ethers. Under these conditions multifunctional compounds including peptides and nucleosides undergo allyl ether cleavage with excellent chemoselectivity. — (TANAKA, S.; SABURI, H.; ISHIBASHI, Y.; KITAMURA*, M.; Org. Lett. 6 (2004) 11, 1873-1875; Res. Cent. Mater. Sci., Nagoya Univ., Chikusa, Nagoya 464, Japan; Eng.) — Jannicke

40- 064